Lecturer: Ivan Kassamakov, Docent Assistant: Kalle Hanhijärvi, Doctoral student Course webpage: http://electronics.physics.helsinki.fi/teaching/optics-2014 Nature of light What am I? Waves? Particles? In the17th century, two scientists had different views about the nature of light… Light is particles No! Light is waves Isaac Newton 1643 - 1727 Christian Huygens 1629 - 1695 In the 17th century, some properties of the light were well known already. For example: Light has different colours. Light can travel through a vacuum. Light can be reflected and refracted, these processes are described by the Laws of Reflection and Laws of Refraction. Newton proposed his “particle theory of light” (or “corpuscular theory of light”) to explain the characteristics of light. (source: “Opticks”, published by Isaac Newton in 1704) I think light is a stream of tiny particles, called Corpuscles … Newton's particle theory Why does light have different colours? The particles of different colours have different properties, such as mass, size and speed. Why can light travel through a vacuum? • Light, being particles, can naturally pass through vacuum. (At Newton’s time, no known wave could travel through a vacuum.) Newton's particle theory Why does light travel in straight lines? A ball thrown into space follows a curved path because of gravity. Yet if the ball is thrown with greater and greater speed, its path curves less and less. Thus, billions of tiny light particles of extremely low mass travelling at enormous speeds will have paths which are essentially straight lines. Newton's particle theory Why does a prism separates a beam of white light into the colours of the rainbow? Why does red light refract least and violet light refract most? Newton’s assumptions: 1. The light particles of different colours have mass. Red light particles have more mass than violet particles. 2. All light particles experience the same refracting force when crossing an interface. Thus, red light particles with more inertia will be refracted less by the same force than violet light particles by the same force . Newton's particle theory How does the particle theory explain the Laws of Reflection? Steel Ball Rebound The rebounding of a steel ball from a smooth plate is similar to the reflection of light from the surface of a mirror. Many light particles in a light ray Light Reflection Mirror Newton's particle theory Laws of Refraction A cannon ball hits the surface of water, it is acted upon by a “refracting” force which is perpendicular to the water surface. It therefore slows down and bends away from the normal. Light does the opposite. Newton explained this observation by assuming that light travels faster in water, so it bends towards the normal. The problem: Does light really travel faster in water? In fact nobody could measure the speed of light at the time of Newton and Huygens Air Cannon ball Another problem: How to explain the textures of the shadows Water Light The concept of the luminiferous ether. Sound waves Mechanical waves Through what do light waves travel? Luminiferous ether Light waves The concept of the luminiferous ether. Through what do light waves travel? Light waves 1704 - Isaac Newton publishes Opticks, in which he proposes a particle theory of light. This had trouble explaining refraction, so he adds a "fudge factor", claiming that an "Aethereal Medium" is responsible for this effect, and going further to suggest it might be responsible for other physical effects such as heat. The concept of the luminiferous ether. Strange characteristics predicted of the ether: • Since light travels through space, the ether would have to permeate all space. • Since light travels through matter, the ether would have to permeate all matter. • It does not affect motions in the sky. It did not affect the earth’s motion. • It was stationary. Query 19: “Doth not the Refraction of Light proceed from the different density of this Ætherial Medium in different places, the Light receding always from the denser parts of the Medium? And is not the density thereof greater in free and open Spaces void of Air and other grosser Bodies, than within the Pores of Water, Glass, Crystal, Gems, and other compact Bodies?” Let’s see how Huygens used his “wave theory” to explain the characteristics of light … (source: Treatise on light, published by Huygens in 1690) I think light is emitted as a series of waves in a medium he called “aether” (“aether” commonly also called “ether”) Light as a wave motion Dutch physicist and mathematician Christiaan Huygens (1629 – 1695) invented the first pendulum clock and discovered one of Saturn’s satellites, Titan. • In 1690 he published a theory that describes light as a wave motion. •Huygens’ Principle says that every point on a wavefront can be considered as a source of secondary wavelets, which spread out with the speed of the original wave. •His theory is able to describe reflection, refraction, diffraction and interference Huygens' pendulum clock had an error of less than 1 minute a day, the first time such accuracy had been achieved. Light as a wave motion Trait de la Lumiere (Treatise on Light) Christiaan Huygens, 1690 Huygens’ own illustration of his principle of secondary wavelets to explain the propagation of light Light as a wave motion How do waves propagate? P A wave starts at P and a “wavefront” W moves outwards in all directions. After a time, t, it has a radius r, so that r = ct if c is the speed of the wave. Each point on the wavefront starts a secondary wavelet. These secondary wavelets to form a new wavefront W’ at time t’. Wave theory of light • But Huygens’ theory left a problem: if light was a wave, through what medium did it travel? • The only waves known were mechanical. Something needed to oscillate for a mechanical wave to propagate. In 1678 and 1690 Huygens proposed a wave theory of light in which waves propagated longitudinally through a stationary aether. The speed of propagation was finite. This aether was continuous throughout space and consisted of hard elastic particles which transmitted impulses without being displaced themselves. This theory describes: Propagation, reflection, refraction, diffraction, interference and attenuation Wave theory does not describe the absorption of light by a photosensitive materials Particle theory of light People tend to accept “authority” when there is not enough evidence to make judgement. Newton’s particle theory could only explain refraction by incorrectly assuming that light travels faster in a denser medium. No one could prove he was wrong at that time. The uncertainty about the speed of light in water remained unresolved for over one hundred years after Newton's death. Wave theory of light However, the wave theory of light was re-examined 100 years after Newton’s particle theory of light had been accepted…… Light is not particles! Thomas Young 1773 - 1829 Wave theory of light • Thomas Young successfully demonstrated the interference of light (which Huygens failed to show), by his famous double-slit experiments. • Since then the wave theory of light has been firmly established. Problems in th 19 -century physics In a speech to the Royal Institution in 1900, Lord Kelvin himself described two “dark clouds on the horizon” of physics: The question of the existence of an electromagnetic medium— referred to as “ether” or “aether.” The failure of classical physics to explain blackbody radiation. "There is nothing new to be discovered in physics now. All that remains is more and more precise measurement." The Aether Space is permeated by an invisible lumineferous aether (light-bearing medium) Medium through which light can propagate The Earth must be moving relative to the aether So light will travel faster or slower, depending on the orientation Differences can be determined by experiment Test for the existence of the aether The Michelson-Morley Experiment Michelson-Morley experiment Resultant Vector 4 km/hr east Resultant Vector 2 km/hr west Michelson-Morley experiment Michelson and Morley realized that the earth could not always be stationary with respect to the aether. And light would have a different path length and phase shift depending on whether it propagated parallel and anti-parallel or perpendicular to the aether. Parallel and anti-parallel propagation Mirror Perpendicular propagation Beamsplitter Mirror Supposed velocity of earth through the aether Michelson’s and Morley’s set up They folded the path to increase the total path of each arm. The Michelson interferometer should’ve revealed a fringe shift as it was rotated with respect to the aether velocity. MM expected 0.4 Their apparatus periods of shift and could resolve 0.005 periods. They saw none! Interference fringes showed no change as the interferometer was rotated. Michelson and Morley's results from A. A. Michelson, Studies in Optics Michelson’s Conclusion In several repeats and refinements with assistance from Edward Morley, he always saw a null result. He concluded that the hypothesis of the stationary aether must be incorrect. Thus, aether seems not to exist! Albert Michelson (1852-1931) Edward Morley (1838-1923) The Ultraviolet Catastrophe Lord Rayleigh used the classical theories of electromagnetism and thermodynamics to show that the blackbody spectrum should be: Rayleigh-Jeans Formula This worked at longer wavelengths but deviates badly at short ones. This problem became known as the ultraviolet catastrophe and was one of the many effects classical physics couldn’t explain. Black-body What is a black-body? An object that absorbs all incident radiation, i.e. no reflection A small hole cut into a cavity is the most popular and realistic example. ⇒None of the incident radiation escapes What happens to this radiation? •The radiation is absorbed in the walls of the cavity •This causes a heating of the cavity walls •Atoms in the walls of the cavity will vibrate at frequencies characteristic of the temperature of the walls •These atoms then re-radiate the energy at this new characteristic frequency The emitted "thermal" radiation characterizes the equilibrium temperature of the black-body Photons Max Planck (1858-1947) Max Planck in 1900 stated that the light emitted by a hot object (black body radiation) is given off in discrete units or quanta. The higher the frequency of the light, the greater the energy per quantum. Photons All the quanta associated with a particular frequency of light have the same energy. The equation is E = hν where E = energy, h = Planck's constant (6.63 x 10-34 J • s), and ν = frequency. Electrons can have only certain discrete energies, not energies in between. The wave theory of light was widely accepted until 1905…… Wave theory of light? “No way!” Albert Einstein 1879 - 1955 Photoelectric Effect (1905) Light as particles Einstein’s (1879-1955) explanation light as particles = photons Light of frequency ν Kinetic energy = hν - Ф Electrons Material with work function Ф Photons Einstein expanded Planck's hypothesis by proposing that light could travel through space as quanta of energy called photons. Einstein's equation for the photoelectric effect is h ν = KE + Ф. Although photons have no mass and travel with the speed of light, they have most of the other properties of particles. The higher the frequency (or shorter the wavelength) the higher the energy. Albert Einstein (1879-1955) Einstein’s explanation Electrons are knocked free from the metal by incoming photons, with each photon carrying an amount of energy E that is related to the frequency (ν) of the light by E=hν Where h is Planck’s constant (6.62 x 10-34 J seconds). Only photons of high enough energy (above a threshold value) can knock an electron free. e.g. blue light, but not red light, has sufficient energy to free an electron from the metal.) What is light? Light exhibits either wave characteristics or particle (photon) characteristics, but never both at the same time. The wave theory of light and the quantum theory of light are both needed to explain the nature of light and therefore complement each other. Albert Einstein provided a piece of convincing evidence for the particle nature of light …… Has the story ended yet? Is light particles or waves? Light is not particles, not waves, but BOTH! Louis de Broglie 1892 - 1987 Louis de Broglie in 1924 proposed that particles also have wave-like properties, this was confirmed experimentally three years later. Most scientists did not understand de Broglie’s Ph.D. dissertation at that time. One scientist passed it on to Einstein for his interpretation. Einstein replied that de Broglie did not just deserve a doctorate but a Nobel Prize! De Broglie was awarded the Nobel Prize in 1929. What is light? Aristotle - Light was emitted from our eyes Christian Huygens - Wave theory of light Sir Isaac Newton - Particle theory of light Thomas Young - Wave theory of light Albert Einstein - Particle theory of light de Broglie - Wave-particle duality of all matter What is light? • Light is a form of electromagnetic energy – detected through its effects, e.g. heating of illuminated objects, conversion of light to current, mechanical pressure (“Maxwell force”) etc. • Light energy is conveyed through particles: “photons” – ballistic behavior, e.g. shadows • Light energy is conveyed through waves – wave behavior, e.g. interference, diffraction • Quantum mechanics reconciles the two points of view, through the “wave/particle duality” assertion Properties of Light The wave-particle duality. Light as a wave. A principle of quantum mechanics which implies that light (and, indeed, all other subatomic particles) sometimes act like a wave, and sometimes act like a particle, depending on the experiment you are performing. E = E0 cos 2πνt c = λν E = amplitude of electric field (J) ν = frequency (Hz) λ = wavelength (m) c = speed of light (2.998 x 108 m/s in vacuum) Light is also viewed as particles or packets of energy - photons. Energy of a photon: E = hν E = energy (J) h = Planck' s constant ( 6.626 ×10 −34 J ⋅ s ) Also written as: E= hc λ = hcν~ ν~ = 1 = wavenumber λ One photon of visible light contains about 10-19 Joules Plane Electromagnetic Waves Photons Photons are stable, chargeless, massless elementary particles that exist only at the speed c. Unlike ordinary objects, photons cannot be seen directly; what is known of them comes from observing the results of their being either created or annihilated Photons begin and end on charged particles; most often they are emitted from and absorbed by electrons. Light is Packets of Energy - Photons Packet with energy h ν "No amount of experimentation can ever prove me right; a single experiment can prove me wrong“ – Albert Einstein Why can’t we see a light beam? Unless the light beam is propagating right into your eye or is scattered into it, you won’t see it. This is true for laser light and flashlights. This is due to the facts that: air is very sparse (N is relatively small), air is also not a strong scatterer, and the scattering is incoherent. This eye sees almost no light. This eye is blinded (don’t try this at home…) To photograph light beams in laser labs, you need to blow some smoke into the beam… Photons "What is known of [photons] comes from observing the results of their being created or annihilated." Eugene Hecht What is known of nearly everything comes from observing the results of photons being created or annihilated. Prof. Rick Trebino Georgia Institute of Technology School of Physics Atlanta Light is not particles, not waves, but BOTH! Louis de Broglie 1892 - 1987 “Light is, in short, the most refined form of matter.” Sources of light When a charge moves nonuniformly, it radiates Linearly accelerating charge Synchrotron radiation - light emitted by charged particles deflected by a magnetic field Bremsstrahlung (Braking radiation) light emitted when charged particles collide with other charged particles B Тhe majority of light in the universe comes from molecular vibrations emitting light. Electrons vibrate in their motion around nuclei High frequency: ~1014 - 1017 cycles per second. Nuclei in molecules vibrate with respect to each other Intermediate frequency: ~1011 - 1013 cycles per second. Nuclei in molecules rotate Low frequency: ~109 - 1010 cycles per second. The Emission of Light from Atoms Surely the most significant mechanism responsible for the natural emission and absorption of radiant energyespecially of light - is the bound charge, electrons confined within atoms. Excitation of the ground state De-excitation with emission of a photon Ground state ~ 10-8 seconds later Atomic and molecular vibrations correspond to excited energy levels in quantum mechanics. Energy levels are everything in quantum mechanics. ⇔ Energy Excited level ∆E = hν Ground level The atom is vibrating at frequency, ν. The atom is at least partially in an excited state. Excited atoms emit photons spontaneously. When an atom in an excited state falls to a lower energy level, it emits a photon of light. Energy Excited level Ground level Molecules typically remain excited for no longer than a few nanoseconds. This is often also called fluorescence or, when it takes longer, phosphorescence. Photon absorption Excited level Energy This is, of course, absorption. Ground level Absorption lines in an otherwise continuous light spectrum due to a cold atomic gas in front of a hot source. Einstein showed that stimulated emission can also occur. Before Spontaneous emission Absorption Stimulated emission After Bohr's Model of the Hydrogen Atom Spontaneous and Stimulated Transitions
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