COMPARISON OF ATACAMA DESERT SOLAR SPECTRUM vs. ASTM G17303 REFERENCE SPECTRA FOR SOLAR ENERGY APPLICATIONS Summary The knowledge on the solar spectrum is essential for the design and study of numerous technologies based on use of the solar resource. In spite of the fact that the Atacama Desert is in the spotlight of solar industry, there is not information about the spectral irradiance present on it. This fact and the special atmospheric conditions of Atacama cause an increasing interest of solar industry to know the spectral differences with other places of the world. In this paper, the information derived from the first spectral measurement campaign in Chile, carried on 2015, is processed and compared with the standard ASTM G173-03 Reference Spectra with the aim of obtain useful information for solar energy applications. 1. Introduction The Atacama Desert is rising like one of the places with the greatest potential in the world for installing solar power plants, which has attracted the positive attention of solar energy industry from Europe. Solar spectral irradiance measurements are required in a lot of studies on solar energy technologies, e.g. water treatment, aging, corrosion, PV cell design, photochemical, etc. In particular, in 1993 Nann and Bakenfelder described 12 possible uses of spectral solar radiation for solar energy systems and building construction applications (Nann and Bakenfelder, 1993). The ASTM G173-03 Reference Spectra was created by the North American PV industry in conjunction with the American Society for Testing and Materials (ASTM) and the research and development laboratories of the US government. It is extensively used worldwide by solar research centres and solar industry, which attests to the recognition of its usefulness. Even though, it was calculated in relation to the atmospheric and geographic conditions of USA (National Renewable Energy Laboratory (NREL), 2015). The lack of information about the solar spectrum in the Atacama Desert has involved a first measurement campaign. It was developed between February 8th and March 9th of 2015 in Antofagasta Region, Chile. The spectral irradiance was measured using a spectroradiometer system based on a double monochromator Bentham DTMS300 (Cordero et al., 2016). This paper recollect the information derived from the spectral measurements. This information is used to estimate a mean tilted global and direct solar spectral irradiance by using a radiative transfer code. The results are compared with the Reference Spectra in order to obtain useful information for the solar energy industry. 2. Procedure and results The atmospheric radiative transfer code can compute clear sky spectral irradiances for specific atmospheric conditions that users can define by inputs. Aerosol Optical Depth, Precipitable Water, Ozone Column and Single Scattering Albedo are derived from the spectral measurements. This atmospheric information is averaged for the area of interest for the construction of solar power plants. The mean values are used for the calculations. Complementary information, as the air mass at noon (eq. 1) or the surface tilt, is derived from equations. In the case of missing information, the input is left equal to the ASTM spectral reference if the code cannot calculate it by default. (eq. 1) Where Mnoon is the air mass at noon, for the latitudes of the area of interest. is the local latitude, and is the declination. The Mnoon is averaged The results of the inter-comparison with the ASTM G173-03 Reference Spectra are shown below. Direct Normal Irradiance [W m-2] ASTM ATACAMA 0.55 1.79 UV-B 45.86 58.02 UV-A 521.37 559.32 VIS 391.05 379.41 NIR_1 32.48 32.84 NIR_2 7.79 7.71 MIR 999.1 1039.09 TOTAL Global Tilted Irradiance [W m-2] ASTM ATACAMA 0.3 0.74 UV-B 29.65 37.09 UV-A 458.35 492.26 VIS 369.87 362.73 NIR_1 32.04 32.16 NIR_2 7.85 7.66 MIR 898.06 932.64 TOTAL Fig. 1 Direct Normal Irradiance and Global Tilted Irradiance results are shown on the top and bottom row, respectively. First column corresponds to the solar spectra, the black line is the extraterrestrial spectrum, blue line is the spectrum for Atacama, and the red line is the ASTM reference spectrum. The spectral differences between the reference and the estimated Atacama spectrum are shown in the second column in [W m-2 nm-1]. In the third column the table with the integral values are presented. The considereted spectral rage are: UV-B [290, 315] nm, UV-A [315, 400] nm, VIS [400, 780] nm, NIR_ 1 [780, 1800] nm, NIR_ 2 [1800, 2500] nm, MIR [2500, 4000] nm. As seen in Fig.1, the shorter the wavelength is, the higher are the differences between the estimated Atacama spectral irradiance with the reference. This fact is mainly due to the low levels of AOD, 0.08 at 550nm, derived from the spectral measurements that was in agreement with the ground-based measurements. The highest differences are found in the UVB and UVA spectral ranges in comparison with the ASTM G173-03 Reference Spectra. Relevant differences are not found in the infrared spectral range. The total irradiance is a 4% higher than the reference. 3. Conclusions On one hand, the high irradiance present in the UVB and UVA spectral ranges implies that special care must to be taken with the design of multi-junction photocells and with the degradation and ageing of materials, such as the used in encapsulates or solar receivers. These conclusion have to take into account in the plant design and the economic feasibility study of the projects. On the other hand, this solar spectrum shape can be used to encourage the processes of water treatment and detoxification. 4. References Cordero, R.R., Damiani, A., Seckmeyer, G., Jorquera, J., Caballero, M., Rowe, P., Ferrer, J., Mubarak, R., Carrasco, J., Rondanelli, R., Matus, M., Laroze, D., 2016. The Solar Spectrum in the Atacama Desert. Scientific Reports 6, 22457. Nann, S., Bakenfelder, A., 1993. Narrow-band Spectral Radiation Data Acquisition, Analysis and Modeling. IEA-SHC P-17 C-1. National Renewable Energy Laboratory (NREL), 2015. Reference Solar Spectral Irradiance: Air Mass 1.5. 2015.
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