Chapter 4 ATOMIC STRUCTURE ATOMS : “Smallest” building blocks of matter. made up of... protons (+) [p+] neutrons (0) [n] electrons (-) [e-] Symbol # p+ #e- Name 1 1 #n Atomic Mass # # 0 1 1 C 6 6 6 Hydrogen-1 1 Carbon-12 12 H 6 12 Gold-197 197 Au 79 79 118 79 197 Chlorine-35 35 Cl 17 17 18 17 35 Chlorine-36 36 17 17 19 17 36 Cl mass of PROTON = mass of NEUTRON = mass of ELECTRON = 1 amu 1 amu 0.00055 amu NOTE: 1 gram = 6.02(10)23 amu CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School Page 1 ISOTOPES Atoms of the same element with DIFFERENT # neutrons naturally occurring Atomic Mass Name 55 e- 55 e- 55 e- 55 p+ 77 n 55 p+ 78 n 55 p+ 79 n 132 133 134 cesium-132 Abundance cesium-133 cesium-134 20.00% 75.00% 5.00% Find: “average” atomic mass of cesium using above info: 0.2000 0.7500 0.0500 x x x 132.0 133.0 134.0 = = = CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School 26.40 99.75 6.70 132.85 amu Page 2 ws – Atomic Structure Directions: Fill in the following table for all NEUTRAL atoms Name 1 Symbol # p+ #e- #n Atomic Mass # # 13 14 59 2 Ni 3 47 4 Calcium-41 5 Iron-55 6 64 Zn 7 8 109 12 22 27 60 9 10 CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School 28 78 24 196 Page 3 ws – Isotopes and Average Atomic Mass Directions: Find the average atomic mass for each of the following elements based on their relative abundances. Report answers to the nearest 0.01 amu. 1. 80% 127I, 17% 126I, 3% 128I 2. 50 % 197Au, 50% 198Au 3. 15% 55Fe, 85% 56Fe 4. 99% 1H, 0.8% 2H, 0.2% 3H 5. 95% 14N, 3% 15N, 2% 16N 6. 98% 12C, 2% 14C CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School Page 4 Lab-Modeling Isotopes – Chapter 4 Name _____________________ Partner ____________________ Date ___________ Period __ Purpose: To model how to determine the average atomic mass of an element using relative abundances of isotopes. PART I Procedure: 1. Find the average mass of a pre-1982 penny using 10 pennies and fill in 1st table below using the balance. 2. Find the average mass of a post-1983 penny using 10 pennies and fill in 1st table below using the balance. 3. Find the average mass of each of the combinations of pennies listed in the 2nd table below using the balance. 4. Show a calculation to find the predicted average mass of each of the combinations of pennies listed in the 3rd table below. Data: # pre-1982 pennies # post-1983 pennies Average penny mass 10 0 Pre-1982 penny = (____________ g) 0 10 Post-1983 penny = ((____________ g)) # pre-1982 pennies 1 # post-1983 pennies 9 2 8 3 7 4 6 5 5 6 4 7 3 8 2 9 1 Total mass (g) CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School Average penny mass (g) Page 5 Calculations: PREDICT the average penny mass for each combination % pre-1982 pennies x mass 0.10 x (____________ g) % post-1983 pennies x mass + 0.90 x ((____________ g)) Average penny mass = ______________ g ______________ g ______________ g ______________ g ______________ g ______________ g ______________ g ______________ g ______________ g CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School Page 6 PART II: Identify which “Mystery Envelopes” containing 10 pennies each correspond to the percentages below and your data from the tables above: Mystery Envelopes Data Envelope Envelope Mass # alone (g) Total Mass (g) Penny Mass Alone (g) Average Mass per Penny (g) 1 2 3 4 5 6 7 8 9 MYSTERY ENVELOPE % pre-1982 pennies % post-1983 pennies 10% 90% 20% 80% 30% 70% 40% 60% 50% 50% 60% 40% 70% 30% 80% 20% 90% 10% CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School Average Penny Mass CODE Page 7 ACTIVITY - Model for Atomic Dimensions + - p mass = n mass = 1840 * e mass + nuclear mass = mass p + mass n = mass number of atom atomic radius = nuclear radius * 10,000. 1 lb = 454 g 1 inch = 2.54 cm 1 mile = 5,280 ft 1. Find the mass of the smaller spherical object which will represent one e -. _________ grams 2. Calculate the TOTAL mass [in grams] of a carbon-14 atom based on the mass of the “electron” above and formulas given above. [Hint: how many p+, n, and e- are there and what mass would each one have?] Number of Mass of each Total mass p+: ______ _________ ___ ___________ ___ n: ______ _________ ___ ___________ ___ e-: ______ _________ ___ ___________ ___ _________ grams 3. Convert the atomic mass above [mass of a carbon-14 atom] to pounds. This # represents how much an atom weighs in relation to the “e-” mass above. _________ lbs -------------------------------------------------------------------------------------------------------------------4. a. Find the radius [in cm.] of the larger spherical object which will represent the “nucleus” of the atom. _________ cm b. Use the nuclear radius above to find the atomic radius. _________ cm 5. Convert the value for the atomic radius to yards. This # represents how BIG an atom is in relation to the “atomic radius” above. CHEMISTRY – Chapter 4 – Scotch Plains-Fanwood High School _________ yards Page 8
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