Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1.
Product identifier
Product form
: Substance in aqueous solution
Trade name
: Oligo Iron DTPA 3.1% Liquid
Chemical name
: Reaction mass of disodium [N,N-bis[2-[bis(carboxymethyl)amino]ethyl]glycinato(5-)]ferrate(2-)
and sodium chlorid
Formula
: C14H18FeN3O10.2Na + NaCl
EC-FERTILISER
: E.1.4.(c)
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Main use category
: Industrial use, Professional use, Consumer use
Use of the substance/mixture
: Use as raw material for fertilizer solutions in agriculture and horticulture
Function or use category
: Fertilisers, Laboratory chemicals
Remark relevant uses
: According to Article 14(4) of the REACh Regulation (EC) No 1907/2006 a human-related
exposure assessment and risk characterization is not required
1.2.2.
Uses advised against
No additional information available
1.3.
Details of the supplier of the safety data sheet
Van Iperen International BV
Smidsweg 24
3273 LK Westmaas - Nederland
T +31 (0) 186 578 888 - F +31 (0) 186 573 452
[email protected] - www.vaniperen.com
1.4.
Emergency telephone number
Country
United Kingdom
Official advisory body
Guy's & St Thomas' Poisons Unit
Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust
Address
Avonley Road
SE14 5ER London
Emergency number
0870 243 2241
SECTION 2: Hazards identification
2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Met. Corr. 1 H290
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Not classified
Adverse physicochemical, human health and environmental effects
No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP)
:
CLP Signal word
: Warning
GHS05
Hazard statements (CLP)
: H290 - May be corrosive to metals
Precautionary statements (CLP)
: P234 - Keep only in original container
P390 - Absorb spillage to prevent material damage
P406 - Store in corrosive resistant container with a resistant inner liner
2.3.
Other hazards
This substance/mixture does not meet the PBT criteria of REACH, annex XIII.
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII.
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 3: Composition/information on ingredients
3.1.
Substances
Substance type
: Multi-constituent
Name
: Oligo Iron DTPA 3.1% Liquid
Name
Product identifier
%
Classification according to
Directive 67/548/EEC
Diethylenetriaminepentaacetic acid, ferric disodium complex
(CAS No) 19529-38-5
(EC no) 243-136-8
(REACH-no) 01-2119963946-19-0003
26
Not classified
Name
Product identifier
%
Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Diethylenetriaminepentaacetic acid, ferric disodium complex
(CAS No) 19529-38-5
(EC no) 243-136-8
(REACH-no) 01-2119963946-19-0003
26
Not classified
Full text of R-, H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1.
Description of first aid measures
First-aid measures general
: Check the vital functions.
Unconscious: maintain adequate airway and respiration.
Respiratory arrest: artificial respiration or oxygen.
Cardiac arrest: perform resuscitation.
Victim conscious with laboured breathing: half-seated.
Victim in shock: on his back with legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia.
Prevent cooling by covering the victim (no warming up).
Keep watching the victim.
Give psychological aid.
Keep the victim calm, avoid physical strain.
Depending on the victim's condition: doctor/hospital
First-aid measures after inhalation
: Product at 20°C has so a low pressure tension that breathing harmful concentration for health is
very limited. If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing. Respiratory problems: consult a doctor/medical service.
First-aid measures after skin contact
: Rinse and then wash skin thoroughly with water and soap. Remove polluted clothing and shoes.
Wash contaminated clothing before reuse. If on skin and if skin irritation or rash occurs, seek
medical advice and attention.
First-aid measures after eye contact
: Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion
: Rinse mouth with water. If victim conscious and alert, give 1-2 glasses of water to drink.
Ingestion of large quantities: immediately to hospital.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
: No effects known
Symptoms/injuries after skin contact
: No significant effects or critical hazards known.
Symptoms/injuries after eye contact
: Slight eye irritant upon direct contact.
Symptoms/injuries after ingestion
: After absorption of high quantities: gastrointestinal complaints, feeling of weakness, metal taste.
4.3.
Indication of any immediate medical attention and special treatment needed
Follow the advices in chapter 4.1. Treat symptomatically.
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
: All extinguishing media allowed.
Use fire extinguishing methods suitable to surrounding conditions. Preferably: water.
Unsuitable extinguishing media
: No unsuitable extinguishing media known.
5.2.
Special hazards arising from the substance or mixture
Fire hazard
: Direct fire hazard: Non combustible.
Explosion hazard
: No direct explosion hazard.
Reactivity
: Stable in use and storage conditions as recommended in item 7.
5.3.
Advice for firefighters
Precautionary measures fire
: Exposure to fire/heat: keep upwind, consider evacuation and have neighbourhood close doors
and windows.
Protection during firefighting
: Do not breathe fumes. Fire-fighters should wear appropriate protective equipment and
selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to
European standard EN 469 will provide a basic level of protection for chemical incidents.
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
General measures
6.1.1.
: Ensure adequate air ventilation. Do not get in eyes, on skin, or on clothing.
Avoid all unnecessary exposure.
For non-emergency personnel
Protective equipment
: Wear protective gloves/protective clothing/eye protection as adviced in section 8.
Emergency procedures
: Mark the danger area. Keep unnecessary and unprotected personnel from entering.
Wash contaminated clothes.
6.1.2.
For emergency responders
Protective equipment
6.2.
: Wear protective gloves/protective clothing/eye protection as adviced in section 8.
See also the information in "For non-emergency personnel".
Environmental precautions
Prevent spreading in sewers. Prevent soil and water pollution. Dam up the liquid spill.
6.3.
Methods and material for containment and cleaning up
For containment
: Stop leak if safe to do so. Contain released substance, pump into suitable containers.
Methods for cleaning up
: Collect as much as possible in a suitable clean container, preferably for re-use, otherwise for
disposal. Take up rest of liquid spill into absorbent material sand, earth, vermiculite. Scoop
absorbed substance into closing containers. Wash down leftovers with plenty of water. Wash
clothing and equipment after handling.
Other information
: Use corrosionproof equipment. Use non-corrodable disposal containers.
6.4.
Reference to other sections
See section 1 for emergency contact information.
See section 8 for information on appropriate personal protective equipment.
See section 13 for additional waste treatment information
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
Additional hazards when processed
: May be corrosive to metals.
Precautions for safe handling
: Avoid all unnecessary exposure. Wear protective gloves/protective clothing/eye protection as
adviced in section 8. Use corrosionproof equipment.
Hygiene measures
: If on skin, take off contaminated clothing. Always wash hands after handling the product.
Do not eat, drink or smoke during use.
7.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
: Store in original container. Store in accordance with local regulations.
Incompatible materials
: Keep away from iron. Do not use with copper/aluminium/zinc - risk of corrosion.
Storage temperature
: -5 - 30 °C
Heat and ignition sources
: Keep substance away from: heat sources.
Storage area
: Meet the legal requirements. Keep container in a well-ventilated place. Store at a dry place, at
normal room temperature. Keep out of direct sunlight. Store in corrosive resistant container with
a resistant inner liner.
Special rules on packaging
: Meet the legal requirements. correctly labelled. closing. Secure fragile packagings in solid
containers. Keep out of direct sunlight. Store opaque. Keep only in original container.
Packaging materials
: Suitable material: polyethylene, polypropylene, steel with rubber inner lining, asphalted tanks.
Material to avoid: metal, stainless steel, aluminium, zinc, iron, monel steel, nickel, copper and its
alloys.
7.3.
Specific end use(s)
Component of mixed fertilisers. Exposure scenarios have not been made.
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
DNEL/DMEL (Workers)
Acute - systemic effects, dermal
No hazard identified
Acute - systemic effects, inhalation
No hazard identified
Acute - local effects, dermal
No hazard identified
Acute - local effects, inhalation
No hazard identified
Long-term - systemic effects, dermal
62500 mg/kg bodyweight/day Repeated dose toxicity
Long-term - local effects, dermal
Hazard unknown (no further information neccessary)
Long-term - systemic effects, inhalation
22 mg/m³ Repeated dose toxicity
Long-term - local effects, inhalation
10 mg/m³
DNEL/DMEL (General population)
Acute - systemic effects, dermal
No hazard identified
Acute - systemic effects, inhalation
No hazard identified
Acute - systemic effects, oral
No hazard identified
Acute - local effects, dermal
No hazard identified
Acute - local effects, inhalation
No hazard identified
Long-term - systemic effects,oral
6,25 mg/kg bodyweight/day Repeated dose toxicity
Long-term - systemic effects, inhalation
5,5 mg/m³ May have an effect on fertility
Long-term - systemic effects, dermal
31250 mg/kg bodyweight/day Repeated dose toxicity
Long-term - local effects, dermal
Hazard unknown (no further information neccessary)
Long-term - local effects, inhalation
2,5
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
PNEC (Water)
PNEC aqua (freshwater)
6,2 mg/l Assessmentfactor: 10
PNEC aqua (marine water)
0,62 mg/l Assessmentfactor: 100
PNEC aqua (intermittent, freshwater)
3,1 mg/l Assessmentfactor: 100
PNEC (Sediment)
PNEC sediment (freshwater)
not derived, low adsorption is predicted based on read-across
PNEC sediment (marine water)
not derived, low adsorption is predicted based on read-across
PNEC (Soil)
PNEC soil
1,23 mg/kg dwt Assesment factor: 100
PNEC (STP)
PNEC sewage treatment plant
50 mg/l Assessment factor: 10
8.2.
Exposure controls
Appropriate engineering controls
: No particular/specific measures required.
Personal protective equipment
:
Hand protection
: Gloves.
Material selection gloves
: Wear chemical-resistant gloves (tested to EN374).
Good resistance gives:Nitrile rubber. Break through time > 480 min.
Take advice to your gloves' supplier. Replace damaged gloves
Eye protection
: Safety glasses.
Skin and body protection
: Normal working clothes are suitable.
Respiratory protection
: No personal breathing protective equipment is normally required.
Environmental exposure controls
: See section 13 for additional waste treatment information.
Other information
: Training staff on good practice.
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Appearance
: Liquid.
Colour
: Brown / Black.
Odour
: Characteristic.
pH
: 6-7
Crystallization temperature
Boiling point
: -10 °C
: +/- 105 °C Decomposes on exposure to temperature rise
Flash point
: > 100 °C
Vapour pressure at 50 °C
: 10,7 kPa Due to the presence of water
Relative vapour density at 20 °C
: No data available
Density
: 1,265 kg/l (25°C)
Solubility
: Soluble in water.
Water: completely soluble in water
Explosive properties
: not explosive.
Oxidising properties
: not oxidising.
9.2.
Other information
No additional information available
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 10: Stability and reactivity
10.1.
Reactivity
Stable in use and storage conditions as recommended in item 7.
10.2.
Chemical stability
Stable under recommended storage and treatment circumstances.
10.3.
Possibility of hazardous reactions
To our knowledge, the product does not present any particular risk, under normal conditions of use.
10.4.
Conditions to avoid
Temperatures lower than -5°C. Unstable on exposure to light. Solutions with pH < 3 or pH > 8.
10.5.
Incompatible materials
Reactive or incompatible with the following materials: oxidizing agents and reducing agents, strong bases, strong acids, hydrogen peroxide,
peroxides, chlorine-based bleaching agents, metals, metal powders, metal alloys. May be corrosive to some metals.
This product can cause pitting of and corrosion of some grades of stainless steel.
10.6.
Hazardous decomposition products
On heating/burning: release of toxic and corrosive gases/vapours nitrous vapours, carbon oxides (CO and CO2), metal oxides, chlorine, hydrogen
chloride.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
: Not classified
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
LD50 oral rat
> 2000 mg/kg OECD Guideline 423 (Acute Oral toxicity - Acute Toxic Class Method)
Reference: Otterdijk van FM (2013a)
LD50 dermal rat
> 2000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity), read-across
Reference: Haferkorn J (2007)
LC50 inhalation rat (mg/l)
> 5,08 OECD Guideline 436 (Acute Inhalation Toxicity: Acute Toxic Class (ATC) Method)
Reference: Jonker D, Triel van JJ (2012)
sodium chloride (7647-14-5)
LD50 oral rat
LD50 dermal rabbit
ATE (oral)
3000 mg/kg (Rat; Experimental value,Rat; Experimental value)
> 10000 mg/kg (Rabbit; Experimental value,Rabbit; Experimental value)
3000 mg/kg
Skin corrosion/irritation
: Not classified
pH: 6 - 7
Serious eye damage/irritation
: Not classified
pH: 6 - 7
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard
: Not classified
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 12: Ecological information
12.1.
Toxicity
Ecology - general
: Classification concerning the environment: not applicable.
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
LC50 fishes 1
> 100 mg/l 96-h Danio rerio OECD Guideline 203 (Fish, Acute Toxicity Test)
Reference: Kean M (2013a)
EC50 Daphnia 1
> 100 mg/l 48-h OECD Guideline 202 (Daphnia sp.Acute Immobilisation Test)
Reference: Kean M (2013b)
EC50 other aquatic organisms 1
9,8 mg/l 72-h OECD Guideline 201 (Alga, Growth Inhibition Test)
Test mat. (meas. (geom. mean)) based on: growth rate
Reference: read-across Kean M (2013c)
LC50 fish 2
1115 mg/l 96-h Lepomis macrochirus, read-across
LOEC (chronic)
134 mg/l 18-d Daphnia carinata.
Equivalent or similar to OECD Guideline 211 (Daphnia magna Reproduction Test)
Reference: Dam van, et al (1996)
NOEC (chronic)
125 mg/l 28-d Melanotaenia fluviatilis
12.2.
Persistence and degradability
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
Persistence and degradability
Slowly biodegradable in surface water under specific environmental conditions.
12.3.
Bioaccumulative potential
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
Log Kow
-11,9
Bioaccumulative potential
Low potential for bioaccumulation (Log Kow < 4).
12.4.
Mobility in soil
Oligo Iron DTPA 3.1% Liquid
Ecology - soil
Soluble in water.
Diethylenetriaminepentaacetic acid, ferric disodium complex (19529-38-5)
Log Koc
1 (worst case, MCI method, EPISUITE Software KOCWIN Program (v2.00)
Ecology - soil
Soluble in water. Low potential for adsorption (based on substance properties).
12.5.
Results of PBT and vPvB assessment
Oligo Iron DTPA 3.1% Liquid
This substance/mixture does not meet the PBT criteria of REACH, annex XIII.
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII.
12.6.
Other adverse effects
Other information
: No other effects known.
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
EURAL code
: 06 03 14 - solid salts and solutions other than those mentioned in 06 03 11 and 06 03 13
Regional legislation (waste)
: Disposal must be done according to official regulations.
Waste treatment methods
: Do not discharge into drains or rivers. Empty and rinsed containers can be disposed as nonhazardous material or be returned for recycling.
Waste disposal recommendations
: Remove to an authorized waste treatment plant. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out.
Additional information
: Can be considered as non hazardous waste according to Directive 2008/98/EC.
Depending on branch of industry and production process, also other EURAL codes may be applicable
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA
14.1.
UN number
UN-No
14.2.
: 1760
UN proper shipping name
Proper Shipping Name
: CORROSIVE LIQUID, N.O.S.
Transport document description
: UN 1760 CORROSIVE LIQUID, N.O.S. (CONTAINS Diethylenetriaminepentaacetic acid, ferricdisodium complex, aqueous solution), 8, III, (E)
14.3.
Transport hazard class(es)
Class (UN)
: 8
Hazard labels (UN)
: 8
14.4.
Packing group
Packing group (UN)
14.5.
Other information
14.6.
: No supplementary information available.
Special precautions for user
Special transport precautions
14.6.1.
: III
Environmental hazards
: This product is corrosive to metals.
Overland transport
State during transport (ADR-RID)
: Substance assigned to class 8 for its corrosion to metals
Hazard identification number (Kemler No.)
: 80
Classification code (UN)
: C9
Orange plates
:
Special provision (ADR)
274
Transport category (ADR)
3
Tunnel restriction code
Limited quantities (ADR)
: E
5L
Excepted quantities (ADR)
: E1
EAC code
: 2X
APP code
: B
14.6.2.
Transport by sea
Transport regulations (IMDG)
: Subject
EmS-No. (1)
: F-A
EmS-No. (2)
: S-B
14.6.3.
Air transport
No additional information available
14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
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Safety Data Sheet
according to Regulation (EC) No. 453/2010
Oligo Iron DTPA 3.1% Liquid
SECTION 15: Regulatory information
15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2.
National regulations
Regional legislation
15.2.
: Ensure all national/local regulations are observed.
Chemical safety assessment
A chemical safety assessment has been carried out
SECTION 16: Other information
Version
: 4.0
Revision date
: 19-07-2013
Date of issue
: 14-12-2006
Supersedes
: 13-07-2011
Indication of changes
: Refer table below.
SDS changed items
3.1
8.1
REACH-no
Added
Added
due to REACH-registration
DNELs and PNEC's included
11
Updated
due to REACH-registration
12.
Updated
due to REACH-registration
Data sources
: BIG-database
Handbook of Chemistry and Physics CRC Press Inc
Test information
REACH registration dossier.
Abbreviations and acronyms
: CLP = Classification, labelling and packaging
DNEL = Derivative No Effect Level
PNEC = Predicted No Effect Concentration
REACH = Registration, evaluation and autorisation of chemicals.
Training advice
: Before using/handling the product one must read carefully the MSDS.
Full text of R-, H- and EUH-phrases::
------ Met. Corr. 1 Corrosive to metals, Category 1
------ H290
May be corrosive to metals
Company disclaimer
The information provided in this safety data sheet is correct to the best of our knowledge, information, and belief at the date of its
publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation,
disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any proceed, unless
specified in the text.
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