Diatomic Elements Some elements cannot exist by themselves, even when they are isolated from any other type of atom. Elements of this nature will combine with atoms of the same element in order to be stable. There are eight elements that form diatomic molecules: Three Hints: “7 that make a 7 and hydrogen” or “sneeze HNOF “ or “GEN-u-INE” General Information A chemical reaction is a process in which one or more substances are converted into new substances that have different physical and chemical properties. In a chemical reaction, those substances present before the reaction are called the reactants. Substances produced in a chemical reaction are called the products. A chemical reaction takes place when an atom can find a more stable way to be joined to other atoms. Chemical Equations Scientists represent chemical reactions in chemical equations. Chemical equations can be in words or in formulas. In writing equations, many times it is important to know the state of the atom or molecule you are working with. To show this, we use the following abbreviations: – (l) - liquid (g) - gaseous (s) - solid (aq) - aqueous Aqueous means dissolved in water. Balancing Equations In all reactions, the Law of Conservation of Matter is adhered to. Therefore, we must have the same number of atoms of each type of element on both sides of the reaction. We accomplish this by placing necessary coefficients in front of the atoms or molecules in order to balance the number of each atom or group on each side of the arrow. Examples Balance: __ Cu (s) + __ HCl (aq) --> __ CuCl2 (aq) + __ H2 (g) __SrF2 (aq) + __ Cu3PO3 (aq) --> __ CuF (aq) + __ Sr3(PO3)2 (s) Balance: Solid calcium is mixed with aqueous nickel (III) sulfate and makes aqueous calcium sulfate and solid nickel. Solid copper (II) oxide mixes with carbon dioxide gas (CO2) to make solid copper (II) carbonate. Examples Balance: __ Mg (s) + __ HI (aq) --> __ MgI2 (aq) + __ H2 (g) __NaF (aq) + __ Ag3P (s) --> __ Na3P (aq) + __ AgF (s) Balance: Solid calcium is mixed with liquid water to make aqueous calcium oxide and hydrogen gas. Solid cobalt (III) chloride mixes with aqueous strontium sulfide to make solid cobalt (III) sulfide and aqueous strontium chloride. Where do elements come from? All the elements that we talk about have to come from somewhere on the Earth: Atmosphere: N2, O2, Ar, some water and CO2 Hydrosphere: Water, NaCl, and smaller amounts of Mg, S, and Ca Lithosphere - Crust: Silicates (Compounds of Si, O and other metals), CaCO3, Fe2O3, PbS. Lithosphere - Mantle: Silicates with Mg & Fe Lithosphere - Core: Fe and Ni Ores & Minerals Very few elements are found uncombined in nature. Exceptions would include Au, N, O, Ag, Cu and noble gases The remainder of elements are usually found in ores, a naturally occurring rock that can be mined profitably. Within these ores are minerals, solid compounds containing the elements of interest. Types of Reactions In this chemistry course, we will focus on five basic types of reactions: 1) Combination or Synthesis - two or more reactants come together to form one product. Types of Reactions 2) Decomposition - a single compound is broken down into two or more smaller compounds or elements. Types of Reactions 3) Combustion - reactions in which a hydrocarbon is combined with O2 and burned to always form carbon dioxide and water. Oxidation & Reduction The process by which a mineral is converted to a pure element is called a reduction: Ex: CuCl2 (s) ---> Cu (s) + Cl2 (g) In a reduction, electrons are gained by an atom or ion. The process by which the metal is changed back into a cation is called an oxidation: Ex: 2 Cu (s) + O2 (g) ---> 2 CuO (s) In an oxidation, electrons are lost by an atom or ion. Redox Reactions When both happen at the same time, it is called a redox reaction EX: CuCl2 (aq) + Mg(s) ---> Cu (s) + MgCl2 (aq) Which of the reactants listed above is the reducing agent (source of electrons)? Which of the reactants listed above is the oxidizing agent (species removing e-)? Types of Reactions 4) Single Replacement - an uncombined element displaces an element that is part of a compound. Types of Reactions 5) Double Replacement or Metathesis - Atoms or ions from two different compounds replace each other. Activity Series of Metals The activity series is a listing of metals in order of their reactivity. An element at the top of the list would rather be in a compound than as an element. This activity series affects only single replacement reactions. Section 2B Review Balancing Balancing 2 Reaction Types Predicting Products Labs & Activities Misc. 10 10 10 10 10 10 20 20 20 20 20 20 30 30 30 30 30 30 40 40 40 40 40 40 50 50 50 50 50 50 60 60 60 60 60 60
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