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A piece of iron, mass about 3 g, was placed in a glass beaker. 50 cm3 of
0.5 mol dm ²3 aqueous copper sulphate solution was measured using a
measuring cylinder and added to the beaker. The temperature of the
mixture was measured immediately before the addition and every minute
afterwards until no further change took place.
Fe + CuSO4
Timing
before
addition
Temperature/°C
22
FeSO 4 + Cu
1 min
2 mins
3 mins
4 mins
5 mins
27
29
26
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Alcohol = ethanol, C 2H5OH
Molar Mass (C2H5OH) = 46.0 g mol ±1
Volume of water in beaker = 200 cm 3
Ú mass of water in beaker = 200 g
Weighings
Spirit lamp + ethanol before combustion =
198.76 g
Spirit lamp + ethanol after combustion = 197.68
g
Temperatures
Water before heating = 19.5 C
Water after heating = 38.1 C
Specific heat capacity of water = 4.18 J g ±1 C±1
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My calculated value of the enthalpy of combustion was
numerically much less than the data
book value. The
reasons for my low value include:
1
heat losses to the surrounding air;
2
when I re-checked the mass of the spirit lamp and
ethanol after combustion, I noticed that it had lost
mass even when it was not being used;
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