Climate in cities Basics Unit 1: Air pollution due to human activity Air pollution is a serious problem in cities. It changes our urban climate, degrades the environment and has negative impacts on the economy and on our health. Industry and transport are the largest sources of air pollutants and emission of these pollutants results in high levels of particles and soot in the air and can cause smog to form. Industrial accidents can cause huge inputs of air pollutants into the atmosphere and these emissions may lead to permanent degradation of the natural environment. One of the most polluted regions in Europe is the so called "Black Triangle", located at the junction of the borders of Germany, Poland and The Czech Republic, where huge brown coal resources are exploited. As the atmosphere is constantly moving, pollutants are carried great distances away from their source region. This means that air pollution is an international rather than local problem. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 1 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Part 1: What is it? Air pollutants can be either gases or aerosols (particles or liquid droplets suspended in the air). They change the natural composition of the atmosphere, can be harmful to humans and other living species and can cause damage to natural water bodies and the land. Clean air is made up of naturally occurring chemicals. Oxygen and nitrogen make up 99% of dry air and the remaining 1% consists of argon, carbon dioxide, helium and other trace gases. Air, of course, also contains water vapour and this may make up as much as 4% of the total air volume. Clean air doesn't contain harmful levels of chemicals or harmful chemicals which adversely affect living things. Some gases which are normal components of clean air - for example, carbon dioxide become dangerous when their concentrations become much higher than normal. 1. Clean air and plants. Lichens living on tree trunks are very sensitive to air pollution. They can only survive in clean air so are a good measure of how polluted the air is. Source: www.freefoto.com Air pollution has both natural and human sources. 2. Natural air pollution. Smoke from volcano Sakura-jima, Japan. Source: UND - University of North Dakota, photo: Mike Lyvers Natural air pollution comes from volcanoes, natural forest fires, soil, plants, seawater, wetlands and even outer space. Inputs of gases and particles from these sources into the air has always happened and the atmosphere adjusts to this new material with minimal complications. Human, or anthropogenic, air pollution comes from the many different human activities which occur during our daily lives. Sources include industry, vehicles, agriculture, power generation (coal, oil or gas power stations), mining and waste dumps. It is difficult for the atmosphere to cope with these these extra pollutants leading to high concentrations locally and regionally. 3. Anthropogenic air pollution. Smoke from a factory chimney. Source: www.freefoto.com ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 2 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Air pollution can be divided into two basic types. Gases come mainly from the burning of fossil fuels. Gaseous pollutants which affect the atmosphere globally include carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). These are all greenhouse gases and are responsible for global warming. 4. Urban traffic. Traffic delivers lots of global and regional air pollution Source: www.freefoto.com Although present throughout much of the atmosphere, gaseous pollutants including nitrogen oxides (NOx), sulfur dioxide (SO2), carbon monoxide (CO) and a wide range of organic compounds are found only in signficant concentrations close to their origin so these are important on a local and regional scale. All these compounds are released during fossil fuel burning although many volatile organic compounds (VOC's) also have significant natural sources from plants. Both the greenhouse gases and regionally important gases are examples of primary pollutants. These species are emitted directly into the air from sources at the Earth’s surface. The regional gases can also react chemically in the atmosphere to form other compounds which are known as secondary pollutants. One of the main results of secondary pollution is photochemical smog. Smog is the main pollutant problem in most of the big cities of the world. Its main component is ozone (O3) which, at high concentrations, can cause breathing problems and burning eyes. While O3 is beneficial in the stratosphere because it absorbs harmful ultraviolet radiation from the Sun, it is a health hazard in the lower atmosphere. Use the link at the bottom of the page to find out more about ozone smog. The second type of pollutant is particulate matter, which consists of a wide range of liquid and solid particles known scientifically as aerosols. The smallest of these particles are hazardous to human health. As with the gases, particles can be directly emitted into the air or can form from gases. In winter in many cities and towns, particularly in poor countries, people burn wood to keep warm. The particles from wood-burning can cause a brown haze over the region and larger particles may interfere with plant growth because they deposit on the leaves. See the link at the bottom of the page to find out more about aerosols and their origin. 5. Forest fires. Forests fires emit lots of gases and particulate matter into the atmosphere. Source: NASA - National Aeronautics and Space Administration Two hundred years ago, air pollutants were mainly from natural sources. The rapid development of industry after 1850 created many new anthropogenic pollution sources, which were initially associated with the production of energy from coal and oil burning. Air pollution is a major environmental issue in many parts of the world. Unless ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 3 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics we control and manage air pollution carefully, air pollution problems will become a lot worse. The figure below summarises the criteria we use to classify air pollution. The Colours in the text correspond to the colours used in the figure. 6. Air pollution classification. The colours in the figure correspond to the colours in the text where the criteria are explained. Authors: Anita Bokwa, Michael Seesing, Pawel Jezioro. Natural air pollution can be divided into: - inorganic pollution, e.g. dust and gases from volcanic eruptions, salt particles brought by the wind from the sea, dust delivered into the air during dust storms, gases originating from lighting during thunderstorms and dust coming to the atmosphere from space. - organic pollution, includes smoke and dust from vegetation fires, pollen and fungi from plants, live organisms including bacteria and volatile substances emitted by trees and flowers. Anthropogenic air pollution can be also divided into two groups according to the character of emission: - controlled emission which takes place according to well established rules, under the supervision of trained staff. - accidental emission which occurs, for example, during industrial accidents and oil spills. So we can define air pollution in two ways: - primary pollution - harmful substances which are emitted directly into the atmosphere. - secondary pollution - substances which become harmful once in the air or harmful substances which form as a result of chemical reactions in the atmosphere. 7. Fire-places are probably one of the first anthropogenic indoor sources of air pollution. Source: www.freefoto.com The air pollution types mentioned so far are also known as outdoor air pollution. Indoor air pollution is also a very important problem. The air within homes and other buildings can sometimes be more polluted than the outdoor air even in the largest and most industrialised cities. Sources of indoor air pollutants such as carbon monoxide (CO) include poorly maintained fires, stoves and heaters. This is a serious problem particularly in poor countries where standards of living are low. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 4 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Other sources of indoor air pollution include tobacco products, products for household cleaning and maintenance, personal care, or hobbies. Inadequate ventilation, high temperatures and high humidity allow the pollutants to accumulate. Many people living in the cities spend approximately 90% of their time indoors. So for many people, exposure to indoor air pollutants poses a greater risk to their health than do outdoor air pollutants. 8. Indoor pollution. Smoking a cigarette, pipe, or cigar delivers a complex mixture of over 4,000 compounds, more than 40 of which are known to cause cancer in humans or animals and many of which are strong irritants. Source: US Environmental Protection Agency; photo: www.freefoto.com Part 2: Causes Causes of anthropogenic air pollution Most of the air pollution which comes from human activity enters the atmosphere from industry, vehicles and the combustion of fossil fuels in power plants. In developed countries vehicles are the main source of air pollutants in the cities. Sources of anthropogenic air pollution Combustion of fossil fuels during power production, in heating systems and in vehicle engines is the main source of anthropogenic air pollution. Other sources include industry and agriculture. At the beginning of human civilisation the only source of anthropogenic air pollution was smoke from fire-places. As the population grew, air pollution problems also increased. By 1273, King Edward the First of England had banned the use of coal in London as it caused enormous air pollution problems. 1. Fire-places were one of the first anthropogenic sources of air pollution. Source: www.freefoto.com ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 5 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics In the 20th Century, industrial development led to high numbers of factories in urban areas. This was accompanied by a significant increase in the urban population and, as a result, the number of buildings and cars grew. High density housing and narrow roads made vehicle traffic a particularly important source of pollutants. This is still a huge problem and in cities of the developed world, vehicles are now the most important source of air pollution. 2. Intensively urbanised area. High concentrations of residential buildings, service industries and factories in urban and industrialised areas are one of the reasons for air pollution. Source: www.freefoto.com Emission and deposition 3. Emission and deposition (denoted imission on the figure). Source: Bundesamt für Umwelt, Wald und Landschaft 1996 Air pollutants are emitted from urban areas and also from rural locations. The harmful gases and aerosols are transported by the wind great distances away from their initial source before they are deposited back to the ground. So when we measure the concentration of a pollutant to determine the air quality, we must remember that the pollutant may have come from some distance away and doesn't necessarily have a local source. Units While emission and deposition values are usually given in large amounts (e.g. tonnes per year), atmospheric concentrations are generally expressed in much smaller units (e.g. in fractions of grams or moles of a substance per cubic metre of air). When we look at atmospheric concentrations we can either talk about average concentrations for the whole Earth (in case of carbon dioxide CO2), or for a given place and time (e.g. sulphur dioxide SO2 levels in London, in December 1952). Concentrations of gases are often given as a mixing ratio, this is the fraction of the compound as a proportion of all the air molecules present. It is usually expressed in ppm (parts per million) or ppb (parts per billion). You can find out more about the mixing ratio in the Higher atmosphere topic. 4. Changes in global content (mixing ratio) of carbon dioxide (CO2, in ppm) and methane (CH4, in ppb) in the atmosphere. Author: Anita Bokwa. Source of data: World Resources Institute (http://earthtrends.wri.org). ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 6 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Anthropogenic emissions As we saw in the section "What is air pollution?", some emissions have a global impact on climate while others have only a local effect. Areas with high levels of anthropogenic air pollution include Eastern USA and Canada, Europe and South and South East Asia. Emissions of sulphur dioxide (SO2) and nitrogen oxides (NOx) from these areas contribute to acid rain and this effect is discussed later in this topic. Large quantities of carbon dioxide (CO2) and Volatile Organic Compounds (VOC's) are also emitted into the air. Some of the VOC's (e.g. methane CH4 and the chlorofluorocarbons) can act as greenhouse gases and we look at these in more detail in the section looking at the impact of industry on air pollution. The table below and the charts in figure 5 show air pollutant emissions in selected countries. The emissions vary greatly and we look at the reasons for these differences below using CO2 as an example. Country SOx NOx CO2 Dust Great Britain 2 028 2 060 539 344 213 Hungary 657 197 58 498 136 Germany 1 468 1 803 834 379 316 France 989 1 691 344 666 211 Poland 2 368 1 154 348 260 1 282 South Korea 1 500 1 258 424 119 423 Japan 903 1 409 1 164 518 - USA 18 481 21 394 5 444 794 3 393 Australia 1 842 2 166 316 704 38 Yearly emissions of sulphur dioxide, nitrogen oxides, carbon dioxide and dust for selected countries (in thousands of tonnes per year). 5. a) Emissions of air pollutants in 1997. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 7 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics 5. b) Emissions of CO2 in 1997 5. c) Emissions USA air pollutants in 1997. 5. Air pollution emissions in chosen countries. Please click icon to see enlarged chart! (15-30 K). Authors: Anita Bokwa, Pawel Jezioro. Source of data: Carbon Dioxide Information Analysis Center, United Nations Framework Convention on Climate Change http://webdab.emep.int Example: Emissions which have global impact: Carbon dioxide (CO2) Emissions of CO2 have a global impact on our climate. Let's see who emits the largest amounts of CO2 in the world. According to the Energy Information Administration, the global emission of CO2 in 2001 amounted to 6567.82 million tonnes of carbon equivalent units. What are carbon and carbon dioxide equivalent units? Carbon equivalent units are defined as the carbon dioxide equivalent multiplied by the carbon content of carbon dioxide (i.e., 12/44). The carbon dioxide equivalent is used to compare greenhouse gases and is derived by multiplying the mass of the gas by its global warming potential. The global warming potential measures how strong a greenhouse gas is. For example, methane has a global warming potential of 21, so its 21 times more powerful a greenhouse gas than CO2. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 8 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Emissions by continents About a third of the world's CO2 emissions come from Asia, Australia and Oceania and 28% comes from North America. So almost 60% of the global CO2 emissions come from these two regions. However, even though both regions emit almost the same amount of CO2 per year, the causes are quite different. About 3.9 billion people live in Asia, Australia and Oceania, that's 61% of the world population, whereas only about 323 million people live in North America (U.S.A. and Canada). High CO2 emissions in Asia, Australia and Oceania are simply the result of the huge number of people living in the region, in North America it is the very high consumption of energy which is the cause. 6. Emissions of CO2 in 2001 by continents. Authors: Anita Bokwa, Pawel Jezioro. Source of data: www.eia.doe.gov/emeu/iea/ Emission by countries 7. Countries which had the largest share (in %) of the world total emission of CO2 in 1999. Author: Elmar Uherek. Source of data: UN Human Development Report 2003 http://hdr.undp.org/reports/global/2003/pdf/hdr03_HDI.pdf Figure 7 shows the countries which emit the largest amounts of CO2 in the world. For example, 23.2% of global CO2 emissions come from the USA. USA, China and Russia together make up over 42% of the global CO2 emissions although only 27% of the world's population lives in these countries. Among the seven largest emitters, one is in North America, three are in Europe and three are in Asia (note that although Russia is in both Europe and Asia, it is usually included with the European countries). There are no large CO2 emitters in the Southern Hemisphere. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 9 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Emission per capita Figure 8 shows how much CO2 is emitted per person in certain countries. For example, 19.7 tonnes of CO2 are emitted per citizen in the USA, while in India it is only 1.1 tonnes. Such huge differences result from the different degree of economic development. The higher the standard of living in a country, the higher the energy consumption (through the use of cars, air conditioning and electrical appliances) and therefore the greater the CO2 emissions. 8. Emissions of CO2 per capita in chosen countries. Author: Elmar Uherek. Source of data: UN Human Development Report 2003 http://hdr.undp.org/reports/global/2003/pdf/hdr03_HDI.pdf Anthropogenic emissions by sectors Anthropogenic air pollution comes from many sources. One source can often emit many different pollutants but some human activities, for example transport, produce very characteristic chemical species. The data from UNECE/EMEP (United Nations Economic Commission for Europe/Co-operative programme for monitoring and evaluation of long range transmission of air pollutants in Europe) shows which sectors of the economy (what kind of human activity) were mainly responsible for emissions of carbon monoxide (CO), nitrogen oxides (NOx) and sulphur oxides (SO2) in Europe in 2001. The emissions are given in gigagrams (Gg) where 1 Gg = 1000 tonnes. Carbon monoxide (CO) 30,679 Gg of CO were emitted in Europe in 2001. The main source of this anthropogenic CO was transport (60%) with industry contributing 36%. Waste management and agriculture were of marginal importance. You can find out more about CO emissions in the topic on the Lower Atmosphere. 9. Emission of CO in Europe in 2001 by sectors. Authors: Anita Bokwa, Pawel Jezioro Source of data: http://webdab.emep.int ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 10 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Nitrogen oxides (NOx) 10,056 Gg of NOx were emitted into the atmosphere in 2001. Transport was the biggest source, making up 63% of the emissions. Industry contributed 35% and emissions from waste management and agriculture were, again, of marginal importance. 10. Emission of NOx in Europe in 2001 by sectors. Authors: Anita Bokwa, Pawel Jezioro Source of data: http://webdab.emep.int Oxidised sulphur compounds (SOx) The main component of the oxidised sulphur compounds is sulphur dioxide (SO2) and, unlike CO and NOx, their main source is industry. Total emissions of oxidised sulphur were 5,949 Gg in 2001 and 93% of these came from industry. Find out more about the impacts of SO2 and NOx in the section on acid rain. 11. Emission of SOx in Europe in 2001 by sectors. Authors: Anita Bokwa, Pawel Jezioro Source of data: http://webdab.emep.int Emissions in cities 12. Urban traffic Urban traffic is the main source of air pollution in many cities. Source: www.freefoto.com The main emission sources and the main air pollutants vary between cities as they depend on the poulation size, the types of industry located there, how much traffic there is and what kinds of heating systems are used. Pollutants are emitted into the city air from low emission sources (e.g. individual heating systems in houses), high emission sources (e.g. tall factory chimneys) and from mobile sources (e.g. cars and buses). For example, Cracow is a medium-sized city in southern Poland with 800,000 inhabitants. It has heavy industry (a steel works and a huge power plant) and large amounts of traffic. Industry emits almost all of the SO2 into the air, most of the NOx and dust and as much CO as transport. Other sources of air pollution are of marginal importance. However, in many Western European cities, transport is the main source of CO and NOx, because heavy industry has declined and ben replaced with clean new technologies. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 11 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics sector/pollutant CO NOx dust transportation 48% 15% 2% industry 44% 83% 88% 8% 2% 10% 100% 100% 100% municipal economy sum Emission of carbon monoxide (CO), nitrogen oxides (NOx) and dust by sectors in Cracow, Poland, in 2001. Source: Inspectorate of Environmental Protection in Cracow. Part 3: Negative effects Negative effects of air pollution Air pollution has an impact on both local and global scales. Harmful substances which are emitted into the atmosphere in one country, are transported by the wind and cross over national borders. International co-operation is, therefore, necessary to improve overall air quality. Global negative effects of air pollution include the enhanced greenhouse effect and the ozone hole. Smog and acid rain are the best known local effects and smog, in particular, affects people living in urban areas. Air pollution is a threat to our health and can also cause economic losses. Let's concentrate on air pollution in cities. Sulphur and nitrogen oxides, hydrocarbons (mainly from refineries and traffic), carbon monoxide, heavy metals (from traffic and industry), dust and soot are all found in urban air. The proportions of these pollutants vary depending on the location. For example, use of low sulphur containing fuels has dramatically decreased the atmospheric concentrations of sulphur dioxide in developed countries. 1. Urban air pollution. Individual heating systems contribute to the urban air pollution. Source: www.freefoto.com ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 12 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Smog In many cities, air pollution levels exceed the allowed concentrations and smog alarms are published. The word "smog" is the combination of the words smoke and fog, it was invented around 1911 by the physician Harold Des Voeux. There are two kinds of smog: - London-type smog. Burning coal leads to emissions of sulphur dioxide and dust. When these pollutants mix with fog, droplets of highly corrosive sulphuric acid (H2SO4) are produced in the air. In London in 1952, concentrations of SO2 during a smog event exceeded 3.5 mg m-3 (3500 µg m-3) and many people died. London type smogs were first recorded in the 1850's and are rather rare today due to better controls on air pollution. For example, in 2001, mean annual concentrations of SO2 reached 3 µg m-3 in Barcelona (Spain), 4 µg m-3 in Munich (Germany), 7 µg m-3 in London (Great Britain - data for 1999) and 13 µg m-3 in Warsaw (Poland). On some days, however, concentrations of 2. Number of deaths in London in December 1952 due to high of sulphur dioxide. Source: Manchester SO2 can be much higher. The concentrations Metropolitan University highest hourly values for SO2 in 2001 were 211 µg m3 in Warsaw, 106 µg m-3 in London (1999), 70 µg m-3 in Barcelona and 17 µg m-3 in Munich. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 13 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics - Los Angeles-type or photochemical smog. This type of smog forms on sunny days and is the result of emissions from traffic. Nitrogen oxides from car exhausts and hydrocarbons from various anthropogenic and biogenic sources react in the presence of sunlight to produce a noxious mixture of aerosols and gases. Photochemical smog contains tropospheric ozone, formaldehyde, ketones and PAN (peroxyacetyl nitrates). Normal tropospheric ozone levels are less than 0.04 ppm but ozone levels can be as high as 12 ppm in these smogs. The substances in these smogs are irritating to our eyes and can damage our respiratory system. They also affect vegetation. This type of smog is rather common now in large cities in the summer and has generally replaced the London-type smog. 3. What is smog and when is it formed?. Authors: Anita Bokwa, Michael Seesing. For more information on concentrations and mixing ratios see the topic on the Higher atmosphere. Dust and soot Another problem in cities is dust and soot. In 1999, for example, the mean annual concentration of particulate matter less than 10 micrometers in diameter (PM10) was 21.8 µg m-3 in London, 29.5 in Budapest, 43.3 in Rome, 44.4 in Sevilla and 45.4 in Cracow. These values have decreased with time due to better pollution control measures. For example, annual mean particulate concentrations in Cracow in the 1970's and 1980's exceeded 100 µg m-3 due to emissions from the steel factory and the power plant and reached levels of 200 µg m-3 in the winter. These factories have since been modernised and production has decreased leading to significant improvements in air quality. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 14 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics 4. Mean annual concentration of particulate matter less than 10 µm in diameter in 1999. Source: APHEIS - Monitoring the Effects of Air Pollution on Health in Europe. Limit values For every pollutant there are established limit values of concentration which should not be exceeded. These limits are designed to prevent damage to human health and to the environment. For the European Union countries, the limit values and alert thresholds for ambient air were established with the Council Directive 96/62/EC, 27 September, 1996. Detailed regulations were included in three Council Directives: 1. 1999/30/EC, 22 April, 1999; 2. 2000/69/EC, 16 November, 2000, and 3. 2002/3/EC, 12 February, 2002. 6. Limit values for NO2, SO2, Pb and PM10 (mean annual concentrations) in the countries of the European Union. Author: Pawel Jezioro. 5. European flag, a symbol of united Europe. As air pollution is an international problem, the legal regulations about emissions are established by the Council of the European Union for all the member countries. Source: www.freefoto.com. For nitrogen dioxide (NO2), sulphur dioxide (SO2), lead (Pb) and particulate matter up to 10 µm in diameter (PM10), the limit values are given as mean annual concentrations. This means that on any particular day, the concentrations may be higher than the limit value, while on other days it may be much lower, but on average over the whole year, the limit value should not be exceeded. The limit values for SO2 and Pb are much lower than those for NO2 and PM10, as these substances are more harmful to human health. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 15 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics For ozone (O3) and carbon monoxide (CO), the limit values are given as 8-hour mean concentrations. These gases are very toxic to people even in very small amounts and over short exposure periods. As you can see, allowed amounts of ozone in the air are much lower than for CO. Low level ozone is formed during photochemical smog episodes and is harmful to us, whereas ozone in the stratosphere protects life on Earth. 7. Limit values for O3 and CO (8-hour mean concentrations) in the countries of the European Union. Author: Pawel Jezioro. Alarm values For NO2, SO2 and O3, as well as the limit values, alarm values have also been established. These are 1-hour mean concentrations. If these values are exceeded, the local authorities should first inform the public and then undertake actions that decrease the pollutants' concentration in the air. For example, they may have to limit the traffic in a city or decrease industrial production until levels of the pollutant have declined sufficiently. 8. Alarm values for NO2, SO2 and O3 (mean 1-hour concentrations) in the countries of the European Union. Author: Pawel Jezioro. Part 4: Areas in danger Areas endangered by air pollution The air above densely populated urbanised areas always contains many unwanted substances. Industrial accidents may spread air pollution to previously clean areas. We have already looked at air pollutants which have either global or local influence. The local effects of air pollution include reductions in the quality of the soil, water and vegetation. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 16 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Air pollution: an international problem 1. Map of Black Triangle area. Source: Inspectorate of Environmental Protection in Wroclaw. Branch Jelenia Gora. Winds transport air pollutants from one place to another, even from one country to another. As a result, the impact of a particular pollutant may be felt far away from the emission source. A good example is the so-called "Black Triangle", an area located at the junction of the Polish, German and Czech borders. In this region there are three big lignite fields where brown coal is mined: Turoszow field, Lusatian field and North-Czech field, together with seven power plants producing 16,000 MWatts of energy. In 1989 this region, covering just 32,400 km2, was responsible for 30% of the total European emissions of SO2. These SO2 emissions contribute significantly to the acid rain problem (see the section on Areas endangered by acid rain). Acid rain falling in this region caused the largest European event of mountain forest decay seen so far. Between 1981 and 1987, 11,000 hectares of spruce forest in the Sudety Mountains were damaged, of which 10,000 hectares were in the Western Sudety area. At the same time, 15,000 hectares of forest were destroyed in the North West Czech Republic and Saxony. At the beginning of the 1990's co-operation between the three countries lead to action being taken to improve the natural environment. In 1992, an integrated network of 43 automatic monitoring stations was established in Poland, The Czech Republic and Germany and SO2 sources were reduced by modernising power plants and heating systems. Another factor which contributed to the improvement of air quality was the economic crisis and decrease in industrial production in Central European countries. As a result of all these factors, emissions of harmful substances decrease every year. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 17 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics 2. Dust, SO2 and NOx emissions in the Black Triangle Area.Source: Inspectorate of Environmental Protection in Wroclaw. Branch Jelenia Gora. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 18 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics Industrial catastrophes Technological risk is an element which has accompanied industrial development right from its beginning. Every installation may malfunction at some point during its operation and people working with the machines and systems can always make mistakes. When an industrial catastrophe takes place, the atmosphere usually gets 3. Chemical complex polluted with very toxic chemicals Source: www.freefoto.com or radioactive substances, for example in the case of nuclear power plant disaster. Here are a few examples of such events and their effects: - 1930 - smog in the Mosa valley (Belgium), sulphur dioxide air pollution caused the death of a few hundred people. - 1948 - Donora (USA), smog killed 20 people. - 1950 - Pozza Rica (Mexico), uncontrolled emissions of hydrogen sulfide (H2S) during a plant malfunction caused respiratory problems in over 300 persons and 22 people died. - 1952 - smog in London, four thousand people died. - 1984 - chemical catastrophe in Bhopal (India), 3400 people died, 600 thousand suffered from respiratory problems. - 1986 - accident at the nuclear power plant in Chernobyl (former USSR, present Ukraine), 31 people died in the first week after the explosion, the exact total number victims are not still not known today; it is estimated that a few million people still suffer from diseases caused by the radiation: cancer (an increase in thyroid cancer has been observed in the surrounding area), immunological dysfunction etc.; large areas were polluted for many years. - 1991-92 - oil fires during the war in Kuwait and Iraq. ESPERE Climate Encyclopaedia – www.espere.net - Climate in Cities Basics - page 19 English offline version supported by the International Max Planck Research School on Atmospheric Chemistry and Physics
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