Lesson Sequence Planning Length of lesson sequence: Three weeks Essential Question: How can the collision theory may be used to explain the decomposition of hydrogen peroxide used to estimate the concentration of household bleach through a simple reaction and the action of a catalyst? (student goals: to understand the effects of changing the temperature or concentration of the reacting particles on the rate at which a reaction occurs?) [Clarification Statement: Emphasis is on student reasoning that focuses on the number and energy of collisions between molecules.] [Assessment Boundary: Assessment is limited to simple reactions in which there are only two reactants; evidence from temperature, concentration, and rate data; and qualitative relationships between rate and temperature.] Cross Cutting Concept Science & Engineering Practices- Skill What skills does the student need to complete Disciplinary Core Idea - Topic Chemical processes, their rates, and whether or not energy the SEP? • provide an explanation of • is stored or released can be understood in terms of the collisions of molecules and the Apply scientific principles and evidence to phenomena and solve design problems, taking into account possible unanticipated effects Different patterns may be observed at each of the scales at which a system is studied and can provide evidence for rearrangements of atoms into new molecules, with consequent changes in the sum of all bond energies in the set of molecules that are matched by changes in causality in explanations of phenomena. kinetic energy. Students are Engaged: What is going to be used to engage students? What is happening? Why do you think this is happening? Check for prior knowledge. (see 5E handout) https://www.youtube.com/watch?v=C5tOEBmBAHg Iodine Clock reaction https://www.youtube.com/watch?v=1TWAR1KtYJU I Didn't Know That - Blowing Up an Airplane Tire Students Explore(What are the TOOLS used by students to explore): Reading: Suggested Grouping Catalyst in Living Organisms Enzymes http://www.rsc.org/learn-chemistry/resource/res00000815/enzymes-and-jellies?cmpid=CMP00000909 http://www.absorblearning.com/chemistry/demo/units/LR1506.html http://www.hhmi.org/biointeractive/lactose-digestion-infants http://www.hhmi.org/biointeractive/natural-selection-lactose-tolerance Catalyst Speed up reactions and Inhibitors slow down a reaction http://www.chem4kids.com/files/react_catalyst.html http://sciencelearn.org.nz/Contexts/Nanoscience/Sci-Media/Video/Catalytic-converters-and-platinum-nanoparticles Effect of temperature changes in reaction rates http://www.middleschoolchemistry.com/multimedia/chapter6/lesson4 http://study.com/academy/lesson/rate-of-a-chemical-reaction-effect-of-temperature.html?seekTo=1:10 https://archive.org/details/DrMattJCarlsonScienceTheaterEp005Temperature_0 Concentration changes and reaction rates http://www.docbrown.info/page03/3_31rates3a.htm http://www.kentchemistry.com/links/Kinetics/FactorsAffecting.htm Hydrogen Peroxide and its use http://www.ch.ic.ac.uk/rzepa/mim/environmental/html/h2o2_text.htm http://www.h2o2.com/municipal-applications/drinking-water-treatment.aspx?pid=123 – Evidence to support claim How does it make sense? How does it connect? Patterns http://www.diyncrafts.com/10960/health/51-extraordinary-everyday-uses-for-hydrogen-peroxide Bleach https://www.rhfs.com/pulse/thermoplastics-solve-the-challenges-of-water-disinfection-using-sodium-hypochlorite/ http://www.oxy.com/OurBusinesses/Chemicals/ResponsibleCare/Documents/Sodium%20Hypochlorite.pdf Video: Hydrogen Peroxide Videos https://www.youtube.com/watch?v=NN2tHSkcObk https://www.youtube.com/watch?v=NI4uL4JN51c https://www.youtube.com/watch?v=uZCCwWx0Z0o Bleach Videos https://www.youtube.com/watch?v=seOe1ythYbQ Writing: Informational Essay answering the essential question with citations to supportive evidence. Hands-on: Three experiments to obtain data and understand reaction rates. Estimating the concentration of bleach by determining its conductivity, measuring oxygen gas pressure, measuring the oxidation reaction potential change and concentrations Titration and conductivity of Bleach http://www2.vernier.com/sample_labs/CHEM-I-19-redox_titrations_open.pdf Estimating the concentration of Bleach reacting with Hydrogen Peroxide http://www.rsc.org/learn-chemistry/resource/res00001729/estimating-the-concentration-of-bleach?cmpid=CMP00005243 Reaction Rates of Hydrogen Peroxide http://www.vernier.com/files/sample_labs/CHEM-I-22-reaction_rates_open.pdf Students Explain (What key concepts students should be able to explain?) guided Questions to explain real situations: The Theory of Kinetic Energy. The Collision Theory. What factors influence the frequency of collisions of reactant molecules? Why do these factors influence reaction rates? What is the rate of reaction? How does the collision theory describe rates and changes in rates of chemical reactions? What is the role a catalyst plays in increasing the reaction rate? How is that achieved? What is the role of activation energy in a chemical reaction? How can potential energy diagrams be used to determine if a chemical reaction is endothermic or exothermic? Students Elaborate (what activities can students do to expand, enrich, and connect/apply to real world situations) Students can learn about Lactose intolerance and enzyme mediated reactions. Students can learn about how catalytic converters work and why are do they have a high price. Students Generate and Evaluate Evidence (Students able to communicate what they have experienced, explored, and learned): Students construct an explanation that includes the idea that as the kinetic energy of colliding particles increases and the number of collisions increases, the reaction rate increases. Students identify and describe evidence to construct the explanation, including: i. Evidence (e.g., from a table of data) of a pattern that increases in concentration (e.g., a change in one concentration while the other concentration is held constant) increase the reaction rate, and vice versa; Student evaluates the evidence of a pattern that increases in temperature usually increase the reaction rate, and vice versa. Student integrates evidence, facts, and scientific principles to construct the explanation: a) Molecules that collide can break bonds and form new bonds, producing new molecules. b) The probability of bonds breaking in the collision depends on the kinetic energy of the collision being sufficient to break the bond, since bond breaking requires energy. c) Since temperature is a measure of average kinetic energy, a higher temperature means that molecular collisions will, on average, be more likely to break bonds and form new bonds. d) At a fixed concentration, molecules that are moving faster also collide more frequently, so molecules with higher kinetic energy are likely to collide more often. e) A high concentration means that there are more molecules in a given volume and thus more particle collisions per unit of time at the same temperature. 1. 2. 3. Completing a full lab report on the GC experiment and the performance on the laboratory procedure. Completing note assignments Writing an essay in response to the essential question; with citations. 4. Performance Expectations rubric Teacher Formative Assessment (what types of questions would you ask your students throughout the activity to determine if they learned the lesson) differentiation • "How are the particles behaving at high temperatures vs. low temperatures?" • answer: high temperature more movement faster rate. Low temperature slow movement longer rate. • "How quickly do reactant turn to products for high concentrations vs. low concentration?" • answer: High concentration faster rate products made quickly. Low concentration slower rate reactants take longer to turn to products. • "How does a large surface area vs. a low surface area affect the rate of the reaction" • answer: Larger surface area is reactants turn to product at a faster rate. Smaller surface area reactants turn to product at a slower rate. Through student teacher discussion it will be feasible to tell how in depth their knowledge of the factors (temperature, concentration, surface area and catalysts) is and it will allow the educator to further their knowledge through visual representation. The online simulations is a great tool to discuss the factors, which can increase a reaction rate, and to demonstrate particle behaviors as those factors are applied. http://www.freezeray.com/flashFiles/RatesOfReactionSurfaceArea.swf http://www.freezeray.com/flashFiles/RatesOfReactionConc.swf http://www.freezeray.com/flashFiles/RatesOfReactionTemp.swf Teacher Summative Assessment performance on NGSS Evidence Statements, ELA and Math Standards ELA Standards: California Common Core State Standards Connections: ELA/Literacy Cite specific textual evidence to support analysis of science and technical texts, attending to important distinctions the author makes and to any gaps or inconsistencies in the account. (HS-PS1-5) Conduct short as well as more sustained research projects to answer a question (including a self-generated question) or solve a problem; narrow or broaden the inquiry when appropriate; synthesize multiple sources on the subject, demonstrating understanding of the subject under investigation. (HS-PS1-3) Write informative/explanatory texts, including the narration of historical events, scientific procedures/ experiments, or technical processes. (HS-PS1-5) Draw evidence from informational texts to support analysis, reflection, and research. (HS-PS1-3) Math Standards: Reason quantitatively and use units to solve problems. (HS-PS1-5) Use units as a way to understand problems and to guide the solution of multi-step problems; choose and interpret units consistently in formulas; choose and interpret the scale and the origin in graphs and data displays. (HS-PS1-5) Choose a level of accuracy appropriate to limitations on measurement when reporting quantities. (HS-PS1-5)
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