CHEM 2100 Practice for Exam 2 Spring 2014 Page 1 of 5 Name_________________Class number______ Circle the best answer on this sheet and on your scantron. 1. An ion with an atomic number of 20 and 18 electrons has a ________ charge. A) –2 B) +38 C) –38 D) +2 E) none of these 2. Which of the following is the carbonate ion? A) CO3-2 B) SO4-2 C) PO4-3 D) S-2 E) none of these Which of the following is one of the main cations in the body that regulates fluids outside cells? A) Fe+2 B) Ba+2 C) Na+ D) NH4+ E) none of these 3. In order to form an octet, an atom of phosphorous will A) lose 5 electrons B) gain 3 electrons C) lose 2 electrons D) gain 2 electrons 4. Which of the following ions is isoelectronic with the noble gas neon? A) OB) ClC) + D) S-2 E) none of these or more than one of these 5. Which of the following is the symbol for the phosphite ion? E) P-3 E) none of these A) PO3-3 B) PO4-3 C) PO-3 D) PO2-3 6. Which of the following anions has the same charge as the sulfate ion? A) NO3B) NH4+ C) CO3-2 D) PO4-3 E) none of these 7. Which of the following formulas in incorrect for a cobalt (II) compound? A) CoCl3 B) CoCO3 C) CoO D) Co3(PO4)2 E) none of these 8. Which compound contains both covalent and ionic bonds? A) NH4OH B) CaCl2 C) HC2H3O2 D) NaCl E) none of these 9. What is the name and symbol of an ion that has 26 protons and 23 electrons? A) Fe+3 B) Fe+2 C) Mn+2 D) Mn+3 E) none of these 10. Iron pyrite (fool's gold) is iron (II) sulfide. What is its formula? A) FeS B) FeSO3 C) FeSO4 D) Fe2S3 E) none of these 11. The correct name for Cr2O3 is: A) chromium oxide B) chromium (II) oxide C) chromium (III) oxide D) dichromium trioxide 12. What is the correct name for a molecule of SO3? A) Sulfur trioxide B) Sulfur oxide C) Sulfite D) Sulfate E) none of these 13. The approximate bond angles between the atoms in a molecule with a trigonal planar electron pair geometry are: A) 90° B) 120° C) 180° D) 109.5° E) none of these 14. What is the molecular geometry of a NH3 molecule? A) Tetrahedral B) Trigonal planar C) Bent D) Trigonal pyramidal E) none of these CHEM 2100 Practice for Exam 2 Spring 2014 Page 2 of 5 Use the following structures to answer the next five questions. A B C D 15. What is the molar mass of structure A? A) 114 g/mole B) 72 g/mole C) 86 g/mole D) 112 g/mole E) none of these 16. Structures A, B and C are: A) isotopes B) structural isomers C) different molecules D) conformational isomers E) None of these 17. Structures A and D are A) different molecules B) structural isomers C) isotopes D) conformational isomers E) None of these 18. Which of the following statements is/are correct? I. Structures A, B, C and D are all alkenes II. Structures A, B, C and D are all alkanes III. Structures A, B, C and D are all polar IV. Structures A, B, C and D are all nonpolar A) I and III B) II and IV C) I, II and III D) IV only E) none of these or more than one of these 19. A bond where the electrons are shared equally is called a(n): A) polar covalent B) coordinate covalent C) nonpolar covalent D) ionic 20. Which of the following molecules is polar? A) CH4 B) CO2 C) SO2 D) SO3 E) none of these, or more than one of these 21. Which of the following molecules is nonpolar? A) NH3 B) CH3F C) CCl4 D) H2O E) none of these, or more than one of these 22. Which of the following molecules are polar? I. Methane gas II. Hydrogen gas III. Hydrogen sulfide IV. CH3CH2OH A) I and III B) II and IV C) I, II and III D) IV only E) none of these or more than one of these Use the following structures to answer the next set of questions: CHEM 2100 Practice for Exam 2 Spring 2014 Page 3 of 5 histrionicotoxin H N amphetamine NH2 HO O HO Palmitoleic acid phenanthrene 23. Which of these molecules is found in secretions from a frog? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 24. Which of these molecules are totally non-polar? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 25. Which of these molecules is an ω-7 mono unsaturated fatty acid? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 26. Which of these molecules has an amine and an alkene group? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 27. Which of these molecules has an aromatic ring and an amine? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 28. Which of these molecules has an alkyne? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 29. Which of these molecules has a phenol group? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 30. Which of these molecules is found in butter? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 31. Which of these molecules is a toxin found in cigarette smoke? A) amphetamine B) histrionicotoxin C) palmitoleic acid D) phenanthrene E) none of these or more than one of these 32. What is the molar mass of manganese(II) bromide? CHEM 2100 Practice for Exam 2 Spring 2014 Page 4 of 5 A) 349.5 g/mole B) 134.8 g/mole C) 189.7 g/mole D) 214.7 g/mole 33. What is the molecular geometry of CH2O? A) Trigonal pyramidal B) Linear C) Tetrahedral D) Trigonal planar 34. A bond where the electrons are shared unequally is called a(n): A) polar covalent B) coordinate covalent C) purely (nonpolar) covalent 35. Which of the following molecules is an ω-3 fatty acid? A) arachidonic acid B) α-linolenic acid C) oleic acid D) ionic D) palmitoleic acid E) none of these 36. Which of the following molecules is polar? A) ethane B) ethene C) ethanol D) ethyne E) none of these or more than one of these 37. Which of the following is the condensed structure of oleic acid? A) CH3(CH2)12COOH B) CH3(CH2)7CH=CH(CH2)7COOH C) CH3(CH2)4CH=CHCH2CH=CH(CH2)7COOH D) CH3(CH2)14COOH E) none of these 38. Which of the following structures is cyclobutane? A) B) C) D) 39. Which of the following is the structure for stearic acid? A) CH3(CH2)14COOH B) CH3(CH2)16COOH C) CH3(CH2)18COOH D) CH3(CH2)10COOH 40. The fatty acid that contains 2 double bonds is: A) oleic acid B) palmitic acid C) linoleic acid D) stearic acid E) none of these 41. Which of the following molecules contains a chiral carbon? A) B) C) D) E) none of these, or more than one of these 42. Which of the following fatty acids is an essential fatty acid? A) Oleic acid B) Arachidonic acid C) Linoleic acid D) Stearic acid 43. A molecule that has both polar and nonpolar parts is said to be: A) an isomer B) amphipathic C) an enantiomer D) hydrophobic E) none of these CHEM 2100 Practice for Exam 2 Spring 2014 Page 5 of 5 44. Which of the atoms in histrionicotoxin are chiral? Each atom (except hydrogen) has a number, select the answer that has all of the numbers for all of the chiral atoms. 6 histrionicotoxin 1 5 11 H N 4 2 16 12 17 10 18 3 HO 7 9 13 15 20 19 8 21 14 A) 2, 11 B) 15, 16, 20, 21 C) 2, 3, 4, 10 D) 1,6,5,8, 9, 17 E) none of these or more than one of these 45. The name of the following alkyl group is: CH3CH2A) Methyl B) Isopropyl C) Propyl D) Ethyl E) none of these or more than one of these 46. Among the following compounds which are isomers? A) I and II B) I and III C) I and IV D) II and III
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