Application Guide: IFRA Compliant Ingredients SAFE TO SAY, HE’LL TAKE TIME TO SMELL THE FLOWERS. FIFTH EDITION Application Guide: IFRA Compliant Ingredients 1 THE FRAGRANCE INDUSTRY PLAYS A KEY ROLE IN OUR DAILY LIVES. One common element to all involved is a devotion to supplying safe and deliciously smelling products to consumers around the world. We share that devotion with you. Sigma-Aldrich is dedicated to providing a variety of quality, certified fragrance ingredients with transparent and easily accessible documentation to customers around the globe. Our expertise in supply chain management helps ensure the products you need arrive to you when you need them. Not only does Sigma-Aldrich supply safe, certified ingredients for fragrance development, we also have a suite of analytical tools to ensure your purity determination and composition verification tests are quick and accurate. To learn more, visit sigma-aldrich.com/flavors-fragrances 2 Flavors and Fragrances SAFE, CERTIFIED INGREDIENTS FOR FRAGRANCE FORMULATION FLOWER Octyl Acetate brings jasmine notes for a clean floral bouquet. LEAF 2-Isobutylthiazole adds green, herbaceous notes for fresh scents. CREAM 2,3-Hexanedione offers a creamy and slightly oily aroma. Application Guide: IFRA Compliant Ingredients 3 INGREDIENTS CONSUMERS CAN FEEL SAFE AND CONFIDENT ABOUT GROWING CONCERN IN CONTACT ALLERGENS IS DRIVING CHANGE IN THE INGREDIENTS USED IN FORMULATIONS. Within the personal care industry we are seeing the growing trend of top companies sharing a list of the fragrance ingredients they use in their formulations. This level of information is what consumers are demanding in the products they use. Transparency and high quality ingredients are two of our core pillars here at Sigma-Aldrich. In this edition of our application guide, we focus on our growing line of fragrance ingredients that meet the IFRA guidelines. We review all of our fragrance ingredients and verify that they do not contain any prohibited substances identified in Annex II or Annex III of EU Regulation No. 1223/2009. Furthermore, we review our ingredients according to the 48th amendment in the IFRA standards for restricted, prohibited or specified substances. We strive to offer the utmost transparency to our customers to help develop safe products for consumers. 4 We partnered with perfumer Tony Leardi to bring accurate and descriptive application information on a number of our upgraded IFRA products to increase your understanding of potential opportunities for these dynamic materials in your fragrance formulations. Along with descriptive applications, the following additional information is provided: • Aroma organoleptic characteristics • Natural occurrences • Quality grade and other certifications Flavors and Fragrances TONY LEARDI HAS EXTENSIVE EXPERIENCE IN THE FRAGRANCE INDUSTRY EVALUATING THE ODOR AND PERFORMANCE OF FRAGRANCE MATERIALS IN FINISHED APPLICATIONS AND FINDING NEW AND INNOVATIVE WAYS TO USE AROMA MATERIALS. Tony Leardi has spent over 30 years in the fragrance industry at several leading companies including Takasago International, Givaudan and Hercules Fragrances, now a part of Symrise. He began his career creating fragrance product formulations for Avon Products, Inc. His interest in fragrance materials led him to the fragrance supplier side of the industry where he directed laboratories for fragrance applications, perfume compounding, and new product innovations. He has patents for several air freshener devices and baby products and has gained insight into Scientific Aromatherapy using brain wave measurements to determine human reactions to fragrances and their components. He now provides consulting services in the fragrance industry to companies needing expertise in fragrance technology, new product development, and laboratory design, staffing, and operations. Application Guide: IFRA Compliant Ingredients 5 6 Flavors and Fragrances α-IONONE ≥90% I FR A , KO S H E R A N D H A L A L This material is a “must have” ingredient in many types of fragrances including floral, fruity, green, aldehydic, chypre and woody perfumes where it provides depth and character. Has many finished product applications including fine fragrances, deodorants & antiperspirants, creams & lotions, hair products, air fresheners and detergents & cleaners. If you find your fragrance composition is “thin”, consider adding α-Ionone to round it out. Odor Type Floral Natural Occurrence Almond, blackberry, black currant, raspberry, acacia, and plum Aroma Characteristics @10% in DPG. Sweet, woody, floral, violet, orris, tropical, fruity. Suggested Use Level 1%-15% Product Number W259403 Application Guide: IFRA Compliant Ingredients 7 p-PROPYL ANISOLE ≥99%, FCC, FG I FR A , KO S H E R A N D H A L A L This material’s interesting anise notes makes it well suited to fruity, floral, mint, powdery and sweet fragrances. It works well in many applications including fine fragrances, deodorants & antiperspirants, creams & lotions, hair products, air fresheners and detergents & cleaners. Its excellent odor intensity coupled with high diffusivity make it a fine choice for candles and air fresheners while providing lift especially to fruity materials. 8 Odor Type Anisic Natural Occurrence Anise and spearmint Aroma Characteristics @10% in DPG. Sweet anise, licorice, sassafras, fennel. Suggested Use Level 1%-10% Product Number W293008 Flavors and Fragrances δ-TRIDECALACTONE ≥95%, FG IFR A, KOSHER AND HALAL This material has the typical “creamy, milky” type odor of lactones in general and finds use in heavy floral fragrances like gardenia, tuberose, etc. Works well in many types of finished products including fine fragrances, creams & lotions and hair products. Odor Type Creamy Natural Occurrence Not found in nature Aroma Characteristics @6% in DPG. Creamy, milky, oily, dairy, buttery, musty. Suggested Use Level 0.1%-6% Product Number W468501 Application Guide: IFRA Compliant Ingredients 9 INDOLE ≥99%, FG IFR A AND KOSHER Used in floral, woody, herbaceous, fruity, and Oriental fragrances. Can be used in many applications including fine fragrances, deodorants & antiperspirants, creams & lotions, hair products, air fresheners and detergents & cleaners. Care must be taken when using this material to minimize its animal, fecal quality. Used properly, it can really add depth to floral, woody and herbaceous fragrances. 10 Odor Type Animal Natural Occurrence Bergamot, roasted coffee, jasmine, neroli, thyme, and ylang ylang Aroma Characteristics @1% in DPG. Animal, floral, naphthyl, fecal, smoke. Suggested Use Level 0.01%-2% Product Number W259306 Flavors and Fragrances 4-CARVOMENTHENOL NATURAL, ≥95%, FG N AT U R A L , I FR A A N D KO S H E R This material’s close association with essential oils such as rose, lavender and geranium makes it useful for many fragrance types. It has applications across the board in fine fragrances, deodorants & antiperspirants, creams & lotions, hair products, air fresheners and detergents & cleaners. Odor Type Spicy Natural Occurrence Bergamot, bois de rose, calamus, cardamom, cassis, chamomile, cinnamon, citronella, clary sage, eucalyptus, fir needle, geranium, grapefruit, juniper, labdanum, lavender, lemongrass, orange flower, patchouli, pennyroyal, pepper, peppermint, petitgrain, pine, rose, rosemary, spearmint, thyme, verbena, wormwood, and yuzu Aroma Characteristics @5% in DPG. Peppery, woody, earthy, green, herbaceous, musty, sweet. Suggested Use Level 0.1%-5% Product Number W224820 Application Guide: IFRA Compliant Ingredients 11 PHENETHYL ALCOHOL ≥99%, FCC, FG IFR A, KOSHER AND HALAL Because it occurs naturally in many flowering plants, consumers think of it as the “preferred” floral note. At lower concentrations, it gives a non-descript floral boost. At higher concentrations, it provides a recognizable rosy character. It is used in many floral and especially rose fragrances as well as some fruit fragrances. Works well in fine fragrances, deodorants & antiperspirants, creams & lotions, hair products, air fresheners and detergents & cleaners. It is also non-discoloring in most media. 12 Odor Type Floral Natural Occurrence In many plants including rose, geranium, jasmine, hyacinth, lily, orange flower, apple, peach, pear and ylang ylang Aroma Characteristics @10% in DPG. Floral, rose. Suggested Use Level 1%-40% Product Number W285803 Flavors and Fragrances (+)-γ-DECALACTONE NATURAL, ≥97%, FG NATUR AL, IFR A, KOSHER AND HAL AL This material is useful in floral and fruity fragrances where it adds richness and depth. Its tenacity makes it useful in many finished products including creams & lotions, shampoos and soaps & detergents. Odor Type Fruity Natural Occurrence Apricot, butter, coconut, nectarine, osmanthus, peach, raspberry and strawberry Aroma Characteristics @10% in DPG. Fresh, oily, waxy, peach, coconut, buttery, sweet. Suggested Use Level 0.1%-12% Product Number W236012 Application Guide: IFRA Compliant Ingredients 13 L-FENCHONE ≥98% I FR A , KO S H E R A N D H A L A L A very good camphoraceous material useful in amber, balsam, woody, fir, floral, Oriental, minty and spicy fragrances. Can be used in many finished products including household cleaning products and detergents. Has good diffusivity in air fresheners and candles. 14 Odor Type Camphoraceous Natural Occurrence Ginger lily, fennel and absinthe Aroma Characteristics @5% in DPG. Camphor, herbal, earthy, woody. Suggested Use Level 0.1%-5% Product Number W507709 Flavors and Fragrances MYRCENE ≥95%, STABILIZED, FCC, FG IFR A, KOSHER AND HALAL This material’s peppery, herbal characteristics make it suitable for many types of fragrances, most notably citrus and spicy types. It can provide a fresh note in household products such as cleaners and especially air fresheners where its high diffusivity enhances topnotes. Odor Type Terpenic Natural Occurrence Angelica and anise seeds, basil, bergamot, bois de rose, cedarleaf, chamomile, citronella, clary sage, eucalyptus, fir needle, geranium, grapefruit, juniper, lavender, lemon, lime, mandarin, lemongrass, orange flower, peppermint, petitgrain, pine, rosemary, sage, thyme, verbena, and ylang ylang Aroma Characteristics @4% in DPG. Peppery, terpene, spicy, balsam, herbal, plastic. Suggested Use Level 0.1%-4% Product Number W276200 Application Guide: IFRA Compliant Ingredients 15 VERATRALDEHYDE ≥98%, FG I FR A , KO S H E R A N D H A L A L This material’s sweet, woody, creamy character goes well with many fragrance types, especially chypre and Oriental fragrances. It can be used in many finished applications including soap where it can deliver a vanilla-like note without discoloration. 16 Odor Type Creamy Natural Occurrence Peppermint, raspberry and vanilla Aroma Characteristics @10% in DPG. Sweet, woody, creamy, vanilla, powdery. Suggested Use Level 1%-15% Product Number W310905 Flavors and Fragrances COPAIBA BALSAM OIL NATURAL, FG N AT U R A L , I FR A , KO S H E R A N D H A L A L This material is used in woody, sweet and spicy fragrances as well as pine and fir odors. Suitable for many finished products including fine fragrances and creams & lotions. Its substantivity makes it especially useful in hair and skin care products. Odor Type Woody Natural Occurrence Copaifera langsdorffii and reticulata Aroma Characteristics @5% in DPG. Woody, balsam, labdanum, spicy, clove. Suggested Use Level 0.1%-5% Product Number W521809 Application Guide: IFRA Compliant Ingredients 17 CIS-3-HEXEN-1-OL NATURAL, >98%, FCC, FG N AT U R A L , I FR A , KO S H E R A N D H A L A L Because it occurs naturally in many plants, this material finds wide usage in green, floral, aldehydic, fruity, pine and woody fragrances. It performs very well in many finished product formulations, especially candles where it provides lift to floral ingredients. 18 Odor Type Green Natural Occurrence Apple, bergamot, carnation, chamomile, citronella, clary sage, cornmint, gardenia, geranium, grass, jasmine, lavender, lemongrass, mango, rose, strawberry, and wormwood Aroma Characteristics @8% in DPG. Fresh, green, cut grass, foliage, vegetable, herbal, oily. Suggested Use Level 0.1%-8% Product Number W256323 Flavors and Fragrances Application Guide: IFRA Compliant Ingredients 19 Sigma-Aldrich ® Worldwide Offices Argentina Free Tel: 0810 888 7446 Tel: (+54) 11 4556 1472 Fax: (+54) 11 4552 1698 Australia Free Tel: 1800 800 097 Free Fax: 1800 800 096 Tel: (+61) 2 9841 0555 Fax: (+61) 2 9841 0500 Austria Tel: (+43) 1 605 81 10 Fax: (+43) 1 605 81 20 Belgium Tel: (+32) 3 899 13 01 Fax: (+32) 3 899 13 11 Brazil Free Tel: 0800 701 7425 Tel: (+55) 11 3732 3100 Fax: (+55) 11 5522 9895 Canada Free Tel: 1800 565 1400 Free Fax: 1800 265 3858 Tel: (+1) 905 829 9500 Fax: (+1) 905 829 9292 Chile Tel: (+56) 2 495 7395 Fax: (+56) 2 495 7396 People’s Republic of China Free Tel: 800 819 3336 Tel: (+86) 21 6141 5566 Fax: (+86) 21 6141 5567 Germany Free Tel: 0800 51 55 000 Free Fax: 0800 64 90 000 Tel: (+49) 89 6513 0 Fax: (+49) 89 6513 1169 Hungary Tel: (+36) 1 235 9055 Fax: (+36) 1 235 9068 India Telephone Bangalore: (+91) 80 6621 9400 New Delhi: (+91) 11 4358 8000 Mumbai: (+91) 22 4087 2364 Pune: (+91) 20 4146 4700 Hyderabad: (+91) 40 3067 7450 Kolkata: (+91) 33 4013 8000 Fax Bangalore: (+91) 80 6621 9550 New Delhi: (+91) 11 4358 8001 Mumbai: (+91) 22 2579 7589 Pune: (+91) 20 4146 4777 Hyderabad: (+91) 40 3067 7451 Kolkata: (+91) 33 4013 8016 Ireland Free Tel: 1800 200 888 Free Fax: 1800 600 222 Tel: +353 (0) 402 20370 Fax: + 353 (0) 402 20375 Israel Free Tel: 1 800 70 2222 Tel: (+972) 8 948 4222 Fax: (+972) 8 948 4200 Czech Republic Tel: (+420) 246 003 200 Fax: (+420) 246 003 291 Italy Free Tel: 800 827 018 Tel: (+39) 02 3341 7310 Fax: (+39) 02 3801 0737 Denmark Tel: (+45) 43 56 59 00 Fax: (+45) 43 56 59 05 Japan Tel: (+81) 3 5796 7300 Fax: (+81) 3 5796 7315 Finland Tel: (+358) 9 350 9250 Fax: (+358) 9 350 92555 Korea Free Tel: (+82) 80 023 7111 Free Fax: (+82) 80 023 8111 Tel: (+82) 31 329 9000 Fax: (+82) 31 329 9090 France Free Tel: 0800 211 408 Free Fax: 0800 031 052 Tel: (+33) 474 82 28 88 Fax: (+33) 474 95 68 08 Luxembourg Tel: (+32) 3 899 1301 Fax: (+32) 3 899 1311 Malaysia Tel: (+60) 3 5635 3321 Fax: (+60) 3 5635 4116 Mexico Free Tel: 01 800 007 5300 Free Fax: 01 800 712 9920 Tel: (+52) 722 276 1600 Fax: (+52) 722 276 1601 The Netherlands Tel: (+31) 78 620 5411 Fax: (+31) 78 620 5421 New Zealand Free Tel: 0800 936 666 Free Fax: 0800 937 777 Tel: (+61) 2 9841 0555 Fax: (+61) 2 9841 0500 Norway Tel: (+47) 23 17 60 00 Fax: (+47) 23 17 60 10 Poland Tel: (+48) 61 829 01 00 Fax: (+48) 61 829 01 20 Portugal Free Tel: 800 202 180 Free Fax: 800 202 178 Tel: (+351) 21 924 2555 Fax: (+351) 21 924 2610 Russia Free Tel: 8 800 100 7425 Tel: (+7) 495 621 5828 Fax: (+7) 495 621 6037 Spain Free Tel: 900 101 376 Free Fax: 900 102 028 Tel: (+34) 91 661 99 77 Fax: (+34) 91 661 96 42 Sweden Tel: (+46) 8 742 4200 Fax: (+46) 8 742 4243 Switzerland Free Tel: 0800 80 00 80 Free Fax: 0800 80 00 81 Tel: (+41) 81 755 2511 Fax: (+41) 81 756 5449 Thailand Tel: (+66) 2 126 8141 Fax: (+66) 2 126 8080 United Kingdom Free Tel: 0800 717 181 Free Fax: 0800 378 785 Tel: (+44) 01747 833 000 Fax: (+44) 01747 833 574 United States Toll-Free: 800 325 3010 Toll-Free Fax: 800 325 5052 Tel: (+1) 314 771 5765 Fax: (+1) 314 771 5757 Vietnam Tel: (+84) 8 3516 2810 Fax: (+84) 8 6258 4238 Internet sigma-aldrich.com Singapore Tel: (+65) 6779 1200 Fax: (+65) 6779 1822 Slovakia Tel: (+421) 255 571 562 Fax: (+421) 255 571 564 South Africa Free Tel: 0800 1100 75 Free Fax: 0800 1100 79 Tel: (+27) 11 979 1188 Fax: (+27) 11 979 1119 Order/Customer Service: sigma-aldrich.com/order Technical Service: sigma-aldrich.com/techservice Development/Custom Manufacturing Inquiries [email protected] Safety-related Information: sigma-aldrich.com/safetycenter ©2016 Sigma-Aldrich Co. 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