Periodic Table Unit 4 Nuclear Chemistry Marie Curie named the process by which materials give off rays of energy ________________. A radioactive atom, or radioisotope, undergoes drastic changes as it emits this energy, called _________________; due to the instability of their nuclei. The stability of the nucleus depends on the relative proportion of neutrons to protons as well as the overall size of the nucleus. _______________________ is the process by which an unstable nucleus emits radiation in order to lose energy. This process is spontaneous, not requiring the input of energy and eventually results in a stable isotope of a different element from the original radioisotope. Three types of radiation can be emitted during radioactive decay: 1) ___________________, which consists of helium nuclei, also known as ________________________ and contain two protons and two neutrons and carry a double positive charge 2) ____________________, which consists of fast moving electrons formed by decomposing a neutron in the atom. The neutron decomposes into a ________, which remains in the nucleus and a ____________________, the electron, which is released. This particle carries a negative charge (indicated by the subscript –1 and a superscript 0 indicating a virtual lack of mass) 0-1 e 3) _____________________, which is high energy electromagnetic radiation, often emitted along with alpha or beta radiation by the nuclei of disintegrating radioactive isotopes. Since gamma rays have no mass or charge, their emission does not alter the atomic number or mass number of the atom. All nuclei with atomic number greater than _____ are radioactive and thus undergo decay. Most of them emit alpha particles, decreasing the mass number by ____ and the atomic number by _____. In this emission, a small amount of energy associated with radiation is produced while a small quantity of mass is lost. Every radioisotope has a characteristic rate of decay measured by the time required for one-half of the nuclei of a sample to decay to stable products. This rate is known as the _______________ and can be calculated using the formula A = A0 X (1/2)t/T When the nuclei of some isotopes are bombarded with neutrons, they undergo ________, the splitting of a nucleus into smaller fragments. This process can unleash large amounts of energy and with the release of additional neutrons as the nucleus fractures, can start a chain reaction. In a controlled chain reaction, the energy can be harnessed and used to produce electricity, like in a nuclear ___________. Uncontrolled nuclear chain reactions are started by devices like _________________________. Another type of nuclear reaction results when nuclei combine to produce a new nucleus of greater mass. This reaction also requires two beta particles and is known as nuclear _____________. This is the type of reaction that occurs in the sun. In solar fusion, hydrogen nuclei fuse to make helium nuclei. The drawback to using fusion as an affordable source of energy production is that it only takes place at extremely high _______________________. H. Cannon, C. Clapper and T. Guillot Klein High School Nuclear Chemistry 1. A radioisotope of the element lead (Pb) decays to an isotope of the element bismuth (Bi) by emission of a beta particle. Complete the equation for the decay process by supplying the missing atomic number and mass number. 210 PB Æ 83Bi + 0-1e 2. Write the symbol and charge for each: alpha particle beta particle gamma ray 3. The disintegration of radium-226 produces an isotope of radon and alpha radiation. The atomic number of radium (Ra) is 88 and the atomic number of radon(Rn) is 86. Write a balanced equation for this transformation. 4. The following radioisotopes are beta emitters. Write balanced nuclear equations for their decay processes. a. Carbon – 14 b. Strontium – 90 c. Potassium - 40 5. The following radioactive nuclei decay by emitting alpha particles. Write the product of the decay process for each. a. 23894 Pu b. 210 c. 210 83 Bi 84 Po 6. A patient is administered 20 mg of iodine – 131. How much of this isotope will remain in the body after 40 days if the half-life for iodine – 131 is 8 days? 7. How are the mass number and atomic number of a nucleus affected by the loss of the following? a. Beta particle b. Alpha particle c. Gamma ray 4-2 HC/CC/TG KHS Nuclear Chemistry For the following, fill in the missing information and tell the type of decay 8. 263 9. 14 Sg Æ 259Rf + ___________ C Æ 14N + 10. + ___________ Æ134Xe + 100Sr + ___________ 11. 2H + 3H Æ 4He + ___________ 13. 63Zn Æ ______ + 0e 30 14. 237Np Æ 93 -1 4 He + _______ 2 _________ __________ 15. If you begin with 1000 atoms of C-14 with a half-life of 5730 years, _______________ atoms will remain after one half-life. 16. If you begin with 1000 atoms of C-14, after 11460 years, which is _______________half lives; _____________ C-14 atoms will remain, after three half lives, __________ C-14 atoms would be left. 17. Thorium 234 has a half life of 25 days. In 25 days, _____% of the sample will remain. In 50 days, __________ % of the sample will remain. In 150 days, _______% of the sample will remain. (start with 100%) 18. Manganese-56 is a beta emitter with a half life of 2.6 hours. What is the mass of Manganese-56 in a 2.0 mg sample of the isotope after 10.4 hours? What is the mass and name of the remaining isotope (the other element)? Look at the graph to the right: 19. What is the half-life for Sodium -24? 20. How much Sodium is left after 3 half lives? 21. 2 grams of Sodium remain after 30 hours, how many grams did the original sample contain? 4-3 HC/CC/TG KHS
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