Gas quality and custody transfer challenges for UK gas network entry of non-conventionally sourced gases Diane Broomhall and Martin Brown GL Noble Denton GL Noble Denton GL Noble Denton are independent advisors providing consulting, design, assurance and project execution services, combining excellent engineering and analytical skills with operational experience of offshore, maritime and onshore oil and gas assets. Diane Broomhall 2 GL Noble Denton: Gas Quality and Interchangeability GL Noble Denton's consultancy services for Gas Quality include: > network integrity > measurement of gas properties to meet safety and contractual obligations > energy metering and combustion analysis Services used by clients to: > > > > > support planning applications review network operations recommend, specify and evaluate monitoring instrumentation Rhinology practices ensure consistent and accurate energy accounting Training courses on variations in natural gas from different international sources and the impact of these variations Diane Broomhall 3 UK Gas Quality Compliance Statutory: > Gas Safety (Management) Regulations 1996 > Gas (Calculation of Thermal Energy) Regulations 1996 UK Health & Safety Executive > Licenced Gas Transporter’s Safety Case to the HSE Licensed Gas Transporter Policies and Procedures Network Entry Agreement between Licensed Gas Transporter and Gas Producer Diane Broomhall 4 UK Gas Safety (Management) Regulations 1996 Property Range or limit Hydrogen sulphide (H2S) < 5 mg m-3 Total sulphur < 50 mg m-3 Hydrogen (H2) < 0.1 mol % Oxygen (O2) < 0.2 mol % Impurities Wobbe Number The gas shall not contain solids or liquids that may interfere with the integrity or operation of the network or appliances ≥ 47.20 and ≤ 51.41 MJ m-3 ICF (Incomplete Combustion Factor) < 0.48 SI (Sooting Index) < 0.60 Odour Gas below 7 barg will have a stenching agent added to give a distinctive odour Water and hydrocarbon dewpoints Diane Broomhall 5 UK Gas Interchangeability Diagram Diane Broomhall 6 UK Gas (Calculation of Thermal Energy) Regulations Legislates for the transfer of natural gas between producers, transporters and customers Ensures customers receive the thermal energy specified on their gas bill A public gas transporter shall make determinations of calorific values of the gas conveyed by him to premises, or to pipe-line systems operated by other public gas transporters Where a public gas transporter has made a CV declaration, any average calorific value of the gas conveyed to any take off point situated in the area in respect of which the declaration is made is not less than that declared calorific value Any public gas transporter contravening any provision of these Regulations shall be guilty of an offence and liable to be fined Diane Broomhall 7 Practical application of Gas (COTE) Regulations Diane Broomhall 8 Practical application of Gas (COTE) Regulations Diane Broomhall 9 Licensed UK Gas Transporter’s Safety Case to the HSE In order to obtain a Gas Transporter’s licence a Safety Case must be submitted to the UK HSE The Safety Case describes what Policies and Procedures are in place to ensure the safe transportation of gas One such Procedure is a Risk Assessment for all new gas connections Diane Broomhall 10 Risk Assessment for New Gas Connections All UK licensed Gas Transporters have an obligation to ensure: > any new gas connections complies with all statutory legislation with regard to gas quality, calorific value and flow measurement > The safety and integrity of the gas network is not compromised > The new gas will not affect the operation of gas customers’ appliances > Will not impact on the health of the general public either directly or indirectly via gas combustion products Diane Broomhall 11 Risk Assessment for New Gas Connections To ensure the correct gas measurement provisions are included in the new NEA, the risk assessment considers: > > > > > > The content and characteristics of gas Odorisation Calorific value measurement Volume and energy flow measurement Volume flow measurement for network control Wet gas control, monitoring and reporting Diane Broomhall 12 Gas Distribution Network Entry Agreement – Gas Composition Gas Component GS(M)R limits Typical NEA limit 5 mg m-3 = 3.3 ppm (v) 5 mg m-3 = 3.3 ppm (v) Total sulphur 50 mg m-3 50 mg m-3 H2 0.1 mol % 0.1 mol % O2 0.2 mol % 0.001 to 0.2 mol % Total inerts GS(M)R gas interchangeability diagram ≤ 7 mol % and CO2 ≤ 2 mol % Gas content GS(M)R gas interchangeability diagram Suitable for Ofgem approved instruments Total organic halides “impurity” ≤ 1.5 mg m-3 Radioactivity “impurity” ≤ 5 Becquerels g-1 H2S Diane Broomhall 13 Gas Distribution Network Entry Agreement – Gas Properties Gas Property GS(M)R limits Typical NEA limit HC dewpoint Maintain integrity of grid & appliances ≤ -2°C up to 85 barg H2O dewpoint WN, ICF, SI CV Characteristic odour for gas ≤ 7 barg Gas temperature Gas pressure ≤ -10°C @ 85 barg See GS(M)R gas interchangeability diagram WN calculation > Target FWACV - 0.5 MJ m-3 No component that removes gas odorant or suppresses its impact on the human nose — 1 to 38°C Safe for gas appliances Depends on back pressure and MOP @ Delivery Point Diane Broomhall 14 Potential contaminants in non-conventionally sourced gases Potential contaminants in non-conventionally sourced gas Component Biomethane BioSNG Coal bed methane Shale gas High Inerts (CO2, N2) H2S Total Sulphur O2 H2 Moisture Siloxanes Organic halides Micro-organisms Terpenes Aldehydes & ketones Ammonia Volatile metals (Hg, As) Pesticides & Pharmaceuticals CO Diane Broomhall 15 Safety consequences of uncontrolled gas connection Component Safety Consequences Corrosion Steel (gas network) Copper (domestic) High Inerts (CO2, N2) High CO2 + H2O H2S If H2O present Combustion Control of industrial Safety processes Leakage detection by public (odour) Total sulphur O2 Depends of partial pressure of O2 and presence of H2O Moisture Siloxanes Organic halides Micro-organisms If H2O present Terpenes Aldehydes & ketones Ammonia Volatile metals (Hg, As) Pesticides & Pharmaceuticals CO Liquid Hg If H2O present Diane Broomhall 16 New gas connections responsibilities Maximum connection model Diane Broomhall 17 New gas connections responsibilities Minimum connection model Diane Broomhall 18 Challenge for the UK gas networks Educate producers of non-conventionally sourced gases: > GS(M)R compliance is a legal requirement > Producers assume the networks have the capacity to accommodate non-compliant gas > Proof of GS(M)R compliance will be required > Detailed analysis of their raw product will reduce retro-fitted clean-up kit > Analytical equipment must be fit-for-purpose > Equipment for monitoring clean-up process not necessarily good enough for monitoring GS(M)R compliance Diane Broomhall 19 In conclusion: Gas supply to the UK has changed and will continue to change Connection to non-conventionally sourced gas supplies currently limited but expected to increase rapidly Regulatory bodies reviewing some safety limits Gas producers must comply with very specific NEA that includes CV limits for billing Current challenge is the education of gas producers with regard to GS(M)R and Gas (COTE) Regulations Diane Broomhall 20 Thank-you for your attention Contacts details: Diane Broomhall Martin Brown Technical Consultant Senior Consultant Gas Quality Group, Utilities Energy Measurement & Compliance GL Noble Denton GL Noble Denton Phone: +44 1509 282128 Phone: +44 1509 282468 [email protected] [email protected] www.gl-nobledenton.com Diane Broomhall 21 Gas Quality supplies to the UK Diane Broomhall 22
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