A foldable activity to help students learn historical development of the periodic table 1. 2. 3. 4. 5. 6. Copies of each page should be made per student Each of the boxes below should be cut out Each of the two circles should be cut out and cut in half Fold each half in half to create four quarter circle “flaps” The front of flap should be the year or the span of years The boxes below will be glued into the inside appropriately dated quadrant EXAMPLE Completed and flaps closed Complete with one flap open Antoine Lavoiser – Listed the 23 known elements Relationships between atomic mass and elemental properties started being recognized Mendeleev gets credit because he published and explain it first More accurate methods of determining atomic mass were developed Boxes are arranged in increases atomic number to create columns (groups) and rows (periods) Non-metals are on the upper right side (above the stairstep) 1869-1913 Electricity was used to separate more compounds to elements John Newlands first noticed repeating patterns in elemental properties every eight elements when in rows of eight Mendeleev organized elements by increasing atomic mass every eight element; this stacked elements with similar properties into groups Spectrometers were developed and used to identify elements By 1870s there were approximately 70 known elements In 1860 chemist began using atomic masses to organize elements Developed the Law of Octaves Not accepted at first because of reference to music Meyer and Mendeleev both recognized a connection between atomic mass and elemental properties Blanks were left in the table where undiscovered should be located Predicted properties of undiscovered elements Some elements were out of order when arranged by mass Moseley corrected Mendeleev’s table Moseley arranged elements by increasing number of protons Table consist of boxes Boxes contain atomic mass, atomic number, symbol, and element name Total of seven periods Divided into representative and transition elements Three main types of elements: metals, non-metals, and metalloids Most of the elements are metals (largest left side portion) Modern 1790s- mid 1800s 1864 Metalloids are found around the stair-step line These are also cut and placed on the front of the appropriate quadrant with the dates The Beginnings of the Periodic Table Before written history, people were aware of some of the elements in the periodic table. Elements such as gold (Au), silver (Ag), copper (Cu), lead (Pb), tin (Sn), and mercury (Hg). It wasn't until 1649, however, until the first element was discovered through scientific inquiry by Hennig Brand . That element was phosphorous (P). By 1869, 63 elements had been discovered. Creating Some Early Blocks for the Periodic Table Between 1817-1829, Johann Dobereiner began to group elements with similar properties in to groups of three or triads. This began in 1817 when he noticed that the atomic weights of strontium, Sr, was halfway between the weights of calcium and barium. These elements possessed similar chemical properties. By 1829, he had discovered the halogen triad made up of chlorine, bromine, and iodine and a alkali metal triad of lithium, sodium and potassium. He postulated that nature contained triads of elements in which the middle element had properties that were an average of the other two elements. Later, other scientists found other triads and recognized that elements could be grouped into set large than three. The poor accuracy of measurements such as that of atomic weights hindered grouping more elements Precursors to the Periodic Table In 1862, A.E.Beguyer de Chancourtois was the first person to make use of atomic weights to reveal that the elements were arranged according to their atomic weights with similar elements occurring at regular intervals. He drew the elements as a continuous spiral around a cylinder divided into 16 parts. A list of elements was wrapped around a cylinder so that several sets of similar elements lined up, creating the first geometric representation of the periodic law In 1863, John Newlands, an English chemist, proposed the Law of Octaves which stated that elements repeated their chemical properties every eighth element. The musical analogy was ridiculed at the time, but was found to be insightful after the work of Mendeleev and Meyer were published. The Fathers of the Periodic Table Lothar Meyer and Dmitri Ivanovich Mendeleev independently produced remarkably similar versions of the periodic table of elements at the essentially the same time. Meyer's 1864 textbook included a abbreviated version of a periodic table used to classify about half of the known elements. In 1868, Meyer constructed an extended table which he gave to a colleague for evaluation. This table unfortunately was not published until 1870, a year after Mendeleev's table was published. Mendeleev periodic table appeared in his work "On the Relationship of the Properties of the Elements to their Atomic Weights" in 1869. Mendeleev placed many elements out of order based on their accepted atomic weights at the time. Mendeleev predicted the existence and properties of unknown elements which he called eka-aluminum, eka-boron, and eka-silicon. The elements gallium, scandium and germanium were found later to fit his predictions quite well. The Modern Periodic Table Glenn Seaborg discovered the transuranium elements, atomic numbers 94 to 102. The completion of the actinide series allow Seaborg to redesign the periodic table into it current form. Both the lanthanide and actinide series of elements were placed under the rest of the periodic table. These elements technically should be placed between the alkaline earth metals and the transition metals, however, since this would make the periodic table too wide, they were placed below the rest of the elements. Dr. Seaborg and his colleagues are also responsible for the identification of more than 100 isotopes of elements. Metals, Nonmetals, & Metalloids Most periodic tables contain a stair step line which allows you to identify which elements are metals, nonmetals, and metalloids. Following are descriptions of each of the three types of materials. Since metals tend to lose electrons and nonmetals tend to gain electrons, metals and nonmetals like to form compounds with each other. These compounds are called ionic compounds. When two or more nonmetals bond with each other, they form a covalent compound. Metals Most elements are metals. 88 elements to the left of the stair step line are metals or metal like elements. Metalloids Elements on both sides of the zigzag line have properties of both metals and nonmetals. These elements are called metalloids. Physical Properties of Metals: • Luster (shininess) • Good conductors of heat and electricity • High density (heavy for their size) • High melting point • Ductile (most metals can be drawn out into thin wires) • Malleable (most metals can be hammered into thin sheets) Physical Properties of Metalloids: • Solids • Can be shiny or dull • Ductile • Malleable • Conduct heat and electricity better than nonmetals but not as well as metals Chemical Properties of Metals: • Easily lose electrons • Corrode easily. Corrosion is a gradual wearing away. (Example: silver tarnishing and iron rusting) Nonmetals Nonmetals are found to the right of the stair step line. Their characteristics are opposite those of metals. Physical Properties of Nonmetals: • No luster (dull appearance) • Poor conductor of heat and electricity • Brittle (breaks easily) • Not ductile • Not malleable • Low density • Low melting point Chemical Properties of Nonmetals: • Tend to gain electrons Information was obtained from various web sources. http://www.bpc.edu/mathscience/chemistry/history_of_the_periodic_tab le.html http://www1.whsd.net/courses/J0078/Periodic__Table/metals.html Antoine Lavoiser – Listed the 23 known elements Relationships between atomic mass and elemental properties started being recognized Mendeleev gets credit because he published and explain it first More accurate methods of determining atomic mass were developed Boxes are arranged in increases atomic number to create columns (groups) and rows (periods) Non-metals are on the upper right side (above the stairstep) 1869-1913 Electricity was used to separate more compounds to elements John Newlands first noticed repeating patterns in elemental properties every eight elements when in rows of eight Mendeleev organized elements by increasing atomic mass every eight element; this stacked elements with similar properties into groups Spectrometers were developed and used to identify elements By 1870s there were approximately 70 known elements In 1860 chemist began using atomic masses to organize elements Developed the Law of Octaves Not accepted at first because of reference to music Meyer and Mendeleev both recognized a connection between atomic mass and elemental properties Blanks were left in the table where undiscovered should be located Predicted properties of undiscovered elements Some elements were out of order when arranged by mass Moseley corrected Mendeleev’s table Moseley arranged elements by increasing number of protons Table consist of boxes Boxes contain atomic mass, atomic number, symbol, and element name Total of seven periods Divided into representative and transition elements Three main types of elements: metals, non-metals, and metalloids Most of the elements are metals (largest left side portion) Metalloids are found around the stair-step line 1790s- mid Modern 1800s Color Coded Key 1864
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