Electron Arrangements in Atoms Say Thanks to the Authors Click http://www.ck12.org/saythanks (No sign in required) To access a customizable version of this book, as well as other interactive content, visit www.ck12.org CK-12 Foundation is a non-profit organization with a mission to reduce the cost of textbook materials for the K-12 market both in the U.S. and worldwide. Using an open-source, collaborative, and web-based compilation model, CK-12 pioneers and promotes the creation and distribution of high-quality, adaptive online textbooks that can be mixed, modified and printed (i.e., the FlexBook® textbooks). Copyright © 2015 CK-12 Foundation, www.ck12.org The names “CK-12” and “CK12” and associated logos and the terms “FlexBook®” and “FlexBook Platform®” (collectively “CK-12 Marks”) are trademarks and service marks of CK-12 Foundation and are protected by federal, state, and international laws. Any form of reproduction of this book in any format or medium, in whole or in sections must include the referral attribution link http://www.ck12.org/saythanks (placed in a visible location) in addition to the following terms. Except as otherwise noted, all CK-12 Content (including CK-12 Curriculum Material) is made available to Users in accordance with the Creative Commons Attribution-Non-Commercial 3.0 Unported (CC BY-NC 3.0) License (http://creativecommons.org/ licenses/by-nc/3.0/), as amended and updated by Creative Commons from time to time (the “CC License”), which is incorporated herein by this reference. Complete terms can be found at http://www.ck12.org/about/ terms-of-use. Printed: May 26, 2015 www.ck12.org C HAPTER Chapter 1. Electron Arrangements in Atoms 1 Electron Arrangements in Atoms Worksheet Name _____________________ Class ______________________ Date ________________ Answer each of the questions below to show your achievement of the lesson objectives Lesson Objective: Understand how to apply the Aufbau principle, the Pauli exclusion principle, and Hund’s rule to determine ground state electron configurations. 1. An atom’s electron configuration describes a. b. c. d. the shape of the electrons the arrangement of electrons the shape of electrons the shape of the orbitals 2. The Aufbau principle states a. b. c. d. lower orbitals are filled last orbitals are filled in random order lower orbitals are filled before upper orbitals no lower energy orbitals are filled 3. The Pauli exclusion principle states that a. b. c. d. all electrons have four quantum numbers quantum numbers are excluded for some elements two electrons in an element may have identical quantum numbers no two electrons in an element can have the same four quantum numbers 4. Hund’s rule states that a. b. c. d. 5. 6. 7. 8. 9. 10. 11. 12. 13. orbitals of equal energy must all have one electron before further filling. all orbitals must first fill with one electron energy levels will change as orbitals are filled orbital filling is a random process True or False: Each element has a unique electron configuration. True or False: The 4f orbital fills just after the 4d orbital./li> True or False: There is one element whose electrons all have the same spin quantum number. True or False: Carbon has one empty 2p orbital. True or False: Nitrogen has one 2p orbital that contains two electrons. The 2p orbital must be filled before the ____ orbital can be filled. The ______ orbital is filled just before the 3p orbital is allowed to fill. Each orbital can contain up to _______ electrons. Boron has ____ empty 2p orbitals. Lesson Objective: Be able to write correct orbital filling diagrams and electron configurations for all elements. 14. The arrows in orbital filling diagrams indicate 1 www.ck12.org a. b. c. d. orbital rotation of the electrons electron spin magnetic rotation orientation of orbital 15. Electron configuration superscripts indicate all of the following except a. b. c. d. number of electrons number of protons atomic number orbital shapes 16. The electron configuration 1s2 2s2 2p is the electron configuration for a. b. c. d. 17. 18. 19. 20. carbon oxygen boron beryllium True or False: The electron configuration for lithium is 1s2 2s2 . True or False: Oxygen will have one paired set of 2p electrons. True or False: The orbital filling diagram for He is ↑ ↑ . The orbital filling diagram for sodium (atomic number 11) is ____________. 21. is the orbital filling diagram for ___________. 22. The electron configuration for Al is ___________. 23. 1s2 2s2 2p6 is the electron configuration for _________. Lesson Objective: Know how to use the noble gas notation shorthand method. 24. The noble gas shorthand method a. b. c. d. indicates reactivity requires writing all the electrons in the diagram allows abbreviation of the electron configuration shows relationships among the noble gases 25. True or False: The noble gas configuration for calcium is [Kr]4s2 . TABLE 1.1: Element Ni Mg Be Atomic Number Electron Configuration [Ar]3d8 4s2 12 4 Lesson Objective: Be able to determine the number of valence electrons and the number of unpaired electrons in any atom. 27. Valence electrons are a. unpaired electrons in the outermost principal energy level b. all electrons in the outermost orbital c. electrons in the outermost principal energy level 2 www.ck12.org Chapter 1. Electron Arrangements in Atoms d. electrons with paired spin in the outermost principal energy level 28. 29. 30. 31. Note: You may use the electron configuration tables for questions 28-30. Sc (atomic number 21) has _____ valence electrons. Chlorine (atomic number 17) would be expected to have _____ unpaired electrons. Nitrogen (atomic number 7) has _____ valence electrons and ____ unpaired electrons. Lesson Objective: Understand that some electron configurations are exceptions to the normal Aufbau process. 31. The first element to show an exception to the Aufbau process is a. b. c. d. Cr Pt Nb Cs 32. The last of the three rules for determining ground state electron configurations gives information on how to arrange electrons in a set of orbitals that are all within the same sublevel. Hund’s rule states that orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron, and all of the unpaired electrons must have the same spin. A slight preference for keeping electrons in separate orbitals helps minimize the natural repulsive forces that exist between any two electrons. 33. Why do all unpaired electrons need to have the same spin? 34. Develop a method using only the electron configuration tables for determining how many unpaired electrons a given atom has. Confine your discussion to elements 1-20. TABLE 1.2: Element Ni Mg Be Atomic Number 28 12 4 Electron Configuration [Ar]3d8 4s2 [Ne]3s2 1s2 2s2 3
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