neighbors The Doe Run Company’s Herculaneum: 200 Years and Counting Sharing the Spotlight Navigating the Global Metals Market 2007 Report to Our Communities The The Doe Doe Run Run Company Company “Because no one can share our story better than those who do the work daily, we’ve tapped some of our talented leaders to share their unique expertise and perspective.” bruce neil, President and Chief Executive Officer, The Doe Run Company 2 Read Gary Hughes’ story on the accomplishments and challenges his team faced in Herculaneum, Mo. 8 Meet our customers, and learn more about where our products go once they leave our operations. 12 Navigating the Global Metals Market 14 Generations of Growth 16 Responsible Reuse 25 TRI Report 20 Learn how safety is a way of life and a source of pride for Doe Run employees. 24 Hear from Angie Nations on how we share our knowledge through educational initiatives. About the cover photo: Doe Run has a long-standing partnership with the Herculaneum Fire Department. In fact, the company helped purchase the department’s first new fire engine to serve the growing community. Today, the tradition continues. In December, Volunteer Firefighter Stephen Partney, Captain Chris Baker, Herculaneum smelter General Manager Gary Hughes and Herculaneum Fire Chief Bill Haggard broke ground for the new Herculaneum Fire Station, slated for completion in July 2008. Both the old and new firehouses stand on Doe Run property; company-owned houses are also used by the firefighters for training. 2007 Report to Our Communities Message from the CEO Welcome to Neighbors, The Doe Run Company’s 2007 Report to Our Communities. Thank you for reading this report and showing an interest in learning more about Doe Run. We are pleased to share with you how our values and promises are reflected in the ways we conduct business every day. As we maintain our tradition as a global provider of premium metals and services, Doe Run’s business is dedicated to enhancing our communities, the environment and the economy. Stories communicate how we live up to these commitments, especially through education, recycling, technology and community contributions. Because no one can share our story better than those who do the work daily, we’ve tapped some of our talented leaders to offer their unique expertise and perspective. We are eager to share our knowledge and passion with you. After all, we depend upon your support — our communities, customers and employees. Inside this year’s edition, Gary Hughes, general manager at the Herculaneum smelter, shares the accomplishments and challenges his team faced this year. Others share their insights on today’s global metals market, such as Jim Grubbs, vice president of sales and marketing, along with Jerry Pyatt, vice president of North American operations and chief operating officer. You will also hear from some of our customers and Message from Doe Run’s Management Team Many people think The Doe Run Company’s reach stops at the Mississippi River. We trust that by reading this report, you’ll learn how this Missouri company has grown into a respected leader in the global marketplace. Over the past hundred-plus years, the world has changed, and so has our industry. Our operations have progressed. Our expertise has grown. The demand for metals has increased worldwide. On behalf of Doe Run, we appreciate your interest in learning how we’re meeting this need. Inside, readers will also get a closer look at Doe Run’s lasting contributions to several stakeholders: our neighbors, our employees and our loyal customers. Their partnerships and incredible insights on the evolving uses for our products and services allow us to stay relevant, informed and successful. Our commitments remain steadfast: to make tomorrow better than today, to practice environmental stewardship, to operate safely and to engage our employees. In this year’s report, you’ll get a sense of how our facilities are performing against these commitments. We know the keys to a sustainable business are meaningful communication and support from our local communities. We welcome your feedback on how we’re doing. learn about where our products go once they leave our operations. As an industry, we continue to learn, evolve and invest in our communities and society. With that in mind, we’re proud of the milestones we’ve reached and have shared many of them in the following pages. We hope you’ll enjoy learning more about our company. Sincerely, bruce neil President and Chief Executive Officer, The Doe Run Company [email protected] Jerry Pyatt Vice President, North American Operations and Chief Operating Officer [email protected] Steve Arnold General Manager, Buick Resource Recycling Division [email protected] Gary Hughes General Manager, Primary Smelting Division [email protected] Bob Roscoe Vice President — Mining; General Manager, Southeast Missouri Mining and Milling Division [email protected] bill wold General Manager, Fabricated Products, Inc. [email protected] The Doe Run Company Herculaneum: 200 years and counting Looking ahead to the bicentennial year of Herculaneum, Gary Hughes, general manager of the Herculaneum Primary Smelting Division, shares his thoughts on 2007’s substantial accomplishments and challenges. By Gary Hughes In 1808, Moses Austin and Samuel Hammond founded Herculaneum, Mo. Doe Run’s predecessor acquired land in the city nearly 80 years later, and soon began construction of its lead smelter. Ever since, the histories of Herculaneum and Doe Run have been intertwined. Plans for a brighter future Consistent attainment of the air standard was a challenge for us in 2007. To address the challenge, we’re applying new technology to reduce emissions. We’re also expanding monitoring, adjusting internal processes and As we’ve grown side by side, we have each overcome obstacles working with the community and celebrated accomplishments. This past year is no exception. to establish greater distance At Doe Run, we are committed to environmental stewardship between operations and our and communicating openly with our neighbors. In 2007, our closest neighbors. communications centered on the vision we share with our We believe this combination of community: providing for a vibrant, clean and safe community, technology and additional space is while operating a viable business that supports our local economy important to meeting our long-term through jobs, taxes, donations and community involvement. goal — consistent attainment. In April 2007, we were pleased that after working with the This latest SIP builds on the tremendous progress we’ve local community, state officials and regulators, we were able to made over the years, and it outlines specific measures to agree upon a revised State Implementation Plan (SIP). The plan be taken, including approximately 60 engineering and identifies steps designed to help us reach our goal of continuous administrative control measures. attainment of the National Ambient Air Quality Standard (NAAQS) for lead. See measures on pages 3 and 4 2007 Report to Our Communities These measures were defined and agreed to by Doe Run and the Missouri Department of Natural Resources (MDNR) and then unanimously approved by the Missouri Air Conservation Commission. So far, Doe Run has: • Installed a new $3.5 million furnace designed to improve emissions. The location of the new furnace improves ventilation and dust capture, which reduces the potential for emissions. • Redesigned the ventilation system, which improves dust capture in the front of the furnace. •S hortened the feed conveyor, which transports feed to the furnace, thereby reducing dust. • Installed automated baghouse malfunction alarms on both furnaces. These alert Doe Run to failures in the baghouse or the ventilation systems early, while automatically reducing process air to the furnace. •A dded improved bags in the baghouses, representing a new technology in the production and performance of this key filtering system. These bags significantly boost the performance of the baghouses. Top photo: Doe Run began constructing a concentrate truck unloading enclosure in 2007. The receiving station will limit windblown dust when concentrates are unloaded at the smelter for further processing. Opposite page: Doe Run’s Broad Street monitor is one of 10 that monitors air emissions and attainment in Herculaneum. The State Implementation Plan (SIP), which was approved in April 2007, will help the area reach consistent attainment of the air standard for lead in the future. The SIP is a process used throughout the U.S. to improve air quality and help achieve federal air standards. The Doe Run Company planning for the future The Herculaneum smelter expects to complete all engineering and administrative controls, and improvements, in the revised State Implementation Plan (SIP) by April 2008. These include: • Raising the stack elevation for baghouses 7, 8 and 9 to 150 feet. This height increase will lessen the impact of emissions on the community. • Partially enclosing the lead concentrate receiving station to limit the potential for windblown emissions during unloading. • Updating the plant-wide sprinkler system to reduce roadway dust created by in-plant traffic. • Establishing a green space between the plant and the neighboring community. • Enclosing the south end of the railcar unloader, which will completely enclose the railcars while they are being unloaded. • Continuously recording fan amperages. Fan amperages allow employees to see and track how well fans are operating so that buildings remain under negative pressure. • Recording air flow from baghouses 3 and 5 to ensure proper ventilation for the sinter plant and blast furnaces, respectively. • Unloading concentrate trucks directly into railcars to minimize handling and stockpiling of lead concentrate. • Enclosing the baghouse 5 dust wetting system (pugger) to better control potential emissions from the handling of baghouse dust when the sinter plant is undergoing prolonged maintenance. 2007 Report to Our Communities Trading spaces Challenges and celebrations In June, we were pleased to close on a real estate transaction For those who follow our news, it will come of little surprise with the city of Herculaneum as the next step in creating more that 2007 provided us with ample opportunity for challenges space between our facility and our neighbors. and celebrations. Sometimes both came wrapped in the At the request of the city, Doe Run sold about 20 acres of its same package. land for $420,000 at the southeast corner of the Herculaneum For example, in August, we were eager to bring the new exit, along Interstate 55, for a shopping center development. $3.5 million furnace on line. As a major project in the SIP, In turn, following unanimous approval by the Board of we expect it to help deliver more efficient — and thereby Aldermen, the city sold 10.32 acres of streets and adjacent cleaner — operations. As a new design, however, it required land near the smelter to Doe Run for $410,000. several modifications to realize its full potential. These land transactions benefit the community and Doe Run. During the same period, our No. 2 furnace became inoperable. The land acquired by Doe Run allows us to create greater distance Having both furnaces down forced us to delay deliveries to around the plant. In addition, plans are being developed for an customers and tackle multiple restarts. Thanks to the efforts architecturally pleasing fence to be built in 2008. The fence of many, both furnaces became operational in early September. will limit public access and provide an unfettered view of the We ended the fiscal year with 134,000 tons of lead produced. green space. Transportation improvements were also evident in Herculaneum, We’re also pleased to be a part of the Herculaneum Fire and many people shared our enthusiasm for the reopening of the Department’s “trading of spaces,” as it moves to a new facility Joachim Bridge in November. The reconstructed bridge provided at the corner of Riverview Drive and Riverview Plaza. Doe Run us the opportunity to reroute all plant traffic and reduce impact will invest $750,000 in building a new station for the department on the community. on company property. Story continued on page 7 We understand from Fire Chief Bill Haggard that the new location will improve the fire department’s access to all areas of the community. The 6,000-square-foot station will include five apparatus and equipment bays; training and conference room space; a weight training room and showers; separate communication and fire chief offices; expanded restrooms; and a bunk room. We marked this milestone with the community on Dec. 1, when we officially broke ground for the new station. The newly constructed Joachim Bridge, reopened in November, is a project more than two years in the making. Approved in 2004 as the largest in the Department of Transportation’s Bridge Discretionary Program, the new construction replaces the previous 90-year-old bridge and helps divert city and Doe Run truck traffic away from residential areas. The Doe Run Company Bicentennial support symbolizes appreciation for shared history and vibrant future growing side by side Two hundred years ago, Herculaneum’s founding fathers likely had several conversations under shade trees overlooking the Mississippi River. Few could have predicted that the sleepy pioneer town of Herculaneum would become a thriving Missouri community, rich with heritage. In 1808, the town boasted some 35 homes, a school house, post office, jail, inn and ferry stop. Situated at the confluence of the Mississippi and Joachim Creek, and near lead smelting operations that produced ammunition, the town prospered as a shipping port. Lead sales ceased during the War of 1812, when the British blockaded sea routes. Overnight, the city and its businesses withered. Overlooking a ghost town, the trees stood, silhouetted against desolate streets. city firsts … Along with being the first major employer, Doe Run and its predecessors helped finance and build several city firsts: the first steamboat crossing, ferryboat stop and firehouse. Doe Run also assisted in the creation of Bates Memorial Park, Dunklin Fletcher Memorial Park, Joachim Golf Course and the Tri-City Little League Complex ball fields. Fast-forward 80 years. The need for lead resurged and New York-based St. Joseph Lead Company entered the booming Missouri Lead Belt as the premier investor. The company acquired a 540-acre tract of land along the Mississippi and in 1890, construction began on what is now The Doe Run Company’s Primary Smelting Division. The facility blossomed with jobs. Residents returned. And Herculaneum flourished as a budding and influential force along the mighty Mississippi. Since then, Doe Run has grown in tandem with Herculaneum. By working together, residents, city leadership and the company have cultivated a prosperous community. In 2007, on the eve of the city’s 200th birthday, Doe Run and its neighbors joined together to celebrate the past and prepare for the future. In honor of the milestone, Doe Run contributed to the Herculaneum Bicentennial Committee, signing on as platinum sponsor for the yearlong bicentennial celebration. Employees participated in the October launch event, the Herculaneum Fall Festival. To recognize Herculaneum’s past, and its promising future, the community officially dedicated a 200-year-old “Bicentennial Tree.” The more than 50-foot-tall white oak tree stands on 2007 Report to Our Communities “Our contributions to the community symbolize our appreciation for where we’ve been and our enthusiasm for the future.” gary hughes, General Manager of the Primary Smelting Division, The Doe Run Company Doe Run property at Mott Street and is now marked with a granite plaque. “Our contributions to the community symbolize our appreciation for where we’ve been and our enthusiasm for the future,” said Gary Hughes, general manager of the Herculaneum smelter. “The facility has the privilege of having served as the city’s first major employer. Along with that comes the responsibility we have to our community. We recognize that without the public’s support, we wouldn’t be here today.” Sowing seeds for the future, the Herculaneum Today and Tomorrow (HT&T) organization was recently awarded a $10,000 grant to help the city work toward a symbolic milestone. Herculaneum will use the funds to attain “Tree City USA” status. The city and Doe Run will plant 200 trees to commemorate the bicentennial. “Doe Run has always been a major supporter of our city. Together, we’ve transformed what was once an industrial hub into a comfortable suburb in which people live, work and play,” said HT&T member Jim Kasten. “Thanks in part to Doe Run’s involvement, the bicentennial celebration has provided a chance for everyone to recognize our heritage. We look forward to a bright future.” During the year, we also reduced our impact on roadways with the addition of a new Tymco street sweeper. This sweeper uses a regenerative air system, in which air dislodges dust and particles from crevices in the roadways and captures particles in the sweeper, leaving roads cleaner. In October, we joined with the city to kick off a yearlong celebration of Herculaneum’s bicentennial. Festivities are planned over the course of the year, culminating in a grand celebration in October 2008. As the only platinum-level sponsor, we are proud to donate our time, talent and resources toward this community-wide initiative. Now, after almost two centuries, I often wonder what Moses and Samuel would say about our community. We started as a riverside town with a modest lead shot tower producing bullets for the Army. Today, our community is home to our nation’s only primary lead smelter, providing materials necessary to power our cars, wireless communications and emergency power sources globally. As we look ahead, I envision an interesting and vibrant place to work, a quality place to live and a well-balanced community. We’re honored to be part of Herculaneum, and we look forward to celebrating our past, present and future this coming year. I hope to see you around town, and I invite you to stop by and share your thoughts. Left: Herculaneum Today and Tomorrow (HT&T) member Jim Kasten stands beside the Bicentennial Tree located on Doe Run property. The tree symbolizes Doe Run’s partnership with the city and HT&T to help become a Tree City USA community as part of the bicentennial celebration. Doe Run planted 100 of the 200 trees needed to achieve this distinction. The city of Herculaneum plans to name a second Bicentennial Tree in 2008. Visit www.herculaneum2008.com to learn more. The Doe Run Company sharing the spotlight The Doe Run Company emphasizes a company-wide dedication to meeting changing customer needs and finding ways to improve service. By leveraging technology, know-how, synergy and opportunity, the people of Doe Run deliver on these promises in very real and valuable ways. Read on to learn more about the relationships that have made Doe Run an industry leader and global metals provider. A Resource for Natural Resources Oil prices reached record highs last summer, which was good news for Doe Run customer Baker Hughes Centrilift. Among its electrical submersible pumping system products, Centrilift makes cable that stretches thousands of feet below the Earth’s surface to power pumping systems in oil wells. The higher demand for oil is driving the market for more pumping systems, which in turn drives Centrilift’s demand for lead. “About half of our cable designs use lead sheathing,” explained Larry Dalrymple, manager of engineering, cable operations. Centrilift’s 1-inch-thick cables carry up to 8,000 volts. “Our entire pumping system depends on cable. One short can shut down an entire on-shore or off-shore project.” Inside Centrilift’s Claremore, Okla., operation, 2,000-pound blocks of lead are melted down, then formed into lead pipe that fits snugly around a copper rod. “We have to make everything consistent,” said Randy Wilbourn, plant manager. “Having a tight fit of the lead and consistent thickness is critical to this application.” This “wall” of lead acts as an impervious shield against the incredibly corrosive environment found around oil wells, where hydrogen sulfide gas can corrode copper in a matter of days. “Oil is somewhat foul when it comes out of the ground,” said Charlie Fowler, vice president of supply chain for Centrilift. “Lead is a cost-effective material to protect the copper in what we like to think of as a really long extension cord.” Right: Centrilift requested Doe Run’s expertise to gather best practices for safely working with lead. This dense, flexible metal is pliable enough to sheath copper wiring (shown here in large spools), yet strong enough to protect it from the harsh environments found in oil wells. Centrilift At a Glance Doe Run customer: 12 years Based near Tulsa, Okla., Centrilift sends all scrap lead pipe back to Doe Run’s Buick Resource Recycling Division. Centrilift’s lead comes from Doe Run’s Herculaneum smelter. Centrilift has been extruding lead since 1995, and has taken cues from Doe Run on the safe handling of lead. 2007 Report to Our Communities Lead Shapes Up at Fabricated Products Inc. (FPI) Among metals, lead is flexible, versatile and strong. FPI, a subsidiary of Doe Run, brings out the best in lead by forming it into shapes that maximize performance in specialized applications. For instance, employees at FPI’s oxide plant in Vancouver, Wash., produce one major product: a lead-oxide powder used to produce a lead-oxide paste, which is a key component of all lead-acid batteries. At the Seafab facility in Casa Grande, Ariz., lead takes other forms. “Our goal is to be the best fabricated lead products company in the world,” said Bill Wold, general manager of FPI. “Twenty-pound lead chunks are tumbled around in a ball mill, where lead creates its own friction and oxidizes,” explained Ken Bartel, plant manager with FPI. “More than 5 million pounds of lead oxide were created in October 2007, setting an all-time monthly production record.” Three techniques create different lead shapes at Seafab. At the rolling mill, warm lead slabs are rolled like pie crusts into sheets for roof flashings and shielding against sound waves, X-rays and nuclear radiation. With a press, lead can be extruded into pipe or wire. Lead can also be cast into various shapes and sizes for use in copper and zinc plating. Lead’s low melting point, 621.5 degrees Fahrenheit, allows Seafab to roll large blocks of lead into 1/4-inch sheets. The facility also fabricates pieces like this star anode, a critical component in copper electroplating. FPI At a Glance Doe Run subsidiary: 10 years Locations: Casa Grande, Ariz., and Vancouver, Wash. Products: Lead oxide (Vancouver); rolled, extruded and cast lead products (Casa Grande). FPI mirrors Doe Run’s commitment to safety. Casa Grande has marked eight years without a lost-time accident; the Vancouver plant has surpassed three years. Above: Seafab’s 35 employees in Casa Grande, Ariz., maintain some of Doe Run’s best safety records. Seafab has earned a “Perfect Record Award” from the National Safety Council every year since joining the organization in 2000. 10 The Doe Run Company Straight Shooters for Remington Doe Run’s Buick Resource Recycling Division supplies secondary, or recycled, lead to Remington Arms Company in Lonoke, Ark. Lead plays a vital role in most ammunition produced by Remington, according to Vic Bettis, purchasing manager. Primarily, lead is processed into a thick wire that is fed into a machine to create rimfire, as well as centerfire bullets for rifles and pistols. Lead is also used to make lead shot for shotgun shells. The primer mix used to ignite cartridges also features lead. Non-lead options do exist in some bullet and shot varieties, but each has limitations. Non-lead bullets, for example, can be used as training ammunition. “If you just want to shoot targets, it’s fine. But these other materials do not have the mass, energy and properties of a lead bullet,” Bettis said. “A lead bullet is designed to mushroom when it hits.” Doe Run employees are straight shooters when it comes to solving problems. Remington recently discovered its typically spherical shot was instead forming as teardrops. Doe Run’s metallurgical experts analyzed the processing and determined that, somewhere along Remington’s production line, the material became contaminated with excess copper. Remington was able to assess its production line and correct the problem. Remington Arms Company At a Glance Doe Run customer: 7 years Remington, headquartered in Madison, N.C., designs, produces and sells products for the hunting and shooting sports markets, as well as military, government and law enforcement. The company has been in business since 1816. The Lonoke plant recently celebrated 3 million man-hours without a safety incident and earned an award from the state of Arkansas. In another instance, Doe Run helped Remington by recycling countless barrels filled with a combination of lead shot, gunpowder and buffering material from shotgun shells. Without Doe Run’s capabilities, Remington would have had to place the material in a hazardous waste landfill, rather than return the metals back to commerce for reuse. Left: At Remington’s Arkansas facility, Doe Run’s lead is processed into bullets for rifles and pistols and lead shot for shotgun shells. Below: These copper-jacketed bullets consist of cores made from Doe Run lead; they’re just a few of Remington’s products, which are distributed to more than 55 countries. 11 2007 Report to Our Communities Superior Battery specializes in marine, or “deep-cycle” batteries, which contain approximately 20 pounds of lead, 1 gallon of sulfuric acid and 2 pounds of plastic. Superior At a Glance Doe Run customer: 11 years Superior Battery uses 2,000-pound blocks to create lead oxide and 60-pound bars (called pigs), all purchased from Doe Run. Superior Battery opens its facility to professors from the local community for courses on industrial maintenance and electronics. Superior Service Superior Battery in Russell Springs, Ky., has the distinction of being the youngest player in its lead-acid battery niche. In the world of lead-acid batteries, competition is fierce, and Randy Hart, chief executive officer of Superior Battery, is proud that his 170-person operation has weathered the storm. Superior now produces more than 1 million lead-acid batteries annually. “Once we grew to a certain size, we found that Doe Run could service our lead metal needs well,” Hart said. Superior Battery supplies the eastern United States, Canada and some areas of export with lead-acid batteries for commercial vehicles and deep-cycle marine batteries. The marine business, in particular, fluctuates with the economy. Boat purchases dip when money is tight. As past president of the Battery Council International, Hart knows the value of finding alternative applications. “The industry buzz is about hybrid vehicles,” he said. “We’re considering how they will enhance our business, as hybrids still have an engine and a starting battery.” Doe Run aims to enhance Superior’s business by offering expertise that goes above and beyond a typical supplier relationship. For instance, two metallurgists from the Buick Resource Recycling Division have repeatedly assisted on site to help address production issues. “For them to take the trouble to come down was a value-added service; one that really helped our process,” Hart said. Above: Like Doe Run, Superior Battery values community involvement. The facility often serves as a practical teaching environment for local colleges. 12 The Doe Run Company navigating Above: These 100-pound bars, commonly called “pigs,” are banded together before being shipped to customers. The orange striping is used by Doe Run to differentiate its end products, including lead or lead alloys. Like a bar code, the stripes help customers with storage, transportation and product selection. the global In January 1875, The New York Times described the mines of Missouri as adding to “the already abundant proof that Missouri is to be the ‘England of the tomorrow.’” Today, Missouri lead is renowned, and widely followed by members of the London Metal Exchange (LME), the world’s premier non-ferrous metals market. In October, Doe Run representatives attended LME Week 2007 in London, England, to meet with customers and other industry experts associated with this booming market. Jim Grubbs, Doe Run’s vice president for sales and marketing, met with industry reporters who track the company as it navigates the global metals market. “I’ve attended LME Week for years, and I am amazed by who watches our operations,” Grubbs explained. “I had complete strangers from the Middle East and other parts of the world ask me how ‘Herky’ was running. There is worldwide interest in what we do.” “Herky,” short for Doe Run’s plant in Herculaneum, Mo., is the only primary lead smelter in the United States. Because of its high quality, Doe Run lead is a sought-after product for applications requiring pure metal. Doe Run’s Herculaneum smelter produced 134,000 tons of lead metal in the fiscal year ending in October 2007. The Doe Run Company is the world’s third largest lead supplier. 13 70,000 Doe Run’s mines produce approximately 70,000 short tons of zinc concentrates annually and 20,000 short tons of copper. 80% Lead-acid batteries, in high demand worldwide, represent 80 percent of Doe Run’s end-use applications. The successful recycling of these batteries protects the environment and helps to preserve the finite quantities of lead ore in the Earth. metals market “Increased demand for lead, like many base metals, is driven largely by the expanding economies of the world. Recent record lead prices benefited us directly,” added Jerry Pyatt, vice president, North American operations and chief operating officer of Doe Run. “We’re taking this opportunity to increase investment in our people, our communities and our operations. We also need to prepare to insulate our company against economic downturns.” To that end, Doe Run is exploring within the Viburnum Trend and looking at properties elsewhere in the United States and abroad. The company is also focused on building workforce capability and new technology to improve its competitive position. Going forward, a comprehensive scope of services will continue to be Doe Run’s market advantage. Providing customers with broad capabilities — incorporating extraction, milling, refining, fabrication and recycling — reflects Doe Run’s commitment to the metals lifecycle. Additional demand for lead will come from cell tower battery needs. 140,000 Doe Run’s recycling division recovered just over 140,000 tons of lead in 2007. 78% Lead concentrates from Missouri are sold to traders worldwide. Concentrates contain about 78 percent lead. 14 The Doe Run Company generations of growth Although the metals market has ebbed and flowed, Doe Run’s employee base remains strong. Like the branches of a tree, entire families have spent careers with Doe Run, sharing the knowledge rooted within them for generations. For some, it’s tradition. 15 2007 Report to Our Communities Tommy Dunlap, a driller at Doe Run’s Southeast Missouri Mining and Milling Division (SEMO), has mined with the Tommy Dunlap Gene Karr Aurielle Weaver* Taylor Howze* company and its predecessors since 1968. A third-generation employee, Dunlap follows in the footsteps of his father and grandfather, whose mining roots can be traced back in decades. Dunlap readily shares his wisdom with newcomers and beginning miners. “When Doe Run hires new crewmen, I’m one of the first to tour them around, show them the ropes, and share all the dos and don’ts. I’ve watched a lot of people grow into great miners, and I’m proud to pass along what I’ve learned from previous generations.” According to Bob Roscoe, vice president — mining and general manager at SEMO, Dunlap’s work ethic and attention to safety are priceless. “In nearly 40 years, Tommy hasn’t had a lost-time incident,” Roscoe said. “That attention to detail is something you can’t learn from a class or book. We’re grateful he’s still eager to demonstrate to new miners the attentiveness it takes to safely accomplish the job. His safety record is one of the best in the company.” In fact, in 2008, Dunlap will be eligible for a 40-year Joseph A. Holmes Safety Association award for 40 years without a Like Dunlap, Karr joined Doe Run as a third-generation employee. Although he followed in the path of his father, a blacksmith, and his grandfather, who worked in sample preparation, he didn’t always aspire to share their profession. In his words, “Not many people dream of doing exactly what their parents do.” But since Karr began at the smelter, his pride has deepened. “I’m proud to have seen the company advance — a lot has changed. When I took my first job, everything was done with pencil and weigh machine. Now, automated systems help manage measurements and testing. A lot has been accomplished, and there isn’t another job I would have rather had.” Since the year Karr started, in 1969, the Herculaneum smelter has: • Achieved numerous awards for safety; • Produced more than 6 million tons of lead metal; and • Reduced emissions by more than 90 percent. lost-time incident. Karr is now enjoying his retirement. After a family vacation Despite all he’s accomplished, Dunlap is still excited about each in Gulf Shores, Ala., he now serves as a part-time bus driver day’s adventure. “Mining for me has always been like a treasure for the Dunklin R-5 School District. hunt. I can hardly wait after each blast — exploring the ore is Two Herculaneum summer employees trace their Doe Run like opening a treasure chest. And, I’m aiming for another year roots back even further. Aurielle Weaver and her cousin, to reach the four-decade mark,” Dunlap said with a grin. Taylor Howze, are fifth-generation employees. Their family tree includes Harrison Casey, the first of their family to work for the Since the year Dunlap started, in 1968, SEMO has: • Achieved 23 Sentinels of Safety awards; and • Milled more than 168 million tons of ore. company. Casey worked the smelter’s blast furnace in 1907. Since the days when the first generations of their families began at Doe Run, the company and industry in which Just one year later and 100 miles away, Gene Karr began Dunlap, Karr, Weaver and Howze work in have grown working at Doe Run’s Herculaneum smelter. He logged 38 years dramatically. Today, lead continues to be vital in providing of service before retiring in 2007. He managed the smelter’s power, protection and convenience in daily life. Doe Run materials handling department. will continue to depend on employees, the proverbial roots who carry years of valuable expertise, skill and knowledge, to be successful in the future. *Weaver and Howze photos by Sherree Faries, Leader Publications. 16 The Doe Run Company reu responsible A roundtable discussion on the second life of lead-acid batteries and computer monitors There’s an ongoing need to responsibly recycle items that contain lead, especially products like spent lead-acid batteries and old computer monitors. Neighbors spoke with Steve Arnold, general manager of Doe Run’s Buick Resource Recycling Division (BRRD); Jim Lanzafame, environmental manager for BRRD; and Lou Magdits, Doe Run’s director of raw materials, to get their insights on lead recycling. Top: Battery recycling is one of the country’s biggest environmental success stories. The Buick Resource Recycling Division recycles virtually every piece of the battery — from the plastic casing and battery acid down to the wood pallet. 17 2007 Report to Our Communities se Why is the lead-acid battery Where can batteries be recycled? an ideal product for recycling? LM: For U.S. consumers, lead-acid Lou Magdits (LM): batteries are collected by automotive The standard lead-acid parts and repair shops, battery specialists battery powers more and mass merchandisers. Those batteries than half a billion are then sent for recycling — many passenger vehicles globally, as well arrive at BRRD. as golf carts, forklifts and other modes of transportation. Because each battery How much battery recycling has to be replaced every two to five happens at BRRD? years, it makes sense that we try to Steve Arnold (SA): recapture as many of the components We recycled as possible. Automotive batteries 13.5 million lead-acid contain approximately 20 pounds batteries in 2007. As of lead, 1 gallon of sulfuric acid and one of the world’s largest, single-site 2 pounds of plastic, so it has a lot of lead recycling facilities, we’re proud valuable, recyclable parts. of our contribution to recycling. Jim Lanzafame (JL): Besides the lead-acid battery, Plus, the 98.8 percent how else does Doe Run contribute recovery rate for to recycling efforts? lead-acid batteries is SA: Lead recycling is a success story — the highest among recycled products. for industry, regulators, consumers and By comparison, the recovery rates those concerned with the responsible use are 88.9 percent for newspapers, of our natural resources. Recycling helps 62.6 percent for office-type papers and preserve limited natural resources, and only 44.8 percent for aluminum cans, our facility recovers tons of materials according to the U.S. Environmental that otherwise would be thrown away. Protection Agency. JL: That’s right. We process recyclable Not only is the lead-acid battery material from customers, too. For recycled more thoroughly than these instance, Centrilift in Oklahoma sends other products, but by recovering the its process scrap to us because it’s more lead from the battery, we are also able economical than disposing of it. to produce high-quality lead for our customers’ reuse. This means lead metal can be recycled over and over again. Above: Doe Run opened the Buick Resource Recycling Division in 1991 and has steadily increased the amount of lead-bearing material it recycles each year. In 1998, the facility began accepting and recovering lead from cathode-ray tube (CRT) glass, which is gaining recycling momentum as consumers upgrade to flat-screen computer monitors and televisions. 18 The Doe Run Company a responsible citizen Employees at BRRD gave back to their neighboring communities in 2007. D oe Run shared science facts with attendees at the “Fall Rocks!” event in Park Hills, Mo.; and, employees helped staff the 2007 Old Miner’s Day Celebration in Viburnum, Mo. RRD, along with SEMO, B donated $50,000 to the Iron County Hospital’s Tree of Life fund. he facility hosted tours and T supported Doe Run’s hands-on minerals education program. RRD also holds annual open B houses for employees and their families. In addition, improvements were made to the blast furnace enclosure to improve our capture efficiencies. Our Breaking, Desulfurization and Crystallization (BDC) department also made great strides in 2007 by eliminating discharge contributions of process water into our wastewater treatment plant. What does the future look like for lead recycling and BRRD? SA: Recycling will continue to be a critical part of being good stewards of our resources and minimizing waste. As consumers switch to flat monitors and televisions, the number of CRTs that need to be replaced — and the lead recovered — is skyrocketing. In addition, some developing countries don’t have a LM: Others look to us for assistance What are the biggest challenges structured system to recover and recycle as well. We also recycle spent bullets in recycling lead products? batteries, so there’s a real need for a from law enforcement, military and JL: Environmentally, there are certainly leader like Doe Run. sporting ranges, and process lead-based challenges. We carefully monitor our LM: We expect to see a growing paint chips from restoration and air emissions and our water discharges. demand for co-products of the recycling remodeling projects throughout the This year, we installed a new tapping- process as well. In addition to capturing U.S. Doe Run safely recovers the lead process for our reverberatory furnace. lead and other trace metals from batteries, from the old paint chips, solving yet It allows us to decrease the amount of plastic casings are recycled (by third another waste issue. waste material we currently dispose of parties), oftentimes into new battery off site by about 18,000 tons per year; cases and other automotive parts. Sodium decrease the amount of iron we consume; sulfate, a co-product of the lead-recycling save about 150,000 gallons of diesel process, has its own unique story. fuel per year; and decrease our overall (See related story on page 19.) SA: BRRD is one of the few facilities that accepts and recovers lead from cathode-ray tube (CRT) glass, found in many computer monitors and television screens. We recycled more than 275,000 CRTs in 2007. sulfur dioxide emissions. In our efforts to continually make improvements in our performance, we have voluntarily installed a vehicle wash station to minimize the tracking of materials out of the facility. Right: The battery recycling process yields sodium sulfate, a high-quality salt that is used in the manufacturing of products such as glass, powdered laundry detergent and carpetfreshening products. 19 2007 Report to Our Communities sodium sulfate recieves kosher certification Though lead is the primary resource extracted from lead-acid batteries at the Buick Resource Recycling Division (BRRD), the recycling process and technology also yields approximately 1,200 tons of sodium sulfate, or salt, per month. To meet certification standards set forth by multiple manufacturing industries, a licensed rabbi from the Chicago Rabbinical Council, a certification organization, visits BRRD each year to ensure the salt-creation process and raw materials are consistent with kosher requirements. “Kosher” is a term used to describe products made in accordance with Jewish law. Nearly 75 percent of all prepackaged foods carry some sort of kosher certification. “Although none of the sodium sulfate we produce is contained in food, it is used in making a corn-based starch,” said Lou Magdits, Doe Run’s director of raw materials. “Suppliers of kosher-certified products require certifications at all steps in the manufacturing supply chain.” Doe Run’s sodium sulfate is also used in the manufacturing of other products such as glass, powdered laundry detergent and carpet-freshening products. 20 The Doe Run Company people + technology = mine saf For Doe Run’s Southeast Missouri Mining and Milling Division (SEMO), pride, dedication and safety are a way of life. Just ask the employees. “One of my proudest moments in my career was telling my father I had officially become a miner Denis Murphy Patrick Murphy with the St. Joseph Lead Company, Doe Run’s predecessor,” said Denis Murphy, SEMO’s safety and environmental manager. “And I’m even more proud now. This is a dedicated and safe industry that has really evolved. Through efforts like accomplished Mine Rescue Teams and exploring new technologies every day, we’re topping safety records on a regular basis while meeting the world’s demand for metals.” A fourth-generation miner with more than 30 years of industry expertise, Murphy is one of Doe Run’s many legacy employees Above: Doe Run’s Mine Rescue Teams annually participate in the University of Missouri-Rolla’s Annual Southeast Missouri Mine Rescue Contest, the only competition in the country that is held in a real mine setting. (see more on page 15). His father dedicated 43 years with St. Joe. Opposite page — right: To help celebrate Women’s History Month in March, Doe Run’s Carrie Heiling (at left), Lori Young (at right) and Vanessa Eckhoff (not pictured) submitted workday diaries for a national book project chronicling women in various professions. previous mining district, known as the “Old Lead Belt.” His grandfather and great-grandfather worked at Missouri’s 21 2007 Report to Our Communities From the U.S. Department of Labor: 539,000 2004 — Total amount of women employed in mining industries: 539,000 (10.2 percent of total workforce) 687,000 2006 — Total amount of women employed in mining industries: 687,000 (13 percent of total workforce) ety Murphy’s sons are continuing the tradition at the Herculaneum smelter and the mines. Murphy’s industry experience and commitment, along with his zero-injury record, make him qualified to oversee Doe Run’s two accomplished Mine Rescue Teams. Underground heroes Murphy recalls the last two years in mining news. “The coal-mining accidents make us even more determined to be better prepared,” he explained. “They also remind us of how important it is to work carefully and safely to prevent a situation, condition or activity that may put someone in harm’s way.” working women true stories of After transforming their work reality into daily snapshots, three women at Doe Run’s Southeast Missouri Mining and Milling Division (SEMO) are now published writers. In 2007, author Joni Cole selected three female Doe Run employees for a 24-hour glimpse into the mining profession. Sharing their unique perspectives were Carrie Heiling, mine geologist; Vanessa Eckhoff, metallurgical engineer; and Lori Young, technical service engineer III. “At first, it felt odd journaling my day,” Heiling said. “But I’ve got a neat job. I get paid to go underground, look at rocks and get dirty. I love the fact that I don’t have to be in an office every day. I think it’s great to be able to go out into the mine and get an up-close look at geological structures and features. It helps me understand the geology of the ore in the mine, which helps me do my job better. Besides, how many people can say they work a thousand feet underground?” In its three Missouri divisions (mining/milling, smelting and recycling), Doe Run employs more than 100 women in roles as diverse as raw materials coordinators, chemical analysts, crusher operators and safety and health specialists. Cole chose the women of Doe Run because the company is a leader in what is viewed as a male-dominated industry. “The women’s journals demonstrate how critical they are to the company,” Cole explained. “Their writings were very real, empowering, smart, funny and a joy to read, making them a home run for the book. The end result transports the reader into these women’s realities. The result was remarkable.” “Water Cooler Diaries: Women across America Share Their Day at Work” is published by Da Capo Lifelong Books, and available on www.amazon.com. The book will feature 35 journal entries (two from Doe Run) from more than 500 that were submitted. The book hits shelves in March 2008. As the third in the “This Day” series, it will join Cole’s two previous works, “This Day in the Life: Diaries from Women Across America” (2006) and “This Day: Diaries from American Women” (2004). 22 The Doe Run Company 2007 mine rescue results Gray Team: Maroon Team: Wayne Marlin (captain), Ken Wood, Charlie Walker, William Johnston, Larry D. Barton, Kenny Sherrill, Randal Hill and Garry Moore, Jr. Steve Setzer (captain), Shawn Pratt, Luke Davis, Keith Markeson, Andrew Hampton, Richard Dickerson, Jerry Laramore, Carl Mann and Ricky Martin Results from the 25th Annual Southeast Missouri Mine Rescue Contest: Results from the 25th Annual Southeast Missouri Mine Rescue Contest: • Fifth place, Field Competition • William Johnston, Randal Hill and Kenny Sherrill: Third place, First Aid Contest • Garry Moore Jr.: First place in the BG4 Benchman Contest with zero discounts* (This was his second consecutive win at the UMR contest.) • Ken Wood: First place in the Multi-Gas Bench Competition, with zero discounts* • First place, Field Competition • Also judged: “Best In-State” Team • Luke Davis: Second place in the Multi-Gas Bench Competition with only two discounts* • Ricky Martin: Fourth place in the BG4 Benchman Contest Hutchinson, Kan., Mine Rescue Contest: • Second place overall, and awards in every category • First place in the Gas Bench Contest • Second place in the First Aid Contest • Third place in the Field Competition • Fourth place in the BG4 Competition For preparation, Doe Run’s Mine Rescue Teams train eight New Iberia, La., Mine Rescue Contest: • Second place overall • Carl Mann: Third place in the BG4 Benchman Contest Larry Hampton and Danny King serve as team trainers for the Doe Run Mine Rescue Teams. *“Discounts” is a mine rescue term used to reflect the number of incorrect answers on written tests and the number of errors made during the mock mine disaster competition. With numerous problems to solve on and off the field, a score reflecting “zero” discounts is a highly respected achievement among mine rescue competitors. “What many people don’t know is that lead mining is far different hours monthly. They’re drilled on emergency scenarios using than coal mining,” said Greg Sutton, mine manager at SEMO the most current technology available. The regimen increases and an industry veteran of more than 20 years. “Our mines consist to 40 hours monthly during competition season, which sharpens mainly of dolomite, a rock with inherent geologic properties skills and brings rescuers together to share best practices. that make it strong and supported in most cases.” In fact, as some of the most recognized and skilled in the nation, Doe Run’s careful, methodic mining practices ensure the Doe Run’s Mine Rescue Teams continued to garner awards in naturally stable environment and integrity of the mine are 2007. For instance, at the University of Missouri-Rolla’s (UMR) not disrupted. SEMO uses the room-and-pillar mining method, mine rescue competition, both Doe Run teams and team members in which rock pillars (up to 35 feet wide and 120 feet tall) won several top awards. (See awards above.) support the ground above. Prevention through technology With six active mines and 200 employees per shift, Doe Run relies on a naturally stable environment, proactive safety Doe Run further secures the mine ceiling (known as a “back”), by installing 5- to 8-foot-long “roof bolts” with steel plates, each supporting 18 tons of rock every 6 feet. initiatives, engineering controls and more than a century of Doe Run’s expertise is shared with universities to help expertise to create one of the safest mining environments educate future mining professionals. In 2007 alone, groups in the world. from Washington University in St. Louis, the University of Missouri-Columbia, Indiana University, Southern Illinois University Edwardsville, Northwest Missouri State and Iowa State, to name a few, toured the SEMO mines. 23 2007 Report to Our Communities the art of Lead may be one of the heaviest elements found on the periodic table, yet a key step in extracting lead from ore requires the metal to be floated on bubbles. That’s right — bubbles. Unearthed lead ore undergoes crushing and grinding processes to reduce it to a fine material, much like sand. This material then enters the “flotation circuit.” There, in flotation tanks, tiny air bubbles are introduced. A chemical known as a reagent is added to the mixture. The reagent — xanthate in this case — serves as a collector, bonding to the tiny lead particles and lifting them to the surface, where a bubbly froth forms floating metal and is skimmed for final processing of the lead. Any remaining materials, such as dolomite, sink to the bottom of the flotation tank. “Flotation is similar to what happens in a washing machine, when laundry detergent latches on to particles of dirt and lifts them away from clothes,” said John Boyer, general mill manager at Doe Run. “But in our process, we are actually retaining the lead particles — it’s the equivalent of collecting the dirt and throwing the clothes away.” Lead isn’t the only metal to undergo flotation. Zinc and copper are also commonly separated this way at Doe Run’s four mills. In 2007, Doe Run developed an innovative copper flotation circuit at its Sweetwater Mine and Mill. The circuit includes several novel processes that allow it to operate more efficiently than other copper circuits in the industry. To create this new circuit, team members used parts from mills that were no longer operating and from existing circuits that had excess capacity. The project was completed ahead of schedule and under budget. “The team was willing to take a chance in the creation of this circuit, and the hard work has truly paid off,” Boyer said. “Sweetwater previously didn’t have a copper circuit, so we were required to haul the ore to another mill for processing. With this new equipment, we are able to generate copper concentrates on site for sale to customers.” Additionally, remote mining allows Doe Run to return to areas of the mines once considered “mined out.” Valuable ore left in the pillars is extracted as miners work their way out, called “retreat” mining. Through people and technology, SEMO has demonstrated a successful equation for mine safety. Employees also work closely with educators and students on “I am proud and honored to be a part projects that improve industry safety. For example, Doe Run of the safety success that Doe Run’s is working with UMR on a research project that monitors mining operations are known for,” ceiling movements at Fletcher Mine. Doe Run provided a said Bob Roscoe, vice president — grant to fund the project, slated for completion in 2008. mining and general manager at SEMO. Doe Run also utilizes “remote mining,” which was developed in the 1980s and increased in use around 1991. By equipping a miner with a unit that allows remote operation of a 25-ton loader, blasted ore can be safely excavated from hundreds of feet away. “Technology has come a long way, but our people are the very core of the equation. They make the difference.” 24 The Doe Run Company building knowledge through community education By Angie Nations Some of the most advanced technologies on the planet, including computers and cell phones, get their start in Doe Run’s In addition to educating teachers, Doe Run shares its knowledge on lead-acid battery recycling through a featured section in the ninth-grade textbook “Global Science: Energy, Resources, Environment.” mines. We’re proud of what we do, and Recognizing the need to help support it’s rewarding to share our knowledge. our future miners and engineers, we Here’s a look at just a few examples: provide valuable skills and a way to save for college through our summer Our widely popular Minerals Education and semester break internship programs. Program provides K-12 students with In 2007, nearly 60 students participated interactive opportunities to learn about in these paid opportunities. the minerals we use in our everyday lives. In one program, for example, students learn about mining and minerals The company also offers numerous Top: At teachers’ requests, Doe Run Minerals Education Teams travel to dozens of schools each year, educating nearly 3,000 students annually. Bottom: Minerals Education Team members Angie Nations (pictured), Pat Mayfield and Sandy Burkes spent time in Casa Grande, Ariz., in 2007 to conduct “birdseed mining” with Stanfield Elementary School second-graders. Here, students identify Missouri’s Viburnum Trend on a U.S. map. scholarships for students in engineering, chemistry, geology, mining and efforts. By sharing our earth science geophysics programs. Scholarships knowledge in the classroom, our are available for students attending minerals education team members are institutions such as the University of accomplishing several goals, including: To share this program with educators Missouri-Rolla, Mineral Area College supporting the Missouri Standards and around the Midwest, we participate in in Park Hills, Mo., and Jefferson Grade Level Expectations, engaging the annual Missouri Minerals Education College in Hillsboro, Mo. students in science through fun and through “chocolate chip cookie mining.” In another, participants use minerals to create toothpaste. Foundation workshop. At the workshops, hundreds of K-8 teachers acquire curriculum ideas for mineral and rock identification, environmental initiatives and everyday uses for minerals. Mine tours may be made available for education, industry-sharing and research initiatives. Doe Run also supports and participates in various public events, such as the Missouri Department of Natural This past year, I spoke at the 16th annual Resources’ free “Fall Rocks!” event at National Minerals Education Conference the Missouri Mines State Historic Site. in Bloomington, Ind. The conference brought together industry professionals to share experiences and provide innovative approaches to minerals and earth science education. Our commitment to our operating communities includes supporting education in various ways, including financially and through our volunteer competitive activities, bringing the importance of rocks and minerals in our lives up close and personal and promoting an awareness of the many exciting and challenging careers as scientists. Angie Nations serves as community relations manager for The Doe Run Company and directs the company’s popular Minerals Education Program. For more information about the program, e-mail: [email protected]. 25 2007 Report to Our Communities 2006 Toxic Release Inventory what is the TRI? SEMO (Total releases in pounds) Materials The TRI, or Toxic Release Inventory, was initiated under Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986. TRI requires that companies annually report to the federal and state governments the disposal or release of specific materials listed as “toxic chemicals.” This also covers waste management activities, including recycling. On the opposite page are The Doe Run Company’s submissions to the Environmental Protection Agency (EPA) for 2006. The 2007 data will be available at www.doerun.com by July 15, 2008. Please note that all releases reported on Doe Run’s TRI are regulated under current federal and state law. Why do the amounts vary by facility? The amounts vary because of the size of the operation, the processes used, the various levels of natural minerals in the materials processed and the emissions from each operation. Large-volume, low-toxicity materials such as mine tailings and smelter slag account for more than 98 percent of all TRI submissions for The Doe Run Company. These materials are stored on Doe Run property following state and federal guidelines. Air Land Water Totals Antimony — — — — Arsenic — — — — Cadmium — — — — Chromium — — — — Cobalt — — — — 2,062 7,143,490 1,095 7,146,647 — — — — Copper Dioxin Lead 44,347 33,123,448 9,290 33,177,085 Nickel — — — — Silver — — — — Sulfuric Acid — — — — Zinc Totals 9,116 23,541,638 21,774 23,572,528 55,525 63,808,576 32,159 63,896,260 Herculaneum (Total releases in pounds) Materials Air Land Water Totals Aluminum 141 2,099,374 — 2,099,515 Why are some substances listed for certain locations not listed at other locations? Antimony 199 72,706 — 72,905 Arsenic 248 54,529 20 54,797 According to guidelines established by the EPA for nearly 650 chemicals and metals covered in TRI reporting, companies must determine, for each chemical or metal used in their process, whether the use or manufacture of that chemical or metal equals or exceeds established threshold values. Only those that exceed threshold values are reported. Cadmium 1,024 9,103 123 10,250 — — — — Why are there such large amounts released to land? The very nature of metals extraction by mining and smelting operations results in large volumes of residual materials, which are reported under the TRI. However, due to the low toxicity of these residual materials, they have been exempted from hazardous waste regulations by Congress. Virtually all of Doe Run’s reported “releases” to land represent materials that are kept in regulated, contained storage or disposal areas such as our permitted slag storage areas and tailings impoundments. These materials aren’t actually “released” to public areas, but rather stay on Doe Run’s private property. When materials are disposed of through off-site, EPA — and state-approved landfills, under the TRI reporting requirements, the materials are considered “released” to the environment. Chromium Cobalt 49 Copper 758 Dioxin 209,029 209,078 181,764 182,566 44 — — — — 56,838 2,104,380 1,092 2,162,310 Nickel 184 20,089 1 20,274 Silver — — — — Sulfuric Acid 512 — — 512 7,188,766 399 7,194,624 Lead Zinc Totals 5,459 65,412 11,939,740 1,679 12,006,831 BRRD (Total releases in pounds) Materials Air Land Water Totals Aluminum — — — — Antimony 285 277,961 233 278,479 Arsenic 144 19,854 72 20,070 — — — — 1,340 — — 1,340 Cadmium Chlorine Why aren’t there reports for your Glover or St. Louis sites? Chromium — 71,244 — 71,244 The Doe Run Company suspended production at its Glover smelter on Dec. 1, 2003. Therefore, there were no reportable releases from that site in 2006. At the company’s St. Louis headquarters and at historic sites, no active production is taking place. Therefore, no reports are required at those locations. Cobalt — — — — Copper — — — — — — Dioxin* Lead 5* 5* 8,390 1,499,007 467 1,507,864 Nickel — — — — Silver — — — — Zinc — — — — 10,159 1,868,066 772 1,878,997 Totals *In grams 26 Doe Run Headquarters 1801 Park 270 Drive, Suite 300 St. Louis, MO 63146 Buick Resource Recycling Division HC1 Box 1395 Boss, MO 65440 SEMO — Mining and Milling Division P.O. Box 500 Viburnum, MO 65566 Glover Smelting Division Route 1, Box 60 Annapolis, MO 63620 Herculaneum Smelting Division 881 Main Street Herculaneum, MO 63048 www.doerun.com The Doe Run Company
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