TWA, MPC- E, toxic substances

DEGA CZ s.r.o., K Žižkovu 640/9, 190 00 Prague 9, Czech Republic
TAX ID: CZ27902943; Company ID: 27902943,
E-mail: [email protected]
Website: www.dega.cz
Telephone : +420 774 447 660-1
List of chemicals and their Permissible Exposure Limits (PEL) and maximum permissible
concentrations (MPC)
In accordance with Act No. 361/2007 Coll. (Appendix 2, Part A)
(an Amendment to Act No. 178/2001)
MPC: the maximum permissible concentration of a chemical substance in the working environment
PEL: Permissible Exposure Limit (TLV) of the chemical substance, i.e. the maximum permissible value of a time-weighted average (TWA) of
the concentration of a gas in the air.
Explanation of the table:
The "permissible concentrations" box refers to the permissible exposure limits, known as PEL, and the maximum permissible
concentrations, designated as MPC
The " CAS number" box – the registration number of the substance used by Chemical Abstracts Services
The "Notes" box:
I – during exposure the substance penetrates through the skin or a strong irritant effect to the skin occurs.
S – the substance has a sensitising effect.
L – potential significant late effects of the substance are unpredictable.
* - in the case of MPCs pay attention to the physico-chemical properties (e.g. explosiveness).
Substance
carbon monoxide
acetaldehyde
acetone
arsenic
Arsan / arsine
Ammonia (Ammonia)
benzene
Petrol (technical mixture of
hydrocarbons)
Formula
CO
CH3CHO
(CH3)2CO
As
AsH3
NH3
C6H6
biphenyl
Brom
Hydrogen bromide
1,3-Butadiene
Butanol (all isomers) / butyl
Br
HBr
C4H6
C4H9OH
Butyl acetate (butyl acetate)
C2H5-COO-C4H9
cyclohexane
cyclohexanol
Cyclohexanone
C6H12
C6H12O
C6H10O
CAS Number
630-08-0
75-07-0
67-61-1
7440-38-2
7784-42-1
7664-41-7
71-43-2
86290-81-5
92-52-4
7726-95-6
10035-10-6
106-99-0
71-36-3
78-92-2
78-83-1
75-65-0
123-86-4
110-19-0
540-88-5
110-82-7
108-93-0
108-94-1
mg.m-3
30
50
800
0,1
0,1
14
3
400
Permissible concentrations
PEL
NPK-P
ppm mg.m-3
Conversi- Notes
on factor
ppm from ppm
26,19
27,75
336,80
0,10
0,03
20,13
0,94
400,00
150
100
1500
0,4
0,2
36
10
1000
130,95
55,50
631,50
0,40
0,06
51,77
3,13
1000,00
0,873
0,555
0,421
1
0,7
1
10
300
0,16
0,11
0,30
4,25
99,00
3
1,4
6
20
600
0,47
0,21
1,81
8,50
198,00
0,158
0,153
0,302
0,425
0,33
950
200,45
1200
253,20 0,211
700
200
40
203,00
48,80
9,96
2000
400
80
580,00 0,29
97,60 0,244
19,92 0,249
Stránka 1 z 3
0,313
1,438
0,313
P
P
P
D, P
D
P
D
D
D
Cyclohexylamine /
Cyklohexanamin
diethylamine
C6 H13 N1
108-91-8
20
4,94
40
9,88 0,247
D
C4H11N
109-89-7
15
5,01
30
10,02 0,334
D
2-diethylaminoethanol
C2H7N
100-37-8
50
10,40
100
20,80 0,208
D
60-29-7
300
99,00
600
198,00 0,33
C12H11N
C2H4Cl2
122-39-4
75-34-3
10
400
10,00
98,80
20
800
20,00
197,60 0,247
D, P
D
C2H4Cl2
107-06-2
10
2,47
2,02
20
D, P
C2H2Cl2
75-35-4
8
4,94 0,247
4,03
0,252
403,20
0,252
4,88 0,542
1062,00 0,531
6,68 0,334
20,10 0,335
0,02 0,407
Diethyl ether / Difenyloxid /
Ethyl
Diphenylamine
1,1-Dichloroethane
1,2-Dichloroethane
1,1-dichlorethene / 1,1dichloroethylene
1,2-dichlorethene / 1,2dichloroethylene
dimethylamine
dimethyl
dimethylethylamino
dimethylformamide
C4H10O
16
201,60
C2H2Cl2
C2H7N
C2H6O
CH3CH2N(CH3)2
C3H7NO
540-59-0
124-40-3
115-10-6
598-56-1
68-12-2
800
4
1000
10
30
2,17
531,00
3,34
10,05
1600
9
2000
20
60
dimethylhydrazine
C2H8N2
Dimethylsulfát
Ethanol / Ethyl
(CH3O)2SO2
C2H6O
57-14-7
77-78-1
64-17-5
0,025
0,1
1000
0,02
532,00
0,05
0,2
3000
ethyl acetate
C4H8O2
141-78-6
700
194,60
900
ethylamine
C2H7N
75-04-7
9
4,88
20
ethylbenzene
C8H10
100-41-4
200
46,00
500
ethylene
C2H4O
75-21-8
1
0,56
3
Chloroethane / ethylchloride
C2H5Cl
phenol
C6H6O
Styrene / Fenylethylen
C8H8
fluor
Hydrogen fluoride
formaldehyde
Phosphide / phosphine /
Phosphine
F
HF
CH2O
Phosgene / carbonyl
Freon 11 /
trichlorofluoromethane
Freon 12 /
dichlorodifluoromethane
Freon 12B2 /
Dibromodifluoromethane
Freon 13 /
Chlortrifluormethan
Freon 13B1 /
Trifluorbrommethan
Freon 21 /
dichlorofluoromethane
Freon 114 / 1,2-Dichloro1,1,2,2-tetrafluoroethane
Glycerol, fog
Heptane (technical mixture of
isomers)
Hexane isomers (excluding nhexane)
n-Hexane
0,01
98,28
75-00-3
260
0,04 0,194
1596,00 0,532
250,20 0,278
10,84 0,542
115,00 0,23
1,67 0,556
540
0,378
3,90 0,26
94,00 0,235
7,5
15
100-42-5
7782-41-4
7664-39-3
50-00-0
100
1,5
1,5
0,5
23,50
1,50
1,83
0,41
400
3
2,5
1
PH3
7803-51-2
0,1
0,07
0,2
0,14 0,719
CCl2O
75-44-5
0,08
0,02
0,4
0,10 0,247
CCl3F
75-69-4
3000
534,00
4500
801,00 0,178
CCl2F2
75-71-8
3000
606,00
5000
1010,00 0,202
CBr2F2
75-61-6
800
92,80
1300
150,80 0,116
CClF3
75-72-9
4000
1093,60
6000
1640,40 0,2734
CBrF3
75-63-8
4000
656,00
6000
984,00 0,164
CHCl2F
75-43-4
40
9,52
50
11,90 0,238
C2Cl2F4
C3H8O3
76-14-2
56-81-5
3000
10
429,00
2,44
5000
15
715,00 0,143
3,66 0,244
C7H16
426260-76-6
1000
244,00
2000
488,00 0,244
110-54-3
1000
70
284,00
19,88
2000
200
568,00 0,284
56,80 0,284
C6H14
Stránka 2 z 3
D, P
D, P
D, P
D
D
D, P
204,12
1,95
108-95-2
D
3,00
3,06 1,223
0,81 0,814
D
D
D,S
D, P
Hydrazine
N 2H 4
potassium hydroxide
sodium hydroxide
calcium hydroxide
KOH
NaOH
Ca(OH)2
chlorine
Chloracetaldehyd
Cl2
ClCH2CHO
302-01-2
1310-58-3
1310-73-2
1305-62-0
7782-50-5
107-20-0
0,05
1
1
2
0,5
1
0,04
1,00
1,00
2,00
0,17
0,31
0,1
2
2
4
1,5
3
0,08 0,763
2,00
2,00
4,00
0,52 0,344
0,93 0,311
chlorobenzene
C6H5Cl
108-90-7
25
5,43
70
15,19 0,217
Ammonium chloride (fumes)
Chloroform /
Trichloromethane
NH4Cl
12125-02-9
5
5,00
10
10,00
CHCl3
hydrogen chloride
HCl
67-66-3
7647-01-0
10
8
2,05
5,43
20
15
4,10 0,205
10,19 0,679
100
3
250
600
10
200
20,30
2,72
188,50
198,00
7,57
53,20
250
10
1000
800
20
500
Isopropylbenzene / Cumene
C9H12
Hydrogen cyanide
Methanol / methyl
HCN
CH4O
methyl
methylamine
Methane / Toluene
C7H8
98-82-8
74-90-8
67-56-1
79-20-9
74-89-5
108-88-3
CH2Cl2
75-09-2
200
57,60
CH3C(O)CH2CH3
78-93-3
600
CH3Cl
74-87-3
100
C6H5NO2
98-95-3
1
11104-93-1
10102-43-9
10102-44-0
10024-97-2
7446-09-5
10028-15-6
7783-06-4
10
180
5
0,1
10
Methylene chloride /
Dichloromethane
Methylethylketone / 2Butanone
Methyl chloride /
Chloromethane
nitrobenzene
carbon dioxide
NO2
nitric oxide
NO
Nitrous gases (NOx), oxides of
nitrogen
with the exception of nitrous
oxide
nitrous oxide
N 2O
carbon dioxide
ozone
Hydrogen sulfide
SO2
O3
H 2S
Stránka 3 z 3
50,75
9,05
754,00
264,00
15,14
133,00
D, S, P
P, D
0,203
0,905
0,754
0,33
0,757
0,266
D
D
D
500
144,00 0,288
D
203,40
900
305,10 0,339
48,40
200
96,80 0,484
0,20
2
0,40 0,199
10,00
99,90
1,91
0,05
7,19
20
360
10
0,2
20
20,00
199,80
3,82
0,10
14,38
0,555
0,382
0,509
0,719
D
D
D, P
D