UV and VIS Radiation Meters for Environmental Monitoring 1) Petro SMERTENKO, Vitaliy KOSTYLYOV, Ivan KUSHNEROV, Olexandra SHMYRYEVA, Eduard MANOILOV, 2) Mykola BRYCHENKO, Valeriy KRUGLOV, Anatoliy MARYENKO, Rostislav STOLYARENKO, 3) Yaroslav BLUME 4) Don J. DURZAN 1) V.Lashkaryov Institute of Semiconductor Physics, Department of Optoelectronics, National Academy of Sciences of Ukraine, 45 Prospect Nauki, Kyiv, 03028 Ukraine 2) S. Korolyov MERYDIAN JSC, 8, I. Lepse blvd, Kyiv, 03680 Ukraine 3) Institute of Cell Biology and Genetic Engineering, Cell Genetics Department, National Academy of Sciences of Ukraine, 112 Zabolotnogo Str., 03207 Kyiv, Ukraine 4) Department of Plant Sciences, MS 6, University of California, One Shields Ave. Davis, CA 95616-8587, USA Abstract. New UV meters and software have been developed and manufactured for environmental monitoring in the Ukraine. The multifunctional meters offer low cost and provide one and four channels for biological, meteorological and medical applications. The main specifications, advantages, and design features of each device developed is presented. Introduction UV irradiation is one of the environment factors that has either a favorable or unfavorable dose-dependent effect on living organisms [1-10]. Exceeding the UV irradiation dose is harmful and even pathological. In humans and animals UV-irradiation deficiency leads to vitamin imbalance, a decrease in immune protection [11-16]. Many an examples exist why it is necessary to carry out the UV monitoring [17-23]. Control of the optical energy irradiation and dose in wide spectral ranges (UV to NIR, including visible radiation) is important to determine the separate actions of UV, photosynthesis, and thermal effects of the radiation. Control also enables the estimation of complex influence of optical radiation on biological objects and their surroundings [24-29]. In all cases, it is necessary to have simple and accurate measuring devices. In the world-wide market there are many different devices. These comprise radiometers of UV radiation, flux meters, radiometers of IR radiation, and others (Fig.1.) [30-32]. Their high costs are prohibitive for common applications in Ukraine. Therefore one of our main criteria for the development and manufacture of the photometers was their cost characteristic with the highest possible design unification in the monitoring system [33]. UV meters Spectral Integral Dose meters Effective Erdosemeters Spectroradiometers Irradiation meters Effective Еnergetic UV dose meters Energetic UV photometers Bactmeters Radiometers Ermeters Figure 1. A proposed classification of UV meters [30]. Bold arrows show the types of devices developed for the Ukraine. 1. Optical energy irradiation and dose meters (OIM and DM) To develop OIM and DM and yet retain their low cost, the filter broadband was redesigned. Classification of the optical devices for measurements of UV radiation is presented in Fig. 1. [33]. The ermeter measures erythema, the device for quantifying the electromagnetic energy to control the degree of erythema. It was calibrated in erythema units. The erdosemeter determines the erythermal dose by optical measurement. It was calibrated in units of erythema doses. The bactmeter is used to evaluate the bacteriological action of UV radiation. It used for to measure disinfection, sterilization or sanitization by UV radiation. These devices measure either irradiance or dose. The devices for measuring of irradiance and dose are divided into those that measure energy values or effective values. We selected the best way to measure energy values (bold arrows in Fig.1.). Their main advantages are: - easy to use; - broad distribution possible; - response function similar to biological weighting function; - low cost. The main disadvantages concern the high demands for instrument calibration for: - wavelength coverage; - sensitivity; - long-time stability; - temperature stabilization; - data logger capacity. These instruments can monitor, collect and store information. This requires linkage with a personal computer (PC) for portability and long-term automated operation for accurate measurements and simplicity of use. These specifications were successfully introduced for two kinds of devices: portable one-channel FEO-M, and professional fourchannel FEO-P photometers. Both kinds were designed as unified selective photodetectors to provide measurements in different ranges of spectrum (spectral types UVА, UVВ, UVАВ, vis etc). They were also modified to meet a variety of end uses and complexity of measurement tasks. The portable photometer of optical energy irradiation and dose FEO-M (Fig.2.) is a simple one-channel portable small current (up to 3 мА) meter. It was designed from the simple and relatively cheap microelectronic elements – microcontroller of type PIC16F628 and ADC of type AD7822, which increases its desirable functionality for: - measuring of optical energy irradiance; - automatic identification of the working photodetector; - automatic calculation of optical irradiance and dose of irradiation; - control of time of radiant dose exposure; - measuring of ambient temperature in the point of measurements; - digital indication of optical irradiance, dose, time of exposure and detector temperature; - interface transmission of data to PC for the next visualization and processing. The professional photometer of optical energy irradiation and dose FEO-P (Fig.3.) is the device that measures information. It has a 4-channel microprocessor block for measurements. Data are displayed on the LCD panel. Automatic turning of the limits of measurements ensures desirable multifunctionality of the device for: - measuring of optical energy irradiance; - automatic identification of the working photodetector; - automatic calculation of optical irradiance and dose of irradiation; - control of time of radiant dose exposure; - measuring of ambient temperature in the point of measurements; - setting of limits of radiant dose or time of exposure in each optical channel; - digital indication of irradiance, dose, temperature, time of exposure, limits of radiant dose and exposure time; - sound signalization about exceeding of set limits; - storage of information in nonvolatile memory; - interface transmission of data to PC for the next visualization and treatment according to procedure. Figure 2. Portable photometer FEO-M Figure 3. Professional photometer FEO-P The device has 4 independent input measuring channels that transform signals into the digital values by 24-bit ADC of type ADS1240. The digital filter and pre-amplifier with 128-stage turning of the amplification coefficient allows us to increase significantly the dynamic range of measurements to 108. In contrast, with FEO-M, a more powerful microcontroller of type РІС16F877 (20 MHz, 8k x 14 – FLESH ROM) provides wider functionalities. The functional possibilities and technical characteristics of devices are shown in Table 1. In comparison with portable photometer FEO-M, the professional photometer FEOP has the following advantages: - multichannel work from the 4 photodetectors simultaneously; - large dynamic range of measurements - due to utilization of more powerful microscheme of ADC with 24-bit and build-up programming 128-time preamplification; - big volume of programming memory up to 4 times (8 kilowords) - high speed of program execution up to 20 times – due to utilization of more powerful microcontroller PIC16F877; - graphic display of 128x64 pixels instead of LCD indicator of 4 numbers; - extended control with the use of keyboard; - registration of IR trends - due to utilization of microscheme of permanent memory 500 Kbytes, sufficient to remember of dozen measurements; - build-up sound indicator of programming limit values of the exposure dose in each channel. Table 1. Technical characteristics of fabricated photometric devices (without photodetectors) Parameters Number of measuring channels Range of measurement of optical energy irradiation E, W/m2 Limit of the irradiation measuring error dE, % Range of measurement of the exposure dose D, kJ/m2 Limits of the dose measuring error dD, % Range of measurement of the exposure time Т, min Limit of the exposure time measuring error dT, % Range of measurement of the temperature, оС Limit of the temperature measuring error dt, % Power supply current Iс, mA - with the illumination Range of work temperatures, oC Interface with PC Transmission speed, bod Operational time in autonomous CW mode, h FEO-M 1 5x10-2...104 ±3 5x10-2...104 ±4 1 ... 6 103 0,01 - 9 ...+60 ±0.5 2 -10 ...+50 RS232 9600 100 – 250 FEO-P 4 10-3...104 ±1 10-3...104 ±1 3.3 10-2... 6 105 0,01 - 9...+60 ±0.5 30 300 -10...+50 RS232 9600 2. Unified photodetector for the photometers of optical energy irradiation and dose FEO-M and FEO-P. The unified selective photodetector (FD) is a constituent part of the photometers FEO-M and FEO-P. FD transforms directly the irradiation into electrical signals. The change of the photodetector changes the sensitivity of the photodetector. The photodetector presents the photosensitive element with the selective optical filter. FD uses an identifier which identifies the photodetector by the spectral range and the limits of measurements. This takes into account the spectral characteristics and corrects for the temperature dependence. It can utilize photodetectors of different types. The identifier’s input limits measurements to 1000, 300, 100, 30, 10, 3, 1 or 0.3 W/m2. This represents a coefficient of transformation provided by the amplifier with the following spectral characteristics: (В type) 280-315 nm, (A-type) 315-400 нm, (АВ-type) 280-400 nm and (V-type) 400-760 nm. The photodetector (PD) has the following components: - optical filters that can transmit optical radiation in the given range; - photosensitive sensor that can transforms the light flux into the electrical signal; - circuit board where pre-amplifier and identifier are situated; - connector for connection between photodetector and microcontroller for data processing. The glass optical filters and photosensors are united into the photoreceiver that has a single case marked by the corresponding types (А, В, С, V, IR). If necessary, interference filters can be used. PD includes the selective photodiode, which transform the optical radiation into the electrical current, the identifier of the detector type (D1 – DS18S20), and the scheme of normalization of the output signals (D2 – ADS8551AR). We recognized the need to regulate the transformation coefficient to adjust of the photodetector and photometer. The identifier (microscheme) has a unique number (48 bits), a temperature sensor (accuracy ±0,50С), and a permanent memory (16 bit) for writing the values of the coefficient of transformation and the type of spectral characteristics. The photodetector is recognized by the photometer, and determines the type and the data necessary for pre-programming corrections and measurements. The normalization of the signal is executed as an amplifier-transformer I/U on a precise operational amplifier. The latter has very low (20 рА) input current and bias (5 µV) with a small temperature drift (0.03 µV/oC). This allows the user to select the coefficient of transformation (ko= Uout /Iin) in a very wide range (roughly – by changing of the resistance nominal R1 in the limits of 1.0...1000 kΩ, and precisely, in 1.5 steps – by the potentiometer R2). The necessary coefficient of transformation ko is determined from the formula ko=Un out / Emax⋅Si, where Unout is output voltage of the transformer. This is equal to maximal input voltage of ADC (2.5 V as for FEO-M and for FEO-P); Emax is the limit of optical energy irradiation, W/m2; Si is integral sensitivity of the phototransformer, µA/Wm-2. Thus, for example, during the measurement of the energy irradiation in the field of UV-B from the natural sun (Emax= 10 W/m2) by the photodetector with sensitivity Si = 1 µA/Wm-2, it is necessary to set a transformation coefficient ko = 0.25 V/µA (Roc = 0.25 MΩ). For the photodiode we used a Si special diode [33, 34]. Its reproducibility is shown on Fig. 4. The spectral characteristics of PD in UV and visible ranges are shown on Figs. 5.6., respectively. B C D E F G H 700 600 S, mA/W 500 400 300 200 100 0 400 600 800 1000 1200 λ, nm Figure 4. Dispersion of spectral sensitivity curves for 7 experimental samples of the Si pgotodiodes [34]. There are photodiodes on the base with other materials [36-40]. The GaN and diamond photodiodes may be used in UV meters to blend with the visible range, but they are currently too expensive for use in our devices. 3. Development of the software for monitoring of UV irradiation For UV irradiation monitoring, the EMMStation program has been developed. It allows collecting, storing and processing the data got from photometer FEO-M/FEO-P. 60 1 50 S, mA/W 40 30 2 20 10 0 280 300 320 340 360 380 400 λ, nm Figure 5. Spectral sensitivity of photosensor in UV ranges:1 – UVA, 2 – UVB. 250 200 S, mA/W 150 100 50 0 400 450 500 550 600 650 700 λ, nm Figure 6. Spectral sensitivity of PD in visible range EMMStation include the following components for: - interaction with FEO-M/FEO-P (data collection and operation); - database support, using BDE driver (Borland Database Engine) and operating the database in Paradox format; - generation and forming of alarm messages ; - a mail agent for sending alarm messages through the SMTP mail server; - an adjustment wizard for the mail agent and parameters of dispatch. EMMStation allows: - inspecting and collecting the data from FEO-M/FEO-P; - storing observed data in the database with possibility of their graphics visualization on each of measuring channels selected by the user and in a selected range of a time; - exporting observed data from the database to a text file and to import from a text file to the database; - carrying out a control of integrity and clearing (restoring) of the database; - inspecting the generation and creation of alarm messages and sending these through a SMTP mail server on the given users addresses. Depending on specific tasks (object of visualization, range and errors of measurements, spatial and temporal resolution, station site, and IOM/DM situation), we can: - select different modes of observation with necessary parameters of monitoring; - offer appropriate methods of diagnostics with necessary characteristics of sensitivity and selectivity; - develop advanced algorithms of signal registration; - processing and represent data; - entered the optimum configuration for the monitoring equipment. Further improvements will yield more informative methods of monitoring and sensing of the optical irradiation and dose of biological active atmospheric radiation from the sun and the sky. 4. Conclusions The cost-effective portable FEO-M and professional FEO-P photometers provide precise measurements of optical energy irradiation in different spectral ranges. The devices have a high accuracy on a real time-scale, and control the irradiation dose. Alarm protection occurs during the accumulation of doses in spectral ranges used for common monitoring. These instruments have a unique combination of functions. The portable photometer FEO-M offers: - measuring of optical energy irradiance; - automatic identification of the working photodetector; - automatic calculation of optical irradiance and dose of irradiation; - control of time of radiant dose exposure; - measuring of ambient temperature in the point of measurements; - digital indication of optical irradiance, dose, time of exposure and detector temperature; - interface transmission of data to PC for the next visualization and processing. The professional photometer FEO-M provides: - measuring of optical energy irradiance; - automatic identification of the working photodetector; - automatic calculation of optical irradiance and dose of irradiation; - control of time of radiant dose exposure; - measuring of ambient temperature in the point of measurements; - setting of limits of radiant dose or time of exposure in each optical channel; - digital indication of irradiance, dose, temperature, time of exposure, limits of radiant dose and exposure time; - sound signalization about exceeding of set limits; - storage of information in nonvolatile memory; - transmission of data to personal computer for the next visualization. The operation of these devices and their software was tested in some centres of ozone and UV irradiation. This includes the Ukrainian Hydrometeorological Research Institute (Kyiv city) and the sunniest zone in Ukraine (Crimea). 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