GPS Product Safety Summary Document Number: GPSSR-6 Pigment Blue 15 GENERAL STATEMENT GPS summary is intended to provide a general overview of the chemical substances in context of ICCA Global Product Strategy. The information in the summary is general information about the chemical properties & hazards involved to human & environment. Additional information is available through the relevant Safety Data Sheet, which should be consulted before use of the chemical. Pigment Blue 15 is mainly used as Colorant/organic pigment in Industrial Performance Chemicals, Paints, lacquers and varnishes industry, Polymers industry, Printing Inks Industry. CHEMICAL IDENTITY Name Chemical Name (IUPAC) Colour Index Name EC Number CAS Number Molecular Formula Molecular Weight Structure : : : : : : : : Pigment Blue 15 (29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper C.I. Pigment Blue 15 205-685-1 147-14-8 C32H16CuN8 576.08 N N N N Cu N N N N USES AND APPLICATIONS Colouring agent for paints, plastics and inks, used in industrial applications and consumer products. PHYSICAL/CHEMICAL PROPERTIES Property Form Physical state Colour Odour Density Page 1 of 4 Value Solid Powder Blue Odourless 1.62 g/cm3 GPS Product Safety Summary Melting point Flammability Explosive properties Self-ignition temperature Granulometry Water solubility 480 °C Non flammable Not explosive 356°C 50-100% <100 micron 22-50% < 10 micron 22% < 4 micron 4 -9 µg/l HEALTH EFFECTS Human Health Safety Assessment No human health hazard was identified. Worker : According to the present knowledge provided the substance is handled properly there is no identified risk to humans. The usual precautions, industrial hygiene and occupational safety measures for handling chemicals have to be observed. In case of unintended exposure during maintenance, sampling, testing, or other procedures workers should follow the recommended safety and first-aid measures in the Safety Data Sheet. Effect Assessment Acute Toxicity Oral / inhalation / dermal Irritant effect on skin & eyes Sensitisation Toxicity after repeated exposure Genotoxicity / Mutagenicity Carcinogenicity Toxicity for reproduction Results Not toxic after oral exposure No acute dermal and inhalation toxicity to be expected Not irritating to skin & eyes Not sensitising Not toxic Not mutagenic in genetic toxicity in-vitro and in-vivo No carcinogenicity to be expected No toxicity for reproduction to be expected ENVIRONMENTAL EFFECTS Environment Safety Assessment No environmental classification is proposed since no (adverse) effects have been observed in the ecotoxicological testing (see below). Furthermore the substance is evaluated to be not PBT (persistent, bioaccumulative, toxic) or vPvB (very persistent, very bioaccumulative). Effect Assessment Acute fish toxicity Acute daphnia toxicity Algae toxicity Bacteria toxicity Page 2 of 4 Results Not toxic to fish Not toxic to daphnia Not toxic to algae (analogy) Not toxic to bacteria GPS Product Safety Summary Fate and Behaviour Biodegradation Bioaccumulation potential PBT / vPvB conclusion Results Not readily biodegradable Low bioaccumulation potential Not PBT or vPvB substances EXPOSURE Human Health: Exposure to Pigment Blue 15 of personnel in manufacturing facilities is also considered low because the process, storage and handling operations are under industrial hygiene considerations and occupational satefy measures. Workers who might accidentally come in contact with the substance should follow the safety and first-aid measures recommended in the Safety Data Sheet. Environment: As Pigment Blue 15 is neither to be classified as dangerous according to CLP Regulation (EC) No 1272/2008 or Directive 67/548/EEC nor is assessed to be PBT or vPvB substances, no exposure assessment and risk characterisation has to be performed. RISK MANAGEMENT RECOMMENDATIONS The substance Pigment Blue 15, a copper phthalocyanine pigment, is not a dangerous substance according to regulation (EC) No 1272/2008. Always apply technical measures and use personal protective equipment as recommended in the Safety Data Sheet to minimize exposure. Observe the usual industrial hygiene measures. Remove soiled or soaked clothing immediately. STATE AGENCY REVIEW This substance has been registered under REACH REGULATORY INFORMATION / CLASSIFICATION AND LABELLING Labeling according CLP regulation (Regulation (EC) No. 1272/2008, as amended): No labelling required Signal Word: No signal word CONCLUSION The assessment has revealed that this substance is considered to be safe for the above described uses and applications as colouring agent . Page 3 of 4 GPS Product Safety Summary CONTACT INFORMATION WITHIN COMPANY Clariant Produkte (Deutschland) GmbH 65926 Frankfurt am Main Telephone no. : +49 69 305 18000 GLOSSARY Acute toxicity: harmful effects after a single exposure Biodegradable: breakdown of materials by a physiological environment Bioaccumulation : accumulation of substances in the environment Carcinogenicity: effects causing cancer Chronic toxicity: harmful effects after repeated exposures Clastogen: a substance that causes breaks in chromosomes Embryotoxicity: harmful effects on foetal health GHS: Global Harmonized System Hazard: situation bearing a threat to health and environment Mutagenicity: effects that change genes Reprotoxicity: combining teratogenicity, embryotoxicity and harmful effects on fertility Sensitising: allergenic Teratogenic: effects on foetal morphology DATE OF ISSUE January 2012 REVISION ADDITIONAL INFORMATION DISCLAIMER The information contained in this paper is intended as advice only and whilst the information is provided in utmost good faith and has been based on the best information currently available, is to be relied upon at the user’s own risk. No representations or warranties are made with regards to its completeness or accuracy and no liability will be accepted by Clariant for damages of any nature whatsoever resulting from the use of or reliance on the information. Page 4 of 4
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