Reactions of Alkenes
HBr (aq )
H2, Pd/C
HBr/ ROOR
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
Dr. Ron Rusay
Fall 2004
H3 O+
1) BH3 2) H O / OH2 2
Cl2 / H2 O
Br2
Br
Br
HBr (aq )
HBr (aq )
H2, Pd/C
HBr/ ROOR
H2, Pd/C
HBr/ ROOR
Br
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
H3 O+
1) BH3 2) H O / OH2 2
Cl2 / H2 O
H3 O+
1) BH3 2) H O / OH2 2
Cl2 / H2 O
Br2
Br2
Br
Br
HBr (aq )
H2, Pd/C
HBr (aq )
HBr/ ROOR
H2, Pd/C
Br
1) Hg(OAc)2 , H2 O/THF
HBr/ ROOR
Br
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
H3 O+
OH
1) BH3 2) H O / OH2 2
Cl2 / H2 O
Br2
2) NaBH4
H3 O+
OH
1) BH3 2) H O / OH2 2
Cl2 / H2 O
Br2
OH
1
Br
Br
HBr (aq )
H2, Pd/C
HBr (aq )
H2, Pd/C
HBr/ ROOR
HBr/ ROOR
Br
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
H3 O+
Br
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
OH
1) BH3 2) H O / OH2 2
Cl2 / H2 O
H3 O+
OH
1) BH3 2) H O / OH2 2
Cl2 / H 2O
Br2
Br2
OH
OH
Br
OH
Br
Cl
Br
Br
Br
Br
H2 , Pd/C
HBr (aq )
H2, Pd/C
HBr (aq )
HBr/ ROOR
HBr/ ROOR
Br
1) Hg(OAc)2 , H2 O/THF
2) NaBH4
H3 O+
Br
1) Hg (OAc)2 , H2 O/THF
2) NaBH4
OH
OH
H3 O+
OH
OH
1) BH3 2) H O / OH2 2
Cl2 / H2 O
1) BH3 2) H O / OH2 2
Cl2 / H2 O
Br2
Br2
OH
OH
OH
Br
Cl
OH
Br
Cl
Br
Br
2