What is a system? Biogeochemical Cycles - 1 • System: a collection of matter, parts, or components which are included inside a specified, often arbitrary, boundary. Class Lecture Goals 1. What are systems? 2. What are biogeochemical cycles? 3. Why are they important? 4. What is common about them? 5. Carbon and nitrogen cycles 6. Focus on the Water Cycle (Monday) • Systems often have inputs and outputs. • For dynamic systems, by definition, one or more aspects of the system change with time. – Example of a simple dynamic system: bathtub or your ‘bank’ account. Flux • The boundary Pool of a dynamic system is chosen for convenient conceptual separation for the system Reading Assignments • Examine this web page (http://www.cses.washington.edu/cig/pnwc/cc.shtml) Carbon dioxide Sugar C-pool Night Select the true statement from below for the PNW: Climate change will What are biogeochemical cycles? • Earth system has four parts – – – – 1. Increase precipitation & snowpack 2. Increase temperature & snowpack 3. Increase precipitation & decrease snowpack Answer Now! 10 Atmosphere Hydrosphere Lithosphere Biosphere • Biogeochemical cycles: The chemical interactions (cycles) that exist between the atmosphere, hydrosphere, lithosphere, and biosphere. • Abiotic (physio-chemical) and biotic processes drive these cycles • Focus on carbon, and water cycles (but could include all necessary elements for life). N - cycle weakly touched on! 1 What is common amongst them? • Each compound (water, carbon, nitrogen) typically exists in all four parts of the Earth System • There are – ‘Pools’ – Fluxes in and out of pools – Chemically or biochemically transformations • Transformations are important • Transformations can lead to positive and negative consequences Carbon Cycle Transformations Examples of Transformations 1. Carbon cycle: Organic compounds to CO2 (processes: respiration, decomposition, or fire) 2. Carbon cycle: CO2 to organic compounds (process: photosynthesis) 3. Nitrogen cycle: N2 to NO3 (atmospheric nitrogen to plant utilizable nitrate) (process: N-fixation) 4. Nitrogen cycle: N2 to NH3 (plant utilizable ammonia) (process: Haber-Bosch Industrial N-fixation) 5. Water cycle: Liquid water to water vapor (process: evaporation and evapo-transpiration) 6. Water cycle: Water vapor to liquid water (process: condensation) Carbon Cycle Data 760 • Burning of fossil fuels • Land conversion • Cement 59 5000 • Role of Oceans • Role of terrestrial plants (trees & soils) http://www.epa.gov/climatechange/kids/carbon_cycle_version2.html Changes in Atmospheric C02 - 1 Dr. Pieter Tans, NOAA/ESRL (www.esrl.noaa.gov/gmd/cgg/trends) Lithosphere Changes in Atmospheric C02 - 2 http://www.whrc.org/resources/online_publications/warming_earth/scientific_evidence.htm 2 Key Aspects of the Carbon Cycle • Carbon is the skeleton of all life. • Carbon dioxide is a critical gas: – Taken up by plants in photosynthesis – Released by plants and animals in respiration – Released during decomposition (and fires) – Greenhouse gas (greenhouse effect - your car in the sun) Question: Photosynthesis is an example of a pool 1. True 2. False 10 Answer Now! Nitrogen Cycle Nitrogen Cycle Forms & Sources of biologically available nitrogen (N 2 ) Forms of Nitrogen (N 2 ) 1. N2 - inert gas, 78% of the atmosphere 2. NO, N20, NO2 - other gases of nitrogen, not directly biologically important. Part of the gases found in smog. 3. NO3 - (nitrate) and NH4+ (ammonium) -- ionic forms of nitrogen that are biologically usable. http://soil.gsfc.nasa.gov/NFTG/nitrocyc.htm Nitrogen Cycle For plants • NO3- (nitrate) • NH4+ (ammonium) • Sources: N-fixation by plants (N2 to NH3 and N2 to NO3), lightening, bacteria decomposition of organic N (amino acids & proteins) For animals • Organic forms: amino acids and proteins (from plants or other animals) http://soil.gsfc.nasa.gov/NFTG/nitrocyc.htm Nitrogen Sources over time Losses of nitrogen from system • In bogs, lakes (places of low oxygen), NO3- is converted to N2 by bacteria (get their oxygen from the NO3 ) • Volatilization of NH4 + (urea) to ammonia gas (NH3 ) warm, dry conditions. • Leaching of NO3 - (nitrate) • Erosion • Fire (combustion) http://soil.gsfc.nasa.gov/NFTG/nitrocyc.htm 3 Nitrogen Cycle: Key Points • Nitrogen is in the atmosphere as N2 (78%) • N2 is an inert gas and cannot be used by plants or animals • N2 can be converted to a usable form via – Lightening – N-fixing plants and cyanobacteria – Industrial process Summary • • • • • 1. What are systems? 2. What are biogeochemical cycles? 3. Why are they important? 4. What is common about them? 5. Carbon and nitrogen cycles • Nitrogen limits plant growth • Nitrogen is easily lost from biological systems 4
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