Human Life Support Requirements: Inputs Life Support Concepts for Space Travel Outputs Daily Rqmt. Oxygen Food Water (% total mass) 0.83 kg 0.62 kg 3.56 kg Daily 2.7% 2.0% 11.4% Carbon 1.00 kg dioxide Metabolic 0.11 kg solids Water 29.95 kg (drink and food prep.) Raymond M. Wheeler Biological Sciences Branch Kennedy Space Center, FL Water 26.0 kg (% total mass) 83.9% (hygiene, flush laundry, dishes) (metabolic / urine (hygiene / flush (laundry / dish (latent 3.2% 0.35% 96.5% 12.3%) 24.7%) 55.7%) 3.6%) TOTAL 31.0 kg TOTAL 31.0 kg Source: NASA SPP 30262 Space Station ECLSS Architectural Control Document Food assumed to be dry except for chemically-bound water. Life Support Approaches for Space Physico-Chemical (PC) Food Oxygen CO2 Removal CO2 Reduction Liquid Wastes Solid Wastes PHYSICO-CHEMICAL (PC) TECHNOLOGIES -CLOSING THE AIR LOOP LEADING OPTIONS Biological OO2 GENERATION 2 GENERATION ¾Static ¾StaticFeed FeedWater WaterElectrolysis Electrolysis Stowage and Resupply Photosynthesis Electrolysis Photosynthesis Chlorate Candles LiOH Photosynthesis Regenerable Amines Molecular Sieves Bosch / Sabatier Photosynthesis CO2 Electrolysis Multi-Filtration Microbiological Evaporation Transpiration Vap. Compr. Distillation Vap. Phase Cat. NH3 Removal Incineration Microbiological Supercritical Oxidation Lyophilization ITALIC = International Space Station ¾¾Solid SolidPolymer PolymerElectrolysis Electrolysis- -Liquid LiquidAnode AnodeFeed Feed ¾¾CO Electrolysis CO22Electrolysis ¾¾Water WaterVapor VaporElectrolysis Electrolysis ¾¾Bioregeneration Bioregeneration CO CO22REDUCTION REDUCTION CO CO22REMOVAL REMOVAL ¾Four ¾FourBed BedMolecular MolecularSieve Sieve ¾¾Solid SolidSolid SolidAmine AmineWater WaterDesorbed Desorbed ¾Sabatier ¾SabatierReactor Reactor ¾¾Electrochemical ElectrochemicalDepolarized DepolarizedConcentrator Concentrator ¾¾Air AirPolarized PolarizedConcentrator Concentrator ¾Bosch ¾BoschReactor Reactor ¾¾Two-Bed Two-BedMolecular MolecularSieve Sieve ¾Advanced ¾AdvancedCarbon CarbonReactor Reactor ¾¾Lithium LithiumHydroxide Hydroxide(LiOH) (LiOH) ¾CO Electrolysis ¾CO22Electrolysis ¾¾Bioregeneration Bioregeneration ¾Bioregeneration ¾Bioregeneration Source: Mark Kliss, NASA ARC ISS Allowable Cabin Air Total Pressure and ppO2 15.5 Max O2 Partial Pressure Max. Total Pressure x Ma N2 r Pa lP tia 1 .6 e1 Normal Range Min. Total Pressure 13.5 2 2.5 3 3.5 Oxygen Partial Pressure (psia) Source: Jim Reuter, NASA MSFC • Oxygen Partial Pressure Control Plan: ¾ Intent is to also utilize Shuttle to raise ppO2 as high as practical prior to undocking. ¾ Normal O2 introduction is via water electrolysis O2 generator. ¾ Can be ~constant introduction of O2 through day to achieve fairly stable O2 cabin concentrations. ¾ Strict adherence to RRD ppO2 limits would restrict operational flexibility. i ps Off-Nominal Range 14 Total Pressure Control Plan: ¾ Intent is to utilize Shuttle to raise ISS pressure as high as practical within allowable range prior to undocking. ¾ Decay to lower end of control band over time, then utilize on-orbit gas storage to maintain pressure. 2 14.5 ur ss re • 24.1 % 15 Max O Total Pressure (psia) Min O2 Partial Pressure ISS Total Pressure and PPO2 Control 4 Source: Jim Reuter, NASA MSFC 1 ATMOSPHERE REVITALIZATION Space Station Strategy CO2 Removal Performance (for ISS) - Development Testing Impact of Varying Airflow Rate Four Bed Molecular Sieve ⇒ CO2 Removal Trap CO2 SABATIER REACTOR ¾ ¾ 4BMS 4BMS composed composed of of two two sets sets of of identical identical beds beds operating operating in in parallel parallel ---- one one set set is is for for adsorbing, adsorbing, the the other other for for desorbing desorbing •• Dessicant Dessicant bed bed for for water water vapor vapor removal removal •• Zeolite Zeolite molecular molecular sieve sieve bed bed for for trapping trapping CO CO22 ¾ ¾ Beds Beds trade trade functions functions when when adsorbing adsorbing beds beds reach reach storage storage capacity capacity CO2 Removal Rate (lb/hr per mmHg) FOUR BED MOLECULAR SIEVE CO2 FROM CABIN AIR 0.22 0.2 0.18 0.16 0.14 Flight Unit Performance ¾ ¾ Beds Beds are are heated heated to to desorb desorb water water to to the the cabin cabin and and CO CO22 to to Sabatier Sabatier Reactor Reactor 0.12 16 ¾ ¾ Adsorption Adsorption efficiency efficiency is is highest highest at at low low temperatures, temperatures, requiring requiring that that warm warm cabin cabin air air pass pass through through an an air-liquid air-liquid heat heat exchanger exchanger before before entering entering adsorbing adsorbing beds. beds. 18 20 22 24 26 Flowrate (cfm) Source: Jim Reuter, NASA MSFC Source: Mark Kliss, NASA ARC Closed Hatch ECLS Test CO2 Removal Performance PC TECHNOLOGIES CLOSING THE WATER LOOP LEADING OPTIONS 5.0 ITALIC = International Space Station ppCO2 (mmHg) 4.5 6 person crew load 4.0 3.5 POTABLE WATER RECYCLING ¾ Multifiltration (and Sabatier) 4 person crew load 3.0 3 person crew load 2.5 2.0 ¾ Reverse Osmosis ¾ Electrodeionization ¾ Bioregeneration 1.5 HYGIENE WATER RECYCLING ¾ Multifiltration ¾ Reverse Osmosis 1.0 0.5 URINE RECYCLING 120:15:00 121:07:00 121:14:15 121:21:30 122:12:30 122:17:00 122:19:30 122:23:15 123:01:30 123:03:15 123:06:30 123:13:30 123:17:00 123:21:00 124:00:00 124:05:00 124:16:00 124:19:30 124:22:00 124:23:40 125:02:00 125:05:30 125:08:00 125:10:30 125:13:00 125:14:45 125:16:00 125:17:37 125:18:47 125:21:00 125:23:00 126:01:30 126:03:00 126:05:30 126:07:45 126:08:45 126:10:15 126:11:30 0.0 ¾ Bioregeneration ¾ Vapor Compression Distillation ¾ Thermoelectric Integrated Membrane Evaporation ¾ Air Evaporation GMT ¾ Vapor Phase Catalytic Ammonia Removal Source: Mark Kliss, NASA ARC Source: Jim Reuter, NASA MSFC WATER RECOVERY MANAGEMENT Space Station Strategy MULTIFILTRATION ⇒ (SABATIER) ⇒ POTABLE WATER RECOVERY MANAGEMENT Space Station Strategy (Evolutionary) MULTIFILTRATION ⇒ (SABATIER) ⇒ POTABLE MULTIFILTRATION (MF) SABATIER REACTOR ¾¾POTABLE POTABLEWATER WATERisisobtained obtainedthrough throughMULTIFILTRATION MULTIFILTRATIONofof condensate condensatefrom fromthe theTemperature Temperatureand andHumidity HumidityControl ControlSystem, System,and and eventually eventuallyalso alsofrom fromwater waterformed formedininthe theSabatier SabatierReactor Reactorduring duringthe the CO reduction process. CO2 reduction process. 2 ¾¾MF MFconsists consistsofofaaparticulate particulatefilter filterupstream upstreamofofsix sixunibeds unibedsininseries. series. Each Eachunibed unibedisiscomposed composedofofan anadsorption adsorptionbed bed(activated (activatedcarbon) carbon)and and ion exchange resin bed. ion exchange resin bed. — — Particulates Particulatesare areremoved removedby byfiltration filtration — — Suspended Suspendedorganics organicsare areremoved removedby byadsorption adsorptionbeds beds — — Inorganic Inorganicsalts saltsare areremoved removedby byion ionexchange exchangeresin resinbeds beds Source: Mark Kliss, NASA ARC CO2 + 4H2 = 2H2O + CH4 + heat ¾ CO2 is reacted with H2 at high temperature (180-530 °C) in the presence of a ruthenium catalyst on a granular substrate. ¾ This produces water and methane for the potable supply. ¾ A single pass through the Sabatier reactor reduces greater than 98% of the input CO2. ¾ CO2 conversion is incomplete (resupply penalty) and methane will likely be vented (interferes with astronomical instrumentation observations). Source: Mark Kliss, NASA ARC 2 Principal Life Support Hardware Distribution ISS Atmospheric Contaminant Control Methods Source: Jim Reuter, NASA MSFC • Passive Control Atmosphere Gas Bottles ¾ Materials selection and control process ¾ Payload materials and processes screening ¾ Hardware design • Service Module Node 2 Node 1 P CAM (Zenith) Not Shown Node 3 UDM Carbon Dioxide Removal ATV Trace Contaminant Control P/H Full Body Cleanser Sabatier (scar) Water Storage Nitrogen Storage Water Processing (P=Potable; H=Hygiene) Source: Jim Reuter, NASA MSFC ESA COF CRV (not shown) Oxygen Storage Urine Processing O2 Compressor Personal Hygiene Facility Air Save Compressor LEGEND Primary Temperature and Humidity Control Vacuum System Pressure Control Assembly Galley Miscellaneous Equip: Fans, Valves, Filters, Smoke Detectors, Portable Fire Extinguishers Plants and Bioregenerative Life Support Metabolic Energy HUMANS Energy Requirements System Mass System Volume Crew Time System Reliability Habitation Module DSM Major Constituent Analyzer Constraints (“Economics”) of Life Support in Space: • • • • • JEM PM Laboratory Module Functional Cargo Module (FGB) Oxygen Generation Incidental Control Overboard leakage Absorption by humidity condensate Human respiration Dilution via atmosphere replenishment Carbon dioxide removal assembly Node 3 Nadir Metal Oxide ¾ Mir: Expendable and regenerable charcoal for volatile trace gas control and ambient temperature catalyst for CO control ¾ ISS U.S. Segment: Expendable charcoal for volatile trace gas control and high temperature catalytic oxidation for CO and methane control ¾ ISS Russian Segment: Same system used onboard Mir ¾ ¾ ¾ ¾ ¾ HTV Airlock Progress Module Active Control • MPLM Atmosphere and User Gas Bottles food (CH2O) + O2 CO2 + H2O Clean Water Waste Water These apply for all Life Support Technologies Light food (CH2O) + O2*+ H2O CO2 + 2H2O* Clean Water Waste Water PLANTS Testing with Plants and Algae for Life Support 1980 1960 Plants as a “Life Support Machines” 2000 US Air Force USSR Air Force Inst. for Biomedical Problems (Moscow) Inst. of Biophysics (Krasnoyarsk, Siberia) NASA NASA (CELSS) NASA (ALS) Natl. Aerospace Lab (Japan) Inst. Env. Sci. (IES) CEN, Cadarache, FR MELISSA / ESA Guelph / CSA University Studies (US, Europe, Japan, Canada) 3 NASA Testing with Plants for Life Support 1990 1980 2000 CELSS Program ALS Program Universities Wheat (Utah State) Gas / Ex (Utah State) Sweetpotato / Peanut (Tuskegee) Potato (Wisconsin) Soybean (NC State) New Jersey NSCORT N-Nutrition (UC Davis) Lettuce (Purdue) NASA Centers ARC Algae Closed Systems KSC Purdue NSCORT Large, Closed System NFT Lighting Joseph Priestley (1772) * • “…a sprig of mint in a glass jar continued growing for some months, I found that the air would neither extinguish a candle, nor was it at all inconvenient to a mouse” • “plants thrive particularly well in air made obnoxious by the exhalations of animals (and humans)” Salad Machine JSC Plants and Life Support: Some Background Waste Recycling Solid Media Pressure Human/Integration * Abstracted from E.I. Rabinowitch. 1945. Photosynthesis and Related Processes. Interscience Publ. Inc. NY. Early Bioregenerative Studies Focused on Algae and Cyanobacteria (1950s and 1960s) • Chlorella pyrenoidosa TX71105 (thermotolerant 39°C) • Other species of Chlorella, Anacystis, Synechocystis, Scenedesmus, Synechococcus, Spirulina were studied • Development of culture systems (chemostats, turbidostats) • Studies with animals (e.g., mice, monkeys) and humans • Interest in Assimilation and Respiration Quotients (AQ and RQ) ¾“…a general misconception in the scientific community is that success of the bioregenerative approach depends on development of a biologically and chemically closed ecology with complete material balance. While this may be the ultimate goal, few consider it possible if indeed necessary” (Miller and Ward, 1966) Photosynthesis in Space Observations from Algae Studies: • Positives – high photosynthetic efficiency – good volume efficiency – good energy efficiency--minimum wastage of light • Negatives – – – – – difficulties with food processing / palatability long-term, sustained production challenges gas / liquid phase issues for µ-gravity no transpiration advantage for water purification not convenient for point source lamps Bioregenerative Life Support for Space: Reviews of Work in 1950s and 1960s: • Eley, J.H. and J. Myers. 1963. A study of a photosynthetic gas exchanger. A quantitative repetition of the Priestley Experiment. Texas J. Sci. 16:296-333. • Miller, R.L. and C.H. Ward. 1966. Algal bioregenerative systems. In K. Kammermeyer (ed.) Atmosphere in Space Cabins and Closed Environments. Appleton-Century-Croft, NY. • Taub, F.B. 1974. Closed ecological systems. In: R.F. Johnston, P.W. Frank, and C.D. Michener (eds.) Annual review of Ecology and Systematics. 5; 139-160. C.H.Ward, S.S. Wilks, and H.L. Craft. 1970. Dev. Indust. Microbiol. 11:276-295 4
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