Scripps Reference Gas Calibration System for Carbon
Dioxide-in-Nitrogen and Carbon Dioxide-in-Air Standards:
Revision of 2012
Ralph F. Keeling
Peter Guenther
Stephen Walker
Dave Moss
Scripps Institution of Oceanography
March 2016
1
Table of Contents
1
Introduction ........................................................................................................5
2
Description and Operation of the Constant-Volume Mercury-Column Manometer
(CMM) ........................................................................................................................9
2.1
Description of the CMM ..................................................................................... 9
2.2
Procedure for Determination of Mole Fraction of CO2 in Air ........................... 11
2.3
Meniscus corrections ........................................................................................ 12
2.4
N2O corrections ................................................................................................. 14
3
Volume Calibrations of Glass Plenums ............................................................... 15
4
CMM Thermometer Drift and Corrections .......................................................... 18
5
4.1
Thermometer Calibration ................................................................................. 19
4.2
Discussion.......................................................................................................... 19
Constants Currently used in Manometric Calculations........................................ 20
5.1
True Constants .................................................................................................. 20
5.1.1 Molar Gas Constant, R .................................................................................. 20
5.1.2 Acceleration due to Gravity, g ...................................................................... 21
5.1.3 Temperature Scales ...................................................................................... 21
5.1.4 Pressure Conversion Constants .................................................................... 22
5.1.5 (Weight) Buoyancy Correction for Calibration of Volume of Apparatus...... 23
5.2
Temperature Dependent Quantities ................................................................ 23
5.2.1 Density of Mercury, ρ (Hg) ............................................................................ 23
5.2.2 Density of Water, ρ (H2O) ............................................................................. 24
2
5.2.3 Second Virial Coefficient: CO2 ....................................................................... 25
5.2.4 Second Virial Coefficient: N2 ......................................................................... 25
5.2.5 Second Virial Coefficient: O2 ......................................................................... 25
5.2.6 Second Virial Coefficient: Air (CO2-free) ....................................................... 25
5.3
6
CO2 Isotopic Constants...................................................................................... 26
Determinations of the Small Chamber Volume .................................................. 27
6.1
Characterization of 4 cc Chamber Drift ............................................................ 28
6.2
Previous Analysis of Small Chamber Volume ................................................... 30
7
Determinations of the Large Chamber ............................................................... 31
8
Calibrations of Cathetometer............................................................................. 32
9
Isotope Corrections ........................................................................................... 34
10 CMM Accuracy and Imprecision ......................................................................... 35
11 Primary Reference Gas Determination ............................................................... 37
12 Infrared Analyzer Calibrations ........................................................................... 38
12.1
APC Linear I and J Scales ................................................................................... 38
12.2
Implementation of the New X12 Calibration Scale .......................................... 40
13 Comparisons with the NOAA Calibration Scale ................................................... 42
14 References ........................................................................................................ 44
15
Tables .............................................................................................................. 47
16
Figures .............................................................................................................. 55
17
Appendix A. Supplemental Tables ............................................................. A1-A7
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18 Appendix B. Supplemental Figures ............................................................ B1-B24
19 Appendix C. MATLAB and FORTRAN Code ....................................... Pages C1-C13
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1 Introduction
This document follows in the sequence of technical reports documenting aspects of the
calibration of carbon dioxide (CO2) in air by the Scripps Institution of Oceanography
(SIO) CO2 Program. The most recent two of such reports were C.D. Keeling et al. [2002]
and Guenther et al [2002a].
This report is the basis for an updated Scripps CO2 scale which addresses analyses and
diagnostic activities carried out on the constant volume manometer (CMM) over the past
few decades, particularly incorporating additional tests done after year 2000.
The Scripps program served as the Central Calibrating Laboratory (CCL) of the
Background Air Pollution Monitoring Network (BAPMoN) of the World Meteorological
Organization from 1975-1995. Although the role of CCL was taken over by the NOAA
Climate Monitoring and Diagnostics Laboratory in 1995, Scripps has continued to
maintain an independent calibration since that time. Maintaining an independent scale
was essential to ensure continuity of the long-term records of CO2 maintained at Scripps
and to allow for continuing comparisons with the NOAA scale, in order to better resolve
any differences.
The propagation of the Scripps CO2 scale since 1990 has been complicated by apparent
drift in the Scripps primary references gases as determined on the constant-volume
mercury-column manometer (CMM). As summarized in the previous reports, it was not
easy to resolve whether this drift was caused by instability in the gases or changing
systematic errors in the manometry. These inconsistencies are reflected in the fact that
the Scripps CO2 data over this period have been worked up on two different scales, one of
which effectively assumes the reference gases on average have remained stable since
1985 (X99A), the other assuming the manometry has remained stable (X99B). This
ambiguity in the Scripps scale has confounded attempts to reconcile the Scripps scale
with NOAA.
The purpose of this report is to examine further the issues involving this scale ambiguity,
with the goal of arriving at a single Scripps scale which optimally reconciles the earlier
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CO2 data with recent data, and which makes the most reasonable assumptions concerning
drift in the Scripps reference gases and in the manometer. This report will advance
evidence showing that drift in both the reference gases and in the manometry both
occurred. The instability in the reference gases is further evaluated by examining more
closely the long-term history of the concentration differences between gases as
determined by infrared analysis.
This report also addresses small corrections to the Scripps CO2 scale, not previously
applied, for differences in the isotopic composition of the primary reference gases
relative to background air.
The Scripps CO2 program has relied, through nearly its full history, on CO2
measurements made on an Applied Physics Corporation (APC) non-dispersive infrared
CO2 analyzer operated at Scripps. (Between Aug. 2012 and Aug.2013, the Scripps APC
analyzer was transitioned to a Picarro 2301 analyzer between, using the same calibration
strategy). The analyzer is calibrated based on suites of reference gases stored in highpressure cylinders ("tanks"). The CO2 mole fraction in these reference gases is assessed
using a manometric analysis on the CMM. The method involves introducing an air
sample from these tanks into a large (~5 liter) chamber at known pressure and
temperature to determine the number of moles of sample. The CO2 is then extracted and
the CO2 is introduced into a smaller chamber (~4cc) at known pressure and temperature
to determine the number of moles of CO2. The manometric reference gases include 12
CO2-in-air gases in use since the early 1980's and CO2-in-N2 gases which were used also
previously. The concentrations in these gases range from about 200 to about 500 ppm.
The full suite of CO2-in-air reference gases was analyzed on the CMM roughly once
every two years from 1981 to 1998 and then again in 2005. Each set of manometric
analyses were paired with so-called "marathon tank days" in which the full suite of
reference gases were analyzed on the APC system. These APC analyses were used to
define a cubic relationship between so-called J-index values and the true CO2
concentrations, as described in other technical reports [Keeling et al., 2002]. The J index
is a scale which is linear in the APC response and propagated in time through a series of
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short-lived secondary reference gases, which are replaced sequentially in self-consistent
fashion. The cubic relationships have been found typically to be slightly different from
one marathon tank day to another. The differences could arise due to drift in the
secondary reference gases, drift in the non-linearity of the APC analyzer, or errors in the
manometric determinations of the primaries. These cubic relationships are linearly
interpolated in time between the marathon tank days, or extrapolated forward from the
last tank day to the present, and yield the time-dependent relationship between the J index
and true concentrations.
Each new marathon tank day provided a basis for revising the calibration of the APC
analyzer (i.e. revising the cubic) back to the previous marathon tank day. The revised
CO2 values were reported as being on a new scale XYY, where YY here refers to the year
of the last marathon tank day (e.g. X95). Each new scale typically only involved changes
to the data since the last marathon tank day, although some of the scale changes also have
entailed changes also to earlier data, as documented in earlier reports.
In principle, the manometric calibration procedure corrects for any long-term drift in the
CO2 concentration of the reference gases by virtue of the repeated manometric
determinations, which automatically track and correct for this drift. In practice, however,
the ability to resolve drift in the reference gases has been obscured by questions about
drift of the CMM.
The reasons for the drift in the manometer have remained obscure. A particularly
sensitive element of the manometer is the small chamber used to assess the molar
amounts of CO2. This chamber is nominally 4 cm3 in volume and referred to as the "4 cc
chamber". A leading hypothesis for the drift in the manometer has been changes in the
effective size of the 4 cc chamber, which would lead to proportional errors in the reported
manometric CO2 mole fractions. Accordingly, the drift in the manometer has been
allowed for by adjusting the apparent size of this chamber to achieve approximately
constant values for the primary reference gases during the calibrations of the APC
analyzer from 1985 to 1999. Significant adjustments for the drift were made for the
calibrations in 1993, 1995, and 1998 [Keeling et al., 2002, Figure 4]. The manometric
7
determinations, adjusted retrospectively for apparent changes in the 4cc chamber in this
way, formed the basis of the X99A scale [Keeling et al., 2002]. This scale, which was
effectively anchored to manometry done in the mid 1980's and early 1990s, formed the
basis of a crucial comparison with NOAA primary reference gases in 1999 [Guenther et
al., 2002b]. Most of the recent Scripps CO2 data has been reported on this scale or on its
extension to the present.
In the case of the drift in the mid 1980's the assumption that the effective size of the 4 cc
chamber changed is still defensible. However, for the drift through the 1990's subsequent
work showed conclusively that the 4 cc chamber remained highly stable [Guenther et al,
2002a], which would appear to undermine the basis on which the X99A scale was based.
Even though the X99A scale is now known to be based on an incorrect assumption about
why the manometer drifted, the scale is still useful as a basis for reporting CO2 data.
Being anchored to the manometry of the 1980s, the scale provides continuity to the
earlier CO2 data at Scripps. The scale was shown to be highly consistent with the NOAA
determinations in 1999. Furthermore, the extrapolation over the troubling period in the
1990s is based on a very clear assumption; namely, that the primary reference gases have
remained stable. An important goal of this report is to examine the available constraints
on this assumption based on the longer history of these and other gases.
Since 1999, the X99A scale has been propagated forward under the assumption that the
values of the primary reference gases remained stable since 1998. Thus for marathon
tank days in 2001, 2003, 2005 and 2008, these gases were assigned the same
concentrations as had been used for their values for the marathon tank day in 1999, thus
forming the basis of the X01A, X03A, X05A and X08A scales. The 1999 marathon tank
day used values from 1998 manometry that allowed for a variable 4cc volume. Note that
the method of propagating the scale after 1999 differs from the method used for the
period of the 1990's. In the earlier period, the marathon tank day indices were paired
with the nearest (in time) measurements on the CMM. The latter were calculated using
adjusted 4cc chamber volumes that allowed the overall reference gas concentrations to
remain constant. The eight different sets of marathon tank days on the APC used five sets
8
of manometrically - determined values based upon adjusted 4 cc volumes in the CMM.
For those years with no manometric measurements the set from the nearest year was
chosen. The adjustments kept the reference gas concentrations approximately, but not
exactly constant. Only in the latter period were the reference gas concentrations kept
exactly constant.
In this report the history of manometer drift will be reviewed following new evidence of
changes in volumes of plenums used in the small chamber calibration and of drift in the
thermometers. These two phenomena give new insight into the behavior of the small
chamber’s volume over time and allow reassessment of all manometric determinations
since 1974. This work supports the introduction of a new calibration scale for 2012, the
X12 scale.
2 Description and Operation of the Constant-Volume MercuryColumn Manometer (CMM)
2.1 Description of the CMM
The CMM at SIO is a mercury manometer assembly adapted to the measurement of
quantities of gas as well as pressure. As such, each manometer (the CMM comprises
three independent manometers) has three "legs" connected to each other and filled with
mercury. See the detailed diagrams in Keeling et al (1986) and Figure 1.
In each manometer, one leg is kept evacuated above the mercury (the "vacuum column"),
one leg contains designated volumes demarcated by glass pointers (the "sample
column"), and the third leg is connected to controllable sources of pressure and vacuum
(the "control column"). The mercury levels in the vacuum and sample columns are
simultaneously raised or lowered by the application of pressure or vacuum to the control
column. The lower parts of the three columns (containing mercury) are connected to each
other via 3 mm ID capillary tubing so that mercury movement is optimally slow.
The CMM consists of three of these manometers. Columns 1 and 3 (numbered from the
left) are the vacuum and sample columns, respectively, of an alternate small-chamber
manometer that has never been used. Columns 2 and 4 are the vacuum and sample
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columns, respectively, of the primary small-chamber manometer. Column 4 contains five
"chambers" with volumes demarcated by glass pointers mounted in the glass tubing of
the columns. The largest chamber (nominally 325 cc) includes all the other volumes and
is defined by a stopcock at the top of the column, by the mercury surface at the pointer
and by the closed-end part of the column. The remaining volumes of nominally 64 cc, 16
cc, 4 cc, and 1 cc, are defined by the mercury surface at the specific glass pointers and by
the closed-end part of the column.
The large-chamber manometer comprises three sample columns, 5, 6, and 7, and one
vacuum column, 8, on the far right. These columns are all connected by the lower
capillary tubing (filled with mercury) to each other and to the large-chamber manometer
control column. The sample columns of the large-chamber manometer each contain two
volumes, both demarcated by the mercury surface aligned at the same glass pointer and
by the stopcocks at the top of the columns. The total volumes are nominally 5000 cc and
1000 cc, the latter obtained by closing the stopcock on a nominally 4000 cc glass flask
attached to the column.
All of the columns are connected at the top with glass stopcocks and manifolds to each
other and to the associated vacuum line. Gas and vacuum can thus be introduced into any
of the columns and gas transferred between columns. The two control columns used are
independent of each other and connected to a vacuum pump and a cylinder of N2 gas for
pressure, with valving to allow precise control of the mercury levels.
The entire manometer assembly is enclosed in a cabinet which is an "air bath," having
five air circulating fans with motors isolated from the interior of the cabinet to control
heat and vibration. The upper part of the front of the manometer cabinet has doubleglazed windows. In front of the cabinet a custom-built high-precision cathetometer is
mounted on a pedestal so that its telescope can be focused on the mercury columns
through the glass windows. The cathetometer telescope is attached to a 1 mm pitch lead
screw and contains a cross hair that can be aligned with the mercury surfaces. The lead
screw has counters and a manual control that allow a readability of 0.002 mm over a
10
range of one meter (the least count of the cathetometer is 0.01 mm). See Section 8 and
Figure 1.
Temperatures within the cabinet are read using the cathetometer telescope on a mercury
thermometer mounted near the 4 cc volume chamber. Six other thermometers of the same
type are mounted inside the cabinet and are also read routinely to monitor gradients. The
temperature read on the primary thermometer in the air bath (No. 6112) is assigned to the
gas and to the mercury for a measurement. See Section 4 of this report for details on the
thermometer calibration.
2.2 Procedure for Determination of Mole Fraction of CO2 in Air
A CO2-in-air reference gas is attached to a pressure regulator that is connected via
stainless steel tubing to an entry point on the CMM's associated vacuum line. The gas is
flowed slowly through a thimble trap cooled to dry ice temperature (-78 °C) and thence
through glass manifolds into one of the sample columns of the large-chamber manometer
(routinely sample column 5). Pressure is applied to the control leg of the large-chamber
manometer to maintain the mercury level in the sample column at the glass pointer, and
causing the mercury level in the vacuum column (8) to rise. Filling the five-liter volume
to a pressure of about 600 mm of mercury requires about 10 minutes.
After temperature equilibration for at least one hour, the mercury is raised to within
approximately 0.2 mm of the pointer and stabilized. The sample column height is
measured with the cathetometer, followed by the vacuum column height and the
temperature. Finally the sample column height is measured again to assure stability. With
the volume of the chamber known and the temperature and pressure measured, the
number of moles of "total gas" is calculated from the gas law, using the temperaturedependent "second virial coefficient" for air (or the appropriate virial coefficients for
another gas such as N2 for a CO2-in- N2 reference gas).
The next step is to extract cryogenically the condensable gases at liquid N2 temperature
(77 K). The 5-liter sample of gas is pumped through a spherical trap located on the
associated vacuum line and kept filled with liquid N2. The extraction rate is kept slow by
throttling the pressure entering the trap to 1 cm mercury or less. For an air reference gas,
11
the perceptible gases extracted are CO2 and N20 (approximately 0.1% of the CO2) and
any residual water.
After the extraction is complete, the gas is transferred by a series of sublimations at dry
ice temperature into the 4 cc chamber of the small-chamber manometer sample column 4.
Three sublimations are routinely done: dry ice slurry applied to sample frozen at liquid
N2 temperature to a destination trap frozen at liquid N2. When the final transfer into the
closed-end portion of the small-chamber manometer is complete, pressure is applied to
the control leg of the small-chamber manometer to raise the mercury level in column 4
above the "entry tube" into the closed-end portion. The sample is then allowed to thaw.
After temperature equilibration, the mercury level is slowly raised to a level just below
contact with the pointer. By experience, this level is visually as close to the pointer as can
be managed without "prematurely" making contact with the pointer. Normally this firststage mercury level is 0.03 mm or less below the pointer. The thermometer and then the
small-chamber manometer vacuum column (2) height are then read. The mercury is then
slowly raised with small increments of added pressure until contact with the pointer just
occurs. The sample column mercury height is then measured (second stage), followed by
the second vacuum column height and the temperature. The before/after vacuum column
heights are usually 0.1 to 0.2 mm apart. Averages are made of the before/after contact
mercury heights and temperatures (usually within 0.02 °C of each other) and recorded for
further processing.
With the volume of the chamber known and the temperature and pressure measured, the
number of moles of CO2 is calculated from the gas law, using the temperature-dependent
"second virial coefficient" for CO2. The moles of CO2 divided by the moles of total gas
yields directly the mole fraction (mixing ratio) of CO2 (including N20 - see below) in the
air reference gas.
2.3 Meniscus corrections
The vacuum columns and most of the sample columns at the pointers delineating the
“constant volume” chambers in the CMM have an I.D. of 1.9 cm (1” gauge glass).
However the 4cc chamber has an I.D. of 0.95 cm at the pointer defining its volume.
12
Consequently a significant “meniscus correction” must be measured and applied to
account for the depression of the mercury in the smaller tube. The only way to measure
this effect is to compare the column heights of the small manometer (sample column
versus vacuum column) with a vacuum in each column. The correction is approximately
0.3 mm in magnitude. The meniscus correction difference is subtracted from mercury
height differences for measurements of CO2 in the 4cc chamber. Corrections were also
measured for the large volume manometer, where the columns are of identical nominal
diameters. In this case the corrections are more properly termed “column corrections”
and if non-zero are presumably caused by an out-of- level swing in the telescope of the
cathetometer.
Meniscus corrections were measured periodically during manometric measurement
periods. The standard procedure (for the small manometer 4 cc chamber) was to evacuate
the sample column and check the vacuum in the vacuum column. The mercury was then
raised to “close” to the pointer in the 4 cc chamber. The control column stopcock was
closed to prevent drift during the measurements. Then the sample and vacuum columns
were alternately measured 10 times each, with each measurement being the average of
two cathetometer cross hair settings on the surface of the mercury. The determined
correction was the average of these 10 column height differences. The large manometer
corrections were measured in the same way, except that the vacuum and sample columns
could be connected; therefore an identical vacuum in each column was assured.
Variation in the meniscus corrections should be small. However, some effects causing
variation were identified during the measurements. One that is always present is variation
in the level of the swing of the cathetometer scope between the columns being compared.
This effect causes the magnitude of the “column corrections” measured for columns with
identical diameters, for example the large manometer corrections. There is a bubble level
on the cathetometer scope. The level was checked frequently and occasionally adjusted.
Small changes in the level observed with the bubble seemed to occur randomly and were
observed but not always corrected, due to the imprecise nature of the leveling
adjustments.
13
A second effect observed in the small manometer corrections apparently depended upon
the distance that the mercury level was set below the pointer. The “jumping mercury
problem” (Guenther and Keeling, Manometer Report III, 1981), probably due to
electrostatic effects, in some cases required the mercury level to be set farther away from
the pointer, whereas when absent or small the mercury could be closer. The mercury level
had to be set sufficiently close to the pointer for the meniscus reader (permanently
mounted behind the 4 cc pointer) to properly delineate the mercury surface. It appeared
that the closer the mercury was to the pointer the larger (more negative) the meniscus
correction. During the “dirty mercury” period in 1984 the pointer could be approached
more closely and the correction was larger.
Figure 2 shows the measured meniscus corrections for both the 4cc chamber column and
the large volume column. These measurements are also listed in Tables 1 and 2. As well
as showing quasi-random scatter, there appear to be two significant shifts, one occurring
at the time the manometer was cleaned in 1985, and one occurring between 1999 and
2004, during a long hiatus in manometer usage. For the latest revision of the manometric
analysis reflected in this report, we have chosen to apply constant meniscus corrections
over each of the three periods demarked by these shifts, as indicated by the solid black
lines in Figure 2. An exception to this procedure is that the meniscus corrections applied
for calibration of the chamber volumes were mostly based on concurrent measurements
and not on long-term averages. The meniscus corrections used for the chamber
calibrations are separately indicated in Figure 2. Previous reports used meniscus
corrections that were also sometimes averaged over certain periods, but less
systematically. The meniscus revisions relative to previous reports cause changes in CO2
mole fractions of the primary air manometric reference gases (“white stripes”) of at most
0.15 ppm for the calibrations made in 1998, while the changes produced in other years’
white stripe determinations are less than 0.06 ppm.
2.4 N2O corrections
The manometric analysis of reference gases involves the cryogenic extraction of the CO2
gas fraction at liquid nitrogen temperatures. For whole air reference gases, this fraction
also contains N2O gas, present at the level of approximately one part in 1000 (~ 0.3 ppm).
14
The mole fractions of N2O gas in the primary air manometric reference gases (“white
stripes”), as well as a some others, have been measured in the laboratory of Professor Ray
Weiss at SIO using gas chromatography (flame ionization detector). The measured N2O
content of compressed air in cylinders filled at our laboratory with unmodified CO2 mole
fractions are within 0.02 ppm of the average atmospheric mole fraction, taken to be 0.31
ppm. The suite of 11 primary air reference gases varied between 0.24 and 0.37 ppm N2O.
Gases with CO2 partially removed during cylinder filling have the largest deviations from
0.31 ppm. N2O corrections applied to manometric measurements of air reference gases
are listed in Appendix A, Table A7. The nominal value of 0.31 ppm has been applied to
those gases not analyzed for N2O.
3 Volume Calibrations of Glass Plenums
The volume of the small (nominally 4 cc) chamber of the CMM since 1974 has been
calibrated with reference to the volumes of a set of glass containers ("plenums"). The
original set of plenums range in size from 1.3 cc to 2.3 cc; their volumes are determined
by weighing them filled with contained liquid. The first volume calibrations were done
using mercury in 1974 by J. A. Adams [1977] with results reported in Guenther [1981]
and Keeling et al., [1986].
In 1999 G. Emanuele utilized improved balance technology to recalibrate the plenum
volumes by weighing them filled with water, to acceptable precision [Guenther et al.,
2002a]. The water used was from a Milli-Q type filtration system that was degassed by
being evacuated and allowed to boil at a slow controlled rate for roughly 1.5 hours.
Emanuele's volumes were smaller on average than the 1974 values by one part in 2350.
At the time we considered that the difference in some way was caused by different
characteristics of the liquid used (e.g. due to interaction with grease near the stopcock),
and we normalized the water results to the mercury results for a time. G. Emanuele
repeated the water calibrations in 2007 and found a further decrease in volumes. Finally,
later in 2007, P. Guenther made calibrations using mercury, for the first time since 1974.
The results quite closely confirmed the 2007 water calibrations. We then revised our
15
approach to consider that the measured volume changes were "real" and henceforth have
given equal weight to all of the volume calibrations.
The original data and resulting volumes of the entire set of plenum volume calibrations
are reported in Table A1.
We hypothesize that the volumes of the plenums have changed by the measured amounts
during the 25 to 33 year period. Support for this conclusion is found in the phenomenon
called "zero creep," documented for mercury thermometers [Douglas, 1966]. The
literature we have found mainly addresses this relatively short-term phenomenon in glass
thermometers that have been heated over the transition temperature [Hall and Leaver,
1961]. For Pyrex glass this temperature is 550 °C. During their lifetime the plenums have
been "ashed" or possibly even annealed usually at least once during every year in which
they were used, in order to clean them thoroughly of grease. The ashing temperature has
been 510 to 525 °C, while the annealing temperature is 565 °C. We have found in the
laboratory notebooks documentation of the plenums being placed in the glass oven 12
times, six between 1974 and early 1999 and six between late 1999 and 2007. There are
also reports in the literature of a decrease in the volume of mercury thermometer bulbs
and capillaries over many years at room temperatures. This slow drift is called "secular
change." A review article [Nemilov, 2003] cites studies of this phenomenon, some dated
in the late 1800's.
In August 2007, D. Lowe and P. Guenther attempted to measure a physical change in the
plenums. They assumed that the volume change would cause the originally round cross
section of the plenum tube to collapse slightly to an elliptical cross section (the plenums
had been placed horizontally in the glass annealing oven). The O.D. of the plenum tubes
were measured in two axes using a micrometer and compared to the measured O.D. of
1/4" O.D. glass tubing. The results indicated measurable eccentricity in the plenums
compared to the new tubing, but it was random in direction rather than always in the
direction of gravity, and the magnitude of the implied volume differences was between 1
in 10,000 and 1 in 50,000 rather than close to 1 in 2350. It is possible that the O.D.
measurements did not reflect the actual change in volume. For instance, the length could
have changed (note that the plenums were stored for long periods (at room temperature)
16
in a vertical position). We postulate that the plenums have changed in volume, due in part
to repeated exposures to high temperatures, notwithstanding the negative result of
physical measurements.
The original plenums are numbered P01 to P07. The table also includes plenums that
have not been used for 4cc chamber volume calibrations. For instance, plenum number
P13 is actually the nominally 4000 cc bulb mounted inside the CMM cabinet as part of
one of the nominally 5000 cc chambers. It was removed from the cabinet and weighed
with and without water to determine its volume in 1974 and in 2004. It serves as the
"plenum" to calibrate the volume of the large manometer 5000 cc chamber by transfer of
CO2 gas (see Section 7). Some plenums have been used only to calibrate the chamber
volume of the electronic manometers. There is a set of eight larger plenums with volumes
ranging from 7 cc to 20 cc (with an "L" prefix). These larger plenums were used to
calibrate the CMM 4 cc chamber in the post- renovation period (2004 - 2010). The larger
plenums (except for L02) were calibrated for volume only with contained water,
beginning in 2007.
There were four sets of volume calibrations of the original set of plenums. In 1974 and
2007 volume calibrations were made with contained mercury, and in 1999 and 2007 with
contained water. We have made a linear fit to each plenum volume as a function of time,
and choose the volume to be used for a particular CMM small chamber calibration based
on the linear fit.
Figure 3 shows all of the plenum volume calibrations for five (P01, P02, P03, P06, P07)
of the original seven plenums versus time, and also linear fits to the data. Plenums P04
and P05 are not shown because they exhibited aberrant behavior. The small chamber
calibrations in 1985 using plenums P04 and P05 were very different from those using the
other five plenums and were rejected. It seemed that the volumes of the two plenums had
changed anomalously between 1974 and 1985. Small chamber calibrations were made
with P04 and P05 again in 1988, and again rejected. Since then those two plenums were
not used again for 4cc chamber calibrations.
17
Figure 3 also shows a time plot for volume calibrations of Plenum L02, although it was
used for small chamber volume calibrations only in 2008 and 2009. It is noteworthy that
this larger plenum (11.09 cc) shows little change in volume between 1974 and 2007,
possibly because it did not go into the glass oven during the intervening period or
because its larger size made it less sensitive to the factors impacting the smaller plenums.
The calibrations in 1974 were done using mercury, while those in 2007 used water. The
other two larger plenums with calibrations in the 1970's and 2000's are P09 (51.4 cc) and
P11 (270.8 cc). Plenum P09 was calibrated for volume in 1974 and in 2008, in both cases
using water, and with little difference between the two sets (1 in 36000), while P11 was
calibrated in 1976 and in 2008, also using water, with a one part in 3000 difference
between the sets. Neither of these plenums has been used to calibrate the CMM 4 cc
chamber.
4 CMM Thermometer Drift and Corrections
Seven mercury-in-glass thermometers are mounted inside the CMM cabinet. The
thermometers were made by W.H. Kessler Co., Inc. They are 1/50 ºC graduated (i.e. 0.02
ºC) and have a range of 17.90 ºC to 28.10 ºC. The total outside length is approx. 20 cm
with an O.D. of approx. 1 cm. Inside the outside tube is the actual mercury expansion
tube of approx. 3 mm O.D. with a glass graduated card mounted behind. The scale
sensitivity is approximately the optimum of 1 cm per ºC. The rather large mercury
reservoir is approximately 2 cm long and 1 cm O.D. The first mention in the CMM
laboratory notebook of the set of thermometers was on 30 May 1961. We have not been
able to find any information about the original calibration of the thermometers. P.
Guenther contacted the company in 2006 and found that that they have no information for
products that old.
The locations of the thermometers in the CMM cabinet have remained essentially the
same since 1969 (see Figure 2 in Manometer Report III [Guenther and Keeling, 1981].
Corrections determined in 1968 by E. Atlas for six of the thermometers relative to the
seventh range from +0.03 ºC to -0.03 ºC. Over the years of CMM operation since 1969,
the uncorrected temperature as read on thermometer #6112 (placed ~4cm from 4 cc
18
pointer of the small manometer) has been recorded as the temperature of manometric
measurements, both on the small and large manometers.
4.1 Thermometer Calibration
The seven CMM mercury thermometers were calibrated in May 2006 by comparing them
to a certified NIST-traceable standard thermistor (Hart Scientific "Super Thermistor").
The thermistor had also been calibrated versus traceable standards by R. Williams at the
Oceanographic Data Facility at SIO and found to be accurate to within 0.01 ºC. All seven
of the thermometers read about 0.1 ºC higher than the standard. The average correction
for #6112 was -0.11 ºC.
The relative differences between the thermometers in 2006 can be compared to those of
E. Atlas in 1968. After applying the 2006 calibration corrections, they range from +0.05
ºC to -0.01 ºC. The average difference (between the six differences) is +0.017 ºC (si =
0.010 ºC) (2006 - 1968) with no 2006 relative correction lower than its counterpart in
1968. We conclude that the Atlas relative corrections were quite good and imply that any
changes in the calibrations of the thermometers since 1968 are similar for all seven
thermometers. The results also may imply that the original differences in absolute
calibrations were greater than 0.01 ºC, up to 0.03 ºC.
4.2 Discussion
We have found in the literature mention of instability of zero in glass thermometers,
identified as a "slow drift known as the secular change" [Van Dijk et al., 1958]. Further,
"the secular change normally takes the form of a slow rise of zero during storage, the rise
being accelerated by exposure to high temperatures." Unlike the plenums discussed
above, the CMM thermometers have not been exposed to high temperatures since their
manufacture. We have not found any information that would allow estimation of the
magnitude of secular change to be expected for the thermometers, although the review
paper cited previously [Nemilov, 2003] does refer to a number of studies, mostly in
Germany and done as long ago as the 1880's.
19
Our own comparisons of the seven thermometers with each other might indicate that the
original accuracy of the thermometers was +/- 0.03 ºC as discussed above. Nevertheless,
we have chosen to assume that the thermometers when purchased in 1961 were
accurately calibrated (i.e. traceable to NBS) to 0.01 ºC. Additionally, we assume that the
thermometers had changed between their installations in the CMM in 1961 until their
calibration in 2006, due to slow secular change at room temperature. By May 2006 they
had drifted as measured, positively by 0.11 ºC. We also make a slight correction for the
change in temperature scales. We assume that the thermometers in 1961 were correct to
0.01 ºC in the International Practical Temperature Scale of 1948 (IPTS-48) and that the
2006 absolute calibration of the Hart Scientific thermistor is with reference to the
International Temperature Scale of 1990 (ITS-90). Thus the two absolute calibration
points for thermometer #6112 are -0.01 ºC on 31 May 1961 (corrected to the 1990 scale)
and -0.11 ºC on 12 May 2006. We calculate the appropriate correction for all CMM
measurement temperatures from a linear fit of the two points with time. This correction
is applied in the MATLAB code cdmntempcor.m presented in Appendix C.
5 Constants Currently used in Manometric Calculations
Since completion of the X99A scale, we have made some small adjustments to the values
of certain physical constants used in the workup. These changes have generally arisen
from adjustments between the late 1960s and the present to the values as accepted in the
scientific community. With the exception of thermometer calibrations discussed in the
previous section, even the largest change in these constant values has a fairly small effect
on final mole fraction determinations. Changes in mole fractions that result from
incorporating each of these adjustments is of order parts in 100,000.
5.1 True Constants
5.1.1 Molar Gas Constant, R
R= 8.314472 Pa m3 K-1 mol-1 (SI units)
R= 8.314472 J /mol K (8.314472*107 erg/mol K used in CMM calculations)
R= 6.236367*10-2 Torr m3/mol K (used in ECM calculations)
20
From on-line Handbook of Chemistry and Physics. Value used in previous reports was
8.31436*107 erg/mol K from early 1970's Handbook.
[Mohr and Taylor, 2005]
The change in R is about 1.3 parts in 100,000
5.1.2 Acceleration due to Gravity, g
g = 9.79537 m/s2 = 979.537 cm/s2
Measured in 2317 Ritter Hall (now 314 RH) by Jeff Ridgway of IGPP in May 1996.
Benchmark on bluff near old snack bar is 979.5397 Gal, which is in good agreement with
RH measurement, given -.000309 Gal/m of altitude. Value used in previous reports was
9.79558 m/s2 (interpolated from Handbook tabular values (for 32° 52' N and zero
altitude).
The standard acceleration due to gravity used for converting mercury column heights to
pressure units (nominally in terms of pressure generated by a mercury column of unit
length and assigned density 13595.1 kg/m3 at 0 °C at approx. 45° N latitude) is 980.665
Gal. (Note that this value is not a measured or modeled value.)
Reference for this last is the website for the National Physical Laboratory (UK)
(http://www.npl.co.uk/reference/measurement-units/)
The change in g is about 2.1 parts in 100,000.
5.1.3 Temperature Scales
We define 0 °C as 273.15 K.
For purposes of relating temperatures measured in the early 1960's to the present, one
needs to account for changes in definition of temperature scales. According to a table in
the on-line Handbook of Chemistry and Physics, the following relationship exists
between the International Practical Temperature Scale of 1948 (IPTS-48) and the
International Temperature Scale of 1990
21
(ITS-90):
at 0 °C t90-t48 = 0.000 °C
at 10 °C t90-t48 = -0.006 °C
at 20 °C t90-t48 = -0.012 °C
at 30 °C t90-t48 = -0.016 °C
The correction for temperatures near 20 °C is t90 = t48 -0.012, or to correct from
temperatures presumed to be in the IPTS-48 scale, subtract 0.01 °C to find the ITS-90
value.
5.1.4 Pressure Conversion Constants
The SI unit of pressure, the pascal (Pa), is defined as one Newton per square meter.
The bar is 105 Pa exactly.
The atmosphere (atm) is 101,325 Pa exactly.
The torr is 1/760 atm exactly.
Therefore: torr = 101325/760 Pa = 133.3224… Pa
Also:
pascal = 760/101325 torr = 7.500616*10-3 torr = 7.500616*10-4 dynes/cm2
mmHg definition: .001 m *13595.1 kg/m3*9.80665 m/s2 = 133.322387415 Pa (exactly)
torr definition:
101325 Pa/atm /760 torr/atm = 133.322368421…Pa (an infinitely long,
periodically repeating decimal).
Thus the mmHg and torr differ by less than 2 parts in 10 million.
22
5.1.5 (Weight) Buoyancy Correction for Calibration of Volume of Apparatus
The general equation for the air buoyancy correction applied to the apparent weight in
air of a sample contained in a chamber in order to calculate the true mass can be
expressed as follows:
m = w(1-Áa/Áw)/(1- Áa/Ás),
where Áis the density of air (a), the weights (w) and the sample (s) being weighed.
If the chamber being calibrated for volume is evacuated before making the "empty"
weighing, the Áa for the sample buoyancy correction in the denominator is zero; thus the
denominator is equal to 1 and there is no correction for the buoyancy of the sample. The
buoyancy for the weights is applied in the numerator. The density of air at sea level is
taken to be 0.0012 g/cc and the density of stainless steel weights to be 8.00 g/cc. Thus the
factor in the numerator becomes:
1-.0012/8 = 1-.00015 = 0.99985
and
ms = ws(.99985)
Reference: [DOE, 1994]
5.2 Temperature Dependent Quantities
5.2.1 Density of Mercury, ρ (Hg)
Á(t) = Á(t0) / (1+ a0t + a1t2 + a2t3 + a3t4)
where t is in ºC. and
Á(t0) = 13595.0828 kg m-3
(density of Hg at 0 ºC)
a0 = 1.815868*10-4
a1= 5.4583*10-9
23
a2= 3.4980*10-11
a3= 1.5558*10-14
[Bettin and Fehlauer, 2004]
This equation reproduces the table in the Handbook of Chemistry and Physics to .0001
g/cm3. In previous reports, fits were made to the tabular values in the Handbook (given
in the obsolete g/ml that is not equal to g/cm3) to find interpolated values and then
converted to g/cm3.
5.2.2 Density of Water, ρ (H2O)
The density of standard mean ocean water (SMOW), free from dissolved salts and gases,
and at a pressure of 101325 Pa and at temperature t (ºC), expressed in terms of the ITS-90
temperature scale is given as:
Á= a5 [1-((t+a1) 2(t+a2))/(a3 (t+a4))]
where
a1 = -3.983035 ºC
a2 = 301.797 ºC
a3 = 522528.9 ºC2
a4 = 69.34881 ºC
a5 = 999.974950 kg m-3
[Tanaka et al., 2001].
The equation matches the detailed tabular values (to 0.1 ºC) given in the on-line version
of the Handbook of Chemistry and Physics to a part in several million. In previous
reports, fits were made to tabular values (given to 1 ºC) in the Handbook to find
interpolated values.
24
The term SMOW refers to a certain isotopic abundance. For tap water the often assumed
value of 999.972 kg m-3 for a5 should be used, accounting for a difference of
approximately three parts per million. We have elected to use the SMOW version of the
density equation as written above.
5.2.3 Second Virial Coefficient: CO2
B (cm3/mol) = 57.400-3.88290*104/T+4.2899*105/T2-1.4661*109/T3
Where T = temperature in Kelvin
[Dymond et al., 2002, page 28]
The temperature dependency equations given in this reference are preceded by the
following statement:
"Recommended values given by the following equation whose coefficients were obtained
by a weighted least square fit of the selected experimental values."
5.2.4 Second Virial Coefficient: N2
B (cm3/mol) = 40.286 - 9.33780*103/T-1.4164*106/T2+6.1253*107/T3-2.7198*109/T4
[Dymond et al., 2002, page 69]
5.2.5 Second Virial Coefficient: O2
B (cm3/mol) = 42.859-1.7696*104/T+5.2007*105/T2-1.6393*108/T3+5.0855*109/T4
[Dymond et al., 2002, page 75]
5.2.6 Second Virial Coefficient: Air (CO2-free)
B (cm3/mol) = -144.45932+.719291*T-8.7808*10-4*T2
Where T = temperature in Kelvin
The quadratic formula for the virial coefficient for air (CO2-free) was calculated using the
old "Sengers et al." data for dry CO2-free air to formulate a temperature-dependency
25
equation. A quadratic fit was made to the listed B values for the following temperatures
in Kelvin:
273.15 (B = -13.5), 280 (-11.9), and 300 (-7.7).
[Sengers et al., 1971]
We used the Sengers data because Dymond et al. do not give virial coefficients for CO2free air. The second virial coefficient for air could alternately have been calculated from
the above equations for N2, O2, and additionally the equation for Ar, plus the cross
virials.
5.3 CO2 Isotopic Constants.
For the first time in this report, small corrections to Scripps manometric scale resulting
from differences in the isotopic composition of manometric reference gases relative to
ambient air are considered, as discussed further below. To estimate corrections for
isotopic differences we utilize the following constants from Lee et al. [2006] (see also
references therein):
Absolute mole ratio of 13C/12C in NBS19:
13
RNBS19 = 0.0112015
Absolute mole ratio 18O/16O of VSMOW: 18RVSMOW = 0.0020052
´ 13C of NBS19 standard as reported on PDB scale: ´ 13C(NBS19)PDB= 1.95‰
Constants used in formula to estimate the 17O/16O ratio from the 18O/16O ratio:
17
R = 18Ra·K
a = 0.516
K = 0.0099235
Here 17R and 18R are the 17O/16O and 18O/16O mole ratios, respectively.
26
For relation between oxygen isotope references, we use determinations from [Coplen et
al., 1983]:
18
RPDB/18RVSMOW = 1.03091
18
RPDB-CO2/18RPDB = 1.01025
6 Determinations of the Small Chamber Volume
The individual calibration volumes of the small, nominally 4 cc, chamber have been
revised using temperature and other constant adjustments as described in Section 4 and
Section 5 respectively. Plenum volumes (Figure 3), were modeled as varying linearly
over time, and the linear fit parameters for each plenum are listed in Table 3.
The small chamber volume is calibrated by transferring into it a known amount of CO2
and measuring the resultant pressure along with the temperature. The known amount of
CO2 is established by filling plenums, with known volumes VP, as described above, with
pure CO2 to a known pressure PP and measured temperature TP. The number of moles of
CO2 in the plenum nC, is calculated from the equation of state including virial coefficients
for carbon dioxide, BC:
The number of moles of CO2 is then given by:
Filling of the plenums from 1974 through 1999 has been described in detail in previous
reports [Keeling et al, 2002, p.16-19]. The original data and resulting calculations of
moles of CO2 in the plenum fills from 1974 to 1999 are reported here in Tables A2 and
A3.
27
Beginning in 2005, after the renovation of the manometer room, the procedure for filling
of the plenums changed. Previously the plenums were filled to ambient atmospheric
pressure with the ambient pressure measured on a wall barometer (Fortin Barometer) and
reported in Table A2. Subsequently, the fills were done to a controlled pressure, as
measured using a dead-weight gauge made by Ruska Instrument Corporation (gas
lubricated piston pressure gage, model 2465-754). This method allowed using plenums
of a larger volume because the fill pressure could be less than one atmosphere. Another
change initiated at that time was the immediate transfer of CO2 gas from the plenums to
flame-off tubes for storage until use. This change in procedure allowed more convenient
and frequent calibrations of the small manometer volume. Transfer of the gas into the 4
cc chamber from either a plenum or a flame-off tube has been done essentially the same
way throughout the history of calibrations, again as described in prior reports. Data and
resulting CO2 moles for all plenum fills from 1999 to 2008 using the dead-weight gauge
are reported here in Table A3. Only a subset of these fills were used for CMM
determinations. We report a description of dead-weight gauge calculations along with
Table A3.
Table A4 shows data supporting revised estimates of the CMM 4 cc chamber volumes
from all of the calibrations made from 1974 to 2009, including new estimates of plenum
fill amounts allowing for drift in plenum volume. The individual determinations of the
4cc volume are presented in Figure 4 as open circles. This figure also shows, as blue
filled triangles, the average of individual measured volumes for manometer calibration
periods in 1974, 1985, 1988, 1990, 1993 and 1998 as listed in Table 6.3 of the previous
manometer report for the X99A scale [Keeling et al., 2002], and as black filled squares,
new averages for these same time periods based upon the above corrections. The vertical
black solid error bars on these new average volumes indicate the standard deviation of
each average.
6.1 Characterization of 4 cc Chamber Drift
Comparing different periods in Figure 4, the mean chamber volume determined here
from plenum calibrations conducted in 1974 is 3.7970 cc, which agrees quite well with
the value of 3.7974 cc reported previously [Keeling et al., 2002]. This is expected since
28
both the plenum drift and temperature correction that impact the small chamber volume is
at a minimum at this time. This new 1974 value has been assumed to represent the 4cc
chamber’s volume up to the period of anomalous behavior in 1983 described in Section
1.
The mean chamber volume determined here for the period between 1985 and 1990 is
3.7993 cc. As seen from Figure 4, this value lies slightly below the determinations within
this period presented in the 2002 report [Keeling et al., 2002].
As seen in Figure 4, the measurements of the small chamber volume in 1994 and 1999
generally fall below those made before 1991 and after 2005. Since the standard
deviations of the calibrations in 1994 and 1999 are about twice those of the 1985 through
1990 data, these data do not appear to have as high integrity. We have therefore excluded
these data from calculation of chamber volume.
In November 1984, the manometer was disassembled, cleaned and annealed [Keeling et
al., 1986]. At the same time the mercury, which had accumulated a considerable amount
of visible oxidation products, was replaced. The black vertical dash/dot line in Error!
Reference source not found.Figure 4 indicates the time at which the manometer was
cleaned.
In April 1999, the mercury in both manometers was removed prior to "boxing" the
manometer cabinet for the duration of the old Ritter Hall renovation. The mercury
surface did not display a visible "scum" as it had in 1984. The mercury was gold-filtered
just prior to refilling the manometer in September – October 2004. The first runs made in
early 2005 after this cleaning indicated some instrument drift and those runs have also
been excluded from the volume analysis.
Because there is little evidence for any systematic trend, we have assumed that the
chamber volume was constant for the entire period 1985 through 2010, with a mean
volume of 3.7934 cc. This value is the mean of all unflagged data between 1985 and
2010 with the exception of the three sets of measurements in 1994, 1999 and early 2005.
If we include all the 1994 and 1999 readings in this average, then the chamber volume
29
would be reduced to 3.7929 cc. If we exclude all data since 1985 then the volume
reduces to 3.7928 cc. Using these volume averages in place of the specified 3.7934 cc
value would tend to decrease CO2 mole fractions for a 400 ppm gas by about -0.05 and 0.06 ppm respectively. These findings are summarized in Table 4.
One series of primary tank analyses was conducted in 1983, during which the physical
condition of the manometer is in question. For this calibration period, mole fractions
calculated using a 4 cc chamber volume from either 1974 (3.7970 cc) or since 1985
(3.7935 cc) yield reference gas concentrations that are well outside the range expected for
each tank when considering the prior and subsequent calibrations. We have no reason to
expect that the primary tanks CO2 concentration actually shifted anomalously in this
period. We have found (by trial and error) that assigning the 4 cc chamber volume to be
3.8000 cc in 1983 yields tank mole fractions that are consistent with measurements made
in the previous and following calibration periods of 1980 and 1985 . We thus assign a
value of 3.8000 cc for this anomalous period. (Plots of the primary reference gas
concentrations that were used to constrain this chamber volume are presented in Figure
12 and Figure 13).
6.2 Previous Analysis of Small Chamber Volume
The assumed 4 cc chamber volume, indicated by the black line in Figure 4, is thus now
primarily constrained by direct observations from plenum calibrations, with only the
portion representing manometer use in 1983 (when there were documented problems
with the instrument) being constrained by prescribing primary reference gas
concentrations. This is in marked contrast to the way in which the chamber volume was
determined for the X99A scale [Keeling et al., 2002], when the volume was allowed to
vary so as to minimize the changes in primary reference gas concentrations. The dashed
line in Figure 4 illustrates the previously assumed time variation of the small chamber’s
volume.
There are three reasons for preferring this revised approach, using direct observations of
the plenum volumes, over the previous approach assuming stable reference gas
concentrations: First, more recent plenum calibrations performed between 2005 and
30
2010 suggest that the decrease in chamber volume previously assumed to have occurred
since 1990 (dashed line in Figure 4) is probably not real. Second, the approach gives
greater weight to the absolute mole-fraction CO2 determinations by manometry. Third,
experience with long term storage of carbon dioxide reference gases in steel cylinders
obtained from the R.F. Keeling lab suggests that these gases do indeed tend to drift
upward slowly in carbon dioxide concentration when compared with gases stored in
aluminum cylinders. Given the direct relationship between chamber volume and mole
fraction, we expect this change to impact derived primary tank concentrations as well as
the APC infrared analyzer scale conversions, Section 1.
7 Determinations of the Large Chamber
The volume of the large manometer chamber of the CMM is determined with reference to
a "plenum" (numbered P13) having a volume calibrated by weighing contained water.
The plenum in this case is a nominally 4-liter flask integral to the CMM, i.e. it is mounted
within the CMM cabinet and connected to the rest of the CMM. It had been removed
from the cabinet and calibrated for volume in 1974 by A. Adams [1976] by weighing it
filled with water. In 2004 P13 was again calibrated for volume, this time with greater
precision on a modern balance by G. Emanuele. After applying the weight buoyancy
correction to Adams' calibration data, the new calibration was one part in 6600 lower
than the earlier calibration. The revised data is included in Table 3 ("Plenum P13"). The
apparent drift is displayed in Figure 5. Compared to the small plenums, the change is
relatively small as a fraction of the volume, less than 1 part in 4000.
Calibration of the volume of the large manometer chamber is analogous to calibrations of
the small chamber, except there is only one plenum and it is part of the CMM so all
relative calibration measurements are made with the CMM. Temperature measurements
are made with the CMM thermometers, but the effect of the thermometer calibration (see
Section 2) "cancels out" in the process. The 4-liter flask is filled with pure CO2 gas at a
measured pressure and temperature, and then the gas is transferred into the 5000 cc
chamber, where its pressure and temperature are again measured. In addition to such
calibrations in 1974 (three) and in 1980 (two), three more calibrations were made in
31
2006. Table A5 reports the 4-liter "fill" data and Table A6 the measurements in the 5000
cc chamber determining its volume relative to the 4-liter volume. Figure 6 displays all of
the large chamber volume calibrations. We approximate the apparent drift as a linear
function of time as shown in Figure 6. The change in volume, including the effects of
virials, resulting from this reassessment of the large chamber corresponds to about one
part in 5000, equivalent to about 0.08 ppm CO2 in a reference gas.
8 Calibrations of Cathetometer
The instrument used to measure mercury heights in the CMM is a custom high-precision
cathetometer made by the Fred Henson & Co. of Pasadena, CA in 1956. We have carried
out calibrations of this instrument several times over the years.
The first calibration occurred in January 2003 during the period of renovation of the
laboratory (1999-2004). "Teeth" on a machinist's "Cadillac" gauge were measured with
the cathetometer. The teeth were one inch apart (+/- .0001"). Figure 7 is a plot of the
results of these measurements, along with the original factory-supplied calibration. An
increasing positive error, the cathetometer reading high relative to the gauge, was
observed as the measured height increased from 138 mm to 875 mm. The factory
calibration was made in 1958 against Johansson "A" gauge blocks. The two calibrations
are in reasonably close agreement. The corrections amount to less than a part in 104 in
pressure with smaller relative impact on CO2 mole fractions because of compensation
from pressure readings on the small and large chambers.
The second calibration exercise was made in April 2006, comparing pressures produced
by a gas piston gauge made by Ruska Corporation with those measured in the CMM
using the cathetometer. The 2006 calibration measurements (shown in Figure 9) were
made on the large manometer only. The results were not very precise because the piston
gauge could not be held steady for the relatively long time required to measure the
mercury heights with the cathetometer.
The final and most intensive calibrations were made between February and September
2009, again comparing pressures on the gas piston gauge and the CMM. This time the
32
gas piston gauge had been modified with automatic pressure control to allow the
maintenance of precise pressure (Ruska autofloat system, model 2465A-754). Both the
large and small manometers were calibrated with eight pressures on each of three
separate days. The results are displayed as errors in pressure (in mm of mercury height)
as a function of the height of the vacuum columns in both manometers. See Figures 8
and 9 for the small and large manometers, respectively. The large manometer plot also
displays the 2006 calibration data, in reasonable agreement with the more precise
measurements in 2009.
There is a striking difference between the machinist's gauge calibrations and the gas
piston gauge calibrations: the latter indicate the cathetometer measured low relative to the
supplied gauge pressures while the former indicate that the cathetometer measured high.
The scatter in the gas piston gauge calibration data is very small and the shape of the
height dependence is generally similar for the two manometers, although the absolute
offsets differ, despite the fact that the offsets would be the same if caused only by the
cathetometer error. The offset is larger for the small-chamber manometer than for the
large-chamber manometer.
A discrepancy between the cathetometer-determined pressures and the dead-weight
determined pressures could occur if the actual density of the mercury density was
different than computed by the Tanaka et al. (2001) formula. For the small-volume
manometer, a density error of roughly 1 part in 104 would be required, or equivalently an
error in temperature of order of ~0.4C, allowing for mercury thermal expansion of ~18
parts in 104 per degree Celsius) which is too large to be a plausible cause of the
discrepancies. We do not understand the reason for the differing offsets, but the
implications for the manometric determinations of CO2 mole fractions is in any case
small.
We have investigated the effect of correcting the CMM measurements to the gas piston
gauge for the reference gas measurements. The quadratic relationship of the corrections
for each manometer was applied to all mercury height measurements, including the
manometer chamber volume calibrations and reference gas analyses. Figure 10 plots the
33
resulting corrections as a function of the mole fraction of CO2 in the reference gases. In
the calibration range of 200 to 500 ppm the indicated correction is between 0.02 and 0.05
ppm.
Since we do not understand the reasons for the differing corrections from the machinist's
gauge and from the gas piston gauge, we have elected not to apply the small corrections
to any of the data reported here. All data are reported adopting the cathetometer readings
without further correction.
9 Isotope Corrections
The CO2 mole fractions determined by manometry include contributions from all the
isotopologues of CO2. The APC analyzer, on the other hand, presumably effectively
responds only to the dominant isotopologue of CO2, i.e. 12C16O16O because it uses a gasfilled detector for wavelength selectivity, with 12C16O16O being the dominant
isotopologue of the fill gas. This high isotopic selectivity of the APC is supported by the
study of Lee et al. (2006) who investigated the isotopic sensitivity of a Siemens Ultramat
CO2 analyzer, which similarly uses a gas-filled detector. If the isotopic composition of
the reference gases differs substantially from natural atmospheric CO2, the difference in
isotopic sensitivity of the manometry and the APC could lead to errors in the propagation
of the manometric calibration to air measurements.
Following Lee et al, we assess the magnitude of the error based on the ratio 44F, i.e. the
ratio of the (molar) abundance of 12C16O16O compared to the abundance of all
isotopologues. Here 12C16O16O is labeled according to its molecular weight, 44 =
12+16+16. If X is the (total) CO2 mole fraction, then 44F·X is the mole fraction of
12 16
C O16O. Natural background air has a near-constant value of 44F = 0.984106 with only
very small variations with space and time. (We estimate that the annual mean value 44F
at Mauna Loa increased from 0.984101 in 1981 to 0.984109 in 2011). The benchmark
value of 44F = 0.984106 was computed assuming a nominal atmospheric CO2 isotopic
composition of ´ 13C = − 8.00 0 and ´ 18O = 0 ‰ (PDB-CO2 scale) (see Table 5).
34
For each manometrically determined mole fraction, X, we compute the isotopicallyequivalent mole fraction X’ = (44F/0.984106)X. Here X’ is the mole fraction the sample
would have if its 12C16O16O mole fraction (and hence its APC response) were unchanged,
but the relative abundance of the rare isotopologues were adjusted to be in natural
proportions.
Calibrating the APC using X’ rather than X values corrects for differences in the isotopic
composition of the reference gases and yields values for secondary reference gases and
air samples analyzed on the APC analyzer on a consistent isotopically-equivalent basis.
For air samples, this isotopically-equivalent basis is an appropriate basis for reporting
true atmospheric mole fractions subject only to very minor errors from neglecting
variations in 44F in background air. For secondary reference gases analyzed at Scripps
for other CO2 programs, further isotopic corrections may be needed depending on the
isotopic response of the analyzers used by those programs. The analyses at Scripps can
be viewed as providing an absolute determination of the 12C16O16O mole fraction divided
by 0.984106.
To compute isotopic corrections, we rely on isotopic analyses carried out on the Scripps
manometric reference gases using standard procedures (Bollenbacher et al., 2000). A
summary of these measurements and the corresponding isotopic corrections is shown in
Table 5. The calculations follow methods described in Lee et al. [2006]. The
differences X’− X are uniformly less than 0.06 ppm, i.e. almost negligible in the context
of other errors. However, because they are systematic rather than random we have
proceeded to apply corrections for these small isotopic effects.
10 CMM Accuracy and Imprecision
The accuracy of the CMM is mainly limited by the determination of the 4cc chamber
volume which is tied to the plenum determinations. The most important known source of
uncertainty is related to the imprecise positioning of the mercury column at the pointer
that marks the end of the chamber. Precise positioning is required to ensure that the
chamber volume is consistently defined during chamber volume measurements and that
35
identical CO2 volumes are trapped in the chamber for each mole fraction measurement as
well as for the chamber volume measurement experiments.
It is estimated that the repeatability of the pointer positioning is approximately
±0.015 mm, which, for a chamber diameter at the pointer of 0.95 cm corresponds to a
volume uncertainty of ±0.0011 cm3 or roughly one part in 1 part in 4000. This is similar
to the scatter of the retained points in Figure 4. However, since the small chamber
volume that is used in mole fraction calculation is determined from an average of many
individual volume readings, the uncertainty in the average, used for the calculations, may
be smaller. On the other hand, the volume itself may be different in different periods,
such that the precision of the long-term average may not be appropriate for assessing
systematic error in any given period. Judging from the shifts that occurred when the
mercury was cleaned in 1984 and the more scattered and lower readings in 1994 and
1999 (Figure 4), it seems possible that there are systematic errors in some periods as large
as part in 1500.
The impact of uncertainty in the large 5 liter chamber volume is clearly much smaller
than that of the 4cc volume. Weighing inaccuracies in determination of the plenum (P13)
used to determine the large volume are less than a part in 10000, as is the reproducibility
of multiple determinations (Figure 5). The reproducibility of the determinations of the
large volume using this plenum is also roughly a part in 10000 (Figure 6).
The impact of uncertainty in the pressure measurement (via column heights) and
temperature measurements are also relatively small. Both of these are accurate to
roughly a part in 10000 or better. The relative error in the manometric determinations
from presure and temperature inaccuracy is even smaller, because the systematic errors in
the small volume determination and systematic errors in normal manometer
determinations partly cancel.
Our best indicator of the precision of manometric determinations is based on repeated
analysis of a particular test cylinder from Sept. 2005 to Feb. 2010. The gas was CO2-inair, contained in aluminum cylinder No. 1661, with a history of stability according to
APC measurements. During the four years and four months duration of the experiment, a
36
total of 32 measurements of the gas were made. The procedures followed for the CMM
analyses were identical to those used to analyze the primary reference gases [Manometer
Report III, Guenther and Keeling, 1981].
Figure 11 is a plot of the data versus time. Using the averaged small volume
determination yields one point per analysis date. A linear fit indicates a downward drift
of about 0.08 ppm over the period relative to the long-term mean, although it is not
clearly significant given the scatter. The standard deviation of the individual points
relative to their long-term mean (not the line) is ± 0.096 ppm or about one in 4000, which
is quite similar to our uncertainty estimate listed in Section 9. [The CO2 extract for the
measurement was always measured at least twice and occasionally more often in the
small manometer and the total gas once in the large manometer.] Looking only at
replicate measurements of the CO2 fraction on the same day yields a standard deviation
of ± 0.049 ppm, or one part in 7700. This was calculated using the standard formula for
the pooled standard deviation [Keeling et al, Appendix A2, 2002].
11 Primary Reference Gas Determination
Using the assumed variations of the large and small chambers volumes, indicated by the
solid black lines shown in Figure 4 and Figure 6, we have recalculated carbon dioxide
concentrations for all gases analyzed on the CMM. The method used to determine gas
pressure and carbon dioxide mole fraction is identical to that used previously [Keeling et
al., 2002]. A list of all derived reference gas concentrations is included with the
manometer data listed in Table A7.
These mole fractions for nitrogen and air primary reference gases are also illustrated in
Figure 12 and Figure 13 respectively. These figures show the deviation in each gas’s
measured concentration from its time-averaged value, with the time-averaged
concentration shown in the figure legend adjacent to the ID number. Filled symbols
represent the individual determinations and open symbols show flagged data.
37
These figures also show straight linear fits through the data that are used to interpolate
the reference gas concentrations in time and to obtain reference gas mole fractions during
APC calibrations, see Section 12 below.
The black dashed vertical lines in these figures indicates the date on which the
manometer was cleaned, immediately prior to which the “anomalous” small chamber
volume was assumed to occur as described in Section 6.1. The small chamber volume in
1983 was fixed at 3.8000 cc, as discussed above, so that the individual gases drifted in a
manner consistent with calibrations performed in 1980 and 1985.
With a few exceptions, the behavior of the primary reference gases over time shows
certain characteristics that are consistent from gas-to-gas. Generally speaking, after an
initial settling-in period, the carbon dioxide concentration within each reference gas tends
to drift upward slightly over time. Gases close to ambient concentration generally drift
upward by about 0.2 ppm per decade, but with considerable tank-to-tank differences, and
not all trends being significant. This is in contrast to previous analysis in which, on
average, primaries were fixed to be stable to within a few hundredths over a decade (see
Figure 5 of Keeling et al. [2002]).
12 Infrared Analyzer Calibrations
On a day-to-day basis, carbon dioxide concentrations of reference gases and flask
samples are measured at Scripps on the APC non-dispersive infrared analyzer. The
response of this analyzer is related in a non-linear way to the carbon dioxide mole
fraction of the sample, and this non-linear relationship has been characterized by a cubic
function.
12.1 APC Linear I and J Scales
In order to precisely characterize the non-linear response, the nitrogen and air primary
cylinders have been run on the APC during certain APC marathon calibration periods that
are spaced several years apart. During these APC calibration periods, two standard
reference gases are analyzed to determine the instrument’s response on a linear I
concentration scale. This determines the instrument’s sensitivity or recorder scale factor,
38
RSF. Each of the air and/or nitrogen primary reference gases is then run on the APC
alternating with a transfer gas or working tank cylinder to correct for short-term
“baseline” instrument drift.
Primary reference gas values are initially reported on the linear APC I scale, which is
then adjusted to a second linear J scale that is closer to true ppm. The linear I and J scales
are related by the following equation:
For each APC calibration period, the non-linear relationship of the APC has been
characterized by performing a cubic fit of the manometrically determined mole fractions
X expressed as a function of the APC J values for each reference gas.
This allows determination of sets of cubic coefficients a0, a1, a2 and a3 for nitrogen and
air primaries for each APC calibration period via an over-constrained least squares fitting
technique. With these fit coefficients identified for each APC calibration period, we have
calculated APC approximations of the reference gas’s carbon dioxide mole fraction XA
for each measured J value as well as the residual r between the manometric and APC X
values:
For APC calibration periods between 1985 and 1999, the J values used in these fits have
been taken directly from the “Average J” column, Table 9.3 of Keeling et al., 2002. For
APC calibration periods since 1999 we have used the same methodology as described in
that report to obtain average J values for each of the APC calibration periods in 2001,
2003, 2005, 2008 and 2012. Average J values used for all APC calibration periods for
nitrogen and air are listed in Table 6 and Table 7 respectively.
The time-varying manometric primary reference gas concentrations X used in these fits
have been extracted from the linear fits through the observed manometric concentrations
39
shown in Figure 12 and Figure 13. Since the last manometric determinations were made
in 2005, we have (for now) kept the X values fixed at the 2005 values for scale
calculations in 2008 and 2012. This will likely be revisited as further information on tank
drift is obtained in recent years, but has no bearing on the comparison with NOAA tanks
which were all made before year 2006.
In Appendix B (Figure B1-B24) we include `figures of all APC fit data. On the left axis
these plots show X concentrations. On the right axis these plots show the fit residual r as
a function of the APC J value for each of the calibration periods 1985, 1987, 1989, 1990,
1993, 1995, 1997, 1999, 2001, 2003, 2005, 2008 and 2012.
The APC residual r is also presented as a function of time for each primary reference gas
in Figure 14 and Figure 15. Since we expect that all the gases should behave in a
consistent manner over time when analyzed on either the manometer or APC, a large
residual for any reference gas and time would indicate a problem with either the APC or
manometric analysis.
12.2 Implementation of the New X12 Calibration Scale
Historically, the J-X cubic corrections, used to assign mole fractions from measured J
values, are incorporated into the APC workup procedures via a series of FORTRAN
functions collectively known as “cal services”. Included in this group are 2 functions
aircubicsXXX.f and n2cubicsXXX.f, where XXX is an abbreviation of the scale name, that
perform cubic adjustment between J and X scales. For example, aircubics08A.f is the
FORTRAN code defining the J-X cubic conversion parameters used for the X08A
calibration scale.
For each APC measurement these functions calculate cubic corrections using polynomial
coefficients from APC calibration dates immediately before and after the date of the
measurement. The X value is then determined as a linear interpolation in time between
these two bracketing points.
For data recorded since 1985, conversion from J to X scale has always been carried out
directly within aircubicsXXX.f and n2cubicsXXX.f, without any additional or preceding
40
conversion factors being required. For these data it has been possible to modify the two
FORTRAN cubic functions, incorporating the new coefficients for each APC calibration
date as listed on Appendix B (Figures B1- B24). These cubic coefficients are now
included in the FORTRAN codes aircubics12.f and n2cubics12.f.
However, for data recorded before 1985 a number of correction factors had been
previously applied to the J values prior to applying the J-X cubic adjustment. These J
value adjustments combined corrections to both the manometric and APC determinations
of primary reference gases. They were implemented sequentially in FORTRAN codes
named corr1.f, corr2.f, corr3.f, corr4.f and corr5.f.
In principle, the plenum drift can impact data back to 1974 (the first year that plenum
calibrations were implemented), while drift in the thermometers and changes in other
constants can impact data back to the beginning of the records. The effect of these
changes before 1983 is very small, however. In 1983, the average difference between the
newer scale and the previous scale would be only 0.02 ppm and would be even smaller
before that. To recalculate the full set of corrections before 1985 is complicated,
however, by the need to revisit the basis of correction factors (corr1.f etc.). Because the
net effect would ultimately involve changes of order 0.02 ppm or smaller, we have
instead adopted a post-hoc linear interpolation method to revise the data before 1985.
These are implemented as two steps:
1) For data between 1968 and 1983, the APC X values are increased linearly over
time with a 0 ppm correction in 1968 and a 0.02 ppm correction in 1983.
2) For data between 1983 and 1985, APC X values are calculated by linearly
interpolating in time between the corrected 1983 and 1985 values described
above.
These adjustments are incorporated into a new correction routine corr6.f.
Comparison of the X12 and X08A APC scales for nitrogen and air are presented in
Figure 16 and Figure 17. Differences between the scales through 2008 can be explained
by the differing manner in which the small chamber volume has been modeled in this and
in the X08A scale analyses. For the X08A scale, the small chamber volume was assumed
to decrease from 1985 to 1997 and was held constant thereafter. The small chamber
41
volume derived in this analysis is smaller than that used for X08A up to 1996 and has
exceeded it since that time. The relative change in small chamber volume match closely
the scale differences through 2008.
In 2012 an additional marathon APC calibration day was conducted that revealed a
change in the primaries responses on that instrument. In general such a change can be
tied solely to the functioning of the APC and its span gas behavior, and may not be a
consequence of primary gas changes. These new APC values mean that cubics calculated
in 2012 are based upon both changed manometric X and APC I values, so that the total
scale change is relatively large. This is a normal characteristic of calibration scale
changes on the APC.
13 Comparisons with the NOAA Calibration Scale
To help evaluate the transition of the CCL function from SIO to NOAA in 1995, two
suites of CO2 in air calibration gases were exchanged between NOAA and SIO. The
original suite consisted of 15 tanks, analyzed at SIO on the APC analyzer between 1992
and 1999. Eight of this set of 15 were also analyzed manometrically at SIO in 1999.
These tanks became the primary CO2 standards for NOAA and were subjected to
repeated manometric determinations at NOAA, starting in 1996 and continuing to the
present (Zhao and Tans, 2006). The second suite consisted of nine tanks that were
analyzed both manometrically and the infrared analysis systems at SIO in 2005 and
subject to repeated infrared and manometric analyses at NOAA, mostly between 2004
and 2010. The summary of the NOAA readings were communicated by Pieter Tans of
NOAA (in Emails sent to R. Keeling in March 2016).
Results from the original suite of 15 tanks are presented in Table 8 and Figure 18. These
comparisons are based on 10 separate manometric runs at NOAA from 1996 through
2015. Each run comprised 3 to 4 separate manometric measurements per tank. Only one
of these tanks (103) showed evidence of significant drift, based on the NOAA
manometric determinations. For all other tanks, we compare the determinations at SIO to
the averages of the NOAA manometric determinations. For tank 103, we compare to a
linear model of the drift provided to us by NOAA (see table caption). The manometric
42
results from this suite were presented previously in Guenther and Keeling (2000), where
it was noted that the manometric determinations for tank103 had about twice the normal
dispersion, which justified neglecting the manometric determinations of this tank.
Disregarding Gas 103, Guenther and Keeling reported an average offset between SIO
results and the CMDL results of −0.17 ppm, i.e. SIO values were lower than NOAA by
0.17 ppm. With the revised analysis supporting the X12 scale, as well as updated values
from NOAA, we now find an average SIO-NOAA offset of −0.09 ppm for these
determinations, with a standard deviation (of individual cylinder offsets) of ±0.12 ppm.
The APC analyses on the original suite of 15 tanks were described in Guenther et al.
(2002b). All 15 tanks were analyzed 5 times, in 1992, 1993, 1996, 1997, and 1999.
Focusing on the six cylinders with concentrations between 350 and 400 ppm, and using
revised values from NOAA and SIO, we find averages offsets of −0.20, 0.01, −0.05,
+0.03, −0.17 ppm in these five years, respectively. The overall average of these five
averages is −0.08 ppm with a standard deviation (of each yearly average) of ±0.10 ppm.
Results from the second suite of nine tanks are presented in Table 9 and Figure 19.
Repeated analyses at NOAA show that all of these tanks except one (17491) appear
stable over time. For the other tanks, we based the comparison on the average of the
NOAA readings. For tank 17491, we use an estimate of linear drift to interpolate to year
2005. This suite includes two cylinders with concentrations above 450 ppm, higher than
any manometric analyses done with the 1992 suite. These higher cylinders show larger
systematic offsets between SIO and NOAA compared to the tanks closer to the ambient
concentration range. Including only the seven cylinders with concentrations below 450
ppm, and based on the manometric workup supporting the X12 scale, we find an average
SIO-NOAA offset of −0.01 ppm, with a standard deviation (of individual cylinder
offsets) of ± 0.06 ppm. A similar comparison of these seven tanks using instead the APC
values from SIO yields an average SIO-NOAA offset of −0.05 ppm, with a standard
deviation ±0.06 ppm. If the APC-based comparison is further restricted to including only
the four cylinders in the 350 to 450 ppm range, we find an average offset of −0.03 ppm
and a standard deviation of ±0.05 ppm.
43
Acknowledgements
This project was supported in part by NSF under award 1036399. Any opinions,
findings, and conclusions or recommendations expressed in this material are those of the
authors and do not necessarily reflect the views of the National Science Foundation.
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System for Carbon Dioxide-in-Air Standards: Revision of 1985. Environmental Pollution
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46
15 Tables
47
Table 1: Meniscus corrections measured on the small manometer. Meniscus correction MnCor (in
mm) measured on given Date is an additive correction to the column height.
Date
1969-11-27
1969-12-08
1969-12-12
1970-03-09
1970-03-13
1970-04-22
1970-04-23
1970-04-23
1970-04-27
1970-04-27
1970-04-29
1970-04-30
1970-05-06
1970-05-18
1972-09-08
1972-11-21
1972-11-21
1974-01-02
1974-02-22
1974-05-31
1974-05-31
1974-06-28
1974-10-17
1975-05-08
1975-09-08
1975-11-07
1976-04-06
MnCor
-0.430
-0.411
-0.363
-0.359
-0.409
-0.409
-0.276
-0.346
-0.272
-0.321
-0.322
-0.355
-0.410
-0.477
-0.432
-0.369
-0.353
-0.341
-0.344
-0.296
-0.351
-0.381
-0.391
-0.318
-0.352
-0.392
-0.376
Date
1976-09-09
1976-09-27
1977-08-30
1977-12-28
1978-10-10
1978-11-27
1979-04-07
1979-07-23
1980-01-22
1980-04-24
1980-09-04
1981-01-30
1981-05-18
1981-08-04
1981-08-12
1981-09-11
1981-09-14
1981-12-28
1982-03-08
1982-04-19
1982-07-26
1982-11-02
1983-03-10
1983-06-24
1983-08-16
1983-11-02
1984-01-26
MnCor
-0.394
-0.368
-0.322
-0.255
-0.333
-0.345
-0.370
-0.304
-0.350
-0.346
-0.344
-0.374
-0.358
-0.351
-0.361
-0.339
-0.346
-0.373
-0.347
-0.368
-0.365
-0.371
-0.343
-0.368
-0.381
-0.397
-0.382
Date
1984-01-26
1984-01-26
1984-01-26
1984-01-26
1984-04-27
1984-04-27
1984-09-13
1984-11-07
1984-12-05
1984-12-06
1984-12-07
1985-01-31
1985-02-07
1985-07-01
1985-08-26
1985-08-26
1986-01-13
1986-01-13
1986-01-14
1986-01-14
1986-01-14
1987-03-24
1987-03-26
1987-03-26
1987-03-26
1988-02-29
1988-03-01
48
MnCor
-0.418
-0.394
-0.428
-0.410
-0.378
-0.352
-0.384
-0.424
-0.310
-0.397
-0.368
-0.292
-0.340
-0.321
-0.275
-0.374
-0.250
-0.280
-0.308
-0.322
-0.344
-0.234
-0.327
-0.350
-0.268
-0.295
-0.294
Date
1990-05-30
1990-10-02
1992-02-12
1992-02-13
1993-06-11
1995-09-05
1995-09-15
1998-01-23
1998-11-13
1999-03-05
1999-04-21
2004-10-27
2005-01-14
2005-02-01
2005-03-28
2005-09-17
2006-01-13
2006-01-13
2006-08-24
2007-03-06
2008-01-14
2008-08-19
2009-07-08
2009-08-28
MnCor
-0.312
-0.314
-0.276
-0.291
-0.310
-0.266
-0.286
-0.207
-0.210
-0.228
-0.306
-0.254
-0.297
-0.255
-0.267
-0.218
-0.276
-0.262
-0.269
-0.275
-0.314
-0.282
-0.279
-0.272
Table 2: Meniscus corrections measured on the large manometer. Meniscus correction MnCor (in
mm) measured on given Date is an additive correction to the column height.
Date
1969-12-08
1969-12-12
1970-03-09
1970-03-13
1970-04-22
1970-05-06
1970-05-15
1972-09-08
1972-11-21
1974-01-02
1974-02-22
1974-05-31
MnCor
-0.036
-0.026
-0.127
-0.126
-0.104
-0.014
+0.015
+0.026
+0.010
-0.111
-0.121
-0.068
Date
1974-08-14
1974-10-17
1979-09-14
1980-04-24
1980-09-04
1981-08-04
1981-09-11
1982-04-19
1982-11-02
1983-08-16
1983-11-02
1984-10-29
MnCor
-0.128
-0.142
+0.014
-0.010
-0.015
-0.066
-0.050
-0.002
+0.044
+0.036
-0.012
+0.009
Date
1985-01-31
1985-07-01
1987-03-27
1988-03-07
1990-05-29
1990-10-02
1992-02-12
1992-02-13
1993-06-18
1995-09-18
1995-11-07
1997-12-29
49
MnCor
-0.005
+0.007
-0.006
+0.052
-0.018
+0.006
+0.017
-0.021
+0.083
-0.006
-0.045
-0.009
Date
1998-11-13
1998-11-13
1999-03-05
1999-04-21
2005-01-03
2005-05-02
2006-02-24
2007-03-06
2008-04-23
2009-02-19
2009-09-02
MnCor
-0.063
-0.055
-0.027
+0.004
+0.112
+0.138
+0.073
+0.149
+0.143
+0.157
+0.171
Table 3: Parameters used to approximate measured plenum and inferred
chamber volumes variation with time. Volume drift is expressed as a constant
(Constant) and linear rate of change (Rate) for specific time windows defined by TStart and T-End. Volume at time T is calculated as Volume = Constant + Rate*(T
- T-Start)
Name
Small
Small
Small
Large
64
L02
L03
L04
L05
L06
L07
L08
P01
P02
P03
P04
P05
P06
P07
P08
P09
P10
P11
P12
P13
P14
P15
P16
P17
P18
P19
P20
P21
Volume
Type
Chamber
Chamber
Chamber
Chamber
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
Plenum
T-Start
T-End
1969-01-01
1982-01-01
1985-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1969-01-01
1982-01-01
1985-01-01
--------------------------------
Constant
cc
3.7970
3.7993
3.7934
4991.1
66.543
11.159
12.652
13.681
16.235
16.274
18.292
20.034
1.3697
1.5295
1.7194
1.9813
2.0429
2.1373
2.3773
2.8010
52.715
1.6924
278.42
1011.1
3976.0
5422.7
5223.1
5314.2
5319.3
5349.3
5236.4
5329.0
5079.8
50
Rate
cc/day
---+3.1989e-05
-4.4280e-06
-8.6182e-08
-------9.9598e-08
-9.3663e-08
-1.1569e-07
-3.2668e-07
-2.8697e-07
-1.3955e-07
-1.4426e-07
--1.7463e-06
--1.0548e-05
--4.1113e-05
-4.7775e-05
--------
Table 4: Summary of small chamber volume averages for measurements since 1985. Standard case
excludes measurements made in 1994 and 1999 as well as in early 2005. Other cases considered exclude only the
early 2005 data and include all data since 1985. Table compares volumes for the three data groups and shows an
estimate of the impact of using each alternate volume on mole fraction for a gas of 400 ppm CO2 .
Data Since 1985
Included/Excluded
Excl. 1994, 1999 and early 2005
Excl. early 2005
Incl. All Data Since 1985
Average
Volume
3.7934 cc
3.7929 cc
3.7928 cc
Difference
0.0005 cc
0.0006 cc
Standard
Error
0.0001 cc
0.0001 cc
0.0001 cc
Concentration
Impact @400 ppm
-0.05 ppm
-0.06 ppm
Table 5: Isotopic corrections to manometric reference gases.
44
Tank ID
X‡ δ 13 CP DB δ 18 OP DB−CO2
F † 44 F /0.984106
X0
X0 − X
natural air 365.00
-8.000
0.000 0.984106
1.000000 365.0000 0.000000
71251 214.23
-8.296
-3.420 0.984125
1.000020 214.2341 0.004064
34819 252.91
-8.528
-5.743 0.984138
1.000034 252.9181 0.008143
71286 297.10
-7.783
-4.226 0.984123
1.000018 297.1050 0.005050
71341 322.29
-8.645
-10.109 0.984159
1.000055 322.3073 0.017255
66638 338.81
-8.026
-4.548 0.984127
1.000023 338.8172 0.007170
66625 344.86
-7.603
-3.794 0.984119
1.000014 344.8645 0.004491
66696 360.54
-7.589
-3.778 0.984119
1.000014 360.5446 0.004613
71308 376.11
-8.197
-7.986 0.984144
1.000040 376.1246 0.014607
71370 406.49
-9.933
-10.113 0.984173
1.000069 406.5176 0.027559
71479 453.13 -12.371
-9.813 0.984198
1.000095 453.1723 0.042314
67615 503.46 -14.336
-12.412 0.984231
1.000128 503.5240 0.063963
‡Nominal mole fractions
†44 F was computed using the following relations (see Lee et al. 2006 for symbol
definitions):
13
R=0.0111797 (1+δ 13 CP DB /1000)
12
F =1/(1+13 R)
δ 18 OV SM OW =1.04148 · δ 18 OP DB−CO2 +41.48
18
R=0.0020052 (1+δ 18 OV SM OW /1000)
17
R=0.0099235 · (18 R)0.516
16
F =1/(1+18 R +17 R)
44
F = (12 F ) · (16 F )2
Here
0.0111797=0.0112015/(1+1.95/1000)=13 RP DB =13 RN BS19 /(1+δ 13 C(N BS19)P DB /1000)
1.04148=(1.01025)(1.03091)=(18 RP DB /18 RV SM OW )(18 RP DB−CO2 /18 RP DB )
0.0020052=18 RV SM OW
52
1990
176.021
238.708
273.448
309.716
323.026
331.549
357.853
375.979
405.586
451.400
p4
1993
178.107
236.208
239.844
274.001
309.848
309.146
319.387
322.948
331.373
357.424
375.340
404.606
449.780
1995
176.582
235.472
273.485
309.560
308.914
319.168
322.733
331.183
357.225
375.162
404.411
449.538
1997
175.670
234.933
273.158
309.343
308.797
319.080
322.514
330.993
357.071
374.999
404.350
449.534
1999
176.046
235.150
273.268
309.446
308.953
319.212
322.638
331.061
357.095
374.984
404.209
449.202
∗
ID
1983
1985∗
1987
1989
1990
1993
1995
71251
194.510
194.625
194.451
194.666
195.148
196.879
195.638
34819
241.910
242.140
242.086
242.120
242.508
243.410
242.822
71286
291.480
291.559
291.459
291.388
291.557
291.839
291.508
71341
317.510
317.479
317.306
317.208
317.293
317.247
317.016
66638
333.190
333.250
333.143
333.128
333.123
332.923
332.818
66625
339.260
339.277
339.116
339.075
339.087
338.765
338.646
66696
353.610
353.720
353.564
353.535
353.466
353.047
352.947
71308
368.320
368.353
368.068
368.004
367.829
367.176
367.022
71370
394.480
394.516
394.324
394.275
393.970
393.105
392.898
71479
432.640
432.676
432.322
432.237
431.810
430.401
430.243
67615
470.250
470.279
469.850
469.809
469.272
467.337
467.106
Adjustment for drift in secondary standard 34850, see Keeling et al.[1986],
1997
194.768
242.340
291.174
316.811
332.575
338.368
352.735
366.825
392.771
430.126
467.206
p4
1999
195.070
242.425
291.325
316.854
332.684
338.458
352.808
366.839
392.725
429.892
466.796
2001
196.087
243.042
291.425
316.865
332.687
338.368
352.721
366.691
392.591
429.853
466.874
2003
195.250
242.560
291.180
316.780
332.630
338.330
352.770
366.690
392.570
429.670
466.650
2005
195.610
242.780
291.280
316.780
332.650
338.350
352.740
366.710
392.600
429.860
466.840
Table 7: Average APC J Values for Air Primaries Run During ”Marathon Tank Day” Calibration Periods
∗
ID
1970
1974
1980
1983
1985∗
1987
1989
2408
181.520
175.260
175.366
175.102
175.512
4274
3753
241.530
238.930
238.100
238.238
238.182
238.294
7366
276.570
275.710
273.840
273.220
273.293
273.214
273.214
6078
310.950
311.180
310.230
309.720
309.768
309.663
309.616
6071
352.800
4296
327.410
2399
324.190
324.250
323.530
323.070
323.104
323.001
322.958
39239
332.240
331.690
331.712
331.571
331.519
10069
355.640
354.440
39272
358.190
358.253
358.034
357.983
1540
377.070
376.460
376.498
376.225
376.208
35299
406.320
407.190
406.300
406.295
405.995
405.930
35316
452.220
453.980
452.530
452.471
452.032
451.915
Adjustment for drift in secondary standard 34850, see Keeling et al.[1986],
Table 6: Average APC J Values for Nitrogen Primaries Run During ”Marathon Tank Day” Calibration Periods
2008
194.030
241.820
290.750
316.390
332.360
338.090
352.590
366.550
392.570
429.820
466.760
2001
177.445
235.855
273.641
309.529
309.146
319.273
322.619
331.115
357.052
374.894
404.165
449.241
2012
194.370
242.070
290.870
316.490
332.390
338.050
352.560
366.510
392.500
429.580
466.470
2003
176.270
235.240
273.200
308.960
319.190
331.000
357.020
374.890
404.040
449.030
2005
176.800
235.510
273.380
309.020
319.220
330.960
357.020
374.920
404.100
449.190
Table 8: Concentration comparisons for NOAA tanks analyzed at Scripps in 1992 through 1999
Tank ID
Identification number of NOAA tank. Tanks 136 and 132 are shown
with a * as Scripps posesses tanks with the same ID numbers.
NOAA Mano
NOAA‘s CO2 concentration based upon measurements with their
manometric system.
X12-1992
Scripps CO2 concentration based upon measurements made in 1992 with
the APC analyzer on the X12 calibration scale
Diff 1992
Difference between X12-1992 and NOAA Mano.
X12-1993
Scripps CO2 concentration based upon measurements made in 1993 with
the APC analyzer on the X12 calibration scale
Diff 1993
Difference between X12-1993 and NOAA Mano.
X12-1996
Scripps CO2 concentration based upon measurements made in 1996 with
the APC analyzer on the X12 calibration scale
Diff 1996
Difference between X12-1996 and NOAA Mano.
X12-1997
Scripps CO2 concentration based upon measurements made in 1997 with
the APC analyzer on the X12 calibration scale
Diff 1997
Difference between X12-1997 and NOAA Mano.
X12-1999
Scripps CO2 concentration based upon measurements made in 1999 with
the APC analyzer on the X12 calibration scale
Diff 1999
Difference between X12-1999 and NOAA Mano.
SIO Mano
Scripps CO2 concentration based upon measurements with the
manometric system.
Diff Mano
Difference between SIO Mano and NOAA Mano.
† Cylinder 103 was determined by NOAA to drift downwards in CO2 at a rate of 0.013
ppm/yr. NOAA values used in this table for cylinder 103 comparisons have been
adjusted linearly over time from 353.34 ppm in 1996
Tank NOAA
ID Mano
110 246.64
102 304.36
111 324.01
130 337.28
121 349.38
103† 353.34
139 360.90
105 369.38
136∗ 381.33
146 389.60
101 396.32
106 412.05
123 423.08
107 453.03
132∗ 521.42
X121992
246.59
304.36
323.95
337.22
349.26
353.10
360.71
369.24
381.17
389.39
396.12
411.77
422.69
452.48
520.30
Diff
1992
-0.05
+0.01
-0.06
-0.07
-0.12
-0.29
-0.19
-0.14
-0.16
-0.21
-0.20
-0.28
-0.39
-0.55
-1.12
X12- Diff
1993 1993
246.50 -0.14
304.22 -0.14
324.01 +0.01
337.24 -0.05
349.35 -0.03
353.18 -0.20
360.86 -0.05
369.41 +0.03
381.37 +0.03
389.67 +0.07
396.39 +0.07
412.27 +0.21
423.27 +0.18
453.15 +0.12
521.62 +0.20
X12- Diff
1996 1996
246.39 -0.25
304.30 -0.05
323.94 -0.06
337.27 -0.01
349.38 -0.01
353.22 -0.12
360.90 -0.01
369.37 -0.00
381.27 -0.06
389.62 +0.01
396.23 -0.09
412.08 +0.03
422.98 -0.10
452.91 -0.12
521.17 -0.25
53
X12
Diff
1997 1997
246.58 -0.06
304.27 -0.09
323.99 -0.02
337.26 -0.02
349.38 -0.00
353.21 -0.11
360.92 +0.02
369.48 +0.10
381.42 +0.09
389.65 +0.05
396.35 +0.03
412.16 +0.11
423.11 +0.03
453.07 +0.04
521.54 +0.12
X12- Diff
1999 1999
247.37 +0.73
304.46 +0.11
324.04 +0.03
337.29 +0.00
349.35 -0.04
353.17 -0.13
360.82 -0.08
369.26 -0.12
381.18 -0.15
389.36 -0.25
396.06 -0.27
411.89 -0.16
422.92 -0.17
452.95 -0.08
521.71 +0.29
SIO
Mano
246.50
323.91
352.78
360.76
369.38
381.37
396.01
453.05
-
Diff
Mano
-0.14
-0.10
-0.52
-0.14
+0.00
+0.04
-0.32
+0.02
-
Table 9: Concentration comparisons for NOAA tanks analyzed at Scripps in 2005.
Tank ID
Identification number of NOAA tank.
NOAA IR
NOAA‘s CO2 concentration based upon measurements with their Infra
Red analyzer.
NOAA Mano
NOAA‘s CO2 concentration based upon measurements with their
manometric system.
X12-2005
Scripps CO2 concentration based upon measurements with the APC
analyzer on the X12 calibration scale
Diff 2005
Difference between X12-2005 and NOAA Mano.
SIO Mano
Scripps CO2 concentration based upon measurements with the
manometric system.
Diff Mano
Difference between SIO Mano and NOAA Mano.
† Cylinder 17491 was determined by NOAA to drift downwards in CO2 . We have
interpolated this drift in time, estimating NOAA’s manometric value for this
cylinder as 402.40 ppm in 2005
Tank ID
17476
18067
18470
18372
17563
†17491
20737
17440
17438
NOAA
IR
348.38
352.20
361.74
375.78
388.46
402.29
427.65
479.52
550.30
NOAA
Mano
348.36
352.18
361.73
375.77
388.46
402.40
427.65
479.51
550.14
X122005
348.30
352.11
361.75
375.80
388.42
402.32
427.66
479.82
550.89
Diff
2005
-0.06
-0.07
0.02
0.03
-0.04
-0.08
0.01
0.31
0.75
SIO
Mano
348.34
352.12
361.71
375.82
388.51
402.38
427.76
479.59
550.50
54
Diff
Mano
-0.02
-0.06
-0.02
0.05
0.05
-0.02
0.11
0.08
0.36
16 Figures
55
Column 3
Column 4
Figure 1: Photographs of the Constant Volume Manometer taken in 2015. Left: Manometer
cabinet as seen from behind the cathetometer. Right: Close-up of the primary sample column
(Column 4), equipped with pointers (resembling icicles), to enclose different volumes. The 4cc
volume is demarked by the pointer closest to the bulb of the mercury thermometer. CO2
samples are transferred into the volume by filling the ”exterior cup” (below the lowest visible
pointer) with liquid nitrogen. An alternate, but unused sample column can be seen to the left
(Column 3).
Large and Small Manometer Meniscus Corrections [mm]
0.2
0.1
0.135
Small manometer measurement
Large manometer measurement
Previously used value for white Stripes
Chamber measurement
Correction appied in this report
−0.005
0
−0.042
−0.1
−0.2
−0.271
−0.303
−0.3
−0.364
−0.4
−0.5
70 72 74 76 78 80 82 84 86 88 90 92 94 96 98 00 02 04 06 08
Date
Figure 2: Measured and applied meniscus corrections for the small and large manometer. Black
hollow circles or squares indicate individual measurements (see Table 1 and 2). The red points
indicate values used in previous reports for determinations of the primary air manometric
reference gases (white stripes). Blue crosses indicate values used here and in previous reports
for chamber volume calibrations, in most cases these are actual measured values at that time.
Solid lines indicate values used here in support of the X12 scale for all tank deteminations.
57
Figure ??: Individual Calibration Volumes for the Plenums P01, P02,
P03, P06, P07 and L02 with Linear Fit
1.2995
P01
P06
2.039
1.2985
2.038
1.298
2.037
1.2975
2.036
1.297
2.035
1.2965
1.296
2.034
1.2955
2.033
1.295
Volume [cc]
Volume [cc]
1.299
2.032
2.277
1.464
P02
P07
2.274
1.462
2.273
2.272
1.461
2.271
1.46
Volume [cc]
2.275
1.463
Volume [cc]
2.276
2.27
2.269
1.459
2.268
1.638
P03
L02
11.115
11.11
11.105
1.636
11.1
1.635
11.095
11.09
1.634
11.085
1.633
11.08
1975 1980 1985 1990 1995 2000 2005 2010
Date
/home/matlab/CDRGMANO/cdmnplotmultiplenum.m
11.075
1975 1980 1985 1990 1995 2000 2005 2010
Date
Figure 3: Individual volumes of the plenums P01, P02, P03, P06, P07 and L02 with linear fit. For
comparison purposes, the y-axes have been scaled to show limits that represent a 0.4% change
in each plenum’s volume.
58
Volume [cc]
Volume [cc]
1.637
Figure ??: Variation of the manometer’s small chamber volume over time. Individual volume determinations are indicated by
the green circles. Solid black triangles and squares represent average chamber volumes as recorded in the 2002 manometry
technical report and corresponding averages for new data over the same time periods respectively. The solid black line
indicates the assumed variation in volume over time. The vertical dashed line indicates the time at which the manometer was
cleaned.
Individual
Flagged
Excluded
Measured Average, 2002 Report
Assumed Volume, 2002 Report
Measured Average, This Report
Assumed Volume, This Report
3.802
3.8
3.796
3.794
Manometer Cleaned
Small Chamber Volume
3.798
3.792
3.79
3.788
1970
1975
1980
1985
1990
Date
/home/matlab/CDRGMANO/cdmnplotplenum.m
1995
2000
2005
2010
Figure 4: Variation of the manometer’s small chamber volume over time. Individual volume
determinations are indicated by the black circles. Analyses conducted in 1994, 1999 and early
2005 have been excluded from the averages and these volumes are indicated by red circles.
Solid blue triangles represent average chamber volumes as recorded in the 2002 manometry
technical report (tables 5.2 and 9.4a-e in that document). Solid black squares are the
corresponding averages from this analysis over the same time periods. The solid black line
indicates the assumed variation in the chamber’s volume over time, while the blue dashed sloping
line represents the variation assumed in 2002 report. The vertical dash-dot line indicates the time
at which the manometer was cleaned.
59
P13
3952
3950
Volume [cc]
3948
3946
3944
3942
3940
1975
1980
1985
1990
1995
2000
2005
2010
Figure 5: Individual volumes measurements of the plenum P13 used for calibrating the 5000 cc
chamber, with linear fit. There are actually 3 data points for 2004 volumes, however these appear
indistinguishable in this plot. The y-axis has been scaled to show limits that represent a 0.4%
change in the plenum’s volume for comparison with Figure 3.
5015.4
Current
Linear Fit
2002 Report
5015.2
5015
Volume
5014.8
5014.6
5014.4
5014.2
5014
74
79
84
89
94
99
04
Date
/home/matlab/CDRGMANO/cdmncalc5litervol.m
Figure 6: Variation of the manometer’s 5 liter chamber volume over time. Individual volume
determinations are indicated by black circles. Black triangles represent average chamber
volumes as used in the 2002 manometry technical report. The solid black line indicates the
assumed variation in the chamber’s volume over time.
60
0.090
0.080
y = 9E-08x2 - 3E-05x + 0.019
R² = 0.7004
Accumulative Error (mm)
0.070
0.060
0.050
0.040
0.030
0.020
0.010
0.000
0
100
200
300
400
500
600
700
800
900
1000
Gauge Reading (mm)
2Jan03Calib
OrigCalib72F
OrigCalib80F
Poly. (2Jan03Calib)
Figure 7: Calibration measurements of the cathetometer, comparing pitch against machinist’s
“Cadillac” gauge
0.02
0
Correction (HGht-DWG), mm
-0.02
y = 0.000000612x2 - 0.0008400x + 0.1934
R2 = 0.7709
-0.04
-0.06
-0.08
-0.1
-0.12
-0.14
0
100
200
300
400
500
600
700
800
900
1000
Vacuum Column (#2), mm
All 3 days (2009)
Average (2009)
Poly. (All 3 days (2009))
Figure 8: Calibration measurements for small chamber manometer, comparing pressure against
dead-weight gauge.
61
0.06
0.04
y = 0.000000315x2 - 0.0004337x + 0.1121
R2 = 0.4473
0.02
Correction (HGht-DWG), mm
0
-0.02
-0.04
-0.06
-0.08
-0.1
-0.12
-0.14
0
100
200
300
400
500
600
700
800
900
Vacuum Column, mm (Col. #8)
All 3days (2009)
Average (2009)
Apr-06
Poly. (All 3days (2009))
Poly. (Apr-06)
Figure 9: Calibration measurements for large chamber manometer, comparing pressure against
dead-weight gauge
62
0.02
Mole Fraction Change, dX [ppm]
0.01
0
−0.01
−0.02
−0.03
−0.04
−0.05
−0.06
250
300
350
CO2 Mole Fraction
400
450
Figure 10: Effect of potential cathetomoter adjustment on manometric mole fractions. Each point
is the shift in single manometric determination. These corrections, which were not fully
understood (see text) were not applied for the X12A scale. The potential corrections here are
additive. A correction of -0.04 ppm signifies that the manometric mole fraction would have been
revised downward by 0.04 ppm had the correction been applied. The data can be seen to cluster
along three lines, which are the result of the impact of the cathetometer adjustments on the
determination of the 4cc volume, and the differing impacts in the three periods: pre 1982,
1982-1985, post 1985.
63
Individual Analyses
Average of Duplicated Analyses
381
Mole Fraction [ppm]
380.8
380.6
380.4
380.2
380
379.8
2006
2007
2008
Date
2009
Figure 11: Time history of manometric determinations of tank 1661
64
2010
Figure ??: Residual of each nitrogen primary tank’s observed manometric mole fraction from the tank’s average value over time. Open
symbols represent flagged data that have been excluded from the average. Solid lines represent the assumed time varying concentration
for each tank that is used to calculate APC cubic coefficients
1
0.8
4274 243.38
3753 246.15
7366 276.67
39239 332.79
10069 355.76
39272 360.68
1540 380.62
6071 310.48
6078 310.92
4296 320.63
2399 324.13
35299 415.10
35316 472.83
Tank Residual [ppm]
Tank Residual [ppm]
0.6
0.4
0.2
0
−0.2
−0.4
−0.6
−0.8
−1
1
0.8
Tank Residual [ppm]
Tank Residual [ppm]
0.6
0.4
0.2
0
−0.2
−0.4
−0.6
−0.8
−1
1970
1975
1980
1985
1990
1995
2000
2005
2010
1970
Year
1975
1980
1985
1990
1995
2000
2005
2010
Year
/home/matlab/CDRGMANO/cdmnplottankdrift.m
Figure 12: Residual of each nitrogen primary tank’s observed carbon dioxide manometric mole
fraction from the tank’s average value over time. Open symbols represent flagged data that have
been excluded from the average. Solid lines represent the assumed time varying concentration
for each tank that is used to calculate APC cubic coefficients. Tanks are identified by cylinder ID
number and average CO2 concentrations in ppm.
65
Figure ??: Residual of each air primary tank’s observed manometric mole fraction from the tank’s average value over time. Open symbols
represent flagged data that have been excluded from the average. Solid lines represent the assumed time varying concentration for
each tank that is used to calculate APC cubic coefficients
1
0.8
71251 213.16
34819 252.00
71286 296.70
66696 360.19
71308 376.24
71370 406.55
71341 322.18
66638 338.42
66625 344.62
71479 453.50
67615 503.90
Tank Residual [ppm]
Tank Residual [ppm]
0.6
0.4
0.2
0
−0.2
−0.4
−0.6
−0.8
−1
1
0.8
Tank Residual [ppm]
Tank Residual [ppm]
0.6
0.4
0.2
0
−0.2
−0.4
−0.6
−0.8
−1
1980
1985
1990
1995
2000
2005
2010
Year
1980
1985
1990
1995
2000
2005
2010
Year
/home/matlab/CDRGMANO/cdmnplottankdrift.m
Figure 13: Residual of each air primary tank’s observed carbon dioxide manometric mole fraction
from the tank’s average value over time. Open symbols represent flagged data that have been
excluded from the average. Solid lines represent the assumed time varying concentration for
each tank that is used to calculate APC cubic coefficients. Tanks are identified by cylinder ID
number and average CO2 concentrations in ppm.
66
Figure ??: Residual of each nitrogen primary tank’s observed manometric mole fraction from cubic fit X value as deterined on the APC
0.4
0.3
0.2
0.2
0.1
0.1
0
0
−0.1
−0.1
−0.2
−0.2
−0.3
−0.3
−0.4
0.4
−0.4
0.4
6071 310.50
6078 310.90
4296 320.63
2399 324.08
0.3
35299 415.16
35316 472.86
0.3
0.2
0.2
0.1
0.1
0
0
−0.1
−0.1
−0.2
−0.2
−0.3
−0.3
−0.4
1970
1975
1980
1985
1990
1995
2000
2005
2010
1970
Year
1975
1980
1985
1990
1995
2000
2005
Residual [ppm]
Residual [ppm]
0.3
Residual [ppm]
39239 332.83
10069 355.77
39272 360.70
1540 380.67
4274 243.39
3753 246.19
7366 276.67
Residual [ppm]
0.4
−0.4
2010
Year
/home/matlab/CDRGMANO/cdmncalccubic.m
Figure 14: Residual of each nitrogen primary tank’s manometric mole fraction X from the APC
cubic fit XA
67
Figure ??: Residual of each air primary tank’s observed manometric mole fraction from cubic fit X value as deterined on the APC
0.4
Residual [ppm]
0.3
0.3
0.2
0.2
0.1
0.1
0
0
−0.1
−0.1
−0.2
−0.2
−0.3
−0.3
−0.4
0.4
−0.4
0.4
71341 322.16
66638 338.50
66625 344.64
0.3
Residual [ppm]
66696 360.28
71308 376.24
71370 406.61
71479 453.54
67615 504.05
0.3
0.2
0.2
0.1
0.1
0
0
−0.1
−0.1
−0.2
−0.2
−0.3
−0.3
−0.4
1980
1985
1990
1995
2000
2005
2010
1980
Year
1985
1990
1995
2000
2005
2010
Residual [ppm]
71251 213.16
34819 252.07
71286 296.71
Residual [ppm]
0.4
−0.4
Year
/home/matlab/CDRGMANO/cdmncalccubic.m
Figure 15: Residual of each air primary tank’s manometric mole fraction X from the APC cubic fit
XA
68
Linear Primaries APC N2 Scale Difference X12−X08A
0.5
0.4
X12 − X08A [ppm]
0.3
0.2
X08A=225
X08A=250
X08A=275
X08A=300
X08A=325
X08A=350
X08A=375
X08A=400
X08A=425
X08A=450
0.1
0
−0.1
−0.2
68
73
78
83
88
93
Date
98
03
08
13
Figure 16: Difference between the X12 and X08A nitrogen calibration scale for the APC analyzer
69
Linear Primaries APC Air Scale Difference X12−X08A
0.5
0.4
X12 − X08A [ppm]
0.3
0.2
X08A=225
X08A=250
X08A=275
X08A=300
X08A=325
X08A=350
X08A=375
X08A=400
X08A=425
X08A=450
0.1
0
−0.1
−0.2
68
73
78
83
88
93
Date
98
03
08
13
Figure 17: Difference between the X12 and X08A air calibration scale for the APC analyzer. The
larger adjustments starting in 2008 and extending to 2015 reflect the need to correct for
extrapolating the cubic corrections forward from the last marathon tank day in 2008. Similarly
large corrections were needed between 2005 and 2008 when updating from the X2005A and
X2008A scales.
70
Comparisons of NOAA tanks run on APC 1993
0.6
0.6
0.4
0.4
0.2
0.2
0
0
−0.2
−0.2
−0.4
−0.4
250
300
350
400
450
500
250
300
350
400
450
500
0.6
0.6
SIO − NOAA [ppm]
(b) 17−Feb−1993 12−Mar−1993 IR
(e) 21−Apr−1999 14−Jul−1999 IR
0.4
0.4
0.2
0.2
0
0
−0.2
−0.2
−0.4
−0.4
−0.6
250
300
350
400
450
500
250
300
350
400
450
500
0.6
−0.6
0.6
(c) 09−Jan−1996 26−Jul−1996 IR
SIO − NOAA [ppm]
−0.6
(f) 1999 Mano
0.4
0.4
0.2
0.2
0
0
−0.2
−0.2
−0.4
−0.4
−0.6
SIO − NOAA [ppm]
−0.6
250
300
350
400
450
NOAA Tank Value [ppm]
500
250
300
350
400
450
NOAA Tank Value [ppm]
500
−0.6
Figure 18: Comparison of cylinder concentrations for suite of gases received from NOAA in 1992.
Figures show difference between values declared by NOAA and values measured at SIO on the
X12 and X08A calibration scales. Panels (a) through (e) present difference between SIO IR
values measured between the dates indicated in each legend and NOAA values. Panel (f) shows
difference between SIO manometric determinations made in 1999 and NOAA.
71
SIO − NOAA [ppm]
SIO − NOAA [ppm]
(d) 28−Jul−1997 23−Sep−1997 IR
SIO X12
SIO X08A
SIO − NOAA [ppm]
(a) 02−Jan−1992 07−Dec−1992 IR
Comparisons of NOAA tanks run at Scripps on APC 2005
0.6
SIO IR X08A
SIO IR X12
SIO Mano
0.5
SIO − NOAA [ppm]
0.4
0.3
0.2
0.1
0
−0.1
−0.2
−0.3
−0.4
300
350
400
450
NOAA Tank Value [ppm]
500
550
600
Figure 19: Comparison of NOAA cylinder concentrations measured in 2005, comparing values
declared by NOAA with values measured at SIO on the X12 and X08A calibration scales. Red
and Green curves show measurements of NOAA tanks made on the APC analyzer. Blue curve
shows direct determinations of the NOAA tanks on the manometer.
72
17 Appendix A. Supplemental Tables
Table A1: Plenum Calibration Data Notes. Data and calculated results are listed for calibrations
of the volumes of plenums by weighing them filled with mercury or with water. The plenums are glass
containers equipped with vacuum stopcocks and are mostly used to calibrate, by transfer of CO2 gas,
the volumes of chambers in the constant-volume mercury-column manometer (CMM) or the electronic
constant-volume manometer (ECM). The calibrations were made between February 1974 and October
2008 by A. Adams (in 1974 and 1976), by P Guenther (mercury calibrations in 2007), and by G. Emanuele
(all water calibrations from 1999 to 2008). Notes on the columns in the table follow.
Date
Date of the measurement, in YYYYMMDD
Med
Medium of the calibrating fluid, either water (h2o) or mercury (hg).
Plnm
Number of plenum. The original set of plenums used to calibrate the 4 cc chamber of the
CMM in 1974 are numbered P01 to P07. The nominally 4000 cc flask, located within the
CMM cabinet, and used to calibrate the 5000 cc chamber, is numbered P13.
Temp
Temperature, in C, of the calibration, in most cases that of a constant- temperature water
bath into which the plenums were immersed after filling them with the calibrating fluid but
before closing the stopcock. In 1974, no water bath was used: the thermometer was placed
adjacent to the plenums, ”in the air.”
Wt-Full
Weight, in grams, of the plenum filled with the calibrating fluid
WtEmpty
Weight, in grams, of the plenum evacuated.
Flg
Flag: two calibrations in 2007 (using water) are flagged, one with a ”1” and the other with
a ”2”.
Bthcor
Correction to the thermometer immersed in the water bath, if any.
Balcor1
Balcor2
Corrections to the weight, as determined by placing weights on the balance at the time of
the full weight (Balcor1) and the evacuated weight (Balcor2). These weights in turn have a
correction determined by weighing them on a calibrated balance: these ”corrections to the
corrections” are applied in the program. There are non-zero corrections only for some 2007
calibrations with water.
Buoy-Wt
Weight of the fluid corrected for the buoyancy of the weights, assuming stainless steel.
Rho
Density of the fluid, in g/cm3 , at the calibration temperature
Volume
Calculated volume of the plenum, in cm3 .
Table A1: Plenum Calibration Data. Page 1/3
Date
20070705
20070706
20070709
20070712
20070911
20070920
20081002
20081002
19740826
19740827
19740827
20070510
20070510
20070511
20071008
20071009
20070501
20070502
20070430
20070430
20070501
20080619
20070502
20070502
20081002
20070510
20070511
20070514
20070502
20070502
20080619
20070514
20070514
20070514
20070911
19740301
19740305
19740308
19740312
19740314
19990715
19990720
20070305
20070313
20070316
20070327
20070402
20070404
20071017
20071017
20071017
19740301
19740305
19740308
19740312
19740314
19990715
19990720
20070305
20070313
20070316
20070327
20070402
20070404
20071019
20071019
20071019
19740301
19740305
19740308
19740312
19740314
19990708
Med
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
hg
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
hg
hg
hg
hg
h2o
Plnm
L01
L01
L01
L01
L01
L01
L01
L01
L02
L02
L02
L02
L02
L02
L02
L02
L03
L03
L04
L04
L04
L04
L05
L05
L05
L06
L06
L06
L07
L07
L07
L08
L08
L08
L08
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P01
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P02
P03
P03
P03
P03
P03
P03
Temp
22.293
22.293
22.310
22.312
22.305
22.304
22.300
22.302
21.800
21.400
21.300
22.294
22.295
22.293
22.308
22.307
22.295
22.295
22.293
22.293
22.293
22.301
22.295
22.295
22.303
22.295
22.294
22.294
22.294
22.295
22.301
22.294
22.295
22.295
22.306
21.200
21.900
21.100
20.900
22.000
23.090
23.100
22.302
22.302
22.298
22.294
22.295
22.294
22.800
22.800
22.800
21.200
21.900
21.100
20.900
22.000
23.100
23.090
22.301
22.300
22.298
22.294
22.294
22.294
22.800
22.800
22.800
21.200
21.900
21.100
20.900
22.000
20.400
Wt-Full
75.1441
75.1400
75.1468
75.1402
75.1412
75.1431
75.1517
75.1364
222.670
222.684
222.680
83.4425
83.4472
83.4439
83.4407
83.4379
81.1031
81.0984
84.5277
84.5228
84.5221
84.5352
81.7606
81.7576
81.7537
93.7860
93.7871
93.7914
81.5167
81.5108
81.5116
101.834
101.833
101.833
101.814
69.9830
69.9850
69.9800
69.9980
69.9950
53.7298
53.7148
53.7218
53.7154
53.7216
53.7168
53.7146
53.7179
69.9910
69.9890
69.9880
72.2440
72.2420
72.2400
72.2420
72.2390
53.9025
53.8934
53.9052
53.8949
53.8973
53.8951
53.8976
53.8963
72.2230
72.2240
72.2250
76.2480
76.2480
76.2450
76.2470
76.2470
55.7233
Wt-Empty
67.6889
67.6819
67.6891
67.6818
67.6835
67.6883
67.6933
67.6805
72.3770
72.3840
72.3720
72.3673
72.3726
72.3690
72.3704
72.3691
68.4781
68.4738
70.8774
70.8743
70.8708
70.8804
65.5613
65.5566
65.5532
77.5472
77.5468
77.5526
63.2648
63.2608
63.2580
81.8350
81.8343
81.8342
81.8314
52.4070
52.4090
52.4000
52.4180
52.4150
52.4356
52.4204
52.4277
52.4225
52.4275
52.4226
52.4214
52.4243
52.4250
52.4260
52.4190
52.4420
52.4430
52.4380
52.4390
52.4420
52.4445
52.4353
52.4483
52.4384
52.4387
52.4367
52.4402
52.4387
52.4430
52.4440
52.4440
54.0900
54.0890
54.0870
54.0890
54.0910
54.0912
Flg
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Bthcor
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.00
0.00
-0.10
-0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.10
-0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.10
Buoy-Wt
7.45409
7.45697
7.45660
7.45727
7.45651
7.45361
7.45726
7.45478
150.270
150.277
150.285
11.0735
11.0730
11.0732
11.0687
11.0672
12.6231
12.6227
13.6482
13.6464
13.6492
13.6528
16.1969
16.1986
16.1982
16.2363
16.2379
16.2363
18.2492
18.2473
18.2509
19.9961
19.9962
19.9958
19.9792
17.5734
17.5734
17.5774
17.5774
17.5774
1.29402
1.29414
1.29388
1.29272
1.29388
1.29409
1.29296
1.29349
17.5634
17.5604
17.5664
19.7990
19.7960
19.7990
19.8000
19.7940
1.45778
1.45796
1.45668
1.45633
1.45835
1.45818
1.45721
1.45737
19.7770
19.7770
19.7780
22.1547
22.1557
22.1547
22.1547
22.1527
1.63184
Rho
0.997706
0.997706
0.997702
0.997702
0.997703
0.997703
0.997704
0.997704
13.5414
13.5424
13.5427
0.997706
0.997706
0.997706
0.997703
0.997703
0.997706
0.997706
0.997706
0.997706
0.997706
0.997704
0.997706
0.997706
0.997704
0.997706
0.997706
0.997706
0.997706
0.997706
0.997704
0.997706
0.997706
0.997706
0.997703
13.5429
13.5412
13.5432
13.5436
13.5409
0.997519
0.997517
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5390
13.5390
13.5390
13.5429
13.5412
13.5432
13.5436
13.5409
0.997517
0.997519
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5390
13.5390
13.5390
13.5429
13.5412
13.5432
13.5436
13.5409
0.998123
Volume
7.47123
7.47412
7.47378
7.47445
7.47368
7.47077
7.47442
7.47194
11.0971
11.0968
11.0972
11.0990
11.0984
11.0987
11.0942
11.0926
12.6521
12.6517
13.6796
13.6778
13.6806
13.6842
16.2341
16.2359
16.2354
16.2737
16.2752
16.2736
18.2911
18.2892
18.2929
20.0421
20.0422
20.0418
20.0252
1.29761
1.29777
1.29788
1.29783
1.29809
1.29723
1.29736
1.29685
1.29569
1.29685
1.29706
1.29593
1.29646
1.29724
1.29702
1.29747
1.46195
1.46191
1.46192
1.46194
1.46179
1.46141
1.46159
1.46003
1.45968
1.46171
1.46153
1.46056
1.46072
1.46075
1.46075
1.46082
1.63589
1.63617
1.63586
1.63580
1.63598
1.63490
Table A1: Plenum Calibration Data. Page 2/3
Date
19990713
19990715
19990720
20070306
20070313
20070316
20070327
20070402
20070404
20070926
20070927
20070927
20071001
20071002
19740226
19740301
19740305
19740308
19740312
19990708
19990713
19990715
19990720
20070305
20070313
20070316
20070327
20070402
20070404
20071029
20071029
20071030
19740308
19740312
19740314
19740314
19740315
19990708
19990713
19990715
19990720
20070305
20070313
20070316
20070327
20070402
20070404
20071030
20071030
20071030
19740301
19740305
19740308
19740312
19740314
19990708
19990713
19990715
19990720
20070305
20070313
20070316
20070327
20070402
20070404
20071018
20071018
20071018
19740301
19740305
19740308
19740312
19740314
Med
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
h2o
h2o
hg
hg
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
hg
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
hg
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
hg
hg
hg
hg
Plnm
P03
P03
P03
P03
P03
P03
P03
P03
P03
P03
P03
P03
P03
P03
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P04
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P05
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P06
P07
P07
P07
P07
P07
Temp
23.090
23.080
23.080
22.301
22.301
22.299
22.294
22.295
22.294
20.800
21.000
20.900
22.306
22.305
20.200
21.200
21.900
21.100
20.900
20.400
23.090
23.100
23.080
22.302
22.301
22.298
22.293
22.295
22.294
22.800
22.800
22.800
21.100
20.900
22.000
21.600
21.900
20.400
23.090
23.090
23.080
22.301
22.301
22.298
22.294
22.295
22.294
22.800
22.800
22.800
21.100
21.900
21.100
20.900
22.000
20.400
23.090
23.060
23.070
22.300
22.301
22.298
22.295
22.294
22.294
22.800
22.800
22.800
21.200
21.900
21.100
20.900
22.000
Wt-Full
55.7200
55.7239
55.7188
55.7219
55.7174
55.7191
55.7199
55.7193
55.7198
76.2340
76.2380
76.2330
55.7265
55.7225
81.1790
81.1680
81.1610
81.1680
81.1680
59.2579
59.2585
59.2616
59.2540
59.2625
59.2560
59.2595
59.2569
59.2571
59.2585
81.1080
81.1090
81.0920
102.457
102.459
102.463
102.454
102.456
79.3762
79.3749
79.3810
79.3667
79.3844
79.3731
79.3734
79.3743
79.3675
79.3668
102.355
102.352
102.361
86.2380
86.2320
86.2310
86.2320
86.2260
60.6817
60.6777
60.6757
60.6713
60.6796
60.6728
60.6739
60.6745
60.6709
60.6731
86.2050
86.2010
86.2040
88.6300
88.6230
88.6240
88.6220
88.6230
Wt-Empty
54.0886
54.0923
54.0872
54.0911
54.0867
54.0882
54.0886
54.0880
54.0895
54.0900
54.0960
54.0890
54.0953
54.0917
57.5300
57.5250
57.5210
57.5210
57.5190
57.5180
57.5195
57.5229
57.5151
57.5245
57.5183
57.5215
57.5200
57.5187
57.5204
57.5200
57.5200
57.5220
77.5920
77.5890
77.5960
77.5880
77.5910
77.5456
77.5452
77.5520
77.5373
77.5566
77.5460
77.5439
77.5450
77.5383
77.5378
77.5480
77.5600
77.5600
58.6500
58.6510
58.6430
58.6440
58.6430
58.6499
58.6465
58.6446
58.6404
58.6496
58.6420
58.6433
58.6441
58.6398
58.6426
58.6490
58.6450
58.6470
57.8380
57.8360
57.8320
57.8300
57.8340
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Bthcor
-0.10
-0.10
-0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.00
0.00
0.00
-0.10
-0.10
-0.10
-0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.10
-0.10
-0.10
-0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.10
-0.10
-0.10
-0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Buoy-Wt
1.63118
1.63132
1.63127
1.63064
1.63049
1.63067
1.63113
1.63104
1.63007
22.1407
22.1387
22.1407
1.63098
1.63054
23.6455
23.6395
23.6364
23.6435
23.6455
1.73967
1.73879
1.73844
1.73858
1.73766
1.73745
1.73776
1.73664
1.73816
1.73788
23.5845
23.5855
23.5665
24.8613
24.8663
24.8633
24.8623
24.8613
1.83036
1.82942
1.82869
1.82911
1.82757
1.82683
1.82917
1.82900
1.82891
1.82870
24.8033
24.7883
24.7973
27.5839
27.5769
27.5839
27.5839
27.5789
2.03154
2.03092
2.03075
2.03066
2.02965
2.03043
2.03020
2.03006
2.03086
2.03018
27.5519
27.5519
27.5529
30.7874
30.7824
30.7874
30.7874
30.7844
Rho
0.997519
0.997522
0.997522
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5439
13.5434
13.5436
0.997703
0.997703
13.5454
13.5429
13.5412
13.5432
13.5436
0.998123
0.997519
0.997517
0.997522
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5390
13.5390
13.5390
13.5432
13.5436
13.5409
13.5419
13.5412
0.998123
0.997519
0.997519
0.997522
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5390
13.5390
13.5390
13.5432
13.5412
13.5432
13.5436
13.5409
0.998123
0.997519
0.997527
0.997524
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5390
13.5390
13.5390
13.5429
13.5412
13.5432
13.5436
13.5409
Volume
1.63523
1.63537
1.63532
1.63439
1.63424
1.63442
1.63488
1.63479
1.63381
1.63474
1.63465
1.63477
1.63473
1.63429
1.74565
1.74552
1.74552
1.74579
1.74587
1.74294
1.74311
1.74277
1.74290
1.74166
1.74145
1.74176
1.74063
1.74216
1.74188
1.74197
1.74204
1.74064
1.83571
1.83601
1.83615
1.83595
1.83597
1.83380
1.83396
1.83323
1.83365
1.83177
1.83103
1.83337
1.83320
1.83311
1.83290
1.83199
1.83088
1.83155
2.03674
2.03652
2.03674
2.03666
2.03670
2.03535
2.03597
2.03578
2.03570
2.03432
2.03510
2.03487
2.03472
2.03553
2.03484
2.03500
2.03500
2.03508
2.27332
2.27324
2.27328
2.27320
2.27343
Table A1: Plenum Calibration Data. Page 3/3
Date
19990708
19990713
19990715
19990720
20070305
20070313
20070316
20070327
20070402
20070404
20070928
20071016
20071016
20070305
20070313
20070316
20070327
20070402
20070404
20070911
19740903
19740903
19740905
20080410
20080410
20070924
20070924
20070925
20070925
20071001
20071002
19760528
19760602
19760602
19760603
20080418
20080418
19740329
19740401
19740402
20080630
20080701
20040824
20040825
20040825
19740109
19740110
19740111
19740114
19740115
20040818
20040819
20040820
19740117
19740117
19740122
19740123
19740124
19740125
19740129
19740130
19740129
19740130
19740129
19740130
19740131
19740201
19740131
19740201
20040713
20040714
20040715
Med
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
hg
hg
hg
hg
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h2o
h20
h20
h20
h20
h20
h20
h20
h2o
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
h20
Plnm
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P08
P08
P08
P08
P08
P08
P08
P09
P09
P09
P09
P09
P10
P10
P10
P10
P10
P10
P11
P11
P11
P11
P11
P11
P13
P13
P13
P12
P12
P13
P13
P13
P14
P14
P14
P14
P14
P14
P14
P14
P15
P15
P15
P15
P15
P15
P16
P16
P17
P17
P18
P18
P19
P19
P20
P20
P21
P21
P21
Temp
20.400
23.290
23.270
23.270
22.301
22.301
22.298
22.295
22.295
22.294
21.200
22.800
22.800
22.302
22.300
22.298
22.294
22.294
22.294
22.305
21.200
21.200
21.600
22.284
22.305
21.200
21.400
20.700
20.800
22.303
22.306
20.100
20.100
20.100
20.100
22.305
22.305
22.100
21.900
21.800
22.300
22.302
22.279
22.280
22.278
18.500
18.800
17.300
18.100
19.100
22.273
22.277
22.278
21.000
17.900
16.300
20.300
21.200
20.500
21.000
21.200
21.000
21.200
21.000
21.200
21.100
21.000
21.100
21.000
22.286
22.285
22.287
Wt-Full
60.1052
60.1037
60.1017
60.1002
60.1055
60.1020
60.0979
60.1008
60.1024
60.1003
88.5990
88.6020
88.5960
66.6631
66.6616
66.6604
66.6641
66.6589
66.6573
66.6661
152.772
152.777
152.766
152.741
152.738
79.1760
79.1690
79.1770
79.1800
57.9375
57.9391
475.623
475.634
475.612
475.598
475.340
475.360
5058.90
5059.10
5059.30
1230.61
1230.56
5059.50
5059.50
5059.60
6162.40
6162.00
6162.60
6162.30
6160.60
6158.00
6158.10
6158.00
6206.60
6208.60
6208.80
6205.50
6204.80
6205.90
6211.10
6211.10
6190.80
6190.50
6236.80
6236.90
6227.50
6226.90
6219.10
6219.10
6187.20
6187.10
6187.20
Wt-Empty
57.8370
57.8371
57.8347
57.8335
57.8394
57.8356
57.8310
57.8341
57.8358
57.8334
57.8340
57.8330
57.8350
63.8691
63.8658
63.8646
63.8679
63.8643
63.8635
63.8717
101.414
101.420
101.413
101.418
101.414
56.2540
56.2540
56.2510
56.2480
56.2487
56.2502
205.264
205.256
205.244
205.255
205.240
205.250
1121.20
1120.80
1120.80
221.670
221.670
1122.10
1122.10
1122.20
782.200
780.400
780.400
780.200
780.800
781.800
781.800
781.800
991.300
991.400
991.900
991.700
991.300
991.900
906.600
907.200
881.100
881.500
897.700
897.400
1000.40
1000.80
900.100
900.000
1118.30
1118.20
1118.30
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Bthcor
-0.10
0.10
0.10
0.10
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.00
0.02
0.02
-0.03
-0.03
-0.03
0.00
0.00
0.00
0.00
0.00
-0.03
-0.03
-0.03
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.03
-0.03
-0.03
Buoy-Wt
2.26795
2.26626
2.26663
2.26637
2.26569
2.26602
2.26656
2.26634
2.26635
2.26654
30.7604
30.7644
30.7564
2.79361
2.79534
2.79548
2.79581
2.79412
2.79337
2.79398
51.3503
51.3493
51.3453
51.3153
51.3163
22.9186
22.9116
22.9226
22.9286
1.68850
1.68869
270.318
270.337
270.327
270.302
270.059
270.069
3937.11
3937.71
3937.91
1008.79
1008.74
3936.81
3936.81
3936.81
5379.39
5380.79
5381.39
5381.29
5378.99
5375.39
5375.49
5375.39
5214.52
5216.42
5216.12
5213.02
5212.72
5213.22
5303.70
5303.10
5308.90
5308.20
5338.30
5338.70
5226.32
5225.32
5318.20
5318.30
5068.14
5068.14
5068.14
Rho
0.998123
0.997472
0.997476
0.997476
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
13.5429
13.5390
13.5390
0.997704
0.997704
0.997705
0.997706
0.997706
0.997706
0.997703
0.997951
0.997951
0.997863
0.997708
0.997703
13.5429
13.5424
13.5441
13.5439
0.997704
0.997703
0.998186
0.998186
0.998186
0.998186
0.997703
0.997703
0.99775
0.997796
0.997818
0.997704
0.997704
0.997709
0.997709
0.997709
0.998505
0.998447
0.998725
0.99858
0.998388
0.997711
0.99771
0.997709
0.997995
0.998617
0.998897
0.998144
0.997951
0.998102
0.997995
0.997951
0.997995
0.997951
0.997995
0.997951
0.997973
0.997995
0.997973
0.997995
0.997708
0.997708
0.997707
Volume
2.27221
2.27200
2.27236
2.27210
2.27090
2.27123
2.27177
2.27155
2.27156
2.27175
2.27133
2.27228
2.27169
2.80004
2.80177
2.80191
2.80224
2.80055
2.79979
2.80041
51.4557
51.4547
51.4553
51.4332
51.4344
1.69229
1.69184
1.69243
1.69291
1.69238
1.69257
270.810
270.829
270.819
270.794
270.681
270.691
3945.99
3946.41
3946.52
1011.11
1011.06
3945.85
3945.85
3945.85
5387.45
5389.16
5388.26
5388.95
5387.68
5387.73
5387.83
5387.73
5224.99
5223.64
5221.88
5222.71
5223.42
5223.13
5314.36
5313.99
5319.57
5319.10
5349.02
5349.66
5236.93
5235.81
5329.00
5328.99
5079.78
5079.78
5079.79
Table A2: Plenum Fills using Fortin Barometer, 1974 to 1999 Notes. Data and calculated
results are listed for fillings of plenums with pure CO2 gas from 1974 to 1999. The plenums were filled to
ambient laboratory pressures, which were measured on a Fortin-type mercury barometer. The pressure
was computed in the same way as for CMM data, using the mercury height and measured temperature
of the barometer along with the acceleration of gravity. When combined with the known volume of the
plenum and the fill temperature, the number of moles of CO2 contained in the plenum was calculated
using the virial equation of state. Notes on the columns in the table follow.
Date
Date of the measurement, in YYYYMMDD.
Fill
Designated consecutive number of the plenum fill, with the prefix ”B” referring to
”barometer.” Each plenum filled has a separate number, including those filled at the
same time.
Plnm
Number of plenum. The original set of plenums (from 1.3 to 2.3 cc in volume) was
used to calibrate the nominally 4 cc chamber in the CMM. Plenum P09 was used for
the nominally 64 cc and 250 cc chambers.
Volume of the plenum, in cc, from the fit versus time of volume calibrations made
between 1974 and 2008 (see Table 3).
Vol
BaroP
Mercury height measured on the mercury barometer in the laboratory, in mm Hg.
BaroCor
Correction to the measured barometer reading, determined by comparing mercury
heights measured on the barometer and on the CMM functioning as a barometer, i.e.
with the sample column open to the room, in mm Hg.
BaroT
Temperature of the mercury column in the barometer, in C.
BathT
Temperature of the water bath surrounding the plenum when filled with CO2, in C.
µ-Moles CO2
Calculated amount of CO2 in the plenum, in micromoles.
Flg
A ”1” or ”2” indicates rejected data, the former for statistical reasons and the latter
for experimental reasons.
Table A2: Plenum Fills using Fortin Barometer, 1974 to 1999. Page 1/2
Date
19740620
19740620
19740626
19740626
19740709
19740709
19740729
19740729
19740730
19740730
19740801
19740801
19740807
19740807
19740807
19740807
19851024
19851024
19851024
19851024
19851030
19851030
19851030
19851030
19851030
19860121
19860121
19860121
19860121
19860121
19860123
19860123
19860123
19860123
19860123
19880219
19880219
19880223
19880223
19880223
19880223
19880223
19880225
19880225
19880225
19880225
19880225
19880302
19880302
19880302
19880302
19880302
19900208
19900208
19900208
19900212
19900212
19900212
19900214
19900214
19900214
19900214
19900214
19900214
19901004
19901004
19901004
19901004
19901004
19901005
19901005
19901008
19901008
Fill
B001
B002
B003
B004
B005
B006
B007
B008
B009
B010
B011
B012
B013
B014
B015
B016
B017
B018
B019
B020
B021
B022
B023
B024
B025
B026
B027
B028
B029
B030
B031
B032
B033
B034
B035
B036
B037
B038
B039
B040
B041
B042
B043
B044
B045
B046
B047
B048
B049
B050
B051
B052
B053
B054
B055
B056
B057
B058
B059
B060
B061
B062
B063
B064
B065
B066
B067
B068
B069
B070
B071
B072
B073
Plnm
P07
P01
P01
P07
P07
P01
P07
P01
P01
P07
P07
P01
P03
P05
P04
P01
P01
P07
P01
P07
P01
P03
P04
P05
P07
P01
P02
P03
P06
P07
P01
P03
P05
P07
P04
P01
P07
P01
P02
P03
P06
P07
P07
P06
P03
P02
P01
P01
P02
P04
P05
P07
P01
P07
P09
P01
P07
P09
P01
P07
P02
P03
P06
P09
P01
P07
P02
P03
P06
P07
P01
P03
P01
Vol
2.2733
1.2979
1.2979
2.2733
2.2733
1.2979
2.2733
1.2979
1.2979
2.2733
2.2733
1.2979
1.6360
1.8360
1.7457
1.2979
1.2974
2.2727
1.2974
2.2727
1.2974
1.6355
1.7443
1.8348
2.2727
1.2974
1.4615
1.6355
2.0361
2.2727
1.2974
1.6355
1.8348
2.2727
1.7443
1.2974
2.2726
1.2974
1.4615
1.6354
2.0360
2.2726
2.2726
2.0360
1.6354
1.4615
1.2974
1.2974
1.4615
1.7440
1.8345
2.2726
1.2973
2.2725
51.4454
1.2973
2.2725
51.4454
1.2973
2.2725
1.4614
1.6353
2.0359
51.4454
1.2973
2.2725
1.4614
1.6353
2.0359
2.2725
1.2973
1.6353
1.2973
BaroP
761.4
761.4
760.8
760.8
763.8
763.8
761.7
761.7
763.4
763.4
763.1
763.1
760.8
760.8
760.8
760.8
765.3
765.3
763.2
763.2
764.4
764.4
764.4
764.4
764.4
764.5
764.5
764.5
764.5
764.5
767.4
767.4
767.4
767.4
767.4
766.6
766.6
764.9
764.9
764.9
764.9
764.9
764.5
764.5
764.5
764.5
764.5
763.4
763.4
763.4
763.4
763.4
765.5
765.5
765.5
763.5
763.5
763.5
762.4
762.4
762.4
762.4
762.4
762.4
764.5
764.5
764.5
764.5
764.5
763.1
763.1
764.0
764.0
BaroCor
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.2
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
-0.1
BaroT
20.8
20.8
20.5
20.5
20.7
20.7
21.2
21.2
20.4
20.4
20.2
20.2
20.3
20.3
20.3
20.3
21.5
21.5
21.3
21.3
21.2
21.2
21.2
21.2
21.2
20.7
20.7
20.7
20.7
20.7
21.0
21.0
21.0
21.0
21.0
21.0
21.0
21.5
21.5
21.5
21.5
21.5
21.3
21.3
21.3
21.3
21.3
21.4
21.4
21.4
21.4
21.4
20.5
20.5
20.5
20.2
20.2
20.2
20.9
20.9
20.9
20.9
20.9
20.9
21.7
21.7
21.7
21.7
21.7
21.8
21.8
20.5
20.5
BathT
20.78
20.78
20.75
20.75
20.77
20.77
20.75
20.75
20.75
20.75
20.77
20.77
20.75
20.75
20.75
20.75
21.86
21.86
21.86
21.86
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.96
21.87
21.87
21.87
21.87
21.87
21.87
21.87
21.86
21.86
21.86
21.86
21.86
21.86
21.86
21.86
21.86
21.86
21.87
21.87
21.87
21.89
21.89
21.89
21.87
21.87
21.87
21.87
21.87
21.87
22.04
22.04
22.04
22.04
22.04
22.32
22.32
22.05
22.05
µ-MolesCO2
94.4635
53.9302
53.8959
94.4036
94.7677
54.1038
94.5036
53.9530
54.0820
94.7294
94.6889
54.0588
67.9395
76.2449
72.4948
53.8977
53.9677
94.5344
53.8207
94.2770
53.8882
67.9291
72.4491
76.2065
94.3952
53.8998
60.7171
67.9438
84.5872
94.4157
54.1025
68.1993
76.5090
94.7707
72.7365
54.0594
94.6961
53.9339
60.7561
67.9871
84.6412
94.4764
94.4334
84.6027
67.9562
60.7285
53.9094
53.8304
60.6395
72.3645
76.1195
94.2950
53.9904
94.5762
2141.05
53.8478
94.3264
2135.40
53.7667
94.1842
60.5682
67.7765
84.3792
2132.18
53.8751
94.3746
60.6906
67.9134
84.5497
94.1083
53.7231
67.8812
53.8496
Flg
00
00
01
00
02
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
02
02
00
00
00
00
00
00
00
00
02
00
02
00
00
00
00
00
00
00
00
00
00
00
00
00
00
02
02
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A2: Plenum Fills using Fortin Barometer, 1974 to 1999. Page 2/2
Date
19901008
19901008
19901008
19931012
19931012
19931012
19940131
19940131
19940131
19940131
19940131
19940202
19940202
19940202
19940207
19940207
19940207
19940207
19940207
19940207
19981210
19981210
19981214
19981214
19981214
19981214
19981214
19990106
19990106
19990106
19990106
19990106
19990113
19990113
19990113
19990113
19990113
19990121
19990121
19990121
19990121
19990121
Fill
B074
B075
B076
B077
B078
B079
B080
B081
B082
B083
B084
B085
B086
B087
B088
B089
B090
B091
B092
B093
B094
B095
B096
B097
B098
B099
B100
B101
B102
B103
B104
B105
B106
B107
B108
B109
B110
B111
B112
B113
B114
B115
Plnm
P07
P02
P06
P01
P07
P09
P01
P07
P02
P03
P06
P01
P07
P09
P01
P07
P02
P03
P06
P09
P01
P07
P01
P02
P03
P06
P07
P02
P07
P01
P06
P03
P01
P07
P02
P06
P03
P01
P07
P02
P06
P03
Vol
2.2725
1.4614
2.0359
1.2972
2.2723
51.4430
1.2971
2.2723
1.4613
1.6352
2.0357
1.2971
2.2723
51.4429
1.2971
2.2723
1.4613
1.6352
2.0357
51.4428
1.2970
2.2720
1.2970
1.4611
1.6349
2.0355
2.2720
1.4611
2.2720
1.2970
2.0355
1.6349
1.2970
2.2720
1.4611
2.0355
1.6349
1.2970
2.2720
1.4611
2.0355
1.6349
BaroP
764.0
764.0
764.0
764.1
764.1
764.1
769.4
769.4
769.4
769.4
769.4
765.0
765.0
765.0
757.3
757.3
757.3
757.3
757.3
757.3
771.9
771.9
766.7
766.7
766.7
766.7
766.7
766.7
766.7
766.7
766.7
766.7
768.0
768.0
768.0
768.0
768.0
768.7
768.7
768.7
768.7
768.7
BaroCor
-0.1
-0.1
-0.1
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.4
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
-0.3
BaroT
20.5
20.5
20.5
21.2
21.2
21.2
19.8
19.8
19.8
19.8
19.8
20.1
20.1
20.1
21.6
21.6
21.6
21.6
21.6
21.6
20.4
20.4
20.7
20.7
20.7
20.7
20.7
21.2
21.2
21.2
21.2
21.2
20.7
20.7
20.7
20.7
20.7
21.1
21.1
21.1
21.1
21.1
BathT
22.05
22.05
22.05
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
22.97
22.97
22.97
22.97
22.97
22.97
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
21.92
µ-MolesCO2
94.3299
60.6619
84.5096
53.8482
94.3287
2135.53
54.2372
95.0104
61.0995
68.3703
85.1187
53.9223
94.4587
2138.48
53.1693
93.1397
59.8965
67.0242
83.4428
2108.62
54.4082
95.3122
54.0366
60.8749
68.1182
84.8052
94.6612
60.8692
94.6525
54.0316
84.7973
68.1119
54.1287
94.8225
60.9786
84.9496
68.2342
54.1743
94.9024
61.0300
85.0212
68.2918
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge, 1999 to 2008. Notes Data and calculated
results are listed for fillings of plenums with pure CO2 gas from 1999 to 2008. The plenums were filled
to pressures that were determined on a Ruska Dead Weight Gauge (DWG). The pressure was computed
from the weights applied to the DWG piston during operation and the measured temperature and
residual pressure in the bell jar of the DWG for correction. When combined with the known volume of
the plenum and the fill temperature, the number of moles of CO2 contained in the plenum was calculated
using the virial equation of state. Notes on the columns in the table follow.
Date
Date of the measurement, in YYYYMMDD.
Fill
Designated number of the plenum fill, with the prefix ”D” referring to ”DWG.” A
single fill number applies to all plenums (up to eight) filled at the same time, i.e. to
the same pressure. The large plenums used for calibration of large CMM volumes in
2008 have the prefix ”E” and were filled individually.
Plnm
Number of plenum. The original set of plenums with prefix P and the set of larger
plenums with prefix L (from 7 to 20 cc in volume) were used to calibrate the small
CMM chamber and the chambers in the Electronic Constant-Volume Manometers
(ECMs).
Vol
Volume of the plenum, in cc, from the fit versus time of volume calibrations made
between 1974 and 2008 (see Table 3).
BellP
Pressure in the bell jar of the DWG during the determination of pressure, in millitorr.
This was used to correct the pressure determined by the DWG.
DWGT
Temperature of the DWG during the determination of pressure, in C.
DWGMassNos
Numbers of the weights used on the piston of the DWG for determination of pressure.
DWGP
Calculated pressure, in mm Hg.
BathT
Temperature of the water bath surrounding the plenum when filled with CO2 , in C.
µ-MolesCO2
Calculated amount of CO2 in the plenum, in micromoles.
Flg
Flag column: none are listed.
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 1/8
Date
19990608
19990608
19990608
19990608
19990608
19990610
19990610
19990610
19990610
19990610
19990614
19990614
19990614
19990614
19990614
19990617
19990617
19990617
19990617
19990617
19990623
19990623
19990623
19990623
19990623
19990628
19990628
19990628
19990628
19990628
20000324
20000324
20000324
20000324
20000324
20000329
20000329
20000329
20000329
20000330
20000330
20000330
20000330
20000330
20000330
20000330
20000330
20000330
20000330
20000331
20000331
20000331
20000331
20000331
20000331
20000331
20000331
20000331
20000331
20000707
20000707
20000707
20000707
20000707
20000707
20000707
20000707
20000707
20000707
20000725
20000725
20000725
20000725
Fill
D001
D001
D001
D001
D001
D002
D002
D002
D002
D002
D003
D003
D003
D003
D003
D004
D004
D004
D004
D004
D005
D005
D005
D005
D005
D006
D006
D006
D006
D006
D007
D007
D007
D007
D007
D008
D008
D008
D008
D009
D009
D009
D009
D009
D010
D010
D010
D010
D010
D011
D011
D011
D011
D011
D012
D012
D012
D012
D012
D013
D013
D013
D013
D013
D014
D014
D014
D014
D014
D015
D015
D015
D015
Plnm
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
Vol
1.6349
1.7427
1.8334
2.0354
2.2720
1.6349
1.7427
1.8334
2.0354
2.2720
1.6349
1.7427
1.8334
2.0354
2.2720
1.6349
1.7427
1.8334
2.0354
2.2720
1.6349
1.7427
1.8334
2.0354
2.2720
1.6349
1.7427
1.8334
2.0354
2.2720
1.6349
1.7426
1.8333
2.0354
2.2720
1.7426
1.8333
2.0354
2.2720
1.6349
1.7426
1.8333
2.0354
2.2720
1.6349
1.7426
1.8333
2.0354
2.2720
1.6349
1.7426
1.8333
2.0354
2.2720
1.6349
1.7426
1.8333
2.0354
2.2720
1.6349
1.7426
1.8333
2.0354
2.2719
1.6349
1.7426
1.8333
2.0354
2.2719
1.6349
1.7426
1.8332
2.0354
BellP
17.5
17.5
17.5
17.5
17.5
10.0
10.0
10.0
10.0
10.0
14.1
14.1
14.1
14.1
14.1
13.9
13.9
13.9
13.9
13.9
14.0
14.0
14.0
14.0
14.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
10.5
10.5
10.5
10.5
10.5
10.0
10.0
10.0
10.0
10.0
10.2
10.2
10.2
10.2
10.2
10.8
10.8
10.8
10.8
10.8
14.0
14.0
14.0
14.0
DWGT
22.0
22.0
22.0
22.0
22.0
22.3
22.3
22.3
22.3
22.3
22.0
22.0
22.0
22.0
22.0
22.5
22.5
22.5
22.5
22.5
22.3
22.3
22.3
22.3
22.3
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.3
22.3
22.3
22.3
21.5
21.5
21.5
21.5
21.5
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.0
22.0
22.0
22.0
22.0
22.1
22.1
22.1
22.1
22.1
23.5
23.5
23.5
23.5
DWGMassNos
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
DWGP
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.12
737.12
737.12
737.12
BathT
20.93
20.93
20.93
20.93
20.93
20.93
20.93
20.93
20.93
20.93
20.47
20.47
20.47
20.47
20.47
20.51
20.51
20.51
20.51
20.51
20.51
20.51
20.51
20.51
20.51
20.47
20.47
20.47
20.47
20.47
22.12
22.12
22.12
22.12
22.12
22.31
22.31
22.31
22.31
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.84
22.84
22.84
22.84
µ-MolesCO2
66.0527
70.4070
74.0699
82.2337
91.7910
66.0515
70.4058
74.0685
82.2323
91.7894
66.1575
70.5187
74.1873
82.3642
91.9366
66.1482
70.5087
74.1769
82.3526
91.9237
66.1480
70.5085
74.1766
82.3524
91.9235
66.1576
70.5187
74.1873
82.3643
91.9368
65.7799
70.1139
73.7622
81.8942
91.4122
70.0677
73.7135
81.8402
91.3519
65.7350
70.0660
73.7118
81.8383
91.3498
65.7343
70.0653
73.7110
81.8374
91.3488
65.7343
70.0652
73.7109
81.8374
91.3487
65.7342
70.0652
73.7109
81.8373
91.3487
65.6211
69.9437
73.5834
81.6964
91.1915
65.6210
69.9437
73.5833
81.6964
91.1914
65.6153
69.9375
73.5768
81.6893
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 2/8
Date
20000725
20000727
20000727
20000727
20000727
20000727
20000727
20000727
20000727
20000727
20000727
20001102
20001102
20001102
20001102
20001102
20001102
20001102
20001102
20001102
20001102
20010321
20010321
20010321
20010322
20010322
20010322
20010322
20010322
20010322
20010322
20010323
20010323
20010323
20010323
20010323
20010323
20010323
20010323
20010323
20010323
20010709
20010709
20010709
20010709
20010709
20010710
20010710
20010710
20010710
20010710
20010710
20010710
20010710
20010710
20010710
20010711
20010711
20010711
20010711
20010711
20010711
20010711
20010711
20010711
20010711
20010712
20010712
20010712
20010712
20010712
20020903
20020903
Fill
D015
D016
D016
D016
D016
D016
D017
D017
D017
D017
D017
D018
D018
D018
D018
D018
D019
D019
D019
D019
D019
D0T1
D0T1
D0T1
D020
D020
D020
D020
D020
D0T2
D0T2
D021
D021
D021
D021
D021
D022
D022
D022
D022
D022
D023
D023
D023
D023
D023
D024
D024
D024
D024
D024
D025
D025
D025
D025
D025
D026
D026
D026
D026
D026
D027
D027
D027
D027
D027
D028
D028
D028
D028
D028
D029
D029
Plnm
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P04
P06
P07
P03
P04
P05
P06
P07
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
Vol
2.2719
1.6349
1.7426
1.8332
2.0354
2.2719
1.6349
1.7426
1.8332
2.0354
2.2719
1.6349
1.7425
1.8332
2.0354
2.2719
1.6349
1.7425
1.8332
2.0354
2.2719
1.7425
2.0353
2.2719
1.6348
1.7425
1.8332
2.0353
2.2719
2.0353
2.2719
1.6348
1.7425
1.8332
2.0353
2.2719
1.6348
1.7425
1.8332
2.0353
2.2719
1.6348
1.7425
1.8331
2.0353
2.2719
1.6348
1.7425
1.8331
2.0353
2.2719
1.6348
1.7425
1.8331
2.0353
2.2719
1.6348
1.7425
1.8331
2.0353
2.2719
1.6348
1.7425
1.8331
2.0353
2.2719
1.6348
1.7425
1.8331
2.0353
2.2719
1.6348
1.7423
BellP
14.0
14.0
14.0
14.0
14.0
14.0
11.0
11.0
11.0
11.0
11.0
17.0
17.0
17.0
17.0
17.0
12.5
12.5
12.5
12.5
12.5
12.0
12.0
12.0
10.0
10.0
10.0
10.0
10.0
9.5
9.5
9.0
9.0
9.0
9.0
9.0
9.5
9.5
9.5
9.5
9.5
13.0
13.0
13.0
13.0
13.0
9.5
9.5
9.5
9.5
9.5
10.0
10.0
10.0
10.0
10.0
8.9
8.9
8.9
8.9
8.9
9.4
9.4
9.4
9.4
9.4
5.6
5.6
5.6
5.6
5.6
6.5
6.5
DWGT
23.5
23.5
23.5
23.5
23.5
23.5
23.3
23.3
23.3
23.3
23.3
22.9
22.9
22.9
22.9
22.9
23.4
23.4
23.4
23.4
23.4
22.7
22.7
22.7
22.7
22.7
22.7
22.7
22.7
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.7
22.7
22.7
22.7
22.7
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.0
23.1
23.1
DWGMassNos
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,7,9,12
1,2,7,9,12
1,2,7,9,12
1,2,7,9,12
1,2,7,9,12
1,3,7,8,13
1,3,7,8,13
DWGP
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.13
737.13
737.13
737.13
737.13
737.12
737.12
737.12
737.12
737.12
737.13
737.13
737.13
737.12
737.12
737.12
737.12
737.12
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
498.50
498.50
498.50
498.50
498.50
518.21
518.21
BathT
22.84
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.83
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.82
22.07
22.07
µ-MolesCO2
91.1835
65.6176
69.9398
73.5793
81.6921
91.1866
65.6175
69.9398
73.5792
81.6920
91.1865
65.6180
69.9395
73.5792
81.6926
91.1873
65.6171
69.9385
73.5781
81.6915
91.1860
69.9374
81.6915
91.1861
65.6192
69.9396
73.5796
81.6941
91.1890
81.6943
91.1892
65.6193
69.9397
73.5797
81.6942
91.1891
65.6191
69.9395
73.5795
81.6940
91.1889
65.6186
69.9381
73.5783
81.6935
91.1883
65.6183
69.9378
73.5779
81.6931
91.1879
65.6184
69.9378
73.5780
81.6931
91.1879
65.6183
69.9377
73.5779
81.6930
91.1878
65.6183
69.9378
73.5779
81.6930
91.1878
44.3038
47.2202
49.6779
55.1570
61.5677
46.1783
49.2156
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 3/8
Date
20020903
20020903
20020903
20020904
20020904
20020904
20020904
20020904
20020904
20020904
20020904
20020904
20020904
20020905
20020905
20020905
20020905
20020905
20020905
20020905
20020905
20020905
20020905
20020906
20020906
20020906
20020906
20020906
20030627
20030627
20030627
20030627
20030627
20030701
20030701
20030701
20030701
20030701
20030701
20030701
20030701
20030701
20030701
20030702
20030702
20030702
20030702
20030702
20030702
20030702
20030702
20030702
20030702
20030703
20030703
20030703
20030703
20030703
20030703
20030703
20030703
20030703
20030703
20041213
20041213
20041213
20041213
20041213
20041213
20041213
20041214
20041214
20041214
Fill
D029
D029
D029
D030
D030
D030
D030
D030
D031
D031
D031
D031
D031
D032
D032
D032
D032
D032
D033
D033
D033
D033
D033
D034
D034
D034
D034
D034
D035
D035
D035
D035
D035
D036
D036
D036
D036
D036
D037
D037
D037
D037
D037
D038
D038
D038
D038
D038
D039
D039
D039
D039
D039
D040
D040
D040
D040
D040
D041
D041
D041
D041
D041
D042
D042
D042
D042
D042
D042
D042
D043
D043
D043
Plnm
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
Vol
1.8330
2.0353
2.2718
1.6348
1.7423
1.8330
2.0353
2.2718
1.6348
1.7423
1.8330
2.0353
2.2718
1.6348
1.7423
1.8330
2.0353
2.2718
1.6348
1.7423
1.8330
2.0353
2.2718
1.6348
1.7423
1.8330
2.0353
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.6348
1.7422
1.8329
2.0352
2.2718
1.2967
1.4609
1.6347
1.7420
1.8328
2.0352
2.2717
1.2967
1.4609
1.6347
BellP
6.5
6.5
6.5
8.5
8.5
8.5
8.5
8.5
9.5
9.5
9.5
9.5
9.5
10.0
10.0
10.0
10.0
10.0
9.0
9.0
9.0
9.0
9.0
12.8
12.8
12.8
12.8
12.8
10.9
10.9
10.9
10.9
10.9
12.6
12.6
12.6
12.6
12.6
9.5
9.5
9.5
9.5
9.5
11.9
11.9
11.9
11.9
11.9
8.9
8.9
8.9
8.9
8.9
9.5
9.5
9.5
9.5
9.5
8.9
8.9
8.9
8.9
8.9
17.0
17.0
17.0
17.0
17.0
17.0
17.0
17.0
17.0
17.0
DWGT
23.1
23.1
23.1
22.5
22.5
22.5
22.5
22.5
23.0
23.0
23.0
23.0
23.0
23.4
23.4
23.4
23.4
23.4
23.0
23.0
23.0
23.0
23.0
23.1
23.1
23.1
23.1
23.1
23.6
23.6
23.6
23.6
23.6
23.0
23.0
23.0
23.0
23.0
23.7
23.7
23.7
23.7
23.7
23.1
23.1
23.1
23.1
23.1
23.8
23.8
23.8
23.8
23.8
23.3
23.3
23.3
23.3
23.3
23.4
23.4
23.4
23.4
23.4
22.2
22.2
22.2
22.2
22.2
22.2
22.2
22.3
22.3
22.3
DWGMassNos
1,3,7,8,13
1,3,7,8,13
1,3,7,8,13
1,3,7,8,13
1,3,7,8,13
1,3,7,8,13
1,3,7,8,13
1,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
DWGP
518.21
518.21
518.21
518.21
518.21
518.21
518.21
518.21
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.11
737.11
737.11
737.11
737.11
737.12
737.12
737.12
737.12
737.12
737.11
737.11
737.11
737.11
737.11
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.12
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
BathT
22.07
22.07
22.07
22.08
22.08
22.08
22.08
22.08
22.09
22.09
22.09
22.09
22.09
22.08
22.08
22.08
22.08
22.08
22.09
22.09
22.09
22.09
22.09
22.10
22.10
22.10
22.10
22.10
22.04
22.04
22.04
22.04
22.04
22.09
22.09
22.09
22.09
22.09
22.08
22.08
22.08
22.08
22.08
22.06
22.06
22.06
22.06
22.06
22.08
22.08
22.08
22.08
22.08
22.07
22.07
22.07
22.07
22.07
22.06
22.06
22.06
22.06
22.06
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
µ-MolesCO2
51.7779
57.4908
64.1728
46.1773
49.2146
51.7768
57.4895
64.1714
65.7814
70.1081
73.7581
81.8961
91.4147
65.7833
70.1101
73.7602
81.8985
91.4174
65.7813
70.1081
73.7580
81.8961
91.4146
65.7793
70.1059
73.7557
81.8935
91.4118
65.7908
70.1158
73.7669
81.9080
91.4281
65.7802
70.1045
73.7549
81.8948
91.4134
65.7815
70.1058
73.7564
81.8964
91.4152
65.7869
70.1115
73.7624
81.9030
91.4226
65.7814
70.1057
73.7562
81.8962
91.4149
65.7842
70.1087
73.7594
81.8997
91.4188
65.7863
70.1109
73.7617
81.9023
91.4218
52.1593
58.7615
65.7525
70.0705
73.7204
81.8603
91.3751
52.1592
58.7614
65.7524
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
01
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 4/8
Date
20041214
20041214
20041214
20041214
20041214
20041214
20041214
20041214
20041214
20041214
20041214
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041215
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20041216
20050503
20050503
20050503
20050503
20050503
20050615
20050615
20050615
20050615
20050615
20050616
20050616
20050616
20050616
20050616
20050617
20050617
20050617
20050617
20050617
20050620
20050620
20050620
20050620
20050620
20050620
20050620
20050707
20050707
20050707
20050707
20050707
20050707
20050707
Fill
D043
D043
D043
D043
D044
D044
D044
D044
D044
D044
D044
D045
D045
D045
D045
D045
D045
D045
D046
D046
D046
D046
D046
D046
D046
D047
D047
D047
D047
D047
D047
D047
D048
D048
D048
D048
D048
D048
D048
D049
D049
D049
D049
D049
D050
D050
D050
D050
D050
D051
D051
D051
D051
D051
D052
D052
D052
D052
D052
D053
D053
D053
D053
D053
D053
D053
D054
D054
D054
D054
D054
D054
D054
Plnm
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
Vol
1.7420
1.8328
2.0352
2.2717
1.2967
1.4609
1.6347
1.7420
1.8328
2.0352
2.2717
1.2967
1.4609
1.6347
1.7420
1.8328
2.0352
2.2717
1.2967
1.4609
1.6347
1.7420
1.8328
2.0352
2.2717
1.2967
1.4609
1.6347
1.7420
1.8328
2.0352
2.2717
1.2967
1.4609
1.6347
1.7420
1.8328
2.0352
2.2717
1.6347
1.7420
1.8327
2.0351
2.2717
1.6347
1.7420
1.8327
2.0351
2.2717
1.6347
1.7420
1.8327
2.0351
2.2717
1.6347
1.7420
1.8327
2.0351
2.2717
1.2967
1.4609
1.6347
1.7420
1.8327
2.0351
2.2717
1.2967
1.4609
1.6347
1.7420
1.8327
2.0351
2.2717
BellP
17.0
17.0
17.0
17.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
13.0
13.0
13.0
13.0
13.0
13.0
13.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
10.5
10.5
10.5
10.5
10.5
13.8
13.8
13.8
13.8
13.8
11.4
11.4
11.4
11.4
11.4
11.1
11.1
11.1
11.1
11.1
11.5
11.5
11.5
11.5
11.5
11.5
11.5
12.9
12.9
12.9
12.9
12.9
12.9
12.9
DWGT
22.3
22.3
22.3
22.3
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.4
22.4
22.4
22.4
22.4
22.4
22.4
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
22.4
22.4
22.4
22.4
22.4
22.4
22.4
DWGMassNos
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
DWGP
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
BathT
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.21
22.33
22.33
22.33
22.33
22.33
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.33
22.33
22.33
22.33
22.33
22.33
22.33
22.32
22.32
22.32
22.32
22.32
22.32
22.32
µ-MolesCO2
70.0704
73.7203
81.8601
91.3750
52.1585
58.7607
65.7515
70.0695
73.7194
81.8591
91.3738
52.1590
58.7612
65.7521
70.0701
73.7200
81.8598
91.3746
52.1585
58.7607
65.7515
70.0695
73.7193
81.8591
91.3738
52.1589
58.7611
65.7520
70.0700
73.7199
81.8597
91.3745
52.1589
58.7612
65.7520
70.0700
73.7199
81.8598
91.3745
65.7245
70.0396
73.6882
81.8255
91.3363
65.7248
70.0395
73.6883
81.8259
91.3368
65.7246
70.0393
73.6880
81.8256
91.3365
65.7251
70.0398
73.6886
81.8263
91.3372
52.1370
58.7366
65.7245
70.0391
73.6878
81.8254
91.3363
52.1368
58.7364
65.7242
70.0387
73.6875
81.8252
91.3360
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 5/8
Date
20050708
20050708
20050708
20050708
20050708
20050708
20050708
20060109
20060109
20060109
20060109
20060109
20060109
20060109
20060110
20060110
20060110
20060110
20060110
20060110
20060110
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060111
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060112
20060822
20060822
20060822
20060822
20060822
20060822
20060822
20060822
20060824
20060824
20060824
20060824
20060824
20060824
20060824
20060824
20060825
20060825
20060825
20060825
20060825
20060825
20060825
20060825
Fill
D055
D055
D055
D055
D055
D055
D055
D056
D056
D056
D056
D056
D056
D056
D057
D057
D057
D057
D057
D057
D057
D058
D058
D058
D058
D058
D058
D058
D059
D059
D059
D059
D059
D059
D059
D060
D060
D060
D060
D060
D060
D060
D060
D060
D060
D060
D060
D060
D060
D061
D061
D061
D061
D061
D061
D061
D061
D062
D062
D062
D062
D062
D062
D062
D062
D063
D063
D063
D063
D063
D063
D063
D063
Plnm
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P02
P03
P04
P05
P06
P07
P01
P01
P02
P02
P03
P03
P04
P04
P05
P05
P06
P06
P07
P07
P01
P02
P03
P04
P05
P06
P07
P08
P01
P02
P03
P04
P05
P06
P07
P08
P01
P02
P03
P04
P05
P06
P07
P08
Vol
1.2967
1.4609
1.6347
1.7420
1.8327
2.0351
2.2717
1.2967
1.4609
1.6346
1.7419
1.8327
2.0351
2.2716
1.2967
1.4609
1.6346
1.7419
1.8327
2.0351
2.2716
1.2967
1.4609
1.6346
1.7419
1.8327
2.0351
2.2716
1.2967
1.4609
1.6346
1.7419
1.8327
2.0351
2.2716
1.2967
1.2967
1.4609
1.4609
1.6346
1.6346
1.7419
1.7419
1.8327
1.8327
2.0351
2.0351
2.2716
2.2716
1.2967
1.4608
1.6346
1.7418
1.8326
2.0351
2.2716
2.8010
1.2967
1.4608
1.6346
1.7418
1.8326
2.0351
2.2716
2.8010
1.2967
1.4608
1.6346
1.7418
1.8326
2.0351
2.2716
2.8010
BellP
11.9
11.9
11.9
11.9
11.9
11.9
11.9
15.1
15.1
15.1
15.1
15.1
15.1
15.1
16.0
16.0
16.0
16.0
16.0
16.0
16.0
14.3
14.3
14.3
14.3
14.3
14.3
14.3
12.9
12.9
12.9
12.9
12.9
12.9
12.9
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
12.6
18.5
18.5
18.5
18.5
18.5
18.5
18.5
18.5
15.4
15.4
15.4
15.4
15.4
15.4
15.4
15.4
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5
DWGT
21.8
21.8
21.8
21.8
21.8
21.8
21.8
22.7
22.7
22.7
22.7
22.7
22.7
22.7
22.1
22.1
22.1
22.1
22.1
22.1
22.1
21.8
21.8
21.8
21.8
21.8
21.8
21.8
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.2
21.2
21.2
21.2
21.2
21.2
21.2
21.2
21.4
21.4
21.4
21.4
21.4
21.4
21.4
21.4
DWGMassNos
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
DWGP
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
BathT
22.32
22.32
22.32
22.32
22.32
22.32
22.32
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
µ-MolesCO2
52.1374
58.7370
65.7250
70.0395
73.6883
81.8261
91.3370
52.1412
58.7415
65.7298
70.0432
73.6926
81.8322
91.3439
52.1415
58.7419
65.7303
70.0437
73.6931
81.8327
91.3445
52.1415
58.7418
65.7302
70.0436
73.6930
81.8326
91.3444
52.1411
58.7414
65.7297
70.0431
73.6925
81.8321
91.3438
52.1422
52.1422
58.7426
58.7426
65.7311
65.7311
70.0445
70.0445
73.6939
73.6939
81.8337
81.8337
91.3456
91.3456
52.1409
58.7413
65.7296
70.0411
73.6909
81.8319
91.3437
112.629
52.1406
58.7410
65.7291
70.0406
73.6904
81.8314
91.3431
112.628
52.1405
58.7409
65.7291
70.0405
73.6903
81.8313
91.3430
112.628
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 6/8
Date
20060825
20060825
20060825
20060825
20060825
20060825
20060825
20060825
20070419
20070419
20070419
20070419
20070419
20070419
20070419
20070419
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070420
20070503
20070503
20070503
20070503
20070504
20070504
20070504
20070504
20070515
20070515
20070515
20070515
20070515
20070515
20070516
20070516
20070516
20070516
20070516
20070516
20070718
20070718
20070718
20070718
20070718
20070718
20070720
20070720
20070720
20070720
20070720
20070720
20070720
20070720
20070720
20070720
20070720
20070720
20070913
20070913
20070913
Fill
D064
D064
D064
D064
D064
D064
D064
D064
D065
D065
D065
D065
D065
D065
D065
D065
D066
D066
D066
D066
D066
D066
D066
D066
D067
D067
D067
D067
D067
D067
D067
D067
D068
D068
D068
D068
D069
D069
D069
D069
D070
D070
D070
D070
D070
D070
D071
D071
D071
D071
D071
D071
D072
D072
D072
D072
D072
D072
D073
D073
D073
D073
D073
D073
D074
D074
D074
D074
D074
D074
D075
D076
D077
Plnm
P01
P02
P03
P04
P05
P06
P07
P08
P01
P02
P03
P04
P05
P06
P07
P08
P01
P02
P03
P04
P05
P06
P07
P08
P01
P02
P03
P04
P05
P06
P07
P08
L03
L04
L05
L07
L03
L04
L05
L07
L02
L04
L05
L06
L07
L08
L02
L04
L05
L06
L07
L08
L01
L02
L04
L06
L07
L08
L01
L02
L04
L06
L07
L08
L01
L02
L04
L06
L07
L07
L01
L01
L01
Vol
1.2967
1.4608
1.6346
1.7418
1.8326
2.0351
2.2716
2.8010
1.2967
1.4608
1.6346
1.7418
1.8325
2.0350
2.2716
2.8010
1.2967
1.4608
1.6346
1.7418
1.8325
2.0350
2.2716
2.8010
1.2967
1.4608
1.6346
1.7418
1.8325
2.0350
2.2716
2.8010
12.6519
13.6812
16.2352
18.2915
12.6519
13.6812
16.2352
18.2915
11.0960
13.6812
16.2352
16.2742
18.2915
20.0336
11.0960
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
13.6812
16.2742
18.2915
20.0336
7.4734
11.0960
13.6812
16.2742
18.2915
20.0336
7.4734
11.0960
13.6812
16.2742
18.2915
18.2915
7.4734
7.4734
7.4734
BellP
11.3
11.3
11.3
11.3
11.3
11.3
11.3
11.3
30.5
30.5
30.5
30.5
30.5
30.5
30.5
30.5
38.9
38.9
38.9
38.9
38.9
38.9
38.9
38.9
26.5
26.5
26.5
26.5
26.5
26.5
26.5
26.5
29.2
29.2
29.2
29.2
27.8
27.8
27.8
27.8
13.9
13.9
13.9
13.9
13.9
13.9
18.8
18.8
18.8
18.8
18.8
18.8
24.5
24.5
24.5
24.5
24.5
24.5
22.7
22.7
22.7
22.7
22.7
22.7
11.2
11.2
11.2
11.2
11.2
11.2
25.0
23.3
13.5
DWGT
21.4
21.4
21.4
21.4
21.4
21.4
21.4
21.4
24.1
24.1
24.1
24.1
24.1
24.1
24.1
24.1
23.9
23.9
23.9
23.9
23.9
23.9
23.9
23.9
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.4
22.4
22.4
22.4
21.9
21.9
21.9
21.9
22.9
22.9
22.9
22.9
22.9
22.9
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.6
22.8
22.8
22.8
22.8
22.8
22.8
23.2
23.2
23.2
23.2
23.2
23.2
23.5
24.2
23.8
DWGMassNos
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,2,3,7,8,13
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,7
1,7,8
DWGP
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.13
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.14
737.15
737.15
737.15
737.15
737.15
737.15
737.15
737.15
99.83
99.83
99.83
99.83
99.83
99.83
99.83
99.83
99.81
99.81
99.81
99.81
99.81
99.81
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.81
99.81
99.81
99.81
99.81
99.81
99.82
145.78
211.45
BathT
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.29
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
µ-MolesCO2
52.1403
58.7406
65.7288
70.0402
73.6900
81.8309
91.3426
112.628
52.1397
58.7401
65.7281
70.0376
73.6877
81.8301
91.3418
112.629
52.1402
58.7408
65.7288
70.0383
73.6885
81.8310
91.3428
112.630
52.1406
58.7412
65.7293
70.0388
73.6890
81.8316
91.3435
112.630
68.5947
74.1749
88.0222
99.1708
68.5947
74.1750
88.0222
99.1708
60.1497
74.1633
88.0083
88.2195
99.1552
108.599
60.1529
74.1673
88.0130
88.2242
99.1605
108.605
40.5146
60.1535
74.1680
88.2250
99.1615
108.606
40.5137
60.1522
74.1664
88.2232
99.1594
108.603
40.5088
60.1449
74.1574
88.2125
99.1474
99.1474
40.5145
59.1878
85.8863
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 7/8
Date
20070913
20070921
20070921
20070921
20070921
20071009
20071009
20071009
20071009
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080129
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080130
20080131
20080131
20080131
20080131
20080131
20080131
20080131
20080131
20080214
20080414
20080421
20080622
20081201
20081201
20081201
20081201
20081201
20081201
20081201
20081201
20081202
20081202
20081202
20081202
20081202
20081202
20081202
20081202
20081202
20081202
20081202
20081202
Fill
D078
D079
D080
D081
D082
D083
D084
D085
D086
D087
D087
D087
D087
D087
D087
D087
D087
D088
D088
D088
D088
D088
D088
D088
D088
D089
D089
D089
D089
D089
D089
D089
D089
D090
D090
D090
D090
D090
D090
D090
D090
D091
D091
D091
D091
D091
D091
D091
D091
E001
E002
E003
E004
D092
D092
D092
D092
D092
D092
D092
D092
D093
D093
D093
D093
D093
D093
D093
D093
D094
D094
D094
D094
Plnm
L01
L01
L01
L01
L01
L02
L02
L02
L02
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
L02
P09
P11
P12
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
Vol
7.4734
7.4734
7.4734
7.4734
7.4734
11.0960
11.0960
11.0960
11.0960
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
11.0960
51.4338
270.6862
1011.0850
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
BellP
15.0
15.4
17.8
22.1
24.5
17.4
19.6
15.0
14.9
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.7
6.7
6.7
6.7
6.7
6.7
6.7
6.7
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
21.0
27.2
21.0
28.6
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
10.6
10.6
10.6
10.6
10.6
10.6
10.6
10.6
10.1
10.1
10.1
10.1
DWGT
24.0
24.4
24.8
24.6
22.3
24.3
24.0
24.5
24.3
24.6
24.6
24.6
24.6
24.6
24.6
24.6
24.6
24.3
24.3
24.3
24.3
24.3
24.3
24.3
24.3
24.2
24.2
24.2
24.2
24.2
24.2
24.2
24.2
24.1
24.1
24.1
24.1
24.1
24.1
24.1
24.1
23.8
23.8
23.8
23.8
23.8
23.8
23.8
23.8
23.8
24.6
24.7
24.6
23.4
23.4
23.4
23.4
23.4
23.4
23.4
23.4
23.9
23.9
23.9
23.9
23.9
23.9
23.9
23.9
24.1
24.1
24.1
24.1
DWGMassNos
1,7,8,9
1,9,11,12,14
1,7
1,7,8
1,7,8,9
1,9
1,9,11,12,14
1,8,9
1,7,8
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,2,3,4,9
1,2,3,4,9
1,2,3,4,9
1,2,3,7,11,12
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
DWGP
255.23
99.81
145.78
211.45
255.24
80.11
99.81
145.78
211.45
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
736.83
736.83
736.82
601.11
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.82
99.81
99.81
99.81
99.81
99.81
99.81
99.81
99.81
99.80
99.80
99.80
99.80
BathT
22.31
22.30
22.30
22.30
22.30
22.31
22.31
22.31
22.31
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.27
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.31
22.26
22.26
22.26
22.26
22.26
22.26
22.26
22.26
22.26
22.29
22.29
22.28
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
µ-MolesCO2
103.701
40.5102
59.1853
85.8891
103.708
48.2659
60.1496
87.8739
127.518
40.5116
60.1489
68.5831
74.1624
88.0073
88.2184
99.1540
108.597
40.5119
60.1495
68.5838
74.1631
88.0082
88.2193
99.1550
108.599
40.5068
60.1417
68.5750
74.1536
87.9969
88.2080
99.1423
108.585
40.5067
60.1417
68.5749
74.1536
87.9968
88.2079
99.1422
108.585
40.5128
60.1507
68.5852
74.1647
88.0100
88.2211
99.1571
108.601
446.046
2067.40
10880.2
33124.4
40.5131
60.1510
68.5856
74.1652
88.0106
88.2217
99.1577
108.602
40.5086
60.1443
68.5780
74.1569
88.0008
88.2119
99.1467
108.590
40.5084
60.1440
68.5777
74.1566
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A3: Plenum Fills using Dead Weight Gauge (DWG), 1999 to 2008. Page 8/8
Date
20081202
20081202
20081202
20081202
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
20081203
Fill
D094
D094
D094
D094
D095
D095
D095
D095
D095
D095
D095
D095
D096
D096
D096
D096
D096
D096
D096
D096
Plnm
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
L01
L02
L03
L04
L05
L06
L07
L08
Vol
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
7.4734
11.0960
12.6519
13.6812
16.2352
16.2742
18.2915
20.0336
BellP
10.1
10.1
10.1
10.1
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
8.7
DWGT
24.1
24.1
24.1
24.1
24.0
24.0
24.0
24.0
24.0
24.0
24.0
24.0
26.0
26.0
26.0
26.0
26.0
26.0
26.0
26.0
DWGMassNos
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
1,9,11,12,14
DWGP
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
99.80
BathT
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
22.30
µ-MolesCO2
88.0004
88.2115
99.1463
108.589
40.5079
60.1433
68.5769
74.1557
87.9993
88.2104
99.1450
108.588
40.5067
60.1415
68.5748
74.1535
87.9967
88.2078
99.1421
108.584
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A4: CMM Chamber Volume Calibrations Notes. Made by Transfer of CO2 from Plenums.
Data and calculated results are listed for measurements in the CMM of CO2 gas transferred from
plenums into the small manometer. The CMM measurements of mercury heights and temperature
allow calculation of the ratio V/n using the virial equation of state, where V is the volume of the
CMM chamber and n the number of moles of CO2 . When this ratio is multiplied by the moles of CO2
contained in the plenum, as determined by the filling detailed in Tables A1 and A2, the volume of the
CMM chamber results. Notes on the columns in the table follow.
Date
Date of the measurement, in YYYYMMDD.
Fill
Designated number of the plenum fill, as listed in Tables A1 and A2.
Plnm
Number of plenum. The original set of plenums with prefix P and the set of larger
plenums with prefix L (from 7 to 20 cc in volume), were used to calibrate chambers in
the ”small” CMM.
Chmb
Nominal volume of the CMM chamber, in cc.
No
Consecutive number of CMM chamber calibration.
HtVac
Mercury column height, in mm, of the vacuum column #2 of the CMM, asmeasured
with the cathetometer.
HtSmp
Mercury column height, in mm, of the sample column #4 of the CMM, asmeasured
with the cathetometer
MnCor
Correction applied to the mercury column measurements to account fordiffering sizes
of the glass tubing on the vacuum and sample columnsand for non-level swing of the
cathetometer telescope. Corrections, inmm, were determined experimentally.
Temperature, in C, for the measurement as read on thermometer No. 6112near the 4
cc chamber, and corrected according to its time-dependenceover the history of measurements.
Temp
µ-MolesCO2
Amount of CO2 in the plenum, in micromoles (from Tables 3 and 4).
V/n
Ratio calculated from CMM measurement (cc/mole).
ChmbVol
Calculated volume of CMM chamber, in cc.
Flg
Flag column.
Table A4: CMM Chamber Volume Calibrations, by Transfer of CO2 from Plenums. Page 1/6
Date
19740621
19740621
19740621
19740621
19740626
19740626
19740627
19740627
19740627
19740627
19740627
19740628
19740628
19740628
19740709
19740709
19740710
19740710
19740729
19740730
19740730
19740730
19740730
19740730
19740730
19740801
19740801
19740801
19740802
19740807
19740807
19740808
19740808
19740808
19740808
19740809
19740809
19851024
19851024
19851024
19851024
19851025
19851025
19851025
19851025
19851030
19851030
19851030
19851030
19851031
19851031
19851031
19851031
19851031
19851031
19860121
19860121
19860122
19860122
19860122
19860122
19860122
19860122
19860123
19860123
19860124
19860124
19860124
19860124
19860124
19860124
19860124
19860124
Fill
B001
B001
B002
B002
B003
B003
B004
B004
B004
B004
B004
B004
B004
B004
B005
B005
B006
B006
B007
B008
B008
B009
B009
B010
B010
B011
B011
B012
B012
B013
B013
B014
B014
B015
B015
B016
B016
B017
B017
B018
B018
B019
B019
B020
B020
B021
B021
B022
B022
B023
B023
B024
B024
B025
B025
B026
B026
B027
B027
B028
B028
B029
B029
B030
B030
B031
B031
B032
B032
B033
B033
B034
B034
Plnm
P07
P07
P01
P01
P01
P01
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P01
P01
P07
P01
P01
P01
P01
P07
P07
P07
P07
P01
P01
P03
P03
P05
P05
P04
P04
P01
P01
P01
P01
P07
P07
P01
P01
P07
P07
P01
P01
P03
P03
P04
P04
P05
P05
P07
P07
P01
P01
P02
P02
P03
P03
P06
P06
P07
P07
P01
P01
P03
P03
P05
P05
P07
P07
Chmb
4
4
4
4
4
4
4
16
16
4
16
4
16
16
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
No.
1
1
2
2
3
3
4
4
4
4
4
4
4
4
5
5
6
6
7
8
8
9
9
10
10
11
11
12
12
13
13
14
14
15
15
16
16
17
17
18
18
19
19
20
20
21
21
22
22
23
23
24
24
25
25
26
26
27
27
28
28
29
29
30
30
31
31
32
32
33
33
34
34
HtVac
827.298
826.917
631.725
631.515
631.522
631.485
826.306
418.110
418.100
826.096
418.070
826.475
418.079
418.062
827.928
827.923
633.268
633.304
826.286
630.979
630.953
631.683
631.513
826.460
826.322
827.544
827.421
631.828
631.954
699.303
699.182
738.966
738.667
719.972
719.888
631.340
631.257
637.122
637.252
833.848
834.170
637.272
637.292
833.337
833.336
636.956
637.071
705.414
705.606
727.812
727.800
745.868
745.880
834.332
834.346
636.946
637.048
670.337
670.418
705.354
705.400
786.092
786.106
833.883
833.700
638.445
638.440
706.632
706.596
746.440
746.436
834.976
834.988
HtSmp
370.618
370.566
370.605
370.580
370.838
370.820
370.820
309.656
309.654
370.792
309.648
370.830
309.650
309.650
370.798
370.804
370.806
370.818
370.798
370.822
370.818
370.800
370.800
370.788
370.791
371.094
371.064
371.018
371.058
371.073
371.074
371.084
371.076
371.044
371.036
371.070
371.060
374.874
374.860
374.860
374.872
374.885
374.886
374.894
374.886
374.903
374.906
374.887
374.914
374.910
374.887
374.884
374.886
374.872
374.892
374.830
374.847
374.854
374.846
374.848
374.824
374.866
374.834
374.858
374.856
374.834
374.846
374.872
374.859
374.831
374.829
374.836
374.824
MnCor
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.014
-0.014
-0.366
-0.014
-0.366
-0.014
-0.014
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.366
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
-0.340
Temp
20.50
20.36
20.24
20.03
19.72
19.69
19.93
19.80
19.84
19.86
19.82
20.09
19.88
19.88
20.83
20.79
20.87
20.87
19.56
19.24
19.16
19.35
19.27
19.02
18.98
19.69
19.60
19.43
19.48
19.92
19.83
19.68
19.51
18.99
18.94
19.56
19.55
21.14
21.26
21.48
21.63
21.92
21.94
21.92
21.91
21.32
21.42
21.68
21.83
22.10
22.09
22.07
22.10
22.14
22.15
21.32
21.42
21.62
21.65
21.67
21.71
21.72
21.74
21.78
21.68
21.80
21.78
21.69
21.66
21.46
21.48
21.48
21.49
µ-MolesCO2
94.4635
94.4635
53.9302
53.9302
53.8959
53.8959
94.4036
94.4036
94.4036
94.4036
94.4036
94.4036
94.4036
94.4036
94.7677
94.7677
54.1038
54.1038
94.5036
53.9530
53.9530
54.0820
54.0820
94.7294
94.7294
94.6889
94.6889
54.0588
54.0588
67.9395
67.9395
76.2449
76.2449
72.4948
72.4948
53.8977
53.8977
53.9677
53.9677
94.5344
94.5344
53.8207
53.8207
94.2770
94.2770
53.8882
53.8882
67.9291
67.9291
72.4491
72.4491
76.2065
76.2065
94.3952
94.3952
53.8998
53.8998
60.7171
60.7171
67.9438
67.9438
84.5872
84.5872
94.4157
94.4157
54.1025
54.1025
68.1993
68.1993
76.5090
76.5090
94.7707
94.7707
V/N
40200.6
40209.3
70380.4
70377.1
70366.0
70363.6
40223.1
169148.
169185.
40229.1
169210.
40232.4
169236.
169263.
40208.8
40204.0
70178.6
70172.2
40168.9
70386.6
70372.2
70218.2
70243.7
40073.8
40080.4
40102.8
40097.9
70258.1
70247.6
55883.2
55885.9
49796.6
49805.4
52380.2
52382.1
70437.5
70454.8
70296.1
70287.8
40136.6
40131.1
70456.0
70456.0
40248.4
40246.3
70394.1
70389.3
55841.8
55844.0
52368.8
52365.3
49802.4
49806.5
40190.8
40192.8
70377.1
70379.5
62473.7
62461.5
55843.2
55839.4
44855.7
44853.9
40176.8
40178.2
70097.5
70096.9
55635.5
55633.3
49609.2
49613.0
40035.7
40035.1
ChmbVol
3.79749
3.79831
3.79563
3.79545
3.79244
3.79231
3.79721
15.9682
15.9717
3.79777
15.9741
3.79808
15.9765
15.9790
3.81050
3.81004
3.79693
3.79658
3.79611
3.79757
3.79679
3.79754
3.79892
3.79617
3.79679
3.79729
3.79683
3.79807
3.79750
3.79668
3.79686
3.79674
3.79741
3.79729
3.79743
3.79642
3.79735
3.79372
3.79327
3.79429
3.79377
3.79199
3.79199
3.79450
3.79430
3.79341
3.79315
3.79328
3.79343
3.79407
3.79382
3.79527
3.79558
3.79382
3.79401
3.79331
3.79344
3.79322
3.79248
3.79420
3.79394
3.79422
3.79407
3.79332
3.79345
3.79245
3.79242
3.79430
3.79415
3.79555
3.79584
3.79421
3.79415
Flg
00
00
00
00
01
01
00
00
00
00
00
00
00
00
02
02
00
00
00
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
02
02
02
02
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
02
02
00
00
Table A4: CMM Chamber Volume Calibrations, by Transfer of CO2 from Plenums. Page 2/6
Date
19860127
19880219
19880219
19880222
19880222
19880223
19880223
19880223
19880224
19880224
19880224
19880224
19880224
19880224
19880225
19880225
19880225
19880225
19880225
19880225
19880226
19880226
19880226
19880226
19880226
19880226
19880302
19880302
19880302
19880302
19880303
19880303
19880303
19880303
19880303
19880303
19900209
19900209
19900209
19900209
19900209
19900209
19900209
19900209
19900212
19900212
19900213
19900213
19900213
19900213
19900213
19900213
19900215
19900215
19900215
19900215
19900215
19900215
19900216
19900216
19900216
19900216
19900216
19900216
19900216
19901004
19901004
19901005
19901005
19901005
19901005
19901005
19901005
Fill
B035
B036
B036
B037
B037
B038
B038
B038
B039
B039
B040
B040
B041
B041
B042
B042
B043
B043
B044
B044
B045
B045
B046
B046
B047
B047
B048
B048
B049
B049
B050
B050
B051
B051
B052
B052
B053
B053
B054
B054
B055
B055
B055
B055
B056
B056
B057
B057
B058
B058
B058
B058
B059
B059
B060
B060
B061
B061
B062
B062
B063
B063
B064
B064
B064
B065
B065
B066
B066
B067
B067
B068
B068
Plnm
P04
P01
P01
P07
P07
P01
P01
P01
P02
P02
P03
P03
P06
P06
P07
P07
P07
P07
P06
P06
P03
P03
P02
P02
P01
P01
P01
P01
P02
P02
P04
P04
P05
P05
P07
P07
P01
P01
P07
P07
P09
P09
P09
P09
P01
P01
P07
P07
P09
P09
P09
P09
P01
P01
P07
P07
P02
P02
P03
P03
P06
P06
P09
P09
P09
P01
P01
P07
P07
P02
P02
P03
P03
Chmb
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
64
64
250
250
4
4
4
4
64
64
250
250
4
4
4
4
4
4
4
4
4
4
250
250
64
4
4
4
4
4
4
4
4
No.
35
36
36
37
37
38
38
38
39
39
40
40
41
41
42
42
43
43
44
44
45
45
46
46
47
47
48
48
49
49
50
50
51
51
52
52
53
53
54
54
55
55
55
55
56
56
57
57
58
58
58
58
59
59
60
60
61
61
62
62
63
63
64
64
64
65
65
66
66
67
67
68
68
HtVac
727.628
637.473
637.585
834.938
835.898
636.999
637.050
637.097
669.866
669.906
704.841
705.011
785.696
785.803
833.400
833.537
833.090
833.220
785.245
785.558
704.916
704.990
670.058
670.064
637.078
637.148
635.978
636.080
669.190
669.329
726.209
726.314
744.208
744.376
832.530
832.589
638.096
638.127
834.755
835.097
855.163
855.408
304.780
304.689
637.248
637.097
833.224
833.423
853.540
853.887
304.299
304.347
636.083
636.189
831.744
831.856
669.296
669.432
704.165
704.280
785.062
785.215
304.058
304.076
852.477
638.148
638.156
834.889
835.051
671.334
671.458
706.425
706.500
HtSmp
374.836
374.830
374.814
374.822
374.780
374.824
374.814
374.791
374.814
374.820
374.828
374.772
374.813
374.777
374.835
374.826
374.822
374.800
374.796
374.788
374.816
374.822
374.824
374.800
374.795
374.796
374.843
374.842
374.832
374.838
374.848
374.834
374.832
374.879
374.848
374.851
375.108
375.090
375.054
375.088
232.413
232.419
182.502
182.432
375.128
375.113
375.100
375.104
232.458
232.442
182.372
182.392
375.088
375.078
375.086
375.060
375.056
375.052
375.067
375.064
375.079
375.079
182.416
182.430
232.460
375.285
375.277
375.256
375.266
375.235
375.225
375.244
375.234
MnCor
-0.340
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.294
-0.313
-0.313
-0.313
-0.313
0.000
0.000
0.000
0.000
-0.313
-0.313
-0.313
-0.313
0.000
0.000
0.000
0.000
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
0.000
0.000
0.000
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
Temp
21.07
21.13
21.21
21.66
22.22
21.23
21.28
21.31
21.05
21.12
21.23
21.30
21.37
21.43
21.39
21.49
21.35
21.40
21.47
21.48
21.33
21.37
21.47
21.50
21.58
21.60
20.64
20.74
21.01
21.08
21.31
21.38
21.35
21.41
21.38
21.43
21.66
21.72
21.76
21.83
21.77
21.87
21.95
21.99
21.51
21.60
21.63
21.73
21.83
21.97
22.03
22.06
20.84
20.94
21.07
21.16
21.24
21.33
21.23
21.35
21.66
21.72
21.67
21.70
21.73
22.07
22.15
22.20
22.30
22.34
22.40
22.46
22.52
µ-MolesCO2
72.7365
54.0594
54.0594
94.6961
94.6961
53.9339
53.9339
53.9339
60.7561
60.7561
67.9871
67.9871
84.6412
84.6412
94.4764
94.4764
94.4334
94.4334
84.6027
84.6027
67.9562
67.9562
60.7285
60.7285
53.9094
53.9094
53.8304
53.8304
60.6395
60.6395
72.3645
72.3645
76.1195
76.1195
94.2950
94.2950
53.9904
53.9904
94.5762
94.5762
2141.05
2141.05
2141.05
2141.05
53.8478
53.8478
94.3264
94.3264
2135.40
2135.40
2135.40
2135.40
53.7667
53.7667
94.1842
94.1842
60.5682
60.5682
67.7765
67.7765
84.3792
84.3792
2132.18
2132.18
2132.18
53.8751
53.8751
94.3746
94.3746
60.6906
60.6906
67.9134
67.9134
V/N
52191.1
70176.3
70162.3
40060.6
40053.9
70327.4
70323.7
70312.4
62428.5
62436.9
55831.6
55807.4
44832.4
44826.5
40157.3
40159.0
40177.7
40171.6
44896.2
44862.6
55837.0
55833.5
62484.2
62484.7
70386.8
70373.3
70458.3
70455.9
62567.0
62554.4
52443.9
52439.4
49885.1
49879.5
40233.7
40236.1
70221.7
70223.8
40112.3
40095.5
29557.6
29556.9
151152.
151199.
70417.0
70476.4
40232.1
40229.5
29643.7
29641.4
151630.
151612.
70551.1
70545.2
40280.1
40281.1
62647.1
62637.5
55989.8
55993.7
44979.7
44972.6
151790.
151802.
29684.1
70360.9
70376.9
40183.3
40184.3
62501.1
62486.3
55884.8
55882.5
ChmbVol
3.79620
3.79369
3.79293
3.79358
3.79295
3.79303
3.79283
3.79222
3.79291
3.79342
3.79583
3.79418
3.79467
3.79417
3.79392
3.79408
3.79412
3.79354
3.79834
3.79550
3.79447
3.79423
3.79457
3.79460
3.79451
3.79378
3.79280
3.79267
3.79403
3.79327
3.79508
3.79475
3.79723
3.79680
3.79384
3.79406
3.79130
3.79141
3.79367
3.79208
63.2843
63.2828
323.623
323.725
3.79180
3.79500
3.79495
3.79470
63.3011
63.2960
323.791
323.751
3.79330
3.79298
3.79375
3.79384
3.79442
3.79384
3.79479
3.79506
3.79535
3.79475
323.644
323.668
63.2918
3.79070
3.79156
3.79228
3.79238
3.79323
3.79233
3.79533
3.79517
Flg
02
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
02
02
02
02
00
00
00
00
00
00
00
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A4: CMM Chamber Volume Calibrations, by Transfer of CO2 from Plenums. Page 3/6
Date
19901005
19901005
19901006
19901006
19901006
19901006
19901009
19901009
19901009
19901009
19901009
19901009
19901010
19901010
19901010
19901010
19931013
19931013
19931013
19931013
19931014
19931014
19931015
19931015
19940201
19940201
19940201
19940201
19940201
19940201
19940202
19940202
19940202
19940202
19940203
19940203
19940203
19940203
19940203
19940203
19940203
19940203
19940208
19940208
19940208
19940208
19940208
19940208
19940208
19940208
19940209
19940209
19940209
19940209
19940209
19940209
19981210
19981210
19981211
19981211
19981214
19981214
19981214
19981214
19981215
19981215
19981215
19981215
19981216
19981216
19981216
19990106
19990106
Fill
B069
B069
B070
B070
B071
B071
B072
B072
B073
B073
B074
B074
B075
B075
B076
B076
B077
B077
B078
B078
B079
B079
B079
B079
B080
B080
B081
B081
B082
B082
B083
B083
B084
B084
B085
B085
B086
B086
B087
B087
B087
B087
B088
B088
B089
B089
B090
B090
B091
B091
B092
B092
B093
B093
B093
B093
B094
B094
B095
B095
B096
B096
B097
B097
B098
B098
B099
B099
B100
B100
B100
B101
B101
Plnm
P06
P06
P07
P07
P01
P01
P03
P03
P01
P01
P07
P07
P02
P02
P06
P06
P01
P01
P07
P07
P09
P09
P09
P09
P01
P01
P07
P07
P02
P02
P03
P03
P06
P06
P01
P01
P07
P07
P09
P09
P09
P09
P01
P01
P07
P07
P02
P02
P03
P03
P06
P06
P09
P09
P09
P09
P01
P01
P07
P07
P01
P01
P02
P02
P03
P03
P06
P06
P07
P07
P07
P02
P02
Chmb
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
64
64
250
250
4
4
4
4
4
4
4
4
4
4
4
4
4
4
64
64
250
250
4
4
4
4
4
4
4
4
4
4
64
64
250
250
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
No.
69
69
70
70
71
71
72
72
73
73
74
74
75
75
76
76
77
77
78
78
79
79
79
79
80
80
81
81
82
82
83
83
84
84
85
85
86
86
87
87
87
87
88
88
89
89
90
90
91
91
92
92
93
93
93
93
94
94
95
95
96
96
97
97
98
98
99
99
100
100
100
101
101
HtVac
787.442
787.725
833.783
833.887
637.510
637.516
705.597
705.829
637.878
637.988
834.522
834.506
670.800
671.010
787.027
787.039
637.849
637.884
834.444
834.444
851.945
852.012
303.885
303.858
639.217
639.224
836.846
837.086
672.645
672.684
707.851
707.987
788.806
789.300
637.954
637.987
834.727
834.981
855.740
855.745
304.653
304.621
634.582
634.514
828.360
828.434
667.016
667.113
702.052
702.155
781.010
781.308
846.706
846.798
302.939
302.974
640.728
640.808
838.767
839.054
638.566
638.696
671.985
672.065
707.174
707.341
788.677
788.880
835.716
835.680
836.118
672.224
672.300
HtSmp
375.232
375.262
375.241
375.218
375.261
375.218
375.184
375.204
375.204
375.215
375.220
375.194
375.171
375.186
375.208
375.188
375.226
375.196
375.213
375.204
232.552
232.499
182.512
182.499
375.064
375.043
375.051
375.099
375.065
375.052
375.064
375.041
375.048
375.046
375.071
375.039
375.066
375.058
232.421
232.410
182.372
182.306
375.080
375.060
375.070
375.041
375.078
375.059
375.048
375.072
375.090
375.084
232.400
232.404
182.374
182.372
374.999
374.976
374.952
374.964
374.982
374.982
374.982
374.978
374.953
374.980
374.961
374.978
374.979
374.952
374.969
374.991
374.990
MnCor
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.313
-0.288
-0.288
-0.288
-0.288
0.000
0.000
0.000
0.000
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
0.000
0.000
0.000
0.000
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
-0.288
0.000
0.000
0.000
0.000
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
Temp
22.52
22.61
22.38
22.44
22.47
22.50
21.85
22.00
22.17
22.28
22.32
22.33
21.99
22.27
22.48
22.54
21.78
21.82
21.88
21.91
21.76
21.83
21.61
21.64
21.59
21.64
21.78
21.83
21.66
21.69
21.68
21.76
21.78
21.86
21.70
21.81
21.95
22.11
22.25
22.32
22.42
22.42
22.09
22.13
21.96
22.02
22.13
22.13
22.26
22.32
21.95
22.14
22.13
22.20
22.33
22.37
22.35
22.41
21.99
22.14
22.01
22.12
22.33
22.39
22.32
22.46
22.75
22.77
22.29
22.40
22.53
22.52
22.59
µ-MolesCO2
84.5497
84.5497
94.1083
94.1083
53.7231
53.7231
67.8812
67.8812
53.8496
53.8496
94.3299
94.3299
60.6619
60.6619
84.5096
84.5096
53.8482
53.8482
94.3287
94.3287
2135.53
2135.53
2135.53
2135.53
54.2372
54.2372
95.0104
95.0104
61.0995
61.0995
68.3703
68.3703
85.1187
85.1187
53.9223
53.9223
94.4587
94.4587
2138.48
2138.48
2138.48
2138.48
53.1693
53.1693
93.1397
93.1397
59.8965
59.8965
67.0242
67.0242
83.4428
83.4428
2108.62
2108.62
2108.62
2108.62
54.4082
54.4082
95.3122
95.3122
54.0366
54.0366
60.8749
60.8749
68.1182
68.1182
84.8052
84.8052
94.6612
94.6612
94.6612
60.8692
60.8692
V/N
44875.9
44862.7
40305.4
40302.8
70627.5
70621.8
55892.5
55886.6
70436.9
70438.2
40229.7
40230.3
62522.3
62543.7
44912.2
44918.3
70343.7
70336.4
40169.0
40172.6
29717.6
29719.3
152095.
152129.
69887.3
69892.4
39930.7
39921.2
62030.6
62026.4
55452.9
55442.3
44584.6
44543.8
70253.7
70263.9
40141.4
40141.6
29581.9
29588.7
151403.
151361.
71271.4
71294.7
40709.2
40708.6
63339.9
63314.7
56554.5
56553.0
45476.4
45473.3
30004.8
30008.1
153510.
153485.
69640.1
69628.1
39779.2
39777.1
70122.7
70115.8
62284.1
62280.0
55662.1
55666.5
44736.2
44719.3
40089.2
40105.9
40087.9
62278.3
62277.8
ChmbVol
3.79424
3.79313
3.79307
3.79283
3.79433
3.79402
3.79405
3.79365
3.79300
3.79307
3.79486
3.79492
3.79272
3.79402
3.79551
3.79603
3.78788
3.78749
3.78909
3.78943
63.4629
63.4666
324.804
324.877
3.79049
3.79077
3.79383
3.79293
3.79004
3.78978
3.79133
3.79061
3.79498
3.79151
3.78824
3.78879
3.79170
3.79172
63.2604
63.2748
323.772
323.682
3.78945
3.79069
3.79164
3.79159
3.79384
3.79233
3.79052
3.79042
3.79468
3.79442
63.2687
63.2757
323.695
323.642
3.78899
3.78834
3.79144
3.79124
3.78919
3.78882
3.79154
3.79129
3.79160
3.79190
3.79386
3.79243
3.79489
3.79647
3.79477
3.79083
3.79080
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
01
00
00
00
Table A4: CMM Chamber Volume Calibrations, by Transfer of CO2 from Plenums. Page 4/6
Date
19990107
19990107
19990107
19990107
19990107
19990107
19990107
19990107
19990113
19990113
19990113
19990113
19990114
19990114
19990114
19990114
19990114
19990114
19990121
19990121
19990121
19990121
19990122
19990122
19990122
19990122
19990122
19990122
20050104
20050104
20050104
20050105
20050105
20050105
20050105
20050105
20050106
20050106
20050201
20050202
20050202
20050202
20050202
20050202
20050315
20050315
20050315
20050315
20050317
20050317
20050606
20050606
20050607
20050607
20050607
20050607
20050721
20050721
20050721
20050721
20050722
20050722
20050722
20050722
20050908
20050908
20050908
20050908
20050909
20050909
20051019
20051019
20051019
Fill
B102
B102
B103
B103
B104
B104
B105
B105
B106
B106
B107
B107
B108
B108
B109
B109
B110
B110
B111
B111
B112
B112
B113
B113
B114
B114
B115
B115
D043
D043
D046
D046
D047
D047
D046
D046
D047
D047
D048
D048
D047
D047
D045
D045
D044
D044
D043
D043
D044
D044
D043
D043
D042
D042
D047
D047
D053
D053
D055
D055
D052
D052
D051
D051
D054
D054
D053
D053
D055
D055
D054
D054
D055
Plnm
P07
P07
P01
P01
P06
P06
P03
P03
P01
P01
P07
P07
P02
P02
P06
P06
P03
P03
P01
P01
P07
P07
P02
P02
P06
P06
P03
P03
P07
P07
P02
P02
P06
P06
P01
P01
P03
P03
P07
P07
P02
P02
P06
P06
P01
P01
P03
P03
P06
P06
P02
P02
P03
P03
P07
P07
P02
P02
P01
P01
P07
P07
P06
P06
P01
P01
P03
P03
P07
P07
P02
P02
P03
Chmb
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
No.
102
102
103
103
104
104
105
105
106
106
107
107
108
108
109
109
110
110
111
111
112
112
113
113
114
114
115
115
116
116
117
117
118
118
119
119
120
120
121
121
122
122
123
123
124
124
125
125
126
126
127
127
128
128
129
129
130
130
131
131
132
132
133
133
134
134
135
135
136
136
137
137
138
HtVac
836.028
836.136
638.930
639.062
788.644
788.850
707.442
707.602
639.326
639.518
837.558
837.642
672.691
672.788
789.648
789.768
708.470
708.490
639.787
639.887
838.038
838.186
673.146
673.152
789.904
789.960
708.675
708.741
818.356
818.346
659.381
659.297
771.892
772.044
627.170
627.276
693.132
693.276
818.648
817.654
658.827
659.004
771.707
771.918
627.854
627.753
694.270
694.542
772.320
772.303
660.160
660.407
694.353
694.384
819.838
820.196
659.784
659.830
627.582
627.647
819.649
819.540
772.661
772.731
627.426
627.440
693.773
693.886
819.012
818.946
659.644
659.686
693.747
HtSmp
375.042
374.972
374.978
374.972
374.993
375.004
374.964
375.000
375.035
375.059
374.977
374.997
374.994
374.960
374.996
374.999
375.027
375.014
375.116
375.132
375.082
375.089
375.164
375.091
375.115
375.117
375.106
375.110
371.477
371.490
371.480
371.492
371.478
371.496
371.516
371.493
371.490
371.524
371.470
371.438
371.438
371.392
371.436
371.448
371.502
371.476
371.491
371.486
371.482
371.486
371.494
371.474
371.504
371.482
371.466
371.454
371.483
371.458
371.582
371.466
371.475
371.474
371.468
371.440
371.488
371.454
371.482
371.481
371.491
371.458
371.428
371.460
371.460
MnCor
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.208
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
Temp
22.46
22.55
22.76
22.78
22.92
22.92
22.95
22.95
22.40
22.48
22.66
22.70
22.42
22.52
22.76
22.82
22.92
22.93
22.33
22.42
22.65
22.71
22.41
22.48
22.65
22.70
22.81
22.82
23.29
23.34
23.30
23.14
23.22
23.32
23.22
23.27
23.05
23.16
23.52
22.88
22.93
23.07
23.32
23.46
24.06
24.02
24.15
24.31
23.53
23.54
24.11
24.41
24.27
24.29
24.42
24.58
24.06
24.10
24.15
24.23
24.25
24.24
24.13
24.17
23.97
23.98
23.96
24.01
24.04
24.05
23.86
23.88
23.86
µ-MolesCO2
94.6525
94.6525
54.0316
54.0316
84.7973
84.7973
68.1119
68.1119
54.1287
54.1287
94.8225
94.8225
60.9786
60.9786
84.9496
84.9496
68.2342
68.2342
54.1743
54.1743
94.9024
94.9024
61.0300
61.0300
85.0212
85.0212
68.2918
68.2918
91.3750
91.3750
58.7607
58.7607
81.8597
81.8597
52.1585
52.1585
65.7520
65.7520
91.3745
91.3745
58.7611
58.7611
81.8598
81.8598
52.1585
52.1585
65.7524
65.7524
81.8591
81.8591
58.7614
58.7614
65.7525
65.7525
91.3745
91.3745
58.7366
58.7366
52.1374
52.1374
91.3372
91.3372
81.8256
81.8256
52.1368
52.1368
65.7245
65.7245
91.3370
91.3370
58.7364
58.7364
65.7250
V/N
40092.0
40089.5
70213.2
70181.5
44770.5
44749.4
55744.7
55723.9
70032.5
70008.0
39982.1
39982.3
62158.7
62153.4
44636.5
44633.4
55577.0
55573.5
69914.1
69914.5
39948.1
39944.5
62096.8
62095.9
44604.1
44606.2
55533.9
55525.6
41491.1
41500.6
64494.3
64479.0
46311.8
46312.9
72632.5
72608.7
57658.5
57661.4
41497.5
41491.8
64524.0
64506.1
46345.0
46345.1
72651.6
72662.6
57681.1
57664.4
46314.0
46318.1
64509.0
64518.2
57693.2
57687.8
41520.0
41509.4
64579.3
64572.5
72774.8
72743.9
41513.1
41521.6
46372.3
46367.5
72745.7
72734.6
57729.3
57719.1
41542.6
41547.2
64552.1
64554.5
57709.4
ChmbVol
3.79481
3.79457
3.79373
3.79202
3.79642
3.79463
3.79688
3.79546
3.79077
3.78944
3.79120
3.79122
3.79035
3.79003
3.79185
3.79159
3.79225
3.79201
3.78755
3.78757
3.79117
3.79083
3.78977
3.78971
3.79229
3.79247
3.79251
3.79194
3.79125
3.79212
3.78973
3.78883
3.79107
3.79116
3.78840
3.78716
3.79116
3.79135
3.79181
3.79129
3.79150
3.79045
3.79379
3.79380
3.78940
3.78997
3.79267
3.79157
3.79122
3.79156
3.79064
3.79118
3.79347
3.79312
3.79387
3.79290
3.79317
3.79277
3.79429
3.79268
3.79169
3.79247
3.79444
3.79405
3.79273
3.79215
3.79423
3.79356
3.79438
3.79480
3.79156
3.79170
3.79295
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
01
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A4: CMM Chamber Volume Calibrations, by Transfer of CO2 from Plenums. Page 5/6
Date
20051019
20051020
20051020
20060111
20060111
20060111
20060112
20060112
20060112
20060112
20060428
20060428
20060619
20060619
20060619
20060619
20060823
20060823
20060823
20060824
20060824
20060824
20061204
20061204
20061204
20061204
20061205
20061205
20070308
20070308
20070309
20070309
20070309
20080108
20080109
20080109
20080109
20080109
20080109
20080109
20080110
20080110
20080110
20080111
20080111
20080215
20080219
20080219
20080219
20080220
20080220
20080220
20080220
20080313
20080313
20080313
20080314
20080415
20080415
20080415
20080415
20080416
20080416
20080416
20080416
20080422
20080422
20080422
20080422
20080520
20080520
20080520
20080521
Fill
D055
D053
D053
D056
D056
D056
D057
D057
D058
D058
D056
D056
D059
D059
D058
D058
D059
D059
D057
D057
D054
D054
D062
D062
D064
D064
D063
D063
D064
D064
D064
D062
D062
D065
D065
D065
D065
D065
D065
D065
D065
D065
D067
D067
D067
E001
E001
E001
E001
E001
E001
E001
E001
D087
D087
D091
D091
E002
E002
E002
E002
E002
E002
E002
E002
E003
E003
E003
E003
D090
D090
D088
D088
Plnm
P03
P06
P06
P07
P07
P07
P01
P01
P03
P03
P02
P02
P03
P03
P06
P06
P01
P01
P02
P02
P07
P07
P01
P01
P03
P03
P06
P06
P02
P02
P02
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P07
P02
P02
P02
L02
L02
L02
L02
L02
L02
L02
L02
L02
L02
L06
L06
P09
P09
P09
P09
P09
P09
P09
P09
P11
P11
P11
P11
L04
L04
L05
L05
Chmb
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
16
16
4
4
16
16
4
4
4
16
16
64
64
16
16
64
64
4
4
4
4
64
64
250
250
250
250
64
64
250
250
1000
1000
4
4
4
4
No.
138
139
139
140
140
140
141
141
142
142
143
143
144
144
145
145
146
146
147
147
148
148
149
149
150
150
151
151
152
152
152
153
153
154
154
154
154
154
154
154
154
154
155
155
155
156
156
156
156
156
156
156
156
157
157
158
158
159
159
159
159
159
159
159
159
160
160
160
160
161
161
162
162
HtVac
693.858
772.802
772.788
818.568
818.912
818.984
626.874
627.006
693.493
693.564
659.732
659.800
694.620
694.660
773.554
773.706
627.298
627.374
659.866
659.828
818.700
818.851
626.170
626.265
692.742
692.848
770.552
770.664
660.092
660.120
659.934
819.080
819.113
816.158
816.006
816.018
416.028
416.022
816.133
816.385
415.911
415.932
657.355
657.358
657.393
826.528
827.606
359.650
359.610
827.373
827.566
359.684
359.719
666.566
666.514
803.833
803.975
834.074
834.109
297.252
297.267
297.214
297.194
833.644
833.810
800.729
800.763
371.730
371.782
735.534
735.395
802.652
801.055
HtSmp
371.428
371.472
371.441
371.442
371.434
371.422
371.449
371.439
371.434
371.456
371.466
371.450
371.464
371.449
371.455
371.470
371.450
371.430
371.422
371.453
371.453
371.422
371.482
371.475
371.484
371.457
371.424
371.424
371.464
371.444
371.464
371.428
371.428
371.416
371.444
371.430
310.302
310.286
371.442
371.420
310.290
310.276
371.404
371.459
371.469
310.320
310.298
228.800
228.753
310.250
310.266
228.772
228.779
371.368
371.386
371.372
371.363
228.744
228.740
178.648
178.670
178.682
178.681
228.713
228.724
178.670
178.642
174.232
174.240
371.412
371.432
371.408
371.420
MnCor
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
0.099
0.099
-0.254
-0.254
0.099
0.099
-0.254
-0.254
-0.254
0.099
0.099
0.079
0.079
0.099
0.099
0.079
0.079
-0.254
-0.254
-0.254
-0.254
0.079
0.079
0.088
0.088
0.088
0.088
0.079
0.079
0.088
0.088
0.143
0.143
-0.254
-0.254
-0.254
-0.254
Temp
23.90
24.07
24.08
23.77
23.88
23.96
23.43
23.55
23.64
23.69
23.95
23.98
24.59
24.65
24.74
24.78
23.79
23.85
24.07
24.00
23.83
23.92
22.53
22.59
22.91
22.98
22.56
22.68
24.32
24.37
24.17
24.07
24.08
22.45
22.14
22.15
22.23
22.28
22.33
22.43
22.04
22.04
22.08
21.91
21.94
22.70
23.34
23.36
23.31
23.22
23.29
23.39
23.52
24.29
24.24
24.25
24.28
23.50
23.54
23.52
23.55
23.38
23.39
23.33
23.42
23.41
23.43
23.38
23.41
24.31
24.18
24.08
23.01
µ-MolesCO2
65.7250
81.8254
81.8254
91.3439
91.3439
91.3439
52.1415
52.1415
65.7302
65.7302
58.7415
58.7415
65.7297
65.7297
81.8326
81.8326
52.1411
52.1411
58.7419
58.7419
91.3360
91.3360
52.1406
52.1406
65.7288
65.7288
81.8313
81.8313
58.7406
58.7406
58.7406
91.3431
91.3431
91.3418
91.3418
91.3418
91.3418
91.3418
91.3418
91.3418
91.3418
91.3418
58.7412
58.7412
58.7412
446.046
446.046
446.046
446.046
446.046
446.046
446.046
446.046
60.1489
60.1489
88.2211
88.2211
2067.40
2067.40
2067.40
2067.40
2067.40
2067.40
2067.40
2067.40
10880.2
10880.2
10880.2
10880.2
74.1536
74.1536
88.0082
88.0082
V/N
57691.9
46346.4
46346.0
41539.2
41522.8
41526.8
72751.6
72742.2
57704.8
57706.4
64561.5
64549.4
57703.6
57706.0
46368.1
46358.8
72724.4
72712.5
64549.2
64548.5
41536.7
41533.1
72728.0
72714.5
57698.0
57688.6
46351.1
46358.1
64565.4
64566.1
64566.2
41534.7
41533.1
41565.0
41535.5
41534.5
174849.
174863.
41551.8
41541.1
174904.
174846.
64651.4
64623.6
64625.0
35797.9
35803.9
141871.
141838.
35801.3
35798.0
141819.
141854.
63117.7
63121.4
43026.6
43016.1
30598.8
30601.2
156600.
156625.
156617.
156647.
30600.3
30602.3
29762.5
29761.7
93947.9
93937.0
51142.0
51140.6
43122.2
43118.6
ChmbVol
3.79180
3.79231
3.79228
3.79435
3.79285
3.79322
3.79338
3.79289
3.79295
3.79305
3.79244
3.79173
3.79284
3.79300
3.79442
3.79366
3.79193
3.79131
3.79174
3.79170
3.79380
3.79347
3.79208
3.79138
3.79242
3.79180
3.79297
3.79354
3.79261
3.79265
3.79266
3.79391
3.79376
3.79662
3.79393
3.79384
15.9710
15.9723
3.79542
3.79444
15.9760
15.9707
3.79770
3.79607
3.79615
15.9675
15.9702
63.2809
63.2662
15.9690
15.9675
63.2577
63.2734
3.79646
3.79668
3.79585
3.79493
63.2600
63.2650
323.754
323.808
323.790
323.853
63.2631
63.2674
323.823
323.814
1022.18
1022.06
3.79236
3.79226
3.79511
3.79479
Flg
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Table A4: CMM Chamber Volume Calibrations, by Transfer of CO2 from Plenums. Page 6/6
Date
20080521
20080521
20080722
20080723
20080723
20080723
20080818
20080818
20080818
20080818
20080819
20080819
20081119
20081119
20081119
20081120
20081120
20081121
20090318
20090318
20090318
20090318
20090319
20090319
20090707
20090707
20090707
20090707
20090708
20090708
20091109
20091109
20091110
20091110
20091110
20091110
20091110
Fill
D089
D089
E004
E004
E004
E004
D090
D090
D089
D089
D091
D091
D090
D090
D091
D091
D091
D091
D094
D094
D093
D093
D095
D095
D092
D092
D094
D094
D093
D093
D092
D092
D095
D095
D092
D092
D092
Plnm
L07
L07
P12
P12
P12
P12
L01
L01
L02
L02
L03
L03
L06
L06
L04
L04
L07
L07
L01
L01
L03
L03
L05
L05
L02
L02
L06
L06
L04
L04
L07
L07
L01
L01
L03
L03
L03
Chmb
4
4
1000
1000
5000
5000
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
No.
163
163
164
164
164
164
165
165
166
166
167
167
168
168
169
169
170
170
171
171
172
172
173
173
174
174
175
175
176
176
177
177
178
178
179
179
179
HtVac
855.030
854.996
771.793
771.378
296.227
296.291
569.644
569.655
665.230
665.216
706.318
706.302
804.748
804.808
736.936
735.890
857.092
856.903
575.704
575.632
710.975
711.190
804.722
804.854
686.214
686.123
821.730
821.842
754.874
754.859
853.272
853.408
569.394
569.467
705.380
705.390
705.390
HtSmp
371.413
371.406
174.144
174.146
174.168
174.164
371.416
371.428
371.416
371.396
371.428
371.414
376.383
376.392
376.366
376.386
376.370
376.388
379.392
379.389
379.422
379.396
379.420
379.394
393.430
393.440
393.426
393.444
393.443
393.440
372.468
372.450
372.448
372.485
372.462
372.453
372.453
MnCor
-0.254
-0.254
0.143
0.143
0.143
0.143
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.254
-0.272
-0.272
-0.272
-0.272
-0.272
-0.272
-0.272
Temp
22.86
22.80
22.29
22.08
22.14
22.26
22.79
22.79
22.77
22.81
22.81
22.81
21.52
21.60
21.53
20.63
21.20
21.04
20.00
19.99
19.99
20.13
20.03
20.14
21.68
21.68
21.57
21.62
22.14
22.17
21.01
21.10
21.09
21.10
21.03
21.07
21.07
µ-MolesCO2
99.1423
99.1423
33124.4
33124.4
33124.4
33124.4
40.5067
40.5067
60.1417
60.1417
68.5852
68.5852
88.2079
88.2079
74.1647
74.1647
99.1571
99.1571
40.5084
40.5084
68.5780
68.5780
87.9993
87.9993
60.1510
60.1510
88.2115
88.2115
74.1569
74.1569
99.1577
99.1577
40.5079
40.5079
68.5856
68.5856
68.5856
V/N
38268.3
38262.3
30855.3
30853.5
151351.
151331.
93592.2
93592.7
63072.2
63079.9
55322.6
55323.0
43015.5
43022.8
51134.8
51120.7
38269.9
38264.3
93565.8
93595.4
55316.3
55304.0
43093.5
43094.7
63047.5
63069.3
43029.4
43027.7
51124.8
51132.0
38238.5
38238.7
93639.3
93625.4
55299.2
55304.0
55304.0
ChmbVol
3.79401
3.79341
1022.07
1022.01
5013.40
5012.76
3.79111
3.79113
3.79327
3.79373
3.79431
3.79434
3.79431
3.79495
3.79240
3.79135
3.79473
3.79418
3.79020
3.79140
3.79348
3.79264
3.79220
3.79230
3.79237
3.79368
3.79569
3.79554
3.79126
3.79179
3.79164
3.79166
3.79313
3.79257
3.79273
3.79306
3.79306
Flg
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
[-25pt]
Table A5: Fills of Nominally 4-liter CMM Flask (”Plenum P13”). NotesData and calculated
results are listed for measurements in the CMM of CO2 gas contained in the nominally 4-liter flask
named ”Plenum P13.” Its volume determinations by weighing contained water are listed in Table 3.
The measured mercury heights and temperature in the CMM, combined with the volume of Plenum
P13, allow calculation of the number of moles of CO2 contained in the plenum using the virial equation
of state. Notes on the columns in the table follow.
Date
Date of the measurement, in YYYYMMDD.
Fill
Designated number of the plenum fill.
HtVac
Mercury column height, in mm, measured with the cathetometer in the vacuum column #8 of the large manometer in the CMM.
HtSmp
Mercury column height, in mm, measured with the cathetometer in the sample column
#6 of the large manometer of the CMM.
MnCor
Correction applied to the mercury column measurements to account for possible nonlevel swing of the cathetometer telescope. Corrections, in mm, were determined experimentally.
Temp
Temperature, in C, for the measurement as read on thermometer #6112 near the
4 cc chamber and corrected according to its time-dependence over the history of
measurements.
Vol
Volume of Plenum P13, in cc, from the fit versus time of volume calibrations made
in 1974 and 2004.
MolesCO2
Calculated amount of CO2 in Plenum P13, in moles.
Table A5: Fills of Nominally 4-liter CMM Flask (”Plenum
Date
Fill
HtVac
HtSMp
MnCor
Temp
19740618 M001 810.640 175.898 -0.100 20.60
19740620 M002 795.622 175.996 -0.100 20.62
19740813 M003 804.851 176.442 -0.100 19.76
19800512 M004 781.453 180.514 -0.013 21.64
19800513 M005 776.269 180.550 -0.013 21.90
20060223 M006 757.209 176.911
0.073 23.35
20060417 M007 747.032 176.958
0.073 23.41
20060418 M008 755.129 176.849
0.073 23.49
P13”).
Vol
3946.30
3946.30
3946.30
3946.21
3946.21
3945.83
3945.82
3945.82
MolesCO2
0.136670
0.133391
0.135714
0.128894
0.127650
0.123715
0.121501
0.123221
Table A6: CMM Large Chamber Volume Calibrations. Made by Transfer of CO2 from Plenum
P13. Data and calculated results are listed for measurements in the CMM of CO2 gas transferred from
Plenum P13 into the nominally 5-liter chamber of the large manometer. The measured mercury heights
and temperature in the CMM allow calculation of the ratio V/n using the virial equation of state, where
V is the volume of the CMM chamber and n the number of moles of CO2 . When this ratio is multiplied
by the number of moles of CO2 determined by the filling of Plenum P13, as detailed in Table A5, the
volume of the CMM large manometer chamber results. Notes on the columns in the table follow.
Date
No
HtVac
HtSmp
MnCor
Temp
MolesCO2
V/n
ChmbVol
Flg
Date of the measurement, in YYYYMMDD.
Number of the plenum fill for the calibration.
Mercury column height, in mm, measured with the cathetometer in
the vacuum column #8 of the large manometer in the CMM.
Mercury column height, in mm, measured with the cathetometer in
the sample column #5 of the large manometer of the CMM.
Correction applied to the mercury column measurements to account
for possible non-level swing of the cathetometer telescope.
Corrections, in mm, were determined experimentally.
Temperature, in C, for the measurement as read on thermometer
#6112 near the 4 cc chamber and corrected according to its
time-dependence over the history of measurements.
Amount of CO2 in Plenum P13, in moles (from Table A5).
Ratio calculated from CMM measurement (cc/mole).
Calculated volume of CMM large chamber, in cc.
Flag column.
Table A6: CMM Large Chamber Volume Calibrations, by Transfer from Plenum P13.
Date
19740619
19740620
19740813
19800512
19800513
19800514
20060223
20060418
20060419
20060420
No
M001
M002
M003
M004
M005
M005
M006
M007
M008
M008
HtVac
673.488
661.175
668.720
651.909
647.575
646.447
631.051
623.921
629.802
630.210
HtSMp
173.240
173.304
173.688
177.792
178.008
177.654
174.117
174.114
174.168
174.110
MnCor
-0.098
-0.098
-0.098
-0.012
-0.012
-0.012
0.111
0.111
0.111
0.111
Temp
20.61
20.36
19.63
21.97
21.97
21.53
23.24
23.87
23.55
23.82
MolesCO2
0.136700
0.133400
0.135700
0.128900
0.127600
0.127600
0.123700
0.121500
0.123200
0.123200
V/N
36681.7
37587.3
36950.0
38899.6
39297.5
39297.5
40539.5
41272.2
40701.6
40701.6
ChmbVol
5014.39
5014.15
5014.12
5014.16
5014.36
5014.36
5014.74
5014.57
5014.44
5014.44
Flg
00
00
00
00
01
00
00
00
00
00
Table A7 Notes. Mercury column data are listed for all measurements of CO2 reference gases made on
the constant-volume mercury-column manometer from December 1969 to February 2010. All measurements
were made by Peter Guenther. Notes on the columns in the table follow.
Date
Date of the measurement, in YYYYMMDD
Cyl
High-pressure gas cylinder number stamped onto the cylinder by the manufacturer, without
any prefix letters (e.g. most standard-size Coyne steel cylinders have the prefix of DL-)
Run
Consecutive number of reference gas analysis. In almost all cases, there are two measurements
of the CO2 portion measured in the nominally 4 cc chamber paired with one measurement
of the total gas portion measured in the nominally 5000 cc chamber. The total gas data are
the same in the two lines of data for a single reference gas analysis. In a few cases there
are three or more CO2 measurements: accordingly there will then be three or more lines of
data. In the very few runs with two or more total gas measurements, they are averaged and
presented as one measurement.
Gas
Type of gas, other than CO2 , comprising the reference gas, i.e. the carrier gas: nitrogen
(N2), natural-air (AIR), and synthetic air, consisting of nitrogen and oxygen (SAIR). The
gas type determines the second virial coefficient used to calculate the total gas mole fraction.
Vol CO2 (cc)
The volume listed is that of the nominally 4 cc chamber as determined from its timedependence over the history of measurements.
Vol Tot (cc)
The volume listed is that of the nominally 5000 cc chamber as determined from a linear fit
of chamber volume determinations over the history of measurements.
Temp
CO2 ,
Tot (C)
Temperature for the measurement as read on thermometer #6112 near the 4 cc chamber
and corrected according to its time-dependence over the history of measurements.
Ht Vac, CO2 ,
Tot and Ht
Smp CO2 , Tot
(mm)
Mercury column height data, in mm, for CO2 and total gas measurements with the
cathetometer. The sample mercury column (Smp) for CO2 is column #4 at the 4 cc chamber
pointer, and the vacuum column (Vac) is column #2. The sample column for total gas is
column #5 at the 5000 cc pointer and the vacuum column is column #8.
MnCor CO2 ,
Tot (mm)
Correction applied to the mercury column measurements to account for differing sizes of the
glass tubing on the vacuum and sample columns and for non-level swing of the cathetometer
telescope. Corrections were determined experimentally. After 1985 a constant meniscus
correction of -0.340 mm for the 4 cc chamber measurement was often applied because of
difficulties in accurate measurement of the correction. However, all calibrations of primary
reference gases reported here have meniscus corrections that were measured concurrently.
N2 O (ppm)
Mole fraction of N2 O gas in the total gas, as measured by gas chromatography or assumed
(0.00 ppm for N2 and SAIR, 0.31 ppm for natural AIR).
Flg
A ”1” in either of the two columns indicates that the measurement has been rejected. The
first column refers to the CO2 measurement in the 4 cc chamber and the second column to
the total gas measurement in the 5000 cc chamber.
CO2 (ppm)
Mole fraction of CO2 corrected by subtraction of the mole fraction of N2 O, since the manometric measurement of CO2 gas includes the N2 Ocomponent.
Comment
Notes indicating unusual experimental observations. No comment for a flagged measurement
usually means that an outlier measurement has been rejected for statistical reasons.
Cyl
6078
6078
6078
6078
2399
2399
2399
2399
6078
6078
6078
6078
10069
10069
6078
6078
6078
6078
2399
2399
2399
2399
2399
2399
10069
10069
10069
10069
2399
2399
7366
7366
7366
7366
7366
7366
2399
2399
10069
10069
6078
6078
2399
2399
6078
6078
2399
2399
6078
6078
10069
10069
2399
Date
19691202
19691202
19691202
19691203
19691203
19691204
19691204
19691205
19691209
19691209
19691210
19691210
19691211
19691211
19691211
19691212
19700310
19700310
19700311
19700312
19700312
19700312
19700423
19700424
19700424
19700424
19700428
19700428
19700429
19700429
19700511
19700512
19700512
19700512
19700513
19700513
19700513
19700514
19700514
19700514
19700515
19700515
19700515
19700515
19721020
19721020
19721031
19721101
19721102
19721103
19721106
19721106
19721108
1
1
2
2
3
3
4
4
5
5
6
6
7
7
8
8
9
9
10
10
11
11
12
12
13
13
14
14
15
15
16
16
17
17
18
18
19
19
20
20
21
21
22
22
23
23
24
24
25
25
26
26
27
Run
Gas Vol
CO2
cc
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
Vol
Tot
cc
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.16
5014.19
5014.19
5014.19
5014.19
5014.19
5014.19
5014.19
5014.19
5014.19
Temp
CO2
o ∗
C
19.95
20.03
19.85
20.18
20.15
20.52
20.24
20.17
19.82
20.12
19.20
19.93
18.69
19.47
19.80
19.56
19.13
19.07
19.13
19.20
19.30
19.26
20.10
19.82
19.97
19.80
19.50
19.65
19.34
19.62
19.92
19.61
19.59
19.85
19.68
19.69
20.03
19.62
19.67
19.99
19.67
19.75
20.11
20.38
19.37
19.45
19.31
19.41
19.27
19.72
19.88
19.93
19.62
Temp
Tot
o ∗
C
20.09
20.09
19.85
19.85
20.23
20.23
20.34
20.34
19.83
19.83
19.62
19.62
19.89
19.89
19.33
19.33
19.24
19.24
19.08
19.08
19.19
19.19
19.98
19.98
19.82
19.82
19.48
19.48
19.54
19.54
19.74
19.74
19.60
19.60
19.88
19.88
19.60
19.60
19.61
19.61
20.03
20.03
19.79
19.79
19.10
19.10
19.66
19.66
19.34
19.34
19.08
19.08
19.62
HtVac
CO2
mm
618.844
618.899
618.124
618.472
626.890
626.996
631.857
631.688
617.370
617.566
616.716
617.249
652.387
653.019
620.472
620.165
613.548
613.381
622.094
622.165
624.113
624.026
627.755
627.410
649.408
649.137
651.634
651.895
622.990
623.235
585.092
584.772
587.199
587.418
588.257
588.190
624.333
623.965
646.598
646.910
612.586
612.607
623.445
623.625
619.690
619.609
641.364
641.700
623.334
624.043
667.633
667.629
637.156
HtVac
Tot
mm
772.173
772.173
769.870
769.870
766.602
766.602
777.489
777.489
768.700
768.700
767.572
767.572
771.326
771.326
774.840
774.840
764.348
764.348
760.504
760.504
764.160
764.160
773.375
773.375
766.329
766.329
771.880
771.880
762.994
762.994
759.159
759.159
765.191
765.191
768.269
768.269
764.334
764.334
760.347
760.347
762.000
762.000
762.927
762.927
779.329
779.329
805.611
805.611
789.278
789.278
803.699
803.699
795.361
HtSmp
CO2
mm
374.697
374.646
374.682
374.684
374.694
374.678
374.685
374.693
374.774
374.779
374.621
374.620
374.613
374.594
374.621
374.629
371.014
370.996
371.019
370.994
371.014
371.001
370.962
370.948
370.963
370.943
370.944
370.964
370.970
370.973
370.982
371.005
370.962
370.971
370.974
370.949
370.965
370.947
370.962
370.969
370.998
370.976
370.956
370.949
370.652
370.648
370.633
370.636
370.639
370.672
370.648
370.638
370.658
HtSmp
Tot
mm
177.232
177.232
177.252
177.252
177.249
177.249
177.274
177.274
177.370
177.370
177.315
177.315
177.243
177.243
177.182
177.182
173.649
173.649
173.657
173.657
173.552
173.552
173.374
173.374
173.512
173.512
173.519
173.519
173.472
173.472
173.600
173.600
173.633
173.633
173.495
173.495
173.561
173.561
173.545
173.545
173.492
173.492
173.588
173.588
173.349
173.349
173.230
173.230
173.298
173.298
173.270
173.270
173.259
Table A7: Manometric Reference Gas Measurements: Original Data. Page 1/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
Flg
0
10
0
10
0
10
1
11
0
10
0
10
0
10
0
10
0
10
0
10
1
11
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ppm
310.94
310.99
311.10
311.17
324.20
323.93
324.66
324.52
310.70
310.61
311.08
310.95
355.79
355.62
311.01
310.88
311.07
310.94
323.99
324.03
324.46
324.41
324.04
323.95
355.67
355.57
355.40
355.51
324.03
324.01
276.62
276.49
276.73
276.74
276.76
276.70
324.33
324.36
355.80
355.78
311.28
311.25
324.12
324.04
310.96
310.77
324.73
325.02
310.79
311.12
355.95
355.90
324.52
CO2
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
RERUN AFTER TRANSFER OUT/IN
Comment
2424
7366
7366
7366
7366
7366
3753
3753
3753
3753
35452
35452 45
35452
35452
35452
6078
6078
35434
35434
35434
35434
35434
19740206
19740206
19740207
19740207
19740208
19740208
19740208
19740211
19740212
19740213
19740213
19740213
19740214
19740214
19740214
19740220
19740221
19740225
19740225
19740226
19740226
19740227
46
46
46
47
47
48
48
48
49
49
40
41
41
41
42
42
43
43
44
44
45
27
28
28
29
29
30
30
31
31
32
32
33
33
34
34
34
35
35
36
36
37
37
38
38
39
39
39
40
2399
10069
10069
2399
2399
6078
6078
6078
6078
35435
35435
35435
35435
2399
2399
2399
2399
2399
2399
2399
10069
10069
10069
10069
2424
2424
2424
2424
19721108
19721109
19721109
19721113
19721113
19740117
19740118
19740118
19740121
19740121
19740122
19740123
19740123
19740124
19740124
19740125
19740128
19740128
19740129
19740130
19740130
19740131
19740201
19740201
19740201
19740204
19740205
19740205
Run
Cyl
Date
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
Vol
Tot
cc
5014.19
5014.19
5014.19
5014.19
5014.19
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
N2 3.7970
N2 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
SAIR 3.7970 5014.21
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
SAIR 3.7970
Gas Vol
CO2
cc
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
20.22
20.19
20.12
20.11
19.91
20.89
20.91
20.19
20.91
20.79
20.54
20.75
20.07
20.42
20.38
20.05
19.86
20.03
20.99
21.00
20.84
20.59
Temp
CO2
o ∗
C
19.78
19.65
19.70
19.99
20.09
18.04
17.70
19.89
20.55
20.27
20.45
20.44
20.48
20.62
20.48
20.62
20.43
20.58
20.31
20.47
20.86
20.66
20.04
19.95
20.14
20.50
20.22
20.39
20.56
20.56
20.56
20.16
20.16
20.75
20.75
20.75
20.28
20.28
20.97
20.23
20.73
20.73
20.73
20.46
20.46
19.97
19.97
20.91
20.91
20.97
Temp
Tot
o ∗
C
19.62
19.67
19.67
19.00
19.00
17.97
17.97
18.09
18.09
20.40
20.40
20.58
20.58
20.50
20.50
20.50
20.59
20.59
20.50
20.50
20.72
20.72
20.86
20.86
20.00
20.00
20.00
20.23
800.724
818.852
818.852
818.852
813.325
813.325
812.929
812.929
824.325
824.325
799.231
HtVac
Tot
mm
795.361
805.530
805.530
797.927
797.927
806.112
806.112
808.666
808.666
803.574
803.574
803.725
803.725
807.787
807.787
807.787
807.650
807.650
801.884
801.884
808.097
808.097
799.587
799.587
799.548
799.548
799.548
800.724
370.684
370.629
370.658
370.622
370.661
370.648
370.658
370.636
370.660
370.656
370.630
HtSmp
CO2
mm
370.620
370.647
370.632
370.654
370.646
370.613
370.616
370.615
370.604
370.629
370.594
370.582
370.590
370.607
370.544
370.584
370.641
370.603
370.654
370.636
370.628
370.654
370.674
370.634
370.648
370.672
370.660
370.660
173.258
173.252
173.252
173.252
173.333
173.333
173.306
173.306
173.280
173.280
173.331
HtSmp
Tot
mm
173.259
173.312
173.312
173.277
173.277
173.226
173.226
173.278
173.278
173.248
173.248
173.275
173.275
173.234
173.234
173.234
173.232
173.232
173.293
173.293
173.326
173.326
173.198
173.198
173.217
173.217
173.217
173.258
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
639.234
639.229
639.196
627.881
627.693
640.876
640.912
640.212
639.810
639.709
802.350
802.350
802.350
800.465
800.465
805.011
805.011
805.011
801.586
801.586
370.666
370.645
370.652
370.593
370.595
370.573
370.570
370.622
370.593
370.624
173.350
173.350
173.350
173.242
173.242
173.240
173.240
173.240
173.274
173.274
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Flg
N2 O
637.689 799.231 370.612 173.331 -0.364 -0.042 0.00
695.941
606.055
606.245
606.380
604.208
604.116
578.580
579.294
582.288
582.150
637.822
HtVac
CO2
mm
637.490
667.890
667.847
639.276
639.323
630.310
630.018
633.028
633.696
648.730
648.808
648.762
648.838
642.001
641.622
641.968
641.952
642.088
639.336
639.482
668.694
668.442
663.690
663.540
694.926
695.554
695.071
695.576
Table A7: Manometric Reference Gas Measurements: Original Data. Page 2/34
∗
Temperature corrected for thermometer drift
VACUUM COLUMN FALLING DURING
MEASUREMENT
HG JUMPING TOWARDS POINTER
HG JUMPING TOWARDS POINTER
HG JUMPING TOWARDS POINTER
HG JUMPING TOWARDS POINTER
Comment
392.19
276.78 HG JUMPING TOWARDS POINTER
276.62
276.86
276.72
276.82
246.00
246.02
245.97
245.96
323.80 VACUUM COLUMN FALLING DURING
MEASUREMENT
323.72 VACUUM COLUMN FALLING DURING
MEASUREMENT
323.82
323.88
323.91 HG CONTACTED POINTER PREMATURELY
310.76
310.75
323.93 HG CONTACTED POINTER PREMATURELY
323.95
323.89
323.83
323.81
ppm
324.78
356.31
356.21
324.61
324.56
310.74
310.77
310.81
310.87
334.09
334.01
334.14
334.17
323.86
323.65
323.85
324.16
324.19
324.02
324.03
355.65
355.57
355.51
355.50
392.26
392.48
392.30
392.29
CO2
Cyl
35389
35389
35389
35389
35441
35441
35441
35441
35442
35442
35442
35442
35435
35435
2399
2399
35405
35405
44726
44726
35405
35405
44695
44695
44726
44726
44695
44695
35378
35378
35378
35378
35401
35401
34770
34770
34770
34770
35401
35401
2408
2408
2408
2408
35316
35316
35316
35316
35299
35299
35299
35299
39239
Date
19740227
19740227
19740228
19740228
19740228
19740301
19740301
19740301
19740304
19740305
19740305
19740307
19740307
19740307
19740308
19740308
19740409
19740410
19740410
19740410
19740411
19740411
19740412
19740412
19740412
19740412
19740415
19740415
19740507
19740507
19740508
19740508
19740510
19740510
19740510
19740510
19740515
19740515
19740515
19740515
19740522
19740522
19740522
19740522
19740523
19740523
19740523
19740523
19740524
19740524
19740524
19740524
19741014
50
50
51
51
52
52
53
53
54
54
55
55
56
56
57
57
58
58
59
59
60
60
61
61
62
62
63
63
64
64
65
65
66
66
67
67
68
68
69
69
70
70
71
71
72
72
73
73
74
74
75
75
76
Run
Gas Vol
CO2
cc
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
AIR 3.7970
AIR 3.7970
N2 3.7970
N2 3.7970
AIR 3.7970
AIR 3.7970
SAIR 3.7970
SAIR 3.7970
AIR 3.7970
AIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
Vol
Tot
cc
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.21
5014.22
Temp
CO2
o ∗
C
20.57
20.69
20.07
20.12
20.84
19.56
20.08
20.12
20.81
20.57
20.93
20.03
20.49
20.41
20.68
20.76
20.67
20.78
20.71
20.72
20.94
20.95
20.62
20.87
20.97
20.96
20.90
20.88
20.68
20.57
20.87
20.88
20.25
20.15
20.00
19.67
20.51
20.57
20.72
20.71
20.28
20.35
20.17
20.09
19.84
19.55
19.23
19.38
19.69
19.78
19.86
19.82
19.98
Temp
Tot
o ∗
C
20.78
20.78
20.64
20.64
20.06
20.06
19.66
19.66
20.52
20.52
20.62
20.62
20.92
20.92
20.55
20.55
20.28
20.28
20.77
20.77
20.71
20.71
20.95
20.95
20.87
20.87
20.88
20.88
20.57
20.57
20.64
20.64
20.40
20.40
20.19
20.19
20.62
20.62
20.53
20.53
20.20
20.20
20.34
20.34
20.14
20.14
19.73
19.73
19.35
19.35
19.72
19.72
20.15
HtVac
CO2
mm
649.209
649.449
648.837
649.021
646.485
645.232
647.291
647.306
647.417
647.324
641.505
640.722
648.074
648.027
636.706
636.866
648.984
649.046
627.215
627.325
653.406
653.436
662.720
663.005
627.333
627.322
663.100
663.245
665.224
665.161
665.419
665.409
665.067
664.922
649.649
649.455
650.481
650.509
662.242
662.328
533.715
533.662
536.086
536.005
758.428
757.934
758.398
758.636
714.074
714.054
714.184
714.235
652.583
HtVac
Tot
mm
803.450
803.450
803.218
803.218
801.108
801.108
803.402
803.402
813.978
813.978
800.229
800.229
803.052
803.052
795.051
795.051
797.619
797.619
801.326
801.326
807.931
807.931
802.820
802.820
801.111
801.111
803.283
803.283
800.343
800.343
800.246
800.246
805.116
805.116
797.885
797.885
799.107
799.107
798.520
798.520
799.513
799.513
809.296
809.296
795.825
795.825
796.412
796.412
799.722
799.722
800.763
800.763
815.255
HtSmp
CO2
mm
370.607
370.584
370.622
370.595
370.577
370.616
370.603
370.610
370.592
370.620
370.601
370.625
370.620
370.587
370.580
370.586
370.643
370.650
370.644
370.612
370.648
370.607
370.636
370.631
370.614
370.618
370.624
370.632
370.644
370.608
370.642
370.616
370.653
370.630
370.630
370.601
370.632
370.600
370.602
370.570
370.644
370.620
370.620
370.602
370.624
370.581
370.618
370.592
370.621
370.582
370.606
370.584
371.044
HtSmp
Tot
mm
173.274
173.274
173.300
173.300
173.278
173.278
173.218
173.218
173.276
173.276
173.332
173.332
173.280
173.280
173.212
173.212
173.284
173.284
173.243
173.243
173.256
173.256
173.263
173.263
173.240
173.240
173.256
173.256
173.254
173.254
173.278
173.278
173.232
173.232
173.261
173.261
173.238
173.238
173.284
173.284
173.319
173.319
173.247
173.247
173.264
173.264
173.266
173.266
173.256
173.256
173.193
173.193
173.596
Table A7: Manometric Reference Gas Measurements: Original Data. Page 3/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.29
0.29
0.00
0.00
0.29
0.29
0.00
0.00
0.29
0.29
0.00
0.00
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.30
0.30
0.29
0.29
0.29
0.29
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ppm
335.17
335.34
335.28
335.47
331.95
331.92
332.08
332.04
326.92
327.06
326.93
327.01
333.97
334.05
324.04
324.13
336.96
336.90
309.44
309.61
336.94
337.01
351.94
351.97
309.55
309.54
351.71
351.90
355.50
355.60
355.65
355.66
352.92
352.90
338.34
338.54
338.57
338.57
352.87
353.02
196.90
196.81
196.88
196.86
472.99
472.93
472.86
472.93
415.15
415.03
414.87
415.01
332.64
CO2
TEMPERATURE INSTABILITY
TEMPERATURE INSTABILITY
TEMPERATURE INSTABILITY
TEMPERATURE INSTABILITY
TEMPERATURE INSTABILITY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
2399 83
2399 83
10069 84
10069 84
10069 85
10069 85
7366 86
7366 86
7366 87
7366 87
34770 88
34770 88
34770 89
34770 89
35405 90
35405 90
35405 91
35405 91
34770 92
34770 92
35401 93
35401 93
35401 94
35401 94
243988 95
243988 95
62206 96
62206 96
61130 97
61130 97
62206 98
62206 98
75934 99
75934 99
243988 100
243988 100
61130 101
61130 101
19790925
19790925
19791003
19791003
19791005
19791005
19791009
19791009
19791019
19791019
19800515
19800515
19800516
19800516
19800516
19800516
19800523
19800523
19800529
19800529
19800530
19800530
19800530
19800530
19800530
19800530
19800603
19800603
19800604
19800604
19800604
19800604
19800605
19800605
19800609
19800609
19800610
19800610
76
76
77
77
78
78
79
79
80
80
81
81
82
82
39239
39239
1540
1540
39239
39239
1540
1540
6078
6078
6078
6078
2399
2399
19741014
19741015
19741015
19741015
19741016
19741016
19741017
19741017
19790918
19790918
19790919
19790919
19790925
19790925
Run
Cyl
Date
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
SAIR 3.7970
SAIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
Gas Vol
CO2
cc
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
5014.27
5014.27
5014.27
5014.27
5014.27
5014.27
5014.27
5014.27
5014.27
5014.27
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
Vol
Tot
cc
5014.22
5014.22
5014.22
5014.22
5014.22
5014.22
5014.22
5014.22
5014.27
5014.27
5014.27
5014.27
5014.27
5014.27
22.67
22.88
21.57
21.71
21.36
21.53
21.50
21.59
21.55
21.58
21.84
21.80
21.75
21.78
21.81
21.90
21.68
21.73
22.15
22.23
21.67
21.84
21.81
21.84
21.81
21.97
21.96
21.99
21.79
21.97
22.08
22.08
21.49
21.70
22.07
22.13
21.89
22.03
Temp
CO2
o ∗
C
19.88
19.81
19.81
19.74
19.68
19.68
19.39
19.58
25.10
25.34
25.48
25.66
21.56
21.75
21.65
21.65
21.06
21.06
20.90
20.90
21.46
21.46
21.43
21.43
21.57
21.57
21.82
21.82
21.77
21.77
21.75
21.75
22.15
22.15
22.20
22.20
21.76
21.76
21.83
21.83
21.72
21.72
21.98
21.98
21.88
21.88
22.08
22.08
21.86
21.86
22.09
22.09
Temp
Tot
o ∗
C
20.15
20.15
19.81
19.81
19.92
19.92
19.69
19.69
24.68
24.68
23.57
23.57
22.72
22.72
638.898
639.061
665.985
666.104
667.001
667.066
602.787
602.802
602.506
602.506
651.653
651.574
651.238
651.239
650.569
650.650
649.951
649.906
652.978
653.030
663.036
663.129
663.022
662.973
658.064
658.130
647.824
647.818
652.862
653.003
648.118
648.069
651.016
651.162
657.972
658.052
651.996
652.056
HtVac
CO2
mm
652.609
652.628
685.812
685.739
646.394
646.288
685.224
685.436
631.082
631.308
628.809
628.880
640.555
640.690
791.927
791.927
795.945
795.945
798.440
798.440
800.818
800.818
799.952
799.952
794.843
794.843
794.023
794.023
796.399
796.399
795.248
795.248
799.250
799.250
796.914
796.914
795.554
795.554
795.769
795.769
796.661
796.661
796.715
796.715
797.606
797.606
796.828
796.828
795.093
795.093
794.773
794.773
HtVac
Tot
mm
815.255
815.255
800.690
800.690
800.907
800.907
799.969
799.969
800.626
800.626
791.396
791.396
800.785
800.785
375.018
375.020
375.074
375.060
375.058
375.040
375.033
375.042
375.061
375.048
375.068
375.022
375.044
375.036
375.062
375.044
375.068
375.032
375.058
375.034
375.066
375.032
375.059
375.014
375.054
375.030
375.032
375.040
375.054
375.030
375.044
375.028
375.086
375.052
375.043
375.018
375.046
375.028
HtSmp
CO2
mm
371.039
371.068
371.067
371.066
371.068
371.020
371.029
371.032
375.030
375.029
375.025
375.015
375.046
375.019
177.644
177.644
177.706
177.706
177.753
177.753
177.788
177.788
177.744
177.744
177.620
177.620
177.672
177.672
177.804
177.804
177.698
177.698
177.770
177.770
177.758
177.758
177.768
177.768
177.859
177.859
177.728
177.728
177.813
177.813
177.807
177.807
177.772
177.772
177.798
177.798
177.706
177.706
HtSmp
Tot
mm
173.596
173.596
173.708
173.708
173.639
173.639
173.625
173.625
177.772
177.772
177.666
177.666
177.686
177.686
Table A7: Manometric Reference Gas Measurements: Original Data. Page 4/34
∗
Temperature corrected for thermometer drift
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
0
0
0
0
0
0
0
0
0
0
11
11
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.30
0.30
0.30
0.30
0.29
0.29
0.30
0.30
0.31
0.31
0.30
0.30
0.00
0.00
0.29
0.29
0.31
0.31
Flg
N2 O
Comment
ppm
332.79
332.86
380.48
380.49
332.82
332.75
380.62
380.61
310.89
310.90
311.06 HG CONTACTED POINTER PREMATURELY
310.96
324.11
324.09 CATHETOMETER MANUAL CONTROL
SLIPPING
324.20
324.16
355.89
355.87
355.81
355.69
276.73
276.65
276.64
276.63
338.83 INSTRUMENTAL PROBLEM
338.84 INSTRUMENTAL PROBLEM
339.24 INSTRUMENTAL PROBLEM
339.22 INSTRUMENTAL PROBLEM
337.03
337.04
336.97
336.90
338.46
338.46
352.73 HG CONTACTED POINTER PREMATURELY
352.67
352.77
352.73
346.71
346.62
333.26
333.21
339.95
339.93
333.19
333.15
338.29 DRIFTING CYLINDER
338.25 DRIFTING CYLINDER
346.67
346.72
339.92
339.84
CO2
34770 102
34770 102
127524 103
127524 103
127693 104
127693 104
66556 105
66556 105
71251 106
71251 106
39239 107
39239 107
39239 108
39239 108
1540 109
1540 109
1540 110
1540 110
35299 111
35299 111
35299 112
35299 112
35316 113
35316 113
35316 114
35316 114
3753 115
3753 115
3753 116
3753 116
127524 117
127524 117
127693 118
127693 118
75934 119
75934 119
2408 120
2408 120
75934 121
75934 121
127524 122
127524 122
127693 123
127693 123
2408 124
2408 124
1540 125
1540 125
35316 126
35316 126
35316 127
19800613
19800613
19800613
19800613
19800616
19800616
19800618
19800618
19800618
19800618
19800619
19800619
19800619
19800619
19800620
19800620
19800624
19800624
19800625
19800625
19800625
19800625
19800626
19800626
19800626
19800626
19800627
19800627
19800627
19800627
19800909
19800909
19800909
19800909
19800910
19800910
19800910
19800910
19800911
19800911
19800916
19800916
19800917
19800917
19800917
19800917
19800918
19800918
19800923
19800923
19800924
Run
Cyl
Date
N2
N2
Vol
Tot
cc
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
3.7970 5014.28
3.7970 5014.28
Gas Vol
CO2
cc
AIR 3.7970
AIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
N2 3.7970
N2 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
21.31
22.06
Temp
CO2
o ∗
C
21.80
21.83
21.94
22.02
22.07
22.07
22.16
22.15
22.19
22.13
21.86
21.90
22.03
22.08
21.98
22.06
22.12
22.05
21.97
21.97
22.32
22.30
21.88
21.99
22.28
22.29
21.90
21.96
22.12
22.20
21.26
21.56
21.89
21.94
21.44
21.59
22.14
22.07
21.63
21.72
21.97
22.08
21.30
21.53
22.35
22.59
21.35
21.85
22.04
22.09
21.66
Temp
Tot
o ∗
C
21.70
21.70
21.80
21.80
21.91
21.91
22.05
22.05
22.13
22.13
22.15
22.15
21.85
21.85
22.04
22.04
21.64
21.64
22.07
22.07
21.96
21.96
22.30
22.30
21.93
21.93
22.29
22.29
21.92
21.92
21.48
21.48
21.52
21.52
21.91
21.91
21.49
21.49
22.08
22.08
21.89
21.89
22.01
22.01
21.45
21.45
22.45
22.45
21.66
HtVac
Tot
mm
798.487
798.487
798.300
798.300
797.247
797.247
795.680
795.680
799.468
799.468
797.614
797.614
798.090
798.090
796.639
796.639
795.532
795.532
797.756
797.756
795.440
795.440
799.739
799.739
797.028
797.028
796.145
796.145
794.767
794.767
794.131
794.131
794.690
794.690
797.602
797.602
795.764
795.764
801.582
801.582
800.021
800.021
797.270
797.270
800.031
800.031
795.695
795.695
797.620
HtSmp
CO2
mm
375.050
375.034
375.042
375.044
375.058
375.019
375.024
375.032
375.028
375.036
375.044
375.046
375.076
375.056
375.024
375.035
375.053
375.016
375.042
375.034
375.058
375.015
375.025
375.004
375.022
375.018
375.052
375.028
375.061
375.038
375.037
374.998
375.012
375.013
375.032
375.006
375.028
375.024
375.034
375.040
375.014
374.996
375.050
375.011
375.022
374.997
375.024
375.050
375.035
HtSmp
Tot
mm
177.700
177.700
177.848
177.848
177.808
177.808
177.730
177.730
177.764
177.764
177.848
177.848
177.728
177.728
177.700
177.700
177.702
177.702
177.824
177.824
177.775
177.775
177.815
177.815
177.704
177.704
177.652
177.652
177.717
177.717
177.765
177.765
177.714
177.714
177.902
177.902
177.770
177.770
177.738
177.738
177.763
177.763
177.768
177.768
177.744
177.744
177.702
177.702
177.699
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
0
0
11
11
11
11
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
ppm
0.29
0.29
0.00
0.00
0.00
0.00
0.37
0.37
0.34
0.34
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
757.791 793.624 375.028 177.804 -0.364 -0.042 0.00
0
11
Flg
N2 O
761.604 797.620 374.998 177.699 -0.364 -0.042 0.00
HtVac
CO2
mm
652.696
652.702
653.394
653.586
670.429
670.502
458.129
458.118
550.573
550.507
646.899
646.966
647.789
647.830
685.324
685.422
685.738
685.668
714.217
714.204
713.628
713.514
761.232
761.358
761.475
761.556
575.810
575.835
575.764
575.778
651.782
652.071
669.801
669.892
652.038
652.122
536.180
536.137
653.824
653.930
654.811
654.953
670.004
670.174
537.518
537.640
684.030
684.614
761.642
Table A7: Manometric Reference Gas Measurements: Original Data. Page 5/34
∗
Temperature corrected for thermometer drift
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
JUMPING TOWARDS POINTER-
LARGE TEMPERATURE DRIFT
HG
HG
HG
HG
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
DRIFTING CYLINDER
HG CONTACTED POINTER PREMATURELY
DRIFTING CYLINDER
Comment
HG JUMPING TOWARDS
POINTER-PREMATURE CONTACT
472.31 TEMPERATURE DROPPING DURING
MEASUREMENT
472.72
ppm
338.39
338.38
339.58
339.72
360.98
361.11
101.02
101.00
213.19
213.15
332.63
332.67
332.81
332.82
380.03
380.03
380.45
380.51
414.91
414.91
415.00
414.95
471.69
471.68
472.66
472.75
246.00
246.00
245.99
245.96
340.29
340.33
361.43
361.48
339.11
339.06
196.75
196.75
339.01
339.02
340.43
340.49
361.56
361.51
196.85
196.86
380.44
380.44
472.35
CO2
Cyl
35316
35316
35316
35316
35316
71286
71286
71286
35452
35452
35452
35452
35441
35441
35441
35441
35442
35442
35442
35442
35389
35389
35389
35389
35434
35434
35434
35434
35434
35434
35401
35401
66556
66556
71251
71251
71286
71286
34819
34819
34819
34819
71341
71341
71341
71341
66638
66638
66638
66638
66625
66625
66625
Date
19800924
19801023
19801023
19801024
19801024
19801024
19801024
19801024
19801111
19801111
19801112
19801112
19801113
19801113
19801113
19801113
19801114
19801114
19801114
19801114
19801118
19801118
19801119
19801119
19801119
19801119
19801120
19801120
19801121
19801121
19810805
19810805
19810806
19810806
19810806
19810806
19810807
19810807
19810807
19810807
19810812
19810812
19810812
19810812
19810813
19810813
19810813
19810813
19810814
19810814
19810814
19810814
19810818
127
128
128
129
129
130
130
130
131
131
132
132
133
133
134
134
135
135
136
136
137
137
138
138
139
139
140
140
141
141
142
142
143
143
144
144
145
145
146
146
147
147
148
148
149
149
150
150
151
151
152
152
153
Run
Gas Vol
CO2
cc
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
N2 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
SAIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
Vol
Tot
cc
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.28
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.29
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
Temp
CO2
o ∗
C
21.54
21.91
21.96
20.99
21.16
21.75
22.12
22.18
21.96
22.05
21.73
21.73
21.08
21.19
21.52
21.58
21.24
21.39
21.69
21.77
21.87
21.90
21.10
21.30
21.83
21.98
21.89
22.15
21.73
21.82
21.79
22.22
21.51
21.69
22.51
22.75
21.60
21.82
22.54
22.79
21.56
21.73
22.58
22.81
21.93
22.22
23.28
23.52
24.04
24.44
25.48
25.57
21.36
Temp
Tot
o ∗
C
22.09
21.58
21.58
21.93
21.93
21.08
21.08
21.08
21.98
21.98
21.50
21.50
21.73
21.73
21.15
21.15
21.53
21.53
21.29
21.29
21.06
21.06
21.89
21.89
21.20
21.20
21.08
21.08
21.28
21.28
21.94
21.94
22.19
22.19
21.62
21.62
22.67
22.67
21.69
21.69
21.70
21.70
21.65
21.65
22.68
22.68
22.07
22.07
23.40
23.40
24.27
24.27
21.62
HtVac
CO2
mm
758.066
761.570
761.620
759.303
759.533
618.378
618.724
618.748
638.979
639.089
640.138
640.106
647.020
647.054
646.700
646.746
643.652
643.751
644.441
644.527
652.823
652.796
651.382
651.548
641.177
641.330
643.115
643.347
647.710
647.772
662.572
663.032
457.924
457.999
551.957
552.054
617.614
617.732
581.128
581.248
582.128
582.249
638.848
639.002
638.368
638.650
650.530
650.712
652.562
652.876
659.470
659.489
657.711
HtVac
Tot
mm
793.624
797.075
797.075
796.442
796.442
796.980
796.980
796.980
795.535
795.535
797.647
797.647
799.911
799.911
796.923
796.923
800.923
800.923
801.166
801.166
803.114
803.114
803.698
803.698
800.971
800.971
803.034
803.034
814.700
814.700
795.238
795.238
796.524
796.524
802.663
802.663
798.793
798.793
795.073
795.073
800.488
800.488
795.170
795.170
797.493
797.493
792.013
792.013
797.910
797.910
800.134
800.134
799.382
HtSmp
CO2
mm
375.003
374.997
374.966
375.002
374.990
375.011
375.008
374.984
374.994
374.994
375.006
374.984
374.990
374.968
375.005
374.995
374.979
374.958
374.997
375.014
374.971
374.952
374.958
374.944
374.952
374.978
374.990
374.984
374.984
374.969
375.008
375.015
375.028
375.018
375.015
375.008
375.035
374.981
375.013
374.994
374.856
374.839
374.842
374.807
374.830
374.830
374.842
374.804
374.844
374.795
374.807
374.800
374.844
HtSmp
Tot
mm
177.804
177.716
177.716
177.778
177.778
177.783
177.783
177.783
177.740
177.740
177.720
177.720
177.766
177.766
177.696
177.696
177.696
177.696
177.720
177.720
177.688
177.688
177.732
177.732
177.730
177.730
177.714
177.714
177.742
177.742
177.737
177.737
177.794
177.794
177.651
177.651
177.680
177.680
177.790
177.790
177.621
177.621
177.601
177.601
177.486
177.486
177.609
177.609
177.544
177.544
177.536
177.536
177.566
Table A7: Manometric Reference Gas Measurements: Original Data. Page 6/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.00
0.32
0.32
0.32
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.30
0.30
0.37
0.37
0.34
0.34
0.32
0.32
0.24
0.24
0.24
0.24
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.29
0.29
0.29
ppm
472.70
472.82
472.83
472.71
472.72
296.57
296.60
296.60
323.67
323.70
323.67
323.66
331.96
331.89
331.89
331.89
326.83
326.80
326.84
326.83
335.57
335.52
335.47
335.45
322.82
322.80
323.84
323.82
323.81
323.80
352.70
352.71
100.92
100.96
213.12
213.07
296.54
296.51
251.69
251.64
251.73
251.74
322.39
322.36
322.48
322.50
338.11
338.09
338.02
337.98
344.59
344.51
344.65
CO2
LARGE TEMPERATURE DRIFT
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
Cyl
66696
66696
66696
66696
67615
67615
67615
67615
71479
71479
71479
71479
71370
71370
71370
71370
71308
71308
71308
71308
18027
18027
18040
18067
18067
16410
16410
18042
18042
16417
16417
39239
39239
39256
39256
39272
39272
39256
39256
39272
39272
39239
39239
39272
39272
39239
39239
3082
3082
39256
39256
3082
3082
Date
19810818
19810818
19810819
19810819
19810820
19810820
19810820
19810820
19810824
19810824
19810825
19810825
19810825
19810825
19810826
19810826
19810827
19810827
19810827
19810827
19820420
19820420
19820420
19820421
19820421
19820421
19820421
19820423
19820423
19820423
19820423
19821104
19821104
19821105
19821105
19821108
19821108
19821110
19821110
19821110
19821110
19821111
19821111
19821112
19821112
19821112
19821112
19821112
19821112
19821115
19821115
19821115
19821115
154
154
155
155
156
156
157
157
158
158
159
159
160
160
161
161
162
162
163
163
164
164
165
166
166
167
167
168
168
169
169
170
170
171
171
172
172
173
173
174
174
175
175
176
176
177
177
178
178
179
179
180
180
Run
Gas Vol
CO2
cc
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7970
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
Vol
Tot
cc
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.3
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
Temp
CO2
o ∗
C
21.96
22.10
21.88
22.02
21.53
21.70
22.36
22.70
21.97
22.12
21.67
22.06
23.53
23.80
24.03
24.29
22.35
22.84
24.01
24.31
21.57
21.73
22.23
21.34
21.44
22.27
22.35
22.77
22.84
22.74
22.81
23.00
23.19
22.73
22.88
22.48
22.52
21.84
21.87
21.77
21.81
21.89
21.95
21.47
21.70
22.09
22.18
22.31
22.34
22.23
22.35
22.50
22.50
Temp
Tot
o ∗
C
21.43
21.43
21.28
21.28
21.95
21.95
21.62
21.62
21.30
21.30
22.04
22.04
21.81
21.81
22.51
22.51
24.14
24.14
22.60
22.60
22.12
22.12
21.65
22.24
22.24
21.39
21.39
21.90
21.90
22.79
22.79
22.74
22.74
21.91
21.91
22.03
22.03
21.48
21.48
21.86
21.86
21.78
21.78
21.91
21.91
21.57
21.57
22.12
22.12
21.63
21.63
22.29
22.29
HtVac
CO2
mm
668.460
668.573
670.634
670.782
788.144
788.372
790.322
790.788
746.356
746.542
743.325
743.786
704.983
705.310
709.620
709.858
680.914
681.364
680.876
681.176
649.868
650.000
648.728
653.049
653.060
663.741
663.802
656.436
656.378
663.813
663.899
649.005
649.202
658.576
658.747
671.714
671.767
659.630
659.592
672.194
672.171
647.392
647.392
673.769
673.936
650.564
650.572
637.388
637.390
660.065
660.148
636.084
636.046
HtVac
Tot
mm
794.153
794.153
798.501
798.501
801.306
801.306
801.731
801.731
797.018
797.018
794.319
794.319
789.210
789.210
798.025
798.025
796.954
796.954
790.024
790.024
799.182
799.182
794.325
794.746
794.746
798.924
798.924
797.678
797.678
800.923
800.923
801.351
801.351
797.665
797.665
800.336
800.336
800.609
800.609
802.583
802.583
797.686
797.686
806.439
806.439
803.951
803.951
804.790
804.790
801.205
801.205
801.727
801.727
HtSmp
CO2
mm
374.816
374.812
374.816
374.808
374.845
374.806
374.834
374.812
374.816
374.808
374.832
374.802
374.830
374.830
374.839
374.792
374.842
374.804
374.831
374.828
374.950
374.941
374.995
374.964
374.931
374.962
374.944
374.989
374.944
374.953
374.954
374.954
374.955
374.949
374.926
374.929
374.940
374.940
374.910
374.940
374.910
374.968
374.924
374.963
374.924
374.934
374.918
374.916
374.946
374.978
374.948
374.992
374.966
HtSmp
Tot
mm
177.578
177.578
177.574
177.574
177.538
177.538
177.565
177.565
177.574
177.574
177.624
177.624
177.605
177.605
177.516
177.516
177.583
177.583
177.589
177.589
177.654
177.654
177.686
177.722
177.722
177.752
177.752
177.666
177.666
177.684
177.684
177.586
177.586
177.582
177.582
177.565
177.565
177.563
177.563
177.680
177.680
177.596
177.596
177.589
177.589
177.622
177.622
177.658
177.658
177.614
177.614
177.678
177.678
Table A7: Manometric Reference Gas Measurements: Original Data. Page 7/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.31
0.31
0.31
0.31
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.31
0.31
0.31
0.31
0.32
0.32
0.32
0.32
0.00
0.00
0.00
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.30
0.30
0.00
0.00
0.30
0.30
ppm
359.84
359.80
359.88
359.89
503.06
503.08
503.31
503.29
453.41
453.40
453.37
453.34
406.32
406.34
406.42
406.38
376.53
376.47
376.43
376.40
335.92
335.90
335.76
342.40
342.33
351.31
351.30
343.01
342.91
351.41
351.42
332.72
332.73
345.74
345.79
360.74
360.74
345.96
345.91
360.78
360.74
332.88
332.86
360.85
360.80
332.96
332.89
316.65
316.59
345.84
345.83
316.52
316.50
CO2
CONTACTED
CONTACTED
CONTACTED
CONTACTED
POINTER
POINTER
POINTER
POINTER
PREMATURELY
PREMATURELY
PREMATURELY
PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG
HG
HG
HG
HG CONTACTED POINTER PREMATURELY
LARGE TEMPERATURE DRIFT
LARGE TEMPERATURE DRIFT
Comment
Cyl
3074
3074
3074
3074
3071
3071
3071
3071
3091
3091
3091
3091
3092
3092
3092
3092
34891
34891
34891
34891
62807
62807
62807
62807
62817
62817
62817
62814
62814
62814
62814
39239
39239
39272
39272
39272
39272
39256
39256
39256
39256
39256
39256
71341
71341
71341
71341
66638
66638
66638
66638
6078
Date
19821116
19821116
19821116
19821116
19821117
19821117
19821117
19821117
19821118
19821118
19821118
19821118
19821119
19821119
19821119
19821119
19821120
19821120
19821121
19821121
19821122
19821122
19821122
19821122
19821123
19821123
19821123
19821123
19821123
19821124
19821124
19830817
19830817
19830817
19830817
19830817
19830818
19830822
19830822
19830822
19830823
19830823
19830823
19830823
19830823
19830824
19830824
19830824
19830824
19830829
19830829
19830830
181
181
182
182
183
183
184
184
185
185
186
186
187
187
188
188
189
189
190
190
191
191
192
192
193
194
194
195
195
196
196
197
197
198
198
199
199
200
200
200
201
201
201
202
202
203
203
204
204
205
205
206
Run
Gas Vol
CO2
cc
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
Vol
Tot
cc
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.31
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
Temp
CO2
o ∗
C
22.21
22.32
22.54
22.60
22.20
22.41
22.52
22.55
22.09
22.52
22.58
22.59
22.46
22.60
22.52
22.51
22.16
22.21
21.97
22.10
21.88
22.17
22.24
22.32
21.68
22.22
22.30
22.44
22.50
21.99
22.22
22.53
22.77
23.23
23.43
23.82
22.38
21.91
22.07
22.42
22.54
22.67
22.76
22.78
22.86
22.42
22.62
23.13
23.35
24.69
24.97
23.83
Temp
Tot
o ∗
C
22.49
22.49
22.27
22.27
22.53
22.53
22.23
22.23
22.52
22.52
22.15
22.15
22.58
22.58
22.47
22.47
22.51
22.51
22.17
22.17
22.04
22.04
22.10
22.10
22.28
21.76
21.76
22.25
22.25
22.47
22.47
23.33
23.33
22.64
22.64
23.28
23.28
21.57
21.57
21.57
21.98
21.98
21.98
22.63
22.63
22.80
22.80
22.52
22.52
23.77
23.77
24.82
HtVac
CO2
mm
646.108
646.157
644.962
645.022
662.768
662.940
665.538
665.514
655.198
655.611
656.354
656.329
675.997
676.127
677.698
677.677
620.370
620.424
620.742
620.828
654.258
654.450
654.044
654.118
675.892
676.450
676.489
726.214
726.283
722.680
722.991
647.458
647.680
672.139
672.332
671.094
669.457
663.374
663.454
663.839
661.814
661.644
661.804
641.893
641.942
640.178
640.308
655.166
655.367
654.620
654.890
630.120
HtVac
Tot
mm
801.696
801.696
797.767
797.767
796.430
796.430
800.914
800.914
799.231
799.231
799.915
799.915
799.256
799.256
802.615
802.615
801.470
801.470
802.100
802.100
802.541
802.541
801.455
801.455
802.477
801.197
801.197
803.321
803.321
798.421
798.421
800.009
800.009
801.112
801.112
798.945
798.945
808.933
808.933
808.933
804.852
804.852
804.852
804.346
804.346
801.515
801.515
803.572
803.572
801.672
801.672
801.880
HtSmp
CO2
mm
374.992
374.980
374.968
374.982
374.977
374.980
374.988
374.964
375.002
374.993
374.992
374.972
374.990
374.978
374.982
374.974
374.996
374.964
375.002
374.967
375.012
374.944
374.995
374.974
374.989
374.966
374.952
374.988
374.953
374.996
375.006
374.993
374.963
374.965
374.950
374.982
374.982
375.024
375.000
375.012
375.024
374.980
375.005
375.008
374.986
375.016
374.988
374.990
374.987
374.993
374.974
374.992
HtSmp
Tot
mm
177.776
177.776
177.600
177.600
177.648
177.648
177.636
177.636
177.628
177.628
177.634
177.634
177.636
177.636
177.653
177.653
177.606
177.606
177.670
177.670
177.660
177.660
177.678
177.678
177.645
177.636
177.636
177.656
177.656
177.644
177.644
177.594
177.594
177.612
177.612
177.676
177.676
177.698
177.698
177.698
177.687
177.687
177.687
177.668
177.668
177.655
177.655
177.642
177.642
177.636
177.636
177.671
Table A7: Manometric Reference Gas Measurements: Original Data. Page 8/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.24
0.24
0.24
0.24
0.29
0.29
0.29
0.29
0.28
0.28
0.28
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.00
ppm
329.37
329.31
329.34
329.32
352.68
352.62
352.72
352.68
341.90
341.89
341.90
341.88
366.98
366.97
366.87
366.87
298.13
298.18
298.15
298.16
338.63
338.59
338.62
338.64
365.62
365.68
365.64
425.22
425.26
425.26
425.27
332.76
332.78
360.61
360.61
360.67
360.53
345.90
345.82
345.84
345.98
345.66
345.72
322.27
322.26
322.24
322.20
338.23
338.21
338.22
338.23
310.83
CO2
TEMPERATURE DROPPING DURING
MEASUREMENT
POOR APPROACH-HG CONTROL LEAKING
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
Cyl
6078
6078
6078
66625
66625
66625
66625
2399
2399
2399
2399
66696
66696
66696
66696
39239
39239
71308
71308
71308
71308
1540
1540
1540
1540
71286
71286
71286
71286
7366
7366
7366
71370
71370
71370
71370
35299
35299
35299
35299
34819
34819
34819
34819
3753
3753
3753
3753
71479
71479
71479
71479
35316
Date
19830830
19830830
19830830
19830831
19830831
19830831
19830831
19830920
19830920
19830921
19830921
19830921
19830921
19830922
19830922
19830926
19830926
19830926
19830926
19830928
19830928
19830928
19830928
19830929
19830929
19830929
19830929
19830930
19830930
19830930
19830930
19830930
19831004
19831004
19831004
19831004
19831005
19831005
19831005
19831005
19831005
19831005
19831006
19831006
19831006
19831006
19831007
19831007
19831007
19831007
19831020
19831020
19831021
206
207
207
208
208
209
209
210
210
211
211
212
212
213
213
214
214
215
215
216
216
217
217
218
218
219
219
220
220
221
222
222
223
223
224
224
225
225
226
226
227
227
228
228
229
229
230
230
231
231
232
232
233
Run
Gas Vol
CO2
cc
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
Vol
Tot
cc
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
Temp
CO2
o ∗
C
23.71
23.29
23.34
22.42
22.44
22.30
22.42
22.89
22.99
22.09
22.26
23.02
23.19
22.40
22.53
21.95
21.99
22.07
22.17
22.23
22.52
23.00
23.22
22.82
23.14
23.87
24.10
22.62
22.87
23.67
24.42
24.48
22.23
22.40
22.53
22.61
22.12
22.23
22.38
22.46
22.38
22.46
21.99
22.10
22.59
22.79
22.22
22.38
22.52
22.63
22.19
22.32
22.01
Temp
Tot
o ∗
C
24.82
23.78
23.78
23.31
23.31
22.45
22.45
22.29
22.29
22.93
22.93
22.18
22.18
23.10
23.10
21.98
21.98
21.96
21.96
22.08
22.08
22.39
22.39
23.12
23.12
22.96
22.96
23.98
23.98
22.74
23.76
23.76
22.19
22.19
22.33
22.33
22.57
22.57
22.17
22.17
22.42
22.42
22.42
22.42
22.05
22.05
22.72
22.72
22.31
22.31
21.86
21.86
22.25
HtVac
CO2
mm
629.926
628.416
628.450
657.323
657.310
658.234
658.347
643.980
644.119
642.946
643.110
674.511
674.656
672.753
672.822
651.204
651.189
687.505
687.596
687.287
687.548
690.080
690.304
687.675
687.984
620.818
620.918
618.518
618.704
601.524
603.530
603.598
710.935
711.054
711.847
711.922
718.144
718.204
719.065
718.985
584.722
584.762
583.729
583.746
578.884
579.102
578.176
578.245
750.369
750.516
750.416
750.565
764.917
HtVac
Tot
mm
801.880
796.836
796.836
800.379
800.379
800.723
800.723
805.522
805.522
806.469
806.469
806.221
806.221
805.853
805.853
806.998
806.998
806.854
806.854
806.257
806.257
804.416
804.416
801.750
801.750
802.842
802.842
801.911
801.911
796.230
802.491
802.491
804.023
804.023
805.470
805.470
805.920
805.920
806.080
806.080
807.952
807.952
805.797
805.797
804.099
804.099
804.016
804.016
805.064
805.064
804.646
804.646
804.282
HtSmp
CO2
mm
374.986
374.954
374.953
374.986
374.965
374.984
374.977
374.984
374.976
375.010
374.951
375.000
374.928
374.969
374.965
374.992
374.961
374.980
374.956
374.990
374.954
374.974
374.948
374.956
374.912
374.962
374.932
374.966
374.912
374.933
374.944
374.940
374.956
374.936
374.956
374.930
374.984
374.938
374.953
374.936
374.966
374.960
374.976
374.934
374.972
374.944
374.995
374.950
374.960
374.958
374.984
374.938
374.978
HtSmp
Tot
mm
177.671
177.672
177.672
177.676
177.676
177.678
177.678
177.614
177.614
177.712
177.712
177.679
177.679
177.743
177.743
177.712
177.712
177.756
177.756
177.708
177.708
177.746
177.746
177.749
177.749
177.742
177.742
177.633
177.633
177.692
177.719
177.719
177.660
177.660
177.700
177.700
177.708
177.708
177.745
177.745
177.669
177.669
177.738
177.738
177.670
177.670
177.658
177.658
177.594
177.594
177.608
177.608
177.847
Table A7: Manometric Reference Gas Measurements: Original Data. Page 9/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.00
0.00
0.32
0.32
0.32
0.32
0.00
0.00
0.00
0.00
0.32
0.32
0.32
0.32
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.24
0.24
0.24
0.24
0.00
0.00
0.00
0.00
0.30
0.30
0.30
0.30
0.00
ppm
310.73
310.76
310.75
344.48
344.47
344.50
344.50
324.01
324.07
323.96
324.03
359.87
359.92
360.01
359.93
332.76
332.73
376.22
376.22
376.22
376.18
380.48
380.49
380.44
380.44
296.71
296.62
296.70
296.72
276.59
276.52
276.55
406.45
406.37
406.41
406.42
415.03
415.00
415.13
414.93
251.82
251.80
251.85
251.82
246.04
246.16
246.09
246.09
453.29
453.30
453.44
453.47
472.81
CO2
HG JUMPING-CONTACTED POINTER
PREMATURELY
HG CONTROL LEAKING-POSSIBLE
HG CONTROL LEAKING-POSSIBLE
OVERESTIMATION
HG CONTACTED POINTER PREMATURELY
Comment
11429 256
11062 257
11062 257
11835 258
19850612
19850612
19850612
19850612
233
234
234
235
235
236
236
237
237
238
238
239
239
240
240
241
241
242
242
243
243
244
244
245
245
246
246
247
247
248
248
249
249
250
250
251
251
252
252
253
253
254
254
255
255
256
35316
35316
35316
71251
71251
71251
71251
2408
2408
2408
2408
67615
67615
67615
67615
2408
2408
39239
39239
66556
66556
66556
66556
39239
39239
39239
39239
66625
66625
66625
66625
62807
62807
62817
62817
39256
39256
11429
11429
11062
11062
11835
11835
83398
83398
11429
19831021
19831021
19831021
19831021
19831021
19831025
19831025
19831025
19831025
19831026
19831026
19831026
19831026
19831027
19831027
19831027
19831027
19831027
19831027
19831031
19831031
19831101
19831101
19831108
19831108
19831109
19831109
19831109
19831109
19831110
19831110
19840109
19840109
19840110
19840110
19841030
19841030
19841030
19841030
19841030
19841030
19841031
19841031
19850206
19850206
19850612
Run
Cyl
Date
Vol
Tot
cc
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.32
5014.33
5014.33
5014.33
5014.33
5014.33
5014.33
5014.33
5014.33
5014.34
5014.34
5014.33
AIR 3.7934 5014.33
AIR 3.7934 5014.33
AIR 3.7934 5014.33
AIR 3.7934 5014.33
Gas Vol
CO2
cc
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
N2 3.7993
N2 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7993
AIR 3.7934
AIR 3.7934
AIR 3.7934
22.63
22.56
22.62
22.60
Temp
CO2
o ∗
C
22.15
22.22
22.20
22.04
22.09
21.97
22.01
22.05
22.16
21.70
21.84
22.28
22.47
21.89
22.10
22.39
22.70
22.74
22.80
22.10
22.20
21.95
22.08
22.24
22.34
21.59
21.75
22.19
22.30
21.92
22.13
21.24
21.31
21.23
21.30
21.62
21.84
22.24
22.33
22.52
22.59
21.08
21.21
22.02
22.13
22.48
22.29
22.57
21.73
22.29
Temp
Tot
o ∗
C
22.25
22.08
22.08
22.21
22.21
21.35
21.35
21.97
21.97
22.10
22.10
21.75
21.75
22.35
22.35
21.97
21.97
22.47
22.47
22.09
22.09
22.16
22.16
21.77
21.77
22.30
22.30
21.65
21.65
22.27
22.27
21.52
21.52
21.30
21.30
21.88
21.88
21.73
21.73
22.29
22.29
22.57
22.57
21.69
21.69
21.73
HtVac
Tot
mm
804.282
802.989
802.989
806.872
806.872
809.473
809.473
803.300
803.300
730.181
730.181
804.534
804.534
803.478
803.478
799.498
799.498
805.703
805.703
808.456
808.456
806.237
806.237
809.382
809.382
806.000
806.000
809.619
809.619
817.272
817.272
814.660
814.660
804.347
804.347
797.171
797.171
803.935
803.935
808.261
808.261
803.402
803.402
509.874
509.874
803.935
HtSmp
CO2
mm
374.956
374.958
374.942
374.962
374.966
375.287
375.256
375.311
375.269
375.324
375.248
375.294
375.246
375.266
375.240
375.260
375.254
375.268
375.250
375.295
375.266
375.288
375.289
375.325
375.283
375.314
375.284
375.295
375.284
375.290
375.282
375.294
375.283
375.278
375.264
374.996
374.954
374.988
374.972
374.964
374.929
374.973
374.988
375.022
375.010
375.188
HtSmp
Tot
mm
177.847
177.750
177.750
177.684
177.684
178.058
178.058
178.130
178.130
178.048
178.048
178.070
178.070
178.162
178.162
178.046
178.046
178.002
178.002
178.084
178.084
178.062
178.062
178.141
178.141
178.033
178.033
178.102
178.102
178.088
178.088
177.938
177.938
177.920
177.920
177.592
177.592
177.670
177.670
177.742
177.742
177.630
177.630
177.726
177.726
177.670
MnCor
CO2
mm
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.364
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.042
-0.005
-0.005
-0.042
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.00
0.00
0.00
0.34
0.34
0.34
0.34
0.00
0.00
0.00
0.00
0.30
0.30
0.30
0.30
0.00
0.00
0.00
0.00
0.37
0.37
0.37
0.37
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.29
0.29
0.28
0.28
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.00
688.106 808.261 375.166 177.742 -0.303 -0.042 0.00
626.626 803.402 375.156 177.630 -0.303 -0.042 0.00
0
0
0
0
Flg
N2 O
658.737 803.935 375.176 177.670 -0.303 -0.042 0.00
688.147 808.261 375.192 177.742 -0.303 -0.042 0.00
HtVac
CO2
mm
764.986
764.656
764.553
552.342
552.412
553.775
553.825
538.004
538.048
518.752
518.804
792.030
792.255
789.776
789.976
537.170
537.327
651.038
651.112
460.006
460.012
459.606
459.604
652.839
652.926
650.214
650.339
663.180
663.216
665.740
665.920
659.627
659.661
677.375
677.490
657.301
657.459
657.908
657.952
687.430
687.433
624.888
624.972
827.697
827.764
658.670
Table A7: Manometric Reference Gas Measurements: Original Data. Page 10/34
∗
Temperature corrected for thermometer drift
Comment
ppm
472.68
472.77 HG CONTACTED POINTER PREMATURELY
472.70
213.17
213.21
213.14
213.21
196.88
196.90
196.78
196.86
503.65
503.64
503.66
503.55
196.86
196.84
332.70
332.74
101.04
101.05
101.00
100.95
332.70
332.73 HG CONTACTED POINTER PREMATURELY
332.68
332.67
344.61
344.53
344.61
344.58
338.55
338.52 HG CONTACTED POINTER PREMATURELY
365.45
365.51
345.74
345.71
341.81
341.77
375.45
375.41
304.23
304.17
1031.86
1031.63
341.74 RERUN MEASUREMENT-SAMPLE STORED
IN FLAME OFF TUBE
341.66 RERUN MEASUREMENT-SAMPLE STORED
375.43 RERUN MEASUREMENT-SAMPLE STORED
IN FLAME OFF TUBE
375.37 RERUN MEASUREMENT-SAMPLE STORED
304.11 RERUN MEASUREMENT-SAMPLE STORED
IN FLAME OFF TUBE
CO2
Cyl
11835
8386
8386
8699
8699
8433
8433
39239
39239
39272
39272
39272
39272
39256
39256
39256
39256
71341
71341
71341
71341
66638
66638
66638
66638
6078
6078
6078
6078
66625
66625
66625
66625
2399
2399
2399
2399
18027
18027
18067
18067
16417
16417
39239
39239
66696
66696
66696
66696
71308
71308
71308
71308
Date
19850612
19850614
19850614
19850614
19850614
19850617
19850617
19850619
19850619
19850620
19850620
19850621
19850621
19850625
19850625
19850626
19850626
19850626
19850626
19850626
19850626
19850627
19850627
19850710
19850710
19850710
19850710
19850711
19850711
19850711
19850711
19850712
19860712
19850712
19850712
19850729
19850729
19850730
19850730
19850730
19850730
19850731
19850731
19850731
19850731
19850801
19850801
19850801
19850801
19850805
19850805
19850806
19850806
258
259
259
260
260
261
261
262
262
263
263
264
264
265
265
266
266
267
267
268
268
269
269
270
270
271
271
272
272
273
273
274
274
275
275
276
276
277
277
278
278
279
279
280
280
281
281
282
282
283
283
284
284
Run
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
Vol
Tot
cc
5014.33
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
Temp
CO2
o ∗
C
22.59
22.32
22.40
22.36
22.45
22.52
22.57
22.49
22.55
22.44
22.47
22.30
22.36
22.52
22.56
22.33
22.32
22.36
22.41
22.56
22.64
22.48
22.51
22.73
22.87
23.43
23.57
22.77
22.89
23.42
23.53
22.83
22.91
23.21
23.35
22.93
22.97
22.62
22.73
23.06
23.16
23.04
23.22
23.23
23.31
22.91
22.93
22.92
22.94
22.73
22.81
22.36
22.46
Temp
Tot
o ∗
C
22.57
22.30
22.30
22.35
22.35
22.39
22.39
22.25
22.25
22.51
22.51
22.45
22.45
22.63
22.63
22.54
22.54
22.32
22.32
22.38
22.38
22.59
22.59
23.56
23.56
22.81
22.81
23.47
23.47
22.83
22.83
23.48
23.47
22.88
22.88
22.61
22.61
22.95
22.95
22.65
22.65
23.10
23.10
23.14
23.14
23.27
23.27
22.92
22.92
22.43
22.43
22.76
22.76
HtVac
CO2
mm
626.660
653.411
653.525
622.488
622.643
682.346
682.402
646.623
646.704
668.286
668.379
667.343
667.466
657.727
657.676
657.174
657.166
636.603
636.602
638.038
638.112
649.824
649.794
650.590
650.656
628.619
628.720
628.620
628.708
656.086
656.180
656.732
656.801
638.640
638.784
639.194
639.176
647.850
647.900
654.797
654.848
660.863
661.054
647.659
647.704
667.961
667.899
668.727
668.754
683.148
683.209
682.976
683.057
HtVac
Tot
mm
803.402
793.876
793.876
792.742
792.742
797.631
797.631
794.981
794.981
793.553
793.553
791.596
791.596
796.749
796.749
795.779
795.779
791.245
791.245
794.284
794.284
791.920
791.920
795.257
795.257
793.274
793.274
796.174
796.174
792.844
792.844
796.954
796.954
792.376
792.376
794.043
794.043
792.599
792.599
794.545
794.545
793.782
793.782
797.378
797.378
793.874
793.874
794.438
794.438
797.427
797.427
797.713
797.713
HtSmp
CO2
mm
375.164
375.155
375.148
375.150
375.152
375.169
375.165
375.165
375.162
375.146
375.133
375.161
375.125
375.162
375.156
375.156
375.143
375.186
375.144
375.154
375.141
375.156
375.132
375.156
375.151
375.152
375.144
375.160
375.141
375.156
375.140
375.166
375.132
375.140
375.142
375.140
375.127
375.167
375.144
375.152
375.145
375.118
375.125
375.124
375.112
375.138
375.106
375.116
375.116
375.159
375.122
375.155
375.138
HtSmp
Tot
mm
177.630
177.826
177.826
177.750
177.750
177.868
177.868
177.767
177.767
177.832
177.832
177.824
177.824
177.812
177.812
177.820
177.820
177.800
177.800
177.798
177.798
177.796
177.796
177.819
177.819
177.732
177.732
177.724
177.724
177.769
177.769
177.750
177.750
177.705
177.705
177.742
177.742
177.766
177.766
177.758
177.758
177.808
177.808
177.735
177.735
177.896
177.896
177.734
177.734
177.868
177.868
177.832
177.832
Table A7: Manometric Reference Gas Measurements: Original Data. Page 11/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.042
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
N2 O
ppm
0.00
0.30
0.30
0.27
0.27
0.33
0.33
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.32
0.32
0.32
0.32
Comment
ppm
304.10 RERUN MEASUREMENT-SAMPLE STORED
341.55
341.61
304.03
304.12
374.76
374.76
332.62
332.65
360.54
360.63
360.60
360.72
345.74
345.63
345.74
345.76
322.14
322.13
322.19
322.21
338.34
338.29
338.33
338.25
310.93
310.91
310.92
310.92
344.70
344.70
344.70
344.71
324.07
324.08
323.91
323.86
336.07
336.03
342.36
342.31
351.22
351.22
332.81
332.78
360.02
359.96
360.11
360.11
375.66
375.67
376.20
376.18
CO2
Cyl
1540
1540
1540
1540
71286
71286
71286
71286
71308
71308
7366
7366
7366
7366
71370
71370
71370
71370
35299
35299
35299
35299
71308
71308
39239
39239
34819
34819
34819
34819
3753
3753
3753
3753
71479
71479
71479
71479
35316
35316
35316
35316
71251
71251
71251
71251
2408
2408
2408
2408
67615
67615
67615
Date
19850806
19850806
19850807
19850807
19850807
19850807
19850807
19850807
19850812
19850812
19850813
19850813
19850813
19850813
19850813
19850813
19850814
19850814
19850814
19850814
19850814
19850814
19850819
19850819
19850820
19850820
19850820
19850820
19850820
19850821
19850821
19850821
19850821
19850821
19850827
19850827
19850827
19850827
19850828
19850828
19850828
19850828
19850829
19850829
19850829
19850829
19850903
19850903
19850904
19850904
19850904
19850904
19850905
285
285
286
286
287
287
288
288
289
289
290
290
291
291
292
292
293
293
294
294
295
295
296
296
297
297
298
298
299
299
300
300
301
301
302
302
303
303
304
304
305
305
306
306
307
307
308
308
309
309
310
310
311
Run
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
Vol
Tot
cc
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
Temp
CO2
o ∗
C
22.76
22.84
22.70
22.72
22.79
22.90
23.16
23.43
22.37
22.44
22.61
22.64
22.53
22.56
22.95
23.06
24.02
24.14
23.64
23.68
23.40
23.45
22.31
22.44
22.70
22.75
22.68
22.71
22.54
22.64
22.65
22.68
22.65
22.71
23.14
23.20
23.12
23.20
23.08
23.15
23.13
23.20
22.50
22.64
23.71
23.97
22.18
22.25
22.40
22.43
22.60
22.63
22.47
Temp
Tot
o ∗
C
22.39
22.39
22.80
22.80
22.71
22.71
22.84
22.84
22.13
22.13
22.40
22.40
22.62
22.62
22.55
22.55
23.00
23.00
24.10
24.10
23.65
23.65
22.05
22.05
22.39
22.39
22.72
22.72
22.69
22.69
22.58
22.58
22.67
22.67
22.98
22.98
23.16
23.16
23.15
23.15
23.10
23.10
23.16
23.16
22.57
22.57
22.04
22.04
22.20
22.20
22.41
22.41
22.61
HtVac
CO2
mm
686.373
686.488
685.572
685.514
617.361
617.392
618.912
619.151
683.071
683.208
602.550
602.508
600.960
600.936
709.354
709.488
708.851
708.984
712.963
713.092
713.126
713.194
683.032
683.174
647.224
647.241
580.944
580.941
581.280
581.306
575.920
576.031
575.822
575.882
745.836
745.824
743.680
743.799
761.173
761.212
758.595
758.534
549.080
549.135
549.080
549.238
535.486
535.498
535.340
535.272
784.788
784.913
785.737
HtVac
Tot
mm
796.210
796.210
795.364
795.364
794.780
794.780
798.142
798.142
797.028
797.028
799.158
799.158
795.570
795.570
799.190
799.190
796.857
796.857
795.598
795.598
795.372
795.372
796.525
796.525
796.288
796.288
795.682
795.682
797.353
797.353
795.349
795.349
795.029
795.029
796.446
796.446
793.554
793.554
796.800
796.800
792.540
792.540
795.561
795.561
791.880
791.880
793.650
793.650
793.029
793.029
793.725
793.725
795.577
HtSmp
CO2
mm
375.158
375.133
375.157
375.122
375.127
375.102
375.120
375.128
375.130
375.115
375.122
375.102
375.136
375.102
375.104
375.096
375.101
375.110
375.101
375.104
375.086
375.085
374.910
374.896
374.914
374.894
374.916
374.874
374.900
374.908
374.916
374.910
374.888
374.914
374.962
374.938
374.957
374.922
374.949
374.910
374.938
374.912
374.918
374.894
374.928
374.918
374.969
374.944
374.942
374.916
374.905
374.896
374.924
HtSmp
Tot
mm
177.768
177.768
177.669
177.669
177.880
177.880
177.749
177.749
177.835
177.835
177.755
177.755
177.748
177.748
177.696
177.696
177.772
177.772
177.800
177.800
177.764
177.764
177.595
177.595
177.587
177.587
177.574
177.574
177.637
177.637
177.601
177.601
177.598
177.598
177.595
177.595
177.616
177.616
177.664
177.664
177.660
177.660
177.584
177.584
177.610
177.610
177.630
177.630
177.623
177.623
177.598
177.598
177.568
Table A7: Manometric Reference Gas Measurements: Original Data. Page 12/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.32
0.32
0.32
0.32
0.32
0.32
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.32
0.32
0.00
0.00
0.24
0.24
0.24
0.24
0.00
0.00
0.00
0.00
0.30
0.30
0.30
0.30
0.00
0.00
0.00
0.00
0.34
0.34
0.34
0.34
0.00
0.00
0.00
0.00
0.30
0.30
0.30
Comment
ppm
380.56
380.62
380.67
380.62
296.68
296.63
296.66
296.66
375.90
375.99
276.68
276.62
276.61
276.59
406.41
406.43
406.48
406.45
414.90 HG CONTACTED POINTER PREMATURELY
414.99
414.94
414.95
376.26
376.27
332.78
332.77
251.87
251.89
251.74
251.68
246.01 HG CONTACTED POINTER PREMATURELY
246.13
246.13
246.12
453.46
453.37
453.27
453.33
472.82
472.80
472.75
472.59 HG CONTACTED POINTER PREMATURELY
213.19
213.18
213.09
213.10
196.83
196.83
196.84
196.77
503.52
503.63
503.73
CO2
18067 335
18067 335
19851217
19851217
311
312
312
313
313
314
314
315
315
316
316
317
317
318
318
319
319
320
320
321
321
322
322
323
323
324
324
325
325
326
326
327
327
328
328
329
329
330
330
331
331
332
332
333
333
334
334
335
67615
66556
66556
66556
66556
39239
39239
83230
83230
83230
83230
83369
83369
83369
83369
83377
83377
83377
83377
83378
83378
83378
83378
83379
83379
83379
83379
83382
83382
83382
83382
83389
83389
83389
83389
11835
11835
11429
11429
11062
11062
18067
18067
16417
16417
18027
18027
18067
19850905
19850905
19850905
19850906
19850906
19850906
19850906
19850910
19850910
19850911
19850911
19850911
19850911
19850911
19850911
19850916
19850916
19850918
19850918
19850919
19850919
19850920
19850920
19850920
19850920
19850920
19850920
19850925
19850925
19850925
19850925
19850925
19850925
19850926
19850926
19850926
19850926
19850927
19850927
19850927
19850927
19851212
19851212
19851212
19851212
19851213
19851213
19851217
Run
Cyl
Date
Vol
Tot
cc
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.34
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
AIR 3.7934 5014.35
AIR 3.7934 5014.35
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
22.17
22.12
Temp
CO2
o ∗
C
22.50
22.33
22.36
21.99
22.04
22.06
22.12
22.36
22.40
22.07
22.10
22.26
22.33
22.41
22.47
22.00
22.08
22.23
22.26
22.14
22.18
22.27
22.29
22.21
22.25
22.29
22.33
22.14
22.18
22.23
22.30
22.63
22.74
22.18
22.24
22.32
22.36
22.30
22.34
22.13
22.23
20.58
20.73
21.24
21.33
21.04
21.18
22.03
19.83
19.83
Temp
Tot
o ∗
C
22.61
22.48
22.48
22.34
22.34
22.00
22.00
22.31
22.31
22.38
22.38
22.08
22.08
22.29
22.29
21.48
21.48
22.03
22.03
22.24
22.24
22.16
22.16
22.28
22.28
22.22
22.22
22.41
22.41
22.16
22.16
22.25
22.25
22.68
22.68
22.21
22.21
22.34
22.34
22.32
22.32
19.83
19.83
20.68
20.68
21.27
21.27
19.83
HtVac
Tot
mm
795.577
793.955
793.955
795.009
795.009
796.725
796.725
794.960
794.960
794.236
794.236
793.595
793.595
796.584
796.584
796.740
796.740
796.906
796.906
793.302
793.302
796.535
796.535
795.603
795.603
797.256
797.256
799.467
799.467
793.728
793.728
794.707
794.707
795.295
795.295
796.441
796.441
795.355
795.355
793.845
793.845
792.926
792.926
766.487
766.487
788.886
788.886
792.926
HtSmp
CO2
mm
374.903
374.906
374.904
374.916
374.889
374.898
374.892
374.897
374.909
374.889
374.894
374.902
374.826
374.878
374.865
374.912
374.892
374.930
374.868
374.894
374.874
374.903
374.877
374.900
374.844
374.886
374.899
374.934
374.892
374.900
374.916
374.907
374.889
374.917
374.894
374.902
374.896
374.908
374.914
374.910
374.888
374.776
374.756
374.790
374.770
374.800
374.798
374.810
HtSmp
Tot
mm
177.568
177.576
177.576
177.613
177.613
177.578
177.578
177.599
177.599
177.590
177.590
177.602
177.602
177.598
177.598
177.614
177.614
177.696
177.696
177.632
177.632
177.628
177.628
177.570
177.570
177.556
177.556
177.590
177.590
177.598
177.598
177.479
177.479
177.562
177.562
177.568
177.568
177.567
177.567
177.553
177.553
177.489
177.489
177.464
177.464
177.502
177.502
177.489
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.30
0.37
0.37
0.37
0.37
0.00
0.00
0.30
0.30
0.30
0.30
0.29
0.29
0.29
0.29
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.00
0.00
0.00
0.00
0.31
655.856 792.926 374.801 177.489 -0.303 -0.005 0.31
0
0
Flg
N2 O
655.751 792.926 374.791 177.489 -0.303 -0.005 0.31
HtVac
CO2
mm
785.767
457.691
457.696
457.749
457.736
647.118
647.154
533.387
533.408
533.017
533.042
596.611
596.631
597.644
597.703
641.044
641.082
640.720
640.787
659.852
659.906
661.660
661.638
680.138
680.176
681.092
681.188
701.712
701.682
698.930
699.086
792.356
792.525
791.494
791.569
623.843
623.776
653.850
653.825
680.404
680.472
654.261
654.505
648.712
648.928
646.053
646.204
655.725
Table A7: Manometric Reference Gas Measurements: Original Data. Page 13/34
∗
Temperature corrected for thermometer drift
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
RERUN M’MENT ON F.O.T. SAMPLE-HG
CONTACTED POINTER PREMATURELY
342.42 RERUN M’MENT-SAMPLE NO. 2 STORED
IN FLAME OFF TUBE
342.47 RERUN M’MENT ON F.O.T. SAMPLE FANS OFF DURING MEASUREMENT
ppm
503.74
100.95
100.94
100.91
100.91
332.73
332.71
193.66
193.64
193.69
193.69
271.78
271.83
271.82
271.85
324.41
324.39
324.32
324.44
350.18
350.22
350.29
350.27
373.72
373.78
373.71
373.76
398.00
397.96
397.84
397.92
511.58
511.61
511.71
511.72
304.25
304.13
341.81
341.72
375.56
375.54
342.51
342.65
351.28
351.47
336.08
336.10
342.47
CO2
16417 336
18027 337
18027
83398
83398
83391
83391
83391
83391
83392
83392
83392
83392
83392
83412
83412
83412
83412
83398
83398
2405
2405
39256
39256
4826
4826
4826
4826
4827
4827
4827
4827
4828
4828
4828
4828
4829
4829
4829
4829
39256
39256
34891
34891
34891
34891
62814
62814
62814
19851218
19851218
19851218
19860211
19860211
19860211
19860211
19860212
19860212
19860213
19860213
19860214
19860219
19860219
19860220
19860220
19860220
19860220
19860221
19860221
19860221
19860221
19870331
19870331
19870401
19870402
19870402
19870402
19870402
19870402
19870403
19870403
19870408
19870408
19870408
19870408
19870409
19870409
19870409
19870409
19870527
19870527
19870527
19870527
19870528
19870528
19870528
19870528
19870529
337
338
338
339
339
340
340
341
341
342
343
343
344
344
345
345
346
346
347
347
348
348
349
349
350
350
351
351
352
352
353
353
354
354
355
355
356
356
357
357
358
358
359
359
360
360
361
18067 335
16417 336
19851217
19851218
Run
Cyl
Date
Vol
Tot
cc
5014.35
5014.35
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
N2
N2
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
N2
N2
AIR
AIR
AIR
AIR
AIR
AIR
AIR
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.35
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
AIR 3.7934 5014.35
AIR 3.7934 5014.35
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
21.63
20.94
21.05
21.38
21.44
21.74
21.78
21.62
21.67
21.92
21.88
21.93
21.33
21.43
21.50
21.54
21.57
21.61
21.58
21.69
21.77
21.80
21.73
21.40
21.82
21.93
21.99
22.04
21.45
21.51
21.72
21.85
21.80
21.84
21.10
21.27
21.70
21.79
21.21
21.35
21.87
22.00
21.56
21.65
21.81
21.91
21.88
21.45
21.63
Temp
CO2
o ∗
C
22.17
21.45
21.27
20.92
20.92
20.99
20.99
21.41
21.41
21.76
21.76
21.65
21.77
21.77
21.91
21.91
21.38
21.38
21.52
21.52
21.59
21.59
21.15
21.15
21.78
21.78
21.77
21.77
21.86
21.86
22.01
22.01
21.48
21.48
21.75
21.75
21.81
21.81
21.16
21.16
21.62
21.62
21.25
21.25
21.92
21.92
21.60
21.60
21.84
20.68
21.27
Temp
Tot
o ∗
C
19.83
20.68
HtVac
Tot
mm
792.926
766.487
HtSmp
CO2
mm
374.778
374.792
HtSmp
Tot
mm
177.489
177.464
MnCor
CO2
mm
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
0
0
ppm
0.31
0.00
646.525
824.260
824.394
784.422
784.696
782.222
782.220
779.308
779.334
659.041
787.850
788.014
781.596
781.674
771.553
771.654
784.594
784.638
788.676
788.900
650.692
650.680
639.483
639.308
639.510
639.668
647.514
647.640
650.386
650.452
658.131
658.262
657.514
657.510
666.356
666.540
672.363
672.502
653.146
653.309
614.801
614.850
614.069
614.126
717.223
717.342
717.222
788.886
507.544
507.544
682.015
682.015
679.084
679.084
544.101
544.101
542.435
551.593
551.593
420.318
420.318
413.771
413.771
478.399
478.399
426.030
426.030
780.177
780.177
783.194
783.194
783.023
783.023
785.881
785.881
793.611
793.611
787.409
787.409
786.437
786.437
781.944
781.944
791.502
791.502
788.201
788.201
784.818
784.818
785.238
785.238
787.334
787.334
787.829
374.810
374.901
374.872
374.908
374.881
374.880
374.896
374.915
374.894
374.904
374.945
374.953
374.966
374.945
374.955
374.956
374.788
374.780
374.776
374.775
374.848
374.800
374.860
374.828
374.822
374.798
374.826
374.792
374.823
374.800
374.828
374.822
374.836
374.807
374.830
374.795
374.843
374.833
374.874
374.822
374.848
374.816
374.844
374.836
374.868
374.847
374.850
177.502
177.556
177.556
177.536
177.536
177.504
177.504
177.527
177.527
177.560
177.652
177.652
177.646
177.646
177.632
177.632
177.604
177.604
177.503
177.503
177.456
177.456
177.510
177.510
177.469
177.469
177.466
177.466
177.488
177.488
177.532
177.532
177.512
177.512
177.490
177.490
177.490
177.490
177.515
177.515
177.534
177.534
177.570
177.570
177.491
177.491
177.578
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0.00
0.31
0.31
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.31
0.31
0.31
0.31
0.31
0.31
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.24
0.24
0.24
0.24
0.31
0.31
0.31
0
0
0
0
0
0
0
0
0
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Flg
N2 O
648.944 766.487 374.792 177.464 -0.303 -0.005 0.00
646.572 788.886 374.838 177.502 -0.303 -0.005 0.00
HtVac
CO2
mm
655.787
648.894
Table A7: Manometric Reference Gas Measurements: Original Data. Page 14/34
∗
Temperature corrected for thermometer drift
Comment
ppm
342.42 RERUN M’MENT-SAMPLE NO. 2 STORED
351.25 RERUN M’MENT-SAMPLE NO. 2 STORED
IN FLAME OFF TUBE
351.31 RERUN M’MENT-SAMPLE NO. 2 STORED
335.96 RERUN M’MENT-SAMPLE NO. 2 STORED
IN FLAME OFF TUBE
335.94 RERUN M’MENT-SAMPLE NO. 2 STORED
1032.16
1032.12
614.08
614.40
614.47
614.35
836.24
836.19
588.67 REJECT- LOST CO2 DURING EXTRACTION
836.32
836.49
1272.45
1272.30
1272.09
1272.23
1032.20
1032.18
1262.19
1262.38
345.67 HG CONTACTED POINTER PREMATURELY
345.68
330.71
330.92
330.74
330.84
339.07
339.20
339.20
339.24
351.32
351.33
351.33
351.31
366.04
366.09
366.13
366.19
345.45 HG CONTACTED POINTER PREMATURELY
345.54
298.04
298.00
297.99
297.98
424.56 HG CONTACTED POINTER PREMATURELY
424.58 -FAN VIBRATION TROUBLE
424.56
CO2
Cyl
62814
62807
62807
62807
62807
62817
62817
62817
62817
39256
39256
11094
11094
7358
7358
7358
7358
11094
11094
75593
75593
75593
75593
39361
39361
39361
39361
2401
2401
64329
64329
34790
34790
11094
11094
11094
11094
6052
6052
6052
6052
11092
11092
11092
11092
75593
75593
75593
75593
39361
39361
39361
39361
Date
19870529
19870602
19870602
19870602
19870602
19870603
19870603
19870603
19870603
19870604
19870604
19880308
19880308
19880308
19880308
19880309
19880309
19880309
19880309
19880310
19880310
19880310
19880310
19880315
19880315
19880315
19880315
19880726
19880726
19880726
19880726
19880727
19880727
19890131
19890131
19890131
19890131
19890201
19890201
19890206
19890206
19890206
19890206
19890207
19890207
19890710
19890710
19890711
19890711
19890711
19890711
19890712
19890712
361
362
362
363
363
364
364
365
365
366
366
367
367
368
368
369
369
370
370
371
371
372
372
373
373
374
374
375
375
376
376
377
377
378
378
379
379
380
380
381
381
382
382
383
383
384
384
385
385
386
386
387
387
Run
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
Vol
Tot
cc
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.36
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.37
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.38
5014.39
5014.39
5014.39
5014.39
5014.39
5014.39
5014.39
5014.39
Temp
CO2
o ∗
C
21.95
21.97
22.03
21.97
22.03
21.53
21.65
21.85
21.95
21.72
21.90
21.34
21.42
21.50
21.54
21.31
21.35
21.27
21.34
20.92
21.00
20.99
21.04
21.16
21.29
21.21
21.27
21.68
21.75
21.74
21.76
21.76
21.92
20.41
20.53
20.96
21.04
20.80
20.85
20.35
20.42
20.40
20.45
20.60
20.69
21.68
21.77
21.13
21.28
21.64
21.75
21.52
21.69
Temp
Tot
o ∗
C
21.84
21.78
21.78
21.99
21.99
21.98
21.98
21.58
21.58
21.88
21.88
21.11
21.11
21.38
21.38
21.52
21.52
21.32
21.32
21.29
21.29
20.94
20.94
21.02
21.02
21.26
21.26
21.76
21.76
21.71
21.71
21.76
21.76
20.73
20.73
20.45
20.45
20.99
20.99
20.03
20.03
20.38
20.38
20.42
20.42
21.60
21.60
21.72
21.72
21.17
21.17
21.69
21.69
HtVac
CO2
mm
717.325
646.668
646.712
647.278
647.359
669.158
669.264
669.539
669.680
654.420
654.596
638.540
638.642
662.811
662.814
663.284
663.326
640.392
640.363
640.120
640.150
639.312
639.380
661.099
661.238
660.926
660.964
779.872
779.968
761.176
761.223
762.641
762.920
637.606
637.824
637.912
638.002
661.483
661.582
664.953
665.170
640.633
640.733
641.340
641.395
638.154
638.188
638.398
638.481
660.428
660.484
659.730
659.866
HtVac
Tot
mm
787.829
784.429
784.429
786.350
786.350
788.066
788.066
787.117
787.117
790.170
790.170
786.953
786.953
790.451
790.451
792.283
792.283
791.850
791.850
790.337
790.337
787.640
787.640
787.754
787.754
787.896
787.896
779.178
779.178
605.048
605.048
515.543
515.543
786.272
786.272
784.913
784.913
786.174
786.174
792.789
792.789
787.734
787.734
788.864
788.864
783.933
783.933
786.001
786.001
784.925
784.925
784.795
784.795
HtSmp
CO2
mm
374.856
374.866
374.844
374.870
374.828
374.866
374.830
374.862
374.852
374.868
374.883
374.840
374.843
374.845
374.820
374.842
374.825
374.868
374.840
374.875
374.837
374.848
374.856
374.850
374.804
374.820
374.830
374.926
374.890
374.889
374.876
374.907
374.880
374.754
374.774
374.788
374.750
374.788
374.758
374.752
374.721
374.744
374.714
374.768
374.740
375.086
375.097
375.128
375.084
375.040
375.049
375.084
375.098
HtSmp
Tot
mm
177.578
177.538
177.538
177.511
177.511
177.566
177.566
177.512
177.512
177.518
177.518
177.394
177.394
177.360
177.360
177.382
177.382
177.456
177.456
177.459
177.459
177.478
177.478
177.514
177.514
177.398
177.398
177.472
177.472
177.490
177.490
177.616
177.616
177.388
177.388
177.422
177.422
177.417
177.417
177.363
177.363
177.725
177.725
177.420
177.420
177.796
177.796
177.779
177.779
177.756
177.756
177.694
177.694
Table A7: Manometric Reference Gas Measurements: Original Data. Page 15/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.31
0.29
0.29
0.29
0.29
0.28
0.28
0.28
0.28
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.30
0.30
0.30
0.30
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ppm
424.57
338.45
338.46
338.37
338.45
365.24
365.26
365.31
365.37
345.62
345.59
327.16
327.19
355.44
355.42
355.40
355.42
327.16
327.08
328.01
328.00
328.00
328.01
354.94
355.00
354.85
354.81
509.87
509.90
684.25
684.31
869.21
869.40
327.11
327.22
327.23
327.29
356.79
356.88
356.60
356.81
329.89
329.99
329.77
329.77
328.39
328.31
328.31
328.29
355.24
355.15
355.16
355.10
CO2
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
Cyl
6052
6052
6052
6052
11081
11081
11081
11081
39239
39239
39272
39272
39272
39272
39256
39256
39256
39256
71341
71341
71341
71341
11092
11092
11092
11092
73292
73292
73292
73292
66638
66638
66638
66638
6078
6078
6078
6078
66625
66625
66625
66625
2399
2399
2399
2399
39239
39239
66696
66696
66696
66696
71308
Date
19900320
19900320
19900320
19900320
19900321
19900321
19900321
19900321
19900322
19900322
19900322
19900322
19900322
19900322
19900327
19900327
19900328
19900328
19900328
19900328
19900328
19900328
19900402
19900402
19900403
19900403
19900403
19900403
19900404
19900404
19900409
19900409
19900410
19900410
19900410
19900410
19900410
19900410
19900417
19900417
19900418
19900418
19900418
19900418
19900419
19900419
19900419
19900420
19900510
19900510
19900510
19900510
19900511
388
388
389
389
390
390
391
391
392
392
393
393
394
394
395
395
396
396
397
397
398
398
399
399
400
400
401
401
402
402
403
403
404
404
405
405
406
406
407
407
408
408
409
409
410
410
411
411
412
412
413
413
414
Run
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
Vol
Tot
cc
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
Temp
CO2
o ∗
C
21.98
22.07
21.91
21.99
21.65
21.83
21.82
22.00
21.75
21.84
21.72
21.81
21.75
21.86
21.60
21.73
21.93
22.04
21.77
21.90
21.70
21.76
21.76
21.86
21.47
21.65
21.71
21.84
21.92
22.02
21.64
21.80
21.68
21.87
21.80
21.92
21.87
22.01
21.87
21.97
21.82
21.94
21.99
22.11
21.68
21.86
21.74
21.74
21.10
21.27
21.25
21.39
21.79
Temp
Tot
o ∗
C
22.11
22.11
22.02
22.02
21.94
21.94
21.72
21.72
21.86
21.86
21.79
21.79
21.75
21.75
21.35
21.35
21.66
21.66
21.99
21.99
21.80
21.80
21.51
21.51
21.80
21.80
21.55
21.55
21.76
21.76
21.34
21.34
21.70
21.70
21.75
21.75
21.85
21.85
21.73
21.73
21.92
21.92
21.86
21.86
22.05
22.05
21.71
21.71
22.00
22.00
21.17
21.17
21.31
HtVac
CO2
mm
661.795
661.878
662.256
662.344
661.754
661.890
661.782
661.986
643.557
643.653
664.877
665.128
666.198
666.300
652.988
653.120
654.457
654.468
632.979
633.116
632.438
632.553
640.936
641.036
641.015
641.176
640.871
641.028
640.124
640.174
649.611
649.807
648.888
649.095
625.932
626.044
627.253
627.384
651.245
651.420
650.812
650.894
633.678
633.734
634.952
635.232
642.939
642.979
664.865
664.989
663.734
664.033
677.304
HtVac
Tot
mm
786.250
786.250
787.136
787.136
784.870
784.870
784.121
784.121
788.740
788.740
786.819
786.819
789.123
789.123
785.736
785.736
788.938
788.938
783.689
783.689
782.181
782.181
786.978
786.978
788.229
788.229
786.391
786.391
784.560
784.560
790.665
790.665
789.472
789.472
788.160
788.160
791.509
791.509
783.525
783.525
782.955
782.955
781.334
781.334
785.520
785.520
786.850
786.850
788.100
788.100
784.386
784.386
784.483
HtSmp
CO2
mm
375.115
375.111
375.140
375.108
375.157
375.118
375.134
375.107
375.162
375.137
375.156
375.140
375.154
375.145
375.212
375.167
375.188
375.152
375.178
375.164
375.190
375.189
375.177
375.168
375.236
375.217
375.230
375.225
375.270
375.274
375.288
375.285
375.315
375.280
375.300
375.292
375.272
375.288
375.322
375.283
375.300
375.282
375.284
375.266
375.310
375.305
375.304
375.335
375.296
375.280
375.304
375.261
375.314
HtSmp
Tot
mm
177.870
177.870
177.862
177.862
177.912
177.912
177.801
177.801
177.916
177.916
177.878
177.878
177.909
177.909
177.878
177.878
177.961
177.961
177.891
177.891
177.962
177.962
177.858
177.858
177.918
177.918
177.936
177.936
177.952
177.952
178.024
178.024
177.902
177.902
178.025
178.025
178.030
178.030
177.980
177.980
177.998
177.998
178.064
178.064
177.985
177.985
178.041
178.041
178.012
178.012
178.009
178.009
177.966
Table A7: Manometric Reference Gas Measurements: Original Data. Page 16/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.32
ppm
356.90
356.90
356.90
356.94
357.84
357.83
357.78
357.84
332.71
332.76
360.29
360.51
360.51
360.50
345.61
345.67
345.68
345.60
321.98
322.02
321.99
322.06
329.93
329.95
330.00
330.01
330.25
330.30
330.27
330.21
338.23
338.29
338.28
338.35
310.80
310.82
310.81
310.80
344.42
344.57
344.54
344.52
324.01
323.96
323.87
324.02
332.70
332.71
360.15
360.11
359.66
359.91
376.00
CO2
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
Cyl
71308
71308
71308
1540
1540
1540
1540
66696
66696
71286
71286
71286
71286
7366
7366
7366
7366
71370
71370
71370
71370
35299
35299
35299
35299
39239
39239
34819
34819
34819
34819
3753
3753
3753
3753
71479
71479
71479
71479
35316
35316
35316
35316
71251
71251
71251
71251
2408
2408
2408
2408
67615
67615
Date
19900511
19900511
19900511
19900511
19900511
19900521
19900522
19900522
19900522
19900523
19900523
19900523
19900523
19900524
19900524
19900524
19900524
19900611
19900611
19900612
19900612
19900612
19900612
19900613
19900613
19900614
19900614
19900615
19900615
19900620
19900620
19900702
19900702
19900703
19900703
19900703
19900703
19900705
19900705
19900706
19900706
19900709
19900709
19900710
19900710
19900710
19900710
19900711
19900711
19900712
19900712
19900712
19900712
414
415
415
416
416
417
417
418
418
419
419
420
420
421
421
422
422
423
423
424
424
425
425
426
426
427
427
428
428
429
429
430
430
431
431
432
432
433
433
434
434
435
435
436
436
437
437
438
438
439
439
440
440
Run
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
Vol
Tot
cc
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
Temp
CO2
o ∗
C
21.87
21.60
21.70
21.52
21.62
21.48
21.63
21.65
21.77
21.72
21.90
21.74
21.82
21.69
21.79
21.71
21.74
22.34
22.41
21.94
22.00
21.85
21.94
22.23
22.25
21.51
21.60
21.69
21.74
22.07
22.14
22.66
22.93
21.92
21.97
22.64
22.73
22.03
22.17
21.92
22.04
21.94
22.11
21.83
22.18
22.51
22.75
22.13
22.36
22.62
22.72
22.53
22.68
Temp
Tot
o ∗
C
21.31
21.83
21.83
21.64
21.64
21.43
21.43
21.52
21.52
21.68
21.68
21.76
21.76
21.77
21.77
21.73
21.73
22.03
22.03
22.35
22.35
21.96
21.96
21.89
21.89
22.24
22.24
21.54
21.54
21.88
21.88
22.01
22.01
22.71
22.71
22.34
22.34
21.48
21.48
22.10
22.10
21.46
21.46
22.00
22.00
21.88
21.88
22.61
22.61
22.20
22.20
22.66
22.66
HtVac
CO2
mm
677.313
675.312
675.556
679.810
679.989
680.464
680.536
663.595
663.578
612.890
612.946
612.150
612.138
594.502
594.558
595.106
595.078
700.414
700.595
700.080
700.134
706.772
706.870
706.754
706.726
640.111
640.262
577.724
577.835
577.618
577.676
572.887
573.058
571.595
571.604
737.860
737.942
737.929
738.108
752.288
752.438
753.748
753.970
546.468
546.709
546.195
546.338
532.377
532.491
531.968
531.972
775.870
776.144
HtVac
Tot
mm
784.483
782.248
782.248
784.325
784.325
784.731
784.731
783.184
783.184
782.953
782.953
781.184
781.184
777.508
777.508
778.988
778.988
782.645
782.645
783.315
783.315
783.148
783.148
781.970
781.970
782.125
782.125
784.616
784.616
783.985
783.985
783.231
783.231
782.221
782.221
782.671
782.671
782.195
782.195
782.360
782.360
783.599
783.599
784.136
784.136
781.454
781.454
781.724
781.724
778.124
778.124
780.502
780.502
HtSmp
CO2
mm
375.273
375.285
375.288
375.298
375.273
375.312
375.295
375.305
375.308
375.340
375.320
375.336
375.311
375.324
375.328
375.329
375.310
375.367
375.366
375.398
375.364
375.350
375.339
375.345
375.337
375.368
375.298
375.352
375.341
375.348
375.355
375.348
375.356
375.360
375.364
375.332
375.350
375.314
375.294
375.338
375.338
375.333
375.298
375.343
375.352
375.320
375.327
375.338
375.324
375.358
375.310
375.328
375.277
HtSmp
Tot
mm
177.966
178.035
178.035
178.004
178.004
177.938
177.938
178.004
178.004
178.060
178.060
178.038
178.038
178.000
178.000
177.974
177.974
178.145
178.145
178.008
178.008
178.082
178.082
178.012
178.012
178.043
178.043
178.040
178.040
178.030
178.030
178.116
178.116
178.040
178.040
178.029
178.029
178.000
178.000
177.964
177.964
178.104
178.104
177.990
177.990
178.029
178.029
178.016
178.016
178.016
178.016
177.972
177.972
Table A7: Manometric Reference Gas Measurements: Original Data. Page 17/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.32
0.32
0.32
0.00
0.00
0.00
0.00
0.31
0.31
0.32
0.32
0.32
0.32
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.24
0.24
0.24
0.24
0.00
0.00
0.00
0.00
0.30
0.30
0.30
0.30
0.00
0.00
0.00
0.00
0.34
0.34
0.34
0.34
0.00
0.00
0.00
0.00
0.30
0.30
Comment
ppm
375.95
375.93
376.09
380.45
380.57
380.72
380.63
360.13
359.95
296.75
296.65
296.75
296.68
276.64
276.60
276.64
276.60
406.43
406.56
406.48
406.50
415.02
415.03
415.10
415.04
332.57
332.74
251.92
252.03
252.01
252.01
246.30 HG CONTACTED POINTER PREMATURELY
246.26
246.31
246.27
453.41
453.34
453.45
453.47
472.88
472.86
472.74
472.77
213.17
213.20
213.21
213.20
196.92
196.92 HG CONTACTED POINTER PREMATURELY
196.92
196.92
503.69 HG CONTACTED POINTER PREMATURELY
503.82
CO2
Cyl
67615
67615
39239
39239
66556
66556
66556
66556
62807
62807
62807
62807
62807
62817
62817
62817
62817
62817
34891
34891
34891
34891
34891
62814
62814
62814
62814
39239
39239
1607
1607
1641
1641
73292
73292
73292
73292
39354
39354
39354
39354
6052
6052
6052
6052
1607
1607
75593
75593
75593
75593
1641
Date
19900712
19900712
19900713
19900713
19900821
19900821
19900821
19900821
19900822
19900822
19900822
19900823
19900823
19900823
19900823
19900823
19900824
19900824
19900824
19900824
19900824
19900828
19900828
19900828
19900828
19900829
19900829
19900829
19900829
19920219
19920219
19920220
19920220
19920305
19920305
19920306
19920306
19920312
19920312
19920313
19920313
19920330
19920331
19920331
19920331
19920421
19920421
19920421
19920421
19920421
19920421
19920514
445
445
446
446
447
447
447
448
448
449
449
449
450
450
451
451
452
452
453
453
454
454
455
455
456
456
457
457
458
458
459
459
460
460
461
461
462
462
463
463
464
464
465
441
441
442
442
443
443
444
444
445
Run
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
N2
N2
AIR
AIR
AIR
AIR
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
AIR
AIR
N2
N2
N2
N2
AIR
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
Vol
Tot
cc
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
5014.4
22.53
22.62
22.46
22.62
22.51
22.63
22.69
22.69
22.81
22.80
23.06
23.10
22.89
22.95
22.58
22.69
23.00
23.05
22.86
22.94
20.87
20.94
20.92
21.01
20.74
20.82
20.75
20.92
21.78
21.99
20.93
21.23
20.55
20.87
20.64
20.71
20.78
20.84
20.93
20.98
21.05
21.09
20.93
Temp
CO2
o ∗
C
22.86
23.05
22.60
22.74
22.63
22.70
22.73
22.88
22.51
22.78
22.78
22.58
22.58
22.51
22.51
22.51
22.56
22.56
22.74
22.74
22.74
22.59
22.59
22.90
22.90
22.62
22.62
23.02
23.02
20.78
20.78
20.89
20.89
20.78
20.78
20.75
20.75
20.34
20.34
21.87
21.87
20.34
20.34
20.63
20.63
20.27
20.27
20.80
20.80
20.95
20.95
21.22
Temp
Tot
o ∗
C
22.58
22.58
22.94
22.94
22.16
22.16
22.66
22.66
22.78
650.941
651.032
646.918
647.149
668.453
668.520
668.514
668.244
668.328
613.540
613.741
613.686
615.448
615.512
714.716
714.838
716.524
716.588
642.227
642.272
815.577
815.633
845.728
845.828
641.176
641.374
642.891
643.056
665.106
665.312
665.994
666.194
669.304
669.808
668.160
668.188
797.088
797.178
641.976
642.116
639.692
639.744
794.834
HtVac
CO2
mm
777.594
777.942
640.012
640.172
457.461
457.454
457.170
457.187
651.074
794.083
794.083
784.641
784.641
784.499
784.499
784.499
783.950
783.950
781.675
781.675
781.675
786.155
786.155
783.526
783.526
785.051
785.051
785.424
785.424
597.438
597.438
392.796
392.796
787.569
787.569
790.888
790.888
787.530
787.530
794.562
794.562
791.426
791.426
789.049
789.049
579.217
579.217
787.240
787.240
781.793
781.793
389.579
HtVac
Tot
mm
782.314
782.314
780.538
780.538
787.620
787.620
786.898
786.898
794.083
375.264
375.204
375.266
375.263
375.258
375.260
375.228
375.220
375.210
375.242
375.250
375.226
375.250
375.247
375.244
375.220
375.256
375.232
375.252
375.229
375.070
375.092
375.080
375.106
375.175
375.154
375.181
375.185
375.160
375.146
375.185
375.068
375.138
375.134
375.163
375.162
375.178
375.136
375.156
375.162
375.140
375.156
375.182
HtSmp
CO2
mm
375.340
375.279
375.300
375.317
375.312
375.282
375.282
375.260
375.276
178.041
178.041
177.962
177.962
177.947
177.947
177.947
178.024
178.024
177.968
177.968
177.968
177.956
177.956
177.968
177.968
177.910
177.910
177.948
177.948
177.704
177.704
177.798
177.798
177.806
177.806
177.790
177.790
177.776
177.776
177.798
177.798
177.794
177.794
177.790
177.790
177.915
177.915
177.832
177.832
177.840
177.840
177.896
HtSmp
Tot
mm
178.012
178.012
177.934
177.934
177.974
177.974
178.051
178.051
178.041
Table A7: Manometric Reference Gas Measurements: Original Data. Page 18/34
∗
Temperature corrected for thermometer drift
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
ppm
0.30
0.30
0.00
0.00
0.37
0.37
0.37
0.37
0.29
0.29
0.29
0.29
0.29
0.28
0.28
0.28
0.28
0.28
0.24
0.24
0.24
0.24
0.24
0.31
0.31
0.31
0.31
0.00
0.00
0.30
0.30
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.30
0.30
0.00
0.00
0.00
0.00
0.30
Flg
N2 O
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
HG CONTACTED POINTER PREMATURELY
TEMP UNCERTAINTY-ALL FANS OFF IN
CABINET
338.71 HG CONTACTED POINTER PREMATURELY
338.79
338.75
338.85
365.65 HG CONTACTED POINTER PREMATURELY
365.57 HG CONTACTED POINTER PREMATURELY
365.53
365.64
365.60
298.33 HG CONTACTED POINTER PREMATURELY
298.29 HG CONTACTED POINTER PREMATURELY
298.21
298.24
298.25
424.75
424.76
424.82
424.86
332.83
332.82
795.11
794.97
1659.77
1659.49
330.23 HG CONTACTED POINTER PREMATURELY
330.41
330.50
330.50
358.15
358.15
358.18
358.18
362.68
362.89
362.90
362.84
795.20
795.28
331.24
331.35
331.42
331.42
1504.15
ppm
503.62
503.79
332.88
332.89
101.05
101.05
101.00
101.00
338.89
CO2
Cyl
1641
181
181
181
181
1641
1641
6052
6052
6052
6052
39361
39361
39361
39361
181
181
181
181
39239
39239
39239
39239
39272
39272
39272
39272
11092
11092
11092
11092
66638
66638
66638
66638
66696
66696
66696
66696
71479
71479
71479
71479
71251
71251
71251
71251
4274
4274
4274
4274
6071
6071
Date
19920914
19920514
19920514
19920514
19920514
19920604
19920604
19921216
19921216
19921217
19921217
19930120
19930120
19930120
19930120
19930210
19930210
19930210
19930210
19930223
19930223
19930223
19930223
19930224
19930224
19930224
19930224
19930324
19930324
19930325
19930325
19930426
19930426
19930427
19930427
19930427
19930427
19930427
19930427
19930506
19930506
19930506
19930506
19930514
19930514
19930514
19930514
19930514
19930514
19930520
19930520
19930520
19930520
465
466
466
467
467
468
468
469
469
470
470
471
471
472
472
473
473
474
474
475
475
476
476
477
477
478
478
479
479
480
480
481
481
482
482
483
483
484
484
485
485
486
486
487
487
488
488
489
489
490
490
491
491
Run
Gas Vol
CO2
cc
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
Vol
Tot
cc
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.42
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
Temp
CO2
o ∗
C
20.99
21.00
21.07
21.11
21.17
21.21
21.31
21.12
21.21
20.70
21.30
21.29
21.43
21.45
21.58
21.44
21.54
21.36
21.45
21.23
21.33
21.39
21.58
21.16
21.28
21.24
21.28
21.36
21.42
21.45
21.48
21.54
21.57
21.68
21.71
21.46
21.49
21.41
21.45
21.25
21.41
21.35
21.47
21.00
21.08
21.12
21.27
21.41
21.47
21.91
21.91
21.65
21.72
Temp
Tot
o ∗
C
21.22
20.95
20.95
21.02
21.02
21.20
21.20
20.91
20.91
21.16
21.16
21.39
21.39
21.33
21.33
21.52
21.52
21.46
21.46
21.25
21.25
21.28
21.28
21.43
21.43
21.20
21.20
21.31
21.31
21.38
21.38
21.49
21.49
21.55
21.55
21.70
21.70
21.46
21.46
21.52
21.52
21.29
21.29
21.16
21.16
21.02
21.02
21.17
21.17
21.47
21.47
21.91
21.91
HtVac
CO2
mm
794.947
640.068
640.209
641.188
641.261
803.500
803.772
670.560
670.780
669.917
670.564
672.274
672.458
671.037
671.253
645.188
645.329
648.194
648.251
646.502
646.578
644.764
644.924
667.280
667.527
666.729
666.918
642.931
643.043
642.243
642.342
648.674
648.790
649.576
649.541
665.538
665.630
666.248
666.276
742.139
742.494
743.316
743.540
548.208
548.210
548.130
548.262
572.556
572.583
571.286
571.303
625.090
625.044
HtVac
Tot
mm
389.579
778.632
778.632
780.888
780.888
393.779
393.779
793.528
793.528
793.467
793.467
797.250
797.250
794.226
794.226
790.054
790.054
796.967
796.967
794.847
794.847
790.686
790.686
791.700
791.700
790.040
790.040
793.676
793.676
791.943
791.943
788.893
788.893
790.475
790.475
788.103
788.103
788.943
788.943
791.136
791.136
792.297
792.297
790.927
790.927
789.869
789.869
790.763
790.763
786.781
786.781
788.049
788.049
HtSmp
CO2
mm
375.125
375.162
375.115
375.154
375.166
375.146
375.118
375.074
375.064
375.091
375.098
375.161
375.134
375.156
375.148
375.186
375.140
375.151
375.146
375.142
375.121
375.156
375.142
375.158
375.127
375.152
375.146
375.212
375.166
375.192
375.222
375.176
375.159
375.184
375.151
375.190
375.160
375.196
375.202
375.202
375.180
375.210
375.191
375.226
375.188
375.164
375.179
375.181
375.178
375.220
375.194
375.230
375.182
HtSmp
Tot
mm
177.896
177.855
177.855
177.910
177.910
177.962
177.962
177.748
177.748
177.802
177.802
177.884
177.884
177.944
177.944
177.798
177.798
177.876
177.876
177.940
177.940
177.978
177.978
177.810
177.810
177.928
177.928
177.832
177.832
177.924
177.924
177.978
177.978
177.957
177.957
177.948
177.948
177.879
177.879
177.859
177.859
177.916
177.916
177.998
177.998
177.928
177.928
177.920
177.920
178.050
178.050
177.910
177.910
Table A7: Manometric Reference Gas Measurements: Original Data. Page 19/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.30
0.00
0.00
0.00
0.00
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.30
0.30
0.30
0.30
0.34
0.34
0.34
0.34
0.00
0.00
0.00
0.00
0.00
0.00
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
Comment
ppm
1504.44
333.68
333.83
333.83
333.84
1504.41
1504.92
363.04
363.20
363.17
363.17
363.33
363.41
363.34 HG
363.45
333.89
334.00 HG
333.96
333.93
332.97
332.97
332.93
332.92
360.62
360.81
360.59 HG
360.78
328.98
329.10
329.11
329.16 HG
338.47
338.60
338.59
338.55
360.23 HG
360.34
360.32
360.30 HG
453.41
453.62
453.50
453.61
213.10
213.09 HG
213.23
213.26
243.34
243.33
243.18
243.24
310.18
310.11
CO2
Cyl
6071
6071
4296
4296
4296
4296
39256
39256
39256
39256
66625
66625
66625
66625
39239
39239
71341
71341
71341
71341
66625
66625
34819
34819
34819
34819
71370
71370
71370
71370
35299
35299
35299
35299
3753
3753
3753
3753
6078
6078
6078
6078
2399
2399
2399
2399
35316
35316
35316
35316
67615
67615
67615
Date
19930521
19930521
19930526
19930526
19930526
19930526
19930527
19930527
19930527
19930527
19930602
19930602
19930603
19930603
19930604
19930604
19930604
19930604
19930609
19930609
19930610
19930610
19930610
19930610
19930610
19930610
19930611
19930611
19930611
19930611
19930616
19930616
19930616
19930616
19930617
19930617
19930617
19930617
19930617
19930617
19930623
19930623
19930624
19930624
19930624
19930624
19930625
19930625
19930630
19930630
19930701
19930701
19930701
492
492
493
493
494
494
495
495
496
496
497
497
498
498
499
499
500
500
501
501
502
502
503
503
504
504
505
505
506
506
507
507
508
508
509
509
510
510
511
511
512
512
513
513
514
514
515
515
516
516
517
517
518
Run
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
Vol
Tot
cc
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
Temp
CO2
o ∗
C
21.35
21.50
21.44
21.53
21.63
21.68
21.57
21.69
21.61
21.66
21.79
21.86
21.31
21.44
21.41
21.56
21.60
21.71
21.67
21.73
21.31
21.44
21.72
21.75
22.32
22.36
21.61
21.68
22.08
22.10
21.48
21.53
21.75
21.75
21.28
21.44
21.50
21.54
21.87
22.13
22.38
22.41
22.21
22.20
22.77
22.74
21.56
21.73
21.65
21.67
21.48
21.54
21.56
Temp
Tot
o ∗
C
21.67
21.67
21.42
21.42
21.48
21.48
21.66
21.66
21.60
21.60
21.54
21.54
21.82
21.82
21.36
21.36
21.49
21.49
21.64
21.64
21.68
21.68
21.35
21.35
21.74
21.74
22.34
22.34
21.64
21.64
21.26
21.26
21.50
21.50
21.75
21.75
21.32
21.32
21.53
21.53
22.03
22.03
22.39
22.39
22.22
22.22
22.77
22.77
21.84
21.84
21.66
21.66
21.50
HtVac
CO2
mm
625.040
625.196
634.253
634.416
635.604
635.665
654.869
654.958
655.504
655.556
655.927
656.074
654.377
654.502
644.678
644.780
635.518
635.610
635.882
635.918
653.701
653.756
578.252
578.282
579.131
579.211
702.030
702.140
702.905
703.018
713.219
713.602
708.764
708.830
573.784
573.900
572.748
572.768
625.993
626.231
625.318
625.376
635.630
635.624
636.578
636.699
754.906
755.162
756.004
756.168
780.146
780.286
780.264
HtVac
Tot
mm
788.049
788.049
789.759
789.759
792.444
792.444
790.302
790.302
791.526
791.526
793.476
793.476
790.903
790.903
790.540
790.540
788.540
788.540
789.795
789.795
789.850
789.850
785.645
785.645
787.901
787.901
787.837
787.837
786.936
786.936
794.512
794.512
786.044
786.044
788.302
788.302
783.648
783.648
787.461
787.461
786.010
786.010
786.490
786.490
787.332
787.332
788.824
788.824
788.708
788.708
786.924
786.924
786.579
HtSmp
CO2
mm
375.214
375.196
375.185
375.178
375.208
375.172
375.199
375.162
375.188
375.182
375.220
375.160
375.222
375.148
375.211
375.182
375.214
375.190
375.218
375.157
375.210
375.173
375.214
375.180
375.206
375.180
375.198
375.202
375.190
375.202
375.210
375.176
375.194
375.182
375.207
375.218
375.207
375.176
375.194
375.194
375.222
375.167
375.205
375.218
375.234
375.228
375.227
375.200
375.202
375.185
375.214
375.188
375.210
HtSmp
Tot
mm
177.972
177.972
177.937
177.937
177.916
177.916
177.936
177.936
177.930
177.930
177.954
177.954
177.925
177.925
177.924
177.924
177.956
177.956
177.892
177.892
177.914
177.914
177.999
177.999
177.924
177.924
177.862
177.862
177.915
177.915
177.920
177.920
177.952
177.952
177.950
177.950
177.981
177.981
177.986
177.986
177.936
177.936
177.926
177.926
177.929
177.929
177.944
177.944
177.942
177.942
177.947
177.947
177.910
Table A7: Manometric Reference Gas Measurements: Original Data. Page 20/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.00
0.00
0.31
0.31
0.31
0.31
0.29
0.29
0.24
0.24
0.24
0.24
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.30
0.30
0.30
Comment
ppm
310.24
310.29
320.44
320.55
320.52
320.58
345.83
345.84
345.82
345.82
344.59
344.76
345.04
345.13
332.88
332.86
322.18
322.20
322.03
322.08
344.63
344.59
252.10
252.16
252.05
252.15
406.51
406.54
406.54
406.64
414.89 HG CONTACTED POINTER PREMATURELY
415.33
415.10
415.20
246.46
246.44
246.49
246.52
311.02
311.03
310.85
310.96
324.08
324.07
323.93
324.12
472.99
473.06
472.76 HG CONTACTED POINTER PREMATURELY
472.95
503.93
504.03
503.91
CO2
Cyl
67615
71286
71286
71286
71286
71308
71308
71308
71308
1540
1540
1540
1540
2408
2408
2408
2408
7366
7366
7366
7366
39361
39361
39361
39361
11092
11092
11092
11092
11081
11081
11081
11081
11076
11076
11076
11076
4286
4286
4286
4286
75593
75593
75593
75593
11076
11076
11076
11076
11081
11081
Date
19930701
19930702
19930702
19930702
19930702
19930707
19930707
19930707
19930707
19930708
19930708
19930708
19930708
19930713
19930713
19930714
19930714
19930714
19930714
19930714
19930714
19930715
19930715
19930715
19930715
19930907
19930907
19930908
19930908
19930909
19930909
19930909
19930909
19930910
19930910
19930910
19930910
19940725
19940725
19940726
19940726
19940726
19940726
19940727
19940727
19940802
19940802
19940802
19940802
19940803
19940803
539
539
540
540
541
541
542
542
543
543
538
518
519
519
520
520
521
521
522
522
523
523
524
524
525
525
526
526
527
527
528
528
529
529
530
530
531
531
532
532
533
533
534
534
535
535
536
536
537
537
538
Run
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
Vol
Tot
cc
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.43
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.44
5014.45
5014.45
5014.45
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
3.7934 5014.45
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
21.90
21.98
22.07
22.08
21.95
21.96
21.82
21.89
21.89
21.94
21.87
Temp
CO2
o ∗
C
21.60
21.46
21.54
21.58
21.63
21.68
21.71
21.96
22.03
21.96
21.96
21.97
21.99
21.66
21.68
21.35
21.41
21.49
21.56
21.71
21.76
21.52
21.63
21.86
21.93
22.18
22.15
22.07
22.06
21.63
21.62
22.10
22.09
21.42
21.54
21.81
21.91
21.95
22.00
21.83
21.84
21.84
21.93
21.93
22.45
22.45
21.95
21.95
21.84
21.84
21.97
Temp
Tot
o ∗
C
21.50
21.58
21.58
21.49
21.49
21.48
21.48
21.69
21.69
21.99
21.99
21.96
21.96
21.81
21.81
21.66
21.66
21.37
21.37
21.52
21.52
21.74
21.74
21.56
21.56
21.31
21.31
22.18
22.18
22.08
22.08
21.63
21.63
22.11
22.11
21.44
21.44
22.18
22.18
21.97
HtVac
Tot
mm
786.579
788.201
788.201
785.083
785.083
789.409
789.409
788.388
788.388
786.132
786.132
789.503
789.503
792.069
792.069
790.839
790.839
788.306
788.306
791.110
791.110
791.899
791.899
792.128
792.128
789.300
789.300
790.655
790.655
790.703
790.703
786.522
786.522
787.984
787.984
783.790
783.790
790.469
790.469
787.829
HtSmp
CO2
mm
375.182
375.235
375.194
375.196
375.186
375.176
375.166
375.175
375.158
375.180
375.158
375.180
375.186
375.201
375.190
375.216
375.174
375.170
375.169
375.174
375.140
375.200
375.162
375.160
375.154
375.210
375.198
375.222
375.209
375.208
375.180
375.216
375.178
375.218
375.192
375.210
375.210
375.259
375.171
375.188
HtSmp
Tot
mm
177.910
177.909
177.909
177.907
177.907
177.912
177.912
177.934
177.934
177.942
177.942
177.925
177.925
177.910
177.910
177.942
177.942
177.923
177.923
177.906
177.906
177.842
177.842
177.904
177.904
177.902
177.902
177.989
177.989
177.938
177.938
177.952
177.952
177.946
177.946
177.958
177.958
177.867
177.867
177.842
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
ppm
0.30
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
667.857
667.915
669.504
669.488
646.390
646.340
645.002
645.198
661.875
661.839
788.725
788.725
791.655
791.655
790.046
790.046
786.506
786.506
784.795
784.795
375.186
375.168
375.214
375.191
375.200
375.155
375.162
375.158
375.198
375.182
177.915
177.915
177.890
177.890
177.914
177.914
177.910
177.910
177.955
177.955
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0
0
0
0
0
0
0
0
0
0
11
Flg
N2 O
647.100 787.829 375.152 177.842 -0.303 -0.005 0.00
HtVac
CO2
mm
780.498
614.836
614.802
613.694
613.740
679.576
679.682
679.187
679.217
680.857
680.985
682.697
682.725
535.039
535.076
534.722
534.806
598.527
598.658
599.548
599.650
669.518
669.841
670.372
670.438
641.838
641.958
641.498
641.530
664.027
664.030
662.945
663.053
645.188
645.292
644.390
644.505
648.434
648.413
647.059
Table A7: Manometric Reference Gas Measurements: Original Data. Page 21/34
∗
Temperature corrected for thermometer drift
Comment
ppm
504.16
296.84
296.76
296.76
296.78
376.30
376.40
376.36
376.32
380.61
380.80
380.73
380.73
196.79
196.84 HG CONTACTED POINTER
196.90
197.02
276.70
276.80
276.62
276.74
363.17
363.47
363.50
363.50
329.05
329.24
329.08
329.15
357.41
357.46
357.33 HG CONTACTED POINTER
357.52
335.80
335.81
335.86
335.88
337.81
337.84
337.53 CO2 LOSS DURING
EXTRACTION-TRANSFERS
337.58 CO2 LOSS DURING
EXTRACTION-TRANSFERS
362.68
362.67
362.84
362.83
335.93 HG CONTACTED POINTER
335.91
335.75
335.92
357.57 HG CONTACTED POINTER
357.48
CO2
PREMATURELY
PREMATURELY
PREMATURELY
PREMATURELY
Cyl
11081
11081
4286
4286
1607
1607
1607
1607
1641
1641
1641
1641
181
181
181
181
6052
6052
6052
6052
6052
6052
6052
6052
181
181
181
181
75593
75593
75593
75593
11094
11094
11094
11094
10067
10067
10067
10067
4286
4286
4286
4286
66625
66625
66625
66625
66638
66638
66638
66638
66696
Date
19940803
19940803
19940804
19940804
19940913
19940913
19940914
19940914
19940914
19940914
19940915
19940915
19950322
19950322
19950322
19950322
19950323
19950323
19950323
19950323
19950626
19950626
19950627
19950627
19950627
19950627
19950628
19950628
19950628
19950628
19950629
19950629
19950629
19950629
19950629
19950630
19950630
19950630
19950630
19950630
19950701
19950701
19950701
19950701
19950921
19950921
19950921
19950921
19950922
19950922
19950926
19950926
19950927
544
544
545
545
546
546
547
547
548
548
549
549
550
550
551
551
552
552
553
553
554
554
555
555
556
556
557
557
558
558
559
559
560
560
561
561
562
562
563
563
564
564
565
565
566
566
567
567
568
568
569
569
570
Run
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
Vol
Tot
cc
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.45
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
Temp
CO2
o ∗
C
21.88
21.91
21.90
22.02
21.77
21.81
21.96
22.04
22.17
22.18
22.18
22.20
21.38
21.49
21.57
21.71
21.62
21.74
21.89
21.96
21.60
21.80
21.45
21.60
21.69
21.80
21.53
21.74
21.94
21.99
21.55
21.68
21.82
21.95
22.16
21.63
21.95
22.07
22.16
22.22
21.99
22.09
22.21
22.24
22.26
22.30
22.22
22.29
22.05
22.09
21.90
21.98
21.77
Temp
Tot
o ∗
C
21.91
21.91
21.89
21.89
21.82
21.82
21.80
21.80
21.98
21.98
22.18
22.18
21.30
21.30
21.42
21.42
21.62
21.62
21.66
21.66
21.52
21.52
21.65
21.65
21.51
21.51
21.73
21.73
21.60
21.60
21.96
21.96
21.60
21.60
21.85
21.85
21.70
21.70
21.99
21.99
22.17
22.17
22.03
22.03
22.20
22.20
22.27
22.27
22.24
22.24
21.84
21.84
21.92
HtVac
CO2
mm
662.238
662.279
645.359
645.433
804.000
804.052
804.426
804.634
795.732
795.690
796.986
797.062
645.516
645.914
648.781
648.851
668.291
668.648
668.196
668.332
669.942
670.092
666.403
666.455
646.534
646.607
647.304
647.458
666.723
666.812
667.052
667.139
649.700
649.834
648.779
648.354
669.363
669.501
670.098
670.148
646.696
646.747
646.688
646.741
652.183
652.276
653.044
653.084
648.284
648.308
649.589
649.542
665.958
HtVac
Tot
mm
785.875
785.875
783.138
783.138
586.842
586.842
586.834
586.834
389.956
389.956
390.686
390.686
782.800
782.800
789.392
789.392
785.844
785.844
784.636
784.636
788.520
788.520
781.650
781.650
784.220
784.220
787.393
787.393
785.022
785.022
787.621
787.621
787.488
787.488
785.785
785.785
785.119
785.119
786.893
786.893
786.320
786.320
785.468
785.468
785.759
785.759
787.854
787.854
788.417
788.417
790.646
790.646
788.632
HtSmp
CO2
mm
375.184
375.152
375.170
375.173
375.185
375.150
375.200
375.142
375.176
375.142
375.194
375.185
375.073
375.072
375.068
375.035
375.100
375.065
375.056
375.063
375.097
375.059
375.102
375.070
375.109
375.062
375.093
375.072
375.088
375.056
375.113
375.094
375.100
375.103
375.132
375.106
375.095
375.082
375.103
375.079
375.098
375.090
375.112
375.095
375.125
375.103
375.102
375.084
375.128
375.108
375.160
375.094
375.112
HtSmp
Tot
mm
177.912
177.912
177.930
177.930
177.918
177.918
177.967
177.967
177.990
177.990
178.002
178.002
177.822
177.822
177.902
177.902
177.862
177.862
177.847
177.847
177.850
177.850
177.854
177.854
177.860
177.860
177.882
177.882
177.842
177.842
177.872
177.872
177.879
177.879
177.870
177.870
177.826
177.826
177.876
177.876
177.880
177.880
177.822
177.822
177.780
177.780
177.739
177.739
177.732
177.732
177.847
177.847
177.832
Table A7: Manometric Reference Gas Measurements: Original Data. Page 22/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.29
0.29
0.29
0.29
0.31
0.31
0.31
0.31
0.31
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
CONTACTED POINTER PREMATURELY
Comment
ppm
357.48
357.54
337.90
337.85
794.77
794.81
795.04
795.31
1502.74
1502.66
1503.10
1503.30
338.27 HG
338.63 HG
338.64
338.59
365.10 HG
365.43
365.45
365.52
365.45
365.42
365.52
365.43
338.60
338.62
338.29
338.25
363.19
363.28
363.02
362.98
340.70
340.70
340.35 HG
340.50
366.53
366.56
366.50
366.52
338.09
338.05
338.07
338.12
344.55
344.64
344.58
344.56
338.46
338.46
338.56
338.49
360.35
CO2
Cyl
66696
66696
66696
71251
71251
71251
71251
67615
67615
67615
67615
71341
71341
71341
71341
71308
71308
71308
71308
71286
71286
71286
71286
71370
71370
71370
71370
34819
34819
34819
34819
71479
71479
71479
71479
62807
62807
62807
62807
62817
62817
62817
62817
34891
34891
34891
34891
62814
62814
62814
62814
7361
7361
Date
19950927
19950927
19950927
19950927
19950928
19950928
19950928
19950928
19950928
19950929
19950929
19951004
19951004
19951005
19951005
19951005
19951005
19951006
19951006
19951010
19951010
19951011
19951011
19951011
19951011
19951012
19951012
19951012
19951012
19951017
19951017
19951018
19951018
19951018
19951018
19951018
19951018
19951024
19951024
19951025
19951025
19951025
19951025
19951026
19951026
19951031
19951031
19951101
19951101
19951101
19951101
19951108
19951108
570
571
571
572
572
573
573
574
574
575
575
576
576
577
577
578
578
579
579
580
580
581
581
582
582
583
583
584
584
585
585
586
586
587
587
588
588
589
589
590
590
591
591
592
592
593
593
594
594
595
595
596
596
Run
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
Vol
Tot
cc
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
Temp
CO2
o ∗
C
21.86
21.99
22.07
22.13
21.96
22.10
22.15
22.06
22.12
21.91
22.03
22.12
22.15
22.32
22.35
22.36
22.37
22.00
22.09
22.33
22.34
22.17
22.17
22.16
22.25
22.11
22.16
22.19
22.21
21.74
21.89
21.96
21.98
21.92
21.97
21.89
21.93
21.86
21.94
21.91
22.00
21.68
21.82
21.76
21.85
21.57
21.69
21.37
21.55
21.70
21.80
21.65
21.76
Temp
Tot
o ∗
C
21.92
21.80
21.80
22.02
22.02
22.14
22.14
22.12
22.12
22.08
22.08
22.08
22.08
22.13
22.13
22.33
22.33
22.36
22.36
22.01
22.01
22.34
22.34
22.17
22.17
22.19
22.19
22.12
22.12
21.60
21.60
21.75
21.75
21.97
21.97
21.94
21.94
21.50
21.50
21.89
21.89
21.93
21.93
21.71
21.71
20.99
20.99
21.60
21.60
21.43
21.43
21.50
21.50
HtVac
CO2
mm
666.034
663.780
663.790
548.486
548.455
548.070
548.099
782.572
782.780
781.344
781.492
633.137
633.214
634.480
634.572
678.210
678.330
677.770
677.899
617.973
617.958
615.948
615.948
703.507
703.610
703.189
703.266
579.169
579.220
580.372
580.474
741.386
741.380
740.198
740.468
649.106
649.145
650.980
651.047
671.750
671.829
672.278
672.435
617.708
617.750
617.216
617.338
717.041
717.185
716.788
716.912
657.566
657.710
HtVac
Tot
mm
788.632
783.229
783.229
791.402
791.402
790.167
790.167
790.506
790.506
788.480
788.480
783.263
783.263
786.235
786.235
787.378
787.378
787.146
787.146
795.607
795.607
791.522
791.522
789.125
789.125
788.829
788.829
789.349
789.349
791.892
791.892
788.660
788.660
787.732
787.732
789.512
789.512
792.718
792.718
791.417
791.417
793.340
793.340
792.313
792.313
789.988
789.988
787.541
787.541
786.084
786.084
794.926
794.926
HtSmp
CO2
mm
375.085
375.130
375.094
375.130
375.112
375.118
375.098
375.115
375.096
375.111
375.102
375.125
375.111
375.146
375.102
375.118
375.114
375.118
375.124
375.142
375.112
375.110
375.087
375.116
375.088
375.126
375.100
375.116
375.109
375.137
375.134
375.135
375.102
375.125
375.116
375.114
375.116
375.134
375.088
375.134
375.084
375.124
375.100
375.131
375.103
375.116
375.132
375.136
375.106
375.110
375.108
375.119
375.086
HtSmp
Tot
mm
177.832
177.834
177.834
177.832
177.832
177.826
177.826
177.844
177.844
177.822
177.822
177.806
177.806
177.840
177.840
177.830
177.830
177.854
177.854
177.793
177.793
177.850
177.850
177.888
177.888
177.815
177.815
177.848
177.848
177.802
177.802
177.829
177.829
177.869
177.869
177.818
177.818
177.821
177.821
177.832
177.832
177.854
177.854
177.840
177.840
177.821
177.821
177.857
177.857
177.836
177.836
177.844
177.844
Table A7: Manometric Reference Gas Measurements: Original Data. Page 23/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.31
0.31
0.31
0.34
0.34
0.34
0.34
0.30
0.30
0.30
0.30
0.31
0.31
0.31
0.31
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.31
0.31
0.31
0.31
0.24
0.24
0.24
0.24
0.30
0.30
0.30
0.30
0.29
0.29
0.29
0.29
0.28
0.28
0.28
0.28
0.24
0.24
0.24
0.24
0.31
0.31
0.31
0.31
0.00
0.00
Comment
ppm
360.36
360.37
360.32
213.13
213.25
213.18
213.20
503.81
503.98
504.14
504.12
322.12
322.20
322.04
322.17
376.09
376.24
376.23
376.26
296.72
296.72
296.78
296.81
406.56
406.59
406.40 HG CONTACTED POINTER PREMATURELY
406.46
252.04
252.09
252.37
252.36
453.58
453.58
453.26
453.52
338.79
338.78
338.81
338.85
365.66
365.70
365.55
365.59
298.39
298.38
298.35
298.36
424.78
424.72
424.73
424.74
346.31
346.39
CO2
Cyl
7361
7361
39361
39361
39361
39361
11094
11094
11094
11094
10067
10067
10067
10067
34819
34819
7358
7358
7358
7358
7361
7361
7361
7361
39361
39361
39361
39361
3756
3756
3756
3756
11081
11081
11081
11081
7358
7358
7358
7358
11094
11094
11094
11094
4289
4289
4289
4289
7361
7361
7361
7361
Date
19951108
19951108
19951109
19951109
19951109
19951109
19960328
19960328
19960328
19960328
19960329
19960329
19960329
19960329
19960402
19960402
19960403
19960403
19960403
19960403
19960404
19960404
19960404
19960404
19960924
19960924
19960925
19960925
19960925
19960925
19960925
19960925
19961205
19961205
19961205
19961205
19961206
19961206
19961206
19961206
19971230
19971230
19971231
19971231
19971231
19971231
19971231
19971231
19980115
19980115
19980115
19980115
622
597
597
598
598
599
599
600
600
601
601
602
602
603
603
604
604
605
605
606
606
607
607
608
608
609
609
610
610
611
611
612
612
613
613
614
614
615
615
616
616
617
617
618
618
619
619
620
620
621
621
622
Run
N2
Vol
Tot
cc
5014.46
5014.46
5014.46
5014.46
5014.46
5014.46
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.47
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
3.7934 5014.49
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
22.47
Temp
CO2
o ∗
C
21.91
21.94
21.56
21.66
21.71
21.89
21.86
21.96
22.15
22.19
21.87
22.00
22.19
22.24
21.91
21.98
21.82
21.90
21.77
21.83
22.02
22.08
22.15
22.19
22.14
22.17
21.30
21.49
22.09
22.15
22.25
22.29
22.72
22.73
22.68
22.71
22.57
22.60
22.52
22.52
22.34
22.44
21.90
22.02
22.23
22.35
22.37
22.44
22.30
22.36
22.39
22.32
Temp
Tot
o ∗
C
21.69
21.69
21.92
21.92
21.59
21.59
22.25
22.25
21.90
21.90
22.16
22.16
21.91
21.91
21.89
21.89
21.93
21.93
21.85
21.85
21.73
21.73
22.04
22.04
21.39
21.39
22.15
22.15
21.38
21.38
22.11
22.11
22.13
22.13
22.73
22.73
22.69
22.69
22.59
22.59
22.00
22.00
22.36
22.36
21.94
21.94
22.29
22.29
21.97
21.97
22.32
HtVac
Tot
mm
793.947
793.947
791.809
791.809
791.678
791.678
782.229
782.229
787.211
787.211
788.340
788.340
787.197
787.197
789.725
789.725
791.653
791.653
790.800
790.800
793.262
793.262
795.494
795.494
791.442
791.442
791.614
791.614
791.032
791.032
789.597
789.597
784.345
784.345
790.546
790.546
788.184
788.184
789.626
789.626
779.719
779.719
782.548
782.548
780.957
780.957
785.109
785.109
788.321
788.321
789.119
HtSmp
CO2
mm
375.108
375.077
375.106
375.098
375.109
375.110
375.078
375.027
375.044
375.007
375.067
375.000
375.040
375.026
375.042
375.030
375.030
375.018
375.018
375.018
375.084
375.047
375.053
375.038
375.088
375.055
375.080
375.054
375.094
375.094
375.110
375.096
375.070
375.048
375.076
375.052
375.075
375.080
375.104
375.073
375.021
374.993
375.010
375.002
375.005
375.000
375.012
375.010
375.081
375.061
375.088
HtSmp
Tot
mm
177.868
177.868
177.852
177.852
177.888
177.888
177.721
177.721
177.813
177.813
177.854
177.854
177.774
177.774
177.780
177.780
177.824
177.824
177.752
177.752
177.772
177.772
177.769
177.769
177.896
177.896
177.836
177.836
177.789
177.789
177.880
177.880
177.844
177.844
177.820
177.820
177.846
177.846
177.805
177.805
177.706
177.706
177.723
177.723
177.661
177.661
177.712
177.712
177.786
177.786
177.795
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.24
0.24
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0
Flg
N2 O
659.378 789.119 375.058 177.795 -0.303 -0.005 0.00
HtVac
CO2
mm
657.072
657.116
675.620
675.700
675.996
676.190
646.802
646.852
649.612
649.665
670.323
670.418
670.408
670.438
579.312
579.330
657.078
657.114
656.678
656.746
656.893
656.964
657.690
657.654
676.873
676.914
675.299
675.466
677.250
677.425
675.970
675.988
655.630
655.643
657.800
657.846
655.478
655.545
656.237
656.208
654.625
654.839
655.172
655.285
673.220
673.415
675.022
675.092
659.160
659.180
659.274
Table A7: Manometric Reference Gas Measurements: Original Data. Page 24/34
∗
Temperature corrected for thermometer drift
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
HG JUMPED INTO CONTACT
PREMATURELY-CONSTRUCTION
351.89 HG CONTACTED POINTER PREMATURELY
ppm
346.19
346.24
371.08
371.06
371.01
371.01
340.71
340.71
340.74
340.80
366.55
366.58
366.58
366.57
252.17
252.14
347.97
347.93
347.90
347.91
346.24
346.30
346.23
346.15
371.42
371.48
371.48
371.46
372.12
372.26
372.20
372.19
349.43
349.47
349.36
349.41
347.92
347.96
347.92
347.93
351.15
351.33
351.22
351.22
373.87
373.96
373.86
373.86
351.82
351.79
351.82
CO2
11076 623
11076 623
11076
11076
11076
11092
11092
11092
11092
11081
11081
11081
11081
3756
3756
3756
3756
67615
67615
71251
71251
66696
66696
71479
71479
34819
34819
67615
67615
71286
71286
71370
71370
71251
71251
66696
66696
71341
71341
71308
71308
71479
71479
34819
34819
66625
66625
66638
66638
19980116
19980116
19980116
19980120
19980120
19980204
19980204
19980204
19980204
19980205
19980205
19980206
19980206
19980206
19980206
19980206
19980206
19980310
19980310
19980311
19980311
19980311
19980311
19980312
19980312
19980312
19980312
19980313
19980313
19980318
19980318
19980318
19980318
19980319
19980319
19980319
19980319
19980401
19980401
19980402
19980402
19980402
19980402
19980403
19980403
19980414
19980414
19980414
19980414
624
624
624
625
625
626
626
627
627
628
628
629
629
630
630
631
631
632
632
633
633
634
634
635
635
636
636
637
637
638
638
639
639
640
640
641
641
642
642
643
643
644
644
645
645
646
646
11076 623
19980116
Run
Cyl
Date
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
N2
N2
Vol
Tot
cc
5014.49
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
3.7934 5014.49
3.7934 5014.49
Gas Vol
CO2
cc
N2 3.7934
22.43
21.96
22.00
21.95
22.04
22.19
22.24
22.45
22.47
22.00
22.09
22.19
22.28
22.45
22.48
22.24
22.34
22.23
22.31
22.31
22.42
21.96
22.14
22.48
22.57
22.33
22.40
22.18
22.27
22.39
22.45
22.33
22.39
22.43
22.48
22.17
22.24
21.94
22.20
22.39
22.44
21.76
21.95
22.21
22.28
22.27
22.31
22.14
21.99
Temp
CO2
o ∗
C
21.91
21.94
21.94
21.94
22.21
22.21
21.98
21.98
22.22
22.22
22.45
22.45
22.03
22.03
22.23
22.23
22.00
22.00
22.27
22.27
22.28
22.28
22.36
22.36
22.03
22.03
22.51
22.51
22.13
22.13
22.22
22.22
22.42
22.42
22.36
22.36
22.27
22.27
22.20
22.20
22.01
22.01
22.41
22.41
21.89
21.89
22.23
22.23
22.41
22.41
Temp
Tot
o ∗
C
22.41
HtVac
Tot
mm
785.108
HtSmp
CO2
mm
375.106
HtSmp
Tot
mm
177.772
MnCor
CO2
mm
-0.303
MnCor N2 O
Tot
mm
ppm
-0.005 0.00
675.518
675.153
675.120
650.886
651.048
656.096
656.250
656.258
656.300
655.124
655.181
672.898
673.000
672.855
672.830
782.704
783.068
543.920
543.943
665.629
665.844
737.184
737.364
577.620
577.710
778.074
778.272
615.232
615.356
700.466
700.584
546.010
546.049
664.000
664.097
633.112
633.410
676.298
676.566
739.458
739.626
579.006
579.136
653.740
653.934
647.300
647.406
786.227
786.227
786.227
774.698
774.698
784.999
784.999
786.464
786.464
785.542
785.542
783.456
783.456
783.212
783.212
790.230
790.230
775.601
775.601
787.906
787.906
783.033
783.033
784.061
784.061
783.746
783.746
789.667
789.667
783.234
783.234
783.144
783.144
784.415
784.415
784.235
784.235
784.167
784.167
784.445
784.445
790.190
790.190
788.853
788.853
786.060
786.060
375.089
375.113
375.070
375.044
375.046
375.053
375.052
375.083
375.030
375.018
375.022
375.059
375.014
375.087
375.020
375.049
375.002
375.070
375.031
375.058
375.038
375.030
375.020
375.052
375.013
375.054
375.025
375.095
375.040
375.076
375.030
375.035
375.062
375.062
375.042
375.074
375.032
375.052
375.078
375.060
374.984
375.056
375.060
375.059
375.044
375.024
375.030
177.771
177.771
177.771
177.734
177.734
177.842
177.842
177.794
177.794
177.786
177.786
177.793
177.793
177.784
177.784
177.791
177.791
177.802
177.802
177.748
177.748
177.814
177.814
177.754
177.754
177.760
177.760
177.788
177.788
177.792
177.792
177.759
177.759
177.791
177.791
177.783
177.783
177.814
177.814
177.812
177.812
177.722
177.722
177.752
177.752
177.796
177.796
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.30
0.30
0.34
0.34
0.31
0.31
0.30
0.30
0.24
0.24
0.30
0.30
0.32
0.32
0.31
0.31
0.34
0.34
0.31
0.31
0.31
0.31
0.32
0.32
0.30
0.30
0.24
0.24
0.29
0.29
0.31
0.31
674.217 785.108 375.092 177.772 -0.303 -0.005 0.00
673.910 785.108 375.081 177.772 -0.303 -0.005 0.00
HtVac
CO2
mm
673.949
Table A7: Manometric Reference Gas Measurements: Original Data. Page 25/34
∗
Temperature corrected for thermometer drift
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
0
11
11
0
0
0
0
0
0
0
0
0
Flg
Comment
ppm
373.22 HG JUMPED INTO CONTACT
PREMATURELY-CONSTRUCTION
373.09 HG JUMPED INTO CONTACT
PREMATURELY-CONSTRUCTION
373.26 HG JUMPED INTO CONTACT VERY
PREMATURELY
373.19
373.33 HG CONTACTED POINTER PREMATURELY
373.29
350.09
350.18
350.14
350.27 HG JUMPED INTO CONTACT PREMATURELY
349.40 HG JUMPED INTO CONTACT PREMATURELY
349.50
349.44
349.40
372.11
372.17
372.08 HG CONTACTED POINTER PREMATURELY
372.09
503.69
504.02
213.17
213.18
360.15
360.30
453.64
453.58
252.00
252.08
504.00
504.16
296.55
296.67
406.42 HG CONTACTED POINTER PREMATURELY
406.54
213.19
213.16
360.15 HG JUMPED INTO CONTACT PREMATURELY
360.23
321.78
322.13
376.16
376.11
454.12
454.35
252.16
252.14
344.48
344.65
338.42
338.50
CO2
Cyl
71370
71370
71286
71286
2408
2408
35316
35316
66638
66638
71308
71308
4274
4274
35299
35299
7366
7366
71341
71341
66625
66625
71479
71479
7361
7361
7361
7361
7358
7358
7358
7358
39361
39361
39361
39361
4289
4289
4289
4289
6071
6071
1540
1540
2408
2408
35316
35316
6078
6078
39272
39272
4274
Date
19980415
19980415
19980415
19980415
19980506
19980506
19980506
19980506
19980507
19980507
19980507
19980507
19980508
19980508
19980707
19980707
19980708
19980708
19980709
19980709
19980709
19980709
19980710
19980710
19980717
19980717
19980804
19980804
19980805
19980805
19980805
19980805
19980806
19980806
19980806
19980806
19980806
19980806
19980807
19980807
19980812
19980812
19980812
19980812
19980813
19980813
19980813
19980813
19980819
19980819
19980820
19980820
19980820
647
647
648
648
649
649
650
650
651
651
652
652
653
653
654
654
655
655
656
656
657
657
658
658
659
659
660
660
661
661
662
662
663
663
664
664
665
665
666
666
667
667
668
668
669
669
670
670
671
671
672
672
673
Run
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
Vol
Tot
cc
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
Temp
CO2
o ∗
C
21.98
22.10
22.19
22.24
21.12
21.31
21.86
21.99
21.34
21.54
21.79
21.90
21.43
21.58
22.11
22.17
21.73
21.84
21.40
21.55
22.07
22.18
21.52
21.69
22.10
22.19
22.16
22.23
22.00
22.07
22.19
22.24
21.61
21.72
21.93
21.98
22.09
22.16
21.63
21.75
22.24
22.28
22.50
22.63
22.55
22.55
22.41
22.50
22.12
22.22
22.18
22.25
22.40
Temp
Tot
o ∗
C
22.29
22.29
22.01
22.01
21.15
21.15
21.20
21.20
21.81
21.81
21.41
21.41
21.82
21.82
21.27
21.27
22.14
22.14
21.77
21.77
21.47
21.47
22.09
22.09
21.45
21.45
21.76
21.76
22.19
22.19
22.03
22.03
22.21
22.21
21.67
21.67
21.94
21.94
22.12
22.12
22.62
22.62
22.23
22.23
22.54
22.54
22.55
22.55
21.69
21.69
22.15
22.15
22.20
HtVac
CO2
mm
702.792
702.878
614.488
614.556
533.938
534.006
754.684
754.960
647.770
647.962
677.990
678.161
571.226
571.332
709.898
710.022
597.113
597.280
633.570
633.836
651.762
651.912
739.151
739.359
656.451
656.503
657.898
657.987
654.398
654.476
654.280
654.307
676.892
676.986
675.970
676.034
675.230
675.390
674.118
674.250
624.263
624.340
680.619
680.755
533.609
533.596
752.403
752.480
624.270
624.351
664.583
664.590
570.830
HtVac
Tot
mm
788.310
788.310
787.285
787.285
787.356
787.356
784.756
784.756
787.965
787.965
786.200
786.200
788.124
788.124
786.759
786.759
785.933
785.933
785.361
785.361
783.482
783.482
786.544
786.544
781.371
781.371
785.005
785.005
783.164
783.164
782.172
782.172
787.173
787.173
783.399
783.399
785.451
785.451
784.367
784.367
785.763
785.763
784.905
784.905
785.914
785.914
782.587
782.587
783.531
783.531
785.263
785.263
785.367
HtSmp
CO2
mm
375.074
375.040
375.045
375.060
375.110
375.110
375.009
375.086
375.116
375.070
375.088
375.079
375.132
375.099
375.176
375.118
375.141
375.108
375.147
375.126
375.138
375.119
375.142
375.116
375.148
375.116
375.124
375.118
375.116
375.132
375.126
375.096
375.136
375.120
375.149
375.096
375.122
375.080
375.143
375.126
375.132
375.141
375.145
375.112
375.132
375.116
375.119
375.104
375.112
375.084
375.106
375.120
375.113
HtSmp
Tot
mm
177.766
177.766
177.716
177.716
177.804
177.804
177.808
177.808
177.789
177.789
177.792
177.792
177.784
177.784
177.861
177.861
177.826
177.826
177.829
177.829
177.819
177.819
177.822
177.822
177.835
177.835
177.857
177.857
177.782
177.782
177.829
177.829
177.807
177.807
177.845
177.845
177.856
177.856
177.800
177.800
177.795
177.795
177.926
177.926
177.840
177.840
177.890
177.890
177.870
177.870
177.922
177.922
177.837
Table A7: Manometric Reference Gas Measurements: Original Data. Page 26/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.31
0.31
0.32
0.32
0.00
0.00
0.00
0.00
0.31
0.31
0.32
0.32
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.29
0.29
0.30
0.30
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ppm
406.62
406.59
296.67
296.68
196.94
196.89
472.87
472.90
338.46
338.51
376.09
376.17
243.30
243.34
415.11
415.24
276.53
276.67
322.00
322.19
344.66
344.73
453.63
453.64
352.01
352.00
352.06
352.09
349.45
349.44
349.46
349.47
375.75
375.74
375.78
375.86
373.77
373.93
373.85
373.87
310.51
310.55
380.70
380.73
196.95
196.95
472.98
472.94
310.82
310.85
360.80
360.70
243.43
CO2
HG CONTACTED POINTER PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
Cyl
4274
35299
35299
4296
4296
39256
39256
7366
7366
1540
1540
2399
2399
39239
39239
6071
6071
39272
39272
6078
6078
4296
4296
39256
39256
2399
2399
39239
39239
62814
62814
62814
62814
62817
62817
62817
62817
39354
39354
39354
39354
10067
10067
10067
10067
39361
39361
39361
39361
7358
7358
7358
7358
Date
19980820
19980821
19980821
19980908
19980908
19980909
19980909
19980909
19980909
19980910
19980910
19981020
19981020
19981020
19981020
19981021
19981021
19981021
19981021
19981022
19981022
19981105
19981105
19981105
19981105
19981106
19981106
19981106
19981106
19981216
19981216
19981217
19981217
19981217
19981217
19981217
19981217
19990128
19990128
19990129
19990129
19990129
19990129
19990129
19990201
19990224
19990224
19990225
19990225
19990225
19990225
19990226
19990226
673
674
674
675
675
676
676
677
677
678
678
679
679
680
680
681
681
682
682
683
683
684
684
685
685
686
686
687
687
688
688
689
689
690
690
691
691
692
692
693
693
694
694
695
695
696
696
697
697
698
698
699
699
Run
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
Vol
Tot
cc
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.49
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
Temp
CO2
o ∗
C
22.40
22.13
22.19
22.21
22.32
22.17
22.28
22.72
22.73
22.45
22.50
22.24
22.30
22.37
22.41
22.01
22.11
22.14
22.21
21.86
21.95
22.21
22.26
22.25
22.34
21.98
22.07
22.27
22.31
22.60
22.62
22.56
22.64
22.77
22.82
22.89
22.93
22.02
22.12
21.39
21.58
22.04
22.13
22.26
22.09
23.00
23.00
22.57
22.65
22.88
22.88
22.32
22.48
Temp
Tot
o ∗
C
22.20
22.40
22.40
22.05
22.05
22.25
22.25
22.21
22.21
22.73
22.73
21.98
21.98
22.27
22.27
22.38
22.38
22.05
22.05
22.17
22.17
22.07
22.07
22.24
22.24
22.29
22.29
22.02
22.02
22.24
22.24
22.60
22.60
22.60
22.60
22.78
22.78
21.63
21.63
22.07
22.07
21.46
21.46
22.08
22.08
22.46
22.46
23.00
23.00
22.59
22.59
22.88
22.88
HtVac
CO2
mm
570.852
707.874
707.832
633.638
633.823
650.660
650.790
597.308
597.366
678.128
678.213
634.160
634.330
640.351
640.330
623.027
623.169
663.368
663.382
624.683
624.717
633.216
633.361
651.918
651.924
635.519
635.526
642.070
642.172
715.150
715.517
717.465
717.498
668.750
668.842
669.203
669.286
662.075
662.237
660.028
660.289
678.662
678.620
680.460
680.194
679.715
679.590
677.522
677.522
655.916
655.860
657.298
657.424
HtVac
Tot
mm
785.367
785.216
785.216
787.891
787.891
780.945
780.945
784.305
784.305
781.105
781.105
782.587
782.587
780.780
780.780
782.820
782.820
782.632
782.632
785.881
785.881
786.987
786.987
783.585
783.585
786.839
786.839
784.770
784.770
783.863
783.863
788.206
788.206
785.375
785.375
786.386
786.386
792.251
792.251
789.844
789.844
786.709
786.709
791.060
791.060
790.334
790.334
787.763
787.763
785.671
785.671
790.439
790.439
HtSmp
CO2
mm
375.070
375.116
375.126
375.120
375.130
375.120
375.114
375.114
375.100
375.103
375.101
375.076
375.060
375.070
375.046
375.086
375.054
375.070
375.042
375.060
375.079
375.086
375.060
375.047
375.025
375.062
375.022
375.060
375.040
374.994
374.948
374.988
374.946
374.990
374.964
374.982
374.970
374.993
374.922
374.939
374.951
374.936
374.868
374.926
374.976
374.955
374.949
374.978
375.005
375.001
374.978
374.953
374.932
HtSmp
Tot
mm
177.837
177.880
177.880
177.847
177.847
177.890
177.890
177.844
177.844
177.842
177.842
177.829
177.829
177.832
177.832
177.779
177.779
177.769
177.769
177.773
177.773
177.817
177.817
177.824
177.824
177.780
177.780
177.792
177.792
177.736
177.736
177.704
177.704
177.742
177.742
177.692
177.692
177.718
177.718
177.760
177.760
177.712
177.712
177.672
177.672
177.659
177.659
177.650
177.650
177.682
177.682
177.679
177.679
Table A7: Manometric Reference Gas Measurements: Original Data. Page 27/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0.31
0.31
0.28
0.28
0.28
0.28
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ppm
243.52
415.37
415.22
320.53
320.62
345.95
345.99
276.65
276.73
380.71
380.75
323.92
324.09
332.88
332.83
310.50
310.61
360.72
360.68
310.97
310.89
320.53
320.68
345.96
345.89
324.00
323.96
332.65
332.76
424.17
424.66
424.62
424.59
365.47
365.55
365.49
365.55
353.16
353.32
353.46
353.53
376.84
376.75
376.91
376.75
375.91
375.76
376.03
375.89
349.39
349.35
349.50
349.49
CO2
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
Cyl
66556
66556
66556
66556
110
110
110
110
111
111
111
111
103
103
103
103
139
139
139
139
107
107
107
107
103
103
101
101
101
101
136
136
136
136
105
105
105
105
103
103
105
105
105
105
105
35355
35355
35355
35355
39354
39354
39354
39354
Date
19990302
19990302
19990303
19990303
19990303
19990303
19990304
19990304
19990304
19990304
19990305
19990305
19990310
19990310
19990310
19990310
19990311
19990311
19990311
19990311
19990316
19990316
19990317
19990317
19990317
19990317
19990318
19990318
19990318
19990318
19990324
19990324
19990325
19990325
19990325
19990325
19990326
19990326
19990330
19990330
19990331
19990331
19990331
19990413
19990413
19990414
19990414
19990414
19990414
19990415
19990415
19990415
19990415
700
700
701
701
702
702
703
703
704
704
705
705
706
706
707
707
708
708
709
709
710
710
711
711
712
712
713
713
714
714
715
715
716
716
717
717
718
718
719
719
720
720
720
721
721
722
722
723
723
724
724
725
725
Run
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
Vol
Tot
cc
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
5014.5
Temp
CO2
o ∗
C
22.81
22.88
22.37
22.46
22.61
22.64
22.14
22.22
22.36
22.42
22.27
22.34
22.25
22.28
22.24
22.30
22.08
22.15
22.38
22.46
22.38
22.41
22.35
22.42
22.63
22.66
22.34
22.43
22.54
22.58
22.76
22.74
22.41
22.50
22.57
22.58
22.04
22.12
22.81
22.81
22.50
22.50
22.53
22.48
22.55
22.77
22.72
22.47
22.49
22.37
22.38
22.42
22.44
Temp
Tot
o ∗
C
22.72
22.72
22.85
22.85
22.39
22.39
22.61
22.61
22.18
22.18
22.38
22.38
22.32
22.32
22.26
22.26
22.26
22.26
22.11
22.11
22.42
22.42
22.39
22.39
22.38
22.38
22.64
22.64
22.37
22.37
22.33
22.33
22.75
22.75
22.47
22.47
22.57
22.57
22.47
22.47
22.81
22.81
22.81
22.09
22.09
22.52
22.52
22.75
22.75
22.47
22.47
22.37
22.37
HtVac
CO2
mm
457.190
457.114
456.577
456.506
573.680
573.641
573.514
573.516
635.110
635.091
636.070
636.098
656.196
656.186
659.141
659.222
666.430
666.481
665.551
665.682
739.829
739.871
738.844
738.901
658.619
658.722
693.786
693.929
695.896
695.925
686.102
686.154
680.973
681.000
672.184
672.274
671.716
671.790
666.882
666.864
667.050
667.227
667.330
674.341
674.135
663.218
663.083
661.627
661.541
659.336
659.305
660.574
660.510
HtVac
Tot
mm
788.545
788.545
785.513
785.513
785.795
785.795
786.956
786.956
784.386
784.386
787.308
787.308
788.325
788.325
786.830
786.830
788.959
788.959
786.534
786.534
787.600
787.600
785.674
785.674
785.993
785.993
787.716
787.716
790.427
790.427
793.956
793.956
785.450
785.450
786.580
786.580
786.219
786.219
802.089
802.089
786.906
786.906
786.906
789.605
789.605
794.077
794.077
791.770
791.770
786.889
786.889
789.031
789.031
HtSmp
CO2
mm
375.048
374.976
375.002
374.957
375.004
374.988
374.991
374.973
374.990
374.964
374.978
374.983
374.950
374.960
374.980
374.950
374.963
374.952
374.938
374.955
374.978
374.924
374.950
374.926
374.932
374.930
374.976
374.950
374.946
374.932
374.978
374.960
374.962
374.944
374.964
374.934
374.962
374.950
374.973
374.952
374.998
374.970
374.950
374.942
374.912
375.034
375.009
375.048
375.000
375.036
375.004
375.022
375.011
HtSmp
Tot
mm
177.710
177.710
177.672
177.672
177.668
177.668
177.666
177.666
177.658
177.658
177.675
177.675
177.670
177.670
177.609
177.609
177.657
177.657
177.686
177.686
177.692
177.692
177.702
177.702
177.730
177.730
177.732
177.732
177.737
177.737
177.700
177.700
177.694
177.694
177.672
177.672
177.713
177.713
177.584
177.584
177.742
177.742
177.742
177.650
177.650
177.772
177.772
177.862
177.862
177.726
177.726
177.772
177.772
Table A7: Manometric Reference Gas Measurements: Original Data. Page 28/34
∗
Temperature corrected for thermometer drift
MnCor
CO2
mm
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
-0.303
MnCor
Tot
mm
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
-0.005
Flg
0
0
0
0
0
0
0
0
0
0
0
0
11
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
11
11
0
0
0
0
0
0
0
0
0
0
N2 O
ppm
0.37
0.37
0.37
0.37
0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ppm
100.98
100.95
100.98
100.91
246.55
246.49
246.50
246.45
323.93
323.87
323.93
323.88
348.38
348.32
352.78
352.84
360.86
360.84
360.66
360.70
452.91
452.99
453.16
453.15
352.40
352.49
395.87
395.95
396.11
396.10
381.35
381.47
381.36
381.30
369.08
369.22
369.58
369.58
353.09
353.10
363.02
363.27
363.39
369.56
369.25
353.67
353.60
353.74
353.67
353.43
353.42
353.58
353.49
CO2
HG CONTACTED POINTER PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
EXTRACTION BLUNDER
EXTRACTION BLUNDER
HG CONTACTED POINTER PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
EXTRACTION BLUNDER
HG JUMPED INTO CONTACT PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
HG JUMPED INTO CONTACT PREMATURELY
HG CONTACTED POINTER PREMATURELY
HG CONTACTED POINTER PREMATURELY
Comment
71251 743
71251
34819
34819
34819
34819
34819 745
71286
71286
71286
71286
39272
39272
39272
20050211
20050211
20050211
20050211
20050215
20050215
20050215
20050215
20050215
20050216
20050216
20050217
20050217
20050217
746
746
747
747
748
748
749
743
744
744
745
745
726
726
727
727
728
728
729
729
730
730
731
731
732
732
733
733
734
734
735
735
736
736
737
737
738
738
739
739
740
740
741
741
742
742
743
66696
66696
66696
66696
71308
71308
71308
71308
71370
71370
71370
71370
66625
66625
66625
66625
71479
71479
71479
71479
66638
66638
66638
66638
71341
71341
71341
71341
67615
67615
67615
67615
71251
71251
71251
20041217
20041217
20041217
20050103
20050107
20050107
20050110
20050110
20050111
20050111
20050111
20050111
20050112
20050112
20050113
20050113
20050113
20050113
20050114
20050114
20050203
20050203
20050204
20050204
20050204
20050204
20050208
20050208
20050208
20050208
20050209
20050209
20050210
20050210
20050210
Run
Cyl
Date
Vol
Tot
cc
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
3.7934
3.7934
3.7934
3.7934
3.7934
5014.57
5014.57
5014.57
5014.57
5014.57
AIR
AIR
AIR
AIR
N2
N2
N2
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
AIR 3.7934 5014.57
AIR
AIR
AIR
AIR
AIR
AIR 3.7934 5014.57
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
23.92
23.97
24.03
24.09
24.06
24.05
24.03
23.88
23.52
23.71
23.73
23.86
23.86
23.50
Temp
CO2
o ∗
C
23.36
23.40
23.09
23.18
23.34
23.42
23.33
23.38
23.31
23.31
23.07
23.24
23.31
23.35
22.94
22.96
23.02
23.13
23.09
23.14
23.31
23.40
23.99
24.08
24.27
24.32
24.08
24.07
23.90
24.01
23.74
23.78
23.60
23.63
23.91
23.86
23.86
23.94
23.94
24.05
24.05
24.06
23.81
23.62
23.96
23.96
23.81
23.81
23.62
Temp
Tot
o ∗
C
22.94
22.94
23.34
23.34
23.32
23.32
23.38
23.38
23.36
23.36
23.31
23.31
23.11
23.11
23.33
23.33
22.94
22.94
23.07
23.07
23.44
23.44
23.35
23.35
24.03
24.03
23.89
23.89
24.07
24.07
23.91
23.91
23.77
23.77
23.62
HtVac
Tot
mm
764.975
764.975
767.070
767.070
758.508
758.508
758.038
758.038
762.565
762.565
760.810
760.810
760.671
760.671
764.440
764.440
766.312
766.312
765.783
765.783
780.551
780.551
767.393
767.393
765.254
765.254
765.408
765.408
763.905
763.905
764.902
764.902
765.300
765.300
762.094
HtSmp
CO2
mm
371.394
371.414
371.459
371.476
371.492
371.448
371.488
371.468
371.464
371.435
371.460
371.436
371.474
371.454
371.476
371.442
371.522
371.518
371.567
371.524
371.406
371.406
371.442
371.407
371.414
371.433
371.432
371.408
371.432
371.400
371.427
371.404
371.447
371.409
371.439
HtSmp
Tot
mm
174.066
174.066
174.127
174.127
174.157
174.157
174.108
174.108
174.092
174.092
174.202
174.202
174.133
174.133
174.084
174.084
174.064
174.064
174.207
174.207
174.202
174.202
174.110
174.110
174.136
174.136
174.152
174.152
174.086
174.086
174.148
174.148
174.188
174.188
174.125
MnCor
CO2
mm
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
MnCor
Tot
mm
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.31
0.31
0.31
0.31
0.32
0.32
0.32
0.32
0.31
0.31
0.31
0.31
0.29
0.29
0.29
0.29
0.30
0.30
0.30
0.30
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.30
0.30
0.30
0.30
0.34
0.34
0.34
762.094
761.517
761.517
766.524
766.524
371.404
371.425
371.410
371.410
371.412
174.125
174.147
174.147
174.163
174.163
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
0.34
0.24
0.24
0.24
0.24
603.015
603.084
603.030
603.116
653.319
653.274
652.084
763.638
763.638
763.687
763.687
765.569
765.569
762.990
371.430
371.376
371.432
371.411
371.396
371.400
371.429
174.165
174.165
174.158
174.158
174.224
174.224
174.162
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
0.32
0.32
0.32
0.32
0.00
0.00
0.00
569.268 766.524 371.422 174.163 -0.271 +0.135 0.24
537.500
567.398
567.490
569.300
569.189
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Flg
N2 O
537.520 762.094 371.420 174.125 -0.271 +0.135 0.34
HtVac
CO2
mm
653.540
653.593
653.863
654.177
662.254
662.432
662.243
662.224
687.982
687.929
686.796
686.852
639.112
639.201
640.354
640.377
726.552
726.754
726.123
726.289
643.002
643.066
637.936
637.944
623.666
623.758
623.720
623.657
764.213
764.366
764.780
764.786
538.430
538.424
537.688
Table A7: Manometric Reference Gas Measurements: Original Data. Page 29/34
∗
Temperature corrected for thermometer drift
Comment
ppm
360.51
360.50
360.46
360.73
376.26
376.44
376.62
376.55
406.96
406.93
407.00
406.86
344.75
344.84
344.83
344.88
453.57
453.65
453.57
453.76
338.80
338.77
338.81
338.75
322.27
322.30
322.30
322.26
504.50
504.54
504.44
504.40
213.27
213.29
213.12 Mercury made
with pointer
213.24 Mercury made
with pointer
213.22
252.24
252.36
252.29
252.15 Mercury made
with pointer
252.22 Mercury made
with pointer
296.78
296.88
296.73
296.81
360.83
360.78
360.79
CO2
premature contact
premature contact
premature contact
premature contact
Cyl
39272
1540
1540
1540
1540
35299
35299
35299
35299
39256
39256
39256
39256
39239
39239
39239
39239
2408
2408
2408
2408
35316
35316
35316
35316
6071
6071
6071
6071
7366
7366
7366
7366
4274
4274
4274
4274
4296
4296
4296
4296
6078
6078
2399
2399
6078
6078
2399
2399
18372
18372
Date
20050217
20050218
20050218
20050317
20050317
20050318
20050318
20050323
20050323
20050324
20050324
20050325
20050325
20050325
20050325
20050329
20050329
20050330
20050330
20050330
20050330
20050331
20050331
20050331
20050401
20050401
20050401
20050503
20050503
20050504
20050504
20050504
20050504
20050505
20050505
20050506
20050506
20050506
20050506
20050509
20050509
20050510
20050510
20050511
20050511
20050511
20050511
20050512
20050512
20050513
20050513
767
767
768
768
769
769
770
770
771
771
772
772
773
773
774
774
752
752
753
753
754
754
755
755
756
756
757
757
758
758
759
759
760
760
761
761
762
762
763
763
764
764
765
765
766
766
749
750
750
751
751
Run
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
AIR
AIR
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
N2
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
Gas Vol
CO2
cc
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
N2 3.7934
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
Vol
Tot
cc
5014.57
5014.57
5014.57
5014.57
5014.57
23.97
23.97
23.81
23.84
23.92
24.01
23.80
23.83
23.81
23.83
23.89
23.94
23.92
23.96
24.18
24.18
23.41
23.45
23.41
23.46
23.38
23.44
23.45
23.48
23.38
23.43
23.40
23.45
23.54
23.60
23.66
23.74
23.17
23.21
23.34
23.49
23.36
23.43
23.80
23.85
23.97
24.00
23.96
23.98
23.86
23.92
Temp
CO2
o ∗
C
24.09
24.39
24.35
23.47
23.53
23.87
23.87
23.97
23.97
23.83
23.83
23.96
23.96
23.82
23.82
23.82
23.82
23.92
23.92
23.94
23.94
23.50
23.50
23.49
23.49
23.43
23.43
23.41
23.41
23.47
23.47
23.80
23.80
23.42
23.42
23.57
23.57
23.70
23.70
23.18
23.18
23.43
23.43
23.84
23.84
23.83
23.83
24.00
24.00
23.97
23.97
Temp
Tot
o ∗
C
24.06
24.06
24.06
23.95
23.95
561.636
561.584
621.232
621.254
623.238
623.254
613.746
613.752
624.722
624.696
613.528
613.570
623.780
623.802
664.036
663.965
694.857
694.901
695.134
695.176
642.464
642.536
642.753
642.728
631.188
631.220
630.735
630.765
526.112
526.066
525.387
525.417
740.356
740.493
742.340
742.729
615.301
615.351
613.846
613.889
587.945
587.920
587.386
587.400
561.674
561.674
HtVac
CO2
mm
652.122
666.770
666.704
666.292
666.454
764.453
764.453
763.605
763.605
767.870
767.870
764.049
764.049
765.358
765.358
763.080
763.080
763.252
763.252
762.374
762.374
763.839
763.839
764.439
764.439
766.834
766.834
767.038
767.038
764.485
764.485
764.200
764.200
766.981
766.981
764.558
764.558
766.230
766.230
767.891
767.891
767.870
767.870
764.569
764.569
765.524
765.524
764.491
764.491
765.035
765.035
HtVac
Tot
mm
762.990
760.496
760.496
761.316
761.316
371.483
371.442
371.482
371.444
371.466
371.436
371.458
371.442
371.450
371.444
371.451
371.438
371.478
371.446
371.477
371.440
371.472
371.461
371.464
371.456
371.484
371.454
371.488
371.451
371.495
371.467
371.484
371.468
371.526
371.475
371.510
371.453
371.484
371.455
371.470
371.472
371.500
371.468
371.490
371.424
371.494
371.440
371.470
371.449
371.478
371.460
HtSmp
CO2
mm
371.404
371.426
371.410
371.501
371.476
174.154
174.154
174.170
174.170
174.173
174.173
174.214
174.214
174.195
174.195
174.178
174.178
174.246
174.246
174.220
174.220
174.208
174.208
174.171
174.171
174.110
174.110
174.179
174.179
174.116
174.116
174.182
174.182
174.220
174.220
174.207
174.207
174.154
174.154
174.127
174.127
174.110
174.110
174.207
174.207
174.291
174.291
174.222
174.222
174.270
174.270
HtSmp
Tot
mm
174.162
174.201
174.201
174.219
174.219
Table A7: Manometric Reference Gas Measurements: Original Data. Page 30/34
∗
Temperature corrected for thermometer drift
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
MnCor
CO2
mm
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
MnCor
Tot
mm
+0.135
+0.135
+0.135
+0.135
+0.135
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31
0.31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Flg
N2 O
Comment
ppm
360.79
380.88
380.86
380.74
380.90 Mercury made premature contact
with pointer
415.41
415.43
415.32
415.31
346.05
346.11
346.23
346.20
332.97
332.99
332.96
332.96
196.98
196.94
196.89
196.95
472.83
472.97
472.88
473.12
310.73
310.76
310.63
310.71
276.75
276.76
276.69
276.72
243.51
243.48 Mercury made premature contact
with pointer
243.46
243.45
320.77
320.81
320.77
320.72
310.95
310.94
324.18
324.13
310.92
310.93
324.11
324.13
375.86
375.81
CO2
18372 775
17438
17438
17438
17438
17476
17476
17476
17476
20737
20737
20737
20737
71308
71308
66696
66696
71370
71370
18067
18067
18067
18067
17563
17563
17563
17563
17491
17491
17491
17491
17440
17440
17440
17440
18470
18470
18470
18470
67615
67615
66638
66638
71479
71479
66625
66625
66625 798
34819 799
20050513
20050608
20050608
20050608
20050608
20050609
20050609
20050610
20050610
20050610
20050610
20050614
20050614
20050614
20050614
20050615
20050616
20050616
20050616
20050617
20050617
20050617
20050617
20050707
20050707
20050707
20050707
20050708
20050708
20050708
20050708
20050712
20050712
20050713
20050713
20050713
20050714
20050714
20050714
20050715
20050715
20050715
20050715
20050719
20050719
20050719
20050719
20050720
20050720
776
776
777
777
778
778
779
779
780
780
781
781
782
782
783
783
784
784
785
785
786
786
787
787
788
788
789
789
790
790
791
791
792
792
793
793
794
794
795
795
796
796
797
797
798
798
18372 775
20050513
Run
Cyl
Date
Vol
Tot
cc
5014.57
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
AIR 3.7934 5014.57
AIR 3.7934 5014.57
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR 3.7934 5014.57
Gas Vol
CO2
cc
AIR 3.7934
24.15
23.97
24.77
24.97
25.67
25.91
24.63
24.76
24.64
24.63
24.77
24.88
23.98
23.98
23.91
23.93
23.94
23.97
23.97
24.00
24.02
24.01
23.93
23.97
24.52
24.55
24.41
24.41
24.36
24.38
24.33
24.38
24.42
24.35
24.38
24.29
24.02
23.94
23.88
23.89
24.06
24.06
23.96
24.00
24.12
24.12
24.07
24.12
24.04
Temp
CO2
o ∗
C
23.96
24.12
24.09
24.37
24.37
24.81
24.81
25.76
25.76
24.69
24.69
24.63
24.63
24.07
24.07
23.98
23.98
23.96
23.96
23.96
23.96
23.99
23.99
24.02
24.02
24.38
24.38
24.53
24.53
24.41
24.41
24.36
24.36
24.29
24.29
24.41
24.41
24.35
24.35
24.02
24.02
23.88
23.88
24.06
24.06
24.07
24.07
24.12
24.12
24.18
Temp
Tot
o ∗
C
24.18
HtVac
Tot
mm
763.453
HtSmp
CO2
mm
371.494
HtSmp
Tot
mm
174.192
MnCor
CO2
mm
-0.271
MnCor N2 O
Tot
mm
ppm
+0.135 0.31
762.003
762.003
761.801
761.801
763.629
763.629
764.521
764.521
761.645
761.645
760.285
760.285
761.242
761.242
760.700
760.700
761.763
761.763
765.539
765.539
763.640
763.640
763.724
763.724
762.317
762.317
762.929
762.929
763.291
763.291
762.808
762.808
762.415
762.415
764.975
764.975
764.091
764.091
764.118
764.118
763.308
763.308
761.630
761.630
761.974
761.974
371.489
371.459
371.466
371.455
371.488
371.474
371.502
371.456
371.468
371.451
371.484
371.436
371.468
371.496
371.486
371.467
371.458
371.440
371.475
371.450
371.462
371.472
371.499
371.470
371.466
371.450
371.482
371.448
371.494
371.478
371.452
371.468
371.478
371.440
371.462
371.471
371.440
371.436
371.484
371.406
371.446
371.443
371.460
371.429
371.434
371.444
174.196
174.196
174.232
174.232
174.186
174.186
174.186
174.186
174.202
174.202
174.180
174.180
174.206
174.206
174.228
174.228
174.132
174.132
174.220
174.220
174.172
174.172
174.243
174.243
174.175
174.175
174.208
174.208
174.168
174.168
174.190
174.190
174.184
174.184
174.213
174.213
174.162
174.162
174.162
174.162
174.188
174.188
174.222
174.222
174.152
174.152
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.32
0.32
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.32
0.31
0.31
0.31
0.31
0.30
0.30
0.31
0.31
0.30
0.30
0.29
0.29
639.483 761.974 371.484 174.152 -0.271 +0.135 0.29
567.683 762.140 371.490 174.150 -0.271 +0.135 0.24
799.454
799.656
799.784
800.190
641.972
642.094
643.456
643.391
703.718
703.898
702.775
702.657
663.392
663.480
651.022
651.069
687.374
687.388
646.914
646.876
645.890
645.916
674.499
674.437
673.440
673.419
684.621
684.621
684.802
684.870
744.551
744.400
744.231
744.014
653.695
653.702
653.480
653.503
764.734
764.640
635.249
635.276
723.684
723.618
639.390
639.374
664.169 763.453 371.472 174.192 -0.271 +0.135 0.31
HtVac
CO2
mm
664.072
Table A7: Manometric Reference Gas Measurements: Original Data. Page 31/34
∗
Temperature corrected for thermometer drift
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Flg
Comment
ppm
375.79 Mercury made premature contact
with pointer
375.83 Mercury made premature contact
with pointer
550.62
550.53
550.39
550.46
348.32
348.33
348.35
348.34
427.71
427.80
427.81
427.71
376.16
376.21
360.43
360.48
406.67
406.67
352.15
352.15
352.11
352.08
388.57
388.48
388.49
388.48
402.41
402.43
402.33
402.36
479.56
479.47
479.70
479.63
361.67
361.77
361.69
361.71
504.36
504.33
338.64
338.63
453.72
453.67
344.71
344.61 Mercury made premature contact
with pointer
344.66
252.14
CO2
Cyl
34819
71341
71341
71286
71286
71251
71251
71308
71308
71370
71370
66696
66696
67615
67615
66638
66638
71479
71479
66625
66625
34819
34819
71341
71341
71286
71286
71251
71251
1661
1661
1649
1649
1649
1649
1653
1653
1653
1653
1661
1661
1661
1661
6873
6873
6873
6873
1662
1662
1662
1662
Date
20050720
20050721
20050721
20050809
20050809
20050809
20050809
20050810
20050810
20050811
20050811
20050812
20050812
20050812
20050812
20050815
20050815
20050816
20050816
20050817
20050817
20050817
20050817
20050818
20050818
20050819
20050819
20050819
20050819
20050907
20050907
20050909
20050909
20050921
20050921
20050922
20050922
20050922
20050923
20050923
20050923
20051012
20051012
20051012
20051012
20051013
20051013
20051014
20051014
20051014
20051014
813
814
814
815
815
816
816
817
817
818
818
819
819
820
820
821
821
822
822
823
823
824
824
811
811
812
812
813
799
800
800
801
801
802
802
803
803
804
804
805
805
806
806
807
807
808
808
809
809
810
810
Run
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
5014.57
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.57
5014.57
5014.57
5014.57
5014.57
Vol
Tot
cc
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
5014.57
24.08
23.83
23.86
23.83
23.87
23.74
23.75
23.80
23.81
23.78
24.06
23.83
23.89
24.72
24.72
24.77
24.58
23.61
23.67
23.79
23.79
23.71
23.80
23.98
23.99
24.43
24.41
24.05
Temp
CO2
o ∗
C
24.02
24.01
24.00
24.01
23.96
24.00
24.08
23.98
24.01
23.92
23.94
24.18
24.18
24.03
24.09
23.98
23.98
23.94
23.98
24.20
24.20
23.98
24.09
24.42
23.93
23.93
23.93
23.93
23.71
23.71
23.74
23.74
23.80
23.80
23.80
23.80
24.43
24.43
24.72
24.72
24.71
24.71
23.63
23.63
23.79
23.79
24.01
24.01
23.98
23.98
24.42
Temp
Tot
o ∗
C
24.09
23.99
23.99
23.77
23.77
23.97
23.97
24.04
24.04
24.01
24.01
23.93
23.93
24.18
24.18
23.98
23.98
23.98
23.98
23.96
23.96
24.20
24.20
537.798
668.550
668.572
661.730
661.773
661.700
661.606
669.832
669.791
668.426
668.766
667.677
667.766
669.871
669.815
653.644
653.458
652.089
652.138
647.012
646.908
644.875
645.029
622.577
622.578
603.354
603.286
537.795
HtVac
CO2
mm
567.675
623.269
623.232
604.333
604.216
538.030
538.040
665.492
665.466
691.763
691.755
653.653
653.607
765.155
765.258
636.766
636.742
724.984
725.028
641.404
641.347
568.363
568.367
763.844
765.269
765.269
767.882
767.882
767.123
767.123
766.875
766.875
764.409
764.409
763.360
763.360
767.017
767.017
766.391
766.391
765.643
765.643
767.765
767.765
763.657
763.657
763.549
763.549
763.831
763.831
763.844
HtVac
Tot
mm
762.140
764.922
764.922
766.590
766.590
764.032
764.032
765.561
765.561
770.222
770.222
765.759
765.759
765.629
765.629
766.638
766.638
764.243
764.243
765.868
765.868
764.532
764.532
371.475
371.486
371.478
371.468
371.518
371.447
371.421
371.474
371.454
371.459
371.458
371.456
371.456
371.477
371.452
371.494
371.447
371.494
371.434
371.464
371.440
371.486
371.436
371.474
371.442
371.464
371.462
371.466
HtSmp
CO2
mm
371.419
371.468
371.454
371.478
371.454
371.469
371.438
371.492
371.434
371.474
371.440
371.480
371.432
371.461
371.453
371.454
371.435
371.464
371.435
371.484
371.457
371.475
371.432
174.222
174.237
174.237
174.230
174.230
174.195
174.195
174.198
174.198
174.187
174.187
174.196
174.196
174.278
174.278
174.180
174.180
174.208
174.208
174.192
174.192
174.196
174.196
174.217
174.217
174.201
174.201
174.222
HtSmp
Tot
mm
174.150
174.172
174.172
174.197
174.197
174.152
174.152
174.227
174.227
174.228
174.228
174.172
174.172
174.232
174.232
174.182
174.182
174.154
174.154
174.170
174.170
174.232
174.232
Table A7: Manometric Reference Gas Measurements: Original Data. Page 32/34
∗
Temperature corrected for thermometer drift
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
MnCor
CO2
mm
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
MnCor
Tot
mm
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
0.34
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.24
0.31
0.31
0.32
0.32
0.34
0.34
0.32
0.32
0.31
0.31
0.31
0.31
0.30
0.30
0.31
0.31
0.30
0.30
0.29
0.29
0.24
0.24
0.31
0.31
0.32
0.32
0.34
Flg
N2 O
Comment
ppm
252.17
322.14
322.13
296.75
296.68
213.02
213.02
376.07
376.07
406.68
406.68
360.35
360.35
504.29
504.32
338.54
338.53
453.47
453.50
344.61
344.57
252.13
252.09 Mercury made premature contact
with pointer
322.08
322.11
296.68
296.61
213.12 Mercury made premature contact
with pointer
213.09
380.27
380.26
369.89
369.82
370.16
370.06
380.65
380.61
380.56
380.61
380.21
380.24
380.34
380.30
360.19
360.25
360.14
360.20
350.79
350.69
350.76
350.91
CO2
Cyl
1658
1658
1658
1658
1655
1655
1661
1661
1661
1661
1655
1655
1661
1661
1661
1661
1659
1659
1659
1659
1654
1654
1654
1654
1661
1661
1661
1648
1648
1648
1648
1661
1661
1661
1661
1661
1653
1653
1658
1658
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
Date
20051018
20051018
20051019
20051019
20051020
20051020
20051021
20051021
20051110
20051110
20051122
20051122
20051122
20051122
20051213
20051213
20051214
20051214
20051215
20051215
20051215
20051215
20051216
20051216
20060109
20060109
20060110
20060110
20060110
20060111
20060111
20060424
20060424
20060622
20060622
20060818
20060821
20060821
20060822
20060822
20060823
20060823
20060925
20060925
20060926
20060927
20060927
20061024
20061024
20061206
849
849
850
845
846
847
848
848
840
841
841
841
842
842
843
843
844
844
825
825
826
826
827
827
828
828
829
829
830
830
831
831
832
832
833
833
834
834
835
835
836
836
837
837
837
838
838
839
839
840
Run
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.59
5014.59
5014.59
5014.59
5014.59
5014.58
5014.59
5014.59
5014.59
5014.59
5014.59
5014.59
5014.59
5014.59
5014.59
Vol
Tot
cc
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
5014.58
AIR 3.7934 5014.59
AIR 3.7934 5014.59
AIR 3.7934 5014.59
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
AIR 3.7934
24.13
24.13
22.07
24.03
24.09
23.78
23.86
23.86
23.74
24.50
24.41
24.66
23.69
23.80
23.60
23.66
23.80
23.80
Temp
CO2
o ∗
C
23.70
23.72
23.85
23.86
23.88
23.90
23.85
23.90
24.13
24.13
23.67
23.82
24.09
24.21
23.53
23.56
23.42
23.47
23.46
23.47
23.46
23.54
23.30
23.34
23.74
23.74
23.07
23.31
23.36
23.35
23.44
23.67
24.44
24.44
22.51
23.88
23.90
23.76
23.85
23.85
23.73
24.22
24.22
24.22
23.89
23.89
23.71
23.71
23.64
23.64
Temp
Tot
o ∗
C
23.82
23.82
23.70
23.70
23.96
23.96
23.89
23.89
24.05
24.05
23.74
23.74
23.71
23.71
23.39
23.39
23.55
23.55
23.45
23.45
23.46
23.46
23.49
23.49
23.55
23.55
23.55
23.74
23.74
23.33
23.33
23.73
764.746
763.893
764.195
770.608
770.608
770.436
766.353
766.353
766.353
766.410
766.410
766.085
766.085
766.638
766.638
HtVac
Tot
mm
764.911
764.911
767.200
767.200
768.797
768.797
768.705
768.705
767.371
767.371
771.376
771.376
768.259
768.259
769.906
769.906
769.817
769.817
774.867
774.867
768.284
768.284
767.234
767.234
772.664
772.664
772.664
770.614
770.614
770.296
770.296
770.436
371.428
371.454
371.422
371.453
371.430
371.472
371.450
371.426
371.451
371.416
371.428
371.457
371.416
371.441
371.450
HtSmp
CO2
mm
371.462
371.422
371.475
371.456
371.451
371.424
371.462
371.477
371.497
371.466
371.444
371.434
371.447
371.448
371.450
371.416
371.431
371.418
371.460
371.405
371.442
371.442
371.425
371.408
371.475
371.428
371.458
371.466
371.420
371.464
371.459
371.454
174.110
174.135
174.128
174.178
174.178
174.186
174.188
174.188
174.188
174.169
174.169
174.196
174.196
174.222
174.222
HtSmp
Tot
mm
174.180
174.180
174.205
174.205
174.180
174.180
174.208
174.208
174.194
174.194
174.246
174.246
174.163
174.163
174.167
174.167
174.183
174.183
174.250
174.250
174.200
174.200
174.188
174.188
174.195
174.195
174.195
174.146
174.146
174.208
174.208
174.186
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
MnCor
CO2
mm
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
MnCor
Tot
mm
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
0.31
0.31
0.31
0.31
0.31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppm
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
Flg
N2 O
667.624 763.693 371.454 174.165 -0.271 +0.135 0.31
667.644 763.693 371.446 174.165 -0.271 +0.135 0.31
671.832 772.360 371.458 174.137 -0.271 +0.135 0.31
668.624
668.158
668.220
671.432
671.438
671.506
669.588
669.474
669.860
669.332
669.440
685.820
685.856
669.569
669.540
HtVac
CO2
mm
685.174
685.170
686.737
686.708
705.630
705.688
670.392
670.429
670.020
669.993
707.284
707.366
670.658
670.798
671.190
671.170
638.802
638.813
641.228
641.194
623.121
623.182
622.503
622.566
672.648
672.670
671.925
609.122
609.130
609.386
609.436
671.420
Table A7: Manometric Reference Gas Measurements: Original Data. Page 33/34
∗
Temperature corrected for thermometer drift
Comment
ppm
401.89
401.91
401.96
401.93
425.35
425.43
380.35
380.31
380.51
380.52
425.66
425.55
380.40
380.41
380.35
380.32
339.51
339.48
339.56
339.57
320.20
320.19
320.21
320.27
380.36
380.45
380.37
301.55
301.56
301.60
301.57
380.58 Mercury made premature contact
with pointer
380.57
380.40
380.40
380.53
380.72
380.69
401.93
401.94
380.39
380.34 Mercury made premature contact
with pointer
380.35 CO2 extract measured in ECMII first
380.23 CO2 extract measured in ECMII first
380.38 CO2 extract measured in ECMII first
380.38
380.42 Mercury made premature contact
with pointer
380.37
380.40
380.36
CO2
Cyl
1661
1661
1661
1661
1661
6874
6874
6874
6874
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
1661
Date
20061206
20070308
20070308
20071114
20071114
20071115
20071115
20071115
20071116
20071119
20071119
20080108
20080108
20080108
20080312
20080312
20080515
20080515
20080515
20080721
20080721
20080917
20080917
20081118
20081118
20090122
20090122
20090319
20090320
20090519
20090519
20090921
20090921
20091210
20091210
20100209
20100209
858
858
859
859
860
860
861
861
862
862
863
863
864
864
865
865
866
866
867
867
857
857
858
856
856
856
854
854
855
855
851
852
852
853
853
850
851
Run
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.6
5014.6
5014.6
5014.6
5014.59
5014.6
5014.6
5014.6
5014.6
Vol
Tot
cc
5014.59
5014.59
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
3.7934
5014.61
5014.61
5014.61
5014.61
5014.61
5014.61
5014.61
5014.61
5014.61
5014.61
5014.62
5014.62
5014.62
5014.62
5014.62
5014.62
5014.63
5014.63
5014.63
5014.63
AIR 3.7934 5014.6
AIR 3.7934 5014.6
AIR 3.7934 5014.61
AIR 3.7934 5014.6
AIR 3.7934 5014.6
AIR 3.7934 5014.6
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
AIR
Gas Vol
CO2
cc
AIR 3.7934
AIR 3.7934
23.03
23.49
22.32
22.36
22.08
22.12
21.83
21.82
21.77
21.87
19.85
19.89
21.12
21.14
21.66
21.75
20.51
20.54
21.73
21.91
24.84
24.65
23.03
21.99
22.24
21.93
24.17
23.41
22.96
22.99
24.20
23.10
23.47
23.11
23.37
Temp
CO2
o ∗
C
22.16
24.19
22.56
22.56
22.42
22.42
21.62
21.62
21.90
21.90
22.11
22.11
20.04
20.04
20.88
20.88
21.89
21.89
20.62
20.62
21.02
21.02
25.49
25.49
22.56
22.43
22.43
22.43
23.14
23.14
23.08
23.08
24.19
23.39
23.39
23.21
23.21
Temp
Tot
o ∗
C
22.51
24.19
764.025
764.025
769.855
769.855
720.085
770.958
770.958
767.796
767.796
HtVac
Tot
mm
772.360
720.085
371.416
371.424
371.400
371.416
371.446
371.452
371.398
371.455
371.426
HtSmp
CO2
mm
371.427
371.472
174.118
174.118
174.094
174.094
174.114
174.123
174.123
174.165
174.165
HtSmp
Tot
mm
174.137
174.114
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
MnCor
CO2
mm
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
MnCor
Tot
mm
+0.135
+0.135
0.31
0.31
0.31
0.31
671.032
671.490
668.210
668.256
670.627
670.598
676.942
677.016
677.680
677.682
678.018
677.968
680.472
680.457
672.360
672.499
674.598
674.638
674.009
674.190
768.906
768.906
764.321
764.321
767.949
767.949
777.129
777.129
776.883
776.883
775.954
775.954
778.314
778.314
772.071
772.071
776.373
776.373
773.442
773.442
371.441
371.408
371.430
371.396
371.447
371.420
376.412
376.374
378.383
378.398
379.430
379.416
381.480
381.436
372.497
372.470
372.464
372.458
372.450
372.446
174.124
174.124
174.092
174.092
174.088
174.088
179.136
179.136
181.140
181.140
182.069
182.069
184.158
184.158
175.199
175.199
175.200
175.200
175.149
175.149
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
-0.271
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
+0.135
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31
675.230 779.876 371.412 174.081 -0.271 +0.135 0.31
675.084 779.876 371.386 174.081 -0.271 +0.135 0.31
670.910 768.906 371.434 174.124 -0.271 +0.135 0.31
669.564 767.987 371.438 174.118 -0.271 +0.135 0.31
669.792 767.987 371.446 174.118 -0.271 +0.135 0.31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
0
10
0
0
0
0
0
0
0
0
0
0
0
ppm
0.31
0.31
0.31
0.31
0.31
0.31
0.31
Flg
N2 O
669.285 767.987 371.454 174.118 -0.271 +0.135 0.31
688.920
688.122
670.848
670.844
646.044
671.488
671.729
689.685
689.884
HtVac
CO2
mm
671.874
646.047
Table A7: Manometric Reference Gas Measurements: Original Data. Page 34/34
∗
Temperature corrected for thermometer drift
Comment
ppm
380.33
380.26 Mercury made premature contact
with pointer
380.28
380.61
380.48
405.68
405.60 Mercury made premature contact
with pointer-Hg "jumping"
405.67
405.74
380.31
380.25 Mercury made premature contact
with pointer
379.98 Mercury made premature contact
with pointer
380.28
380.22 Mercury made premature contact
with pointer
380.19
380.30
380.17 Mercury made premature contact
with pointer
380.32
380.32
380.43
380.47
380.40
380.35
380.21
380.36
380.44
380.29
380.53
380.43
380.28
380.29
380.29
380.38
380.28
380.30
380.26
380.24
CO2
18 Appendix B. Supplemental Figures
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.34
J
X
Fit
Res
175.366 196.864 196.848 +0.016
238.238 246.178 246.219 −0.041
273.293 276.673 276.694 −0.021
309.768 310.908 310.888 +0.020
323.104 324.106 324.061 +0.044
331.712 332.778 332.763 +0.016
358.253 360.662 360.604 +0.058
376.498 380.579 380.659 −0.080
406.295 415.055 415.092 −0.037
452.471 472.821 472.796 +0.025
Standard Deviation 0.043
Central Date: 29−Jul−1985
Coefficients
+8.7122521e+01
+5.3715469e−01
+3.8352208e−04
+6.9205292e−07
Cyl
2408
3753
7366
6078
2399
39239
39272
1540
35299
35316
Figure B-1: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1985
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1985
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.34
J
X
Fit
Res
194.625 213.164 213.132 +0.032
242.140 251.848 251.929 −0.080
291.559 296.662 296.670 −0.008
317.479 322.216 322.091 +0.126
333.250 338.241 338.257 −0.016
339.277 344.579 344.579 +0.001
353.720 360.004 360.060 −0.056
368.353 376.250 376.232 +0.018
394.516 406.417 406.408 +0.010
432.676 453.403 453.456 −0.053
470.279 503.567 503.539 +0.028
Standard Deviation 0.056
Central Date: 29−Jul−1985
Coefficients
+8.8009480e+01
+5.3560752e−01
+4.1801357e−04
+6.8451741e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-2: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1985
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1985
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.37
J
X
Fit
Res
175.102 196.873 196.867 +0.006
238.182 246.237 246.244 −0.007
273.214 276.672 276.692 −0.020
309.663 310.903 310.898 +0.005
323.001 324.090 324.097 −0.007
331.571 332.793 332.777 +0.016
358.034 360.671 360.599 +0.072
376.225 380.607 380.643 −0.036
405.995 415.087 415.134 −0.047
452.032 472.833 472.814 +0.019
Standard Deviation 0.033
Central Date: 06−Dec−1987
Coefficients
+8.8951442e+01
+5.2163260e−01
+4.2431314e−04
+6.6439670e−07
Cyl
2408
3753
7366
6078
2399
39239
39272
1540
35299
35316
Figure B-3: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1987
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1987
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.37
J
X
Fit
Res
194.451 213.164 213.125 +0.039
242.086 251.895 251.987 −0.092
291.459 296.672 296.696 −0.024
317.306 322.205 322.066 +0.139
333.143 338.295 338.320 −0.025
339.116 344.593 344.594 −0.001
353.564 360.061 360.106 −0.045
368.068 376.248 376.164 +0.084
394.324 406.457 406.513 −0.055
432.322 453.431 453.488 −0.057
469.850 503.668 503.630 +0.038
Standard Deviation 0.069
Central Date: 06−Dec−1987
Coefficients
+8.8421354e+01
+5.3405876e−01
+4.1559472e−04
+6.9931253e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-4: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1987
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1987
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.38
J
X
Fit
Res
175.512 196.878 196.870 +0.007
238.294 246.268 246.280 −0.012
273.214 276.671 276.696 −0.025
309.616 310.900 310.887 +0.013
322.958 324.082 324.095 −0.013
331.519 332.801 332.769 +0.032
357.983 360.676 360.597 +0.078
376.208 380.622 380.686 −0.064
405.930 415.104 415.140 −0.036
451.915 472.840 472.821 +0.019
Standard Deviation 0.039
Central Date: 03−Mar−1989
Coefficients
+8.6428635e+01
+5.4337081e−01
+3.6215343e−04
+7.2457290e−07
Cyl
2408
3753
7366
6078
2399
39239
39272
1540
35299
35316
Figure B-5: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1989
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1989
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.38
J
X
Fit
Res
194.666 213.164 213.132 +0.032
242.120 251.920 252.004 −0.084
291.388 296.678 296.684 −0.006
317.208 322.199 322.036 +0.162
333.128 338.323 338.377 −0.053
339.075 344.600 344.624 −0.024
353.535 360.092 360.148 −0.056
368.004 376.246 376.165 +0.081
394.275 406.478 406.529 −0.050
432.237 453.446 453.467 −0.020
469.809 503.722 503.702 +0.020
Standard Deviation 0.071
Central Date: 03−Mar−1989
Coefficients
+8.6158478e+01
+5.5333635e−01
+3.6262044e−04
+7.4779432e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-6: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1989
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1989
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.40
J
X
Fit
Res
176.021 196.882 196.882 +0.001
238.708 246.298 246.298 +0.000
273.448 276.670 276.670 +0.000
309.716 310.898 310.887 +0.011
323.026 324.075 324.126 −0.052
331.549 332.808 332.804 +0.005
357.853 360.680 360.597 +0.083
375.979 380.637 380.670 −0.033
405.586 415.121 415.144 −0.023
451.400 472.846 472.838 +0.008
Standard Deviation 0.036
Central Date: 22−May−1990
Coefficients
+8.7257233e+01
+5.2977109e−01
+4.0686706e−04
+6.9079957e−07
Cyl
2408
3753
7366
6078
2399
39239
39272
1540
35299
35316
Figure B-7: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1990
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1990
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.40
J
X
Fit
Res
195.148 213.164 213.139 +0.025
242.508 251.944 252.015 −0.071
291.557 296.683 296.670 +0.014
317.293 322.193 322.055 +0.138
333.123 338.351 338.380 −0.029
339.087 344.607 344.676 −0.068
353.466 360.121 360.187 −0.066
367.829 376.245 376.162 +0.083
393.970 406.499 406.511 −0.012
431.810 453.461 453.491 −0.030
469.272 503.774 503.757 +0.017
Standard Deviation 0.065
Central Date: 22−May−1990
Coefficients
+8.7093478e+01
+5.3877584e−01
+4.1008218e−04
+7.1147549e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-8: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1990
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1990
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.43
J
X
Fit
Res
178.107 196.895 196.886 +0.009
236.208 243.286 243.306 −0.020
274.001 276.668 276.677 −0.009
309.146 310.247 310.221 +0.025
309.848 310.892 310.917 −0.026
319.387 320.507 320.482 +0.025
322.948 324.056 324.103 −0.047
331.373 332.828 332.781 +0.046
357.424 360.693 360.633 +0.060
375.340 380.673 380.711 −0.038
404.606 415.162 415.208 −0.046
449.780 472.863 472.843 +0.020
Standard Deviation 0.036
Central Date: 20−May−1993
Coefficients
+8.2349129e+01
+5.5876927e−01
+3.3268398e−04
+7.8982815e−07
Cyl
2408
4274
7366
6071
6078
4296
2399
39239
39272
1540
35299
35316
Figure B-9: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1993
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1993
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.43
J
X
Fit
Res
196.879 213.164 213.143 +0.021
243.410 252.004 252.050 −0.046
291.839 296.698 296.729 −0.031
317.247 322.178 322.078 +0.100
332.923 338.420 338.425 −0.005
338.765 344.625 344.660 −0.035
353.047 360.195 360.239 −0.044
367.176 376.241 376.134 +0.107
393.105 406.549 406.602 −0.052
430.401 453.497 453.536 −0.039
467.337 503.904 503.878 +0.026
Standard Deviation 0.058
Central Date: 20−May−1993
Coefficients
+7.9667590e+01
+5.9271913e−01
+2.5743622e−04
+8.9142171e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-10: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1993
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1993
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.46
J
X
Fit
Res
176.582 196.903 196.901 +0.002
235.472 243.322 243.336 −0.014
273.485 276.667 276.636 +0.031
308.914 310.335 310.288 +0.047
309.560 310.887 310.926 −0.039
319.168 320.551 320.529 +0.022
322.733 324.043 324.145 −0.102
331.183 332.841 332.828 +0.013
357.225 360.701 360.627 +0.074
375.162 380.698 380.718 −0.020
404.411 415.191 415.209 −0.018
449.538 472.875 472.870 +0.005
Standard Deviation 0.045
Central Date: 09−Jul−1995
Coefficients
+8.6386741e+01
+5.3614788e−01
+3.7099179e−04
+7.7596891e−07
Cyl
2408
4274
7366
6071
6078
4296
2399
39239
39272
1540
35299
35316
Figure B-11: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1995
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1995
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.46
J
X
Fit
Res
195.638 213.164 213.145 +0.019
242.822 252.046 252.096 −0.050
291.508 296.708 296.703 +0.005
317.016 322.168 322.060 +0.108
332.818 338.469 338.504 −0.035
338.646 344.638 344.715 −0.078
352.947 360.247 360.303 −0.055
367.022 376.238 376.133 +0.105
392.898 406.586 406.552 +0.034
430.243 453.522 453.613 −0.090
467.106 503.996 503.960 +0.036
Standard Deviation 0.068
Central Date: 09−Jul−1995
Coefficients
+8.4790601e+01
+5.6004859e−01
+3.2417627e−04
+8.5202886e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-12: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1995
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1995
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.48
J
X
Fit
Res
175.670 196.912 196.932 −0.020
234.933 243.357 243.299 +0.058
273.158 276.666 276.638 +0.027
308.797 310.423 310.402 +0.021
309.343 310.882 310.941 −0.058
319.080 320.595 320.654 −0.059
322.514 324.029 324.130 −0.100
330.993 332.855 332.827 +0.027
357.071 360.710 360.622 +0.088
374.999 380.723 380.675 +0.048
404.350 415.221 415.242 −0.021
449.534 472.886 472.897 −0.010
Standard Deviation 0.055
Central Date: 19−Aug−1997
Coefficients
+8.9270938e+01
+5.1621597e−01
+4.2192033e−04
+7.2991402e−07
Cyl
2408
4274
7366
6071
6078
4296
2399
39239
39272
1540
35299
35316
Figure B-13: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1997
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1997
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.48
J
X
Fit
Res
194.768 213.165 213.156 +0.009
242.340 252.088 252.114 −0.026
291.174 296.718 296.698 +0.021
316.811 322.158 322.139 +0.019
332.575 338.518 338.523 −0.005
338.368 344.650 344.690 −0.040
352.735 360.299 360.331 −0.031
366.825 376.236 376.159 +0.076
392.771 406.622 406.618 +0.004
430.126 453.548 453.592 −0.044
467.206 504.087 504.069 +0.018
Standard Deviation 0.035
Central Date: 19−Aug−1997
Coefficients
+8.9424432e+01
+5.2291767e−01
+4.3141107e−04
+7.4684974e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-14: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1997
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1997
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.50
J
X
Fit
Res
176.046 196.917 196.942 −0.025
235.150 243.380 243.319 +0.060
273.268 276.665 276.606 +0.058
308.953 310.480 310.453 +0.027
309.446 310.879 310.940 −0.061
319.212 320.623 320.696 −0.073
322.638 324.021 324.170 −0.149
331.061 332.863 332.824 +0.039
357.095 360.715 360.628 +0.087
374.984 380.739 380.691 +0.048
404.209 415.240 415.228 +0.012
449.202 472.894 472.917 −0.024
Standard Deviation 0.069
Central Date: 01−Jan−1999
Coefficients
+8.7332862e+01
+5.3493344e−01
+3.5502030e−04
+8.1259534e−07
Cyl
2408
4274
7366
6071
6078
4296
2399
39239
39272
1540
35299
35316
Figure B-15: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1999
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 1999
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.50
J
X
Fit
Res
195.070 213.165 213.178 −0.013
242.425 252.116 252.079 +0.036
291.325 296.725 296.756 −0.032
316.854 322.151 322.103 +0.049
332.684 338.550 338.568 −0.018
338.458 344.658 344.722 −0.064
352.808 360.333 360.366 −0.033
366.839 376.234 376.159 +0.075
392.725 406.645 406.632 +0.013
429.892 453.564 453.576 −0.012
466.796 504.146 504.148 −0.001
Standard Deviation 0.040
Central Date: 01−Jan−1999
Coefficients
+8.6122322e+01
+5.5588082e−01
+3.1825660e−04
+8.7691585e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-16: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 1999
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 1999
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.53
J
X
Fit
Res
177.445 196.927 196.953 −0.025
235.855 243.422 243.348 +0.074
273.641 276.664 276.649 +0.015
309.146 310.584 310.549 +0.035
309.529 310.874 310.930 −0.056
319.273 320.675 320.711 −0.036
322.619 324.005 324.118 −0.113
331.115 332.879 332.882 −0.004
357.052 360.725 360.662 +0.063
374.894 380.769 380.698 +0.071
404.165 415.275 415.280 −0.006
449.241 472.907 472.925 −0.018
Standard Deviation 0.056
Central Date: 10−Jul−2001
Coefficients
+8.5270257e+01
+5.3669135e−01
+3.8939939e−04
+7.4961768e−07
Cyl
2408
4274
7366
6071
6078
4296
2399
39239
39272
1540
35299
35316
Figure B-17: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2001
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 2001
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.53
J
X
Fit
Res
196.087 213.165 213.162 +0.003
243.042 252.166 252.171 −0.005
291.425 296.736 296.728 +0.008
316.865 322.139 322.119 +0.020
332.687 338.607 338.642 −0.035
338.368 344.672 344.716 −0.044
352.721 360.395 360.404 −0.009
366.691 376.230 376.155 +0.076
392.591 406.688 406.658 +0.030
429.853 453.594 453.661 −0.067
466.874 504.255 504.232 +0.023
Standard Deviation 0.039
Central Date: 10−Jul−2001
Coefficients
+8.3826354e+01
+5.6090544e−01
+3.4098056e−04
+8.2748854e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-18: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2001
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 2001
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.55
J
X
Fit
Res
176.270 196.935 196.949 −0.014
235.240 243.454 243.422 +0.032
273.200 276.663 276.644 +0.019
308.960 310.663 310.604 +0.059
319.190 320.715 320.828 −0.113
331.000 332.890 332.925 −0.035
357.020 360.733 360.729 +0.004
374.890 380.792 380.779 +0.012
404.040 415.301 415.238 +0.063
449.030 472.918 472.946 −0.028
Standard Deviation 0.052
Central Date: 09−Jun−2003
Coefficients
+8.5757451e+01
+5.4788920e−01
+3.2190447e−04
+8.4235986e−07
Cyl
2408
4274
7366
6071
4296
39239
39272
1540
35299
35316
Figure B-19: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2003
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 2003
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.55
J
X
Fit
Res
195.250 213.165 213.178 −0.013
242.560 252.204 252.184 +0.019
291.180 296.745 296.698 +0.047
316.780 322.130 322.148 −0.019
332.630 338.651 338.656 −0.004
338.330 344.683 344.738 −0.054
352.770 360.442 360.499 −0.056
366.690 376.228 376.185 +0.043
392.570 406.720 406.684 +0.036
429.670 453.617 453.599 +0.018
466.650 504.338 504.355 −0.017
Standard Deviation 0.036
Central Date: 09−Jun−2003
Coefficients
+8.4635842e+01
+5.6759933e−01
+2.8757327e−04
+9.0757168e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-20: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2003
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 2003
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.57
J
X
Fit
Res
176.800 196.942 196.953 −0.011
235.510 243.483 243.439 +0.044
273.380 276.662 276.707 −0.045
309.020 310.735 310.641 +0.094
319.220 320.751 320.852 −0.101
330.960 332.901 332.891 +0.010
357.020 360.740 360.750 −0.010
374.920 380.812 380.826 −0.014
404.100 415.325 415.274 +0.051
449.190 472.927 472.945 −0.018
Standard Deviation 0.054
Central Date: 04−Apr−2005
Coefficients
+8.5353844e+01
+5.4353506e−01
+3.5642502e−04
+7.8915432e−07
Cyl
2408
4274
7366
6071
4296
39239
39272
1540
35299
35316
Figure B-21: Cubic fit of nitrogen primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2005
calibration period
X
Figure ??: Linear Primaries Nitrogen Cubic Fit J−X 2005
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.57
J
X
Fit
Res
195.610 213.165 213.165 +0.000
242.780 252.238 252.233 +0.005
291.280 296.753 296.754 −0.001
316.780 322.121 322.136 −0.015
332.650 338.691 338.673 +0.018
338.350 344.693 344.757 −0.064
352.740 360.485 360.462 +0.023
366.710 376.226 376.198 +0.028
392.600 406.750 406.682 +0.068
429.860 453.638 453.731 −0.093
466.840 504.412 504.381 +0.031
Standard Deviation 0.045
Central Date: 04−Apr−2005
Coefficients
+8.3251628e+01
+5.7459967e−01
+2.8198652e−04
+8.9861524e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-22: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2005
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 2005
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.61
J
X
Fit
Res
194.030 213.165 213.153 +0.012
241.820 252.238 252.260 −0.022
290.750 296.753 296.765 −0.012
316.390 322.121 322.110 +0.011
332.360 338.691 338.656 +0.035
338.090 344.693 344.740 −0.047
352.590 360.485 360.496 −0.011
366.550 376.226 376.164 +0.062
392.570 406.750 406.726 +0.024
429.820 453.638 453.727 −0.089
466.760 504.412 504.375 +0.037
Standard Deviation 0.043
Central Date: 16−Sep−2008
Coefficients
+8.5783963e+01
+5.7076226e−01
+2.5876972e−04
+9.4212719e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-23: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2008
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 2008
Fit Residual [ppm]
J
350
400
450
−0.4
500
−0.3
200
300
−0.2
250
250
−0.1
300
200
0
350
150
150
0.1
400
0.3
0.2
X
Residual
0.4
450
500
550
Third order fit to NDIR (J) vs.
Manometrix (X) runs calculated for
4cc Volume=3.7934 large Volume=5014.65
J
X
Fit
Res
194.370 213.165 213.150 +0.015
242.070 252.238 252.268 −0.030
290.870 296.753 296.757 −0.004
316.490 322.121 322.143 −0.022
332.390 338.691 338.657 +0.034
338.050 344.693 344.681 +0.012
352.560 360.485 360.485 +0.000
366.510 376.226 376.179 +0.047
392.500 406.750 406.782 −0.032
429.580 453.638 453.684 −0.046
466.470 504.412 504.386 +0.026
Standard Deviation 0.030
Central Date: 13−Mar−2012
Coefficients
+8.5425661e+01
+5.7083681e−01
+2.5978353e−04
+9.4732152e−07
Cyl
71251
34819
71286
71341
66638
66625
66696
71308
71370
71479
67615
Figure B-24: Cubic fit of air primary tanks manometric carbon dioxide mole fractions as a function of APC J value for the 2012
calibration period
X
Figure ??: Linear Primaries Air Cubic Fit J−X 2012
Fit Residual [ppm]
19 Appendix C. MATLAB and FORTRAN Code
=================================================================
Source Code 1 Matlab cdmncmmco2.m
=================================================================
function iquit=cdmncmmco2(icorcath,icormen);
% Calculates number of moles of CO2 in 4cc chamber
%
% Input:
% input/CMMco2.dta’
%
% Output:
% output/cmmco2.csv’;
%
MFILE=upper(mfilename);
if nargin<1,
error(’Need ICORCATH’);
end
if nargin<2,
error(’Need ICORMEN’);
end
iquit=1;
% Read co2 column data
%
fname=’input/CMMco2.dta’;
[T1,cyl,irun,gas,mencor,gasmm,i1,htvac,htsmp,temp,ofr,sflag,scom,lcom]=...
cdmnreadcmmco2(fname);
% Apply stepwise meniscor correction
%
if any(icormen==[1 2]),
mencor=cdmnmenisccor(T1,cyl,mencor,2,icormen);
end
% Uncertainty analysis - adjust the heights, temps
%
[htvac,htsmp,temp]=uncertadj(htvac,htsmp,temp);
% Correct heights
%
ilrg=0;
[htvac]=cdmnmanocor(htvac,ilrg,icorcath);
[htsmp]=cdmnmanocor(htsmp,ilrg,icorcath);
% Convert flag to float
%
flag=ones(size(T1));
I=strmatch(’00’,sflag);
flag(I)=0;
% Apply temperature correction at time T1
%
temp=cdmntempcor(temp,T1);
% Read Virial coefficients
%
Vircoef=virials(’co2’,temp);
% Mercury Density
%
Rhohgn=rhohg(temp);
% Look up small (4cc) chamber volume at each time T1
%
Smlvolco2=plnvols(T1,meshgrid(’4’,T1));
% Calculate CO2 pressure
%
presco2 =(htvac-htsmp+mencor).*Rhohgn*stdConst(’gravconst’)/10;
% Calculate moles of CO2, equation (1) of 2002 manometry report
%
step1=1+(4*presco2.*Vircoef)./(stdConst(’gasconst’).*(temp+stdConst(’tk0c’)));
step3=1000000;
molesCo2=step3*(-Smlvolco2./(2.0*Vircoef)).*(1.0-sqrt(step1));
C1
% Write data to file
%
fname=’output/cmmco2.csv’;
fid=fopen(fname,’w’);
if fid<1,
fprintf(2,’ %s: Couldn’’t open %s\n’,MFILE,fname);
return
end
fprintf(2,’ %s: Writing to %s\n’,MFILE,fname);
[yr,mn,dy]=datevec(T1);
sfmt=[’%4d-%2.2d-%2.2d, %6d, %4d, %4s, %7.3f, %7.3f, %5.3f, %5.2f,’...
’ %5.3f, %1d, %8.5f, %11.8f, %s\n’];
fprintf(fid,’%%\n’);
fprintf(fid,’%%\n’);
fprintf(fid,’%%
fprintf(fid,[’%% Date
’
CO2
fprintf(fid,’%%\n’);
Cyl. Run
number no
corr Temp
Mercury Column Data\n’);
gas ’...
OxyFr Fg
Vol Moles(Gas)\n’]);
fprintf(fid,[’%%
Date
number
no
gas
(mm)
’
(C)’...
’ OxyFr Flg
Vol
Moles(Gas)\n’]);
fprintf(fid,[’%%--------- ------ ---- ----- ------’ ------ --- ------- --------\n’]);
fprintf(fid,’%%\n’);
(mm)
------
(mm) ’...
----- -----’...
for ii=1:length(yr),
fprintf(fid,sfmt, ...
yr(ii),mn(ii),dy(ii),cyl(ii),irun(ii),char(gas(ii)),...
htvac(ii),htsmp(ii),mencor(ii),...
temp(ii),ofr(ii),flag(ii),...
Smlvolco2(ii),molesCo2(ii),char(scom(ii)));
end
fclose(fid);
iquit=0;
return
%%%%%%%%%%%%%%%%%%%%%%%%%%
function [htvac,htsmp,temp]=uncertadj(htvac,htsmp,temp);
% Uncertainty analysis - adjust the heights, temps
%
% directly imopacts mole fract
%htvac=htvac+0.1;
%temp=temp+0.01;
return
=================================================================
Source Code 2 Matlab cdmncmmtotalgas.m
=================================================================
function iquit=cdmncmmtotalgas(icor,icormen);
% Calculates total moles of gas in 5L chamber
%
% Input:
% input/CMMtotalgas.dta’
%
% Output:
% output/cmmtotalgas.csv’;
%
MFILE=upper(mfilename);
if nargin<1,
error(’Need ICOR’);
end
if nargin<2,
error(’Need ICORMEN’);
end
iquit=1;
C2
% Read totalgas column data
%
fname=’input/CMMtotalgas.dta’;
[T1,cyl,irun,gas,mencor1,mencor2,i1,htvac,htsmp,temp,ofr,sflag,scom,lcom]=...
cdmnreadcmmco2(fname);
% Apply stepwise meniscor correction
%
if any(icormen==[1 2]),
mencor2=cdmnmenisccor(T1,cyl,mencor2,1,icormen);
end
% Uncertainty analysis - adjust the heights, temps
%
[htvac,htsmp,temp]=uncertadj(htvac,htsmp,temp);
% Correct heights
%
ilrg=1;
[htvac]=cdmnmanocor(htvac,ilrg,icor);
[htsmp]=cdmnmanocor(htsmp,ilrg,icor);
% Convert flag to float
%
flag=ones(size(T1));
I=strmatch(’00’,sflag);
flag(I)=0;
% Apply temperature correction at times T1
%
temp=cdmntempcor(temp,T1);
% Read Virial coefficients
%
Vircoef=virials(’air’,temp);
I=strmatch(’sair’,lower(gas));
Vircoef(I)=virials(’sair’,temp(I),ofr(I));
I=strmatch(’n2’,lower(gas));
Vircoef(I)=virials(’n2’,temp(I));
% Look up large chamber volume at each time T1
%
Lrgvolgas=plnvols(T1,cellstr(meshgrid(’5000’,T1)));
% Density of mercury
%
Rhohgn=rhohg(temp);
% Calculate total moles of gas, equation (1) of 2002 manometry report
%
presn2 =(htvac-htsmp+mencor2).*Rhohgn*stdConst(’gravconst’)/10;
step2=1+(4*presn2.*Vircoef)./(stdConst(’gasconst’).*(temp+stdConst(’tk0c’)));
molesGas=(-Lrgvolgas./(2.0*Vircoef)).*(1.0-sqrt(step2));
% Write results
%
fname=’output/cmmtotalgas.csv’;
fid=fopen(fname,’w’);
if fid<1,
fprintf(2,’ %s: Couldn’’t open %s\n’,MFILE,fname);
return
end
fprintf(2,’ %s: Writing to %s\n’,MFILE,fname);
fprintf(fid,’%%\n’);
fprintf(fid,’%%\n’);
fprintf(fid,[’%%
Date
number
no
gas
(mm)
’ OxyFr Flg
Vol
Moles(Gas)\n’]);
fprintf(fid,[’%%--------- ------ ---- ----- ------’ ------ --- ------- --------\n’]);
fprintf(fid,’%%\n’);
(mm)
(mm)
------
-----
sfmt=[’%4d-%2.2d-%2.2d, %6d, %4d, %4s, %7.3f, %7.3f, %5.3f, %5.2f, ’...
’%5.3f, %1d, %8.5f, %11.8f, %s\n’];
C3
Temp’...
----- -----’...
[yr,mn,dy]=datevec(T1);
for ii=1:length(yr),
fprintf(fid,sfmt, ...
yr(ii),mn(ii),dy(ii),cyl(ii),irun(ii),char(gas(ii)),...
htvac(ii),htsmp(ii),mencor2(ii),...
temp(ii),ofr(ii),flag(ii),...
Lrgvolgas(ii),molesGas(ii),char(scom(ii)));
end
fclose(fid);
iquit=0;
return
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
function [htvac,htsmp,temp]=uncertadj(htvac,htsmp,temp);
% Uncertainty analysis - adjust the heights, temps
%
%htvac=htvac+0.1;
return
=================================================================
Source Code 3 Matlab cdmnmolefract.m
=================================================================
function iquit=cdmnmolefract
% Given number of moles of carbon dioxide and total gas,
% Calculates mole fraction of CO2 in total gas
%
% Input:
% output/cmmco2.csv’;
% output/cmmtotalgas.csv’;
%
% Output:
% output/cmmmolefract.csv
% output/cmmmolefract_id.csv
%
MFILE=upper(mfilename);
iquit=1;
% Read number of moles of CO2 in small 4cc chamber
% Calculated in cdmncmmco2.m
%
fname=’output/cmmco2.csv’;
[T1C,cylC,runC,gasC,htvacC,htsmpC,tempC,ofrC,flagC,volC,molesC,mencorC,...
scomC]=cdmnreadgas(fname);
% Read total number of moles of gas in large volume
% Calculated in cdmncmmtotalgas.m
%
fname=’output/cmmtotalgas.csv’;
[T1T,cylT,runT,gasT,htvacT,htsmpT,tempT,ofrT,flagT,volT,molesT,mencorT,...
scomT]=cdmnreadgas(fname);
% Check for non existant data
%
if isempty(T1T) | isempty(T1C),
return
end
% Build arrays to store output parameters for each input CO2 run
%
molefrac=NaN*T1C;
flag
=11*ones(size(T1C));
n2oconc =zeros(size(T1C));
molesTm =NaN*T1C;
C4
tempTm =molesTm;
volTm
=molesTm;
htvacTm =molesTm;
htsmpTm =molesTm;
mencorTm=molesTm;
% Read the N2O content for each cylinder
%
cyln2o=load(’input/cyln2o.txt’);
[yr,mn,dy]=datevec(T1C);
% Loop through each CO2 gas measurement, match with Total Gas measurement
%
for ico2=1:length(T1C),
% Match Unflagged cylinder ID & Run number
% Failing that, include flagged data
%
I=find(cylT==cylC(ico2) & runT==runC(ico2) & flagT==0);
if isempty(I),
% Include flagged data
I=find(cylT==cylC(ico2) & runT==runC(ico2));
end
if length(I)>0,
% Correct cylinder for N2O
%
IN=find(cylC(ico2)==cyln2o(:,1));
if isempty(IN),
n2oconc(ico2)=0;
else
n2oconc(ico2)=cyln2o(IN,2);
end
% Save average Total Gas numbers
%
molesTm(ico2) =mean(molesT(I));
tempTm(ico2) =mean(tempT(I));
volTm(ico2)
=mean(volT(I));
htvacTm(ico2) =mean(htvacT(I));
htsmpTm(ico2) =mean(htsmpT(I));
mencorTm(ico2)=mean(mencorT(I));
if length(I)>1,
fprintf(2,’ %s: Averaging %d Total Air Meas. for cyl %d run %d\n’,...
MFILE,length(I),cylC(ico2),runC(ico2));
end
molefrac(ico2)=(molesC(ico2)/molesTm(ico2))-n2oconc(ico2); %-n2oconc
% Combine flags
%
flag(ico2)=10*flagC(ico2)+max(flagT(I));
end
end
% Define output file format
%
sfmt=[’%4d-%2.2d-%2.2d,%7d,%4d, %4s, %6.4f, %6.3f, %5.2f, %5.2f,’...
’ %7.3f, %7.3f, %7.3f, %7.3f, %+5.3f, %+5.3f, %2.2d, %11.8f, %10.8f,’ ...
’ %4.2f,%9.4f, %s\n’];
% Open results output file
%
fname=’output/cmmmolefract.csv’;
fid=fopen(fname,’w’);
if fid<1,
fprintf(2,’ %s: Couldn’’t open %s\n’,MFILE,fname);
return
end
fprintf(2,’ %s: Writing to %s\n’,MFILE,fname);
C5
% Write the output file header
%
fprintf(fid,’%% Isotopic corrections have NOT been made to these data\n’);
fprintf(fid,’%%\n’);
fprintf(fid,[’%%
Date,
cyl, Run, Gas, Vol-C,
Vol-T,’...
’ Tem-C, Tem-T, HtVacC, HtVacT, HtSmpC, HtSmpT,’...
’mencorC,mencorT, Flag,
moles-C,
moles-T,
N2O,
mfrac, Com\n’]);
fprintf(fid,’%%\n’);
for ico2=1:length(T1C),
fprintf(fid,sfmt,yr(ico2),mn(ico2),dy(ico2),...
cylC(ico2),runC(ico2),char(gasC(ico2)),volC(ico2),...
volTm(ico2),tempC(ico2),tempTm(ico2),...
htvacC(ico2),htvacTm(ico2),htsmpC(ico2),htsmpTm(ico2), ...
mencorC(ico2),mencorTm(ico2),...
flag(ico2),molesC(ico2),molesTm(ico2),n2oconc(ico2),...
molefrac(ico2),char(scomC(ico2)));
end
fclose(fid);
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
% Re write data sorted by cylinder-ID
%
fname=’output/cmmmolefract_id.csv’;
fid2=fopen(fname,’w’);
if fid2<1,
fprintf(2,’ %s: Couldn’’t open %s\n’,MFILE,fname);
return
end
fprintf(2,’ %s: Writing to %s\n’,MFILE,fname);
% Write file header
%
fprintf(fid,’%% Isotopic corrections have NOT been made to these data\n’);
fprintf(fid2,’%%\n’);
fprintf(fid2,[’%%
Date,
cyl, M-Frac,
Dev,Flg, run, Vol-C,
Vol-T,’...
’ Tem-C, Tem-T, HtVacC, HtVacT, HtSmpC, HtSmpT,’...
’Flag, moles-C,
moles-T\n’]);
% Sort into cylinder ID order
%
[cylC,IS]=sort(cylC);
[yr,mn,dy,runC,gasC,volC,tempC...
,htvacC,htsmpC,flag,flagC,molesC,molefrac,mencorC,n2oconc ...
,molesTm,tempTm,volTm,htvacTm,htsmpTm,mencorTm...
]=keeprows(IS,yr,mn,dy,runC,gasC,volC,tempC,...
htvacC,htsmpC,flag,flagC,molesC,molefrac,mencorC,n2oconc ...
,molesTm,tempTm,volTm,htvacTm,htsmpTm,mencorTm...
);
sfmt2=[’%4d-%2.2d-%2.2d,%7d,%8.3f, %+7.3f, %2.2d,%4d, %4s, %6.4f, %6.3f,’...
’ %5.2f, %5.2f, %7.3f, %7.3f, %7.3f, %7.3f, %+5.3f, %+5.3f, %11.8f,’...
’ %10.8f, %4.2f\n’];
for ico2=1:length(T1C),
% Calculate mean value for each cylinder
%
J=find(cylC==cylC(ico2) & flag==0);
if isempty(J),
Cmn=NaN;
else
Cmn=mean(molefrac(J));
end
fprintf(fid2,sfmt2,yr(ico2),mn(ico2),dy(ico2),...
cylC(ico2),molefrac(ico2),molefrac(ico2)-Cmn,...
flag(ico2),runC(ico2),char(gasC(ico2)),volC(ico2),volTm(ico2),...
tempC(ico2),tempTm(ico2),...
htvacC(ico2),htvacTm(ico2),htsmpC(ico2),htsmpTm(ico2), ...
mencorC(ico2),mencorTm(ico2),...
molesC(ico2),molesTm(ico2),n2oconc(ico2));
C6
end
fclose(fid2);
iquit=0;
return
=================================================================
Source Code 4 Matlab virials.m
=================================================================
function virial=virials(Gastype,Tc,O2fr)
% Virial coefficient for CO2, O2, N2, Air
% Landolt-Bornstein
% Numerical Data and Functional Relationships in Science and Technology
% New Series/Editor in Chief: W. Martienssen
%
% equations from: "Virial Coefficients of Pure Gases and Mixtures",
% Subvolume A Virial Coefficients of Pure Gases
% J.H. Dymond, et al
%
Tk0=stdConst(’tk0c’);
TK=Tc+Tk0;
if strcmp(Gastype,’co2’),
virial=+5.7400*10-3.88290*10ˆ04./(TK)+4.2899*10ˆ05./(TK).ˆ2-1.4661*10ˆ9./(TK).ˆ3; % B/cm3
end
if strcmp(Gastype,’n2’ ),
virial=+4.0286*10-9.33780*10ˆ03./(TK)-1.4164*10ˆ06./(TK).ˆ2+6.1253*10ˆ7./(TK).ˆ3-2.7198*10ˆ9./(TK).ˆ4;
end
% B/cm3
if strcmp(Gastype,’o2’ ),
virial=+4.2859*10-1.76960*10ˆ04./(TK)+5.2007*10ˆ05./(TK).ˆ2-1.6393*10ˆ8./(TK).ˆ3+5.0855*10ˆ9./(TK).ˆ4;
end
% B/cm3
if strcmp(Gastype,’air’ ),
virial=polyval([-0.0008780872378
end
0.7192905979421
-144.4593279778207],TK);
if strcmp(Gastype,’sair’ ),
virialn=+4.0286*10-9.33780*10ˆ03./(TK)-1.4164*10ˆ06./(TK).ˆ2+6.1253*10ˆ7./(TK).ˆ3-2.7198*10ˆ9./(TK).ˆ4;
% B/cm3
virialo=+4.2859*10-1.76960*10ˆ04./(TK)+5.2007*10ˆ05./(TK).ˆ2-1.6393*10ˆ8./(TK).ˆ3+5.0855*10ˆ9./(TK).ˆ4;
% B/cm3
virial=O2fr.*virialo + (1-O2fr).*virialn;
end
%Last "if" above: virials for co2 free air from ’Sengers,et al March 1971
return
=================================================================
Source Code 5 Matlab rhohg.m
=================================================================
function rho=rhohg(temp)
% Density of Mercury
%
%Peter Guenther internet research on hg rho. Today’s: Sept. 12, 2008
%valid from -20 to 300 degrees C
%’Density of Mercury - measurements and reference values’
%by H. Bettin and H. Fehlauer
%Metrologia 41 pp s16-s23. 2004
rho0=13595.0828;
a0=1.815868e-4;
a1=5.4583e-9;
a2=3.4980e-11;
a3=1.5558e-14;
%density of hg at 0 degrees C
a4=(1+(a0*temp+a1*temp.ˆ2+a2*temp.ˆ3+a3*temp.ˆ4));
rho=rho0./a4;
rho=rho*1e-3;
return
C7
=================================================================
Source Code 6 Matlab stdConst.m
=================================================================
function const=stdConst(name)
% Standard constants
%
if strcmp(name,’tk0c’);
const=273.15;
end;
if strcmp(name,’bouywt’);
const=0.99985;
end;
if strcmp(name,’gravconst’); const=979.537;
end;
if strcmp(name,’gravconst45’); const=980.665;
end;
if strcmp(name,’gconst’);
const=62363.8;
end;
%Gas constant from "The 2002 CODDATA Recommended Values of the
%the Fundamental Physical Constants" Rev.Mod.Phys. 77,1,2005
%see also http://physics.nist.gov/constants
%if strcmp(name,’gasconst’); const=8.31436e+07; end; % Old
if strcmp(name,’gasconst’); const=8.314472e+07; end; % New
if strcmp(name,’pa2torr’);
const=7.500616e-4; end;
return
=================================================================
Source Code 7 Matlab cdmntempcor.m
=================================================================
function to=cdmntempcor(TempIn,TimeIn)
% Apply temperature correction to allow fo mercury thermometer time drift
%
% to=cdmntempcor(TempIn,TimeIn)
%
XL=[
1900
1961
2006
2106
];
01
05
05
01
01
31
12
01
-0.01
-0.01
-0.11
-0.11
Timei =datenum(XL(:,1),XL(:,2),XL(:,3));
dTempi=XL(:,4);
% Interpolate temperature correction between above limits
%
dt=interp1(Timei,dTempi,TimeIn);
% Add temperature correction
%
to=TempIn+dt;
return
=================================================================
Source Code 8 FORTRAN corr6.F
=================================================================
c===============================================================================
c
CORR5
c co2-in-air gas mixtures corrections for 2012 scale
subroutine corr6(dayn, fj, xin)
# include "cal.h"
C Prior to 1970, no correction to X scale
C
if(dayn.lt.CD70) then
return
endif
C From 1970 to 1983, linearly increase correction to 0.02ppm
C
if(dayn.lt.CD83) then
xin=xin + 0.02*(dayn - CD70)/(CD83 - CD70)
return
endif
C8
C From 1983 to 1985 linearly interpolate between the 0.02ppm corrected 1983
C values and the new 1985 values
C
if(dayn.le.CD85) then
x83 = ACUB83(fj)
x83 = x83*1.000503
! efs added 26Jan2000: as in VAX CAL99
x83 = x83+.02;
x85 = ACUB85(fj)
xin = (x85*(dayn-CD83) + x83*(CD85-dayn))/(CD85 - CD83)
return
endif
return
end
c===============================================================================
=================================================================
Source Code 9 FORTRAN n2cubics12.f
=================================================================
C
21-Dec-2015 16:05:13
C
C Section of the file with cubics since 1985 written automatically using matlab script
C
/home/matlab/CDRGMANO/cdmncalccubic.m
C
as a part of the manometry workup functions
C
C The new cubic coefficients are obtained from fits of the time-varying manometric
C tank values and J-values obtained on the APC
C Cubic coefficients are stored in $MANO/output/cubics_n2.csv
C Cubic coefficients prior to 1985 have been retained from previous routines.
C Cubic coefficients from 1985 on are from matlab workup that includes
C temperature and plenum drifts.
C
C X scale modifications prior to 1985 are added in new corr?.F routines
C after cubics have been applied
C
C White stripe drift is obtained from single linear fit to concentrations vs time
C
C White stripe concentrations are held constant past last measured value
C
C Cathatometer corrections are NOT applied
C
C
c===============================================================================
c
CUB60
c CUBIC FUNCTION FOR CO2-IN-N2
function CUB60(a60)
dj = 0.576 - 0.005011*a60
a74 = a60 + dj
CUB60 = CUB74(a74)
return
end
c===============================================================================
c===============================================================================
c
CUB74
C CUBIC FUNCTION FOR CO2-IN-N2
function CUB74(a74)
CUB74 = 77.455 + a74*(0.573302 +
:
a74*(3.5735E-04 + 6.7618E-07*a74))
return
end
c===============================================================================
c===============================================================================
c
CUB80
C CUBIC FUNCTION FOR CO2-IN-N2
function CUB80(a80)
CUB80 = 84.370 + a80*(0.542223 +
:
a80*(4.2284E-04 + 5.8862E-07*a80))
return
end
c===============================================================================
c===============================================================================
c
CUB80I
C9
C
CUBIC FUNCTION FOR CO2-IN-N2
function CUB80I(x)
aj = x
do i = 1, 100
xx = CUB80(aj)
if(ABS(xx-x) .lt. .001) go to 20
aj = aj - xx + x
enddo
write(*,’(A,E14.6)’)
:
’ Inverse of 1980 cubic did not converge, X = ’, x
20 CUB80I = aj
return
end
c===============================================================================
c===============================================================================
c
CUBQ80
C CUBIC FUNCTION FOR CO2-IN-N2
C THIS FIT INCLUDES QUARTERLY RUNS ON THE NEW N2 MANOS AROUND 1980
function CUBQ80(a80)
CUBQ80 = 84.776 + a80*(0.537732 +
:
a80*(4.3849E-04 + 5.7171E-07*a80))
return
end
c===============================================================================
c===============================================================================
c
CUB83
c CUBIC FUNCTION FOR CO2-IN-N2
function CUB83(a83)
CUB83 = 86.946 + a83*(0.537883 +
:
a83*(3.8471E-04 + 6.8562E-07*a83))
return
end
c===============================================================================
c===============================================================================
c
CUB83I
c CUBIC FUNCTION FOR CO2-IN-N2
function CUB83I(x)
aj = x
do i = 1, 100
xx = CUB83(aj)
if(ABS(xx-x) .lt. .001) go to 20
aj = aj - xx + x
enddo
write(*,’(A,E14.6)’)
:
’ Inverse of 1983 cubic did not converge, X = ’, x
20 CUB83I = aj
return
end
c===============================================================================
c
c===============================================================================
c Cubics since 1985 are from new manomtry including plenum and temperature drift
c===============================================================================
c
function CUB85(a85)
CUB85 = 87.12252 + a85*(5.371547e-01 +
+
a85*(3.835221e-04 + 6.920529e-07*a85))
RETURN
END
c=========================================================
function CUB87(a87)
CUB87 = 88.95144 + a87*(5.216326e-01 +
+
a87*(4.243131e-04 + 6.643967e-07*a87))
RETURN
END
c=========================================================
function CUB89(a89)
CUB89 = 86.42863 + a89*(5.433708e-01 +
+
a89*(3.621534e-04 + 7.245729e-07*a89))
C10
RETURN
END
c=========================================================
function CUB90(a90)
CUB90 = 87.25723 + a90*(5.297711e-01 +
+
a90*(4.068671e-04 + 6.907996e-07*a90))
RETURN
END
c=========================================================
function CUB93(a93)
CUB93 = 82.34913 + a93*(5.587693e-01 +
+
a93*(3.326840e-04 + 7.898281e-07*a93))
RETURN
END
c=========================================================
function CUB95(a95)
CUB95 = 86.38674 + a95*(5.361479e-01 +
+
a95*(3.709918e-04 + 7.759689e-07*a95))
RETURN
END
c=========================================================
function CUB97(a97)
CUB97 = 89.27094 + a97*(5.162160e-01 +
+
a97*(4.219203e-04 + 7.299140e-07*a97))
RETURN
END
c=========================================================
function CUB99(a99)
CUB99 = 87.33286 + a99*(5.349334e-01 +
+
a99*(3.550203e-04 + 8.125953e-07*a99))
RETURN
END
c=========================================================
function CUB01(a01)
CUB01 = 85.27026 + a01*(5.366913e-01 +
+
a01*(3.893994e-04 + 7.496177e-07*a01))
RETURN
END
c=========================================================
function CUB03(a03)
CUB03 = 85.75745 + a03*(5.478892e-01 +
+
a03*(3.219045e-04 + 8.423599e-07*a03))
RETURN
END
c=========================================================
function CUB05(a05)
CUB05 = 85.35384 + a05*(5.435351e-01 +
+
a05*(3.564250e-04 + 7.891543e-07*a05))
RETURN
END
c=========================================================
function CUB08(a08)
CUB08 = 85.35384 + a08*(5.435351e-01 +
+
a08*(3.564250e-04 + 7.891543e-07*a08))
RETURN
END
c=========================================================
=================================================================
Source Code 10 FORTRAN aircubics12.f
=================================================================
C
21-Dec-2015 16:02:47
C
C Section of the file with cubics since 1985 written automatically using matlab script
C
/home/matlab/CDRGMANO/cdmncalccubic.m
C
as a part of the manometry workup functions
C
C The new cubic coefficients are obtained from fits of the time-varying manometric
C11
C tank values and J-values obtained on the APC
C Cubic coefficients are stored in $MANO/output/cubics_air.csv
C Cubic coefficients prior to 1985 have been retained from previous routines.
C Cubic coefficients from 1985 on are from matlab workup that includes
C temperature and plenum drifts.
C
C X scale modifications prior to 1985 are added in new corr?.F routines
C after cubics have been applied
C
C White stripe drift is obtained from single linear fit to concentrations vs time
C
C White stripe concentrations are held constant past last measured value
C
C Cathatometer corrections are NOT applied
C
C
c===============================================================================
c
ACUB83
c CUBIC FUNCTIONS FOR CO2-IN-AIR
function ACUB83(c83)
ACUB83 = 88.579 + c83*(0.529183 +
:
c83*(4.4239E-04 + 6.5448E-07*c83))
return
end
c===============================================================================
c
c===============================================================================
c Cubics since 1985 are from new manomtry including plenum and temperature drift
c===============================================================================
c
function ACUB85(c85)
ACUB85 = 88.00948 + c85*(5.356075e-01 +
+
c85*(4.180136e-04 + 6.845174e-07*c85))
RETURN
END
c=========================================================
function ACUB87(c87)
ACUB87 = 88.42135 + c87*(5.340588e-01 +
+
c87*(4.155947e-04 + 6.993125e-07*c87))
RETURN
END
c=========================================================
function ACUB89(c89)
ACUB89 = 86.15848 + c89*(5.533364e-01 +
+
c89*(3.626204e-04 + 7.477943e-07*c89))
RETURN
END
c=========================================================
function ACUB90(c90)
ACUB90 = 87.09348 + c90*(5.387758e-01 +
+
c90*(4.100822e-04 + 7.114755e-07*c90))
RETURN
END
c=========================================================
function ACUB93(c93)
ACUB93 = 79.66759 + c93*(5.927191e-01 +
+
c93*(2.574362e-04 + 8.914217e-07*c93))
RETURN
END
c=========================================================
function ACUB95(c95)
ACUB95 = 84.79060 + c95*(5.600486e-01 +
+
c95*(3.241763e-04 + 8.520289e-07*c95))
RETURN
END
c=========================================================
function ACUB97(c97)
ACUB97 = 89.42443 + c97*(5.229177e-01 +
+
c97*(4.314111e-04 + 7.468497e-07*c97))
RETURN
END
c=========================================================
C12
function ACUB99(c99)
ACUB99 = 86.12232 + c99*(5.558808e-01 +
+
c99*(3.182566e-04 + 8.769159e-07*c99))
RETURN
END
c=========================================================
function ACUB01(c01)
ACUB01 = 83.82635 + c01*(5.609054e-01 +
+
c01*(3.409806e-04 + 8.274885e-07*c01))
RETURN
END
c=========================================================
function ACUB03(c03)
ACUB03 = 84.63584 + c03*(5.675993e-01 +
+
c03*(2.875733e-04 + 9.075717e-07*c03))
RETURN
END
c=========================================================
function ACUB05(c05)
ACUB05 = 83.25163 + c05*(5.745997e-01 +
+
c05*(2.819865e-04 + 8.986152e-07*c05))
RETURN
END
c=========================================================
function ACUB08(c08)
ACUB08 = 85.78396 + c08*(5.707623e-01 +
+
c08*(2.587697e-04 + 9.421272e-07*c08))
RETURN
END
c=========================================================
function ACUB12(c12)
ACUB12 = 85.42566 + c12*(5.708368e-01 +
+
c12*(2.597835e-04 + 9.473215e-07*c12))
RETURN
END
c=========================================================
C13