Studying is a Gas! Unit 3 Study Guide ü Know the main points of the Kinetic Theory of Gases ü Know what causes pressure…elastic collisions between gas particles and the container (if in a sealed vessel)…more or less particles changes pressure: this can be helpful when answering questions about reactions going to completion (comparing moles/particles of gaseous reactants versus moles/particles of gaseous products) ü Know what can cause pressure to increase (more particles, decreased container volume, increased temperature/KE of particles) or decrease (less particles, increased container volume, decreased temperature/KE of particles) ü If gas particles get close enough together, intermolecular forces of attraction can cause them to stay together…aka, become a liquid (liquefy). This can be accomplished through increased pressure, decreased container volume and/or decreased temp, the same variables that make gases more dense ü If temperature is held constant, the average kinetic energy stays the same! ü Avogadro’s Law (1 mole of any gas at STP = 22.4 L) means different samples of gas at STP have the same P, V, T, and number of particles (moles), but NOT mass/density! ü Remember the difference between SPEED of gas particles and KE…Speed depends on size (mass – effusion): particles can have different speeds with the same KE, as KE depends on mass and speed (1/2mv2) and is measured as an average (temperature, on the Kelvin scale) ü 100oC to 300oC is NOT an increase in temperature of a factor of 3! (100K to 300K is!) ü A sample of gas doesn’t automatically weigh less than a liquid or solid…for example, when a substance changes phase, its MASS does NOT change! (25 g of ice melts to become 25 g of water which vaporizes to become 25 g of steam) ü Gases deviate from Ideal behavior at lower temperatures and higher pressures; IMF’s lower the actual pressure, and the volume of particles increases the actual pressure ü Understand how to interpret the Maxwell-Boltzmann distribution curve for gases at different temperatures ü Know what information is given to you in your test taking packet so you are not unnecessarily memorizing things: Ideal Gas Law (from which you can see Boyle’s, Charles’s, Gay-Lussac’s and the Combined Gas Laws!); mole fraction (X) equation and how it relates to pressure of gases in a nonreactive mixture as well as Dalton’s Law of Partial Pressure for nonreactive/inert gas mixtures; conversion from Celsius to Kelvin; equation for KE; R constants for kPa (8.314), atm (0.08206) and torr/mmHg (62.36); conversion between atm and torr/mmHg; STP conditions (273.15 K = 0°C); and 22.4 L/mol for an Ideal gas at STP And be able to do these calculations: Boyle’s Law Charles’s Law Avogadro’s Law Combined Gas Law PV=nRT Find Molar Mass and Density of gases as well as do Stoichiometry problems using PV=nRT Find mystery metal “M” like #5 on “R” lab
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