Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 13/08/2015 Revision date: 07/11/2016 Supersedes: 13/08/2015 Version: 2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1.
Product identifier
Product form
: Substance
Trade name
: Acetyl chloride Extra Pure
Chemical name
: acetyl chloride
EC index no
: 607-011-00-5
EC no
: 200-865-6
CAS No
: 75-36-5
Product code
: ACCH-00T
Formula
: CH3COCl
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Main use category
1.2.2.
: Laboratory use
Uses advised against
No additional information available
1.3.
Details of the supplier of the safety data sheet
labbox labware s.l.
Joan Peiró i Belis, 2
08339 Vilassar de Dalt - ES
T +34 937 552 084 - F +34 937 909 532
[email protected] - www.labkem.com
1.4.
Emergency telephone number
Emergency number
: +34 937 552 084 ( Office Hours)
SECTION 2: Hazards identification
2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU)
2015/830 (REACH Annex II)
Flammable liquids, Category 2
H225
Skin corrosion/irritation, Category 1B H314
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP)
:
Signal word (CLP)
: Danger
Hazard statements (CLP)
: H225 - Highly flammable liquid and vapour
H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP)
: P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
EUH-statements
: EUH014 - Reacts violently with water
GHS02
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
2.3.
Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1.
Substances
Name
Product identifier
%
Acetyl chloride
(CAS No) 75-36-5
(EC no) 200-865-6
(EC index no) 607-011-00-5
100
Full text of H-statements: see section 16
3.2.
Mixtures
Not applicable
SECTION 4: First aid measures
4.1.
Description of first aid measures
First-aid measures general
: Get medical advice/attention if you feel unwell.
First-aid measures after inhalation
: Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical
advice. Allow the victim to rest. Assure fresh air breathing.
First-aid measures after skin contact
: Wash with plenty of soap and water. Remove affected clothing and wash all exposed skin area
with mild soap and water, followed by warm water rinse. Get medical advice/attention.
First-aid measures after eye contact
: Rinse eyes with water as a precaution. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a physician
immediately.
First-aid measures after ingestion
: Rinse mouth. Do NOT induce vomiting.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after skin contact
: Causes severe burns.
Symptoms/injuries after eye contact
: Serious damage to eyes.
4.3.
Indication of any immediate medical attention and special treatment needed
Never give anything by mouth to an unconscious person.
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
: Sand. Carbon dioxide. Foam. Dry powder.
Unsuitable extinguishing media
: Strong water jet. Do not use extinguishing media containing water.
5.2.
Special hazards arising from the substance or mixture
Fire hazard
: Highly flammable liquid and vapour.
Hazardous decomposition products in case of
fire
: fume. Corrosive vapours.
5.3.
Advice for firefighters
Precautionary measures fire
: Evacuate area.
Firefighting instructions
: Evacuate area. Exercise caution when fighting any chemical fire.
Protection during firefighting
: Do not attempt to take action without suitable protective equipment.
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
6.1.1.
For non-emergency personnel
Emergency procedures
6.1.2.
For emergency responders
Emergency procedures
6.2.
: Only qualified personnel equipped with suitable protective equipment may intervene. Notify
police and fire brigade as soon as possible.
: Stop leak if safe to do so.
Environmental precautions
Avoid release to the environment. Do not allow water (or moist air) contact with this material.
6.3.
Methods and material for containment and cleaning up
For containment
: Collect spillage.
Methods for cleaning up
: Take up liquid spill into absorbent material. Mechanically recover the product. On land, sweep
or shovel into suitable containers.
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Other information
6.4.
: Dispose of materials or solid residues at an authorized site.
Reference to other sections
See Heading 8.
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
Additional hazards when processed
: Keep containers closed.
Precautions for safe handling
: Eliminate all ignition sources if safe to do so. Avoid contact with skin, eyes and clothing. Wash
hands and other exposed areas with mild soap and water before eating, drinking or smoking
and when leaving work. Do not eat, drink or smoke when using this product. Do not breathe
dust. Do not breathe vapours.
Hygiene measures
: Do not eat, drink or smoke when using this product. Always wash hands after handling the
product.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Ground/bond container and receiving equipment. Comply with applicable regulations.
Storage conditions
: Store in a closed container. Keep in fireproof place. Keep only in original container. Heat
sources. Direct sunlight. Keep cool. Keep away from ignition sources.
Incompatible products
: Strong acids. Oxidizing agent. Strong bases.
Incompatible materials
: Heat sources. Sources of ignition. Direct sunlight.
Special rules on packaging
: Store in a closed container. Keep only in original container.
7.3.
Specific end use(s)
Laboratory chemicals.
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
No additional information available
8.2.
Exposure controls
Personal protective equipment:
Protective clothing. Gloves. Safety glasses.
Environmental exposure controls:
Avoid release to the environment.
Consumer exposure controls:
Avoid contact during pregnancy/while nursing.
Other information:
The present safety data sheet is consistent with the specific conditions relied on to justify the registration of the substance as isolated intermediate.
Do not eat, drink or smoke when using this product.
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Colour
: Colourless.
Odour
: Disagreeable.
Odour threshold
: No data available
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: -112 °C
Freezing point
: No data available
Boiling point
: No data available
Flash point
: 5 °C
Auto-ignition temperature
: 390 °C
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: 2,7
Relative density
: No data available
Density
: 1,1 g/cm³
Solubility
: No data available
Log Pow
: No data available
Viscosity, kinematic
: No data available
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidising properties
: No data available
Explosive limits
: 7,3 - 19 vol %
9.2.
Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.
Reactivity
Highly reactive material.
10.2.
Chemical stability
Stable under normal conditions.
10.3.
Possibility of hazardous reactions
Reacts violently with water.
10.4.
Conditions to avoid
Water, humidity. Heat. Sparks. Overheating.
10.5.
Incompatible materials
Strong acids. Strong bases. Water.
10.6.
Hazardous decomposition products
Carbon dioxide. fume. Carbon monoxide.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
Acetyl chloride Extra Pure (75-36-5)
LD50 oral rat
: Not classified
910 mg/kg
Skin corrosion/irritation
: Causes severe skin burns and eye damage.
Serious eye damage/irritation
: Serious eye damage, category 1, implicit
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
STOT-single exposure
: Not classified
STOT-repeated exposure
: Not classified
Aspiration hazard
: Not classified
SECTION 12: Ecological information
12.1.
Toxicity
No additional information available
12.2.
Persistence and degradability
No additional information available
12.3.
Bioaccumulative potential
No additional information available
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
12.4.
Mobility in soil
No additional information available
12.5.
Results of PBT and vPvB assessment
No additional information available
12.6.
Other adverse effects
No additional information available
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations.
Additional information
: Handle empty containers with care because residual vapours are flammable. Do not allow
water (or moist air) contact with this material.
Ecology - waste materials
: Avoid release to the environment. Hazardous waste due to toxicity.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1.
UN number
UN-No. (ADR)
: 1717
UN-No. (IMDG)
: 1717
UN-No. (IATA)
: 1717
UN-No. (ADN)
: 1717
UN-No. (RID)
: 1717
14.2.
UN proper shipping name
Proper Shipping Name (ADR)
: ACETYL CHLORIDE
Proper Shipping Name (IMDG)
: ACETYL CHLORIDE
Proper Shipping Name (IATA)
: Acetyl chloride
Proper Shipping Name (ADN)
: ACETYL CHLORIDE
Proper Shipping Name (RID)
: ACETYL CHLORIDE
Transport document description (ADR)
: UN 1717 ACETYL CHLORIDE, 3 (8), II, (D/E)
Transport document description (IMDG)
: UN 1717 ACETYL CHLORIDE, 3 (8), II (5°C c.c.)
Transport document description (IATA)
: UN 1717 Acetyl chloride, 3 (8) (8), II
Transport document description (ADN)
: UN 1717 ACETYL CHLORIDE, 3 (8), II
Transport document description (RID)
: UN 1717 ACETYL CHLORIDE, 3 (8), II
14.3.
Transport hazard class(es)
ADR
Transport hazard class(es) (ADR)
: 3 (8)
Danger labels (ADR)
: 3, 8
:
IMDG
Transport hazard class(es) (IMDG)
: 3 (8)
Danger labels (IMDG)
: 3, 8
:
IATA
Transport hazard class(es) (IATA)
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Hazard labels (IATA)
: 3, 8
:
ADN
Transport hazard class(es) (ADN)
: 3 (8)
Danger labels (ADN)
: 3, 8
:
RID
Transport hazard class(es) (RID)
: 3 (8)
Danger labels (RID)
: 3, 8
:
14.4.
Packing group
Packing group (ADR)
: II
Packing group (IMDG)
: II
Packing group (IATA)
: II
Packing group (ADN)
: II
Packing group (RID)
: II
14.5.
Environmental hazards
Dangerous for the environment
: No
Marine pollutant
: No
Other information
: No supplementary information available
14.6.
Special precautions for user
- Overland transport
Classification code (ADR)
: FC
Limited quantities (ADR)
: 1l
Excepted quantities (ADR)
: E2
Packing instructions (ADR)
: P001, IBC02
Mixed packing provisions (ADR)
: MP19
Portable tank and bulk container instructions
(ADR)
: T8
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR)
: L4BH
Vehicle for tank carriage
: FL
Transport category (ADR)
: 2
Special provisions for carriage - Operation
(ADR)
: S2, S20
Hazard identification number (Kemler No.)
: X338
Orange plates
:
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Tunnel restriction code (ADR)
: D/E
EAC code
: 4WE
APP code
: A(fl)
- Transport by sea
Limited quantities (IMDG)
: 1L
Excepted quantities (IMDG)
: E2
Packing instructions (IMDG)
: P001
IBC packing instructions (IMDG)
: IBC02
IBC special provisions (IMDG)
: B20
Tank instructions (IMDG)
: T8
Tank special provisions (IMDG)
: TP2
EmS-No. (Fire)
: F-E
EmS-No. (Spillage)
: S-C
Stowage category (IMDG)
: B
Flash point (IMDG)
: 5°C c.c.
Properties and observations (IMDG)
: Colourless liquid. Flashpoint: 5°C c.c. Boiling point: 51°C. Reacts violently with water, evolving
hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of
moisture, highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes.
- Air transport
PCA Excepted quantities (IATA)
: E2
PCA Limited quantities (IATA)
: Y340
PCA limited quantity max net quantity (IATA)
: 0.5L
PCA packing instructions (IATA)
: 352
PCA max net quantity (IATA)
: 1L
CAO packing instructions (IATA)
: 363
CAO max net quantity (IATA)
: 5L
ERG code (IATA)
: 3C
- Inland waterway transport
Classification code (ADN)
: FC
Limited quantities (ADN)
: 1L
Excepted quantities (ADN)
: E2
Carriage permitted (ADN)
: T
Equipment required (ADN)
: PP, EP, EX, A
Ventilation (ADN)
: VE01
Number of blue cones/lights (ADN)
: 1
- Rail transport
Classification code (RID)
: FC
Limited quantities (RID)
: 1L
Excepted quantities (RID)
: E2
Packing instructions (RID)
: P001, IBC02
Mixed packing provisions (RID)
: MP19
Portable tank and bulk container instructions
(RID)
: T8
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID)
: L4BH
Transport category (RID)
: 2
Colis express (express parcels) (RID)
: CE7
Hazard identification number (RID)
: X338
14.7.
Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
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Acetyl chloride Extra Pure
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
3. Liquid substances or mixtures which are regarded as dangerous in accordance with
Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or
categories set out in Annex I to Regulation (EC) No 1272/2008
3(a) Substances or mixtures fulfilling the criteria for any of the following hazard classes or
categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4,
2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1
and 2, 2.15 types A to F
3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or
categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6,
3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than
narcotic effects, 3.9 and 3.10
40. Substances classified as flammable gases category 1 or 2, flammable liquids categories
1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with
water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric
solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation
(EC) No 1272/2008 or not.
Acetyl chloride Extra Pure
Acetyl chloride Extra Pure
Acetyl chloride Extra Pure
Acetyl chloride Extra Pure
Acetyl chloride Extra Pure
is not on the REACH Candidate List
Acetyl chloride Extra Pure
is not on the REACH Annex XIV List
15.1.2.
National regulations
Germany
VwVwS Annex reference
: Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex
1 or 2; ID No. 784)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen
: The substance is not listed
SZW-lijst van mutagene stoffen
: The substance is not listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen – Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen – Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen – Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard
: Class I-1
Store unit
: 1 liter
Classification remarks
: F <Flam. Liq. 2>; Emergency management guidelines for the storage of flammable liquids
must be followed
Recommendations Danish Regulation
: Young people below the age of 18 years are not allowed to use the product
15.2.
Chemical safety assessment
No additional information available
SECTION 16: Other information
Full text of H- and EUH-statements:
Flam. Liq. 2
Skin Corr. 1B
H225
H314
EUH014
Flammable liquids, Category 2
Skin corrosion/irritation, Category 1B
Highly flammable liquid and vapour
Causes severe skin burns and eye damage
Reacts violently with water
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product
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