Phase changes What is a phase change? A phase change is a phenomenon of transition of a thermodynamic system from one phase to another. A phase is a state of matter. The states can be of various types: liquid, solid or gas. and… what about Plasma state? In many books we can find only three states of matter: solid, liquid and gas. The fourth state of matter is plasma. It is made up of two types of intermixed gas: a gas of ions and a gas of electrons. When a liquid turns into gas and its temperature of 100°C increases, the electrons and the nucleus that constitute an atom no longer can stay together. The atoms are striped of their electrons and a plasma is formed. Plasma is a collection of positively and negatively charged particles. Melting (solid to liquid) ENDOTHERMIC PHASE (energy absorbed) Vaporization (liquid to gas) Sublimation (solid to gas) Condensing (gas to liquid) EXOTHERMIC PHASE (energy released) Freezing (liquid to solid) Deposition (gas to solid) Melting When a solid changes into liquid, we are talking about Melting. The solid absorbs heat and its temperature rises till a point called Melting Point. At this point the temperature stops rising. As more energy the solid absorbs, solid particles change into liquid ones. Q = m · Lfus Freezing When the liquid changes into solid by realising heat energy, the phase change is known as freezing. The heat the liquid realeses to turns into a solid is the same it absorbed when he became a liquid. Q = m (-Lfus) Vaporization Vaporization happens when liquid state of matter turns into gaseous state. The liquid absorbs heat energy and its temperature increases till a level called Boiling Point. Now the temperature stops rising and the liquid starts boiling. As more heat energy the liquid absorbs, the liquid particles convert into gas. Q = m · Lvap Saturated steam The steam is in equilibrium with liquid state: the number of particles that from liquid change into gaseous ones is equal to the number of gaseous particles that condens into liquid. The pressure of saturated steam is the pressure, the steam applies on the wall of the container, when the evaporation of the liquid stops happening. Sublimation When the solid turns directly into gas, we have the Sublimation. Sublimation happens in solid compounds like: ammonium chloride (NH4 Cl), carbon dioxide (CO2) or iodine. Chemists use this phase change to purify solid compounds. CONDENSING Condensing is the process of transition from GAS TO LIQUID. When the heat is removed from the gas, its temperature reduces to a certain level. After that level, the gas start changing from gaseous phase to liquid. This phase change occurs at almost constant temperature. DEPOSITION This is the process of the direct transition from GAS TO SOLID. It appears in nature and its opposite is the sublimation.. Relative humidity A great abundance of water vapor in a determined zone and instant is described by a physical quantity called: relative humidity. Relative humidity is the ratio of water vapor pressure (Pw) to the saturation vapor pressure (Pws), at the same temperature. To measure the relative humidity, we can use a tool called: hygrometer. There are different types of hygrometer, but one of the most common used is the hair hygrometer that makes use of hair characteristics to contract when there is humidity. Temperature for bodies Evaporation of perspiration on skin is a natural mechanism to regulate internal temperature. - A very hight relative humidity slows down the evaporation of perspiration, making this process less efficient. The skin, for this reason, feels cold. - A relative humidity of 100 % stops completely the evaporation of perspiration. Hence the skin feels hot. - A combination of cold and wind makes body feel colder than the actual temperature. That happens because wind distances from the skin the air exposed to it ,which is damper, changing it with air more dehydrate that comes from other zones. In this case, the evaporation of perspiration can be a very efficient process to defend our organism. Phase change diagram A phase change diagram is a common way to represent the different phases of a substance. At the point A, there is a solid with a temperature of -25°C. The temperature increases to 0°C. At the point B, there is the Melting Point, because the solid turns into water. At the point C, water’s temperature increases to 100°C. At the point D, the temperature stops rising and the water turns into steam. It is called Vaporisation Phase. Once the water has completely vaporised, the temperature of the steam increases. (Point E/F)
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