Marine and Petroleum Geology 22 (2005) 109–122 www.elsevier.com/locate/marpetgeo Mineralogical and microstructural development of the sediments on the Mid-Norwegian margin Carl Fredrik Forsberga,*, Jacques Locatb a Norwegian Geotechnical Institute, P.O. Box 3930, Ulleval Hageby, N-0806 Oslo, Norway b Université Laval, Québec City, Que., Canada G1K 7P4 Abstract As a contribution to the understanding of the mechanisms and causes for Storegga Slide, the mineralogy and microstructure of samples from a series of boreholes from the slide neighbourhood have been analysed. The results show a change from kaolinite-rich oozes through smectite-rich fossilferous clays/clayey oozes to illite dominated hemipelagic and glacial sediments from the Brygge (Eocene to earliest Miocene) to Kai (earliest Miocene to late Pliocene) to Naust Formations (late Pliocene to present), respectively. The deposits are interpreted as the effect of denudation of weathered regolith and an increase in physical erosion in conjunction with the deterioration of the climate and the initiation of glacial cycles during the late Cenozoic. During the Quaternary, climate has controlled the mixing of current transported, fine grained sediments that are probably derived from the region around the Faeroe Islands and coarser grained glacial sediments containing a broad spectrum of minerals eroded from the North Sea and Scandinavian mainland. Since currents have been most important during warm periods, sediments from these periods are finer grained and contain more smectite than the glacial sediments. However, it is concluded that the mineralogical differences between finer grained sediments from warm periods and the coarser grained glacial sediments are not great enough to explain the ubiquitous utilisation of glacial marine/hemipelagic sediments as slip planes for the slides in the area, but that this is probably a consequence of the differences in the grain size distribution of the sediments. Voids that may be casts left behind by gas hydrates have been observed. q 2004 Elsevier Ltd. All rights reserved. Keywords: Gas hydrates; Storegga; Cenozoic 1. Background The discovery of the Ormen Lange Gas field within the upper part of the Storegga Slide scar (Fig. 1) resulted in considerable interest in unravelling the Cenozoic geological history of this area. The Storegga Slide itself combined with this interest from industry meant that the region became one of the key areas for several multinational programmes that included studies of slope processes (e.g. ENAM, COSTA, STRATAGEM). As a consequence of these studies the mid-Norwegian margin has become one of the best studied offshore areas of the world. There is now a well-founded model of the geological development of the area (Bryn et al., 2005a; Berg et al., 2005; Rise et al., * Corresponding author. E-mail address: [email protected] (C.F. Forsberg). 0264-8172/$ - see front matter q 2004 Elsevier Ltd. All rights reserved. doi:10.1016/j.marpetgeo.2004.12.002 2005; Sejrup et al., 2000; Hjelstuen et al., 1999; King et al., 1996, 1998). This model shows a development from deposition of siliceous and calcareous oozes during the early Cenozoic (Brygge and Kai formations; Table 1) with a transition to repeated sedimentation of stacked glacial and hemipelagic units from the late Pliocene (Naust formation; Table 1) through the Quaternary and until the present. The stacking of the Quaternary slope sediments reflects the interaction of sedimentation from the currents flowing northwards along the continental margin and the supply of glacially derived sediments from the hinterland (Berg et al., 2005; Bryn et al., 2005b). The currents have had a maximum influence during interglacial periods, and were subdued, but still important, during glacials. During glacial maxima, while only lasting for a few thousand years, there was deposition of thick diamictons and glacial debris flows on the slope from shelf edge glaciers. 110 C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 Fig. 1. The Storegga area with the positions of the investigated geoborings. The Ormen Lange gas field is outlined in white. Water depths are indicated by black numbers and thin black lines. The Storegga Slide outline is shown by the thick black line. Deglaciations were accompanied by short periods of local rapid deposition from meltwater plumes (Nygård et al., 2004). The layering indicated in Fig. 2 symbolises the stratigraphy produced by this climatically induced oscillation of depositional mechanisms. Large landslides have repeatedly formed in the area (Solheim et al., 2005; Rise et al., 2005; Berg et al., 2005; Bryn, et al., 2005a; Evans et al., 1996), and this study is one of many performed to improve the understanding of this sliding. Prior to these investigations only mineralogical information from ODP sites on the Vøring Plateau and basin had to the authors knowledge been published from the mid-Norwegian margin (Froget et al., 1989; Krissek, 1989). The mineralogy of surface sediments of the Norwegian Sea have, however, been studied by Eisma and van der Gaast (1983), whereas Kuhlemann et al. (1993), Berner and Wefer (1994), Forsberg et al. (1999), and Butt et al. (2000) have published minalogical data from further north in the Norwegian-Greenland Sea. We will here present the mineralogy and microstructure from 11 sites (Fig. 1) in relation to depositional setting and briefly discuss their contribution to the sliding in the area. Table 1 The ages of the Neogene formations in the Storegga region Time period Seismic formations/units Late Pleistocene to recent (0.13 Ma-present) Mid-Pleistocene (0.73–0.13 Ma) Late Pliocene to (early) midPleistocene (2.6–0.73 Ma) Earliest Miocene to LatePliocene (23–2.6 Ma) Eocene to earliest Miocene (55–23 Ma) Naust units 01–03 and the Storegga slide deposits Naust Units 04–07, R1–R3 and S1–S3 Naust units S4–S5, u1, u2 and W Kai formation Brygge formation C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 111 Fig. 2. Schematic diagram showing the core recovery in a stratigraphic framework for the Ormen Lange geoboring sites. The recovery is against a simplified seismic stratigraphy. Note that the thickness of individual sub-units varies between sites, and the figure is therefore not to scale and must be viewed in a qualitative way. No mineralogical samples were analysed from Sites OB1, OB2. Site NF (North Flank) is outside of the slide scar. See Fig. 1 for location of the sites. Ages given in million years before present (Ma) are from Berg et al. (2005). 2. Material and methods 2.1. Sample locations and recovery Borings with geological and geotechnical sampling (geoborings) have been performed at 12 sites in the Storegga area (Tjelta et al., 2002). We have investigated 10 of these, together with samples from well 6305/4-1 (Well 4-1) (Fig. 1). The sample ages span the Miocene to the present, thereby covering pre-glacial times through the Quaternary glaciations (Fig. 2). The sample retrieval in the geoborings was not continuous (Fig. 2) because of difficult ground conditions and strategic sampling imposed by time constraints. Wireline logs were however recorded for all holes giving continuous borehole information (A. Solheim, pers. com., 2004). Nevertheless, the sites have provided samples from all the Cenozoic stratigraphic units in the area (Figs. 2 and 3) and have provided the opportunity to investigate the mineralogy and microfabric changes in a range of settings where the post depositional history includes shelf areas with glacial loading as well as deep water sites with modest rates of sedimentation. 2.2. X-ray diffraction analyses (XRD) 2.2.1. Sample preparation All analyses were performed at the XRD laboratory at the Geological Institute, University of Oslo. Unoriented bulk samples were prepared by filling crushed, dried sediment into a standard holder for powder 112 C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 Fig. 3. Idealized cross-sections through the geoborings demonstrating the sampling strategy and the units recovered. Two cross-sections are represented. The upper one through the northern part of the Storegga Slide (Sites 22, NF and 28—see Fig. 1) where only a shallow layers have moved, and the lower one through the deep slide scar (Sites 20, 19_2, 31,99,27, Well 4-1, 17 and 18_2). The paler layers are the marine/hemipelagic layers, the darker ones, layers from glacial deposits. The Storegga slide sediments have a variable shading. XRD analyses. Oriented clay fraction samples were prepared by filtering the less than 2 mm size fraction obtained from a settling tube and inverting them onto ceramic holders. To differentiate swelling minerals such as smectite from chlorite and illite, samples were treated with ethylene glycol (glycolation) vapour overnight in an exsiccator. Samples were also heated to 550 8C for about 2 h to remove the kaolinite peak so that a positive identification of chlorite could be achieved (Fig. 4). Minerals were classified manually according to standard procedures (e.g. Carroll, 1974). Quantification was performed digitally using a Unix-based script previously used by Forsberg et al. (1999) and Butt et al. (2000, 2001). The script subtracts the background level and finds the number of X-ray counts under selected peaks between the half peak heights on each flank. Peaks can be chosen from any combination of diffractograms. The X-ray counts obtained can then be processed in a spreadsheet or similar software where weighting factors etc. can be applied. For the present work processing was accomplished using Unix-based scripts with weighting factors from Biscaye (1965) for clay and Ramm (1991) for the bulk samples (Fig. 4). The kaolinite/chlorite ratio was determined from detailed scans of the peak between 248 2q and 268 2q (Biscaye, 1964). Peaks common to different diffractograms (e.g. the quartz peak) were used to normalise the different scan amplitudes to those of the glycolated runs. No internal standards were used, so the quantification assumes that the sum of all the quantified minerals is 100%. The same minerals were quantified in all samples. Silica was the major constituent in four samples from the Brygge formation (Well 4-1). Because of the amorphous nature of silica, the quantification of the silica content was not performed. The results for these samples therefore only reflect the relative mineral distributions, not the silica content. 2.3. Scanning electron microscopy (SEM) 2.3.1. Sample preparation Samples used for SEM work were prepared by first freezing them in liquid nitrogen. The surfaces to be observed were obtained by cutting while the sample was still frozen and were perpendicular to the bedding plane. Cutting while frozen normally ensures that the surface is as planar as possible and that the porosity is well exposed to the viewer. For samples which are coarse, usually at a clay content of less than 30%, it may, however, be difficult to obtain planar surfaces. The top of the layering is up on all SEM images. Magnifications used for SEM analyses varied from 20 to a maximum of 20,000. During inspection micrographs were taken at increasing magnifications. Characteristics of the microstructure (orientation, alignments, grain sizes, shapes), types of particles present and features of special interest were noted. During inspection X-ray dispersive spectrometer (XREDS) analyses were performed on single particles to provide the relative abundance of various C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 113 Fig. 4. Examples of diffractograms recorded: the left hand diagram from a smectite rich sample, the right hand one from one rich in illite. The numbers next to the curves refer to scan descriptions below the plots. All runs were performed on a Philips X’Pert X-ray diffractometer with a q-q goniometer using an automatic divergence slit and Cu Ka radiation. Peaks used for quantification are indicated on the plots. Weighting factors used for quantification of clay fraction: smectite-1; illite-4; kaolinite-2; quartz-2, feldspars-1; calcite-1. Weighting factors, bulk samples: total clay minerals-20; quartz-7.5; potassium feldspar-3.7; plagioclase-4.2; calcite-1.6; dolomite-1.6; pyrite-3. elements in the grain or the aggregate as an aid to identification. low feldspar contents in the Brygge and Kai formations (Well 4-1 and Site 28). Through the Naust formation, however, there is considerable variation in the sediment composition. 3. Results 3.1. Mineralogy Most samples contain a similar suite of minerals (Figs. 5 and 6). The exceptions are the samples from Well 4-1 and Site 28 that were from Eocene to Early Miocene siliceous oozes (Brygge formation) and the Miocene to Pliocene Kai formation, respectively. Where sub-unit boundaries occur between samples they have been picked from wireline logs and correlation with high resolution seismic data (Solheim, pers. com., 2004). Site 31 demonstrates the variability of results within a single sub-unit (R2). In the following, only general trends will be presented whereas details can be examined in Figs. 5 and 6. 3.1.1. Mineralogy of bulk samples The minerals quantified were quartz, potassium feldspars, plagioclase, calcite, dolomite, pyrite and the total clay mineral content. The mineral concentrations reflect the large scale stratigraphy (Fig. 5) showing high clay mineral and 3.1.2. Mineralogy of clay fraction The clay minerals smectite, chlorite, illite and kaolinite as well as quartz, potassium feldspars, plagioclase, calcite and pyrite were quantified in the clay fraction. The clay mineral composition (Fig. 6) reflects the stratigraphy showing differences in composition between the Brygge, Kai and Naust formations. The mineral fraction of the Brygge formation has high kaolinite contents whereas chlorite is absent. The Naust W and Naust U units are only sampled at Site 28 but can be seen to be rich in smectite compared to all but a few of the samples from the remaining units that are otherwise dominated by illite. It should be noted that the chlorite content increases from the Kai formation into the Naust formation. 3.2. SEM analyses 3.2.1. Microfabric From the many SEM pictures taken for the various layers investigated as part of the Ormen Lange project, only a few 114 C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 Fig. 5. The results of the mineralogical analyses of the bulk sediment samples. The red lines between columns represent selected horizons. Horizon names appear in the columns. C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 Fig. 6. The results of the mineralogical analyses of the clay sized fraction of the samples. The red lines between columns represent selected horizons. Horizon names appear in the columns. 115 116 C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 were selected to illustrate the different signatures related to the main pre-Storegga slide stratigraphic units encountered in this area. The intervals chosen are the Kai formation (clayey ooze), the Naust W (hemipelagic) unit, the Naust S3 (debris flow or diamicton)and the Naust R2 (hemipelagic) sub-units. Their respective typical SEM pictures have been assembled in Fig. 7. The microfabric, i.e. the layout of the sediment skeleton, is very much influenced by the nature of the sediments, its sedimentary environment, mode of deposition and post-depositional evolution, and burial stress (Mitchell, 1993). So, the end product, observed today, can be the result of many processes which have been interacting over time. The orientation of particles has been evaluated qualitatively. In many samples, the orientation of clay particles around coarser (silt or sand) particles is quite intense. In fact, it seems that if clay particles lie close to any flat or larger continuous surface, they will get moulded onto it (Fig. 8). The Kai formation consists of clayey ooze deposits rich in both siliceous and calcareous microfossils with secondary Fig. 7. SEM examples of the main facies found in the Storegga area. (a–b): R2 layer at borehole 31, sample 7 at a depth of 97 mbsf; (c–d): S3 layer at borehole 27, sample 5 at a depth of 248 mbsf; (e–f): Naust W layer at borehole 28, sample 5 at a depth of 61 mbsf; (g–h): Kai formation at borehole 28, sample 10 at a depth of 110 mbsf. In each case, two microphotographs are provided with scale bar at 100 and 10 mm respectively. The small square on the lower magnification microphotographs show the location of the larger magnification one. The orientation of the sample is normal. Symbols are as follows: DiZdiatom; FoZ Fossil; MiZmica; OZorganic matter; PZpyrite; SiZsilica; SmZsmectite. C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 117 Fig. 8. Micrograph of an amalgamated crust that has formed where it was in contact with the larger particle seen in the upper left hand part of the picture. The crust can be seen to be very thin and does not appear to influence the structure in the clay below (Site 31, sample 18C, 104.2 mbsf) b. Intricate hole with a thin crust that is interpreted to have formed around a nodule of gas hydrates that decomposed during climatic amelioration (Site 19_2, sample 28-I, 225.8 mbsf). porosity related to the presence of the various microfossils (Fig. 7g). As is often the case with siliceous deposits (Tanaka and Locat, 1999), diatoms’ intra-skeletal porosity is filled with framboı̈dal pyrite (Fig. 7h). This formation is particularly rich in smectite which can be seen in Fig. 7h forming a fine texture of flocculated particles less than 2 mm in size. Another characteristic of this formation is its higher content of organic matter, exceeding 2% by weight. Still in Fig. 7h, a piece of organic matter can be seen. Although its composition has been confirmed with XREDS, it also exhibits a typical shrinkage upon freeze-drying leaving a gap which is about 5 mm in width. The base of the Naust W unit represents sedimentation in a hemipelagic environment. This can also be seen at the microstructure level with a homogeneous texture (Fig. 7e) and a microfabric that still contains a few flocs (smectite ?) that may have been protected from greater compaction by larger silt particles like the mica grain identified in Fig. 7f. The various debris flow/diamicton sequences reflecting the glacial or stadial phases on the margin during the Pleistocene have produced a series of thick layers composed mostly of glacial sediments with some reworked marine material. At small magnifications they usually showed numerous silt particles floating in a well oriented clayey matrix (Fig. 7c and d). The development of flow features and the post-depositional compaction may be responsible for the high degree of orientation of the platy particles. The Storegga slide deposits exhibit a typical flow like structure as shown in Fig. 9. Here this sample does not contain large amounts of fine sand but most of the coarse particles are more or less aligned with respect to the horizontal plane. Since some marine sediments may be reworked during the slide event, it does contain some microfossils, often as debris (Fig. 9b). The example shown in Fig. 9 is from a sample taken at a depth of only 9.6 m so that the degree of compaction is not very high and which therefore suggests that the orientation observed in Fig. 9b is only due to the flow phenomena. 4. Discussion 4.1. Influence of environmental changes The sampling at site 28 provides a good opportunity to compare two different microstructures resulting from two Fig. 9. Microphotographs of the Storegga slide deposit at site 18, sample 1 taken at a depth of 9.6 mbsf. The fossil (Fo) seen in (b) consist of calcite and may be a foraminifera fragment. The two microphotographs are provided with scale bar at 100 and 10 mm, respectively. The small square on the lower magnification microphotographs show the location of the larger magnification one. The orientation of the sample is normal. 118 C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 Fig. 10. Micrographs from Site 28 showing how crusts from contact with larger particles are better developed in the Naust formation (a and b) than the underlying Kai formation (c and d). Annotations indicate various minerals identified through XREDS analyses. distinct sedimentary environments. A series of four SEM pictures of both the Naust W and Kai B units have been assembled in Fig. 10 to illustrate the control that the presence of a microfossil skeleton has on the fabric of the matrix. Surfaces in contact with coarser particles, even at a fairly shallow depth, are much more amalgamated than those in deeper samples. In Kai B (Fig. 10d), the matrix which surrounds the grain is still quite open and very porous whereas the surface in Naust W (Fig. 10b) is almost polished. This is an illustration of the sort of ‘potential strain’ which can be released once the yield strength of the ooze is exceeded and the skeletal support collapses. A significant difference is also to be expected in terms of permeability and compressibility for the units, the ooze being more compressible and permeable than the Naust sediments. In the Kai formation there are little or no aggregates, but rather flocs of fine clay particles, which allow the observation of the floc porosity (Fig. 10). The presence of flocs and the lack of signs indicating in situ mineral transformations in the SEM study is evidence pointing to the detrital origin of the minerals detected. In general, the weathering of rocks produces clay minerals in quite well defined trends (e.g. Jackson et al., 1948). The clay minerals produced depend on the intensity and duration of the weathering. In warm humid climates, kaolinite is the end product with smectite and illite as precursors. The stratigraphic sequence of clay minerals in our samples follows this trend. The depositional period from the Miocene to the late Pliocene is the time interval during which Northern Hemisphere glaciations were initiated. The oozes sampled in the Brygge formation (Well 4-1) only have a very small terrigenous component with a significant kaolinite fraction, whereas the sediments in the upper part of the Kai formation sampled at Site 28 have a significant contribution from both biogenic and terrigenous sources (Fig. 7). The terrigenous fraction is smectite-rich. The greater terrigeneous contribution may reflect the increased denudation rate on land and the smectite the deeper erosion of weathered rocks (i.e. rocks that are not completely weathered). However, oceanic currents flowing northwards have probably given the sediments their contouritic seismic facies (Bryn et al., 2005b) and may also have transported C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 sediments from the continental margin to the south and therefore from the region around the volcanogenic Faeroe Islands. Smectite is a common product of weathering of basaltic igneous rocks (Blatt et al., 1980). In concordance with this, Eisma and van der Gaast (1983) have mapped high smectite contents in the sediments around the Faeroes. Irrespective of whether the smectite is from erosion of the hinterland or the Faeroes region, the increased detrital input to the sediments is a signal of greater erosional activity and is interpreted to reflect that the pre-glacial land areas were probably eroded by fluvial processes and covered by weathered rocks and soils in which the content of kaolinite was high. We therefore suggest that the progressive denudation by increased glacial activity gradually exposed less weathered and more crystalline rocks resulting in the mineralogical changes observed. The lower part of the Kai formation has not been sampled. Any transitional changes closer to the Brygge formation are therefore unknown. Krissek (1989) presents a similar stratigraphic development and interpretation to ours from ODP Leg 104 on the Vøring Plateau. The base of the Quaternary, Naust W, is dominated by hemipelagic deposits from before the first continental shelf glaciation (1.1 Ma, Haflidason et al., 1991). However, there is a significantly lower biogenic component than in the Kai formation (Fig. 7). The increase in the relative importance of physical erosion is probably signalled by the appearance of chlorite, a mineral that is associated with low grade metamorphic rocks and an early stage of weathering of igneous and intrusive rocks. Glacial ‘flour’, fine grained non-clay minerals in the clay fraction, is found throughout the Kai and Naust formations and also demonstrates the effect of physical erosion. Support for this notion comes from seismic stratigraphy (Berg et al., 2005) that shows the Naust U2 sub-unit to be the first glacial debris flow deposit, signalling glacial expansion to the shelf edge. Debris flow deposition did not, however, reach Site 28 where Naust U is glacial marine/hemipelagic (Fig. 10). The distal position of Site 28 in relation to most of the other sites (Fig. 1), may also explain the high smectite contents because current transport from the Faeroes to the south is probably relatively more important in this setting as demonstrated by the results of Eisma and van der Gaast (1983) who mapped a high but decreasing smectite content in the Norwegian Sea from the Faeroe Islands and northwards along the Norwegian margin. The Naust formation was deposited under the influence of the Quaternary climatic fluctuations. In order to examine the changes more closely, the results have been compared to grain size analyses. However, grain size analyses were not performed on the same samples as the mineralogical samples, but within each sub-unit variations in the total clay mineral content calculated from the bulk XRD scans can be seen to reflect similar changes in the clay content from grain size analyses (Fig. 11). Such a correspondence is as one should expect because the clay minerals have the highest relative concentrations in the clay fraction and 119 means that the total clay mineral content can be used as a rough proxy for the grain size of the sediments on which the mineralogical analyses were performed. There is a higher smectite (Fig. 12) content in samples with higher clay mineral concentrations, i.e. the more fine grained samples. Furthermore, the relative concentration of feldspars is lower and carbonates higher in bulk samples with high clay mineral contents (Fig. 13). The more fine grained interglacial or interstadial units as demonstrated by samples from Sub-unit R2 (Fig. 7) exhibit a homogeneous microfabric and can be distinguished from the debris flow or diamicton deposits by its much larger content of microfossils (e.g. foraminifera and diatoms), a smaller content of dispersed silt particles and a lesser degree of orientation of the platy particles in the clayey matrix. Because feldspars are depleted and smectite may be enriched in weathered soils and sediments, the results are interpreted to reflect the relative contribution of erosional products of crystalline rocks on one hand and from sedimentary rocks and weathering combined with ocean current transport on the other. The availability of most of the clay minerals from physical erosion is demonstrated by their widespread occurrence in the North Sea area (Irion and Zollmer, 1999). However erosion of crystalline rocks is interpreted to have been associated with glaciations whereas a greater relative contribution from sedimentary rocks, weathering and current transport are thought to signal warmer periods. Currents were also active during glacials and there has been reworking of interglacial sediments during glacial periods. The result is that that there is a gradational change in sediment composition both laterally and stratigraphically that reflects changing climatic and oceanographic conditions. The marine /glacial marine sediments are more sensitive (loose strength upon deformation; Berg et al., 2005; Kvalstad et al., 2005) than the diamictons and debris flow deposits, and is a property that has been interpreted as the main cause of their ubiquitous utilization as slip planes for the slides (Berg et al., 2005; Bryn, et al., 2005a; Kvalstad et al., 2005). While these layers contain more smectite than the glacial sediments from the same site, we do not think that the differences are great enough to explain this phenomenon. We are of the opinion that the grain size distribution and the consequences this has for the physical properties (e.g. higher plasticity index and water content; Mitchell, 1993) is of greater importance. 4.2. Indications of gas hydrates Almost polished surfaces observed surrounding coarser particles embedded in the clay matrix is seen on surfaces of silt or sand particles in contact with the clayey matrix (Figs. 8 and 10b). In marine clays the particle arrangement is usually flocculated, with edge to flank contacts. The crust formation observed here, where the distinction between individual particles disappears, may perhaps be termed 120 C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 Fig. 11. The clay content of the samples (CC) compared to the total content of clay minerals (TCM) in the bulk samples. The right hand columns represent the clay content. C.F. Forsberg, J. Locat / Marine and Petroleum Geology 22 (2005) 109–122 121 embedded particle. The cast therefore appears to have been produced by a solid that has dissolved without disturbing the matrix. A tentative interpretation is that is was produced during an earlier presence of gas hydrate, that disappeared during a climatic amelioration. Gas hydrates are not stable at the site at present, but were so during glacial periods. 5. Conclusions Fig. 12. Ternary diagram showing the relative concentrations of Illite, smectite and chloriteCkaolinite for the clay fractions of Naust formation. The shading indicates the total content of clay minerals found in the bulk sediment. ‘cold bounding’ (Mitchell, 1993; Locat et al., 2003) and involves the transformation from edge to flank to flank to flank contacts. The kinetics and mechanisms involved in the process are not known, but our observations here show that the effect is limited to a very thin zone (Fig. 8) close to the larger particles which suggests it is a surface phenomenon. Fig. 8b shows an intricately shaped void with a coating (one of several in this sample) surrounded by an undisturbed clay matrix. The latter seems to exclude the extraction of an Both the mineralogy and microfabric reflect the changes in depositional processes that have occurred in the study area. There is a compositional transition from the Miocene Brygge formation through the late Pliocene Kai to the Quaternary Naust formation that reflects a change in oceanic circulation and climate in conjunction with growing glacial activity that involves 1. An increase in terrigenous and a reduction in biogenic sedimentation. 2. Mineralogical changes from kaolinite-rich Miocene sediments through smectite-rich late Pliocene to illitedominated Quaternary deposits that is interpreted to reflect gradual denudation of a weathered regolith and sedimentary rocks and an increased erosion of crystalline rocks. Fluctuations in the Quaternary mineralogy is mostly related to the inter-fingering contribution from glacial and glacial marine and hemipelagic processes that can be seen in both the microfabric and the fluctuations in the mineral contents. Higher smectite and calcite concentrations reflect contouritic and biogenic deposition, respectively, and are associated with the more fine grained sediments from interstadial and interglacial periods. Coarser, more glacially influenced sediments have higher feldspar concentrations reflecting a higher contribution from physical erosion. The more fine grained nature of hemipelagic/glacial marine deposits is thought to be more important than their somewhat higher smectite content in determining their ubiquitous use as slip planes for slides in the Storegga region. Voids interpreted to have been left behind after dissolution of gas hydrates may have been detected. Acknowledgements Fig. 13. Ternary diagram showing the relative concentrations of feldspars, quartz and carbonates in the bulk sediments of the Naust formation. The shading indicates the total content of clay minerals found in the bulk sediment. 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