Safety Data Sheet Alloy 910 3D Printing Filament 05/09/2016 Rev: 0 Emergency HOTLINE: 1-717-665-2421 Monday-Friday; 8:00 AM – 5:00 PM, EST 1. IDENTIFICATION Product name: Alloy 910 3D Printer Filament Synonyms: Polyamide copolymer, Nylon 6/69 Product Use: For use in 3D printing machines Supplier: Fenner Drives 311 W Stiegel Street, Manheim, PA 17545 Emergency telephone numbers (24 hours a day): (717) 665-2421 2. HAZARDS IDENTIFICATION Emergency Overview: This product does not have health hazards if used as directed. During processing when converted to the molten state, normal precautions of handling hot, sticky, fluid melts should be observed Potential Health Effects: Eyes: None Skin: None Ingestion: None Inhalation: None Chronic Health Hazards: See section 11 for more information Other Hazards: Dust may be generated from processing or other means that may become combustible. Classification: The classification and labeling information in this Safety Data Sheet should be viewed as provisional, as the product’s ingredients and percentages are kept as a trade secret / proprietary. This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CRF 1910.1200). However, this SDS contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. 3. COMPOSITION / INFORMATION ON INGREDIENTS Substance or Preparation: Substance Chemical Name: Proprietary Cyclic Amide Content: 0-10 wt% Formula: Proprietary CAS No: Proprietary Fenner Drives, Manheim, PA 17545 Copyright 2016 by Fenner Drives. All Rights Reserved This document is Engineering controlled. It is subject to change. Contact Fenner Drives for latest revision 1 of 6 Safety Data Sheet Alloy 910 3D Printing Filament 4. FIRST AID MEASURES Inhalation: In case of gases evolving from melted filament, move subject to fresh air. Treat symptomatically. Skin Contact: Wash with water. In case of melted filament, wash affected skin area and clothing with plenty of (soap and) water. Seek medical advice. Eye Contact: In case of small particles, flush with plenty of water for at least 15 minutes. Seek medical advice if any small particles still remain. In case of gases evolving from melted filament of high temperature, flush with plenty of water for at least 15 minutes. Seek medical advice if necessary. Ingestion: Not a likely route of exposure Most important symptoms and effects Symptoms: Dermatitis may occur. May cause irritation to the mucous membranes and upper respiratory tract. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Water, Foam, carbon dioxide, Dry chemical powder Special Fire-Fighting Procedure: Self-contained breathing apparatus, MSHA/NIOSH approved full protective gear. Fire and Explosion Hazards: Product is not flammable or combustible 6. ACCIDENTAL RELEASE MEASURES Methods for Cleaning up: Recovery if not contaminated or disposal Personal Precautions: Strands/string remaining on ground may cause slipping. Wear protective clothing as described in Section 8 of this SDS Environmental Precautions: Do not allow material to contaminate ground water, soil, ditches, and/or sewers. See Section 12 for additional Ecological Information. 7. HANDLING AND STORAGE Handling: Taulman3D Nylons are thermoplastic resins. In the solid state, they are not hazardous. During processing when converted to the molten state, normal precautions for the handling of hot, sticky, fluid melts should be observed. Avoid breathing dust. Storage: Keep containers tightly closed in a cool, dry, and well-ventilated area. 2 of 6 Safety Data Sheet Alloy 910 3D Printing Filament 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: Occupational Exposure Limit Values: Chemical Name ACGIH TLV Proprietary Cyclic Amide 3 TWA: 5 mg/m inhalable fraction and vapor OSHA PEL NIOSH IDLH 3 (Vacated) TWA: 1.5 mg/m dust (Vacated) TWA: 5 ppm vapor 3 (Vacated) TWA: 20 mg/m vapor 3 (Vacated) STEL: 3 mg/m dust (Vacated) STEL: 10 ppm vapor 3 (Vacated) STEL: 40 mg/m vapor 3 TWA: 1 mg/m dust TWA: 0.22 ppm vapor 3 TWA: 1 mg/m vapor 3 STEL: 3 mg/m dust STEL: 0.66 ppm vapor 3 STEL 3 mg/m vapor Engineering Controls: Apply technical measures to comply with the occupational exposure limits. Showers, eyewash stations, ventilation systems Respiratory Protection: None required under normal use. Eye Protection: Safety glasses with side shields Skin Protection: Protective gloves required if in contact with molten material or newly molded polymer parts. Protective clothing. Work Hygienic Practices: Handle in accordance with good industrial hygiene and safety practice 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: String/strand Color: Amber transparent Odor: no noticeable odor Physical State: Solid pH: Not determined Melting Temperature: 193 °C Decomposition Temperature: >290 °C Solubility: Not determined Specific Gravity: 1.11 (Air=1) 10. STABILITY AND REACTIVITY Reactivity: Not reactive under normal conditions Conditions to avoid: Temperatures above 290 °C may result in thermal decomposition Reactivity with Water: No Stability: Stable and non-reactive under normal handling and storage conditions Hazardous Decomposition Products: Ammonia, hydrogen cyanide, carbon monoxide, hydrocarbons 11. TOXICOLOGICAL INFORMATION Principal Routes of Exposure: Eye contact, skin contact, inhalation, ingestion Acute Toxicity: Lack of data 3 of 6 Safety Data Sheet Alloy 910 3D Printing Filament Local Effects: Dust may be irritating to eyes, skin, and respiratory system Specific Effects: May cause skin irritation. Fumes may cause respiratory tract infection Long Term Toxicity: None Found Mutagenic Effects: None Found Reproductive Toxicity: None Found Carcinogenic Effects: None Found Target Organ Effects: Lack of Data Skin: Lack of data Ingestion: Lack of data Chemical Name ATEmix (oral ATEmix (dermal) Inhalation LC50 Proprietary Cyclic Amide = 1210 mg/kg (rat) = 1410 L/kg (rabbit = 1438 mg/kg (rabbit( = 8.16 mg/L (rat) 4 h 12. ECOLOGICAL INFORMATION Ecotoxicity Effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal Persistence and Degradability: Not determined Bioaccumulation: Not determined Mobility: Proprietary Cyclic Amide partition coefficient = -0.02 Component Information Chemical Name Algae/aquatic plants Proprietary Cyclic Amide 130: 72h desmodesmus subspicatus mg/L EC50 160: 96h desmodesmus subspicatus mg/L EC50 4320 – 4800: 72h pseudokirchneriella subcapirara mg/L EC50 Fish Crustacea 1400: 96h pimephales promelas mg/L LC50 static 930: 96h lepomis macrochirus mg/L LC50 static 500: 40h daphnia magna straus mg/L EC50 828-2920: 48h daphnia magna mg/L EC50 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: In accordance with local and federal regulations 14. TRANSPORT INFORMATION Not regulated by the US Department of Transportation 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA Proprietary Cyclic Amide X DSL/ NDSL X EINECS/ ELINCS X ENCS Present IECSC KECL X Present PICCS AICS X X 4 of 6 Safety Data Sheet Alloy 910 3D Printing Filament US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355) SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals US State Right-to-Know Regulations Chemical Name New Jersey Proprietary Cyclic Amide X Massachusetts X Pennsylvania X 16. OTHER INFORMATION NFPA Health Hazards Flammability Instability Special Hazards Not determined Not determined Not determined Not determined HMIS Health Hazards Flammability Instability Special Hazards Not determined Not determined Not determined Not determined REVISION SUMMARY: Date Prepared: May 9, 2016 Last Revised: Previous Revision: Summary of Revisions: 05/09/2016 - New SDS Prepared by: Fenner Drives The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult the Company for Further Information. 5 of 6 Safety Data Sheet Alloy 910 3D Printing Filament NOTICE REGARDING MEDICAL APPLICATION RESTRICTIONS: The company does not recommend any of its products, including samples, for use: (A) in any application which is intended for any internal contact with human body fluids or body tissues (B) as a critical component in any medical device that supports or sustains human life; and (C) specifically pregnant women or in any applications designed specifically to promote or interfere with human reproduction. 6 of 6
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