WileyPLUS Assignment 5 is available Chapters 28, 29, 30 Due Friday, April 9 at 11 pm Friday, April 9 Review - send questions! PHYS 1030 Final Exam Friday, April 23, 1:30-4:30 pm Frank Kennedy Brown Gym, 30 questions, the whole course, formula sheet provided Wednesday, April 7, 2010 29 β– Decay Energy released = [mX - mY] x 931.5 MeV Atomic masses β+ Decay Energy released = [mX - (mY + 2me)] x 931.5 MeV Atomic masses Wednesday, April 7, 2010 30 Prob. 31.31/27: Find the energy released when !+ decay converts 22 Na (Z = 11, atomic mass = 21.994434 u). Notice that the atomic mass for 22Na includes the mass of 11 electrons, whereas the atomic mass for 22Ne (Z = 10, atomic mass = 21.991383 u) includes the mass of only 10 electrons. Using tabulated atomic masses, the energy released in the decay is, " #E = [mNa - (mNe + 2me)] x 931.5 MeV 1.82 MeV Wednesday, April 7, 2010 31 Beta-decay – a problem Beta-decay X→Y+e Y (daughter) Expected energy of the e+ X (parent, at rest) e– or e+ http://hyperphysics.phy-astr.gsu.edu/hbase/nuclear/beta.html Kinematics: if energy and momentum are conserved, the electron (e– or e+) should have a well-determined kinetic energy following the beta-decay. But, the electron does not have a well-determined energy, as seen above. Is energy conserved?! Wednesday, April 7, 2010 Yes, energy is conserved... 32 The Neutrino A third particle, a neutrino, is also emitted in the decay, so that the released energy is shared between three particles instead of two: 64 29 Cu → 64 28 Ni + e+ + ν Expected energy of the e+ The neutrino is very difficult to detect. Wednesday, April 7, 2010 33 A neutrino detector in Japan Wednesday, April 7, 2010 34 Neutrino detector in Japan - X-Files version Wednesday, April 7, 2010 35 Gamma (γ) Decay A ∗ ZX → A ZX +! Excited state of the nucleus Nuclear Energy X* Gamma rays are produced in the decay (de-excitation) of a nuclear state. $ ray photon X This is similar to the production of a photon by an atom, except that the energy levels are associated with the nucleus itself, not with electrons in the atom. Gamma rays are generally of higher energy and are even more penetrating than x-rays. Wednesday, April 7, 2010 36 Gamma Knife – to zap a tumour 60 Co gamma ray source: 60 27 Co → 60 ∗ − ¯ 28 Ni + e + ! 60 ∗ 28 Ni → 60 28 Ni + ! Tumour (� 1.2 MeV) Gamma rays from 60Co sources are channeled through collimators in a metal helmet. Gamma rays are concentrated at the site of the tumour, to selectively destroy the malignant tissue. Half of the 60Co decays away in 5.3 years, so has to be replaced... Wednesday, April 7, 2010 37 Winnipeg Free Press, April 4, 2004 Wednesday, April 7, 2010 38 Winnipeg Free Press, March 19, 2008 Wednesday, April 7, 2010 39 N0 Radioactive Decay Start with N0 unstable nuclei Observe how many survive to time t Half-life, T1/2: the time for half of the nuclei to decay. After each succeeding halflife, half of the remaining unstable nuclei remain... N0/2 N0/4 N0/8 Wednesday, April 7, 2010 40 Radioactive Decay � � 1 After time T1/2, N0 are left 2 � �� � � �2 1 1 1 After time 2T1/2, N0 = N0 are left 2 2 2 � � � �2 � �3 1 1 1 After time 3T1/2, N0 = N0 are left 2 2 2 � �n 1 After time nT1/2, N0 are left 2 � �n 1 t So, N(t) = N0 = number of half-lives n= 2 T1/2 Wednesday, April 7, 2010 41 Radioactive Decay � �n 1 So, N(t) = N0 2 n= t T1/2 = number of half-lives This is the same as an exponential decay: % = “decay constant” Natural log, loge Take logs: −n ln 2 = −!t So, ! = and, n = ln 2 0.693 = T1/2 T1/2 != Wednesday, April 7, 2010 t T1/2 1 0.693 = “mean life” T1/2 42 Radioactive decay � �n 1 N(t) = N0 = N0e−!t 2 T1/2 ln 2 0.693 = = λ λ Some Half Lives 214Po 0.164 ms Decay Mode &, $ 89Kr 3.16 min !–, $ 222Rn 3.83 days &, $ 60Co 5.271 y !–, $ 90Sr 29.1 y !– 226Ra 1600 y &, $ 14C 5730 y !– 238U 4.47!109 y 115In 4.41!1014 y!!! Isotope % = “decay constant” n = t/T1/2 Wednesday, April 7, 2010 Half Life &, $ !– Radioactive Decay, Activity 43 Radioactive Decay, Activity Activity, A = number of decays per second = –ΔN/Δt, N = no. of nuclei left The rate of decay is proportional to the number of radioactive nuclei present. A=− !N = "N(t) = "N0e−"t !t Calculus initial activity, A0 = %N0 dN d = − N0e−!t dt dt = !N0e−!t A=− Units: Becquerel (Bq): 1 Bq = 1 decay per second Curie (Ci, old unit): 1 Ci = 3.7 x 1010 Bq = activity of 1 g of pure radium Short half life means large decay constant and large activity (% = 0.693/T1/2). Wednesday, April 7, 2010 44 Radioactive Decay The number of radioactive nuclei left after time t is: � �n 1 N(t) = N0 2 n= t T1/2 = number of half-lives or N(t) = N0e−!t , ! = decay constant != 0.693 T1/2 Activity, A(t) = %N(t) Wednesday, April 7, 2010 45 238 U A Radioactive Decay Series A 238 92 U 222 → 234 90 Th Rn → 234 4 90 Th + 2 He 234 91 Pa + e− + !¯ and so on... ...ending at 206 82 Pb Radon, of basement fame Other decay series: 235 232 Z Wednesday, April 7, 2010 U→ Th → 207 Pb 208 Pb All formed in a supernova explosion about 4.5 billion years ago. 46 Radon in the Basement 222 Rn – produced in the decay chain that starts with 238U. 222 Rn half life is only 3.83 days, but it is generated continually by the decay of longer-lived nuclei. Suppose 3!107 radon nuclei are trapped in a basement when the walls are sealed so no more can enter. How many are left after 31 days? � �n 1 t 31 N = N0 , n= = = 8.094 2 T1/2 3.83 � �8.094 1 N = N0 = 0.00366 N0 = 1.1 × 105 2 The initial activity of the radon is 0.693 N0 0.693 × 3 × 107 A0 = !N0 = = = 62.8 Bq T1/2 3.83 × 24 × 3600 s Wednesday, April 7, 2010 47 Prob. 31.35/32: Strontium 90Sr has a half-life of 29.1 years. It is chemically similar to calcium, enters the body through the food chain and collects in the bones. Consequently, 90Sr is a particularly serious health hazard. How long will it take for 99.99% of the 90Sr released in a nuclear reactor accident to disappear? 387 years Wednesday, April 7, 2010 48 Radioactive Dating The best known is radiocarbon dating, based on the decay of 14C. “Carbon-based life forms” take up carbon in food or as CO2 (plants, trees, in photosynthesis). One atom in 8.3!1011 of carbon has a 14C nucleus, the rest are 12C, 13C (activity 0.232 Bq per gram of naturally occurring C). 14 C has a half-life of 5730 years, 12 C, 13C are stable. When the organism dies, the uptake of carbon ceases, and the amount of 14C present decreases, halving every 5730 years. Measure how much 14C is left work out how long since organism died. Wednesday, April 7, 2010 49 31.58/40: Material found with a mummy in the arid highlands of southern Peru has a 14C activity per gram of carbon that is 78.5% of the activity present initially. How long ago did this individual die? (half life of 14C is 5730 y). 2000 years ago Wednesday, April 7, 2010 50 31.46/52: An archeological specimen containing 9.2 g of carbon has an activity of 1.6 Bq. How old is the specimen? Present-day activity is 0.232 Bq per gram of carbon. 2370 years Wednesday, April 7, 2010 51 Prob. 31.47/41: The practical limit for radiocarbon dating is about 41,000 years. What fraction of the 14C is left after this time? (halflife = 5730 years) The number of half-lives that have elapsed in 41,000 years is: n = 41,000/5,730 = 7.16 and so the fraction of 14C left after 41,000 years is N/N0 = (1/2)7.16 = 0.007 so, only 0.7% of the 14C is left. Wednesday, April 7, 2010 52 Radioactive Dating The amount of 14C left can be measured by: • Counting the rate of decay (activity) of 14C, activity being proportional to the number of radioactive nuclei – the accuracy of the age measurement depends on the size of the sample and on for how long you are willing to count. The more decays seen, the more accurate the measurement. • Counting the number of 14C nuclei directly by vaporizing the sample and counting the 14C nuclei in a mass spectrometer. You are no longer waiting for nuclei to decay and can get much higher precision on the age. Wednesday, April 7, 2010 53 Radioactive dating – origin of the The 14C comes from cosmic rays that interact with atmosphere: n+ 14 7N → 14 6C 14 14 C N in the upper + p Stable, the usual form of N Number of nucleons: 1 + 14 = 14 + 1 Charge: " 0+7=6+1 The 14C combines with O2 to form 14CO2 which mixes with normal CO2 in a stable proportion (1 in 8.3!1011). 14 C decays back to 14N with a half-live of 5730 years. Wednesday, April 7, 2010 14 6C → 14 7N + e− + !¯ 54 Radioactive Dating on Geological Timescales 238 U 206 Pb in decay series and T1/2 = 4.5 ! 109 years for 238U. Number of &-particles produced in the decay series is (238 – 206)/4 = 8. If the decays occur in rock, the 4He can be trapped. Measure how much 4 He is present in the rock. Each U decay should generate a total of 8 &particles. Then, the original number of 238U nuclei in the rock when it was formed is: N! N(t) = number of U nuclei present now 8 Now � �n Now 1 t Then, N(t) = N0 , n= → t 2 T1/2 N0 = N(t) + Oldest rocks, t = 3.7!109 y; meteorites, moon rocks, t = 4.5!109 y. + other methods based on ratios of isotopes. Wednesday, April 7, 2010 55 A Geiger Counter Ionizing radiation (high energy charged particle, gamma ray) enters the counter: • ionizes a gas atom • freed electron is accelerated by the electric field near the wire electrode, collides with and ionizes another gas atom • ionization of atoms continues, generating an avalanche of charge • pulse of charge produces a click in a loudspeaker. Geiger counter does not discriminate between types of ionizing radiation or its energy. Wednesday, April 7, 2010 56 A Scintillation Counter Ionizing radiation excites molecules of the scintillating material (eg CsI, NaI, plastic scintillator). • The amount of excitation is proportional to the energy deposited by the radiation. • Flashes of light are emitted when the molecules return to their ground state. • The light is detected via the photoelectrons it liberates from a photocathode, one photoelectron per photon. • The current of photoelectrons is amplified by accelerating the electrons and making them strike surfaces from which they release more electrons. Wednesday, April 7, 2010 57 Nuclei • Made up of nucleons (neutrons + protons), and held together by the strong nuclear force, which is of short range. • Radius r = r0A1/3 , r0 = 1.2!10-15 m. Constant density. • Binding energy, B = energy to separate neutral atom into neutrons and hydrogen atoms. B = Δm c2, Δm = mass defect. • Unstable nuclei decay to objects of lower total mass, converting the difference in mass to energy: " &-decay: " !-decay: " $-decay: Wednesday, April 7, 2010 A A−4 4 Z X → Z−2 Y + 2He + energy A A − ¯ + energy Z X → Z+1 Y + e + ! A A + Z X → Z−1 Y + e + ! + energy A ∗ A Z X → Z X + ! + energy 58 Radioactive Decay • Half life, T1/2 = time for half of the radioactive nuclei to decay. • Number of nuclei left after time t: � �n 1 N(t) = N0 = N0e−!t 2 n = number of half-lives = t T1/2 0.693 ! = decay constant = T1/2 • Activity = rate of decay, A = –#N/#t A = ! N(t) " 1 Bq = 1 decay/second Wednesday, April 7, 2010 59
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