P.O. Box 282186, Dubai, United Arab Emirates
Tel. +971 4 880 2928, Fax +971 4 880 2446
[email protected]
www.specialityllc.com
MARBLE CHIPS
Section 1: Product and Company Information
Refractive Index
Product Name
:
Marble Chips
Chemical Formula
:
CaCO3
Synonyms
:
Calcium Carbonate, Chalk,
Calcite, Agstone
Manufacturer
:
Speciality Industries L.L.C.
:
1.6
Coefficient of Dispensation n-octanol/water:
P.O.Box 282186, Dubai,
N/A
Section 4: Stability and Reactivity
Chemical stability
:
Chemically Stable.
Conditions to Avoid
:
Dusting and incompatibles
Incompatibility to other substances:
U.A. E.
:
+971 4 8802928
Fax
:
+971 4 8802446
Email
:
[email protected]
Reactive with oxidizing agents, acids.
Special Remarks on Reactivity:
Hygroscopic. Will ignite and burn fiercely in contact with
fluorine. Incompatible with acids, alum, ammonium salts,
mercury + hydrogen, aluminum and magnesium.
Section 2: Composition and Ingredient
Decomposition Temperature:
Percentage
Decomposes above 825°C
Ingredient
CAS Number
Calcium Carbonate CaCO3
1317-65-3
> 98%
Hazardous Decomposition Products:
Crystalline Silica SiO2
14808-62-7
0.1-1.5%
Carbon Dioxide, Calcium Oxide
Hazardous Polymerization: Will Not Occur
Section 3: Physical and Chemical Properties
Section 5: Hazards Identification
Physical State/ Appearance
:
Odor
:
Solid
White/
Off-white Powder / CAUTION:
Granules/ Chips
May Cause Irritation to Skin, Eyes and Respiratory Tract,
Odorless
Nuisance Dust.
Odor Threshold
:
Not Relevant.
Boiling Point
:
N/A
Melting point
:
825 °C.
Solubility in water
:
Poorly soluble in
pure water (14-66)
mg/L.
Specific Gravity (H2O=1, at 4 °C)
:
2.65—2.95
Bulk Density
:
900-1900 Kg/m3
pH
:
8 – 10 (400g/l
water at 20°C)
Flash Point
:
N/A.
Flammability (Solid, Gas)
:
N/A.
Explosive Properties
:
N/A.
Oxidizing Properties
:
N/A.
Vapor Pressure
:
N/A.
Vapor Density
:
N/A.
Evaporation Rate
:
N/A.
Moisture Content
:
<0.10%.
Oil Absorption
:
15-35 g/100 g.
Hardness
:
3 Mohs.
Viscosity
:
N/A.
Potential Health Effects
Inhalation: Excessive concentration of a nuisance dust may
cause nuisance conditions such as coughing, sneezing and
nasal irritation.
Ingestion: Non toxic.
Skin Contact: Not expected to be health hazard from skin
exposure.
Eye Contact: No information found, but expected to be a
mechanical irritation.
Chronic Exposure: Excessive oral doses may produce alkalosis and hypocalcaemia.
Aggravation of Pre-existing Conditions: No information
found.
Material Safety Data Sheet — P1
Phone Number
Chronic Health Effects: This product contains small
amounts of crystalline silica. Long-term exposure to crystalline silica causes silicosis, a form of pulmonary fibrosis. Continued exposure to crystalline silica can lead to cardiopulmonary impairment. Symptoms are usually delayed (10
years or more).
Accute Health Effects: Crystalline silica has been reviewed
by IRAC. IARC found limited evidence for carcinogenicity of
crystalline silica in humans and sufficient evidence in experimental animals.
________________________________________________________________________________________
A Bujsaim Group Company
P.O. Box 282186, Dubai, United Arab Emirates
Tel. +971 4 880 2928, Fax +971 4 880 2446
[email protected]
www.specialityllc.com
Explosion Data:
Section 6: First Aid Measure
Inhalation: If inhaled, remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Sensitivity to chemical Impact : N/A
Sensitivity to Static Discharge : N/A
Special Remarks on Explosion Hazards:
When a mixture of calcium carbonate and magnesium is
heated in a current of hydrogen, a violent explosion occurs.
Skin Contact: Wash with soap and water. Cover irritated skin
with an emollient. Get medical advice if irritation occurs.
Section 9: Handling and Storage
Eye Contact: Check for and remove contact lenses. In case of
contact immediately flush eyes with gentle but large stream
of water for at least 15 minutes. Warm water must be used.
Call a physician if irritation occurs.
Precautions for safe handling:
Do not ingest. Do not breathe dust. Avoid contact with eyes.
Wear suitable protective clothing. If ingested, seek medical
advice immediately and show the container or the label.
Keep away from incompatibles such as oxidizing agents,
acids.
Section 7: Accidental Release Measures
Storage:
Keep container tightly closed. Keep container in a cool, well
-ventilated area. Hygroscopic. Protect against physical
damage. Isolate from incompatible substances.
Ventilate area of leak or spill.
Wear appropriate personal protective equipment.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient
waste disposal container. Finish cleaning by spreading water
on the contaminated surface and dispose of according to
local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the
sanitary system. Be careful that the product is not present at
a concentration level above TLV. Check TLV on the MSDS and
with local authorities.
Section 8: Fire Fighting Measures
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other
engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust,
fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal Protection:
Personal Respirators:
For emergencies or instances where the exposure levels
are not known, use a full-face piece positive-pressure, airsupplied respirator.
Flammable Properties
Flammability
Flash Point: F (C)
Flammable Limits in Air - Lower (%)
Flammable Limits in Air - Upper (%)
Auto Ignition Temp. (°C)
Hazardous Combustion Products
Section 10: Exposure Controls and P.P.E.
: Non-Flammable
: N/A
: N/A
: N/A
: N/A
: N/A
WARNING: Air-purifying respirators do not protect workers
in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, as appropriate, to
prevent skin contact. ( Lab Coat, Gloves )
Eye Protection:
Special Remarks on Fire Hazards:
Will ignite and burn fiercely in contact with fluorine.
Extinguishing Media:
Use extinguishing Media appropriate to surrounding fire
conditions.
Protection of Fire-Fighters:
Calcium Carbonate is generally non-flammable, but ignites on
contact with fluorine. Wear adequate personal protection to
prevent contact with material or its combustion products.
Firefighters should use self-contained NIOSH approved
breathing apparatus with full face piece to protect against
the products of combustion.
Use chemical safety goggles and/or full face shield where
dusting or splashing of solutions is possible. Maintain eye
wash fountain and quick-drench facilities in work area.
Material Safety Data Sheet — P2
Ingestion: Do NOT induce vomiting. If large amounts were
swallowed, give large quantities of water. Get medical advice.
Exposure Limits:
TWA:
- 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation
Total.
- 10 STEL: 20 (mg/m3) [Canada] Inhalation Total.
- 5 (mg/m3) from OSHA (PEL) [United States] Inhalation
Respirable.
- 15 from OSHA (PEL) [United States] Inhalation Total.
Consult local authorities for acceptable exposure limits.
________________________________________________________________________________________
A Bujsaim Group Company
P.O. Box 282186, Dubai, United Arab Emirates
Tel. +971 4 880 2928, Fax +971 4 880 2446
[email protected]
www.specialityllc.com
Section 11: Ecological Information
Section 14: Regulatory Information
Ecotoxicity: Not available.
Federal and State Regulations:
BOD5 and COD: Not available.
TSCA Chemical Inventory: This product is listed in Initial Inventory, Vol 1, Appendix A.
Products of Biodegradation:
Possibly hazardous short term degradation products are
not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation:
Other Regulations:
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
Special Remarks on the Products of Biodegradation:
DSCL (EEC):
Not available.
R36- Irritating to eyes. S2- Keep out of the reach of children.
S46- If swallowed, seek medical advice immediately and
show this container or label.
Section 12: Toxicological Information
HMIS (U.S.A.):
Routes of Entry: Inhalation. Ingestion.
Health Hazard: 2
Toxicity to Animals: Acute oral toxicity (LD50): 6450 mg/
kg [Rat].
Fire Hazard: 0
Chronic Effects on Humans: May cause damage to the
following organs: kidneys.
Reactivity: 0
Personal Protection: E
Other Toxic Effects on Humans: Slightly hazardous in case
of skin contact (irritant), of ingestion, of inhalation.
National Fire Protection Association (U.S.A.):
Special Remarks on Toxicity to Animals: Not available.
Health: 1
Special Remarks on Chronic Effects on Humans: Not available.
Flammability: 0
Special Remarks on other Toxic Effects on Humans:
Reactivity: 0
Specific hazard:
Acute Potential Health Effects:
Skin: Causes skin irritation.
Protective Equipment:
Eyes: Dust causes eye irritation.
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
Inhalation: Excessive inhalation causes respiratory tract
and mucous membrane irritation. Low hazard for usual
industrial handling.
Ingestion: Ingestion of large amounts may cause gastrointestional tract disturbances with nausea and possibly
constipation. Expected to be a low hazard for usual industrial handling.
OSHA Status: This product is hazardous under the criteria of
the Federal OSHA Hazard Communication Standard 29 CFR
1910.1200.
SARA 313 Title III:
Section 302 Extremely Hazardous Substances: None
Chronic Potential Health Effects: Chronic ingestion may
affect kidneys, and may cause hypercalcemia with alkalosis.
Section 311/312 Hazardous Categories: None
Section 13: Disposal Considerations
Section 16:. Transport Information
Whatever cannot be saved for recovery or recycling
should be managed in an appropriate and approved
waste facility.
Speciality Industries Marble Chips is not a dangerous
substance according to the relevant transport regulations
within the meaning of dangerous substance regulation.
Although not a listed as a hazardous waste, this material
may exhibit one or more characteristics of a hazardous
waste and require appropriate analysis to determine specific disposal requirements.
DOT Proper Shipping Name:
Not regulated by this mode of transportation
Processing, use or contamination of this product may
change the waste management options. Dispose of container and unused contents in accordance with national
and local requirements.
Section 313 Toxic Chemicals: None
Material Safety Data Sheet — P3
The product itself and its products of degradation are not
toxic.
IMO Proper Shipping Name:
Not regulated by this mode of transportation
IATA Proper Shipping Name:
Not regulated by this mode of transportation
This safety data sheet should be used in conjunction with technical sheets. This information is not exhaustive. The aim of the mandatory regulations mentioned is
to help the user. It is the sole responsibility of the user to take all precautions required in handling the product.
________________________________________________________________________________________
A Bujsaim Group Company