Gill Sans Bold Earth and Environmental Science Preliminary course Stage 6 Planet Earth and its environment A five thousand million year journey 2 0 0 I EES Prelim 43177 2 r be S o t c NT O ng DM E i t ra E N o rp A M o nc P0025967 Number: 43177 Title: Planet earth and its environment This publication is copyright New South Wales Department of Education and Training (DET), however it may contain material from other sources which is not owned by DET. We would like to acknowledge the following people and organisations whose material has been used: Photographs © R.A. Binns, CSIRO, taken from JAMSTEC submersible “Shinkai-6500” Part 3 p 17 Photograph courtesy of Paul Brooks Part 4 p 7 Photograph courtesy of Upgrade Business Systems Pty Ltd Part 4 p 11 Photograph courtesy of NASA Part 6 p 18 COMMONWEALTH OF AUSTRALIA Copyright Regulations 1969 WARNING This material has been reproduced and communicated to you on behalf of the New South Wales Department of Education and Training (Centre for Learning Innovation) pursuant to Part VB of the Copyright Act 1968 (the Act). The material in this communication may be subject to copyright under the Act. Any further reproduction or communication of this material by you may be the subject of copyright protection under the Act. All reasonable efforts have been made to obtain copyright permissions. All claims will be settled in good faith. Published by Centre for Learning Innovation (CLI) 51 Wentworth Rd Strathfield NSW 2135 _______________________________________________________________________________________________ _ Copyright of this material is reserved to the Crown in the right of the State of New South Wales. Reproduction or transmittal in whole, or in part, other than in accordance with provisions of the Copyright Act, is prohibited without the written authority of the Centre for Learning Innovation (CLI). © State of New South Wales, Department of Education and Training 2008. Contents Module overview ............................................................................................ ii Indicative time....................................................................................... ii Resources............................................................................................ iii Icons .....................................................................................................v Glossary............................................................................................... vi Part 1: The evolution of the solar system ............................1–16 Part 2: The evolution of the Earth........................................1–26 Part 3: The evolution of life on Earth ...................................1–30 Part 4: The evolution of the atmosphere .............................1–38 Part 5: Carbon in the atmosphere and hydrosphere ...........1–22 Part 6: Climatic variation .....................................................1–36 Student evaluation Introduction i Module overview In this course you will be investigating the Earth and its processes. There are four modules in the preliminary course. In this first module you will explore the changes that have occurred throughout time–the evolution of the universe, solar system and the Earth. In particular you will focus on the evolution of the atmosphere and its relationship to life on Earth. Before you begin this module it is assumed that you can discuss the currently accepted theory of the origin of the Universe. These ideas will be briefly revised as work through the module. The achievement of the outcomes, as listed below, will be assessed by: • you, when comparing your answers to those suggested • your teacher, using the exercises you are asked to complete and return. The best way to help your teacher help you is by: • attempting each of the questions and activities • returning your exercises regularly and on time. Remember your teacher is there to help you! Indicative time There are four modules in the preliminary course in Earth and Environmental Science. Each module should take you about 30 hours to complete. All modules in this course are composed of six parts. You need to spend about five hours on each part though the learning in some parts might take a little longer and in others could take a little less time. ii Planet Earth and its environment Resources Materials and equipment that you need to complete all activities in this module are listed below. Remember that some of the activities are best conducted at a practical session with your teacher. If you do not have access to some of the materials do not become concerned. Your teacher may suggest alternative activities or materials. For Part 1 you will need access to: No specialised equipment required. For Part 2 you will need access to: • small baby food jar • oil (such as cooking oil) • water • iron sample eg. a bolt or nails (to simulate core material) • a rock sample preferably a non–porous rock such as granite (to simulate crustal material) • graduated measuring flask or measuring cylinder, eg. baby bottle, measuring cup • a set of scales, eg. kitchen cooking scales For Part 3 you will need access to: Introduction • a gas tight container (in which to carry out the fermentation) with a tube passing to a smaller container • 25 g of glucose C6H12O6 or sucrose (table sugar) C12H22O11 • 1 g of table salt • 7 g dried yeast (found in the bread making or flour section of a supermarket–usually in 7g, 12g or 28 g packets) • 250 mL of water • a warm area to place the equipment (20–30°C is suitable) • limewater Ca(OH)2(aq) to fill the smaller container; made using the following two items • lime (a chemical obtainable from a hardware store, bricklayer or builder) • a sealable container eg. a glass jar with a lid iii For Part 4 you will need access to: • four glass jars (similar to vegemite or peanut butter jars) • steel wool • table salt • cooking oil • limewater prepared in Part 3 • glass jar • straw For Part 5 you will need access to: No specialised equipment For Part 6 you will need access to: iv • ruler • pen • five metres of adding machine tape (or a roll of toilet paper or even a roll of wide ribbon) • graph paper (supplied in the part) Planet Earth and its environment Icons The following icons are used within this module. The meaning of each icon is written beside it. The hand icon means there is an activity for you to do. It may be an experiment or you may make something. You need to use a computer for this activity. Discuss ideas with someone else. You could speak with family or friends or anyone else who is available. Perhaps you could telephone someone? There is a safety issue that you need to consider. There are suggested answers for the following questions at the end of the part. There is an exercise at the end of the part for you to complete. You need to go outside or away from your desk for this activity. Introduction v Glossary The following words, listed here with their meanings, are found in the learning material in this module. They appear bolded the first time they occur in the learning material. accrete to build upon through the compilation and compaction of material accretion product of accretion aerobic an environment that contains free oxygen albedo fraction of incident radiation scattered by a surface amino acids are referred to as the basic building blocks of life and link together by peptide bonds to produce proteins anaerobic an environment that contains little to no free oxygen Archaea the first cellular organisms on earth archaeobacteria very simple prokaryotic bacteria; are thought to have been the very earliest forms of life on Earth asteroid solid pieces of rock orbiting the Sun between Mars and Jupiter asthenosphere is situated in the upper mantle and is thought to contain between one and two percent molten rock; the material that the lithosphere moves over astrophysicist a scientist who studies objects within the universe, in particular the formation and destruction of stars atmosphere the gaseous environment surrounding the surface of the Earth (or any other body in the universe) banded iron formation particular formations whereby iron was deposited in layers after having being transported in the soluble (Fe2+) form (BIF) vi bar a unit used to measure pressure; one bar of pressure is equal to 105 Newton of force per square metre black smokers submarine volcanic vents that emit black sulfides into the ocean BP before present Planet Earth and its environment Introduction carbon carbon is present in all living organisms. Carbon can combine with itself and hydrogen to form very long chains of hydrocarbons which form our reserves of fossil fuels carbon dioxide (CO2) a gas that is emitted by volcanoes and is expelled by living organisms through the process of cellular respiration, and is used in the process of photosynthesis carbonate carbonates are a group of minerals that combine with the carbonate (CO3) radical carbon flux flow or movement of carbon in a carbon cycle cellular respiration the process whereby living cells break up carbon molecules (glucose) to extract energy. In this process carbon dioxide is also given off chemosynthesis is the process where organic molecules are manufactured from elements other than oxygen in an oxygen free environment chemosynthesise undergo the process of chemosynthesis chemosynthetic organisms have the ability to chemosynthesise and are classified as chemotrophs chemotrophs are organisms which can exist in the absence of sunlight, and are capable of manufacturing organic molecules from elements other than oxygen in their environment coccoliths micro-fossil useful in the dating of rocks combusts a chemical reaction in which a substance combines with oxygen producing heat, light and flame comets small bodies of watery ice containing dust and compounds of carbon, nitrogen, oxygen, hydrogen constellations groups of stars with allocated names. Names are often based on characters in Greek mythological stories condensation the act of reducing a gas or vapour to liquid form cosmic particles dust particles from space Cretaceous this period makes up the upper one third of the Mesozoic era, beginning approximately 141 million years ago and extended through until 65 million years ago crust the uppermost portion of the lithosphere; the two types are continental and oceanic vii viii cyanobacteria prokaryotic bacteria able to photosynthesise; sometimes incorrectly labeled as blue-green algae daughter product product of radioactive decay degassing the process of heating a solid body to release molecules of gas into its atmosphere diffraction when a beam of radiation is split up into its constituent rays by passing through such objects as lens electromagnetic spectrum the range of frequencies over which electromagnetic radiation are displayed. Included is the visible spectrum of light electrons negatively charged particles orbiting the nuclei of atoms energy levels regions of energy around the nucleus of an atom in which electrons orbit equilibrium a state of balance between opposing forces or effects evaporite a sediment resulting from the evaporation of saline water evolved to make changes to be able to adapt better to the environment flux flow or movement foraminifera micro-fossil useful in the dating of rocks fossils an organic trace buried by natural processes and subsequently preserved fossil fuels refer to hydrocarbons–coal, oil, oil shale and natural gas free (oxygen) existing in the atmosphere as a gas molecule (O2) and not combining with any other atom or molecules fumaroles a type of volcanic vent that emits gases containing mineralogy usually in the form of sulfides galaxy a cluster of stars within the Universe; one of the stars includes our Sun geo-chemical analysis the study of chemistry in rocks and fossils glaciation large ice sheet glacier ice masses that accumulate from compacted snow on a seasonal basis; when the snow has compacted sufficiently and it exerts enough pressure, the body of ice will begin to gradually move. Planet Earth and its environment Introduction gravity force of attraction between all masses; very noticeable for small objects near extremely large objects halons gases that contain either fluorine, chlorine, or bromine homogeneous uniform mixture hydrocarbons organic compounds which contain which contain only carbon and hydrogen, including coal, oil, and natural gas hydrosphere includes all bodies of water on the planet, oceans, rivers, streams, lakes, ground water ice sheets large deposits of accumulated ice inert not easily changed by chemical reaction inner core inner most layer of the Earth consisting of solid iron interglacial period a period of time in history between ice ages iron is a metal which rarely occurs in its pure form, due mainly to the fact it reacts readily with oxygen to form oxides isotopes different types of atoms for the same element; they only vary in the number of neutrons they have in their nuclei. life for the purposes of this module refers to cellular organisms whether they be single celled or multi-celled; they may or may not have a nucleus but do contain nucleic material light year the distance covered by light in one year. Light travels at 300 000 km/s lithosphere the outermost rock layer of the Earth which includes the uppermost mantle as well as the continental and oceanic crust LPTM Late Palaeocene Thermal Maximum – high temperature period about 55 million years ago Ma / mya million years ago mantle layer of Earth between the outer core and the lithosphere, containing about two-thirds of the Earth’s mass; consists of iron and magnesium bearing silicates. marine sediments sediments deposited in oceans mass spectrometer specialised equipment with the ability to measure the mass of particular atoms ix x meteorites are solid fragments of asteroids methane (CH4) a natural gas; the simplest of the hydrocarbons; one molecule contains one carbon atom combined with four hydrogen atoms mineralogy different types of minerals that go to make up rocks, sediments, shells molluscs members of the phylum Mollusca, including snails, pippies, squids and octopuses nebulae swirling gaseous cloud of cosmic dust that begins to form stars neutrons atomic particles with no charge found in the nuclei of atoms oil liquid hydrocarbon found in ‘oil traps’ in the Earth’s crust ostracod micro-fossil useful in the dating of rocks. Inhabited a fresh water environment outgassing see degassing outer core surrounds the inner core and is thought to be composed of liquid iron and nickel based minerals oxide a compound produced by another substance combining and reacting with oxygen oxidised to combine and produce a compound with oxygen oxygen the most abundant element present in the Earth’s crust. Reacts readily to produce oxides and makes up approximately 20% of the Earth’s atmosphere parent material the original unstable radioactive material before it decays into its more stable daughter product partially molten state in between liquid and solid peptide bonds these bonds link amino acids together to form proteins periodic table table of elements showing atomic structure photodissociation the decomposition of water vapour into hydrogen and oxygen gas by the ultraviolet radiation from the Sun photolysis see photodissociation Planet Earth and its environment Introduction photosynthesis the process whereby sunlight combines with carbon dioxide to produce glucose (energy rich) molecules and oxygen gas photosynthetic organisms that are capable of photosynthesising planetesimals planets in their infant stage of development undergoing accretion of material precipitation means to ‘fall out’ or ‘drop out’; may refer to rain, hail, sleet, or snow; in chemical terms it refers to solid being formed after a chemical reaction which will then sink if in a solution prokaryotic cell with no nucleus proteins are large molecules formed by the linking of amino acids. All proteins contain carbon, hydrogen, oxygen and nitrogen; used for the growth and repair of cells protons atomic particle with a positive charge occupying the nuclei of atoms pyruvate an important three carbon molecule formed from the division of glucose Quaternary most recent Period of time, extending from two million years ago to the present day radioactive decay the breakdown of elements into other elements by the emission of charged particles from the nuclei (radiation) reactant chemical that reacts reservoir see sinks respiration energy releasing process in cells sedimentary to be deposited as a sediment. the sediment will have been eroded and transported from another source shells common name given to energy level sinks storage of a particular substance, in particular carbon Solar System system of nine planets circling the Sun including the Earth soluble a particle (solute) that is dissolved in a solvent stromatolites layered structures formed by the action of bacteria and the entrapment of fine mud. Alternating layers of calcium salts and mud make up the stromatolite structure xi xii subduction zone a convergent lithospheric plate boundary where one plate, due to its greater density, will be subducted beneath an opposing plate; the subducting plate is remelted into the upper mantle sulfides are compounds of sulfur that contain sulfur atoms or sulfide ions the Dreaming Aboriginal belief system involving the telling of mythological stories which are often linked to the land; the Dreaming has spiritual significance Universe contains the total amount of matter, energy and space uraninite uranium dioxide (UO2) - a mineral visible spectrum a colourful band of waves emitted from the Sun; wavelengths range from 0.4-0.7mm volcanic vent openings from volcanoes through which, gases, dust and igneous material is ejected; can be above or below sea level volcanism includes any emissions onto the Earth’s surface (including under the oceans) or into the atmosphere of gas, or igneous material from a vent or fissure in the Earth’s crust weathered to break down either physically or chemically to produce a type of sediment Planet Earth and its environment Gill Sans Bold Earth and Environmental Science Preliminary Course Stage 6 Planet Earth and its environment Part 1: The evolution of the Solar System 2 0 0 In r2 e b S o t c NT O ng DM E i t ra E N o rp A M o c 0 1 2 3 4 5 Eon Era Period Quaternary Epoch Pleistocene Pliocene Holocene (last 10 000 years) Change of scale 10 Miocene 20 Cenozoic 30 Tertiary Oligocene 40 Millions of years before present (Ma BP) Eocene 50 60 Palaeocene Phanerozoic mass extinction 70 Change of scale Cretaceous Mesozoic 100 Jurassic 200 Triassic Permian Carboniferous 300 Palaeozoic 400 500 mass extinction Devonian Silurian Ordovician Cambrian Ediacaran 600 Change of scale Precambrian 1000 Proterozoic age of BIFs 2000 3000 4000 Archaean Hadean oldest stromatolites oldest evidence indicating life Gill Sans Bold Contents Introduction ............................................................................... 3 Placing the Earth in Perspective within the Universe ................ 4 Origin of the Universe ..........................................................................4 Galaxies................................................................................................6 Solar System ........................................................................................7 Suggested answers................................................................. 13 Exercises–Part 1 ..................................................................... 15 Part 1: The evolution of the Solar System 1 2 Planet Earth and its environment Gill Sans Bold Introduction What are the features of the Universe? How did it form? These are the questions you will be seeking answers to in this part. In this Part you will be given opportunities to: • explain the existence of matter in the universe using current scientific ideas, and describe the process of accretion of such matter to form stars and planets • identify a sequence of events described by scientists to outline the formation of the Solar System At the end of Part 1, you should: • gather, process and present information that outlines a sequence of events that led to the formation of the Solar System. Extract from Earth and environmental science Stage 6 Syllabus © Board of Studies NSW, amended November 2002. The original and most up–to–date version of this document can be found on the Board’s website at: http://www.boardofstudies.nsw.edu.au/syllabus_hsc/syllabus2000_liste.html#e . Part 1: The evolution of the Solar System 3 Placing the Earth in perspective The Universe includes all of space. It is composed of all known matter and energy, including billions of galaxies each of which contain up to 100 000 billion stars. To put this into perspective the Sun is considered to be a smaller than average star. Have you ever wondered where all this matter came from? How did all these stars, planets, moons, and other objects such as meteors and comets come to exist? These questions lead to other questions such as, how significant is our own planet? And, could life exist on other planets? Questions such as these have been teasing and challenging humans since our beginnings. Stonehenge, for example was built approximately 5000 years ago in Wiltshire England to trace the paths of the Sun and the Moon. The study of astronomy took a great leap forward during the age of learning in the Renaissance. Galileo Galilei (1564–1642) invented the refracting telescope which greatly enhanced the study of stars and other objects in the night sky. Origin of the Universe What are your thoughts on the origin of the Universe? How do you think it came to be? The current scientific thinking is that the Universe is thought to be expanding away from a central group of galaxies which began about 11 to 15 billion years ago. One theory suggests that this occurred after a huge explosion. This theory is known as the Big bang theory. 4 Planet Earth and its environment Gill Sans Bold Big bang theory The observations of modern day astronomers suggest that the Universe including space and matter is still expanding from an infinitely dense and energetic state that existed some 11 to 15 billion years ago. The implication of the Big bang theory is that before the Big bang there was no matter. All matter was created during the Big bang. Initially the heat energy of that concentration of matter was high. As time went on space continued to expand and the matter created in the Big bang became more dispersed, temperatures decreased and eventually condensation resulted in galaxies being formed. These galaxies included stars (such as our own Sun) which formed from smaller condensations and were sometimes accompanied by planets. As the Universe continues to expand it drags the galaxies with it. Therefore galaxies do not maintain a fixed position within the Universe. This theory presents a ‘closed model’, in that the same matter that is currently expanding will eventually collapse in on itself under its own gravity. The result would be another big collision and explosion, similar to the initial Big bang, and the cycle will begin once again. 1 2 3 4 5 The Big bang theory seeks to explain the formation of the Universe. An explosion releases all energy and matter which condenses to form galaxies. The process goes through a cycle of steps from 1 to 4 before beginning again. Flat Universe theory A new slant on the Big bang theory idea is an idea that the Universe may continue to expand forever and may not undergo gravitational collapse. Under this model the fate of the Universe is a black cold place with no illumination. This theory also states that the Universe began initially with a large explosion. However, it assumes that the material is less dense, and as such the material will not collapse in on itself, as in the model above. Instead, the material will keep on moving away from the point of explosion. This will effectively mean that the Universe will continue to expand and is therefore considered an ‘open model’. Part 1: The evolution of the Solar System 5 1 2 3 4 5 The flat Universe theory states that the Universe began with a huge explosion and the materials released will continue to expand. Comparing the theories 1 Which of the above theories seems to you to give the best explanation for the origin of the Universe? Has this information changed your original ideas? Why? Why not? ______________________________________________________ ______________________________________________________ ______________________________________________________ 2 Describe your preferred theory to another person. Tell them how this theory differs from one of the other theories outlined above. 3 In your opinion, what part of your preferred theory needs more explanation? Where do you think you would go to try and find more information about this theory? ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ Galaxies Galaxies are the largest structures within the Universe, and are classified according to shape. Galaxies are made up from stars, gas and dust. Our galaxy is known as the Milky Way. A galaxy is a concentration of matter in the emptiness of space. When you look up into the sky at night, all the stars that you see are not revolving around the Sun. Our Sun is only one of 100 billion stars that orbit about a common centre of gravity. This collection of stars make up our Milky Way galaxy. The Milky Way is one of an estimated 125 billion galaxies in the Universe. 6 Planet Earth and its environment Gill Sans Bold How long do you think it would take to travel from one end of our galaxy to the other? If you were in a special space ship that could travel at the speed of light (300 000 kilometres per second), it would take you 100 000 years to cross our galaxy. Keep in mind that our galaxy is only one of many billions of galaxies in the Universe! The Solar System Our Solar System comprising our star, the Sun, and its planets lies within the Milky Way galaxy and is composed of a number of objects. Before moving on, try and see how much you already know about the Solar System. Answer the following questions as best you can. 1 Apart from planets, what other objects are included in the Solar System? _____________________________________________________ _____________________________________________________ 2 How many planets make up our Solar System? _____________________________________________________ 3 What are the names of the planets in our Solar System? List them in order from the Sun to the outermost planet. _____________________________________________________ _____________________________________________________ _____________________________________________________ Check your answers. Satellites In your answer to question one above, you should have mentioned satellites. What do think of when someone mentions the term satellite? You probably picture a metal device with reflectors orbiting the Earth after having been launched from the back of the space shuttle. This is just one type of satellite, classified as an artificial satellite. The first artificial satellite was built and launched from Russia in 1957. It communicated information about the upper atmosphere back to Earth. Satellites refer to bodies that rotate in orbits around other bodies of greater mass, and are held in a gravitational field. Natural satellites Part 1: The evolution of the Solar System 7 include moons, such as our own, rotating around planets. Our Solar System contains many of these natural satellites. The origin of our Solar System The Solar System has fascinated humankind for centuries. Prior to the invention of the telescope Mercury, Venus, Mars, Jupiter and Saturn, together with the Sun and Moon, could be studied at length with the eye due to their brightness. Aristarchus of Samos (280–264 BC) stated that all the planets rotated around the Sun and that the Earth was one of the planets. Unfortunately, this idea went ignored and it took almost 2000 years before it was considered to be correct. During this 2000 year period the most accepted theory was that the Earth held the central position of the Universe. It was not until Nicholas Copernicus in 1543, published his book stating that the Sun was the centre of the Universe, did modern astronomy take off. It was only during the last two hundred years that the development of the telescope enabled the discovery of Uranus, Neptune, and Pluto. Sun The Solar System is made up of the Sun, nine planets, satellites, minor planets and comets. The Solar System also contains asteroids. These are relatively small compared to say our Moon, and are made up from solid fragments of matter that orbit the Sun largely between Mars and Jupiter. Meteorites, which are solid fragments of asteroids, and comets, made up of ice and dust, are also included in the contents of the Solar System. There are many theories proposed for the formation of the Solar System. Some of these are outlined below. 8 Planet Earth and its environment Gill Sans Bold Nebular hypothesis In 1755 the German philosopher Immanuel Kant proposed a model whereby rotating clouds of gas (nebula) condense into individual globular bodies which, as they do so, would increase their rotational speed. This phenomenon obeys the Law of conservation of angular momentum, and can be illustrated by an ice skater spinning on his or her own axis. If an ice skater begins spinning with their arms outstretched and then they bring their arms in close to their body, they will increase their rate of spin. Therefore, the centrifugal force that results from these globular bodies condensing, flings gases off into a succession of rings orbiting the Sun. These rings are then thought to eventually condense to form individual planets. The speed of an ice skater spinning changes with the position of the arms. Approximately 100 years later physicists James Maxwell and Sir James Jeans from Britain disagreed with this theory stating that there was not enough mass in the gaseous rings to produce a gravitational field strong enough to condense the gases into planets. More recent ideas The Chemical condensation sequence model really builds upon the ideas of the nebular model outlined above. This model goes some way in explaining and predicting the different compositions and densities of materials in the different planets. Part 1: The evolution of the Solar System 9 Chemical condensation sequence model endeavours to explain and predict the different compositions and densities of different planets. It builds on the nebular hypothesis. A spinning cloud of gas and dust surrounds a developing sun. Planets formed as this mass cooled. In this model a spinning hot disc of gas and dust surrounds the developing star. As this cooled, small particles begin to come together forming larger particles and eventually planetesimals (planets in their infant stage). Depending on how close these planetesimals are to the star, different materials will not be able to condense because of the heat, and will be blown away as a gas by solar radiation. Therefore, those closest to the Sun will condense materials such as metals and rocks which have high boiling points. This would explain Mercury’s high iron content, and the lighter rock forming minerals such as magnesium, silicon and oxygen, accumulating on planets which are at a greater distance from the Sun. Planets which were being formed on the outer edge of the Solar System furthest away from the Sun, would accumulate materials such as water, methane and ammonia as ice. Jupiter and Saturn are said to be large enough to have a gravitational attraction which could hold on to all of the materials present in their original nebula, including hydrogen and helium. The planetesimals, due to their gravitational attraction, accumulated material through a process known as accretion. As more and more material bombarded these planetesimals they grew in size, and eventually formed into planets. 10 Planet Earth and its environment Gill Sans Bold The accretionary process. This accretionary process is thought to have been a major factor in generating heat within the Earth’s interior. Heat is also generated through the decay of radioactive elements held within the Earth’s rocks. To see a link site that contains a set of archived stories about planetesimals and evidence for the formation of solar systems about stars viewed with space telescopes such as the Hubble space telescope see a site on the EES links page at http://www.lmpc.edu.au/science. The latest generation of space telescopes has enabled scientists to test theories of solar system formation through searching for examples of dust discs surrounding young stars. The success in finding the evidence to support what was once only theory has been nothing short of spectacular. Create a series of labelled diagrams summarising the sequence of events outlined above under the heading of More recent ideas. You should create at least four diagrams to do this activity correctly. The use of colour and a key is often helpful in diagrams such as these. You should also include a small description under each of the diagrams to help explain each diagram. Turn to the exercises at the end of this part and complete Exercise 1.1 and 1.2. What’s next? In this part you learned about how scientists now believe the Solar System evolved. In the next part you will focus on events closer to home: the evolution of the early Earth and its changing composition. Part 1: The evolution of the Solar System 11 12 Planet Earth and its environment Gill Sans Bold Suggested answers Solar System 1 The Solar System consists of: the Sun; nine planets; many satellites (bodies of rock revolving around planets); and a large number of minor planets, meteoroids and comets. 2 There are nine planets. 3 The name and order of the planets from the Sun are Mercury, Venus, Earth, Mars, Jupiter, Saturn, Uranus, Neptune and Pluto. Part 1: The evolution of the Solar System 13 14 Planet Earth and its environment Gill Sans Bold Exercises – Part 1 Exercise 1.1 and 1.2 Name: _________________________________ Exercise 1.1: How the Earth came to be In your own words, and with the aid of diagrams, explain how you understand the Solar System to have formed. In your explanation you will need to include the following terms: nebular, satellites, meteorites, asteroids, comets, telescope, accretion, planetesimals, star, Uranus, Neptune, Pluto, gravity, ice, radioactive. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Part 1: The evolution of the Solar System 15 Exercise 1.2: Evidence for how the Solar System formed Using the Internet or very recent publications gather then present some of the evidence discovered by space telescopes describing the formation of planets and solar systems. If you do not have access to the Internet or a library of recent astronomy publications your teacher may supply you with some reference materials . Make sure you reference any information you present. Use of the following key words in any Internet search will get you started: nebular, satellites, space telescope, accretion, planetesimals, star, solar system formation. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ 16 Planet Earth and its environment Gill Sans Bold Earth and Environmental Science Preliminary Course Stage 6 Planet Earth and its environment Part 2: The evolution of the Earth 0 20 I er b to T S c O EN g in D M t a r EN o p or AM c n 2 0 1 2 3 4 5 Eon Era Period Quaternary Epoch Pleistocene Pliocene Holocene (last 10 000 years) Change of scale 10 Miocene 20 Cenozoic 30 Tertiary Oligocene 40 Millions of years before present (Ma BP) Eocene 50 60 Palaeocene Phanerozoic mass extinction 70 Change of scale Cretaceous Mesozoic 100 Jurassic 200 Triassic Permian Carboniferous 300 Palaeozoic 400 500 mass extinction Devonian Silurian Ordovician Cambrian Ediacaran 600 Change of scale Precambrian 1000 Proterozoic age of BIFs 2000 3000 4000 Archaean Hadean oldest stromatolites oldest evidence indicating life Gill Sans Bold Contents Introduction ............................................................................... 3 Evolution of the Earth ................................................................ 4 The earliest stage.................................................................................4 Fpormation of a layered Earth................................................... 7 The role of gravity.................................................................................9 Theory to explain a layered Earth .....................................................10 The Earth’s layers ..............................................................................12 A traditional Aboriginal perspective ......................................... 18 The evolution of the atmosphere............................................. 21 The composition of the atmosphere ..................................................21 The early atmosphere ........................................................................21 Suggested answers................................................................. 23 Exercises–Part 2 ..................................................................... 25 Part 2: The evolution of the Earth 1 2 Planet Earth and its environment Gill Sans Bold Introduction At the end of Part 2, you will have been given opportunities to learn to: • compare cultural beliefs with the views of astronomers and other scientists that may arise in discussion of the origins of the Earth • explain the role of gravity in the formation of the Earth • describe the relationship between the density of Earth materials and the layered structure of the Earth • describe the composition of the early (pre–oxygen) atmosphere and compare it with the composition of the present atmosphere. At the end of Part 2, you will have been given opportunities to: • gather and process information that compares a cultural explanation with an astronomical or scientific model of the origin of the Earth • perform a first–hand investigation to measure the density of a selection of earth materials representative of core, mantle and crust • identify data sources, process and present information from secondary sources to compare Earth’s earliest atmosphere with the present atmosphere. Extract from Earth and environmental science Stage 6 Syllabus © Board of Studies NSW, amended November 2002. The original and most up–to–date version of this document can be found on the Board’s website at: http://www.boardofstudies.nsw.edu.au/syllabus_hsc/syllabus2000_liste.html#e . Part 2: The evolution of the Earth 3 Evolution of the Earth How old do you think the Earth is and what would you use to measure its age? If you take the age of the oldest known sedimentary rocks on the planet as being the age of the Earth, then the Earth would be approximately 3 800 million (3.8 billion) years old. However, if you accept the position of many of the world’s leading astrophysicists, that the Solar system, including the Earth and meteorites all formed at the same time, then the age of the Earth could then be estimated at approximately 4 700 million (4.7 billion) years old. The age of the Earth has been derived from the dating of known meteorites that have landed on the Earth. The earliest stage For the first billion years of its life the Earth existed as a relatively cool and homogenous mass of silicon compounds; and iron and magnesium oxides. These materials would have been distributed relatively evenly throughout the Earth’s interior at this very early stage. Temperature and pressure As materials began to react with each other producing new material, planetesimals (small planets), began to accrete (gather and build upon each other) and the temperature began to increase. This increase in temperature is due to the energy being carried and released upon the impact of accreting material, and also due to the increase in pressure as a result of the accretion itself. This event occurred approximately 4 700 million (4.7 billion) years ago. Refer to the diagram on the next page. 4 Planet Earth and its environment Gill Sans Bold The accretionary model. Materials react to form new products which accrete (build on each other). This results in an increase in temperature. It has been estimated that the average temperature reached as high as 1000°C as a result of accretion and compression of material during this early stage of the Earth’s development. (An increase in pressure causes an increase in temperature. Have you ever felt how hot your push bike pump is after you have pumped up one of your tyres on a pushbike?) Temperature and radioactive decay Radioactive elements such as uranium, thorium and potassium, only make up a small percentage of the Earth’s elements however, these play an important role as they contributed to the heating of the Earth’s interior. How do you think radioactive elements are able to generate heat? When radioactive elements are first formed they are said to be ‘unstable’. This is because as soon as they are formed they begin to change into a different element, which is more ‘stable’. Part of this transformation of an unstable radioactive element into a stable non–radioactive element involves the production and emission of radiation and heat. This process of change is called radioactive decay. The unstable radioactive element is also called the parent material, and the stable non–radioactive element produced from the decay of the parent material is known as the daughter product. Part 2: The evolution of the Earth 5 Parent material Daughter product uranium lead potassium argon thorium lead rubidium strontium Radioactive elements decay to form daughter products. Parent material and daughter products The table above shows some examples of radioactive elements and their daughter products. Remember, when each of the above parent materials decay to their stable daughter products they give off radiation and heat. It is this heat which contributed to the Earth’s initial heat source and is still contributing to heat the Earth’s core today. The heat generated through accretion and the heat generated through decay of radioactive elements was being produced at a faster rate than it could escape. Because rocks are poor conductors of heat, the Earth’s interior began to increase in temperature. 6 Planet Earth and its environment Gill Sans Bold Formation of a layered Earth Did you know that the Earth is made up of a series of layers? Try this self–correct exercise to see what you already know. Draw and label a diagram showing a cross–section of the Earth. Check your answer. Did the Earth always have this layered structure? If it did not, then how did it come to develop this structure? What is density? The ideas behind how the Earth formed in layers relies heavily on the concept of density. It is therefore important to understand thoroughly what density is. The density of a substance is the amount of matter that substance contains in a given volume. 1 tonne feathers 1 tonne steel One tonne of feathers has the same mass as one tonne of steel. Part 2: The evolution of the Earth 7 Every one knows that one tonne of feathers weighs the same as one tonne of steel. However, the steel would take up considerably less volume than the feathers would. This is because the atoms that go to make up the matter in steel are packed much closer together than the atoms that go to make up the feathers. Therefore, steel is said to be more dense than feathers. The diagram on the next page shows a range of substances. It compares the density of these different materials. Each of the boxes in the diagram has the same volume–one cubic metre. The mass of the matter in each of the boxes is measured in kilograms and is shown on the top of each box. 750 kg feathers wood re 1000 kg a s in g d e ns i ty inc 1.5 kg 45 kg air water 11 300 kg 1600 kg lead 7800 kg 2700 kg steel aluminium coal Different materials have different densities. 1 8 List the materials shown in the diagram in order from the least dense through to the most dense. a) ____________________ b)________________________ c) ____________________ d)________________________ e) ____________________ f) ________________________ g) ____________________ h)________________________ Planet Earth and its environment Gill Sans Bold 2 The average density of the Earth is 5500 kg per cubic metre. Which of the materials in your list above would best represent the average Earth material? _____________________________________________________ _____________________________________________________ Check your answers at the back of this part. The role of gravity What is gravity? Is gravity the same everywhere? Gravity is the force that one object applies on another object and is determined by the amount of mass or matter in that object. Isaac Newton proposed the Law of Gravitation, that states ‘every particle in the Universe attracts every other particle with a force that is directly proportional to the combined masses of the particles and inversely proportional to the distances between the particles’. In other words, the more massive the particles the greater is the gravitational force those particles can supply. For example, the Earth has more matter, and therefore has a greater mass than the Moon. As a result the Earth has a stronger gravitational force. In fact the Earth’s gravitational force is six times stronger than that of the Moon. This force attracts or ‘pulls’ objects towards the centre of the mass that created it. The Earth, therefore, attracts objects towards its centre. If the Earth’s gravitational attraction is stronger than the Moon’s, why doesn’t the Moon come crashing into the Earth? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer. We are also attracted towards the centre of the Earth but are prevented from accelerating towards it by a solid and rigid continental crust. However if we were to attempt to stand on something less rigid such as the ocean we would be drawn closer to the Earth’s centre. Part 2: The evolution of the Earth 9 Implications for a developing Earth One implication is that gravity formed the driving mechanism for the accretionary model of the Earth. Material is attracted and accreted from out of space due to the Earth’s gravitational force. As the Earth gained in mass so did the amount of gravitational attraction, which in turn led to more material being attracted and accreted. Another implication is that once the Earth heated up as a result of the impact and pressure from this accretionary process, (and from the decay of radioactive elements) material became partially molten. This allowed the denser materials to be drawn down more easily to the centre of the Earth by the Earth’s gravitational force. This attracting force allowed the very first layering of Earth materials. What possible conclusions can you make about the composition of the Earth’s interior, given that the average density of all the Earth’s material is 5.5 grams per cubic centimetre, and the average density for continental crustal material is approximately 2.5 grams per cubic centimetre? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answers. Theory to explain a layered Earth As you know, heat was generated from the impact of material accreting as well as from radioactive elements decaying down to their daughter products. The temperature eventually rose enough for iron to melt. The melted iron then began to accumulate and, due to its greater density, began to sink towards the centre of the Earth forcing other material not as dense to be positioned above it. This movement of iron in itself would generate heat due to the friction created during movement. Approximately one–third of the Earth’s material sank towards the centre of the Earth. Due to this material being heated it was not in a completely solid state. However, it was also not in a completely liquid state either, as we would perhaps imagine. This material is said to be in a partially molten state, which is somewhere in between liquid and solid. 10 Planet Earth and its environment Gill Sans Bold The lighter molten material rose to the surface and cooled in the process, forming an early type of crust. Between the iron core and this early crust remained a mantle. During this time gases were most probably released from the Earth’s interior which, in turn led to the formation of the atmosphere and oceans. The result is a layered planet. The diagram below illustrates the basic sequence of events leading to the Earth’s layered structure. Label the layers of the last diagram by referring to the previous information. As well, you may need to refer to the following information The Earth’s layers. Please note this diagram of the Earth’s layers does not include the atmosphere, and that the crust is included in the lithosphere layer. The early Earth – a homogenous mixture. Iron sank to the centre. The result is a zoned planet. Check your answers at the back of this part. Part 2: The evolution of the Earth 11 The Earth’s layers The inner core is thought to be solid and consisting almost entirely of iron. The outer core is thought to be liquid and is mostly composed of iron and nickel based minerals. The mantle is thought to be composed mainly from the oxides of silica and magnesium as well as some oxides of iron and aluminium. The mantle is separated into upper and lower regions based on the density differences between minerals. Since the lower mantle is deeper, minerals produced in this region have done so under greater pressure than the minerals produced in the upper mantle. As a result their crystal structure will change but not necessarily their chemical composition, producing a more dense structure. Carbon is a well–known example of a material changing its structure according to differing pressure at the time of its formation. If the pressure is high enough the carbon will take the form of diamond, if the pressure is lower it will take the form of graphite. The boundary between the upper and lower mantle is mainly based upon the different structures and density of material produced rather than differences in chemical composition. Asthenosphere The asthenosphere is situated in the upper mantle and is thought to contain between one and two percent molten rock. This small percentage of molten material reduces the friction between rocks and allows rocks above it (the lithosphere) to move over the top. (See the diagram below) The asthenosphere has been likened to conveyor belt–creating a mobile zone for material to move above it. oceanic crust 0 Depth (km) 50 70 oceanic crust continental crust lithosphere (rigid – includes crust) 100 150 asthenosphere (partially molten) 200 250 12 Planet Earth and its environment Gill Sans Bold Lithosphere The lithosphere is composed of the uppermost part of the mantle and the overlying crust, and comprises of relatively cool and rigid rock situated above the asthenosphere. The lithosphere is a mobile layer and can move across the top of the partially molten asthenosphere. The crust, which forms the upper most part of the lithosphere, is either continental or oceanic. The continental crust is less dense than the asthenosphere and therefore cannot be puled down into the lower mantle. Continental crustal material generally ranges from 20 to 70 kilometres in thickness. In most cases, however, the continental crust is approximately 35 km in thickness. This crustal material is largely composed of oxides of silica, aluminium, iron, magnesium, potassium and calcium. (See the diagram on previous page.) The minerals that make up the continental crust do not undergo transformation to new minerals that increase in density as they are placed under greater pressure. Oceanic crust does not vary in composition as much as continental crust. Oceanic crust is denser than continental crust and is composed of basaltic rock that is rich in iron, magnesium and silica. The minerals that make up the oceanic crust are converted to other more dense minerals when placed under great pressure. This increased density aids oceanic crust to be subducted or sink into the lithosphere. Oceanic crust is relatively thin ranging from approximately 6 to 10 km in most places. Its thickness is much more uniform than that of the continental crust. Lying on the oceanic crust are the oceans and seas that make up the majority of the hydrosphere. (The remainder of the hydrosphere is made up from rivers, creeks and all other bodies of water on the Earth’s crust.) The outermost layer of the Earth is known as the atmosphere, and is composed largely from nitrogen (78%) and oxygen (21%). The atmosphere is both the outermost and the least dense layer of the Earth. Write a statement linking the different density of Earth’s materials with their location, as described in the layered model of the Earth above. _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer at the back of this part. Complete Exercise 2.1 at the end of this section. Part 2: The evolution of the Earth 13 Density of liquids and layering Aim: To create a model that represents the layering of the Earth based on density differences between different materials. Materials: • small baby food jar • oil (such as cooking oil) • water Procedure: 1 Fill approximately one third of the jar with oil. 2 Fill another third of the jar with water. 3 Allow the jar to sit until all the fluids in the jar have settled. Results: 1 Make a labelled sketch of the jar immediately after you have poured in the water and before the liquids have settled. 2 Make a labelled sketch after the liquids have settled. Sketch before settling 14 Sketch after settling Planet Earth and its environment Gill Sans Bold Conclusion: How can these results be used to model the formation of the Earth’s interior? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Density of Earth materials Aim: The purpose of this activity is to find material which would simulate the composition of the Earth’s crust and mantle, and then perform an investigation to compare their densities. Background information: The density of a material is determined by the amount of material in a given volume. Density is often given in: • kilograms per cubic metre (kg/m3) • grams per cubic centimetre (g/cm3 or g/cc). Therefore, the density of an object can be calculated by dividing the mass of an object by its volume. density (D) = mass (m) ∏ volume (V) It is also important to note that, when dealing with volume there is a direct relationship between cubic centimetres (cm3) and millilitres (mL). 1 cm3 = 1 mL 1000 cm3 = 1 L The mass of an object can be found by using a mass balance or a set of scales marked in kilograms or grams. The volume of a small object can be found by lowering the object into a container of water with measuring graduations on its side. Remember the narrower the container (with finer graduations on its side) the more accurate the reading will be. That is why a measuring cylinder is normally used in laboratories. When the object is fully immersed, the rise in water level gives the volume of the solid. Part 2: The evolution of the Earth 15 Method: 1 You need to collect the following: • iron sample eg. a bolt or nails (to simulate core material) • a rock sample preferably a non–porous rock such as granite (to simulate crustal material) • graduated measuring flask or measuring cylinder eg. baby bottle, measuring cup • a set of scales eg. kitchen cooking scales. Equipment required to determine the density of a bolt. 2 With the above information and the equipment you have collected, write out a series of steps which will enable you to calculate the density of your simulated core material sample, and your simulated crustal material sample. Use diagrams where appropriate. Place these steps under the heading of Procedure. ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 16 Planet Earth and its environment Gill Sans Bold Results Record your findings under the heading of Results. Remember to use the correct units for density. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Conclusion Under the heading of Conclusion, make a statement about the density of each of your samples linking them with the formation of the Earth. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Part 2: The evolution of the Earth 17 A traditional Aboriginal perspective The Aboriginal belief system is known as the Dreaming. In the Dreaming, meaning is handed down from generation to generation by the telling of mythological stories, which are often linked to the land. Their religion is the land and therefore has spiritual significance. The following stages give a brief outline of the formation of the Earth as described in one version of the Dreaming. 18 1 At the beginning the enormous flat mass of Earth was surrounded by evil and murky water and everything was enveloped in darkness. Sand and soil covered the surface and gigantic rocks were hidden beneath the surface. These rocks were supported by many huge tree trunks. Without this support the Earth would have collapsed in on itself and be lost forever. 2 Suddenly the Sun was born and he forced his way up through the land mass and still water. This was thought to be the first man and his face was a blaze of fire which shed light on the very flat and dusty plains. The day ended when the Sun became weary and gradually sank underground leaving everything in darkness. 3 After resting the Sun returned to the east through an underground passage which he had made. The Sun felt he must once again see this strange place. The Sun’s habits have been regular since this first day. 4 The Sun did not know that mysterious things were hidden underground and only needed light to make them flourish. The soil awakened and every day was different. Springs began to trickle out of the dirt and these springs eventually formed creeks, lagoons and lakes. Grasses, plants and trees rose from the soil covered with fruit, berries and flowers. The Sun saw more and different plants every day, while the trees grew in height. 5 One day he saw an unbelievable change when the Earth beneath him appeared to erupt. Level ground was pushed toward him as hills and mountains appeared. Large trees and rocks rose from the soil and flowing water was spread in all directions. The Sun saw that living creatures were emerging from underground. They had been asleep, but now they had light, water and plant growth, and it was time to waken. Planet Earth and its environment Gill Sans Bold In the boxes below make diagrammatic representations of how you visualise the five stages described above. 1. 2. 3. 4. Part 2: The evolution of the Earth 19 5. Discuss with members of your community, family or class why it is important to include a cultural perspective when considering the origin of the Earth. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Complete Exercise 2.2 at the end of this section. 20 Planet Earth and its environment Gill Sans Bold The evolution of the atmosphere The composition of the atmosphere As stated earlier, the Earth’s current atmosphere is largely composed of two gases: • nitrogen (78%) • oxygen (21%). The remaining 1% is mostly made up of argon (0.93%), carbon dioxide (0.03%) and trace elements of other gases. This composition is the result of a continual evolutionary process. The early atmosphere Our planet was unable to keep an atmosphere of gases such as hydrogen, as the radiation given off by the Sun would have driven these very light gases away and they would have escaped into space. Our early atmosphere is thought to have developed from within the Earth’s interior in a process known as outgassing or degassing. During this process gases are released from the Earth’s interior due to internal heat gained from the process of accretion and the decay of radioactive elements. The earliest evidence we have for the composition of Earth’s primitive atmosphere originates from rock samples. The oldest rocks on the planet are approximately 3800 million years old and they provide with some clues about the atmosphere at the time of their formation. This leaves a question mark over what our very first atmosphere was like, 800 to 900 million years before these rocks were formed. We have no direct evidence. The current scientific view is that the early atmosphere probably consisted of methane (CH4), water vapour (H2O), nitrogen (N2), carbon dioxide (CO2), ammonia (NH3), and hydrogen sulfide (H2S). Methane is Part 2: The evolution of the Earth 21 thought to have been the dominant gas at this early stage. The role of methane as a greenhouse gas in the early atmosphere was probably critical to the development of the planet. In the early days of the planet the Sun was much less luminous than it is today so the transfer of energy to Earth’s surface as solar radiation would have been much lower. Without the greenhouse effect of the methane atmosphere the presence of liquid water essential to early life and sedimentary processes would not have been possible on Earth’s surface. The 3800 million year old rocks referred to above were found in Greenland and were originally deposited as sediments in water. It can be inferred that: • the Earth had at least cooled to a surface temperature below 100°C by this stage and that the greenhouse effect keeping the surface temperature in the range for liquid water was operating • these sediments must have been derived from the erosion of even older rocks. Comparison of atmospheric composition Compare the composition of the early atmosphere to the gases present in our current atmosphere. Describe the similarities and differences between the early atmosphere and the current one. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answers. Ideas and evidence for the composition of the Earth’s earliest atmosphere is an area of active research by scientists. Check out some of the links to studies of this fascinating area on the EES website links page at: http://www.lmpc.edu.au/science. Next… So far you have learned about the origin of the Universe and the Earth. In the next part you will find out how scientists believe living cells originated. 22 Planet Earth and its environment Gill Sans Bold Suggested answers Formation of a layered Earth lower mantle inner core outer core lithosphere asthenosphere upper mantle What is density? 1 a) air b) feathers c) wood d) water e) coal f) aluminium g) steel h) lead 2 A material more dense that aluminium and less dense that steel would represent the density of the average Earth material. The role of gravity Even though the Earth has a stronger gravitational attraction than the Moon, the Moon will not be drawn into a collision with the Earth. This is because it also wants to be hurled outwards away from the Earth due to its orbit around the Earth (centrifugal force). These two forces, gravity and the centrifugal force cancel each other out resulting in the Moon remaining in its present orbit. Part 2: The evolution of the Earth 23 Implications for a developing Earth The fact that the Earth’s average density is virtually double that of the rocks that go to make up continental crust, means that the Earth’s interior must be made up of material that is far greater in density than the material in the Earth’s crust. This therefore supports the layered model of the Earth. Theory to explain a layered Earth solid iron core (4980–6370 km) liquid outer core (2900–4980 km) lithosphere (0–70 km) asthenosphere (70–250 km) lower mantle (700–2900 km) upper mantle (250–700 km) The result is a zoned planet. Lithosphere The very dense elements such as iron, nickel, cobalt and the radioactive elements are concentrated mostly in the inner and outer core. Material gradually becomes less dense in the mantle until the least dense material is concentrated in the Earth’s crust which ‘floats’ on the more dense upper mantle. The atmosphere could even be considered the Earth’s outermost layer and is by far the least dense layer. Comparison of atmospheric composition It is difficult to say for certain what the early atmosphere was like, however, it did contain methane, nitrogen, carbon dioxide and water vapour like our current atmosphere. The present atmosphere contains much less methane, ammonia and hydrogen sulfide. 24 Planet Earth and its environment Gill Sans Bold Exercises – Part 2 Exercises 2.1 to 2.2 Name: _________________________________ Exercise 2.1: Formation of the Earth Read carefully the previous sections on The earliest stage, The formation of a layered planet and Theory to explain a layered Earth. You may even wish to do some of your own research for this exercise. Create a flow diagram summarising the events that led to the formation of the Earth. These diagrams should show a logical sequence from the Earth’s earliest beginnings through to its present day structure. Ensure these diagrams are well labelled and contain a summarising caption beneath each diagram. Your flow diagram should contain at least six individual diagrams and should not be too small (approximately 2 to 3 diagrams per page.) Part 2: The evolution of the Earth 25 Exercise 2.2: Research assignment Research, and in no more than two A4 pages, report on the beliefs of a particular cultural group on the Earth’s origin. You may wish to take another story from the Dreaming, or you might like to take a particular religious viewpoint or perhaps even draw from another culture altogether. In your two page report, include such things as relevant diagrams and quotes. Your research may include: accessing the internet, visiting your local library or even conducting an interview with an appropriate elder. Below are some questions you may use to help guide your research. 26 • Where did the culture or religion you have chosen originate from? • How is this perspective of the origin of the Earth communicated to others? (eg. story, song, dance, symbols, pictures, rituals, writing) • Has this means of communication changed over time? • At what age and to whom is this perspective communicated? • Does it have religious significance? • Does it have any significance for the way people live from day to day? • Is there any similarity with any other culture (or religion)? • Are there any other messages being communicated, apart from an explanation for the origin of the Earth? Planet Earth and its environment Gill Sans Bold Earth and Environmental Science Preliminary Course Stage 6 Planet Earth and its environment Part 3: The evolution of life on Earth 2 0 0 In r2 e b S o t c NT O ng DM E i t ra E N o rp A M o c 0 1 2 3 4 5 Eon Era Period Quaternary Epoch Pleistocene Pliocene Holocene (last 10 000 years) Change of scale 10 Miocene 20 Cenozoic 30 Tertiary Oligocene 40 Millions of years before present (Ma BP) Eocene 50 60 Palaeocene Phanerozoic mass extinction 70 Change of scale Cretaceous Mesozoic 100 Jurassic 200 Triassic Permian Carboniferous 300 Palaeozoic 400 500 mass extinction Devonian Silurian Ordovician Cambrian Ediacaran 600 Change of scale Precambrian 1000 Proterozoic age of BIFs 2000 3000 4000 Archaean Hadean oldest stromatolites oldest evidence indicating life Gill Sans Bold Contents Introduction ............................................................................... 3 Origin of the atmosphere and life .............................................. 5 The early atmosphere ..........................................................................5 Studying the Earth’s atmosphere ........................................................7 The origin of life....................................................................... 10 The basic building blocks of life.........................................................11 The Urey/Miller experiment................................................................12 Extraterrestrial material......................................................................14 The earliest forms of life .......................................................... 15 Archaea ..............................................................................................15 Obtaining energy ..................................................................... 18 Respiration..........................................................................................18 Chemosynthesis.................................................................................19 Fermentation ......................................................................................21 Appendix ................................................................................. 25 Suggested answers................................................................. 27 Exercises–Part 3 ..................................................................... 29 Part 3: The origin of life on Earth 1 2 Planet Earth and its Environment Gill Sans Bold Introduction In the last part, you examined theories and ideas about the formation of the Earth. Now, in this part, you will be studying how the Earth has evolved and produced an atmosphere that could ultimately support life. How do you define ‘life’? Life has not always existed as we know it today. In the previous section of work you learnt that the Earth’s earliest atmosphere consisted of gases other than oxygen. Therefore the question becomes obvious. How did oxygen come to occupy 21% of our present day atmosphere? From this stems the next obvious question. How did life originate and eventually evolve into dominantly oxygen dependent organisms? This part will help shed some light on these questions and hopefully give you some stimulus for your own thoughts and ideas. At the end of Part 3, you will have been given opportunities to learn to: • summarise the experiments of Urey and Miller and consider the importance of their findings to developing an understanding of how amino acids may have originated on Earth • outline the evidence that indicates how the first cellular organisms (Archaea) may have developed and describe their mode of respiration (anaerobic fermentation) • outline the role of chemosynthesis in providing a suitable energy source for early organisms • explain how the existence of Archaea near fumeroles and submarine vents can be used to support ideas on early development of life. Part 3: The origin of life on Earth 3 At the end of Part 3, you will have been given opportunities to: • gather and process information from secondary sources about the synthesis of amino acids caused by discharging an electric spark in mixtures of methane, ammonia, hydrogen and water • perform a first–hand investigation to demonstrate fermentation of sugar by yeast and use an appropriate chemical test to identify the produced gas as carbon dioxide • gather and process second–hand information about both ancient Archaea and present day Archaea that live near fumeroles and submarine vents known as black smokers Extract from Earth and environmental science Stage 6 Syllabus © Board of Studies NSW, amended November 2002. The original and most up–to–date version of this document can be found on the Board’s website at: http://www.boardofstudies.nsw.edu.au/syllabus_hsc/syllabus2000_liste.html#e . 4 Planet Earth and its Environment Gill Sans Bold Origin of the atmosphere and life Try and recall information from your last part to answer the following questions. 1 What gas currently makes up 78% of the Earth’s atmosphere? _____________________________________________________ 2 What gas currently makes up 21% of the Earth’s atmosphere? _____________________________________________________ 3 What currently makes up the remaining 1% of the Earth’s atmosphere? _____________________________________________________ _____________________________________________________ Check your answers. Our atmosphere has not always been made up of these gases. It has evolved into its present form. The early atmosphere As stated in the previous section, the earliest evidence for our atmosphere comes from our oldest rocks, those being deposited some 3800 million years ago in a watery environment. 1 What do you think is significant about the fact that the Earth had a watery environment so long ago? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Part 3: The origin of life on Earth 5 The current scientific view, is that that the early atmosphere consisted of methane (CH4), water vapour (H2O), nitrogen (N2), carbon dioxide (CO2) ammonia (NH3), and hydrogen sulfide (H2S). (Refer to the section of work Evolution of the Earth’s atmosphere in Part 2.) These gases are thought to have existed before the evidence shown in the 3800 million year old Greenland rocks. 2 Where do you think scientists obtained their evidence to support such a scientific view? ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ Check your answers. As mentioned above, sediments that were deposited in a watery environment formed the Earth’s oldest rocks from Greenland. Where do you think this water originally came from? Initially water did not exist! But, the elements which make up the compound, water did. These elements, as you know, are oxygen and hydrogen. However, the atoms of these elements were locked up in minerals such as potassium–aluminium mica–KAl3 Si3O10(OH)2. As the Earth heated up, a small proportion of the rocks in the asthenosphere become partially molten. (See section Theory to explain a layered Earth in the previous part.) Water was released as steam, together with lava from volcanoes. The steam quickly formed into clouds and eventually cooled enough to rain down on the Earth’s surface creating streams, rivers and oceans. The following activity should help you to develop an understanding of the current atmosphere of the Earth by comparing it with those from some of our neighbours. You may need to refer to the periodic table (in the Appendix) to help you locate and identify the particular elements mentioned. 6 Planet Earth and its Environment Gill Sans Bold Studying the Earth’s atmosphere Use the information in the following table to answer the questions that follow. Mars Earth Venus 210K 288K 737K Distance from the Sun 227 940 000 km 149 600 000 km 108 200 000 km Atmospheric pressure 0.007 bars 1.013 bars 92 bars Surface temperature Composition of atmosphere • CO2: 95.3% • N2: 78% • CO2: 96.5% • N2: 2.7% • O2:21% • N2: 3.5% • Ar: 1.6% • • • trace amounts of: O2, CO, H2O, NO, Ne, Kr, Xe water vapour: 1% • trace amounts of: Ar, CO2, Ne, He, CH4, Kr, H2 trace amounts of: SOs, Ar, H2O, CO, He, Ne Total atmosphere compared to Earth 0.0070 1.0 41.0 % of greenhouse gases 95.0% 1.5% 96.0% Greenhouse effectiveness 0.267 1.0 0.071 Greenhouse strength 0.077 0.65 121.0 • The unit used for temperature is the Kelvin (K). Kelvin equals ∞C – 273.15. • One of the units for measuring pressure is the bar. One bar of pressure is equal to 105 Newton of force per square metre. • ‘Total amount of atmosphere’ is a measure of how much gas is present in the atmosphere compared to the Earth’s atmosphere. • ‘% greenhouse gases’ represent the percentage of the total amount of gas in the atmosphere that is made up of greenhouse gases. • ‘Greenhouse effectiveness’ refers to how effective the gas is in trapping heat. (Water vapour is very good at trapping heat.) • ‘Greenhouse strength’ refers to the total amount of heat that a planet traps as a relative amount. Part 3: The origin of life on Earth 7 1 Relate the ‘distance from the Sun’ and ‘surface temperature’ with the orbits of each of the planets. _____________________________________________________ _____________________________________________________ 2 Give an explanation as to why Earth would have a low amount of CO2 in its atmosphere, compared to both Venus and Mars. Think about the main difference between Earth and the other two planets. ______________________________________________________ ______________________________________________________ ______________________________________________________ 3 Which planet has the greatest amount of atmosphere? ______________________________________________________ 4 Which planet has the greatest proportion of greenhouse gases? ______________________________________________________ 5 Which planet has the highest greenhouse effectiveness? ______________________________________________________ 6 Which planet has the greatest overall greenhouse strength? ______________________________________________________ 7 Why is Earth’s greenhouse strength smaller than that of Venus, even though Earth has a larger greenhouse effectiveness? ______________________________________________________ ______________________________________________________ ______________________________________________________ 8 Why is the greenhouse strength of Mars smaller than that of Earth, even though Mars has a greater percentage of greenhouse gases? ______________________________________________________ ______________________________________________________ ______________________________________________________ 8 Planet Earth and its Environment Gill Sans Bold 9 Why does Earth have a greater greenhouse effectiveness than Mars or Venus, even though it has a smaller percentage of greenhouse gases? _____________________________________________________ _____________________________________________________ 10. Why is Venus too hot and Mars too cold for generally available liquid water, where as Earth’s conditions are perfect? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Check your answers. Part 3: The origin of life on Earth 9 The origin of life Scientific investigation into the origin of life has come a long way when you consider that in the early 1800s it was widely believed that old socks and rotting meat would create lice and maggots from no previous organisms ! Charles Darwin (1809–1882) was a naturalist and is considered the founder of the modern day theory of evolution. His findings are still part of the basis of modern day research into evolution and the inheritance of characteristics from one generation to another. Darwin speculated that life may well have been generated from within a warm, phosphate–rich pond. It was not until approximately 100 years later that similar ideas were being proposed and given serious consideration. JBS Haldane, a Scottish biochemist working with AP Oparin from the former Soviet Union, proposed that the basic chemicals for life could be made from an atmosphere of ammonia, methane and water, if electricity was used to initiate chemical reactions. The electricity could be used to simulate lightning in early storms. In 1953, approximately twenty five years after Haldane and Oparin proposed their hypothetical model for the origin of life, a student at the University of Chicago named Stanley Miller, under the direction of chemist Harold Urey, began to experiment in earnest with Haldane’s and Oparin’s model. The details of this experiment are outlined in the following section. It is important to remember that when considering the origin of life, a scientific point of view is only one perspective. Other perspectives may include a religious point of view, or the idea that life has always existed in one form or another. What are your own thoughts on the origin of life? You may also wish to consider exactly what your definition of a living thing is! 10 Planet Earth and its Environment Gill Sans Bold The basic building blocks of life Amino acids are the basic building blocks of life. So what are amino acids? Amino acids are made up from a basic structure containing nitrogen, carbon, oxygen and hydrogen. They are commonly referred to as the basic building blocks of life. This is because they combine together in different arrangements to form different types of proteins. Proteins in turn are responsible for the formation, repair and function of all cells in living organisms. These amino acids are linked by peptide bonds to form many different types of proteins. peptide bond amino acids An amino acid chain. There are four amino acids shown in the key. These are linked by peptide bonds. These chains of amino acids form proteins. There are only 20 different amino acids used in the assembly of thousands of different proteins. The human body, for example contains about 150 000 different proteins. To help illustrate this, think about our 26–letter alphabet. How many different words can you produce from these 26 letters? The answer of course is millions. Answer the following questions and then check your answers at the end of this part. In the analogy of the alphabet given above: 1 What do the 26 letters represent? _____________________________________________________ 2 What do the words represent? _____________________________________________________ Check your answers. Part 3: The origin of life on Earth 11 The Urey/Miller experiment As stated above, theories on the composition of the Earth’s primitive atmosphere led scientists to believe that it was largely made up from methane (CH4), water vapour (H2O), ammonia (NH3), and hydrogen (H2). Based on this information, Stanley Miller and Harold Urey in 1953, set up equipment to try and emulate this ancient atmosphere, and then performed a series of experiments to try and replicate the environment of the time. The experimental set up is shown in the diagram below. water vapour sparks H2O water vapour CH4 H2 simulated reducing primitive atmosphere NH3 positive electrode negative electrode condenser boiling water with CH4, NH3 and H2 cold water sample for chemical analysis Urey/Miller experiment. They passed electricity through a mixture of the gases thought to exist in the early atmosphere to simulate lightning from ancient storms. The result produced a collection of organic compounds including amino acids, which have the potential when combined to form proteins. (See The basic building blocks of life above.) 12 Planet Earth and its Environment Gill Sans Bold These results of this experiment were obtained in an atmosphere without free oxygen (oxygen existing as a gas and not bonded to any other element). Oxygen has the effect of breaking down these newly formed chemicals. This experiment energised further research into the area of possible primitive atmospheres and how amino acids could be produced in such environments. At present the relevance of this experiment is under investigation, since it is debatable whether the atmospheric conditions used in this experiment actually reflect the composition of the atmosphere of the early Earth. To answer the following questions, please refer to the diagram opposite, then check your answers at the end of this part. 1 In the experiment outlined above, what part of the experimental set up represented: a) the ancient oceans _________________________________________________ b) lightning _________________________________________________ c) the ancient atmosphere? _________________________________________________ 2 What is the role of the ‘condenser’ in the experiment and what is it supposed to simulate in the real world? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ 3 Why are the results of the Urey/Miller experiment so important? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Check your answer. Part 3: The origin of life on Earth 13 Summarise Urey and Miller’s experiment by drawing a diagram showing a scenario of how amino acids may have been first produced on Earth. Refer to the conditions that Urey and Miller were trying simulate, and ensure your diagram is labelled carefully. Extraterrestrial material Asteroids are very small planets not exceeding 500 km in diameter that orbit the Sun between Mars and Jupiter. These asteroids, together with comets and meteorites (bodies of solid rock) and even traces of cosmic dust are now considered as an alternative mechanism for the formation of the earliest atmosphere. This idea gained momentum when in 1997 studies of the comet Hale–Bopp revealed to scientists that its contents contained: water, ammonia, formaldehyde and hydrogen cyanide which can react to form amino acids, the building blocks for proteins necessary for life. (See notes above.) It is known that very early in the Earth’s history the Earth was bombarded heavily with asteroids approximately between 4500 and 3800 million years ago. During this time, life developed and once the asteroid bombardment eased, life accelerated at a great rate. Meteorites and comets also deposit their mineralogy as they either land on the Earth or pass through our primitive atmosphere. 14 Planet Earth and its Environment Gill Sans Bold The earliest forms of life What do you think was the very first life form on Earth? Archaea The earliest cellular organisms are thought to have been very simple organisms belonging to the Archaea. The term archeo means beginning, so these bacteria are thought to be the very first bacteria. They are classified as prokaryotic, pro meaning before and karyo meaning nucleus. The cells of these bacteria therefore had no nucleus. These first prokaryotic cells are thought to have existed in the absence of oxygen. The evidence of the existence of living things or life can be found in the Earth’s oldest sedimentary rocks, dating back approximately 3800 million years. However, it is important to realise that this evidence has been obtained from stable carbon isotopes (different versions of the carbon atom) from ancient carbonaceous films in a metamorphic rock called a schist and not nicely preserved fossils. Therefore, scientists assuming these remains are truly organic will never really know what these early organisms looked like. The earliest cellular fossil The earliest cellular fossils now known, are the filamentous microfossils from the Apex Chert (chert is a silica rich sedimentary rock) near Marble Bar in northwestern Australia. These fossils were discovered by the palaeobiologist J W Schopf in 1992, and have been dated at approximately 3465 million years. These fossils have been described as being ‘cyanobacterium–like’, implying then that they may have been able to photosynthesise. If these organisms were a type of photosynthetic bacteria, then this would be the earliest evidence of oxygen being produced by organic means. Part 3: The origin of life on Earth 15 Present day Archaea Is there life existing on Earth today that does not need oxygen to survive? It might surprise you to hear that oxygen is in fact poisonous to a number of life–forms on Earth today. There are a number of areas where very simple microscopic bacteria flourish in the absence of oxygen. What do you think of when someone says to you, ‘you need to do more aerobic exercise’? You should be thinking in terms of exercise that involves a high heart rate and lots of breathing such as running, boxercise and swimming. The word aerobic means in the presence of free oxygen. We are therefore considered aerobic organisms, since we need oxygen to extract the energy necessary for living. What therefore, do you think the term anaerobic organisms means? An environment, which has very little to no oxygen, is said to be anaerobic. There are a number of anaerobic environments such as anaerobic marshes, sewage treatment plants, and in the digestive tract of animals including ourselves. In each of these environments Archaea happily exists. These bacteria are known as anaerobic organisms. Modern day Archaea have been found living in high–temperature, deep marine environments such as those associated with submarine (beneath the water) volcanic vents known as fumaroles. These present day Archaea, due to their very simple structure and their ability to live in very harsh, hot and oxygen depleted environments are thought to be related to the very first life forms on Earth because it is hypothesised by scientist that early Earth was like that. The best way of understanding these early life forms is to study present day archaeobacteria. The volcanic vents on the deep ocean floor, produce structures known as black smokers. The name black smoker is derived from the way dissolved sulfides are emitted into the ocean when hot lava from the submarine volcanic vents, come into contact with the surrounding sea–water and precipitate out from the liquid as a black fine sediment. The result is a black cloud of sulfides and sulfates, which become deposited around the vent and eventually build up to form a submarine ‘chimney stack’. All this volcanic activity produces water temperatures in excess of 300∞C. If you can obtain access to the video The Living Machine, from the Planet Earth series, it has some vary rare footage of these black smokers in action. This is an excellent film. 16 Planet Earth and its Environment Gill Sans Bold Archaea can be found underwater around volcanic vents known as ‘black smokers’. No light penetrates to the water depths at which these black smokers are found so photosynthesis cannot form the base of the food chain in these environments. The Archaea use a process called chemosynthesis to obtain their energy. The Archaea are using the energy contained in the chemical bonds in the sulfides and sulfates to form the base of the food chain of this strange undersea community. You can see the presence of organisms such as snails, tubeworms and clams on the photograph on the left. The photograph on the right shows the sulfides being emitted as ‘smoke’. Photo courtesy of Dr Ray Binns, CSIRO. On the EES website page there is an interview with a CSIRO scientist, Dr Joanna Par, who does much of her work on modern day black smokers on the ocean floor. The interview is a Real© audio interview and can be found at: http://www.lmpc.edu.au/science on the EES page. Part 3: The origin of life on Earth 17 Obtaining energy Almost 4000 million years ago, the Earth is thought to have been a very different planet to the Earth we know today. The Sun was shining with only 70% of its present strength and each day lasted less than 18 hours due to the more rapid rate of rotation of the Earth on its axis. There was no free oxygen in the atmosphere and no continents as such, only volcanic island chains, similar to the Tongan islands, Indonesian islands and Hawaii. Today most cells have evolved in an oxygen rich atmosphere, to enable them to ‘burn’ sugars to obtain energy. This process is known as respiration. Respiration What do you think of when you hear the term respiration? Do you think about lungs and the inhaling/exhaling of air? If you do you are really thinking about the process of breathing and not cellular respiration. Breathing involves oxygen being absorbed into the blood stream from the lungs and the carbon dioxide waste (CO2) being extracted out of the blood stream and being exhaled from the lungs. However, cellular respiration is far more complex than just breathing. Cellular respiration is the process whereby cells use oxygen in order to extract energy and create carbon dioxide as a waste product. This can occur in animal and plant cells. The equation below is a summary of the many chemical reactions that occur in the respiration process within a cell: glucose + oxygen Æ carbon dioxide + water + energy C6H12O6 + 6O2 Æ 6CO2 + 6H2O + energy. 18 Planet Earth and its Environment Gill Sans Bold As you can see from the equation above, one of the ‘ingredients’ or reactants needed for respiration is oxygen. In an environment depleted of oxygen organisms need to use other means to obtain their energy. A number of theories have been put forward to explain how early bacteria could have survived in such an anaerobic environment. These theories are based on processes that are occurring today. Chemosynthesis Chemotrophs are organisms which can exist in the absence of sunlight, and are capable of manufacturing organic molecules using energy obtained by mediating chemical reactions using certain chemicals (other than oxygen) from elements in their environment. This is known as chemosynthesis. Chemosynthesis is the process whereby carbohydrates are manufactured from carbon dioxide and water using chemical bond energy rather than sunlight as used in photosynthesis. Organisms from the Archaea which chemosynthesise, are found in locations associated with black smokers where the water is super heated to temperatures exceeding 300°C. These chemosynthetic Archaea form the basis of entire ecosystems on the sea floor. At these temperatures the sulfates, which previously existed in a stable condition under normal temperatures, are converted into hydrogen sulfide. Chemosynthetic bacteria use the hydrogen sulfide as an energy source instead of obtaining energy from sunlight as plants do in photosynthesis. Water remains as a liquid at these temperatures (around 300°C) due to the great pressure associated with depths of approximately 2500 m or more. Outline the difference between the terms chemosynthesis, chemosynthesise, and chemosynthetic. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer. Part 3: The origin of life on Earth 19 Anaerobic fermentation The early Earth’s surface was probably a very inhospitable place. Chemosynthetic bacteria at depths or in the ancient ocean or living in a very unusual environment such as a hot spring environment may well have been the first life forms on the planet. Bacteria living in anaerobic environments can generate their own energy through anaerobic fermentation. Initially, this involves the decomposition of a glucose sugar molecule into two pyruvate molecules (C3H4O3) in the cytoplasm of the cell. To see links to sites that describe these deep sea communities that have chemosynthetic Archaea as the basis of their food chain see sites on the EES links page at http://www.lmpc.edu.au/science. Glucose is a six carbon molecule and pyruvate is a three carbon molecule This process of breaking the glucose into two smaller molecules releases two units of energy. This also occurs in aerobic respiration. Refer to the diagram below. glucose (C6H12O6) 2 units of energy water pyruvate (C3H4O3) Aerobic with oxygen 36 units of energy Anaerobic without oxygen carbon dioxide water carbon dioxide 2 units of energy carbon dioxide carbon dioxide ethanol (CH3CH2OH) Different pathways for the production of energy in cells. 20 Planet Earth and its Environment Gill Sans Bold Anaerobic fermentation involves further decomposition of these pyruvate molecules which go on to form ethanol. The following equation summarises this process. C6H12O6 Æ 2 CH3CH2OH + 2 CO2 + 168 kJ of energy glucose Æ ethanol + carbon dioxide + energy. Now let’s see if you can put some of this theory into practice by conducting an experiment that produces ethanol, through anaerobic fermentation. Anaerobic fermentation of sugar by yeast Yeast is a familiar and economically important fungus. Yeast cells will survive in oxygen depleted environments by carrying out anaerobic fermentation. The waste products from this fermentation are carbon dioxide and ethyl alcohol (ethanol). For the next activity and for an activity in Part 4, you will need some limewater. Prepare the limewater at least one day before you do the experiment. Fermentation What you will need: • a gas tight container (in which to carry out the fermentation) with a tube passing to a smaller container • 25 g of glucose C6H12O6 or sucrose (table sugar) C12H22O11 • 1 g of table salt • 7 g dried yeast (found in the bread making or flour section of a supermarket–usually in 7g, 12g or 28 g packets) • 250 mL of water • a warm area to place the equipment (20–30°C is suitable) • limewater Ca(OH)2(aq) to half fill the smaller container; made using the following two items • lime (a chemical obtainable from hardware store, bricklayer or builder) • a sealable container eg. a glass jar with lid Part 3: The origin of life on Earth 21 Keep lime and limewater away from eyes and skin. Lime or limewater in eyes must be immediately washed away with lots of water. Limewater is made by adding a small amount of lime (a chemical obtainable from a hardware store, bricklayer or builder) to a sealable container half filled with water. (Do not use lime from a nursery or agricultural supplier—this is usually powdered limestone, calcium carbonate CaCO3). Shake the lime with the water then add more water until the container is almost full. Some of the solid lime, Ca(OH)2(s), will dissolve to form a water solution, Ca(OH)2(aq). Prepare the limewater at least one day before you start the activity because Ca(OH)2(s) is not very soluble in water and takes a while to form Ca(OH)2(aq). Seal the container and always keep it topped up with water to minimise contact with air. When the limewater is needed it is decanted as a colourless, transparent solution and the container resealed. Limewater turns cloudy when exposed to CO2 because Ca(OH)2(aq) + CO2(g) Æ CaCO3(s) + H2O(l). The small particles of calcium carbonate (CaCO3) formed reflect light like clouds do. Limewater turns cloudy when exposed to CO2. This a product of the fermentation reaction along with the ethanol alcohol. When you have prepared your limewater go on with the activity on the next page. You may have to wait a day or so to make sure your limewater is prepared. Keep your remaining limewater well sealed in an air tight container for an activity in Part 4 of this module. 22 Planet Earth and its Environment Gill Sans Bold bend straw to fit in small plastic container seal straw push straw through the lid ensure straw is immersed in water cut hole for straw in plastic bottle stir in a circular motion fill 1§3 full with water dissolve sugar place powdered yeast into sugar solution Laboratory equipment Home equipment Method 1 Place the fermentation mixture of sugar, water, salt and yeast into the larger container and swirl to mix. 2 Half fill the smaller container with limewater. 3 Put the two containers in a warm area and leave for a day or so until obvious bubbling is occurring in the larger container. 4 Place the end of the gas transferring equipment so that any gas produced in the large container enters the limewater about 1 cm below the limewater surface. 5 Record the appearance of the fermentation mixture and limewater in the results section below. Results _________________________________________________________ _________________________________________________________ Part 3: The origin of life on Earth 23 Conclusion: 1 What colour did the limewater change to over a day or so of bubbling happening? ______________________________________________________ 2 What type of gas does this change in the limewater indicate is being produced during the fermentation? ______________________________________________________ Now turn to the exercise at the back of this part. Complete the research according to the suggested guidelines then send your report to your teacher. 24 Planet Earth and its Environment Part 3: The origin of life on Earth 21 Ra Radium Fr Francium 24 25 Uranium Protactinium Thorium U Actinium 92 91 Pa 90 Th 89 Ac Neptunium Np 93 Promethium Neodymium Praseodymium Cerium 61 Plutonium Pu 94 Samarium Sm 62 Hassium Bohrium Pm Hs Iridium Osmium 5 6 65 96 Americium Curium Cm 95 7 8 9 Californium Berkelium Einsteinium 99 Fermium Fm 100 Erbium Holmium Es 68 69 70 Mendelevium Nobelium No 102 101 Md Ytterbium Yb Thulium Tm Ununhexium Ununquadium Er Uuh 116 Polonium Bismuth 115 84 Po 54 Lawrencium Lr 103 Lutetium Lu 71 118 Ununoctium Uuo Radon 117 Rn 86 Xenon Xe Astatine At 85 Iodine Tellurium Bi I Krypton Bromine Te 36 Kr Argon Ar 18 Neon 35 53 83 Antimony 10 Ne Br Chlorine 52 Selenium Uuq 114 Lead Pb 82 Tin Sb 51 Sn Arsenic 50 67 98 Dysprosium 34 Se 33 As Sulfur Cl 17 S Fluorine 16 F Oxygen O Phosphorus P 15 Nitrogen N Germanium Ge Ho Cf 97 66 Dy 113 Thallium Bk Terbium Tb Ununbium Uub 112 Tl 81 In 49 Gallium Ga 80 Hg Mercury 64 Gd Silicon Aluminium Indium Gold Uuu Si Al 32 14 31 Carbon 13 C Boron B Cadmium Cd 111 Unununium Gadolinium Am 79 Au Ununnilium Uun 110 Platinum Pt Europium Eu 63 Meitnerium Mt 109 Ir 78 Silver Palladium Rhodium Ag Pd 48 Zinc 47 Copper Rh Nickel 30 Zn 29 Cu 46 77 Bh 28 Ni 45 Cobalt 76 108 60 27 Co Os Ruthenium Ru 107 Rhenium Nd Lanthanum 59 Pr 58 Ce Seaborgium 57 Dubnium Sg 106 Db Tungsten 105 Rutherfordium Rf 75 Re 74 Tc Iron 44 43 Technetium W 26 Fe Name Symbol Hydrogen Atomic number 1 H Manganese Mn Molybdenum Mo Tantalum Ta 73 Niobium Nb 42 Chromium Cr La ACTINIDES 89-103 104 Hafnium 88 87 LANTHANIDES Barium Caesium 72 57-71 Hf Zirconium Yttrium 56 Strontium Rubidium Zr Y Ba Sr Rb 41 Vanadium Titanium 40 V Ti 39 Scandium 23 22 55 38 37 Sc Cs Calcium Potassium Magnesium Sodium 20 Mg Na Ca 12 11 K Beryllium Lithium 19 4 Be 3 Helium Hydrogen Li 2 He 1 H Gill Sans Bold Appendix The periodic table. 25 26 Planet Earth and its Environment Gill Sans Bold Suggested answers Origin of the atmosphere and life 1 Nitrogen 2 Oxygen 3 The remaining 1% is mostly made up of argon (0.93%), carbon dioxide (0.03%) and trace elements of other gases. The early atmosphere 1 The Earth would need to have cooled down sufficiently for water vapour to condense into water and flow on the Earth’s surface. Also water is an absolute necessity for life, therefore having water at this early stage does not rule out the possibility that life existed. 2 Some of the evidence would have been gained from the study of meteorites that are older than our oldest rocks, and some evidence is also gained from the study of the contents of comets. Also studying the gases being emitted from present day volcanoes can help scientists make assumptions about the early atmosphere. Studying the Earth’s atmosphere 1 The greater the distance the orbit is away from the Sun, the lower is the surface temperature for the inner rocky planets. 2 Because plants take in carbon dioxide and produce oxygen in the process of photosynthesis. Carbon dioxide is also dissolved in our oceans, reducing the amount available in the atmosphere. 3 Venus 4 Venus 5 Earth 6 Venus 7 Venus has a far larger amount of greenhouse gas in its atmosphere than does Earth, enabling greater amounts of heat to be trapped underneath it. Part 3: The origin of life on Earth 27 8 Because Mars does not have as much atmosphere as Earth. Earth also has a large amount of water vapour to trap in the heat. 9 Because it has a large amount of water. 10 Venus is closer to the Sun, so any water would have evaporated off and out of the atmosphere. Mars is too cold, and any water would be in the form of ice since Mars is further away from the Sun Earth is just the right amount of distance from the Sun so the temperature enables the water to exist as a liquid and is not evaporated off or frozen as ice. Basic building blocks of life 1 The 26 letters represent amino acids. 2 The words represent the types of proteins produced. Urey/Miller 1 a) The ancient oceans are represented by the flask with water in it. b) Lightning is represented by the electrical spark at the electrodes. c) The ancient atmosphere is represented by the gases present at the time the electrical spark is generated. 2 The condenser cools the gases down and converts the ‘atmosphere’ into liquid. This simulates clouds forming and rain in the real world. 3 The results from this experiment are important because, even though it has become controversial in recent times, it gives scientists a starting point to hypothesise about how life came to be and then to begin experiments. Chemosynthesis Chemosynthesis is the process where organisms produce organic material through the generation of energy derived from chemical reactions without the use of sunlight. Chemosynthesise is to have undergone the process of chemosynthesis described above. Chemosynthetic organisms have the ability to chemosynthesise, they are chemotrophs. 28 Planet Earth and its Environment Gill Sans Bold Exercise – Part 3 Name: _________________________________ Exercise: The generation of first life From the information given in this part of work, and any other research you may wish to conduct on this matter, write a two–page response to the following statement: Fumeroles associated with black smokers are responsible for generating the Earth’s first ecosystem based on chemosynthesis via Archaea. Resources Apart from these notes you may wish to search: • the Internet • National Geographic magazines– past issues, in particular October 1999, and January 2000 • your local library • your school library, including the audio–visual section. Points to include Your response should include the following information. • Definitions of fumeroles, black smokers and ecosystem. • Comments about aerobic and anaerobic environments. • Discussion on different ways organisms can generate energy–respiration, anaerobic fermentation and chemosynthesis. • Alternative ideas for the formation of first life Part 3: The origin of life on Earth 29 More stimulus The following points are designed to help you stimulate thoughts on the above quote. You may wish to comment on these points directly or just use them to generate your own thoughts. 30 • Fumaroles versus the Sun as the origin of food chains. • Other organisms such as: giant clams (half a metre long); colonies of tube worms (up to one and a half metres in length); and long necked barnacles, co–exist with bacteria around black smokers. • Making assumptions about the past, based on the present. • The mid–ocean ridge where black smokers and hot springs are common today are over 40 000 km long in today’s ocean and may well have been even longer in the earliest Earth environment. Planet Earth and its Environment Gill Sans Bold Earth and Environmental Science Preliminary Course Stage 6 Planet Earth and its environment Part 4: The evolution of the atmosphere 2 0 0 I 2 r be S o t c NT O ng DM E i t ra E N o rp A M o nc 0 1 2 3 4 5 Eon Era Period Quaternary Epoch Pleistocene Pliocene Holocene (last 10 000 years) Change of scale 10 Miocene 20 Cenozoic 30 Tertiary Oligocene 40 Millions of years before present (Ma BP) Eocene 50 60 Palaeocene Phanerozoic mass extinction 70 Change of scale Cretaceous Mesozoic 100 Jurassic 200 Triassic Permian Carboniferous 300 Palaeozoic 400 500 mass extinction Devonian Silurian Ordovician Cambrian Ediacaran 600 Change of scale Precambrian 1000 Proterozoic age of BIFs 2000 3000 4000 Archaean Hadean oldest stromatolites oldest evidence indicating life Gill Sans Bold Contents Introduction ............................................................................... 3 Early life forms .......................................................................... 5 What are stromatolites? .......................................................................6 The early atmosphere ............................................................. 12 Evidence of an anaerobic environment.............................................12 What is a BIF? ....................................................................................13 Changing atmospheric composition ........................................ 18 How was oxygen first produced? ......................................................18 The removal of methane ....................................................................20 The removal of carbon dioxide ..........................................................21 The production of carbon dioxide ......................................................24 Carbon cycles.....................................................................................26 Carbon reservoirs...............................................................................27 Suggested answers................................................................. 31 Exercise–Part 4 ....................................................................... 35 Part 4: The evolution of the atmosphere 1 2 Planet Earth and its environment Gill Sans Bold Introduction In the last part you looked at the evolution of the earliest atmosphere from anaerobic conditions to aerobic. You were also introduced to the earliest cellular fossils and what is considered to be the earliest representation of life–the Archaea. In this part you will be dealing with anaerobic and aerobic atmospheres in greater detail. You will be looking at the processes responsible and evidence for the evolution of the current atmosphere. In addition you will examine the impact that living organisms and photosynthesis in particular have had on the evolution of the atmosphere. By the end of Part 4, you will have been given opportunities to learn to: • discuss the impact of photolysis on the composition of the early (pre–oxygen) atmosphere • identify photosynthetic bacteria as the first organisms to release oxygen into the environment • discuss the roles of precipitation and photosynthesis in the removal of carbon dioxide from the early atmosphere • predict and explain the differences in composition of the oceans before and after the evolution of photosynthesis • explain that reactions between oxygen and other elements would readily occur producing oxide minerals and thus moderate the release of oxygen into the oceans and atmosphere • describe the forms in which carbon is now locked up in the lithosphere and biosphere. By the end of Part 4, you will have had opportunities to: • perform a first–hand investigation to gather information about the conditions under which iron reacts with oxygen to form iron oxides • perform a first–hand investigation to demonstrate the precipitation of carbonate minerals in solution by bubbling carbon dioxide through limewater Part 4: The evolution of the atmosphere 3 • gather and process information from secondary sources and use available evidence to analyse differences in the composition of the oceans before and after the evolution of photosynthesis • process and present information from secondary sources to list and describe the forms in which carbon is now ‘locked up’ in the lithosphere and biosphere. Extract from Earth and environmental science Stage 6 Syllabus © Board of Studies NSW, amended November 2002. The original and most up–to–date version of this document can be found on the Board’s website at: http://www.boardofstudies.nsw.edu.au/syllabus_hsc/syllabus2000_liste.html#e . 4 Planet Earth and its environment Gill Sans Bold Early life forms The following questions will help you to recall some background material on this topic from your previous learning. 1 What compounds are considered the basic building blocks of life? _____________________________________________________ 2 What particular group of molecules do these ‘building blocks of life’ join together to form? _____________________________________________________ 3 What group of organisms are considered to be the earliest forms of cellular life here on Earth? _____________________________________________________ 4 What is the approximate age of the oldest sedimentary rocks on Earth? Did these rocks contain fossils? _____________________________________________________ _____________________________________________________ 5 How old are the oldest cellular fossils? Describe these fossils _____________________________________________________ _____________________________________________________ _____________________________________________________ Check your answers. The sometimes ancient fossils known as stromatolites are similar to structures currently forming in Shark Bay, Western Australia. These structures are also stromatolites, and are known as ‘living fossils’. Part 4: The evolution of the atmosphere 5 What are stromatolites? Ancient stromatolites provide evidence for early life. These ancient structures have been found in the Pilbara region in Western Australia and have been dated at 3450 million years old. Stromatolites dominated the fossil record between 2000 and 1000 million years ago. They are about the only fossil known. Stromatolites are layered structures, thought to have resulted from the activities of bacteria, which produce lime (calcium rich salts) and trapped silt (very fine mud). Stromatolites display a variety of shapes from mushroom shapes to egg–carton shapes, which have all been constructed from these alternating layers of lime and silt. A cross section of a fossilised stromatolite. This sample is on display at Macquarie University. (Photo: Tim Reid) The photograph above is a cross section of a fossil stromatolite. The stromatolite in this photograph has been placed on its side. Note the fine layering in what appears to be concentric rings. In fact, these layers were produced in a dome shape. Modern day stromatolites have been found forming in Hamelin Pool, Shark Bay in Western Australia. The photograph below shows these stromatolites in Shark Bay and the environment in which they are forming. 6 Planet Earth and its environment Gill Sans Bold Stromatolites forming in Hamelin Pool, Shark Bay in Western Australia. (Photo courtesy of Paul Brooks) Write a brief description of the environment that these structures are forming in, shown in the above photograph. _________________________________________________________ Check your answers. Part 4: The evolution of the atmosphere 7 The formation of present day stromatolites Present day stromatolite structures are formed by the action of cyanobacteria. These cyanobacteria are also prokaryotic in structure. Remember the term prokaryotic means ‘before nucleus’. Refer to your work in the previous part under the heading of Archaea. Present day stromatolites are also photosynthetic, which means they liberate oxygen as a by–product. Because of their photosynthetic nature, these simple bacteria are sometimes incorrectly referred to as blue–green algae. Below is a summary of the chemical equation for photosynthesis. light CO2 + H2O Æ C6H1206 + O2 + H2O light carbon dioxide + water Æ glucose + oxygen + water Look at the photosynthesis equation shown above. Now, refer to your notes from the previous part on respiration. Look carefully at the equation for respiration and answer the following questions. 1 In what way are the two equations similar? ______________________________________________________ ______________________________________________________ 2 How do the two reactions compliment each other? (In other words, how does one reaction affect the other?) ______________________________________________________ ______________________________________________________ ______________________________________________________ 3 In what way do the two reactions differ? ______________________________________________________ ______________________________________________________ Check your answers. 8 Planet Earth and its environment Gill Sans Bold Formation of ancient stromatolites Debate about the origin of ancient stromatolites is usually based on comparisons with the living stromatolites such as the ones found in Shark Bay. If the ancient stromatolites were formed in an identical fashion to the modern examples, then this would have major implications regarding the production of free oxygen in the early atmosphere since ancient stromatolites have been around since almost 3.5 billion years ago. What do you think these major implications would be? To help you answer this question go back and have a look at the proposed composition of the earliest atmosphere. Now have a look at the formula for photosynthesis above. You should be looking at the gases being used in photosynthesis and those being emitted, and then comparing the early atmosphere with our present day atmosphere. (Remember CO2 is produced by volcanoes). _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answers. There is one difficulty in drawing a comparison between fossilised stromatolites and the stromatolites currently forming today. That problem is a lack of sufficient, direct evidence. Although the two structures appear similar in structure, there is a distinct lack of fossilised organisms that are said to have formed the ancient stromatolites. There is evidence that ancient stromatolites are formed by filamentous organisms but exactly what the nature of these organisms was is a good question. In other words, the structures are prevalent, but traces of the organisms which are said to have formed them are scarce. If we continue the assumption that the stromatolites forming today represent the method of formation for ancient stromatolites, then the following sequence holds true for the formation of all stromatolites. Part 4: The evolution of the atmosphere 9 sunlight cynobacterial filaments bacteria Step 1. Initially cyanobacteria accumulate and grow during the day, using the Sun’s light for photosynthesis. night silt deposited and trapped within filaments Step 2. During the night, photosynthesis ceases and fine silt accumulates on the cyanobacterial mats. sunlight bacterial growth Step 3. New bacteria will begin to grow during the following day on top of the thin silt layer, once again photosynthesising. 10 Planet Earth and its environment Gill Sans Bold night decaying cynobacteria CaCO3 precipitation Step 4. As the bacteria in step 1 die and decay, it encourages the precipitation of calcium carbonate. Present day stromatolites are found in environments in which other organisms find it very difficult to survive. These environments include saline lakes and near hot springs. A modern stromatolite from the saline Lake Thetis in Western Australia. Photo: Upgrade Business Systems Pty Ltd. This stromatolite is probably on the order of 1200 years old and although not as famous a location as the Shark Bay area, indicates the variety of locations in which stromatolites exist today. Part 4: The evolution of the atmosphere 11 The early atmosphere From your work in the previous part can you remember the term used to describe an oxygen poor environment? Evidence of an anaerobic atmosphere The term you should have recalled is ‘anaerobic’. The early atmosphere is described as anaerobic and therefore had very little to no free oxygen. The oxygen that did exist was ‘locked up’ with other elements as molecules. An example of this are the oxides, such as iron (II) oxide (FeO2) and aluminium oxide (Al2O3). Another example is water (H2O). Any free oxygen that was produced was immediately consumed and formed into oxides. Uraninite One of the main pieces of evidence for this early anaerobic atmosphere comes from the study of uraninite (uranium dioxide–UO2). This mineral no longer accumulates as a free particle in our present atmosphere to be washed down streams and deposited in sediments. Why? Because it changes its structure when exposed to oxygen forming uranium oxide (U3O8). The following equation shows the basic chemical reaction that occurs with uranite and oxygen. The oxygen on the left–hand side of the equation would need exist as ‘free’ oxygen in the atmosphere for this reaction to proceed. 3UO2 + O2 Æ U3O8 uraninite + oxygen Æ uranium oxide Massive deposits of uraninite which were deposited as sediments in rivers and streams as long as 2300 million years ago, have been found in 12 Planet Earth and its environment Gill Sans Bold South Africa and Canada. The fact that they could be deposited as sediments suggests that they did not have an opportunity to react with oxygen. This therefore, is good evidence of an oxygen deficient atmosphere. Sulfides The presence of sedimentary rocks rich in sulfide minerals prior to about 2400 to 2100 million years ago when the change to less sulfide minerals are found in deposits suggests that the oceans and atmosphere would have been low in oxygen. Sulfides react with oxygen to form sulfates that are mostly soluble. Sulfates are also the basis of the chemical energy chain for sulfate reducing bacteria, a primitive type of Archaea. Low sulfate concentrations in the oceans probably means that in the early oceans these bacteria did not thrive. Their absence would have left to door open for other bacteria such as the methane producing anaerobic Archaea to thrive in the world oceans. What is a BIF? BIF stands for banded iron formation. The occurrence of these formations only from about 2400 million years ago are further evidence for an oxygen deficient environment in the time before the age of BIFs which extended from about 2400 million to 1800 million years ago. During that interval of time extensive world wide deposits of iron in BIFs occurred. Deposits such as those found in the Hamersley Ranges in Western Australia (which make up the world’s largest iron ore deposit) were deposited in ancient watery environments more than 1800 million years ago. BIFs such as these can be found in rocks of many ages. They’re found in the oldest rocks on Earth, though they are not usually found in formations younger than 1700 million old. The interval 2400 to 1800 million years ago probably indicates a time when oxygen was increasing in the atmosphere due to the photosynthetic process of prokaryotic bacteria form the Archaea. Formation of iron oxides BIFs were formed when soluble iron (II) ions (Fe2+) were dissolved, transported and deposited in shallow oceanic waters without reacting with oxygen (becoming oxidised). Iron (II) ions (Fe2+) form a green solution. Part 4: The evolution of the atmosphere 13 BIFs could not be deposited in the oceans of today as the oxygen, which is now dissolved in our oceans, would quickly react with the iron to oxidise it into the iron (III) (Fe3+) state. The iron would then be transformed into orange–red iron oxide. In the age of BIFs sediments of alternatively higher and lower concentrations of iron oxide were precipitated out on the ocean floors. They later metamorphosed into massive banded–iron formations showing the characteristic banding of BIFs. The banding was possibly caused by fluctuations in the iron oxide deposits as a result of a combination of seasonal upwelling of iron–rich waters from the depths of the ocean encouraging photosynthetic blue–green algal blooms (Archaea) and seasonal variations in the algal photosynthetic activity. It may be that the layers in the BIFs may represent a sort of seasonal non living growth ring, indicating increases in oxygen production by the Archaea in longer daylight seasons and lower oxygen production in shorter daylight seasons. Nobody knows for sure and the formation of BIFs continues to be a controversial and well researched scientific area. A sample of a polished section of a BIF showing the well developed banding typical of such rocks. This specimen shows considerable folding of the bands. Photo: Ric Morante. An everyday example of iron oxide is rust. 1 a) List three objects that rust. _________________________________________________ b) What is common to these three objects? Why do they rust? _________________________________________________ 14 Planet Earth and its environment Gill Sans Bold 2 a) List three objects which do not rust. __________________________________________________ b) What is common to these three objects? Why don’t they rust? __________________________________________________ __________________________________________________ Check your answers. Reactions with iron and oxygen In the following activity you will be investigating the conditions under which iron reacts with oxygen. You may find it helpful to refer to experimental procedure in the resource book before attempting the following activity. If you wish, you may want to use the following as an example and come up with your own activity, or modify the activity below to investigate conditions under which iron reacts with oxygen to form iron oxides. With your activity, ensure that you choose appropriate materials and write up your activity in accordance with the outline of experimental procedure in the Resource book. Aim: To observe and analyse the conditions in which oxygen reacts with iron to form oxides. Materials: • 4 glass jars (similar to vegemite or peanut butter jars) • Steel wool • Table salt • Cooking oil Procedure: 1 Place a ball of steel wool, about the size of a table tennis ball, into each of the four glass jars. 2 Boil some water in a pot on the stove for 5 to 10 minutes. Let this water settle and then fill the first glass jar with the warm to hot water. Part 4: The evolution of the atmosphere 15 3 Pour a small amount of cooking oil on top of the water to seal it from the air. 4 Fill the next glass jar with tap water. 5 Fill the third glass jar with tap water and stir in a tablespoon of salt. 6 Leave the steel wool by itself in the fourth and final jar. 7 Leave these jars for four days. 8. Record your observations in the following table. oil boiled water tap water salt water 1 2 3 4 Results: Day Jar 1 (boiled water) Jar 2 (tap water) Jar 3 (salt water) Jar 4 (no water) 1 2 3 4 16 Planet Earth and its environment Gill Sans Bold Conclusion: 1 When iron is oxidised into the iron (III) (Fe3+) state it turns an orange–red colour. If the iron is in the iron (II) (Fe2+) state it should have a blue–green colour. In which of these states would iron exist if it were to be in an anaerobic environment? _________________ 2 In which of the glass jars did the steel wool oxidise or react the quickest? Jar _____ 3 In the glass jar you were referring to in question two, was the environment aerobic or anaerobic? What evidence did you base your answer on? _____________________________________________________ _____________________________________________________ _____________________________________________________ 4 In which of the glass jars did the steel wool oxidise or react the slowest?___________________ 5 What effect does salt have on the oxidation of iron in steel wool? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ 6 Why was steel wool placed in a jar by itself? In scientific terms, what is this known as? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Discuss your results with others. You may choose your friends, family, teacher or a fellow student. In your discussion think of how reactive oxygen is and how many molecules actually contain oxygen. Part 4: The evolution of the atmosphere 17 Changing atmospheric composition In your previous discussion at the end of your experiment on the oxidation of steel wool, you should have discussed the reactivity of oxygen. Now consider the amount of oxygen that needs to be produced to enable oxygen to exist ‘freely’ in the atmosphere as it does today. How was oxygen first produced? How has all this oxygen been produced, considering our Earth began with an anaerobic environment? What processes are responsible for the production of oxygen? The production of oxygen is thought to have initially occurred by the decomposition of water vapour into hydrogen and oxygen gas, by the ultraviolet radiation from the Sun. This process is known as photo–dissociation or photolysis. 2H2O Æ H2 + O2 water Æ hydrogen + oxygen The hydrogen, due to its extremely low density, was not be held by the Earth’s gravity and was lost in space. The oxygen, on the other hand, due to its high reactivity would have quickly combined with other elements to form oxides. True free oxygen probably did not occur in the atmosphere until the advent of abundantphotosynthetic organisms. In photosynthesis, oxygen is released after carbon dioxide has combined with water using the energy from sunlight. light CO2 + H2O Æ C6H1206 + O2 + H2O light carbon dioxide + water Æ glucose + oxygen + water 18 Planet Earth and its environment Gill Sans Bold What do you think happened to the carbon dioxide (CO2) and oxygen (O2) levels in the atmosphere as increased numbers of organisms carried out photosynthesis? _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answers. Because carbon dioxide is taken up and used in the process of photosynthesis the concentration of carbon dioxide in the atmosphere decreased. Think about the photosynthetic organisms of today. What organisms do you think were photosynthetic thousands of millions of years ago? The earliest known photosynthetic organisms are the cyanobacteria. These very primitive, single celled organisms which have been found in rocks dating back to about 3465 million years ago. The release of oxygen into the atmosphere increased dramatically with the advent of the highly photosynthetic algae, that first appeared approximately 1500 million years ago. This date approximately coincides with the end of the banded iron formations. It was from this point on that the atmosphere became abundant in free oxygen. Oxygen’s effect on the ocean Oxygen gas is an extremely reactive element. As soon as oxygen was produced in the ancient oceans it would have reacted immediately with hydrogen, carbon, and iron to form oxides. These would have included water, calcium carbonate which is deposited as limestone, and iron ores such as hematite and magnetite that are insoluble as oxides in water and hence would have precipitated out of solution to form BIFs or other large iron ore deposits. Without the presence of oxygen the ocean would have been richer in dissolved iron and calcium. Its fundamental composition would have differed. Once photosynthesis evolved the chemical structure of the oceans would have changed forever. Most soluble forms of iron were removed rapidly. This is perhaps reflected in the absence of iron ore deposits such as BIFs after about 1500 million years ago. It could be interpreted that once all the free iron dissolved in the ocean was precipitated that oxygen from photosynthesis in the oceans was able to begin building up in the atmosphere in earnest. Part 4: The evolution of the atmosphere 19 To see links that outline some of the theories about the evolution of an oxygen rich atmosphere see the EES links page at: http://www.lmpc.edu.au/science. The role of ozone As the amount of oxygen (O2) increased in the atmosphere so too did the production of ozone (O3) in the upper atmosphere. Ozone is a poisonous gas formed by the action of ultraviolet radiation on oxygen molecules. This ozone layer helps prevent intensive ultraviolet radiation from penetrating into the lower atmosphere and onto the surface of the Earth. This protective ozone layer enabled life to evolve into the shallower waters and eventually on to land. The ozone shield probably first appeared at about the same time as sedimentary rocks began to be deposited containing a lot of oxidised iron in them indicating significant oxygen in the atmosphere. These rocks are known as redbeds and were first deposited from about 2000 million years ago. This was about 400 million years after the initiation of the BIF depositional time at 2400 million years ago. The removal of methane The early atmosphere was thought to contain large amounts of methane (CH4). As a result, the sky would have appeared reddish in colour due to the scattering of light. The large amount of nitrogen in our present atmosphere is responsible for our blue sky. Oxygen which had been produced by the photo–dissociation (splitting) of water molecules by UV radiation from the Sun and through early photosynthetic Archaea would have assisted in the removal of that methane. An interesting note here is that the higher the oxygen level in the atmosphere the higher the ozone content and ozone is a gas that filters UV from reaching the surface. Low oxygen in the atmosphere means a low ozone level which would therefore mean an accelerated photolytic breakdown of water into hydrogen and oxygen. Methane is a reactive gas and combusts (burns) in the presence of oxygen. The following equation shows how oxygen and methane react together to produce carbon dioxide and water vapour. CH4 + O2 Æ CO2 + H2O methane + oxygen Æ carbon dioxide + water 20 Planet Earth and its environment Gill Sans Bold 1 What effect do you think this reaction would have on the composition of the atmosphere over long periods of time? _____________________________________________________ _____________________________________________________ 2 As photosynthesising organisms evolved and increased in number, so too did the rate of photosynthesis. What effect do you think this increase in photosynthesis would have had on the amount of methane in the atmosphere? _____________________________________________________ _____________________________________________________ Check your answers. The removal of carbon dioxide Carbon exists in many different forms. In Part 5 you will be looking at the carbon cycle in detail. However, in this section you will be dealing with carbon in the form of carbon dioxide. The role of photosynthesis Carbon dioxide was initially produced from volcanism (in emissions from volcanoes and associated vents) and by reactions with oxygen and methane. The carbon dioxide produced as a result would have been a large component of the atmosphere but it was gradually removed from the atmosphere as more organisms carried out photosynthesis to produce nutrients and energy. Carbon dioxide was hence removed from the atmosphere through the burial of carbon from the remains of the organisms in sediments. Photosynthesis involves carbon dioxide reacting with water to form organic compounds and oxygen. Look carefully at the diagram on the following page. 1 Where would you expect photosynthesis to occur? Include the equation for photosynthesis. _____________________________________________________ _____________________________________________________ Part 4: The evolution of the atmosphere 21 2 As non photosynthesising organisms developed, cellular respiration producing net amounts of CO2 became more common. Refer to your previous work on respiration and its corresponding equation. What would be the effect on the carbon dioxide cycle once the occurrence of this type of organism increased? Explain your answer. ______________________________________________________ ______________________________________________________ ______________________________________________________ Check your answers. The role of weathering Carbon dioxide was removed from the atmosphere, and continues to be removed , through the erosion of calcium and magnesium silicate rocks uplifted as mountains. The breakdown of these silicate rocks by the weathering action of rainwater is a very efficient process. Carbon dioxide dissolves in the rainwater to produce a weak acidic solution. This then reacts with the rock. The rock is weathered chemically. During periods when the amount of fresh calcium and magnesium silicate rocks available to react at the surface of the Earth such as during mountain building episodes, the level of CO2 removed from the atmosphere would be dramatically accelerated. The reaction is shown below using the erosion of the rock, calcium silicate as an example. Note that CO2 is consumed in this reaction. CaSiO3 + CO2 + H2O Æ Ca2+ + 2HCO3– + SiO2 You can see that calcium silicate reacts with carbon dioxide and water to produce calcium ions, bicarbonate ions and silicon dioxide (silica). Refer to the diagram of the carbon dioxide cycle below. 22 Planet Earth and its environment Gill Sans Bold CO2 CO2 weathering of silicate rocks draws CO2 from the atmosphere CaSiO3 + CO2 +H2O Ca2+ + 2HCO3– + SiO2 ions carried by rivers to oceans HCO3– 2+ Organisms use ions to build calcium carbonate shells (CaCO3) Ca Ca2+ + 2HCO3– CaCO3 + CO2 + H2O CO2 subduction CaCO3 + SiO2 CaSiO3 + CO2 increased pressure and temperature Carbon cycle note that it has input and output paths that over the longer term smooth out fluctuations in the level of atmospheric carbon. It is important to realise that although the figure above looks like a system in equilibrium (what is produced is equal to what is being used), this would definitely not be the case with the earliest atmosphere for CO2. The active volcanism and fresh Ca and Mg silicate rock surfaces not protected by a coat of soil in the earliest Earth would have been much greater than today. The result would have been a removal rate of CO2 in excess to its replacement Carbon dioxide would also have been removed from the atmosphere at a far greater rate than it would have been replaced due to the relatively small amount of animal life in the oceans compared to today. This would, in effect, give reduced amounts of carbon dioxide being released into the atmosphere from the volcanoes above the subduction zones. Estimates have been made as to the amount of time it would take one atom of carbon to complete the cycle, from atmosphere to ocean and back into the atmosphere, taking into account the current rate of tectonic plate movement. The estimate is about 60 million years although this estimate could be two orders of magnitude too short and the real time for the completion of such a cycle could be on the order of billions of years. Part 4: The evolution of the atmosphere 23 The production of carbon dioxide Although carbon dioxide is being extracted from the atmosphere by two processes (weathering and photosynthesis) carbon dioxide is also being replaced through the emissions of gas from volcanoes and the precipitation of carbonates. The precipitation of carbonates The calcium ions (Ca2+) and bicarbonate ions (HCO3–) produced in the weathering of rocks are quite reactive. The ions are used by shell–forming organisms eg molluscs to make shells that are mainly composed of calcium carbonate (CaCO3). Ca2+ + 2HCO3– Æ CaCO3 + CO2 + H2O These shells, along with those made of silica, are deposited as thick layers of sediment on the floors of lakes, seas and oceans. It is important to realise that once these products of erosion eventually get washed into the oceans, organisms then use these ions to build carbonate shells, which are eventually deposited on the ocean floor. This process then releases carbon dioxide back into the atmosphere. In the following activity you will observe the precipitation of calcium carbonate. Aim: To model the precipitation of a carbonate in solution. Materials: • Limewater prepared in Part 3 • Glass jar • Straw Procedure: 24 1 Put some limewater into the glass jar 2 Using the straw, blow into the limewater. Do this for only a minute or so. Planet Earth and its environment Gill Sans Bold 3 Record your observation as a diagram of the glass jar, Before and After. Results: Before After Conclusion: What conclusion, or comments can be made about this experiment and the deposition of carbonate in oceans? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Emission of gases Periods of non–volcanic mountain building (fold mountains) are directly responsible for the uptake of massive amounts of carbon dioxide (CO2) from the atmosphere. Mountains encourage weathering processes, and in doing so consume carbon dioxide from the atmosphere. This process is still occurring today in places such as the Himalayas. The ocean floor is continually being recycled back into the mantle at subduction zones. (Refer to the diagram of the carbon dioxide cycle). At these zones the oceanic plate, due to its high density, is subducted underneath an opposing plate and the carbonate sediments which were Part 4: The evolution of the atmosphere 25 deposited on top are carried down with it. Much of this subducted material is melted back into the mantle at temperatures well in excess of 1000K. As a result of this remelting, calcium silicates (CaSiO3) and carbon dioxide are produced. The carbon dioxide is emitted through the volcanoes above these subduction zones and released back into the atmosphere once again. Carbon cycles nis bustio m sto r a ge carbonate v o rock Carbon c o compounds for example fossil fuels to sp iratio n s y nt he sis CO2(g) lca et long term cycle CO2(g) 2(g) n medium term cycle m C2H12O6 r e ph o short term cycle te s CO m a l s ili c a There are really three cycles involving carbon. Years 10 2 10 3 decade century millenium 10 4 10 5 10 6 10 7 10 8 10 9 10 10 age of Earth average human lifetime month day billion years 10 1 million years 1 year 10 –2 10 –1 You are probably most familiar with the relatively short term carbon cycle involving photosynthesis and respiration that operates on a years or days timeframe. 26 Planet Earth and its environment Gill Sans Bold In other words, a carbon atom involved in photosynthesis and respiration takes years or days to travel once around the cycle. There is another medium term carbon cycle that involves carbon storage and combustion operating on timeframes from 105 to 108 years. These cycles are dwarfed in terms of the quantities of carbon involved when the long term carbon cycle involving carbonate rock storage, shale deposition and volcanism and metamorphism is considered. The long term carbon cycle operates on timeframes from 107 to 109 years. Carbon reservoirs Carbon reservoirs are broad ways or locations where carbon is stored (usually as a compound combined with other elements). The actual amount of carbon in the Earth is not clearly known. The mantle for example, has huge quantities of carbon but exactly how much is uncertain. Because of extremely limited contact with the mantle this source of carbon probably can be ignored over meaningful timeframes. The table below describes the main reservoirs of carbon that are accessible over the time frames of the long term carbon cycle or shorter intervals. The amounts of carbon in some of the reservoirs are quite imprecisely known because estimating the size of the carbon reservoir is extremely difficult. Reservoirs such as the atmosphere are currently growing whereas other reservoirs such as the marine biomass are relatively constant. A quick look at the table might surprise you. For example, the level of land based biomass being so much greater than that of marine based biomass is not generally known. This is of course largely because of the presence of trees and extensive forests. The mass of people in terms of a carbon storage is really a very insignificant amount compared to other carbon reservoirs. All the people in the world for example have a carbon mass of about only 0.036 ¥1012 kg. Part 4: The evolution of the atmosphere 27 Look at the table below that describes global carbon reservoirs then answer the questions below. 12 Reservoir Amount of carbon ( ¥10 kg) Land biomass About 700 Atmosphere About 600 Marine biomass 3 Surface ocean 900–1000 Methane as clathrate 10 000 Deep ocean 38 000 Soil 1500 –1600 Sediments including shales, coal and limestones 77 000 000 1 How much carbon is contained in living things? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ 2 How does the amount of carbon in living things compare to that in non–living things? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ 28 Planet Earth and its environment Gill Sans Bold The information contained below has been compiled from information you have covered in previous parts. Read carefully through the following and fill in the blank spaces by selecting the appropriate word from the list below:carbonate, oxygen, carbon dioxide, photosynthesis, free, oceans, iron, evolved, increases, volcanic, weathered, carbon, life, oil, dead, warm, condensation, oxides. 3 The early oceans probably originated from the ………………… of water vapour (produced from the degassing of the Earth’s interior), and would have been relatively ………… compared to the oceans of today. The oceans became saline as rocks were ………………… to sediment and deposited in oceans from rivers and streams. Hot springs, associated with submarine ……………… activity, are another major source of salt within the oceans. As life ……………… and …………………… took hold, oxygen became more abundant within the oceans and was in the first instance ‘locked up’ as ……………. with many elements and minerals within the seas. This resulted in banded ………… formations being deposited in the oceans. This production of ……………, eventually led to the existence of ‘free’ oxygen within the atmosphere. Another implication of increased photosynthesis within the oceans, is the subsequent reduction of …………… …………… dissolved in the water. Carbon dioxide is used as a reactant in the photosynthetic equation, and so as photosynthesis, and therefore oxygen, …………… dissolved carbon dioxide concentration decreases. As life continued to evolve and increase in quantity and diversity, ……………… layers began to be deposited on ocean floors from accumulated shell and bone material, originating from ………… organisms. These carbonates eventually formed limestone and dolomite layers. This increase in carbonate within the …………… was, and still is important, as it provides a mechanism which enables the carbon to be ‘locked up’. (Coal, ………, oil shales and natural gas also serve the same purpose in continental crustal material). If the …………… was not removed in this manner, then it would combine with the oxygen, reducing the amount of ………… oxygen in the oceans and atmosphere, which is a necessary requirement for the process of most…………. 4 Recall the equation for photosynthesis and predict how photosynthetic organisms may possibly change the composition of the oceans. _____________________________________________________ _____________________________________________________ _____________________________________________________ Check your answers. Part 4: The evolution of the atmosphere 29 30 Planet Earth and its environment Gill Sans Bold Suggested answers Early life forms 1 Amino acids are the basic building blocks of life. 2 Amino acids join to form proteins. 3 Archaeobacteria are considered to be the earliest form of cellular life on Earth. 4 The oldest sedimentary rocks are estimated to be 3800 million years old. No, these rocks do not contain fossils. But, they contain carbon deposits from living organisms that were dated using carbon isotopes. 5 The oldest cellular fossils are estimated at 3465 million years old. These fossils have been described as ‘cyanobacterium–like’ implying then that they may have been able to photosynthesise. What are stromatolites? The stromatolites are forming in a shallow marine environment. The waters as a result would probably be relatively warm. 1 The same types of molecules appear in the equations for both processes. 2 Respiration requires oxygen which is produced by photosynthesis. Photosynthesis requires carbon dioxide which is produced in respiration. But, these processes are not the same, in reverse. 3 Light energy is required for photosynthesis to proceed, respiration releases energy. Formation of ancient stromatolites Carbon dioxide was abundant in the early atmosphere. If these early stromatolites were photosynthetic, then oxygen would have been produced and begin accumulating in the atmosphere. Part 4: The evolution of the atmosphere 31 Formation of iron oxides 1 a) There are many metal objects that can rust eg. the bodywork of cars, unpainted metal hand rails, old metal gates, nails, fish hooks, bicycle wheel rims and spokes, sheet metal roofing. b) Rusted objects are all bare metal (made of iron) and exposed to the atmosphere. Don’t forget the atmosphere is approximately 20% oxygen and also contains water vapour. 2 a) Objects that do not rust include: plastic containers; painted or galvanised metal surfaces; wooden furniture; objects that are made out of metals other than iron eg. copper, gold, silver and aluminium; metal objects in space. b) Objects that do not rust either do not contain iron or are protected from the atmosphere which is rich in oxygen. Iron is protected from rusting by painting or galvanising. How was oxygen first produced? The amount of carbon dioxide would decrease and the amount of oxygen would increase as a result of this process. Removal of methane 1 The amount of methane would reduce and the amount of carbon dioxide would increase. 2 The amount of methane would reduce even further since photosynthesis produces oxygen. This oxygen would react with methane reducing methane levels in the atmosphere. Removal of CO2 from the atmosphere 1 Photosynthesis would occur in photosynthetic organisms on the land and in the oceans. light CO2 + H2O Æ C6H1206 + O2 + H2O light carbon dioxide + water Æ glucose + oxygen + water 2 C6H12O6 + O2 Æ CO2 + H20 glucose + oxygen Æ carbon dioxide + water As a result of increased respiration the amount of carbon dioxide in the atmosphere would increase. However, this should be offset to some degree by an increase in photosynthetic organisms, which would take in the carbon dioxide as a reactant. 32 Planet Earth and its environment Gill Sans Bold Carbon reservoirs 1 12 About 703 ¥10 kg. 2 It is very tiny. The non living carbon reservoirs are much larger. They therefore have the capacity to affect carbon cycles dramatically. 3 The early oceans probably originated from the condensation of water vapour (produced from the degassing of the Earth’s interior), and would have been relatively warm compared to the oceans of today. The oceans became saline as rocks were weathered to sediment and deposited in oceans from rivers and streams. Hot springs, associated with submarine volcanic activity, are another major source of salt within the oceans. As life evolved and photosynthesis took hold, oxygen became more abundant within the oceans and was in the first instance ‘locked up’ as oxides with many elements and minerals within the seas. This resulted in banded iron formations being deposited in the oceans. This production of oxygen, eventually led to the existence of ‘free’ oxygen within the atmosphere. Another implication of increased photosynthesis within the oceans, is the subsequent reduction of carbon dioxide dissolved in the water. Carbon dioxide is used as a reactant in the photosynthetic equation, and so as photosynthesis, and therefore oxygen, increases dissolved carbon dioxide concentration decreases. As life continued to evolve and increase in quantity and diversity, carbonate layers began to be deposited on ocean floors from accumulated shell and bone material, originating from dead organisms. These carbonates eventually formed limestone and dolomite layers. This increase in carbonate within the oceans was, and still is important, as it provides a mechanism which enables the carbon to be ‘locked up’. (Coal, oil, oil shales and natural gas also serve the same purpose in continental crustal material). If the carbon was not removed in this manner, then it would combine with the oxygen, reducing the amount of free oxygen in the oceans and atmosphere, which is a necessary requirement for the process of most life. 4 CO2 + H2O Æ C6H12O6 + O2+ H20 carbon dioxide + water Æ glucose + oxygen + water Marine algae and other photosynthetic marine organisms would reduce the concentration of carbon dioxide and increase the amount of oxygen in the oceans. Part 4: The evolution of the atmosphere 33 34 Planet Earth and its environment Gill Sans Bold Exercise – Part 4 Name: _________________________________ Exercise 4.1 Changes in the Earth’s atmosphere 1 Describe what you understand the word ‘anaerobic’ to mean. _____________________________________________________ 2 Explain, in detail, how oxygen came to be so abundant on Earth. In your answer you should make reference to particular time periods and processes involved. _____________________________________________________ _____________________________________________________ _____________________________________________________ 3 Identify and outline some of the earliest indicators of oxygen having being produced. You must state why the indicators you have chosen could be used to show the existence of oxygen, and give their estimated age of indicating oxygen. _____________________________________________________ _____________________________________________________ _____________________________________________________ 4 Describe ozone and explain why it was important to the evolution of life. _____________________________________________________ _____________________________________________________ 5 Where is the ozone layer? _____________________________________________________ _____________________________________________________ Part 4: The evolution of the atmosphere 35 Exercise 4.2 Changes in the composition of oceans In this exercise you will investigate the composition of oceans before and after the evolution of photosynthesis. After reading the notes above and going over your notes in this Part, complete the following table in point form. You may even wish to do some of your own research. Resources Some useful texts you may have access to include: • Frank Press, F and Siever, R. Earth. Freeman. • Emiliani, C. Planet Earth. Cambridge University Press. • Clark, IF and Cook, BJ. Perspectives of the Earth. Australian Academy of Science. • Environmental science. Australian Academy of Science. You may have access to the Internet. If you do you may find the sites listed on the Earth and Environmental Science pages of the following site helpful. http://www.lmpc.edu.au/science Ensure that you also carry out your own searches whether it is on the Internet or your local or school library. You may find the following key words useful when conducting your searches: • evolution of the Earth • evolution of the Earth’s atmosphere • hydrosphere • photosynthesis • evolution of life Procedure Place your response in the table outlined below. On the first page record your findings about the composition of the oceans before the advent of photosynthesis in the table. In the left column place, in point form, notes about the composition of the ocean. And in the right column list the evidence or what led you to write that point. You should also list the source of your information in the right column. On the second page answer the questions about the composition of oceans. 36 Planet Earth and its environment Gill Sans Bold Composition of oceans before evolution of photosynthesis Part 4: The evolution of the atmosphere Supporting evidence 37 Analysis of research 1 Was oxygen being produced from the oceans before the advent of photosynthesis? (Refer to your notes regarding photolysis of water.) ______________________________________________________ ______________________________________________________ 2 Comment on the interrelationship between the atmosphere and the ocean. ______________________________________________________ ______________________________________________________ 3 What gases were more abundant in the ocean before the evolution of photosynthesis? ______________________________________________________ ______________________________________________________ 4 What gases became more abundant in the ocean after the evolution of photosynthesis? ______________________________________________________ ______________________________________________________ 5 What evidence do scientists use to indicate the presence of oxygen in ancient oceans? ______________________________________________________ ______________________________________________________ 38 Planet Earth and its environment Gill Sans Bold Earth and Environmental Science Preliminary Course Stage 6 Planet Earth and its environment Part 5: Carbon in the atmosphere and hydrosphere 2 0 0 In r2 e b S o t c NT O ng DM E i t ra E N o rp A M o c 0 1 2 3 4 5 Eon Era Period Quaternary Epoch Pleistocene Pliocene Holocene (last 10 000 years) Change of scale 10 Miocene 20 Cenozoic 30 Tertiary Oligocene 40 Millions of years before present (Ma BP) Eocene 50 60 Palaeocene Phanerozoic mass extinction 70 Change of scale Cretaceous Mesozoic 100 Jurassic 200 Triassic Permian Carboniferous 300 Palaeozoic 400 500 mass extinction Devonian Silurian Ordovician Cambrian Ediacaran 600 Change of scale Precambrian 1000 Proterozoic age of BIFs 2000 3000 4000 Archaean Hadean oldest stromatolites oldest evidence indicating life Gill Sans Bold Contents Introduction................................................................................ 3 Carbon occurs in many forms.................................................... 4 The release of carbon dioxide .............................................................4 The carbon cycle ..................................................................................5 The greenhouse effect .............................................................. 9 Greenhouse gases .............................................................................11 Global temperature variations............................................................12 Predictions for the future....................................................................13 Suggested answers................................................................. 15 Appendix ................................................................................. 17 Exercises–Part 5 ..................................................................... 19 Part 5: Carbon in the atmosphere and hydrosphere 1 2 Planet Earth and its environment Gill Sans Bold Introduction Previously you followed the development of the atmosphere from anaerobic through to aerobic, and considered the effects of the evolution of life on the development of the atmosphere. In this part you will consider the relationship between CO2 and the temperature of the surface of the Earth. You will also have a more detailed look at how carbon exists on Earth and the role carbon cycling plays in relation to variations in the Earth’s surface temperature. At the end of Part 5, you will have been given opportunities to learn to: • outline the links between the concentration of atmospheric carbon dioxide and average global temperature over geological time. At the end of part 5 you will have been given opportunities to: • identify data, process and analyse information from secondary sources and use available evidence to assess claims of a relationship between changing carbon dioxide concentrations and changes in average global temperatures. Extract from Earth and environmental science Stage 6 Syllabus © Board of Studies NSW, amended November 2002. The original and most up–to–date version of this document can be found on the Board’s website at: http://www.boardofstudies.nsw.edu.au/syllabus_hsc/syllabus2000_liste.html#e . Part 5: Carbon in the atmosphere and hydrosphere 3 Carbon occurs in many forms Carbon presents itself in different compounds on the Earth, and is ‘locked up’ within different molecules. Much discussion until now has centred on carbon in the form of carbon dioxide. However, the carbon that makes up carbon dioxide has originated from elsewhere and is part of a cyclic process. Carbon can take the form of: – inorganic (not from living material) material in rocks and minerals – organic material from living or once living organisms – gases such as carbon dioxide (CO2), carbon monoxide (CO), and methane (CH4). These stores of carbon are referred to as carbon sinks and reservoirs. The release of carbon dioxide Trees and fossil fuels such as coal, oil and natural gas, are important carbon sinks. Industrial activities such as automobiles, burning of forests, home heating, and the generation of electricity, have seen these fossil fuels burn and release their storage of carbon into the atmosphere as carbon dioxide. The oxygen in the atmosphere has allowed human kind to burn these fossil fuels to obtain energy. As stated above carbon is released from the burning of fossil fuels. This carbon then combines with oxygen during combustion to release carbon dioxide into the atmosphere. Write a word equation showing this combustion reaction. Write an equation using chemical formulas as well. _________________________________________________________ _________________________________________________________ Check your answer. 4 Planet Earth and its environment Gill Sans Bold The burning of fossil fuels has been particularly prevalent since the nineteenth century and is claimed by many to have had a major impact on climatic change. This period of time is known as the industrial revolution. Some of the carbon dioxide produced is dissolved in the oceans but much of it ends up as atmospheric carbon dioxide. Once released, carbon dioxide produced from industrialised activities remains in the oceans and atmosphere until it is used in biological processes or weathering and deposited as sediment on the ocean floor. This is discussed in more detail below. Carbon can be easily converted to carbon dioxide gas through the combustion of fossil fuels, however it takes a much greater time for this carbon then to be converted back into fossilised fuel. Read over the last paragraph once again. Comment on the effect of carbon being easily converted from fossil fuels to carbon dioxide and the time taken for fossil fuels to be produced. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer. Estimates are have shown that by the year 2500, atmospheric carbon dioxide levels could be as high as 1000 to 2000 parts per million, compared with 350 parts per million of today. Now read over your response to the last self–correct exercise. This increase in carbon dioxide, should it occur, will affect global climates and is discussed in detail below. The carbon cycle The different stores of carbon are connected through the carbon cycle. Carbon in one form and over time can be removed, transported and converted into other forms. The carbon cycle on the next page illustrates the interrelationship between these different stores of carbon. Part 5: Carbon in the atmosphere and hydrosphere 5 atmospheric CO2 fossil fuel combustion photosynthetic assimilation decomposition respiration land plants coal and oil dead organic matter ocean plants ocean dead organic matter sediments sedimentation The carbon cycle. Carbon exists in carbonates (CO32–) deposited on the bottom of oceans, lakes and rivers, by being bonded to ions such as calcium (Ca2+), sodium (Na+) and magnesium (Mg2+). Limestone, composed largely from calcium carbonate (CaCO3), is deposited on ocean floors from shells of marine organisms such as plankton. Coral, calcareous algae and shellfish accumulate carbonate in shallow water and may form reef structures. Coal and natural gas (methane) are hydrocarbons (compounds of carbon and hydrogen), and are formed when dead organisms (mainly plants) accumulated in a swamp–type environment. Oil is formed mainly in a marine environment, and formed by decay of decay of animal and plant material. Photosynthesis incorporates carbon into organic molecules by taking carbon dioxide in from the atmosphere. Carbon in this form is passed along the food chain by other organisms that eat these plants. Once these organisms die the carbon is released into the soil as organic compounds and as carbon dioxide into the atmosphere. The cells of most living organisms use oxygen in respiration to release energy stored in organic molecules and in so doing release carbon dioxide into the atmosphere. Generally, plants take in more carbon dioxide for use in photosynthesis than they lose in respiration. This is used in growth and development of the plants. 6 Planet Earth and its environment Gill Sans Bold The diagram shown above is one example of a diagrammatic representation of the carbon cycle. 1 Draw your own version of the carbon cycle showing the flux or transfer of carbon from one carbon sink to another using the information given in the table below. You may decide to use drawings or you may decide to use symbols on your carbon cycle. Use arrows to show the transfer of carbon from one form into another. Be sure to label your diagram to show the amount of carbon transferred in tonnes. Movement of carbon Amount of carbon transferred (billions of tonnes) Atmosphere to ocean surface 100 Atmosphere to land plants (photosynthesis) 700 Vaporisation—ocean to atmosphere 97 Respiration–land plants to atmosphere 10 Use of fossil fuels—industry to atmosphere 5 Decaying land plants to soil 25 Decaying organic matter–soil to atmosphere 700 Respiration–ocean to ocean plants 40 Decaying ocean plants to organic sediment 40 Part 5: Carbon in the atmosphere and hydrosphere 7 2 The table below shows some of the main stores of carbon known as sinks and the amount of carbon stored in each of these sinks. Carbon stores (sinks) atmosphere oceans sedimentary rocks coal and oil land plants and animals ocean plants dead organic matter on ocean floor Carbon present (billions of tonnes) 700 38 000 77 000 000 10 000 700 3 3 000 Identify which of these sinks you would anticipate were increasing at the present time and which sinks are decreasing in size. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ 3 What effect do you think the industrial revolution, in the late eighteenth century, had on the carbon cycle in terms of increasing CO2 levels in the atmosphere? You may wish to comment on: combustion; the advent of the motor car; logging of forests; the mining of coal, oil and natural gas; or any other activity you feel is relevant. ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 8 Planet Earth and its environment Gill Sans Bold The greenhouse effect Without the greenhouse effect the average surface temperature of the Earth would be –20°C. There is approximately 700 billion tonnes of carbon in the atmosphere. This amount is not fixed and has varied through the history of the Earth. At present it is on the increase due to transport, industrial emissions and deforestation. In what form does carbon mainly exist in the atmosphere? _________________________________________________________ Check your answer. What effect does all this carbon dioxide have on the atmosphere? It enhances the greenhouse effect. The diagram below shows how the greenhouse effect contributes to an increase temperature. infrared waves trapped by atmosphere infrared waves trapped by glass visible light waves greenhouse atmosphere The greenhouse effect. Visible wavelengths penetrate to the surface and are absorbed and re–radiated as infrared radiation. That infrared radiation is trapped by the atmosphere and re–radiated back to the surface of the Earth so increasing the temperatures at the surface. A similar thing happens in greenhouses for plants hence the name. Part 5: Carbon in the atmosphere and hydrosphere 9 A greenhouse is a glass building designed to protect and cultivate plants in cool climates. Sunlight passes through the glass so that these plants can photosynthesise and grow. However, the glass also traps heat in the form of re–radiated infrared radiation and the temperatures increase in the greenhouse as a result. This increase in temperature is a result of this ‘greenhouse’ effect. Another example where this greenhouse effect operates is in the heating of a motor cars’ interior when it is left parked in the sun. Sunlight passes through the glass areas of the car because the glass does not impede the visible wavelengths (light). The light energy is partly absorbed by the seats, dashboard and other parts of the cars’ interior and re–emitted, not as visible light energy, but as infrared energy. This energy does not completely pass back through the glass but is partly absorbed by it and is partly reflected back into the interior of the car, heating the interior. Why should you place the windscreen sun protector on the outside of a car’s windscreen rather than on the inside? _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Check your answer. In the example of the car above, the windscreen of the car represents the atmosphere, and the car’s interior represents the Earth. This greenhouse effect has been used to help describe the increase in global temperatures over the past two hundred years. 10 • Visible rays from the Sun can readily pass through the Earth’s atmosphere to the surface. • At the surface, the radiation is reflected back as invisible infrared radiation. • Most of the infrared radiation is reflected back into space. However, some of this radiation is absorbed by clouds (water vapour), carbon dioxide and other greenhouse gases and is therefore prevented from escaping into space. • The net effect is that the Earth increases its overall average temperature as the heat is radiated back from the atmosphere towards the Earth’s surface. This is similar to the greenhouse in that the heat is radiated back from the glass heating the interior of the greenhouse. Planet Earth and its environment Gill Sans Bold Greenhouse gases Apart from naturally occurring carbon dioxide and water vapour in the atmosphere, other gases also contribute to the trapping of infrared radiation, resulting in an increase in surface temperatures. In the agricultural industry nitrogen based fertilisers are used extensively. The nitrogen reacts with oxygen to produce nitrous oxide, which is then released into the atmosphere. This nitrous oxide absorbs infrared radiation in the same way as carbon dioxide. Similarly, halons (gases that contain either fluorine, chlorine, or bromine) and CFCs (chlorofluorocarbons) have the same heat trapping properties. These gases were once widely used as solvents, in aerosols, fire extinguishers and refrigeration units. Other gases that contribute to the greenhouse effect are methane (produced in marshes, rice paddies and cattle) and carbon dioxide from combustion in industry and transport. ing om Inc Most infrared radiation goes back into space adi ar r sol n atio Some heat radiation escapes but greenhouse gases trap the rest methane s ca rb lo on id ox us tro ni aerosols fire extinguishers refrigeration fertiliser Activities that release gases and contribute to greenouse effect di ox i cattle paddy fields e ha de the re phe tropos ns CFC coal oil petrol the Earth The greenhouse effect is enhanced by increased levels of greenhouse gases such as carbon dioxide, halogens, CFCs, methane and nitrogen oxides. Part 5: Carbon in the atmosphere and hydrosphere 11 Since the acceleration of the industrial revolution at the end of the nineteenth century the concentration of carbon dioxide in the atmosphere has increased considerably. The carbon dioxide is released when fossil fuels such as coal, oil and natural gas are burned (combusted) to provide energy for industry. Although some of this carbon dioxide is absorbed into the oceans, a large percentage remains in the atmosphere where it acts to absorb and re–radiate the infrared radiation back towards the Earth’s surface. Concern has arisen as to the increased greenhouse effect and the rise in the Earth’s average temperature that appears to be happening now. Global temperature variations From your work above you now realise the level of carbon dioxide concentrations in the atmosphere contribute to the overall impact of the greenhouse effect. Correlation between CO2 and temperature An analysis of past carbon dioxide concentrations and temperature fluctuations has shown a correlation. Although this does not necessarily prove that temperature increases or decreases are the result of fluctuations in carbon dioxide, it does, however, raise some important points for further investigation. There is strong evidence to link higher atmospheric carbon dioxide fluctuations with global temperature fluctuations. However, the interrelationship between the Earth’s atmosphere, oceans and land is so complex that it is difficult to say that one factor was the sole cause. Complexities that must be considered include: • the degree to which oceans dissolve carbon dioxide • the degree to which carbon dioxide is distributed throughout the oceans by currents • the effects of different clouds eg. some clouds cool the Earth whilst other types of clouds warm the Earth. Even given these complex issues, it is generally accepted that an increase in carbon dioxide will increase average global temperatures due to an increase in the greenhouse effect. Do the return exercise now. 12 Planet Earth and its environment Gill Sans Bold Comparisons with our neighbours One argument which supports the idea that increased carbon dioxide levels are related to increased temperatures on Earth are the observations made about Earth’s neighbour Venus. Venus receives less light energy at its surface than Earth does due to its large volume of reflective clouds. However its surface temperature is much hotter that that of Earth’s. It is also known that the atmosphere of Venus consists of 300 000 times more carbon dioxide (CO2) than Earth’s. This may indicate that the greenhouse effect is operating to a much greater degree on Venus and is heating the planet up. Predictions for the future Climate modelling by scientists indicate that a doubling of the amount of carbon dioxide (CO2) will lead to a average global surface temperature increase in the range of 1 to 5.5∞C due largely to the enhanced greenhouse effect. It is also estimated by some scientist based on projection modelling with computers that over the next century carbon dioxide (CO2) levels should double those of the nineteenth century levels. Other aspects apart from climate need to be considered when looking at increased levels of atmospheric carbon dioxide and their effect on the planet. One area in particular is the effect on photosynthetic organisms in both aquatic (water) and terrestrial (land) environments. This has widespread implications on food chains and crop production. Experiments on plants with increased concentrations of atmospheric carbon dioxide have shown both positive and negative effects, depending on the species of the plant, and the amount the carbon dioxide was increased. This area requires further research. Discuss the implications of increased amounts of carbon dioxide for our future. Where should scientific funding be allocated? Should we be learning to live with increasing amounts of atmospheric carbon dioxide or should we be learning how to avoid increasing carbon dioxide output? You may decide to discuss this with your family, friends or teacher, or you may even decide to locate a relevant scientist in this field and find out what approach they are taking to studying the enhanced greenhouse effect. Part 5: Carbon in the atmosphere and hydrosphere 13 14 Planet Earth and its environment Gill Sans Bold Suggested answers Carbon occurs in many different forms carbon + oxygen Æ carbon dioxide. C + O2 Æ CO2 Our society relies heavily on fossil fuels for energy. Fossil fuels are popular because they are relatively easy to extract and we obtain large amount sof energy when they are burned. However, combine this rapid rate of fossil fuel consumption with the millions of years it takes for these fossil fuels to form we can conclude will deplete the worlds current reserves of fossil fuels in a very short period of time. The greenhouse effect Carbon exists mainly in the form of carbon dioxide (CO2). If the sun protector was placed on the inside of the windscreen, above the dashboard, the visible light will still pass through the glass and the invisible infrared radiation will be trapped within the car, heating the interior. By placing the sun protector on the outside of the window both the visible light and the infrared radiation will be reflected before it enters the cabin. Part 5: Carbon in the atmosphere and hydrosphere 15 16 Planet Earth and its environment Gill Sans Bold Appendix Part 5: Carbon in the atmosphere and hydrosphere 17 18 Planet Earth and its environment Gill Sans Bold Exercise – Part 5 Name: _________________________________ The following activity illustrates the correlation between past carbon dioxide levels and temperature variations. Aim: To recognise a correlation in plotted data between carbon dioxide concentrations and average global temperatures. Method: 1 Plot the two datasets from the table on the same graph. Graph paper is in the Appendix. Use a different colour for each dataset but a common horizontal axis. You should end up with two lines on the one graph. It may be useful to plot the change in temperature in red and the change in carbon dioxide concentrations in blue. 2 Use the left hand vertical axis to plot the carbon dioxide levels. 3 Use the right hand vertical axis to plot the change in temperature (from the current mean). 4 Use the horizontal axis to plot Years ago (x1000 yr). 5 Remember to label your axis correctly and include the correct units. You may also find it useful to consult the Resource book for graphing procedures. You should submit your graph with the return pages. Part 5: Carbon in the atmosphere and hydrosphere 19 Data 20 Concentration of CO2 in atmosphere (ppm) Years ago (X1000 yr) 277 0 200 20 230 30 177 40 220 52 195 60 247 70 220 80 210 85 238 95 222 100 245 108 280 120 260 130 298 135 190 145 200 160 Planet Earth and its environment Gill Sans Bold Change in temperature from current mean (°C) Years ago (X1000 yr) 0.00 0 +1.40 8 –10.00 20 –6.25 40 –7.70 50 –3.75 52 –8.75 60 –2.50 80 –6.00 85 –2.50 100 –7.50 110 0.00 130 +3.00 135 –9.00 145 –8.75 160 Part 5: Carbon in the atmosphere and hydrosphere 21 Conclusion: 1 In analysing your results look for any similarity in trends such as common decreases or increases, between the datasets over time. Can you say certainly that the carbon dioxide levels influenced the temperature changes? Explain your answer. ______________________________________________________ ______________________________________________________ ______________________________________________________ 2 From this information alone is it just as valid to say that the changes in temperature caused the changes in carbon dioxide? Discuss this point. ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 3 With the information contained in the graphs, and the information outlined above about the greenhouse effect, write your own thoughts in a concluding statement. ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 4 From a broader perspective, what impact do you think increased global temperatures would have on world climates? ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 22 Planet Earth and its environment Gill Sans Bold Earth and Environmental Science Preliminary Course Stage 6 Planet Earth and its environment Part 6: Climatic variation 2 0 0 In r2 e b S o t c NT O ng DM E i t ra E N o rp A M o c 0 1 2 3 4 5 Eon Era Period Quaternary Epoch Pleistocene Pliocene Holocene (last 10 000 years) Change of scale 10 Miocene 20 Cenozoic 30 Tertiary Oligocene 40 Millions of years before present (Ma BP) Eocene 50 60 Palaeocene Phanerozoic mass extinction 70 Change of scale Cretaceous Mesozoic 100 Jurassic 200 Triassic Permian Carboniferous 300 Palaeozoic 400 500 mass extinction Devonian Silurian Ordovician Cambrian Ediacaran 600 Change of scale Precambrian 1000 Proterozoic age of BIFs 2000 3000 4000 Archaean Hadean oldest stromatolites oldest evidence indicating life Gill Sans Bold Contents Introduction ............................................................................... 3 Geological time line ................................................................... 4 Quaternary temperature changes .......................................................6 The 60 million year climate........................................................ 8 Evidence for cooling.............................................................................8 Past climate ........................................................................................10 What affects climate?.........................................................................11 A look at CO2 ......................................................................................14 Oxygen isotopes.................................................................................15 Ice core records..................................................................................22 Sea level changes..............................................................................23 Marine sediments ...............................................................................26 Lake sediments ..................................................................................27 Appendix ................................................................................. 29 Suggested answers................................................................. 33 Exercises–Part 6 ..................................................................... 35 Part 6: Climatic variation 1 2 Planet Earth and its environment Gill Sans Bold Introduction In Part five you learned how carbon can exist in different forms and the interrelationship between these forms is described by the carbon cycle. You also examined the way that carbon compounds may influence the Earth’s temperature by enhancing the greenhouse effect. In this part you will study climatic variations over time and the evidence used in determining these variations. In particular you will gather, process and analyse information regarding climatic variations over the past sixty million years. At the end of Part 6, you be given opportunities to learn to: • identify that evidence from marine and lake sediments, ice cores and sea level change suggests average global temperatures have decreased over the last 60 million years At the end of Part 6, you be given opportunities to: • gather, process and analyse information from secondary sources on the varying climate of the Earth since the end of the Cretaceous, sixty million years ago. Extract from Earth and environmental science Stage 6 Syllabus © Board of Studies NSW, amended November 2002. The original and most up–to–date version of this document can be found on the Board’s website at: http://www.boardofstudies.nsw.edu.au/syllabus_hsc/syllabus2000_liste.html#e . Part 6: Climatic variation 3 Geological time line This is a good activity that will help you gain a better understanding of relative time frames and will help consolidate some of the areas covered in previous parts. As you find out more information throughout this part of your work you can add this to your time line. Materials: • Ruler • Pen • 5 metres of adding machine tape (or a roll of toilet paper or even a roll of wide ribbon) Procedure: 1 Calculate the scale you will use. For example: If the 5 metres (500 centimetres) of tape represents roughly 5000 million years, then calculate how many years 1 mm represents and use this as your scale. 5 m = 5000 million years _______ mm = 5000 million years 1 mm = _______________ years 2 Mark the eras listed below on the tape. Era 4 Time period (millions of years ago) Cenozoic 0–65 Mesozoic 65–250 Palaeozoic 250–542 Proterozoic 542–4700 (?) Planet Earth and its environment Gill Sans Bold Using the scale you have just devised, mark the geological eras across your tape at their boundaries as shown in the diagram below. adding machine tape era Cenozoic Mesozoic boundary You can use adding machine tape to produce your time line. 3 Using the scale you have created, measure and record the following on your geological time line. Event Age (millions of years ago) oldest known rocks 3800 stromatolites (formed by photosynthesising bacteria) 3450 last sedimentary deposits of uraninite 2300 rise of the redbed sedimentation 2000 last main sedimentary deposits of banded iron formations (BIF) from continual depositional sequence 1700 first eukaryote filamentous algae fossils 1500 primitive small shelled animals 550 the greatest loss of species in a mass extinction (96 % of all known species wiped out)–said by some to be the time the Earth almost died 250 rise of dinosaurs 200 first birds 150 extinction of 65% of species including the dinosaurs 65 first human–like primates (Homo habilis–Africa) 1.7 Part 6: Climatic variation 5 Conclusion: From the information above make a statement about the amount of free oxygen available at different times in the Earth’s history and the implications this would have on weathering, the composition of rocks (mineralogy) and the evolution of life. _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ _________________________________________________________ Quaternary temperature changes Temperature records in the distant past are less well known than more modern record. The further back in time the less reliable the precision of placement of the indicator of climate against a numerical timescale. For example the current Holocene epoch would be almost an undetectable blip on the geological record 50 million years ago despite its 10 000 year duration. The Quaternary refers to the latest period of geological time and extends from two million years ago to the present day. It occurs within the Cenozoic era. (Refer to your time line.) The Quaternary is characterised by an alternation of warm and cold climatic periods. These periods occur relatively regularly. We are currently in a warming phase or what is correctly known as an interglacial period, even though we have a substantial amount of land ice. Global temperatures during this period of climatic variation range between the present–day temperatures and 5 to 10∞C cooler. There is a large degree of uncertainty surrounding the reasons why these fluctuations occur. However, there is sufficient evidence to suggest that these fluctuations have occurred. 6 Planet Earth and its environment Gill Sans Bold The formation of the Quaternary ice was a relatively slow process. For ice to form and stabilise, the temperature of the ocean as a whole needs to decrease sufficiently to maintain ice at its surface. This cooling process takes a relatively large amount of time. However, for ice to melt, only the top layers need to be heated, and so the melting of ice occurs over a relatively short period of compared to its formation time. This has resulted in an asymmetrical or uneven pattern of cooling and heating, which is evident in the Quaternary. Apart from the past two million years (the Quaternary) scientists have compiled detailed evidence for climatic changes over the past sixty million years. Earlier in the Earth’s history major glaciations (large ice sheets) affected larger areas including land closer to the Equator, than did the Quaternary ice. Questions of how this more extensive ice formed, and how it eventually retreated, remain largely unanswered. Perhaps you have some thoughts on this matter. Part 6: Climatic variation 7 The 60 million year climate The Cretaceous period makes up the upper one third of the Mesozoic era. It expanded over a period of approximately 76 million years, beginning at approximately 141 million years ago and extending through until 65 million years ago. Almost since the close of the Cretaceous the Earth’s climate has been on a bit of a roller coaster but with a general temperature direction of down. That is not to say though that there has not been extended periods of warming. Climate variation The causes of temperature changes over extended periods are often confirmed by complex computer models with the data suggested by modelling confirmed by on the ground observations. If the data from the ground doesn’t confirm the computer model predictions it is necessary to reconfigure the computer model. The gathering of on the ground data is painstaking work. The precise timing and ordering of geologically historical events is often less precise than people would like to admit. The recent interglacial or warm period of about 10 000 years duration known as the Holocene would probably be an unnoticed blip on the geological record if it had occurred even 20 million years ago. For that reason to say that the Earth’s climate has been cooling for the past 60 million years is somewhat of a confusing statement. Distinct periods of time were in fact extended warming trend periods whereas other periods were of a cooling trend within the past 60 million years. Evidence for cooling There is some evidence of climate fluctuations trending toward a decrease on global average temperature over the past 60 million years though this fluctuation was by no means a linear decrease in temperature. One of the problems facing people who study climate over this interval is 8 Planet Earth and its environment Gill Sans Bold the direct lack of records. All the information must be accumulated by interpretation of data from indirect means. Many of the climate predictions for the past are based on computer modelling. The trend in the Earth’s climate appears to have been a long term decrease from a high temperature period at the Late Palaeocene thermal maximum (LPTM) about 55 million years ago until today. At the LPTM the temperature of the Earth’s surface was about 7° C on average higher than it is today. At this time a large mass extinction (much above average extinction rates) of animal and plant life also occurred. Climate changes either warmer or colder can result in mass extinctions of organisms. Estimates for the proportion of species that became extinct at the Paleocene/Eocene boundary are generally around the 55% mark. The cause of the LPTM is uncertain though there is one theory that suggests a rapid release of the gas methane from storage in deposits called methane clathrates, a type of methane iceblock that is stabilised by high pressures and low temperatures, may have been the cause. Methane clathrates exist at water depths between 300–500m and are extensive on continental shelves today. The sudden release of methane over a period of some hundreds of years from these large reservoirs of methane could have potentially altered climate and produced a warm period. Methane as a greenhouse enhancing gas is around 26 times more effective than CO2. The evidence for the decrease in global average temperatures throughout the 60 million years is varied and patchy. It is mostly based on the following: • Sediment changes. Sediments deposited in warm climates are different than they are in cold climates. A change in the sediments deposited at a certain latitude may therefore indicate a change in the temperature of the time of deposition of that sediment. The presence of certain types of sediments such as varved shales or tillites indicate glacial conditions. The presence of evaporates indicates warm conditions. The expansion and contraction of the continental shelf is represented in fossil bearing sediments that indicate sea–level rise and fall. Sea level rises in times of warming as ice–sheets melt and then falls as land ice–sheets form. Sediment changes in lakes represent the waxing and waning of lake levels and the fossils within the sediments indicate climate changes in the surrounding areas. • Isotopic ratios in sediments. Certain isotopes like those of oxygen preserved in calcium carbonate from shells of animals or in limestone can indicate the climate at the time of their deposition. • Fossil types found in the sediments. Organism types are different in warm climates to those in cold climates. You know today that the types of organisms living in the tropics are different and have Part 6: Climatic variation 9 different adaptations to those living in cooler climates. Similar differences existed in the past. • Ice cores. These can provide a relatively recent look at the fluctuations in temperature over the past 2 million years or shorter time frames. Ice is no use in times older than that because the ice sheets melt in times of periodic temperature rise. Once melted the information the ice contains about climate is lost. Ice cores are critical to modern climate studies because they actually contain samples of past atmospheres trapped in small bubbles. Scientists using precise equipment like mass spectrometers can analyse the composition of the small gas samples and get a picture of past atmospheres. The assumption is that the atmosphere was well mixed and the bubbles are representative of past atmospheres. Past climate The broad climate over the past 60 million years can be described as follows: 10 • 57 to 52 mya in the Eocene, the Earth was much warmer than it is today. Tropical conditions were experienced into the mid–latitudes and polar regions were temperate by today’s standard. The temperature gradient or difference between the Equator and the poles was less than it is today. The evidence for this warm period includes things such as the isotopic ratio of O18/O16 in carbonate shells of foraminifera, the fossils of trees in the Arctic and Antarctic where none grow today and reptile fossils at much higher latitudes than can be found today. If it gets too cold reptiles that are cold blooded cannot survive. • 52 to 36 mya in the Eocene was characterised by a global cooling trend that has been repeated twice since. During the interval from 52 to 36 mya, ice caps developed in East Antarctica, the water temperature at or near the surface dropped to between 5 and 8° C and the air temperature at mid latitudes fell significantly on the order of 10° C based on the vegetation types found as fossils at such latitudes. • 20 to 16 mya in the Miocene, was characterised by a warming interval when temperatures rose. • 16 to 6 mya in the Miocene was a second major cooling period that was more pronounced than the periods that occurred earlier. During that interval southeastern Greenland was completely covered with glaciers and the glaciation extended south from the North Pole into Scandinavia. Ice sheet formation in Antarctica accelerated. Planet Earth and its environment Gill Sans Bold • 5 to 3 mya in the Pliocene was a warming period and fossils on the land and in the oceans indicate that Earth was much warmer than it is today. Fossils suggest that warm–weather plants grew in Northern Europe, trees grew in Iceland, Greenland, and Canada as far north as 80 degrees North of the Equator and the European and North American continents were free of ice. • 3 mya to present in the Pliocene, Pleistocene and recent Holocene a cooling period developed. That cooling continues with minor fluctuations that are controlled by numerous factors including atmospheric composition and differences in solar behaviour. These shorter term deviations in the climate controlling conditions are superimposed on the longer term trend toward cooling. Why the 60 my cooling trend? The most expected answer to this question by people is that the global climate is controlled by the level of CO2 in the atmosphere. More CO2 means a warmer world doesn’t it? The truth of that statement is still not firmly established over the time frame of the past 60 million years though some scientist have argued strongly the link is there. The real problem is that the CO2 levels for the past 60 million years aren’t all that clear about a direct link between high atmospheric CO2 and high temperatures. The truth is that some evidence exists for elevated CO2 levels in the atmosphere during times of cooling. The picture long term over millions of years simply isn’t clear and the precision difficulties in matching data to exact ages doesn’t help the situation. What affects climate? The factors that could and probably do change the levels of temperature on the surface of the Earth, over the time frames that a 60 million year study can detect as trends, are: • The output of energy from the Sun. Evidence from astronomy suggests that the luminosity and therefore energy output from the Sun has increased over the past 60 million years. That should suggest a warming. Contrary to that is the cooling trend described above. There is some evidence that the low energy output periods of the Sun correlate with periods of cooling though this is open to interpretation. Another superimposed problem in describing whether of not the cooling effect over the past 60 million years has any relation to the energy output from the Sun is the issue of constancy Part 6: Climatic variation 11 of solar energy output. Studies to investigate whether it was constant are inconclusive at the present time. • Plate tectonic motions. These cause changes in the elevations and position of the continents. These processes are long term and therefore have the potential to affect climate long term. Plate motions lead to cycles of ocean basin growth and contraction and involve continental splitting, seafloor spreading, subduction, and plate collisions. Effects of plate tectonics on climate Through the course of the continuous plate tectonic cycle continents collide and split apart, mountains are uplifted and eroded, and ocean basins are born, grow and close again. Changes in the size, position and shape of landmasses over time can cause changes in factors such as the ocean circulation and weathering rates of rocks that potentially affect long term climate. Weathering rates at lower latitudes (tropics) can accelerate removing atmospheric CO2 while rapid seafloor spreading volcanism can cause release of vast amounts of CO2. The presence of a continental landmass at the poles means that the heat energy distribution to the poles by ocean currents is more limited. Changing topography may assist to explain long term cooling trends. The Himalayas, the greatest mountain chain on the continents were born almost at the same time as the long climatic cooling trend began. Mountains and high plateaus such as Tibet and western North America may have effected global temperature to some degree but the question is whether these changes in topography alone can explain the longevity of the cooling trend. They fail to suggest why climate reversal in the last 60 million years occurs periodically because the rate of mountain uplift seems to have been consistent. Plateau uplift can have a significant impact on climate due to factors such as the diversion of Northern Hemisphere westerly winds. Plateaus also increase the Earth’s albedo or ability to reflect radiation energy back into space as more land areas are covered in reflective snow at altitude. The ocean is critical in the redistribution of the solar energy from the Sun that is dominantly received at the Equator. This is accomplished by large ocean currents. As continents drift they may have opened or closed a passage for the flow of energy redistributing ocean currents. 12 Planet Earth and its environment Gill Sans Bold It is proposed that the cooling of Antarctica was at least in part due to the opening of the Southern Ocean when Australia and Antarctica separated and the resulting development of the circum–polar (around Antarctica) ocean current that prevents the redistribution of energy from the Equator to the Antarctic continent. This cooling has caused the growth of ice sheets and sea ice, and increased the temperature gradient between the Equator and the South Pole. The separation of Australia from Antarctica to form the Southern Ocean began somewhere around 55 mya and was finally achieved about 38 mya when the last bonds between Tasmania and Antarctica were finally broken. After that cooling really began. Atmospheric greenhouse gases Changes in the concentration of carbon dioxide in the atmosphere are the immediate thought of most people trying to explain the overall pattern of climatic change. This is partly due too the extensive publicity of recent times. The question is though can this be justified. It may surprise you to find out that opinion on the long term effect of elevated or depressed CO2 levels in the atmosphere is not as clearly defined as you might expect. Carbon dioxide does have the capacity to influence the mean global temperature through the enhanced greenhouse effect. There would be few scientists today that would question the validity of that statement. The average surface temperature of the Earth is 15° C. Without the enhanced greenhouse effect it would be considerably lower, in fact below zero. But it must be remembered that CO2 is only one of a host of greenhouse gases in the atmosphere. Water vapor, carbon dioxide, methane, and other minor gases in the Earth's atmosphere are also greenhouse gases. The potential role of methane in producing the extensive warm period around 55 mya has already been mentioned. Methane when it reacts with oxygen produces CO2. The effect of methane has apparently been dramatic. Greenhouse gases can therefore cause dramatic changes in Earth history and climate. Part 6: Climatic variation 13 A look at CO2 The average amount of carbon dioxide in the atmosphere is affected by four factors that increase or decrease the amount of atmospheric CO2 .These factors, called carbon fluxes are: • metamorphic degassing that releases CO2 trapped in minerals subducted or buried and subjected to increased heat and pressure. This degassing may occur at mid–ocean ridges as part of the seafloor spreading regime though this cycle may be on a billion year plus timeframe. • weathering of organic carbon bearing rocks such as shales and limestones which release CO2 into the atmosphere that was previously stored • weathering of silicate rocks that absorbs CO2, • burial of organic carbon that returns CO2 to storage as organic carbon in shales or limestones for a long term. The deposition of the Tertiary brown coals of the world may have been a significant contributor to the reduction in global CO2. The 45 million year old Loy Yang brown coal seam in Victoria’s La Trobe Valley for example is extensive and up to 250 m thick. Extensive brown coals were deposited in South Australia, New Zealand and North America and South America during the Tertiary, many coinciding with, or contributing to, cooling events. Age of Victorian Tertiary coals The Yallourn seam is approximately 7 million years old The Morwell 1 seam is approximately 10 million years old The Morwell 2 seam is approximately 25 million years old The Traralgon South/Loy Yang seam is approximately 45 million years old Plate motions affect carbon fluxes tending to elevate or lower the atmospheric CO2 level. For example it has been suggested that the LPTM 55 million years ago, was caused by elevated atmospheric carbon dioxide resulting from the methane release and that the decrease in elevated atmospheric carbon dioxide from that time has been a major cause of the cooling trend that has existed since over the past 52 million years. 14 Planet Earth and its environment Gill Sans Bold One mechanism proposed as a cause of this decrease in carbon dioxide is that mountain uplift such as the Himalayas lead to increased weathering of fresh silicate. Refer back to your time line that you constructed earlier in this part. Mark the Cretaceous period and the other times mentioned in the passages above on your geological time line. Work out a scheme to mark in times of warming and cooling over the past 60 million years. Evidence for the temperature from shortly after the end of the Cretaceous (65 million years ago) includes the results of studies of: • oxygen isotopes • ice core records • sea level changes • marine sediments • lake sediments. Oxygen isotopes What is an isotope? An isotope is a different type of atom of the one element. That means that different atoms of the same element have the same number of positively charged protons in the nucleus giving them the same atomic number on the periodic table . Both atoms also have the same number of negatively charged electrons orbiting around the nucleus giving them the same degree of reactivity. However, the isotopes differ in the number of neutrons they contain in the nucleus. Neutrons do not have any charge and really only add mass and therefore weight to the atom. They do affect the ratio of atoms of a particular type which react and participate in chemical reactions. Molecules that are made up of isotopes that are heavier tend to be less likely to be evaporated. That means that in times of low temperature the more likely water molecules to evaporate are rich in O16. That means that the remaining water is enriched in O18. The next diagram shows how this isotope separation occurs as you boil water. Part 6: Climatic variation 15 H 16 2 O 16 O H2 H 1 2 6 O H 16 2 O H 1 2 6 O H216O H216O H216O H218O 16 18 H218O H2 O H2 O 16O H 18 2 H2 O H218O H216O You may find it useful to refer to the Resource book or a periodic table to refresh your memory of some basic chemistry. You may recall the following from some of your studies of science in previous years: atomic number = the number of protons atomic mass = the number of protons + the number of neutrons The following diagram represents the oxygen–16 isotope. e– e– 8 protons 8 electrons e– e– p+ + n p n n n p+ p+ n p+ n p+ p+ n p+ e– n e– nucleus e– 8 neutrons e– 16 Planet Earth and its environment Gill Sans Bold Answer the following questions using the information above. 1 a) What is the atomic number of oxygen–16? __________________________________________________ b) How did you obtain this answer? _________________________________________________ _________________________________________________ 2 a) What is the atomic mass of oxygen–16? _________________________________________________ b) How did you obtain this answer? _________________________________________________ _________________________________________________ Oxygen isotopes are used to determine past temperature conditions. The ratio of oxygen–16 (O16) isotope to oxygen–18 (O18) is used to provide a sort of past historical thermometer. 3 By referring to the information given above draw an atomic diagram of the oxygen–18 isotope. Refer to the atomic diagram of the oxygen–16 isotope above. Check your answers. Part 6: Climatic variation 17 Using the evidence of isotopes How do scientists use isotopes in determining past climatic conditions? Oxygen isotopes are locked up in the calcium carbonate (CaCO3) of shells in microfossils. Temperature of the environment can be determined by determining the isotope ratio O16/O18 that is locked up in the shells. Oxygen–16 (O16) has been found in a higher ratio in the carbonate shells of microfossils that existed in warmer environments, whereas oxygen–18 (O18) has been found in a higher ratio in the shells of microfossils that were thought to exist during much colder conditions. The reason for these differences is discussed below. If latitude data is known this can indicate an ice age for shallow water fossils. The microfossils that have proven to be most useful in this type of study are the bottom dwelling foraminiferas. Foraminiferas. (Photo credit: NASA) The photograph above shows the particular type of foraminiferas commonly though not exclusively, used to determine the temperature of the past. These were photographed using a scanning electron microscope. This photograph is magnified approximately 120 times the original size. The oxygen isotope O16/O18 can be measured using a special piece of equipment called a mass spectrometer. During an ice age, the seawater is heavier due to an increased evaporation of water enriched in oxygen–16 (O16) that ends up being precipitated and can end up as long term ice sheets, such as the ones in Greenland and Antarctica. Therefore, the oxygen which is absorbed in the calcium carbonate (CaCO3) of these ocean dwelling foraminifera will be the heavier oxygen–18 (O18) because the ocean waters are enriched in the heavier isotope and the composition of the water affects the oxygen isotope ratio of the shells of the animals that live in it. 18 Planet Earth and its environment Gill Sans Bold precipitation (O16 enriched H2O) evaporation (O16 enriched H2O) ice sheet snow and ice (O16 enriched H2O) ocean (O18 enriched H2O) land The different concentrations of oxygen–16 and oxygen–18 in different water bodies. Note that the ocean waters are relatively well mixed on a time frame of about 4000 years and certainly to depths of hundreds of metres in a decade or so. By mapping the relative abundance of both the O18 rich and the O18 depleted foraminifera through time, a good picture can be obtained of the temperature conditions under which these organisms existed. The difficulty is in determining the precise age of the foraminifera. In this activity you will be using the data gathered from oxygen isotopes to analyse variations in global temperatures over the last sixty million years. Method: The following data has been collected from oxygen isotopic data taken from the shells of foraminifers. 1 Graph the data shown in the table below. (Graph paper can be found in the Appendix.) 2 Ensure that you: • use a new page and turn your page on its side (landscape) • place the Years before present data along the horizontal axis • place Temperature along the vertical axis • include the correct units. Part 6: Climatic variation 19 Oxygen isotropic data from foraminifers 20 Average global water temperature (°C) Years before present (x1000) 18.0 62 400 19.5 62 000 15.5 58 000 17.5 57 500 15.0 57 200 12.5 54 500 13.5 52 000 12.5 50 500 13.5 49 500 11.5 46 800 11.0 44 200 10.5 41 500 6.8 40 800 7.0 36 400 8.0 35 000 6.9 34 000 8.0 32 500 6.8 31 000 7.0 28 600 Planet Earth and its environment Gill Sans Bold Average global water temperature (°C) Years before present (x1000) 6.8 24 000 9.0 19 000 7.5 15 600 9.0 13 000 5.5 10 500 3.5 7 500 6.0 6 500 3.5 2 700 0.5 2 500 3.8 200 1.0 100 Conclusion: 1 Make a statement, based on your graph, on the overall trend of the temperature variations. _____________________________________________________ _____________________________________________________ _____________________________________________________ 2 Do you think this trend will continue? What information do you base the answer to this question on? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ Part 6: Climatic variation 21 Ice core records Sensitive records about past climatic conditions can be obtained from ice cores that have been drilled to depths of up to 2 km. Cores have been taken from ice sheets in the Antarctic, Canadian Arctic, Greenland and various sites in Peru and Tibet. The deeper the ice is, within an ice core, the further back in time scientists can analyse. Think about when your desk at home becomes very messy. The most recent pieces of paper and books that you were working on would be closest to the top. The books and notes that you first began using would be on the bottom. Similarly, the oldest precipitation would be present as ice at the bottom of the ice core sample and the more recent ice accumulations would be nearer to the top and closer to the surface. Often two metres of ice represents about 100 years although it can represent a longer or shorter time period. Ice cores also record the relative abundance of oxygen isotopes. As discussed above, water containing oxygen–18 is more inclined to exist as a liquid and is less likely to be evaporated off as water vapour, than water containing oxygen–16. The warmer the climate the greater proportion there will be of water vapour containing oxygen–18 in the atmosphere. Under cooler conditions, water containing oxygen–18 will tend to remain in the liquid state. The clouds that carry these isotopes as water vapour are pushed towards the poles, where precipitation results in them being stored as ice. Which is the heaviest isotope, oxygen–16 (O16) or oxygen–18 (O18)? _________________________________________________________ Check your answer. Taking ice core samples, therefore, allows scientists to analyse the different isotopic ratios of oxygen and then draw conclusions about the temperature of their environment at the time they were deposited. These ice cores are so precise in their layering, that they can indicate temperature variations over centuries and even decades. The ice cores also preserve and record carbon dioxide levels in the atmosphere at the time of freezing. Carbon dioxide gas is trapped in air bubbles in the ice during deposition whenever the temperatures fall low enough for ice to form and accumulate. Why do you think it becomes increasingly difficult to analyse carbon dioxide bubbles as the depth of the ice samples increase? _________________________________________________________ Check your answer. 22 Planet Earth and its environment Gill Sans Bold Sample sites have to be selected carefully as the weight of overlying ice can sometimes squash these air bubbles to the point where they cannot be sampled. Dust is also preserved, indicating the degree of dryness for particular time periods. The drier the environment the more dust there will be in the atmosphere. This dust can travel long distances eg dust from central Australia is found in the ice of glaciers in the mountains of New Zealand. Other information can also be gathered from ice cores, such as: sea salts, pollen, volcanic debris, cosmic particles (particles from space) and in more recent times, isotopes from nuclear testing, can also be obtained from ice cores. Where these events are a unique time marker they provide a datum or marker level in the core. Sea level changes During the last two million years large quantities of ice have accumulated on the Earth’s surface during cooler periods. Most of the water that precipitated as snow evaporated from the oceans. The more water that is locked up in ice, the less run–off from rivers and the less water available to replenish the oceans. The result is a drop in the level of the oceans. There have been four broad time intervals during the past two million years, each is considered to be an ‘ice age’. During these glacial periods the Earth’s ocean levels dropped considerably, and during the periods in between glacial periods, referred to as interglacial periods, the ice melted and the ocean levels once again rose. The following activity shows the sea level changes over the past twenty thousand years. This data was gathered from studying the distribution of a particular species of coral that only exists within two metres of the ocean surface and therefore is a good indicator of sea level. 1 Graph the following data and answer the questions that follow. The graph paper is in the Appendix at the back of this part. 2 Place Sea level (m) up along the vertical axis with 0 metres (present level) at the top and–140 metres (below present sea level) at the base. 3 Place Age (x 1000 yr) along the horizontal axis, beginning with 0 (present day) on the left–hand side ranging to 20 on the right–hand side. Part 6: Climatic variation 23 4 Sea level (metres below present) Age (x1000 years before present) 0 0 –20 8 –25 9 –30 10 –42 11.5 –60 12 –66 13 –72 14 –92 14.5 –99 15 –110 18 –115 19 Comment on the general trend shown by your graph. ______________________________________________________ ______________________________________________________ ______________________________________________________ 5 Are the results you obtained in the previous activity on temperature variation over time related in any way to the results you obtained in this activity? Explain. ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ ______________________________________________________ 24 Planet Earth and its environment Gill Sans Bold The total volume of ice on Earth today is approximately 25 million cubic kilometres. The volume during the height of the ice ages has been estimated to be approximately 70 million cubic kilometres. This would have resulted in the oceans being lowered by approximately 130 m from its present day level. 1 What do you think would be the implications of ocean waters becoming warmer due to increased surface temperatures? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ 2 If the warming trend over the past century were to continue, sea level would increase by an estimated 15 cm by the year 2100 due to the increase in global temperature. In the last part of your work you were asked to consider the effects industrialisation has had on the atmosphere. How does this information relate to changes in sea levels? _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ 3 Change in the sea level and the causes and effects of such change is controversial and a complex issue. Increased temperature at the surface of the sea means an increase in evaporation over the oceans, leading to an increase in precipitation. Read again carefully the last paragraph, immediately above this exercise, then answer the following questions. a) Present an explanation identifying how an increase in global temperature could result in an increase in sea level. _________________________________________________ _________________________________________________ _________________________________________________ _________________________________________________ Part 6: Climatic variation 25 b) Now present an explanation describing how an increase in global temperature may result in a decrease in sea level. You may find this question challenging. __________________________________________________ __________________________________________________ __________________________________________________ __________________________________________________ __________________________________________________ Check your answers. Marine sediments Marine sediments (sediments deposited in oceans) collected from ocean floors can be obtained from deep sea drilling programs. From these sediments, microfossils of minute organisms such as coccoliths and foraminifera can be extracted. The type of fossils retrieved indicates the type of environment from which it came. If the conditions at the surface (when the organism was living) were tropical then only a tropical species of this organism would exist. The same would apply if the surface temperatures were temperate. Then a different species of the micro organism would exist. By obtaining a date on the sediments and matching the type of organism found in particular sediments, a history of temperature variations can be created. Turn to the end of this part and complete the exercise. 26 Planet Earth and its environment Gill Sans Bold Lake sediments Climatic conditions can be reflected in the different mineralogy and chemistry of the sediment deposited in the lakes. In layers that contain fossils, differences in animal/plant compositions can indicate different environments and therefore temperatures in which they were deposited. Salts and evaporites give an indication of warmer temperatures and lower lake levels. These deposits can be observed today in many places throughout the northern part of South Australia. Fossils of particular animals and plants surrounding lakes can also give a good indication of the type of temperature and climatic conditions that existed when these organisms were alive. Geochemical analysis (the study of chemistry in rocks and fossils) of microfossil remains, similar to those used on the foraminiferas in determining oceanic sequences (outlined above), can be used in the analysis of lake sediments. Different ratios of oxygen isotopes (O16/O18) used in the construction of their calcareous shells, give an indication of the temperature conditions at the lake’s surface at the time of their formation. This process is very similar to the process used in oceans, however due to the absence of foraminifera in lakes, scientists have had to analyse a different type of microorganism–the lake dwelling ostracod. (Refer to your notes above on oxygen isotopes.) Part 6: Climatic variation 27 28 Planet Earth and its environment Gill Sans Bold Appendix Graph: Oxygen isotopes Part 6: Climatic variation 29 30 Planet Earth and its environment Gill Sans Bold Graph: Sea level changes Part 6: Climatic variation 31 32 Planet Earth and its environment Gill Sans Bold Suggested answers Oxygen isotopes 1 a) The atomic number of oxygen is eight. b) The atomic number is equivalent to the number of protons in the nucleus. 2 a) The atomic mass is equal to 16. b) The atomic mass is calculated by adding the number of protons and neutrons in the nucleus of an atom. e– e– 8 protons 8 electrons e– + n p n + p+ n p n n n + + n p p p+ n n p+ e– p+ n e– e– nucleus e– 10 neutrons e– Ice core records Oxygen–18, since it has two more neutrons in the nucleus than oxygen–16. Sample sites have to be selected carefully as the weight of overlying ice can sometimes squash these air bubbles to the point where they cannot be sampled. Part 6: Climatic variation 33 Sea level changes 1 If the water is warmed, as has been the case over the past century, the sea level will rise due to an expansion of the water. Other contributing factors would be the shrinking of ice caps, retreating of glaciers and the melting of ice sheets. 2 Industrialisation since the acceleration of the industrial revolution at the end of the nineteenth century, has been responsible for the release of massive amounts of carbon dioxide into the atmosphere. This is the result of the burning of fossil fuels. This increase in carbon dioxide enhances the greenhouse effect resulting in an increase in surface temperature. This increased surface temperature will in turn heat the oceans. 3 a) If temperatures increase then ice sheets, glaciers and even the polar caps may either be reduced or if the temperature is high enough may even disappear. The water contained in bodies of ice will then run into the oceans via rivers and streams, raising the sea level. b) If temperatures increase then so will the amount of evaporation. Temperatures nearer the equator are the warmest therefore evaporation in these lower latitudes will be the greatest. The atmosphere will precipitate this water in the colder regions near the poles on land where the water will remain locked up as ice. As a result the oceans will experience a subsequent drop in sea level, whilst the land ice caps will increase in volume. This would have no effect on ocean ice in a similar way to ice melting in your drink doesn’t cause your drink to flow over. If all the sea ice in the world were to melt then the effect on sea level would be negligible. 34 Planet Earth and its environment Gill Sans Bold Exercise – Part 6 Name: _________________________________ Identifying past climatic conditions Read the following information and then answer the questions that follow. The following foraminifera (microfossils) were obtained from the same coastal area on the east coast of Australia at three different sites. • Site A is 2 metres above the present sea level. • Site B is 10 metres above the present sea level. • Site C is 18 metres above the present sea level. Five different types of foraminifera fossils were recovered from the three sites. The distribution and abundance of these fossils are shown below. Foram type Site A Site B Site C Foram 1 10% 0% 0% Foram 2 20% 0% 0% Foram 3 40% 30% 0% Foram 4 15% 50% 30% Foram 5 15% 20% 70% These foraminiferas lived in a shallow marine environment, therefore they were deposited when the sea level was higher than present. An explanation could be that over time either the sea level has changed due to a change in the climate. Or, the land on the coast where these fossils were recovered has been uplifted. Part 6: Climatic variation 35 The following diagram shows the relative abundance of the foraminifera fossils plotted against sea water temperatures. 30∞C Sea water temperature 25∞C 20∞C 15∞C 10∞C 5∞C 0∞C Foram 1 Foram 2 Foram 3 Foram 4 Foram 5 Relative abundance of foraminifera. 1 At approximately what temperature was the sea when foraminiferas were deposited at each of the three sites? An answer is required for each of the three sites. Site A Site B Site C temperature 2 Comment on the relationship between temperature and the present day height above sea level of the three sites. ______________________________________________________ ______________________________________________________ 3 What extra evidence would you look for to support that sea level changes are linked to changes in the temperature of the water? ______________________________________________________ ______________________________________________________ 4 If an ice age occurred and the temperature of the waters around this location were between 8–12∞, what type and proportion of foraminifera fossils would be deposited. Comment on the resultant sea level. ______________________________________________________ ______________________________________________________ 36 Planet Earth and its environment Student evaluation of the module Name: _______________________ Location: ______________________ We need your input! Can you please complete this short evaluation to provide us with information about this module. This information will help us to improve the design of these materials for future publications. 1 Did you find the information in the module clear easy to understand? _____________________________________________________ 2 What did you most like learning about? Why? _____________________________________________________ _____________________________________________________ 3 Which sort of learning activity did you enjoy the most? Why? _____________________________________________________ _____________________________________________________ 4 Did you complete the module within 30 hours? (Please indicate the approximate length of time spent on the module.) _____________________________________________________ _____________________________________________________ 5 Do you have access to the appropriate resources? eg a computer, the internet, scientific equipment, chemicals, people that can provide information and help with understanding science. _____________________________________________________ _____________________________________________________ _____________________________________________________ Please return this information to your teacher, who will pass it along to the materials developers at OTEN–DE. EESPrelim 43177 Learning Materials Production Open Training and Education Network – Distance Education NSW Department of Education and Training
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