Honors Theses Geology - Environmental Studies Fall 2011 Cracking up : lithological controls on non-tectonic rock cracks, Mojave Desert, California Sarah G. Evans Penrose Library, Whitman College This thesis has been deposited to Arminda @ Whitman College by the author(s) as part of their degree program. All rights are retained by the author(s) and they are responsible for the content. CRACKING UP: LITHOLOGICAL CONTROLS ON NON-TECTONIC ROCK CRACKS, MOJAVE DESERT, CALIFORNIA by Sarah G. Evans A thesis submitted in partial fulfillment of the requirements for graduation with Honors in Geology and Environmental Studies. Whitman College 2011 Certificate of Approval This is to certify that the accompanying thesis by Sarah G. Evans has been accepted in partial fulfillment of the requirements for graduation with Honors in Geology and Environmental Studies. _________________________________ Professor Robert J. Carson Whitman College May 11, 2011 - ii - TABLE OF CONTENTS Title Page………………………………………………………………………...……..….i Certificate of Approval…………………………………………………………...……….ii List of Figures……………………………………………………………...……………. iv Abstract……………………………………………………………….…………..……….v Introduction………………………………………………………………………...……...1 Literature Review…………………………………………………………......…..1 Project Goals………………………………………………………….…..….…..6 Geologic Background………………………………………………………………...…...8 Geologic Setting…………………………………………………………...……...9 Environmental Application………………………………………………...……..17 Methods……………………………………………………………………...……...……19 Field Methods…………………………………………………………………...19 Lab Methods………………………………………………………….…………20 Results……………………………………………………………………………...…….23 Discussion………………………………………………………………………………..28 Conclusions……………………………………..……………………………...………...33 References Cited…………………………………………………………………...…….35 Appendix……………………………………………….………………………………..39 A: Crack Orientation Data……………………………………………………..39 B: Raw Crack Data……………………………………………………....……..40 - iii - FIGURE LIST Figure 1: Depiction of the diurnal pattern of solar heating 3 Figure 2: Graph of tensile stresses in heated rock cores of various diameters 4 Figure 3: Example of referred orientation data for cracks not parallel to rock shape or fabric 5 Figure 4: Field site location map 8 Figure 5: Generalized geologic history cross-section of the Mojave Desert 10 Figure 6: Photo of desert pavement 11 Figure 7: Photo of rock varnish 12 Figure 8: Photo of the Providence Mountains 13 Figure 9: Geologic map of Providence Mountains 14 Figure 10: Desert pavement at Cima Volcanic field 15 Figure 11: Geologic map of Cima Volcanic field 16 Figure 12: Photo of transect along the Cima Basalt Flow Surface-I 19 Figure 13: Photo of field methods 20 Figure 14: Crack density box and whisker plot 23 Figure 15: Table of percent of rocks with one or more cracks 24 Figure 16: Images of crack size as a function of rock type 24 Figure 17: Rose diagrams of preferred crack orientations 25 Figure 18: Quantile-quantile plot of preferred crack orientations 26 Figure 19: Image of vesicles in basalt 26 Figure 20: Graph of rock varnish versus crack density 27 Figure 21: Solar path chart for the Mojave field site 29 Figure 22: Image of differences in crack preservation 32 - iv - ABSTRACT Physical weathering affects erosion rates, sediment production, and atmospheric concentrations of CO2, yet non-tectonic-related crack formation is poorly understood. Thermal stresses related to diurnal directional insolation may play the primary role in generating cracks initially, but it is unknown how specific rock properties affect this process. In this study we utilized field data from the 130 ka Providence Mountain alluvial fans and the ~140 ka Cima Volcanic Field basalt flows in the Mojave Desert to determine if crack population characteristics vary as a function of lithology. We measured crack density and orientation for more than 400 rocks along 19 transects. Analysis suggests that rock type influences crack density, size, and orientation. Basalt clasts have a median crack density of 15 c/m2 (cracks per square meter), and metavolcanics have 35 c/m2. Generally about 70% of all rock types excluding basalt contained one or more cracks while only 38% of basalt clasts contained at least one crack. As the density of vesicles increases in basalts, the average number of cracks per clast decreases, possibly due to heat dissipation and reduction of thermal stresses. All rock types display preferred crack orientations with the majority of mean crack orientations toward the northeast. The lone exception to this trend is limestones, which show a southeast trend. The differences in orientations may be due to differences in mineralogy, heat capacity, and other thermodynamic properties of different rocks and minerals, making them susceptible to cracking at different times of the day or year. -v- INTRODUCTION The rate at which rocks break down mechanically is the primary rate-limiting process in landscape evolution and sediment production. Mechanical weathering of rocks initiates a complicated suite of surface processes, all of which depend on the creation of cracks and the exposure of fresh clast surfaces. Since mechanical weathering rates affect chemical weathering rates, long-term changes in mechanical weathering influence global climate via carbon sequestration and the weathering of silicate rocks (Riebe et al., 2004). Furthermore, the surface breakdown of rocks permits desert pavements to form. Since desert pavement plays an important role in stabilizing underlying silt and sand over vast arid regions, this has far-reaching contributions to Earth’s climatic system (e.g., erosion by wind and water is reduced). LITERATURE REVIEW Physical weathering is the mechanical breakdown of rocks into smaller materials. In combination with chemical weathering it plays a key role in the rock cycle. For example, in arid regions the in-situ weathering of existing surface rocks plays a key role in desert pavement formation (Wells et al., 1995). Many near-surface rocks of a variety of lithologies are commonly cracked, representing the initial stages of rock disintegration (McFadden et al., 2005). Thus, the start of mechanical weathering is the formation of an incipient crack. Some cracks may be related to geological inheritance (e.g. tectonics), salt weathering, or -1- forest fires. Many surface clasts exhibit discrete cracks that extend beyond individual grain boundaries throughout a range of climatic and geomorphic settings (Eppes et al., 2010). Cracks are even visible in images of Mars (Eppes et al., 2010). While a substantial body of geologic and geomorphic literature (e.g., Ritter et al. 2002, Blackwelder, 1933) and many researchers (e.g., Goudie et al., 2002) suggest several processes that may cause crack growth and expansion in rocks, the mechanism of crack origin continues to be disputed. Salt weathering has been suggested to be the primary physical weathering process in deserts (e.g., Amit et al., 1993). However, salt weathering appears to be more effective in crack propagation than crack formation (McFadden et al., 2005). Only after salts fit into the clast’s interior via small cracks can crystallization, expansion, or hydration of salts induce thermal stresses significant enough to crack the rock (Amit et al., 1993). Thermal stresses have also been suggested to play an important role in rock weathering and crack formation, especially in deserts. It was recognized as early as 1832 that solar heating caused steep temperature gradients that produced stresses in the outer few centimeters of a clast (Bartlett, 1832). As these stresses increase, exceeding the tensile strength of the rock, brittle failure occurs. However, classic papers of experimental findings by Griggs (1936a, 1936b) cast doubt on the idea that thermal stresses produced by insolation are important in rock cracking. In his experiments Griggs simulated 244 years of diurnal cycling with a uniform temperature range of 10-110 ºC. He found no cracking in his samples. -2- Since Griggs’ experiments, some geomorphologists (e.g., Rice, 1976) continue to argue that insolation is an important process in arid regions, while others continue to rule it out (e.g., Twidale, 1968). Even more recent studies conclude that thermally induced cracks may form, but likely only in secondary association with other processes or in the presence of high levels of moisture or salts (Ritter et al., 2002; Bloom, 1998; Ahnert, 1996). Nearly seventy years after Griggs’ initial papers, geologists continue to dispute the effectiveness of solar insolation in the mechanical breakdown of rocks. Recently, McFadden and others (2005) re-evaluated Griggs’ experiment and Figure 1. Cartoon depicting diurnal pattern of solar heating that creates tensile stresses in rocks, view to north. Boulder exhibits cracking in a direction perpendicular to the direction of the sun’s rays in the morning and afternoon. On the associated sketch warm colors are hot temperatures; cool colors are cold temperatures (McFadden et al., 2005). -3- found a flaw in his methods: clasts in natural environments on the Earth’s surface are not subject to such uniform heating. On the contrary, he discovered clasts on the Earth’s surface experience tensile stresses caused by directional heating and cooling during the sun’s east to west transition across the sky (Fig. 1). McFadden further suggested that these stresses may play the key role in the initial generation of cracks (McFadden et al., 2005). When a clast is heated by insolation cracking, a steep temperature gradient develops in the outer few centimeters of the clast (Warke and Smith, 1994). Clast surface temperature gradients are rapid and not spatially uniform (Sumner, 2004). They produce sufficient stresses (Fig. 2) within the rock surface which exceed the tensile strength of Normal stress (vertical; tensile is positive) at core of clast Figure 2. Temperature and normal stress at the core of rock spheres of different sizes (diameters 0.05, 0.5, and 5.0 m). Positive stresses are tensile. Stresses produced upward of 7-15 Megapascals (MPa = Newton/mm2) (Eppes et al., 2010). -4- most rocks and cause brittle failure (Eppes et al., 2010). Fire-induced rock spalling is a common example of this. Although the diurnal cycles of solar heating and cooling that cause expansion and contraction are of a much smaller magnitude than temperature changes during fires, they tend to penetrate more deeply than fires do (Bloom, 1998). How then may one prove that insolation is the mechanism of crack formation? The majority of cracks on geomorphic surfaces have preferred orientation independent of rock shape and fabric (Fig. 3) (Eppes et al., 2010). These preferred orientations are difficult to explain by mechanisms other than directional insolation heating, as they reflect the largest recurring thermal stresses. Cracks produced by processes such saltshattering would exhibit random azimuthal crack orientations. Likewise, cracks produced by the freezing and thawing cycle of water (freeze-thaw weathering and frost wedging) would not necessarily form depending on the sun’s angle, and would not produce unimodal or bimodal orientations. Figure 3. Rose diagrams of preferred orientation data for cracks not parallel to rock shape or fabric. A. boulders on a variety of geomorphic surfaces (McFadden et al., 2005), B. west-facing boulder field in Virginia, C. a single large boulder on south-facing slope in North Carolina (Eppes et al., 2010). -5- McFadden and others (2005) tested the possibility of insolation crack generation by measuring the orientations of approximately 700 cracks in the southwestern United States (California, Arizona, and New Mexico). They found that a significant number of cracks (462 out of ~700) had a mean orientation of N 5º E ± 12 º. This, they concluded, was fundamentally related to thermal stresses that arise daily from non-uniform heating. Furthermore, their research supported the hypothesis that insolation plays a key role in the physical weathering of rocks exposed to the sun, and that this mechanism is viable in other climates, as well as outcrops, man-made structures, and rocks in non-terrestrial environments. Eppes and others (2010) further explored these north-south insolation-generated cracks. Azimuth orientation of ~470 cracks was measured in three desert study sites: the Mojave Desert of southern California, the Gobi Desert of Mongolia, and the Strzelecki Desert of Australia. The mean orientation for all data over all three sites was N 26º E ± 30 º, again supporting a preferred crack orientation in deserts of various latitudes and around the globe. Based on this data they concluded that thermal conditions resulting in maximum temperature gradients on the rock surface are the most important for inducing rock fractures with preferred orientations. Additionally, Eppes and others (2010) proposed that rock size, surface age, latitude, aspect, and lithology play important roles in the formation of on rock cracks. PROJECT GOALS Despite these recent investigations, it is still unknown how specific rock properties affect cracks initiated by thermal stresses related to diurnal directional -6- insolation. In this study I measured rock cracks in the field to determine if non-tectonic rock crack population characteristics vary as a function of rock type. We measured over 400 rocks and 600 cracks in the Mojave Desert, California. My fellow REU researchers examined three other aspects of insolation cracking: age, rock shape, and relations between rock cracks and surface parallel faces. By analyzing our data and comparing our results we were able to constrain the relationship between rock characteristics and insolation-generated cracks, further characterizing the role of the sun in the propagation of rock fractures. -7- GEOLOGIC BACKGROUND Data was obtained from the Providence Mountain alluvial fans and the Cima Volcanic Field basalt flows in the arid eastern Mojave Desert (Fig. 4). Both the Providence Mountain alluvial fans and Cima Volcanic basalt flows are classic localities of desert geomorphology, desert ecology, and desert soil chronosequences. They have been studied extensively for their classic examples of desert pavement (e.g., McFadden et al., 1989). Thus they represent a unique location to build on existing work in order to further understand the role of Cima Volcanic Field physical weathering in landscape evolution. Mojave Desert Preserve Cima Providence Mtns. Prov. Mtns. Figure 4. Field sites were located in California, in the western portion of the Mojave National Preserve (USGS, 2009). Google Earth images illustrate the Qf3 Providence Mountain alluvial fans in the southern portion of the Mojave and Cima Volcanic Field basalt Surface-I in the northern portion of the Mojave. Stars identify the fans or flows where rocks were measured. -8- In the southern Mojave Desert, elevations range from ~600 m in the distal fan areas to more than 2000 m at mountain tops (McDonald et al., 2003). Plant communities are characterized by sparsely scattered scrubs, Larrea tridenata (creosotebush), Ambrosia dumosa (white bursage), Yucca schidigera (Mojave yucca), juniper, and grasses with no large trees (McDonald et al., 2003). The climate ranges from arid to semi-arid with an average rainfall of approximately 150 mm which is associated with winter Pacific frontal storms (McDonald et al., 2003). GEOLOGIC SETTING During the Proterozoic the region that is now the Mojave Desert in southern California experienced little structural change as erosion gradually wore down the landscape to nearly sea level. As the supercontinent Rodinia began to rift apart, a protoPacific basin developed. The edge of the North America continent gradually sank beneath the ocean surface, and a thick sequence of sedimentary rocks began to accumulate on the continental margin. This miogeosynclinal, passive continental margin (Fig. 5 ―A‖) continued to be passive for approximately 800 Ma. The great carbonate-rich sedimentary rock section preserved in the Mojave region records that during this time North America gradually drifted northward across the equatorial region, becoming home to a warm, shallow continental platform (USGS, 2009). This passive margin continued until the Triassic Period (~ 240 Ma) when the supercontinent Pangea began to rift apart, forming a new subduction zone and the Atlantic Ocean basin. The relative westward motion of the North American continent caused the its western margin to override the adjacent oceanic crust (Fig. 5 ―B‖). In addition to subduction, erosion began to degrade -9- the exposed rocks and sediment, and magma generated by subducting plates caused igneous activity. Beginning in the Jurassic Period, an extensive volcanic arc developed across the Mojave region, and granitic batholiths were emplaced (USGS, 2009). Figure 5. Generalized geologic history cross-section of the Mojave Desert (USGS, 2009). - 10 - Extrusive and intrusive volcanism ended in Late Cretaceous time (~80 Ma). Then, beginning in the Late Oligocene Epoch (~ 30 My\a), new tectonic forces acted on the landscape. A great rift-style fault system developed across the region as the Great Basin began to spread apart (Fig. 5 ―C‖). The Mojave Block was uplifted around 25 Ma. Around 18 to 14 Ma two detachment fault systems affected parts of the Mojave. Today active fault systems in the region are a result of right-lateral shearing forces associated with the San Andreas Fault system (USGS, 2009). Throughout the Late Tertiary and Quaternary periods, large volcanic eruptions occurred fairly frequently in the region. Ash recurrently blanketed the landscape; many ash beds are preserved in the alluvial deposits today. The last volcanic episode in this area was about 8,000 ka. Climate changes during the last millions of years were mostly Figure 6. Desert pavement is a distinctive surficial feature where at least 65% of the soil surface is clast-covered (Wood et al., 2004). - 11 - responsible for the majority of the landscape features evident today (USGS, 2009). There is no evidence of tectonic activity along the mountain front during the late Quaternary (McDonald et al., 2003). In more recent time, inflationary desert pavements have formed (Fig. 6). These pavements originate as a surface of coarse particles. The protruding cobbles attract fines, which settle and sift downward through the spaces between the larger clasts, ejecting the cobbles upwards. Infiltrating rainwater aids this process. Such desert pavements are marked by silty layers within the soil Vesicular A Horizon (Av). Additionally, many of the Mojave rock surfaces have rock varnish (Fig. 7). Rock varnish is formed by wind-transported manganese- and iron-rich clays that become plastered to wet desert rocks, becoming oxygenated with dew or carbonic acid in rain. Figure 7. Rock varnish as pictured here is a shiny, thin, red/brown layer of manganese oxides and iron oxides. - 12 - N Figure 8. The Providence Mountains of the Mojave range in elevation from 600 to 2000 m, shedding sediment to create eight different Quaternary alluvial fan depositional units. The carbonic acid in rain separates manganese from iron, and then oxidizing conditions concentrate manganese oxides and hydroxides as a cement to form the varnish (Dorn, 2007). In recent times both desert pavement and rock varnish serve as signs that the clasts have not been disturbed by humans or recent floods. The Providence Mountains (Fig. 8) are a prominent feature along the eastern edge of the Mojave. Eight alluvial fans have been identified in the Providence Mountains based on stratigraphic relations, gravel bar relief, soil development, pavement particle size, and distinct weathering characteristics (McDonald et al., 2003). These aggregated over one and a half million years (McDonald et al., 2003). Locally fans are labeled from Qf8, modern fans, to Qf1, from the early Pleistocene Epoch (Fig. 9). All fans are suggested to have accumulated during wet times or transitions between climatic regimes. Fans were deposited along the western margin of the Providence Mountains and grade to - 13 - an extensive draa associated with the Kelso Dunes (McDonald et al., 2003). Each fan has bar and swale depositional topography, with a half to a whole meter of relief. Figure 9. Geologic map of Providence Mountains showing Qf3 fans in dark gray (McDonald et al., 2003). - 14 - For this study, measurements were taken only from the Qf3 Middle Pleistocene, 130 ka alluvial fan surfaces in the Providence Mountains (McDonald et al., 2003). Qf3 fans were distinguished by having a strong desert pavement, clay loam between clasts, and an argillic to petrocalic B horizon (McDonald et al., 2003). Limestone clast faces are very etched. Qf3 was deposited during OIS 6, when climate was wetter than present (Eppes et al., 2003). The elevation here is approximately 975 m. Approximately 30 miles north of the Providence Mountains lies the Cima Volcanic field (Fig. 10). Here K-Ar dated basalt flows range in age from early to latest Pleistocene (McFadden et al., 1987; Wells et al., 1985). Flow surfaces have developed coarse accretionary mantles composed of weathered bedrock with fine eolian deposits trapped by the irregular flow-top surface. The lava flows overlie Tertiary crystalline rocks and gravels (Wells et al., 1985). There is well-preserved desert pavement on all N Figure 10. Desert pavement in the Cima Volcanic Field. - 15 - flows. Flow slopes range from ~3% to ~6% with a mean slope of ~4.5%. Many basalt clasts have calcium carbonate rinds. For this study to be comparable with the Qf3 Providence Mountain alluvial fan, data was only taken from Surface-I (Fig.11), a 140 ka basalt flow surface with an approximate elevation of 1000 m (Wells et al., 1985). This flow was chosen in hopes of avoiding confounding variables because it most closely matched the 130 ka, 975 m elevation Providence Mountain alluvial fan surface. Figure 11. Geologic map of Cima Basalt Flows showing Surface-I in yellow (Wells et al., 1985). - 16 - ENVIRONMENTAL IMPLICATIONS Insolation-generated cracking affects mechanical weathering, which increases surface area, therefore affecting chemical weathering rates. Long-term changes in mechanical and chemical weathering influence global climate via carbon sequestration and the weathering of silicate rocks (Riebe et al., 2004). Furthermore, the surface breakdown of rocks permits desert pavements to form in arid lands. Since desert pavement plays an important role in stabilizing underlying silt and sand over vast arid regions, this has far-reaching contributions to Earth’s climatic system (e.g., erosion by wind and water is reduced) (Eppes et al., 2010). Rock breakdown is closely associated with chemical weathering of silicate minerals which influences the amount of carbon dioxide (CO2) in the atmosphere (Chernicoff and Whitney, 2002). When the atmosphere is rich in CO2 the climate warms via the greenhouse effect. In this situation, atmospheric CO2 allows incoming shortwave, ultraviolet radiation to pass through to the Earth’s surface. This CO2 also traps outgoing, long-wave radiation near the surface, warming the Earth’s atmosphere. Conversely, when the amount of heat-trapping CO2 is relatively low, the global climate cools. CO2 is added to the Earth’s atmosphere through volcanic eruptions and extrusion of mantle-derived magma at oceanic divergent boundaries (Chernicoff and Whitney, 2002). This CO2 is then integrated into many surface processes, including chemical weathering. The following equation outlines the general reaction illustrating the role of CO2 in chemical weathering: - 17 - silicate minerals + CO2 + H2O→ carbonate minerals + SiO2 (in solution) Thus, as the rate of chemical weathering increases, the amount of CO2 that is removed from the atmosphere and stored in carbonate minerals will increase, perhaps driving global cooling (Chernicoff and Whitney, 2002). In arid regions the in-situ weathering of existing surface rocks plays a key role in desert pavement formation (Wells et al., 1995). The formation of desert pavements also has plays a unique effect on global climate. Desert pavement limits infiltration and delivers rainfall as runoff to nearby bare ground areas where scrubs cluster (Wood et al., 2004). Additionally, desert pavements shield surfaces from eolian processes while capturing eolian sand, silt, clay, and salts. While quantitative models of desert pavement development explain many features of landforms, until now, no mechanism has been proposed to account for the rapid breakdown of both cobbles and boulders into the stable clasts that form the pavement of these fans and flow surfaces. Insolation-generated cracks allow desert pavement formation. A distant and perhaps unexpected connection arises between desert pavement and global climate, since desert pavement plays an important role in stabilizing underlying silt and sand over vast arid regions (Eppes et al., 2010). Thus, any temporal or spatial variation in the process that changes the rate of formation of desert pavements has the potential to alter climate by changing the dustiness of our planet. - 18 - METHODS FIELD METHODS Over 400 rocks and 600 cracks were measured along 19 transects; nine along the Qf3 (130 ka) alluvial fan surface and ten along the surface-I (140 ka) of the Cima basaltic field. These surface ages (130 ka and 140 ka, respectively) were determined in previous surveys by C-14 dating and K-Ar dating, respectively (e.g., McDonald et al., 2003; Wells et al., 1985). Transects (Fig. 12) were completed by laying a 100-m tape parallel to the fan or a’a’ flow surface within the area of highest rock density. Data was collected for each rock that fell under every half-meter tick mark of tape, moving up each fan or flow. If a rock under the half-meter tick mark did not meet the size specifications that follow or there was no rock under the mark, the area under the mark was scanned in a clockwise direction to locate the closest rock to the tick mark. The following data was collected for each rock: rock type, width, length, depth, azimuthal orientation of the rock’s longest axis, and number of total cracks. It was also noted whether or not the rock had granular disintegration, fabric, spalling, vesicles, rock Figure 12. Transect along the Cima Basalt Flow Surface-I. varnish, microcracks (>2 cm in length), and if it was embedded. - 19 - Characteristics were measured for every crack. A crack is defined as a linear void of which ambient light did not illuminate the bottom. Cracks shorter than 2 cm, rocks longer than 5cm or greater than 50 cm, and rocks with evidence of disturbance such as a displaced CaCO3 collar or unaligned rock varnish were excluded. Current active channels were not studied because cracking there could be attributed to joint inheritance and transport. If the rock was not disturbed, it was recorded regardless of whether or not it had any cracks. For Figure 13. Author collecting data in stylish extra-large golden shorts―all the rage in the Mojave. every crack data was collected with a ruler and Brunton compass (Fig. 13). Crack data collected included: observed crack type (ie. fabric, longitudinal, spall, or other), maximum width, length, strike, and dip. Any crack with a width less than 0.5 mm was recorded as incipient. Rock types measured include: metavolcanic rocks, basalt rocks, limestone rocks (also fine-grained marbles), and coarse- and fine-grained plutonic rock. We attempted to minimize sample bias by collecting data with a consistent procedure for each transect. However, inherent bias is preserved by the non-random choice of transect locations. LAB METHODS Data was analyzed with open-source GEOrient © v9.4.4 software (Holcombe, 2009) and Oriana © v3.0 (Kovach Computing Services, 2009) to plot crack orientation data as - 20 - rose diagrams (Fig. 17). Data was also plotted as a quantile-quantile plot (Fig. 18). Fisher (1993) suggested that a quantile-quantile plot of i(n-1) vs. Xi/180 is a more objective, visual indication of preferred orientations for circular data, where n=total number of data points, Xi is the orientation value of the data converted to 0-180 for axial data, and i is the ranking of those data from 1 to n. If data is perfectly uniform and random, then it will fall on a line that intersects the orgin at (0,0). Systematic, periodic deviations from this straight line indicate preferred orientations in that azimuthal direction (e.g., Fig. 18). Statistics were analyzed with R © v2.10.1 (R Foundation for Statistical Computing, 2009) software, GEOrient © v9.4.4, and Oriana © v3.0 to report circular variance as well as the Rayleigh Uniformity Test and Rao's Spacing Test (all after Fisher, 1993; Mardia and Jupp, 2000). Circular variance is a simple measure (0 to 1) of the scatter of recorded crack azimuths; values close to 0 indicate low variance, and values close to 1 indicate high variance (McFadden et al., 2005). This statistic is based on a von Mises distribution (in circular statistics, a normal distribution is referred to as a von Mises distribution) of data about a single mean (i.e., unimodal data). Therefore, for multimodal data, the variance might be high, but the data might nevertheless be non-uniform. ―The Rayleigh Uniformity Test calculates the probability of the null hypothesis that the data are distributed in a uniform manner. Again, this test is based on statistical parameters that assume that the data are clustered about a single mean. If p-values for this test are <0.05 then data are considered nonuniform or non-random. Rao's Spacing Test is also a test for the null hypothesis that the data are uniformly distributed; however, the Rao statistic examines the spacing between adjacent points to see if they are roughly equal - 21 - (random with a spacing of 360/n) around the circle. Thus, Rao's Spacing Test is appropriate for multi-modal data and may find statistical significance where other tests do not. If the p-value for this test is <0.05, then the data are considered to be non-random‖ (Eppes et al., 2010). These statistics are expressed in Appendix A. - 22 - RESULTS Data recorded along the 19 transects in the Providence Mountains and Cima flows is presented here. This data represents a total of 604 cracks measured on 407 rocks. Results will be presented in terms of crack density, crack size, crack orientation, and influential factors. CRACK DENSITY Most rocks on all examined surfaces exhibited cracks. Crack density, defined as the total number of observed cracks per rock area (m2), varies as a function of rock type. Basalt rocks have a median crack density of 15, coarse plutonic have 26, fine plutonics have 22, limestones have 24, and metavolcanics have 35 (Fig. 14). However, it is important to notice the large size of the error bars (Fig. 14). Crack Density (# total cracks/rock area [m2]) 1000 100 10 1 Basalt Coarse Plutonic Fine Plutonic Limestone Volcanic Metavolcanic Figure 14. There is a nearly significant effect of rock type on crack density (F=2.33, p=0.059). - 23 - Additionally, around 70% of all rock types excluding basalts contained one or more cracks (Fig. 15). Only 38% of basalt rocks from the Cima flow contained at least one crack. Figure 15. Percent of rocks with one or more rock crack (p=0.018). CRACK SIZE There appears to be a pattern of crack widths and lengths as a function of rock type (Fig. 16). Basalts have the widest cracks (1.52 +/- 1.16 mm) and coarse plutonics have the narrowest cracks (0.87 +/- 0.66 mm). Average crack lengths also vary by rock type. Fine plutonics have the longest average length (49 +/- 30 mm) and basalts have the shortest average length (38 +/- 20 mm). Figure 16. Differences in crack sizes between limestone (left) and fine plutonic rocks (right). - 24 - CRACK ORIENTATION A large number of all cracks have a nonrandom, moderately strong north-south orientation. All rock types display preferred crack orientations, but crack vector mean orientation varies by rock type (Appendix A). N 47° E N 79° E N 92° E Basalt 0.90 > p > 0.50; n=83 Coarse Plutonic 0.50>p>0.10; n=89 Metavolcanic p < 0.01; n=191 S 54° E N 67° E Limestone 0.50 > p > 0.10; n=89 Fine Plutonic 0.50 > p > 0.10 ; n=152 Figure 17. Rose diagrams of preferred crack orientations, rock type labeled. Rao’s Spacing Test results listed on diagram, p<0.05 indicates non-random orientation of data. Mean resultant direction as calculated by Oriana © v 3.0 is in red. The majority of mean resultant directions of crack orientation is toward the northeast with N 75° E for all plutonic rocks, N 92° E for basalts, and N 47° E for metavolcanics. The lone exception to this northeast trend is that found in limestones with a southeast trend, S 54° E (Fig. 17). Orientation data is also expressed in a quantile-quantile plot as discussed in the lab methods (Fig. 18). Limestone (green) deviates most strongly from - 25 - the crack orientations of the other rock types on both the rose diagram and quantilequantile plot. All Rocks Basalt Limestone Coarse Plutonic Fine Plutonic Metavolcanic n=total number of data Xi=orientation values of data (0-180) i= ranking of data from 1 to n Figure 18. Quantile-quantile plot of preferred crack orientations. If data are perfectly uniform and random, they will fall on a line that intersects at the origin (0,0). Deviations from this straight line indicate non-random, preferred orientations (Fischer 1993). INFLUENTIAL FACTORS The most notable confounding variables in this study were the presence of vesicles and rock varnish. As the density of vesicles increased in basalts, the average number of cracks per rock decreased, possibly due to heat dissipation and reduction of thermal stresses (Fig. 19). Most rock types with 76-100% rock varnish coverage rock had - 26 - Figure 19. Vesicles in basalt may dissipate heat. a higher average number of cracks (Fig. 20). However, this may be a function of rock age. That is, an older rock will have accumulated more rock varnish, as well as more cracks, as both appear to be a function of age (Eppes et al., 2010). Metavolcanic Figure 20. Clasts with more rock varnish covering the surface have more average cracks than those with little varnish. - 27 - DISCUSSION Previous studies (e.g., McFadden et al., 2005 and Eppes et al., 2010) predicted that the stresses related to diurnal directional insolation play the primary role in initially generated cracks. If this solar mechanical process, related to directional insolation, is indeed the primary cause of cracking in desert clasts, and different minerals exhibit different thermal properties, then there should be a difference in initial crack generation and thus crack density and orientation among rock types. To test this hypothesis, I developed a field-based strategy to attempt to document variations in crack initiation in different rock types. Results support initial crack generation from solar insolation in clasts as a function of rock type, thereby providing additional evidence of the importance of directional insolation in cracking rocks. Specifics in crack orientation, density, and size differences among rock types may be due to differences in mineralogy, coefficients of thermal expansion, clast energy threshold, and other thermodynamic properties of different rock types and minerals. COEFFICIENT OF THERMAL EXPANSION The majority of mean resultant directions of crack orientation is toward the northeast from N 75° E for all plutonic rocks, to N 92° E for basalts, and N 47° E for metavolcanics. The lone exception to this northeast trend is that found in limestones, whose cracks have a southeast trend, S 54° E. These specific variations in crack orientations of different rock types may suggest that the coefficient of thermal expansion and thus the efficiency of heat absorption is different for different temperature ranges of unique minerals (Moores et al., 2008). If so, our data suggests that afternoon cracks (Fig. - 28 - 21) play a predominant role in limestone cracks (mean orientation of S 54° E), while other rock types might be more susceptible to morning cracking. Eppes et al., 2010 suggested that observed differences in mean resultant directions and modality reflected the times of day that are most influential in producing insolation cracks. They found the most influential time of the day to be the morning, proposing that the early-morning 10 20 30 40 50 60 70 80 90 Jun 21 May21 Apr 20 19h 18h 17h 16h Mar 20 15h 14h Jun 21 5h 6h May21 Apr 20 7h 8h Mar 20 9h 13h 12h 11h 10h Feb 20 Feb 20 Jan 21 Jan 21 Dec 21 Dec 21 Limestone Basalt Plutonic Metavolcanics Figure 21. Solar path chart for the Mojave field site, modified from a chart created through the University of Oregon Solar Radiation Monitoring Laboratory website. Shaded areas represent times and days when the sun would be at 90° to the mean resultant observed crack angles. - 29 - temperature gradient is most important for cracking rocks (Eppes et al., 2010). During this morning warming, ambient air temperatures are low and the insolation of the sunrise rapidly heats one side of a rock surface, causing the greatest stress to build up over the clast surface (McFadden et al., 2005). This would therefore suggest that limestone rocks behave contrary to the morning norm with preferred afternoon cracking. However, this may also indicate that limestone is more susceptible to winter water freeze-thaw cracking as compared to summer insolation cracking. Greater winter cracking may be explained by limestone’s increasing likeliness to crack and weather when wet via the chemical weathering process of etching (CO2 + H2O→ carbonic acid), which brings minerals into solution and cracks the limestone. Etching could occur during the winter monsoons in the Mojave. It must be kept in mind that monsoonal or other temporally-controlled diurnal and seasonal conditions have likely been variable over the past 130 ka. If indeed cracking has been changing partially as a function of climate over the last 130 ka, crack populations with varying preferred orientations may develop for a particular site. This adds additional explanation to the observed multimodality in the crack orientation rose diagrams. DIFFERENCES IN MINERALOGY If cracking varies by clast mineralogy, then cracks should occur along different mineral boundaries depending on the chemical composition of the mineral. Ebherhardt and others (1999) showed that the initiation and development of stress-induced microcracks in granite varies by mineral. Samples of Lac du Bonnet granite were - 30 - stressed with weight in a laboratory to observe how cracks formed in relation to different minerals. Results suggested that initial cracking occurred along grain boundaries between quartz and feldspar grains, and intragranularly within feldspar grains. These cracks occurred when a significant number of critically oriented cracks initiated and propagated in the sigma one (the greatest compressive stress) direction, opening cracks perpendicular to the axial load (Ebherhardt et al., 1999). This evidence that cracks occur through or next to minerals depending on their composition supports the theory that crack orientations may vary as a function of mineralogy. DIFFERENCES IN OTHER THERMODYNAMIC PROPERTIES Our data suggests that characteristics such as the presence of vesicles likely have an effect on rock cracking. Basalts may have a comparatively low average crack density (around 70% of all rock types excluding basalts contained one or more cracks while only 38% of basalt rocks from the Cima flow contained at least one crack) likely due to heat dissipation and reduction of thermal stresses through vesicles. The presence of vesicles does not allow sufficient thermal stresses to build, keeping the pressure below 7 MPa, and preventing tensile failure and the formation of a crack. This is supported not only by correlation between decreases in the average number of cracks with increases in the density of vesicles, but also by crack size data: cracks on basalt rocks are comparatively short, due to a relatively low amount of tensile stress buildup on the clast surface that would be needed to cause long cracks. - 31 - CRACK PRESERVATION Basalt rocks have a median crack density of 15, coarse plutonics have 26, fine plutonics have 22, limestones have 24, and metavolcanics have 35. However, differences in crack density may be partly a function of crack preservation instead of susceptibility to cracking (Fig. 22). For example, cracks may not be preserved in plutonic rocks because cracks tend to form at grain boundaries, resulting in rapid granular disintegration. Similarly, in limestone, edges of cracks that form at the clast surface dissolve rapidly and challenging to identify on etched surfaces. This hypothesis is supported by crack size data presented previously where cracks on plutonic rocks never achieve large sizes. Figure 22. An example of differences in crack preservation between a coarse plutonic rock (left) and limestone (right). Overall this data supports the hypothesis that there is a correlation between rock type and crack orientation, density, and size. Also supported is the hypothesis that surface rock cracks may exhibit preferential orientations as a function of rock type. Since the majority of cracking is in the NE quadrant, this data also provides additional evidence of the importance of directional insolation in cracking rocks. - 32 - CONCLUSIONS The agreement of this Mojave Desert data with previous studies (e.g., McFadden et al., 2005, Eppes et al., 2010) supports the hypothesis that surface rock cracks may exhibit preferential orientations as a function of rock type, thereby providing additional evidence of the importance of directional insolation in cracking rocks. Evaluation of this data indicates that rock type plays an important role with respect to rock crack density and size. With the exception of basalt, differences in crack density and size are likely attributed to differences in crack preservation for different rock types, not necessarily to differences in the rate of cracking. For basalts, data correlating crack density with vesicle volume suggest that cracks do not form as rapidly in vesicular basalt, possibly due to heat dissipation in vesicles. Rock type should be further evaluated to explore the mechanisms such as differences in mineralogy, clast energy threshold (ala Moores et al., 2008), and other thermodynamic properties that might control cracking. - 33 - ACKNOWLEDGMENTS This study was made possible through the National Science Foundation Research Experience for Undergraduates, NSF Award #EAR-0844335. Thank you to the Sweeny Granite Mountains Desert Research Center for the wonderful housing. Special thanks to Professors Bob Carson and Nick Bader at Whitman College and Professor Missy Eppes at University of North Carolina at Charlotte for their excellent advice, editing, and immeasurable help along the way. A huge thank you to my fellow REU-ers: Ivy, Josh, and Kiernan for sweating, measuring, and experiencing the Mojave with me. Lastly, a big thank you fellow geology majors at Whitman and my parents− thank you for laughing with and supporting me along the way. - 34 - REFERENCES CITED Ahnert, F., 1996, Introduction to Geomorphology: Arnold, London, UK, 352 p. Amit, R., Gerson, R., and Yaalon, D.H., 1993, Stages and rate of the gravel shattering process by salts in desert Reg soils: Geoderma, v. 57, p. 295–324. Bartlett, W.H.C., 1832, Experiments on the expansion and contraction of building stones by variations in temperature: American Journal of Science, v. 22, p. 136–140. Blackwelder, E.B., 1933. The insolation hypothesis of rock weathering. American Journal of Science v.226, p.324–340. Bloom, A.L., 1998, Geomorphology—A Systematic Analysis of Late Cenozoic Landforms, 3rd Edition: New Jersey, Prentice Hall, 482 p. Chernicoff, S., and Whitney, D., 2002, Geology: An Introduction to Physical Geology, 3rd Edition: Houghton Mifflin Harcourt, 648 p. Ebherhardt, E., Stimpson, B., Stead, D. 1999. 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S., Kirchner, J. W., Finkel, R. C., 2004. Erosional and climatic effects on long-term chemical weathering rates in granitic landscapes spanning diverse climate regimes. Earth and Planetary Science Letters, vol.244, no.3-4, p.547-562. Ritter, D.F., Kochel, R.C. and J.R., M., 2002. Process Geomorphology. McGraw Hill, Boston, 530 p. Sumner, P., 2004. Rock weathering rates on subantarctic Marion Island: Arctic, Antarctic, and Alpine Research, v. 36,p.123-127. Twidale, C.R., 1968, Geomorphology with special reference to Australia: Nelson, Melbourn and Sydney, 406 p. United States Geologic Survey (USGS), 2009, General Geologic History of Mojave Region. http://pubs.usgs.gov/of/2004/1007/geologic.html [accessed 02/06/2011]. Warke, P.A., and Smith, B.J., 1994, Short-term rock temperature fluctuations under simulated hot desert conditions: Some preliminary results, Robinson, D.A., and Williams, R.B.G., eds., Rock weathering and landform evolution: Chichester, UK, John Wiley and Sons Ltd., p. 57–70. Watson, A., 1992, Wells, S.G., McFadden, L.D., Dohrenwend, J.C., Mahrer, B.D., 1985. Late Cenozoic landscape evolution of lava flow surfaces of the Cima volcanic field, Mojave Desert, California. Geological Society of America Bulletin, v. 96, p.1518–1529. Wells, S.G., Dohrenwend, J.C., McFadden, L.D., 1985, Turrin B.D., Mahrer, K.D., Late Cenozoic landscape evolution on flow surfaces of the Cima volcanic field, Mojave Desert, California, Geological Society of America Bulletin, v. 96, p. 15181529. Wells, S.G., McFadden, L.D., Poths, J., and Olinger, C.T.,1995, Cosmogenic 3He exposure dating of stone pavements: Implications for landscape evolution in deserts: Geology, v.23, p. 613–616. Wood, Y.A., Graham, R.C., Wells, S.G., 2004, Surface control of desert pavement - 37 - pedologic process and landscape function, Cima Volcanic field, Mojave Desert, California: Catena, v.59, p. 205-230. - 38 - APPENDIX A. CRACK ORIENTATION DATA Rock Type Number of Observations Mean resultant direction 1 Circular 1* Variance Rayleigh 2* Test (p) Basalt 83 N 92° E 0.59 0.923 Limestone 89 S 54° E 0.52 0.17 Coarse Plutonic 89 N 79° E 0.46 0.01 Fine Plutonic 152 N 67° E 0.51 0.083 Metavolcanic 191 N 47° E 0.44 0.638 1 Calculated with GEOrient © v9.4.4 2 Calculated with Oriana © v 3.0 *See page 21 for explanation of variables - 39 - Rao’s Spacing Test (p) 2* 0.90 > p > 0.50 0.50 > p > 0.10 0.50 > p > 0.10 0.50 > p > 0.10 <0.01 APPENDIX B. RAW CRACK DATA FROM PROVIDENCE MOUNTAINS AND CIMA VOLCANIC FIELD, MOJAVE DESERT, CALIFORNIA Rocks with zero cracks are not included, but were used in data analysis. Strike Dip Rock Type 2 63 B 3 38 B 10 18 B 15 74 B 19 57 B 26 53 B 36 85 B 37 38 B 37 60 B 42 73 B 44 81 B 48 70 B 56 65 B 59 73 B 65 67 B 70 79 B 73 81 B 85 68 B 87 76 B 95 67 B 96 89 B 98 50 B 99 63 B 103 11 B 104 89 B 106 66 B 109 76 B 110 79 B 112 17 B 116 82 B 118 72 B 122 41 B 124 35 B 126 63 B 133 75 B 296 61 B 56 87 CP 135 73 B 298 72 B 57 82 CP 138 78 B 305 48 B 57 48 CP 139 35 B 305 88 B 58 81 CP 144 43 B 310 72 B 59 84 CP 145 89 B 311 70 B 59 77 CP 159 64 B 323 72 B 61 90 CP 170 74 B 326 61 B 62 45 CP 174 75 B 334 39 B 64 42 CP 174 73 B 336 73 B 68 54 CP 187 63 B 338 37 B 70 38 CP 196 86 B 340 64 B 85 38 CP 204 55 B 344 50 B 87 73 CP 212 50 B 351 68 B 93 80 CP 220 75 B 0 73 CP 97 59 CP 221 66 B 5 49 CP 100 72 CP 221 76 B 5 65 CP 105 4 CP 221 70 B 12 89 CP 107 62 CP 228 16 B 16 46 CP 109 54 CP 239 69 B 23 81 CP 109 68 CP 240 67 B 33 53 CP 109 67 CP 240 67 B 35 38 CP 109 54 CP 246 68 B 36 65 CP 112 80 CP 250 74 B 37 32 CP 117 73 CP 251 33 B 39 60 CP 119 74 CP 252 70 B 39 71 CP 131 76 CP 253 48 B 43 38 CP 133 77 CP 254 65 B 44 38 CP 147 79 CP 261 77 B 48 52 CP 147 90 CP 263 65 B 51 46 CP 150 20 CP 263 66 B 51 85 CP 158 10 CP 265 69 B 52 72 CP 163 59 CP 268 83 B 52 33 CP 170 19 CP 273 80 B 52 37 CP 172 65 CP 294 80 B 53 69 CP 176 45 CP - 40 - 197 78 CP 9 56 FP 95 53 FP 176 88 FP 210 63 CP 10 77 FP 96 75 FP 177 41 FP 218 60 CP 11 7 FP 98 71 FP 184 70 FP 233 88 CP 22 76 FP 99 66 FP 185 73 FP 234 55 CP 24 74 FP 102 36 FP 187 75 FP 243 12 CP 25 81 FP 103 73 FP 188 40 FP 245 46 CP 26 76 FP 103 52 FP 189 84 FP 250 62 CP 30 14 FP 103 88 FP 189 78 FP 252 39 CP 34 74 FP 105 60 FP 195 87 FP 259 18 CP 38 77 FP 106 81 FP 197 87 FP 264 47 CP 39 36 FP 110 65 FP 201 50 FP 269 64 CP 39 79 FP 110 56 FP 204 45 FP 270 56 CP 39 62 FP 112 51 FP 205 74 FP 274 80 CP 39 76 FP 114 3 FP 209 31 FP 283 64 CP 40 74 FP 115 70 FP 210 45 FP 285 38 CP 41 54 FP 115 67 FP 211 24 FP 285 34 CP 41 78 FP 118 51 FP 212 75 FP 287 6 CP 43 61 FP 119 30 FP 213 54 FP 290 74 CP 50 50 FP 121 57 FP 214 2 FP 291 32 CP 53 52 FP 127 77 FP 220 78 FP 294 82 CP 54 61 FP 129 71 FP 224 74 FP 294 76 CP 58 5 FP 130 84 FP 230 80 FP 308 58 CP 60 75 FP 134 80 FP 230 80 FP 309 89 CP 61 65 FP 136 35 FP 236 79 FP 309 21 CP 68 0 FP 140 26 FP 242 77 FP 317 76 CP 69 68 FP 140 74 FP 245 73 FP 321 42 CP 75 81 FP 142 84 FP 246 54 FP 323 39 CP 75 58 FP 144 65 FP 247 52 FP 325 30 CP 81 65 FP 145 77 FP 248 81 FP 330 63 CP 82 55 FP 148 22 FP 249 45 FP 334 30 CP 83 69 FP 156 26 FP 258 31 FP 335 82 CP 85 74 FP 156 73 FP 261 63 FP 356 71 CP 85 54 FP 157 58 FP 262 40 FP 0 64 FP 86 68 FP 159 33 FP 264 17 FP 1 71 FP 86 70 FP 164 1 FP 265 61 FP 1 29 FP 87 61 FP 165 78 FP 267 56 FP 2 30 FP 88 45 FP 165 76 FP 269 62 FP 2 55 FP 89 26 FP 168 72 FP 269 70 FP 5 63 FP 89 73 FP 171 45 FP 270 66 FP 6 39 FP 95 12 FP 175 65 FP 271 49 FP - 40 - 274 81 FP 69 83 L 190 81 L 7 42 V 276 5 FP 71 44 L 203 86 L 8 49 V 276 48 FP 73 21 L 213 73 L 16 84 V 278 78 FP 78 71 L 213 34 L 18 66 V 279 87 FP 81 54 L 215 49 L 20 16 V 280 44 FP 85 47 L 215 90 L 20 30 V 288 76 FP 86 54 L 218 64 L 20 50 V 290 76 FP 91 80 L 225 90 L 25 61 V 291 55 FP 91 68 L 250 68 L 26 21 V 298 66 FP 94 48 L 268 72 L 27 72 V 314 26 FP 97 78 L 272 73 L 29 23 V 322 43 FP 104 55 L 280 41 L 34 56 V 323 51 FP 104 77 L 285 78 L 34 76 V 329 61 FP 107 12 L 289 74 L 35 85 V 330 39 FP 107 49 L 290 44 L 36 54 V 339 78 FP 109 24 L 292 68 L 36 25 V 342 66 FP 114 64 L 293 8 L 37 87 V 344 78 FP 114 22 L 295 79 L 38 74 V 347 68 FP 114 33 L 298 56 L 43 57 V 348 51 FP 115 66 L 298 73 L 44 44 V 352 44 FP 116 59 L 300 75 L 46 75 V 353 36 FP 116 62 L 307 45 L 49 78 V 353 71 FP 116 65 L 308 49 L 50 29 V 356 59 FP 126 71 L 309 68 L 50 13 V 359 69 FP 135 18 L 311 19 L 51 41 V 0 80 L 141 63 L 312 75 L 51 54 V 5 54 L 142 8 L 314 63 L 53 242 V 9 71 L 143 75 L 315 66 L 54 75 V 12 47 L 143 60 L 323 69 L 54 63 V 16 38 L 144 12 L 331 74 L 55 50 V 19 49 L 146 67 L 335 90 L 55 62 V 21 79 L 148 27 L 344 64 L 58 60 V 21 85 L 149 66 L 348 18 L 60 22 V 27 45 L 149 74 L 352 60 L 60 29 V 27 83 L 158 72 L 359 46 L 60 45 V 28 86 L 160 80 L 3 60 V 62 34 V 36 41 L 161 70 L 4 54 V 63 78 V 38 62 L 165 94 L 5 16 V 64 35 V 50 84 L 175 75 L 5 21 V 65 56 V 64 78 L 186 31 L 5 66 V 65 71 V - 41 - 67 35 V 168 75 V 229 80 V 292 19 V 70 44 V 170 64 V 230 68 V 292 68 V 73 24 V 170 29 V 230 74 V 293 71 V 76 37 V 172 49 V 231 10 V 293 30 V 79 64 V 174 40 V 234 79 V 295 22 V 79 40 V 174 14 V 239 48 V 295 63 V 81 78 V 175 67 V 239 70 V 297 66 V 81 55 V 175 69 V 244 12 V 299 41 V 83 36 V 176 62 V 244 37 V 300 70 V 90 19 V 176 55 V 254 53 V 301 44 V 91 44 V 179 55 V 254 20 V 302 24 V 93 88 V 180 36 V 255 75 V 302 31 V 94 63 V 180 49 V 257 70 V 303 35 V 97 67 V 180 20 V 259 79 V 304 56 V 99 65 V 181 70 V 259 72 V 305 335 V 99 30 V 181 10 V 260 66 V 307 16 V 101 75 V 183 61 V 265 76 V 308 35 V 104 14 V 184 114 V 265 80 V 311 68 V 113 84 V 184 44 V 268 52 V 314 52 V 122 86 V 186 63 V 269 60 V 314 44 V 123 48 V 186 61 V 270 75 V 315 26 V 125 34 V 190 76 V 270 35 V 319 43 V 125 28 V 190 90 V 271 75 V 320 55 V 125 9 V 191 90 V 271 79 V 321 44 V 131 41 V 193 78 V 271 60 V 331 53 V 135 84 V 194 46 V 274 75 V 332 48 V 138 31 V 195 65 V 274 55 V 332 68 V 142 86 V 198 43 V 276 52 V 340 116 V 148 40 V 204 76 V 278 71 V 340 65 V 150 29 V 204 62 V 280 68 V 342 71 V 152 43 V 204 64 V 280 50 V 351 42 V 160 72 V 205 64 V 284 41 V 351 44 V 161 66 V 205 78 V 285 49 V 353 90 V 162 68 V 206 44 V 288 51 V 355 44 V 163 44 V 209 86 V 288 48 V 357 52 V 164 67 V 211 74 V 288 39 V 358 53 V 165 58 V 212 64 V 289 67 V 165 20 V 214 79 V 289 78 V Key: B=Basalt, CP= Coarse Plutonic, FP=Fine Plutonic, L=Limestone, V=Metavolcanic - 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