Zeitschrift für Naturforschung
Band 33 b
1978
Contents
C o n t e n t s of N u m b e r 1
Original Communications
Cyclic Diazastannylenes, II. Intermolecular LewisAcid-Base Adducts of 1,3,2,4 A2-Diazasilastannetidines (In German)
M. VEITH
1
Cyclic Amidines Complexes:
Complexes of 5:6:11:12-Tetrahydro-2,8-dimethylphenhomazine with Copper(II), Nickel(II)
and Zinc (II)
M . S. HUSSAIN a n d SAEED-UR-REHMAN
67
Arylazoisoxazolinthiones: Preparation and Reactionsof4-Arylazo-3-methyl-2-isoxazolin-5-thiones
N . A . KASSAB, S. O. A . ALLAH, a n d S. A . ELCyclic Diazastannylenes, III. The Crystal- and
BAHATT
75
Molecular Structure of the Monoclinic Phase of
1,3 - Di - tert - butyl - 2,2 - dimethyl -1,3,2,4 A2 - diaza - Derivatives of 5H-Cyclopenta[2,l-b:3,4-b']dipyridin-5-one (4,5-Diazafluoren-9-one)
silastannetidine (In German)
M. VEITH
7
Cyclic Diazastannylenes, IV. Oxidation of 1,3-Ditert - butyl- 2,2 - dimethyl-1,3,2,4 X2- diazasilastanne tidine (In German)
M . VEITH, 0 . RECKTENWALD, a n d E . HUMPFER
14
Preparation of Polyborates with Hindered Tertiary
Amines and Quaternary Ammonium Bases in
Organic Solvents (In German)
G. HELLER a n d B . BICHOWSKI
20
N,N'-Dimethylacetamidin Derivatives of Aluminium, Gallium and Indium (In German)
F . GERSTNER a n d J. WEIDLEIN
24
Kinetics of the Alkaline Solvolysis of Trichloroacetate Ion in Water-Ethanol Solutions
I. M .
ISSA, E .
M.
DIEFALLAH,
M.
R.
MAHMOUD,
and A. M. EL-NADY
30
LiBeSb and LiZnBi, Ternary Compounds with a
Wurtzit-type Lattice (In German)
CH. TIBURTIUS a n d H . - U . SCHUSTER
35
New Antimony(V) Oxides and Hydroxides
(In German)
H.
RUMPEL,
W .
BERNDT,
K.
ADAM,
and
SCHWARZMANN
E.
39
Dibromo(dimethylamino)alane and Diiodo(dimethylamino)alane. Preparation and Crystal Structure (In German)
A . AHMED, W .
SCHWARZ, a n d H . HESS
43
Coordination Chemistry of Ambivalent Ligands,
VIII. Synthesis and Reactivity of Ionic and
Covalent Sulfinato Complexes of TetraorganylVB-Elements of the Type R 4 'E0 2 SR (In German)
I.-P. LORENZ a n d J. K .
THEKUMPARAMPIL
47
Formation of Copper(II) Complexes of 1,3-Diamino2-propanol in Aqueous Solution
L. H . J. LAJUNEN a n d R . KIVEKÄS
59
ESR Study of Copper Complexes Adsorbed on Fully
Hydrated X and Y Zeolites
G. MARTINI a n d M . F . OTTAVIANI
62
I.
F.
ECKHARD,
N.
G.
KEATS,
and
L.
A.
SUM-
MERS
80
Investigations of Quaternary Pyridinium Salts,
VII. Quaternary Pyridinium Salts with Urea or
Carbamate Group. Preparation of Inner Salts
(In German)
W . - H . GÜNDEL
84
Chemistry of Carbon Subsulphide, III. Formation of
Pyrimidinthiones (In German)
W . STADLBAUER, TH. KAPPE, a n d E . ZIEGLER
89
Intramolecular Exchange Processes in Cyclopentadien Systems. Structural Dependence of
Activation Barrieres (In German)
K . ALBERT a n d J. HAMBRECHT
94
Synthesis and 13C NMR Spectra of £er£-Butylated
Cyclohexenone Epoxides (In German)
K.
ALBERT,
H.-P.
SCHNEIDER,
D.
A. RIEKER
KOCH,
and
100
Photoreactions of 2,2'-Dihalogen Substituted Benzoin Ether and Benzildimethylmonoketals in
Solution (In German)
C. BAK a n d K .
PRAEFCKE
106
Notes
Ternary Compounds of Sodium and Potassium with
Manganese and Elements of the 5. Maingroup
(In German)
H . - U . SCHUSTER a n d G . ACHENBACH
113
A Contribution to the Knowledge of Ternary Intermetallic Lithium-Phases with Zinc (resp. Cadmium and Indium) and Tin or Lead (In German)
W.
POBITSCHKA a n d H . - U . SCHUSTER
115
6 H - Dipjrrido [2,1 - b: 1', 2' - e] -1,3,5 - selenadiazinium
Dibromide: A Dipyrido Analogue of Selenaxanthene
H . G . GRANT a n d L . A . SUMMERS
118
Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung
in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der
Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht:
Creative Commons Namensnennung-Keine Bearbeitung 3.0 Deutschland
Lizenz.
This work has been digitalized and published in 2013 by Verlag Zeitschrift
für Naturforschung in cooperation with the Max Planck Society for the
Advancement of Science under a Creative Commons Attribution-NoDerivs
3.0 Germany License.
Zum 01.01.2015 ist eine Anpassung der Lizenzbedingungen (Entfall der
Creative Commons Lizenzbedingung „Keine Bearbeitung“) beabsichtigt,
um eine Nachnutzung auch im Rahmen zukünftiger wissenschaftlicher
Nutzungsformen zu ermöglichen.
On 01.01.2015 it is planned to change the License Conditions (the removal
of the Creative Commons License condition “no derivative works”). This is
to allow reuse in the area of future scientific usage.
IV
Contents
The Behaviour of Phosphinato Complexes of
Rhenium towards l,2-Bis(diphenylphosphine)ethane (In German)
E. LINDNER and H . - H .
OETJEN
120
Oxidation of Sulfur-Nitrogen Compounds to Sulfoxides by Peroxyacids (In German)
R . STEUDEL a n d F . ROSE
122
Preparation of the Manganese (II) Complex with
3,4-Dihydroxi-L-phenylalanine (L-DOPA)
(In German)
K . v . MARTIUS a n d K .
E . SCHWARZHANS
124
N-Methylsulfonyl and N-Phenylsulfonyl N-methylhydroxylamine (In German)
M . BACKHAUS a n d C. BLIEFERT
125
Indole[3,2 gjindolizidines via Sodium Borohydride
Reduction of Indolic Imides
W .
N.
SPECKAMP,
J.
DIJKINK,
P.
PASMAN,
J. C. HUBERT
and
127
Mass Spectrometric Investigation of Organic Nitrogen Compounds, X X I X . Electron Impact Induced
1,1-Elimination of Nitrenes from Silylated Hydroxylamine Derivatives (In German)
H.
SCHWARZ,
B.
STEINER,
G.
ZON,
and
Y.
CHANG
H.
129
Semiempirical Use of Chirality Functions for the
Description of the Optical Activity of Methan
Derivatives in the Transparent Region II
(In German)
W.
J. RICHTER
165
X-ray Photoelectron Studies of Pentacarbonyl
Chromium and Tungsten Complexes with Nitrogen Ligands (In German)
H . BINDER a n d D . SELLMANN
173
Synthesis of l,l,4,4-Tetramethyl-l,4-distanna-2,5cyclohexadiene and its Bis(copper(I)chloride)
Complex (In German)
G. E. HERBERICH a n d B . HESSNER
180
Investigations of Beryllium Chelates with Substituted Acetoacetanilides by Mass, NMR and
IR Spectroscopy (In German)
A . KETTRUP, P. ACKERMANN, a n d W . RIEPE
183
On the Coordination of Carbon Monoxide on Bis(dithiolato)-Iron Complexes (In German)
D . SELLMANN, P . KREUTZER, a n d E . U N G E R
190
Raman Intensities and Reactivity of Phenyl Vinyl
Ethers and Phenyl Vinyl Sulphides (In German)
R. R.
M.
BRAND,
M.
L.
HALLENSLEBEN,
H.
SCHENKEL, a n d E . D . SCHMID
Contents of Number 2
Original Communications
Reactions of Phosphanes MenP[OCH(CF3)2]3_n with
Hexafluoroacetone (In German)
G . - V . RÖSCHENTHALER
131
1,4-Dioxane • H 2 0 • SbCls; Vibrational Spectra,
Crystal and Molecular Structure (In German)
W . SCHWARZ, A . SCHMIDT, a n d G . E . BINDER
136
Tetramethylsilane - a Methylating Agent for Borontrihalides (In German)
W . HAUBOLD, A . GEMMLER, a n d U . KRAATZ
140
Preparation and Structure of [Ti(acac)3]C104
(In German)
U. THEWALT and T. ADAM
About Ba2Fe22+Fe93+Alii034
142
(In German)
H K . MÜLLER-BUSCHBAUM a n d M . HARDER
146
New Metal - Pentafluorothiophenol Compounds
D . M . KAMINARIS a n d A . G . GALINOS
149
The Crystal Structure of BaZn 2 P 2 and BaZn2As2
(In German)
P. KLÜFERS and A. MEWIS
151
About the Formation of Macrocyclic B-N-Compounds (In German)
A . MELLER a n d H . J. FÜLLGRABE
G. HELLER a n d D . MARQUARD
The Crystal and Molecular Structures of Methyl(4- Br- phenyl )amino - chlorpheny lborane,
(BrC6H4)(CH3)NB(Cl)(C6H5)
and Methyl(2-methyl-4-Br-phenyl)amino-chlor(2 - methy lpheny 1) - borane,
(BrC7Hti)(CH3)NB(Cl)(C7H7) (In German)
M . L . ZIEGLER,
RIETH, a n d H .
K . WEIDENHAMMER,
K.
AUTEN-
FRIEBOLIN
200
Synthesis of New Oxindolotrimethine Merocyanine
Dyes
Z. H . KHALIL
209
Thermal Decomposition of P,P-diphenyl-N-benzylphosphinothioic Amide and P,P-diphenyl-Nmethyl-phosphinothioic Amide
N . S. SRIDHARA
212
Angular Heterocycles: Studies in the Synthesis of
Some Substituted 6-Anilino-5-alkoxy-12H-benzo[ajphenothiazines
J. P. TIWARI and R . L. MITAL
214
Reactions with Heterocyclic Diazonium Salts, II.
Synthesis of Some New Pyrazolo[l,5-c]-astriazines and l,2,4-Triazolo[l,5-c]-as-triazines
M.
H.
ELNAGDI,
M.
R.
H.
ELMOGHAYAR,
FAHMY, M . K . A . IBRAHEIM,
and
H.
H.
S.
159
M.
ALNIMA
216
156
On the Perhydrolysis of Tris(alkoxy)boranes in the
Presence of Some Inorganic and Organic Bases
in Nonaqueous Solvents (In German)
K.
197
Spectroscopic Studies on Pyrazaboles
C. E . MAY, K . NIEDENZU, a n d S. TROFIMENKO
220
Substituent Effects in the Oxythallation of Alkenes
M . STRASAK
224
Contents
V
Selenium Heterocycles, III. Synthesis of Selenolo(2,3-b)quinolines
T. K.
RAJA, N . SOUNDARARAJAN, V .
BAKTHAVA-
CHALAM, a n d P . SHANMUGAM
228
Complexation of Tertiary Amides by Phenols in
Carbon Tetrachloride Solutions
E.
KWIATKOWSKI,
K.
KOZUBEK,
and
Z.
LINSKI
PEP230
Ion Pairs of Semiquincnes with Diorgano Thallium(III) Cations (In German)
K.
B.
ULMSCHNEIDER,
H.
B.
STEGMANN,
SCHEFFLER, a n d G . VIERTEL
K.
237
A Neutron Diffraction Study on the Modifications
of CuZrFe (In German)
V . PROPACH a n d F . STEFFENS
W.
MÜLLER and K .
VOLK
275
Chalcogenides of As, Sb and Bi as Positive Electrodes
in Lithium Cells (In German)
J. 0 .
BESENHARD
279
Photoelectron Spectra and Molecular Properties,
L X I X . Molecules with S—N Multiple Bonds (In
German)
B . SOLOUKI, H . BOCK, a n d 0 .
GLEMSER
284
Oxidation of Mandelic Acid by Os(VIII)
Notes
First Alkali Metal Thallium(I) Sulfides (In German)
E . GEHLE a n d H . SABROWSKY
241
Synthesis of Tri-ter£-butylstibine and Tetra-tertbutylcyclotetrastibane by Reaction of Di-tertbutylantimonychloride with Magnesium
(In German)
H . J. BREUNIG
242
Synthesis of Tetrakis(trimethylgermyl)-distibane
(In German)
H . J. BREUNIG
244
Tin-Chalcogen Heterocycles, VIII. Dimethyltin
Telluride, a Six-membered Ring (In German)
A . BLECHER a n d B . MATHIASCH
246
Optically Active Transition Metal Complexes, LV.
Preparation and Stereochemistry of
[C5H5Mo(CO)2NN']PFfl with NN' = Ethylenediamine and Propylenediamine (In German)
H . BRUNNER a n d M . MUSCHIOL
247
Isolation of w-Triacontane, Aliphatic Alcohols and
Sitosterols from Convolvulus Microphyllus Sieb
N.
268
The Structures of the Phases NagSru and NaisSn4
(In German)
P.
S.
BISHT,
R.
SINGH,
R.
K.
BANSAL,
and
P . SINGH
249
Book Beview
250
B. L . CHANDWANI a n d G. D . MENGHANI
291
Chemiluminescence of S02-0xidation (In German)
J. STAUFF a n d W .
JAESCHKE
293
The Alcoholysis Reaction of 3,5-Difluoro-l,l,3,5tetraoxo-2-alkyl-l A6,3A6,5A6,2,4,6-trithiatriazin
(In German)
D . - L . WAGNER, H . WAGNER, a n d 0 . GLEMSER
W.
STORZER a n d G . - V . RÖSCHENTHALER
305
The Insertion of Hexafluoroacetone into P - H Bonds
of Phosphanes Me«PH3 n (In German)
G . - V . RÖSCHENTHALER
311
Crystal and Molecular Structure of 4-Phenyl-1,2,3thiadiazol-3-oxide (In German)
W.
WINTER, U . PLÜCKEN, a n d H . MEIER
316
Radiolysis of Cytosine, 5-Methyl Cytosine and 2'Deoxycytidine in Deoxygenated Aqueous Solution. A Pulse Spectroscopic and Pulse Conductometric Study of the OH Adduct
A . HISSUNG a n d C. VON SONNTAG
321
Free Radical Induced Oxidation of Neutral
Aqueous Solutions of D-Glucose in the Presence
of Oxygen - a Non-Chain Process
M . N . SCHUCHMANN a n d C . VON SONNTAG
329
Properties of Molecules in Excited States
(In German)
Contents of Number 3
W.
Original Communications
The Tricarbonyl Iron Cycloheptatrienide Anion:
?73-Allyl Anion or r/4-Butadiene Complex ?
(In German)
P. HOFMANN
251
The Structure of the Cycloheptatrienide Tricarbonyl
Iron(O) Anion, [C 7 H 7 Fe(CO) 3 ]- (In German)
E . SEPP, A . PÜRZER, G . THIELE, a n d H .
300
Spin-Labeled Cyclic Oxyphosphoranes 4 - 0 x y - l oxyl-2,2,6,6-tetramethylpiperidine (In German)
BEHRENS
261
Vibrational Spectrum and Crystal Structure of the
cw-Dioxo-dipicolinato-vanadium(V) Anion
(In German)
B. NUBER, J. WEISS, a n d K . WIEGHARDT
265
FABIAN
332
Synthesis of Some 7,8-Disubstituted 2-Trifluoromethyl Phenothiazines and their Sulphoxides
M . MITTAL a n d R .
L. MITAL
336
Notes
The Dimeric Phosphinimine Complex
[CdI 2 (HN: PPh 3 ) 2 ] 2 Containing N - H - I Hydrogen Bonds
E.
W .
ABEL,
ST.
A.
MÜCKLEJOHN,
CAMERON, a n d R . E . CORDES
T.
ST.
339
Tri- and Tetraseleninato Complexes of Tin
(In German)
E. LINDNER a n d U . ANSORGE
341
Contents
VI
Potentiometrie Determination of the Dissociation
Constants of 3-Styryl- and 3-(2,2-Diarylvinyl)2-benzo[b]furancarboxylic, and 2-Styryl- and
2-(2,2-Diarylvinyl)-5-methyl-3-furancarboxylic
Acids
Y . ANGHELOVA, S. SPIROVA, a n d V .
MICHAYLOVA
343
Bentonite, a Layered Silicate in Electrophilic
Aromatic Substitution (In German)
J . GOSSELCK a n d W .
W .
LÖTZ
346
New Alkaloids from Prosopis juliflora DC
V . U . AHMAD, A . BASHA, a n d W .
HAQUE
347
Synthesis of Side Chain Hydroxylated Tetrahydrocannabinoles (In German)
F . LÖTZ, U . KRAATZ, a n d F . KORTE
P-Functionally Bridged
Complexes (In German)
Manganese
349
Carbonyl
H . SCHÄFER
13C,
351
XH
Spin-Spin Coupling Constants Part I I I :
Naphthalene (In German)
H . SEEL, R . A Y D I N , a n d H . GÜNTHER
353
Organoboration of Alkynylstannanes, VI. Formation of an Allene by Deorganoboration
(In German)
B. WRACKMEYER
385
Molecular Reactions in Cold Methane-Water Plasma
and the Elfect of UV Irradiation (In German)
CR. SIMIONESCU,
S. DUMITRIU,
V . I. POPA, a n d B .
V.
BULACOVSCHI,
SIMIONESCU
390
Reactions of Phosphorus Ylides with Transition
Metal Compounds, V. 1-Diphenylphosphinyl
Alkylidenetriphenylphosphorane Carbonyl
Chrom and Iron Complexes (In German)
L. KNOLL
396
1,3-Dionedioximes and their Metal(II) Complexes
with Ions Nickel(II), Palladium(II) and Platinum(II) (In German)
N . GOTTSTEIN a n d H . J . K E L L E R
399
Synthesis of Sulphones from Sulphonyl Fluorides
and Organometallic Compounds
A . I. KHODAIR, A . A . ABDEL-WAHAB,
and A.
EL-KHAWAGA
Optically Active Transition Metal Complexes, LVII.
( + )- and (—)-C 5 H 5 M(CO)(P0 2 R*)X with M =
Fe, " F e , and X = I, COCH3, CH3 (In German)
H . BRUNNER, M . MUSCHIOL, a n d W . N O W A K
Contents of Number 4
Contributions to the Chemistry of Phosphorus, 80.
About the Phosphorus Boron Three-Membered
Ring Compound (£-BuP)2BN(i-Pr)2 (In German)
M . BAUDLER, A . MARX, a n d J. HAHN
355
Synthesis and Characterisation of the Species
R - C 7 H 7 M O ( C O ) 3 and the X-ray Structure Determination of ??6-CH3-C-CH(CH3)-C7H7Mo(CO)3
II
O
(In German)
SOMMER,
K.
WEIDENHAMMER,
H.
WIENAND,
361
The Crystal Structure of RbGeCl3 (In German)
366
On Ternary Pnictides and Chalkogenides of Alkaline Metals and IB- resp. IIB-Elements
(In German)
G . SAVELSBERG a n d H . SCHÄFER
370
Preparation and Thermal Decomposition of Carbamoylphosphates of Alkaline-earth Metals
(In German)
F . SEEL a n d F . SCHINNERLING
374
AB 2 X 2 Compounds with the CaAl2Si2 Structure, IV.
The Crystal Structure of CaZn2Sb2, CaCd2Sb2,
SrZn2Sb2, and SrCd2Sb2 (In German)
A. MEWIS
R . TACKE and R . NIEDNER
412
Organic Sulfur Compounds, X X I X . Thiocarbonyl
Derivatives of 2-Thioxomalonic Acid Esters
(In German)
K . BEELITZ, G. HÖHNE, a n d K . PRAEFCKE
417
Aromatic Photosubstitution Reactions of Halogenated Benzoic Acid Benzylesters (In German)
C. B A K a n d K . PRAEFCKE
420
Synthesis and Some Reactions of Naphthoylacetanilides
a n d M . L . ZIEGLER
D . MESSER
407
Sila-Drugs, 9th Communication. Preparation and
Properties of Silicon Compounds with Potential
Curare-Like Activity, I (In German)
Original Communications
M.
M.
403
382
M . I. ALI, M . M . S. E L - M O R S Y , N . M . HASSAN,
and
M . SHARAF
425
Betaines as Intermediates in the Rearrangement of
a Spiro-oxiran into a Dioxolen (In German)
H . WITTMANN a n d H . SIEGEL
429
Synthesis and Mesomorphic Properties of Diphenyland Biphenylyl-pyrimidines
A . BOLLER, M . CEREGHETTI, a n d H .
SCHERRER
433
Neighboring Group Effects in the Aminolysis of
Esters, II. The Aminolysis of 2-(2-Hydroxybenzyl)phenylacetates (In German)
V . BÖHMER and K . WÖRSDÖRFER
439
The Nature of Zolon Red
A . M . QURESHI a n d A . N . PATEL
450
Novel Aspects in the Preparation of Phorone
M . KONIECZNY a n d G . SOSNOVSKY
454
VII
Contents
Notes
Preparation and Structure of Potassium 1,2-Diselenooxalate (In German)
CH. MATZ a n d R . MATTES
461
£-In2S3, a High Pressure Modification with Corundum Type Structure (In German)
K . - J . RANGE a n d M . ZABEL
463
Preparation and Structure of Dipotassium Sulfenothioxo-acetate(2-), K 2 [0 2 C-C(S)S0] • H 2 0, the
Salt of a Mixed 0,S-Peracid (In German)
S. BIELAK, K . MENNEMANN, a n d R . MATTES
465
Cis- and
trans-1,3-Diisopropyl-2,4-bis(diisopropylamino)-l,3,2,4-diazadiphosphetidine (In German)
0 . J . SCHERER a n d K . ANDRES
467
Synthetic Studies of amfi-Leukaemic Alkaloids, I X .
Some Aspects of the Chemistry of Catharanthine
ATTA-UR-RAHMAN, S. FIRDOUS, a n d A . BASHA
469
Synthesis of Chiral and Non-chiral Phosphites Containing the Hexafluoroisopropoxy Group
D.
DAKTERNIEKS,
G.-V.
RÖSCHENTHALER,
and
R . SCHMUTZLER
507
The Ionic Conductivity of Mixed Lithium Iodide
Samples (In German)
G . EICHINGER
14N NMR Studies
K.
511
on Aminophosphines (In German)
BARLOS, H . NÖTH, a n d B . W R A C K M E Y E R
515
Reactions of Lithio-aminofluorosilanes with Halogensilanes and Trimethylinchloride (In German)
U . KLINGEBIEL
521
Substitution and Ring Coupling at the Cyclotrisilazane System (In German)
D.
ENTERLING, U .
KLINGEBIEL, a n d A .
MELLER
Tetraphenylphosphonium - Isopolymolybdates
German)
527
(In
R . GRASE a n d J . FUCHS
533
Stereochemistry of the Metal-Metal Bond: Preparation and Structure of Co2(CO)4C5H5P(CH3)2
(In German)
Contents of Number 5
E. KELLER a n d H . VAHRENKAMP
Original Communications
Novel Silaza- and Silaoxaza-spiro[4,4] nonanes and
[4,5]decanes (In German)
U . W A N N A G A T a n d G . EISELE
471
Attempts for Synthesis of Inorganic Rings with
Phenylboric Acid (In German)
U . W A N N A G A T a n d G . EISELE
475
The Crystal Structure of S114SI6 (In German)
J. FENNER
479
KaPtSis, Synthesis and Crystal Structure (In German)
M . SPANGENBERG a n d W .
BRONGER
482
Crystal Structure of the Dimeric Dimethylantimony
Trichloride and Tetramethylantimony Hexachloroantimonate [(CH3)2SbCl3]2 and
[(CH3)4Sb]+[SbCl6]- (In German)
W .
SCHWARZ a n d H . - J . GUDER
485
1,1 -Dimethyl-1 -methoxy-1 A5phospholane and -phosphorinane: Synthesis, Structure and Dynamic
Behaviour (In German)
H . SCHMIDBAUR a n d P . HOLL
489
Crystal and Molecular Structure of N-(Trichlorogermyl)-trimethylphosphinimine
[Cl 3 Ge-N=PMe 3 ]7 l , n = 1 and 2 (In German)
W . S. SHELDRICK, D . SCHOMBURG, a n d W . W O L F S BERGER
493
Electrochemical Syntheses, XIV. Radical Cation
Salts of Naphthalene (In German)
H.
P.
FRITZ,
H.
GEBAUER,
P.
FRIEDRICH,
ECKER, R . ARTES, a n d U . SCHUBERT
P.
498
537
Tungsten Carbonyl Complexes with Nitrogen Hydride Ligands (In German)
D . SELLMANN, A . BRANDL, a n d R . ENDELL
Benzo-benzothiopyranoquinoline
Possible Antiparasitic Activity
Derivatives
A. ZAYED a n d J. METRI
542
of
554
Structural Effects on Nitrile Infrared Integrated
Intensities of Alpha,Beta-Diaryl Cyanoethylenes:
Hammett and Quantum Chemical Approaches
I.
JUCHNOVSKI,
R.
KUZMANOVA,
J.
TSENOV,
KANETI, a n d I. BINEV
J.
557
Notes
Layer Compounds of Polyanion-Forming Transition
Elements with Cation Exchange Capacity (In
German)
K . BENEKE and G. LAGALY
564
The Crystal Structure of Tetramethylstibonium
Tetrachlorogallate [(CH3)4Sb]+[GaCl4]- (In German)
H.-D.
HAUSEN,
H.
BINDER,
and
W .
SCHWARZ
567
Formation, Crystal Structure and Properties of
AU7P10I (In German)
M . BINNEWIES
570
Reaction of a Mixed Double Ylide with Ethylene
Oxide (In German)
H . SCHMIDBAUR a n d P . H O L L
572
Alkylsulfonyl Hydroxylamines
CH3(CH2)WS02NH0H ( n = 1.2.3) (In German)
U . HERMANN, M . YAKTAPOUR, a n d C.
BLIEFERT
574
Contents
VIII
Contents of Number 6
A Simple Method for Preparation of Catalysts for
Preparative Organic Chemistry (In German)
Original Communications
F . BÖLSING a n d A . HAKIM
On Derivatives of Hydrazine, VIII. Bis(trimethylsilyl)amino-isocyanate and -isothiocyanate
(In German)
N. WIBERG and G. HÜBLER
575
Crystal Structure of 2,2' -Bipyridine-bis (o- phenylenedioxy)phosphonium Hexafluorophosphate
(In German)
W .
S. SHELDRICK,
A.
SCHMIDPETER,
and
TH.
CRIEGERN
V.
583
The Crystal Structure of a Spirocyclic Cyclophosphazene NsPatNMeaMNHC^CHaNH) - Evidence for Intermolecular Hydrogen Bonding
Y.
SUDHAKARA
BABU,
H.
MANOHAR,
K.
RA-
MACHANDRAN, a n d S. S. KRISHNAMURTHY
588
On the Preparation and Crystal Structure of K3CU3P2
(In German)
G . SAVELSBERG a n d H .
SCHÄFER
590
LiaNaSru - a Phase with Puckered Nets of SixMembered Sn-Rings (In German)
K . VOLK and W .
MÜLLER
593
On Cyanatomercurates M 2 Hg 3 (NCO) 8 (M = K, Rb,
Cs) - Syntheses, Crystal Structures and Vibrational Spectra (In German)
G. THIELE a n d P . HILFRICH
597
Chemistry of Polyfunctional Ligands, XLIV. Preparation and Characterization of l,l,l-Tris(diiodarsinomethyl)ethane (In German)
J. ELLERMANN, H .
SCHÖSSNER, a n d H . A .
LIND-
NER
603
AB2X2-Compounds with the CaAl2Si2 Structure, V.
The Crystal Structure of CaMn2P2, CaMn2As2,
SrMn2P2, and SrMn2As2 (In German)
A. MEWIS
606
Cis-2-telhirium-l .3.2 A5,4A3-diazadiphosphetidine Crystal Structure of a Redox System Fluctuating
in Solution (In German)
S. POHL
610
Fluorescence and Proton Nuclear Magnetic Resonance Studies of Thallous Ions - Crown Ether
Complexes in Organic Solvents
T . PLATZNER, J. K . THOMAS, a n d M .
GRÄTZEL
614
The Different Colours of "NiO" (In German)
V.
PROPACH,
D.
REINEN,
H K . MÜLLER-BUSCHBAUM
H.
DRENKHAHN,
and
619
Production and Reaction of Singlet Oxygen in
Aqueous Micellar Solutions Using Pyrene as
Photosensitizer
N . MIYOSHI a n d G . TOMITA
622
Semiempirical SCF-Calculations of the Excited
States of Hydroxycoumarines (In German)
W . FABIAN
628
632
Synthesis of N-(Chloromethyl)carboximidoyl Chlorides (In German)
H . BÖHME, K . H . AHRENS, H . - J . DRECHSLER,
and
G. RUMBAUR
636
The Reactivity of the C=N-Double Bound System,
XIV. Reactions with 3,4-Dihydroisoquinoline
(In German)
E . ZIEGLER, W .
LEITNER, a n d H . STERK
640
Gas-chromatographic Investigation of Products
Formed by UV Irradiation of Uracil and Thymine
in Solution and Ice Matrix (In German)
E . FAHR, G. PH. ROTH, and P. WÜSTENFELD
646
Elementorganic Amino/Imino Compounds, XVIII.
Aminoiminothiophosphoranes: o 3 , A5-Phosphazenes (In German)
0.
J.
SCHERER,
N.-T.
KÜLBACH,
and
W.
GLÄS-
652
Mechanism of Hg(II) Oxidation of D-Galactose in
Alkaline Medium
SEL
M . P . SINGH, A . K .
SINGH, a n d M . K U M A R
657
Synthesis of 2-Methyl-l-phenylthiocarbamoylglyoxal Arylhydrazones and Diethy 1 (arylazo) (phenylthiocarbamoyl)malonate and their Reactions with Hydrazines
F . A . AMER, A . H . HARHASH, a n d M . L . A W A D
660
Short Time Pyrolysis, VIII. Reactions after C0Elimination from Quinoid Compounds
(In German)
G . SCHADEN
663
Reaction of B r 3 2 - with 2-Deoxy-D-ribose. A Preferred Attack at C-l
B.
J.
PARSONS,
D.
SCHULTE-FROHLINDE,
C. VON SONNTAG
and
666
Notes
About Occupation of Octahedral- and Tetrahedral
Positions of Bi2Ga2Fe209 (In German)
HK.
MÜLLER-BUSCHBAUM
and
D.
CH. DE
BEAU-
LIEU
669
Ternary Compounds in the Systems CalciumCopper-Phosphorus (Arsenic) (In German)
A . MEWIS a n d P . BLUMSTENGEL
671
Preparation and Association of Some Phosphiniminoboranes (In German)
W.
MARINGGELE,
A.
MELLER,
H.
NÖTH,
SCHROEN
and
R.
673
BaSb3, an Antimonide with an Infinite Twodimensional [Sb32_|n - Anion (In German)
K . DELLER a n d B . EISENMANN
676
The Crystal Structure of Na3AsS4 • 8 H 2 0
(In German)
G . DITTMAR a n d H . SCHÄFER
678
IX
Contents
The X-ray Structure of N 4 P 4 Cl 7 (NPPh 3 ) - a Novel
Conformation of the N P P I 1 3 Group
Y . S U D H A K A R A B A B U , H . MANOHAR, T . ST. CAMERON, a n d
R . A . SHAW
682
A NMR Study of the Exchange Kinetics of the
Nonamethylimidodiphosphoramide with its Complexes of Diamagnetic Cations
P.
R.
RUBINI,
L.
RODEHÜSER,
and
J.-J.
PUECH
DEL684
Is Phosgene Formed in the Thermal Decomposition
of Sodium Trichloroacetate ? (In German)
E. V. DEHMLOW and K . H. FRANKE
686
Note on the Absolute Configuration of Epoxipiperolide (In German)
R . H A N S E L a n d J . SCHULZ
688
690
Erratum
Tl6Ag2Iio, a Polyiodide with Ag 2 Pairs. Preparation,
Properties, and Crystal Structure (In German)
W .
STOEGER a n d A . RABENAU
S.
BALT,
Original Communications
M . BAUDLER a n d E . TOLLS
691
The Structure of 2,3,4,6,7,8-Hexamethyl-2,3,4,6,7,8hexaphosphabicyclo[3,3,0]octane (PMe)eC2H2
(In German)
MAY
698
Long-lived Radical Cations and Anodic Substitution
of Simple Arenes (In German)
P. FRITZ a n d H . GEBAUER
702
On the Crystal Structure of Sr5(Cr04)3Cl
(In German)
W .
DE
KIEVIET,
and
745
K . DEHNICKE a n d P. RUSCHKE
750
G . STRUCKMEIER, J . ENGEL, a n d U . THEWALT
753
Heterocycles Containing Arsenic (In German)
R O E S K Y a n d G . SIDIROPOULOS
756
H K . MÜLLER-BUSCHBAUM a n d K .
SANDER
G . SAVELSBERG a n d H . SCHÄFER
708
711
Crystallisation Processes in Metal Rich Rubidium
Oxides (In German)
H . J . DEISEROTH a n d A . SIMON
714
Crystal and Molecular Structures of Two transDiazadiphosphetidines (In German)
ZEISS
723
Synthesis and Crystal Structure of //-Oxo-bis(phosphenyl-orfÄo-toluidide)
T . ST. CAMERON, R . E . CORDES, a n d F . A . JACKMAN
728
Cation-Ordering in Synthetic Mg2-zFe.rSi04-01ivines
CH. RIEKEL a n d A . WEISS
R O E S K Y a n d K . AMBROSIUS
Spectra and Decay Kinetics of
Dioxetane Chemiluminescence
759
Diadamantyl-
C. NEIDL a n d J . STAUFF
763
Fragmentation of the a-Amino Acid Methionine in
Field Desorption Mass Spectrometry
J. VAN DER GREEF, N .
SCHULTEN, a n d W .
M.
M . NIBBERING,
D . LEHMANN
H.-R.
770
The Stereochemistry of P - N Bond Cleavage in the
Staudinger-Wittig-type Reaction of 2-Anilido3,4-dimethyl-5-phenyl-l,3,2-oxazaphospholidine2-thiones
K . LESIAK a n d W .
J . STEC
782
The Bimolecular Decay of the a-Hydroxymethylperoxyl Radicals in Aqueous Solution
Preparation and Crystal Structure of Na2AgAs and
KCuS (In German)
SCHWARZ, H . HESS, a n d W .
CHATTEL,
Crystal and Molecular Structure of 5,5'-Diethoxycarbonyl-3,3'-diethyl-4,4'-dimethyl-pyrromethene
Hydrobromide (In German)
H. W .
Contributions to the Chemistry of Phosphorus, 84.
1,2,3- Trimethyl-1,2,3 - triphosphole, (PMe)3C2H2,
and2,3,4,6,7,8-Hexamethyl-2,3,4,6,7,8-hexaphosphabicyclo[3,3,0]octane, (PMe)eC2H2 (In German)
W .
DU
The Ultraviolet Spectra of the Halogen Azides CIN3,
BrN3 and IN3 (In German)
H. W .
H.
G.
A . TIELEMAN
Reactions of 3-Trifluoromethylphenyl Substituted
Silicon and Tin Organic Compounds (In German)
C o n t e n t s of N u m b e r 7
H . - G . VON SCHNERING a n d W .
740
Ion Association and Solvation in Dichloromethane
of Tetrachloro- and Tetrabromoferrates(III)
Compared with Simple Halides
731
Electrochemical Intercalation and Electrical Conductivity of Graphite Fibers (In German)
J . 0 . BESENHARD, H . P . FRITZ, H . MÖHWALD,
and
J. J. NICKL
737
E . BOTHE a n d D . SCHULTE-FROHLINDE
786
Montanin-C, A New Furanoid Diterpene from
Teucrium montanum L
P. Y . MALAKOV, G. Y .
PAPANOV, N . M .
a n d ST. L . SPASSOV
MOLLOV,
789
Utilization of the Sterically Hindered Base, 4Hydroxy-2,2,6,6-tetramethylpiperidine, as a Hydrogen Halide Acceptor
G . SOSNOVSKY a n d M . KONIECZNY
792
Investigation of Inductive Effects on the Transphosphorylation Reaction of Spin-Labeled Phosphoryl Imidazolides, Part II
G . SOSNOVSKY a n d M . KONIECZNY
797
Investigation of Dipeptides by Electron Impact and
Field Desorption Mass Spectrometry (In German)
I. LÜDERWALD, M . PRZYBYLSKI,
a n d D . SILBERHORN
H.
RINGSDORF,
805
Investigation of Isomeric Tripeptides and Thyrotropin Releasing Hormone Derivatives by Elec-
Contents
X
tron Impact and Field Desorption Mass Spectrometry (In German)
I. LÜDERWALD, M . PRZYBYLSKI, H .
RINGSDORF,
D . SILBERHORN, H . KALBACHER, a n d W .
VOELTER
809
Notes
Deblocking of 2-Bromoethyl Esters via Thiazolium
Salts
T.-L. Ho
818
New Ternary Alkaline Earth Compounds of Arsenic
with Manganese (In German)
E . BRECHTEL, G . CORDIER, a n d H . SCHÄFER
820
Contents of Number 8
MÜLLER
SCHÄFER
827
CaAl2Se4 and SrAl2Se4 - Variants of the TlSe-Structure (In German)
KLEE and H.
SCHÄFER
829
The Crystal and Molecular Structure of (Pentane2,4-dionato) -tetrafluorophosphorane
W .
S. SHELDRICK a n d M . J . C. HEWSON
834
Molecular and Crystal Structure of 5,10-Dihydro5,10-dimethylphenaziniumtriiodide and 5,10-Dihydro-5,10-diethylphenaziniumtriiodide
(In German)
H . J. KELLER, W . MORONI, D . NÖTHE, M .
SCHERZ,
and J. WEISS
838
Crystal and Molecular Structure of a New Linear
Chain Compound: Bis(diphenylglyoximato)platinum(III)perchlorate
H . ENDRES, H . J . KELLER, H . VAN DE SAND,
and
V u
843
DONG
Behavior of (Halogeno)Acylphosphines Towards
Molecular Oxygen in Dependence of the Acyl
Residue (In German)
E . LINDNER a n d H .
LESIECKI
849
Organoboration of Alkynylstannanes, VIII. The
Reaction of Alkynyltrimethylstannanes with 1Boracyclopentanes and Methylbis(£erf-butyl)borane (In German)
A . SCHMIDT a n d B . W R A C K M E Y E R
855
CHaNHgSNBrJg-z (x = 0-3), a Sn(II)-System with
Cubic Perovskite Structure (In German)
D. WEBER
862
AggGeTe6, a Representative of the Argyrodite Family (In German)
J . VON UNTERRICHTER a n d K . - J . R A N G E
W .
BUCHHOLZ a n d H . - U . SCHUSTER
877
Preparation and Structure of Bicyclo-[4,4,0]-1,4,6,9tetraazadecane CeHi4N4 (In German)
W . M A Y a n d H . G . VON SCHNERING
881
Contributions to the Study of Inorganic Non-Stoichiometric Compounds, VII. A New Simple Method to Calculate Values of [(0,F)/Me] for Block
Structures (In German)
A . MELLER, W . MARINGGELE, a n d K . - D .
823
The Crystal Structure of /S-NaSbS2 (In German)
W.
873
H . HIBST and R . GRUEHN
Preparation and Crystal Structure of Li5Na2Sn4
(In German)
K . VOLK and H .
F . SEEL a n d F . SCHINNERLING
The Compounds MgFeßGee and LiCoöGeö
(In German)
884
Reactions of Metal and Metalloid Compounds with
Polyfunctional Molecules, XVIII. Synthesis of
Amidinoborazines (In German)
Original Communications
K . VOLK and W .
The Conversion of Calcium Hydrogenphosphate into
Calcium Diphosphate by Cyanate - a Prebiotic
Key Reaction ? (In German)
866
KABLAU
891
Spectroscopic Investigations in Solid State Chemistry, XII. Re NQR and *H Wideline NMR
Studies on Rhenium(VII) Oxygen Compounds
(In German)
P. K.
BURKERT a n d F. M. HUTTER
896
Transition Metal Substituted VB Element Systems,
12. Mono- and Dinuclear Transition Metal Complexes with Dihalogenarsenic Groups (In German)
W .
MALISCH, P . PANSTER, a n d R . ALSMANN
899
The Isolation and Characterization of Square Planar,
Square Pyramidal, and Octahedral Copper(II)
Complexes with Mixed Ligands
M. M. A L Y
906
Complex Chemistry of Reactive Organic Compounds, X X V . Stabilization of Diphenylmethylene and Diphenyldiazomethane in Carbonyl Cobalt Complexes (In German)
W .
A . HERRMANN a n d I. SCHWEIZER
911
A Contribution to the Composition of the Insecticide
"Toxaphene". Gaschromatographic-Masspectroscopical Characterisation of the Oily and the
Crystalline Fraction of Technical Toxaphene and
their Insecticidal Activity (In German)
H.
PARLAR,
S. NITZ,
A . MICHNA, a n d F .
KORTE
915
On the Chemistry of Pyrrole Pigments, X X I I I . The
Structure of a Bilatriene-abc Derivative in the
State of Solution (In German)
H . FALK, K . GRUBMAYR, a n d K . THIRRING
924
The Molecular Structure of Allenes and Ketenes,
X I I . Four-Bond Proton-Proton Spin-Spin Couplings in Allenes
W.
RUNGE
932
Contents
XI
Novel Rearrangement of 5-Arylazo-2-thiohydantoin
Derivatives with Alkali and Aromatic Amines
A . F. SHALABY, H . A . DABOUN, a n d M. A .
ABDEL
AZIZ
937
Photolysis (A 185 nm) of Liquid Tetrahydropyran
H.-P.
SCHUCHMANN, P . NADERWITZ, a n d
C.
VON
SONNTAG
942
Synthesis of Xanthone-O-glycosides, I. Synthesis of
3-0-ßGlycosides
V . M . CHARI, R .
RLAPFENBERGER, and H .
WAG-
946
NER
A. MEWIS
983
Complexes of Oxamic Acid with Al(III), Ga(III),
In(III), Tl(III), Y(III), Fe(III), Mn(III) and
V(III)
J. K .
KOUINIS, J . M . TSANGARIS, a n d A . G .
LINOS
A New Method for the Preparation of Carbo- and
Sulfurdiimides (In German)
U . KLINGEBIEL
950
Strontiumchromate(V, VI),
Sr2.67Do.33(Cr04)i.33(Cr04)o.67, a High-Temperature Compound with Defect-Bariumphosphate
Structure (In German)
K . HARTL and R .
BRAUNGART
952
Strontiumphosphate- Chromate (VI),
Sr3(P04)2 • SrCr0 4 , a Dimorphie High-Temperature Compound (In German)
K . HARTL a n d R . BRAUNGART
954
Crystal Structure of Sro.5Bao.5Si2 at High Pressures
(In German)
J . EVERS, G . OEHLINGER, a n d A . WEISS
956
On the Structure of Rutacridone (In German)
J. REISCH, Zs. RÖZSA, a n d I. MESTER
957
Contents of Number 9
Di4-butyl(trimethylstannyl)stibine and Tetrakis(trimethylstannyl)distibane (In German)
Derivatives of cis-NPCl2(NSOCl)2 and
(NPC12)2NS0C1, Part I X . Substitution Reactions
of cis-NPCl2(NSOCl)2 with Piperidine
H.
BAALMANN,
R.
KEIZER,
J.
C.
VAN
GRAMPEL, a n d C. K R U K
DE
959
Derivatives of as-NPCl2(NSOCl)2 and
(NPC12)2NS0C1, Part X . Aminolysis
NPC1 2 (NS0F) 2 and (NPC12)2NS0F
of
H . H . BAALMANN a n d J . C. VAN DE GRAMPEL
cis964
Preparation and Characterisation of Tetraalkylmamonium-lithium-phthalocyanines (In German)
H . HOMBORG a n d W .
KALZ
968
A Convenient Praparation Method of Anhydrous
Sodium Dithiocarboxylates (In German)
S. K A T O ,
K.
ITO,
R.
HATTORI,
M.
MIZUTA,
T. KATADA
and
976
Molecular and Electronic Structure of the Thiohetero Anion [S2WS2C0S2WS2]2_ (In German)
A . MÜLLER, N , MOHAN, a n d H . BÖGGE
978
990
15N
NMR Spectroscopy of Hydrazoic Acid and
Chlorine Azide (In German)
J. MÜLLER
993
Reduction of Induction Periods and Increase of
Activity of Homogenous Iridium Hydrogenation
Catalysts (In German)
E. HITZEL
997
Complexes of Some Platinum Metals with p-Diethylamino Anil of Phenyl Glyoxal
H . S. VERMA a n d R . C. SAXENA
1001
Synthesis and Biological Activity of Some New
Benzthiazoloazetidin-2-ones and Benzthiazolothiazolidin-4-ones, IV
K H . M . HASSAN, A . M . MAHMOUD, a n d H . A .
SHERIEF
EL1005
The Unusual Reaction of 1,2-5,6-Di-O-isopropylidene Glucofuranose (Diacetoneglucose) with the
System Triphenylphosphine/Azodicarboxylate (In
German)
H.
Original Communications
GA987
H . J. BREUNIG
Notes
H.
A B X Compounds with the Structure Ni2ln. Preparation and Crystal Structure of CaCuP(As),
SrCuP(As), SrAgP(As), and EuCuAs (In German)
K U N Z a n d P . SCHMIDT
1009
Syntheses with Aliphatic Dialdehydes, X X V I I . A
Non-Template Synthesis for the Preparation of
Metal-Free l,4,8,ll-Tetraaza[14]annulene Derivatives (In German)
CH. REICHARDT a n d W .
SCHEIBELEIN
1012
The Reactivity of the C=N-Double Bond System,
X V . The Reaction of Anilinomethylene-barbituric Acids with Methyleneactive Nitriles (In German)
H.
WIPFLER,
E.
ZIEGLER,
and
0.
S.
WOLFBEIS
1016
Behaviour of 5-Hydroxykawain Derivatives under
Mild Alkaline Conditions (In German)
R . HANSEL, J . SCHULZ, A . PELTER, M . T .
a n d R . REINHARDT
AYOUB,
1020
Determination of Ring Current Anisotropy Effects
in the XH NMR Spectra of 9-Phenyl Derivatives
of 1,4-Dimethylanthracene and 1,4-Dimethyltriptycene (In German)
H.-D.
ESSWEIN a n d G. HÄFELINGER
1026
XII
Contents
Utilization of Various Phosphoryl Halides and
Imidazolides for the Conversion of Aldoximes to
Nitriles
M . KONIECZNY a n d G . SOSNOVSKY
Reaction of Trivalent Organophosphorus
pounds with Selenium
1033
A . JUNGBAUER and H . BEHRENS
1083
Com-
New Intercalation Complexes of
chloride, FeOCl (In German)
Iron(III) Oxi-
M . KONIECZNY a n d G . SOSNOVSKY
1040
Notes
A1(H 2 P04)(HP04)(H 2 0), an Acid Phosphate with
Two-Dimensional A l - O - P Linking (In German)
R . KNIEP, D . MOOTZ, a n d A . WILMS
1047
On 2.2'-Biphenylylenephosphoric Acids and the Gas
Chromatographic Separation of Lewis-Bases on
Bis(2,2' - biphenylylenedithiophosphato)nickel(II)
(In German)
W .
KUCHEN and H .
F. MAHLER
1049
Preparation and X-ray Structure of 2-Methylthio1,3,2-benzodithiastibole (In German)
M . WIEBER, CH. BURSCHKA, a n d U . BAUDIS
1051
A Contribution on the Synthesis and Reactivity of
Nitrosyl Complexes. Direct Preparation of Thiocyanatonitrosyl Complexes and of
[ M O ( N O ) ( C N ) 5 ] 3 - (In German)
S. SARKAR a n d A . MÜLLER
1053
Structure of 4-Arylazo-3-methylisoxazol-5-thiones
L . A . SUMMERS
1056
Photoelectron Spectra of Dithiapropellanes
M. KOBAYASHI and R .
1057
M . PRASHAD, M . SETH, a n d A . P . BHADURI
1059
New Syntheses of ReNCl3 (In German)
LIESE a n d K .
DEHNICKE
1061
Preparation of Phthalocyanines of lb-Elements in
Aprotic Solvents (In German)
KALZ
1063
The Oxidation of Phthalocyanines: Preparation and
Characterisation of Lithiumphthalocyanine(l-)
(In German)
KALZ
1067
N-Sulfonylsulfimides (In German)
H.
W .
ROESKY,
M.
ARAMAKI,
Preparation
P . PERINGER
G . BIENEK, W . TUSZYNSKI, a n d G . GLIEMANN
L.
SCHÖN-
FELDER
1072
Preparation and Crystal Structure of KAu4Sn2
(In German)
H . - D . SINNEN a n d H . - U . SCHUSTER
1077
NaMgAs(Sb) - Ternary Compounds in a Modified
Cu2Sb Structure (In German)
B . K R E N K E L a n d H . - U . SCHUSTER
1080
1095
The Mechanism of the Sorption of Monovalent
Cations on Cobalt(II)-hexacyanoferrate(II)
T.
CERANIC,
D.
TRIFUNOVIC,
and
R.
ADAMOVIC
1099
The Crystal Molecular Structure of the Adduct
of 2,2,2-Trifluoro-4,4,5,5-tetrakis(trifluoromethyl)l,3,2A5-dioxaphospholane with Trimethylphosphine. A Strong P-^P Coordinate Bond
W .
S.
SHELDRICK,
J.
A.
GIBSON,
and
G.-V.
RÖSCHENTHALER
1102
Thermal Analysis of the Cadmium and Manganese
Hydrogen Orthoarsenate Monohydrates
(M HAs0 4 • H 2 0, where M = Cd, Mn)
1106
Preparation of Cyclopentadienyl-vanadylidyne-tricobaltenneacarbonyl (In German)
H . J. HAUSTEIN a n d K . E . SCHWARZHANS
1108
Bis[-//-methyl-l,3-dimethyl-h3-allyl-nickel].
The Bonding in an Alkyl-Bridged Ni-Ni System
(In German)
J.
C. SEKUTOWSKI,
H.
BERKE,
and
1110
The Influence of the Exchangeable Monovalent
Cations on Vibrations of Y Zeolite Framework
V . M . R A D A K , T . S. CERANIC, a n d I . M .
NOVTC
2IVADI1116
Metal(II) Complexes of 1,2,5-Oxadiazole
W.
L . DRIESSEN a n d P . L. A . EVERSTIJN
1120
Reactions of Transition Metal-Tyrosine Complexes
with Potassium Nitrosodisulfonate (In German)
K . v . MARTIUS a n d K . E . SCHWARZHANS
and
and
1091
R . HOFFMANN
Original Communications
H . HOMBORG a n d W .
1087
-
The Electronic Single Crystal Spectrum of Binuclear
Rhodium(II)acetate Hydrate
Rh2(CH3COO)4 • 2 H 2 0
C. KRÜGER,
C o n t e n t s o f N u m b e r 10
H . HOMBORG a n d W .
A . W E I S S a n d E . SICK
N-Organomercury-triazenes
Properties (In German)
M. A . NABAR and A. P. DALVI
GLEITER
Unusual Grignard Reaction of a-Arylcinnamonitriles
W .
Syntheses and Spectral Data of New Substituted
??5-Cyclopentadienyl Ruthenium Carbonyl Cations
(In German)
1124
Transition Metal Methylene Complexes, VI. On the
Irreversible //-Methylene/Carbonyl Isomerization
of Binuclear Cobalt Complexes with Bifunctional
Methylene Ligands (In German)
W .
A . HERRMANN a n d I. SCHWEIZER
1128
The Delayed Fluorescence of Indole in AlcoholAlkane Mixed Glasses at 77 K
S. YAMASHITA a n d G. TOMITA
1136
Contents
XIII
Montanin-D, a New Furanoid Diterpene of Clerodane Type from Teucrium montanum L.
P. Y .
and
S.
MALAKOV, G. Y .
L.
PAPANOV, N . M .
MOLLOY,
SPASSOV,
1142
Cleavage Reactions of Oxazolin-5-ones Reactions
with 4-Substituted-2-aryl-2-oxazolin-5-ones
N . A . KASSAB, A . H . HARHASH, a n d S. A .
HALT
ELBA-
CH.
WESDEMIOTIS,
H.
SCHWARZ,
F.
BORCHERS,
HEIMBACH, a n d K . LEVSEN
1150
Reactions of f-Butyl Peresters, XVI. Reactions of
Dialkyl f-Butylperoxy Phosphates and Alkyl
f-Butylperoxy Alkylphosphonates with Cycloalkenes in the Presence of Copper Ions
G . SOSNOVSKY a n d G . A . K A R A S
1165
Reactions of /-Butyl Peresters, XVII. The Photochemical Reaction of Dialkyl f-Butylperoxy
Phosphates and Alkyl f-Butylperoxy Alkylphosphonates with Cyclohexene and Cyclopentene in
the Presence of Copper Ions
G . SOSNOVSKY a n d G . A . KARAS
1177
On Thiotitanates(IV): Synthesis and Structure of
Cs2[TiS3] (In German)
D.
R A D a n d R . HOPPE
1184
Bis(trimethylstannyl)lithiumphosphide (In German)
H.
SCHUMANN,
L.
RÖSCH,
and
W .
SCHMIDT-
FRITSCHE
1186
Redistribution Reactions of Monoorganothallium
Compounds (In German)
1188
U . POHL and F. HUBER
N-SalicylideneL-D,L-valinato-thiourea-copper(II)
Complex (In German)
0.
SVAJLENOVÄ a n d J .
KRÄTSMAR-SMOGROVIC
N- (Dimethylaminosulfonyl )hy droxylamine,
(CH 3 ) 2 NS0 2 NH0H (In German)
J.
OETTLE, K .
BRINK, G. MORAWIETZ, M .
HAUS, M . BOLDHAUS, a n d C. BLIEFERT
1191
J.
STEIDEL,
T.
SANDOW,
and
BACK1193
EISENBARTH a n d W .
SUNDERMEYER
1194
Unusual Formation of Carbamate Salts: an Experimental Proof for the Mechanism of the Removal
of Carbobenzoxy Group by Catalytic Hydrogenolysis
I . SCHÖN a n d L . K I S F A L U D Y
1196
F.
1198
H . JUNEK, B. UNTERWEGER, a n d R .
PELTZMANN
1201
1204
Erratum
C o n t e n t s o f N u m b e r 11
Portrait of E. 0. Fischer
1205
Original Communications
A New Way to Determine Smallest Amounts of
H 2 0 by Means of Ph 3 P and CC14 (In German)
R . APPEL, W .
MICHEL, a n d W .
MORBACH
1205
Contributions to the Chemistry of Phosphorus, 85.
Synthesis and Properties of the Diphosphiranes
(*-BuP)2CMe2 and (f-BuP)2CH2 (In German)
M . BAUDLER a n d F . SAYKOWSKI
1208
Strong Organometallic Lewis Acids: Tricarbonyl-7rcyclopentadienyl Cations of Molybdenum and
Tungsten [(7i-C5H5)(OC)3M]+ (M = Mo, W)
(In German)
BECK and K .
SCHLOTER
1214
Substituent Effects and Perturbation of n Systems,
X X X V . Radical Anions of Tin-Substituted Naphthalenes (In German)
H.
BOCK, W .
K A I M , a n d H . TESMANN
1223
Stable Mercury (I)-Selenium Compounds, 2 nd Communication. The Structure of the Red Modification
of Tetrakis(diphenyl-seleno)-dimercury(I)-bis(chlorate(VII)) (In German)
K.
BRODERSEN,
G.
LIEHR,
M.
ROSENTHAL,
G. THIELE
and
1227
Optically Active Transition Metal Complexes, LIX.
(+) 4 3 6 - and (—) 436 -C 5 H 5 Fe(CO)(COCH 3 )P0 2 R*.
The Equilibrium C5H5Fe(CO)2CH3 + PR 3
C 5 H 5 Fe(CO)(COCH 3 )PR 3 (In German)
H . BRUNNER a n d H .
Tetrakis - difluorooxosulfurimidato-metallates (II),
[M(NSOF 2 ) 4 ] 2 -, (M = Hg, Co, Pd) (In German)
R.
STEUDEL,
A Simple Synthesis of Tetrahydroxy-benzoquinone1,4 (In German)
W .
Notes
H.
R.
SCHUSTER
1145
Mass Spectrometric Investigations on the Formation of [M-Me]+, [M-Et]+, [C7H7]+ and [C7H8]+from
Butyl and w-Pentyl Benzenes: Time
Dependent Neighbouring Group Participation,
Isomerization and Competitive Hydrogen Rearrangements (In German)
H.
Convenient Preparation and Vibrational Spectra of
Cyclodecasulfur, Sio, and of the Adduct SÖ • Sio
VOGT
1231
The Crystal Structure of Bis(cyclopentadienyl)manganese, a Polymeric Compound with Cyclopentadienyl Bridges (In German)
W .
BÜNDER and E. WEISS
1235
On the Chemistry of the Surface of Titaniumoxide,
V. Surface Acidity of Titanium Dioxide and of
Titanium Dioxide Covered with Adsorbed Phosphate Ions (In German)
J . CORNEJO, J . STEINLE, a n d H . P . BOEHM
1238
Molybdenumnitridobromide, MoNBr3 (In German)
K . DEHNICKE a n d N . KRÜGER
1242
XIV
Contents
High Power Density Lead Acid Cell Operating at
70 °C
H . P . FRITZ, J. 0 . BESENHARD, a n d A . S. PAXINOS
1245
(CO)5CrFe2(CO)6PPh, a Tetrahedral Cluster Containing an Eightfold Coordinated Chromium (0)
(In German)
G. HUTTNER, G. MÖHR, a n d P . FRIEDRICH
1254
Molecular Structure of 7-Methyl-l,3,5-triaza-7phosphaadamantane - 7 -ium - tetrafluoroborate.
Preparation and Characterization of 7-MethylI,3,5-triaza-7-phospha-tricyclo[3,3,2,l3'7]undecan-7-ium-iodide (In German)
K.
H.
JOGUN,
J.
J.
STEZOWSKI,
E.
FLUCK,
H . - J . WEISSGRAEBER
and
1257
Crystal and Molecular Structure of a Linear Chain
Solid with Three Different Metal Chains:
[Pt(dapn)2][Pt(dapn)2Br2][(Cu3Br5)2]
(dapn = 1,2-diaminopropane (In German)
H . J. KELLER, R . MARTIN, a n d U . TRAEGER
1263
A Novel Association of Potassium and Co-ordinated
Dinitrogen - Crystal Structure of KN2Co(PMe3)3
(In German)
H.-F.
KLEIN,
R.
HAMMER,
J.
WENNINGER,
P . FRIEDRICH, a n d G. HUTTNER
1267
NMR Spectroscopy on Paramagnetic Complexes,
X I X . 13C and *H NMR Access to Bent Titanocenes
(In German)
F . H . KÖHLER a n d D . COZAK
1274
Surface Compounds of Transition Metals, X X .
Complexes of Surface Chromium(II) with Olefines
(In German)
H.-L. KRAUSS and U . WESTPHAL
1278
Photochemical Reactions of Transition Metal Olefin
Complexes, II. The Reaction of Tricarbonyljj-l,3,5-cycloheptatriene-chromium(0) with Substituted Fulvenes (In German)
C. G. KREITER a n d H . K U R Z
1285
Metal Complexes with Anionic Ligands of Elements
of the Main Group IV, XI. Homogenous Trichlorostannido Metalate(O) Complexes of the
Transition Groups VI and VIII (In German)
TH. KRÜCK, W . THIELMANN, a n d CH. SAUER
1291
Preparation and Properties of and Reactions with
Organometallic Heterocycles, I. Organometallic
Complexes of Manganese and Rhenium with two
Functional Centres (In German)
E . L I N D N E R , G . VON A U , a n d H . - J . E B E R L E
1296
The Radical Cp(C0)3Cr in Solution (In German)
TH. MADACH and H . VAHRENKAMP
1301
BACH
J. MÜLLER and W .
HOLZINGER
1309
Contributions to the Chemistry of Boron, XCIX.
Borylphosphine Metal Carbonyls of Group VI
Transition Metals (In German)
H . N Ö T H a n d S. N . SZE
1313
Synthesis and Chemical Transport of Ternary
Compounds, Investigated with
CoO + Nb 2 0 5 = CoNb206 (In German)
H.
SCHÄFER a n d M . TRENKEL
1318
Elementorganic Amino/Imino Compounds, X I X .
Phospha(III)azene Complexes of Platinum
(In German)
0 . J . SCHERER, N . K U H N , a n d H . JUNGMANN
1321
Some Gold(I) Complexes of Phosphorus Ylides and
their Effect in Gold Therapy with the Adjuvans
Arthritis Model (In German)
H.
SCHMIDBAUR, J . R .
MANDL, A .
WOHLLEBEN-
HAMMER, a n d A . FÜGNER
1325
Four- and Five-Membered Phosphorus Heterocycles, X X X I V . Cj^cloadducts from Phosphazenes of Coordination Number 2, 3, and 4
(In German)
A . SCHMIDPETER a n d T H . VON CRIEGERN
1330
Synthesis and Properties of Di-hydrogensulfido,
Di-hydrogenselenido and Di-sodiumsulfido Complexes of Palladium(II) and Platinum(II)
(In German)
M . SCHMIDT a n d G . G . HOFFMANN
1334
Di-//-methoxi-bis[dicarbonyl(tri-<er<-butylphosphine)ruthenium(I)](Ru-Ru) (In German)
H.
SCHUMANN a n d J . OPITZ
1338
N2H4 Coordination on Iron Sulfur Centres: Synthesis
and Structure of
[N(C4H9)4]2[//-N2H4{Fe(S2C6H4)2}2] (In German)
D.
SELLMANN,
P.
KREUTZER,
G.
HUTTNER,
A. FRANK
and
1341
Preparation, Crystal Structure and Infrared Spectrum of [M0NCI3 • P0C13]4 (In German)
J. STRÄHLE, U . WEIHER, a n d K . DEHNICKE
1347
Photochemical Reductive Jra/w-Elimination from
fraTts-Diacidotetracyanoplatinate(IV) Complexes
A.
VOGLER,
A.
KERN,
B.
HÜTTERMANN
FUSSEDER,
and
J.
1352
A Lead Dioxide Reference Electrode (In German)
D. W A B N E R , F . H I N D E L A N G , and R. Huss 1357
Binuclear Complexes Containing a Heterometallic
Palladium-Platinum Bond (In German)
H . WERNER and A. KÜHN
1360
MER-
Preparation and Structure of the Complex
[C5H5Cr(NSiMe3)2]2 (Reaction of Cyclopentadienylmetal Chlorides with Bis(trimethylsilyl)diazene) (In German)
1304
N . W I B E R G , H . - W . HÄRING, a n d U . SCHUBERT 1 3 6 5
On New Dinuclear Metal Carbonyl Complexes with
Cyclohexadienyl Cycloheptatriene and Cyclohexadienyl Isonitrile Bridges (In German)
M . MOLL, P . WÜRSTL, H . BEHRENS, a n d P .
Tetraisopropylchromium as Starting Material for the
Synthesis of Chromium Complexes (In German)
Contents
VX
C o n t e n t s o f N u m b e r 12
Preparation and Crystal Structure of Li2ln and
Lii3ln3 (In German)
Original Communications
J . STÖHR, W .
Metal Complexes with Tetrapyrrole Ligands, X I X .
Synthesis and Electrochemical Characterization
of Thiocarbonyl Metallooctaethylporphyrins with
Iron(II) or Osmium(II) in the Center. A Contribution to the "Rule of Bathochromism"
(In German)
J. W .
BUCHLER, W .
KOKISCH, P . D . SMITH,
B. TONN
and
1371
Diazadiene Nickel Complexes, I : Bis(diazadiene)
Nickel(O) and Bromo-diazadiene Nickel(I)
(In German)
H . TOM D I E C K , M . S V O B O D A , a n d J . K O P F
1381
Chemistry of Polyfunctional Ligands, 48. Synthesis,
Vibrational Spectra, Molecular and Crystal Structure of an Organocyclotriarsane-pentacarbonylchromium Complex (In German)
J. ELLERMANN,
H.
A. LINDNER,
H.
SCHÖSSNER,
G . THIELE, a n d G. ZOUBEK
1386
Tris(pentahaptocyclopentadienyl)uranium(IV)
Halides and Pseudohalides as Lewis-Acids: Preparation and Structure of Uranium Organyls
[(^5-C5H5)3UXL] with Trigonal-Bipyramidal Coordination (In German)
R . D . FISCHER, E . KLÄHNE, a n d J . K O P F
1393
Organometallic Polychalcogenide Chelates, X . Disulfidobis(?;5-cyelopentadienyl)molybdenum(IV),
a Pseudotetrahedral Disulfide Chelate
(In German)
H . KÖPF, S. K . S. HAZARI, a n d M . LEITNER
1398
Transition Metal Substituted Phosphines, Arsines
and Stibines, XVIII. Evidence for a Conformational Isomerism of Dicarbonyl(cyclopentadienyl)iron Substituted Arsines (In German)
W.
MALISCH a n d P . PANSTER
1405
Synthesis, Properties and Structure of the Cyclopentadienyl( 1,3-diborolenyl)nickel Sandwich
(In German)
W .
SIEBERT, M . BOCHMANN, a n d J . E D W I N
1410
Preparation and Reactions of S-Trifluoromethyl
Sulfurmonofluoride Imides (In German)
I. STAHL, R . MEWS, a n d 0 .
GLEMSER
1417
Synthesis of Some Phenyl and Trifluorovinyl Substituted Phosphanes (In German)
H.-G.
HORN,
R.
KÖNTGES,
F.
H . CH. MARSMANN
KOLKMANN,
and
1422
Reactions of Tris(trifluorovinyl)phosphane with
Organic Lithium Reagents or Substituted Lithium
Phosphides (In German)
H . - G . HORN a n d F. KOLKMANN
1427
Preparation and Crystal Structure of CaRh 2 B 2 and
Cah*2B2 (In German)
B . SCHMIDT a n d W . JUNG
1430
M Ü L L E R F, a n d H . SCHÄFER
1434
Synthesis and Properties of Iron and Molybdenum
Complexes with Sulfur Ligands (In German)
D . SELLMANN a n d E . UNGER
1438
CH 3 NH 3 PbX 3 , a Pb(II)-System with Cubic Perovskite Structure (In German)
D. WEBER
1443
Studies on Nitrogen-Iodine Compounds, XVII.
Further Tertiary N-Bases as Stabilizers of the
Iodonium Cation and Iodine Halides (In German)
J. JANDER a n d A . MAURER
1446
Tri(ter£-butyl)phosphine Imine (In German)
W .
WOLFSBERGER
1452
Bifunctional Acyl(diorganyl)phosphanes and their
Behavior Towards Molecular Oxygen
(In German)
E . LINDNER a n d G. VORDERMAIER
1457
Compound Formation in the System Ag2S-GeS2-AgI
(In German)
A. NAGEL a n d K.-J. RANGE
1461
Silicon Compounds with Strong Intramolecular
Steric Interactions, VII. Tri-£er£-butylsilicon
Pseudohalides (In German)
M . WEIDENBRUCH a n d H . PESEL
1465
Silicon Compounds with Strong Intramolecular
Steric Interactions, VIII. New Siloxane Compounds of Some Transition Metals (In German)
M.
WEIDENBRUCH,
C. PIERRARD,
and
H.
PESEL
1468
Azido and Isocyanato Trichloro
Aluminate (In German)
Borate
L . CHOW, F . SCHMOCK, a n d U . MÜLLER
and
1472
Halo-Elpasolites, IV. On Bromo-Elpasolites
Cs2B1MIIIBr6 (Bx = Li, Na; M m = Sc, Y, La-Lu,
In, V, Cr) (In German)
G . MEYER a n d H.-CH. GAEBELL
1476
Kinetic Study of the Acid Hydrolysis of Ethyl
Hydrogen Succinate in Binary Solvent Mixtures
F . Y . KHALTL a n d M . T . HANNA
1479
The Structure Model of an Inorganic Ion Exchanger
Cobalt (II) -hexacyanoferrate (II)
T . CERANIC
1484
NMR Studies on Organoelement(IVb)-phosphines,
V. 59 Co-NMR, IR and UV Spectroscopic Investigations on Organoelement(IVb)Substituted
Complexes of Tricarbonylnitrosylcobalt
(In German)
H.
SCHUMANN,
M.
MEISSNER,
and
H.-J.
KROTH
1489
Synthesis of New Furobenzoxazole and Furoflavone
Derivatives
O.
H.
HISHMAT,
K.
M.
KHALIL,
EBRASHI, a n d M . N . M . KHODEIR
N.
M.
A.
EL1491
XVI
Contents
Heavy Atom Kinetic Isotope Effects in HCN
Elimination from Some Tricyanides in Methanol
F. M . FOUAD a n d P. G. FARRELL
1496
Synthesis of 5,6-Diaryl-l,2,4-triazines
E L S. A . IBRAHIM, S. A . SHAMS E L D I N E , F . S.
SOLIMAN, a n d I. M . LABOUTA
G.
1503
Studies on Ferrocene and its Derivatives, VI. Cyclocondensation Reactions of Some Ferrocenyl Anils
K H . M . HASSAN
1508
Synthesis of Some New Spiro Heterocyclic Nitrogen
Compounds, II
KH.
M.
HASSAN,
A.
K.
EL-SHAFEI,
and
H.
EL-KASHEF
S.
1515
Carbenium Periodides, I (In German)
M . J. VOLZ-DE LECEA
1520
On the Pigment of the Gram Staining of Bacteria
(In German)
M . J. VOLZ-DE LECEA
1525
Hydrazine Derivatives of ß-T>icarbonyl Compounds,
Part I. Studies on Some Benzoylacetaldehyde
Aroylhydrazones
L.
RATEB,
B.
AZMY,
M.
A.
NASHED,
and
M.
ISKANDER
F.
M . HARGREAVES, R . MCDOUGALL, a n d L .
RABARI
1535
Syntheses of Heterocycles, CCVIII. The Chemistry
of Vicinal Triketones, X I . Ringcontractions of
Quinolinetriones (In German)
H . WITTMANN a n d F. GÜNZL
1540
13C
NMR Spectra of Chromeno- and Prenylated
Flavones Structure Revision of Mulberrin, Mulberrochromene, Cyclomulberrin and Cyclomulberrochromene
M.
CHARI,
Redetermination of the Crystal and Molecular
Structure of Cyclohexasulfur, SÖ
J . STEIDEL, J. PICKARDT, a n d R . STEUDEL
1554
Tri(£er£-butyl)phosphine Oxide, Imine, Methylene
and Borane (In German)
H.
SCHMIDBAUR a n d G . BLASCHKE
1556
Exchange Reactions of Complexed Ligands of
Elements of Group Vb, VI. Lithiation of
if - CöHöMn (CO) 2PH3 (In German)
M.
HÖFLER,
H.
HAUSMANN,
and
A.
SCHNEIDER
1559
Fluorination of Ammine Complexes of Platinum(IV)
in Aqueous Solution (In German)
J. JANDER and H .
0. MAYER
1561
An Unusual Intramolecular Photoreaction of a
Hexachlorohexahydromethanonaphthaline
(In German)
H . PARLAR
1563
1565
Book Reviews (In German)
1527
3-Mercaptodihydrocarvone (True Carvone Hydrosulphide) and (1S, 4S, 5S)-4,7,7-Trimethyl-6-thial,5-bicyclo-[3,2,l]-octan-3-one
V.
Notes
S. AHMAD,
and
B.-G.
0 . S. WOLFBEIS
J. KIEFER,
D.
SHAW,
Ultraviolette Strahlen
(G.
GAUGLITZ)
250
Fourier Transform NMR Spectroscopy
( W . VOELTER)
1565
Fundamental Aspects of Organic Mass
Spectrometry ( K . - P . Z E L L E R )
1565
K . LEVSEN,
E r r a t a in t h i s V o l u m e
ÖSTERDAHL
1547
The Reactivity of C = N Double Bond Systems, X V I .
Synthesis of 2-Hydroxy-6-oxo-l,6-dihydro-pyridines (In German)
E . ZIEGLER, H .
B o o k R e v i e w s in this V o l u m e
WIPFLER, A . KNIERZINGER,
To M.
To M.
BAUDLER
BAUDLER
et al. (33b, 357 [1978])
et al. (33b, 691 [1978])
690
1204
and
1550
Portrait of E. 0 . Fischer
1205