Page 1 / 6
SAFETY DATA SHEET
Heti Jyty
Date 10.4.2015
Previous date: 4.12.2012
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/
UNDERTAKING
1.1
1.1.1
Product identifier
Commercial Product Name
Heti Jyty
1.1.2
Product code
32.26830, 26838, 26839
1.2
1.2.1
Relevant identified uses of the substance or mixture and uses advised against
Recommended use
Alkaline detergent
Details of the supplier of the safety data sheet
Supplier
Berner Oy
Street address
Eteläranta 4 B
Postcode and post office
00130 Helsinki
P.O.Box
PL 15
Postcode and post office
00131 Helsinki
Telephone
02079100
Telefax
0207914376
Email
[email protected]
1.3
1.3.1
1.4
1.4.1
Emergency telephone number
Telephone number, name and address
HUS Myrkytystietokeskus suora puh. (09) 471 977, 24 h (vaihde (09) 4711)
SECTION 2. HAZARDS IDENTIFICATION
2.1
2.2
2.3
Classification of the substance or mixture
Causes severe skin burns and eye damage. Causes serious eye damage.
1272/2008 (CLP)
Skin Corr. 1B, H314
Eye Dam. 1, H318
67/548/EEC - 1999/45/EC
Xi; R36/38
Label elements
1272/2008 (CLP)
GHS05
Signal word
Danger
Hazard Statements
Causes severe skin burns and eye damage.
H314
Causes serious eye damage.
H318
Precautionary Statements
Do not get in eyes, on skin, or on clothing.
P262
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
Immediately call a POISON CENTER or doctor/physician.
P310
Wear protective gloves/protective clothing/eye protection/face protection.
P280
Other hazards
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Page 2 / 6
SAFETY DATA SHEET
Heti Jyty
Date 10.4.2015
Previous date: 4.12.2012
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2
Mixtures
Mixture
Hazardous components
CAS/EC and EINECS
Reg.number
10213-79-3, 01-229-912-9
211944981137-0000
7320-34-5
174955-61-4
68610-44-6
164462-16-2
3.3
271-865-1
Chemical name of the
substance
Sodiummetasilikate,
pentahydrate
Concentratio Classification
n
1-5%
C; R34-37;
Skin Corr. 1B, H314; STOT SE
3, H335; Met. Corr. 1, H290
Tetrapotassiumpyrophosphat 1-5%
Xi; R36
e
Eye Irrit. 2, H319;
Nopol ethoxylated
1-5%
Xn; R22-41
propoxylated
Acute Tox. 4, H302; Eye
Dam. 1, H318
Sodiumoctylaminopropionate 1-2%
Xn; R10-38-41-68/20/21/2220/21/22
Flam. liq. 3, H226; Eye Dam.
1, H318; Skin Irrit. 2, H315;
STOT SE 2, H371; Acute Tox.
4, H302;
alaniini, N,N-bis
1-5%
(carboksymethyl)-, trisodium
salt
Met. Corr. 1, H290
Other information
Contains: Nonionic surfactants 5-15 %, Amfphoteric surfactants <5%, Phosphate < 5 %
SECTION 4. FIRST AID MEASURES
4.1
Description of first aid measures
-
4.1.2
Inhalation
Remove from exposure, lie down. If symptoms persist, call a physician.
4.1.3
Skin contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
4.1.4
Eye contact
Rinse immediately with plenty of water for at least 15 minutes. Consult a physician.
4.1.5
Ingestion
Do NOT induce vomiting. If conscious, drink plenty of water. Consult a physician.
4.2
Most important symptoms and effects, both acute and delayed
-
4.3
Indication of immediate medical attention and special treatment needed
-
SECTION 5. FIREFIGHTING MEASURES
5.1
5.1.1
Extinguishing media
Suitable extinguishing media
The product itself does not burn. Use foam, CO2, powder or waterspray.
5.2
Special hazards arising from the substance or mixture
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Page 3 / 6
SAFETY DATA SHEET
Heti Jyty
Date 10.4.2015
Previous date: 4.12.2012
5.3
Advice for firefighters
Self-contained breathing apparatus
5.4
Specific methods
-
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1
Personal precautions, protective equipment and emergency procedures
Contaminated surfaces will be extremely slippery.
6.2
Environmental precautions
Do not flush into surface water or sanitary sewer system.
6.3
Methods and materials for containment and cleaning up
Clean-up methods - small spillage: Flush into sewer with plenty of water. Clean-up methods - large spillage:
Sweep up or vacuum up spillage and collect in suitable container for disposal. After cleaning, flush away
traces with water.
6.4
Reference to other sections
For suitable protective equipment, see section 8.
Dispose of waste, see section 13.
SECTION 7. HANDLING AND STORAGE
7.1
Precautions for safe handling
Avoid contact with skin and eyes. Avoid exposure - obtain special instructions before use. No special
precautions required..
7.2
Conditions for safe storage, including any incompatibilities
Perishable if frozen. Store in original container.
7.3
Specific end use(s)
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
8.2
8.2.1
Control parameters
Exposure controls
Appropriate engineering controls
Wash hands before breaks and at the end of workday. Ensure that eye flushing systems and safety showers
are located close to the working place.
8.2.2
8.2.2.1
Individual protection measures
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
8.2.2.2
Hand protection
Use when needed Rubber or plastic gloves
8.2.2.3
Eye/face protection
Use when needed Safety glasses.
8.2.2.4
Skin protection
Normal work clothes are adequate.
8.2.3
Environmental exposure controls
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
9.1
Important Health Safety and Environmental Information
Page 4 / 6
SAFETY DATA SHEET
Heti Jyty
Date 10.4.2015
Previous date: 4.12.2012
9.1.1
Appearance
clear liquid.
9.1.2
Odour
characteristic
9.1.4
pH
13.5 (10 % water solution 12)
9.1.6
Initial boiling point and boiling range
n. 100°C
9.1.13
Relative density
1080 g/dm³
9.1.14
9.1.14.1
Solubility(ies)
Water solubility
completely soluble
9.2
Other information
-
SECTION 10. STABILITY AND REACTIVITY
10.1
Reactivity
Stable under normal conditions.
10.2
Chemical stability
Stable at normal ambient temperature and pressure.
10.3
Possibility of hazardous reactions
Exothermic reaction with acids. Contact with metals liberates hydrogen gas.
10.4
Conditions to avoid
Stable under normal conditions.
10.5
Incompatible materials
Strong acids Materials to avoid aluminum, zinc and tin
10.6
Hazardous decomposition products
None reasonably foreseeable.
SECTION 11. TOXICOLOGICAL INFORMATION
11.1
11.1.1
Information on toxicological effects
Acute toxicity
Nopol ethoxylated propoxylated:
LD50/oral/rat = > 200-200mg/kg Harmful if swallowed.
Sodium metasilicate:
LD50/oral/rat = 1280mg/kg Harmful by ingestion.
11.1.2
Irritation and corrosion
Causes severe skin burns and eye damage. Causes serious eye damage.
11.1.3
Sensitisation
No sensitisation responses were observed.
11.1.4
Subacute, subchronic and prolonged toxicity
No known.
11.1.5
STOT-single exposure
-
11.1.8
Other information on acute toxicity
-
SECTION 12. ECOLOGICAL INFORMATION
12.1
Toxicity
Page 5 / 6
SAFETY DATA SHEET
Heti Jyty
Date 10.4.2015
12.1.1
Previous date: 4.12.2012
Aquatic toxicity
The product is harmful to aquatic organisms because of alkalinity. No data is available on the product itself.
Sodium metasilicate, pentahydrate:
LC50/96h/Brachydanio rerio = 210mg/l
EC50/48h/daphnia = 1700mg/l
Nopol ethoxylated propoxylated:
EC50/48h/daphnia = > 100mg/l
alaniini, N,N-bis(carboxymethyl)-, trisodiumsalt:
LC50/96h/Brachydanio rerio > 200 mg/l
EC50/48h/daphnia = > 200 mg/l
12.2
12.2.1
Persistence and degradability
Biodegradation
Inherently biodegradable.
12.3
Bioaccumulative potential
Not expected to be bioaccumulative.
12.4
Mobility in soil
Mobile liquid. Soluble in water.
12.5
Results of PBT and vPvB assessment
This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This
mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
12.6
Other adverse effects
-
SECTION 13. DISPOSAL CONSIDERATIONS
13.1
Waste treatment methods
Dispose of in accordance with local regulations.
SECTION 14. TRANSPORT INFORMATION
14.1
UN number
UN 1719
14.2
UN proper shipping name
Corrosive liquid, alkaline, N.O.S
14.3
Transport hazard class(es)
8
14.4
Packing group
III
14.5
Environmental hazards
14.6
Special precautions for users
No known.
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicaple
SECTION 15. REGULATORY INFORMATION
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
648/2004/EC
15.2
Chemical safety assessment
Blend
Page 6 / 6
SAFETY DATA SHEET
Heti Jyty
Date 10.4.2015
Previous date: 4.12.2012
SECTION 16. OTHER INFORMATION
16.3
Key literature references and sources for data
1. REACH ja CLP
2. STM: HTP-arvot 2014
3. Raaka-ainetoimittajien laatimat käyttöturvallisuustiedotteet
16.5
List of relevant R phrases, hazard statements, safety phrases and/or precautionary statements
Flammable.
R10
Harmful by inhalation, in contact with skin and if swallowed.
R20/21/22
Harmful if swallowed.
R22
Causes burns.
R34
Irritating to eyes and skin.
R36/38
Irritating to respiratory system.
R37
Irritating to skin.
R38
Risk of serious damage to eyes.
R41
Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if
R68/20/21/22
swallowed.
May be corrosive to metals.
H290
Harmful if swallowed.
H302
Harmful in contact with skin.
H312
Causes severe skin burns and eye damage.
H314
Causes skin irritation.
H315
Causes serious eye damage.
H318
Harmful if inhaled.
H332
May cause respiratory irritation.
H335
May cause damage to organs <or state all organs affected, if known> <state route of
H371
exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
16.7
Recommended restrictions
Only for professional use.
16.8
Additional information available from:
Manufacturer and the label of the product.