Modeling magmatic accumulations in the upper crust: Metamorphic implications for the country rock Madison M. Douglas, Adelina Geyer, Antonio M. Álvarez-Valero, Joan Martı́ PII: DOI: Reference: S0377-0273(16)30018-X doi: 10.1016/j.jvolgeores.2016.03.008 VOLGEO 5788 To appear in: Journal of Volcanology and Geothermal Research Received date: Revised date: Accepted date: 23 October 2015 29 February 2016 8 March 2016 Please cite this article as: Douglas, Madison M., Geyer, Adelina, Álvarez-Valero, Antonio M., Martı́, Joan, Modeling magmatic accumulations in the upper crust: Metamorphic implications for the country rock, Journal of Volcanology and Geothermal Research (2016), doi: 10.1016/j.jvolgeores.2016.03.008 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. D MA NU SC RI PT ACCEPTED MANUSCRIPT TE Corresponding author: Adelina Geyer, Group of Volcanology, SIMGEO (UB-CSIC), AC CE P Institute of Earth Sciences Jaume Almera, ICTJA-CSIC, Lluis Solé i Sabaris s/n, 08028 Barcelona, Spain. ([email protected]) 1 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 2 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT The extent and degree of the generated aureole depend on many parameters, including: temperature, composition and thermal properties (i.e. thermal conductivity, specific heat capacity) of the magma and country rock; the degree of crystallization of the magma; the size and geometry of the reservoir; the latent heat of fusion for the crystallizing magma; and the amount of heat energy consumed by endothermic metamorphic reactions taking place in the aureole (Johnson et 3 ACCEPTED MANUSCRIPT al., 2011;Peacock and Spear, 2013). Additionally, at shallow crustal levels, hydrothermal processes may play an important role in incorporating cations and H2O into the system, PT as well as redistributing the heat released from the cooling magma reservoir that can NU SC RI affect contact metamorphism equilibria (e.g. Peacock and Spear, 2013). , 2013 AC CE P TE D MA ) 4 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 5 RI PT ACCEPTED MANUSCRIPT SC Heat transfer models NU The temperature distribution within the magma chamber and the host rock is calculated using FEM, by solving the pure conductive heat transfer equation, and MA assuming the effects of viscous heating and pressure-volume work are negligible (see [1] TE D Rodríguez et al., 2015 for further details): AC CE P where the equation parameters refer to density (), specific heat capacity at constant pressure (Cp), temperature (T), time (t), thermal conductivity (k) and Q denotes heat sources other than viscous heating (see Table 1 for details of the thermal and physical parameters). 6 Symbol AD Cp PT ACCEPTED MANUSCRIPT d Supp. Mat. Table S8 Supp. Mat. Tables S4-6 Supp. Mat. Tables S4-6 Specific heat capacity of crust4 J/(kg K) Specific heat capacity of magma (melt phase) Specific heat capacity of magma (solid phase) J/(kg K) J/(kg K) Supp. Mat. Table S7 Magma chamber depth km SC Cpmelt Cpsolid 0.25-2 e EA 120,000 magma thermal_grad T_liquidus T_solidus T_surface T0_magma T0_crust P J/mol Magma chamber height km m2/s m2/s · Cp · Thermal conductivity W/(m K) Latent heat of crystallization1 Melt fraction3 Subcrustal heat flow1 Surface heat flow1 Crust density Magma density3 Solid fraction3 kJ/kg W/m2 W/m2 kg/m3 kg/m3 - D Thermal diffusivity of crust4 400 Supp. Mat. Tables S1-3 0.03 0.07 2700 2344-2694 AC CE P R Activation energy Supp. Mat. Table S8 TE k L ϕ - Thermal diffusivity of magma 4 crust crust magma Magma chamber aspect ratio MA 1.061-9.141 h Qmantle Qsurface SI Unit Pa s J/(kg K) NU Cpcrust Variable Dorn parameter Specific heat capacity at constant pressure RI Value 109 1- 8.314 25-30 Supp. Mat. Tables S1-3 Supp. Mat. Tables S1-3 298.15 1-3106 Eq. 3 Molar gas constant Crustal thermal gradient Magma liquidus temperature3 Magma solidus temperature3 Surface temperature Initial magma temperature Initial crustal temperature Magma chamber internal pressure at h/2 Country rock viscosity J/(mol K) K/km K K K K K Pa Pa s 4.243-19.696 Magma chamber width w km 1, Bea (2010); 2, Whittington et al. (2009); 3, use Rhyolite MELTS code by Gualda et al. (2012); 4 Rodríguez et al. (2015) Physical and thermal parameters 7 ACCEPTED MANUSCRIPT We consider the modeled magma chamber to be emplaced immediately before it PT begins cooling. The completely liquefied magma reservoir (Gelman et al., 2013) is assumed to intrude in a single episode without further replenishment (Gutiérrez and carried out with COMSOL Multiphysics SC are RI Parada, 2010). The geometric modeling, mesh discretization and numerical computations v4.4 software package NU (http://www.comsol.com). To simulate the solidifying magma, we use the heat transfer with phase change module, which allows us to solve Equation 1 after setting the MA properties of a phase-change material (from liquid to solid) according to the Apparent Heat Capacity formulation (AHC) (see Rodríguez et al., 2015 and references therein). D The AHC formulation is considered to be the best representation of a naturally occurring TE wide phase-change temperature interval, as occurs during magma cooling (Rodríguez et AC CE P al., 2015). The latent heat of crystallization is accounted for by increasing the heat capacity of the material within the phase change temperature range. For further details on the methodology, the reader is referred to the work by Rodríguez et al. (2015). A comprehensive report detailing one of the models, which includes all settings within COMSOL (e.g. model properties; physics settings; geometry; mesh), as well as an example of one of the models, are available from the corresponding author upon request (COMSOL Multiphysics commercial software V4.4 or greater and heat transfer with phase change module are required). The performed FE models are axisymmetric and constructed over a cylindrical coordinate system with positive z values related to altitudes above sea level (Fig. 1a). The magma chamber geometry is oblate, spherical or prolate in shape with height h and width w (Fig. 1a). The computational domain corresponds to a section of the crust with a 40 km 8 ACCEPTED MANUSCRIPT radius stretching to a depth of 40 km below sea level (Fig. 1a). The FE mesh consists of between 200,000 and 400,000 linear triangular elements up to 250 m in size farther from PT the magma reservoir, and 2 m in size near the edge of the magma chamber (Fig. 1b). RI Time steps taken to perform the calculations range from less than a year at the beginning of the cooling processes, up to 300 years to speed calculations once reached the SC metamorphic peak. We have tested that the chosen time steps do not affect the results NU obtained. The selected starting magmatic compositions for the numerical simulations MA correspond to three representative types that range from alkaline basalt to rhyolite (Table 2). The former, typical of intraplate magmatism, is taken from Polat (2009). The TE D intermediate magma is of andesitic composition and from a subduction zone taken from Yogodzinski et al. (1994). The rhyolitic composition is from an archetypal case of pelitic AC CE P crustal melting taken from Sensarna et al. (2004). Depending on the model, pressure at the magma chamber center ranges from 1 to 3 kbar (Supplementary Material, Table S1). 9 ACCEPTED MANUSCRIPT Andesite 35-10/3 [1] Rhyolite DM 4 [2] Alkaline Basalt SC95-86 [3] SiO2 56.88 75 50 TiO2 0.68 0.29 2.2 Al2O3 18.36 11.69 FeO* 4.72 2.8 MgO 4.04 MnO 0.1 CaO 7.48 Na2O 4.05 K2O 1.3 P2O5 0.11 RI 4.9 0.03 SC 0.3 0.79 9.6 2.2 3.2 5.11 0.04 0.4 0.4 TE [2] Sensarma et al., 2004 [3] Polat, 2009 13.95 D [1] Yogodzinski et al., 1994 13.5 0.15 NU MA * FeO as total iron PT Major elements (wt%) AC CE P Table 2: Starting magma compositions for the different numerical simulations 10 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 11 ACCEPTED MANUSCRIPT The melt () and solid (ϕ) fractions, as well as the thermal properties of the PT crystallizing magmas, are determined using the Rhyolite-MELTS code (Gualda et al., RI 2012). Results are reported in the Supplementary Material (Table S2 – S7) and are used SC as input data for the models. We simulate isobaric cooling at 1, 2 and 3 kbar pressure, with redox conditions one log unit above the quartz-fayalite-magnetite (QFM) oxygen NU buffer. Using the thermal properties provided by MELTS, we explicitly account for the MA temperature dependence of thermal diffusivity () and heat capacity (CP). Incorporating a temperature-dependent diffusivity is critical due to its strong influence on the TE D temperature-dependence of thermal conductivity (k= ρ · CP ·) at high temperatures AC CE P (Nabelek et al., 2012). Average magma density magma values obtained from MELTS are 2344 kg/m3, 2440 kg/m3 and 2694kg/m3 for the rhyolitic, andesitic and basaltic magmas, respectively. For most models , we consider a crustal density of 2700 kg/m3 (Whittington et al., 2009), a temperature-dependent thermal diffusivity as provided by Chapman and Furlong (1992) for the upper crust and a specific heat capacity calculated with Equations 3 and 4 of Whittington et al. (2009) . In order to evaluate the influence of the crustal thermal properties on the results obtained, we have also considered for specific models alternative temperature-dependent thermal diffusivity and specific heat capacity for the country rock . The latter are further described in Table S8 of the Supplementary Material. 12 ACCEPTED MANUSCRIPT The input temperature profile for the country rock is a typical geothermal gradient varying from 25 to 30ºC/km depending on the model PT . We assume a relatively uniform lateral temperature RI profile, and consider the surrounding walls of the country rock to have no heat flux (i.e. the outer edge of the rotationally symmetric model is insulating). The subcrustal mantle SC heat flow Qmantle = 0.03 W/m2 and the surface heat flow Qsurface = 0.07 W/m2 are assigned NU to the bottom and top limits of the computational domain, respectively (Fig. 1a) (Table 1). For the magma chamber, we assume an initial temperature T0_magma equivalent to the MA liquidus temperature of the magma (Supplementary Material, Tables S2-S4). Following the approach by Jellinek and DePaolo (2003) and Chen and Jin (2011), TE D under high temperatures and confining pressures, crustal rocks are assumed to behave viscoplastically or also referred to as a solid-state creep flow. Thus, the host rock AC CE P rheology can be described by the Weertman-Dorn power-law formulation where the relationship between strain rate and deviatoric stress is defined as follows (Jellinek and DePaolo, 2003 and references therein; Chen and Jin, 2011): [2] where K is a constant that depends on the material, G is the activation energy for creep, n is the power law exponent, v is the deviatoric stress, and R is the molar gas constant (Table 1). Interesting feature of this approach to the knowledge of the wall-rock rheology is that the effective wall-rock viscosity is an explicit function of temperature and strain rate (Jellinek and DePaolo, 2003). The thermal effects on the country rock are examined as a function of the temperature-dependent viscosity determined by the temperature field 13 ACCEPTED MANUSCRIPT distribution and calculated using the Arrhenius formulation (Del Negro et al., 2009; [3] RI PT Chen and Jin, 2011; Gregg et al., 2012) : SC where AD is the Dorn parameter (a material constant) and EA is the activation energy (Table 1). According to Equation 2, higher temperatures close to the magma chamber- NU host rock boundary would implicate lower viscosities. Thus, the viscosity values of the D continental crust (i.e. > 1019 Pa s). MA heated aureole are expected to be much lower than the average viscosity estimates for AC CE P TE 2.2 Mineral assemblage prediction: phase diagram modeling Magma chamber emplacement disrupts the temperature-dependent chemical equilibrium of the surrounding crust, triggering reactions to establish a new equilibrium. Thereby, we use thermodynamic modeling (P-T pseudosections) to predict equilibrium phase assemblages, reactions and modal changes occurring in the country rock around the magmatic body. We use the thermodynamic database of Holland and Powell (1998, with updates) and Perple_X (Connolly, 2005) in the system Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O (NCKFMASH) (Fig. 2, Supplementary Material Figures S1 and S2). We consider three representative upper continental crustal compositions to simulate the magma emplacements effects on country rock, namely (Fig. 2, Supplementary Material Figures S1 and S2): (i) the anhydrous standard upper continental crust of Rudnick and Gao 14 ACCEPTED MANUSCRIPT (2003); (ii) a typical hydrous metapelite (Tinkham et al., 2001); and (iii) a metamarl (Miron et al., 2013). The growth of hydrated phases such biotite and cordierite in the PT standard continental crust requires a minimum amount of H2O. Therefore, we include RI 0.25 of wt% water in the bulk composition of Rudnick and Gao (2003) to permit the formation of hydrated phases. SC The activity–composition models for silicate melt (M), garnet (Grt) and biotite (Bt) are NU from White et al. (2007); staurolite (St), epidote (Ep) and cordierite (Crd) are taken from Holland and Powell (1998); plagioclase (Pl) and K-feldspar (Kfs) are from Holland MA (2003); calcite (Cc) is from Anovitz and Essene (1987); chlorite (Chl) is from Holland et AC CE P TE D al. (1998); and white mica (Ms, Pa, Ma) is from Coggon and Holland (2002). 15 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 16 ACCEPTED MANUSCRIPT Figure 2 (1.5 column): Pressure-Temperature pseudosection in the NCKFMASH system. Darker shading indicates higher variance. Bulk composition (wt.% normalized to 100) is of a hydrated metapelite from Tinkham et al. (2001): Na2O: 1.65, CaO: 1.21, K2O: 3.70, PT FeO: 6.87, MgO: 3.44, Al2O3: 16.88, SiO2: 60.78, H2O: 5.44. And (andalusite), St (staurolite); Bt (biotite); Ms (muscovite); Ep (epidote); Pa (paragonite); Pl RI (plagioclase); Qtz (quartz); M (melt); Crd (cordierite); Grt (garnet); Chl (chlorite); Kfs AC CE P TE D MA NU SC (K-feldspar). 17 ACCEPTED MANUSCRIPT [4] MA NU SC RI PT AC CE P TE D 18 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 19 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT Figure 3 (double column): Summary of the most relevant results discussed in the text regarding temperature distribution at the country rock due to the heated magma chamber. (a) Temperature distribution along the D-D’ profile at different time steps. 20 ACCEPTED MANUSCRIPT Results for the oblate (left) (M_reference model) and spherical (right) (M_shape_spherical model) reservoir are illustrated. Depth z is normalized towards the magma chamber center depth d, i.e. z/depth = -1 indicates magma chamber horizontal PT axis. Temperature increase T along the D-D’ (b) and E-E’ (c) profiles for the oblate reservoir (M_reference model). Comparison of the temperature evolution at the three reservoirs (M_reference, M_shape_sphere and M_shape_prolate models, SC (e) RI control points (A-C) for the case of the oblate and spherical (d) and oblate and prolate respectively). Model name as listed in Table S1 of the Supplementary Material indicated TE D MA NU within brackets. Roman numerals detailed in the text. AC CE P ν ν 21 ACCEPTED MANUSCRIPT AC CE P TE D MA NU SC RI PT ν 22 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT Figure 4 (double column): Summary of the most relevant results discussed in the text regarding viscosity changes at the country rock due to the magma chamber accumulation. (a) Viscosity of the country rock at the metamorphic peak of point C for the reference model (M_reference, i.e. rhyolitic magma at 3 kbar depth). (B) Country rock viscosity along the E-E’ crustal profile at different time steps for the reference 23 ACCEPTED MANUSCRIPT oblate reservoir. Evolution of the country rock’s viscosity at the three control points (A, B, C) for the oblate (c), spherical (d) and prolate (e) reservoirs (M_reference, M_shape_sphere and M_shape_prolate models, respectively). The dashed lines with PT double arrows indicate the time interval in which the control crustal points remain below AC CE P TE D MA NU SC RI viscosity value of 1016 Pa s. III) and spherical (Fig. 5b, label IV) reservoirs, respectively. 24 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT Figure 5 (double column): (a) Evolution of the metamorphic aureole for the reference model at different time steps corresponding to the metamorphic peak of the three control points: A, B and C. (b) Predicted mineral assemblage for the case of a spherical reservoir. The time step corresponds to the metamorphic peak of point C (i.e. magma 25 ACCEPTED MANUSCRIPT chamber bottom). (c) The same for the prolate reservoir at t= 0s and at the metamorphic peak of C (i.e. magma chamber bottom). (d) For illustrative purposes we also show the predicted mineral assemblage for the metapelitic crust color-coded for the different PT phases identified in the results shown in (a), (b) and (c). The green, red and blue horizontal lines indicate the temperature increase experienced at the top (control point RI A), horizontal axis (control point B) and bottom (control point C) of the magma chamber SC in the case of the spherical (dotted lines), oblate (solid lines) and prolate (dashed lines) reservoirs. Roman numerals are detailed in the main text. And (andalusite), St NU (staurolite); Bt (biotite); Ms (muscovite); Ep (epidote); Pa (paragonite); Pl (plagioclase); Qtz (quartz); M (melt); Crd (cordierite); Grt (garnet); Chl (chlorite); Kfs MA (K-feldspar). D We also run the same simulations for two other crustal compositions including: (i) a TE crustal metamarl (Supplementary Material, Fig. S2), which shows a similar metamorphic trend to the described above for the metapelitic case but with different mineral AC CE P assemblages; (ii) a typical upper crust (Rudnick and Gao, 2003), which shows no contact metamorphic changes as the P-T evolution of the three control points are stable within the same equilibrium mineral assemblage (Supplementary Material Fig. S1). Numerical modeling of heat transfer from the magma chamber to the surrounding crust There is a general agreement when computing numerical simulations of cooling evolution in a magma chamber, about the restrictions or simplifications that may potentially influence the estimates of the thermal effects in the surrounding host rock. On 26 ACCEPTED MANUSCRIPT this regard, many of the existing numerical models so far: (i) simulate the reservoir as a pressurized cavity with a constant heat flux to the country rock (e.g. Jellinek and De PT Paolo, 2003); (ii) assume the thermal properties to keep constant values, including RI diffusivity and specific heat capacity for a constant P, regardless of T (e.g. Gottsmann and Odbert, 2014); (iii) ignore the existence of hydrothermal fluids in the country rock SC (e.g. Gregg et al., 2012); (iv) consider just the conductive term of the heat transfer NU equation assuming that no convection is taking place inside the magma chamber (e.g. Gelman et al., 2013); (v) consider the magma reservoir to be instantaneously emplaced MA (e.g. Gutiérrez and Parada, 2010); and (vi) ignore endothermic metamorphic reactions occurring in the country rocks during the thermal evolution of the aureole (e.g. Jellinek TE D and De Paolo, 2003). Concerning the first simplification, i.e. considering constant heat flux from the AC CE P magma chamber uniformly distributed along the reservoir-host rock contact, it leads to an overestimation of the thermal effects at the country rock (e.g. Gregg et al. 2012). Yet the heat flux from the magma chamber to the country rock is high at the beginning of the magma-cooling episode, but rapidly decreases as the reservoir cools down (Fig. 6). Hence, keeping the thermal heat flux constant during the simulation leads to an overheating of the country rock over long periods of time, which translates in to an overestimate of the thermal aureole’s size and duration. 27 MA NU SC RI PT ACCEPTED MANUSCRIPT Figure 6 (single column): Heat flux along the D-D’ profile at 5 m from the magma D chamber – host rock contact for different time steps. Depth z is normalized towards the magma chamber center depth d, i.e. z/depth = -1 indicates magma chamber horizontal AC CE P TE axis. Results correspond to those obtained with the reference model (M_reference). The second assumption of temperature-independent thermal properties of the magma and country rock limits the model’s accuracy in describing thermal evolution over large temperature ranges. The numerical simulations presented by Nabelek et al. (2012) demonstrated that the modeled longevities of magmatic systems are significantly extended by accounting for thermal dependencies in material properties. The time for the magma solidification is long because of both its low thermal diffusivity and the wall rocks become more insulating as temperature rises (Whittington et al., 2009, Supplementary Material Table S8). Thus, the temperature increase rate and the duration of elevated temperature regimes in the country rock are affected. According to Nabelek et al. (2012), assuming constant diffusivity values does not significantly impact peak temperature values at any location in the country rock. However, once the country rocks 28 ACCEPTED MANUSCRIPT are heated up and their thermal diffusivity decreases, they remain at high temperatures for longer than in models assuming a constant thermal diffusivity (Nabelek et al., 2012). PT As mentioned in the methodology section, our models overcome the first two RI restrictions. The temperature-dependent thermal properties of the crust are considered to be homogeneous among the whole computational domain (i.e. crustal section). However, SC results obtained when changing the thermal properties of the crust (Supplementary NU Material Table S8) indicate that variations in the thermal diffusivity and specific heat capacity may influence the thermal evolution of the country rock, especially the MA temperature value at the metamorphic peak (Supplementary Material Figure S4). Therefore, when working with real case studies, the implementation of a proper TE D numerical model considering the individual geologic units and their specific temperaturedependent thermal properties is strongly recommended (e.g. Cook and Bowman, 1994; AC CE P Cui et al. 2001, Álvarez-Valero et al., 2015; Pla and Álvarez-Valero, 2015). This would allow accounting for variations of the thermal properties due to changes of the host rock composition, water content, porosity, etc. Regarding the third and fourth limitations, i.e. not including magma convection within the chamber as well as neglecting the presence of fluids in the country rock, their effects on the outcomes are still under discussion. On the one hand, internal magmatic convection has been shown to affect peak temperatures in the contact aureole (Jaeger, 1964;Cook and Bowman, 1994). These effects are expected to be minor on distance profiles normal to the igneous contacts of planar or regular geometries, except when being either close to the reservoir-rock contact (Bowers et al., 1990), or next to local reservoir irregularities, such as re-entrants and apophyses (Cook and Bowman, 1994). 29 ACCEPTED MANUSCRIPT Bowers et al. (1990) demonstrated that magmatic convection can also result in isotherm geometries that significantly differ from pure conduction, causing isotherms near the PT igneous contact to conform more closely to the shape of the reservoir. On the contrary, RI Bergantz and Dawes (1994) argued that given a realistic set of parameters and boundary conditions, those models considering convection inside the magma chamber do not give SC fundamentally distinctive results from purely conductive ones. Thus, this evidences that NU the influence of the convective processes inside the magma chamber is not well understood yet and should be analyzed in future works by taking into account as starting MA point, for example, the works by Bea (2010), Gutierrez and Parada (2010) or Koyaguchi and Taneko (2000). TE D Regarding the effects of fluids in the country rock during thermal cooling processes, conductive heat transfer seems to play the prevailing role in the evolution of AC CE P the aureole (Johnson et al., 2011). However, the country rock permeability and amount of fluids seem to control the degree to which conduction or convection may dominate the system (Johnson et al., 2011). The aureoles of intrusions emplaced at shallow crustal levels are most likely to experience significant heat transfer through fluid convection, owing to the higher permeability of wall rocks and the greater availability of significant fluid volumes, including meteoric waters (see Johnson et al., 2011 and references therein). At depths greater than ~8–10 km, as in our models, the role of fluid convection diminishes significantly due to decreased permeability and fluid availability (cf. Johnson et al., 2011) Probably the most remarkable oversimplification in our models is that the cooling magma is emplaced instantaneously in the crust, i.e. we are not modeling the 30 ACCEPTED MANUSCRIPT emplacement and growth of the chamber, but once is already accumulated within the upper crust. Hence, we are not considering possible thermal effects occurring during PT magma ascent and emplacement. Numerous authors also assumed this simplification RI presumably because of numerical limitations but also due to the fact that the main mechanisms of magma transport and emplacement into the crust are not fully understood SC (e.g. Gregg et al., 2012;Gottsmann and Odbert, 2014). From diapirism to hydrofracturing NU (dyke injection), there are several theories aimed to explain how magma arrives at shallow crustal levels and starts accumulating (e.g. Petford and Clemens, 2000; Petford et MA al., 2000). Considering the recent results by Keller et al. (2013), the change from one mechanism to the other, would mainly depend on the host rock viscosity and tensile TE D strength. Numerical models combining transport, emplacement and magma cooling have been recently developed by Gelman et al. (2013). They simulated formations of large AC CE P magmatic reservoirs by periodic accumulations (controlled by the injection rate) of new magma pulses at the bottom of the reservoir. Their results allowed to quantitatively assessing the heat balance between a crystallizing magma and the surrounding crust as it is periodically rejuvenated by hot recharge from below (cf. Gelman et al., 2013). They did not focus on how the accumulating sills may thermally affect the country rock, but on inferring the necessary injection rates to keep melting the upper crust and form huge (>500 km3) batches of mobile silicic magma. We assume that this aspect will depend on the sill size, the injection rate and the thermal properties of the crust. Future works are needed to investigate the thermal effects on the country rock due to magma intrusions based on the way the latter accumulates in the crust either as large single batch or as periodic sill injections. 31 ACCEPTED MANUSCRIPT Finally, our preliminary models allow to broadly constraining the potential feedback between petrological and mechanical changes. Despite this requires a further PT and detailed study of the endothermic reactions record in the host rock to be incorporated RI into the numerical simulations, our calculated temperature regimes and predicted petrological changes represent a novel advance on this purpose. As indicated in previous SC works, the incorporation of metamorphic endothermic reactions into the numerical NU simulations decreases the overall temperature throughout the aureole (Cook and Bowman, 1994) by consuming a significant quantity of heat (Ferry, 1980). This effect MA was investigated in the Cupsuptic pluton (Main, United States) by Bowers et al. (1990) (Fig. 7). They included the chlorite dehydratation reaction in their numerical simulations, TE D which represents the greatest heat sink of all endothermic reactions taking place around the Cupsuptic pluton. Their results also indicated that metamorphic AC CE P reaction leads to a thinner contact aureole (Figure 7a, label I) and to slightly different geometrical distribution of the maximum temperatures around apophyses and pluton’s geometrical irregularities (Fig. 7a, labels II and III). However, they also showed that the general . the no inclusion in the numerical simulations of the endothermic reactions may lead to an overestimation of temperature by as much as 40-50 ºC . Bowers and co-workers considered a non- constant latent heat of crystallization that decreases with temperature (Fig. 7c). Therefore, with time, our calculated temperature regimes and predicted petrological 32 ACCEPTED MANUSCRIPT changes (e.g. Fig. 5) have to be considered as maximum estimates. Due to the nature of the Arrhenius formulation (Eq. 3), to what extent a 40-50 ºC temperature difference PT influences the calculated viscosity for the country rock depends significantly on RI temperature. Thus, for low temperatures, e.g. passing from 400 to 350 ºC, a 50 ºC disparity would translate in a viscosity increase of nearly one order of magnitude, ranging SC from 2.05 1018 to 1.15 1019 Pa s. However, at higher temperatures, a temperature drop NU of 50ºC (i.e. from 900 to 850 ºC) has minor consequences for the viscosity, which just increases from 2.20 1013 to 3.81 1013 Pa s. Accordingly, differences in the numerical MA results due to the endothermic reactions will have a lesser effect close to the contact magma chamber-host rock and at the metamorphic peak, where temperatures are much AC CE P TE D higher. 33 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT Figure 7 (double column): (a) Results for the thermal conduction model of the Cupsuptic pluton carried out by Bowers and co-workers (1990). The left figure shows maximum temperature isotherms computed including effect of the 35 cal/ g of latent heat released non-linearly according to the crystallization model of Nekvasil as shown in (c). The right figure includes both latent heat and the effect of the 20 cal/g endothermic 34 ACCEPTED MANUSCRIPT chlorite dehydration reaction in the aureole. (b) Time-temperature curves at a distance of 40 m from the contact illustrating the consequences on temperature distribution of including latent heat of fusion and the biotite isograd endothermic reaction in the PT numerical simulations (c). Curves for latent heat released with temperature decrease for Cupsuptic melt with 0.25, 0.30, and 0.35 mole fraction water (computed by H. Nekvasil, RI in Bowers et al., 1990). (d) Maximum temperature isotherms obtained from two- SC dimensional conduction heat flow models of an infinite cylinder (left), an infinite parallelepiped (center) and Cupsuptic intrusion (right) (all figures modified from Bowers AC CE P TE D MA NU et al., 1990). Jellinek and DePaolo (2003) pointed out that viscous deformation of wall rocks may 35 ACCEPTED MANUSCRIPT influence the dynamics governing the formation of dikes. Their numerical simulations indicate that this phenomenon is strongly controlled by the influx of new magma into the PT chamber, the reservoir volume, and the country rock rheology. On the one hand, RI chambers of less than 100 km3, with relatively cool wall rocks, can be pressurized up to the critical overpressure needed to form and propagate dikes from the chamber to the SC surface (i.e. 10-40 MPa) (Fig. 8a). On the contrary, assuming a typical magma supply NU rate, larger reservoirs capable of heating the country rock to a great extent, cannot achieve this overpressure. Subsequently, there is a strong tendency for magma to MA accumulate in the chamber, which will continue growing in volume as new magma arrives. Jellinek and DePaolo (2003) stated that it may not be necessary that the viscous TE D regime develops around the entire magmatic reservoir, but just with a substantial fraction of the chamber walls the reservoir would not be able to reach the critical overpressure AC CE P necessary for a magma chamber’s rupture and subsequent dike’s injection. Nonetheless, their results may vary depending on the magma chamber geometry, e.g. l ll with higher curvature (Jellinek and DePaolo, 2003). 36 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 37 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 38 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT upper crust, such as the one of Rudnick and Gao (2003). Since the whole magma body and immediate surrounding host rock fall within the same Bt-Grt-Ab-Kfs-An-Qtz stability field, an increase of the host rock temperature due to the magma accumulation predicts no mineralogical changes based on phase diagram modeling (Supplementary Material Figure S1). Thus, while Equation 3 foresees the existence of a viscous shell around the magma reservoir (Fig. 9a), this may not leave a visible contact aureole due to petrologic alteration This relation is a direct result of the upper crust standard composition used for the P-T pseudosections. While the crustal composition from Rudnick and Gao (2003) is commonly used in numerical simulations, 39 ACCEPTED MANUSCRIPT these results indicate that using an average crustal composition may not provide accurate AC CE P TE D MA NU SC RI PT petrologic predictions for a local, rapidly changing thermal gradient. 40 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 41 AC CE P TE D MA NU SC RI PT ACCEPTED MANUSCRIPT 42 ACCEPTED MANUSCRIPT Figure 7 (single column): Combination of the petrological and thermomechanical results for the different reservoir geometries. Colored areas correspond to the predicted mineral assemblage at the metamorphic peak of C for each model (color code as in PT Fig.5), and the magenta solid and the black dashed lines indicate the log10 of the host rock viscosity (in Pa s) t t=0s (i.e. T = T0_crust , initial crustal temperature based on the RI imposed geothermal gradient) and at the indicated time step , respectively. Roman AC CE P TE D MA NU SC numerals detailed in the text 43 RI PT ACCEPTED MANUSCRIPT AG is grateful for her Ramón y Cajal contract (RYC-2012-11024). A-V thanks the SC assistance of the “Ramón y Cajal” research program (MINECO 2011) and Programa NU Propio I (USal-2014). MD acknowledges the MISTI program (Massachusetts Institute of Technology [MIT] International Science and Technology Initiative) for funding work at MA the University of Salamanca in 2014. The authors are grateful to Carmen Rodríguez and an anonymous reviewer for their insightful comments and review of the manuscript, D which have helped us improve this work. We also thank the Editor Lionel Wilson for his AC CE P TE comments and for handling this paper. References Álvarez-Valero, A.M., Pla, F., Kriegsman, L.M., Geyer, A., and Herrero, H. (2015). Observing silicic magma transport in dykes at depths of 8-19km: Evidences from crustal xenoliths and numerical modelling. 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