Bio Energy technologies and processes Feedstock Technique Products Waste: · Landfill gas · Organic waste Fermentation /Digesting & Biogas cleanup Methane as LNG Methane as CNG Celluloses: · Black Liquor · Wood chips etc · Pine oil Gasification/Pyrolysis & Synthesis Methanol DME FT Diesel Crops: · Corn · Wheat · Sugarcane · Algae · Vegetable oils Diesel Otto Starch/cellulose conversion & Fermentation Ethanol Esterification Process is energy and energy is process. We use the synergetic. With 60 years of design experience from Gas & Oil, we know how to design and construct a process unit. We combine techniques and project execution within the window of safety, quality and cost. COWI AB [email protected] www.cowi.se Used as FAME/BioDiesel Chemical Today we design and construct plants for production of power, heat and fuels, both based on fossil and renewable energy sources. We have experience of bio-gas (compressed and liquified), methanol, ethanol, bio-diesel and bio-oil. Technologies we handle are esterification, gasification, pyrolysis, fermentation etc. Bio Energy technologies and processes Fermentation/Digestion & Biogas cleanup Anaerobic digestion is a series of processes in which microorganisms break down biodegradable material in the absence of oxygen. It is widely used to treat wastewater sludges and organic wastes because it provides volume and mass reduction of the input material. As part of an integrated waste management system, anaerobic digestion reduces the emission of landfill gas into the atmosphere. Biogas from anaerobic digestion is a renewable energy source since the process produces a methane and carbon dioxide rich biogas suitable for energy production helping replace fossil fuels. Also, the nutrient-rich solids left after digestion can be used as fertilizer. Biogas cleanup is used to concentrate the methane in biogas to natural gas standards. The system removes carbon dioxide and contaminants from the biogas. This purified biogas is also called biomethane. It can be used to power vehicles or alternatively input directly into the local gas grid. Gasification/Pyrolysis & Synthesis Gasification is a process that converts carbonaceous materials, such as coal, petroleum, or biomass, into carbon monoxide and hydrogen by reacting the raw material at high temperatures with a controlled amount of oxygen and/or steam. The resulting gas mixture is called synthesis gas or syngas and is itself a fuel. Gasification is an efficient method for extracting energy from many different types of organic materials, and also has applications as a clean waste disposal technique. The advantage of gasification is that using the syngas is potentially more efficient than direct combustion of the original fuel because it can be combusted at higher temperatures or even in fuel cells, so that the thermodynamic upper limit to the efficiency defined by Carnot’s rule is higher or not applicable. Syngas may be burned directly in internal combustion engines, used to produce methanol and hydrogen, or converted via the Fischer-Tropsch process into synthetic fuel. Gasification can also begin with materials that are not otherwise useful fuels, such as biomass or organic waste. In addition, the high-temperature combustion refines out corrosive ash elements such as chloride and potassium, allowing clean gas production from otherwise problematic fuels. COWI AB [email protected] www.cowi.se Gasification of fossil fuels is currently widely used on industrial scales to generate electricity. Pyrolysis is the chemical decomposition of a condensed substance by heating. It does not involve reactions with oxygen or any other reagents but can take place in their presence. Pyrolysis is a special case of thermolysis, and is most commonly used for organic materials - extreme pyrolysis, which leaves only carbon as the residue, is called carbonization and is related to the chemical process of charring. Starch / cellulose conversion & Fermentation Ethanol fermentation is the biological process by which sugars such as glucose, fructose, and sucrose are converted into cellular energy and thereby producing ethanol and carbon dioxide as metabolic waste products. Yeasts carry out ethanol fermentation on sugars in the absence of oxygen. Because the process does not require oxygen, ethanol fermentation is classified as anaerobic. Ethanol fermentation is responsible for the rising of bread dough, the production of ethanol in alcoholic beverages, and for much of the production of ethanol for use as fuel. Esterification The Transesterification process is the reaction of a triglyceride (fat/oil) with an alcohol to form esters and glycerol. A triglyceride has a glycerine moleculeas its base with three long chain fatty acids attached. The characteristics of the fat are determined by the nature of the fatty acids attached to the glycerine. The nature of the fatty acids can in turn affect the characteristics of the biodiesel. During the esterification process, the triglyceride is reacted with alcohol in the presence of a catalyst, usually a strong alkaline like sodium hydroxide. The alcohol reacts with the fatty acids to form the mono-alkyl ester, or biodiesel and crude glycerol. In most production methanol or ethanol is the alcohol used (methanol produces methyl esters, ethanol produces ethyl esters) and is base catalysed by either potassium or sodium hydroxide. Potassium hydroxide has been found to be more suitable for the ethyl ester biodiesel production, either base can be used for the methyl ester. Processes with fixed bed catalysts also exist.
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