CHEM 2061 SI Chapter 11 Vaporization and Vapor Pressure 1. Arrange the following molecules in order of increasing vapor pressure: H3COCH3 CH3CH2OH H2O 2. Arrange the following molecules in order of increasing vapor pressure: NF3 NH3 BCl3 3. Ammonia has a heat of vaporization of 23.4 kJ/mol and molar mass of 17.031 g/mol. What mass of ammonia can be vaporized with 1760 kJ of heat? 4. A 1.20 L sample of methanol is vaporized at its boiling point. How much heat is required to complete the process given a density of 0.792 g/cm3, heat of vaporization of 35.2 kJ/mol, and molar mass of 32.04 g/mol? CHEM 2061 SI Chapter 11 5. Ethanol has a heat of vaporization of 38.56 kJ/mol and a normal boiling point of 78.4°C. What is the vapor pressure of ethanol at 15.0°C? 6. Benzene has a heat of vaporization of 30.72 kJ/mol and a normal boiling point of 80.1°C. At what temperature does benzene boil if the external pressure is 445 torr? 7. A small amount of water (5.00 mL) condenses on a standard gold bar with a mass of 12.4 kg initially at 25.0°C. Assuming that all of the heat from the condensation is absorbed by the metal, what is the final temperature of the bar? Density of water = 1.00 g/mL, heat of vaporization of water at 25.0°C is 44.0 kJ/mol, molar mass of water is 18.02 g/mol, and specific heat of gold at 25.0°C is 0.129 J/(g∙°C).
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