NiMH Batteries
ChemWatch Review SDS
Chemwatch Hazard Alert Code: 4
Chemwatch: 61-7122
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 17/12/2015
Print Date: 22/11/2016
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name
Synonyms
Proper shipping name
Other means of
identification
NiMH Batteries
Not Available
BATTERIES, NICKEL-METAL HYDRIDE
Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Sealed batteries. NOTE: Chemical materials are stored in sealed metal case. The toxic properties of the electrode materials are hazardous only if the
materials are released by damaging the cell or if exposed to fire.The sealed battery is not hazardous in normal use. The MSDS Risk codes and the chemical
hazards are related to the leaked battery contents.
Details of the supplier of the safety data sheet
Registered company name
Address
Telephone
Fax
Website
Email
Dentsply (Australia) Pty Ltd
11-21 Gilby Road Mount Waverley VIC 3149 Australia
1300 55 29 29
+61 3 9538 8260
www.dentsply.com.au
[email protected]
Emergency telephone number
Association / Organisation
Emergency telephone
numbers
Other emergency telephone
numbers
Poisons Information Centre (AUSTRALIA)
13 11 26 - AUSTRALIA (24 hour service)
Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Min
Flammability
Toxicity
Body Contact
Reactivity
Chronic
Max
0
2
4
0
2
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule
Classification [1]
Legend:
Not Applicable
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1, Respiratory
Sensitizer Category 1, Skin Sensitizer Category 1, Germ cell mutagenicity Category 2, Carcinogenicity Category 2, Specific target organ toxicity - repeated
exposure Category 1, Acute Aquatic Hazard Category 1, Chronic Aquatic Hazard Category 1
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD
DANGER
Hazard statement(s)
H302
Harmful if swallowed.
Continued...
Chemwatch: 61-7122
Page 2 of 11
Version No: 2.1.1.1
NiMH Batteries
H332
Harmful if inhaled.
H314
Causes severe skin burns and eye damage.
H318
Causes serious eye damage.
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317
May cause an allergic skin reaction.
H341
Suspected of causing genetic defects.
H351
Suspected of causing cancer.
H372
Causes damage to organs through prolonged or repeated exposure.
H410
Very toxic to aquatic life with long lasting effects.
Issue Date: 17/12/2015
Print Date: 22/11/2016
Precautionary statement(s) Prevention
P201
Obtain special instructions before use.
P260
Do not breathe dust/fume/gas/mist/vapours/spray.
P271
Use only outdoors or in a well-ventilated area.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P301+P330+P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340
P305+P351+P338
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Precautionary statement(s) Storage
P405
Store locked up.
Precautionary statement(s) Disposal
P501
Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No
%[weight]
Name
hermetically sealed container contains;
7439-92-1
<40
lead
7440-43-9
<20
cadmium
18540-29-9
<5
chromium(VI) ion
7439-97-6
<5
mercury (elemental)
59536-65-1
<1
polybrominated biphenyls
12054-48-7
<30
nickel(II) hydroxide
1310-58-3
<20
potassium hydroxide
1310-73-2
<20
sodium hydroxide
Not Available
<30
Ingredients determined not to be hazardous
electrolyte liquid of
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
Skin Contact
Inhalation
If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin or hair contact occurs:
Immediately flush body and clothes with large amounts of water, using safety shower if available.
Quickly remove all contaminated clothing, including footwear.
Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
Transport to hospital, or doctor.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Continued...
Chemwatch: 61-7122
Page 3 of 11
Version No: 2.1.1.1
NiMH Batteries
Issue Date: 17/12/2015
Print Date: 22/11/2016
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
Transport to hospital, or doctor.
For advice, contact a Poisons Information Centre or a doctor at once.
Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Transport to hospital or doctor without delay.
Ingestion
Indication of any immediate medical attention and special treatment needed
For acute or short-term repeated exposures to highly alkaline materials:
Respiratory stress is uncommon but present occasionally because of soft tissue edema.
Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary.
Oxygen is given as indicated.
The presence of shock suggests perforation and mandates an intravenous line and fluid administration.
Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow deep penetration into the tissue.
Alkalis continue to cause damage after exposure.
INGESTION:
Milk and water are the preferred diluents
No more than 2 glasses of water should be given to an adult.
Neutralising agents should never be given since exothermic heat reaction may compound injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.
Supportive care involves the following:
Withhold oral feedings initially.
If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.
Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.
Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).
SKIN AND EYE:
Injury should be irrigated for 20-30 minutes.
Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]
In cases of nickel poisoning, dimercaptol delivered by deep intramuscular injection may be a suitable antidote. (Patients should not exhibit renal or hepatic dysfunction.) The use of
diethyldithiocarbamate is the subject of ongoing research.
Irritant contact dermatoses or eczemas may respond to applications of weak antiseptic packs, antibiotic ointments (tetracycline or erythromycin) or inert pastes and ointments. Systemic
antibiotics are advisable in the presence of lymphangitis or lymphadenitis.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Special hazards arising from the substrate or mixture
Fire Incompatibility
None known.
Advice for firefighters
Fire Fighting
Fire/Explosion Hazard
HAZCHEM
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Slight hazard when exposed to heat, flame and oxidisers.
Non combustible.
Not considered to be a significant fire risk.
Heating may cause expansion or decomposition leading to violent rupture of containers.
May emit acrid smoke.
Not Applicable
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up
Minor Spills
Clean up all spills immediately.
Secure load if safe to do so.
Bundle/collect recoverable product.
Collect remaining material in containers with covers for disposal.
Continued...
Chemwatch: 61-7122
Page 4 of 11
Version No: 2.1.1.1
Issue Date: 17/12/2015
Print Date: 22/11/2016
NiMH Batteries
Clean up all spills immediately.
Wear protective clothing, safety glasses, dust mask, gloves.
Secure load if safe to do so. Bundle/collect recoverable product.
Major Spills
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
||
Safe handling
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Never disassemble a battery.
Do not store disorderly fashion or allow metal objects to be mixed with stored batteries.
|
Other information
DO NOT store near acids, or oxidising agents
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Store away from incompatible materials.
Keep batteries between -20C to 35C.
Conditions for safe storage, including any incompatibilities
Suitable container
Packaging as recommended by manufacturer.
In presence of moisture, the material is corrosive to aluminium, zinc and tin producing highly flammable hydrogen gas.
Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.
Avoid contact with copper, aluminium and their alloys.
Storage incompatibility
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source
Ingredient
Material name
TWA
STEL
Peak
Notes
Australia Exposure Standards
lead
Lead, inorganic dusts & fumes (as Pb)
0.15 mg/m3
Not Available
Not Available
Not Available
Australia Exposure Standards
cadmium
Cadmium and compounds (as Cd)
0.01 mg/m3
Not Available
Not Available
Not Available
Australia Exposure Standards
chromium(VI) ion
Chromium (VI) compounds (as Cr), water soluble
0.05 mg/m3
Not Available
Not Available
Sen
Australia Exposure Standards
mercury (elemental)
Mercury, elemental vapour (as Hg)
0.025 mg/m3 / 0.003 ppm
Not Available
Not Available
Not Available
Australia Exposure Standards
potassium hydroxide
Potassium hydroxide
Not Available
Not Available
2 mg/m3
Not Available
Australia Exposure Standards
sodium hydroxide
Sodium hydroxide
Not Available
Not Available
2 mg/m3
Not Available
EMERGENCY LIMITS
Ingredient
Material name
TEEL-1
TEEL-2
TEEL-3
lead
Lead
0.15 mg/m3
120 mg/m3
700 mg/m3
Not Available
cadmium
Cadmium
Not Available
Not Available
mercury (elemental)
Mercury vapor
0.15 mg/m3
Not Available
Not Available
nickel(II) hydroxide
Nickel(II) hydroxide; (Nickelous hydroxide)
0.071 mg/m3
8.8 mg/m3
53 mg/m3
potassium hydroxide
Potassium hydroxide
0.18 mg/m3
2 mg/m3
54 mg/m3
sodium hydroxide
Sodium hydroxide
Not Available
Not Available
Not Available
Ingredient
Original IDLH
Revised IDLH
lead
700 mg/m3
100 mg/m3
cadmium
50 mg/m3 / 9 mg/m3
9 mg/m3 / 9 [Unch] mg/m3
chromium(VI) ion
Not Available
Not Available
mercury (elemental)
10 mg/m3 / 28 mg/m3
2 mg/m3 / 10 mg/m3
polybrominated biphenyls
Not Available
Not Available
nickel(II) hydroxide
N.E. mg/m3 / N.E. ppm
10 mg/m3
potassium hydroxide
Not Available
Not Available
sodium hydroxide
250 mg/m3
10 mg/m3
Ingredients determined not to
be hazardous
Not Available
Not Available
Exposure controls
Appropriate engineering
controls
None under normal operating conditions.
Provide adequate ventilation in warehouse or closed storage areas.
Continued...
Chemwatch: 61-7122
Page 5 of 11
Version No: 2.1.1.1
Issue Date: 17/12/2015
Print Date: 22/11/2016
NiMH Batteries
Personal protection
Eye and face protection
Skin protection
Hands/feet protection
None under normal operating conditions.
OTHERWISE:
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of
lenses or restrictions on use, should be created for each workplace or task.
See Hand protection below
None under normal operating conditions.
OTHERWISE:
Elbow length PVC gloves
Wear general protective gloves, eg. light weight rubber gloves.
Body protection
See Other protection below
Other protection
None under normal operating conditions.
OTHERWISE:
Overalls.
P.V.C. apron.
Barrier cream.
Thermal hazards
Not Available
Recommended material(s)
Respiratory protection
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computergenerated selection:
NiMH Batteries
Type HG-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001,
ANSI Z88 or national equivalent)
Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the
"Exposure Standard" (or ES), respiratory protection is required.
Degree of protection varies with both face-piece and Class of filter; the nature of protection
varies with Type of filter.
Material
CPI
BUTYL
C
Required Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
NAT+NEOPR+NITRILE
C
up to 10 x ES
HG-AUS P2
-
NATURAL RUBBER
C
HG-PAPR-AUS /
Class 1 P2
NATURAL+NEOPRENE
C
up to 50 x ES
-
HG-AUS / Class
1 P2
-
NEOPRENE
C
up to 100 x ES
-
HG-2 P2
HG-PAPR-2 P2 ^
NEOPRENE/NATURAL
C
NITRILE
C
NITRILE+PVC
C
PE
C
PE/EVAL/PE
C
PVC
C
SARANEX-23
C
SARANEX-23 2-PLY
C
TEFLON
C
VITON/CHLOROBUTYL
C
##sodium
hydroxide
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen
cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
Respiratory protection not normally required due to the physical form of the product.
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final
selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Physical state
Hermetically sealed cylindrical shape articles.
Manufactured
Relative density (Water = 1)
Not Available
Odour
Not Available
Partition coefficient
n-octanol / water
Not Available
Odour threshold
Not Available
Auto-ignition temperature
(°C)
Not Applicable
Continued...
Chemwatch: 61-7122
Page 6 of 11
Version No: 2.1.1.1
Issue Date: 17/12/2015
Print Date: 22/11/2016
NiMH Batteries
pH (as supplied)
Not Applicable
Decomposition
temperature
Not Applicable
Melting point / freezing
point (°C)
Not Applicable
Viscosity (cSt)
Not Applicable
Initial boiling point and
boiling range (°C)
Not Applicable
Molecular weight (g/mol)
Not Applicable
Flash point (°C)
Not Applicable
Taste
Not Available
Evaporation rate
Not Applicable
Explosive properties
Not Available
Flammability
Not Applicable
Oxidising properties
Not Available
Upper Explosive Limit (%)
Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Applicable
Lower Explosive Limit (%)
Not Applicable
Volatile Component (%vol)
Not Applicable
Vapour pressure (kPa)
Not Applicable
Gas group
Solubility in water (g/L)
Immiscible
Vapour density (Air = 1)
Not Applicable
pH as a solution (1%)
VOC g/L
Not Available
Not Applicable
Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity
Chemical stability
See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Ingestion
Skin Contact
Eye
Chronic
NiMH Batteries
Not normally a hazard due to physical form of product.
Inhaling corrosive bases may irritate the respiratory tract. Symptoms include cough, choking, pain and damage to the mucous membrane.
Regular exposure to nickel fume, as the oxide, may result in "metal fume fever" a sometimes debilitating upper respiratory tract condition resembling influenza.
Symptoms include malaise, fever, weakness, nausea and may appear quickly if operations occur in closed or poorly ventilated areas. Pulmonary oedema,
pulmonary fibrosis and asthma has been reported in welders using nickel alloys; level of exposure are generally not available and case reports are often
confounded by mixed exposures to other agents.
Inhalation of freshly formed metal oxide particles sized below 1.5 microns and generally between 0.02 to 0.05 microns may result in "metal fume fever".
Considered an unlikely route of entry in commercial/industrial environments
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious
damage to the health of the individual.
Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations and swellings of the mucous membranes, profuse saliva production, with an
inability to speak or swallow. Both the oesophagus and stomach may experience burning pain; vomiting and diarrhoea may follow.
Not normally a hazard due to physical form of product.
The material can produce severe chemical burns following direct contact with the skin.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use
of the material and ensure that any external damage is suitably protected.
Not normally a hazard due to physical form of product.
If applied to the eyes, this material causes severe eye damage.
Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the
jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.
Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Toxic: danger of serious damage to health by prolonged exposure through inhalation.
This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains a substance which can produce severe
defects.
Laboratory (in vitro) and animal studies show, exposure to the material may result in a possible risk of irreversible effects, with the possibility of producing
mutation.
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
IRRITATION
dermal (rat) LD50: >2000 mg/kg
[1]
lead
Inhalation (rat) LC50: >5.05 mg/l/4hr
Oral (rat) LD50: >2000 mg/kg
Not Available
[1]
[1]
Continued...
Chemwatch: 61-7122
Page 7 of 11
Version No: 2.1.1.1
Issue Date: 17/12/2015
Print Date: 22/11/2016
NiMH Batteries
TOXICITY
IRRITATION
[1]
Inhalation (monkey) LC50: 0.03 mg/L15 min
Not Available
Inhalation (monkey) LC50: 0.0467 mg/L15 min[1]
Inhalation (monkey) LC50: 0.204 mg/L15 min[1]
Inhalation (monkey) LC50: 0.23 mg/L15 min[1]
cadmium
Inhalation (monkey) LC50: 0.94 mg/L15 min[1]
Inhalation (mouse) LC50: >0.00902 mg/L15 min[1]
Inhalation (rabbit) LC50: >0.0224 mg/L15 min[1]
Inhalation (rat) LC50: 0.025 mg/L/30m[2]
Oral (rat) LD50: >63-<259 mg/kg>[1]
chromium(VI) ion
mercury (elemental)
polybrominated biphenyls
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
IRRITATION
Oral (rat) LD50: >9.2 mg/kg [1]
Not Available
TOXICITY
IRRITATION
Oral (mouse) LD50: >15000 mg/kg [2]
Not Available
TOXICITY
IRRITATION
dermal (rat) LD50: >2000 mg/kg
[1]
nickel(II) hydroxide
Inhalation (rat) LC50: 1.2 mg/L/4hr
Not Available
[2]
Oral (rat) LD50: >200 mg/kg [1]
TOXICITY
IRRITATION
Oral (rat) LD50: 273 mg/kg [2]
Eye (rabbit):1mg/24h rinse-moderate
potassium hydroxide
Skin (human): 50 mg/24h SEVERE
Skin (rabbit): 50 mg/24h SEVERE
TOXICITY
IRRITATION
Oral (rabbit) LD50: 325 mg/kg [1]
Eye (rabbit): 0.05 mg/24h SEVERE
sodium hydroxide
Eye (rabbit):1 mg/24h SEVERE
Eye (rabbit):1 mg/30s rinsed-SEVERE
Skin (rabbit): 500 mg/24h SEVERE
Legend:
LEAD
CHROMIUM(VI) ION
MERCURY (ELEMENTAL)
POLYBROMINATED
BIPHENYLS
1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data
extracted from RTECS - Register of Toxic Effect of chemical Substances
WARNING: Lead is a cumulative poison and has the potential to cause abortion and intellectual impairment to unborn children of pregnant workers.
No significant acute toxicological data identified in literature search.
Animal studies have shown that mercury may be a reproductive effector.
From available experimental data, the potential for polybrominated fire retardants (PBFRs) to cause cancer, hormonal dysfunction and neuro-developmental
toxicity are of concern. Their structural similarities to the polychlorinated diphenyl ethers, nitrofen and polychlorinated biphenyls add to concerns for their health
effects. They cause mild eye, airway and skin irritation, damage to the liver, thyroid and sex organs. They can be harmful following prolonged contact with the
skin or if swallowed.
WARNING: This substance has been classified by the IARC as Group 2A: Probably Carcinogenic to Humans.
Somnolence, liver changes recorded.
NICKEL(II) HYDROXIDE
Tenth Annual Report on Carcinogens: Substance anticipated to be Carcinogen
[National Toxicology Program: U.S. Dep. of Health & Human Services 2002]
Tumours of the respiratory and musculo-skeletal system and at sites of application recorded.
POTASSIUM HYDROXIDE
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.
SODIUM HYDROXIDE
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
CHROMIUM(VI) ION &
NICKEL(II) HYDROXIDE
MERCURY (ELEMENTAL)
& POTASSIUM HYDROXIDE
& SODIUM HYDROXIDE
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczema involves
a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune
reactions.
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known as
reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis
of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes
Continued...
Chemwatch: 61-7122
Page 8 of 11
Version No: 2.1.1.1
Issue Date: 17/12/2015
Print Date: 22/11/2016
NiMH Batteries
to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on
methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of
RADS.
POTASSIUM HYDROXIDE &
SODIUM HYDROXIDE
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of
vesicles, scaling and thickening of the skin. Repeated exposures may produce severe ulceration.
Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Serious Eye
Damage/Irritation
STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity
Aspiration Hazard
Legend:
– Data available but does not fill the criteria for classification
– Data required to make classification available
– Data Not Available to make classification
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Ingredient
Endpoint
Test Duration (hr)
Species
Value
Source
lead
LC50
96
Fish
0.0079mg/L
2
lead
EC50
48
Crustacea
0.029mg/L
2
lead
EC50
72
Algae or other aquatic plants
0.0205mg/L
2
lead
BCFD
8
Fish
4.324mg/L
4
lead
EC50
48
Algae or other aquatic plants
0.0217mg/L
2
lead
NOEC
672
Fish
0.00003mg/L
4
cadmium
LC50
96
Fish
0.001mg/L
4
cadmium
EC50
48
Crustacea
0.0033mg/L
5
cadmium
EC50
72
Algae or other aquatic plants
0.018mg/L
2
cadmium
BCF
960
Fish
500mg/L
4
cadmium
EC50
336
Crustacea
0.00065mg/L
5
cadmium
NOEC
168
Fish
0.00001821mg/L
4
mercury (elemental)
LC50
96
Fish
0.004mg/L
4
mercury (elemental)
EC50
48
Crustacea
0.0035mg/L
5
mercury (elemental)
EC50
72
Algae or other aquatic plants
0.0025mg/L
4
mercury (elemental)
BCF
720
Fish
0.001mg/L
4
mercury (elemental)
EC50
240
Fish
0.0003mg/L
5
mercury (elemental)
NOEC
2688
Crustacea
0.00025mg/L
2
nickel(II) hydroxide
LC50
96
Fish
0.4mg/L
2
nickel(II) hydroxide
EC50
48
Crustacea
0.1455mg/L
2
nickel(II) hydroxide
EC50
72
Algae or other aquatic plants
0.0407mg/L
2
nickel(II) hydroxide
EC50
720
Crustacea
0.0062mg/L
2
nickel(II) hydroxide
NOEC
72
Algae or other aquatic plants
0.0035mg/L
2
potassium hydroxide
LC50
96
Fish
80mg/L
4
potassium hydroxide
NOEC
96
Fish
56mg/L
2
sodium hydroxide
LC50
96
Fish
4.16158mg/L
3
sodium hydroxide
EC50
96
Algae or other aquatic plants
1034.10043mg/L
3
sodium hydroxide
EC50
384
Crustacea
27901.643mg/L
3
sodium hydroxide
NOEC
96
Fish
56mg/L
4
Legend:
Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment
wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient
Persistence: Water/Soil
Persistence: Air
sodium hydroxide
LOW
LOW
Bioaccumulative potential
Continued...
Chemwatch: 61-7122
Page 9 of 11
Version No: 2.1.1.1
Issue Date: 17/12/2015
NiMH Batteries
Ingredient
Bioaccumulation
sodium hydroxide
LOW (LogKOW = -3.8796)
Print Date: 22/11/2016
Mobility in soil
Ingredient
Mobility
sodium hydroxide
LOW (KOC = 14.3)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.
Product / Packaging
disposal
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant
HAZCHEM
Not Applicable
Land transport (ADG)
UN number
UN proper shipping name
3496
BATTERIES, NICKEL-METAL HYDRIDE
Class
9
Subrisk
Not Applicable
Transport hazard class(es)
Packing group
Not Applicable
Environmental hazard
Not Applicable
Special provisions
117
Limited quantity
0
Special precautions for user
Air transport (ICAO-IATA / DGR)
UN number
UN proper shipping name
3496
Batteries, nickel-metal hydride
ICAO/IATA Class
Transport hazard class(es)
Not Applicable
ERG Code
9L
Packing group
Not Applicable
Environmental hazard
Not Applicable
Special precautions for user
9
ICAO / IATA Subrisk
Special provisions
A199
Cargo Only Packing Instructions
See A199
Cargo Only Maximum Qty / Pack
See A199
Passenger and Cargo Packing Instructions
See A199
Passenger and Cargo Maximum Qty / Pack
See A199
Passenger and Cargo Limited Quantity Packing Instructions
Forbidden
Passenger and Cargo Limited Maximum Qty / Pack
Forbidden
Sea transport (IMDG-Code / GGVSee)
UN number
UN proper shipping name
3496
BATTERIES, NICKEL-METAL HYDRIDE
Continued...
Chemwatch: 61-7122
Page 10 of 11
Version No: 2.1.1.1
NiMH Batteries
IMDG Class
9
IMDG Subrisk
Not Applicable
Issue Date: 17/12/2015
Print Date: 22/11/2016
Transport hazard class(es)
Packing group
Environmental hazard
Not Applicable
Marine Pollutant
Special precautions for user
EMS Number
F-A, S-I
Special provisions
117 963
Limited Quantities
0
Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
LEAD(7439-92-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs
CADMIUM(7440-43-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
Australia Work Health and Safety Regulations 2016 - Hazardous chemicals (other than lead)
requiring health monitoring
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs
CHROMIUM(VI) ION(18540-29-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs
MERCURY (ELEMENTAL)(7439-97-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs
POLYBROMINATED BIPHENYLS(59536-65-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs
NICKEL(II) HYDROXIDE(12054-48-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs
POTASSIUM HYDROXIDE(1310-58-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
SODIUM HYDROXIDE(1310-73-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
National Inventory
Status
Australia - AICS
N (polybrominated biphenyls; chromium(VI) ion)
Canada - DSL
N (polybrominated biphenyls; chromium(VI) ion)
Canada - NDSL
N (nickel(II) hydroxide; lead; polybrominated biphenyls; chromium(VI) ion; mercury (elemental); potassium hydroxide; sodium hydroxide; cadmium)
China - IECSC
N (polybrominated biphenyls; chromium(VI) ion)
Europe - EINEC / ELINCS /
NLP
N (polybrominated biphenyls; chromium(VI) ion)
Japan - ENCS
N (lead; chromium(VI) ion; mercury (elemental); cadmium)
Korea - KECI
N (chromium(VI) ion)
New Zealand - NZIoC
N (polybrominated biphenyls; chromium(VI) ion)
Philippines - PICCS
Y
USA - TSCA
N (polybrominated biphenyls; chromium(VI) ion)
Legend:
Y = All ingredients are on the inventory
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other information
Continued...
Chemwatch: 61-7122
Page 11 of 11
Version No: 2.1.1.1
NiMH Batteries
Issue Date: 17/12/2015
Print Date: 22/11/2016
Ingredients with multiple cas numbers
Name
CAS No
polybrominated biphenyls
59536-65-1, 67774-32-7
nickel(II) hydroxide
12054-48-7, 36897-37-7
sodium hydroxide
1310-73-2, 12200-64-5
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations
PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
This document is copyright.
Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH.
TEL (+61 3) 9572 4700.
end of SDS