Elaborate Design for Building Intrinsic Energy-saving Refineries Elaborate Design, the Basis for Building Intrinsic Energy-saving Refineries SINOPEC Engineering Incorporation Nov. 2008 Elaborate Design for Building Intrinsic Energy-saving Refineries CONTENTS 1. Summary 2. Elaborate Design, the Basis for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.2 Optimization of Main Utility Scheme 2.3 Effective Energy-saving Measures 2.4 Analysis on Differences in Energy Consumption 3. Conclusion 2 Elaborate Design for Building Intrinsic Energy-saving Refineries 1. Summary ¾New challenges to oil refining enterprises. high oil price the increasing market demand for oil products ¾The rapid growth of China’s GDP results in the increasing market demand for transportation fuel. ¾Oil refining enterprises have to build resource-saving and energy-saving refineries . ¾SEI always sticks to the principles of refinery construction in the new century, i.e. advanced technology, reasonable investment, resource conservation, energy consumption reduction and good economic benefit. 3 Elaborate Design for Building Intrinsic Energy-saving Refineries 2. Elaborate Design for Building Intrinsic Energy-saving Refineries The two typical refineries newly built in the 21st Century: ¾Refinery A processes Middle East sour crude with a sulfur content of 1.0%. A CDU/VDU-RDS-RFCC/HCU based process scheme is selected. Its light oil yield amounts to 81% and comprehensive commodity rate reaches 93%. It was put into operation in September 2006 and has run smoothly for two years. ¾Refinery B processes a crude mixture of 50% AL and 50% AH with a sulfur content of 2.56%. A CDU/VDU-DCU-HTUFCC is selected. Its light oil yield amounts to 76.1% and comprehensive commodity rate reaches 90.6%. It was put into operation in May 2008 and has run smoothly for several months. 4 Elaborate Design for Building Intrinsic Energy-saving Refineries 2. Elaborate Design for Building Intrinsic Energy-saving Refineries ¾In engineering design, an important objective of the research on project scheme is energy conservation and consumption reduction. ¾The analysis results show that the sum of energy consumption of CDU/VDU, RFCCU, HTU and CCRU in Refinery A accounts for 61.2%, while Refinery B holds a 65.4% in the same aspect. ¾The proportions of energy consumption of process units to refinery-wide energy consumption in Refinery A and Refinery B are 88.15% and 89.55%, respectively. ¾ Consumption of fuel, power and steam takes up 70~85% of the refinery-wide energy consumption. 5 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.1 The capacity of VDU, an accessory unit of CDU, should be rationally determined to minimize the investment and the energy consumption of unit. 2.1.2 Full advantages of RDS-RFCC combined process should be taken to recycle the HCO from RFCC unit to RDS unit. ¾ A large amount of aromatics component in HCO can dissolve the resin and asphaltene in residue. It improves RDS reaction, reduces carbon deposit on catalyst, decreases gas yield, and improves product distribution in HTU and FCCU. Both the light oil yield and liquid yield of FCCU are 1.5~2wt% higher than those of the conventional process. ¾ Since less slurry and coke is produced in FCC unit, the energy consumption of unit is lowered. 6 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.3 Heat exchange network should be optimized to improve the heat utilization efficiency. ¾The final temperature of heat exchange in CDU/VDU might be above 300℃. ¾Multiple circulating refluxes are designed for the fractionation tower in FCCU together with the features of product distribution. High temperature slurry reflux is used to generate MP steam in priority in catalyst cooler, while other circulating refluxes are used as heat source for the bottom reboilers in desorption tower and stabilizer, and overhead circulating reflux and low temperature heat are used as heat source for gas fractionation unit or deaerated water preheating. 7 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.4 Refinery-wide overhead gas should be collected for recovery, and the flow direction of dry gas and LPG should be carefully arranged. ¾A centralized light ends recovery facility is designed to maximize the recovery of LPG products. It is estimated that LPG recovery can be increased by 25,000~30,000 tons per year. The recovery system can be located in combination with CDU/VDU to fully utilize the low temperature heat. ¾Two trains of dry gas desulfurization are designed, one of which treat FCC dry gas, then it is directly sent for rational recovery and utilization of dilute ethylene byproduct. ¾Two or three trains of LPG desulfurization, one of which treat FCC LPG, are designed to increase the additional value of propylene product. 8 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.5 Importance should be attached to hydrogen recovery, and hydrogen resource should be allocated rationally. ¾ Both refineries have several large-scale HTUs. Low pressure separator vapor from various units is collected to desulfur. Then it is sent to PSA unit. About 10,000 tons of pure hydrogen can be recovered per year. The pressurized PSA tail gas is used as feed to the hydrogen plant. ¾According to the characteristics of hydrogen-consuming units and their requirements, most of the hydrogen-containing gas from CCRU is provided for HTU and SRU, while the rest is sent to PSA unit together with hydrogen-containing gas for purification. Pure hydrogen from PSA unit and from the hydrogen plant is provided for RDSU and HCU. And there is a connection line between the two hydrogen network to ensure the safety of hydrogen use. 9 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.6 A centralized amine regeneration system should be designed for the refinery. ¾Two regeneration towers are designed to treat rich amine from hydrogenation units and that from desulfurization units, respectively. Regenerated lean amine is collected and sent to amine-consuming units. Surge tank, which will be pressurized for use, is designed according to the pressure requirements of each unit. ¾Centralized administration can lower energy consumption, avoid long-distance transportation, decrease the pressure loss of hazardous high-concentration H2S inside the refinery, and reduce the corrosion risk of pipelines. ¾The two regeneration towers match in capacity, and the two solvent systems are connected to each other as mutual backup. 10 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.7 Advanced energy-saving technologies should be adopted. ¾A combined vacuum system of steam vacuum pumping and mechanical vacuum pumping is adopted as the overhead vacuum system in large-scale VDUs. Compared with the steam ejection vacuum pumping system, a consumption reduction of 0.5 kg oe/t of crude oil can be achieved, and the payback period is only half a year. ¾Proprietary technologies or equipment, such as highefficiency atomizing nozzle, high-efficiency stripper and highefficiency cyclone, may be used in the reactor to improve product distribution and reduce coke formation. 11 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.7 Advanced energy-saving technologies should be adopted. ¾The pressure energy of high-pressure liquid in HTU may be fully utilized to drive pumps. Hydrogen combined before heater is applied to improve heat transfer efficiency, to reduce the number of heat exchanger and to lower the pressure drop across system. ¾Advanced furnace design methods are applied to delayed coker to realize operation at low recycle ratio or even zero recycle ratio to minimize the circulation. 12 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.1 Optimization of Process Scheme and Selection of Advanced Energy-saving Equipment 2.1.8 Advanced energy-saving equipment should be adopted. ¾Advanced feed distributor and corresponding internals may be used in fractionation tower to minimize the consumption of stripping steam. ¾AC and DC electric desalting technology or high velocity electric desalting technology is adopted. ¾An innovative high-efficiency heat exchanger is adopted. ¾Energy-saving chemical process pump or high-efficiency centrifugal pump, which is equipped with energy-saving motor, is used. ¾Frequency control motor is selected for air coolers, in which the quantity and temperature of process stream varies a lot, to save power energy while ensuring a stable temperature after cooling. 13 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.2 Optimization of Main Utility Scheme 2.2.1 Furnace design should be optimized to reduce fuel consumption and improve thermal efficiency of furnace. Consumption of furnace fuel accounts for about 40% of refinerywide energy consumption, so fuel saving is of great importance to refinery-wide energy conservation. ¾Fuel system is optimized to supply clean furnace fuel. All the fuel gas produced is desulfurized to reduce its H2S content to less than 50ppm so that lowering flue gas temperature and improving the thermal efficiency of furnace may become possible. ¾Energy-saving burner is adopted to expedite the burning rate of fuel to realize forced convection by the high velocity and uniform flow of flue gas. In this way the efficiency of furnace can be increased by 2%. ¾Effective waste heat recovery facilities are designed for the 14 furnace to improve its thermal efficiency. Elaborate Design for Building Intrinsic Energy-saving Refineries 2.2 Optimization of Main Utility Scheme 2.2.2 Hot feed and heat integration of units should be realized to reduce heat loss. ¾Integrated units are designed for main process units according to the closeness requirements of their functions and materials. Only 4 integrated units are planned for the 15 main process units in both refineries. The best heat utilization scheme is to optimize the integrated heat exchange of materials from various units and select reasonable inlet/outlet temperatures. The capacity of intermediate tank farm can only ensure 2 days’ operation of downstream units. There is one central control room in the refinery, which has features of distributed control, centralized operation and centralized management. ¾Heat integration is realized between units which have a close relationship with each other. For example, the overhead waste heat from FCC fractionator is used as heat source for gas 15 fractionation unit. Elaborate Design for Building Intrinsic Energy-saving Refineries 2.2 Optimization of Main Utility Scheme 2.2.3 Low temperature heat should be fully utilized to further reduce energy consumption. Low temperature heat in process units is used to heat boiler feed water. However, no other low temperature hot trap is available for refining systems, so low temperature heat is not fully utilized. Utilization method and technology of low temperature heat is to be further studied and developed. 2.2.4 Steam system in refinery should be optimized to improve steam utilization and reduce steam consumption. Firstly, cascade utilization of steam should be realized. Secondly, power generation should be determined by steam demand. Thirdly, steam leakage should be minimized. High quality valves and steam traps should be used on steam pipelines to minimize steam leakage. 16 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.2 Optimization of Main Utility Scheme 2.2.5 Effective water saving measures should be taken. ¾Consumption of fresh water should be minimized, circulating water is used as feed water to blow down cooling tank and water tank, and effluent is sent to force circulation hot water piping system after being pressurized via a pump. ¾Purified water reuse rate should be improved. ¾Wastewater reuse rate should be improved. ¾Condensate reuse rate should be improved. A centralized condensate recovery network and treatment facilities are designed for the refinery to recover, treat and utilize refinerywide turbine condensate and condensate formed in the heating and heat tracing of process units. The recovery of condensate is above 80%. 17 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.3 Effective Energy-saving Measures for Good Energy-saving Results ¾Attention has been paid to the application of new energy-saving technologies and the adoption of advanced energy-saving equipment. In this way, design energy consumption of production units attained world advanced level, and design refinery-wide energy consumption was remarkably reduced. ¾The design energy consumption of process units in the two refineries varies from unit to unit because of different feedstock property, process condition and scope of design, but the design energy consumption of almost all the units meet or are even lower than the energy consumption quota stipulated by SINOPEC. ¾Operation data show that both the energy consumption of main units and the refinery are lower than the design value, indicating that the energy consumption can be further reduced by optimizing the operation of production units. 18 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.4 Analysis on Differences in Energy Consumption ¾The design energy consumption of each unit meets or is even lower than the energy consumption quota stipulated by SINOPEC ¾The comprehensive energy consumption is higher than the statistical energy consumption of advanced energy-saving enterprises in SINOPEC, especially the new energy consumption target of SINOPEC (65 kg oe/t of crude oil). 19 Elaborate Design for Building Intrinsic Energy-saving Refineries 2.4 Analysis on Difference in Energy Consumption The reasons are list below: ¾The complexity of process flow is one of the reasons for high comprehensive energy consumption. ¾Poor quality crude oil processing increases refinery-wide energy consumption. ¾Design data are selected based on the worst conditions, so design energy consumption is higher than actual energy consumption. ¾Conditions for larger scale systematic optimization are unavailable. 20 Elaborate Design for Building Intrinsic Energy-saving Refineries 3. Conclusion ¾The launch of a movement for effective energy-saving is an arduous, complicated and painstaking task. ¾The subject of our study has already moved from energy optimization of a single unit to integrated optimization of the whole refinery. ¾Energy conservation of utility system should also be emphasized while paying attention to the energy conservation of process units, and researches and development of low temperature heat resource recovery and utilization technology should be strengthened. 21 Elaborate Design for Building Intrinsic Energy-saving Refineries 3. Conclusion ¾ Analysis on energy consumption of above-mentioned typical grassroots refineries shows that the key to energy consumption reduction is the optimization of overall process scheme and adjustment in unit configuration. ¾ The proportion of steam and power consumption to energy consumption is relatively high, so optimizing steam and power balance is an effective measure for energy conservation. ¾ In future, we will further implement the incentive mechanism for energy conservation based on the achievements we have already made, and put a lot of work in both administration and technology to carry out energy conservation and effective utilization of resources into each link of project planning and engineering. Meanwhile, we will pay further attention to energy-saving technology and administration in actual operation so as to build intrinsic energy-saving refineries. 22 Elaborate Design for Building Intrinsic Energy-saving Refineries 23
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