Early Paleozoic Tectonic Evolution of the South Tianshan Collisional Belt: Evidence from Geochemistry and Zircon U-Pb Geochronology of the Tie’reke Monzonite Pluton, Northwest China Author(s): He Huang, Zhaochong Zhang, M. Santosh, Dongyang Zhang, Zhidan Zhao, and Junlai Liu Source: The Journal of Geology, Vol. 121, No. 4 (July 2013), pp. 401-424 Published by: The University of Chicago Press Stable URL: http://www.jstor.org/stable/10.1086/670653 . Accessed: 29/07/2013 14:19 Your use of the JSTOR archive indicates your acceptance of the Terms & Conditions of Use, available at . http://www.jstor.org/page/info/about/policies/terms.jsp . JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new forms of scholarship. For more information about JSTOR, please contact [email protected]. . The University of Chicago Press is collaborating with JSTOR to digitize, preserve and extend access to The Journal of Geology. http://www.jstor.org This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Early Paleozoic Tectonic Evolution of the South Tianshan Collisional Belt: Evidence from Geochemistry and Zircon U-Pb Geochronology of the Tie’reke Monzonite Pluton, Northwest China He Huang, Zhaochong Zhang,* M. Santosh, Dongyang Zhang, Zhidan Zhao, and Junlai Liu State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China ABSTRACT We report an Early Paleozoic hornblende quartz monzonitic pluton from the Tie’reke region in the central South Tianshan Collisional Belt (STCB). Laser ablation ICP-MS U-Pb zircon dating reveals that the pluton was emplaced during the Late Silurian at ∼419.9 Ⳳ 2.1 Ma. Our data, together with those from coeval intrusive rocks in the eastern STCB and the eastern Northern Margin of the Tarim Block (NMTB), indicate a major late Early Paleozoic magmatic event in the region. This magmatic event is supported by a detrital zircon U-Pb age population of 462–395 Ma obtained from a Cenozoic sandstone sample from the Kangsu region and an Early Paleozoic metasandstone sample from the Jigen region. Geochemically, the Tie’reke pluton is intermediate in composition, with SiO2 contents ranging from 60.73 to 64.73 wt%, and belongs to the alkali-calcic and shoshonitic series. The pluton displays relative depletion of Nb, Ta, P, and Ti and enrichment of large-ion lithophile elements (Ba, K, and Rb), typical of continental arc–related igneous rocks. Whole-rock Sr-Nd and zircon Hf isotopic data reveal that the magma was derived dominantly from partial melting of the Paleoproterozoic continental crust, with input from juvenile materials from a depleted-mantle wedge. In general, geochronological, geochemical, and isotopic features of the Late Silurian igneous rocks in the present STCB and NMTB, coupled with detrital zircon U-Pb geochronological data from the two sedimentary rocks, suggest that the northern margin of the Paleozoic Tarim Block was an Andean-type active continental margin during Middle Ordovician to Middle Devonian time. Given the coeval magmatism in the Central Tianshan Block, which necessitates a northward subduction of the Paleozoic South Tianshan Ocean, we propose a double-subduction model for the evolution of the Paleozoic South Tianshan Ocean during the Late Ordovician to Middle Devonian period. During the Late Devonian to Middle Carboniferous, the northern margin of the Paleozoic Tarim Block was likely characterized by tectonomagmatic quiescence, whereas the Central Tianshan Block was still extensively affected by arc-type magmatism, furthering the northward subduction of the Paleozoic South Tianshan Ocean. Online enhancements: supplementary tables. Introduction gens on the planet and contains numerous tectonic units, including microcontinents, island arcs, oceanic plateaus, seamounts, ophiolites, and accretionary complexes (Windley et al. 1990, 2007; Jahn et al. 2004; Rojas-Agramonte et al. 2011; Kröner et al. 2013). In general, the Neoproterozoic and Paleozoic tectonics of the CAOB were closely related to the evolution of the Paleo-Asian Ocean and the amalgamation of different terranes (Qian et al. 2007; Han et al. 2011; Xiao et al. 2013; Xu et al. The Central Asia Orogenic Belt (CAOB), also known as the Altaid Tectonic Collage or Altaids, is sandwiched between the Siberian and European Cratons to the north and the Karakum, Tarim, and North China Cratons to the south (fig. 1a; Şengör et al. 1993; Cawood et al. 2009; Xiao et al. 2013). The CAOB is one of the largest accretionary oroManuscript received June 25, 2012; accepted February 3, 2013. * Author for correspondence; e-mail: [email protected]. [The Journal of Geology, 2013, volume 121, p. 401–424] 䉷 2013 by The University of Chicago. All rights reserved. 0022-1376/2013/12104-0005$15.00. DOI: 10.1086/670653 401 This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 402 H. HUANG ET AL. Figure 1. a, Tectonic sketch map of the Central Asian Orogenic Belt. b, Geological map of the Central Tianshan Block, the South Tianshan Collisional Belt, and the Northern Margin of the Tarim Block (modified from Gao et al. 2011; Huang et al. 2012b). c, Geological map of the Tie’reke hornblende quartz monzonitic pluton. 2013). However, the nature of individual terranes in the CAOB and their complete geological record remain to be investigated. The South Tianshan Collisional Belt (STCB), along the southern margin of the CAOB, was formed by the final amalgamation of the Tarim Block to the south and the Central Tianshan Block to the north (present coordinates). Before this collisional event, the two blocks were separated by the Paleozoic South Tianshan Ocean, the southernmost branch of This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT the gigantic Paleo-Asian Ocean. Notably, almost all paleogeographic studies regard the Tarim Block as the last terrane to dock with the CAOB; thus, the formation of the STCB may represent the termination of the prolonged Paleozoic Central Asian accretionary orogeny (Xiao et al. 2010, 2013 and references therein). Consequently, the geological evolution of the STCB is critical for understanding the reconstruction of the Paleozoic tectonic framework of the CAOB. Previous studies have mainly focused on the Late Paleozoic tectonic evolution, including the time of closure of the Paleozoic South Tianshan Ocean and the subsequent collision between the Tarim and Central Tianshan Blocks. The Early Paleozoic tectonic evolution of the region is not well constrained, however. One of the disputed aspects of this evolution involves the Paleozoic South Tianshan Ocean. Some authors argue that the opening of the Paleozoic South Tianshan Ocean was triggered by back-arc extension during southward subduction of the Paleozoic Terskey Ocean (PTO, or Paleo-Tianshan Ocean in some literature; Long et al. 2011a; Wang et al. 2011), which existed between the Paleozoic Central Tianshan Block and the Kazakhstan-Yili Block (KYB). In contrast, other workers suggest that the opening of the Paleozoic South Tianshan Ocean was nearly simultaneous with or even earlier than that of the PTO (see Ge et al. 2012 and references therein). The subduction polarity of the Paleozoic South Tianshan Ocean is also in dispute. Although the northward-subduction (present coordinates) model has been widely advocated (see Han et al. 2011; Xiao et al. 2013 and references therein), a southwardsubduction model, predominantly based on the north-verging ductile deformation in the accretionary complexes, has recently been proposed (e.g., Charvet et al. 2007, 2011; Wang et al. 2011). Intermediate to felsic igneous rocks, widely distributed in the STCB, can be used to constrain the STCB’s geodynamic and tectonic settings. However, most of the rocks examined in previous studies display Late Carboniferous to Early Permian ages and were emplaced in nonsubduction (postcollisional or intraplate) settings. In comparison with those in other terranes of the CAOB, Early Paleozoic igneous rocks are generally rare in the STCB. We have recently discovered a Late Silurian hornblende quartz monzonitic pluton intruding the Precambrian basement strata in the Tie’reke region in the central STCB. This is the first report of detailed investigations of this pluton that includes laser ablation (LA)-ICP-MS U-Pb and Lu-Hf isotopic data and bulk-rock geochemical and Sr-Nd isotopic compositions. In addition, detrital zircon U-Pb ages 403 from a Cenozoic sandstone sample from the Kangsu region and another Early Paleozoic metasandstone sample from the Jigen region are also presented to constrain the geological history of the region. In combination with previously published data, a new tectonic model is proposed for the Paleozoic evolution of the southern margin of the CAOB. Geological Setting The Tianshan (Tien Shan, or Tian Shan) range, extending more than 2500 km from Uzbekistan to southwestern Mongolia, is on the southern margin of the CAOB. Roughly separated by the TuokexunKumishi High Road, the Chinese Tianshan is generally subdivided into eastern and western domains (Gao et al. 2009). Tectonically, the western Tianshan is composed of, from north to south, the North Tianshan Collisional Belt, the KYB, the Central Tianshan Block, the STCB, and the Northern Margin of the Tarim Block (NMTB; fig. 1b). Among these tectonic domains, the North Tianshan Collisional Belt and the STCB are Paleozoic accretionary/collisional belts, whereas the KYB, the Central Tianshan Block and the NMTB are microcontinental blocks or terranes (Li et al. 2006). Detailed descriptions of the geological evolution of the western Tianshan are given in Han et al. (2011), Xiao et al. (2010, 2013), and Long et al. (2011a). Our study focuses mainly on the Central Tianshan Block, the STCB, and the NMTB, and a brief summary on the geological settings of these three terranes is given below. Although the Central Tianshan Block was once considered the southern extension of the so-called Central Tianshan–Yili-Kazakhstan Block, recent geological studies suggest that it is an independent tectonic terrane separated from the KYB by the “Nikolaev Line” in Kyrgyzstan and Kazakhstan and the “North Nalati Fault” in Xinjiang in northwestern China (fig. 1b). Ophiolites are occasionally exposed along the Nikolaev Line–North Nalati Fault. These ophiolites are interpreted as remnants of a paleo-ocean, the PTO, which existed from the end Neoproterozoic until the Early Ordovician (Qian et al. 2007; Gao et al. 2009). To the south, the Central Tianshan Block is separated from the STCB by the South-Central Tianshan Suture (SCTS), also known as the Atbashy-Inyl’chek Fault in Kyrgyzstan and the South Nalati–Qawabulak Fault in northwestern China. The Central Tianshan Block is underlain by Meso- to Neoproterozoic basement, is composed of gneisses, schists, migmatites, and marbles, and is covered by Ediacaran carbonates and tillites. Recent detrital zircon U-Pb geochronology and Hf isotope data (Ma et al. 2012) This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 404 H. HUANG ET AL. reveal that the Central Tianshan Block was likely a component of the Proterozoic “Tarim Craton” (or Xinjiang Craton); therefore, the basement rocks of the Central Tianshan Block show some similarities in age to the STCB and the NMTB. CambrianOrdovician carbonate and flysch are well exposed in Kyrgyzstan (Qian et al. 2007) but are absent in the Chinese segment of the Central Tianshan Block. Late Silurian and Carboniferous island-arc volcanic and volcaniclastic rocks were locally thrust over the basement rocks (Gao et al. 1998; Zhu et al. 2005, 2009). Early Ordovician to Early Permian dioritic and granitic intrusions are extensively exposed in this terrane. The STCB might represent the northernmost margin of the Paleozoic Tarim Block before the final amalgamation, given that the Central Tianshan and Tarim Blocks collided along the present SCTS (Qian et al. 2007; Gao et al. 2009; Han et al. 2011). The basement rocks of this belt are represented by the Paleoproterozoic Xingditagh Formation and the Mesoproterozoic Akesu Formation, both exposed in the central part of the STCB (Yang and Zhou 2009). An accretionary complex composed of Paleozoic ophiolites/ophiolitic mélanges, representing remnants of the Paleozoic South Tianshan Ocean, and two typical high-pressure/low-temperature metamorphic belts, is well exposed south of the SCTS. Ediacaran to Lower Cambrian sedimentary rocks and Cambrian to Carboniferous carbonates, clastic rocks, cherts, and interlayered volcanics are widely exposed in the STCB. Permian strata are sparse and are occasionally composed of terrestrial volcanics unconformably overlying the strongly folded upper Carboniferous marine carbonate rocks (Huang et al. 2012b). Compared to those of other Tianshan terranes, the STCB intrusive rocks comprise only a small proportion, ca. 5%, of the total area and were emplaced mostly during Late Carboniferous to Early Permian time. Some Late Silurian granitoids in the Precambrian basement have been recently identified in the Kuluketage area, the easternmost part of the STCB (Han et al. 2004; Zhang et al. 2007a). The NMTB is the area between the North Tarim Suture to the north and Tarim Desert to the south. In general, the NMTB basement is represented by Archean and Paleoproterozoic metamorphic rocks in the block’s eastern part (Zhang et al. 2010a). Lower to Middle Paleozoic marine chert, limestone, and flysch occur in the central part. Upper Paleozoic limestone, sandstone, and shale with minor volcanic rocks are also widely exposed. In contrast to those of the STCB, the NMTB Permian sedimentary strata are better exposed and conform- ably overlie the upper Carboniferous marine carbonate rocks. Except for one recently identified Late Silurian porphyritic granodioritic pluton in the Korla region (Ge et al. 2012), most NMTB Paleozoic igneous rocks are of latest Early Permian (∼282– 275 Ma) age, and their genesis has been attributed to a mantle plume (Zhang et al. 2008, 2010a; Zhou et al. 2009). Geology and Petrography of the Tie’reke Pluton The Tie’reke region is in the central part of the STCB. The Mesoproterozoic Akesu Formation, composed predominately of granulite facies metamorphic rocks, is well exposed in the southern part of the study area. To the north, the Middle Devonian Alatage Formation, consisting of metasedimentary rocks, tectonically overlies the Akesu Formation. The Middle Carboniferous Kangkelin Formation, in the eastern part of the area, is dominated by shallow marine carbonate and clastic sequences and discordantly overlies the earlier Akesu and Alatage Formations. At least two discrete pulses of magmatism have been recognized in the study area. The earlier is represented by a Neoproterozoic pluton with an emplacement age of ∼657 Ma (Xinjiang Bureau of Geology and Mineral Resources, unpublished data). The hornblende quartz monzonitic pluton of Tie’reke reported in our study is exposed immediately north of the Neoproterozoic pluton, representing the younger magmatic pulse. The pluton outcrops occupy over an area of ∼3.5 km2 and exhibit an intrusive contact relationship with the Mesoproterozoic Akesu Formation. Round to oblong mafic microgranular enclaves (MMEs) commonly occur in the pluton (fig. 2, top). The Tie’reke pluton is mainly composed of hornblende quartz monzonite. The rocks exhibit medium-grained textures and are predominately composed of hornblende (∼20 vol%), K-feldspar (∼35 vol%), plagioclase (∼25 vol%), biotite (∼10 vol%), and quartz (∼5 vol%), with accessory Fe-Ti oxides, titanite, zircon, and apatite (fig. 2, middle). Some feldspar grains are partly altered to kaolinite or muscovite. Poikilitic texture characterized by several anhedral hornblende, biotite, and quartz grains enclosed by subhedral K-feldspar grains is also observed in some thin sections (fig. 2, bottom). Description of Sedimentary and Metasedimentary Samples Since no Early Paleozoic rocks have been found in the western STCB or in the NMTB, we employ This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT 405 detrital zircon U-Pb data to constrain the geological history of the region. As shown in figure 1b, one Cenozoic sandstone sample (DKX-10) was collected from the Kangsu region and one Early Paleozoic metasandstone sample (WGST-1) from the Jigen region. Sample DKX-10 is coarse grained, with a modal content of 170% quartz, 20% K-feldspar, and 5% biotite. Chlorite is the main alteration product. Sample WGST-1 is medium grained and consists mainly of quartz (75 vol%), plagioclase (15 vol%), and biotite (5 vol%), with minor amounts of muscovite. Recrystallized biotite and quartz grains are commonly observed in this sample. Analytical Methods Figure 2. Top, mafic microgranular enclave (MME) in the Tie’reke pluton. Middle, the pluton is predominately composed of euhedral hornblende and biotite, subhedral K-feldspar and plagioclase, and anhedral quartz. Bottom, several anhedral hornblende, biotite, and quartz grains are enclosed by a subhedral K-feldspar grain, suggesting poikilitic texture of the pluton. Bi p biotite; Hb p hornblende; Kf p K-feldspar; Pl p plagioclase; Qz p quartz. A color version of this figure is available in the online edition or from the Journal of Geology office. Zircon U-Pb and Lu-Hf Isotopic Analyses. A representative sample from the monzonite pluton (TLK-2) was selected for zircon separation and UPb age and Lu-Hf isotope analyses. Zircons from the two sandstone/metasandstone samples (DKX10 and WGST-1) were also analyzed. The zircons were separated from crushed rocks with conventional magnetic and density techniques and by handpicking under a binocular microscope. Before isotopic analysis, the morphology and internal structure of the zircon grains were investigated through backscattered electron and cathodoluminescence (CL) imaging that used a LEO1450VP scanning electron microscope with a MiniCL detector at the Institute of Geology, Chinese Academy of Geological Sciences. The CL images were used to select the positions for LA-ICP-MS U-Pb and Lu-Hf analyses (fig. 3a). Zircon U-Pb dating of zircons from sample TLK2 was carried out at the Key Laboratory of Continental Collision and Plateau Uplift, Chinese Academy of Sciences, Beijing, with an Elan 6100 DRC ICP-MS equipped with 193-nm Excimer lasers. UTh-Pb ratios were determined relative to the Plešovice standard zircon, and the absolute abundances of U, Th, and rare earth elements (REEs) were determined by using the NIST 612 standard glass. A mean age of 338.2 Ⳳ 1.5 Ma was obtained for the Plešovice zircon standard. Most analyses used a beam with a 40-mm diameter. Corrections for common Pb were made with the method of Andersen (2002). Data were processed via the Glitter and Isoplot (Ludwig 2003) Excel programs. Errors on individual analyses by LA-ICP-MS are quoted at the 94.5% (1j) confidence level. Details of the analytical procedures can be found in Yuan et al. (2004). U-Pb dating of detrital zircon grains from the This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 406 H. HUANG ET AL. Figure 3. a, Representative cathodoluminescence images showing the internal structure of zircons of sample TLK2 from the Tie’reke pluton. The U-Pb (solid circles) and Hf (dashed circles) analytical sites are marked, and the numbers refer to the analytical data presented in tables S1 and S3. b, U-Pb concordia diagrams of zircons. c, Weightedaverage diagram of zircons. Data-pt errs p data-point errors. sandstone/metasandstone samples used LA-ICPMS at the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan. A pulse Geolas of 193-nm ArF Excimer laser with 50-mJ/pulse energy at a repetition ratio of 10 Hz, coupled to an Agilent 7500a quadrupole ICP-MS, was used for ablation. Zircon 91500 was used as an external standard to normalize isotopic fractionation during analysis. A mean age of 1062 Ⳳ 8 Ma was obtained for the 91500 zircon standard. Zircon standard GJ-1 was analyzed as a controlled standard and was measured four times during the analysis of each sample. Processing of lead isotopic data, U-Pb ages, and traceelement contents used the ICPMSDataCal software (Liu et al. 2010). The external errors of the standard 91500 were propagated to the ultimate results of each analytical spot. In situ zircon Hf isotope analysis of zircon grains from sample TLK-2 was conducted at Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing, and used a New Wave UP213 LA microprobe attached to a Neptune multicollector ICP-MS. With the CL images as guides, Lu-Hf spots were selected to be partly overlapping with or close to those of U-Pb dating. Instrumental conditions and data acquisition were comprehensively described by Hou et al. (2007) and Wu et al. (2006). A stationary spot was used for the analyses, with a beam diameter of either 40 or 55 mm, depending on the size of ablated domains. Helium was used as the carrier gas to transport the ablated sample, This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT mixed with argon, from the LA cell to the ICP-MS torch via a mixing chamber. In order to correct the isobaric interferences of 176Lu and 176Yb on 176Hf, a 176 Lu/175Lu of 0.02658 and a 176Yb/173Yb of 0.796218 were determined (Chu et al. 2002). For instrumental mass-bias correction, Yb isotope ratios were normalized to a 172Yb/173Yb of 1.35274 (Chu et al. 2002) and Hf isotope ratios to a 179Hf/177Hf of 0.7325 with an exponential law. The mass-bias behavior of Lu was assumed to follow that of Yb. Zircon GJ-1 was used as the reference standard, with a weighted mean 176Hf/177Hf of 0.282013 Ⳳ 0.00008 (2j, n p 10) or 0.282013 Ⳳ 0.000024 (2j, n p 10) during our routine analyses. These values are not distinguishable from the weighted mean 176Hf/177Hf of 0.282013 Ⳳ 19 (2j) from in situ analysis by Elhlou et al. (2006). Major and Trace Elements. After careful petrographic examination, a representative suite of six fresh samples from the pluton was crushed and powdered in an agate mill for geochemical analysis. Major and trace (including rare earth) elements were determined in the Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, School of Earth and Space Sciences, Peking University. Major-element compositions were measured by a scanning wavelength-dispersion X-ray fluorescence spectrometer (Thermo ARL Advant XP⫹) on fused glass disks. The analytical precision, as determined on the Chinese National standards GSR-1 and GSR-3, was 11%. Trace-element compositions were determined as solute by Agilent 7500ce ICP-MS. About 50 mg of powder of each sample was dissolved for about 7 days at ca. 100⬚C with HF-HNO3 (10 : 1) mixtures in screw-top Teflon beakers, followed by heating to 70⬚C for 12 h (overnight). Subsequently, the material was dissolved in 7N HNO3, taken to incipient dryness again, and then redissolved in 2% HNO3 to a sample-solution weight ratio of 1 : 1000. According to the analyses of Chinese national standards GSR-1 and GSR-3, the accuracy for most elements was estimated to be better than 5%–15% (relative), depending on their concentrations. Sr and Nd Isotope Analysis. Two samples from the Tie’reke pluton were analyzed for Sr-Nd isotopic compositions at the National Research Center for Geoanalysis, Chinese Academy of Geological Sciences, Beijing. The Sr isotopic compositions were measured by isotope dilution on a Finnigan MAT262 mass spectrometer. Nd isotopic compositions were acquired by a Nu Plasma HR MC-ICP-MS (Nu Instruments). The procedures followed those described by He et al. (2007). Total procedural blanks 407 were !100 pg for Sr and !50 pg for Nd, and the estimated analytical uncertainties of 147Sm/144Nd and 87Rb/86Sr were !0.5%. The 143Nd/144Nd and 87 Sr/86Sr were corrected for mass fractionation by normalization to 146 Nd/142 Nd p 0.7219 and 86 Sr/ 88Sr p 0.1194, respectively. Results Zircon U-Pb Geochronology. Zircon grains separated from sample TLK-2 are prismatic, transparent, and colorless or pale yellow, with lengths varying from 100 to 250 mm and width-length ratios generally ranging from 1 : 1.5 to 1 : 4 (fig. 3a). Thirty-six grains were analyzed, and the results are listed in table S1 (tables S1–S5 are available in the online edition or from the Journal of Geology office). Among these, six spots are discordant, probably reflecting postmagmatic lead loss, and the other 30 fall along a concordia (fig. 3b). The 27 youngest ones are clustered around 206Pb/238Pb ages of 410–430 Ma, with a weighted mean age of 419.9 Ⳳ 2.1 Ma (n p 27, MSWD p 2.8; fig. 3c). The clear oscillatory zoning and high Th/U (0.4– 2.0, with an average of 1.0) of the youngest zircon population indicate a magmatic origin; thus, the weighted mean age can be interpreted to be the crystallization age of the Tie’reke pluton. The second group of three zircons, with 206Pb/238Pb ages of 614 Ⳳ 5, 521 Ⳳ 5, and 661 Ⳳ 6 Ma, also shows oscillatory zoning and high Th/U. They are likely to be inherited zircons captured during magma ascent from the surrounding, slightly older (Neoproterozoic to Cambrian) magmatic rocks. A total of 85 detrital zircons, of which 41 grains were separated from sample DKX-10 and 44 from sample WGST-1, were analyzed. The U-Pb results are listed in table S2. Sixty-six detrital zircon grains have Th/U 1 0.4 (0.41–2.04), and the other 19 yield Th/U from 0.10 to 0.37. Most of the analyses from this sample are concordant or nearly concordant (fig. 4a, 4c). Detrital zircons from sample DKX-10 yield predominantly Paleozoic ages, except for 11 grains with Proterozoic 206Pb/238U ages and one grain with a Triassic 206Pb/238U age (fig. 4b). The Paleozoic grains yield a 206Pb/238U age range of 462– 253 Ma and show two age populations of 462–420 and 302–276 Ma, with two major peak ages at 440 and 293 Ma. In addition, among the sample DKX10 Paleozoic zircons, two grains show 206Pb/238U ages of 396 Ma and one has a 206Pb/238U age of 253 Ma. Sample WGST-1 detrital zircons exhibit a wide range of ages, from latest Mesoarchean to latest Late Ordovician (2814 to 443 Ma, fig. 4d). Among This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 408 H. HUANG ET AL. Figure 4. Combined concordia plots (a, c) and relative probability density-histogram plots (b, d) of detrital zircon ages from samples DKX-10 (a, b) and WGST-1 (c, d). the zircons with ages !1.0 Ga, 14 give 206Pb/238U ages between 904 and 786 Ma and additional seven yield Early Paleozoic 206Pb/238U ages, defining two major age populations. Zircon Lu-Hf Isotopes. Thirty zircons from the grains analyzed for U-Pb that showed a well-defined concordia in the 207Pb/235Pb-versus-206Pb/238Pb diagram were selected for in situ Lu-Hf isotopic analysis (fig. 3b). The decay constant of 176Lu, 1.867 # 10⫺11 per year (Scherer et al. 2001), was adopted in the calculation. Single-stage model ages (TDM) were calculated on the basis of the chondrite model with 176 Hf/177 Hf p 0.282772 and 176 Lu/177 Hf p 0.0332 (Blichert-Toft and Albarède 1997) and the depleted-mantle model with presentday 176 Hf/177 Hf p 0.28325 and 176 Lu/177 Hf p 0.0384 (Griffin et al. 2000). The two-stage continental model age (TDM2) was calculated on the assumption that the initial 176Hf/177Hf of zircon refers back to the depleted-mantle growth curve and using 176 Lu/177 Hf p 0.015 for the average continental crust (Griffin et al. 2000). Twenty-seven spots on the 27 youngest zircon grains (∼410–430 Ma) give 176Lu/177Hf varying from 0.001103 to 0.004662, with an average of 0.002066, indicating very low radiogenic Hf (see table S3). These grains yield variable 176Hf/177Hf between 0.282224 and 0.282505 and corresponding Hf(t) values of ⫺11.4 to ⫺1.4 (calculated at respective 206Pb/ 238 Pb ages; fig. 5a, 5c). The corresponding two-stage model ages (TDM2) were calculated at ca. 1.5–2.1 Ga (fig. 5b). The xenocrystic zircons with ages of 521, 614, and 661 Ma show 176Hf/177Hf of 0.282350, 0.282346, and 0.282446, respectively. Computations based on the 206Pb/238Pb ages yielded Hf(t) values of ⫺4.0, ⫺3.0, and ⫹2.1, respectively (fig. 5). Major and Trace Elements. The major- and traceelement data for six representative samples are pre- This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT 409 sented in table S4. The loss on ignition ranges from 0.94 to 1.94 wt%. In accordance with the petrography, the rocks are intermediate in composition, with SiO2 contents from 60.73 to 64.73 wt%. The other major-element ranges are as follows: 3.96– 5.61 wt% for Fe2O3T, 2.64–3.96 wt% for MgO, 2.54– 3.97 wt% for CaO, 0.19–0.43 wt% for P2O5, and 0.52–0.75 wt% for TiO2. The rocks show high K2O (3.87–5.38 wt%), Na2O (3.84–3.33 wt%), and K2O⫹Na2O (7.20–8.22 wt%) contents. Except for one sample that plots in the alkalic series field, the majority plot in the alkalic-calcic field in the SiO2versus–K 2 O ⫹ Na 2 O ⫺ CaO diagram (fig. 6a). In the SiO2-versus-K2O diagram (fig. 6b), they classify as a shoshonitic series. The Al2O3 contents of the pluton are high, ranging from 14.88 to 16.03 wt%, with A/CNK (molar Al 2 O 3 /(CaO ⫹ Na 2 O ⫹ K 2 O)) values ranging from 0.91 to 1.02, exhibiting metaluminous and slightly peraluminous affinities on A/ CNK-versus-A/NK (molar Al 2 O 3 /(Na 2 O ⫹ K 2 O) plots (fig. 6c). The primitive mantle–normalized spider diagram shows that the Tie’reke pluton is relatively depleted in high-field-strength elements (e.g., Nb, Ta, and Ti, and REEs) but enriched in large-ion lithophile elements (e.g., Rb, Ba, and Th; fig. 7a). The rocks show moderate total REE concentrations, from 181.1 to 337.2 ppm. On the chondrite-normalized REE diagram, light REEs are moderately enriched relative to heavy REEs (HREEs), with (La/ Yb)N varying from 10.3 to 19.4. HREEs show a relatively flat distribution pattern (fig. 7b). The rocks lack any prominent Eu anomaly, with Eu/Eu∗ ranging from 0.77 to 0.91. These geochemical features resemble those of modern arc volcanics and arcrelated plutons (e.g., Pearce et al. 1984; Pearce and Peate 1995) and are comparable to the ∼420-Ma granodiorites in the Korla region in the eastern NMTB (see fig. 7; Ge et al. 2012). The latter has been considered to be emplaced in a continentalarc setting. Sr-Nd Isotopic Compositions. Sr and Nd isotopic data for the Tie’reke samples are listed in table S5, and initial Sr and Nd isotopic ratios are calculated at the age of 420 Ma. The results are shown in the plots of (87Sr/86Sr)t versus Nd(t) in figure 8a and intrusive age versus Nd(t) in figure 8b. Some of the published isotopic data for Paleozoic igneous rocks Figure 5. Histograms showing the distribution of Hf(t) values (a) and two-stage model ages (TDM2; b) and ageversus-Hf(t) diagram (c) for all analyzed zircons from sample TLK-2 and those from the Korla granodioritic pluton (Ge et al. 2012); additional data for the Tarim Block Neoarchean basement from Long et al. (2010, 2011b). CHUR p chondrite uniform reservoir. This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 410 H. HUANG ET AL. from the STCB and the Central Tianshan Block are also shown for comparison. The two Tie’reke pluton samples have low 87Rb/ 86 Sr (0.4052 and 0.6382) and demonstrate relatively high age-corrected (87Sr/86Sr)t (0.71161 and 0.70792). The two samples exhibit 147Sm/144Nd of 0.09317 and 0.10563 and 143Nd/144Nd of 0.51202 and 0.51204. The age-corrected Nd(t) values for the samples are ⫺6.8 and ⫺6.6. Discussion Tectonic Setting and Sources of the Tie’reke Pluton. The petrographic data on the Tie’reke pluton document the ubiquitous presence of hornblende, and the geochemical data show an intermediate, alkalicalcic, shoshonitic, and metaluminous to weakly peraluminous character, broadly comparable with an I-type magmatic source. Furthermore, our samples show relatively low 10000Ga/Al as well as a negative correlation between SiO2 and P2O5 (fig. 9), further indicating an I-type affinity. The intermediate, alkali-calcic and I-type features of the Tie’reke pluton, in combination with the relative depletion of Nb, Ta, P, and Ti and enrichment of large-ion lithophile elements (Ba, K, and Rb), are typical features of arc-related magmatism and are suggestive of an ocean-derived fluid metasomatized source, as in the cases of most modern subductionrelated volcanic and plutonic rocks (e.g., Wood et al. 1979; Briqueu et al. 1984; Pearce and Peate 1995). Furthermore, our samples exhibit moderately fractionated REE patterns, low HREE abundances, and ancient Hf and Sr-Nd isotopic compositions, all of which resemble those of Andean-type continental-arc granitoids (Högdahl et al. 2008; Ge et al. 2012). In the SiO2-versusFeOT/(FeOT ⫹ MgO) and M-versus-F diagrams (Maniar and Piccoli 1989), all of the Tie’reke samples plot in the IAG⫹CAG⫹CCG field (fig. 10a, 10b). In the Y-versus-Nb and Y⫹Nb-versus-Rb discrimination diagrams (Pearce et al. 1984), the rocks fall within the volcanic-arc granite area (VAG; fig. 10c, 10d). We therefore infer that the Tie’reke pluton probably formed in an Andean-type active continental margin. Alternately, the above features could be an inFigure 6. Chemical classification diagrams for the Tie’reke and Huangjianshishan plutons in the South Tianshan Collisional Belt, the Korla pluton in the Northern Margin of the Tarim Block, and some granitoids in the Central Tianshan Block. a, SiO2-versusK2O ⫹ Na2O ⫺ CaO diagram (after Frost et al. 2001). b, SiO2-versus-K2O diagram (after Peccerillo and Taylor 1976). c, A/CNK (Al2O3/(CaO ⫹ Na2O ⫹ K2O))-versus- A/NK (Al2O3/(Na2O ⫹ K2O) diagram (after Maniar and Piccoli 1989). Data sources: Korla pluton: Ge et al. (2012); Huangjianshishan pluton: Zhang et al. (2007a); granitoids exposed in the Central Tianshan Block: Yang et al. (2006); Qian et al. (2007); Gao et al. (2009); Long et al. (2011a); Gou et al. (2012). This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT 411 members of magma sources may include (1) aqueous fluids and/or partial melts released by dehydration of altered oceanic crust and/or subducted sediments, (2) subcontinental mantle wedge, and (3) overriding continental crust (Hawkesworth et al. 1997; Bedard 1999; Macdonald et al. 2000; Elburg et al. 2002; Zhu et al. 2009; Zhang et al. 2010b). In Figure 7. a, Primitive mantle–normalized spidergram for the Tie’reke hornblende quartz monzonitic pluton. b, Chondrite-normalized rare earth element (REE) pattern of the Tie’reke hornblende quartz monzonitic pluton. Trace-element and REE patterns for samples from the Korla granodioritic pluton are shown for comparison, based on the data set published by Ge et al. (2012). Normalized values are from Sun and McDonough (1989). heritance from the source rocks that were ultimately generated in subduction-related tectonic settings. In this case, the arc-like nature cannot be directly utilized to constrain the possible tectonic setting. However, many coeval intermediate to felsic rocks intruding the Precambrian basement rocks have been recently identified in the STCB and the NMTB (see fig. 1b; Han et al. 2004; Zhang et al. 2007a; Ge et al. 2012), and they mark an important tectonothermal event along the NMTB in the Early Paleozoic. Interestingly, despite their variable SiO2 contents, the rocks examined in this study are uniformly characterized by continental arc–like geochemical features (figs. 9, 10). It is unlikely that all of these arc-like geochemical characteristics were inherited from source rocks, in which case a highly variable geochemical and isotopic signature should result. We therefore infer that the Silurian magmatic rocks in the STCB and the NMTB were formed in an Andean-type continental-arc setting. In a continental-arc setting, the possible end Figure 8. Plots of (87Sr/86Sr)t versus Nd(t) (a) and intrusive age versus Nd(t) (b) for the Tie’reke and other intrusive rocks in the South Tianshan Collisional Belt (STCB), the Northern Margin of the Tarim Block, and the Central Tianshan Block. Data sources: Korla pluton: Ge et al. (2012); Huangjianshishan pluton: Zhang et al. (2007a); Jingbulake mafic-ultramafic intrusion: Yang and Zhou (2009); granitoids exposed in the Central Tianshan Block: Zhu et al. (2006); Qian et al. (2007); Long et al. (2011a); Gou et al. (2012). The Sr-Nd data for West Junggar, East Junggar, and the Chinese Altai are obtained from Long et al. (2011a). CHUR p chondrite uniform reservoir. This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 412 H. HUANG ET AL. Figure 9. K2O⫹Na2O–versus–10000Ga/Al (a) and Nbversus–10000Ga/Al (b) diagrams of Whalen et al. (1987) and an SiO2-versus-P2O5 diagram (c), showing the I-type nature of the Tie’reke pluton. Symbols and data sources are as in figure 6. the case of the Tie’reke pluton, our samples generally display high K2O contents (3.87–5.38 wt%) as well as “ancient” whole-rock Sr-Nd isotopic signatures ((87Sr/ 86Sr)t p 0.71161 and 0.70792, Nd(t) p ⫺6.8 and ⫺6.6), and zircon Hf (Hf(t) values for zircon grains with ages of 430–410 Ma are from ⫺11.0 to ⫺1.4, all of which suggests that continental crust was the major source for the magma. The two-stage Hf model ages for ∼410- to ∼430-Ma zircon grains vary from 1.5 to 2.2 Ga, which implies that the source region was mainly composed of Paleoproterozoic basement rocks. The pluton exhibits moderate Sr (305–614 ppm) and high Y (21.3–27.6 ppm) and Yb (2.2–2.8 ppm) concentrations, resulting in low Sr/Y (13.9–26.5) and Sr/Yb (125–284). In addition to the flat HREE patterns (fig. 7), these features preclude garnet as a residual phase (Defant and Drummond 1990; Drummond and Defant 1990; Gou et al. 2012). Besides, the insignificant Eu anomalies (Eu/Eu∗ p 0.77– 0.91) imply a lack of any significant plagioclase fractionation. All these features point to melt generation in the lower part of a normal to slightly thickened crust (!50 km; Ge et al. 2012; Gou et al. 2012). According to previous experimental studies (e.g., Beard and Lofgren 1991; Rapp and Watson 1995), the K2O content of crustal melts is predominately controlled by source rocks and pressure. Furthermore, dehydration melting involving the breakdown of hydrous minerals, such as hornblende or zoisite, more readily gives rise to K-rich melts. At low to normal pressures, high-K crustal magma can be generated by partial melting of moderately hydrous medium- to high-K basaltic rocks (Sisson et al. 2005). All of our samples have low Al 2 O 3 /(FeOT ⫹ MgO ⫹ TiO2 ) (1.67–2.27) and fall in the partial-melt field of amphibolites in a Al 2 O 3 ⫹ FeOT ⫹ MgO ⫹ TiO2– versus–Al 2 O 3 /(FeOT ⫹ MgO ⫹ TiO2 ) diagram (not shown; Patiño Douce 1999), further indicating that the crustal magma was mainly derived from partial melting of K-rich, metabasaltic rocks. However, the presence of xenocrystic zircons, captured by the magma, with Neoproterozoic to Cambrian 206Pb/238Pb ages implies that in addition to the Paleoproterozoic basement rocks, some comparatively younger magmatic rocks were probably assimilated during magma ascent. Indeed, their presence also testifies to some earlier Neoproterozoic to Cambrian magmatic pulses in the study area, although the tectonic settings are still unclear. More importantly, the large variation in ∼410- to ∼430-Ma zircon Hf isotopic compositions (up to 10 units for zircons from a single sample; see fig. 5) precludes the possibility of magma generation in a closed system but instead necessitates This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT 413 Figure 10. Tectonic-setting discrimination diagrams for the granitoids exposed in the present-day South Tianshan Collisional Belt, the Northern Margin of the Tarim Block, and the Central Tianshan Block: SiO2-versus– FeOT/(FeOT ⫹ MgO) (a) and M-versus-F (b) diagrams after Maniar and Piccoli (1989); Y-versus-Nb (c) and Y⫹Nb-versusRb (d) diagrams after Pearce et al. (1984). Symbols and data sources are as in figure 6. a, b, CAG p continental-arc granitoids; CCG p continental-collision granitoids; CEUG p continental epeirogenic-uplift granitoids; IAG p islandarc granitoids; POG p postorogenic granitoids; RRG p rift-related granitoids. c, d, ORG p ocean ridge granites; synCOLG p syn-collisional granites; VAG p volcanic-arc granites; WPG p within-plate granites. a complex process that juxtaposes magmas with variable Hf isotopic compositions. This interpretation is also supported by the occurrence of MMEs and poikilitic texture, both suggesting that a magma-mixing process may have been involved in the genesis of the pluton. Experimental work by Rapp and Watson (1995) showed that melts with Mg# (molar MgO/(MgO ⫹ FeOT)) greater than 40 can be obtained only with a mantle component. Thus, the high Mg# values (61–64) for our samples indicate that the mafic magma involved in the genesis was likely derived from a depleted-mantle wedge. If this is the case, then the absence of zircons with positive Hf(t) values can be explained by possibilities including (1) use of an insufficient number of zircons in the study and/or (2) the fact that zircons are fairly difficult to crystallize in mantle-derived magmas, particularly when they are mafic or ultramafic in composition, until these magmas have sufficiently interacted with crustal This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 414 H. HUANG ET AL. melts and cooled down to the zircon saturation temperature (Watson and Harrison 1983; Ge et al. 2012). In summary, the Tie’reke continental-arc rocks were dominantly produced by partial melting of a Paleoproterozoic crustal source, probably triggered by underplating of mantle wedge-derived magmas, followed by the assimilation of Neoproterozoic to Cambrian igneous rocks during magma ascent. In conjunction with previously published Hf isotopic data for the Korla granodiorites (Ge et al. 2012), we conclude that the involvement of mantle materials is a common feature for the Silurian continental arc–type magmatism in the STCB and the NMTB. Timescale of the Paleozoic South Tianshan Ocean. Some of the fundamental issues related to the tectonic evolution of the Paleozoic South Tianshan Ocean, including its nature and subduction polar- ity, are still under contention. The timescale of the paleo-ocean is an important factor in this context, and we show in figure 11a a compilation of the ages of ophiolitic rocks, including mafic-ultramafic igneous rocks and the sedimentary strata. Two Late Neoproterozoic ages for gabbro and basalt within the Dalubayi ophiolite (see figs. 1b, 11) have recently been reported by Yang et al. (2005). Basalts and gabbros from this ophiolite were interpreted as ocean island igneous rocks (Yang et al. 2005). This interpretation implies that the opening of the Paleozoic South Tianshan Ocean and, consequently, the separation of the Central Tianshan Block from the Proterozoic Tarim Craton took place as early as the Late Neoproterozoic. Note that recent studies have shown that the PTO was likely to have opened in the late Neoproterozoic to early Cambrian and to have closed in the Ordovician (Lomize et al. Figure 11. Simplified schematic diagram showing ages of mafic-ultramafic rocks and sedimentary strata of the representative ophiolites of the STCB. Data sources: Yang et al. (2005, 2011); Liu and Hao (2006); Long et al. (2006); Alekseev et al. (2007); Li et al. (2007); Wang et al. (2007a, 2011, 2012); Kang et al. (2010, 2011); Han et al. (2011). This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT 1997; Bazhenov et al. 2003; Qian et al. 2007; Gao et al. 2009). We infer that the opening of the Paleozoic South Tianshan Ocean was nearly simultaneous with or even earlier than that of the PTO. According to published data sets, the majority of mafic-ultramafic rocks within ophiolites exposed in the STCB have Late Ordovician to Middle Devonian emplacement ages (fig. 11). In fact, the geochemical data on some of the mafic-ultramafic rocks in the ophiolite suites indicate a suprasubduction zone (SSZ) origin. For instance, Wang et al. (2011) reported that mafic rocks—including oceanic island basalt–like alkali basalt and andesite, normal mid-ocean ridge basalt (MORB)–like tholeiitic basalt, sheeted diabase dikes, cumulate gabbro, and peridotite—of the Heiyingshan ophiolite display suprasubduction signatures and were emplaced in a continental-margin setting. However, many researchers have argued that some of the ophiolites exposed on the southern side of the SCTS are tectonic klippen (e.g., Windley et al. 1990; Gao et al. 1998; Han et al. 2011; Xiao et al. 2013 and references therein), and as a result, whether those SSZ-type rocks were initially emplaced in the northern margin of the Early Paleozoic Tarim Block or the southern margin of the Early Paleozoic Central Tianshan Block is debatable. Thus, the SSZ features barely contribute to clarification of the subduction polarity of the Paleozoic South Tianshan Ocean (see below). However, in spite of such uncertainties, the SSZ signatures still suggest that subduction of the Paleozoic South Tianshan Ocean should have begun as early as the Ordovician. In this case, the onset of the subduction of the Paleozoic South Tianshan Ocean was evidently earlier than the emplacement of the Silurian to Carboniferous igneous rocks exposed in the present NMTB, STCB, and Central Tianshan Block, including the Tie’reke pluton. The time of closure of the Paleozoic South Tianshan Ocean and that of the collisional event are also debated. Within the sedimentary rocks of the ophiolites, Middle Devonian to Early Carboniferous microfossils (i.e., radiolarians and conodonts) are well preserved (see fig. 11). This suggests that the final closure of the Paleozoic South Tianshan Ocean, as well as the subsequent collisional event, occurred after the Early Carboniferous. Considering the widespread occurrence of Late Carboniferous to Early Permian collision-related granitoids in the STCB and the Central Tianshan Block (see Gao et al. 2011 and references therein; Han et al. 2011; Huang et al. 2012b) and the ages of high-/ultrahighpressure metamorphic rocks exposed along the SCTS (see Gao et al. 2009, 2011 and references 415 therein; Han et al. 2011), we tentatively propose that the Paleozoic South Tianshan Ocean was closed in the Late Carboniferous, although some workers prefer a Permian- or Triassic-closure model (Xiao et al. 2013 and references therein; also Zhang et al. 2007b). Subduction Polarity of the Paleozoic South Tianshan Ocean. It has been widely accepted that the Early Paleozoic accretionary processes of the Tianshan tectonic collage were closely associated with the evolution of several oceanic basins, all of which were branches of the Paleo-Asian Ocean (e.g., Coleman 1989; Charvet et al. 2007, 2011; Kröner et al. 2007; Xiao et al. 2008, 2013). However, in the case of the Paleozoic South Tianshan Ocean (the southernmost constituent of the Paleo-Asian Ocean), the subduction direction is still a controversial issue. Previous studies were mainly based on kinematic analyses. For instance, the Kyrgyzstan geological data from areas near Atbashi revealed top-to-the-south thrusting on north-dipping thrusts as well as southward propagation of thrusts during the Middle Carboniferous to Early Permian (Hegner et al. 2010; Xiao et al. 2013), supporting a northward-subduction model. In contrast, a southward-subduction model was recently proposed for the Paleozoic South Tianshan Ocean, mainly based on deformation structures in which north-vergent (D1) thrust sheets are documented in the Chinese STCB and NMTB (Charvet et al. 2007, 2011; Lin et al. 2009; Wang et al. 2011). In addition, the SSZ features of some mafic-ultramafic rocks within ophiolites or ophiolitic mélanges, which are exposed in the present STCB, are considered strong evidence for southward subduction (Wang et al. 2011). Some authors (e.g., Coutand et al. 2002; Makarov et al. 2010) emphasize that Tianshan Paleozoic deep structures may have been strongly overprinted and obliterated by Permian-Mesozoic transcurrent and extensional tectonics and thereafter by Cenozoic intracontinental shortening. Furthermore, it is still unknown whether the ophiolites and ophiolitic mélanges are tectonic klippen. As a result, models that rely on kinematic analyses and SSZ features are equivocal. Evaluation of the Paleozoic arc-type igneous rocks in the NMTB, the STCB, and the Central Tianshan Block is a more reliable tool in reconstructing the polarity of oceanic subduction. Because the closure of the PTO occurred in the early Late Ordovician, the Central Tianshan Block should have been amalgamated with the KYB before the Silurian, forming the united Paleozoic Central Tianshan–Yili-Kazakhstan Block. In other words, during Early Silurian to Middle Carboniferous time, the present narrow Central Tianshan This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions 416 H. HUANG ET AL. Block constituted the southernmost margin of the united Central Tianshan–Yili-Kazakhstan Block. In addition, previous studies have suggested that only the igneous rocks in the northern margin of the present KYB were related to the southward subduction of the Paleozoic Junggar Ocean (North Tianshan Ocean in some literature; e.g., Long et al. 2011a). Taking into account the above geological features and the timescale of the Paleozoic South Tianshan Ocean, we postulate that the majority, if not all, of the Early Silurian to Middle Carboniferous igneous rocks located south of the Nikolaev Line–North Nalati Fault (in the present Central Tianshan Block, STCB, and NMTB) should be genetically related to the subduction of the Paleozoic South Tianshan Ocean. We plot in figure 12 the upto-date information on the ages of intrusive rocks from the three terranes. During the subduction of oceanic crust beneath a continental block, subduction-related magmatism takes place only along the active margin of the overriding plate (Han et al. 2011). According to the northward-subduction model, the NMTB has been interpreted as a long-lived passive continental margin. However, some previously studied calc-alkalic to alkali-calcic felsic rocks in the eastern part of the STCB and the NMTB (fig. 12a; Han et al. 2004; Zhang et al. 2007a; Ge et al. 2012) consistently show Silurian ages (430–420 Ma). Our identification of the ∼420-Ma arc-like signature for the Tie’reke monzonitic pluton within the middle segment of the Chinese STCB strongly favors an active continental margin during the Late Silurian. Notably, the Tie’reke pluton intruded into the Mesoproterozoic Akesu Formation, believed to be a constituent of the basement of the Tarim Block (Zhang et al. 2011). Furthermore, when the timescale of the Paleozoic South Tianshan Ocean is taken into account, the Akesu Formation was unlikely to have belonged to the accretionary complex that was produced by the consumption of the Paleozoic South Tianshan Ocean. In addition, considering the established model that the Central Tianshan and Tarim Blocks collided along the present SCTS, it is reasonable to infer that the pluton was initially emplaced in the northern margin of the Early Paleozoic Tarim Block. In the western part of the STCB and the NMTB, no Early Paleozoic rocks have yet been found. Detrital zircon U-Pb data can constrain the geological history of the region. As illustrated in figure 13a, 51 Paleozoic to Early Mesozoic detrital zircon grains exhibit two distinct age populations, 462– 395 and 302–276 Ma. In contrast to the Central Figure 12. Statistics of the zircon ages obtained for the intrusive rocks intruding into the South Tianshan Collisional Belt (STCB) and the Northern Margin of the Tarim Block (NMTB, a) and the Central Tianshan Block (b). Data sources for a: this study; Han et al. (2004); Konopelko et al. (2007, 2009); Wang et al. (2007a, 2007b); Zhu et al. (2008a, 2008b); Zhang et al. (2010a); Huang et al. (2011, 2012a, 2012b); Long et al. (2011a); De Grave et al. (2012); Ge et al. (2012). Data sources for b: Qian et al. (2007); Gao et al. (2009) and references therein; Dong et al. (2011); Long et al. (2011a); Gou et al. (2012). Tianshan Block samples (fig. 13b; details discussed below), the Cenozoic sandstone sample from the Kangsu region lacks detrital zircon grains with ages ranging from 395 to 302 Ma (Middle Devonian to Late Carboniferous), precluding the possibility that the detrital zircon grains were partly derived from the igneous rocks initially emplaced in the Central Tianshan Block. In summary, the abundance of 462–395-Ma detrital zircons in the sandstone samples indicates that the northwestern margin of the Paleozoic Tarim Block was extensively affected by a Middle Ordovician to Middle Devonian mag- This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT Figure 13. Combined relative probability density and histogram plots of the detrital zircon ages from one Cenozoic sandstone and one Early Paleozoic sandstone sample collected from the western part of the South Tianshan Collisional Belt (STCB; our unpublished data; a) and those from modern river sands in the Central Tianshan Block (from Ren et al. 2011; b). The data for detrital zircon grains from the STCB are listed in table S2. A total of 85 detrital zircon grains were dated, and only the 51 grains that exhibit Paleozoic to Early Mesozoic ages are shown here. matic event, likely associated with the subduction of the Paleozoic South Tianshan Ocean. The foregoing discussion suggests that the northern margin of the Paleozoic Tarim Block transformed into an active continental margin with arcrelated magmatism no later than the Late Silurian, probably as early as the Middle Ordovician. This conclusion is also sustained by sedimentary evidence (Ge et al. 2012). A widespread unconformity at the Ordovician-Silurian boundary is well documented in the northern margin and the inner part of the Tarim Block and has been interpreted as representing the transition of the tectonic setting from extension to compression (e.g., Carroll et al. 2001; Shi et al. 2007; Ge et al. 2012). However, even though the northern margin of the Early Paleozoic Tarim Block has been confirmed to have been an active continental margin, the present data still do not support a southward-subduction model. As 417 shown in figure 12b, a large number of continental arc–like igneous rocks with ages ranging from Early Ordovician to Middle Devonian are documented in the present Central Tianshan Block (see references in fig. 12). Even though those generated earlier than the Early Silurian can be regarded as products of PTO subduction, the majority, if not all, of the Early Silurian to Middle Devonian arc-type magmatic records should be interpreted by the subduction of the Paleozoic South Tianshan Ocean. This indicates that, during this time span, the southern margin of the united Paleozoic Central Tianshan– Yili-Kazakhstan Block was an active continental margin as well; accordingly, a double-subduction model is reasonable for the Middle Ordovician to Middle Devonian subduction of the Paleozoic South Tianshan Ocean. The age data synthesized in figure 12a do not show any Middle Devonian to Middle Carboniferous magmatism in the present STCB and NMTB, and the sandstone samples do not contain any ∼395- to ∼302-Ma detrital zircon grains (fig. 13a). Furthermore, the Middle Devonian to Carboniferous shallow marine sedimentary strata, which were interpreted as passive-margin sediments, generally occur in the southern part of the STCB and unconformably overlie the Silurian sequence (Zhou and Chen 1990; Han et al. 2011 and references therein). In contrast to the tectonomagmatic quiescence of the northern margin of the Paleozoic Tarim Block, both geochronological data of intrusive rocks and the detrital zircon U-Pb ages of modern river sands from the present Central Tianshan Block (figs. 12b, 13b) exhibit numerous Late Devonian to Carboniferous ages, confirming long-lived Late Paleozoic magmatism in the southern margin of the united Central Tianshan–Yili-Kazakhstan Block. Thus, it is reasonable to infer that the northern margin of the Paleozoic Tarim Block must have changed into a passive continental margin at least since the Middle Devonian, whereas the southern margin of the united Paleozoic Central Tianshan–Yili-Kazakhstan Block was still an active continental margin during this period. A New Tectonic Evolution Model. Considering these various points, we propose a new tentative model for the tectonic evolution of the southern margin of the CAOB during Late Neoproterozoic and Paleozoic time, as illustrated in figure 14. Our model is derived in part from the ideas developed by previous studies (e.g., Gao et al. 1998, 2009, 2011; Chen et al. 1999; Qian et al. 2007; Xiao et al. 2008, 2009, 2013). In this model, the opening of the PTO and the Paleozoic South Tianshan Ocean and, conse- This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Figure 14. Tectonic-evolution model for the southern margin of the Central Asia Orogenic Belt. This content downloaded from 132.203.169.244 on Mon, 29 Jul 2013 14:19:29 PM All use subject to JSTOR Terms and Conditions Journal of Geology S O U T H T I A N S H A N C O L L I S I O N A L B E LT quently, the separation of Central Tianshan Block and the KYB from the Proterozoic Tarim Craton (or Xinjiang Craton) are presumed to have occurred in the Late Neoproterozoic (fig. 14a), as also recorded by the Xiate transitional MORB (Yang et al. 2005) and the Dalubayi ophiolite mélanges (Qian et al. 2007), respectively. The southward or double subduction of the PTO took place during the Ordovician (Qian et al. 2007; Gao et al. 2009; Long et al. 2011a), leading to the final closure of the oceanic basin and the amalgamation of the Central Tianshan Block in the south and the KYB in the north (fig. 14b) before the Silurian. The double subduction of the Paleozoic South Tianshan Ocean is assumed to have occurred during the Late Ordovician to Middle Devonian, when both the northern margin of the Paleozoic Tarim Block and the southern margin of the united Central Tianshan–YiliKazakhstan Block were active continental margins (fig. 14c). Subsequently, the subduction polarity of the Paleozoic South Tianshan Ocean changed to just northward until the final closure (fig. 14d). Conclusions 1. LA-ICP-MS U-Pb zircon dating indicates that the Tie’reke hornblende quartz monzonitic pluton was emplaced at ∼419.9 Ⳳ 2.1 Ma, in the Late Silurian. 2. The pluton was produced by partial melting of a Paleoproterozoic crustal source, probably through the underplating of mantle wedge-derived magmas, followed by assimilation of Neoproterozoic to Cambrian igneous rocks during magma ascent. 3. The Tie’reke pluton, as well as the other Late 419 Silurian magmatic rocks exposed in the present STCB and NMTB, likely formed in an Andean-type continental arc. Given the coeval arc magmatism in the Central Tianshan Block, a double-subduction model seems applicable to the Late Ordovician to Middle Devonian evolution of the Paleozoic South Tianshan Ocean. 4. Several lines of evidence suggest that the northern margin of the Paleozoic Tarim Block transformed into a passive continental margin at least since the Middle Devonian, whereas the southern margin of the united Central Tianshan– Yili-Kazakhstan Block was still an active continental margin during the period. ACKNOWLEDGMENTS We thank editor D. Rowley and referees W. J. Xiao and A. Robinson for their constructive and helpful comments, which helped improve our manuscript. This study was financially supported by National 305 Project (2011BAB06B02-04) and a Natural Science Foundation of China grant (40925006). A Talent Award to M. 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