Utah State University From the SelectedWorks of Mario Yuuji Harper April 17, 2013 Franck-Hertz Experiment Mario Yuuji Harper, Utah State University Blake Moore, Utah State University Available at: http://works.bepress.com/mario_harper/3/ Franck-Hertz Experiment Mario Harper and Blake Moore USU Physics Utah State University, Logan, UT 84332-4414 Introduction Abstract The apparatus used for the experiment consist of a tube containing low pressure gas, fitted with three electrodes: cathode for electron emission, a mesh grid for the acceleration of electrons and a collecting plate. The phenomenon investigated in this experiment was whether or not it was possible to excite atoms by low-energy electron bombardment, and to determine if the energy transferred from the colliding electrons were always in discrete amounts. This was investigated using thermally excited electrons that were accelerated across a potential through a homogenous gas of a single element. A slowing potential was applied at the anode making electrons that transferred their energy via inelastic collisions to lose their energy before arriving at the detector, this caused drastic decreases in the current observed. These decreases in current always occurred at the same accelerating potential, which can be interpreted as electrons only being able to transfer discrete amounts of energy to atoms, and this energy correspondingly associates with the allowable energy levels within the atoms. With the help of thermal excitation emission, electrons are boiled off by a heated cathode and accelerated toward a grid which is held at a positive potential, relative to the cathode. The collecting plate is at a lower potential and is held negative with respect to mesh grid. If electrons have sufficient energy upon reaching the grid, they will pass through and reach the collecting plate thus causing a measurable current as can be read by an ammeter. Electrons which do not have sufficient energy on reaching the grid will be slowed down, and will fall back to the grid. The experimental results can confirm the existence of discrete energy levels of atoms. 2 Inelastic collision 1 Inelastic collision Elastic collision In 1914, James Franck and Gustav Hertz performed an experiment which demonstrated the existence of discrete excited states in mercury atoms, helping to confirm the quantum theory which predicted that electrons occupied only discrete, quantized energy states. Electrons were accelerated across a potential toward a positively charged grid in a glass envelope filled with mercury vapor. Past the grid was a collection plate which was held at a small negative voltage with respect to the grid. The values of accelerating voltage where the current dropped gave a measure of the energy necessary to force an electron to an excited state. Method As long as the electron collision is elastic, the electrons will not lose energy on colliding with gas molecules in tube. As the accelerating potential increases, the current also subsequently increases. The interesting phenomenon occurs when the accelerating potential reaches a particular value, (12.13eV for Xenon, 19eV for Neon), each electron that posses that particular energy causes that the collision becomes inelastic. As a result, the energy level of an electron bound to the atom is raised. Now the electrons at this potential loses its energy and fails to reach the collecting plate, we can see this by observing subsequent current drops. Fig. 1. Typical results and explanation of the Franck-Hertz experiment for Mercury. Fig. 2. Full spectrum emission of Neon, both visible and not visible. Theory (b) Fig. 3. Visible spectrum of Xenon (a) We can view quantized energy states as a function of wavelength and energies. For a bounded particle, the wave function is similar to that of a standing wave. The standing wave (bounded) can only have integer relations to its state, at other states the waves interfere destructively, resulting in zero probability density. (a) Electrons can be seen as a standing wave in its bounded orbits. If we view the electron as existing in a potential well, it naturally follows that we should get a standing wave (and correlating energy and wavelength). This means that the electron cannot absorb any energy below a certain threshold, as it cannot exist at that energy. However, at a quantized energy, the electron can absorb energy and move into a new bounded orbit that is associated with this new energy state. The Frank-Hertz experiment supported the theory of the Bohr atom which was first derived from the study of Hydrogen. The spectral lines of hydrogen was estimated by the Bohr-Balmer Series, showing a relation between wavelength and discrete energies as follows: 𝟏 𝟏 𝟏 = 𝑹𝑯 𝟐 − 𝟐 λ 𝟐 𝒏 The Frank-Hertz experiment was designed to test this relation and explained that all gases have a quantized energy bandwidth that is related to the spectral lines. (c) (b) (d) Fig. 6. Diagram of the Franck-Hertz apparatus: a) Heated cathode produces electrons. b) Positively charged grid accelerates electrons. c) Collecting plate, slightly negative with respect to the grid so that only those electrons above the threshold will reach it. d) Current from collector measured as a function of accelerating voltage. Fig. 3. The wavelength compared to the intensity of the emitted light: a) Neon b) Xenon References • R.E. Robson, B. Li, and R.D. White, “Spatially periodic structures in electrons and the Franck-Hertz experiment,” Journal of Physics B: Molecular and Optical Physics, 33, 3, (2000) • G.F. Hanne, “What really happens in Franck-Hertz experiment with mercury?,” American Journal of Physics, 56, 8, August (1988) • Gerald Rapior, Klaus Sengstock, and Valery Baev, “New features of the Franck-Hertz experiment,” American Journal of Physics, 74, 5, May (2006) Results The results we obtain are relatively comparable to the expected results for both neon and xenon. However, they are not as pronounced as expected. (a) Fig. 7. Experimentally acquired data, Current vs. Potential energy: a) Neon b) Xenon (b)
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