Notes # _____ Chemistry Chapter 5 Notes, Part IV Date: _______ 5.3 Light Waves are disturbances that transmit _______________ either through a substance, called a ________________, or through empty space ( a ________________). __________________________ waves are produced by disturbances in electric and magnetic fields (hence, EM). ____________________ often cause waves. Light is EM radiation that travels as a transverse wave but is _______________ (given off) or _______________ (taken in) as a massless particle called a _____________. This is called the “wave-particle duality” of light. James Maxwell proposed the Electromagnetic theory that states an electromagnetic wave, such as light, is a periodic disturbance involving electric and magnetic fields. The speed of light is affected by its medium, decreasing when the medium gets ______________. Since light travels as an EM wave it does not require a medium so it travels ____________ in a vacuum. The speed of light, represented as ____, is equal to _____________ m/s ( ______________________m/s) or about _______________ miles per second!! At this speed light would travel _____ times around the Earth in one second; from the moon to the Earth in _____ seconds; and from the Sun to Earth (93 million miles) in ______________________. Wave Characteristics The _____________ ( ) is the time required for one full wave to pass a point--it is measured in _____________. The _________________ ( is the reciprocal of the ______________ ( so ) is how often a wave passes by--it = –—– ). So, if the period is 10.0 seconds the frequency is ________ or __________. [ or ________ which is also _____________ ( Example 1: _____________________________________________ since T = ______ f = ________ = _________ )] Figure 5-10 (on p. 139) shows the range of visible light and the entire EM spectrum. Note: _______ frequencies = _________ wavelengths and the ___________ the frequency the ___________ the energy. Visible light has wavelengths between ______ nm ( _______ nm ( ). Note 1 ________________ ( ) = _______ m or _______ nm. ) and Speed of Light Recall that velocity equals distance ÷ time so: Example 2: What is the velocity of a 1.0 m wave if its period is 4.0 seconds? Example 3: What is the wavelength if a wave traveling at 15.0 m/s has a frequency of 5 Hz? Production of Light When an atom gains a specific energy, called a ______________, electrons in its electron cloud will jump to higher energy levels (further from the nucleus) then immediately “fall” back down to lower levels. Regardless of how the energy was originally gained by the electron (heat, electricity, sound), the released energy is always light. Depending on the amount of energy released different colors can be produced following the pattern: ROY G BIV. The pattern of light produced is called the _____________ _____________ _______________ of the element and might look like this for the element to the left: Each element has its own unique fingerprint that can be used to identify it. When all of the electrons of an atom are in their lowest energy the atom is said to be in its _______________ state. If a quantum of energy is applied to the atom an electron (or more) can jump to higher energy levels and the atom is in an __________________ state. When the electron falls back to the ground state the energy released can be found using the equation: Where E is the energy in J h, is the Planck’s constant (6.626 x 10 –34 J·s) –1 f is the frequency in hertz (s ) or, if one knows the wavelength the following equation can be used: Where c is the speed of light λ is the wavelength in meters The atomic emission spectrum for hydrogen had been intensely studied. Since there is only one electron in its spectrum we can look closely at its pattern. In the diagram below one ground state and two excited states are shown. Each of the series has a name and a corresponding energy in the EM spectrum:
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