HighFour Chemistry Category C: Grades 9 – 10 Round 9 Tuesday, May 10, 2016 The use of calculator is required. Question #1 How many kilograms of iron could be obtained from 5400 g of FeCO3? Question #2 In an experiment, what do you call a tentative explanation for a set of observations based on the data gathered? Question #3 At one time there was a chemical atomic mass scale based on the assignment of the value 16.0000 to naturally occurring oxygen. What would have been the atomic mass, on such a table, of silver, if current information had been available? The atomic masses of oxygen and silver on the present table are 15.9994 and 107.8682. Question #4 A 12.5843 g sample of ZrBr4 was dissolved and, after several chemical steps, all of the combined bromine was precipitated as AgBr. The silver content of the AgBr was found to be 13.2160 g. Assume the atomic masses of silver and bromine to be 107.868 and 79.904, respectively. What value was obtained for the atomic mass of Zr from this experiment? Question #5 What do you call the instrument that separates particles of different isotopic composition and measures their individual relative masses? HighFour Chemistry Category C: Grades 9 – 10 Round 9 Tuesday, May 10, 2016 The use of calculator is required. Question #6 A 15.00 g sample of a hydrated salt, Na2SO4· XH2O, was found to contain 7.05 g of water. Determine X in the given formula. Question #7 A compound gave on analysis the following percentage composition: K = 26.57%, Cr = 35.36%, O = 38.07%. Find x, y, and z to derive the empirical formula of the compound KXCryOz. (Use molecular weight of K= 39.10 g/mol; Cr =52 g/mol; O=16g/mol) Question #8 How much 56.0% sulfuric acid solution is needed to provide 150 g of H2SO4? Question #9 Calculate the mass of pure HNO3 per cm3 of the concentrated acid which assays 69.8% by weight HNO3 and has a density of 1.45 g/cm3. Question #10 The blue iridescence of butterfly wings is due to striations that are 0.15 µm apart, as measured by the electron microscope. What is this distance in centimeters? (Use ^ for “raise to” ex. 105 or 10^5) HighFour Chemistry Category C: Grades 9 – 10 Round 9 Tuesday, May 10, 2016 The use of calculator is required. Question #11 Determine the molar mass of potassium hexachloroiridate (IV). (Use molecular weight of K= 39.10 g/mol; Cl =35.45 g/mol; Ir=192.22g/mol) Question #12 How many molecules are contained in 92.91 g of P4? (Use ^ for “raise to” ex. 105 or 10^5) (Use molecular weight of P= 30.947 g/mol) Question #13 The bromine content of average ocean water is 65 parts by weight per million. Assuming 100 percent recovery, how many cubic meters of ocean water must be processed to produce 0.61 kg of bromine? Assume that the density of seawater is 1.0 x 103 kg/m3. Question #14 What is the mass (kg) of one molecule of C1200H2000O1000? (Use ^ for “raise to” ex. 105 or 10^5) (Use molecular weight of C= 12 g/mol; H =1 g/mol; O=16g/mol) Question #15 How many moles of N are contained in 132.4 g of Cd(NO3)2 ·4H2O? (Use molecular weight of Cd= 112.411 g/mol; H =1 g/mol; O=16g/mol; N = 14g/mol) HighFour Chemistry Category C: Grades 9 – 10 Round 9 Tuesday, May 10, 2016 The use of calculator is required. Question #16 How many molecules of water of hydration are in 132.4 g of Cd(NO3)2 ·5H2O? (Use ^ for “raise to” ex. 105 or 10^5) (Use molecular weight of Cd= 112.411 g/mol; H =1 g/mol; O=16g/mol; N = 14g/mol) Question #17 A 5.82 g silver coin is dissolved in nitric acid. When sodium chloride is added to the solution, all the silver is precipitated as AgCl. The AgCl precipitate weighs 7.20 g. Determine the percentage of silver in the coin. (Use molecular weight of Ag= 107.9 g/mol; Cl =35.45 g/mol) Question #18 A 1.2048 g impure sample of Na2CO3 is dissolved and allowed to react with a solution of CaCl2. The resulting CaCO3, after precipitation, filtration, and drying, was found to weigh 1.0262 g. Assuming that the impurities do not contribute to the weight of the precipitate, calculate the percentage purity of the Na2CO3 (Use molecular weight of Na= 23 g/mol; Ca =40 g/mol; O=16 g/mol; C=12g/mol) Question #19 How high (m) a column of air would be necessary to cause the barometer to read 78 cm of mercury, if the atmosphere were of uniform density 1.2 kg/m3? The density of mercury is 13.53 x 103 kg /m3. Question #20 The density of helium is 0.178 6 kg/m3 at S.T.P. If a given mass of helium at S.T.P. is allowed to expand to 1.500 times its initial volume by changing the temperature and pressure, compute its resultant density.
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