TEANBY: PLANETARY ATMOSPHERES Cassini at Titan Cassini’s first year examining Saturn and its moons has uncovered many surprises, not least on the enigmatic moon Titan. Nick Teanby reviews the progress made and discusses prospects for the future. T he launch of the Cassini probe on 15 October 1997 was the start of an epic seven-year journey that included flybys of Earth, Venus and Jupiter and eventually arrived at Saturn in July 2004. The Cassini/Huygens probe and mission are summarized in “The Cassini/Huygens Mission” p5.22. Titan was last visited by Voyager I in 1981 during its grand tour of the solar system. Unlike Voyager, which only encountered Titan during a brief flyby, Cassini will remain in the Saturnian system for many years, providing the opportunity for detailed mapping of Titan’s surface and atmosphere and studies of seasonal variations. This article focuses on recent results about the atmosphere and surface of Saturn’s largest moon, Titan. Titan is one of the main science objectives of the Cassini/Huygens mission. It is the second largest moon in the solar system, slightly smaller than Jupiter’s moon Ganymede and bigger than the planet Mercury. Titan is of especial interest to planetary scientists because it is the only moon to have a substantial atmosphere – with a pressure of 1.5 bar at the surface. Knowledge of Titan prior to Cassini’s arrival is reviewed by Taylor and Coustenis (1998), Coustenis and Taylor (1999), and Lorenz and Mitton (2002). What makes Titan so fascinating is that many processes that occur on the Earth are thought to have analogues on Titan, at much colder temperatures because Titan is so much farther from the Sun. Such processes may include: tectonics; weather, including rain; erosion by winds and liquids; formation of complex organic compounds; a greenhouse effect; and volcanism. Titan’s atmosphere is up to 98% nitrogen and 2–6% methane, which makes it the only object in the solar system, apart from Earth, to have nitrogen as its main atmospheric component. Table 1 shows a comparison of Earth and Titan, and illustrates the many similarities and differences. The nitrogen–methane atmosphere could give rise to many interesting organic compounds – created when solar UV photons and energetic electrons from Saturn’s radiation belt cause dissociation of 5.20 ABSTRACT Saturn’s giant moon Titan is the second largest moon in the solar system and is the only planetary body, other than our Earth, to have a substantial nitrogen-based atmosphere. Many exotic chemical reactions, driven by solar radiation, result in an atmosphere awash with primitive organic compounds, which eventually rain down onto the surface. It is now just over one year into the Cassini/Huygens mission to explore the Saturnian system, and already Titan is proving to be a very curious moon indeed. The atmosphere contains clouds made of hydrocarbons, which race round the planet, blown by winds rotating faster than the planet itself. There is evidence of a varied surface laced with drainage channels, tectonic features, dunes and even volcanoes and hydrocarbon lakes. Strange hazes adorn the sky, which made studying Titan’s surface difficult prior to Cassini’s arrival. This article summarizes recent discoveries about the atmosphere and surface of Titan from the mission so far. Table 1: Comparison of properties of Earth and Titan Atmospheric composition Surface pressure Surface temperature Atmosphere thickness (at top of stratosphere) Clouds/rain Radius Axial tilt Distance from Sun Solar energy Length of year Length of day Earth 78% N2, 21% O2, <1% H2O 1bar 296K Titan 98% N2, 2% CH4 1.5bar 95K 50km H2O 6371km 23.5° 1AU 1368Wm–2 1 1 300km CH4 2575km 26.7° 9.5AU 15.0Wm–2 29.5 15.9 nitrogen and methane in the upper atmosphere. The resulting radicals combine to form complex hydrocarbons and nitriles such as ethane, acetylene, hydrogen cyanide and benzene (Wilson and Atreya 2004). The photochemical processes in Titan’s atmosphere are thought to be similar to those that occurred on the early Earth. But because of its low temperature and predicted replenishment of atmospheric methane from the surface or interior, Titan has preserved much of this primordial atmospheric composition. It is hoped that studying Titan will eventually provide clues to the formation of the compounds that preceeded the development of life on Earth. Eventually the photochemically produced organic compounds filter down from the upper atmosphere towards the surface and lower atmosphere. Temperatures are colder here so the organics condense and rain out onto the surface. The heavier hydrocarbons and nitriles combine to form fine particles of orange-coloured organic haze, which gives Titan its characteristic orange hue at visible wavelengths (figure 1). This haze shrouds the surface from view at many wavelengths, a fact that has allowed astronomers to indulge in much speculation about processes on the surface – processes that Cassini is now starting to unravel. Titan is thought to have a rocky core made of silicates overlain by a crust mainly composed of water ice. The surface temperature on Titan is around 95 K, far too low for the existence of liquid water. In fact, water ice behaves more like rock at these temperatures. However, the pressures and temperatures on the surface are close to the triple point of methane and it is thought that a methane cycle – similar to the water cycle on Earth – exists on Titan, with evaporation, condensation to form rain clouds, and even the possibility of liquids on the surface. The instruments onboard Cassini have seen a possible hydrocarbon lake and large numbers of localized clouds, providing evidence for an active “hydrological cycle”. There are also surface features that appear to have been shaped by flowing liquids. One of the many mysteries about Titan is the fact that there is so much methane in the atmosphere. Methane forms the basis of many photoA&G • October 2005 • Vol. 46 TEANBY: PLANETARY ATMOSPHERES : the story so far 1: Titan shown in visible light as viewed by Cassini’s ISS instrument. Titan’s surface is shrouded by a dense orange haze, which is composed of organic material formed by photochemical reactions in the upper atmosphere. (NASA/JPL–Caltech/Space Science Institute) chemical reactions on Titan, which cause its depletion over time so that it has a lifetime of only 10 million years in the atmosphere (Yung 1984). Therefore, unless it is being replenished somehow, we should not observe it in such high quantities. Before Cassini arrived, an ocean of liquid hydrocarbons had been proposed as a source for methane replenishment. However, current data from Cassini make large-scale global oceans unlikely. Volcanoes may provide an alternative source of methane, and features resembling cryovolcanic domes have been observed by Cassini on the surface. Titan’s dynamic atmosphere A close flyby in December 2004 revealed a highly complex haze structure in Titan’s upper atmosphere. Cassini observed Titan from the night side, which resulted in stunning images of numerous detached haze layers illuminated by scattered sun light (figure 2). These haze layers extend up to 500 km above the surface, about 150 km higher than the hazes seen by Voyager in 1981. At the time of the Voyager flyby the northern hemisphere was in early spring, but the current season is early winter. It is possible that the difference in haze altitudes represents seasonal variations in the haze structure. In another close A&G • October 2005 • Vol. 46 2: Titan’s complex haze structure is captured in this image of scattered sunlight taken from the night side. As many as 12 separate haze layers are visible above the main orange haze, extending to over 500km above the surface. The layers are thought to be caused by waves in the atmosphere (Porco et al. 2005). (NASA/JPL-Caltech/Space Science Institute) flyby this April, Cassini passed within 1000 km of Titan’s surface. This allowed the mass spectrometer to scoop up gas from the upper atmosphere and determine molecular masses of the constituents (Waite et al. 2005). A complex array of short- and long-chain hydrocarbons and nitriles was detected, with masses up to the maximum range of the instrument (100 atomic mass units). The largest chains had up to seven carbon atoms – surprisingly complex for this atmospheric level. This soup of organic compounds eventually combines to form the thick orange haze in the lower atmosphere. The complex interaction between photochemically produced organic compounds and haze production on Titan is not yet fully understood. The mass spectrometer has also shown that Titan’s atmosphere is enriched in the heavy isotope of nitrogen (15N) with respect to the more abundant lighter one (14N). The isotope ratio 15 N/14N is much greater than on Earth (Waite et al. 2005). This is also apparent in infrared spectra of the stratosphere taken by the CIRS instrument. Upon orbital insertion, Cassini’s magnetospheric imaging instrument detected a vast torus of gas orbiting around Saturn along with Titan. Titan lies within the magnetosphere of Saturn and is constantly bombarded by ener- getic particles from Saturn’s radiation belts. These particles collide with gas in Titan’s atmosphere and cause gas to be ejected, forming a vast cloud of gas encircling Saturn and its rings. The loss of atmosphere caused by this process – and also by the molecules’ intrinsic thermal energy – results in enrichment of heavy isotopes because lighter isotopes move faster and therefore escape preferentially from Titan’s gravitational field. It is thought that large amounts of nitrogen must have been lost from Titan’s atmosphere in the past to give the large enrichment that we see today. The exact amount lost is hard to constrain at present, but it is estimated that in the past Titan’s atmosphere was between 1.6 and 100 times more massive (Waite et al. 2005). In contrast to the nitrogen enrichment, the heavy isotope of carbon is not enriched. In fact, the ratio 13C/ 12C is slightly lower than it is on Earth. This is consistent with methane replenishment, which would maintain the same relative abundance of each isotope, and requires a source of methane on the surface. Stormy weather One of the most exciting aspects of Titan is the prospect of clouds and rain, composed of condensed hydrocarbons. The largest concentra5.21 TEANBY: PLANETARY ATMOSPHERES The Cassini/Huygens Mission The Cassini/Huygens mission is an international collaboration between NASA, the European Space Agency and the Italian Space Agency, with a total of 17 countries taking part. The prime mission objectives are to study Saturn and its rings, Titan and its atmosphere, and the icy moons. Cassini has 12 scientific instruments, described below, as well as the Huygens probe, which descended into Titan’s murky atmosphere early this year. The primary mission is planned to last for four years and includes 45 flybys of Titan and 76 orbits of Saturn. The Cassini orbiter’s 12 instruments Imaging Science Subsystem (ISS): Wide- and narrow-angle imaging cameras covering 0.2–1.1 µm. Several filters correspond to atmospheric “window” regions, allowing images of Titan’s surface to be taken. ● Visible and Infrared Mapping Spectrometer (VIMS): Imaging spectrometer covering 0.35–5.1 µm, allowing composition mapping of Titan’s surface and atmosphere. ● Composite Infrared Spectrometer (CIRS): Fourier transform spectrometer covering the mid- and far-infrared (7–1000 µm). Atmospheric composition and temperature mapping. ● Ultraviolet Imaging Spectrograph (UVIS): ● tions of clouds seen by Cassini so far accumulate around the south polar region (Porco et al. 2005). These are suspected to be convective clouds composed of methane and provide some of the first direct evidence of meteorological activity on Titan (see figure 3). Cassini has also seen a feature that could be a hydrocarbon lake – perhaps fed by rain from the methane clouds. The south pole is currently in early summer and the extra heating there is expected to cause evaporation of surface methane; the hot air then rises and forms cumulus clouds, just like those on Earth but made of methane instead of water. These clouds move between successive images and during some flybys were not present at all. The south pole seems to be a region of intense meteorological activity at present. Clouds also occur at mid-latitudes, although they are a lot fainter than at the south pole and last only for a few hours. Tracking cloud features in the troposphere has provided estimates of the wind speed as high as 34 m s–1 (75 mph) from west to east at mid-latitudes, which is faster than Titan itself rotates. Such circulations are referred to as “super-rotation”, and have been predicted for Titan but never directly observed before (Del Genio et al. 1993). Venus also has a super-rotating atmosphere and this seems to be a characteristic of slowly rotating planets. 5.22 Imaging spectrometer covering 56–190 nm designed for investigating atmospheric aerosol properties, composition and temperature. ● Radar: Both active and passive modes allow the radar to measure Titan’s surface elevation, textures and provide information on composition. ● Radio Science Subsystem (RSS): Uses Cassini’s main dish to perform, for example, radio occultations through Titan’s atmosphere to determine the vertical temperature structure. ● Cassini Plasma Spectrometer (CAPS): Measures energy and electrical charge of particles in the Saturnian system. ● Ion and Neutral Mass Spectrometer (INMS): Measures the masses of charged and neutral particles in the upper atmospheres of Saturn and Titan, allowing composition and temperature determinations. ● Cosmic Dust Analyser (CDA): Measures size and velocity of tiny dust grains in the Saturnian system. ● Duel Technique Magnetometer (MAG): Measures the strength and direction of the magnetic field around Saturn in order to map the magnetic field and magnetosphere. ● Magnetospheric Imaging Instrument Perhaps the strangest clouds observed so far take the form of east-west streaks hundreds of kilometres long. These clouds seem to originate from fixed positions and one interpretation is that they are produced by processes on the surface, and may be gas vented from Titan’s interior, which is then swept along by the super-rotating winds. To understand many of the processes described above requires knowledge of temperature, composition and wind speeds. The CIRS instrument is ideally suited for this task and some of the early results from CIRS are discussed later on. Titan’s mysterious surface The surface of Titan has long been a mystery and the subject of much speculation, as it is very hard to see due to absorption of radiation emitted from the surface by methane and the thick organic haze that permeates the atmosphere. Cassini’s instruments were designed with this in mind and so far have provided a wealth of information on the surface characteristics, although there is still much speculation at present and future flybys are eagerly anticipated. The main instruments that Cassini uses to penetrate the atmosphere are: the radar, which is not impeded by atmospheric absorption; and ISS and VIMS, which can see down to the surface through several atmospheric (MIMI): Images the particles trapped in Saturn’s magnetic field. ● Radio and Plasma Wave Science (RPWS): Measures radio signals from Saturn and the interaction of the solar wind with the Saturnian system. Main instruments for studying Titan ● Atmosphere: CIRS, INMS, ISS, RSS, UVIS, VIMS. ● Surface: ISS, Radar, VIMS. ● Huygens Probe: six instrument packages for taking in-situ measurements through Titan’s atmosphere and on the surface. Cassini/Huygens timeline 15 Oct 1997 26 Apr 1998 24 Jun 1999 18 Aug 1999 30 Dec 2000 1 Jul 2004 2 Jul 2004 13 Dec 2004 24 Dec 2004 14 Jan 2005 15 Feb 2005 31 Mar 2005 16 Apr 2005 launch first Venus swing-by second Venus swing-by Earth swing-by Jupiter encounter Saturn orbital insertion Titan flyby (339 000 km alt.) Titan flyby (1200 km alt.) Huygens probe leaves Cassini Huygens lands on Titan Titan flyby (950 km alt.) Titan flyby (2520 km alt.) Titan flyby (950 km alt.) windows – wavelengths where the absorption from haze and methane is reduced. The descent of the Huygens probe on 14 January provided valuable information on the surface around the landing site, although data interpretation continues. So far around 1% of the surface has been mapped by high-resolution radar and very few impact craters have been detected (Elachi et al. 2005). Objects that would cause craters less than 20 km wide would burn up in Titan’s atmosphere before reaching the surface. However, based on observations of other moons of Saturn, we would expect to observe hundreds of craters larger than 20 km in the areas mapped so far, but there are only a few, rather weathered-looking craters. Figure 4 shows the largest crater discovered so far, provisionally named Circus Maximus, which is 440 km wide and believed to be caused by an object 5–10 km across (Elachi et al. 2005). The characteristic central peak from this crater is missing and has probably been removed by surface processes ISS and VIMS have also seen very small numbers of craters (Porco et al. 2005 and Sotin et al. 2005). The low crater count tells us that the surface of Titan is geologically very young, possibly only 130–300 Myr in places (Porco et al. 2005) and is being reworked by processes such as viscous sagging, tectonics, cryovolcanism, erosion A&G • October 2005 • Vol. 46 TEANBY: PLANETARY ATMOSPHERES 3: These ISS images of the surface of Titan, taken through one of the atmospheric windows, show distinct light and dark regions. These regions are suspected to have different surface compositions and one possibility is that the dark areas are rich in organic material, perhaps precipitated from the atmosphere, and light areas are outcrops of the ice bedrock. Clouds near the south pole are clearly visible in all images (white blobs). These clouds change with time, indicating that active meteorology is taking place on Titan and provide evidence for a methane-cycle, much like the water cycle on Earth – with evaporation, cloud formation and rain. The image on the right shows a possible hydrocarbon lake (dark patch) in the south polar region. Enhanced meteorological activity here, as evidenced by the white methane clouds, could be feeding this lake. Alternatively, the dark patch could be a dried up lake bed or a concentrated deposit of organic material. Also see article by Porco et al. (2005). (NASA/JPL-Caltech/Space Science Institute) 4: Radar can penetrate through Titan’s thick atmosphere, providing these surface images. Brighter areas correspond to rougher surfaces, different composition, or slopes facing the radar. The image on the left shows a large impact crater, provisionally named Circus Maximus, which is 440km in diameter. The crater has no central peak, which may have been removed by erosion or viscous sagging. Titan has very few impact craters compared to other bodies in the Saturnian system, indicating that its surface is very young and may be reworked by tectonic and erosion processes. On the right is an image just to the east of the crater, which shows linear features that could be channels where liquid methane has washed rubble from the crater downslope. This rough rubble surface would then appear bright to the radar. (NASA/JPL-Caltech) by winds or liquids, or possibly a combination of all of these. Ice pebbles photographed by the Huygens probe on Titan’s surface have a rounded appearance, consistent with erosion of sharp edges by wind or liquids (see figure 5). All three instruments show a varied and complex surface terrain comprising light and dark areas (Porco et al. 2005, Sotin et al. 2005 and Elachi et al. 2005) as seen in figure 3. One very large bright area, Xanadu Regio, is thousands of kilometres wide. Light and dark areas may correspond to different materials, textures, or illumination cause by sloped surfaces. There are thin dark features that extend for many hundreds of kilometres. Some of these are linear and may be caused by tectonic activity. Others are more sinuous and may be channels cut by liquids flowing on the surface. Parallel streaky features reminiscent of wind-blown dunes have been observed A&G • October 2005 • Vol. 46 near the equator. These are oriented east–west and have sharp western boundaries and extended eastern boundaries, which is consistent with formation by the super-rotating winds from west to east derived from cloud tracking. The numerous channel-like features observed on Titan provide some of the best evidence for the presence of liquids on the surface. Many sizes, types and locations of channels have been observed so far. Figure 4 shows channels originating from the Circus Maximus crater seen by radar, which are up to 200 km long and may be composed of debris washed from within the crater walls. Down at the south pole, where large numbers of clouds have been observed, there is an extensive system of channels. One possible explanation is that these were cut by liquid methane which fell as rain caused by the enhanced meteorological activity indicated by the convective clouds observed there. Indeed, one such channel is over 1500 km long and could act as an intermittent river. During its descent, the Huygens probe captured many images of smaller channels with dark material in the channel “valley” compared to the surrounding terrain of higher and lighter material (see figure 5). It may be that the light areas represent outcrops of the ice bedrock, and the dark areas are organics deposited from the atmosphere and washed into low-lying regions by methane rain. It has long been suspected that there were oceans, or perhaps lakes, of liquid methane on the surface of Titan. So far there has been no direct evidence of this from the radar, VIMS, or ISS, although very recently a dark patch seen by ISS near the south pole has features remarkably similar to a shoreline and it could be a hydrocarbon lake – possibly dried up (see figure 5). If 5.23 TEANBY: PLANETARY ATMOSPHERES indeed there is no large-scale reservoir of liquid methane on the surface, then an alternative source of methane is required to explain the atmospheric composition. One possible source of atmospheric methane could be out-gassing from cryovolcanoes, which might erupt mixtures of methane and water ice combined with other compounds. The VIMS instrument recently observed a circular feature, approximately 30 km in diameter, which may be the first cryovolcano to be discovered on Titan (Sotin et al. 2005). Close inspection of the infrared images show boundaries that may correspond to overlapping flows, along with a central “caldera” (see figure 6). Other possible interpretations are a cloud or dune. However, the feature has not been seen to move between successive images and the shape and spectral characteristics are different to clouds already observed. A circular-shaped dune is also unlikely, given the strong east–west winds. Interpreting this feature as a volcano is appealing, not only because of its appearance, but because cryovolcanoes would help provide the source of methane required to sustain Titan’s atmospheric composition. The energy source for such a volcano is currently unknown but could be from tidal heating or radioactive decay in Titan’s interior. 5: Titan’s surface photographed by Huygens Descent Imaging Spectral Radiometer (DISR). The lefthand image was taken as the probe descended through Titan’s atmosphere on 14 January this year. The image shows what appears to be a complex network of drainage channels, possibly cut by liquid methane. The dark material in the channels is not thought to be liquid but may be organic material that has been deposited from the atmosphere and subsequently washed into the “valleys” by methane rainfall. The right-hand image was taken by DISR on the surface and shows rounded ice pebbles, which may have been eroded by the wind or fluid flow. (ESA/NASA/JPL-Caltech/University of Arizona) CIRS atmospheric mapping The Composite Infrared Spectrometer (CIRS) measures spectra covering a wide range of wavelengths (7–1000 µm) in order to obtain quantitative information on the temperature and composition of Titan’s atmosphere (Flasar et al. 2004). This wavelength range overlaps with the peak in thermal emission from Titan and corresponds to the spectral features of many organic compounds. This makes CIRS ideal for probing the chemistry of this complex world. In order to extract information from the CIRS spectra, a computer model of the atmosphere must be constructed. The atmosphere is modelled as a series of layers and each layer is prescribed a temperature, pressure, composition, haze and cloud properties. The modelled spectrum is then the sum of contributions from all the layers and should be comparable to the observed spectra if the model is a good representation of the real atmosphere. Infrared properties of gases are taken from laboratory measurements. However, the spectral properties of hazes on Titan are poorly known, which introduces some uncertainty into the models. Spectra measured from laboratory synthesis of the Titan haze particles, made by passing electricity though nitrogen–methane mixtures, are used as a best guess of the haze properties. As the mission progresses, the complex hazes on Titan will be better characterized. To extract temperature and composition information, we start with an initial guess of the atmospheric temperature and composition, 5.24 10 8 6 –148 –146 –144 –142 30 km 6:OntheleftisaninfraredVIMSimageofasuspectedcryovolcano.Thecircularfeatureat–143.5°W, 8.5°Nisabout30kmindiameter.Ithasremainedstationaryandsoisnotthoughttobeacloud.It appearstohaveacentralcaldera,similartovolcanoesonEarthandalsoaseriesofoverlappingflows. Aschematic“geologicalmap”isshownontheright,whichshowsthesefeaturesmoreclearly.Different coloursrepresentareaswithdifferentbrightnessandtexture.Themagmafromsuchavolcanois thoughtobeamethane–watericemixwithothercompounds.Cryovolcanoesmaysupplymethaneinto Titan’satmosphere.AlsoseeSotinetal.(2005).(NASA/JPL-Caltech/UniversityofArizona) based on measurements from Voyager and telescopes. This gives a synthetic spectrum that can be compared to the observations. The model is then perturbed until a good fit to the measured spectrum is obtained. Different parts of the spectrum can be used to investigate temperature or gas abundances. An example segment of a spectrum from CIRS is shown in figure 7. Atmospheric temperature affects the height of all the spectra peaks. A larger peak could mean a larger gas abundance or a higher temperature. Therefore, the most important first step in analysing the CIRS spectra is to determine the variation of temperature with altitude. This is done using the emission features of methane from 7.4–8.1 µm, which depend only on temperature and methane abundance: if the abundance is fixed, the temperature can be found. Methane abundance is measured independently using a different part of the spectrum. A&G • October 2005 • Vol. 46 radiance (µW/cm2 /sr/µm) TEANBY: PLANETARY ATMOSPHERES 14 C 2H 2 12 10 8 CH 4 HCN 6 C 2H 6 4 C 3H 4 C 4H 2 C 2H 4 2 0 HC 3N CO 2 x10 –7 K 7 8 9 10 11 12 13 14 15 16 17 wavelength (µm) 7: Example infrared spectrum of Titan taken at latitude 60°N by the CIRS instrument. The emission features of many stratospheric gases occur in this range and some of the more prominent species are marked on the figure. The methane feature centred around 7.7µm can be used to extract atmospheric temperature as it does not overlap with any of the other gases and this region of the spectrum is not affected much by Titan’s haze. Once temperature is determined the other peaks can be used to obtain abundances of trace gases. Currently CIRS has surveyed latitudes between 90°S and 60°N on Titan. Temperature varies mostly with latitude and variations with longitude are very small, giving a banded appearance to the temperature map shown in figure 8. The temperature gradient is related to the wind speed and can be used to determine wind speeds indirectly. Strong zonal winds have been inferred, consistent with the high speeds determined from cloud tracking. The temperature gradient in the northern hemisphere is much greater than in the south; winds in the north are therefore stronger (Flasar et al. 2005). CIRS found that at the south pole, which is now in summer, the stratosphere is colder than in the equatorial region by about 4–5 K (Flasar et al. 2005). This is unexpected because, if the haze and gases are uniformly distributed across Titan, the south pole should be about 15 K warmer, because it is in constant sunlight. This implies that the gas or haze distribution could differ with latitude. Alternatively, there is atmospheric circulation with upwelling at the south followed by transport towards the north. The rising air in the south would be adiabatically cooled as it rises and expands, explaining the colder temperatures. Further analysis is required and subsequent flybys may give more clues. Once the atmospheric temperature profile has been determined, the abundances of trace organic gases can be found by adjusting the composition in the model to give the best fit to the measured spectrum. Figure 8 shows maps of the abundance of two nitriles: hydrogen cyanide (HCN) and cyanoacetylene (HC3N) (Teanby et al. 2005). The gradient of the abundance variations from south to north differ for these two gases, but they both display a banded pattern, consistent with zonal winds derived from cloud tracking and temperatures. The abundance of A&G • October 2005 • Vol. 46 140 145 150 155 160 temperature at 3 mbar 1 2 3 4 5 6 HCN abundance at 3 mbar x10 –10 0.0 0.5 1.0 1.5 2.0 2.5 HC 3N abundance at 3 mbar 8: Maps of temperature, HCN, and HC3N in Titan’s atmosphere at the 3mbar level (140km altitude). Temperature shows a banded pattern, with most of the variation in the latitude coordinate. The north pole is experiencing winter, which explains the cold temperatures there. HCN abundance is roughly constant in the southern hemisphere, and gradually increases towards the winter pole. This is thought to be due to organic enriched air from the upper atmosphere sinking to lower levels, where it can be observed. HC3N increases much more steeply than HCN, and is almost undetectable southwards of 40°N. HC3N has a much shorter lifetime in Titan’s atmosphere than HCN and hence does not have time to become mixed with air at lower latitudes before it dissociates. Maps like these give us clues about the nature of winds and circulations occurring in Titan’s atmosphere. (Redrawn from Teanby et al.) both gases increases towards the winter north pole, probably because cold dense air in the north subsides, dragging down air enriched in organics from the high atmosphere where the organics are produced by photochemistry. A simple numerical model explains this enrichment if the air is subsiding at around 0.3 mm s–1. The different gradients observed for HCN and HC3N are thought to be due to different photochemical lifetimes. HCN has a lifetime of around 10 years and HC3N has a lifetime of under a year (Wilson and Atreya 2004). HCN therefore has time to mix in with air at lower latitudes, decreasing the gradient, whereas HC3N dissociates before it has a chance to mix. Other organic compounds also increase towards the north pole, for example cyanogen (C2N2), methylacetylene (C3H4) and diacetylene (C4H2) (Flasar et al. 2005 and Teanby et al. 2005). The enrichment of these gases at high northern latitudes is consistent with subsidence and isolation of the north polar atmosphere from the atmosphere at lower latitudes. It is possible that the high winds around the north pole create a polar vortex, which inhibits the mixing of air from inside the vortex with that outside. This may be analogous to the polar vortex that surrounds Antarctica on the Earth, where cold temperatures, and subsiding air from the high atmosphere, leads to the formation of polar stratospheric clouds, which in turn facilitate chlorine production and subsequent ozone depletion. Similar strange chemistry, involving different gases, may happen at Titan’s winter pole. CIRS data already show spectral features of organic compounds that are not detectable at more southern latitudes. More detailed analysis must wait until Cassini observes the north polar region later in the mission. Discoveries for the near future? Cassini is now just over one year into its fouryear primary mission and already there have been many discoveries, and even more questions left to answer. Although a large-scale ocean now seems unlikely, the search continues for liquid methane on the surface and methane lakes now seem like a possibility. Evolution of the south polar clouds as summer progresses may reveal seasonal variations in the meteorological processes that shape the surface. The region where VIMS observed a possible cryovolcano has yet to be mapped in detail by the radar, and with only 1% of the surface mapped, what other exotic surface formations await discovery? Titan’s north polar region is just entering winter and has yet to be mapped. Strange organic molecules and even stranger chemistry are anticipated as organic molecules are accumulated by atmospheric circulation as winter progresses. The Cassini mission has only just begun, but already there is enough data to keep scientists busy for years. ● Nick Teanby is a postdoctoral researcher working as part of the Cassini–CIRS investigation team at Oxford University. [email protected] References Coustenis A and Taylor F W 1999 Titan: the Earth-like moon (World Scientific). Del Genio A D et al. 1993 Icarus 101 1. Elachi C et al. 2005 Science 308 970. Flasar F M et al. 2005 Science 308 975. Flasar F M et al. 2004 Space Sci. Rev. 115 169. Lorenz R and Mitton J 2002 Lifting Titan’s veil (CUP). Porco C C et al. 2005 Nature 434 159. Sotin C et al. 2005 Nature 435 786. Taylor F W and Coustenis A 1998 Planet. Space Sci. 46 1085. Teanby N A et al. 2005 submitted to Icarus. Waite J H et al. 2005 Science 308 982. Wilson E H and Atreya S K 2004 J. Geophys. Res. 109 E06002. Yung Y L et al. 1984 Astrophys. J. Suppl. 55 465. More information Images and movies from the Cassini Mission: http://saturn.jpl.nasa.gov 5.25
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