1.3 IONS AND THE OCTET RULE A stable octet is an arrangement that some atoms have when their valence shells are completely filled. Noble gases have a filled shell of eight electrons. Helium is the exception, and has 2 electrons in its valence shell. The Octet Rule is followed when atoms of other elements must combine with other atoms in order to achieve a stable electron arrangement. Atoms can achieve stability in one of three ways: by sharing their electrons, losing or gaining electrons. An ion (a positive or negatively charged atom) occurs when the atom loses or gains electrons. It depends on the number of valence electrons. Cations are positively charged ions. They are usually formed from the metals on the left side of the periodic table. These elements tend to have a few electrons in their valence shell. Metals generally tend to lose those electrons. Example 1: 11p+ 12n0 + 11p+ 12n0 energy - +e Anions are negatively charged ions. They are usually formed from the non-metals on the right side of the periodic table. These elements tend to have more than four electrons in their valence shell. Non-metals generally tend to gain electrons. Non-metal anions are named by replacing the end of the element’s name with -ide Example 2: 8p+ 8n0 + 2e- 8p+ 8n0 + energy Multivalent Elements Some elements are able to form more than one stable ion. The majority of these elements are transition metals (elements found in the middle of the periodic table). There are two ways to name these multivalent ions – The Latin way and the IUPAC way Ex. Copper (I) or cuprous is Cu+ and Copper (II) or cupric is Cu2+ Polyatomic Ions - Ions that consist of more than one kind of atom. Some polyatomic ions occur naturally and are important to health, while others can be made synthetically. Example: Calcium phosphate is found in bones and teeth. Hydrogen carbonate help to regulate the pH of the blood. Table 3 – Some Important Ions in the Human Body (Page 21) Ion + Na K+ Role Source salt, cheese, preservatives Bananas, milk, potatoes Ca2+ Milk, cheese, spinach Fe3+ Kidney beans, asparagus, pine nuts Mg2+ Green plants, nuts, grains ClIHOMEWORK: Page 22 #1-8 Salt Fish, dairy products, iodized salt
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