Handbook of Basic Atomic Spectroscopic Data
J. E. Sansonettia… and W. C. Martin
National Institute of Standards and Technology, Gaithersburg, Maryland 20899-0001
共Received 4 March 2004; revised manuscript received 30 April 2004; accepted 21 May 2004; published online 28 September 2005兲
© 2005 American Institute of Physics. 关DOI: 10.1063/1.1800011兴
Contents
1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.1. Atomic Data Tables. . . . . . . . . . . . . . . . . . . . . .
1.2. Strong Line Tables. . . . . . . . . . . . . . . . . . . . . .
1.2.1. Wavelengths. . . . . . . . . . . . . . . . . . . . . .
1.2.2. Intensities. . . . . . . . . . . . . . . . . . . . . . . .
1.3. Persistent Line Tables. . . . . . . . . . . . . . . . . . . .
1.3.1. Transition Probabilities. . . . . . . . . . . . .
1.3.2. Energy-Level Classifications. . . . . . . . .
1.4. Energy Level Tables. . . . . . . . . . . . . . . . . . . . .
1.5. Finding List. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.6. Acknowledgments. . . . . . . . . . . . . . . . . . . . . . .
1.7. References. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2. Data Tables for the Elements 共Ordered
Alphabetically兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Actinium 共Ac兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Aluminum 共Al兲. . . . . . . . . . . . . . . . . . . . . . . . .
Americium 共Am兲. . . . . . . . . . . . . . . . . . . . . . . .
Antimony 共Sb兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Argon 共Ar兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Arsenic 共As兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Astatine 共At兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Barium 共Ba兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Berkelium 共Bk兲. . . . . . . . . . . . . . . . . . . . . . . . .
Beryllium 共Be兲. . . . . . . . . . . . . . . . . . . . . . . . .
Bismuth 共Bi兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Boron 共B兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Bromine 共Br兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Cadmium 共Cd兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Calcium 共Ca兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Californium 共Cf兲. . . . . . . . . . . . . . . . . . . . . . . .
Carbon 共C兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cerium 共Ce兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cesium 共Cs兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Chlorine 共Cl兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Chromium 共Cr兲. . . . . . . . . . . . . . . . . . . . . . . . .
Cobalt 共Co兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Copper 共Cu兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Curium 共Cm兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Dysprosium 共Dy兲. . . . . . . . . . . . . . . . . . . . . . . .
Einsteinium 共Es兲. . . . . . . . . . . . . . . . . . . . . . . .
Erbium 共Er兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Europium 共Eu兲. . . . . . . . . . . . . . . . . . . . . . . . . .
1560
1560
1560
1560
1561
1561
1561
1562
1562
1562
1562
1562
1564
1564
1568
1573
1577
1582
1592
1595
1596
1600
1606
1609
1614
1617
1622
1625
1630
1634
1640
1652
1657
1664
1673
1679
1684
1691
1698
1702
1708
a兲
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© 2005 American Institute of Physics.
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1559
Fluorine 共F兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Francium 共Fr兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Gadolinium 共Gd兲. . . . . . . . . . . . . . . . . . . . . . . .
Gallium 共Ga兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Germanium 共Ge兲. . . . . . . . . . . . . . . . . . . . . . . .
Gold 共Au兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Hafnium 共Hf兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Helium 共He兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Holmium 共Ho兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Hydrogen 共H兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Indium 共In兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Iodine 共I兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Iridium 共Ir兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Iron 共Fe兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Krypton 共Kr兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Lanthanum 共La兲. . . . . . . . . . . . . . . . . . . . . . . . .
Lead 共Pb兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lithium 共Li兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lutetium 共Lu兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Magnesium 共Mg兲. . . . . . . . . . . . . . . . . . . . . . . .
Manganese 共Mn兲. . . . . . . . . . . . . . . . . . . . . . . .
Mercury 共Hg兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Molybdenum 共Mo兲. . . . . . . . . . . . . . . . . . . . . .
Neodymium 共Nd兲. . . . . . . . . . . . . . . . . . . . . . .
Neon 共Ne兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Neptunium 共Np兲. . . . . . . . . . . . . . . . . . . . . . . .
Nickel 共Ni兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Niobium 共Nb兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Nitrogen 共N兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Osmium 共Os兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Oxygen 共O兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Palladium 共Pd兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Phosphorus 共P兲. . . . . . . . . . . . . . . . . . . . . . . . .
Platinum 共Pt兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Plutonium 共Pu兲. . . . . . . . . . . . . . . . . . . . . . . . .
Polonium 共Po兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Potassium 共K兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Praseodymium 共Pr兲. . . . . . . . . . . . . . . . . . . . . .
Promethium 共Pm兲. . . . . . . . . . . . . . . . . . . . . . .
Protactinium 共Pa兲. . . . . . . . . . . . . . . . . . . . . . .
Radium 共Ra兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Radon 共Rn兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Rhenium 共Re兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Rhodium 共Rh兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Rubidium 共Rb兲. . . . . . . . . . . . . . . . . . . . . . . . .
Ruthenium 共Ru兲. . . . . . . . . . . . . . . . . . . . . . . . .
Samarium 共Sm兲. . . . . . . . . . . . . . . . . . . . . . . . .
Scandium 共Sc兲. . . . . . . . . . . . . . . . . . . . . . . . . .
1715
1720
1721
1731
1734
1739
1744
1750
1756
1763
1766
1771
1776
1782
1797
1805
1811
1816
1820
1825
1831
1836
1840
1847
1855
1867
1871
1878
1885
1891
1898
1904
1909
1915
1926
1932
1933
1937
1944
1951
1957
1960
1962
1968
1974
1978
1985
1992
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
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J. E. SANSONETTI AND W. C. MARTIN
Selenium 共Se兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Silicon 共Si兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Silver 共Ag兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Sodium 共Na兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Strontium 共Sr兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Sulfur 共S兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tantalum 共Ta兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Technetium 共Tc兲. . . . . . . . . . . . . . . . . . . . . . . .
Tellurium 共Te兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Terbium 共Tb兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Thallium 共Tl兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Thorium 共Th兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Thulium 共Tm兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Tin 共Sn兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Titanium 共Ti兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Tungsten 共W兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Uranium 共U兲. . . . . . . . . . . . . . . . . . . . . . . . . . .
Vanadium 共V兲. . . . . . . . . . . . . . . . . . . . . . . . . .
Xenon 共Xe兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ytterbium 共Yb兲. . . . . . . . . . . . . . . . . . . . . . . . .
Yttrium 共Y兲. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Zinc 共Zn兲. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Zirconium 共Zr兲. . . . . . . . . . . . . . . . . . . . . . . . .
3. References and Notes. . . . . . . . . . . . . . . . . . . . . . . .
4. Finding List. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5. Indices. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.1. Index by Atomic Number. . . . . . . . . . . . . . . . .
5.2. Index by Chemical Symbol. . . . . . . . . . . . . . .
1997
2001
2009
2013
2018
2022
2028
2035
2041
2046
2051
2054
2064
2071
2076
2086
2093
2101
2109
2118
2124
2130
2133
2141
2157
2258
2258
2259
Although we have made heavy use of previous compilations, our tables for the great majority of elements include at
least some data compiled by us from more recent original
literature and, in some cases, from unpublished material. Our
most extensive use of data from the original literature has
been for the heavier elements. Although the data are incomplete, our wavelength and energy level tables for these elements, especially, comprise a supplement to the ASD. For
example, the current version of the ASD includes energylevel data for only two spectra 共Mo I,II兲 of the 72 spectra of
the neutral and singly-ionized atoms of the elements Rb to
Ba (Z⫽37– 56) and Hf to Ra (Z⫽72– 88). No complete and
critical compilations of energy levels have appeared for most
of these spectra since Vols. 2 and 3 of Atomic Energy Levels
关M52, M58兴. For the actinide elements Ac–Es (Z
⫽89– 99), we were able to rely almost entirely on the very
complete compilation by Blaise and Wyart 关BW92b兴.
For some spectra, especially some of the lighter elements,
we have taken data from existing compilations that have
been superseded by data reported in more recent literature.
1.1. Atomic Data Tables
A small selection of nonspectroscopic atomic data has
been provided for each element. Included are the atomic
number and weight and a list of naturally occurring isotopes,
including the isotopic mass, the relative abundance, the
nuclear spin 共in units of h/2␲兲, and the magnetic moment 共in
units of nuclear magnetons兲. For elements with no naturally
occurring isotopes, the most commonly observed isotopes
are listed. These data are taken from J. Emsley 关E95兴.
1. Introduction
1.2. Strong Line Tables
This handbook is designed to provide a selection of the
most important and frequently used atomic spectroscopic
data in an easily accessible compact format. The compilation
includes data for the neutral and singly-ionized atoms of all
elements hydrogen through einsteinium (Z⫽1 – 99). The
wavelengths, intensities, and spectrum assignments are given
in a table for each element, and the data for the approximately 12 000 lines of all elements are also collected into a
single table, sorted by wavelength 共a ‘‘finding list’’兲.
More complete data for a smaller number of the most persistent lines of each spectrum are given in additional tables
for each element. In addition to the wavelengths and intensities, the energy levels and transitions probabilities 共where
available兲 are listed for a total of about 2400 lines in these
tables. We also give a separate table of energy level data for
each spectrum which, although incomplete, includes levels
additional to those involved in the persistent-line transitions.
More complete data than those selected for this Handbook
can usually be found in references given with the tables for
particular spectra. The data from most of the NIST compilations we have used are available online from the Atomic
Spectra Database 共ASD兲 共see 关MFKM99兴兲. In addition to
more extensive data for many of the spectra in this Handbook, the ASD has data for higher ionization stages of many
elements and includes the references.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
For each of the elements a list of the strongest lines in the
spectra of the neutral and singly-ionized atom has been compiled. This list includes the wavelength, the ionization stage,
the reference for the wavelength measurement, and an intensity. Unless otherwise noted, the spectroscopic data in this
Handbook pertain to the naturally occurring isotopic mix for
each element.
1.2.1. Wavelengths
The wavelengths for many spectra have been taken from
Reader et al., 关RCWM80兴. Wavelengths given to three decimal places in 关RCWM80兴 have a stated uncertainty of less
than 0.001, and many of the two-place wavelengths in
关RCWM80兴 are rounded off from three-place values in the
original literature.
Laboratory observations carried out since the publication
of 关RCWM80兴 have yielded improved wavelength data for
many spectra, including more accurate wavelengths, increased range of wavelength coverage, and more reliable assignments of observed lines to particular spectra. We have
used more recent data for many of the spectra. However, it is
important to note that our retention of wavelengths from
关RCWM80兴, for any particular spectrum does not imply that
more accurate data do not now exist.
ATOMIC SPECTROSCOPIC DATA
In compiling these data, we have in many cases departed
from the practice of 关RCWM80兴 by quoting wavelengths
from the literature without rounding off, especially in cases
where the literature values were given to three or fewer decimal places. The original references should be consulted for
uncertainty estimates.
1.2.2. Intensities
Unlike the other tabulated data, the relative intensities are
not basic data and must be used with caution. The relative
intensities of the spectral lines observed for any element depend upon the light source and excitation conditions. Thus,
even if the relative intensities observed in a particular experiment are adjusted to correct for the wavelength dependence
of the sensitivity of the spectrometer and detector, the intensities will in general be different from relative intensities
given by a previous observer or tabulated in a compilation
such as this one. With a caveat that users should keep these
considerations in mind, we list a relative intensity for each
line. For some lines the wavelengths are so close to another
that it was impossible to make two separate intensity measurements. For those lines the intensity of the blended line is
given for each and both intensities are marked with an asterisk.
For uniformity we have assigned an intensity of 1000 to
the strongest line共s兲 of each spectrum. In most cases the chosen line 共or lines兲 can reasonably be regarded as the ultimate
line 共Sec. IV兲. The relative intensities for most spectra here
are based on values from 关RCWM80兴. We have attempted to
give improved intensities for some spectra by using more
recent and apparently more accurate data than that available
to the compilers of 关RCWM80兴.
It should be noted that the intensities in 关RCWM80兴 for
lines of neutral and singly-ionized atoms of about half the
elements 共mainly nd- and nf-shell metals兲 were taken at least
in part from 关MCS75兴. These intensities were obtained from
observations of 10 A 220 V direct-current arc discharges between copper electrodes having 0.1% of the element under
investigation. The relative intensities were put on a linear
scale by the use of standardized lamps.
For several spectra we have altered some of the intensities
found in the literature to give smoother transitions between
wavelength regions covered by different observers. We have
also adjusted reported intensities given in a single reference
in some cases where the reported values were clearly affected by strong self-absorption and/or by large wavelengthdependent nonlinearities. Such adjustments were necessary
in order to assign the largest intensities to the inherently
strongest persistent lines 共usually the ultimate lines兲.
Lines we have selected as persistent 共Sec. IV兲 are indicated by the letter ‘‘P’’ following the intensity. For some
spectra, other descriptive codes have been included to characterize the line shape or give other related information.
They have the following meanings:
b—band head
c—complex
1561
d—line consists of two unresolved lines
h—hazy
l—shaded to longer wavelengths
P—a persistent line
r—easily reversed
s—shaded to shorter wavelengths
u—unresolved shoulder on strong line
w—wide
*—intensity may be affected by nearby line
In general, the character of a line depends on the spectroscopic source used, the resolution of the spectrometer, etc.
Most of the line characterizations in our tables are quoted
from 关RCWM80兴, so that the characters given for lines of
metallic elements usually pertain to the arc source used by
Meggers et al. 关MCS75兴 共see above兲. In some cases we have
given character notations from 关RCWM80兴 for lines for
which the tabulated wavelengths were obtained with a very
different 共low-pressure兲 source.
1.3. Persistent Line Tables
In spectroscopic observations made with low concentrations of a particular element relative to other substances in
the source, the number of observable lines of the element is
found to decrease with decreasing concentration until only
the most ‘‘persistent’’ or ‘‘sensitive’’ lines remain. Some authors refer to the last such line共s兲 as the raie共s兲 ultime, i.e.,
the ultimate line共s兲. Although the ultimate lines depend in
principle on the source, the spectrometer, and other features
of the experiment, a relatively small group of lines can be
specified for each element that will include the ultimate lines
as observed over a broad range of experimental conditions.
We designate our selection of these lines ‘‘persistent lines.’’
The strongest persistent lines usually include one or more
resonance lines, i.e., transitions to the ground level or term.
We include at least one of the resonance lines in our persistent line table for each spectrum. The most sensitive or ultimate lines for many spectra lie in the vacuum-ultraviolet
region (wavelength⬍2000 Å). In such cases we have tried
to include some lines above 2000 Å in the persistent lines
list. We have also tried to make these tables more generally
useful for many spectra by covering broader wavelength
ranges than most tables of this sort.
In addition to the information given in the strong lines
table, the list of persistent lines includes the energy levels
involved in the transition, complete with configuration, term
designations, and J values. Where available, the transition
probability is also given, along with the reference from
which it is taken.
1.3.1. Transition Probabilities
The values are listed as A ki in units of 108 s⫺1 . These A ki
values can easily be converted to oscillator strengths, f ik ,
g i f ik , or log(gi f ik), or line strength, S, using the following
formula:
g i f ik ⫽1.499⫻10⫺8 A ki ␭ 2 g k ⫽303.8␭ ⫺1 S,
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1562
J. E. SANSONETTI AND W. C. MARTIN
where i refers to the lower energy level, k refers to the upper
level, ␭ is the wavelength in Ångstroms, and g⫽2J⫹1 for a
given level.
The transition probability data are taken primarily from
three compilations and from references cited therein. The
NIST compilation 关FW96兴 contains transition probabilities
for about 9000 lines, covering most elements. Major recent
compilations by Morton for elements from H to Ga
关M91,M03兴 and from Ge to Bi 共plus Th and U兲 关M00兴 have
data for wavelengths longward of the Lyman limit 共911.754
Å兲, and include a number of useful new references.
1.3.2. Energy-Level Classifications
Data pertaining to the two levels classifying each line are
given with data for the lower level above that for the upper
level. Included are the level values, configurations, term
names, and J values for the levels classifying the line. The
energy-level classifications for a few persistent lines are not
known, as indicated by the absence of level values. The accuracies and spectroscopic designations of the levels are discussed in the next section.
1.4. Energy Level Tables
The tabulated energy levels represent a selection of the
available data for each spectrum, including all levels involved in the persistent-line classifications. At least the lower
levels of the ground configuration and other low-lying configurations are given. The levels of some of the simpler spectra are given complete up through the highest tabulated level,
but most of the known energy level structures of the more
complex spectra are omitted here. The ionization energies are
included except for a few spectra for which no reliable values are available. The reference for each level represents the
source of the level value.
Estimated uncertainties for the levels can usually be found
in the references. In our tables, the uncertainties are only
roughly indicated by the number of decimal places or significant figures in the values. The uncertainty corresponding to a
particular number of decimals may easily vary by an order of
magnitude, however, even within the data for one spectrum.
In most cases, the uncertainty is between 1 and ⬃30 units in
the last decimal place or significant figure, but still larger
errors can occur. The uncertainty in the relative position of
two levels having different uncertainties is at least as large as
the greater of the two level uncertainties. In this regard, it is
important to notice the number of decimals given for the
ground level; the uncertainties of the absolute values of the
excited levels and ionization energy are at least as large as
the indicated ground-level uncertainty.
The configuration and term notations are standard for
NIST compilations. Explanations of the notations for the different coupling schemes and of the arrangement of the data
can be found in 关MZH78兴, 关MW96兴 and online as a part of
the ‘‘Help’’ section of ASD 关MFKM99兴. Some levels of
complex spectra are given without term names, either because the level has not been interpreted theoretically or beJ. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
cause the calculated eigenvector for the level yields no
meaningful unique name. Some of these levels have been
assigned simple numerical designations under ‘‘Term.’’ The
parity of levels lacking designations is indicated by a degree
symbol in the ‘‘Term’’ column for odd-parity levels.
1.5. Finding List
This table gives the wavelength, intensity, spectrum, and
reference for each line in this compilation, listed in order of
increasing wavelength. Although this list has fewer lines than
the finding list of 关RCWM80兴 or 关MCS75兴, it includes some
lines not given in the earlier publications.
1.6. Acknowledgments
We wish to acknowledge the generous help of several
NIST colleagues. Shari Young, with much patience and persistence, assembled the database, including all the markup
language. Arlene Robey gave expert assistance with datahandling and bibliographic aspects of the work. The cooperation and helpfulness of Jonathan Baker, Svetlana Kotochigova, Peter Mohr, Victor Kaufman, Gillian Nave,
Joseph Reader, Craig Sansonetti, and Jack Sugar in supplying unpublished data are greatly appreciated. We thank Jeffrey Fuhr and Wolfgang Wiese for guidance in finding and
assessing transition-probability data. We also thank John
Rumble for his advocacy and advice about publication of this
work.
A number of colleagues from other laboratories have
kindly provided unpublished data or electronically readable
files of published data. We are very grateful to Vladimir Azarov, Jean Blaise, James Brault, Gordon Drake, Sveneric Johansson, Gabriele Kalus, Alexander Kramida, Ulf Litzen,
Donald Morton, Byron Palmer, Juliet Pickering, Alexander
Ryabtsev, Toshizo Shirai, and Ward Whaling for this help.
1.7. References
BW92b
E95
FW96
M91
M00
M03
J. Blaise and J.-F. Wyart, Energy Levels
and Atomic Spectra of Actinides, Int’l Tables
of Selected Constants 20 共Tables de Constantes,
Paris, 1992兲. Available: http//www.lac.
u-psud.fr/Database/Contents.html
J. Emsley, The Elements, Oxford Chemistry
Guides 共Oxford University Press, New York,
NY, 1995兲.
J. R. Fuhr and W. L. Wiese, NIST Atomic
Transition Probability Tables, CRC Handbook
of Chemistry and Physics, 77th ed., D. R. Lide,
ed. 共CRC Press, Boca Raton, FL, 1996兲.
D. C. Morton, Astrophys, J. Suppl. Ser. 77, 119
共1991兲.
D. C. Morton, Astrophys, J. Suppl. Ser. 130,
403 共2000兲.
D. C. Morton, Astrophys. J. Suppl. Ser. 149,
205 共2003兲.
ATOMIC SPECTROSCOPIC DATA
M52
M58
MCS75
MFKM99
MW96
C. E. Moore, Atomic Energy Levels, Natl. Bur.
Stand. 共U.S.兲 Circ. 467, Vol. II 共1952兲; reprinted
as Natl. Stand. Ref. Data Ser., Natl. Bur. Stand.
共U.S.兲 35 共1971兲.
C. E. Moore, Atomic Energy Levels, Natl. Bur.
Stand. 共U.S.兲 Circ. 467, Vol. III 共1958兲;
reprinted as Natl. Stand. Ref. Data Ser., Natl.
Bur. Stand. 共U.S.兲 35 共1971兲.
W. F. Meggers, C. H. Corliss, and B. F.
Scribner, Tables of Spectral-Line Intensities,
Natl. Bur. Stand. 共U.S.兲, Monogr. 145 共1975兲.
W. C. Martin, J. R. Fuhr, D. E. Kelleher, A.
Musgrove, J. Sugar, W. L. Wiese, P. J. Mohr,
and K. Olsen, NIST Atomic Spectra Database
共Version 2.0兲, 共1999兲 关Online兴. Available: http://
physics.nist.gov/asd. National Institute of
Standards and Technology, Gaithersburg, MD.
W. C. Martin and W. L. Wiese, Atomic
Spectroscopy, in Atomic Molecular, & Optical
Physics, G. W. F. Drake, ed. 共American Inst. of
Physics, Woodbury, New York, 1996兲, pp. 135–
153.
MZH78
RCWM80
1563
W. C. Martin, R. Zalubas, and L. Hagan, Atomic
Energy Levels—The Rare-Earth Elements, Nat.
Stand. Ref. Data Ser., Nat. Bur. Stand 共U.S.兲 60
共1978兲.
J. Reader, C. H. Corliss, W. L. Wiese, and G. A.
Martin,
Wavelengths
and
Transition
Probabilites for Atoms and Atomic Ions, Natl.
Stand. Ref. Data Ser., Natl. Bur. Stand. 共U.S.兲
68 共1980兲. Part I, Sec. 1 of these tables 共lines
arranged by element兲 are included with some
corrections and additions in J. Reader and C. H.
Corliss, Line Spectra of the Elements, CRC
Handbook of Chemistry and Physics, 77th ed.,
D. R. Lide, Ed. 共CRC Press, Boca Raton, FL,
1997兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1564
J. E. SANSONETTI AND W. C. MARTIN
2. Data Tables for the Elements „Ordered Alphabetically…
Actinium „Ac…
Atomic number⫽89
Atomic weight⫽(227)
Isotope
227
Ac
Ac
228
Mass
Abundance
Spin
Mag moment
227.027750
228.031015
Trace
Trace
3/2
3
⫺1.1
Ac I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 6d7s 2 2D3/2
Ionization energy: 41 700 cm⫺1 共5.17 eV兲
Ac II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 7s 2 1S0
Ionization energy: 94 800 cm⫺1 共11.75 eV兲
Strong Lines of Actinium 共Ac兲
Intensity
100
130
300
130
130
300
300
150
130
300
130
130
200
300
130
130
700
150
70
700
400
200
150
200
1000
700
1000
500
400
100
130
300
500
400
400
700
300
300
200
500
300
h
s
s
s
s
s
s
s
P,s
s
P,s
P
s
P,s
P,s
P
P
P
s
P,l
P,l
P
P
P,l
P
P
s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2847.16
2994.17
3043.30
3069.36
3112.83
3153.09
3154.41
3164.81
3230.59
3260.91
3383.53
3413.84
3417.77
3481.16
3489.53
3554.99
3565.59
3756.67
3799.82
3863.12
3885.56
4034.63
4061.60
4063.10
4088.44
4168.40
4179.98
4183.12
4194.40
4209.69
4359.13
4384.53
4386.41
4396.71
4462.73
4507.20
4605.45
4613.93
4705.78
4716.58
4720.16
Spectrum
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
II
II
I
I
I
II
II
I
II
I
I
II
II
I
I
I
II
Ref
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
ATOMIC SPECTROSCOPIC DATA
1565
Strong Lines of Actinium 共Ac兲—Continued
Intensity
200
300
200
70
130
300
200
30
100
300
200
300
200
Wavelength 共Å兲
Spectrum
4812.22
5258.24
5569.26
5732.05
5758.97
5910.85
6164.75
6167.83
6242.83
6359.86
6691.27
7290.40
7866.10
P
l
P
l
l
P
P,l
P
l
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ac
Ref
II
I
I
II
II
II
II
II
II
I
I
I
I
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
MFT57
Persistent Lines of Neutral Actinium 共Ac I兲
Inten
Wavelength 共Å兲
400
3885.56
1000
500
400
300
400
400
300
500
300
300
200
300
4179.98
4183.12
4194.40
4384.53
4396.71
4462.73
4613.93
4716.58
5258.24
6359.86
6691.27
7290.40
A ki (108 s⫺1 )
Configuration
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 1 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
6d7s 2
6d7s( 3 D)7p
Term
2
D
P
2 o
2
D
F
2 o
2
D
P
4 o
2
2
D
Do
2
D
P
4 o
2
D
F
2 o
2
D
P
4 o
2
D
P
4 o
2
4
D
Do
2
4
D
Do
2
2
D
Do
2
D
F
4 o
2
D
F
4 o
J
Level (cm⫺1 )
Wl Ref
3/2
1/2
0.00
25729.03
MFT57
3/2
5/2
0.00
23916.84
MFT57
3/2
5/2
0.00
23898.86
MFT57
5/2
3/2
2231.43
26066.04
MFT57
3/2
3/2
0.00
22801.10
MFT57
5/2
7/2
2231.43
24969.30
MFT57
3/2
1/2
0.00
22401.52
MFT57
5/2
5/2
2231.43
23898.86
MFT57
3/2
5/2
0.00
21195.87
MFT57
3/2
3/2
0.00
19012.46
MFT57
5/2
5/2
2231.43
17950.71
MFT57
3/2
5/2
0.00
14940.72
MFT57
3/2
3/2
0.00
13712.90
MFT57
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1566
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Actinium 共Ac I兲
Level (cm⫺1 )
J
Ref
Configuration
Term
6d7s 2
2
D
3/2
5/2
0.00
2231.43
MFT57
MFT57
6d 2 7s
4
F
3/2
5/2
7/2
9/2
9217.28
9863.59
10 906.02
12 078.07
MFT57
MFT57
MFT57
MFT57
6d7s( 3 D)7p
4 o
F
3/2
5/2
7/2
13 712.90
14 940.72
17 683.87
MFT57
MFT57
MFT57
6d7s( 3 D)7p
4
Do
1/2
3/2
5/2
7/2
17 199.71
19 012.46
21 195.87
23 475.94
MFT57
MFT57
MFT57
MFT57
6d7s( 3 D)7p
2
Do
3/2
5/2
17 736.26
17 950.71
MFT57
MFT57
6d7s( 3 D)7p
4 o
P
1/2
3/2
5/2
22 401.52
22 801.10
23 898.86
MFT57
MFT57
MFT57
6d7s( 3 D)7p
2 o
F
5/2
7/2
23 916.84
24 969.30
MFT57
MFT57
6d7s( 3 D)7p
2 o
P
1/2
3/2
25 729.03
27 009.84
MFT57
MFT57
6d7s( 1 D)7p
2
Do
3/2
5/2
26 066.04
26 533.16
MFT57
MFT57
6d7s( 1 D)7p
2 o
F
5/2
7/2
26 836.20
28 568.40
MFT57
MFT57
6d7s( 1 D)7p
2 o
P
3/2
30 396.61
MFT57
6d 2 ( 3 F)7p
4
Go
5/2
7/2
9/2
11/2
31 494.68
32 219.62
32 867.39
33 429.76
MFT57
MFT57
MFT57
MFT57
Limit
41700
S74
Ac II ( 1 S0 )
Persistent Lines of Singly-ionized Actinium 共Ac II兲
Inten
Wavelength 共Å兲
700
3565.59
700
1000
700
500
A ki (108 s⫺1 )
3863.12
4088.44
4168.40
4386.41
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
6d7s
6d7 p
3
D
Do
2
2
5267.16
33304.96
MFT57
6d7s
6d7 p
3
D
Do
3
2
7426.52
33304.96
MFT57
6d7s
6d7 p
3
D
Do
3
2
7426.52
31878.87
MFT57
1
6d7s
6d7 p
3
D
2
1
5267.16
29250.40
MFT57
6d7s
6d7 p
1
D
Do
2
2
9087.54
31878.87
MFT57
3
3
o
1
A Ref
ATOMIC SPECTROSCOPIC DATA
1567
Persistent Lines of Singly-ionized Actinium 共Ac II兲—Continued
Inten
Wavelength 共Å兲
700
300
A ki (108 s⫺1 )
Configuration
2
4507.20
7s
7s7p
5910.85
Term
J
Level (cm⫺1 )
Wl Ref
1
S
P
0
1
0.00
22180.52
MFT57
D
P
2
1
5267.16
22180.52
MFT57
3 o
3
6d7s
7s7p
3 o
A Ref
Energy Levels of Singly-ionized Actinium 共Ac II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
2
1
S
0
0.00
MFT57
6d7s
3
D
1
2
3
4739.63
5267.16
7426.52
MFT57
MFT57
MFT57
6d7s
1
D
2
9087.54
MFT57
6d 2
3
F
2
3
4
13236.46
14949.21
16756.90
MFT57
MFT57
MFT57
6d 2
3
P
0
1
2
17737.10
19015.32
22199.45
MFT57
MFT57
MFT57
6d 2
1
D
2
19203.02
MFT57
6d 2
1
G
4
20848.23
MFT57
7s7p
3 o
P
0
1
2
20956.40
22180.52
26446.96
MFT57
MFT57
MFT57
6d7 p
3 o
2
28201.11
MFT57
6d7 p
o
1
29250.40
MFT57
5 f 7s
1 o
3
29881.09
MFT57
6d7 p
o
3
31174.60
MFT57
6d7 p
1
Do
2
31878.87
MFT57
5 f 7s
3 o
F
4
32965.55
MFT57
6d7 p
3
Do
2
1
3
33304.96
33388.61
36144.35
MFT57
MFT57
MFT57
94800
MHRS74
7s
Ac III (7s 2 S1/2)
F
F
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1568
J. E. SANSONETTI AND W. C. MARTIN
Aluminum „Al…
Atomic number⫽13
Atomic weight⫽26.981 54
Isotope
27
Al
Mass
Abundance
Spin
Mag moment
26.981540
100%
5/2
⫹3.6415
Al I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 2P1/2
Ionization energy: 48 278.48 cm⫺1 共5.985 768 eV兲
Al II Ground state: 1s 2 2s 2 2p 6 3s 2 1S0
Ionization energy: 151 862.5 cm⫺1 共18.828 55 eV兲
Strong Lines of Aluminum 共Al兲
Intensity
800
1000
800
500
900
500
900
30
500
700
50
300
50
400
50
600
700
1000
700
700
40
50
90
25
50
600
40
50
500
800
200
400
400
500
1000
1000
600
400
400
400
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1539.830
1670.7886
1719.440
1721.244
1721.271
1724.952
1724.984
1762.899
1763.869
1763.952
1765.636
1765.815
1766.385
1767.731
1769.140
1828.588
1858.026
1862.311
1990.531
Air
2094.264
2269.096
2367.052
2373.124
2567.984
2575.094
2816.185
3050.073
3057.144
3082.153
3092.710
3092.839
3586.557
3900.675
3944.006
3961.520
4663.056
4666.800
5593.302
6006.410
6073.198
Spectrum
Ref
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
II
II
II
II
II
II
II
I
II
II
I
II
I
II
I
II
II
II
II
KM91b
GK00
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
II
I
I
I
I
I
II
I
I
I
I
I
II
II
I
I
II
II
II
II
II
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
ATOMIC SPECTROSCOPIC DATA
1569
Strong Lines of Aluminum 共Al兲—Continued
Intensity
Wavelength 共Å兲
400 h
400
400 P
400
40
30
40
50
50
60
60
50
30
6183.42
6201.463
6243.36
6335.701
6696.015
7836.134
8772.866
8773.896
11253.189
11254.926
13123.378
13150.708
16750.429
Spectrum
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
II
II
II
II
I
I
I
I
I
I
I
I
I
Ref
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
KM91b
Persistent Lines of Neutral Aluminum 共Al I兲
Inten
40
50
90
Wavelength 共Å兲
2269.096
2367.052
2373.124
A ki (108 s⫺1 )
0.691
0.628
0.748
Configuration
2 1
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3s ( S)3p
3s 2 ( 1 S)5d
2 o
P
D
3/2
5/2
112.061
44168.847
KM91b
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)4d
2 o
P
D
1/2
3/2
0.000
42233.742
KM91b
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)4d
2 o
P
D
3/2
5/2
112.061
42237.783
KM91b
M03
2
2
2
50
2575.094
0.226
3s 2 ( 1 S)3p
3s 2 ( 1 S)4d
2 o
P
y 2D
3/2
5/2
112.061
38933.968
KM91b
M03
500
3082.153
0.622
3s 2 ( 1 S)3p
3s 2 ( 1 S)3d
2 o
P
D
1/2
3/2
0.000
32435.453
KM91b
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)3d
2 o
P
D
3/2
5/2
112.061
32436.796
KM91b
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)3d
2 o
P
D
3/2
3/2
112.061
32435.453
KM91b
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)4s
2 o
P
S
1/2
1/2
0.000
25347.756
KM91b
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)4s
2 o
3/2
1/2
112.061
25347.756
KM91b
M03
800
200
500
1000
3092.710
3092.839
3944.006
3961.520
0.738
0.123
0.498
0.982
2
2
2
2
2
P
S
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1570
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Aluminum 共Al I兲
Configuration
2 1
Term
Level (cm⫺1 )
J
Ref
3s ( S)3p
2 o
P
1/2
3/2
0.000
112.061
3s 2 ( 1 S)4s
2
S
1/2
25347.756
MZ79
3s3p 2
4
P
1/2
3/2
5/2
29020.41
29066.96
29142.78
MZ79
MZ79
MZ79
3s 2 ( 1 S)3d
2
D
3/2
5/2
32435.453
32436.796
MZ79
MZ79
3s 2 ( 1 S)4p
2 o
P
1/2
3/2
32949.807
32965.639
MZ79
MZ79
3s 2 ( 1 S)5s
2
S
1/2
37689.407
MZ79
3s 2 ( 1 S)4d
y 2D
3/2
5/2
38929.413
38933.968
MZ79
MZ79
3s 2 ( 1 S)5p
2 o
P
1/2
3/2
40271.978
40277.883
MZ79
MZ79
3s 2 ( 1 S)4 f
2 o
F
5/2
7/2
41319.390
41319.398
MZ79
MZ79
3s 2 ( 1 S)6s
2
S
1/2
42144.411
MZ79
3s 2 ( 1 S)4d
2
D
3/2
5/2
42233.742
42237.783
MZ79
MZ79
3s 2 ( 1 S)6p
2 o
P
1/2
3/2
43335.024
43337.889
MZ79
MZ79
3s 2 ( 1 S)5 f
2 o
F
5/2
7/2
43831.101
43831.105
MZ79
MZ79
3s 2 ( 1 S)5g
2
G
7/2,9/2
43875.749
MZ79
3s 2 ( 1 S)5d
2
D
3/2
5/2
44166.398
44168.847
MZ79
MZ79
Limit
48278.48
KM91b
Al II ( 1 S0 )
MZ79
MZ79,BE99
Persistent Lines of Singly-ionized Aluminum 共Al II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
1 o
P
D
1
2
59852.02
124794.13
KM91b
FW96
1
S
P
0
1
0.00
59852.02
GK00
FW96
A Ref
800
1539.830
8.8
3s3 p
3s4d
1000
1670.7886
14.6
3s 2
3s3 p
800
1719.440
6.79
3s3p
3s3d
3 o
P
D
0
1
37393.03
95551.44
KM91b
FW96
900
1721.271
9.14
3s3 p
3s3d
3 o
P
D
1
2
37453.91
95550.51
KM91b
WSM69
900
1724.984
3s3 p
3s3d
3 o
2
3
37577.79
95549.42
KM91b
WSM69
12.1
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1
1 o
3
3
P
D
3
ATOMIC SPECTROSCOPIC DATA
1571
Persistent Lines of Singly-ionized Aluminum 共Al II兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
700
1763.952
9.8
3s3p
3p 2
3 o
P
P
2
2
37577.79
94268.68
KM91b
FW96
700
1858.026
2.48
3s3p
3s4s
3 o
P
S
1
1
37453.91
91274.50
KM91b
FW96
1000
1862.311
4.12
3s3p
3s4s
3 o
P
S
2
1
37577.79
91274.50
KM91b
FW96
600
2816.185
3.83
3s3p
3s4s
1 o
P
S
1
0
59852.02
95350.60
KM91b
FW96
1000
4663.056
0.53
3p 2
3s4 p
D
P
2
1
85481.35
106920.56
KM91b
FW96
400
6243.36
1.1
3s4 p
3s4d
3 o
2
3
105470.93
121483.50
KM91b
FW96
3
3
3
1
1
1 o
3
P
D
Energy Levels of Singly-ionized Aluminum 共Al II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
0.00
MZ79
3s3p
3 o
P
0
1
2
37393.03
37453.91
37577.79
MZ79
MZ79
MZ79
3s3 p
1 o
1
59852.02
MZ79
1
D
2
85481.35
MZ79
3s4s
3
S
1
91274.50
MZ79
3p 2
3
P
0
1
2
94084.96
94147.46
94268.68
MZ79
MZ79
MZ79
3s4s
1
S
0
95350.60
MZ79
3s3d
3
D
3
2
1
95549.42
95550.51
95551.44
MZ79
MZ79
MZ79
3s4p
3 o
P
0
1
2
105427.52
105441.50
105470.93
MZ79
MZ79
MZ79
3s4 p
1 o
P
1
106920.56
MZ79
3s3d
1
D
2
110089.83
MZ79
3p 2
1
S
0
111637.33
MZ79
3s5s
3
S
1
120092.919
MZ79
3s5s
1
S
0
121366.725
MZ79
3s4d
3
D
3
2
1
121483.50
121483.92
121484.252
MZ79
MZ79
MZ79
3s
2
3p
2
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1572
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Aluminum 共Al II兲—Continued
J
Level (cm⫺1 )
3s4 f
3 o
F
2
3
4
123418.48
123420.45
123423.36
MZ79
MZ79
MZ79
3s4 f
1 o
F
3
123470.5
MZ79
3s4d
1
D
2
124794.13
MZ79
Limit
151862.5
KM91b
Configuration
Term
Al III ( 2 S1/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1573
Americium „Am…
Atomic number⫽95
Atomic weight⫽(243)
Isotope
241
Am
Am
243
Mass
Abundance
Spin
Mag moment
241.056823
243.061375
0
0
5/2
5/2
⫹1.61
⫹1.61
o
Am I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 7 7s 2 8S7/2
⫺1
Ionization energy: 48 182 cm 共5.9738 eV兲
Am II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 7 7s 9So4
Ionization energy: not available
Strong Lines of Americium 共Am兲
Intensity
40
40
200
1000
200
40
40
200
40
40
100
200
200
200
100
200
100
100
40
400
40
100
40
10
100
20
40
20
200
1000
500
100
40
500
50
500
200
1000
1000
200
10
s
s
l
P,s
l
l
l
s
l
l
l
l
l
s
l
s
s
l
s
s
s
s
l
l
s
l
s
l
P,l
P
l
s
P
P
s
P,l
P,l
l
s
Wavelength 共Å兲
Air
2756.550
2812.920
2815.282
2832.258
2888.505
2899.562
2911.130
2920.593
2927.534
2936.992
2950.393
2966.712
2969.292
2987.238
2993.508
3004.250
3027.990
3038.363
3053.688
3120.486
3161.826
3282.320
3286.666
3343.867
3362.546
3395.010
3419.662
3446.186
3452.098
3483.308
3510.127
3530.948
3562.680
3569.163
3603.410
3673.121
3696.420
3777.504
3926.248
3952.576
4020.252
Spectrum
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
II
I
II
II
I
I
II
I
I
I
II
II
II
II
I
Ref
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1574
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Americium 共Am兲—Continued
Intensity
10
100
1000
10
200
100
500
40
400
400
1000
1000
200
10
10
500
200
400
100
400
20
10
200
40
100
100
200
100
1000
100
50
50
s
s
P,s
s
s
P
s
s
s
P,l
P,l
s
l
l
P,l
l
l
l
l
l
s
l
l
s
s
l
s
P,l
l
l
s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4035.808
4036.365
4089.291
4140.959
4188.121
4265.550
4289.258
4309.652
4324.570
4441.357
4509.450
4575.590
4593.307
4649.119
4653.448
4662.790
4681.651
4699.700
4706.802
4872.220
4990.786
5000.21
5020.96
5215.99
5402.62
5424.70
5584.21
5598.13
6054.64
6405.11
6544.16
6955.58
Spectrum
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
Am
I
II
II
I
II
I
I
II
II
II
II
II
II
I
I
I
I
II
I
II
I
I
II
II
I
I
II
I
I
I
I
I
Ref
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
FT57
ATOMIC SPECTROSCOPIC DATA
1575
Persistent Lines of Neutral Americium 共Am I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
7 8 o
J
Level (cm⫺1 )
8 o
Term
2
Wl Ref
500
3510.127
5 f ( S )7s
o
)7s7p( 1 P1 )
5 f 7 ( 8 S7/2
S
共7/2,1兲
7/2
9/2
0.00
28480.87
FT57
500
3569.163
5 f 7 ( 8 So)7s 2
o
)7s7p( 1 P1 )
5 f 7 ( 8 S7/2
8 o
S
共7/2,1兲
7/2
7/2
0.00
28009.81
FT57
500
3673.121
5 f 7 ( 8 So)7s 2
o
)7s7p( 1 P1 )
5 f 7 ( 8 S7/2
8 o
S
共7/2,1兲
7/2
5/2
0.00
27217.14
FT57
500
4289.258
5 f 7 ( 8 So)7s 2
8 o
S
7/2
9/2
0.00
23307.41
FT57
500
4662.790
5 f 7 ( 8 So)7s 2
o
)7s7p( 3 P2 )
5 f 7 ( 8 S7/2
8 o
S
共7/2,2兲
7/2
7/2
0.00
21440.37
FT57
1000
6054.638
5 f 7 ( 8 So)7s 2
o
)7s7p( 3 P1 )
5 f 7 ( 8 S7/2
8 o
7/2
9/2
0.00
16511.82
FT57
S
共7/2,1兲
A Ref
Energy Levels of Neutral Americium 共Am I兲
Configuration
7 8 o
J
Level (cm⫺1 )
Ref
8 o
7/2
0.00
BW92b
5 f 6 ( 7 F)6d7s 2
8
3/2
10683.57
BW92b
5 f 6 ( 7 F)6d7s 2
8
5/2
12974.03
BW92b
5 f 6 ( 7 F)6d7s 2
8
3/2
13292.51
BW92b
5/2
7/2
9/2
11/2
13/2
14506.92
14752.02
15136.02
15764.81
—
BW92b
BW92b
BW92b
BW92b
5 f ( S )7s
2
Term
S
7 8 o
H
H
D
5 f ( S )6d7s
10
5 f 6 ( 7 F)6d7s 2
8
G
1/2
14943.63
BW92b
5 f 7 ( 8 So)7s 2
6 o
7/2
15017.69
BW92b
8
7/2
15273.16
BW92b
o
)7s7p( 3 Po1 )
5 f 7 ( 8 S7/2
共7/2,1兲
9/2
16511.82
BW92b
o
5 f 7 ( 8 S7/2
)7s7p( 3 Po2 )
共7/2,2兲
7/2
21440.37
BW92b
9/2
23307.41
BW92b
5/2
7/2
9/2
27217.14
28009.81
28480.87
BW92b
BW92b
BW92b
48182
KDEE97
6 7
5 f ( F)6d7s
D
P
2
o
)7s7p( 1 Po1 )
5 f 7 ( 8 S7/2
Am II ( 9 So4 )
o
H
共7/2,1兲
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1576
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Americium 共Am II兲
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
2832.258
5 f 7 ( 8 So)7s
9 o
S
4
5
0.00
35297.13
FT57
1000
3483.308
5 f 7 ( 8 So)7s
7 o
S
3
4
2598.32
31298.50
FT57
1000
3777.504
5 f 7 ( 8 So)7s
7 o
S
3
3
2598.32
29063.30
FT57
1000
3926.248
5 f 7 ( 8 So)7s
7 o
S
3
4
2598.32
28060.74
FT57
1000
4089.291
5 f 7 ( 8 So)7s
9 o
S
4
4
0.00
24447.22
FT57
1000
4509.450
5 f 7 ( 8 So)7s
7 o
S
3
4
2598.32
24767.76
FT57
1000
4575.590
5 f 7 ( 8 So)7s
7 o
3
4
2598.32
24447.22
FT57
Inten
Wavelength 共Å兲
1000
A ki (108 s⫺1 )
S
A Ref
Energy Levels of Singly-ionized Americium 共Am II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
5 f 7 ( 8 So)7s
9 o
S
4
0.00
BW92b
7 8 o
5 f ( S )7s
7 o
S
3
2598.32
BW92b
5 f 7 ( 8 So)6d
9
Do
2,3
14222.21
BW92b
5 f 7 ( 8 So)6d
9
Do
3,4
14479.56
BW92b
5 f 7 ( 8 So)6d
9
Do
4,5
14905.50
BW92b
4
24447.22
BW92b
4
24767.76
BW92b
4
28060.74
BW92b
3
29063.30
BW92b
4
31298.50
BW92b
5
35297.13
BW92b
o
)
Am III ( 8 S7/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1577
Antimony „Sb…
Atomic number⫽51
Atomic weight⫽121.75
Isotope
121
Sb
Sb
123
Mass
Abundance
Spin
Mag moment
120.903821
122.904216
57.3%
42.7%
5/2
7/2
⫹3.3592
⫹2.5466
o
Sb I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 3 4S3/2
⫺1
Ionization energy: 69 431.34 cm 共8.608 39 eV兲
Sb II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 2 3P0
Ionization energy: 134 100 cm⫺1 共16.63 eV兲
Strong Lines of Antimony 共Sb兲
Intensity
800
800
800
600
800
1000
600
800
800
800
800
800
900
800
1000
700
400
200
300
30
60
100
400
20
40
40
100
600
100
120
120
120
1000
150
120
150
150
800
600
P
P
P
P
P
P
P
P,r
r
r
P,r
P,r
r
P,r
P,r
P,r
P,r
P,r
r
r
P,r
h
h
r
P,r
P,r
Wavelength 共Å兲
Vacuum
1274.938
1327.378
1354.955
1358.009
1384.656
1387.565
1407.784
1436.447
1498.549
1513.255
1524.367
1565.501
1576.099
1581.353
1606.952
1814.964
1871.154
1882.568
1950.393
Air
2039.792
2049.577
2054.734
2068.344
2098.424
2139.698
2144.841
2170.855
2175.818
2179.190
2208.430
2262.483
2306.507
2311.463
2373.631
2383.616
2445.502
2478.316
2528.509
2598.048
Spectrum
Ref
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
AJK89
SM02
SM02
SM02
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
I
I
II
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
SM02
SM02
AJK89
SM02
SM02
SM02
SM02
AJK89
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1578
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Antimony 共Sb兲—Continued
Wavelength 共Å兲
Intensity
200
120
120
150
400
200
250
300
200
400
200
500
200
300
150
150
120
400
300
250
150
120
60
12
r
r
r
r
P,r
r
P,r
P,r
Spectrum
2598.084
2612.304
2670.630
2769.931
2877.913
3029.809
3232.495
3267.491
4711.68
5568.12
5639.77
6005.57
6079.67
6130.00
9518.68
9949.14
10260.849
10677.246
10741.898
10839.571
10879.698
11012.728
11266.082
11863.229
P
P
P
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Ref
I
I
I
I
I
I
I
I
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
C66b
C66b
C66b
C66b
C66b
C66b
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
SM02
Persistent Lines of Neutral Antimony 共Sb I兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
S
P
3/2
5/2
0.000
53442.967
SM02
Do
F
3/2
5/2
8512.125
57287.052
SM02
4 o
S
P
3/2
5/2
0.000
48332.424
SM02
GL80
Do
D
3/2
3/2
8512.125
55232.963
SM02
GL80
Do
F
3/2
5/2
8512.125
55120.943
SM02
4 o
S
P
3/2
3/2
0.000
45945.340
SM02
GL80
Do
D
5/2
5/2
9854.018
55728.264
SM02
GL80
Do
F
5/2
5/2
9854.018
55120.943
SM02
4 o
S
P
3/2
1/2
0.000
43249.337
SM02
GL80
Do
P
5/2
3/2
9854.018
49391.133
SM02
GL80
Inten
Wavelength 共Å兲
400
1871.154
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)5d
4
60
2049.577
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)5d
2
400
2068.344
1.81
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
4
40
2139.698
1.74
5s 2 5 p 3
5s 2 5 p 2 ( 1 D)6s
2
40
2144.841
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)5d
4
600
2175.818
1.75
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
4
100
2179.190
2.39
5s 2 5 p 3
5s 2 5 p 2 ( 1 D)6s
2
120
2208.430
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)5d
4
1000
2311.463
1.69
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
4
800
2528.509
1.77
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
Term
4 o
2
2
2
2
2
2
A Ref
ATOMIC SPECTROSCOPIC DATA
1579
Persistent Lines of Neutral Antimony 共Sb I兲—Continued
Wavelength 共Å兲
Inten
600
A ki (108 s⫺1 )
2598.048
400
0.210
2877.913
250
0.424
3232.495
300
0.307
3267.491
0.495
Configuration
2
3
5s 5 p
5s 2 5 p 2 ( 3 P)6s
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
5s 2 5 p 3
5s 2 5 p 2 ( 3 P)6s
J
Level (cm⫺1 )
Wl Ref
A Ref
o
D
P
3/2
1/2
8512.125
46991.058
SM02
GL80
Do
P
3/2
1/2
8512.125
43249.337
SM02
GL80
2 o
P
P
3/2
3/2
18464.202
49391.133
SM02
GL80
2 o
1/2
1/2
16395.359
46991.058
SM02
GL80
Term
2
2
2
4
2
2
P
P
Energy Levels of Neutral Antimony 共Sb I兲
Ref
Term
5s 2 5p 3
4 o
3/2
0.000
HARV88
2
o
D
3/2
5/2
8512.125
9854.018
HARV88
HARV88
5s 2 5p 3
2 o
P
1/2
3/2
16395.359
18464.202
HARV88
HARV88
5s 2 5p 2 ( 3 P)6s
4
P
1/2
3/2
5/2
43249.337
45945.340
48332.424
HARV88
HARV88
HARV88
5s 2 5p 2 ( 3 P)6s
2
P
1/2
3/2
46991.058
49391.133
HARV88
HARV88
5s 2 5p 2 ( 3 P)5d
4
P
5/2
3/2
1/2
53442.967
56151.802
56698.608
HARV88
HARV88
HARV88
5s 2 5p 2 ( 3 P)5d
4
F
3/2
5/2
7/2
53527.956
55120.943
56528.132
HARV88
HARV88
HARV88
5s 2 5p 2 ( 1 D)6s
2
D
3/2
5/2
55232.963
55728.264
HARV88
HARV88
5s 2 5p 2 ( 3 P)5d
2
F
5/2
7/2
57287.052
61125.741
HARV88
HARV88
5s 2 5p 2 ( 1 S)6s
2
S
1/2
65654.41
HARV88
Limit
69431.34
BW86
2
5s 5p
3
Sb II ( 3 P0 )
S
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1580
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Antimony 共Sb II兲
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
1274.938
5s 2 5 p 2
5s 2 5 p5d
1
D
F
2
3
12789.8
91225.0
AJK89
800
1327.378
5s 2 5 p 2
5s5 p 3
P
P
1
2
3054.6
78390.9
AJK89
800
1384.656
P
P
1
2
3054.6
75274.5
AJK89
1000
1387.565
P
F
2
3
5658.2
77726.9
AJK89
800
1436.447
P
P
2
2
5658.2
75274.5
AJK89
800
1576.099
5s 2 5 p 2
5s5 p 3
3
P
Do
1
2
3054.6
66502.3
AJK89
1000
1606.952
5s 2 5 p 2
5s5 p 3
3
P
Do
2
3
5658.2
67887.5
AJK89
400
5568.12
5s 2 5 p6s
5s 2 5 p6 p
1 o
P
D
1
2
75898.9
93853.2
C66b
500
6005.57
5s 2 5 p6s
5s 2 5 p6 p
3 o
P
D
1
2
69535.7
86183.6
C66b
300
6130.00
5s 2 5 p6s
5s 2 5 p6 p
3 o
2
3
75274.5
91583.2
C66b
Inten
Wavelength 共Å兲
800
A ki (108 s⫺1 )
1.1
5.2
1 o
3
3 o
5s 2 5 p 2
5s 2 5 p6s
3
5s 2 5 p 2
5s 2 5 p5d
3
5s 2 5 p 2
5s 2 5 p6s
3
3 o
3 o
3 o
3
3
1
3
3
P
D
A Ref
M00
M00
Energy Levels of Singly-ionized Antimony 共Sb II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5s 2 5p 2
3
0
1
2
0.0
3054.6
5658.2
AJK89
AJK89
AJK89
5s 2 5p 2
1
2
12789.8
AJK89
5s 2 5p 2
1
S
0
23905.5
AJK89
5s5p 3
5 o
S
2
51722.9
AJK89
5s5p 3
3
Do
1
2
3
66291.6
66502.3
67887.5
AJK89
AJK89
AJK89
5s 2 5p6s
3 o
P
0
1
2
69137.3
69535.7
75274.5
AJK89
AJK89
AJK89
5s 2 5p5d
1
Do
2
72389.7
AJK89
5s 2 5p6s
1 o
P
1
75898.9
AJK89
3 o
2
3
4
76691.8
77726.9
81083.0
AJK89
AJK89
AJK89
2
5s 5p5d
P
D
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1581
Energy Levels of Singly-ionized Antimony 共Sb II兲—Continued
J
Level (cm⫺1 )
Ref
3 o
P
0
1
2
76857.8
77139.4
78390.9
AJK89
AJK89
AJK89
5s 2 5p6p
3
D
1
2
3
83826.4
86183.6
91583.2
C66b
C66b
C66b
5s 2 5p5d
3
Do
1
2
3
85094.1
86027.3
88259.7
AJK89
AJK89
AJK89
5s 2 5p5d
1 o
F
3
91225.0
AJK89
5s 2 5p6p
1
D
2
93853.2
C66b
Configuration
5s5 p
3
o
)
Sb III ( 2 P1/2
Term
Limit
134100
C66b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1582
J. E. SANSONETTI AND W. C. MARTIN
Argon „Ar…
Atomic number⫽18
Atomic weight⫽39.948
Isotope
36
Ar
Ar
40
Ar
38
Mass
Abundance
Spin
35.967545
37.962732
39.962384
0.337%
0.063%
99.600%
0
0
0
Mag moment
Ar I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 1S0
Ionization energy: 127 109.842 cm⫺1 共15.759 610 eV兲
o
Ar II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 5 2P3/2
⫺1
Ionization energy: 222 848.3 cm 共27.629 66 eV兲
Strong Lines of Argon 共Ar兲
Intensity
10
15
10
10
10
70
25
25
25
10
25
10
25
10
10
150
10
70
300
1000
25
10
10
70
70
1000
150
25
70
70
25
20
100
60
30
40
50
120
70
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
487.2272
490.6495
490.7013
519.3270
542.9124
543.2033
547.4606
556.8170
573.3619
576.7364
580.2632
583.4371
597.7001
602.8584
612.3716
661.8690
664.5623
666.0109
670.9455
671.8513
676.2425
677.9518
679.2184
679.4006
718.0899
723.3606
725.5485
730.9297
740.2692
744.9248
745.3223
802.85896
806.4710
806.86887
807.21842
807.6529
809.92660
816.23193
816.46391
Spectrum
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
Ref
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M71
M73
M73
M73
M73
M73
M73
M73
M73
ATOMIC SPECTROSCOPIC DATA
1583
Strong Lines of Argon 共Ar兲—Continued
Intensity
80
120
120
150
100
100
180 P
150 P
180P
180 P
150 P
300 P
300 P
1000 P
500 P
2
3
3
5
8
70
30
15
15
7
8
7
8
8
8
25
7
15
30
25
25
25
25
30
30
25
8
15
25
8
7
12
25
15
50
15
1
7
Wavelength 共Å兲
820.12352
825.34592
826.36484
834.3918
835.00210
842.80506
866.79997
869.75411
876.05767
879.94656
894.31013
919.7810
932.0537
1048.21987
1066.65980
Air
2420.456
2516.789
2534.709
2562.087
2891.612
2942.893
2979.050
3033.508
3093.402
3243.689
3293.640
3307.228
3350.924
3376.436
3388.531
3476.747
3478.232
3491.244
3491.536
3509.778
3514.388
3545.596
3545.845
3559.508
3561.030
3576.616
3581.608
3582.355
3588.441
3622.138
3639.833
3718.206
3729.309
3737.889
3765.270
3766.119
3770.369
3770.520
Spectrum
Ref
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
M73
M73
M73
M73
M73
M73
M73
M73
M73
M73
M73
M71
M71
VHU99
M73
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1584
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Argon 共Ar兲—Continued
Intensity
Wavelength 共Å兲
8
8
15
25
12
12
15
8
25
1
7
12
15
15
7
50
1
30
70
25
8
12
8
50
100
12
11
1
12
1
3
1
6
11
8
8
8
30
30
1
6
3
25
4
200 P
7
3
8
25
70
15
3
1
1
3780.840
3803.172
3809.456
3850.581
3868.528
3925.719
3928.623
3932.547
3946.097
3948.979
3979.356
3994.792
4013.857
4033.809
4035.460
4042.894
4044.418
4052.921
4072.005
4072.385
4076.628
4079.574
4082.387
4103.912
4131.724
4156.086
4158.590
4164.180
4179.297
4181.884
4190.713
4191.029
4198.317
4200.674
4218.665
4222.637
4226.988
4228.158
4237.220
4251.185
4259.362
4266.286
4266.527
4272.169
4277.528
4282.898
4300.101
4300.650
4309.239
4331.200
4332.030
4333.561
4335.338
4345.168
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
I
II
I
I
I
I
I
II
II
II
II
II
I
I
I
II
I
II
II
I
II
II
II
II
I
I
I
Ref
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
ATOMIC SPECTROSCOPIC DATA
1585
Strong Lines of Argon 共Ar兲—Continued
Intensity
250
15
8
15
70
25
15
50
15
25
70
130
50
15
15
7
12
30
70
3
1
7
130
7
130
130
200
12
130
7
200
15
100
250
200
50
15
250
25
7
12
70
15
25
25
7
30
25
8
1
7
1
1
1
P
P
P
P
P
P
Wavelength 共Å兲
4348.064
4352.205
4362.066
4367.832
4370.753
4371.329
4375.954
4379.667
4385.057
4400.097
4400.986
4426.001
4430.189
4430.996
4433.838
4439.461
4448.879
4474.759
4481.811
4510.733
4522.323
4530.552
4545.052
4564.405
4579.350
4589.898
4609.567
4637.233
4657.901
4721.591
4726.868
4732.053
4735.906
4764.865
4806.020
4847.810
4865.910
4879.864
4889.042
4904.752
4933.209
4965.080
5009.334
5017.163
5062.037
5090.495
5141.783
5145.308
5165.773
5187.746
5216.814
5495.874
5558.702
5606.733
Spectrum
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
I
I
Ref
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1586
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Argon 共Ar兲—Continued
Intensity
1
1
1
2
1
1
30
50
8
1
2
8
8
7
15
8
3
12
4
7
4
1
300
4
300
3
1
1
30
2
60
1
1
2
6
7
300
1
1
600
400
700
400
300
600
600
700
600
1000
300
1
400
600
400
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5650.704
5888.584
5912.085
6032.127
6043.223
6059.372
6114.923
6172.278
6243.120
6384.717
6416.307
6483.082
6638.221
6639.740
6643.698
6666.359
6677.282
6684.293
6752.834
6861.269
6871.289
6937.664
6965.431
7030.251
7067.218
7068.736
7107.478
7125.820
7147.042
7206.980
7272.936
7311.716
7316.005
7353.293
7372.118
7380.426
7383.980
7392.980
7435.368
7503.869
7514.652
7635.106
7723.761
7724.207
7948.176
8006.157
8014.786
8103.693
8115.311
8264.522
8392.27
8408.210
8424.648
8521.442
Spectrum
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
I
I
I
I
I
I
II
II
II
I
I
II
II
II
II
II
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
M73
N73
N73
N73
ATOMIC SPECTROSCOPIC DATA
1587
Strong Lines of Argon 共Ar兲—Continued
Intensity
130
7
5
1
1000 P
15
400
11
50
700 P
130
5
1
30
50
5
6
2
1
1
2
1
11
6
6
1
1
6
6
3
6
4
1
6
1
14
6
6
6
3
14
30
30
1
30
1
11
6
30
6
3
1
1
1
Wavelength 共Å兲
8667.944
8771.860
8849.91
9075.394
9122.967
9194.638
9224.499
9291.531
9354.220
9657.786
9784.503
10052.06
10332.72
10467.177
10470.054
10506.50
10673.565
10683.034
10733.87
10759.16
10812.896
11106.46
11488.109
11668.710
12112.326
12139.738
12343.393
12402.827
12439.321
12456.12
12487.663
12702.281
12733.418
12802.739
12933.195
12956.659
13008.264
13213.99
13228.107
13230.90
13272.64
13313.210
13367.111
13499.41
13504.191
13599.333
13622.659
13678.550
13718.577
14093.640
15046.50
15172.69
15989.49
16519.86
Spectrum
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
I
II
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
N73
N73
M73
N73
N73
N73
N73
N73
N73
N73
N73
M73
M73
N73
N73
M73
N73
N73
M73
M73
N73
M73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
N73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1588
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Argon 共Ar兲—Continued
Intensity
Wavelength 共Å兲
14
1
1
1
1
16940.58
20616.23
20986.11
23133.20
23966.52
Spectrum
Ar
Ar
Ar
Ar
Ar
Ref
I
I
I
I
I
N73
N73
N73
N73
N73
Persistent Lines of Neutral Argon 共Ar I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
180
866.79997
3.14
3p
o
)3d
3p 5 ( 2 P1/2
1
150
869.75411
0.35
3p 6
o
)5s
3p 5 ( 2 P1/2
1
180
876.05767
2.69
3p 6
o
)3d
3p 5 ( 2 P1/2
1
180
879.94656
0.77
3p 6
o
)5s
3p 5 ( 2 P1/2
1
150
894.31013
3p 6
o
)3d
3p 5 ( 2 P3/2
1
1000
1048.21987
5.32
3p 6
o
)4s
3p 5 ( 2 P1/2
1
500
1066.65980
1.32
3p 6
o
)4s
3p 5 ( 2 P3/2
1
300
6965.431
0.067
o
)4s
3 p 5 ( 2 P3/2
o
3p 5 ( 2 P1/2
)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P1/2)4p
2
o
)4s
3 p 5 ( 2 P1/2
o
3p 5 ( 2 P1/2
)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
o
)4s
3 p 5 ( 2 P1/2
5 2 o
3p ( P1/2)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
o
)4s
3 p 5 ( 2 P3/2
5 2 o
3p ( P3/2)4p
2
300
600
700
600
600
700
600
1000
1000
700
7067.218
7503.869
7635.106
7948.176
8006.157
8014.786
8103.693
8115.311
9122.967
9657.786
0.0395
0.472
0.274
0.196
0.0490
0.0928
0.25
0.331
0.189
0.0543
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
6
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Term
J
Level (cm⫺1 )
Wl Ref
S
关 3/2兴 o
0
1
0.000
115366.871
M73
VVF96
S
关 1/2兴 o
0
1
0.000
114975.024
M73
VVF96
S
关 3/2兴 o
0
1
0.000
114147.737
M73
VVF96
S
关 3/2兴 o
0
1
0.000
113643.265
M73
VVF96
S
关 1/2兴 o
0
1
0.000
111818.033
M73
S
关 1/2兴 o
0
1
0.000
95399.8329
VHU99
M03
S
关 3/2兴 o
0
1
0.000
93750.6031
M73
M03
关 3/2兴 o
关 1/2兴
2
1
93143.7653
107496.4219
N73
RCWM80
关 3/2兴 o
关 3/2兴
2
2
93143.7653
107289.7054
N73
RCWM80
关 1/2兴 o
关 1/2兴
1
0
95399.8329
108722.6247
N73
RCWM80
关 3/2兴 o
关 3/2兴
2
2
93143.7653
106237.5571
N73
RCWM80
关 1/2兴 o
关 3/2兴
0
1
94553.6705
107131.7139
N73
RCWM80
关 3/2兴 o
关 3/2兴
1
2
93750.6031
106237.5571
N73
FW96
关 3/2兴 o
关 5/2兴
2
2
93143.7653
105617.2753
N73
FW96
关 3/2兴 o
关 3/2兴
1
1
93750.6031
106087.2651
N73
FW96
关 3/2兴 o
关 5/2兴
2
3
93143.7653
105462.7649
N73
FW96
关 3/2兴 o
关 1/2兴
2
1
93143.7653
104102.1043
N73
FW96
关 3/2兴 o
关 1/2兴
1
1
93750.6031
104102.1043
N73
FW96
A Ref
ATOMIC SPECTROSCOPIC DATA
1589
Energy Levels of Neutral Argon 共Ar I兲
Configuration
3p
6
Term
J
S
0
1
Level (cm⫺1 )
0.000
Ref
VHU99
o
)4s
3p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
93143.7653
93750.6031
M73
M73
o
)4s
3 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
94553.6705
95399.8329
M73
VHU99
o
)4p
3 p 5 ( 2 P3/2
2
关 1/2兴
1
0
104102.1043
107054.2773
M73
M73
o
)4p
3 p 5 ( 2 P3/2
2
关 5/2兴
3
2
105462.7649
105617.2753
M73
M73
o
)4p
3 p 5 ( 2 P3/2
2
关 3/2兴
1
2
106087.2651
106237.5571
M73
M73
o
)4p
3 p 5 ( 2 P1/2
2
关 3/2兴
1
2
107131.7139
107289.7054
M73
M73
o
)4p
3 p 5 ( 2 P1/2
2
关 1/2兴
1
0
107496.4219
108722.6247
M73
M73
o
)3d
3 p 5 ( 2 P3/2
2
关 1/2兴 o
0
1
111667.771
111818.033
M73
M73
o
)3d
3 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
112138.929
114147.737
M73
M73
o
)3d
3 p 5 ( 2 P3/2
2
关 7/2兴 o
4
3
112750.158
113020.360
M73
M73
o
)3d
3 p 5 ( 2 P3/2
2
关 5/2兴 o
2
3
113425.969
113716.560
M73
M73
o
)5s
3 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
113468.478
113643.265
M73
M73
o
)3d
3 p 5 ( 2 P1/2
2
关 5/2兴 o
2
3
114640.997
114821.944
M73
M73
o
)3d
3 p 5 ( 2 P1/2
2
关 3/2兴 o
2
1
114805.140
115366.871
M73
M73
o
)5s
3 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
114861.640
114975.024
M73
M73
Limit
127109.842
VHU99
o
)
Ar II ( 2 P3/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1590
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Argon 共Ar II兲
Inten
150
300
1000
1000
300
300
200
250
200
200
250
200
250
Wavelength 共Å兲
661.8690
670.9455
671.8513
723.3606
919.7810
932.0537
4277.528
4348.064
4609.567
4726.868
4764.865
4806.020
4879.864
A ki (108 s⫺1 )
8.05
6.43
7.90
23.1
1.43
0.700
0.80
1.17
0.789
0.588
0.64
0.780
0.823
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
2
5
3s 3 p
3s 2 3 p 4 ( 3 P)3d
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)3d
3s 2 3 p 5
3s 2 3 p 4 ( 1 D)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s3 p 6
3s 2 3 p 5
3s3 p 6
J
Level (cm⫺1 )
Wl Ref
A Ref
P
D
3/2
5/2
0.0000
151087.3128
M71
VVF96
2 o
P
D
1/2
3/2
1431.5831
150474.9900
M71
VVF96
2 o
P
D
3/2
5/2
0.0000
148842.4674
M71
VVF96
2 o
P
P
3/2
3/2
0.0000
138243.6442
M71
VVF96
2 o
P
S
3/2
1/2
0.0000
108721.53
M71
M03
2 o
P
S
1/2
1/2
1431.5831
108721.53
M71
M03
D
P
5/2
3/2
148842.4674
172213.8800
N73
FW96
P
Do
5/2
7/2
134241.7392
157234.0200
N73
FW96
D
F
5/2
7/2
148842.4674
170530.4041
N73
FW96
P
Do
3/2
3/2
138243.6442
159393.3850
N73
FW96
P
P
1/2
3/2
139258.3384
160239.4280
N73
FW96
P
P
5/2
5/2
134241.7392
155043.1622
N73
FW96
P
Do
3/2
5/2
138243.6442
158730.2997
N73
FW96
Term
2 o
2
2
2
2
2
2
3s 2 3 p 4 ( 1 D)4s
3s 2 3 p 4 ( 1 D)4p
2
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 1 D)4s
3s 2 3 p 4 ( 1 D)4p
2
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
2
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
2
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
2
2 o
4
2 o
2
2 o
4 o
2
ATOMIC SPECTROSCOPIC DATA
1591
Energy Levels of Singly-ionized Argon 共Ar II兲
Configuration
2
J
Level (cm⫺1 )
Ref
2 o
3/2
1/2
3s3 p 6
2
S
1/2
108721.53
M71
3s 2 3p 4 ( 3 P)3d
4
D
7/2
5/2
3/2
1/2
132327.3621
132481.2071
132630.7281
132737.7041
WACB95
WACB95
WACB95
WACB95
3s 2 3p 4 ( 3 P)4s
4
P
5/2
3/2
1/2
134241.7392
135085.9960
135601.7336
WACB95
M71
WACB95
3s 2 3p 4 ( 3 P)4s
2
P
3/2
1/2
138243.6442
139258.3384
WACB95
WACB95
3s 2 3p 4 ( 3 P)3d
4
F
9/2
7/2
5/2
3/2
142186.3157
142717.0967
143107.6804
143371.4365
WACB95
WACB95
WACB95
WACB95
3s 2 3p 4 ( 1 D)4s
2
D
3/2
5/2
148620.1411
148842.4674
WACB95
WACB95
3s 2 3p 4 ( 3 P)3d
2
D
3/2
5/2
150474.9900
151087.3128
WACB95
WACB95
3s 2 3p 4 ( 3 P)4p
4 o
P
5/2
3/2
1/2
155043.1622
155351.1209
155708.1080
WACB95
WACB95
WACB95
3s 2 3p 4 ( 3 P)4p
4
Do
7/2
5/2
3/2
1/2
157234.0200
157673.4136
158167.8003
158428.1087
WACB95
WACB95
WACB95
WACB95
3s 2 3p 4 ( 3 P)4p
2
Do
5/2
3/2
158730.2997
159393.3850
WACB95
WACB95
3s 2 3p 4 ( 3 P)4p
2 o
P
1/2
3/2
159706.5334
160239.4280
WACB95
WACB95
3s 2 3p 4 ( 1 D)4p
2 o
F
5/2
7/2
170401.0168
170530.4041
WACB95
WACB95
3s 2 3p 4 ( 1 D)4p
2 o
3/2
1/2
172213.8800
172816.2926
WACB95
WACB95
222848.3
M60b
3s 3p
5
Term
Ar III ( 3 P2 )
P
P
Limit
0.0000
1431.5831
YKH85
YKH85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1592
J. E. SANSONETTI AND W. C. MARTIN
Arsenic „As…
Atomic number⫽33
Atomic weight⫽74.9216
Isotope
75
As
Mass
Abundance
Spin
Mag moment
74.921594
100%
3/2
⫹1.43947
o
As I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 3 4S3/2
⫺1
Ionization energy: 78 950 cm 共9.7886 eV兲
As II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 2 3P0
Ionization energy: 149 932 cm⫺1 共18.5892 eV兲
Strong Lines of Arsenic 共As兲
Intensity
800
800
800
1000
900
800
1000
800
800
700
700
700
800
1000
800
1000
800
1000
800
800
800
700
400
200
200
50
100
70
400
900
1000
700
700
700
800
800
700
500
150
150
200
250
200
P
P
P
P
P
P,r
P,r
P,r
P,r
P,r
P,r
P,r
P,r
P,r
P,r
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
1211.17
1218.10
1241.31
1243.08
1245.67
1258.58
1263.77
1266.34
1267.59
1280.99
1287.54
1305.70
1333.15
1341.55
1355.93
1369.77
1373.65
1375.07
1375.78
1394.64
1400.31
1890.43
1937.59
1972.62
Air
2003.35
2288.12
2349.84
2370.77
2456.53
2780.22
2860.44
4190.082
4458.469
4466.348
4494.230
4507.659
4543.483
6170.27
9597.92
9626.65
9833.78
9923.03
10024.01
Spectrum
Ref
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
LA71
HA85
HA85
HA85
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
As
I
I
I
I
I
I
I
II
II
II
II
II
II
II
I
I
I
I
I
HA85
HA85
HA85
HA85
HA85
HA85
HA85
LA71
LA71
LA71
LA71
LA71
LA71
LA71
HA85
HA85
HA85
HA85
HA85
ATOMIC SPECTROSCOPIC DATA
1593
Persistent Lines of Neutral Arsenic 共As I兲
Inten
Wavelength 共Å兲
700
400
200
200
50
100
70
400
900
1000
A ki (108 s⫺1 )
1890.43
2.7
1937.59
2.2
1972.62
2.0
Configuration
3
2288.12
2.8
2349.84
3.1
2370.77
0.42
2456.53
0.072
2780.22
0.78
2860.44
0.55
Level (cm⫺1 )
Wl Ref
A Ref
S
P
3/2
5/2
0.000
52898.056
HA85
M00
4 o
S
P
3/2
3/2
0.000
51610.393
HA85
M00
4 o
S
P
3/2
1/2
0.000
50693.897
HA85
M00
Do
D
5/2
5/2
10914.866
60815.218
HA85
Do
P
5/2
3/2
10914.866
54605.491
HA85
FW96
Do
P
3/2
1/2
10592.666
53135.750
HA85
FW96
2 o
P
D
3/2
5/2
18647.663
60815.218
HA85
FW96
Do
P
5/2
3/2
10914.866
51610.393
HA85
FW96
2 o
P
P
3/2
3/2
18647.663
54605.491
HA85
FW96
2 o
1/2
1/2
18186.328
53135.750
HA85
FW96
4 o
4p
4 p 2 ( 3 P)5s
4
4p 3
4 p 2 ( 3 P)5s
4
4p 3
4 p 2 ( 3 P)5s
4
4p 3
4 p 2 ( 1 D)5s
2003.35
J
Term
2
2
4p 3
4 p 2 ( 3 P)5s
2
2
4p 3
4 p 2 ( 3 P)5s
2
2
4p 3
4 p 2 ( 1 D)5s
2
4p 3
4 p 2 ( 3 P)5s
2
4
4p 3
4 p 2 ( 3 P)5s
2
4p 3
4 p 2 ( 3 P)5s
2
P
P
Energy Levels of Neutral Arsenic 共As I兲
Ref
Term
4p3
4 o
3/2
0.000
HA85
4p3
2
Do
3/2
5/2
10592.666
10914.866
HA85
HA85
4p3
2 o
P
1/2
3/2
18186.328
18647.663
HA85
HA85
4 p 2 ( 3 P)5s
4
P
1/2
3/2
5/2
50693.897
51610.393
52898.056
HA85
HA85
HA85
4p 2 ( 3 P)5s
2
P
1/2
3/2
53135.750
54605.491
HA85
HA85
4p 2 ( 1 D)5s
2
D
5/2
3/2
60815.218
60834.954
HA85
HA85
78950
BJ71
As II ( 3 P0 )
S
J
Level (cm⫺1 )
Configuration
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1594
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Arsenic 共As II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1000
1243.08
2.9
4p 2
4p5s
3
P
(3/2,1/2) o
1
2
1063.49
81508.925
LA71
M00
1000
1263.77
3.6
4p 2
4p5s
3
P
(1/2,1/2) o
0
1
0.0
79128.33
LA71
M00
1000
1341.55
4p 2
4p4d
1
3 o
2
1
10095.82
84636.186
LA71
1000
1369.77
4p 2
4p4d
1
2
2
10095.82
83100.804
LA71
1000
1375.07
4p 2
4p5s
1
D
(3/2,1/2) o
2
1
10095.82
82819.214
LA71
Configuration
D
P
1
D
Do
Energy Levels of Singly-ionized Arsenic 共As II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4p2
3
0
1
2
0.0
1063.49
2541.35
LA71
LA71
LA71
4p 2
1
2
10095.82
LA71
4p 2
1
S
0
22598.6
LA71
4s4p 3
5 o
2
54817.08
LA71
4s4 p 3
3
1
2
3
73749.89
73862.33
74244.42
LA71
LA71
LA71
4p5s
(1/2 ,1/2) o
0
1
78730.893
79128.33
LA71
LA71
4p5s
(3/2 ,1/2) o
2
1
81508.925
82819.214
LA71
LA71
4p4d
1
Do
2
83100.804
LA71
4p4d
3 o
1
0
2
84636.186
84648.426
85105.86
LA71
LA71
LA71
P
D
S
Do
P
o
)
As III ( 2 P1/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
149932
LA71
ATOMIC SPECTROSCOPIC DATA
1595
Astatine „At…
Atomic number⫽85
Atomic weight⫽210
Isotope
210
At
At
221
Mass
Abundance
Spin
209.987126
210.987469
0
0
5
9/2
Mag moment
o
At I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 5 2P3/2
Ionization energy: not available
Strong Lines of Astatine 共At兲
Intensity
Wavelength 共Å兲
Spectrum
Ref
Air
2162.25
2244.01
At I
At I
M64a
M64a
800 P
1000 P
Persistent Lines of Neutral Astatine 共At I兲
Inten
Wavelength 共Å兲
800
1000
A ki (108 s⫺1 )
Configuration
5
2162.25
Level (cm⫺1 )
P
P
3/2
3/2
0.0
46233.6?
M64a
2 o
3/2
5/2
0.0
44549.3?
M64a
2 o
6p
6 p 4 ( 3 P)7s
4
6p 5
6 p 4 ( 3 P)7s
2244.01
J
Term
4
P
P
Wl Ref
A Ref
Energy Levels of Neutral Astatine 共At I兲
Configuration
6p
5
6 p 4 ( 3 P)7s
At II ( 3 P2 )
Term
J
2 o
P
3/2
4
P
5/2
3/2
Level (cm⫺1 )
0.0
44549.3?
46233.6?
Ref
M64a
M64a
M64a
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1596
J. E. SANSONETTI AND W. C. MARTIN
Barium „Ba…
Atomic number⫽56
Atomic weight⫽137.327
Isotope
130
Ba
Ba
134
Ba
135
Ba
136
Ba
137
Ba
138
Ba
132
Mass
Abundance
Spin
Mag moment
129.906282
131.905042
133.904486
134.905665
135.904553
136.905812
137.905232
0.11%
0.10%
2.42%
6.59%
7.85%
11.23%
71.70%
0
0
0
3/2
0
3/2
0
⫹0.8365
⫹0.9357
Ba I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 6s 2 1S0
Ionization energy: 42 034.91 cm⫺1 共5.211 664 eV兲
Ba II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 6s 2S1/2
Ionization energy: 80 686.30 cm⫺1 共10.003 83 eV兲
Strong Lines of Barium 共Ba兲
Intensity
20 P
30 P
30 P
80 P
20 P
25 P
9
3
30
2
1000 P
6
300 P
1000 P
80
40
80
250
300 P
200 P
250 P
110 P
100 P
50
50 P
9
200 P
30
9
150 P
15
25
80 P
50
25
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2304.247
2335.267
3071.584
3501.108
3891.779
4130.649
4132.427
4166.001
4283.097
4524.926
4554.033
4899.927
4934.077
5535.481
5777.619
5853.675
5997.087
6110.783
6141.713
6496.898
6498.760
6527.312
6595.325
6675.270
6693.842
6865.686
7059.943
7120.331
7195.230
7280.296
7392.405
7488.075
7672.085
7780.478
7905.747
Spectrum
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
II
II
I
I
II
II
I
II
I
II
II
II
II
I
I
II
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
ATOMIC SPECTROSCOPIC DATA
1597
Strong Lines of Barium 共Ba兲—Continued
Intensity
Wavelength 共Å兲
12
9
60
8
50
15
40
60
50
60
7911.329
8210.239
8559.998
8915.013
9370.119
9608.894
10032.139
14999.852
23253.56
25514.88
P
P
P
P
Spectrum
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ref
I
I
I
I
I
I
I
I
I
I
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
KL99
Persistent Lines of Neutral Barium 共Ba I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
2
Term
J
Level (cm⫺1 )
1
S
P
0
1
0.000
32547.033
KL99
KFW02
S
P
0
1
0.000
28554.221
KL99
KFW02
S
P
0
1
0.000
18060.261
KL99
KFW02
D
Do
3
3
9596.533
24979.834
KL99
KFW02
D
Do
2
2
9215.501
24531.513
KL99
KFW02
D
Do
1
1
9033.966
24192.033
KL99
KFW02
D
Do
3
2
9596.533
24531.513
KL99
KFW02
D
F
3
4
9596.533
23757.049
KL99
KFW02
D
F
2
3
9215.501
22947.423
KL99
KFW02
D
F
1
2
9033.966
22064.645
KL99
KFW02
D
Do
2
2
11395.350
23074.387
KL99
KFW02
D
P
2
1
11395.350
18060.261
KL99
KFW02
D
P
2
2
9215.501
13514.745
KL99
D
P
3
2
9596.533
13514.745
KL99
30
3071.584
0.41
6s
6s7 p
1 o
80
3501.108
0.35
6s 2
5d6 p
1 o
1000
5535.481
1.19
6s 2
6s6 p
1 o
250
6498.760
0.54
6s5d
5d6 p
3
110
6527.312
0.33
6s5d
5d6 p
3
100
6595.325
0.38
6s5d
5d6 p
3
50
6693.842
0.146
6s5d
5d6 p
3
200
7059.943
0.50
6s5d
5d6 p
3
150
7280.296
0.32
6s5d
5d6 p
3
80
7672.085
0.15
6s5d
5d6 p
3
60
8559.998
0.20
6s5d
5d6 p
1
60
14999.852
0.0025
6s5d
6s6 p
1
50
23253.56
6s5d
6s6 p
3
60
25514.88
6s5d
6s6 p
3
1
1
3
3
3
3
3 o
3 o
3 o
1
1 o
3 o
3 o
Wl Ref
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1598
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Barium 共Ba I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
6s 2
1
S
0
0.000
KL99
6s5d
3
D
1
2
3
9033.966
9215.501
9596.533
KL99
KL99
KL99
6s5d
1
D
2
11395.350
KL99
6s6p
3 o
P
0
1
2
12266.024
12636.623
13514.745
KL99
KL99
KL99
6s6 p
1 o
P
1
18060.261
KL99
5d6 p
3 o
2
3
4
22064.645
22947.423
23757.049
KL99
KL99
KL99
5d6 p
1
Do
2
23074.387
KL99
5d6 p
3
o
D
1
2
3
24192.033
24531.513
24979.834
KL99
KL99
KL99
5d6 p
1 o
P
1
28554.221
KL99
6s7 p
1 o
1
32547.033
KL99
Limit
42034.91
PVHA85
F
P
Ba II ( 2 S1/2)
Persistent Lines of Singly-ionized Barium 共Ba II兲
Inten
20
30
20
25
1000
300
300
200
Wavelength 共Å兲
A ki (108 s⫺1 )
2304.247
2335.267
3891.779
4130.649
4554.033
4934.077
6141.713
6496.898
2.17
2.18
1.11
0.953
0.412
0.310
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
D
F
3/2
5/2
4873.852
48258.617
KL99
D
F
5/2
7/2
5674.824
48483.332
KL99
6p
6d
2 o
P
D
1/2
3/2
20261.561
45949.472
KL99
KFW02
6p
6d
2 o
P
D
3/2
5/2
21952.404
46154.847
KL99
KFW02
6s
6p
2
S
P
1/2
3/2
0.000
21952.404
KL99
KFW02
6s
6p
2
S
P
1/2
1/2
0.000
20261.561
KL99
KFW02
5d
6p
2
D
P
5/2
3/2
5674.824
21952.404
KL99
KFW02
5d
6p
2
D
P
3/2
1/2
4873.852
20261.561
KL99
KFW02
Configuration
Term
5d
4f
2
5d
4f
2
2 o
2 o
2
2
2 o
2 o
2 o
2 o
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1599
Energy Levels of Singly-ionized Barium 共Ba II兲
Ref
Term
6s
2
S
1/2
0.000
KL99
5d
2
D
3/2
5/2
4873.852
5674.807
KL99
KL99
6p
2 o
P
1/2
3/2
20261.561
21952.404
KL99
KL99
7s
2
S
1/2
42355.175
KL99
6d
2
D
3/2
5/2
45949.472
46154.847
KL99
KL99
4f
2 o
F
5/2
7/2
48258.617
48483.332
KL99
KL99
7p
2 o
1/2
3/2
49389.822
50011.340
KL99
KL99
Limit
80686.30
KL99
Ba III ( 1 S0 )
P
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1600
J. E. SANSONETTI AND W. C. MARTIN
Berkelium „Bk…
Atomic number⫽97
Atomic weight⫽(247)
Isotope
247
Bk
Bk
249
Mass
Abundance
Spin
Mag moment
247.070300
249.074980
0
0
3/2
7/2
2.0
o
Bk I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 9 7s 2 6H15/2
⫺1
Ionization energy: 49 989 cm 共6.1979 eV兲
Bk II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 9 7s (15/2,1/2) o8
Ionization energy: not available
Strong Lines of Berkelium 共Bk兲
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
s
s
l
P,s
l
s
s
l
s
s
l
P,l
l
l
l
P,s
s
P,l
P
s
P,l
P
P
l
s
s
s
s
l
l
P,s
l
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2748.019
2827.567
2872.114
2878.572
2884.772
2889.803
2893.660
2910.645
2926.489
2927.907
2941.713
2951.761
2969.125
2987.755
3178.466
3247.262
3252.191
3263.473
3288.750
3289.347
3335.261
3387.446
3408.281
3412.131
3426.951
3442.664
3453.897
3461.244
3464.133
3472.016
3477.620
3528.721
3531.397
3535.731
3542.187
3553.596
3556.515
3567.254
3590.320
3595.880
Spectrum
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
I
I
II
I
II
I
I
I
II
II
II
II
I
I
I
II
I
I
II
I
I
Ref
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
ATOMIC SPECTROSCOPIC DATA
1601
Strong Lines of Berkelium 共Bk兲—Continued
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
s
P
s
l
s
l
s
l
l
s
s
s
s
s
s
s
l
s
s
l
l
l
l
P,l
P,s
l
l
l
Wavelength 共Å兲
3601.115
3603.201
3604.781
3609.614
3616.620
3621.805
3627.607
3637.054
3640.255
3640.928
3675.585
3681.221
3684.427
3686.737
3695.368
3703.279
3704.015
3711.135
3712.929
3725.385
3739.916
3743.047
3745.403
3750.075
3751.905
3757.851
3771.060
3788.205
3791.419
3796.206
3798.629
3802.345
3802.470
3823.098
3824.083
3825.190
3825.844
3831.565
3833.480
3835.967
3842.185
3846.618
3847.626
3855.030
3859.888
3877.937
3880.106
3882.602
3894.547
3906.094
3916.365
3921.415
3928.045
4147.134
Spectrum
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
I
II
I
I
I
II
I
I
I
II
I
II
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
II
I
II
II
I
II
I
I
I
I
II
II
I
I
II
II
II
I
II
II
Ref
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1602
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Berkelium 共Bk兲—Continued
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Wavelength 共Å兲
P,s
P,s
l
P
P
l
l
s
P
P
l
s
l
l
s
l
P
P
l
s
s
l
l
P,l
P,l
s
P,s
s
s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4189.692
4197.441
4329.580
4351.504
4363.636
4423.011
4466.457
4765.40
5118.24
5135.53
5170.61
5197.55
5212.53
5271.95
5392.03
5394.24
5449.63
5467.47
5484.58
5512.22
5537.93
5556.80
5557.09
5581.21
5656.54
5659.03
5702.24
5910.71
7040.85
7107.85
7252.50
7306.94
7394.26
7903.90
9429.13
9862.39
10126.20
10292.44
10570.53
11293.14
11500.30
11575.34
11793.09
12159.05
13498.36
14196.93
Spectrum
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
Bk
II
II
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
Ref
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
WC78
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
CWBC77
ATOMIC SPECTROSCOPIC DATA
1603
Persistent Lines of Neutral Berkelium 共Bk I兲
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
J
Level (cm⫺1 )
6 o
11/2
13/2
5416.690
35814.60
WC78
Configuration
9
5 f 7s
2
Term
F
Wl Ref
1000
3288.750
1000
3289.347
1000
3426.951
5 f 9 7s 2
o
)7s7p( 3 Po2 )
5 f 9 ( 6 H13/2
6
Ho
共13/2,2兲
15/2
17/2
0.000
29172.103
WC78
1000
3442.664
5 f 9 7s 2
o
)7s7p( 3 Po2 )
5 f 9 ( 6 H13/2
6
Ho
共13/2,2兲
15/2
15/2
0.000
29038.930
WC78
1000
3609.614
5 f 9 7s 2
6
15/2
15/2
0.000
27695.870
WC78
1000
4363.636
5 f 9 7s 2
o
)7s7p( 3 Po2 )
5 f 9 ( 6 H15/2
6
Ho
共15/2,2兲
15/2
15/2
0.000
22910.225
WC78
1000
4466.457
5 f 9 7s 2
o
)7s7p( 3 Po2 )
5 f 9 ( 6 H15/2
6
Ho
共15/2,2兲
15/2
17/2
0.000
22382.830
WC78
1000
5212.53
5 f 9 7s 2
o
)7s7p( 3 Po1 )
5 f 9 ( 6 H15/2
6
Ho
共15/2,1兲
15/2
15/2
0.000
19179.210
WC78
1000
5271.95
5 f 9 7s 2
6
13/2
13/2
6530.720
25493.793
WC78
1000
5659.03
5 f 9 7s 2
o
)7s7p( 3 Po1 )
5 f 9 ( 6 H15/2
6
Ho
共15/2,1兲
15/2
17/2
0.000
17665.980
WC78
1000
5910.71
5 f 9 7s 2
o
)7s7p( 3 Po0 )
5 f 9 ( 6 H15/2
6
Ho
共15/2,0兲
15/2
15/2
0.000
16913.770
WC78
1000
11293.14
5 f 8 6d7s 2
5 f 8 ( 7 F6 )7s 2 7 p 1/2
8
G
(6,1/2) o
13/2
13/2
9141.115
17993.628
CWBC77
1000
11500.30
5 f 8 6d7s 2
5 f 8 ( 7 F6 )7s 2 7 p 1/2
8
D
(6,1/2) o
11/2
13/2
9300.585
17993.628
CWBC77
1000
11793.09
5 f 8 6d7s 2
5 f 8 ( 7 F6 )7s 2 7 p 1/2
8
11/2
11/2
9300.585
17777.808
CWBC77
Ho
Ho
D
(6,1/2) o
A Ref
Energy Levels of Neutral Berkelium 共Bk I兲
Configuration
9
5 f 7s
2
5 f 9 7s 2
J
Level (cm⫺1 )
Ref
o
H
15/2
13/2
11/2
9/2
7/2
0.000
6530.720
9535.130
10605.570
12067.63
BW92b
BW92b
BW92b
BW92b
BW92b
6 o
11/2
9/2
7/2
5/2
5416.690
5757.440
10985.83
12568.38
BW92b
BW92b
BW92b
BW92b
Term
6
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1604
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Berkelium 共Bk I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
5 f 8 6d7s 2
8
13/2
15/2
7/2
9/2
11/2
5/2
3/2
1/2
9141.115
10587.345
13191.915
13439.485
13769.315
13931.000
15626.860
16145.840
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 8 6d7s 2
8
11/2
9300.585
BW92b
2
8
9/2
10735.955
BW92b
5 f 8 6d7s 2
8
7/2
14920.166
BW92b
o
)7s7p( 3 Po0 )
5 f 9 ( 6 H15/2
共15/2,0兲
15/2
16913.770
BW92b
o
5 f 9 ( 6 H15/2
)7s7p( 3 Po1 )
共15/2,1兲
17/2
15/2
13/2
17665.980
19179.210
19334.710
BW92b
BW92b
BW92b
5 f 8 ( 7 F6 )7s 2 7p 1/2
(6,1/2) o
11/2
13/2
17777.808
17993.628
BW92b
BW92b
o
)7s7p( 3 Po2 )
5 f 9 ( 6 H15/2
共15/2,2兲
17/2
22382.830
BW92b
o
5 f 9 ( 6 H15/2
)7s7p( 3 Po2 )
共15/2,2兲
15/2
22910.225
BW92b
13/2
25493.793
BW92b
15/2
27695.870
BW92b
8
5 f 6d7s
G
D
D
D
o
)7s7p( 3 Po2 )
5 f 9 ( 6 H13/2
共13/2,2兲
15/2
29038.930
BW92b
o
5 f 9 ( 6 H13/2
)7s7p( 3 Po2 )
共13/2,2兲
17/2
29172.103
BW92b
13/2
35814.60
BW92b
Limit
49989
KDEE97
Bk II
((15/2,1/2) o8 )
Persistent Lines of Singly-ionized Berkelium 共Bk II兲
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
2878.572
o
)7s
5 f 9 ( 6 H15/2
9 6 o
5 f ( H15/2)7p 3/2
(15/2,1/2) o
共15/2,3/2兲
8
9
0.00
34729.28
WC78
1000
2951.761
o
)7s
5 f 9 ( 6 H15/2
(15/2,1/2) o
7
8
1487.51
35355.68
WC78
1000
3247.262
o
)7s
5 f 9 ( 6 H15/2
(15/2,1/2) o
8
7
0.00
30786.30
WC78
1000
3412.131
o
)7s
5 f 9 ( 6 H15/2
(15/2,1/2) o
7
7
1487.51
30786.30
WC78
1000
3542.187
o
)7s
5 f 9 ( 6 H15/2
8
5 f 6d7s
(15/2,1/2) o
H
8
8
0.00
28223.10
WC78
7
(15/2,1/2) o
共15/2,1/2兲
7
8
1487.51
27157.155
WC78
(15/2,1/2) o
H
8
8
0.00
25593.755
WC78
Inten
Wavelength 共Å兲
1000
A ki (108 s⫺1 )
1000
3894.547
o
)7s
5 f 9 ( 6 H15/2
9 6 o
5 f ( H15/2)7p 1/2
1000
3906.094
o
)7s
5 f 9 ( 6 H15/2
8
5 f 6d7s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
9
A Ref
ATOMIC SPECTROSCOPIC DATA
1605
Persistent Lines of Singly-ionized Berkelium 共Bk II兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
o
8
7
0.00
23861.38
WC78
(15/2,1/2) o
8
7
0.00
23817.32
WC78
Configuration
9 6
Term
o
H15/2
)7s
1000
4189.692
5f (
1000
4197.441
o
)7s
5 f 9 ( 6 H15/2
(15/2,1/2)
A Ref
Energy Levels of Singly-ionized Berkelium 共Bk II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
o
)7s
5 f 9 ( 6 H15/2
(15/2 ,1/2) o
8
7
0.00
1487.51
BW92b
BW92b
o
)7s
5 f 9 ( 6 F11/2
(11/2 ,1/2) o
6
5
5598.10
6906.07
BW92b
BW92b
o
)7s
5 f 9 ( 6 F9/2
(9/2 ,1/2) o
5
4
6051.18
7038.48
BW92b
BW92b
o
)7s
5 f 9 ( 6 H13/2
(13/2 ,1/2) o
7
6
6809.52
7786.75
BW92b
BW92b
5 f 8 7s 2
7
6
7040.98
BW92b
5 f 8 7s 2
7
F
5
10191.14
BW92b
8
5 f 6d7s
9
G
8
12340.96
BW92b
5 f 8 6d7s
9
G
7
12558.97
BW92b
5 f 8 6d7s
9
G
6
12583.03
BW92b
5 f 8 6d7s
9
G
5
13889.43
BW92b
7
23817.32
BW92b
7
23861.38
BW92b
8
25593.755
BW92b
F
5 f 8 6d7s
9
o
)7p 1/2
5 f 9 ( 6 H15/2
共15/2 ,1/2兲
8
27157.155
BW92b
7
8
28223.10
BW92b
7
30786.30
BW92b
9
34729.28
BW92b
8
35355.68
BW92b
8
5 f 6d7s
o
)7p 3/2
5 f 9 ( 6 H15/2
Bk III (
6
o
H15/2
)
H
H
共15/2 ,3/2兲
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1606
J. E. SANSONETTI AND W. C. MARTIN
Beryllium „Be…
Atomic number⫽4
Atomic weight⫽9.01218
Isotope
9
Be
Be
10
Mass
Abundance
Spin
Mag moment
9.012182
10.013534
100%
Trace
3/2
0
⫺1.1776
Be I Ground state: 1s 2 2s 2 1S0
Ionization energy: 75 192.64 cm⫺1 共9.322 70 eV兲
Be II Ground state: 1s 2 2s 2S1/2
Ionization energy: 146 882.8 cm⫺1 共18.211 14 eV兲
Strong Lines of Beryllium 共Be兲
Intensity
200
400
600
800
100
50
60
50
50
60
1000
60
300
100
100
60
200*
200*
60
100
1000
600
100
15
60
100
12
140
200
40
60
100
12
12
10
10
4
5
12
20
6
6
5
6
5
P
P,c
P
c
c
P,c
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
1143.039
1197.188
1512.269
1512.412
1661.478
1964.59
1998.01
Air
2056.012
2174.986
2175.103
2348.610
2350.703
2350.829
2494.728
2650.454
2650.550
2650.613
2650.619
2650.694
2650.760
3130.4219
3131.0667
3321.340
3813.454
4360.663
4360.988
4572.664
4673.329
4673.423
4828.159
5270.28
5270.81
6547.89
6558.36
6982.749
7209.134
8254.070
8801.370
10119.92
12095.36
14643.92
14644.75
16157.72
18143.54
31778.70
Spectrum
Ref
Be
Be
Be
Be
Be
Be
Be
II
II
II
II
I
I
I
J61a
J61a
J61a
J61a
KM97
KM97
KM97
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
Be
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
II
II
I
II
II
II
II
II
II
II
I
I
I
I
II
II
I
I
I
I
I
KM97
KM97
KM97
KM97
KM97
KM97
KM97
KM97
KM97
KM97
KM97
KM97
KM97
BWWI85
BWWI85
KM97
KM97
J61a
J61a
KM97
J61a
J61a
J61a
J61a
J61a
J61a
J61a
KM97
KM97
KM97
KM97
J61a
J61a
KM97
KM97
HJ69
KM97
HJ69
ATOMIC SPECTROSCOPIC DATA
1607
Persistent Lines of Neutral Beryllium 共Be I兲
Inten
Wavelength 共Å兲
100
1000
100
100
60
200*
200*
60
100
100
12
4
1661.478
2348.610
2494.728
2650.454
2650.550
2650.613
2650.619
2650.694
2650.760
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
2s
2s3p
1
S
1 o
0
1
0.000
60187.34
KM97
M03
2s 2
2s2p
1
S
1 o
0
1
0.000
42565.35
KM97
M03
2s2 p
2s3d
3 o
P
3
2
1,2,3
21981.27
62053.72
KM97
FW96
4.24*
2s2 p
2p 2
3 o
P
3
1
2
21978.925
59697.08
KM97
FW96
4.24*
2s2 p
2p 2
3 o
P
3
0
1
21978.28
59695.07
KM97
FW96
4.24*
2s2 p
2p 2
3 o
P
3
1
1
21978.925
59695.07
KM97
FW96
4.24*
2s2 p
2p 2
3 o
P
3
2
2
21981.27
59697.08
KM97
FW96
4.24*
2s2 p
2p 2
3 o
P
3
1
0
21978.925
59693.65
KM97
FW96
4.24*
2s2 p
2p 2
3 o
P
3
2
1
21981.27
59695.07
KM97
FW96
2s2 p
2s3s
3 o
P
3
2
1
21981.27
52080.94
KM97
2s2 p
2s3d
1 o
P
1
1
2
42565.35
64428.31
KM97
2s2 p
2s3s
1 o
P
1
1
0
42565.35
54677.26
KM97
0.0726
5.53
1.6
3321.340
4572.664
0.79
8254.070
Configuration
2
P
P
D
P
P
P
P
P
P
S
D
S
FW96
Energy Levels of Neutral Beryllium 共Be I兲
Configuration
Level (cm⫺1 )
Term
J
1
S
0
0.000
KM97
2s2 p
3 o
P
0
1
2
21978.28
21978.925
21981.27
KM97
KM97
KM97
2s2 p
1 o
P
1
42565.35
KM97
2s3s
3
S
1
52080.94
KM97
2s3s
1
S
0
54677.26
KM97
D
2
56882.43
KM97
2s3 p
3 o
0,1
2
58907.45
58907.83
KM97
KM97
2p2
3
P
0
1
2
59693.65
59695.07
59697.08
KM97
KM97
KM97
2s3p
1 o
P
1
60187.34
KM97
2s3d
3
D
1,2,3
62053.72
KM97
2s3d
1
D
2
64428.31
KM97
Limit
75192.64
KM97
2s
2
2p
2
Be II ( 2 S1/2)
1
P
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1608
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Beryllium 共Be II兲
Inten
Wavelength 共Å兲
600
800
1000
600
60
100
140
200
100
A ki (108 s⫺1 )
1512.269
9.2
1512.412
11.
3130.4219
1.13
3131.0667
1.13
4360.663
0.92
4360.988
1.1
4673.329
4673.423
5270.811
0.66
Configuration
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1s 2 p
1s 2 3d
2 o
P
D
1/2
3/2
31928.744
98054.55
J61a
FW96
1s 2 2 p
1s 2 3d
2 o
P
D
3/2
5/2
31935.320
98055.10
J61a
FW96
1s 2 2 p
1s 2 3d
2 o
P
D
3/2
3/2
31935.320
98054.55
1s 2 2s
1s 2 2 p
2
S
P
1/2
3/2
0.000
31935.320
BWWI85
M03
1s 2 2s
1s 2 2 p
2
S
P
1/2
1/2
0.000
31928.744
BWWI85
M03
1s 2 3 p
1s 2 4d
2 o
P
D
1/2
3/2
96495.34
119421.18
J61a
FW96
1s 2 3 p
1s 2 4d
2 o
P
D
3/2
5/2
96497.26
119421.42
J61a
FW96
1s 2 3d
1s 2 4 f
2
D
F
3/2
5/2
98054.55
119446.59
J61a
1s 2 3d
1s 2 4 f
2
D
F
5/2
7/2
98055.10
119446.71
J61a
1s 2 3 p
1s 2 4s
2 o
3/2
1/2
96497.26
115464.38
J61a
2
2
2
2 o
2 o
2
2
2 o
2 o
2
P
S
FW96
Energy Levels of Singly-ionized Beryllium 共Be II兲
J
Level (cm⫺1 )
Ref
Configuration
Term
1s 2 2s
2
S
1/2
0.000
BWWI85
1s 2 2p
2 o
P
1/2
3/2
31928.744
31935.320
BWWI85
BWWI85
1s 2 3s
2
S
1/2
88231.89
KM00
1s 3p
2 o
P
1/2
3/2
96495.34
96497.26
KM00
KM00
1s 2 3d
2
D
3/2
5/2
98054.55
98055.10
KM00
KM00
1s 2 4s
2
S
1/2
115464.38
KM00
1s 2 4p
2 o
P
1/2
3/2
118760.51
118761.30
KM00
KM00
1s 2 4d
2
D
3/2
5/2
119421.18
119421.42
KM00
KM00
1s 2 4 f
2 o
5/2
7/2
119446.59
119446.71
KM00
KM00
Limit
146882.84
KM00
2
F
Be III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1609
Bismuth „Bi…
Atomic number⫽83
Atomic weight⫽208.9804
Isotope
209
Bi
Bi
210
Mass
Abundance
Spin
Mag moment
208.980347
209.984095
100%
Trace
9/2
1
⫹4.110
⫺0.044
Bi I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 3 4S3/2
Ionization energy: 58 762.0 cm⫺1 共7.2855 eV兲
Bi II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 2 3P0
Ionization energy: 134 720 cm⫺1 共16.703 eV兲
Strong Lines of Bismuth 共Bi兲
Intensity
400
300
400
500
400
400
400
300
400
400
600
400
400
800
600
700
700
1000
300
250
P
P
P
250
300
400
200
120
600
400
120
600
600
80
50
500
400
300
80
300
1000
70
400
60
50
P
P
h
P
P
P
P
P
P
P
P
P
h
P
P
P
P
P
P
P
P
P,c
c
c
c
c
Wavelength 共Å兲
Vacuum
1241.045
1283.715
1436.810
1455.091
1486.954
1520.549
1533.139
1536.745
1538.037
1573.69
1591.76
1609.69
1611.358
1777.05
1787.406
1791.842
1823.728
1902.341
1954.706
1960.049
Air
2021.149
2061.634
2068.937
2110.217
2133.600
2186.930
2214.031
2228.203
2230.602
2368.384
2627.904
2780.476
2897.965
2938.297
2989.019
2993.336
3024.621
3067.700
3397.198
3430.605
3510.864
3596.097
Spectrum
Ref
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
I
I
II
I
I
II
II
I
I
II
I
I
I
I
I
I
I
I
I
II
I
I
WBBF01
WBBF01
WBBF01
WBBF01
WBBF01
DLW02
DLW02
WBBF01
WBBF01
DLW02
WBBF01
WBBF01
WBBF01
WBBF01
GMV85
GMV85
GMV85
WBBF01
GMV85
DLW02
GMV85
GMV85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1610
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Bismuth 共Bi兲—Continued
Wavelength 共Å兲
Intensity
700
300
400
800
700
600
70
300
500
600
800
400
400
400
500
300
70
50
P
Spectrum
3792.564
3864.025
4079.072
4259.413
4301.697
4705.285
4722.527
4730.267
5124.356
5144.492
5209.325
5270.512
5719.138
6600.339
6809.196
8532.
9657.04
11710.83
h
P,h
P,h
P,h
P,c
P,h
P,h
P,h
h
h
h
h
P,d
P,d
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Bi
Ref
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
I
DLW02
DLW02
DLW02
DLW02
DLW02
DLW02
GMV85
DLW02
DLW02
DLW02
DLW02
DLW02
DLW02
DLW02
DLW02
CM34
GMV85
GMV85
Persistent Lines of Neutral Bismuth 共Bi I兲
Inten
300
250
250
300
200
120
600
500
400
300
80
300
Wavelength 共Å兲
1954.706
1960.049
2021.149
2061.634
2110.217
2228.203
2230.602
2897.965
2938.297
2989.019
2993.336
3024.621
A ki (108 s⫺1 )
0.586
0.154
0.060
0.96
0.53
0.88
2.34
1.53
1.23
0.54
0.145
0.86
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
3
Term
4 o
6p
6 p 2 ( 3 P0 )7d
2
6p 3
6 p 2 ( 3 P0 )7d
2
6p 3
6 p 2 ( 3 P2 )7s
2
6p 3
6 p 2 ( 3 P2 )7s
2
6p 3
6 p 2 ( 3 P0 )8s
2
6p 3
6 p 2 ( 3 P1 )7s
2
6p 3
6 p 2 ( 3 P0 )6d
2
6p 3
6 p 2 ( 3 P1 )7s
2
6p 3
6 p 2 ( 3 P2 )7s
2
6p 3
6 p 2 ( 3 P1 )7s
2
6p 3
6 p 2 ( 3 P0 )6d
2
6p 3
6 p 2 ( 3 P2 )7s
2
S
关2兴
4 o
S
关2兴
4 o
S
关2兴
4 o
S
关2兴
4 o
S
关0兴
4 o
S
关1兴
4 o
S
关2兴
2
Do
关1兴
2
Do
关2兴
2
Do
关1兴
2
Do
关2兴
2
Do
关2兴
J
Level (cm⫺1 )
Wl Ref
A Ref
3/2
5/2
0.000
51158.494
WBBF01
CBZS95
3/2
3/2
0.000
51019.090
WBBF01
CBZS95
3/2
3/2
0.000
49460.910
WBBF01
FW96
3/2
5/2
0.000
48489.869
WBBF01
CBZS95
3/2
1/2
0.000
47373.477
WBBF01
CBZS95
3/2
3/2
0.000
44865.076
WBBF01
CBZS95
3/2
5/2
0.000
44816.841
WBBF01
CBZS95
3/2
1/2
11419.039
45915.883
WBBF01
FW96
5/2
3/2
15437.501
49460.910
WBBF01
FW96
3/2
3/2
11419.039
44865.076
GMV85
CBZS95
3/2
5/2
11419.039
44816.841
GMV85
CBZS95
5/2
5/2
15437.501
48489.869
GMV85
CBZS95
endtab
ATOMIC SPECTROSCOPIC DATA
1611
Persistent Lines of Neutral Bismuth 共Bi I兲—Continued
Inten
1000
70
70
50
Wavelength 共Å兲
A ki (108 s⫺1 )
3067.700
4722.527
Configuration
3
1.67
0.094
9657.04
11710.83
J
Level (cm⫺1 )
Wl Ref
A Ref
S
关0兴
3/2
1/2
0.000
32588.221
WBBF01
CBZS95
Do
关0兴
3/2
1/2
11419.039
32588.221
GMV85
CBZS95
关0兴
关1兴o
1/2
3/2
32588.221
42940.519
GMV85
关0兴
关1兴o
1/2
1/2
32588.221
41124.985
GMV85
Term
4 o
6p
6p 2 ( 3 P0 )7s
2
6p 3
6p 2 ( 3 P0 )7s
2
2
6p 2 ( 3 P0 )7s
6p 2 ( 3 P0 )7p
2
6p 2 ( 3 P0 )7s
6p 2 ( 3 P0 )7p
2
2
2
Energy Levels of Neutral Bismuth 共Bi I兲
Ref
Term
6p3
4 o
3/2
0.000
GMV85
2
o
D
3/2
5/2
11419.039
15437.501
GMV85
GMV85
6p 3
2 o
P
1/2
3/2
21660.914
33164.805
GMV85
GMV85
6p 2 ( 3 P0 )7s
2
关0兴
1/2
32588.221
GMV85
6p 2 ( 3 P0 )7 p
2
关1兴o
1/2
3/2
41124.985
42940.519
GMV85
GMV85
6p 2 ( 3 P0 )6d
2
关2兴
3/2
5/2
43912.374
44816.841
GMV85
GMV85
6p 2 ( 3 P1 )7s
2
关1兴
3/2
1/2
44865.076
45915.883
GMV85
GMV85
6p 2 ( 3 P0 )8s
2
关0兴
1/2
47373.477
GMV85
6p 2 ( 3 P2 )7s
2
关2兴
5/2
3/2
48489.869
49460.910
GMV85
GMV85
6p 2 ( 3 P0 )7d
2
关2兴
3/2
5/2
51019.090
51158.494
GMV85
GMV85
Limit
58761.65
MGGB89
6p
3
Bi II ( 3 P0 )
S
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1612
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Bismuth 共Bi II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
2
400
1241.045
6p
6 p6d
300
1283.715
6p 2
6s6 p 3
400
1436.810
600
1591.76
3.47
Term
J
Level (cm⫺1 )
Wl Ref
共1/2,1/2兲
(1/2,3/2) o
0
1
0.000
80577.071
WBBF01
共3/2,1/2兲
Do
2
2
17031.698
94930.640
WBBF01
3
共1/2,1/2兲
(1/2,1/2) o
0
1
0.000
69598.475
WBBF01
共3/2,1/2兲
S
1
2
13325.401
76148.712
WBBF01
5 o
Configuration
6p 2
6 p7s
6p 2
6s6 p 3
A Ref
M00
800
1777.05
0.970
6p 2
6 p7s
共3/2,1/2兲
(1/2,1/2) o
1
1
13325.401
69598.475
WBBF01
M00
700
1791.842
6.41
6p 2
6 p7s
共3/2,1/2兲
(1/2,1/2) o
1
0
13325.401
69133.891
WBBF01
M00
700
1823.728
6p 2
6 p7s
共3/2,3/2兲
(3/2,1/2) o
2
2
33938.718
88771.443
WBBF01
1000
1902.341
6p 2
6 p7s
共3/2,1/2兲
(1/2,1/2) o
2
1
17031.698
69598.475
WBBF01
600
2186.930
6p 2
6p7s
(3/2,3/2)
(3/2,1/2) o
0
1
44173.768
89885.675
DLW02
700
3792.564
6p6d
6p5 f
(1/2,3/2) o
共1/2,5/2兲
2
3
79091.141
105451.045
DLW02
800
4259.413
6p6d
6p5 f
(1/2,5/2) o
共1/2,7/2兲
3
4
82257.251
105728.060
DLW02
700
4301.697
6p6d
6p5 f
(1/2,5/2) o
共1/2,7/2兲
2
3
82049.632
105289.732
DLW02
600
4705.285
6p7 p
6 p7d
共1/2,1/2兲
(1/2,3/2) o
1
2
84280.446
105527.197
DLW02
500
5124.356
6p7s
6p7p
(3/2,1/2) o
共3/2,3/2兲
2
3
88771.443
108280.656
DLW02
600
5144.492
6p7s
6p7p
(1/2,1/2) o
共1/2,3/2兲
0
1
69133.891
88566.685
DLW02
800
5209.325
6p7s
6p7p
(1/2,1/2) o
共1/2,3/2兲
1
2
69598.475
88789.478
DLW02
3.55
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
M00
ATOMIC SPECTROSCOPIC DATA
1613
Energy Levels of Singly-ionized Bismuth 共Bi II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
2
共1/2,1/2兲
0
0.000
DLW02
6p2
共3/2,1/2兲
1
2
13325.401
17031.698
DLW02
DLW02
6p2
共3/2,3/2兲
2
33938.718
DLW02
6p2
共3/2,3/2兲
0
44173.768
DLW02
6 p7s
(1/2,1/2) o
0
1
69133.891
69598.475
DLW02
DLW02
6s6 p 3
5 o
2
76148.712
DLW02
6 p6d
(1/2,3/2) o
2
1
79091.141
80577.071
DLW02
DLW02
6 p6d
(1/2,5/2) o
2
3
82049.632
82257.251
DLW02
DLW02
6 p7 p
共1/2,1/2兲
1
0
84280.446
87078.777
DLW02
DLW02
6 p7 p
共1/2,3/2兲
1
2
88566.685
88789.478
DLW02
DLW02
6 p7s
(3/2,1/2) o
2
1
88771.443
89885.675
DLW02
DLW02
6s6 p 3
3
1
2
3
94442.227
94930.640
96062.356
DLW02
DLW02
DLW02
6 p5 f
共1/2,7/2兲
3
4
105289.732
105728.060
DLW02
DLW02
6 p5 f
共1/2,5/2兲
3
105451.045
DLW02
6 p7d
(1/2,3/2) o
2
105527.197
DLW02
6 p7 p
共3/2,3/2兲
3
108280.656
DLW02
134720
JM86
6p
o
)
Bi III ( 2 P1/2
S
Do
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1614
J. E. SANSONETTI AND W. C. MARTIN
Boron „B…
Atomic number⫽5
Atomic weight⫽10.81
Isotope
10
11
B
B
Mass
Abundance
Spin
Mag moment
10.012937
11.009305
19.9%
80.1%
3
3/2
⫹1.8007
⫹2.6886
o
B I Ground state: 1s 2 2s 2 2p 2P1/2
Ionization energy: 66 928.04 cm⫺1 共8.298 02 eV兲
B II Ground state: 1s 2 2s 2 1S0
Ionization energy: 202 887.0 cm⫺1 共25.1548 eV兲
Strong Lines of Boron 共B兲
Intensity
180
500
500
500
500
500
1000
700
500
1000
300
700
300
500
300
500
800
1000
500
200
200
250
400
500
200
500
800
700
500
300
110
110
110
110
110
100
50
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
693.947
882.543
882.681
1081.875
1082.073
1230.160
1362.463
1623.597
1623.790
1624.023
1624.175
1624.376
1666.850
1667.272
1817.843
1818.348
1825.894
1826.400
1842.820
Air
2066.364
2066.646
2067.186
2088.889
2089.570
2395.048
2496.769
2497.722
2918.076
3451.303
4121.933
4194.792
4472.101
4472.851
4940.376
6080.44
11660.028
11662.452
Spectrum
Ref
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
II
O70
O70
O70
O70
O70
O70
LZJK98
LZJK98
LZJK98
LZJK98
LZJK98
LZJK98
BTG74
BTG74
BTG74
BTG74
EL01
EL01
LZJK98
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
I
I
I
I
I
II
I
I
II
II
II
II
II
II
II
II
I
I
GV72,GM62
GV72,GM62
GV72,GM62
JLKK93
JLKK93
O70
JLKK93
JLKK93
O70
LZJK98
O70
O70
O70
O70
O70
O70
EL01
EL01
ATOMIC SPECTROSCOPIC DATA
1615
Persistent Lines of Neutral Boron 共B I兲
Inten
800
1000
400
500
500
800
100
50
Wavelength 共Å兲
A ki (108 s⫺1 )
1825.894
1826.400
2088.889
2089.570
2496.769
2497.722
Configuration
2
1.70
2.04
0.361
0.432
0.837
1.67
11660.028
11662.452
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
2s 2 p
2s 2 3d
2 o
P
D
1/2
3/2
0.000
54767.698
EL01
M03
2s 2 2 p
2s 2 3d
2 o
P
D
3/2
5/2
15.287
54767.844
EL01
M03
2s 2 2 p
2s2p 2
2 o
P
D
1/2
3/2
0.000
47857.127
JLKK93
M03
2s 2 2 p
2s2p 2
2 o
P
D
3/2
5/2
15.287
47856.807
JLKK93
M03
2s 2 2 p
2s 2 3s
2 o
P
S
1/2
1/2
0.000
40039.695
JLKK93
M03
2s 2 2 p
2s 2 3s
2 o
P
S
3/2
1/2
15.287
40039.695
JLKK93
OL92
2s 2 3s
2s 2 3 p
2
S
P
1/2
3/2
40039.695
48613.655
EL01
2s 2 3s
2s 2 3 p
2
S
P
1/2
1/2
40039.695
48611.872
EL01
2
2
2
2
2
2
2 o
2 o
Energy Levels of Neutral Boron 共B I兲
Ref
Term
2s 2 2p
2 o
1/2
3/2
2s2 p 2
4
P
1/2
3/2
5/2
28870.0⫹x
28875.0⫹x
28881.3⫹x
RT76
RT76
RT76
2s 2 3s
2
S
1/2
40039.695
JLKK93
2s2p 2
2
D
5/2
3/2
47856.807
47857.127
JLKK93
JLKK93
2s 2 3p
2 o
P
1/2
3/2
48611.872
48613.655
EL01
EL01
2s 2 3d
2
D
3/2
5/2
54767.698
54767.844
EL01
EL01
2s 2 4s
2
S
1/2
55010.236
EL01
2s 2 4p
2 o
P
1/2
3/2
57786.436
57787.071
EL01
EL01
2s 2 4 f
2 o
5/2,7/2
60031.085
EL01
Limit
66928.04
R02
B II ( 1 S0 )
P
F
J
Level (cm⫺1 )
Configuration
0.000
15.287
JLKK93
JLKK93
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1616
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Boron 共B II兲
Inten
1000
700
500
1000
700
500
200
500
Wavelength 共Å兲
A ki (108 s⫺1 )
1362.463
11.9
15.6
1624.376
13.3
Wl Ref
1
S
P
0
1
0.00
73396.51
LZJK98
2s2p
2p2
3 o
P
P
1
2
37342.15
98933.76
LZJK98
2s2p
2p2
3 o
P
P
0
1
37336.04
98920.37
LZJK98
2s2p
2p2
3 o
P
P
2
2
37358.30
98933.76
LZJK98
2s2p
2p2
3 o
P
P
2
1
37358.30
98920.37
LZJK98
2s2p
2p2
1 o
P
S
1
0
73396.51
127661.19
LZJK98
D
P
2
1
102362.77
144103.17
O70
1 o
1
2
73396.51
102362.77
LZJK98
1 o
3
3
3
3
1
2p 2
2s3 p
2395.05
3451.303
Level (cm⫺1 )
2s
2s2 p
1623.790
1842.820
J
2
1623.597
1624.023
Term
Configuration
0.54
1
1 o
2s2p
2p2
1
P
D
Energy Levels of Singly-ionized Boron 共B II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
2s 2
1
S
0
0.00
2s2p
3 o
P
0
1
2
37335.54
37341.65
37357.80
R98
R98
R98
2s2p
1 o
P
1
73396.51
LZJK98
2p2
3
P
0
1
2
98911.38
98919.87
98933.26
R98
R98
R98
2p 2
1
D
2
102362.77
LZJK98
2
1
S
0
127661.19
LZJK98
2s3s
3
S
1
129773.21
R98
2s3p
3 o
P
0
2
1
143989.33
143989.94
143993.49
R98
R98
R98
2s3p
1 o
P
1
144102.81
R98
2s3d
3
D
1,2,3
150649.09
R98
2s3d
1
D
2
154685.96
R98
Limit
202887.0
R98
2p
B III ( 2 S1/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
LZJK98
A Ref
M03
LZJK98
LZJK98
LZJK98
ATOMIC SPECTROSCOPIC DATA
1617
Bromine „Br…
Atomic number⫽35
Atomic weight⫽79.904
Isotope
79
81
Br
Br
Mass
Abundance
Spin
Mag moment
78.918336
80.916289
50.69%
49.31%
3/2
3/2
⫹2.1064
⫹2.2706
o
Br I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 5 2P3/2
⫺1
Ionization energy: 95 284.8 cm 共11.8138 eV兲
Br II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 4 3P2
Ionization energy: 174 140 cm⫺1 共21.591 eV兲
Strong Lines of Bromine 共Br兲
Intensity
1000
500
500
500
500
1000
500
1000
400
500
100
150
700
400
300
400
250
300
1000
P
500
500
400
500
400
500
500
500
1000
1000
130
130
250
200
500
500
500
500
500
400
h
P
P
P
P
P
P
h
P
P
P
Wavelength 共Å兲
Vacuum
889.25
896.65
906.01
984.99
1012.13
1015.53
1036.98
1048.94
1064.71
1071.84
1232.43
1384.60
1488.45
1531.74
1540.65
1574.84
1576.39
1582.31
1633.40
Air
2317.30
2386.70
2388.96
2389.69
2521.70
2972.26
3914.38
3980.38
4223.89
4365.63
4441.74
4472.61
4477.72
4525.59
4542.89
4678.70
4704.92
4785.48
4816.68
4930.62
Spectrum
Ref
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
MT84
MT84
MT84
MT84
MT84
MT84
MT84
MT84
MT84
MT84
T63
T63
T63
T63
T63
T63
T63
T63
T63
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
II
II
II
II
II
II
II
II
II
II
I
I
I
I
II
II
II
II
II
II
R58
R58
R58
R58
R58
R58
RR44
K40
K40
K40
T63
T63
T63
T63
K40
K40
K40
K40
K40
K40
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1618
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Bromine 共Br兲—Continued
Wavelength 共Å兲
Intensity
500
500
500
500
500
800
250
700
250
700
250
130
130
130
500
400
400
130
400
400
130
300
200
1000
250
130
500
250
130
200
300
400
400
200
250
500
200
130
400
Spectrum
5182.36
5238.26
5332.07
5506.72
6148.60
6350.73
6544.57
6559.80
6582.17
6631.62
6682.28
6692.13
7005.19
7348.51
7512.96
7803.02
7938.68
7978.57
7989.94
8131.52
8153.75
8154.00
8264.96
8272.44
8334.70
8343.70
8446.55
8638.66
8793.47
8819.96
8825.22
8897.62
9166.06
9173.63
9178.16
9265.42
9320.86
9896.40
10457.96
c
c
P
P
P
P,c
P,c
P
P
c
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Br
Ref
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
K40
K40
K40
K40
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
T63
Persistent Lines of Neutral Bromine 共Br I兲
Inten
700
300
400
1000
Wavelength 共Å兲
1488.45
1540.65
1574.84
1633.40
A ki (108 s⫺1 )
2.0
2.2
0.20
0.23
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
5
4p
4 p 4 ( 3 P)5s
4p 5
4 p 4 ( 3 P)5s
4p 5
4 p 4 ( 3 P)5s
4p 5
4 p 4 ( 3 P)5s
J
Level (cm⫺1 )
P
P
3/2
3/2
2 o
P
P
2 o
Term
Wl Ref
A Ref
0.00
67183.58
T63
M00
3/2
3/2
0.00
64907.19
T63
M00
P
P
1/2
3/2
3685.24
67183.58
T63
M00
2 o
1/2
3/2
3685.24
64907.19
T63
M00
2 o
2
4
2
4
P
P
ATOMIC SPECTROSCOPIC DATA
1619
Persistent Lines of Neutral Bromine 共Br I兲—Continued
Inten
Wavelength 共Å兲
130
500
400
400
1000
130
500
7348.51
7512.96
7803.02
7938.68
A ki (108 s⫺1 )
0.12
0.12
0.053
0.19
8272.44
8343.70
8446.55
0.22
0.12
Configuration
4 3
J
Level (cm⫺1 )
P
Do
3/2
5/2
P
Do
Term
4p ( P)5s
4 p 4 ( 3 P)5p
4
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
4p 4 ( 1 D)5s
4 p 4 ( 1 D)5p
2
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
2
4
Wl Ref
A Ref
64907.19
78511.60
T63
FW96
5/2
3/2
63436.45
76743.08
T63
FW96
P
P
1/2
3/2
66883.87
79695.89
T63
FW96
Do
Do
5/2
5/2
75890.33
88483.42
T63
FW96
P
Do
5/2
7/2
63436.45
75521.50
T63
P
Do
1/2
1/2
66883.87
78865.72
T63
FW96
P
Do
3/2
3/2
64907.19
76743.08
T63
FW96
2 o
2
4
4
4
Energy Levels of Neutral Bromine 共Br I兲
J
Level (cm⫺1 )
Ref
2 o
P
3/2
1/2
0.00
3685.24
T63
T63
4 p 4 ( 3 P)5s
4
P
5/2
3/2
1/2
63436.45
64907.19
66883.87
T63
T63
T63
4p 4 ( 3 P)5s
2
P
3/2
1/2
67183.58
68970.21
T63
T63
4p 4 ( 3 P)5p
4 o
P
5/2
3/2
1/2
74672.32
75009.13
75814.00
T63
T63
T63
4 p 4 ( 3 P)5p
4
Do
7/2
5/2
3/2
1/2
75521.50
75697.05
76743.08
78865.72
T63
T63
T63
T63
4 p 4 ( 3 P)5p
2
Do
5/2
3/2
78511.60
78676.65
T63
T63
4 p 4 ( 3 P)5p
2 o
S
1/2
78076.00
T63
4 p 4 ( 3 P)5p
4 o
S
3/2
79178.33
T63
4 p 4 ( 3 P)5p
2 o
P
3/2
1/2
79695.89
79868.03
T63
T63
4 p 4 ( 1 D)5s
2
D
5/2
3/2
75890.33
75908.53
T63
T63
4p 4 ( 1 D)5p
2 o
5/2
7/2
87061.23
87225.16
T63
T63
Configuration
Term
4p5
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1620
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Bromine 共Br I兲—Continued
J
Level (cm⫺1 )
Ref
4 p ( D)5p
2
o
D
3/2
5/2
88438.78
88483.42
T63
T63
4 p 4 ( 1 D)5p
2 o
P
3/2
1/2
87259.29
87499.03
T63
T63
4 p 4 ( 1 S)5s
2
S
1/2
91937.95
T63
Limit
95284.8
T63
Configuration
Term
4 1
Br II ( 3 P2 )
Persistent Lines of Singly-ionized Bromine 共Br II兲
Inten
Wavelength 共Å兲
1000
889.25
1000
1000
500
500
500
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
3
P
Do
2
3
0.00
112454.52
MT84
P
S
2
1
0.00
98470.12
MT84
P
S
1
1
3136.50
98470.12
MT84
4p 3 ( 4 So)5s
4p 3 ( 4 So)5p
5 o
S
P
2
3
93921.36
115170.02
K40
FW96
4p 3 ( 4 So)5s
4p 3 ( 4 So)5p
5 o
S
P
2
2
93921.36
114812.00
K40
FW96
4p 3 ( 4 So)5s
4p 3 ( 4 So)5p
5 o
2
1
93921.36
114676.79
K40
FW96
Configuration
4p 4
4 p 3 ( 4 So)4d
4p 4
4 p 3 ( 4 So)5s
1015.53
4p 4
4 p 3 ( 4 So)5s
1048.94
4704.92
1.1
4785.48
0.94
4816.68
1.1
3
3
3 o
3
3 o
5
5
5
S
P
A Ref
Energy Levels of Singly-ionized Bromine 共Br II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4p4
3
2
1
0
0.0
3136.5
3837.4
MT84
MT84
MT84
4p 4
1
2
12089.1
MT84
4p 4
1
S
0
27867.1
MT84
4p 3 ( 4 So)5s
5 o
S
2
93921.36
MT84
4s4 p 5
3 o
P
2
1
0
96433.28
98801.10
100236.18
MT84
MT84
MT84
4 p 3 ( 4 So)5s
3 o
S
1
98470.12
MT84
4 p 3 ( 4 So)4d
5
Do
3
2
4
1
0
104038.64
104080.24
104091.43
104145.53
104199.96
MT84
MT84
MT84
MT84
MT84
4 p 3 ( 2 Do)5s
3
Do
1
2
3
109422.21
109676.51
110372.20
MT84
MT84
MT84
P
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1621
Energy Levels of Singly-ionized Bromine 共Br II兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
3 4 o
4 p ( S )4d
3
o
D
2
1
3
111524.25
112389.85
112454.52
MT84
MT84
MT84
4 p 3 ( 2 Do)5s
1
Do
2
112933.31
MT84
4s4 p 5
1 o
P
1
113336.75
MT84
4 p 3 ( 4 So)5p
5
P
1
2
3
114676.79
114812.00
115170.02
MT84
MT84
MT84
4p 3 ( 4 So)5p
3
P
1
2
0
117555.18
117761.14
117828.36
MT84
MT84
MT84
174140
M98
o
)
Br III ( 4 S3/2
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1622
J. E. SANSONETTI AND W. C. MARTIN
Cadmium „Cd…
Atomic number⫽48
Atomic weight⫽112.411
Isotope
106
Cd
Cd
110
Cd
111
Cd
112
Cd
113
Cd
114
Cd
116
Cd
108
Mass
Abundance
Spin
105.906461
107.904176
109.903005
110.904182
111.902758
112.904400
113.903357
115.904754
1.25%
0.89%
12.51%
12.81%
24.13%
12.22%
28.72%
7.47%
0
0
0
1/2
0
1/2
0
0
Mag moment
⫺0.5943
⫺0.6217
Cd I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 1S0
Ionization energy: 72 540.07 cm⫺1 共8.993 82 eV兲
Cd II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2S1/2
Ionization energy: 136 374.74 cm⫺1 共16.908 31 eV兲
Strong Lines of Cadmium 共Cd兲
Intensity
200
200
300
200
1000
1000
1000
800
1000
200
500
1000
100
100
200
200
500
100
100
150
150
400
500
400
500
400
200
1000
100
150
500
1000
1000
P,r
P
P,r
P
P
P
r
r
r
P
P
P
P
P
P
P
P,h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
1514.26
1571.58
1922.23
1995.43
Air
2144.408
2194.557
2265.018
2288.022
2312.766
2321.074
2572.930
2748.549
2836.900
2880.767
2914.672
2929.271
2980.620
2981.362
3133.167
3252.524
3261.055
3403.652
3466.200
3467.655
3610.508
3612.873
4134.768
4415.63
4678.149
4799.912
5085.822
5337.48
5378.13
Spectrum
Ref
Cd
Cd
Cd
Cd
II
II
II
II
SP49
SP49
SP49
SP49
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
II
II
II
I
II
II
II
II
I
I
II
II
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
II
II
SP49
SP49
SP49
BA56
SP49
SP49
SP49
SP49
BA56
BA56
SP49
SP49
BA56
BA56
BA56
BA56
BA56
BA56
BA56
BA56
BA56
BA56
SP49
SP49
BA56
BA56
BA56
SP49
SP49
ATOMIC SPECTROSCOPIC DATA
1623
Strong Lines of Cadmium 共Cd兲—Continued
Wavelength 共Å兲
Intensity
200
150
400
500
1000 P
400
500
500
Spectrum
5381.89
6099.142
6354.72
6359.98
6438.470
6464.94
6725.78
7345.670
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Ref
II
I
II
II
I
II
II
I
SP49
BA56
SP49
SP49
BA56
SP49
SP49
BA56
Persistent Lines of Neutral Cadmium 共Cd I兲
Inten
800
400
500
400
500
400
100
150
500
1000
Wavelength 共Å兲
2288.022
3403.652
3466.200
3467.655
3610.508
3612.873
4678.149
4799.912
5085.822
6438.470
A ki (108 s⫺1 )
5.3
0.77
1.2
0.67
1.3
0.35
0.13
0.41
0.56
0.59
Term
J
Level (cm⫺1 )
1
S
P
0
1
5s5 p
5s5d
3 o
P
D
5s5 p
5s5d
3 o
Configuration
Wl Ref
A Ref
0.000
43692.384
BA56
FW96
0
1
30113.990
59485.768
BA56
FW96
P
D
1
2
30656.087
59497.868
BA56
FW96
5s5 p
5s5d
3 o
P
D
1
1
30656.087
59485.768
BA56
FW96
5s5 p
5s5d
3 o
P
D
2
3
31826.952
59515.980
BA56
FW96
5s5 p
5s5d
3 o
P
D
2
2
31826.952
59497.868
BA56
FW96
5s5 p
5s6s
3 o
P
S
0
1
30113.990
51483.980
BA56
FW96
5s5 p
5s6s
3 o
P
S
1
1
30656.087
51483.980
BA56
FW96
5s5 p
5s6s
3 o
P
S
2
1
31826.952
51483.980
BA56
FW96
5s5 p
5s5d
1 o
1
2
43692.384
59219.734
BA56
FW96
2
5s
5s5p
1 o
3
3
3
3
3
3
3
3
1
P
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1624
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Cadmium 共Cd I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
0.000
BA56
5s5p
3 o
P
0
1
2
30113.990
30656.087
31826.952
BA56
BA56
BA56
5s5 p
1 o
P
1
43692.384
BA56
5s6s
3
S
1
51483.980
BA56
5s6s
1
S
0
53310.101
BA56
5s5d
1
D
2
59219.734
BA56
5s5d
3
D
1
2
3
59485.768
59497.868
59515.980
BA56
BA56
BA56
Limit
72540.07
BTG75
5s
2
Cd II ( 2 S1/2)
Persistent Lines of Singly-ionized Cadmium 共Cd II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
1000
2144.408
2.8
1000
1000
500
1000
2265.018
3.0
2312.766
2572.930
1.7
2748.549
2.8
J
Level (cm⫺1 )
S
P
1/2
3/2
S
P
4d 105 p
4d 105d
2 o
Configuration
Term
Wl Ref
A Ref
4d 105s
4d 105 p
2
0.00
46618.55
SP49
FW96
4d 105s
4d 105 p
2
1/2
1/2
0.00
44136.08
SP49
FW96
P
D
3/2
5/2
46618.55
89843.78
SP49
4d 105 p
4d 106s
2 o
P
S
1/2
1/2
44136.08
82990.66
SP49
FW96
4d 105 p
4d 106s
2 o
3/2
1/2
46618.55
82990.66
SP49
FW96
2 o
2 o
2
2
2
P
S
Energy Levels of Singly-ionized Cadmium 共Cd II兲
Ref
Term
4d 105s
2
S
1/2
0.00
SP49
4d 105p
2 o
1/2
3/2
44136.08
46618.55
SP49
SP49
4d 9 5s 2
2
D
5/2
3/2
69258.91
74893.66
SP49
SP49
4d 106s
2
S
1/2
82990.66
SP49
4d 105d
2
D
3/2
5/2
89689.25
89843.78
SP49
SP49
Limit
136374.74
SP49
P
Cd III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
ATOMIC SPECTROSCOPIC DATA
1625
Calcium „Ca…
Atomic number⫽20
Atomic weight⫽40.078
Isotope
40
Ca
Ca
43
Ca
44
Ca
46
Ca
48
Ca
42
Mass
Abundance
Spin
39.962591
41.958618
42.958766
43.955480
45.953689
47.952553
96.941%
0.647%
0.135%
2.086%
0.004%
0.187%
0
0
7/2
0
0
0
Mag moment
⫹1.3173
Ca I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 1S0
Ionization energy: 49 305.95 cm⫺1 共6.113 16 eV兲
Ca II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2S1/2
Ionization energy: 95 751.87 cm⫺1 共11.871 72 eV兲
Strong Lines of Calcium 共Ca兲
Intensity
250
140
250
120
140
700
800
700
700
800
1000
1000
1000
500
500
500
500
500
600
600
400
500
300
500
500
500
500
500
500
500
500
500
600
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
1649.858
1651.991
1840.061
Air
2197.787
2208.611
2275.462
2721.645
3158.869
3179.332
3181.275
3706.026
3736.901
3933.6614
3968.4673
4226.727
4302.527
4307.741
4425.441
4434.960
4435.688
4454.781
4455.887
4456.605
4878.132
5019.971
5188.848
5265.557
5270.270
5349.472
5581.971
5588.757
5590.120
5594.468
5598.487
5857.452
Spectrum
Ref
Ca II
Ca II
Ca II
ER56
ER56
ER56
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
ER56
ER56
R68
R68
ER56
ER56
ER56
ER56
ER56
L99
L99
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
ER56
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
II
II
I
I
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1626
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Calcium 共Ca兲—Continued
Intensity
500
600
600
500
600
700
600
300
700
600
600
600
500
600
700
600
700
300
400
500
600
700
700
400
500
500
400
400
500
500
400
500
300
300
500
400
400
500
500
600
600
1000
1000
900
1000
700
700
500
600
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
6102.722
6122.219
6162.172
6169.055
6169.559
6439.073
6449.810
6456.874
6462.566
6471.660
6493.780
6499.649
6572.777
6717.685
7148.147
7202.194
7326.146
7601.304
8201.720
8248.797
8498.018
8542.089
8662.140
8912.07
8927.36
9213.900
9311.998
9319.560
9320.650
9416.967
9567.965
9599.235
9601.815
9854.74
9890.63
9931.39
10223.04
12816.04
12909.10
13033.57
19046.14
19309.20
19452.99
19505.72
19776.79
19853.10
19862.22
22624.93
22651.23
Spectrum
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
Ca
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
Ref
R68
R68
R68
R68
R68
R68
R68
ER56
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
ER56
ER56
ER56
ER56
ER56
ER56
ER56
R68
R68
R68
R68
R68
R68
R68
R68
ER56
ER56
ER56
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
R68
ATOMIC SPECTROSCOPIC DATA
1627
Persistent Lines of Neutral Calcium 共Ca I兲
Inten
140
1000
500
500
500
600
600
400
500
500
600
600
700
700
600
500
Wavelength 共Å兲
2721.645
4226.727
4425.441
4434.960
4435.688
4454.781
4455.887
A ki (108 s⫺1 )
0.0027
2.20
0.498
0.67
0.342
0.87
0.20
4456.605
5588.757
6102.722
6122.219
6162.172
6439.073
6462.566
6493.780
6572.777
0.49
0.096
0.287
0.354
0.53
0.47
0.44
Term
J
Level (cm⫺1 )
1
S
P
0
1
S
P
4s4 p
4s4d
3 o
Configuration
Wl Ref
A Ref
0.000
36731.615
R68
M03
0
1
0.000
23652.304
R68
M03
P
D
0
1
15157.901
37748.197
R68
FW96
4s4 p
4s4d
3 o
P
D
1
2
15210.063
37751.867
R68
FW96
4s4 p
4s4d
3 o
P
D
1
1
15210.063
37748.197
R68
FW96
4s4 p
4s4d
3 o
P
D
2
3
15315.943
37757.449
R68
FW96
4s4 p
4s4d
3 o
P
D
2
2
15315.943
37751.867
R68
FW96
4s4 p
4s4d
3 o
P
D
2
1
15315.943
37748.197
R68
3d4s
3d4 p
3
D
Do
3
3
20371.000
38259.124
R68
FW96
4s4 p
4s5s
3 o
P
S
0
1
15157.901
31539.495
R68
FW96
4s4 p
4s5s
3 o
P
S
1
1
15210.063
31539.495
R68
FW96
4s4 p
4s5s
3 o
P
S
2
1
15315.943
31539.495
R68
FW96
3d4s
3d4 p
3
D
F
3
4
20371.000
35896.889
R68
FW96
3d4s
3d4 p
3
D
F
2
3
20349.260
35818.713
R68
FW96
3d4s
3d4 p
3
D
F
1
2
20335.360
35730.454
R68
FW96
S
P
0
1
0.000
15210.063
R68
2
4s
4s5p
4s 2
4s4p
4s 2
4s4p
1 o
1
1 o
3
3
3
3
3
3
3
3
3
3
3 o
3 o
3 o
1
3 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1628
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Calcium 共Ca I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
0.000
SC85
4s4p
3 o
P
0
1
2
15157.901
15210.063
15315.943
SC85
SC85
SC85
3d4s
3
D
1
2
3
20335.360
20349.260
20371.000
SC85
SC85
SC85
3d4s
1
D
2
21849.634
SC85
4s4p
1 o
P
1
23652.304
SC85
4s5s
3
S
1
31539.495
SC85
4s5s
1
S
0
33317.264
SC85
3d4 p
3 o
F
2
3
4
35730.454
35818.713
35896.889
SC85
SC85
SC85
3d4p
1
Do
2
35835.413
SC85
4s5 p
3 o
P
0
1
2
36547.688
36554.749
36575.119
SC85
SC85
SC85
4s5 p
1 o
P
1
36731.615
SC85
4s4d
1
D
2
37298.287
SC85
4s4d
3
D
1
2
3
37748.197
37751.867
37757.449
SC85
SC85
SC85
3d4p
3
Do
1
2
3
38192.392
38219.118
38259.124
SC85
SC85
SC85
4p2
3
0
1
2
38417.543
38464.808
38551.558
SC85
SC85
SC85
Limit
49305.95
SC85
4s
2
Ca II ( 2 S1/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
P
ATOMIC SPECTROSCOPIC DATA
1629
Persistent Lines of Singly-ionized Calcium 共Ca II兲
Inten
Wavelength 共Å兲
700
800
700
800
1000
1000
700
700
A ki (108 s⫺1 )
3158.869
3.1
3179.332
3.6
3706.026
0.88
3736.901
1.7
3933.6614
1.35
3968.4673
1.32
8542.089
8662.140
J
Level (cm⫺1 )
P
D
1/2
3/2
4p
4d
2 o
P
D
4p
5s
2 o
Configuration
Term
4p
4d
2 o
Wl Ref
A Ref
25191.51
56839.25
ER56
FW96
3/2
5/2
25414.40
56858.46
ER56
FW96
P
S
1/2
1/2
25191.51
52166.93
ER56
FW96
4p
5s
2 o
P
S
3/2
1/2
25414.40
52166.93
ER56
FW96
4s
4p
2
S
P
1/2
3/2
0.00
25414.40
L99
M03
4s
4p
2
S
P
1/2
1/2
0.00
25191.51
L99
M03
3d
4p
2
D
P
5/2
3/2
13710.88
25414.40
ER56
3d
4p
2
D
P
3/2
1/2
13650.19
25191.51
ER56
2
2
2
2
2 o
2 o
2 o
2 o
Energy Levels of Singly-ionized Calcium 共Ca II兲
Ref
Term
4s
2
S
1/2
3d
2
D
3/2
5/2
13650.20
13710.89
SC85
SC85
4p
2 o
P
1/2
3/2
25191.518
25414.414
L99
L99
5s
2
S
1/2
52166.94
SC85
4d
2
D
3/2
5/2
56839.26
56858.47
SC85
SC85
5p
2 o
P
1/2
3/2
60533.03
60611.29
SC85
SC85
4f
2 o
F
5/2,7/2
68056.92
SC85
6s
2
S
1/2
70677.63
SC85
Limit
95751.88
SC85
Ca III ( 1 S0 )
J
Level (cm⫺1 )
Configuration
0.000
L99
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1630
J. E. SANSONETTI AND W. C. MARTIN
Californium „Cf…
Atomic number⫽98
Atomic weight⫽(251)
Isotope
249
Cf
Cf
252
Cf
251
Mass
Abundance
Spin
249.074844
251.079580
252.081621
0
0
0
9/2
1/2
0
Mag moment
Cf I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 107s 2 5I8
Ionization energy: 50 665 cm⫺1 共6.2817 eV兲
Cf II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 107s (8,1/2) 17/2
Ionization energy: 关95 000兴 cm⫺1 共11.8 eV兲
Strong Lines of Californium 共Cf兲
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Wavelength 共Å兲
P,s
P
l
s
P
P
l
l
P
P,s
s
P,l
l
s
P,l
P
b,s
s
s
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2739.31
2759.10
2774.52
2852.03
2855.24
3298.14
3352.71
3367.79
3392.22
3481.07
3513.47
3531.49
3540.98
3598.77
3605.32
3612.11
3617.49
3626.76
3659.46
3662.70
3699.49
3722.11
3739.35
3785.61
3789.04
3893.23
3993.57
4035.45
4099.12
4242.38
4329.03
4335.22
5173.96
5179.08
5219.24
5279.01
5320.09
5339.13
5408.88
Spectrum
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
II
II
II
II
II
I
I
II
I
I
II
I
I
I
I
I
I
II
I
I
II
II
I
I
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
Ref
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
ATOMIC SPECTROSCOPIC DATA
1631
Strong Lines of Californium 共Cf兲—Continued
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Wavelength 共Å兲
Spectrum
5726.05
6622.83
6631.26
6677.90
6894.59
6927.10
7074.52
7307.90
8141.29
8241.77
8333.85
8423.49
8568.83
9228.52
9337.70
9649.51
10308.41
10568.83
10614.84
11300.19
11681.85
11941.33
12183.05
12352.72
12437.48
12787.41
13329.98
13362.98
13376.89
13474.44
14772.49
15281.32
15587.12
15675.92
16759.06
17626.25
18718.69
19068.71
19336.96
19576.84
20393.38
20869.98
P
l
s
P
l
s
l
s
P
P,l
s
s
P,l
l
s
P,l
l
l
s
P
s
l
h
l
l
l
s
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Cf
Ref
I
I
I
I
I
II
I
I
I
II
II
II
II
I
I
I
I
I
I
I
I
I
II
I
I
I
II
I
II
I
II
I
II
I
II
I
I
I
I
I
I
I
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
CWBV77
Persistent Lines of Neutral Californium 共Cf I兲
Inten
Wavelength 共Å兲
1000
3298.14
A ki (108 s⫺1 )
Configuration
5 f 107s 2
Term
J
Level (cm⫺1 )
Wl Ref
5
8
7
0.000
30311.400
RCWM80
8
8
0.000
29818.055
RCWM80
I
o
1000
3352.71
5 f 107s 2
5 f 9 6d7s 2
5
I
o
1000
3598.77
5 f 107s 2
5 f 10( 5 I8 )7s7p( 1 Po1 )
5
I
(8,1) o
8
9
0.000
27779.345
RCWM80
1000
4329.03
5 f 107s 2
5 f 10( 5 I8 )7s7p( 1 Po2 )
5
8
9
0.000
23093.355
RCWM80
I
(8,2) o
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1632
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Californium 共Cf I兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
5
Configuration
10
2
Term
1000
5408.88
5 f 7s
5 f 10( 5 I8 )7s7p( 3 Po1 )
I
(8,1) o
8
9
0.000
18483.060
RCWM80
1000
8141.29
o
)6d 3/27s 2
5 f 9 ( 6 H15/2
9 6 o
5 f ( H15/2)7s 2 7 p 3/2
(15/2,3/2) o
共15/2,3/2兲
9
9
19907.460
32187.145
RCWM80
1000
11941.33
o
)6d 3/27s 2
5 f 9 ( 6 H15/2
9 6 o
5 f ( H15/2)7s 2 7 p 1/2
(15/2,3/2) o
共15/2,1/2兲
8
8
16909.535
25281.530
CWBV77
1000
12787.41
o
)6d 3/27s 2
5 f 9 ( 6 H15/2
9 6 o
5 f ( H15/2)7s 2 7 p 1/2
(15/2,3/2) o
共15/2,1/2兲
8
7
16909.535
24727.600
CWBV77
A Ref
Energy Levels of Neutral Californium 共Cf I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5 f 107s 2
5
8
7
6
4
5
0.000
9078.145
11074.390
15375.470
15846.145
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 107s 2
5
5
8516.380
BW92b
10
2
3
2
10589.250
BW92b
5 f 107s 2
5
4
13965.750
BW92b
o
)6d 3/27s 2
5 f 9 ( 6 H15/2
(15/2,3/2) o
8
7
6
9
16909.535
17308.170
19055.82
19907.460
BW92b
BW92b
BW92b
BW92b
5 f 10( 5 I8 )7s7p( 3 Po0 )
(8,0) o
8
17459.210
BW92b
I8 )7s7p( 3 Po1 )
o
9
8
7
18483.060
19303.065
19322.220
BW92b
BW92b
BW92b
5 f 10( 5 I8 )7s7p( 3 Po2 )
(8,2) o
9
23093.355
BW92b
o
5 f 9 ( 6 H15/2
)7s 2 7p 1/2
共15/2,1/2兲
7
8
24727.600
25281.530
BW92b
BW92b
5 f 10( 5 I8 )7s7p( 1 Po1 )
(8,1) o
9
27779.345
BW92b
o
8
29818.055
BW92b
o
7
30311.400
BW92b
共15/2,3/2兲
9
32187.145
BW92b
50665
KDEE97
5 f 7s
10 5
5f (
9
5 f 6d7s
I
F
P
F
2
o
)7s 2 7p 3/2
5 f 9 ( 6 H15/2
Cf II (5 f 10( 5 I8 )7s (8,1/2) 17/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
(8,1)
Limit
ATOMIC SPECTROSCOPIC DATA
1633
Persistent Lines of Singly-ionized Californium 共Cf II兲
Inten
Wavelength 共Å兲
1000
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
5 f ( I8 )7s
5 f 10( 5 I8 )7p 3/2
共8,1/2兲
17/2
17/2
0.00
36233.01
RCWM80
o
Configuration
10 5
2759.10
A Ref
1000
2774.52
5 f 10( 5 I8 )7s
5 f 10( 5 I8 )7p 3/2
共8,1/2兲
(8,3/2) o
17/2
19/2
0.00
36031.74
RCWM80
1000
3626.76
5 f 10( 5 I8 )7s
5 f 10( 5 I8 )7p 1/2
共8,1/2兲
(8,1/2) o
17/2
17/2
0.00
27564.94
RCWM80
1000
3722.11
5 f 10( 5 I8 )7s
5 f 10( 5 I8 )7p 1/2
共8,1/2兲
(8,1/2) o
17/2
15/2
0.00
26858.90
RCWM80
1000
3993.57
5 f 10( 5 I8 )7s
5 f 9 6d7s
共8,1/2兲
15/2
17/2
1180.52
26213.78
RCWM80
o
1000
6927.10
5 f 10( 5 I8 )6d 3/2
5 f 10( 5 I8 )7p 3/2
共8,3/2兲
(8,3/2) o
19/2
19/2
21599.67
36031.74
RCWM80
1000
12183.05
5 f 10( 5 I8 )6d 3/2
5 f 10( 5 I8 )7p 1/2
共8,3/2兲
(8,1/2) o
15/2
17/2
19359.06
27564.94
CWBV77
1000
13376.89
5 f 10( 5 I8 )6d 3/2
5 f 10( 5 I8 )7p 1/2
共8,3/2兲
(8,1/2) o
17/2
17/2
20091.38
27564.94
CWBV77
1000
16759.06
5 f 10( 5 I8 )6d 3/2
5 f 10( 5 I8 )7 p1/2
共8,3/2兲
(8,1/2) o
19/2
17/2
21599.67
27564.94
CWBV77
Energy Levels of Singly-ionized Californium 共Cf II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
5 f ( I8 )7s
共8,1/2兲
17/2
15/2
0.00
1180.52
BW92b
BW92b
5 f 10( 5 F5 )7s
共5,1/2兲
11/2
9/2
8852.05
9633.09
BW92b
BW92b
5 f 10( 5 I7 )7s
共7,1/2兲
15/2
13/2
9350.19
9922.27
BW92b
BW92b
5 f 10( 5 I8 )6d 3/2
共8,3/2兲
15/2
17/2
13/2
19/2
19359.06
20091.38
20445.10
21599.67
BW92b
BW92b
BW92b
BW92b
5 f 9 6d7s
o
19/2
24213.34
BW92b
5 f 9 6d7s
o
17/2
26213.78
BW92b
5 f 10( 5 I8 )7p 1/2
(8,1/2) o
15/2
17/2
26858.90
27564.94
BW92b
BW92b
5 f 10( 5 I8 )7p 3/2
(8,3/2) o
19/2
36031.74
BW92b
5 f 10( 5 I8 )7p 3/2
(8,3/2) o
17/2
36233.01
BW92b
10 5
Cf III ( 5 I8 )
Limit
关95000兴
CNWM70
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1634
J. E. SANSONETTI AND W. C. MARTIN
Carbon „C…
Atomic number⫽6
Atomic weight⫽12.011
Isotope
12
13
C
C
Mass
Abundance
Spin
Mag moment
12.000000
13.003355
98.90%
1.10%
0
1/2
⫹0.70241
C I Ground state: 1s 2 2s 2 2p 2 3P0
Ionization energy: 90 820.45 cm⫺1 共11.260 30 eV兲
o
C II Ground state: 1s 2 2s 2 2p 2P1/2
⫺1
Ionization energy: 196 664.7 cm 共24.3833 eV兲
Strong Lines of Carbon 共C兲
Intensity
600
1000
150
300
750
150
250
500
300*
300*
400
100
200
400
800
200
1000
800
200
100
80
150
200
500
200
600
500
400
1000
400
400
500
500
1000
400
500
400
400
300
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
h
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
687.0526
687.346
903.6235
903.9616
904.1416
904.4801
1036.3367
1037.0182
1193.0088
1193.0308
1193.2402
1193.2644
1261.5520
1277.2452
1277.2824
1277.5131
1277.5497
1280.3330
1329.5775
1329.6005
1334.5323
1335.7077
1560.309
1560.682
1560.709
1561.438
1656.267
1656.928
1657.008
1657.379
1657.907
1658.121
1751.827
1930.906
Air
2478.561
2836.710
2837.603
2992.618
3918.978
Spectrum
Ref
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
J66
J66
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
C
C
C
C
C
I
II
II
II
II
J66
MG93
MG93
MG93
MG93
ATOMIC SPECTROSCOPIC DATA
1635
Strong Lines of Carbon 共C兲—Continued
Intensity
Wavelength 共Å兲
400 P
400 P
500 P,c
300
200
150
300
150
400 P
300
400 P
500 P
250 P
220
150
400 P
150
150
90
140 P
110 P
50
3920.693
4267.003
4267.258
5145.16
5151.09
5380.34
5889.77
6013.22
6578.05
6582.88
7231.32
7236.42
8335.15
9094.83
9111.80
9405.73
9658.44
10691.25
11748.22
11753.32
11754.76
16890.38
Spectrum
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Ref
II
II
II
II
II
I
II
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
MG93
MG93
MG93
MG93
MG93
J66
MG93
J66
MG93
MG93
MG93
MG93
J66
J66
J66
J66
J66
J66
JL65
JL65
JL65
JL65
Persistent Lines of Neutral Carbon 共C I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
400
1277.2452
1.27
2s 2 2 p 2
2s 2 2 p( 2 Po)3d
800
200
1000
800
500
200
600
500
400
1000
1277.2824
1277.5131
1277.5497
1280.3330
1560.682
1560.709
1561.438
1656.267
1656.928
1657.008
1.73
0.912
2.31
0.577
0.908
0.505
1.21
0.858
1.13
2.52
2s 2 2 p 2
2s 2 2 p( 2 Po)3d
2s 2 2 p 2
2s 2 2 p( 2 Po)3d
2s 2 2 p 2
2s 2 2 p( 2 Po)3d
2s 2 2 p 2
2s 2 2 p( 2 Po)4s
2s 2 2 p 2
2s2 p 3
2s 2 2 p 2
2s2 p 3
2s 2 2 p 2
2s2 p 3
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
Term
J
Level (cm⫺1 )
Wl Ref
3
P
Do
0
1
0.00000
78293.50
KE74
WFD96
P
Do
1
2
16.41671
78307.62
KE74
WFD96
P
Do
1
1
16.41671
78293.50
KE74
WFD96
P
Do
2
3
43.41350
78318.23
KE74
WFD96
P
P
2
2
43.41350
78148.09
KE74
WFD96
P
Do
1
2
16.41671
64090.97
KE74
M03
P
Do
1
1
16.41671
64089.86
KE74
M03
P
Do
2
3
43.41350
64086.95
KE74
M03
P
P
1
2
16.41671
60393.15
KE74
WFD96
P
P
0
1
0.00000
60352.64
KE74
WFD96
P
P
2
2
43.41350
60393.15
KE74
WFD96
3
3
3
3
3
3
3
3
3 o
3
3
3
3
3
3
3
3 o
3
3 o
3
3 o
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1636
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Carbon 共C I兲—Continued
Wavelength 共Å兲
Inten
400
A ki (108 s⫺1 )
1657.379
400
0.864
1657.907
500
3.43
1658.121
500
1.44
1751.827
1000
0.907
1930.906
400
3.51
2478.561
250
0.340
8335.15
400
0.351
9405.73
140
0.291
11753.32
101
0.263
11754.76
0.240
Term
J
Level (cm⫺1 )
Wl Ref
3
P
P
1
1
16.41671
60352.64
KE74
WFD96
P
P
1
0
16.41671
60333.43
KE74
WFD96
P
P
2
1
43.41350
60352.64
KE74
WFD96
S
P
0
1
21648.02
78731.28
KE74
WFD96
D
P
2
1
10192.66
61981.82
KE74
WFD96
S
P
0
1
21648.02
61981.82
J66
WFD96
2s 2 2 p( 2 Po)3s
2s 2 2 p( 2 Po)3p
1 o
P
S
1
0
61981.82
73975.91
J66
WFD96
2s 2 2 p( 2 Po)3s
2s 2 2 p( 2 Po)3p
1 o
P
D
1
2
61981.82
72610.73
J66
WFD96
2s 2 2 p( 2 Po)3p
2s 2 2 p( 2 Po)3d
3
D
F
3
4
69744.03
78249.93
JL65
WFD96
2s 2 2 p( 2 Po)3p
2s 2 2 p( 2 Po)3d
3
D
F
2
3
69710.67
78215.50
JL65
WFD96
Configuration
2
2
2s 2 p
2s 2 2 p( 2 Po)3s
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
2s 2 2 p 2
2s 2 2 p( 2 Po)3d
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
2s 2 2 p 2
2s 2 2 p( 2 Po)3s
3 o
3
3 o
3
3 o
1
1 o
1
1 o
1
1 o
1
1
3 o
3 o
A Ref
Energy Levels of Neutral Carbon 共C I兲
Configuration
Term
J
Level (cm⫺1 )
2s 2 2p 2
3
0
1
2
0.00000
16.41671
43.41350
2s 2 2p 2
1
2
10192.66
KW66
2s 2 2p 2
1
S
0
21648.02
KW66
5 o
S
2
33735.22
J66
2s 2 2p( 2 Po)3s
3 o
P
0
1
2
60333.43
60352.64
60393.15
CG98
CG98
CG98
2s 2 2p( 2 Po)3s
1 o
1
61981.82
CG98
2s2 p 3
3
Do
3
1
2
64086.95
64089.86
64090.97
CG98
CG98
CG98
2s 2 2p( 2 Po)3p
1
P
1
68856.34
CG98
2s 2 2p( 2 Po)3p
3
D
1
2
3
69689.47
69710.67
69744.03
CG98
CG98
CG98
2s 2 2p( 2 Po)3p
3
S
1
70743.95
CG98
2s2p
3
P
D
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
YS91
YS91
YS91,CSBE86
ATOMIC SPECTROSCOPIC DATA
1637
Energy Levels of Neutral Carbon 共C I兲—Continued
Term
J
Level (cm⫺1 )
Ref
2s 2p( P )3p
3
P
0
1
2
71352.52
71364.92
71385.39
CG98
CG98
CG98
2s 2 2p( 2 Po)3p
1
D
2
72610.73
CG98
2s 2 2p( 2 Po)3p
1
S
0
73975.91
CG98
2s2p 3
3 o
P
1
2
0
75253.98
75255.28
75256.15
CG98
CG98
CG98
2s 2 2p( 2 Po)3d
1
Do
2
77679.83
CG98
2s 2 2p( 2 Po)4s
3 o
P
0
1
2
78104.97
78116.75
78148.09
CG98
CG98
CG98
2s 2 2p( 2 Po)3d
3 o
F
2
3
4
78199.06
78215.50
78249.93
CG98
CG98
CG98
2s 2 2p( 2 Po)3d
3
Do
1
2
3
78293.50
78307.62
78318.23
CG98
CG98
CG98
2s 2 2p( 2 Po)3d
1 o
1
78731.28
CG98
Limit
90820.45
J66
Configuration
2
2 o
P
o
)
C II ( 2 P1/2
Persistent Lines of Singly-ionized Carbon 共C II兲
Inten
600
1000
750
250
500
80
150
500
400
Wavelength 共Å兲
687.053
687.345
904.142
1036.3367
1037.0182
1334.5323
1335.7077
2836.710
2837.603
A ki (108 s⫺1 )
23.7
28.4
34.2
7.34
14.7
2.40
2.88
0.398
0.397
Configuration
2 1
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
2s ( S)2p
2s 2 ( 1 S)3d
2 o
P
D
1/2
3/2
0.00
145549.27
KE74
WFD96
2s 2 ( 1 S)2p
2s 2 ( 1 S)3d
2 o
P
D
3/2
5/2
63.42
145550.70
KE74
WFD96
2s 2 ( 1 S)2p
2s2 p 2
2 o
P
P
3/2
3/2
63.42
110665.56
KE74
WFD96
2s 2 ( 1 S)2p
2s2 p 2
2 o
P
S
1/2
1/2
0.00
96493.74
KE74
M03
2s 2 ( 1 S)2p
2s2 p 2
2 o
P
S
3/2
1/2
63.42
96493.74
KE74
M03
2s 2 ( 1 S)2p
2s2 p 2
2 o
P
D
1/2
3/2
0.00
74932.62
KE74
M03
2s 2 ( 1 S)2p
2s2 p 2
2 o
P
D
3/2
5/2
63.42
74930.10
KE74
M03
S
P
1/2
3/2
96493.74
131735.52
MG93
WFD96
S
P
1/2
1/2
96493.74
131724.37
MG93
WFD96
2s2 p 2
2s 2 ( 1 S)3p
2s2p 2
2s 2 ( 1 S)3p
2
2
2
2
2
2
2
2
2 o
2
2 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1638
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Carbon 共C II兲—Continued
Inten
Wavelength 共Å兲
300
400
400
500
3918.978
3920.693
4267.003
4267.258
A ki (108 s⫺1 )
0.636
1.27
2.23
2.38
0.159
400
400
500
6578.05
7231.32
7236.42
0.363
0.352
0.422
Configuration
2 1
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
2s ( S)3p
2s 2 ( 1 S)4s
2 o
P
S
1/2
1/2
131724.37
157234.07
MG93
WFD96
2s 2 ( 1 S)3p
2s 2 ( 1 S)4s
2 o
P
S
3/2
1/2
131735.52
157234.07
MG93
WFD96
2s 2 ( 1 S)3d
2s 2 ( 1 S)4 f
2
D
F
3/2
5/2
145549.27
168978.34
MG93
WFD96
2s 2 ( 1 S)3d
2s 2 ( 1 S)4 f
2
D
F
5/2
7/2
145550.70
168978.34
MG93
WFD96
2s 2 ( 1 S)3d
2s 2 ( 1 S)4 f
2
D
F
5/2
5/2
145550.70
168978.34
2s 2 ( 1 S)3s
2s 2 ( 1 S)3p
2
S
P
1/2
3/2
116537.65
131735.52
MG93
WFD96
2s 2 ( 1 S)3p
2s 2 ( 1 S)3d
2 o
P
D
1/2
3/2
131724.37
145549.27
MG93
WFD96
2s 2 ( 1 S)3p
2s 2 ( 1 S)3d
2 o
3/2
5/2
131735.52
145550.70
MG93
WFD96
2
2
2 o
2 o
2 o
2 o
2
2
P
D
WFD96
Energy Levels of Singly-ionized Carbon 共C II兲
Configuration
2 1
Term
J
Level (cm⫺1 )
Ref
2s ( S)2p
2 o
1/2
3/2
2s2 p 2
4
1/2
3/2
5/2
43003.3
43025.3
43053.6
MG93
MG93
MG93
2s2p 2
2
5/2
3/2
74930.10
74932.62
MG93
MG93
2s2p 2
2
1/2
96493.74
MG93
2s2p 2
2
P
1/2
3/2
110624.17
110665.56
MG93
MG93
2s 2 ( 1 S)3s
2
S
1/2
116537.65
MG93
2s 2 ( 1 S)3p
2 o
P
1/2
3/2
131724.37
131735.52
MG93
MG93
2p3
4 o
S
3/2
142027.1
MG93
2s 2 ( 1 S)3d
2
D
3/2
5/2
145549.27
145550.70
MG93
MG93
2p3
2
Do
5/2
3/2
150461.58
150466.69
MG93
MG93
2s 2 ( 1 S)4s
2
P
P
D
S
0.00
63.42
MG93
MG93
S
1/2
157234.07
MG93
2s ( S)4p
2 o
P
1/2
3/2
162517.89
162524.57
MG93
MG93
2s2 p( 3 Po)3s
4 o
1/2
3/2
5/2
166967.13
166990.73
167035.71
MG93
MG93
MG93
2 1
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1639
Energy Levels of Singly-ionized Carbon 共C II兲—Continued
Configuration
2 1
Term
J
Level (cm⫺1 )
Ref
2s ( S)4d
2
D
3/2
5/2
168123.74
168124.45
MG93
MG93
2p 3
2 o
P
1/2
3/2
168729.53
168748.30
MG93
MG93
2s 2 ( 1 S)4 f
2 o
5/2,7/2
168978.34
MG93
Limit
196664.7
MG93
C III ( 1 S0 )
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1640
J. E. SANSONETTI AND W. C. MARTIN
Cerium „Ce…
Atomic number⫽58
Atomic weight⫽140.115
Isotope
136
Ce
Ce
140
Ce
142
Ce
138
Mass
Abundance
Spin
135.907140
137.905985
139.905433
141.909241
0.19%
0.25%
88.48%
11.08%
0
0
0
0
Mag moment
Ce I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 5d6s 2 1Go4
Ionization energy: 44 672 cm⫺1 共5.5387 eV兲
o
Ce II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 5d 2 4H7/2
⫺1
Ionization energy: 87 500 cm 共10.85 eV兲
Strong Lines of Cerium 共Ce兲
Intensity
Wavelength 共Å兲
200
200
300
200
250
200
200
300
200
200
300
300
200
500 P
250
250
300
300
400
250
200
200
250
700 P
250
300
300
250
250
300
300
200
200
300
400
300
200
200
Air
3063.008
3194.821
3201.712
3218.944
3221.171
3227.114
3234.161
3272.253
3485.046
3539.076
3560.798
3577.450
3653.664
3655.843
3660.639
3667.976
3709.285
3709.926
3716.364
3728.414
3764.115
3781.616
3786.628
3801.520
3803.086
3808.110
3838.535
3848.595
3853.148
3854.187
3854.320
3855.301
3876.971
3878.358
3882.447
3889.984
3895.113
3907.286
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
ATOMIC SPECTROSCOPIC DATA
1641
Strong Lines of Cerium 共Ce兲—Continued
Intensity
300
200
200
200
600 P
800 P
200
900 P
300
200
200
200
200
250
800 P
250
250
800 P
250
250
250
250
600 P
250
200
200
300
300
500
400
400
200
250
200
300
300
800 P
600 P
200
200
300
400
400
200
1000 P
200
250
250*
250*
400
200
300
300
200
200
600 P
400
200
200
Wavelength 共Å兲
3912.426
3918.269
3931.082
3940.326
3942.157
3942.746
3943.881
3952.545
3956.275
3960.913
3967.044
3984.671
3992.381
3993.818
3999.237
4003.769
4005.232
4012.387
4014.897
4024.487
4028.404
4031.332
4040.752
4042.578
4046.337
4053.500
4055.836
4071.773
4073.475
4075.698
4075.844
4081.219
4083.219
4118.141
4123.873
4127.371
4133.802
4137.649
4142.397
4144.996
4149.895
4151.969
4165.600
4166.881
4186.596
4196.330
4198.715
4202.926
4202.956
4222.598
4227.747
4239.909
4248.668
4255.779
4270.186
4289.935
4296.680
4300.327
4306.722
Spectrum
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
M75c
C73
C73
C73
C73
C73
C73
C73
C73
C73
M75c
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1642
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Cerium 共Ce兲—Continued
Intensity
300
200
250
250
200
500
300
200
200
200
700
400
200
200
250
250
200
250
250
250
200
600
300
250
500
500
300
300
400
300
400
600
300
300
400
500
250
800
800
500
110
500
700
500
700
100
400
400
400
300
400
70
300
500
400
250
600
500
600
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4337.773
4349.788
4364.650
4382.164
4386.826
4391.660
4418.778
4429.265
4449.322
4450.727
4460.204
4471.237
4479.358
4483.891
4486.905
4506.413
4523.077
4527.349
4528.472
4539.745
4560.283
4562.358
4572.281
4593.924
4628.157
4632.320
4650.509
4822.547
4847.774
4943.44
4994.627
5009.098
5040.846
5071.775
5112.703
5129.569
5149.993
5159.686
5161.484
5174.554
5187.459
5211.877
5223.461
5229.745
5245.916
5274.230
5296.563
5328.082
5397.638
5420.380
5449.239
5512.049
5556.252
5564.966
5565.965
5595.875
5601.280
5655.140
5669.959
Spectrum
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
II
I
I
I
I
I
II
I
I
I
I
I
I
I
Ref
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
C73
M75c
C73
C73
C73
C73
C73
C73
C73
C73
C73
BWCC91
M75c
M75c
M75c
MCS75
BWCC91
M75c
M75c
M75c
M75c
M75c
BWCC91
M75c
M75c
M75c
C73
BWCC91
M75c
M75c
M75c
C73
M75c
M75c
M75c
BWCC91
BWCC91
C73
BWCC91
M75c
M75c
BWCC91
M75c
M75c
M75c
ATOMIC SPECTROSCOPIC DATA
1643
Strong Lines of Cerium 共Ce兲—Continued
Intensity
300
300
800
1000
600
400
300
300
250
150
200
250
600
150
150
150
200
300
30
150
90
90
90
90
120
90
90
90
13
90
90
90
90
80
90
80
80
10
10
90
90
9
60
50
P
P
P
P
Wavelength 共Å兲
5677.752
5692.943
5696.993
5699.226
5719.031
5773.122
5788.143
5812.919
5862.491
5926.301
5928.342
5937.720
5940.857
6001.901
6005.861
6006.817
6013.419
6024.193
6043.378
6047.397
6057.995
6069.484
6072.006
6093.192
6123.673
6186.173
6208.985
6228.936
6272.024
6295.574
6310.013
6430.067
6458.031
6555.645
6704.272
6924.813
6986.015
7061.75
7086.35
7252.710
7397.764
8025.57
8120.367
8495.829
Spectrum
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
II
I
I
II
I
I
Ref
BWCC91
BWCC91
M75c
M75c
M75c
BWCC91
BWCC91
M75c
BWCC91
BWCC91
BWCC91
BWCC91
M75c
M75c
BWCC91
BWCC91
BWCC91
BWCC91
C73
BWCC91
M75c
M75c
BWCC91
M75c
BWCC91
BWCC91
BWCC91
M75c
C73
BWCC91
BWCC91
M75c
BWCC91
BWCC91
BWCC91
BWCC91
BWCC91
C73
C73
BWCC91
BWCC91
C73
BWCC91
BWCC91
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1644
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Cerium 共Ce I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
Wl Ref
500
4632.320
4 f 5d6s
4 f 5d( 3 Ho)6s6p( 3 Po)
G
4
5
0.000
21581.408
BWCC91
600
5009.098
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
5 o
I
4
3
3196.607
23154.693
M75c
800
5159.686
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
5 o
7
6
5315.803
24691.432
M75c
800
5161.484
4 f 2 6s 2
4 f 2 ( 3 H6 )6s6p( 1 Po1 )
3
H
(6,1) o?
6
7
7780.202
27149.080?
M75c
700
5223.461
4 f 2 6s 2
4 f 2 ( 3 H4 )6s6p( 1 Po1 )
3
H
(4,1) o
4
4
4762.718
23901.786
M75c
700
5245.916
4 f 2 6s 2
4 f 2 ( 3 H4 )6s6p( 1 Po1 )
3
H
(4,1) o
4
5
4762.718
23819.871
M75c
600
5601.280
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Io)6p
5 o
I
I
8
8
6809.128
24657.245
M75c
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Ho)6p
o
5
6
3210.583
20842.504
M75c
I
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Io)6p
5 o
I
K
7
8
5315.803
22864.055
M75c
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Io)6p
5 o
I
K
8
9
6809.128
24350.503
M75c
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Ho)6p
5
Ho
I
7
8
5802.108
23282.722
M75c
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Io)6p
5 o
5
6
3764.008
20591.937
M75c
5669.959
800
5696.993
1000
5699.226
600
5719.031
600
5940.857
o
Level (cm⫺1 )
1
600
2
J
I
5
5
5
5
5
5
I
K
A Ref
Energy Levels of Neutral Cerium 共Ce I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
o
G
4
0.000
MZH78
4 f 5d6s 2
3 o
2
3
4
228.849
1663.120
3100.151
MZH78
MZH78
MZH78
4 f 5d6s 2
3
4
5
6
1279.424
2208.657
3976.104
MZH78
MZH78
MZH78
4 f 5d6s 2
3
Go
3
5
1388.941
4199.367
MZH78
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
5
Ho
3
4
6
7
2369.068
2437.629
4746.627
5802.108
MZH78
MZH78
MZH78
MZH78
4 f 5d6s 2
1
2
2378.827
MZH78
4 f 5d6s
2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
F
Ho
Do
ATOMIC SPECTROSCOPIC DATA
1645
Energy Levels of Neutral Cerium 共Ce I兲—Continued
Term
J
Level (cm⫺1 )
4 f ( F )5d ( F)6s( F)
5 o
4
5
6
7
8
3196.607
3764.008
4455.756
5315.803
6809.128
MZH78
MZH78
MZH78
MZH78
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
5
3210.583
MZH78
4 f 5d6s 2
o
4
3312.240
MZH78
2
3
1
2
3
3710.513
4766.323
5006.719
MZH78
MZH78
MZH78
Configuration
2 o
4 f 5d6s
2 3
4
I
o
D
Ref
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
0
3974.503
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
1
4020.954
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
3
Go
3
4160.283
MZH78
4 f ( F )5d ( F)6s( F)
o
4
4173.494
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
5
4417.618
MZH78
4 f 2 6s 2
3
H
4
5
6
4762.718
6238.934
7780.202
MZH78
MZH78
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
3 o
1
5097.777
MZH78
4 f ( F )5d ( F)6s( F)
o
2
5210.906
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
5
2
3
4
5
6
5409.236
6234.792
6856.559
7467.160
8055.526
MZH78
MZH78
MZH78
MZH78
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
3
5519.751
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
0
5571.156
MZH78
4 f ( F )5d ( F)6s( F)
o
4
5572.074
MZH78
4 f 5d6s 2
o
1
5637.233
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
5 o
1
2
3
4
5
5674.829
5904.006
6337.061
7174.156
7933.558
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 5d6s 2
o
2
6303.984
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 2 F)
o
4
6475.540
MZH78
4 f 5d6s 2
o
3
6621.892
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
5
6663.226
MZH78
4 f ( F )5d ( F)6s( F)
o
2
6836.628
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
3
7169.751
MZH78
2 o
2 o
2 o
2 o
2 3
2 3
2 3
2 3
4
4
4
4
S
Go
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1646
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Cerium 共Ce I兲—Continued
Term
J
Level (cm⫺1 )
4 f ( F )5d ( F)6s( F)
o
4
7348.299
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
6
7696.210
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)?
o
5
7715.236
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 2 F)?
o
5
7841.955
MZH78
4 f ( F )5d ( D)6s( D)
o
1
7853.119
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
o
4
7890.429
MZH78
4 f ( 2 Fo)5d 2 ( 3 P)6s( 4 P)
5
Go
2
3
4
5
6
8088.912
8307.309
8762.126
9462.705
11030.470
MZH78
MZH78
MZH78
MZH78
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)6s( 4 F)
5 o
2
3
1
8101.187
8270.249
8430.846
MZH78
MZH78
MZH78
4 f 2 6s 2
3
F
2
3
4
8235.605
9206.305
9379.148
MZH78
MZH78
MZH78
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Io)6 p
5
K
5
6
7
8
9
19791.740
20591.937
21654.060
22864.055
24350.503
MZH78
MZH78
MZH78
MZH78
MZH78
5
20338.893
MZH78
6
7
8
20842.504
22063.473
23282.722
MZH78
MZH78
MZH78
5
21581.408
MZH78
5
6
7
8
21725.348
22321.098
23452.626
24657.245
MZH78
MZH78
MZH78
MZH78
3
23154.693
MZH78
5
4
3
23819.871
23901.786
—
MZH78
MZH78
6
24691.432
MZH78
7
5
6
27149.080?
27192.300?
27491.670
M75c
MZH78
MZH78
44672
WSPC78
Configuration
2 o
2 o
2 3
2
2 1
2
P
4 f 5d( 3 Go)6s6p( 3 Po)
2 o
2 3
4
o
4 f ( F )5d ( F)( H )6 p
5
I
4 f 5d( 3 Ho)6s6p( 3 Po)
4 f ( 2 Fo)5d 2 ( 3 F)( 4 Io)6 p
2 3
4f (
H4 )6s6p( 1 Po1 )
4 f 2 ( 3 H6 )6s6p( 1 Po1 )?
o
)
Ce II ( 4 H7/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5
I
(4,1)
o
(6,1) o?
Limit
Ref
ATOMIC SPECTROSCOPIC DATA
1647
Persistent Lines of Singly-ionized Cerium 共Ce II兲
Inten
500
700
600
800
Wavelength 共Å兲
3655.843
3801.520
3942.157
3942.746
A ki (108 s⫺1 )
0.47
1.7
0.43
1.4
Configuration
2 o
2 3
J
Level (cm⫺1 )
I
H
11/2
9/2
Go
H
Term
Wl Ref
A Ref
2563.233
29908.904
C73
BPQ01
11/2
13/2
7233.627
33531.388
C73
BPQ01
Ho
G
7/2
5/2
0.000
25359.686
C73
BPQ01
Ho
I
13/2
15/2
6913.392
32269.252
C73
BPQ01
4 f ( F )5d ( F)
4 f 5d( 3 Go)6p
4 o
4 f 5d( 3 Go)6s
4 f 5d( 3 Go)6p
4
4 f ( 2 Fo)5d 2 ( 3 F)
4 f 5d( 3 Fo)6p
4
4 f 5d( 3 Ho)6s
4 f 5d( 3 Ho)6p
4
4
4
4
4
900
3952.545
0.38
4 f 5d( 1 Go)6s
4 f 5d( 3 Ho)6p
o
7/2
9/2
2641.559
27934.638
C73
BPQ01
800
3999.237
0.061
4 f 5d( 1 Go)6s
4 f 5d( 1 Go)6p
o
9/2
11/2
2382.246
27379.949
C73
BPQ01
800
4012.387
0.80
4 f 5d( 3 Ho)6s
4 f 5d( 3 Ho)6p
4
9/2
11/2
4523.033
29438.817
C73
BPQ01
600
4040.752
0.81
4 f 5d( 1 Go)6s
4 f 5d( 3 Ho)6p
o
9/2
9/2
3593.882
28334.756
C73
BPQ01
800
4133.802
0.076
4 f 2 ( 3 H)6s
4 f 2 ( 3 H6 )6p 3/2
4
H
(6,3/2) o
13/2
11/2
6967.547
31151.534
C73
BPQ01
600
4137.649
0.89
4 f 2 ( 3 H)6s
4 f 2 ( 3 H4 )6p 3/2
4
H
(4,3/2) o
9/2
11/2
4165.550
28327.071
C73
BPQ01
1000
4186.596
1.3
4 f 2 ( 3 H)6s
4 f 2 ( 3 H6 )6p 3/2
4
13/2
15/2
6967.547
30846.582
C73
BPQ01
600
4289.935
0.63
4 f 5d( 1 Go)6s
4 f 5d( 1 Go)6p
o
7/2
7/2
2641.559
25945.396
C73
BPQ01
700
4460.204
0.87
4 f 2 ( 3 H)6s
4 f 2 ( 3 H4 )6p 1/2
4
H
(4,1/2) o
7/2
7/2
3854.012
26268.203
C73
BPQ01
600
4562.358
0.55
4 f 2 ( 3 H)6s
4 f 2 ( 3 H4 )6p 1/2
4
7/2
9/2
3854.012
25766.355
C73
BPQ01
Ho
H
(6,3/2) o
H
(4,1/2) o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1648
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Cerium 共Ce II兲
J
Level (cm⫺1 )
Ref
7/2
9/2
11/2
13/2
0.000
2581.257
2879.695
4203.934
C73
C73
C73
C73
9/2
987.611
C73
9/2
11/2
13/2
15/2
1410.304
2563.233
3793.634
5455.845
C73
C73
C73
C73
o
7/2
1873.934
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
1/2
2140.492
C73
4 f 5d( 1 Go)6s
o
9/2
2382.246
C73
4 f 5d( 3 Fo)6s
4 o
3/2
5/2
7/2
9/2
2595.644
3363.427
4459.872
5675.763
C73
C73
C73
C73
4 f 5d( 3 Fo)6s
o
5/2
2634.666
C73
1
4 f 5d( G )6s
o
7/2
2641.559
C73
4 f ( 2 Fo)5d 2 ( 3 F)
2 o
1/2
3508.470
C73
4 f 5d( 1 Go)6s
o
9/2
3593.882
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
7/2
3703.594
C73
Configuration
Term
4 f ( 2 Fo)5d 2 ( 3 F)
4
4 f ( 2 Fo)5d 2 ( 3 F)
o
4 f ( 2 Fo)5d 2 ( 3 F)
4 o
4 f ( 2 Fo)5d 2 ( 3 F)
o
2 o
2 3
Ho
I
F
S
4 f ( F )5d ( F)
4
D
3/2
3745.475
C73
4 f 2 ( 3 H)6s
4
H
7/2
9/2
11/2
13/2
3854.012
4165.550
5513.709
6967.547
C73
C73
C73
C73
4 f 5d( 3 Ho)6s
4
Ho
7/2
9/2
11/2
13/2
3995.460
4523.033
5651.357
6913.392
C73
C73
C73
C73
4 f ( 2 Fo)5d 2 ( 3 F)
4
F°
3/2
5/2
7/2
9/2
4201.893
5010.870
5964.896
7059.072
C73
C73
C73
C73
4 f 5d( 3 Go)6s
o
7/2
4266.397
C73
4 f 5d( 3 Go)6s
o
5/2
4322.708
C73
3
4 f 5d( G )6s
4
5/2
4511.257
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
5/2
4737.373
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
3/2
4844.644
C73
4 f 5d( 3 Ho)6s
o
11/2
4910.963
C73
1
4 f 5d( D )6s
o
5/2
5118.806
C73
4 f ( 2 Fo)5d 2 ( 1 D)
o
1/2
5283.029
C73
o
o
o
o
G
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1649
Energy Levels of Singly-ionized Cerium 共Ce II兲—Continued
Configuration
2 o
Level (cm⫺1 )
Ref
4 f ( F )5d ( F)
G
7/2
9/2
11/2
5437.422
6389.942
7522.622
C73
C73
C73
4 f 2 ( 3 H)6s
2
H
9/2
11/2
5616.739
7341.007
C73
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
7/2
5716.216
C73
4 f 5d( G )6s
o
9/2
5819.113
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
3/2
5924.204
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
7/2
5942.798
C73
4 f ( 2 Fo)5d 2 ( 1 G)
o
11/2
5969.007
C73
3 o
4 f 5d( F )6s
o
5/2
6517.619
C73
4 f 5d( 3 Do)6s
o
3/2
6521.332
C73
4 f 5d( 3 Fo)6s
o
5/2
6549.908
C73
4 f ( 2 Fo)5d 2 ( 3 F)
o
9/2
6638.258
C73
o
2 3
o
J
4
3
2 3
Term
4 f ( H)5d
2
H
9/2
11/2
7011.804
8278.054
C73
C73
4 f 5d( 3 Do)6s
4
Do
1/2
3/2
5/2
7/2
7061.838
7818.147
8175.863
8402.668
C73
C73
C73
C73
4 f 2 ( 3 H)5d
4
K
11/2
13/2
15/2
17/2
7092.265
8423.672
9771.956
11165.796
C73
C73
C73
C73
4 f ( 2 Fo)5d 2 ( 3 P)
4
Go
5/2
7/2
9/2
11/2
7202.529
7878.328
8804.224
10035.711
C73
C73
C73
C73
4 f 5d( 3 Go)6s
4
Go
11/2
7233.627
C73
4 f 5d( 3 Fo)6s
o
7/2
7259.075
C73
4 f ( 2 Fo)5d 2 ( 3 F)
4 o
P
3/2
1/2
5/2
7278.922
7522.458
7746.185
C73
C73
C73
4 f ( 2 Fo)5d 2 ( 3 F)
2 o
I
13/2
7293.938
C73
4 f 2 ( 3 F)6s
4
F
3/2
5/2
7/2
9/2
7454.951
7722.285
8531.678
8774.064
C73
C73
C73
C73
4 f ( 2 Fo)5d 2 ( 1 G)
o
9/2
7713.089
C73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1650
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Cerium 共Ce II兲—Continued
Configuration
2 3
Term
J
Level (cm⫺1 )
Ref
4 f ( H)5d
4
I
9/2
11/2
13/2
15/2
8131.217
8896.729
10058.226
11309.972
C73
C73
C73
C73
4 f ( 2 Fo)5d 2 ( 3 F)
4 o
S
3/2
8169.698
C73
4 f ( 2 Fo)5d 2 ( 3 P)
2
Do
5/2
3/2
8280.946
8702.444
C73
C73
4 f 2 ( 3 H)5d
4
G
5/2
7/2
9/2
11/2
8448.641
9316.912
10314.162
11458.353
C73
C73
C73
C73
4 f 2 ( 3 F)6s
2
F
5/2
7/2
8789.380
9053.629
C73
C73
4 f 5d( 3 Ho)6s
o
11/2
8927.514
C73
4 f ( 2 Fo)5d 2 ( 1 G)
2
7/2
9198.326
C73
1/2
9269.826
C73
2 o
2 3
Go
4 f ( F )5d ( P)
o
4 f 5d( 3 Po)6s
4 o
1/2
3/2
5/2
9491.493
9634.186
10641.442
C73
C73
C73
4 f ( 2 Fo)5d 2 ( 1 G)
o
9/2
9723.335
C73
4 f 2 ( 3 H)5d
4
H
7/2
9/2
11/2
13/2
9725.733
10703.305
11759.467
13027.758
C73
C73
C73
C73
4 f ( 2 Fo)6s 2
2 o
F
5/2
9778.986
C73
4 f 5d( 3 Fo)6p
4
G
5/2
7/2
9/2
11/2
25359.686
27187.047
29166.597
31089.731
C73
C73
C73
C73
4 f 2 ( 3 H4 )6p 1/2
(4,1/2) o
9/2
7/2
25766.355
26268.203
C73
C73
4 f 5d( 1 Go)6p
7/2
25945.396
C73
1
11/2
27379.949
C73
9/2
11/2
7/2
5/2
27432.782
28327.071
28349.582
28396.150
C73
C73
C73
C73
9/2
27934.638
C73
7/2
9/2
11/2
13/2
28297.473
29908.904
31738.484
33531.388
C73
C73
C73
C73
9/2
28334.756
C73
P
o
4 f 5d( G )6p
4 f 2 ( 3 H4 )6p 3/2
(4,3/2) o
4 f 5d( 3 Ho)6p
3
o
4 f 5d( G )6p
4
H
4 f 5d( 3 Ho)6p
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1651
Energy Levels of Singly-ionized Cerium 共Ce II兲—Continued
Configuration
3
Term
o
4 f 5d( H )6p
J
Level (cm⫺1 )
11/2
29438.817
C73
Ref
4 f 2 ( 3 H6 )6p 3/2
(6,3/2) o
15/2
11/2
13/2
9/2
30846.582
31151.534
31340.393
32372.621
C73
C73
C73
C73
4 f 5d( 3 Ho)6p
4
15/2
32269.252
C73
Limit
87500
SR65
3
Ce III ( H4 )
I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1652
J. E. SANSONETTI AND W. C. MARTIN
Cesium „Cs…
Atomic number⫽55
Atomic weight⫽132.9054
Isotope
Mass
133
Cs
Abundance
Spin
100%
7/2
132.905429
Magmoment
⫹2.579
Cs I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 6s 2S1/2
Ionization energy: 31 406.467 69 cm⫺1 共3.893 905 eV兲
Cs II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 1S0
Ionization energy: 186 777.4 cm⫺1 共23.157 44 eV兲
Strong Lines of Cesium 共Cs兲
Intensity
20
150
150
150
400
400
1
1
1
1
P
P
P
P
15
8
14
10
15
11 w
25
30 c
10 c
30
40
25
20
80
20
20
20
10
140
200 w
50
80
40
40 w
120
200 P
40
15 P,c
8 P,c
1000 P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
639.36
718.14
808.76
813.84
901.27
926.66
1840.50
1859.16
1883.93
1935.19
Air
2267.65
2273.84
2332.46
2392.86
2931.08
3785.44
3805.12
3876.15
3888.61
3896.99
3959.51
3965.20
3974.25
4039.85
4068.78
4213.14
4232.20
4234.41
4264.70
4277.13
4288.38
4363.30
4373.04
4405.26
4501.55
4526.74
4538.97
4555.28
4593.17
4603.79
Spectrum
Ref.
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
II
II
II
II
II
II
II
II
II
II
RE75
RE75
RE75
RE75
RE75
RE75
S81
S81
S81
S81
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
II
II
II
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
K62b
K62b
S81
ATOMIC SPECTROSCOPIC DATA
1653
Strong Lines of Cesium 共Cs兲—Continued
Intensity
40
70
250
200
50
400
80
250
70
800
300
110
100
200
1
1
400
2
3
50
250
1
5
500
10
1
100
15
3
5
80
100
8
2
90
50
100
3
5
400
80
150
15
130
13
2
20
40
25
50
200
20
60
80
c
c
c
P
c
c
c
c
c
c
w
c
w
c
c
70
1000 P,c
15
250 P,c
Wavelength 共Å兲
4616.17
4763.64
4830.19
4870.04
4880.05
4952.85
4972.60
5043.80
5209.58
5227.04
5249.38
5274.05
5349.13
5370.99
5465.94
5502.88
5563.02
5635.21
5664.02
5814.16
5831.14
5838.83
5845.14
5925.63
6010.49
6034.09
6128.61
6213.10
6217.60
6354.55
6495.53
6536.44
6586.51
6628.66
6646.57
6723.28
6724.47
6824.65
6870.45
6955.50
6973.30
6979.67
6983.49
7149.54
7228.53
7279.90
7279.96
7608.90
7852.52
7943.88
7997.44
8012.98
8015.73
8047.13
8078.94
8079.04
8521.13
8608.31
8761.41
Spectrum
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
I
II
II
I
I
II
I
I
II
I
I
I
II
II
I
I
II
I
II
I
I
II
I
II
I
II
I
I
I
I
II
I
II
II
I
II
I
I
I
II
I
Ref.
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
K62b
K62b
S81
K62b
K62b
S81
S81
K62b
K62b
S81
K62b
K62b
S81
K62b
K62b
K62b
S81
S81
K62b
EW70
S81
S81
S81
EW70
EW70
S81
K62b
S81
K62b
S81
EW70
EW70
EW70
K62b
S81
K62b
S81
S81
EW70
S81
EW70
EW70
EJN64
S81
EJN64
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1654
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Cesium 共Cs兲—Continued
Intensity
Wavelength 共Å兲
1000 P,c
300 P
90
30 c
14
300
80
400
30 c
25
13
50
20 w
11
20 c
50
600 P,c
140
40 c
90
14 c
900 P,c
20 c
15 c
11 c
13
25
12
14
20
60
70
14
9
15 d
8
11 c
50 P
10 c
20 P
3
8943.47
9172.32
9208.53
9220.75
9994.79
10024.36
10123.41
10123.60
10176.02
10379.66
10480.93
10504.51
10807.88
12604.29
12735.52
13424.31
13588.29
13602.56
13692.91
13758.81
13868.82
14694.91
15293.80
15356.61
16426.14
16535.63
17012.32
20138.47
22811.86
23037.98
23344.47
24251.21
24374.96
25220.37
25763.51
25764.73
29310.06
30103.27
30953.06
34900.13
36131.00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
Cs
I
I
I
II
II
I
I
I
II
II
II
II
II
II
II
I
I
I
II
I
II
I
II
II
II
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
Ref.
EJN64
EJN64
EJN64
S81
S81
EW70
EW70
EW70
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
S81
SAV81
SAV81
S81
S81
S81
S81
S81
ATOMIC SPECTROSCOPIC DATA
1655
Persistent Lines of Neutral Cesium 共Cs I兲
Inten
Wavelength 共Å兲
15
4555.28
8
4593.17
1000
8521.13
250
8943.47
300
900
50
20
0.0188
0.0080
0.3276
8761.41
1000
600
A ki (108 s⫺1 )
0.287
9172.32
13588.29
14694.91
30103.27
34900.13
J
Level (cm⫺1 )
S
P
1/2
3/2
S
P
Configuration
Term
6s
7p
2
Wl Ref
A Ref
0.0000
21946.396
K62b
FW96
6s
7p
2
1/2
1/2
0.0000
21765.35
K62b
FW96
6s
6p
2
S
P
1/2
3/2
0.0000
11732.3079
EJN64
FW96
6p
6d
2 o
P
D
1/2
3/2
11178.2686
22588.8210
EJN64
6s
6p
2
S
P
1/2
1/2
0.0000
11178.2686
EJN64
6p
6d
2 o
P
D
3/2
5/2
11732.3079
22631.6863
EJN64
6p
7s
2 o
P
S
1/2
1/2
11178.2686
18535.529
S81
6p
7s
2 o
P
S
3/2
1/2
11732.3079
18535.529
S81
6p
5d
2 o
P
D
1/2
3/2
11178.2686
14499.2584
S81
6p
5d
2 o
3/2
5/2
11732.3079
14596.8423
S81
2 o
2 o
2 o
2
2 o
2
2
2
2
2
P
D
FW96
Energy Levels of Neutral Cesium 共Cs I兲
Configuration
Term
5p 6 ( 1 S)6s
2
J
Level (cm⫺1 )
Ref
S
1/2
0.0000
WS87
5p ( S)6p
2 o
P
1/2
3/2
11178.2686
11732.3079
WS87
EW70
5 p 6 ( 1 S)7s
2
S
1/2
18535.529
WS87
5p 6 ( 1 S)7p
2 o
P
1/2
3/2
21765.35
21946.396
WS87
K62b
5 p 6 ( 1 S)5d
2
D
3/2
5/2
14499.2584
14596.8423
WS87
WS87
5p 6 ( 1 S)6d
2
D
3/2
5/2
22588.8210
22631.6863
EJN64
EJN64
Limit
31406.46766
WS87
6 1
Cs II ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1656
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Cesium 共Cs II兲
Inten
Wavelength 共Å兲
150
A ki (108 s⫺1 )
6
808.76
150
813.84
400
901.27
400
926.66
200
4526.74
1000
4603.79
800
Configuration
5227.04
1
5p
o
)5d
5p 5 ( 2 P3/2
2
5p 6
o
)6s
5p 5 ( 2 P1/2
2
5p 6
o
)6s
5p 5 ( 2 P3/2
2
5p 6
o
)5d
5p 5 ( 2 P3/2
2
1
1
1
o
)5d
5 p 5 ( 2 P3/2
5 2 o
5 p ( P3/2)6p
2
o
)6s
5 p 5 ( 2 P3/2
5 2 o
5 p ( P3/2)6p
2
o
)6s
5 p 5 ( 2 P3/2
5 2 o
5 p ( P3/2)6p
2
2
2
2
Term
J
Level (cm⫺1 )
S
关 3/2兴 o
0
1
0.0
123645.5813
RE75
S
关 1/2兴 o
0
1
0.0
122875.4487
RE75
S
关 3/2兴 o
0
1
0.0
110954.3607
RE75
S
关 1/2兴 o
0
1
0.0
107914.1587
RE75
关 1/2兴 o
关 3/2兴
1
1
107914.1587
129998.9106
S81
关 3/2兴 o
关 5/2兴
2
3
107401.5602
129116.7070
S81
关 3/2兴 o
关 1/2兴
2
1
107401.5602
126527.5324
S81
Wl Ref
A Ref
Energy Levels of Singly-ionized Cesium 共Cs II兲
Configuration
5p
6
Term
J
S
0
1
Level (cm⫺1 )
0.0
Ref
S81
o
)6s
5p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
107401.5602
110954.3607
S81
S81
o
)5d
5 p 5 ( 2 P3/2
2
关 1/2兴 o
0
1
107572.0610
107914.1587
S81
S81
o
)5d
5 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
112804.3010
123645.5813
S81
S81
o
)6s
5 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
122374.8156
122875.4487
S81
S81
o
)6p
5 p 5 ( 2 P3/2
2
关 1/2兴
1
0
126527.5324
133162.6932
S81
S81
o
)6p
5 p 5 ( 2 P3/2
2
关 5/2兴
2
3
128098.9117
129116.7070
S81
S81
o
)6p
5 p 5 ( 2 P3/2
2
关 3/2兴
1
129998.9106
S81
186777.4
S81
Cs III
o
( 2 P3/2
)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1657
Chlorine „Cl…
Atomic number⫽17
Atomic weight⫽35.4527
Isotope
35
37
Cl
Cl
Mass
Abundance
Spin
Mag moment
34.968852
36.965903
75.77%
24.23%
3/2
3/2
⫹0.82187
⫹0.68412
o
Cl I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 5 2P3/2
⫺1
Ionization energy: 104 591.0 cm 共12.967 63 eV兲
Cl II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 4 3P2
Ionization energy: 192 070 cm⫺1 共23.8136 eV兲
Strong Lines of Chlorine 共Cl兲
Intensity
600
600
600
700
900
800
600
700
300
1000
700
600
600
150
300
1000
500
500
120
500
500
500
500
25
15
20
60
40
140
25
60
30
25
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P,h
600 P
150 P
90
400 P
Wavelength 共Å兲
Vacuum
787.580
788.740
793.342
839.297
839.599
841.414
851.691
1063.831
1067.945
1071.036
1071.767
1075.230
1079.080
1179.293
1335.726
1347.240
1351.657
1363.447
1373.116
1379.528
1389.693
1389.957
1396.527
Air
3833.348
3845.367
3845.651
3850.991
3851.373
3860.83
3860.985
4132.498
4372.93
4768.649
4781.318
4794.55
4810.06
4819.471
4896.77
Spectrum
Ref
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1658
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Chlorine 共Cl兲—Continued
Intensity
Wavelength 共Å兲
250 P
140 P
60
140 P
300 P
130 P
80 P
600 P
60
110 P
60
30
40
25
60 P
12
40
50 P
11
11
8
15
12
9
15
10
8
14
11
8
11
15
12
11
11
90 P
15
100 P
90 P
500 P
80 P
11
11
100 P
400 P
20
11
15
10
12
10
40
15
20
20
4904.776
4917.731
4995.477
5078.264
5217.94
5221.355
5392.119
5423.23
5423.507
5443.37
5444.205
5457.022
7256.620
7414.114
7547.072
7672.419
7717.581
7744.970
7769.163
7821.363
7830.746
7878.215
7899.310
7915.084
7924.645
7933.894
7935.012
7997.854
8015.611
8084.508
8085.562
8086.672
8194.420
8199.128
8200.21
8212.038
8220.445
8221.742
8333.307
8375.94
8428.254
8467.341
8550.438
8575.24
8585.97
8686.26
8912.921
8948.063
9038.982
9045.433
9073.166
9121.146
9191.731
9288.856
9452.098
9592.222
15730.1
15869.7
8
14
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK74
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
RK69
ATOMIC SPECTROSCOPIC DATA
1659
Persistent Lines of Neutral Chlorine 共Cl I兲
Inten
300
1000
500
500
500
500
500
500
60
50
90
100
90
500
80
100
400
Wavelength 共Å兲
1335.726
1347.240
1351.657
1363.447
1379.528
1389.693
1389.957
1396.527
7547.072
7744.970
8212.038
8221.742
8333.307
8375.94
8428.254
8575.24
8585.97
A ki (108 s⫺1 )
2.24
5.62
4.24
0.99
0.096
0.0030
0.023
0.011
0.12
0.063
Configuration
2
5
3s 3 p
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 5
3s 2 3 p 4 ( 3 P)4s
J
Level (cm⫺1 )
P
P
3/2
1/2
2 o
P
P
2 o
Term
Wl Ref
A Ref
0.00
74865.667
RK69
M03
3/2
3/2
0.00
74225.846
RK69
M03
P
P
1/2
1/2
882.35
74865.667
RK69
M03
2 o
P
P
1/2
3/2
882.35
74225.846
RK69
M03
2 o
P
P
3/2
3/2
0.00
72488.568
RK69
M03
2 o
P
P
3/2
5/2
0.00
71958.363
RK69
M03
2 o
P
P
1/2
1/2
882.35
72827.038
RK69
M03
2 o
P
P
1/2
3/2
882.35
72488.568
RK69
M03
P
S
3/2
3/2
72488.568
85735.091
RK69
FW96
P
S
1/2
3/2
72827.038
85735.091
RK69
FW96
P
Do
5/2
5/2
71958.363
84132.262
RK69
P
Do
3/2
5/2
72488.568
84648.100
RK69
P
Do
3/2
3/2
72488.568
84485.309
RK69
P
Do
5/2
7/2
71958.363
83894.037
RK69
P
Do
1/2
1/2
72827.038
84688.637
RK69
P
Do
1/2
3/2
72827.038
84485.309
RK69
P
Do
3/2
5/2
72488.568
84132.262
RK69
2 o
2
2
2
2
4
4
4
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
3s 2 3 p 4 ( 3 P)4s
3s 2 3 p 4 ( 3 P)4p
4
4 o
4 o
4
2
4
4
4
4
4
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1660
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Chlorine 共Cl I兲
Configuration
2
Term
Ref
2 o
P
3/2
1/2
0.00
882.35
RK69
UH87
3s 2 3p 4 ( 3 P)4s
4
P
5/2
3/2
1/2
71958.363
72488.568
72827.038
RK69
RK69
RK69
3s 2 3p 4 ( 3 P)4s
2
P
3/2
1/2
74225.846
74865.667
RK69
RK69
3s 2 3p 4 ( 3 P)4p
4 o
P
5/2
3/2
1/2
82918.893
83130.900
83364.927
RK69
RK69
RK69
3s 2 3p 4 ( 3 P)4p
4
Do
7/2
5/2
3/2
1/2
83894.037
84132.262
84485.309
84688.637
RK69
RK69
RK69
RK69
3s 2 3p 4 ( 1 D)4s
2
D
5/2
3/2
84120.263
84121.872
RK69
RK69
3s 2 3p 4 ( 3 P)4p
2
Do
5/2
3/2
84648.100
84988.480
RK69
RK69
3s 2 3p 4 ( 3 P)4p
2 o
1/2
3/2
85244.330
85442.430
RK69
RK69
3s3 p 6
2
S
1/2
85678.94
RK69
3s 2 3p 4 ( 3 P)4p
4 o
3/2
85735.091
RK69
3s 3p
5
Level (cm⫺1 )
J
P
S
Cl II ( 3 P2 )
Limit
104591.0
RK69
Persistent Lines of Singly-ionized Chlorine 共Cl II兲
Inten
Wavelength 共Å兲
700
839.297
900
800
600
700
300
1000
700
A ki (108 s⫺1 )
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)3d
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)3d
839.599
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)3d
841.414
3s 2 3 p 4
3s 2 3 p 3 ( 2 Do)4s
851.691
1063.831
1067.945
1071.036
1071.767
Configuration
0.49
1.17
0.87
0.29
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3s 2 3 p 4
3s3 p 5
3s 2 3 p 4
3s3 p 5
3s 2 3 p 4
3s3 p 5
3s 2 3 p 4
3s3 p 5
Term
J
Level (cm⫺1 )
3
P
Do
1
1
696.00
119843.31
RK74
P
Do
1
2
696.00
119800.32
RK74
P
Do
0
1
996.47
119843.31
RK74
D
Do
2
2
11653.58
129066.96
RK74
P
P
2
1
0.00
93999.88
RK74
M03
P
P
1
0
696.00
94333.84
RK74
M03
P
P
2
2
0.00
93367.56
RK74
M03
P
P
1
1
696.00
93999.88
RK74
M03
3
3
3
3
3
1
1
3
3 o
3
3 o
3
3 o
3
3 o
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1661
Persistent Lines of Singly-ionized Chlorine 共Cl II兲—Continued
Inten
600
600
60
40
140
60
600
150
400
250
140
140
300
130
80
600
110
Wavelength 共Å兲
1075.230
1079.080
3850.991
3851.373
A ki (108 s⫺1 )
0.38
0.28
1.8
1.6
3860.83
4132.498
4794.55
4810.06
1.6
1.04
0.99
4896.77
4904.776
4917.731
5078.264
0.81
0.75
0.77
5217.94
5221.355
5392.119
5423.23
5443.37
1.0
Configuration
2
3s 3 p
3s3p 5
4
Term
J
Level (cm⫺1 )
3
P
P
0
1
P
P
Wl Ref
A Ref
996.47
93999.88
RK74
M03
1
2
696.00
93367.56
RK74
M03
P
Do
2
3
128663.57
154623.57
RK74
FW96
P
Do
2
2
128663.57
154620.97
RK74
FW96
P
Do
3
4
128730.82
154624.66
RK74
3 o
3s 2 3 p 4
3s3p 5
3
3s 2 3 p 3 ( 4 So)4p
3s 2 3 p 3 ( 4 So)4d
5
3s 2 3 p 3 ( 4 So)4p
3s 2 3 p 3 ( 4 So)4d
5
3s 2 3 p 3 ( 4 So)4p
3s 2 3 p 3 ( 4 So)4d
5
3s 2 3 p 3 ( 2 Do)4s
3s 2 3 p 3 ( 2 Do)4p
1
Do
D
2
2
129066.96
153258.61
RK74
FW96
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
5 o
S
P
2
3
107879.66
128730.82
RK74
FW96
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
5 o
S
P
2
2
107879.66
128663.57
RK74
FW96
3s 2 3 p 3 ( 2 Do)4s
3s 2 3 p 3 ( 2 Do)4p
3
Do
F
3
4
126784.37
147200.24
RK74
3s 2 3 p 3 ( 2 Do)4s
3s 2 3 p 3 ( 2 Do)4p
3
Do
F
2
3
126744.97
147127.57
RK74
FW96
3s 2 3 p 3 ( 2 Do)4s
3s 2 3 p 3 ( 2 Do)4p
3
Do
F
1
2
126726.70
147055.61
RK74
FW96
3s 2 3 p 3 ( 2 Do)4s
3s 2 3 p 3 ( 2 Do)4p
3
Do
D
3
3
126784.37
146470.64
RK74
FW96
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
3 o
S
P
1
2
112609.36
131768.66
RK74
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
3 o
S
P
1
1
112609.36
131756.12
RK74
3s 2 3 p 3 ( 2 Do)4s
3s 2 3 p 3 ( 2 Do)4p
1
Do
F
2
3
129066.96
147607.37
RK74
3s 2 3 p 3 ( 4 So)3d
3s 2 3 p 3 ( 4 So)4p
5
Do
P
4
3
110296.84
128730.82
RK74
3s 2 3 p 3 ( 4 So)3d
3s 2 3 p 3 ( 4 So)4p
5
Do
P
3
2
110297.72
128663.57
RK74
3 o
5
5
5
1
5
5
3
3
3
3
3
3
1
5
5
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1662
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Chlorine 共Cl II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
4
3
2
1
0
0.00
696.00
996.47
RK74
RK74
RK74
3s 2 3p 4
1
2
11653.58
RK74
3s 2 3p 4
1
S
0
27878.02
RK74
3s3p 5
3 o
P
2
1
0
93367.56
93999.88
94333.84
RK74
RK74
RK74
3s 2 3p 3 ( 4 So)4s
5 o
S
2
107879.66
RK74
3s 2 3p 3 ( 4 So)3d
5
Do
4
3
2
1
0
110296.84
110297.72
110300.56
110303.12
110304.52
RK74
RK74
RK74
RK74
RK74
3s 2 3p 3 ( 4 So)4s
3 o
S
1
112609.36
RK74
3s 3p ( D )3d
1 o
P
1
115657.77
RK74
3s 2 3p 3 ( 4 So)3d
3
Do
2
3
1
119800.32
119811.22
119843.31
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)3d
1 o
S
0
125245.89
RK74
3s 2 3p 3 ( 2 Do)3d
3 o
F
2
3
4
126033.54
126220.74
126458.10
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)4s
3
Do
1
2
3
126726.70
126744.97
126784.37
RK74
RK74
RK74
3s 2 3p 3 ( 4 So)4p
5
P
1
2
3
128622.99
128663.57
128730.82
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)4s
1
Do
2
129066.96
RK74
3s 2 3p 3 ( 4 So)4p
3
P
1
2
0
131756.12
131768.66
131769.41
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)3d
3
Go
3
4
5
132164.13
132175.11
132193.12
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)3d
1
Go
4
134393.27
RK74
3s 2 3p 3 ( 2 Po)4s
3 o
P
0
1
2
137771.77
137806.15
137879.37
RK74
RK74
RK74
3s 2 3p 3 ( 2 Po)3d
1
Do
2
138624.73
RK74
3s 2 3p 3 ( 2 Po)4s
3 o
1
140260.64
RK74
2
3s 3p
2
3 2
P
D
o
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1663
Energy Levels of Singly-ionized Chlorine 共Cl II兲—Continued
Term
J
Level (cm⫺1 )
3s 3p ( D )3d
3
o
D
1
2
3
140741.80
141011.58
141351.14
RK74
RK74
RK74
3s 2 3p 3 ( 2 Po)3d
3 o
F
4
3
2
143998.08
144176.42
144345.56
RK74
RK74
RK74
3s 2 3p 3 ( 2 Po)3d
3 o
P
0
1
2
145175.45
145421.24
146014.75
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)4p
1
P
1
145470.16
RK74
3s 2 3p 3 ( 2 Do)4p
3
D
1
2
3
146331.76
146335.55
146470.64
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)4p
3
F
2
3
4
147055.61
147127.57
147200.24
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)4p
1
F
3
147607.37
RK74
3s 3p ( D )4p
3
P
2
1
0
149800.12
149954.18
150020.90
RK74
RK74
RK74
3s 2 3p 3 ( 2 Po)3d
3
Do
3
2
1
150683.38
151020.06
151135.31
RK74
RK74
RK74
3s 2 3p 3 ( 2 Do)3d
3 o
S
1
150813.12
RK74
3s 2 3p 3 ( 2 Do)3d
1 o
F
3
151094.06
RK74
3s 3p ( S )5s
5 o
S
2
152234.91
RK74
3s 2 3p 3 ( 2 Do)4p
1
D
2
153258.61
RK74
3s 2 3p 3 ( 4 So)5s
3 o
S
1
153634.97
RK74
3s 2 3p 3 ( 4 So)4d
5
Do
0
1
2
3
4
154618.09
154619.10
154620.97
154623.57
154624.66
RK74
RK74
RK74
RK74
RK74
192070
RK74
Configuration
2
2
2
3 2
3 2
o
o
3 4 o
o
)
Cl III ( 4 S3/2
Limit
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1664
J. E. SANSONETTI AND W. C. MARTIN
Chromium „Cr…
Atomic number⫽24
Atomic weight⫽51.9961
Isotope
50
Cr
Cr
53
Cr
54
Cr
52
Mass
Abundance
Spin
49.946046
51.940509
52.940651
53.938882
4.35%
83.79%
9.50%
2.36%
0
0
3/2
0
Mag moment
⫺0.47454
Cr I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 5 4s 7S3
Ionization energy: 54 575.6 cm⫺1 共6.766 51 eV兲
Cr II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 5 6S5/2
Ionization energy: 132 966 cm⫺1 共16.4857 eV兲
Strong Lines of Chromium 共Cr兲
Intensity
90
150
1000
800
600
600
500
600
400
350
300
170
150
200
180
180
150
Wavelength 共Å兲
P
P
P
P
P
P
P
P
1000 P
700 P
500 P
6
7
8
10
20
8
6
8
20
13
13
15
25
15
20
15
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1220.165
1247.554
1426.208
1431.323
1431.865
1432.056
1433.004
1434.808
1435.207
1435.582
1448.428
1669.876
1672.738
1676.152
1752.585
1760.747
1767.457
Air
2055.59
2061.54
2065.46
2383.303
2408.60
2496.30
2504.31
2519.51
2549.548
2560.695
2571.74
2591.84
2653.57
2658.59
2663.42
2666.02
2668.71
2671.80
2672.83
Spectrum
Ref
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
SKRR03
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
II
II
II
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
K51
K51
K51
K53
K53
K53
K53
K53
K53
K53
K53
K53
K51
K51
K51
K51
K51
K51
K51
ATOMIC SPECTROSCOPIC DATA
1665
Strong Lines of Chromium 共Cr兲—Continued
Intensity
90
15
12
15
9
9
9
20
14
8
13
15
20
15
8
20
40
40
12
30
9
9
130
90
60
50
30
25
40
40
30
25
11
15
12
9
8
40
20
10
10
9
13
13
12
25
25
11
25
10
20
25
80
100
30
25
12
15
40
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
2677.19
2678.79
2687.09
2691.03
2698.40
2698.68
2722.74
2726.496
2731.895
2736.463
2743.63
2748.98
2750.72
2751.85
2757.086
2757.72
2762.58
2766.55
2769.902
2780.695
2822.38
2830.46
2835.63
2843.24
2849.83
2855.67
2858.91
2860.92
2862.57
2865.10
2866.72
2867.65
2870.43
2875.97
2876.24
2877.97
2886.995
2889.294
2893.254
2894.168
2896.756
2905.477
2909.049
2910.892
2911.148
2967.64
2971.102
2971.90
2975.478
2979.73
2980.784
2985.849
2986.01
2986.466
2988.638
2991.877
2994.06
2995.094
2996.571
Spectrum
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
II
II
II
II
II
II
II
I
I
I
II
II
II
II
I
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
Ref
K51
K51
K51
K51
K51
K51
K51
K53
K53
K53
K51
K51
K51
K51
K53
K51
K51
K51
K53
K53
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K51
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K51
K53
K51
K53
K53
K53
K53
K53
K53
K53
K53
K53
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1666
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Chromium 共Cr兲—Continued
Intensity
10
60
40
40
40
70
40
140
20
12
20
140
60
8
40
7
20
30
30
40
13
25
25
30
13
12
9
6
7
9
25
9
20
11
14
14
8
7
8
8
10
6
6
15
1000 P
800 P
20
600 P
6
20
30
11
11
8
11
6
6
6
6
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
2998.783
3000.88
3005.06
3013.72
3014.756
3014.932
3015.197
3017.591
3018.492
3018.827
3020.671
3021.576
3024.359
3029.165
3030.25
3031.346
3034.191
3037.049
3040.837
3053.87
3118.64
3120.36
3124.94
3132.05
3180.70
3197.08
3209.19
3257.826
3339.81
3358.49
3368.04
3403.30
3408.76
3421.19
3422.73
3433.589
3436.190
3441.449
3445.604
3447.426
3453.328
3455.607
3573.636
3574.796
3578.682
3593.481
3601.655
3605.320
3632.832
3636.588
3639.80
3641.84
3648.993
3653.916
3656.26
3663.206
3686.82
3687.25
3730.805
Spectrum
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K51
K51
K51
K51
K51
K51
K51
K53
K51
K51
K51
K51
K51
K51
K51
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
ATOMIC SPECTROSCOPIC DATA
1667
Strong Lines of Chromium 共Cr兲—Continued
Intensity
8
25
30
15
12
13
6
6
6
7
10
25
9
9
6
20
10
7
14
7
10
7
13
30
30
20
13
20
50
10
90
30
30
20
90
80
80
50
10
8
50
8
10
8
10
8
7
7
8
8
1000 P
800 P
500 P
40
60
20
90
20
120
Wavelength 共Å兲
3732.03
3743.57
3743.887
3749.00
3757.659
3768.237
3791.384
3792.142
3793.872
3797.138
3797.714
3804.801
3815.438
3819.57
3826.427
3841.28
3848.983
3849.35
3850.029
3852.221
3854.229
3855.58
3857.63
3883.289
3885.24
3886.80
3894.039
3902.911
3908.762
3916.25
3919.165
3921.031
3928.647
3941.499
3963.694
3969.748
3976.674
3983.901
3984.339
3989.984
3991.118
3991.677
3992.846
4001.443
4039.098
4048.784
4126.513
4163.627
4174.808
4179.27
4254.331
4274.806
4289.733
4337.566
4339.45
4339.74
4344.51
4351.055
4351.77
Spectrum
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1668
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Chromium 共Cr兲—Continued
Intensity
30
25
25
30
20
20
12
12
12
7
30
20
20
25
12
30
30
80
30
40
12
10
12
7
15
10
7
6
13
250
400
600
14
25
9
15
30
15
40
20
70
9
6
8
P
P
P
h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4359.647
4371.279
4384.974
4496.85
4526.458
4530.72
4535.714
4540.50
4540.715
4544.607
4545.946
4580.045
4591.405
4600.745
4613.36
4616.120
4626.181
4646.151
4651.285
4652.155
4698.46
4708.02
4718.43
4737.33
4756.09
4789.324
4870.79
4887.013
4922.276
5204.505
5206.021
5208.415
5247.58
5264.16
5265.73
5296.69
5298.29
5328.36
5345.77
5348.30
5409.78
5791.00
7400.22
7462.35
Spectrum
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
Cr
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
K53
ATOMIC SPECTROSCOPIC DATA
1669
Persistent Lines of Neutral Chromium 共Cr I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5 6
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
7
1000
3578.682
1.48
3d ( S)4s
3d 4 ( 5 D)4s4p( 3 Po)
a S
y 7Po
3
4
0.00
27935.26
K53
FW96
800
3593.481
1.50
3d 5 ( 6 S)4s
3d 4 ( 5 D)4s4p( 3 Po)
a 7S
y 7Po
3
3
0.00
27820.23
K53
FW96
600
3605.320
1.62
3d 5 ( 6 S)4s
3d 4 ( 5 D)4s4p( 3 Po)
a 7S
y 7Po
3
2
0.00
27728.87
K53
FW96
1000
4254.331
0.315
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 7S
z 7Po
3
4
0.00
23498.84
K53
FW96
800
4274.806
0.307
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 7S
z 7Po
3
3
0.00
23386.35
K53
FW96
500
4289.733
0.316
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 7S
z 7Po
3
2
0.00
23305.01
K53
FW96
250
5204.505
0.509
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 5S
z 5Po
2
1
7593.16
26801.93
K53
FW96
400
5206.021
0.514
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 5S
z 5Po
2
2
7593.16
26796.28
K53
FW96
600
5208.415
0.506
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 5S
z 5Po
2
3
7593.16
26787.50
K53
FW96
Energy Levels of Neutral Chromium 共Cr I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
3d ( S)4s
7
a S
3
0.00
SC85
3d 5 ( 6 S)4s
a 5S
2
7593.16
SC85
3d 4 4s 2
a 5D
0
1
2
3
4
7750.78
7810.82
7927.47
8095.21
8307.57
SC85
SC85
SC85
SC85
SC85
3d 5 ( 4 G)4s
a 5G
2
6
3
4
5
20517.40
20519.60
20520.92
20523.69
20523.94
SC85
SC85
SC85
SC85
SC85
3d 5 ( 4 P)4s
a 5P
3
2
1
21840.84
21847.88
21856.94
SC85
SC85
SC85
3d 4 4s 2
a 3P
0
1
2
23163.27
23512.00
24093.16
SC85
SC85
SC85
3d 5 ( 6 S)4p
z 7Po
2
3
4
23305.01
23386.35
23498.84
SC85
SC85
SC85
5 6
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1670
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Chromium 共Cr I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3d ( D)4s4p( P )
7 o
z F
0
1
2
3
4
5
6
24971.21
25010.64
25089.20
25206.02
25359.62
25548.64
25771.40
SC85
SC85
SC85
SC85
SC85
SC85
SC85
3d 5 ( 6 S)4p
z 5Po
3
2
1
26787.50
26796.28
26801.93
SC85
SC85
SC85
3d 4 ( 5 D)4s4p( 3 Po)
z 7Do
1
2
3
4
5
27300.19
27382.18
27500.37
27649.71
27825.45
SC85
SC85
SC85
SC85
SC85
3d 4 ( 5 D)4s4p( 3 Po)
y 7Po
2
3
4
27728.87
27820.23
27935.26
SC85
SC85
SC85
Limit
54575.6
SC85
Configuration
4 5
3 o
Cr II ( 6 S5/2)
Persistent Lines of Singly-ionized Chromium 共Cr II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
4 5
Term
J
Level (cm⫺1 )
Wl Ref
6
A Ref
1000
1426.208
3d ( D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a D
y 6Fo
9/2
11/2
12496.44
82612.69
SKRR03
800
1431.323
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Fo
9/2
9/2
12496.44
82362.19
SKRR03
600
1431.865
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Fo
7/2
7/2
12303.86
82143.15
SKRR03
600
1432.056
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Do
5/2
7/2
12147.82
81978.08
SKRR03
500
1433.004
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Do
3/2
5/2
12032.58
81816.29
SKRR03
600
1434.808
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Do
9/2
9/2
12496.44
82192.59
SKRR03
400
1435.207
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Fo
5/2
3/2
12147.82
81824.40
SKRR03
350
1435.582
3d 4 ( 5 D)4s
3d 3 ( 4 F)4s4 p( 3 Po)
a 6D
y 6Fo
7/2
5/2
12303.86
81962.29
SKRR03
1000
2055.59
1.2
3d 5
3d 4 ( 5 D)4p
a 6S
z 6Po
5/2
7/2
0.00
48632.12
K51
M03
700
2061.54
1.2
3d 5
3d 4 ( 5 D)4p
a 6S
z 6Po
5/2
5/2
0.00
48491.10
K51
M03
500
2065.46
1.2
3d 5
3d 4 ( 5 D)4p
a 6S
z 6Po
5/2
3/2
0.00
48398.95
K51
M03
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1671
Persistent Lines of Singly-ionized Chromium 共Cr II兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
4 5
Term
J
Level (cm⫺1 )
Wl Ref
6
A Ref
90
2677.19
3d ( D)4s
3d 4 ( 5 D)4p
a D
z 6Do
9/2
9/2
12496.44
49838.38
K51
40
2762.58
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Po
7/2
5/2
12303.86
48491.10
K51
40
2766.55
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Po
9/2
7/2
12496.44
48632.12
K51
130
2835.63
2.0
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Fo
9/2
11/2
12496.44
47751.62
K51
FW96
90
2843.24
0.64
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Fo
7/2
9/2
12303.86
47464.55
K51
FW96
60
2849.83
0.92
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Fo
5/2
7/2
12147.82
47227.24
K51
FW96
50
2855.67
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Fo
3/2
5/2
12032.58
47040.35
K51
40
2862.57
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Fo
7/2
7/2
12303.86
47227.24
K51
40
2865.10
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
z 6Fo
5/2
5/2
12147.82
47040.35
K51
0.63
FW96
Energy Levels of Singly-ionized Chromium 共Cr II兲
Configuration
J
Level (cm⫺1 )
Ref
6
a S
5/2
0.00
SC85
3d 4 ( 5 D)4s
a 6D
1/2
3/2
5/2
7/2
9/2
11961.81
12032.58
12147.82
12303.86
12496.44
SC85
SC85
SC85
SC85
SC85
3d 4 ( 5 D)4s
a 4D
1/2
3/2
5/2
7/2
19528.25
19631.17
19797.88
20024.01
SC85
SC85
SC85
SC85
3d 5
a 4G
5/2
11/2
7/2
9/2
20512.06
20512.10
20517.83
20519.33
SC85
SC85
SC85
SC85
3d 5
a 4P
5/2
1/2
3/2
21822.52
21823.84
21824.11
SC85
SC85
SC85
3d 4 ( 5 D)4p
z 6Fo
1/2
3/2
5/2
7/2
9/2
11/2
46823.39
46905.17
47040.35
47227.24
47464.55
47751.62
SC85
SC85
SC85
SC85
SC85
SC85
3d
5
Term
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1672
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Chromium 共Cr II兲—Continued
Term
J
Level (cm⫺1 )
3d ( D)4p
6 o
z P
3/2
5/2
7/2
48398.95
48491.10
48632.12
SC85
SC85
SC85
3d 4 ( 5 D)4p
z 4Po
1/2
3/2
5/2
48749.36
49005.93
49706.33
SC85
SC85
SC85
3d 4 ( 5 D)4p
z 6Do
5/2
1/2
3/2
7/2
9/2
49351.80
49492.77
49564.60
49645.77
49838.38
SC85
SC85
SC85
SC85
SC85
3d 3 ( 4 F)4s4p( 3 Po)
y 6Do
1/2
3/2
5/2
7/2
9/2
81649.19
81707.87
81816.29
81978.08
82192.59
SC85
SC85
SC85
SC85
SC85
3d 3 ( 4 F)4s4p( 3 Po)
y 6Fo
1/2
3/2
5/2
7/2
9/2
11/2
81735.02
81824.40
81962.29
82143.15
82362.19
82612.69
SC85
SC85
SC85
SC85
SC85
SC85
Configuration
4 5
Cr III ( 5 D0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
132966
Ref
SC85
ATOMIC SPECTROSCOPIC DATA
1673
Cobalt „Co…
Atomic number⫽27
Atomic weight⫽58.933 20
Isotope
59
Co
Mass
Abundance
Spin
Mag moment
58.933198
100%
7/2
⫹4.627
Co I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 7 4s 2 4F9/2
Ionization energy: 63 564.6 cm⫺1 共7.881 01 eV兲
Co II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 8 3F4
Ionization energy: 137 795 cm⫺1 共17.084 eV兲
Strong Lines of Cobalt 共Co兲
Intensity
140
200
200
200
1000
200
300
300
800
120
500
500
300
200
110
300
200
500
200
200
90
500
400
200
300
200
500
200
200
250
250
250
250
300
200
150
140
110
200
200
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
1970.769
Air
2193.605
2256.745
2283.522
2286.159
2291.991
2293.390
2301.403
2307.860
2309.010
2311.604
2314.056
2314.975
2317.070
2323.145
2324.321
2326.100
2326.473
2347.399
2353.422
2353.368
2363.800
2378.626
2381.765
2383.459
2386.370
2388.917
2397.386
2404.172
2407.256
2411.624
2414.464
2415.290
2417.659
2424.935
2432.213
2436.662
2439.040
2442.617
2446.017
Spectrum
Ref
Co I
PT96
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PT96
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PT96
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PT96
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PT96
PT96
PT96
PT96
PRUJ98
PT96
PT96
PT96
PT96
PRUJ98
PRUJ98
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
I
II
II
II
II
II
II
II
II
I
I
I
I
II
I
I
I
I
II
II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1674
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Cobalt 共Co兲—Continued
Intensity
200
200
200
200
200
500
200
500
200
200
300
500
140
200
200
140
300
200
300
200
500
800
300
500
500
200
200
200
200
150
100
500
200
300
100
130
120
200
400
200
100
1000
250
250
400
400
250
110
500
300
140
250
200
250
130
200
300
130
300
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2447.711
2450.002
2464.199
2486.441
2498.821
2506.464
2511.160
2519.823
2521.365
2524.634
2524.974
2528.616
2528.970
2530.080
2533.801
2535.966
2541.953
2546.739
2559.405
2560.031
2564.034
2580.326
2582.240
2587.220
2587.524
2588.904
2666.740
2706.606
2707.343
3044.005
3395.373
3405.118
3409.176
3412.337
3412.633
3417.157
3431.582
3433.040
3443.645
3449.170
3449.440
3453.510
3462.805
3465.793
3473.974
3474.042
3489.400
3495.682
3502.280
3506.312
3509.841
3512.640
3513.481
3518.347
3521.566
3523.433
3526.850
3529.033
3529.808
Spectrum
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
II
II
II
II
II
II
II
II
I
II
II
II
I
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PT96
PRUJ98
PRUJ98
PRUJ98
PT96
PRUJ98
PRUJ98
PT96
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
ATOMIC SPECTROSCOPIC DATA
1675
Strong Lines of Cobalt 共Co兲—Continued
Intensity
Wavelength 共Å兲
400 P
120
300
300
250
130
400
300
130
200
3569.376
3575.360
3587.187
3845.469
3873.114
3873.955
3894.078
3995.308
4118.774
4121.318
Spectrum
Co
Co
Co
Co
Co
Co
Co
Co
Co
Co
I
I
I
I
I
I
I
I
I
I
Ref
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
PT96
Persistent Lines of Neutral Cobalt 共Co I兲
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3d 7 4s 2
3d 7 ( 4 F)4s4 p( 1 Po)
a 4F
x 4Go
9/2
11/2
0.000
41528.455
PT96
FW96
3d 7 4s 2
3d 7 ( 4 F)4s4 p( 1 Po)
a 4F
x 4Go
7/2
9/2
816.000
42269.229
PT96
3.2
3d 7 4s 2
3d 7 ( 4 F)4s4 p( 1 Po)
a 4F
x 4Fo
9/2
9/2
0.000
41225.710
PT96
FW96
2521.365
3.0
3d 7 4s 2
3d 7 ( 4 F)4s4 p( 1 Po)
a 4F
x 4Do
9/2
7/2
0.000
39649.124
PT96
FW96
500
3405.118
1.0
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
b 4F
y 4Fo
9/2
9/2
3482.780
32841.916
PT96
FW96
400
3443.645
0.69
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
b 4F
y 4Fo
7/2
7/2
4142.631
33173.313
PT96
FW96
1000
3453.510
1.1
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
b 4F
y 4Go
9/2
11/2
3482.780
32430.535
PT96
FW96
400*
3473.974
0.0299
3d 7 4s 2
3d 7 ( 4 F)4s4 p( 3 Po)
a 4F
z 4Fo
9/2
7/2
0.000
28777.236
PT96
M03
400*
3474.042
0.56
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
b 4F
y 4Go
5/2
7/2
4690.141
33466.823
PT96
FW96
500
3502.280
0.80
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
b 4F
y 4Do
9/2
7/2
3482.780
32027.440
PT96
FW96
300
3526.850
0.137
3d 7 4s 2
3d 7 ( 4 F)4s4 p( 3 Po)
a 4F
z 4Fo
9/2
9/2
0.000
28345.814
PT96
M03
300
3529.808
0.46
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
b 4F
y 4Go
7/2
9/2
4142.631
32464.688
PT96
FW96
400
3569.376
1.6
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
a 6F
y 2Fo
7/2
7/2
7442.399
35450.505
PT96
FW96
Inten
Wavelength 共Å兲
250
2407.256
250
2411.624
200
2424.935
200
A ki (108 s⫺1 )
3.6
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1676
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Cobalt 共Co I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
3d 7 4s 2
a 4F
9/2
7/2
5/2
3/2
0.000
816.000
1406.852
1809.313
PT96
PT96
PT96
PT96
3d 8 ( 3 F)4s
b 4F
9/2
7/2
5/2
3/2
3482.780
4142.631
4690.141
5075.788
PT96
PT96
PT96
PT96
3d 8 ( 3 F)4s
a 6F
7/2
5/2
7442.399
8460.783
PT96
PT96
3d 7 4s 2
a 4P
5/2
3/2
1/2
13795.491
14036.241
14399.220
PT96
PT96
PT96
3d 8 ( 3 P)4s
b 4P
5/2
3/2
1/2
15184.013
15774.009
16195.610
PT96
PT96
PT96
3d 7 ( 4 F)4s4p( 3 Po)
z 4Fo
9/2
7/2
5/2
3/2
28345.814
28777.236
29216.332
29563.111
PT96
PT96
PT96
PT96
3d 7 ( 4 F)4s4p( 3 Po)
z 4Go
11/2
9/2
7/2
5/2
28845.165
29269.675
29735.131
30102.912
PT96
PT96
PT96
PT96
3d 7 ( 4 F)4s4p( 3 Po)
z 4Do
7/2
5/2
3/2
1/2
29294.482
29948.730
30443.596
30742.605
PT96
PT96
PT96
PT96
3d 7 ( 4 F)4s4p( 3 Po)
z 2Go
9/2
7/2
31699.638
32733.008
PT96
PT96
3d 7 ( 4 F)4s4p( 3 Po)
z 2Fo
7/2
5/2
31871.118
32781.672
PT96
PT96
3d 8 ( 3 F)4p
y 4Do
7/2
5/2
3/2
1/2
32027.440
32654.463
33150.616
33449.086
PT96
PT96
PT96
PT96
3d 8 ( 3 F)4p
y 4Go
11/2
9/2
7/2
5/2
32430.535
32464.688
33466.823
33674.326
PT96
PT96
PT96
PT96
3d 8 ( 3 F)4p
y 4Fo
9/2
7/2
5/2
3/2
32841.916
33173.313
33945.846
34196.147
PT96
PT96
PT96
PT96
3d 8 ( 3 F)4p
y 2Go
9/2
7/2
33439.661
34133.537
PT96
PT96
3d 7 ( 4 F)4s4p( 3 Po)
z 2Do
5/2
3/2
33462.795
34352.358
PT96
PT96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1677
Energy Levels of Neutral Cobalt 共Co I兲—Continued
J
Level (cm⫺1 )
Ref
3d ( F)4p
2 o
y F
7/2
5/2
35450.505
36329.834
PT96
PT96
3d 8 ( 3 F)4p
y 2Do
5/2
3/2
36092.420
36875.089
PT96
PT96
3d 7 ( 4 F)4s4p( 1 Po)
x 4Do
7/2
5/2
3/2
1/2
39649.124
40345.908
40827.712
41101.756
PT96
PT96
PT96
PT96
3d 7 ( 4 P)4s4p( 3 Po)
z 4So
3/2
40621.588
PT96
3d 7 ( 4 P)4s4p( 3 Po)
6 o
7/2
5/2
3/2
41041.348
41104.912
41247.585
PT96
PT96
PT96
3d 7 ( 4 F)4s4p( 1 Po)
x 4Fo
9/2
7/2
5/2
3/2
41225.710
41918.353
42434.160
42796.626
PT96
PT96
PT96
PT96
3d 7 ( 4 F)4s4p( 1 Po)
x 4Go
11/2
9/2
7/2
5/2
41528.455
42269.229
42811.351
43199.624
PT96
PT96
PT96
PT96
Limit
63564.6
PG90
Configuration
Term
8 3
P
Co II ( 3 F4 )
Persistent Lines of Singly-ionized Cobalt 共Co II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1000
2286.159
3.3
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Go
5
6
3350.494
47078.491
PRUJ98
FW96
800
2307.860
2.6
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Go
4
5
4028.988
47345.842
PRUJ98
FW96
500
2311.604
2.8
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Go
3
4
4560.789
47807.490
PRUJ98
FW96
500
2314.056
2.8
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Go
2
3
4950.062
48150.937
PRUJ98
FW96
200
2347.399
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Do
2
2
4950.062
47537.362
PRUJ98
200
2353.422
1.8
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Do
3
3
4560.789
47039.102
PRUJ98
FW96
500
2363.800
2.1
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Do
4
4
4028.988
46320.829
PRUJ98
FW96
400
2378.626
1.9
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Fo
5
4
3350.494
45378.751
PRUJ98
FW96
300
2383.459
1.8
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Fo
4
3
4028.988
45972.033
PRUJ98
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1678
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Cobalt 共Co II兲—Continued
Inten
Wavelength 共Å兲
200
2386.370
500
2388.917
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
3d ( F)4s
3d 7 ( 4 F)4p
5
a F
z 5Fo
3
2
4560.789
46452.697
PRUJ98
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Fo
5
5
3350.494
45197.708
PRUJ98
Configuration
7 4
1.5
A Ref
FW96
Energy Levels of Singly-ionized Cobalt 共Co II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
3
a F
4
3
2
0.000
950.324
1597.197
PRUJ98
PRUJ98
PRUJ98
3d 7 ( 4 F)4s
a 5F
5
4
3
2
1
3350.494
4028.988
4560.789
4950.062
5204.698
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
3d 7 ( 4 F)4s
b 3F
4
3
2
9812.859
10708.330
11321.859
PRUJ98
PRUJ98
PRUJ98
3d 7 ( 4 F)4p
z 5Fo
5
4
3
2
1
45197.708
45378.751
45972.033
46452.697
46786.406
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
3d 7 ( 4 F)4p
z 5Do
4
3
2
1
0
46320.829
47039.102
47537.362
47848.778
47995.591
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
3d 7 ( 4 F)4p
z 5Go
6
5
4
3
2
47078.491
47345.842
47807.490
48150.937
48388.439
PRUJ98
PRUJ98
PRUJ98
PRUJ98
PRUJ98
3d
8
Co III ( 4 F9/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
137795
SC85
ATOMIC SPECTROSCOPIC DATA
1679
Copper „Cu…
Atomic number⫽29
Atomic weight⫽63.546
Isotope
63
65
Cu
Cu
Mass
Abundance
Spin
Mag moment
62.939598
64.927793
69.17%
30.83%
3/2
3/2
⫹2.2233
⫹2.3817
Cu I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2S1/2
Ionization energy: 62 317.44 cm⫺1 共7.726 38 eV兲
Cu II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 10 1S0
Ionization energy: 163 669.2 cm⫺1 共20.2924 eV兲
Strong Lines of Copper 共Cu兲
Intensity
400
400
500
400
400
500
400
400
400
400
400
400
400
400
400
400
500
500
400
400
400
400
400
200 P
150 P
500
400
500
400
400
300 P
150
200
150
250
600
130
150
500
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
886.943
890.567
893.678
896.759
901.073
914.213
922.019
932.939
935.058
935.086
935.898
943.335
945.525
1036.470
1039.348
1039.582
1044.519
1044.744
1054.690
1056.955
1059.096
1060.634
1063.005
1358.773
1367.951
1488.637
1519.837
1541.703
1593.556
1621.426
1979.956
Air
1999.698
2035.854
2037.127
2043.802
2135.981
2165.09
2178.94
2179.410
Spectrum
Ref
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
II
II
II
II
II
I
I
II
R69
R69
R69
R69
R69
S48
S48
R69
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1680
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Copper 共Cu兲—Continued
Intensity
150
500
600
150
500
150
500
200
150
250
600
250
700
200
250
250
150
100
200
250
500
500
400
500
400
250
500
400
250
250
250
200
150
150
1000
1000
150
250
150
200
700
200
200
700
600
500
600
150
200
250
150
150
150
400
400
500
500
500
700
P
P
P
P
P
P
P
P
P
h
P
P
h
h
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
2181.72
2189.630
2192.268
2199.58
2210.268
2214.58
2218.108
2225.70
2227.78
2230.08
2242.618
2244.26
2247.002
2263.08
2293.84
2392.63
2406.66
2441.64
2492.15
2618.37
2689.300
2700.962
2703.184
2713.508
2718.778
2766.37
2769.669
2877.100
2961.16
3036.10
3063.41
3108.60
3194.10
3243.16
3247.54
3273.96
3290.54
3307.95
3337.84
3530.38
3686.555
4062.64
4651.12
4909.734
4931.698
4953.724
5051.793
5105.54
5153.24
5218.20
5292.52
5700.24
5782.13
6000.120
6150.384
6154.222
6216.939
6219.844
6273.349
Spectrum
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
I
II
II
I
II
I
II
I
I
I
II
I
II
I
I
I
I
I
I
I
II
II
II
II
II
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
II
II
II
II
I
I
I
I
I
I
II
II
II
II
II
II
Ref
S48
R69
R69
S48
R69
S48
R69
S48
S48
S48
R69
S48
R69
S48
S48
S48
S48
S48
S48
S48
R69
R69
R69
R69
R69
S48
R69
R69
S48
S48
S48
S48
S48
S48
S48
S48
S48
S48
S48
S48
R69
S48
S48
R69
R69
R69
R69
S48
S48
S48
S48
S48
S48
R69
R69
R69
R69
R69
R69
ATOMIC SPECTROSCOPIC DATA
1681
Strong Lines of Copper 共Cu兲—Continued
Wavelength 共Å兲
Intensity
600
500
600
500
600
500
500
500
700
500
700
500
500
1000
700
500
150
800
200
500
500
400
400
400
Spectrum
6301.009
6377.840
6423.884
6448.559
6470.168
6481.437
6624.292
6641.396
7404.354
7652.333
7664.648
7778.738
7805.184
7807.659
7825.654
7902.553
7933.13
7988.163
8092.63
8283.160
8511.061
9861.280
9864.137
10054.938
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Ref
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
II
II
II
II
II
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
R69
S48
R69
S48
R69
R69
R69
R69
R69
Persistent Lines of Neutral Copper 共Cu I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
130
2165.09
0.547
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
150
2178.94
0.913
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
150
200
250
250
100
200
1000
1000
2181.72
2225.70
0.994
0.444
3d 9 4s 2
3d 9 ( 2 D)4s4p( 1 Po)
2230.08
2244.26
2441.64
2492.15
3247.54
3273.96
0.0185
0.0201
0.0279
1.37
1.36
J
Level (cm⫺1 )
S
1/2
3/2
S
P
Term
Wl Ref
A Ref
0.000
46172.842
S48
M03
1/2
3/2
0.000
45879.311
S48
M03
S
P
1/2
1/2
0.000
45821.00
S48
M03
S
Do
1/2
1/2
0.000
44915.61
S48
M03
D
F
5/2
7/2
11202.565
56029.95
S48
S
Do
1/2
3/2
0.000
44544.153
S48
M03
S
P
1/2
1/2
0.000
40943.73
S48
M03
S
P
1/2
3/2
0.000
40113.99
S48
M03
S
P
1/2
3/2
0.000
30783.686
S48
M03
S
P
1/2
1/2
0.000
30535.302
S48
M03
2 o
2 o
4
2
2 o
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
3d 10( 1 S)4s
3d 9 ( 2 D)4s4p( 3 Po)
2
3d 10( 1 S)4s
3d 10( 1 S)4p
2
3d 10( 1 S)4s
3d 10( 1 S)4p
2
4
4 o
4 o
2 o
2 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1682
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Copper 共Cu I兲—Continued
Inten
Wavelength 共Å兲
150
200
250
5105.54
5153.24
5218.20
A ki (108 s⫺1 )
J
Level (cm⫺1 )
D
P
5/2
3/2
3d 10( 1 S)4p
3d 10( 1 S)4d
2 o
P
D
3d 10( 1 S)4p
3d 10( 1 S)4d
2 o
Configuration
9
Term
2
2
3d 4s
3d 10( 1 S)4p
0.020
0.60
0.75
2 o
2
2
P
D
Wl Ref
A Ref
11202.565
30783.686
S48
FW96
1/2
3/2
30535.302
49935.200
S48
FW96
3/2
5/2
30783.686
49942.057
S48
FW96
Energy Levels of Neutral Copper 共Cu I兲
Configuration
Term
3d 10( 1 S)4s
2
3d 9 4s 2
S
J
Level (cm⫺1 )
Ref
1/2
0.000
SM90
2
D
5/2
3/2
11202.565
13245.423
SM90
SM90
3d 10( 1 S)4p
2 o
P
1/2
3/2
30535.302
30783.686
SM90
SM90
3d 9 ( 2 D)4s4p( 3 Po)
4 o
P
5/2
3/2
1/2
39018.652
40113.99
40943.73
SM90
SM90
SM90
3d 9 ( 2 D)4s4p( 3 Po)
4 o
9/2
7/2
5/2
3/2
40909.138
41153.433
41562.895
42302.47
SM90
SM90
SM90
SM90
3d 10( 1 S)5s
2
F
1/2
43137.209
SM90
3d ( D)4s4p( P )
4
o
D
7/2
5/2
3/2
1/2
43513.95
44406.268
44544.153
44915.61
SM90
SM90
SM90
SM90
3d 9 ( 2 D)4s4p( 3 Po)
2 o
1/2
3/2
45821.00
45879.311
SM90
SM90
3/2
46172.842
SM90
9 2
3 o
S
P
3d 9 ( 2 D)4s4p( 3 Po)
3d 10( 1 S)4d
2
D
3/2
5/2
49935.200
49942.057
SM90
SM90
3d 9 ( 2 D)4s4p( 1 Po)
2 o
7/2
5/2
56029.95
58119.28
SM90
SM90
Limit
62317.44
SM90
F
Cu II ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1683
Persistent Lines of Singly-ionized Copper 共Cu II兲
Inten
200
150
300
150
200
150
250
600
600
500
700
Wavelength 共Å兲
A ki (108 s⫺1 )
1358.773
3.17
1367.951
2.13
1979.956
1999.698
2.21
2035.854
2037.127
1.41
2043.802
2135.981
3.33
2192.268
2.54
2218.108
2247.002
3.27
Configuration
10
Term
J
Level (cm⫺1 )
1
0
1
0.000
73595.813
R69
M03
S
Do
0
1
0.000
73102.038
R69
M03
D
Do
2
2
22847.131
73353.292
R69
D
Do
3
3
21928.754
71920.102
R69
D
Do
1
1
23998.381
73102.038
R69
D
Do
2
3
22847.131
71920.102
R69
D
F
3
3
21928.754
70841.470
R69
D
F
3
4
21928.754
68730.893
R69
CKNJ94
D
F
2
3
22847.131
68447.741
R69
CKNJ94
D
P
2
1
22847.131
67916.555
R69
D
P
3
2
21928.754
66418.687
R69
S
P
3d
3d 9 4 p
1 o
3d 10
3d 9 4 p
1
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3d 9 4s
3d 9 4 p
3
3
3
3
3
1 o
3 o
3 o
3 o
3 o
Wl Ref
A Ref
CKNJ94
CKNJ94
CKNJ94
Energy Levels of Singly-ionized Copper 共Cu II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3d 10
1
S
0
0.000
SM90
3d 9 4s
3
D
3
2
1
21928.754
22847.131
23998.381
SM90
SM90
SM90
3d 9 4s
1
D
2
26264.568
SM90
3d 9 4p
3 o
P
2
1
0
66418.687
67916.555
68850.260
SM90
SM90
SM90
3d 9 4p
3 o
F
3
4
2
68447.741
68730.893
69867.983
SM90
SM90
SM90
3d 9 4p
1 o
F
3
70841.470
SM90
3d 9 4p
3
Do
3
1
2
71920.102
73102.038
73353.292
SM90
SM90
SM90
3d 9 4p
1 o
1
73595.813
SM90
Cu III ( 2 D5/2)
P
Limit
163669.2
SM90
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1684
J. E. SANSONETTI AND W. C. MARTIN
Curium „Cm…
Atomic number⫽96
Atomic weight⫽(247)
Isotope
245
Cm
Cm
247
Cm
248
Cm
246
Mass
Abundance
Spin
Mag moment
245.058830
246.067218
247.070347
248.072343
0
0
0
0
7/2
0
9/2
0
0.5
⫹0.37
Cm I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 7 6d7s 2 9Do2
Ionization energy: 48 324 cm⫺1 共5.9914 eV兲
o
Cm II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 7 7s 2 8S7/2
Ionization energy: not available
Strong Lines of Curium 共Cm兲
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Wavelength 共Å兲
P
P
P
P
P
P
b
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2462.764
2617.169
2636.281
2651.171
2653.804
2725.682
2736.892
2748.039
2784.826
2811.618
2824.204
2833.580
2899.904
2912.965
2928.922
2996.180
2999.385
3014.867
3044.848
3109.690
3116.411
3135.099
3137.160
3147.325
3158.599
3169.983
3177.554
3179.098
3186.412
3188.109
3207.121
3207.708
3209.892
3209.943
3210.050
3220.759
3224.226
3225.108
Spectrum
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
I
I
I
I
I
I
II
I
I
I
I
II
I
II
I
II
II
I
I
Ref
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
ATOMIC SPECTROSCOPIC DATA
1685
Strong Lines of Curium 共Cm兲—Continued
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
P
b
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3226.412
3230.278
3230.349
3236.737
3238.548
3242.657
3246.247
3252.675
3265.806
3280.450
3296.708
3304.849
3317.143
3374.696
3452.922
3458.338
3510.279
3522.355
3524.938
3542.059
3547.018
3547.922
3561.437
3572.949
3600.615
3639.944
3664.340
3709.426
3729.004
3732.351
3747.863
3763.045
3775.751
3816.304
3825.138
3833.315
3837.593
3842.000
3849.924
3854.106
3900.253
3904.064
3908.238
3936.666
3942.025
3944.146
3948.683
3953.362
3964.827
3995.100
4016.17
4031.76
4048.29
4049.65
4113.29
4129.71
4207.66
4211.62
4266.45
Spectrum
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
II
I
II
I
II
II
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
Ref
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1686
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Curium 共Cm兲—Continued
Intensity
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Wavelength 共Å兲
Spectrum
4293.00
4330.82
4345.69
4447.77
4459.16
4608.40
5846.07
5952.41
6058.90
6243.35
6376.71
6554.41
6640.17
6686.87
6706.85
6726.68
6793.15
7162.69
7720.47
8392.37
10542.98
10792.25
11834.28
12464.99
13004.56
13258.18
13289.84
13480.54
13590.01
13644.77
13789.52
13908.46
14235.27
14334.52
14563.41
14580.23
15018.13
P
P
P
P
P
P
P
P
P
P
P
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
Cm
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
WHGC76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
CBV76
Persistent Lines of Neutral Curium 共Cm I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
8
2
Term
J
Level (cm⫺1 )
Wl Ref
7
F
6
6
1214.203
33362.424
WHGC76
1000
3109.690
5 f 7s
5 f 7 6d7s 2
o
1000
3116.411
5 f 7 6d7s 2
5 f 7 6d7s7 p
5
Do
P
2
2
0.000
32078.886
WHGC76
1000
3224.226
5 f 7 6d7s 2
5 f 7 6d7s7 p
9
Do
5
4
1764.268
32770.516
WHGC76
1000
3225.108
5 f 7 6d7s 2
5 f 7 6d7s7 p
9
Do
5
6
1764.268
32762.036
WHGC76
1000
3304.849
5 f 8 7s 2
7
F
6
7
1214.203
31464.053
WHGC76
1000
3452.922
5 f 7 6d7s 2
5 f 7 6d7s7 p
Do
6
6
3809.355
32762.036
WHGC76
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
9
o
9
A Ref
ATOMIC SPECTROSCOPIC DATA
1687
Persistent Lines of Neutral Curium 共Cm I兲—Continued
Inten
1000
Wavelength 共Å兲
3458.338
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
F
6
5
1214.203
30121.545
WHGC76
F
6
7
1214.203
27410.123
WHGC76
F
(6,1) o
6
7
1214.203
26609.213
WHGC76
9
Do
D
2
3
0.000
25023.578
WHGC76
F
F
6
7
1214.203
24951.328
WHGC76
Do
D
2
3
0.000
23083.822
WHGC76
Configuration
8
5 f 7s
2
Term
7
o
1000
3816.304
5 f 8 7s 2
7
o
1000
3936.666
5 f 8 7s 2
5 f 8 ()7s7 p( 1 Po1 )
1000
3995.100
5 f 7 6d7s 2
5 f 7 6d7s7 p
1000
1000
4211.62
4330.82
5 f 8 7s 2
5 f 7 6d 2 7s
5 f 7 6d7s 2
5 f 7 6d7s7 p
7
7
7
9 o
9
9
1000
4459.16
5 f 8 7s 2
5 f 8 ()7s7 p( 3 Po2 )
7
F
(6,2) o
6
6
1214.203
23633.638
WHGC76
1000
4608.40
5 f 8 7s 2
5 f 8 ()7s7 p( 3 Po2 )
7
F
(6,2) o
6
7
1214.203
22907.611
WHGC76
1000
5952.41
5 f 8 7s 2
5 f 8 ( 7 F6 )7s7p( 3 Po1 )
7
F
(6,1) o
6
7
1214.203
18009.483
WHGC76
1000
6376.71
5 f 7 6d7s 2
5 f 7 6d7s7 p
9
2
3
0.000
15677.750
WHGC76
Do
F
11
1000
6706.85
5 f 7 6d7s 2
5 f 7 ( 8 So)7s 2 7 p
9
Do
共7/2,3/2兲
4
5
815.655
15721.679
WHGC76
1000
7162.69
5 f 7 6d7s 2
5 f 7 ( 8 So)7s 2 7 p
9
Do
共7/2,3/2兲
5
5
1764.268
15721.679
WHGC76
1000
7720.47
5 f 7 6d7s 2
5 f 7 6d7s7 p
7
5
5
9064.880
22013.913
WHGC76
9
Do
F
1000
8392.37
5 f 7 6d7s 2
5 f 7 ( 8 So)7s 2 7 p
9
Do
共7/2,3/2兲
6
5
3809.355
15721.679
WHGC76
1000
10542.98
5 f 7 6d7s 2
5 f 7 ( 8 So)7s 2 7 p
9
Do
共7/2,1/2兲
3
4
302.153
9784.543
WHGC76
1000
10792.25
5 f 7 6d7s 2
5 f 7 ( 8 So)7s 2 7 p
9
2
3
0.000
9263.374
WHGC76
Do
共7/2,1/2兲
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1688
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Curium 共Cm I兲
Configuration
7
5 f 6d7s
2
Term
9
o
D
J
Level (cm⫺1 )
Ref
2
3
4
5
6
0.000
302.153
815.655
1764.268
3809.355
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 8 7s 2
7
6
4
5
3
2
1
0
1214.203
4877.610
5136.519
7208.827
7521.122
8696.688
8887.265
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 7 6d7s 2
7
4
5
3
2
1
8958.447
9064.880
9458.053
9671.692
10133.857
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 7 ( 8 So)7s 2 7p
共7/2,1/2兲
3
4
9263.374
9784.543
BW92b
BW92b
5 f 7 6d7s7p
11
3
15677.750
BW92b
5 f 7 ( 8 So)7s 2 7p
共7/2,3/2兲
5
15721.679
BW92b
5 f 8 ( 7 F6 )7s7p( 3 Po1 )
(6,1) o
7
18009.483
BW92b
5 f 6d7s7p
9
F
5
22013.913
BW92b
5 f 7 6d7s7p
9
D
3
23083.822
BW92b
5 f 8 ()7s7p( 3 Po2 )
(6,2) o
7
22907.611
BW92b
5 f 8 ()7s7p( 3 Po2 )
(6,2) o
6
23633.638
BW92b
5 f 6d 7s
9 o
F
7
24951.328
BW92b
5 f 7 6d7s7p
7
D
3
25023.578
BW92b
5 f 8 ()7s7p( 1 Po1 )
(6,1) o
7
26609.213
BW92b
o
7
27410.123
BW92b
o
5
30121.545
BW92b
o
7
31464.053
BW92b
2
32078.886
BW92b
6
32762.036
BW92b
4
32770.516
BW92b
6
33362.424
BW92b
48324
KDEE97
7
7
2
5 f 7 6d7s7p
F
Do
5
F
P
5 f 7 6d7s7p
7
5 f 6d7s7p
5 f 7 6d7s 2
o
o
)
Cm II ( 8 S7/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1689
Persistent Lines of Singly-ionized Curium 共Cm II兲
Inten
1000
1000
1000
1000
1000
Wavelength 共Å兲
A ki (108 s⫺1 )
7
2
5 f 7s
5 f 7 ( 8 So)7s7p( 1 Po)
2462.764
5 f 7 6d7s
5 f 7 6d7 p
2636.281
5 f 7 7s 2
5 f 7 6d7 p
2833.580
Wl Ref
S
P
7/2
5/2
0.000
40592.510
WHGC76
10
7/2
9/2
4411.540
42332.445
WHGC76
S
P
7/2
9/2
0.000
35397.790
WHGC76
8 o
S
D
7/2
5/2
0.000
35280.665
WHGC76
F
13/2
13/2
2093.870
36413.100
WHGC76
F
13/2
15/2
2093.870
36226.140
WHGC76
8 o
8
Do
D
8 o
8
10
5 f 8 7s
2912.965
Level (cm⫺1 )
Term
8
5 f 7 7s 2
5 f 7 ( 8 So)7s7p( 3 Po)
2824.204
J
Configuration
8
o
1000
5 f 8 7s
2928.922
8
o
1000
3044.848
5 f 8 7s
5 f 8 ( 7 F6 )7p 3/2
8
F
(6,3/2) o
13/2
13/2
2093.870
34926.680
WHGC76
1000
3242.657
5 f 8 7s
5 f 7 6d 2
8
13/2
13/2
2093.870
32923.880
WHGC76
7/2
5/2
0.000
27980.085
WHGC76
13/2
13/2
2093.870
27700.945
WHGC76
7/2
9/2
0.000
25579.725
WHGC76
11/2
13/2
3941.439
27700.945
WHGC76
1000
5 f 7 7s 2
5 f 7 ( 8 So)7s7p( 3 Po)
3572.949
1000
3904.064
5 f 8 7s
5 f 8 ( 7 F6 )7p 1/2
1000
3908.238
5 f 7 7s 2
5 f 7 ( 8 So)7s7p( 3 Po)
1000
8 o
8
S
P
8
F
(6,1/2) o
5 f 8 7s
5 f 8 ( 7 F6 )7p 1/2
4207.66
F
o
8 o
S
P
10
6
F
(6,1/2) o
A Ref
Energy Levels of Singly-ionized Curium 共Cm II兲
Configuration
Term
5 f 7 7s 2
8 o
J
Level (cm⫺1 )
Ref
S
7/2
0.000
BW92b
8
5 f 7s
8
F
13/2
9/2
11/2
7/2
5/2
3/2
1/2
2093.870
5919.263
6347.900
7067.133
8436.099
9127.846
9801.305
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 8 7s
6
F
11/2
9/2
7/2
5/2
3/2
1/2
3941.439
8144.306
9073.572
10433.776
11250.886
11978.441
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1690
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Curium 共Cm II兲—Continued
J
Level (cm⫺1 )
Ref
D
5/2
7/2
9/2
11/2
13/2
4010.645
4411.540
5067.900
6202.430
8425.360
BW92b
BW92b
BW92b
BW92b
BW92b
Do
3/2
5/2
7/2
9/2
11/2
8199.890
8474.775
9012.480
10134.785
12913.101
BW92b
BW92b
BW92b
BW92b
BW92b
9/2
25579.725
BW92b
13/2
27700.945
BW92b
5/2
27980.085
BW92b
Configuration
Term
7
5 f 6d7s
10
5 f 7 6d7s
8
5 f 7 ( 8 So)7s7p( 3 Po)
10
8 7
o
P
o
5 f ( F6 )7p 1/2
(6,1/2)
5 f 7 ( 8 So)7s7p( 3 Po)
8
5 f 7 6d 2
o
13/2
32923.880
BW92b
5 f 8 ( 7 F6 )7p 3/2
(6,3/2) o
13/2
34926.680
BW92b
5/2
35280.665
BW92b
9/2
35397.790
BW92b
o
15/2
36226.140
BW92b
o
13/2
36413.100
BW92b
7
P
5 f 6d7p
10
5 f 7 ( 8 So)7s7p( 3 Po)
8
7 8 o
1 o
D
P
5 f ( S )7s7p( P )
8
P
5/2
40592.510
BW92b
5 f 7 6d7p
8
D
9/2
42332.445
BW92b
Cm III (5 f 8 7F6 ?)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1691
Dysprosium „Dy…
Atomic number⫽66
Atomic weight⫽162.50
Isotope
160
Dy
Dy
162
Dy
163
Dy
164
Dy
161
Mass
Abundance
Spin
159.925193
160.926930
161.926795
162.928728
163.929171
2.34%
18.9%
25.5%
24.9%
28.2%
0
5/2
0
5/2
0
Mag moment
⫺0.48
⫹0.673
Dy I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 106s 2 5I8
Ionization energy: 47 900 cm⫺1 共5.9389 eV兲
Dy II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 9 ( 5 I8)6s (8,1/2) 17/2
Ionization energy: 94 100 cm⫺1 共11.67 eV兲
Strong Lines of Dysprosium 共Dy兲
Intensity
25
20
30
40
50
30
50
40
50
40
50
40
50
40
250
30
150
60
250
60
40
90
60
150
40
120
60
200
30
60
200
40
40
40
60
200
1000
P
P
P
P
P
Wavelength 共Å兲
Air
2623.688
2634.803
3038.288
3135.384
3156.521
3162.833
3169.992
3216.627
3251.268
3280.091
3308.883
3316.316
3319.878
3340.993
3385.014
3388.850
3393.567
3396.156
3407.792
3413.783
3419.631
3434.367
3441.446
3445.572
3446.992
3454.315
3456.557
3460.966
3468.429
3477.067
3494.489
3498.707
3504.528
3505.452
3506.812
3523.979
3531.703
Spectrum
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1692
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Dysprosium 共Dy兲—Continued
Intensity
200
250
200
80
60
200
100
100
40
60
200
80
40
150
60
50
80
25
80
50
200
50
500
50
30
25
40
60
100
40
50
80
200
40
70
20
60
50
60
60
80
200
40
20
40
25
25
150
70
30
25
30
60
30
100
25
60
20
25
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3534.958
3536.018
3538.516
3542.327
3546.832
3550.217
3551.615
3563.146
3573.830
3574.152
3576.242
3576.865
3577.983
3585.058
3585.778
3591.416
3595.037
3600.374
3606.121
3629.419
3630.239
3640.249
3645.396
3648.786
3664.614
3666.838
3672.296
3674.086
3676.586
3678.504
3684.850
3685.777
3694.811
3698.206
3724.445
3727.996
3739.340
3747.813
3753.504
3753.747
3757.049
3757.367
3767.625
3771.106
3773.051
3774.714
3781.467
3786.176
3788.438
3791.870
3806.269
3812.272
3816.762
3825.682
3836.504
3840.890
3841.307
3844.361
3847.019
Spectrum
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
I
I
I
II
II
II
I
I
II
II
II
I
II
I
I
I
I
I
II
II
II
II
I
II
II
II
I
II
I
I
Ref
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
ATOMIC SPECTROSCOPIC DATA
1693
Strong Lines of Dysprosium 共Dy兲—Continued
Intensity
50
25
100
40
300
50
250
30
25
30
90
25
500
40
25
600
120
60
70
40
70
400
25
30
25
800
70
110
300
25
25
200
50
70
40
20
25
50
60
400
25
60
800
140
400
50
40
40
30
1000
110
250
300
300
30
150
40
40
30
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3853.026
3858.402
3868.803
3869.861
3872.103
3873.986
3898.528
3917.286
3927.860
3930.147
3931.526
3936.701
3944.679
3957.791
3962.590
3968.384
3978.564
3981.926
3983.651
3984.210
3996.688
4000.449
4005.837
4013.822
4023.715
4045.970
4050.566
4073.119
4077.965
4085.336
4096.100
4103.305
4103.874
4111.340
4129.423
4130.352
4133.850
4143.100
4146.060
4167.974
4171.931
4183.721
4186.821
4191.640
4194.846
4198.015
4201.301
4202.240
4211.238
4211.714
4213.180
4215.159
4218.092
4221.110
4222.212
4225.154
4232.024
4239.856
4245.912
Spectrum
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
II
I
I
II
II
II
II
I
I
I
II
I
II
II
I
II
II
II
II
II
II
II
I
I
I
I
II
II
II
I
I
II
I
II
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1694
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Dysprosium 共Dy兲—Continued
Intensity
Wavelength 共Å兲
50
20
30
25
130 P
60
20
15
4308.630
4325.868
4449.705
4577.775
4589.364
4612.258
4957.347
6259.087
Spectrum
Dy
Dy
Dy
Dy
Dy
Dy
Dy
Dy
II
I
II
I
I
I
II
I
Ref
NG00
NG00
NG00
NG00
NG00
NG00
NG00
NG00
Persistent Lines of Neutral Dysprosium 共Dy I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
10
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
5
800
4045.970
1.92
4 f 6s
4 f 10( 5 I8 )6s6p( 1 Po1 )
I
(8,1) o
8
7
0.000
24708.971
NG00
WLN00
400
4167.974
1.92
4 f 106s 2
4 f 10( 5 I7 )6s6p( 1 Po1 )
5
I
(7,1) o
7
6
4134.222
28119.931
NG00
WLN00
800
4186.821
1.26
4 f 106s 2
4 f 10( 5 I8 )6s6p( 1 Po1 )
5
I
(8,1) o
8
8
0.000
23877.739
NG00
WLN00
140
4191.640
0.71
4 f 106s 2
4 f 9 ( 6 Ho)5d 2 ( 3 F)( 8 Lo)6s
5
I
7
7
4134.222
27984.513
NG00
WLN00
I
8
8
0.000
23832.060
NG00
WLN00
I
(8,1) o
8
9
0.000
23736.610
NG00
WLN00
5
7
8
4134.222
27851.435
NG00
WLN00
400
4194.846
0.88
4 f 106s 2
4 f 9 ( 6 Ho)5d 2 ( 3 F)( 8 Ko)6s
1000
4211.714
2.08
4 f 106s 2
4 f 10( 5 I8 )6s6p( 1 Po1 )
250
4215.159
0.81
4 f 106s 2
4 f 9 ( 6 Ho)5d 2 ( 3 P)( 8 Io)6s
o
5
o
5
I
o
300
4218.092
1.20
4 f 106s 2
4 f 10( 5 I7 )6s6p( 1 Po1 )
5
I
(7,1) o
7
7
4134.222
27834.933
NG00
WLN00
300
4221.110
1.28
4 f 106s 2
4 f 10( 5 I7 )6s6p( 1 Po1 )
5
I
(7,1) o
7
8
4134.222
27818.000
NG00
WLN00
150
4225.154
1.95
4 f 106s 2
4 f 10( 5 I6 )6s6p( 1 Po1 )
5
I
(6,1) o
6
7
7050.603
30711.717
NG00
WLN00
130
4589.364
0.137
4 f 106s 2
4 f 9 ( 6 Ho)5d6s 2
5
8
7
0.000
21783.407
NG00
WLN00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5
I
Ko
ATOMIC SPECTROSCOPIC DATA
1695
Energy Levels of Neutral Dysprosium 共Dy I兲
Term
J
Level (cm⫺1 )
2
5
8
7
6
5
4
0.000
4134.222
7050.603
9211.591
10925.277
NG00
NG00
NG00
NG00
NG00
4 f 9 ( 6 Ho)5d6s 2
7
8
7
6
5
4
3
2
7565.610
8519.210
10088.802
12298.551
13952.001
15254.936
—
NG00
NG00
NG00
NG00
NG00
NG00
4 f 9 ( 6 Ho)5d6s 2
7 o
9
8
7
6
5
4
3
9990.974
12007.121
14367.806
14970.701
16684.731
—
—
NG00
NG00
NG00
NG00
NG00
4 f 9 ( 6 Ho)5d6s 2
5
9
8
7
6
5
13495.932
19688.595
21783.407
23464.019
24881.867
NG00
NG00
NG00
NG00
NG00
4 f 10( 5 I8 )6s6p( 1 Po1 )
(8,1) o
9
8
7
23736.610
23877.739
24708.971
NG00
NG00
NG00
4 f 9 ( 6 Ho)5d 2 ( 3 F)( 8 Ko)6s
o
8
23832.060
NG00
4 f 10( 5 I7 )6s6p( 1 Po1 )
(7,1) o
8
7
6
27818.000
27834.933
28119.931
NG00
NG00
NG00
4 f 9 ( 6 Ho)5d 2 ( 3 P)( 8 Io)6s
o
8
27851.435
NG00
4 f 9 ( 6 Ho)5d 2 ( 3 F)( 8 Lo)6s
o
7
27984.513
NG00
4 f 10( 5 I6 )6s6p( 1 Po1 )
(6,1) o
7
6
5
30711.717
30778.958
—
NG00
NG00
47900
WSPC78
Configuration
10
4 f 6s
Dy II ( 5 I8 )6s 1/2 (8,1/2) 17/2
I
Ho
I
Ko
Limit
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1696
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Dysprosium 共Dy II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
250
3385.014
0.539
4 f ( I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
4 o
H
15/2
13/2
828.314
30361.810
NG00
WLN00
250
3407.792
0.488
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
6 o
I
17/2
17/2
0.000
29336.093
NG00
WLN00
200
3460.966
0.297
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
17/2
15/2
0.000
28885.393
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
15/2
15/2
828.314
29436.610
NG00
WLN00
o
200
3494.489
0.315
10 5
o
1000
3531.703
1.56
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
6 o
K
17/2
19/2
0.000
28306.843
NG00
WLN00
250
3536.018
1.01
4 f 10( 5 I7 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 3 F)
共7,1/2兲
15/2
17/2
4341.104
32613.423
NG00
WLN00
o
200
3630.239
0.305
4 f 10( 5 I7 )6s 1/2
4 f 10( 5 I)6p
共7,1/2兲
6 o
K
15/2
17/2
4341.104
31879.655
NG00
WLN00
500
3645.396
0.620
4 f 10( 5 I8 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 1 G)
共8,1/2兲
15/2
17/2
828.314
28252.357
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 3 F)
共8,1/2兲
15/2
15/2
828.314
27885.593
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 3 P)
共8,1/2兲
15/2
15/2
828.314
27435.132
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
17/2
17/2
0.000
25818.435
NG00
WLN00
4 f 10( 5 I7 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 3 F)
共7,1/2兲
13/2
15/2
4755.673
30399.107
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 3 P)
共8,1/2兲
17/2
17/2
0.000
25343.427
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
17/2
15/2
0.000
25192.039
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
15/2
17/2
828.314
25818.435
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 9 ( 6 Ho)5d 2 ( 3 P)
共8,1/2兲
15/2
17/2
828.314
25343.427
NG00
WLN00
4 f 10( 5 I8 )6s 1/2
4 f 10( 5 I)6p
共8,1/2兲
15/2
15/2
828.314
25192.039
NG00
WLN00
200
200
300
250
500
600
400
300
200
3694.811
3757.367
3872.103
3898.528
3944.679
3968.384
4000.449
4077.965
4103.305
0.237
0.201
0.254
0.469
0.307
0.455
0.254
0.202
0.104
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
o
o
o
o
o
o
o
o
o
o
ATOMIC SPECTROSCOPIC DATA
1697
Energy Levels of Singly-ionized Dysprosium 共Dy II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
4 f ( I8 )6s 1/2
共8,1/2兲
17/2
15/2
0.000
828.314
NG00
NG00
4 f 10( 5 I7 )6s 1/2
共7,1/2兲
15/2
13/2
4341.104
4755.673
NG00
NG00
4 f 10( 5 I6 )6s 1/2
共6,1/2兲
11/2
13/2
7463.905
7485.117
NG00
NG00
4 f 10( 5 I5 )6s 1/2
共5,1/2兲
9/2
11/2
9432.105
9871.028
NG00
NG00
4 f 9 ( 6 Ho)5d( 7 Ho)6s
8
17/2
15/2
13/2
11/2
9/2
7/2
5/2
3/2
10594.197
11394.912
12674.694
14347.205
16015.394
—
—
—
NG00
NG00
NG00
NG00
NG00
4 f 10( 5 I4 )6s 1/2
共4,1/2兲
7/2
9/2
10953.984
11801.052
NG00
NG00
4 f 9 6s 2
6
15/2
13/2
11/2
9/2
7/2
5/2
12336.314
15822.169
18121.480
—
—
—
NG00
NG00
NG00
4 f 10( 5 I)6p
o
15/2
25192.039
NG00
4 f 9 ( 6 Ho)5d 2 ( 3 P)
o
17/2
25343.427
NG00
4 f 10( 5 I)6p
o
17/2
25818.435
NG00
4 f 9 ( 6 Ho)5d 2 ( 3 P)
o
15/2
27435.132
NG00
4 f ( H )5d ( F)
o
15/2
27885.593
NG00
4 f 9 ( 6 Ho)5d 2 ( 1 G)
o
17/2
28252.357
NG00
4 f 10( 5 I)6p
6
19/2
28306.843
NG00
4 f 10( 5 I)6p
o
10 5
9 6
o
2 3
Ho
Ho
Ko
15/2
28885.393
NG00
4 f ( I)6p
6 o
17/2
29336.093
NG00
4 f 10( 5 I)6p
o
15/2
29436.610
NG00
4 f 10( 5 I)6p
4
13/2
30361.810
NG00
15/2
30399.107
NG00
17/2
31879.655
NG00
17/2
32613.423
NG00
Limit
94100
MZH78
10 5
9 6
o
I
4 f ( H )5d ( F)
o
4 f 10( 5 I)6p
6
4 f 9 ( 6 Ho)5d 2 ( 3 F)
o
Dy III ( 5 I8 )
2 3
Ho
Ko
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1698
J. E. SANSONETTI AND W. C. MARTIN
Einsteinium „Es…
Atomic number⫽99
Atomic weight⫽(254)
Isotope
252
Es
Es
254
Es
255
Es
253
Mass
Abundance
Spin
252.082944
253.084818
254.088019
255.090270
0
0
0
0
5
7/2
7
7/2
Mag moment
4.10
o
Es I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 117s 2 4I15/2
⫺1
Ionization energy: 51 800 cm 共6.42 eV兲
Es II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 11( 4 I 15/2)7s (15/2,1/2) o8
Ionization energy: 关 97 000兴 cm⫺1 共12.0 eV兲
Strong Lines of Einsteinium 共Es兲
Intensity
1000
100
100
300
100
300*
300*
300
100
300
100
1000
1000
300
300
300
1000
1000
1000
1000
1000
1000
1000
300
300
100
100
300
100
1000
100
300
1000
100
1000
100
1000
1000
P,s
s
l
P,l
l
l
P,l
l
l
P,s
s
s
P,s
P,l
P,s
P,s
s
P,s
P,l
s
s
s
s
P,s
s
l
s
l
P,l
l
P,l
l
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2708.66
2724.57
2765.76
2787.10
2796.11
2815.15
2815.15
2907.03
3065.40
3135.25
3154.27
3413.17
3428.48
3445.25
3452.36
3484.59
3498.11
3514.33
3521.38
3523.49
3536.01
3547.75
3555.34
3556.65
3560.92
3575.68
3582.95
3590.28
3595.47
3602.43
3606.75
3631.09
3632.87
3651.94
3670.01
3720.56
3728.55
3792.99
Spectrum
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
II
II
II
II
II
I
II
I
II
I
I
I
I
I
I
II
I
II
II
II
II
II
II
Ref
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
ATOMIC SPECTROSCOPIC DATA
1699
Strong Lines of Einsteinium 共Es兲—Continued
Wavelength 共Å兲
Intensity
1000
300
1000
300
100
100
100
300
1000
100
1000
1000
300
P,l
Spectrum
3801.49
3930.77
4082.24
4107.59
4176.94
4789.93
4802.21
4958.29
5052.08
5102.93
5161.74
5204.40
5615.51
s
l
l
h
h
s
s
P,s
P,l
P,l
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
Es
I
I
Ref
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
WLGC74
I
I
I
I
Persistent Lines of Neutral Einsteinium 共Es I兲
J
Level (cm⫺1 )
Wl Ref
4 o
I
15/2
15/2,17/2
0.00
29159.28
WLGC74
5 f 117s 2
5 f 106d7s 2
4 o
I
15/2
15/2,17/2
0.00
28578.60
WLGC74
3514.33
5 f 117s 2
5 f 117s7p
4 o
15/2
13/2
0.00
28447.02
WLGC74
1000
3521.38
5 f 117s 2
o
13/2
11/2
10244.29
38634.04
WLGC74
1000
3523.49
5 f 117s 2
5 f 106d7s 2
4 o
I
15/2
13/2,15/2,17/2
0.00
28372.78
WLGC74
1000
3555.34
5 f 117s 2
5 f 106d7s 2
4 o
I
15/2
13/2
0.00
28118.65
WLGC74
1000
3801.49
5 f 117s 2
4 o
F
9/2
9/2
7894.54
34192.6
WLGC74
1000
5161.74
5 f 117s 2
5 f 106d7s 2
4 o
I
I
15/2
17/2
0.00
19367.85
WLGC74
4 o
I
I
15/2
17/2
0.00
19209.15
WLGC74
4 o
15/2
15/2
0.00
17803.09
WLGC74
Inten
Wavelength 共Å兲
1000
A ki (108 s⫺1 )
Configuration
Term
3428.48
5 f 117s 2
1000
3498.11
1000
1000
300
5204.40
5615.51
5 f 117s 2
5 f 117s7p
5 f 117s 2
5 f 117s7p
I
6
6
6
I
I
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1700
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Einsteinium 共Es I兲
Configuration
11
Level (cm⫺1 )
J
Ref
4 o
I
15/2
0.00
BW92b
5 f 117s 2
4 o
9/2
7894.54
BW92b
5 f 117s 2
2
11/2
8759.27
BW92b
11
o
13/2
10244.29
BW92b
5 f 117s7p
6
I
15/2
17803.09
BW92b
5 f 117s7p
6
I
17/2
19209.15
BW92b
5 f 106d7s 2
6
17/2
19367.85
BW92b
5 f 7s7p
13/2,15/2
19788.32
BW92b
5 f 106d7s 2
13/2
28118.65
BW92b
5 f 106d7s 2
13/2,15/2,17/2
28372.78
BW92b
5 f 117s7p
5 f 7s
5 f 7s
2
Term
F
Ho
2
I
11
13/2
28447.02
BW92b
2
15/2,17/2
28578.60
BW92b
5 f 106d7s 2
15/2,17/2
28689.74
BW92b
15/2,17/2
29159.28
BW92b
13/2
29204.89
BW92b
11/2
31829.03
BW92b
13/2
31886.3
BW92b
13/2
32770.06
BW92b
10
5 f 6d7s
5 f 117s7p
5 f 106d7s 2
o
)7s8s( 3 S1 )
5 f 11( 4 I15/2
(15/2,1) o
17/2
33829.35
BW92b
o
5 f 11( 4 I15/2
)7s8s( 3 S1 )
(15/2,1) o
15/2
34068.94
BW92b
9/2
34192.6
BW92b
13/2
35507.74
BW92b
11/2
38634.04
BW92b
Limit
51800
S74
Es II
((15/2,1/2) o8 )
Persistent Lines of Singly-ionized Einsteinium 共Es II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
(15/2,1/2) o
(15/2,3/2)
8
9
0.00
36907.83
WLGC74
1000
2708.66
o
)7s
5 f 11( 4 I15/2
o
5 f 11( 4 I15/2
)7p
300
2787.10
o
)7s
5 f 11( 4 I15/2
10
5 f 6d7s
(15/2,1/2) o
7
7
938.65
36807.72
WLGC74
300*
2815.15
o
)7s
5 f 11( 4 I15/2
11 2 o
5 f ( H11/2)7p
(15/2,1/2) o
共11/2,1/2兲
7
6
938.65
36450.29
WLGC74
1000
3547.75
o
)7s
5 f 11( 4 I15/2
11
5 f 7p
(15/2,1/2) o
共15/2,1/2兲
8
8
0.00
28178.81
WLGC74
1000
3602.43
o
)7s
5 f 11( 4 I15/2
11
5 f 7p
(15/2,1/2) o
共15/2,1/2兲
8
7
0.00
27751.11
WLGC74
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
A Ref
ATOMIC SPECTROSCOPIC DATA
1701
Persistent Lines of Singly-ionized Einsteinium 共Es II兲—Continued
Wavelength 共Å兲
Inten
1000
A ki (108 s⫺1 )
Configuration
3670.01
1000
3728.55
Term
J
Level (cm⫺1 )
Wl Ref
o
)7s
5 f 11( 4 I15/2
11
7
8
938.65
28178.81
WLGC74
5 f 7p
(15/2,1/2)
共15/2,1/2兲
o
o
)7s
5 f 11( 4 I15/2
11
5 f 7p
(15/2,1/2) o
共15/2,1/2兲
7
7
938.65
27751.11
WLGC74
A Ref
Energy Levels of Singly-ionized Einsteinium 共Es II兲
Configuration
Term
o
)7s
5 f 11( 4 I15/2
(15/2 ,1/2)
o
)7s
5 f 11( 4 F9/2
J
o
Level (cm⫺1 )
Ref
8
7
0.00
938.65
BW92b
BW92b
(9/2 ,1/2) o
5
4
7588.09
8123.26
BW92b
BW92b
o
)7s
5 f 11( 2 H11/2
(11/2 ,1/2) o
6
5
9085.30
9580.22
BW92b
BW92b
o
)7s
5 f 11( 4 I13/2
(13/2 ,1/2) o
7
6
11335.68
11764.95
BW92b
BW92b
5 f 117p
共15/2 ,1/2兲
7
8
27751.11
28178.81
BW92b
BW92b
o
)7p
5 f 11( 2 H11/2
共11/2 ,1/2兲
6
5
36450.29
36803.23
BW92b
BW92b
7
36807.72
BW92b
9
36907.83
BW92b
5 f 106d7s
o
)7p
5 f 11( 4 I15/2
Es III
o
( 4 I15/2
)
(15/2 ,3/2)
Limit
关97000兴
CNWM70
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1702
J. E. SANSONETTI AND W. C. MARTIN
Erbium „Er…
Atomic number⫽68
Atomic weight⫽167.26
Isotope
162
Er
Er
166
Er
167
Er
168
Er
170
Er
164
Mass
Abundance
Spin
161.928775
163.929198
165.930290
166.932046
167.932368
169.935461
0.14%
1.61%
33.6%
22.95%
26.8%
14.9%
0
0
0
7/2
0
0
Mag moment
⫺0.5665
Er I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 4 f 126s 2 3H6
Ionization energy: 49 262 cm⫺1 共6.1077 eV兲
Er II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 4 f 12( 3 H6 )6s (6,1/2) 13/2
Ionization energy: 96 200 cm⫺1 共11.93 eV兲
Strong Lines of Erbium 共Er兲
Intensity
40
60
50
90
140
140
110
50
60
70
60
70
80
80
60
200
50
250
70
70
200
50
70
70
120
130
130
700
90
150
200
40
70
30
40
90
P
P
P
d
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2670.260
2755.630
2770.016
2904.469
2910.359
2964.520
3002.407
3072.53
3073.344
3082.083
3084.020
3122.722
3181.919
3220.729
3223.306
3230.582
3259.050
3264.782
3279.326
3280.218
3312.424
3316.390
3323.195
3332.702
3346.036
3364.078
3368.022
3372.71
3374.173
3385.083
3391.998
3428.388
3441.128
3442.684
3469.509
3471.709
Spectrum
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
Ref
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
ATOMIC SPECTROSCOPIC DATA
1703
Strong Lines of Erbium 共Er兲—Continued
Intensity
60
90
600
40
40
60
30
70
110
40
90
20
70
20
90
25
40
30
60
90
50
30
300
50
50
50
20
90
40
110
80
50
50
25
50
25
700
25
50
50
50
25
120
50
80
60
40
150
50
50
40
50
110
300
40
50
50
500
140
P
P
P
P
P
Wavelength 共Å兲
3479.413
3485.854
3499.104
3502.780
3514.889
3524.912
3539.590
3549.844
3558.016
3558.713
3559.896
3565.172
3570.753
3578.244
3580.519
3586.601
3590.764
3595.835
3599.501
3599.826
3604.898
3607.424
3616.565
3617.850
3618.916
3628.037
3629.368
3633.536
3634.674
3638.676
3645.936
3650.408
3652.874
3664.445
3682.701
3684.012
3692.650
3697.679
3700.719
3707.637
3712.391
3719.351
3729.524
3738.162
3742.640
3747.430
3756.050
3786.836
3787.858
3791.829
3792.794
3797.058
3810.330
3830.482
3849.914
3855.898
3858.392
3862.851
3880.611
Spectrum
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
II
II
II
I
II
II
I
II
I
I
II
I
I
I
II
I
I
I
II
II
II
I
II
II
II
I
I
II
I
I
II
II
II
I
II
I
II
I
II
II
II
I
II
II
II
I
I
II
II
II
I
II
I
II
I
I
II
I
II
Ref
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1704
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Erbium 共Er兲—Continued
Intensity
110
300
500
70
90
1000
70
250
200
250
40
25
200
250
130
60
80
60
1000
80
200
30
70
90
40
60
30
50
250
80
25
25
40
50
500
70
100
50
25
20
60
50
25
25
70
20
50
20
20
20
20
15
15
20
30
25
9
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3882.886
3892.684
3896.234
3902.756
3905.404
3906.311
3932.254
3937.014
3938.626
3944.420
3948.062
3956.416
3973.036
3973.575
3974.719
3977.019
3982.331
3987.655
4007.965
4012.533
4020.512
4021.548
4046.955
4055.465
4059.515
4059.779
4077.880
4081.243
4087.632
4098.099
4116.361
4118.546
4131.504
4142.914
4151.108
4190.697
4218.425
4286.556
4298.905
4386.397
4409.340
4419.608
4424.571
4426.769
4606.606
4673.161
4675.619
4900.080
4934.115
5007.234
5042.049
5164.767
5188.898
5762.801
5826.786
6221.019
7469.51
Spectrum
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
II
I
II
II
I
II
II
I
II
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
I
II
I
II
I
I
I
I
I
II
I
I
I
I
I
I
I
II
I
I
I
I
II
II
II
I
II
II
II
I
I
I
I
Ref
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
M64b
MCS75
ATOMIC SPECTROSCOPIC DATA
1705
Persistent Lines of Neutral Erbium 共Er I兲
Wavelength 共Å兲
Inten
500
3862.851
300
3892.684
250
3937.014
250
A ki (108 s⫺1 )
12
3973.036
250
3973.575
3
3
H
0.000
25880.274
M64b
M00
6
5
0.000
25681.933
M64b
M00
3
H
6
6
0.000
25392.779
M64b
M00
F
4
5
5035.193
30380.282
M64b
H
6
5
0.000
25162.553
M64b
M00
H
6
7
0.000
25159.143
M64b
M00
H
6
7
0.000
24943.272
M64b
M00
H
5
6
6958.329
31823.748
M64b
H
6
6
0.000
24457.139
M64b
M00
H
6
5
0.000
24083.166
M64b
M00
o
4 f 126s 2
4 f 11( 4 Io)5d6s 2
3
o
3
o
4 f 126s 2
0.366
6
6
A Ref
o
4 f 126s 2
4 f 11( 4 Io)5d 2 ( 3 F)( 4 Fo)6s
0.479
H
Wl Ref
o
4 f 126s 2
4 f 11( 4 Fo)5d6s 2
0.292
3944.420
200
2
4 f 126s 2
4 f 11( 4 Fo)5d6s 2
0.728
Level (cm⫺1 )
Term
4 f 6s
4 f 12( 3 H)6s6p
1.16
J
Configuration
3
o
1000
4007.965
200
4 f 126s 2
4 f 12( 3 H)6s6p
1.73
4 f 126s 2
4 f 12( 3 H)6s6p
4020.512
250
4087.632
500
4151.108
3
o
3
o
4 f 126s 2
4 f 11( 4 Io)5d6s 2
0.303
3
o
4 f 126s 2
4 f 12( 3 H)6s6p
0.960
3
o
70
4606.606
0.0754
4 f 126s 2
o
)5d 5/26s 2
4 f 11( 4 I11/2
3
H
(11/2,5/2) o
6
6
0.000
21701.885
M64b
M00
30
5826.786
0.0104
4 f 126s 2
4 f 12( 3 H6 )6s6p( 3 Po1 )
3
H
(6,1) o
6
7
0.000
17157.307
M64b
M00
25
6221.019
0.0084
4 f 126s 2
o
)5d 3/26s 2
4 f 11( 4 I13/2
3
6
6
0.000
16070.095
M64b
M00
H
(13/2,3/2) o
Energy Levels of Neutral Erbium 共Er I兲
Configuration
12
Term
J
Level (cm⫺1 )
Ref
2
3
H
6
5
4
0.000
6958.329
10750.982
MZH78
MZH78
MZH78
4 f 126s 2
3
F
4
3
2
5035.193
12377.534
13097.906
MZH78
MZH78
MZH78
o
)5d 3/26s 2
4 f 11( 4 I15/2
(15/2,3/2) o
6
7
9
8
7176.503
7696.956
8620.565
9350.106
MZH78
MZH78
MZH78
MZH78
o
)5d 5/26s 2
4 f 11( 4 I15/2
(15/2,5/2) o
10
9
5
8
6
7
9655.848
10557.916
11401.197
11557.670
11799.778
11887.503
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1706
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Erbium 共Er I兲—Continued
Term
J
Level (cm⫺1 )
Ref
o
)5d 3/26s 2
4 f 11( 4 I13
(13/2,3/2) o
8
5
7
6
15083.114
15185.352
15846.549
16070.095
MZH78
MZH78
MZH78
MZH78
4 f 12( 3 H6 )6s6p( 3 Po0 )
(6,0) o
6
16321.110
MZH78
o
4 f 11( 4 I15/2
)6s 2 6p 1/2
共15/2,1/2兲
7
8
16464.934
16727.479
MZH78
MZH78
4 f 12( 3 H6 )6s6p( 3 Po1 )
(6,1) o
6
7
5
17073.800
17157.307
17347.860
MZH78
MZH78
MZH78
o
)5d 5/26s 2
4 f 11( 4 I11
(11/2,5/2) o
3
8
4
7
5
6
19269.640
20566.805
20619.731
21168.430
21392.817
21701.885
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 12( 3 H)6s6p
o
5
24083.166
MZH78
4 f 11( 4 Io)5d6s 2
o
6
24457.139
MZH78
o
7
24943.272
MZH78
o
7
25159.143
MZH78
4 f 11( 4 Io)5d6s 2
o
5
25162.553
MZH78
4 f 11( 4 Fo)5d6s 2
o
6
25392.779
MZH78
o
5
25681.933
MZH78
4 f 12( 3 H)6s6p
o
6
25880.274
MZH78
4 f 11( 4 Io)5d 2 ( 3 F)( 4 Fo)6s
o
5
30380.282
MZH78
o
6
31823.748
MZH78
49262
WSPC78
Configuration
12 3
4 f ( H)6s6p
11 4 o
4 f ( F )5d6s
2
12 3
4 f ( H)6s6p
Er II ( 3 H6 )6s 1/2 (6,1/2) 13/2
Limit
Persistent Lines of Singly-ionized Erbium 共Er II兲
Inten
200
Wavelength 共Å兲
3230.582
A ki (108 s⫺1 )
1.5
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
4 f ( H6 )6s 1/2
共6,1/2兲
11/2
11/2
440.434
31385.667
M64b
K91
o
12 3
250
3264.782
0.58
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 3/2?
共6,1/2兲
(6,3/2) o?
13/2
13/2
0.000
30621.102
M64b
K91
200
3312.424
0.37
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 3/2?
共6,1/2兲
(6,3/2) o?
11/2
13/2
440.434
30621.102
M64b
K91
700
3372.71
1.3
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 3/2?
共6,1/2兲
(6,3/2) o?
13/2
15/2
0.000
29640.863
M64b
K91
200
3391.998
0.235
4 f 12( 3 H6 )6s 1/2
共6,1/2兲
13/2
15/2
0.000
29472.789
M64b
K91
o
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 3/2?
共6,1/2兲
(6,3/2) o?
11/2
9/2
440.434
29011.015
M64b
K91
600
3499.104
0.75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1707
Persistent Lines of Singly-ionized Erbium 共Er II兲—Continued
Inten
Wavelength 共Å兲
300
700
3616.565
3692.650
A ki (108 s⫺1 )
Configuration
Term
0.48
Level (cm⫺1 )
Wl Ref
A Ref
4 f ( H6 )6s 1/2
共6,1/2兲
13/2
11/2
0.000
27642.658
M64b
K91
4 f 12( 3 H6 )6s 1/2
共6,1/2兲
11/2
13/2
440.434
27513.555
M64b
K91
o
12 3
0.20
J
o
300
3830.482
0.14
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 1/2?
共6,1/2兲
(6,1/2) o?
13/2
13/2
0.000
26098.972
M64b
K91
500
3896.234
0.18
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 1/2?
共6,1/2兲
(6,1/2) o?
11/2
13/2
440.434
26098.972
M64b
K91
1000
3906.311
0.323
4 f 12( 3 H6 )6s 1/2
4 f 12( 3 H6 )6p 1/2?
共6,1/2兲
(6,1/2) o?
13/2
11/2
0.000
25592.343
M64b
K91
200
3938.626
4 f 12( 3 H6 )6s 1/2
共6,1/2兲
13/2
11/2
0.000
25382.379
M64b
o
Energy Levels of Singly-ionized Erbium 共Er II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4 f ( H6 )6s 1/2
共6,1/2兲
13/2
11/2
0.000
440.434
MZH78
MZH78
4 f 12( 3 F4 )6s 1/2
共4,1/2兲
9/2
7/2
5132.608
5403.688
MZH78
MZH78
4 f 116s 2
4 o
15/2
13/2
11/2
9/2
6824.774
13338.777
16948.197
—
MZH78
MZH78
MZH78
4 f 12( 3 H5 )6s 1/2
共5,1/2兲
11/2
9/2
7149.630
7195.355
MZH78
MZH78
4 f 11( 4 Io)5d6s
o
13/2
10667.186
MZH78
4 f 12( 3 H4 )6s 1/2
共4,1/2兲
7/2
9/2
10893.936
11042.640
MZH78
MZH78
11/2
25382.379
MZH78
(6,1/2) ?
11/2
13/2
25592.343
26098.972
MZH78
MZH78
o
13/2
27513.555
MZH78
o
11/2
27642.658
MZH78
(6,1/2) o?
9/2
11/2
15/2
13/2
29011.015
29492.329
29640.863
30621.102
MZH78
MZH78
MZH78
MZH78
o
15/2
29472.789
MZH78
o
11/2
31385.667
MZH78
Limit
96200
SR65
12 3
I
o
12 3
4 f ( H6 )6p 1/2?
4 f 12( 3 H6 )6p 3/2?
Er III ( 3 H6 )
o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1708
J. E. SANSONETTI AND W. C. MARTIN
Europium „Eu…
Atomic number⫽63
Atomic weight⫽151.965
Isotope
151
Eu
Eu
153
Mass
Abundance
Spin
Mag moment
150.919847
152.921225
47.8%
52.2%
5/2
5/2
⫹3.464
⫹1.530
o
Eu I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 7 6s 2 8S7/2
⫺1
Ionization energy: 45 734.74 cm 共5.670 38 eV兲
Eu II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 7 6s 9So4
Ionization energy: 90 700 cm⫺1 共11.25 eV兲
Strong Lines of Europium 共Eu兲
Intensity
Wavelength 共Å兲
4
15
6
11
4
4
9
12
13
4
15
12
70
6
8
30
4
60
9
30
7
4
5
20
13
30
50
15
14
3
4
5
5
11
4
30
90
40
90
40
Air
2577.14
2638.77
2641.27
2668.34
2678.29
2685.66
2692.03
2701.14
2701.90
2705.28
2709.981
2716.98
2727.78
2729.44
2781.89
2802.84
2811.75
2813.94
2816.18
2820.78
2828.72
2859.67
2862.57
2892.502
2893.013
2893.838
2906.68
2908.993
2925.04
2952.68
2960.21
2991.33
3054.94
3058.975
3077.36
3106.162
3111.427
3210.566
3212.804
3213.745
P
P
c,w
P
c,w
c,w
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
II
I
II
II
II
II
II
I
II
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ST76
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ST76
ST76
ST76
MCS75
ST76
MCS75
MCS75
MCS75
MCS75
MCS75
ST76
MCS75
ST76
ST76
ST76
ST76
ST76
ATOMIC SPECTROSCOPIC DATA
1709
Strong Lines of Europium 共Eu兲—Continued
Intensity
4
90 P
10
5
8 c,w
110 P
300 P,c,w
6
4
11
600 P,c,w
15
14
500 P,c,w
20
500 P,c,w
500 P,c,w
11
600 P,c,w
10
1000 P,c,w
14
4
250 P,c,w
50 P
1000 P
900 P
800 P
10
14
15
15
15
10
15
15
20
25
20
20
10
11
70 P
25
11
20
40
10
14
11
11
50 P
11
10
11
40
30
25
11
Wavelength 共Å兲
3277.78
3334.313
3350.397
3396.58
3521.09
3688.42
3724.94
3741.31
3761.12
3811.33
3819.67
3865.57
3884.75
3907.10
3917.29
3930.48
3971.96
4039.19
4129.70
4182.22
4205.05
4298.73
4355.09
4435.56
4522.57
4594.03
4627.22
4661.88
4867.62
4907.18
4911.40
5013.17
5022.91
5029.54
5114.37
5129.10
5133.52
5160.07
5166.70
5199.85
5200.96
5206.44
5215.10
5223.49
5239.24
5266.40
5271.96
5272.48
5282.82
5291.26
5294.64
5357.61
5361.61
5376.94
5392.94
5402.77
5451.51
5452.94
5488.65
Spectrum
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
II
I
I
II
II
II
II
II
II
I
II
I
I
II
I
II
II
I
II
I
II
I
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
ST76
ST76
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1710
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Europium 共Eu兲—Continued
Intensity
11
20
14
20
11
20
30
15
50 P,c,w
6
40 c,w
15
20
10
40
15
7
13
20
20
11
6
10
25 c,w
13
20
15
4
11 c,w
11 c,w
15
13
14
11
25
13
30
11
6
10
10
9
12
5
15
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
5510.52
5547.44
5570.33
5577.14
5580.03
5645.80
5765.20
5783.69
5830.98
5966.07
5967.10
5972.75
5992.83
6012.56
6018.15
6029.00
6049.51
6057.36
6083.84
6099.35
6118.78
6173.05
6178.76
6188.13
6195.07
6262.25
6299.77
6303.41
6350.04
6400.93
6410.04
6411.32
6437.64
6457.96
6645.11
6802.72
6864.54
7040.20
7077.10
7194.81
7217.55
7301.17
7370.22
7426.57
7583.91
Spectrum
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
Eu
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
I
I
I
I
II
I
I
I
I
I
II
I
I
I
I
II
I
II
I
I
I
II
II
II
II
II
II
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1711
Persistent Lines of Neutral Europium 共Eu I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
7
2
Term
J
Level (cm⫺1 )
8 o
Wl Ref
A Ref
90
3111.427
0.34
4 f 6s
4 f 6 ( 7 F)5d6s 2
a S
8
P
7/2
9/2
0.00
32130.25
ST76
M00
90
3212.804
0.33
4 f 7 6s 2
4 f 6 ( 7 F)5d6s 2
a 8So
8
P
7/2
7/2
0.00
31116.38
ST76
M00
90
3334.313
0.39
4 f 7 6s 2
4 f 6 ( 7 F)5d6s 2
a 8So
8
P
7/2
5/2
0.00
29982.50
ST76
M00
1000
4594.03
1.60
4 f 7 6s 2
4 f 7 ( 8 So)6s6p( 1 Po)
a 8So
y 8P
7/2
9/2
0.00
21761.26
MCS75
M00
900
4627.22
1.53
4 f 7 6s 2
4 f 7 ( 8 So)6s6p( 1 Po)
a 8So
y 8P
7/2
7/2
0.00
21605.17
MCS75
M00
800
4661.88
1.45
4 f 7 6s 2
4 f 7 ( 8 So)6s6p( 1 Po)
a 8So
y 8P
7/2
5/2
0.00
21444.58
MCS75
M00
70
5215.10
0.40
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
a 10Do
y 10P
13/2
11/2
13778.68
32948.41
MCS75
HWL02
50
5357.61
0.23
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
a
z
10
Do
D
11/2
13/2
13457.21
32117.10
MCS75
HWL02
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
a
z
10
Do
F
13/2
15/2
13778.68
30923.71
MCS75
HWL02
50
5830.98
0.51
10
10
Energy Levels of Neutral Europium 共Eu I兲
Configuration
Term
J
4 f 7 6s 2
a 8So
7/2
7 8 o
9
o
10
o
D
Level (cm⫺1 )
Ref
0.00
MZH78
5/2
7/2
9/2
11/2
13/2
12923.72
13048.90
13222.04
13457.21
13778.68
MZH78
MZH78
MZH78
MZH78
MZH78
4 f ( S )5d( D )6s
a
4 f 7 ( 8 So)6s6p( 3 Po)
z
P
7/2
9/2
11/2
14067.86
14563.57
15581.58
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 9 Do)6s
a 8Do
3/2
5/2
7/2
9/2
11/2
15137.72
15248.76
15421.25
15680.28
16079.76
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)6s6p( 3 Po)
z 8P
5/2
7/2
9/2
15890.53
15952.31
16611.79
MZH78
MZH78
MZH78
4 f 7 ( 8 So)6s6p( 3 Po)
z 6P
7/2
5/2
3/2
17340.65
17707.42
17945.49
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 7 Do)6s
a 6Do
9/2
7/2
5/2
3/2
1/2
19273.24
19364.50
19462.05
19543.69
19599.16
MZH78
MZH78
MZH78
MZH78
MZH78
10
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1712
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Europium 共Eu I兲—Continued
Configuration
7 8 o
7
o
Term
J
Level (cm⫺1 )
Ref
8
o
4 f ( S )5d( D )6s
b D
11/2
9/2
7/2
5/2
3/2
19447.19
19631.26
19712.15
19763.78
19794.21
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)6s6p( 1 Po)
y 8P
5/2
7/2
9/2
21444.58
21605.17
21761.26
MZH78
MZH78
MZH78
4 f 6 ( 7 F)5d6s 2
8
3/2
5/2
7/2
9/2
11/2
—
27852.90
28827.83
29838.59
30819.44
MZH78
MZH78
MZH78
MZH78
3/2
5/2
7/2
9/2
11/2
13/2
15/2
28519.97
28667.39
28918.17
29186.32
29612.69
30211.09
30923.71
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
5/2
7/2
9/2
29982.50
31116.38
32130.25
MZH78
MZH78
MZH78
5/2
7/2
9/2
11/2
13/2
30945.07
31138.11
31382.61
31725.93
32117.10
MZH78
MZH78
MZH78
MZH78
MZH78
7/2
9/2
11/2
32398.25
32596.31
32948.41
MZH78
MZH78
MZH78
Limit
45734.74
NRCA00
D
4 f 7 ( 8 So)5d( 9 Do)6p
z
10
4 f 6 ( 7 F)5d6s 2
8
4 f 7 ( 8 So)5d( 9 Do)6p
z
10
4 f 7 ( 8 So)5d( 9 Do)6p
y
10
F
P
D
P
Eu II ( 9 So4 )
Persistent Lines of Singly-ionized Europium 共Eu II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
J
Level (cm⫺1 )
Wl Ref
A Ref
70
2727.78
0.65
4 f 7 ( 8 So)6s
4 f 6 ( 7 F)5d( 8 P)6s
a 9So
y 9P
4
5
0.00
36648.95
MCS75
ZLLZ00
60
2813.94
0.55
4 f 7 ( 8 So)6s
4 f 6 ( 7 F)5d( 8 P)6s
a 9So
y 9P
4
4
0.00
35527.02
MCS75
ZLLZ00
50
2906.68
0.41
4 f 7 ( 8 So)6s
4 f 6 ( 7 F)5d( 8 P)6s
a 9So
y 9P
4
3
0.00
34393.57
MCS75
ZLLZ00
110
3688.42
0.13
4 f 7 ( 8 So)6s
o
)6p 3/2
4 f 7 ( 8 S7/2
a 9So
共7/2,3/2兲
4
3
0.00
27104.07
MCS75
ZLLZ00
300
3724.94
0.45
4 f 7 ( 8 So)6s
o
)6p 3/2
4 f 7 ( 8 S7/2
a 9So
共7/2,3/2兲
4
4
0.00
26838.50
MCS75
K91
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Term
ATOMIC SPECTROSCOPIC DATA
1713
Persistent Lines of Singly-ionized Europium 共Eu II兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
7 8 o
Term
J
Level (cm⫺1 )
Wl Ref
9 o
A Ref
600
3819.67
1.27
4 f ( S )6s
o
)6p 3/2
4 f 7 ( 8 S7/2
a S
共7/2,3/2兲
4
5
0.00
26172.83
MCS75
K91
500
3907.10
1.37
4 f 7 ( 8 So)6s
o
)6p 3/2
4 f 7 ( 8 S7/2
a 7So
共7/2,3/2兲
3
2
1669.21
27256.35
MCS75
K91
500
3930.48
1.07
4 f 7 ( 8 So)6s
o
)6p 3/2
4 f 7 ( 8 S7/2
a 7So
共7/2,3/2兲
3
3
1669.21
27104.07
MCS75
ZLLZ00
500
3971.96
0.89
4 f 7 ( 8 So)6s
o
)6p 3/2
4 f 7 ( 8 S7/2
a 7So
共7/2,3/2兲
3
4
1669.21
26838.50
MCS75
K91
600
4129.70
0.68
4 f 7 ( 8 So)6s
o
)6p 1/2
4 f 7 ( 8 S7/2
a 9So
共7/2,1/2兲
4
4
0.00
24207.86
MCS75
K91
1000
4205.05
0.71
4 f 7 ( 8 So)6s
o
)6p 1/2
4 f 7 ( 8 S7/2
a 9So
共7/2,1/2兲
4
3
0.00
23774.28
MCS75
K91
250
4435.56
0.31
4 f 7 ( 8 So)6s
o
)6p 1/2
4 f 7 ( 8 S7/2
a 7So
共7/2,1/2兲
3
4
1669.21
24207.86
MCS75
K91
50
4522.57
0.099
4 f 7 ( 8 So)6s
o
)6p 1/2
4 f 7 ( 8 S7/2
a 7So
共7/2,1/2兲
3
3
1669.21
23774.28
MCS75
K91
Energy Levels of Singly-ionized Europium 共Eu II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
7 8 o
4 f ( S )6s
9 o
a S
4
0.00
MZH78
4 f 7 ( 8 So)6s
a 7So
3
1669.21
MZH78
4 f 7 ( 8 So)5d
a 9Do
2
3
4
5
6
9923.00
10081.65
10312.82
10643.48
11128.22
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d
a 7Do
5
4
3
2
1
16860.72
17004.06
17140.87
17247.67
17324.66
MZH78
MZH78
MZH78
MZH78
MZH78
o
4 f 7 ( 8 S7/2
)6p 1/2
共7/2,1/2兲
3
4
23774.28
24207.86
MZH78
MZH78
o
)6p 3/2
4 f 7 ( 8 S7/2
共7/2,3/2兲
5
4
3
2
26172.83
26838.50
27104.07
27256.35
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)5d( 8 D)6s
z 9D
2
3
4
5
6
30189.31
31500.82
32486.10
33420.20
34764.97
MZH78
MZH78
MZH78
MZH78
MZH78
101
4
33779.95
MZH78
102
3
33919.70
MZH78
103
2
33944.49
MZH78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1714
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Europium 共Eu II兲—Continued
Configuration
6 7
8
4 f ( F)5d( P)6s
Term
J
Level (cm⫺1 )
9
3
4
5
34393.57
35527.02
36648.95
MZH78
MZH78
MZH78
90700
SR65
y P
o
)
Eu III ( 8 S7/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
Ref
ATOMIC SPECTROSCOPIC DATA
1715
Fluorine „F…
Atomic number⫽9
Atomic weight⫽18.998 4032
Isotope
19
F
Mass
Abundance
Spin
Mag moment
18.9984032
100%
1/2
⫹2.6887
o
F I Ground state: 1s 2 2s 2 2p 5 2P3/2
⫺1
Ionization energy: 140 524.5 cm 共17.4228 eV兲
F II Ground state: 1s 2 2s 2 2p 4 3P2
Ionization energy: 282 058.6 cm⫺1 共34.9708 eV兲
Strong Lines of Fluorine 共F兲
Intensity
900
900
800
1000
700
800
900
500
1000
800
500
400
100
100
200
200
200
200
200
200
150
200
200
200
200
200
250
250
250
200
200
250
200
250
200
150
200
200
150
200
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
484.602
605.669
606.288
606.804
606.923
607.472
608.062
951.870
954.826
955.546
958.525
973.895
976.217
977.743
Air
3501.388
3501.451
3501.569
3502.840
3502.964
3503.106
3505.369
3505.515
3505.628
3601.393
3602.838
3704.526
3847.086
3849.985
3851.668
3898.825
3901.933
4024.726
4025.010
4025.491
4103.074
4103.216
4103.508
4103.710
4103.870
4246.227
Spectrum
Ref
F
F
F
F
F
F
F
F
F
F
F
F
F
F
II
II
II
II
II
II
II
I
I
I
I
I
I
I
P69
P69
P69
P69
P69
P69
P69
L49
L49
L49
L49
L49
L49
L49
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
P69
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1716
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Fluorine 共F兲—Continued
Wavelength 共Å兲
Intensity
200
200
150
150
200
150
150
200
130
100
80
20
70
90
500
80
150
60
40
500
300
130
150
130
150
50
100
40
20
25
50
50
70
200
150
80
6
6
25
30
20
Spectrum
4246.385
4246.590
4246.774
4246.844
4299.170
4446.527
4446.722
4447.188
6239.651
6348.508
6413.651
6690.481
6773.984
6834.264
6856.030
6870.215
6902.475
6909.816
6966.349
7037.469
7127.890
7179.90
7202.360
7211.79
7311.019
7331.957
7398.688
7425.645
7482.723
7489.155
7552.235
7573.384
7607.170
7754.696
7800.212
8016.01
8129.26
8179.339
8214.726
8230.773
8298.581
P
P
P
P
P
P
P
h
P
P
P
P
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
Ref
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
P69
P69
P69
P69
P69
P69
P69
P69
L49
L49
L49
L49
L49
L49
L49
L49
L49
L49
L49
L49
L49
P69
L49
P69
L49
L49
L49
L49
L49
L49
L49
L49
L49
L49
L49
P69
L49
L49
L49
L49
L49
Persistent Lines of Neutral Fluorine 共F I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
500
951.870
2.55
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
1000
800
500
954.826
955.546
958.525
6.32
5.05
1.25
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
J
Level (cm⫺1 )
P
P
3/2
1/2
2 o
P
P
2 o
Term
Wl Ref
A Ref
0.000
105056.283
L49
M03
3/2
3/2
0.000
104731.048
L49
M03
P
P
1/2
1/2
404.141
105056.283
L49
M03
2 o
1/2
3/2
404.141
104731.048
L49
M03
2 o
2
2
2
2
P
P
ATOMIC SPECTROSCOPIC DATA
1717
Persistent Lines of Neutral Fluorine 共F I兲—Continued
Inten
130
100
500
150
500
300
150
150
100
200
150
Wavelength 共Å兲
6239.651
6348.508
6856.030
6902.475
7037.469
7127.890
7202.360
7311.019
7398.688
7754.696
7800.212
A ki (108 s⫺1 )
0.25
0.18
0.494
0.32
0.30
0.38
0.072
0.39
0.285
0.382
0.21
Configuration
2
4 3
J
Level (cm⫺1 )
P
S
5/2
3/2
102405.714
118427.814
L49
FW96
P
S
3/2
3/2
102680.439
118427.814
L49
FW96
P
Do
5/2
7/2
102405.714
116987.391
L49
FW96
P
Do
3/2
5/2
102680.439
117164.002
L49
FW96
P
P
3/2
3/2
104731.048
118936.791
L49
FW96
P
P
1/2
1/2
105056.283
119081.814
L49
FW96
P
P
1/2
3/2
105056.283
118936.791
L49
WSG66
P
S
3/2
1/2
104731.048
118405.256
L49
FW96
P
P
5/2
5/2
102405.714
115917.904
L49
FW96
P
Do
3/2
5/2
104731.048
117622.917
L49
FW96
P
Do
1/2
3/2
105056.283
117872.917
L49
FW96
Term
2s 2 p ( P)3s
2s 2 2 p 4 ( 3 P)3p
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
4 o
4 o
4
4
2 o
2 o
2 o
2 o
4 o
2
2
Wl Ref
A Ref
Energy Levels of Neutral Fluorine 共F I兲
J
Level (cm⫺1 )
Ref
Configuration
Term
2s 2 2p 5
2 o
P
3/2
1/2
0.000
404.141
2s 2 2p 4 ( 3 P)3s
4
P
5/2
3/2
1/2
102405.714
102680.439
102840.378
A95
A95
A95
2s 2 2p 4 ( 3 P)3s
2
P
3/2
1/2
104731.048
105056.283
A95
A95
2s 2 2p 4 ( 3 P)3p
4 o
P
5/2
3/2
1/2
115917.904
116040.880
116143.578
A95
A95
A95
2s 2 2p 4 ( 3 P)3p
4
Do
7/2
5/2
3/2
1/2
116987.391
117164.002
117308.552
117391.945
A95
A95
A95
A95
2s 2 2p 4 ( 3 P)3p
2
Do
5/2
3/2
117622.917
117872.917
A95
A95
LB82
LB82
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1718
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Fluorine 共F I兲—Continued
J
Level (cm⫺1 )
Ref
2s 2p ( P)3p
2 o
S
1/2
118405.256
A95
2s 2 2p 4 ( 3 P)3p
4 o
S
3/2
118427.814
A95
2s 2 2p 4 ( 3 P)3p
2 o
3/2
1/2
118936.791
119081.814
A95
A95
140524.5
L49
Configuration
2
Term
4 3
P
F II ( 3 P2 )
Limit
Persistent Lines of Singly-ionized Fluorine 共F II兲
Inten
Wavelength 共Å兲
900
484.602
900
800
1000
700
800
900
250
250
250
250
200
250
605.669
606.288
606.804
606.923
607.472
608.062
3847.086
3849.985
3851.668
4024.726
4025.010
4025.491
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
1
D
P
2
1
20873.4
227228.42
P69
P
P
2
1
0.00
165106.66
P69
WSG66
P
P
1
0
341.1400
165279.19
P69
WSG66
P
P
2
2
0.00
164797.88
P69
WSG66
P
P
1
1
341.1400
165106.66
P69
WSG66
P
P
0
1
489.6845
165106.66
P69
WSG66
P
P
1
2
341.1400
164797.88
P69
WSG66
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
5 o
S
P
2
3
176493.93
202480.26
P69
WSG66
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
5 o
S
P
2
2
176493.93
202460.69
P69
WSG66
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
5 o
S
P
2
1
176493.93
202449.35
P69
WSG66
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
3 o
S
P
1
2
182864.40
207703.79
P69
WSG66
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
3 o
S
P
1
0
182864.40
207702.04
P69
WSG66
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
3 o
1
1
182864.40
207699.07
P69
WSG66
Configuration
2s 2 2 p 4
2s 2 2 p 3 ( 2 Po)3s
43
100
78
26
33
25
1.3
1.3
1.3
1.2
1.2
1.2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2s 2 2 p 4
2s2 p 5
2s 2 2 p 4
2s2 p 5
2s 2 2 p 4
2s2 p 5
2s 2 2 p 4
2s2 p 5
2s 2 2 p 4
2s2 p 5
2s 2 2 p 4
2s2 p 5
1 o
3
3 o
3
3 o
3
3 o
3
3 o
3
3 o
3
3 o
5
5
5
3
3
3
S
P
A Ref
ATOMIC SPECTROSCOPIC DATA
1719
Energy Levels of Singly-ionized Fluorine 共F II兲
Term
J
Level (cm⫺1 )
4
3
2
1
0
0.00
341.1400
489.6845
2s 2 2p 4
1
2
20873.4
P69
2s 2 2p 4
1
S
0
44918.1
P69
2s2p 5
3 o
P
2
1
0
164797.88
165106.66
165279.19
P69
P69
P69
2s 2 2p 3 ( 4 So)3s
5 o
S
2
176493.93
P69
2s 2 2p 3 ( 4 So)3s
3 o
S
1
182864.40
P69
2s 2 2p 3 ( 4 So)3p
5
P
1
2
3
202449.35
202460.69
202480.26
P69
P69
P69
2s 2 2p 3 ( 4 So)3p
3
P
1
0
2
207699.07
207702.04
207703.79
P69
P69
P69
2s 2 2p 3 ( 2 Do)3s
3
Do
3
2
1
211866.13
211887.19
211900.26
P69
P69
P69
2s 2 2p 3 ( 2 Do)3s
1
Do
2
215069.59
P69
2s 2 2p 3 ( 2 Po)3s
1 o
P
1
227228.42
P69
3 o
2
1
0
229550.11
229551.79
229554.45
P69
P69
P69
Limit
282058.6
P69
Configuration
2
2s 2p
2
3 2 o
2s 2p ( P )3s
o
)
F III ( 4 S3/2
P
D
P
Ref
P69
P69,BZE98
P69,BZE98
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1720
J. E. SANSONETTI AND W. C. MARTIN
Francium „Fr…
Atomic number⫽87
Atomic weight⫽223
Isotope
212
Fr
Fr
223
Mass
Abundance
Spin
211.996130
223.019733
0
some
5
3/2
Note: Although not occuring naturally, the available spectroscopic data is for
Mag moment
212
Fr.
Fr I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 7s 2S1/2
Ionization energy: 32 848.872 cm⫺1 共4.072 741 eV兲
Fr II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 1S0
Ionization energy: not available
Strong Lines of Francium 共Fr兲
Wavelength 共Å兲
Intensity
Spectrum
Air
4225.655
4325.361
7179.866
8169.418
Fr
Fr
Fr
Fr
Ref
I
I
I
I
ABDJ90
ABDJ90
ABDJ90
ABDJ90
Persistent Lines of Neutral Francium 共Fr I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
4225.655
4325.361
7179.866
8169.418
J
Level (cm⫺1 )
Wl Ref
S
P
1/2
3/2
0.000
23658.306
ABDJ90
S
P
1/2
1/2
0.000
23112.960
ABDJ90
S
P
1/2
3/2
0.000
13923.998
ABDJ90
S
P
1/2
1/2
0.000
12237.409
ABDJ90
Configuration
Term
7s
8p
2
7s
8p
2
7s
7p
2
7s
7p
2
2
2 o
2 o
2 o
A Ref
Energy Levels of Neutral Francium 共Fr I兲
Ref
Term
7s
2
S
1/2
0.000
ABDJ90
7p
2 o
P
1/2
3/2
12237.409
13923.998
ABDJ90
ABDJ90
8p
2 o
1/2
3/2
23112.960
23658.306
ABDJ90
ABDJ90
Limit
32848.872
ABDJ90
P
Fr II ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
ATOMIC SPECTROSCOPIC DATA
1721
Gadolinium „Gd…
Atomic number⫽64
Atomic weight⫽157.25
Isotope
152
Gd
Gd
155
Gd
156
Gd
157
Gd
158
Gd
160
Gd
154
Mass
Abundance
Spin
151.919786
153.920861
154.922618
155.922118
156.923956
157.924099
159.927049
0.20%
2.18%
14.80%
20.47%
15.65%
24.84%
21.86%
0
0
3/2
0
3/2
0
0
Mag moment
⫺0.27
⫺0.36
Gd I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 7 5d6s 2 9Do2
Ionization energy: 49 601.45 cm⫺1 共6.149 80 eV兲
Gd II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 7 5d6s
Ionization energy: 97 500 cm⫺1 共12.09 eV兲
10
o
D5/2
Strong Lines of Gadolinium 共Gd兲
Intensity
Wavelength 共Å兲
110
90
140
250
200
250
200
110
70
250
400
70
110
110
110
80*
110
90
90
150
90
130
70
600
500
90
600
130
130*
130*
150
150
800
250*
250*
Air
2796.93
2809.72
2999.04
3010.13
3027.60
3032.84
3034.05
3068.64
3076.92
3081.99
3100.50
3102.55
3145.00
3156.53
3161.37
3223.74
3266.73
3291.48
3294.08
3331.38
3332.13
3336.18
3345.98
3350.47
3358.62
3360.71
3362.23
3392.53
3407.56
3407.61
3416.95
3418.73
3422.47
3423.90
3423.92
P
P
P
P
Spectrum
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1722
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Gadolinium 共Gd兲—Continued
Intensity
Wavelength 共Å兲
90
80
200
90
300
150
130
100
300
200
200
150
250
200
110
200
150
90
130
150
110
500
400
150
80
110
600
130
250
90
90
100
700
70
400
400
150
300
250
200
70
400
80
400
250
150
300
400
150
400
200*
200*
150
100
500
150
200
150
90
3424.59
3432.99
3439.21
3439.78
3439.99
3450.38
3451.23
3454.90
3463.98
3467.27
3468.99
3473.22
3481.28
3481.80
3491.95
3494.40
3505.51
3512.22
3512.50
3513.65
3524.20
3545.80
3549.36
3557.05
3571.93
3581.91
3584.96
3592.71
3604.87
3608.75
3610.76
3645.62
3646.19
3652.54
3654.62
3656.15
3662.26
3664.60
3671.20
3674.05
3679.21
3684.13
3686.33
3687.74
3697.73
3699.73
3712.70
3713.57
3716.36
3717.48
3719.45
3719.53
3730.84
3739.76
3743.47
3744.83
3757.94
3758.31
3759.00
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
I
I
I
II
II
II
II
II
I
II
I
II
II
II
I
II
I
I
II
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1723
Strong Lines of Gadolinium 共Gd兲—Continued
Intensity
70
200
100
1000
70
150
110
600
130
90
600
80
400
90
110
110
140
300
150
400
600
500
300
150
90
90
250
250*
250*
90
120
300
120
140
90*
90*
120
70
150
80
70
150
100
70
70
80
70
90
250
150
250
200
150
70
150
80
90
300
150
P
P
P
P
P
P
Wavelength 共Å兲
3760.71
3762.20
3767.04
3768.39
3769.45
3770.69
3782.34
3783.05
3787.56
3791.17
3796.37
3801.29
3813.97
3816.64
3836.91
3839.64
3842.20
3843.28
3844.58
3850.69
3850.97
3852.45
3866.99
3894.70
3902.40
3905.65
3916.51
3934.79
3934.82
3941.80
3942.63
3945.54
3953.37
3957.67
3959.44
3959.52
3966.28
3968.26
3969.00
3972.71
3973.98
3979.33
3987.84
3992.69
3994.16
3996.32
4008.33
4017.71
4023.14
4023.35
4028.15
4030.88
4033.49
4035.40
4037.33
4037.90
4043.71
4045.01
4049.43
Spectrum
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
II
I
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
I
II
I
II
I
I
I
I
II
II
II
I
II
I
I
II
I
I
I
II
II
I
I
I
I
I
I
I
I
II
II
I
I
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1724
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Gadolinium 共Gd兲—Continued
Intensity
250
90
500
150
500
140
70
200
110
90*
90*
70
150
600
110
150
140
250
300
140
250
130
150
500
300
500
90
150
70
150
110
70
70
1000
70
200
100
70
150
300
140
100
100
90
90
250
400
110
80
90*
90*
300*
300*
400
80
100
110
500
200
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4049.86
4053.29
4053.64
4054.72
4058.22
4059.88
4062.59
4063.39
4068.35
4070.29
4070.39
4073.20
4078.44
4078.70
4083.70
4085.56
4090.41
4092.71
4098.61
4100.26
4130.37
4132.28
4134.16
4175.54
4184.25
4190.78
4191.07
4191.63
4204.86
4212.00
4215.02
4217.20
4225.03
4225.85
4238.78
4251.73
4253.37
4253.61
4260.12
4262.09
4266.60
4267.00
4280.49
4285.82
4299.29
4306.34
4313.84
4314.40
4320.52
4321.11
4321.20
4325.57
4325.69
4327.12
4329.58
4342.18
4344.30
4346.46
4346.62
Spectrum
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
II
II
I
I
I
I
II
II
I
II
II
II
II
I
I
II
I
I
II
I
II
II
I
I
II
I
II
I
II
II
II
II
I
I
II
II
II
II
I
I
I
I
II
I
I
I
I
I
I
II
I
II
I
I
I
II
II
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1725
Strong Lines of Gadolinium 共Gd兲—Continued
Intensity
200
300
110
110
200
150
300
250
110
150
200
100
90
250
200
90
90
90
110
90
90
90
150
90
90
70
100
70
150
200
200
90
70
80
90
P
P
P
P
P
P
Wavelength 共Å兲
4373.83
4401.86
4403.14
4411.16
4414.16
4414.73
4422.41
4430.63
4467.08
4474.13
4476.12
4497.13
4506.21
4519.66
4537.81
4581.29
4583.07
4598.90
4614.50
4636.64
4653.54
4683.33
4694.33
4697.42
4743.65
4758.70
4767.24
4821.69
5015.04
5103.45
5155.84
5197.77
5251.18
5696.22
6114.07
Spectrum
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1726
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Gadolinium 共Gd I兲
Inten
400
400
Wavelength 共Å兲
3684.13
3713.57
A ki (108 s⫺1 )
0.91
0.92
Configuration
7 8 o
2
4 f ( S )5d6s
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
9
o
D
P
2
3
0.000
27135.695
MCS75
M00
Do
P
3
3
215.124
27135.695
MCS75
M00
9
9
9
400
3717.48
0.68
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
4
4
532.977
27425.245
MCS75
M00
600
3783.05
0.94
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
5
4
999.121
27425.245
MCS75
M00
500
4053.64
0.62
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 7 Do)6s6p( 3 Po)
9
Do
5
6
999.121
25661.340
MCS75
M00
500
4058.22
0.57
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 7 Do)6s6p( 3 Po)
9
Do
3
4
215.124
24849.514
MCS75
M00
600
4078.70
0.59
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
4
5
532.977
25043.649
MCS75
M00
500
4175.54
0.42
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 7 Do)6s6p( 3 Po)
9
Do
6
6
1719.087
25661.340
MCS75
M00
500
4190.78
0.30
4 f 7 ( 8 So)5d6s 2
4 f 8 ( 7 F)5d( 8 G)6s
9
Do
G
5
6
999.121
24854.297
MCS75
M00
9
1000
4225.85
0.89
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
6
7
1719.087
25376.313
MCS75
M00
400
4313.84
0.43
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
3
3
215.124
23389.782
MCS75
M00
400
4327.12
0.52
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6p
9
Do
2
1
0.000
23103.660
MCS75
M00
500
4346.46
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
5
5
999.121
23999.912
MCS75
300
4401.86
0.38
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
6
6
1719.087
24430.425
MCS75
M00
300
4422.41
0.28
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 7 Do)6s6p( 3 Po)
9
Do
D
3
4
215.124
22820.895
MCS75
M00
Do
D
2
3
0.000
22563.824
MCS75
M00
M00
250
4430.63
250
4519.66
200
5103.45
200
0.30
0.38
5155.84
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 7 Do)6s6p( 3 Po)
9
9
9
4 f 7 ( 8 So)5d6s 2
4 f 7 ( 8 So)5d( 9 Do)6s6p( 1 Po)
9
Do
3
2
215.124
22334.508
MCS75
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6s
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6p
11 o
F
G
7
8
7947.294
27536.397
MCS75
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6s
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6p
11 o
6
7
7480.348
26870.393
MCS75
11
11
F
G
ATOMIC SPECTROSCOPIC DATA
1727
Energy Levels of Neutral Gadolinium 共Gd I兲
Term
J
Level (cm⫺1 )
Ref
9
o
D
2
3
4
5
6
0.000
215.124
532.977
999.121
1719.087
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6s
11 o
F
2
3
4
5
6
7
8
6378.146
6550.395
6786.184
7103.420
7480.348
7947.294
8498.434
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d6s 2
7
Do
5
4
3
2
1
6976.508
7234.910
7426.710
7562.457
7653.927
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6s
9 o
1
2
3
4
5
6
7
10222.233
10359.905
10576.410
10883.505
11296.465
11830.393
12486.547
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 8 6s 2
7
F
6
5
4
3
2
1
0
10947.210
12519.997
13506.051
14253.948
14777.975
15121.220
15289.035
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d 2 ( 3 P)( 10Po)6s
11 o
4
5
6
11685.594
12057.164
12345.966
MZH78
MZH78
MZH78
4 f 7 ( 8 So)6s 2 6p
9
3
4
5
13433.851
13926.311
15665.424
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 9 Do)6s6 p( 3 Po)
11
2
3
4
5
6
7
8
14036.026
14298.311
14669.148
15174.000
15852.245
16775.024
17909.944
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
2
22334.508
MZH78
Configuration
7 8 o
4 f ( S )5d6s
2
4 f 7 ( 8 So)5d( 9 Do)6s6 p( 1 Po)
F
P
P
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1728
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Gadolinium 共Gd I兲—Continued
Term
J
Level (cm⫺1 )
Ref
9
3
4
5
6
2
22563.824
22820.895
23196.410
23229.298
24655.639
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6 p
1
23103.660
MZH78
4 f 7 ( 8 So)5d( 9 Do)6s6 p( 1 Po)
3
23389.782
MZH78
5
23999.912
MZH78
7
8
6
5
4
3
2
1
0
24255.103
—
24854.297
25380.885
25820.720
26247.609
26588.338
26834.311
27089.815
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 9 Do)6s6 p( 1 Po)
6
24430.425
MZH78
4 f 7 ( 8 So)5d( 7 Do)6s6 p( 3 Po)
4
24849.514
MZH78
5
25043.649
MZH78
1
2
3
4
5
6
7
8
9
25069.179
25164.640
25403.265
25571.672*
25940.122
26337.071
26870.393
27536.397
28432.859
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
7
25376.313
MZH78
6
25661.340
MZH78
3
27135.695
MZH78
4
27425.245
MZH78
Limit
49601.45
MOW98
Configuration
7 8 o
7
o
3 o
4 f ( S )5d( D )6s6 p( P )
7 8 o
9
o
D
1 o
4 f ( S )5d( D )6s6 p( P )
4 f 8 ( 7 F)5d( 8 G)6s
7 8 o
9
o
9
G
1 o
4 f ( S )5d( D )6s6 p( P )
4 f 7 ( 8 So)5d 2 ( 3 F)( 10Fo)6 p
11
G
4 f 7 ( 8 So)5d( 9 Do)6s6 p( 1 Po)
4 f 7 ( 8 So)5d( 7 Do)6s6 p( 3 Po)
7 8 o
9
o
1 o
4 f ( S )5d( D )6s6 p( P )
4 f 7 ( 8 So)5d( 9 Do)6s6 p( 1 Po)
o
)
Gd II ( 10D5/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
9
P
ATOMIC SPECTROSCOPIC DATA
1729
Persistent Lines of Singly-ionized Gadolinium 共Gd II兲
Inten
600
500
600
800
500
600
700
500
1000
600
600
500
250
Wavelength 共Å兲
3350.47
3358.62
3362.23
3422.47
3545.80
3584.96
3646.19
3743.47
3768.39
3796.37
3850.97
3852.45
3916.51
A ki (108 s⫺1 )
Configuration
7 8 o
9
o
J
Level (cm⫺1 )
Wl Ref
D
D
11/2
13/2
1158.943
30996.851
MCS75
Do
D
7/2
9/2
261.841
30027.378
MCS75
Do
D
9/2
11/2
633.273
30366.818
MCS75
Do
F
13/2
15/2
1935.310
31145.651
MCS75
Do
F
11/2
13/2
1158.943
29353.344
MCS75
Do
D
11/2
9/2
1158.943
29045.291
MCS75
Do
F
13/2
13/2
1935.310
29353.344
MCS75
Do
F
11/2
11/2
1158.943
27864.534
MCS75
Do
F
9/2
9/2
633.273
27162.224
MCS75
Do
F
7/2
7/2
261.841
26595.222
MCS75
Do
F
5/2
3/2
0.000
25960.073
MCS75
Do
F
7/2
5/2
261.841
26211.912
MCS75
11/2
11/2
4841.106
30366.818
MCS75
Term
4 f ( S )5d( D )6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
10
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
8
10
8
10
10
10
10
10
10
10
10
10
10
o
Do
D
10
250
4049.86
4 f 8 ( 7 F)6s
4 f 8 ( 7 F6 )6p 1/2
8
F
(6,1/2) o
13/2
13/2
7992.268
32677.540
MCS75
300
4098.61
4 f 7 ( 8 So)5d 2 ( 3 F)
4 f 7 ( 8 So)5d( 9 Do)6p
10 o
F
D
15/2
13/2
6605.154
30996.851
MCS75
10
250
4130.37
4 f 7 ( 8 So)5d 2 ( 3 F)
4 f 7 ( 8 So)5d( 9 Do)6p
10 o
F
13/2
11/2
5897.264
30101.366
MCS75
300
4184.25
4 f 7 ( 8 So)5d( 9 Do)6s
4 f 7 ( 8 So)5d( 9 Do)6p
8
Do
F
9/2
11/2
3972.167
27864.534
MCS75
10
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1730
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Gadolinium 共Gd II兲
Configuration
7 8 o
Level (cm⫺1 )
Ref
D
5/2
7/2
9/2
11/2
13/2
0.000
261.841
633.273
1158.943
1935.310
MZH78
MZH78
MZH78
MZH78
MZH78
Do
3/2
5/2
7/2
9/2
11/2
2856.678
3082.011
3427.274
3972.167
4841.106
MZH78
MZH78
MZH78
MZH78
MZH78
4 f ( S )5d( D )6s
10
4 f 7 ( 8 So)5d( 9 Do)6s
8
4 f 7 ( 8 So)6s 2
8 o
S
7/2
3444.235
MZH78
4 f ( S )5d ( F)
10 o
3/2
5/2
7/2
9/2
11/2
13/2
15/2
4027.161
4212.756
4483.854
4852.304
5339.477
5897.264
6605.154
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 8 ( 7 F)6s
8
F
13/2
11/2
9/2
7/2
5/2
3/2
1/2
7992.268
9092.491
10292.567
11084.335
11669.863
12071.778
12309.508
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 7 Do)6s
8
Do
11/2
9/2
7/2
5/2
3/2
8551.049
8884.809
9142.904
9328.864
9451.697
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 8 ( 7 F)6s
6
F
11/2
9/2
7/2
5/2
3/2
1/2
9943.779
11343.525
12318.288
13030.786
13515.189
13800.345
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 9 Do)6p
10
F
3/2
5/2
7/2
9/2
11/2
13/2
15/2
25960.073
26211.912
26595.222
27162.224
27864.534
29353.344
31145.651
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 9 Do)6p
10
D
5/2
7/2
9/2
11/2
13/2
27297.741
27988.074
29045.291
30366.818
30996.851
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 7 ( 8 So)5d( 9 Do)6p
8
3/2
5/2
7/2
9/2
29877.937
29965.752
30008.894
30027.378
MZH78
MZH78
MZH78
MZH78
11/2
30101.366
MZH78
11/2
13/2
32595.348
32677.540
MZH78
MZH78
Limit
97500
SR73
7 8 o
9
J
Term
o
2 3
o
F
D
4 f 7 ( 8 So)5d( 9 Do)6p
4 f 8 ( 7 F6 )6p 1/2
(6,1/2) o
Gd III ( 9 Do2 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1731
Gallium „Ga…
Atomic number⫽31
Atomic weight⫽69.723
Isotope
69
71
Ga
Ga
Mass
Abundance
Spin
Mag moment
68.925580
70.924700
60.11%
39.89%
3/2
3/2
⫹2.01659
⫹2.56227
o
Ga I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 2P1/2
⫺1
Ionization energy: 48 387.634 cm 共5.999 301 eV兲
Ga II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 1S0
Ionization energy: 165 465.8 cm⫺1 共20.515 14 eV兲
Strong Lines of Gallium 共Ga兲
Intensity
140
200
200
300
1000
800
800
900
1000
150
200
300
300
400
600
200
600
500
500
300
500
1000
300
500
500
1000
100
70
900
800
800
50
40
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
829.529
1113.708
1119.133
1130.760
1414.401
1535.309
1813.878
1845.199
Air
2090.771
2450.08
2500.19
2700.491
2779.977
2874.235
2943.636
2944.173
3374.915
3375.948
3470.347
3735.024
4032.984
4172.042
4262.019
5219.65
5416.36
6334.05
6396.56
6413.45
6419.23
6455.89
7792.26
11949.12
12109.78
Spectrum
Ref.
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
II
II
II
II
II
II
II
II
IL85
IL85
IL85
IL85
IL85
IL85
IL85
IL85
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
II
I
I
II
II
I
I
I
II
II
II
II
I
I
II
II
II
II
I
I
II
II
II
I
I
IL85
MM52
MM52
IL85
IL85
JL67
JL67
JL67
IL85
IL85
IL85
IL85
ND82
JL67
IL85
IL85
IL85
IL85
JL67
JL67
IL85
IL85
IL85
JL67
JL67
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1732
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Gallium 共Ga I兲
Inten
Wavelength 共Å兲
400
A ki (108 s⫺1 )
2874.235
600
200
1.34
2944.173
500
0.261
4032.984
1000
2
1.17
2943.636
0.485
4172.042
Configuration
0.945
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
4s 4 p
4s 2 4d
2 o
P
D
1/2
3/2
0.000
34781.66
JL67
M03
4s 2 4 p
4s 2 4d
2 o
P
D
3/2
5/2
826.19
34787.85
JL67
M03
4s 2 4 p
4s 2 4d
2 o
P
D
3/2
3/2
826.19
34781.66
JL67
M03
4s 2 4 p
4s 2 5s
2 o
P
S
1/2
1/2
0.000
24788.530
ND82
M03
4s 2 4 p
4s 2 5s
2 o
3/2
1/2
826.19
24788.530
JL67
M03
2
2
2
2
2
P
S
Energy Levels of Neutral Gallium 共Ga I兲
Configuration
Term
2
Level (cm⫺1 )
J
Ref
4s 4p
2 o
P
1/2
3/2
0.000
826.19
4s 2 5s
2
S
1/2
24788.530
ND82
4s 2 5p
2 o
P
1/2
3/2
33044.05
33155.07
JL67
JL67
4s 2 4d
2
D
3/2
5/2
34781.66
34787.85
JL67
JL67
4s 2 6s
2
S
1/2
37584.79
JL67
Limit
48387.634
ND82
Ga II ( 1 S0 )
JL67
JL67
Persistent Lines of Singly-ionized Gallium 共Ga II兲
Inten
1000
800
800
900
1000
1000
900
800
Wavelength 共Å兲
1414.401
1535.309
A ki (108 s⫺1 )
19.7
14.5
1813.878
1845.199
2090.771
0.00409
6334.05
6419.23
6455.89
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Term
J
Level (cm⫺1 )
4s
4s4 p
1
S
P
0
1
4s4p
4s4d
3 o
P
D
4s4 p
4s5s
3 o
Configuration
Wl Ref
A Ref
0.00
70701.27
IL85
M03
2
3
48749.74
113883.19
IL85
C00
P
S
1
1
47814.05
102944.55
IL85
4s4 p
4s5s
3 o
P
S
2
1
48749.74
102944.55
IL85
4s 2
4s4 p
1
S
P
0
1
0.00
47814.05
IL85
4s5s
4s5 p
3
S
P
1
2
102944.55
118727.89
IL85
4s5s
4s5 p
3
S
P
1
1
102944.55
118518.47
IL85
4s5s
4s5 p
3
S
P
1
0
102944.55
118430.02
IL85
2
1 o
3
3
3
3 o
3 o
3 o
3 o
M03
ATOMIC SPECTROSCOPIC DATA
1733
Energy Levels of Singly-ionized Gallium 共Ga II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
0.00
IL85
4s4p
3 o
P
0
1
2
47367.51
47814.05
48749.74
IL85
IL85
IL85
4s4 p
1 o
P
1
70701.27
IL85
4s5s
3
S
1
102944.55
IL85
4s5s
1
S
0
106662.21
IL85
4p 2
1
D
2
107720.56
IL85
4s4d
3
D
1
2
3
113815.92
113842.19
113883.19
IL85
IL85
IL85
4s5p
3 o
0
1
2
118430.02
118518.47
118727.89
IL85
IL85
IL85
Limit
165465.8
IL85
4s
2
Ga III ( 2 S1/2)
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1734
J. E. SANSONETTI AND W. C. MARTIN
Germanium „Ge…
Atomic number⫽32
Atomic weight⫽72.61
Isotope
70
Ge
Ge
73
Ge
74
Ge
76
Ge
72
Mass
Abundance
Spin
Mag moment
69.924250
71.922079
72.923463
73.921177
75.921401
20.5%
27.4%
7.8%
36.5%
7.8%
0
0
9/2
0
0
⫺0.87946
Ge I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 2 3P0
Ionization energy: 63 713.24 cm⫺1 共7.899 43 eV兲
o
Ge II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 2P1/2
⫺1
Ionization energy: 128 521.3 cm 共15.934 61 eV兲
Strong Lines of Germanium 共Ge兲
Intensity
300
500
500
500
500
200
300
500
500
500
80
80
80
80
80
80
80
200
120
200
120
200
500
500
80
80
200
80
120
120
200
P
P
P
P
P
P
r
h
h
r
r
r
r
r
P
P
h
P
r
80
700 P
900 P,r
600 P,r
150
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
1085.51
1106.74
1120.46
1181.19
1181.65
1188.73
1191.26
1237.059
1261.905
1576.855
1716.784
1750.043
1774.176
1785.046
1841.328
1842.410
1853.134
1860.086
1874.256
1904.702
1917.592
1929.826
1938.008
1938.891
1944.731
1955.115
1962.013
1970.880
1987.849
1988.267
1998.887
Air
2011.29
2019.068
2041.712
2043.770
2054.461
Spectrum
Ref
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
S63a
S63a
S63a
S63a
S63a
S63a
S63a
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
KE74
Ge
Ge
Ge
Ge
Ge
I
I
I
I
I
AM59
AM59
AM59
AM59
AM59
ATOMIC SPECTROSCOPIC DATA
1735
Strong Lines of Germanium 共Ge兲—Continued
Wavelength 共Å兲
Intensity
80
300
1000
150
800
90
130
500
200
500
200
200
300
400
250
1000
1000
300
250
40
300
1000
1000
1000
500
90
70
250
500
400
90
200
h
r
P,r
Spectrum
2057.238
2065.215
2068.656
2086.021
2094.258
2105.824
2198.714
2500.54
2592.534
2651.172
2651.568
2691.341
2709.624
2729.78
2754.588
2831.843
2845.527
3039.067
3067.021
3269.489
3499.21
4741.806
4814.608
5893.389
6021.041
11252.83
11614.81
11714.76
12069.20
12391.58
13107.61
14822.38
P,r
P,r
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ref
I
I
I
I
I
I
I
II
I
I
I
I
I
II
I
II
II
I
I
I
II
II
II
II
II
I
I
I
I
I
I
I
AM59
AM59
AM59
AM59
AM59
AM59
AM59
S63a
AM59
AM59
AM59
AM59
AM59
S63a
AM59
S63a
S63a
AM59
AM59
AM59
S63a
S63a
S63a
S63a
S63a
HA64
HA64
HA64
HA64
HA64
HA64
HA64
Persistent Lines of Neutral Germanium 共Ge I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
120
1988.267
0.41
200
700
900
600
1000
800
130
1998.887
2019.068
2041.712
2043.770
2068.656
2094.258
2198.714
1.24
0.49
1.51
0.86
1.2
1.70
Configuration
Term
J
Level (cm⫺1 )
4s 2 4 p 2
4s 2 4 p4d
3
P
P
2
1
4s 2 4 p 2
4s 2 4 p4d
3
P
P
4s 2 4 p 2
4s 2 4 p4d
3
4s 2 4 p 2
4s 2 4 p4d
3
4s 2 4 p 2
4s 2 4 p4d
3
4s 2 4 p 2
4s 2 4 p4d
3
4s 2 4 p 2
4s 2 4 p4d
3
4s 2 4 p 2
4s 2 4 p4d
1
Wl Ref
A Ref
1409.9609
51705.020
KE74
M00
2
2
1409.9609
51437.802
KE74
M00
P
F
1
2
557.1341
50068.954
AM59
M00
P
Do
0
1
0.0000
48962.783
AM59
M00
P
F
2
3
1409.9609
50323.465
AM59
M00
P
Do
1
2
557.1341
48882.263
AM59
M00
P
Do
2
3
1409.9609
49144.397
AM59
M00
D
F
2
3
7125.2989
52592.224
AM59
3 o
3 o
3 o
3
3 o
3
3
1 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1736
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Germanium 共Ge I兲—Continued
Inten
Wavelength 共Å兲
200
2592.534
500
2651.172
200
2651.568
200
2691.341
300
2709.624
250
2754.588
300
3039.067
40
500
400
3269.489
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3
P
P
1
2
557.1341
39117.9021
AM59
BDGL98
P
P
2
2
1409.9609
39117.9021
AM59
BDGL98
P
P
0
1
0.0000
37702.3054
AM59
BDGL98
P
P
1
1
557.1341
37702.3054
AM59
BDGL98
P
P
1
0
557.1341
37451.6893
AM59
BDGL98
P
P
2
1
1409.9609
37702.3054
AM59
BDGL98
D
P
2
1
7125.2989
40020.5604
AM59
BDGL98
D
P
2
1
7125.2989
37702.3054
AM59
BDGL98
4s 2 4 p5s
4s 2 4 p5 p
3 o
P
D
1
1
37702.3054
45985.592
HA64
4s 2 4 p5s
4s 2 4 p5 p
1 o
1
1
40020.5604
48088.3504
HA64
Configuration
2
2
4s 4 p
4s 2 4 p5s
0.60
3 o
4s 2 4 p 2
4s 2 4 p5s
1.60
3
3 o
4s 2 4 p 2
4s 2 4 p5s
0.69
3
3 o
4s 2 4 p 2
4s 2 4 p5s
0.47
3
3 o
4s 2 4 p 2
4s 2 4 p5s
2.08
3
3 o
4s 2 4 p 2
4s 2 4 p5s
0.79
3
3 o
4s 2 4 p 2
4s 2 4 p5s
2.04
1
1 o
4s 2 4 p 2
4s 2 4 p5s
0.17
12069.20
12391.58
1
3 o
3
3
P
P
Energy Levels of Neutral Germanium 共Ge I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4s 2 4p 2
3
0
1
2
0.0000
557.1341
1409.9609
SM93b
SM93b
SM93b
4s 2 4p 2
1
2
7125.2989
SM93b
4s 2 4p 2
1
S
0
16367.3332
SM93b
4s 4p5s
3 o
P
0
1
2
37451.6893
37702.3054
39117.9021
SM93b
SM93b
SM93b
4s 2 4p5s
1 o
P
1
40020.5604
SM93b
4s4 p 3
5 o
S
2
41926.726
SM93b
4s 2 4p5p
3
D
1
2
3
45985.592
46834.3798
48104.1003
SM93b
SM93b
SM93b
4s 2 4p5p
1
P
1
46765.2705
SM93b
4s 2 4p5p
3
P
0
1
2
47502.6257
48088.3504
48726.1143
SM93b
SM93b
SM93b
4s 2 4p4d
1
Do
2
48480.048
SM93b
2
P
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1737
Energy Levels of Neutral Germanium 共Ge I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
4s 2 4p4d
3
Do
2
1
3
48882.263
48962.783
49144.397
SM93b
SM93b
SM93b
4s 2 4p5p
3
S
1
49075.8917
SM93b
4s 2 4p5p
1
D
2
49649.5807
SM93b
4s 2 4p4d
3 o
F
2
3
4
50068.954
50323.465
50786.79
SM93b
SM93b
SM93b
4s 2 4p5p
1
S
0
51011.4392
SM93b
4s 4p4d
3 o
P
2
1
0
51437.802
51705.020
51978.15
SM93b
SM93b
SM93b
4s 2 4p4d
1 o
F
3
52592.224
SM93b
1 o
1
52847.215
SM93b
Limit
63713.24
SM93b
2
2
4s 4p4d
P
o
)
Ge II ( 2 P1/2
Persistent Lines of Singly-ionized Germanium 共Ge II兲
Inten
500
500
200
500
500
500
500
500
1000
1000
1000
1000
Wavelength 共Å兲
1106.74
1120.46
1188.73
1237.059
1261.905
A ki (108 s⫺1 )
48.
24.
7.7
27.
29.
1576.855
1938.008
1938.891
0.0028
0.0047
0.46
0.51
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
4s 4 p
4s4 p 2
2 o
P
P
3/2
3/2
1767.357
92122.7
S63a
M00
4s 2 4 p
4s4 p 2
2 o
P
P
3/2
1/2
1767.357
91016.2
S63a
M00
4s 2 4 p
4s4 p 2
2 o
P
S
3/2
1/2
1767.357
85890.55
S63a
M00
4s 2 4 p
4s 2 4d
2 o
P
D
1/2
3/2
0.000
80836.880
KE74
M00
4s 2 4 p
4s 2 4d
2 o
P
D
3/2
5/2
1767.357
81012.598
KE74
M00
4s 2 4 p
4s4 p 2
2 o
P
D
3/2
5/2
1767.357
65184.738
KE74
4s 2 4 p
4s4 p 2
2 o
P
P
3/2
5/2
1767.357
53366.738
KE74
M00
4s 2 4 p
4s4 p 2
2 o
1/2
1/2
0.000
51575.885
KE74
M00
3/2
5/2
65015.672
100317.976
S63a
D
F
5/2
7/2
65184.738
100317.283
S63a
4s 2 5 p
4s 2 5d
2 o
P
D
1/2
3/2
79006.985
100090.088
S63a
FW96
4s 2 5 p
4s 2 5d
2 o
3/2
5/2
79366.627
100130.936
S63a
FW96
4s4p 2
4s 2 4 f
2845.527
4814.608
2
4s4 p 2
4s 2 4 f
2831.843
4741.806
Configuration
2
2
2
2
2
2
4
P
P
4
2
D
F
2 o
2
2 o
2
2
P
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1738
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Germanium 共Ge II兲—Continued
Wavelength 共Å兲
Inten
1000
A ki (108 s⫺1 )
5893.389
500
0.92
6021.041
Configuration
2
J
Level (cm⫺1 )
S
P
1/2
3/2
S
P
1/2
1/2
Term
4s 5s
4s 2 5 p
2
4s 2 5s
4s 2 5 p
2
2 o
2 o
Wl Ref
A Ref
62403.15
79366.627
S63a
FW96
62403.15
79006.985
S63a
Energy Levels of Singly-ionized Germanium 共Ge II兲
Configuration
2
Term
J
Level (cm⫺1 )
Ref
4s 4p
2 o
P
1/2
3/2
0.000
1767.357
SM93b
SM93b
4s4 p 2
4
P
1/2
3/2
5/2
51575.885
52290.942
53366.738
SM93b
SM93b
SM93b
4s 2 5s
2
S
1/2
62403.028
SM93b
2
2
D
3/2
5/2
65015.672
65184.738
SM93b
SM93b
4s 2 5p
2 o
P
1/2
3/2
79006.853
79366.494
SM93b
SM93b
4s 2 4d
2
D
3/2
5/2
80836.880
81012.598
SM93b
SM93b
4s4p 2
2
S
1/2
85890.55
SM93b
2
2
P
1/2
3/2
91016.2
92122.7
SM93b
SM93b
4s 2 6s
2
S
1/2
94784.381
SM93b
4s 2 5d
2
D
3/2
5/2
100089.970
100130.812
SM93b
SM93b
4s 2 4 f
2 o
7/2
5/2
100317.283
100317.976
SM93b
SM93b
128521.3
SM93b
4s4p
4s4p
F
Ge III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1739
Gold „Au…
Atomic number⫽79
Atomic weight⫽196.966 543
Isotope
197
Au
Mass
Abundance
Spin
Mag moment
196.966543
100%
3/2
⫹0.1457
Au I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2S1/2
Ionization energy: 74 408.88 cm⫺1 共9.225 53 eV兲
Au II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 10 1S0
Ionization energy: 162 950 cm⫺1 共20.20 eV兲
Strong Lines of Gold 共Au兲
Intensity
600
600
9
400
400
9
9
500
20
9
14
9
20
600
600
9
150
1000
250
150
400
500
200
400
700
250
15
11
250
400
100
400
25
300
100
9
600
200
1000
400
P
h
P
P
P
P
P
P
P
P
P
P
P
P
P
h
Wavelength 共Å兲
Vacuum
1224.592
1229.901
1328.374
1355.616
1362.326
1408.451
1481.764
1486.547
1587.158
1624.335
1646.674
1665.755
1699.339
1740.475
1783.200
1879.829
Air
2000.792
2012.00
2021.38
2044.587
2082.077
2110.685
2228.915
2248.562
2263.627
2304.684
2352.65
2387.75
2427.95
2533.518
2552.658
2616.393
2641.480
2675.954
2748.253
2780.822
2802.036
2819.793
2822.546
2825.437
Spectrum
Ref.
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
II
II
I
II
II
I
I
II
I
I
I
I
I
II
II
I
RW97
RW97
BG78
RW97
RW97
BG78
BG78
RW97
BG78
BG78
BG78
BG78
BG78
RW97
RW97
BG78
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
II
I
I
II
II
II
II
II
II
II
I
I
I
II
II
II
I
I
I
I
II
II
II
II
RW97
MCS75
MCS75
RW97
RW97
RW97
RW97
RW97
RW97
RW97
MCS75
MCS75
MCS75
RW97
RW97
RW97
ED71
ED71
ED71
ED71
RW97
RW97
RW97
RW97
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1740
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Gold 共Au兲—Continued
Intensity
Wavelength 共Å兲
120
400
25
25
400 P
20
40
400 P
200
200 h
400 P
30 P
25
150 P
9
25
25
25
25
25
9
9h
25
9h
9
9
9
40
25
40
60
20
11 h
25
80 h
50
25
25
25 h
50 P
9
50
2837.848
2846.920
2883.446
2891.961
2893.247
2907.042
2913.517
2918.235
2954.222
2990.268
2994.800
3029.204
3065.424
3122.784
3194.720
3230.632
3308.305
3309.638
3557.365
3586.731
3611.568
3631.311
3637.905
3645.016
3650.739
3709.622
3796.007
3897.865
3909.383
4040.931
4065.068
4315.110
4437.269
4488.253
4607.512
4792.583
5230.259
5837.374
5956.965
6278.170
6562.680
7510.728
Spectrum
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
Au
II
II
I
I
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
RW97
RW97
ED71
ED71
RW97
RW97
RW97
RW97
RW97
RW97
RW97
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
ED71
Persistent Lines of Neutral Gold 共Au I兲
Inten
14
Wavelength 共Å兲
A ki (108 s⫺1 )
1646.674
Configuration
Term
5d 106s
5d 107 p
2
S
P
2 o
J
Level (cm⫺1 )
1/2
3/2
0.000
60728.49
BG78
Wl Ref
20
1699.339
5d 106s
5d 9 ( 2 D3/2)6s6p( 1 Po1 )
2
S
(3/2,1) o
1/2
3/2
0.000
58845.414
BG78
1000
2012.060
5d 9 6s 2
5d 9 ( 2 D3/2)6s6p( 1 Po1 )
2
D
(3/2,1) o
5/2
3/2
9161.177
58845.414
ED71
250
2021.364
5d 9 6s 2
5d 9 ( 2 D3/2)6s6p( 3 Po1 )
2
5/2
5/2
9161.177
58616.764
ED71
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
D
(3/2,1) o
A Ref
ATOMIC SPECTROSCOPIC DATA
1741
Persistent Lines of Neutral Gold 共Au I兲—Continued
Wavelength 共Å兲
Inten
250
2427.944
300
2675.954
A ki (108 s⫺1 )
1.63
Level (cm⫺1 )
S
P
1/2
3/2
S
P
Term
10
1.98
J
Configuration
5d 6s
5d 106 p
2
5d 106s
5d 106 p
2
2 o
2 o
Wl Ref
A Ref
0.000
41174.613
ED71
M00
1/2
1/2
0.000
37358.991
ED71
M00
100
2748.253
5d 9 6s 2
5d 9 ( 2 D5/2)6s6p( 3 Po1 )
2
D
(5/2,1) o
5/2
7/2
9161.177
45537.195
ED71
30
3029.204
5d 9 6s 2
5d 9 ( 2 D5/2)6s6p( 3 Po0 )
2
D
(5/2,0) o
5/2
5/2
9161.177
42163.530
ED71
150
3122.784
2
5/2
3/2
9161.177
41174.613
ED71
FW96
3/2
1/2
21435.191
37358.991
ED71
FW96
50
6278.170
5d 9 6s 2
5d 106 p
0.190
D
P
2 o
5d 9 6s 2
5d 106 p
0.034
2
D
P
2 o
Energy Levels of Neutral Gold 共Au I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
10
5d 6s
2
S
1/2
0.000
ED71
5d 9 6s 2
2
D
5/2
3/2
9161.177
21435.191
ED71
ED71
5d 106p
2 o
1/2
3/2
37358.991
41174.613
ED71
ED71
5d 9 ( 2 D5/2)6s6p( 3 Po0 )
(5/2,0) o
5/2
42163.530
ED71
5d 9 ( 2 D5/2)6s6p( 3 Po1 )
(5/2,1) o
7/2
5/2
3/2
45537.195
46174.979
47007.433
ED71
ED71
ED71
5d 9 ( 2 D5/2)6s6p( 3 Po2 )
(5/2,2) o
9/2
7/2
3/2
5/2
1/2
48697.147
51028.894
51231.530
51653.460
53196.32
ED71
ED71
ED71
ED71
BG78
5d 107s
2
P
1/2
54485.235
ED71
o
3/2
56105.748
ED71
5d 9 ( 2 D3/2)6s6p( 3 Po1 )
(3/2,1) o
5/2
58616.764
ED71
5d 9 ( 2 D3/2)6s6p( 1 Po1 )
(3/2,1) o
3/2
58845.414
ED71
5d 107p
2 o
1/2
3/2
60032.85
60728.49
BG78
BG78
Limit
74408.88
BG78
9 2
5d (
D3/2)6s6p( 3 Po0 )
Au II ( 1 S0 )
S
(3/2,0)
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1742
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Gold 共Au II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
10
Term
J
Level (cm⫺1 )
Wl Ref
600
1224.592
5d
5d 9 ( 2 D3/2)6p
1
S
(3/2,1/2) o
0
1
0.00
81659.828
RW97
400
1362.326
5d 10
5d 9 ( 2 D5/2)6p
1
S
(5/2,3/2) o
0
1
0.00
73403.839
RW97
400
2082.077
5d 9 ( 2 D5/2)6s
5d 9 ( 2 D5/2)6p
共5/2,1/2兲
(5/2,1/2) o
3
2
15039.572
63053.318
RW97
500
2110.685
5d 9 ( 2 D5/2)6s
5d 9 ( 2 D5/2)6p
共5/2,1/2兲
(5/2,1/2) o
2
3
17640.616
65003.594
RW97
700
2263.627
5d 9 ( 2 D3/2)6p
5d 9 ( 2 D3/2)7s
(3/2,1/2) o
共3/2,1/2兲
2
1
76659.700
120822.927
RW97
600
2802.036
5d 9 ( 2 D5/2)6p
5d 9 ( 2 D5/2)7s
(5/2,3/2) o
共5/2,1/2兲
4
3
72495.129
108172.952
RW97
1000
2822.546
5d 9 ( 2 D3/2)6p
5d 9 ( 2 D3/2)7s
(3/2,3/2) o
共3/2,1/2兲
3
2
85700.201
121118.779
RW97
400
2893.247
5d 9 ( 2 D3/2)6p
5d 9 ( 2 D3/2)7s
(3/2,3/2) o
共3/2,1/2兲
2
2
86565.667
121118.779
RW97
400
2918.235
5d 9 ( 2 D3/2)6p
5d 9 ( 2 D3/2)7s
(3/2,3/2) o
共3/2,1/2兲
2
1
86565.667
120822.927
RW97
400
2994.800
5d 9 ( 2 D5/2)6p
5d 9 ( 2 D5/2)7s
(5/2,3/2) o
共5/2,1/2兲
3
3
74791.477
108172.952
RW97
A Ref
Energy Levels of Singly-ionized Gold 共Au II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5d 10
1
0
5d 9 ( 2 D5/2)6s
共5/2 ,1/2兲
3
2
15039.572
17640.616
RW97
RW97
5d 9 ( 2 D3/2)6s
共3/2 ,1/2兲
1
2
27765.758
29621.249
RW97
RW97
5d 8 6s 2
3
4
3
40478.750
52176.508
RW97
RW97
5d 8 6s 2
1
2
48510.894
RW97
5d 8 6s 2
2
2
58191.630
RW97
5d 8 6s 2
3
0
1
58550.226
61749.419
RW97
RW97
5d 9 ( 2 D5/2)6p
(5/2 ,1/2) o
2
3
63053.318
65003.594
RW97
RW97
5d 9 ( 2 D5/2)6p
(5/2 ,3/2) o
4
2
1
3
72495.129
73178.291
73403.839
74791.477
RW97
RW97
RW97
RW97
5d 9 ( 2 D3/2)6p
(3/2 ,1/2) o
2
1
76659.700
81659.828
RW97
RW97
S
F
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
0.00
RW97
ATOMIC SPECTROSCOPIC DATA
1743
Energy Levels of Singly-ionized Gold 共Au II兲—Continued
Configuration
9 2
Term
o
J
Level (cm⫺1 )
Ref
0
3
1
2
82613.781
85700.201
85707.570
86565.667
RW97
RW97
RW97
RW97
5d ( D3/2)6p
(3/2 ,3/2)
5d 9 ( 2 D5/2)7s
共5/2 ,1/2兲
3
2
108172.952
108631.442
RW97
RW97
5d 9 ( 2 D5/2)6d
共5/2 ,3/2兲
1
4
2
3
116050.55
116946.327
117065.629
117511.998
RW97
RW97
RW97
RW97
5d 9 ( 2 D5/2)7p
(5/2 ,1/2) o
2
3
119446.50
120257.120
RW 97
RW97
5d 9 ( 2 D3/2)7s
共3/2 ,1/2兲
1
2
120822.927
121118.779
RW97
RW97
162950
RW97
Au III ( 2 D5/2)
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1744
J. E. SANSONETTI AND W. C. MARTIN
Hafnium „Hf…
Atomic number⫽72
Atomic weight⫽178.49
Isotope
176
Hf
Hf
178
Hf
179
Hf
180
Hf
177
Mass
Abundance
Spin
175.941406
176.943217
177.943696
178.945812
179.946545
5.21%
18.6%
27.30%
13.63%
35.10%
0
7/2
0
9/2
0
Mag moment
⫹0.7935
⫺0.6409
Hf I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 2 6s 2 3F2
Ionization energy: 55 047.9 cm⫺1 共6.825 07 eV兲
o
Hf II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d6s 2 2P3/2
⫺1
Ionization energy: 120 000 cm 共15 eV兲
Strong Lines of Hafnium 共Hf兲
Intensity
700
1000
140
60
40
70
70
40
40
40
60
50
80
60
40
40
50
50
50
70
70
100
40
40
100
40
40
40
40
50
50
50
130
130
80
300
110
Wavelength 共Å兲
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2012.78
2028.18
2096.18
2210.82
2254.01
2277.16
2322.47
2323.25
2324.89
2347.44
2351.22
2393.36
2393.83
2405.42
2410.14
2417.69
2447.25
2460.49
2464.19
2512.69
2513.03
2516.88
2531.19
2551.40
2571.67
2573.90
2576.82
2578.14
2582.54
2606.37
2607.03
2622.74
2638.71
2641.41
2647.29
2705.61
2718.59
Spectrum
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1745
Strong Lines of Hafnium 共Hf兲—Continued
Intensity
80
40
200
120
200
100
140
60
200
120
90
90
1000
400
800
500
400
900
250
40
60
200
80
900
500
500
250
600
300
80
100
500
400
130
250
130
400
500
50
300
500
400
1000
110
200
40
80
300
100
200
120
80
200
400
50
40
80
140
150
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
2738.76
2751.81
2761.63
2773.36
2779.37
2817.68
2820.22
2822.68
2845.83
2850.96
2861.01
2861.70
2866.37
2889.62
2898.26
2904.41
2904.75
2916.48
2918.58
2919.59
2929.63
2929.90
2937.80
2940.77
2950.68
2954.20
2958.02
2964.88
2966.93
2968.81
2975.88
2980.81
3005.56
3012.90
3016.78
3016.94
3018.31
3020.53
3031.16
3050.76
3057.02
3067.41
3072.88
3074.79
3080.84
3101.40
3109.12
3131.81
3134.72
3156.63
3159.82
3162.61
3168.39
3172.94
3176.86
3193.53
3194.19
3206.11
3247.66
Spectrum
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
II
II
I
II
I
I
II
II
I
I
II
II
I
I
I
I
I
I
I
II
II
I
II
I
I
I
I
I
I
II
II
I
I
II
I
II
I
I
II
I
I
I
I
I
I
II
II
I
II
I
I
II
I
I
II
II
II
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1746
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Hafnium 共Hf兲—Continued
Intensity
100
100
150
300
400
40
100
90
100
100
100
250
100
200
300
60
110
400
140
400
120
300
60
150
120
130
250
400
40
90
150
200
1000
130
40
500
80
200
200
600
600
80
400
150
600
130
400
250
100
40
300
70
150
200
100
60
500
150
110
Wavelength 共Å兲
P
P
P
d
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3249.53
3253.70
3310.27
3312.86
3332.73
3352.06
3358.91
3389.83
3392.81
3397.26
3397.60
3399.80
3417.34
3419.18
3472.40
3479.28
3497.16
3497.49
3505.23
3523.02
3535.54
3536.62
3552.70
3561.66
3567.36
3569.04
3599.87
3616.89
3630.87
3644.36
3649.10
3675.74
3682.24
3696.51
3701.15
3717.80
3719.28
3733.79
3746.80
3777.64
3785.46
3793.37
3800.38
3811.78
3820.73
3830.02
3849.18
3858.31
3860.91
3880.82
3899.94
3918.09
3931.38
3951.83
4062.84
4093.16
4174.34
4294.79
4356.33
Spectrum
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
I
II
I
I
I
II
I
II
I
I
I
II
I
I
I
II
I
I
II
I
II
I
II
II
I
II
I
I
II
II
I
I
I
I
II
I
II
I
I
I
I
II
I
I
I
I
I
I
I
II
I
II
I
I
I
II
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1747
Strong Lines of Hafnium 共Hf兲—Continued
Intensity
Wavelength 共Å兲
110
250 d
100
140
100
100
100
250
300 P
200
150
140
110
4565.94
4598.80
4620.86
4800.50
5181.86
5550.60
5552.12
7131.81
7237.10
7240.87
7624.40
7845.35
7994.73
Spectrum
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Hafnium 共Hf I兲
Inten
Wavelength 共Å兲
1000
2866.37
800
500
900
900
1000
1000
500
300
A ki (108 s⫺1 )
5d 2 6s 2
5d 2 ( 3 F)6s( 2 F)6p
5d 2 6s 2
5d 2 ( 1 G)6s( 2 G)6p
2898.26
5d 2 6s 2
5d 2 ( 3 F)6s( 2 F)6p
2904.41
5d 2 6s 2
5d 2 ( 1 G)6s( 2 G)6p
2916.48
5d 2 6s 2
5d 2 ( 1 G)6s( 2 G)6p
2940.77
5d 2 6s 2
5d 2 ( 3 F)6s( 2 F)6p
3072.88
3682.24
4174.34
7237.10
Configuration
0.26
0.046
5d 2 6s 2
5d 2 ( 3 F)6s( 4 F)6p
5d 2 6s 2
5d 2 ( 3 F)6s( 4 F)6p
5d 2 6s 2
5d6s 2 6 p
Term
J
Level (cm⫺1 )
Wl Ref
3
F
F
2
3
0.00
34877.04
MCS75
F
Go
3
4
2356.68
36850.04
MCS75
F
Go
4
4
4567.64
38987.85
MCS75
F
Go
4
5
4567.64
38845.45
MCS75
F
F
2
2
0.00
33994.86
MCS75
F
Go
2
3
0.00
32533.32
MCS75
F
F
2
2
0.00
27149.64
MCS75
M00
F
Do
3
3
2356.68
26305.78
MCS75
M00
F
Do
4
3
4567.64
18381.50
MCS75
1 o
3
3
3
1
3
3
3
3 o
3
3
3
3 o
3
5
3
3
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1748
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Hafnium 共Hf I兲
Term
J
Level (cm⫺1 )
2
3
2
3
4
0.00
2356.68
4567.64
MM76
MM76
MM76
5d 2 6s 2
3
0
1
2
5521.77
6572.54
8983.74
MM76
MM76
MM76
5d 2 6s 2
1
D
2
5638.61
MM76
5d6s 6p
3 o
2
3
4
10508.88
14541.66
18224.97
MM76,MS96
MM76
MM76
5d 2 6s 2
1
G
4
10532.55
MM76
5d6s 2 6p
3
Do
1
2
3
14017.81
16163.35
18381.50
MM76
MM76
MM76
5d6s 2 6p
1
Do
2
14435.12
MM76,MS96
5d6s 6p
3 o
1
0
2
18143.39
18270.12
19791.29
MM76
MM76
MM76
5d 2 6s 2
1
S
0
20328.36
W78
5d6s 2 6p
1 o
F
3
23644.74
MM76
5d 2 ( 3 F)6s( 4 F)6p
5
Do
3
26305.78
MM76
5d6s 6p
1 o
P
1
26463.93
MM76
5d 2 ( 3 F)6s( 4 F)6p
3 o
F
2
27149.64
MM76
5d 2 ( 3 F)6s( 2 F)6p
3
Go
3
32533.32
MM76
5d 2 ( 1 G)6s( 2 G)6p
3 o
F
2
33994.86
MM76
5d ( F)6s( F)6p
1 o
F
3
34877.04
MM76
5d 2 ( 1 G)6s( 2 G)6p
3
Go
4
5
36850.04
38845.45
MM76
MM76
5d 2 ( 3 F)6s( 2 F)6p
1
Go
4
38987.85
MM76
Limit
55047.9
CHR88b
Configuration
2
5d 6s
F
P
2
F
2
P
2
2 3
2
Hf II ( 2 D3/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1749
Persistent Lines of Singly-ionized Hafnium 共Hf II兲
Inten
Wavelength 共Å兲
700
1000
100
130
120
140
100
100
250
60
A ki (108 s⫺1 )
Configuration
2
2012.78
2028.18
2516.88
2641.41
2773.36
2820.22
3134.72
3253.70
0.21
3399.80
0.31
4093.16
J
Level (cm⫺1 )
Wl Ref
D
Do
5/2
3/2
3050.88
52717.46
MCS75
P
F
5/2
5/2
13485.56
62774.9
MCS75
D
P
5/2
3/2
3050.88
42770.6
MCS75
F
Go
9/2
11/2
8361.76
46209.05
MCS75
F
Go
7/2
9/2
6344.34
42391.09
MCS75
D
Go
5/2
7/2
3050.88
38498.53
MCS75
D
Go
5/2
5/2
3050.88
34942.36
MCS75
D
F
5/2
7/2
3050.88
33776.24
MCS75
M00
D
F
3/2
5/2
0.00
29405.12
MCS75
M00
F
F
3/2
3/2
3644.65
28068.79
MCS75
Term
5d6s
5d 2 ( 3 P)6p
2
5d 2 ( 3 P)6s
5d 2 ( 1 G)6p
4
5d6s 2
5d6s( 3 D)6p
2
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
4
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
4
5d6s 2
5d 2 ( 3 F)6p
2
5d6s 2
5d 2 ( 3 F)6p
2
5d6s 2
5d6s( 3 D)6p
2
5d6s 2
5d6s( 3 D)6p
2
5d 2 ( 3 F)6s
5d6s( 3 D)6p
4
4
2 o
2 o
4
4
4
4
4 o
4 o
4 o
A Ref
Energy Levels of Singly-ionized Hafnium 共Hf II兲
Ref
Term
5d6s 2
2
D
3/2
5/2
0.00
3050.88
M58
M58
5d 2 ( 3 F)6s
4
F
3/2
5/2
7/2
9/2
3644.65
4904.85
6344.34
8361.76
M58
M58
M58
M58
5d 2 ( 3 P)6s
4
P
5/2
13485.56
M58
5d6s( 3 D)6p
4 o
F
3/2
5/2
7/2
9/2
28068.79
29405.12
33776.24
38185.67
M58
M58
M58
M58
5d6s( 3 D)6p
2 o
P
3/2
42770.6
M58
5d 2 ( 3 F)6p
4 o
F
9/2
46124.89
M58
5d 2 ( 3 F)6p
4
Go
5/2
7/2
9/2
11/2
34942.36
38498.53
42391.09
46209.05
M58
M58
M58
M58
5d 2 ( 3 P)6p
4
Do
3/2
52717.46
M58
5d 2 ( 1 G)6p
2 o
5/2
62774.9
M58
Hf III ( 3 F2 )
F
J
Level (cm⫺1 )
Configuration
Limit
120000
M58
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1750
J. E. SANSONETTI AND W. C. MARTIN
Helium „He…
Atomic number⫽2
Atomic weight⫽4.002 602
Isotope
3
4
He
He
Mass
Abundance
Spin
Mag moment
3.01603
4.00260
0.000138%
99.999862%
1/2
0
⫺2.12762
Note: The spectroscopic data below are for the isotope 4He.
He I Ground state: 1s 2 1S0
Ionization energy: 198 310.669 cm⫺1 共24.587 387 eV兲
He II Ground state: 1s 2S1/2
Ionization energy: 438 908.8789 cm⫺1 共54.417 760 eV兲
Strong Lines of Helium 共He兲
Intensity
15
20
30
50
100
300
150
1000
500
10
2
3
4
5
7
10
15
20
25
35
50
100
400
1000
50
5
6
8
15
30
35
50
120
50
7
25
180
25
15
Wavelength 共Å兲
c
c
c
c
c
P
P
P
P
P
P
P
c
c
c
c
c
c
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
231.4541
232.5842
234.3472
237.3307
243.0266
256.3166
256.3177
303.7804
303.7858
320.293
505.50035
505.68433
505.91252
506.20034
506.57057
507.05802
507.71809
508.64338
509.99829
512.09856
515.61684
522.21309
537.02992
584.33436
591.41207
958.70
972.11
992.36
1025.27
1084.94
1215.09
1215.17
1640.3321
1640.3447
1640.3750
1640.3914
1640.4742
1640.4897
1640.5326
Spectrum
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
GM65
GM65
GM65
GM65
GM65
MK00b
MK00b
MK00b
MK00b
TW71
M02
M02
M02
M02
M02
M02
M02
M02
M02
M02
M02
M02
M02
M02
M02
GM65
GM65
GM65
GM65
GM65
GM65
GM65
MK00b
MK00b
MK00b
MK00b
MK00b
MK00b
MK00b
ATOMIC SPECTROSCOPIC DATA
1751
Strong Lines of Helium 共He兲—Continued
Intensity
Wavelength 共Å兲
7
9
1
12
2
10
4
10
40
20
15
1
2
1
3
2
3
1
10
1
60
200
300
20
1
50
5
12
2
3
10
3
200
25
4
3
15*
15*
12
30
4
20
100
10
5
500
250
120
8
200
3
100
60
20
50
1
2
2
Air
2385.40
2511.20
2723.19
2733.30
2763.80
2818.2
2829.08
2945.11
3013.7
3187.74
3203.10
3354.55
3447.59
3587.27
3613.64
3634.23
3705.00
3732.86
3819.607
3819.76
3888.6046
3888.6456
3888.6489
3964.729
4009.27
4026.191
4026.36
4120.82
4120.99
4143.76
4387.929
4437.55
4471.479
4471.68
4685.3769
4685.4072
4685.7038
4685.7044
4685.8041
4713.146
4713.38
4921.931
5015.678
5047.74
5411.52
5875.6148
5875.6404
5875.9663
6560.10
6678.1517
6867.48
7065.1771
7065.2153
7065.7086
7281.35
7816.15
8361.69
9063.27
c
c
c
c
P
P
P
P,c
P,c
P,c
P,c
P,c
c
P
P
P
c
P
P
P
P
Spectrum
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
II
II
I
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
I
I
I
I
I
II
I
I
I
II
I
I
I
I
I
I
I
I
I
Ref
GM65
GM65
M60a
GM65
M60a
BDD72
M60a
M60a
BDD72
M60a
GM65
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M02
M02
M02
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
MK00b
MK00b
MK00b
MK00b
MK00b
M60a
M60a
M60a
M60a
M60a
GM65
M02
M02
M02
GM65
M02
M60a
M02
M02
M02
M60a
M60a
M60a
M60a
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1752
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Helium 共He兲—Continued
Wavelength 共Å兲
Intensity
2
10
4
3
1
1
3
6
2
15
1
10
2
3
150
500
1000
9
3
4
30
20
50
20
7
10
2
12
200
1
6
500
200
100
20
500
80
10
20
3
4
Spectrum
9210.34
9463.61
9516.60
9526.17
9529.27
9603.42
9702.60
10027.73
10031.16
10123.6
10138.50
10311.23
10311.54
10667.65
10829.0911
10830.2501
10830.3398
10913.05
10917.10
11626.4
11969.12
12527.52
12784.99
12790.57
12845.96
12968.45
12984.89
15083.64
17002.47
18555.55
18636.8
18685.34
18697.23
19089.38
19543.08
20581.287
21120.07
21121.43
21132.03
30908.5
40478.90
c
P
P
P
c
c
P
c
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
He
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
I
Ref
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
M60a
GM65
M60a
M60a
M60a
M60a
M02
M02
M02
L70a
L70a
GM65
L70a
L70a
L70a
L70a
L70a
L70a
L70a
L70a
L70a
M60a
GM65
L70a
L70a
L70a
L70a
M02
L70a
L70a
L70a
GM65
L70a
Persistent Lines of Neutral Helium 共He I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
0
1
0.000
191492.7120
M02
D96
S
P
0
1
0.000
186209.3651
M02
D96
S
P
0
1
0.000
171134.8970
M02
D96
S
P
1
0
159855.9745
185564.8547
M02
D96
S
P
1
1
159855.9745
185564.5840
M02
D96
100
522.21309
2.4356
1s
1s4 p
1
400
537.02992
5.6634
1s 2
1s3 p
1
1000
584.33436
1s 2
1s2 p
1
17.989
2
Term
1 o
1 o
1 o
60
3888.6046
0.0947
1s2s
1s3 p
3
200
3888.6456
0.0947
1s2s
1s3 p
3
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3 o
3 o
ATOMIC SPECTROSCOPIC DATA
1753
Persistent Lines of Neutral Helium 共He I兲—Continued
Inten
Wavelength 共Å兲
300
3888.6489
500
5875.6148
250
5875.6404
120
5875.9663
200
6678.1517
100
7065.1771
60
7065.2153
20
7065.7086
50
150
500
1000
500
7281.3507
10829.0911
10830.2501
10830.3398
20581.287
A ki (108 s⫺1 )
0.0947
0.7070
0.5303
0.3927
0.6369
0.1547
0.0928
0.0309
0.1830
0.1022
0.1021
0.1021
0.0197
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1s2s
1s3 p
3
S
P
1
2
159855.9745
185564.5620
M02
D96
1s2p
1s3d
3 o
P
D
2
3
169086.7666
186101.5463
M02
D96
1s2 p
1s3d
3 o
P
D
1
2
169086.8430
186101.5488
M02
D96
1s2 p
1s3d
3 o
P
D
0
1
169087.8309
186101.5930
M02
D96
1s2 p
1s3d
1 o
P
D
1
2
171134.8970
186104.9668
M02
D96
1s2 p
1s3s
3 o
P
S
2
1
169086.7666
183236.7918
M02
D96
1s2 p
1s3s
3 o
P
S
1
1
169086.8430
183236.7918
M02
D96
1s2 p
1s3s
3 o
P
S
0
1
169087.8309
183236.7918
M02
D96
1s2 p
1s3s
1 o
P
S
1
0
171134.8970
184864.8294
M02
D96
1s2s
1s2 p
3
S
P
1
0
159855.9745
169087.8309
M02
D96
1s2s
1s2 p
3
S
P
1
1
159855.9745
169086.8430
M02
D96
1s2s
1s2 p
3
S
P
1
2
159855.9745
169086.7666
M02
D96
1s2s
1s2 p
1
S
P
0
1
166277.4403
171134.8970
M02
D96
3 o
3
3
3
1
3
3
3
1
3 o
3 o
3 o
1 o
Energy Levels of Neutral Helium 共He I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
1s2s
3
S
1
159855.9745
M02
1s2s
1
S
0
166277.4403
M02
1s2 p
3 o
P
2
1
0
169086.7666
169086.8430
169087.8309
M02
M02
M02
1s2 p
1 o
P
1
171134.8970
M02
1s3s
3
S
1
183236.7918
M02
1s3s
1
S
0
184864.8294
M02
1s3 p
3 o
2
1
0
185564.5620
185564.5840
185564.8547
M02
M02
M02
1s
2
P
0.000
M02
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1754
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Helium 共He I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
1s3d
3
D
3
2
1
186101.5463
186101.5488
186101.5930
M02
M02
M02
1s3d
1
D
2
186104.9668
M02
1s3p
1 o
P
1
186209.3651
M02
1s4 p
1 o
1
191492.7120
M02
Limit
198310.6691
M02
P
He II ( 2 S1/2)
Persistent Lines of Singly-ionized Helium 共He II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
1/2
3/2
0.0000
390142.5605
MK00b
BM00
S
P
1/2
1/2
0.0000
390140.8250
MK00b
BM00
S
P
1/2
3/2
0.0000
329185.1511
MK00b
BM00
Configuration
Term
300
256.3166
26.77
1s
3p
2
150
256.3177
26.77
1s
3p
2
1000
303.7804
100.27
1s
2p
2
500
303.7858
100.28
1s
2p
2
S
P
1/2
1/2
0.0000
329179.2940
MK00b
BM00
120
1640.3321
8.624
2p
3d
2 o
P
D
1/2
3/2
329179.2940
390142.5576
MK00b
BM00
50
1640.3447
3.593
2s
3p
2
S
P
1/2
3/2
329179.7623
390142.5605
MK00b
BM00
7
1640.3750
0.337
2p
3s
2 o
P
S
1/2
1/2
329179.2940
390140.9646
MK00b
BM00
25
1640.3914
3.594
2s
3p
2
S
P
1/2
1/2
329179.7623
390140.8250
MK00b
BM00
180
1640.4742
2p
3d
2 o
P
D
3/2
5/2
329185.1511
390143.1361
MK00b
BM00
25
1640.4897
1.725
2p
3d
2 o
P
D
3/2
3/2
329185.1511
390142.5576
MK00b
BM00
15
1640.5326
0.674
2p
3s
2 o
P
S
3/2
1/2
329185.1511
390140.9646
MK00b
BM00
4
4685.3769
0.939
3p
4d
2 o
P
D
1/2
3/2
390140.8250
411477.8537
MK00b
BM00
3
4685.4072
0.491
3s
4p
2
S
P
1/2
3/2
390140.9646
411477.8550
MK00b
BM00
15*
4685.7038
2.060
3d
4f
2
D
F
3/2
5/2
390142.5576
411478.0973
MK00b
BM00
15*
4685.7044
1.126
3p
4d
2 o
P
D
3/2
5/2
390142.5605
411478.0978
MK00b
BM00
12
4685.8041
2.207
3d
4f
2
D
F
5/2
7/2
390143.1361
411478.2193
MK00b
BM00
10.35
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2 o
2 o
2 o
2 o
2
2 o
2
2 o
2
2
2
2
2 o
2 o
2
2 o
ATOMIC SPECTROSCOPIC DATA
1755
Energy Levels of Singly-ionized Helium 共He II兲
Ref
Term
1s
2
S
1/2
0.0000
MK00b
2p
2 o
P
1/2
3/2
329179.2940
329185.1511
MK00b
MK00b
2s
2
S
1/2
329179.7623
MK00b
3p
2 o
P
1/2
3/2
390140.8250
390142.5605
MK00b
MK00b
3s
2
S
1/2
390140.9646
MK00b
3d
2
D
3/2
5/2
390142.5576
390143.1361
MK00b
MK00b
4p
2 o
P
1/2
3/2
411477.1228
411477.8550
MK00b
MK00b
4s
2
S
1/2
411477.1818
MK00b
4d
2
D
3/2
5/2
411477.8537
411478.0978
MK00b
MK00b
4f
2 o
5/2
7/2
411478.0973
411478.2193
MK00b
MK00b
Limit
438908.8789
MK00b
He
F
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1756
J. E. SANSONETTI AND W. C. MARTIN
Holmium „Ho…
Atomic number⫽67
Atomic weight⫽164.930 32
Isotope
165
Ho
Mass
Abundance
Spin
164.93032
100%
7/2
Mag moment
o
Ho I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 116s 2 4I15/2
⫺1
Ionization energy: 48 567 cm 共6.0215 eV兲
o
)6s (15/2,1/2) o8
Ho II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 11( 4 I15/2
⫺1
Ionization energy: 95 200 cm 共11.80 eV兲
Strong Lines of Holmium 共Ho兲
Intensity
30
40
25
25
25
30
25
30
30
60
25
50
40
25
50
25
50
25
25
25
25
60
25
40
25
60
500
50
25
90
300
80
120
120
40
40
200
50
1000
100
50
Wavelength 共Å兲
c
c
c
c
c
c
c
c
d,l
c
c
c
c
c
c
c
P,c
c
c
c
P
c
c
c
P
c
P,c
c
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2880.98
2909.41
2973.00
2979.63
2987.64
3049.38
3054.00
3057.45
3082.34
3084.36
3086.54
3118.50
3166.62
3171.72
3173.78
3174.84
3181.50
3183.84
3197.83
3201.76
3278.15
3281.97
3288.46
3337.23
3338.86
3343.58
3398.95
3410.26
3410.65
3414.90
3416.44
3421.63
3425.34
3428.13
3429.18
3449.35
3453.11
3455.70
3456.02
3461.97
3473.91
Spectrum
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
Ref.
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MCS75
MCS75
MCS75
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MCS75
MZH78
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1757
Strong Lines of Holmium 共Ho兲—Continued
Intensity
300
400
30
40
150
50
25
90
250
25
40
100
70
25
25
40
90
25
25
40
70
40
30
20
50
25
30
25
25
200
50
80
150
50
30
80
80
80
25
70
40
50
30
40
50
50
120
40
90
200
40
600
600
60
60
40
25
80
25
P,c
P
c
c
c
c
P,c
c
c
c
c
c
c,w
c
c
c
c
c
c
c
P,c,w
P,c
P,c
c
P
c
c,w
c
Wavelength 共Å兲
3474.25
3484.80
3489.58
3493.09
3494.76
3498.88
3506.95
3510.73
3515.56
3519.94
3540.76
3546.05
3556.78
3560.15
3573.24
3574.80
3579.12
3580.75
3581.83
3592.23
3598.77
3599.48
3600.95
3613.31
3618.43
3626.69
3627.25
3631.76
3638.30
3662.29
3662.99
3666.65
3667.97
3669.52
3674.77
3679.19
3679.70
3682.65
3685.16
3690.65
3691.95
3700.04
3702.35
3709.76
3712.88
3720.72
3731.40
3732.09
3736.35
3748.17
3769.09
3796.75
3810.74
3811.86
3813.25
3829.27
3835.35
3837.51
3842.05
Spectrum
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
I
II
II
II
II
I
I
I
I
I
II
I
I
I
II
I
I
I
II
I
I
I
I
I
I
II
I
II
II
I
II
I
II
II
II
Ref.
MZH78
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1758
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Holmium 共Ho兲—Continued
Intensity
Wavelength 共Å兲
70
30 c
30
110 c
25 c,w
40
150 c
60
40
30
200 P,c
60
800 P,c
30
40
80 c,w
40
40
25
25
70
60
25
40 c
40
25
40
30
25
300 P
300 P,c
25 c
900 P
30
30
25
110
80
30
30
30
25
25
1000 P
30
300 P
30
30
150
150
500 P
30
150
25
30
60 c,w
900 P
300 P
60
3843.86
3846.73
3849.88
3854.07
3856.94
3857.72
3861.68
3862.62
3874.68
3881.61
3888.96
3890.42
3890.94
3896.76
3904.44
3905.68
3911.80
3919.45
3938.85
3950.56
3955.73
3959.68
3975.88
3976.93
3999.58
4003.39
4027.21
4028.86
4037.62
4040.81
4045.47
4047.52
4053.87
4054.48
4057.55
4060.31
4065.09
4068.05
4071.83
4073.13
4073.51
4083.67
4100.22
4103.80
4106.50
4108.62
4112.00
4116.73
4120.20
4125.65
4127.16
4134.54
4136.22
4142.19
4148.97
4152.61
4163.03
4173.20
4194.35
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
II
II
I
II
II
II
II
I
II
II
II
I
II
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
Ref.
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MCS75
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MZH78
MCS75
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MCS75
MZH78
MCS75
MCS75
MCS75
MCS75
MZH78
MCS75
MCS75
MCS75
MCS75
MCS75
MZH78
MZH78
MCS75
ATOMIC SPECTROSCOPIC DATA
1759
Strong Lines of Holmium 共Ho兲—Continued
Wavelength 共Å兲
Intensity
30
30
200
25
30
150
60
30
150
30
25
25
30
15
Spectrum
4222.29
4223.47
4227.13
4229.52
4243.78
4254.38
4264.05
4266.04
4350.73
4939.01
4979.97
5982.85
6604.91
7555.09
P
P,c,w
P
P
P,c
P
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
Ho
I
I
I
II
I
I
I
I
I
I
I
I
I
I
Ref.
MCS75
MCS75
MZH78
MCS75
MCS75
MZH78
MCS75
MCS75
MZH78
MZH78
MCS75
MZH78
MZH78
MCS75
Persistent Lines of Neutral Holmium 共Ho I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
300
4040.81
0.373
4 f 116s 2
4 f 105d6s 2
4 o
I
15/2
13/2
0.00
24740.52
MZH78
M00
900
4053.87
1.62
4 f 116s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I15/2
4 o
I
共15/2,1兲
15/2
15/2
0.00
24660.80
MZH78
M00
1000
4103.80
1.55
4 f 116s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I15/2
4 o
I
共15/2,1兲
15/2
17/2
0.00
24360.81
MZH78
M00
300
4108.62
2.0
4 f 116s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I13/2
4 o
I
共13/2,1兲
13/2
13/2
5419.70
29751.91
MZH78
HWL99
500
4127.16
2.1
4 f 116s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I13/2
4 o
I
共13/2,1兲
13/2
15/2
5419.70
29642.60
MZH78
HWL99
900
4163.03
0.897
4 f 116s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I15/2
4 o
I
共15/2,1兲
15/2
13/2
0.00
24014.22
MZH78
M00
300
4173.20
0.258
4 f 116s 2
o
)6s6p( 3 Po2 )
4 f 11( 4 I13/2
4 o
I
共13/2,2兲
15/2
13/2
0.00
23955.69
MZH78
M00
200
4227.13
1.1
4 f 116s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I13/2
4 o
I
共13/2,1兲
13/2
11/2
5419.70
29069.78
MZH78
HWL99
150
4254.38
0.115
4 f 116s 2
o
)6s6p( 3 Po2 )
4 f 11( 4 I13/2
4 o
I
共13/2,2兲
15/2
17/2
0.00
23498.57
MZH78
M00
150
4350.73
0.089
4 f 116s 2
4 f 10( 5 I5 )5d 5/26s 2
4 o
I
共5,5/2兲
15/2
13/2
0.00
22978.19
MZH78
M00
30
4939.01
0.026
4 f 116s 2
4 f 10( 5 I6 )5d 5/26s 2
4 o
I
共6,5/2兲
15/2
13/2
0.00
20241.31
MZH78
M00
25
5982.85
0.0093
4 f 116s 2
o
)6s6p( 3 Po1 )
4 f 11( 4 I15/2
4 o
I
共15/2,1兲
15/2
17/2
0.00
16709.82
MZH78
M00
30
6604.91
4 f 116s 2
4 f 10( 5 I7 )5d 3/26s 2
4 o
15/2
15/2
0.00
15136.06
MZH78
Configuration
Term
I
共7,3/2兲
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1760
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Holmium 共Ho I兲
J
Level (cm⫺1 )
Ref
4 o
15/2
13/2
11/2
9/2
0.00
5419.70
8605.16
10695.75
MZH78
MZH78
MZH78
MZH78
4 f 10( 5 I8 )5d 3/26s 2
共8,3/2兲
17/2
15/2
13/2
19/2
8378.91
8427.11
9147.08
9741.50
MZH78
MZH78
MZH78
MZH78
4 f 10( 5 I8 )5d 5/26s 2
共8,5/2兲
21/2
17/2
19/2
15/2
11/2
11322.31
11530.56
11689.77
12339.04
16937.43
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 10( 5 I7 )5d 3/26s 2
共7,3/2兲
13/2
11/2
17/2
15/2
12344.55
13082.93
15130.31
15136.06
MZH78
MZH78
MZH78
MZH78
4 f 116s 2
4 o
9/2
13094.42
KWL97
4 f 10( 5 I)5d6s 2
13/2
15081.12
MZH78
4 f 10( 5 I)5d6s 2
11/2
15792.13
MZH78
15/2
15855.28
MZH78
15/2
16154.21
MZH78
Configuration
11
4 f 6s
2
o
)6s6p( 3 Po0 )
4 f 11( 4 I15/2
Term
I
F
共15/2,0兲
4 f 105d6s 2
4 f 10( 5 I7 )5d 5/26s 2
共7,5/2兲
17/2
16438.01
MZH78
4 f 10( 5 I7 )5d 5/26s 2
共7,5/2兲
19/2
16683.52
MZH78
o
)6s6p( 3 Po1 )
4 f 11( 4 I15/2
共15/2,1兲
17/2
15/2
13/2
16709.82
16882.28
17059.35
MZH78
MZH78
MZH78
4 f 10( 5 I6 )5d 5/26s 2
共6,5/2兲
13/2
20241.31
MZH78
4 f 10( 5 I5 )5d 5/26s 2
共5,5/2兲
13/2
22978.19
MZH78
o
)6s6p( 3 Po2 )
4 f 11( 4 I13/2
共13/2,2兲
17/2
15/2
9/2
11/2
13/2
7/2
23498.57
23834.94
23861.17
23946.16
23955.69
—
MZH78
MZH78
MZH78
MZH78
MZH78
o
)6s6p( 1 Po1 )
4 f 11( 4 I15/2
共15/2,1兲
13/2
17/2
15/2
24014.22
24360.81
24660.80
MZH78
MZH78
MZH78
13/2
24740.52
MZH78
11/2
15/2
13/2
29069.78
29642.60
29751.91
MZH78
MZH78
MZH78
Limit
48567
WSPC78
4 f 105d6s 2
o
)6s6p( 1 Po1 )
4 f 11( 4 I13/2
o
)6s (15/2 ,1/2) o8
Ho II ( 4 I15/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
共13/2,1兲
ATOMIC SPECTROSCOPIC DATA
1761
Persistent Lines of Singly-ionized Holmium 共Ho II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
0.635
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
o
)6s 1/2
4 f 11( 4 I15/2
o
4 f 11( 4 I15/2
)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
8
8
0.00
29412.38
MZH78
M00
500
3398.95
300
3416.44
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
7
7
637.40
29899.21
MZH78
200
3453.11
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
7
6
637.40
29588.49
MZH78
1000
3456.02
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
8
9
0.00
28926.70
MZH78
300
3474.25
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
7
8
637.40
29412.38
MZH78
400
3484.80
o
)6s 1/2
4 f 11( 4 I15/2
(15/2,1/2) o
7
7
637.40
29325.2
MZH78
250
3515.56
o
)6s 1/2
4 f 11( 4 I15/2
(15/2,1/2) o
7
6
637.40
29074.26
MZH78
200
3748.17
600
3796.75
600
0.487
M00
MCS75
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 1/2
(15/2,1/2) o
共15/2,1/2兲
8
8
0.00
26330.85
MZH78
3810.74
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 1/2
(15/2,1/2) o
共15/2,1/2兲
8
7
0.00
26234.19
MZH78
200
3888.96
o
)6s 1/2
4 f 11( 4 I13/2
o
4 f 11( 4 I13/2
)6p 1/2
(13/2,1/2) o
共13/2,1/2兲
6
7
5849.74
31556.3
MZH78
800
3890.94
o
)6s 1/2
4 f 11( 4 I15/2
11 4 o
4 f ( I15/2)6p 1/2
(15/2,1/2) o
共15/2,1/2兲
7
8
637.40
26330.85
MZH78
300
4045.47
o
)6s 1/2
4 f 11( 4 I15/2
(15/2,1/2) o
8
7
0.00
24712.0
MZH78
0.430
0.699
M00
M00
Energy Levels of Singly-ionized Holmium 共Ho II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
o
)6s 1/2
4 f 11( 4 I15/2
(15/2 ,1/2) o
8
7
0.00
637.40
MZH78
MZH78
o
)6s 1/2
4 f 11( 4 I13/2
(13/2 ,1/2) o
7
6
5617.04
5849.74
MZH78
MZH78
o
)6s 1/2
4 f 11( 4 I11/2
(11/2 ,1/2) o
5
6
8850.55
9001.65
MZH78
MZH78
o
)6s 1/2
4 f 11( 4 I9/2
(9/2 ,1/2) o
4
5
10838.85
11204.50
MZH78
MZH78
o
)5d 3/2
4 f 11( 4 I15/2
(15/2 ,3/2) o
6
7
9
8
16281.60
16748.98
17713.75
18404.87
MZH78
MZH78
MZH78
MZH78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1762
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Holmium 共Ho II兲—Continued
Configuration
o
)5d 5/2
4 f 11( 4 I15/2
Term
(15/2 ,5/2)
o
o
J
Level (cm⫺1 )
Ref
10
9
5
8
6
7
18258.95
19111.47
19882.92
20029.35
20314.90
20492.00
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
5
19000.54
MZH78
7,8
21688.7
MZH78
7
24712.0
MZH78
7,8
26008.3
MZH78
o
)6p 1/2
4 f 11( 4 I15/2
共15/2 ,1/2兲
7
8
26234.19
26330.85
MZH78
MZH78
o
)6p 3/2
4 f 11( 4 I15/2
共15/2 ,3/2兲
9
8
6
7
28926.70
29412.38
29588.49
29899.21
MZH78
MZH78
MZH78
MZH78
6
29074.26
MZH78
7,8
29275.0
MZH78
7,8
29325.2
MZH78
7
29810.85
MZH78
7,8
30884.7
MZH78
6
7
31505.0
31556.3
MZH78
MZH78
95200
MZH78
o
)6p 1/2
4 f 11( 4 I13/2
共13/2 ,1/2兲
o
)
Ho III ( 4 I15/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1763
Hydrogen „H…
Atomic number⫽1
Atomic weight⫽1.007 94
Isotope
1
2
H
H
Mass
Abundance
Spin
Mag moment
1.007825
2.0140
99.985%
0.015%
1/2
1
⫹2.79284
⫹0.85743
Notes: The wavelengths and energy levels given below are for the isotope 1H.
Although the tabulated energy levels comprise values for each level through n⫽5, we give 共Ritz兲 wavelengths for resolved fine
structures only for the Lyman-alpha, Balmer-alpha, and Balmer-beta lines 共1215, 6562, and 4861 Å兲. As indicated by the
energy-level notations in the persistent-lines table, the other wavelengths represent unresolved multiplets. These wavelengths
are from the corresponding weighted-average energies.
H I Ground state: 1s 2S1/2
Ionization energy: 109 678.7717 cm⫺1 共13.598 433 eV兲
Strong Lines of Hydrogen 共H兲
Intensity
15
20
30
50
100
300
1000
500
5
6
8
15
30
30
10
60
90
30
180
5
7
12
20
40
5
8
15
4
6
3
P
P
P
P
P
P
P
P
P
P
P
P
P
P,c
Wavelength 共Å兲
Vacuum
926.2256
930.7482
937.8034
949.7430
972.5367
1025.7222
1215.66824
1215.67364
Air
3835.384
3889.049
3970.072
4101.74
4340.462
4861.2786
4861.2870
4861.3615
6562.7110
6562.7248
6562.8518
9545.97
10049.4
10938.1
12818.07
18751.01
21655.3
26251.5
40511.6
46525.1
74578
123685
Spectrum
Ref
H
H
H
H
H
H
H
H
I
I
I
I
I
I
I
I
MK00a
MK00a
MK00a
MK00a
MK00a
MK00a
MK00a
MK00a
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
H
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
RCWM80
RCWM80
RCWM80
RCWM80
MK00a
MK00a
MK00a
MK00a
MK00a
MK00a
MK00a
RCWM80
RCWM80
RCWM80
MK00a
MK00a
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1764
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Hydrogen 共H I兲
Inten
50
100
300
1000
500
Wavelength 共Å兲
949.7430
972.5367
1025.7222
1215.66824
1215.67364
A ki (108 s⫺1 )
0.34375
0.6819
1.6725
6.2648
6.2649
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
1/2
1/2,3/2
0.0000
105291.6443
MK00a
BM00
S
P
1/2
1/2,3/2
0.0000
102823.8791
MK00a
BM00
S
P
1/2
1/2,3/2
0.0000
97492.2835
MK00a
BM00
S
P
1/2
3/2
0.0000
82259.2850
MK00a
BM00
S
P
1/2
1/2
0.0000
82258.9191
MK00a
BM00
82259.1109
105291.6587
MK00a
WSG66
Configuration
Term
1s
5p
2
1s
4p
2
1s
3p
2
1s
2p
2
1s
2p
2
2 o
2 o
2 o
2 o
2 o
30
4340.462
0.0253
2s,p
5s,p,d, f ,g
30
4861.2786
0.1719
2p
4d
2 o
2s
4p
2
10
60
90
30
180
4861.2870
4861.3615
6562.7110
6562.7248
6562.8518
0.0967
0.2063
0.5388
0.2245
0.6465
P
D
1/2
3/2
82258.9191
102823.8942
MK00a
BM00
S
P
1/2
3/2
82258.9544
102823.8943
MK00a
BM00
2p
4d
2 o
P
D
3/2
5/2
82259.2850
102823.9095
MK00a
BM00
2p
3d
2 o
P
D
1/2
3/2
82258.9191
97492.3195
MK00a
BM00
2s
3p
2
S
P
1/2
3/2
82258.9544
97492.3196
MK00a
BM00
2p
3d
2 o
3/2
5/2
82259.2850
97492.3556
MK00a
BM00
2
2 o
2
2
2 o
2
P
D
20
12818.07
0.0220
3s,p,d
5s,p,d, f ,g
97492.3087
105291.6587
MK00a
WSG66
40
18751.01
0.0899
3s, p,d
4s,p,d, f
97492.3087
102823.9002
MK00a
WSG66
Energy Levels of Neutral Hydrogen 共H I兲
Ref
Term
1s
2
S
1/2
0.0000
MK00a
2p
2 o
P
1/2
3/2
82258.9191
82259.2850
MK00a
MK00a
2s
2
S
1/2
82258.9544
MK00a
3p
2 o
P
1/2
3/2
97492.2112
97492.3196
MK00a
MK00a
3s
2
S
1/2
97492.2217
MK00a
3d
2
D
3/2
5/2
97492.3195
97492.3556
MK00a
MK00a
4p
2 o
1/2
3/2
102823.8486
102823.8943
MK00a
MK00a
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
ATOMIC SPECTROSCOPIC DATA
1765
Energy Levels of Neutral Hydrogen 共H I兲—Continued
J
Level (cm⫺1 )
Ref
S
1/2
102823.8530
MK00a
D
3/2
5/2
102823.8942
102823.9095
MK00a
MK00a
4f
2 o
F
5/2
7/2
102823.9095
102823.9171
MK00a
MK00a
5p
2 o
P
1/2
3/2
105291.6287
105291.6521
MK00a
MK00a
5s
2
S
1/2
105291.6309
MK00a
5d
2
D
3/2
5/2
105291.6520
105291.6599
MK00a
MK00a
5f
2 o
F
5/2
7/2
105291.6598
105291.6637
MK00a
MK00a
5g
2
G
7/2
9/2
105291.6637
105291.6661
MK00a
MK00a
Limit
109678.7717
MK00a
Configuration
Term
4s
2
4d
2
H
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1766
J. E. SANSONETTI AND W. C. MARTIN
Indium „In…
Atomic number⫽49
Atomic weight⫽114.82
Isotope
113
115
In
In
Mass
Abundance
Spin
Mag moment
112.904061
114.903800
4.3%
95.7%
9/2
9/2
⫹5.5229
⫹5.534
o
In I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 2P1/2
⫺1
Ionization energy: 46 670.11 cm 共5.786 36 eV兲
In II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 1S0
Ionization energy: 152 199 cm⫺1 共18.8703 eV兲
Strong Lines of Indium 共In兲
Intensity
Wavelength 共Å兲
20 P
14 P,w
14 P,w
6P
6P
11 P
14 P
6 P,c
1
2
3
2h
6
9 P,d
60 P
11
90 P
15
40 P
2
10 c
2c
7 P,d
60 P
6P
1c
400 P
700 P
150 P
20 w
13 c
14 c
11 c
14 w
25 w
900 P
1000 P
14 c
20 c
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1586.340
1711.1
1757.3
1936.217
1966.711
1977.359
Air
2078.608
2306.046
2306.86
2389.54
2460.08
2468.02
2521.37
2554.434
2560.150
2601.76
2710.265
2713.94
2753.878
2775.37
2836.92
2858.14
2890.179
2932.630
2941.050
2957.01
3039.356
3256.089
3258.565
3716.14
3799.21
3834.65
3842.18
3962.35
4056.94
4101.7504
4511.2972
4620.14
4638.16
Spectrum
Ref
In
In
In
In
In
In
II
I
I
II
II
II
SM02
G54
G54
B69
B69
B69
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
II
II
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
II
II
II
II
II
II
I
I
II
II
SM02
PC38,B69
P38
P38
P38
P38
P38
PC38
P38
P38
P38
P38
P38
P38
P38
P38
PC38
P38
PC38
P38
P38
P38
P38
PC38
PC38
PC38
PC38
PC38
PC38
DMZ53
DMZ53
PC38
PC38
ATOMIC SPECTROSCOPIC DATA
1767
Strong Lines of Indium 共In兲—Continued
Wavelength 共Å兲
Intensity
12 c
20 c
20 w
25 w
15 c
11 w
13 c
12 w
20 c
14 w
13 c
11 w
3
3
12 c
25 w
14 w
14 c
12 c
13 w
13 w
20 w
15 w
15 w
15 w
15 w
12 c
20 P,w
20 P,w
12 c
20 c
12 c
13 c
12 w
3h
6
11
3h
6h
1P
1P
Spectrum
4644.58
4655.62
4656.74
4684.8
5120.80
5121.75
5175.42
5436.70
5513.00
5523.28
5576.90
5636.70
5709.91
5727.68
5853.15
5903.4
5915.4
6095.95
6108.66
6128.7
6129.4
6132.1
6228.3
6304.8
6362.3
6469.0
6541.20
6891.56
7182.89
7276.5
7350.6
7740.7
8227.0
9213.0
9370.27
9977.86
10257.03
10717.42
10744.31
12912.59
13429.96
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
In
Ref
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
P38
P38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
PC38
JL67
JL67
JL67
JL67
JL67
JL67
JL67
Persistent Lines of Neutral Indium 共In I兲
Inten
14
14
60
90
Wavelength
共Å兲 A ki (108 s⫺1 )
1711.1
1757.3
2560.150
2710.265
0.20
0.27
J
Level (cm⫺1 )
P
P
3/2
3/2
2212.598
60654
G54
5p
5s5 p 2
2 o
P
S
1/2
1/2
0.000
56905
G54
5p
6d
2 o
P
D
1/2
3/2
0.000
39048.53
P38
M00
5p
6d
2 o
3/2
5/2
2212.598
39098.38
P38
M00
Configuration
Term
5p
5s5 p 2
2 o
2
2
2
2
P
D
Wl Ref
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1768
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Indium 共In I兲—Continued
Inten
Wavelength
40
2753.878
60
0.23
3039.356
700
1.11
3256.089
150
1.30
3258.565
900
0.30
4101.7504
1000
1
0.13
2932.630
400
1
共Å兲 A ki (108 s⫺1 )
0.50
4511.2972
0.89
12912.59
13429.96
J
Level (cm⫺1 )
P
S
1/2
1/2
5p
7s
2 o
P
S
5p
5d
2 o
Configuration
Term
5p
7s
2 o
Wl Ref
A Ref
0.000
36301.84
P38
M00
3/2
1/2
2212.598
36301.84
P38
M00
P
D
1/2
3/2
0.000
32892.21
P38
M00
5p
5d
2 o
P
D
3/2
5/2
2212.598
32915.54
P38
M00
5p
5d
2 o
P
D
3/2
3/2
2212.598
32892.21
P38
M00
5p
6s
2 o
P
S
1/2
1/2
0.000
24372.956
DMZ53
M00
5p
6s
2 o
P
S
3/2
1/2
2212.598
24372.956
DMZ53
M00
6s
6p
2
S
P
1/2
3/2
24372.956
32115.22
JL67
6s
6p
2
S
P
1/2
1/2
24372.956
31816.96
JL67
2
2
2
2
2
2
2
2 o
2 o
Energy Levels of Neutral Indium 共In I兲
J
Level (cm⫺1 )
Ref
5p
2 o
P
1/2
3/2
0.000
2212.598
JL67,DMZ53
JL67,DMZ53
6s
2
S
1/2
24372.956
JL67,DMZ53
6p
2 o
P
1/2
3/2
31816.96
32115.22
JL67
JL67
5d
2
D
3/2
5/2
32892.21
32915.54
JL67
JL67
5s5p 2
4
P
1/2
3/2
5/2
34977.68
36020.82
37451.94
P38
P38
P38
7s
2
S
1/2
36301.84
JL67
6d
2
D
3/2
5/2
39048.53
39098.38
JL67
JL67
Limit
46670.11
ND81,JL67
Configuration
Term
In II ( 1 S0 )
5s5 p 2
2
1/2
56905
G54
5s5p 2
2
1/2
3/2
59657
60654
G54
G54
S
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1769
Persistent Lines of Singly-ionized Indium 共In II兲
Inten
Wavelength 共Å兲
1000
250
250
500
600
250
400
300
250
800
1000
1586.340
A ki (108 s⫺1 )
12.2
1936.217
1966.711
12.9
1977.359
2078.608
2306.046
0.023
2554.434
0.01
2890.179
2941.050
1.4
6891.56
7182.89
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1
S
P
0
1
0.0
63038.18
SM02
C00
5s5 p
5s6s
3 o
P
S
0
1
42276.4
93923.40
B69
5s5 p
5s5d
1 o
P
D
1
2
63038.18
113884.44
B69
5s5 p
5s6s
3 o
P
S
1
1
43350.9
93923.40
B69
5s5 p
5s6s
3 o
P
S
2
1
45829.6
93923.40
SM02
S
P
0
1
0.0
43350.9
PC38
C00
5s5 p
5s5d
1 o
P
D
1
2
63038.18
102174.00
PC38
C00
5s5 p
5p 2
1 o
P
D
1
2
63038.18
97627.98
PC38
5s5 p
5s6s
1 o
P
S
1
0
63038.18
97029.73
PC38
5s6s
5s6p
3
S
P
1
2
93923.40
108429.89
PC38
5s6s
5s6p
3
S
P
1
1
93923.40
107841.54
PC38
Configuration
2
5s
5s5p
1 o
3
1
3
3
5s 2
5s5p
1
3 o
3
1
1
3 o
3 o
C00
FW96
Energy Levels of Singly-ionized Indium 共In II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
5s 2
1
S
0
0.0
SM02
5s5p
3 o
P
0
1
2
42276.4
43350.9
45829.6
SM02
SM02
SM02
5s5 p
1 o
P
1
63038.18
SM02
5s6s
3
S
1
93923.40
SM02
5s6s
1
S
0
97029.73
SM02
5p 2
1
2
97627.98
SM02
2
3
P
0
1
2
101607.7
103248.84
105564.56
SM02
SM02
SM02
5s5d
3
D
1
2
3
102088.00
102174.00
102307.60
SM02
SM02
SM02
5s6p
3 o
0
1
2
107662.24
107841.54
108429.89
SM02
SM02
SM02
5p
D
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1770
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Indium 共In II兲—Continued
J
Level (cm⫺1 )
5s6 p
1 o
P
1
109779.76
SM02
5s5d
1
D
2
113884.44
SM02
5p 2
1
0
121289.08
SM02
152199
SM02
Configuration
Term
S
In III ( 2 S1/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
Ref
ATOMIC SPECTROSCOPIC DATA
1771
Iodine „I…
Atomic number⫽53
Atomic weight⫽126.904 47
Isotope
Mass
Abundance
Spin
Mag moment
127
126.904473
100%
5/2
⫹2.808
I
I I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 5 2P3/2
Ionization energy: 84 295.14 cm⫺1 共10.451 26 eV兲
I II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 4 3P2
Ionization energy: 154 304 cm⫺1 共19.1313 eV兲
Strong Lines of Iodine 共I兲
Intensity
100
200
500
100
150
250
120
200
100
500
500
1000
250
500
800
500
250
400
1000
1000
40
40
130
40
40
40
1000
70
40
70
40
50
40
110
70
70
P
P
P
P
P
P
P
P
P
P
70
130 P
50
70
Wavelength 共Å兲
Vacuum
879.84
1018.58
1034.66
1066.34
1075.21
1105.00
1111.16
1125.25
1131.50
1139.80
1160.56
1166.48
1175.84
1178.65
1187.34
1190.85
1198.88
1200.22
1220.89
1234.06
1259.51
1289.40
1300.34
1302.98
1313.95
1317.54
1336.52
1355.10
1357.97
1360.97
1361.11
1383.23
1390.75
1425.49
1446.26
1453.18
1457.39
1457.47
1457.98
1459.15
1492.89
Spectrum
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
KC59
KC59
KC59
KC59
KC59
KC59
MC60
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1772
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Iodine 共I兲—Continued
Wavelength 共Å兲
Intensity
70
70
200
70
70
200
150
70
1000
200
25
100
250
130
150
150
500
250
150
100
500
100
200
250
100
100
70
200
70
70
130
50
130
40
70
200
150
50
40
40
70
70
Spectrum
1507.04
1514.68
1518.05
1593.58
1617.60
1702.07
1782.76
1799.09
1830.38
1844.45
Air
2061.63
2582.79
3078.75
5119.29
5161.20
5245.71
5338.22
5345.15
5435.83
5464.62
5625.69
5690.91
5710.53
5950.25
6074.98
6127.49
6619.66
6812.57
7402.06
7468.99
8043.74
8240.05
8393.30
8857.50
9022.40
9058.33
9113.91
9426.71
9427.15
9653.06
9731.73
10466.54
P
P
P
P
P
P
P
P,c
c
P
P,c
P,c
P
c
c
c
c
P
c
P
d
Ref
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
KC59
MC60
MC60
KC59
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
MC60
KC59
MC60
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
KC59
Persistent Lines of Neutral Iodine 共I I兲
Inten
130
200
200
150
Wavelength 共Å兲
A ki (108 s⫺1 )
5
1457.98
1518.05
1702.07
1782.76
Configuration
2.05
2.71
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Term
2 o
5p
5 p 4 ( 1 D2 )6s
2
5p 5
5 p 4 ( 3 P1 )5d
2
5p 5
5 p 4 ( 3 P2 )5d
2
5p 5
5 p 4 ( 3 P2 )6s
2
P
关2兴
2 o
P
关1兴
2 o
P
关1兴
2 o
P
关2兴
J
Level (cm⫺1 )
3/2
5/2
0.00
68587.87
KC59
1/2
1/2
7603.15
73477.24
KC59
1/2
3/2
7603.15
66355.10
KC59
M00
3/2
3/2
0.00
56092.88
KC59
FW96
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1773
Persistent Lines of Neutral Iodine 共I I兲—Continued
Inten
Wavelength 共Å兲
1000
200
25
130
130
200
1830.38
1844.45
2061.63
A ki (108 s⫺1 )
0.16
0.070
0.030
5119.29
8043.74
9058.33
Configuration
5
J
Level (cm⫺1 )
Wl Ref
A Ref
3/2
5/2
0.00
54633.46
KC59
FW96
1/2
3/2
7603.15
61819.76
KC59
M00
P
关2兴
1/2
3/2
7603.15
56092.88
KC59
M00
关2兴
关1兴
3/2
3/2
56092.88
75621.41
KC59
关2兴
关1兴o
5/2
3/2
54633.46
67062.09
KC59
关2兴
关3兴o
5/2
7/2
54633.46
65669.99
KC59
Term
2 o
5p
5 p 4 ( 3 P2 )6s
2
5p 5
5 p 4 ( 3 P1 )6s
2
5p 5
5 p 4 ( 3 P2 )6s
2
P
关2兴
2 o
P
关1兴
2 o
5p 4 ( 3 P2 )6s
5 p 4 ( 3 P2 )7p
2
5p 4 ( 3 P2 )6s
5 p 4 ( 3 P2 )6p
2
5p 4 ( 3 P2 )6s
5 p 4 ( 3 P2 )6p
2
2
2
2
Energy Levels of Neutral Iodine 共I I兲
Configuration
5p
5
J
Level (cm⫺1 )
Ref
P
3/2
1/2
0.00
7603.15
M62
M62
Term
2 o
5 p 4 ( 3 P2 )6s
2
关2兴
5/2
3/2
54633.46
56092.88
M62
M62
5 p 4 ( 3 P0 )6s
2
关0兴
1/2
60896.23
M62
5 p ( P1 )6s
2
关1兴
3/2
1/2
61819.76
63186.75
M62
M62
5 p 4 ( 3 P2 )6p
2
关2兴o
5/2
3/2
64906.31
64990.00
M62
M62
5 p 4 ( 3 P2 )6p
2
关3兴o
5/2
7/2
65644.49
65669.99
M62
M62
5 p 4 ( 3 P2 )6p
2
关1兴o
1/2
3/2
65856.96
67062.09
M62
M62
5 p 4 ( 3 P2 )5d
2
关1兴
3/2
1/2
66355.10
67298.33
M62
M62
5 p 4 ( 1 D2 )6s
2
关2兴
3/2
5/2
68549.75
68587.87
M62
M62
5 p 4 ( 3 P1 )6p
2
关0兴o
1/2
71501.47
M62
5 p 4 ( 3 P0 )6p
2
关1兴o
1/2
3/2
71813.90
71976.72
M62
M62
5 p 4 ( 3 P1 )6p
2
关2兴o
5/2
3/2
72529.16
72807.13
M62
M62
5 p 4 ( 3 P1 )6p
2
关1兴o
3/2
1/2
73054.54
73387.15
M62
M62
5 p 4 ( 3 P 1 )5d
2
关1兴
1/2
3/2
73477.24
74587.42
M62
M62
4 3
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1774
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Iodine 共I I兲—Continued
Term
J
Level (cm⫺1 )
Ref
5 p ( P2 )7p
2
关1兴
1/2
3/2
75303.13
75621.41
M62
M62
5 p 4 ( 1 D2 )6p
2
关1兴o
3/2
1/2
78415.25
79701.59
M62
M62
5 p 4 ( 1 D2 )6p
2
关3兴o
5/2
7/2
78592.55
79003.61
M62
M62
5 p 4 ( 1 D2 )6p
2
关2兴o
3/2
5/2
80039.82
80125.45
M62
M62
Limit
84295.14
M62
Configuration
4 3
I II ( 3 P2 )
Persistent Lines of Singly-ionized Iodine 共I II兲
Inten
Wavelength 共Å兲
1000
800
1000
1000
1000
150
500
250
500
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
3
2
3
0.0
85727.98
MC60
2
1
0.0
84222.19
MC60
2
2
0.0
81907.83
MC60
2
2
0.0
81032.70
MC60
P
P
1
2
7087.0
81907.83
MC60
5p 3 ( 4 S)6s
5 p 3 ( 4 S)6p
5 o
S
P
2
3
81032.70
100402.68
MC60
5p 3 ( 2 Do)6s
5 p 3 ( 2 Do)6p
3
Do
F
2
3
93691.35
112419.04
MC60
5p 3 ( 2 Do)6s
5 p 3 ( 2 Do)6p
3
Do
F
3
4
96650.55
115353.94
MC60
5p 3 ( 4 S)6s
5 p 3 ( 4 S)6p
3 o
1
2
84842.87
102613.52
MC60
Configuration
4
1166.48
5p
5p 3 ( 4 S)5d
5p 4
5s5 p 5
1187.34
3
P
P
3
P
P
3 o
5p 4
5p 3 ( 4 S)6s
1234.06
3
P
S
5 o
5p 4
5s5 p 5
1336.52
5161.20
5338.22
5345.15
5625.69
P
Do
3 o
5p 4
5s5 p 5
1220.89
5
3
3 o
5
3
3
3
S
P
A Ref
Energy Levels of Singly-ionized Iodine 共I II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5p 4
3
P
2
1
0
0.0
7087.0
6447.9
MC60
MC60
MC60
5p 4
1
D
2
13727.2
MC60
5p4
1
S
0
29501.3
MC60
5 p 3 ( 4 S)6s
5 o
S
2
81032.70
MC60
3 o
1
84842.87
MC60
3 4
5 p ( S)6s
S
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1775
Energy Levels of Singly-ionized Iodine 共I II兲—Continued
J
Level (cm⫺1 )
3 o
P
2
1
0
81907.83
84222.19
90404.95
MC60
MC60
MC60
5 p 3 ( 4 S)5d
5
Do
0
1
2
3
4
85384.15
87734.06
86164.86
85727.98
86036.32
MC60
MC60
MC60
MC60
MC60
5 p 3 ( 2 Do)6s
3
Do
1
2
3
94825.33
93691.35
96650.55
MC60
MC60
MC60
5 p 3 ( 2 Do)6s
1
Do
2
97700.81
MC60
5 p 3 ( 4 S)6p
5
P
1
2
3
99219.61
99327.14
100402.68
MC60
MC60
MC60
5 p 3 ( 4 S)6p
3
P
2
1
0
102613.52
101644.21
103004.04
MC60
MC60
MC60
5 p 3 ( 2 Do)6p
3
F
2
3
4
111298.09
112419.04
115353.94
MC60
MC60
MC60
154304
MC60
Configuration
5s5 p
5
o
)
I III ( 4 S3/2
Term
Limit
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1776
J. E. SANSONETTI AND W. C. MARTIN
Iridium „Ir…
Atomic number⫽77
Atomic weight⫽192.22
Isotope
191
Ir
Ir
193
Mass
Abundance
Spin
Mag moment
190.960584
192.962917
37.3%
62.7%
3/2
3/2
⫹0.1461
⫹0.1591
Ir I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 7 6s 2 4F9/2
Ionization energy: 72 323.9 cm⫺1 共8.967 02 eV兲
Ir II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 7 6s 5F5
Ionization energy: not available
Strong Lines of Iridium 共Ir兲
Intensity
600
500
900
400
300
200
200
1000
800
150
800
250
200
150
600
150
500
120
1000
250
150
300
200
500
150
80
400
120
120
80
80
50
60
60
150
50
50
150
50
30
40
30
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2010.65
2022.35
2033.57
2052.22
2060.64
2083.22
2085.74
2088.82
2092.63
2112.68
2126.81
2127.94
2148.22
2150.54
2152.68
2155.81
2158.05
2162.88
2169.42
2175.24
2178.17
2187.43
2190.38
2204.96
2208.09
2220.37
2242.69
2253.38
2255.10
2255.81
2258.86
2264.61
2266.33
2268.90
2281.02
2298.05
2300.50
2304.22
2308.93
2333.30
2333.84
2334.50
Spectrum
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
I
I
I
I
I
I
I
I
I
I
II
I
I
I
II
I
I
I
II
I
I
II
II
II
II
I
II
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
KM78
MCS75
MCS75
MCS75
KM78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
KM78
MCS75
MCS75
KM78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1777
Strong Lines of Iridium 共Ir兲—Continued
Intensity
90
40
30
150
60
200
50
30
80
150
150
30
40
30
30
30
80
50
80
50
200
120
40
250
30
60
60
30
30
500
50
50
40
40
40
40
110
40
200
110
150
30
30
200
30
30
90
40
70
50
60
50
200
50
40
250
70
50
150
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
2343.18
2343.61
2355.00
2363.04
2368.04
2372.77
2375.09
2381.62
2386.89
2390.62
2391.18
2413.31
2418.11
2426.53
2427.61
2431.24
2431.94
2452.81
2455.61
2467.30
2475.12
2481.18
2493.08
2502.98
2512.58
2533.13
2534.46
2537.22
2542.02
2543.97
2546.03
2564.18
2577.26
2592.06
2599.04
2608.25
2611.30
2634.17
2639.71
2661.98
2664.79
2669.91
2671.84
2694.23
2781.29
2797.35
2797.70
2823.18
2824.45
2836.40
2839.16
2840.22
2849.72
2882.64
2897.15
2924.79
2934.64
2936.68
2943.15
Spectrum
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
I
I
I
I
II
I
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
KM78
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1778
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Iridium 共Ir兲—Continued
Intensity
Wavelength 共Å兲
70
40
90
30
30
200
40
300 P
30
40
200 P
70
40
30 P
30
200
30
15
13
2951.22
3003.63
3068.89
3100.29
3100.45
3133.32
3212.12
3220.78
3368.48
3437.02
3513.64
3573.72
3628.67
3731.36
3747.20
3800.12
3976.31
4268.10
4311.50
Spectrum
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Iridium 共Ir I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
4
9/2
9/2
0.00
49158.63
MCS75
Configuration
Term
7
2
900
2033.57
5d 6s
1000
2088.82
5d 7 6s 2
4
F
1o
9/2
11/2
0.00
47858.45
MCS75
500
2158.05
5d 8 ( 3 F)6s
4
9/2
9/2
2834.99
49158.63
MCS75
200
2372.77
5d 7 6s 2
5d 8 ( 3 F)6p
9/2
11/2
0.00
42131.84
MCS75
9/2
9/2
0.00
40389.83
MCS75
FW96
F
F
9/2
11/2
0.00
39940.37
MCS75
FW96
F
Go
9/2
11/2
2834.99
42131.84
MCS75
9/2
9/2
0.00
37871.69
MCS75
FW96
F
P
9/2
7/2
0.00
37515.32
MCS75
FW96
F
F
9/2
11/2
2834.99
39940.37
MCS75
FW96
9/2
9/2
0.00
35080.70
MCS75
FW96
9/2
11/2
0.00
34180.46
MCS75
FW96
200
250
500
200
150
200
200
250
2475.12
2502.98
0.21
0.32
2664.79
2694.23
2849.72
2924.79
5d 7 6s 2
5d 6 6s 2 ( 5 D)6p
5d 8 ( 3 F)6s
5d 8 ( 3 F)6p
2543.97
2639.71
5d 7 6s 2
5d 6 6s 2 ( 5 D)6p
0.47
0.40
0.48
0.22
0.142
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5d 7 6s 2
5d 7 ( 4 P)6s6 p( 3 Po)
5d 7 6s 2
5d 7 ( 4 P)6s6 p( 3 Po)
5d 8 ( 3 F)6s
5d 6 6s 2 ( 5 D)6p
5d 7 6s 2
5d 7 ( 4 F)6s6 p( 3 Po)
5d 7 6s 2
5d 7 ( 4 F)6s6 p( 3 Po)
F
2o
A Ref
F
2o
4
4
F
Go
4
F
F
6 o
4
6 o
4
4
4
6
F
Do
4
6 o
4
6 o
4
6
F
Go
4
6
F
Go
ATOMIC SPECTROSCOPIC DATA
1779
Persistent Lines of Neutral Iridium 共Ir I兲—Continued
Wavelength 共Å兲
Inten
300
3220.78
200
A ki (108 s⫺1 )
Configuration
Term
8 3
4
5d ( F)6s
5d 7 ( 4 F)6s6 p( 3 Po)
0.24
5d 7 6s 2
5d 7 ( 4 F)6s6 p( 3 Po)
3513.64
F
F
6 o
4
F
F
6 o
J
Level (cm⫺1 )
Wl Ref
A Ref
9/2
7/2
2834.99
33874.44
MCS75
FW96
9/2
11/2
0.00
28452.31
MCS75
Energy Levels of Neutral Iridium 共Ir I兲
J
Level (cm⫺1 )
Ref
4
F
9/2
7/2
5/2
3/2
0.00
7106.63
9877.58
11831.13
K57
K57
K57
K57
5d 8 ( 3 F)6s
4
F
9/2
7/2
3/2
5/2
2834.99
6323.96
10578.70
12218.50
K57
K57
K57
K57
5d 7 6s 2
2
P
3/2
1/2
4078.95
12505.75
K57
K57
5d 8 ( 3 F)6s
2
D
5/2
3/2
5784.63
22110.29
K57
K57
5d 7 6s 2
4
P
5/2
3/2
1/2
12951.73
18547.10
20236.75
K57
K57
K57
5d 8 ( 3 F)6s
2
F
7/2
5/2
13087.94
19060.68
K57
K57
5d 7 6s 2
2
G
9/2
7/2
13939.83
17779.30
K57
K57
5d 8 ( 3 P)6s
4
P
5/2
3/2
1/2
16103.37
16565.41
16681.27
K57
K57
K57
5d 7 6s 2
2
D2
3/2
1/2
23310.40
26229.51
K57
K57
5d 8 ( 3 F)6s
2
G
9/2
7/2
23505.94
26365.19
K57
K57
5d 7 6s 2
2
5/2
26404.22
K57
9/2
7/2
3/2
5/2
1/2
26307.49
30529.67
32463.60
33064.84
35647.96
K57
K57
K57
K57
K57
Configuration
7
5d 6s
7 4
Term
2
F
3 o
5d ( F)6s6p( P )
6
o
5d 9
2
D
3/2
27970.06
K57
5d 7 ( 4 F)6s6p( 3 Po)
6 o
11/2
9/2
7/2
28452.31
32513.42
33874.44
K57
K57
K57
D
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1780
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Iridium 共Ir I兲—Continued
J
Level (cm⫺1 )
11/2
9/2
34180.46
35080.70
K57
K57
6 o
P
7/2
37515.32
K57
5d 7 ( 4 P)6s6p( 3 Po)
6
Do
9/2
37871.69
K57
5d 6 6s 2 ( 5 D)6p
6 o
F
11/2
9/2
39940.37
40389.83
K57
K57
5d 8 ( 3 F)6p
4
Go
11/2
42131.84
K57
1o
11/2
47858.45
K57
2o
9/2
49158.63
K57
Limit
72323.9
CLS97
Configuration
Term
5d 7 ( 4 F)6s6p( 3 Po)
6
5d 7 ( 4 P)6s6p( 3 Po)
Go
5
Ir II ( F5 )
Ref
Persistent Lines of Singly-ionized Iridium 共Ir II兲
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
5
F
(9/2,1/2) o
5
5
0.00
47003.98
KM78
5
4
3
4787.93
51226.62
KM78
Inten
Wavelength 共Å兲
800
2126.81
5d 7 ( 4 F)6s
5d 7 ( 4 F9/2)6p 1/2
600
2152.68
5d 7 ( 4 F)6s
5d 7 ( 4 F7/2)6p 1/2
1000
2169.42
500
2204.96
5d 7 ( 4 F)6s
5d 7 ( 4 F7/2)6p 1/2
5
F
(7/2,1/2) o
3
4
8186.96
53525.25
KM78
400
2242.69
5d 7 ( 4 F)6s
5d 7 ( 4 F9/2)6p 1/2
5
5
4
0.00
44575.66
KM78
150
2281.02
60
2368.04
30
3731.36
Configuration
F
(7/2,1/2) o
A Ref
MCS75
F
(9/2,1/2) o
MCS75
5d 7 ( 4 F)6s
5d 7 ( 4 F9/2)6p 1/2
5
F
(9/2,1/2) o
4
5
4787.93
47003.98
KM78
MCS75
Energy Levels of Singly-ionized Iridium 共Ir II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5d 7 ( 4 F)6s
5
5
4
3
2
1
0.00
4787.93
8186.96
11307.32
11957.70
KM78
KM78
KM78
KM78
KM78
5d 8
3
F
4
3
2
2262.75
9927.83
17413.24
KM78
KM78
KM78
a 3P
2
1
0
3090.17
9062.14
11211.93
KM78
KM78
KM78
1
2
8975.01
KM78
2
4
11719.09
KM78
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1781
Energy Levels of Singly-ionized Iridium 共Ir II兲—Continued
Configuration
7 4
Term
J
Level (cm⫺1 )
Ref
3
2
1
12714.64
15676.35
18676.50
KM78
KM78
KM78
5d ( P)6s
5
5d 6 6s 2
5
D
4
17210.14
KM78
5d 7 ( 2 G)6s
3
G
5
17477.92
KM78
5d 7 ( 4 F)6s
3
F
3
17499.29
KM78
5d 7 ( 4 F9/2)6p 1/2
(9/2 ,1/2) o
4
5
44575.66
47003.98
KM78
KM78
5d 7 ( 4 F7/2)6p 1/2
(7/2 ,1/2) o
3
4
51226.62
53525.25
KM78
KM78
Ir III ( 4 F9/2)
P
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1782
J. E. SANSONETTI AND W. C. MARTIN
Iron „Fe…
Atomic number⫽26
Atomic weight⫽55.847
Isotope
54
Fe
Fe
57
Fe
58
Fe
56
Mass
Abundance
Spin
53.939612
55.934939
56.935396
57.933277
5.82%
91.18%
2.1%
0.28%
0
0
1/2
0
Mag moment
⫹0.09044
Fe I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 6 4s 2 5D4
Ionization energy: 63 737 cm⫺1 共7.9024 eV兲
Fe II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 6 4s 6D9/2
Ionization energy: 130 563 cm⫺1 共16.1877 eV兲
Strong Lines of Iron 共Fe兲
Intensity
30
30
30
60
30
60
60
200
120
400
50
90
120
150
120
90
70
40
120
50
50
50
40
60
40
70
50
70
1000
40
200
700
200
500
150
50
200
120
Wavelength 共Å兲
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2178.0808
2259.5103
2292.5249
2298.1689
2300.1418
2327.3958
2331.3084
2332.7990
2338.0065
2343.4951
2343.9610
2344.2816
2348.1159
2348.3025
2359.1322
2359.9997
2360.2945
2363.8612
2364.8281
2365.7654
2368.5964
2369.9534
2373.6245
2373.7357
2375.1940
2376.4294
2379.2765
2380.7616
2382.0376
2383.2452
2388.6289
2395.6254
2399.2413
2404.8858
2406.6612
2406.9761
2410.5192
2411.0677
Spectrum
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
ATOMIC SPECTROSCOPIC DATA
1783
Strong Lines of Iron 共Fe兲—Continued
Intensity
90
50
40
90
70
70
50
40
90
40
60
60
150
90
40
50
60
150
80
40
40
60
40
50
80
100
60
40
120
60
50
60
1000
30
100
40
80
600
50
100
500
40
200
60
60
300
60
100
40
40
50
50
100
70
40
30
80
40
400
P
P
P
P
P
Wavelength 共Å兲
2413.3104
2417.8707
2422.6882
2424.1456
2428.3638
2430.0783
2432.2612
2432.8732
2439.3014
2443.7100
2444.5154
2445.5732
2457.5891
2458.7838
2460.4404
2461.2835
2461.8610
2462.6472
2465.1492
2466.6713
2466.8194
2468.8799
2469.5147
2470.6694
2472.3320
2472.8713
2474.8145
2478.5722
2479.7764
2480.1577
2482.1172
2482.6577
2483.2708
2483.5334
2484.1875
2484.2446
2486.3728
2488.1426
2489.4833
2489.7524
2490.6443
2490.8584
2491.1550
2491.3965
2493.1846
2493.2637
2496.5337
2501.1318
2502.3930
2503.8745
2506.0935
2507.9004
2510.8350
2511.7603
2512.3650
2517.6611
2518.1018
2519.0472
2522.8494
Spectrum
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
I
II
II
I
II
II
I
I
I
II
I
II
II
II
I
I
I
II
I
I
II
I
I
II
I
II
II
II
I
I
II
II
II
I
I
II
I
I
I
II
I
Ref
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NJLT94
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
NJLT94
NJLT94
NJLT94
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NJLT94
NJLT94
NJLT94
NLTH91
NJLT94
NJLT94
NLTH91
NJLT94
NJLT94
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NJLT94
NJLT94
NLTH91
NLTH91
NLTH91
NJLT94
NJLT94
NLTH91
NJLT94
NJLT94
NJLT94
NLTH91
NJLT94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1784
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Iron 共Fe兲—Continued
Intensity
50
120
200
200
80
70
60
70
40
40
120
60
60
90
120
60
50
40
30
40
80
50
60
50
50
40
60
40
30
250
120
40
90
30
40
60
150
300
60
400
700
30
200
80
300
400
200
200
60
40
120
90
150
150
30
40
30
60
300
Wavelength 共Å兲
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2524.2925
2525.3879
2526.2939
2527.4351
2529.1350
2533.6274
2534.4186
2535.4856
2535.6069
2536.6726
2536.80
2538.7987
2538.9094
2538.99
2540.66
2540.9722
2541.1010
2541.8358
2542.1013
2543.3781
2545.9785
2546.6701
2548.7442
2549.0833
2549.3947
2549.4616
2549.6133
2550.0274
2550.6832
2562.5356
2563.4755
2566.9126
2574.3662
2576.6902
2577.9219
2582.5832
2584.5359
2585.8758
2591.5428
2598.3692
2599.3956
2599.5669
2606.5162
2606.8264
2607.0871
2611.8736
2613.8243
2617.6174
2620.41
2623.5339
2625.6671
2628.2931
2631.0471
2631.3232
2635.8088
2664.6638
2666.8125
2679.0242
2684.7536
Spectrum
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
I
II
II
I
I
II
II
II
I
II
II
II
II
II
II
I
II
II
I
II
I
II
II
II
II
II
I
II
II
II
II
II
II
I
II
II
I
II
II
II
II
I
II
I
II
II
II
II
II
I
II
II
II
II
I
II
I
I
II
Ref
NJLT94
NLTH91
NLTH91
NJLT94
NJLT94
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
C74
NLTH91
NLTH91
C74
C74
NJLT94
NLTH91
NLTH91
NJLT94
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
D38
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NJLT94
NJLT94
NLTH91
ATOMIC SPECTROSCOPIC DATA
1785
Strong Lines of Iron 共Fe兲—Continued
Intensity
40
40
40
40
50
400
150
40
50
50
100
50
50
400
80
120
200
400
60
120
50
500
100
30
60
300
40
150
250
30
60
150
20
100
80
120
100
60
150
80
120
50
60
100
100
50
80
50
40
50
150
60
50
50
80
80
60
100
50
P
P
P
P
P
Wavelength 共Å兲
2689.2122
2692.6019
2703.9891
2706.5820
2714.4129
2719.0273
2720.9023
2723.5774
2727.5392
2728.90
2733.5806
2735.4753
2737.3091
2739.5474
2742.4053
2743.1969
2746.4838
2749.3216
2749.4860
2750.1406
2753.2877
2755.7365
2761.81
2772.0740
2778.2202
2788.1047
2804.5203
2806.9841
2813.2864
2823.2756
2825.5557
2832.4355
2838.1194
2843.9763
2851.7969
2936.9033
2947.8760
2953.9399
2966.8982
2970.0994
2973.1323
2973.2354
2981.4451
2983.5696
2994.4268
2999.5117
3000.9478
3008.1382
3020.01
3020.4907
3020.6389
3021.0728
3024.0327
3025.8423
3037.3887
3047.6045
3057.4458
3059.0857
3193.2258
Spectrum
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
I
II
II
I
II
I
I
I
II
II
I
I
I
II
I
II
II
II
II
I
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
Ref
NJLT94
NLTH91
NLTH91
NJLT94
NLTH91
NJLT94
NJLT94
NJLT94
NLTH91
C74
NJLT94
NJLT94
NJLT94
NLTH91
NJLT94
NLTH91
NLTH91
NLTH91
NLTH91
NJLT94
NLTH91
NLTH91
C74
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
C74
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1786
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Iron 共Fe兲—Continued
Intensity
80
30
60
30
40
50
50
400
250
100
120
200
50
250
50
30
40
30
40
40
100
120
80
600
30
40
50
150
150
120
150
150
50
120
30
60
600
150
50
120
700
600
40
600
120
300
400
300
40
150
40
60
40
40
60
150
500
250
150
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3193.2998
3222.0591
3225.7871
3236.2224
3355.2278
3407.4597
3427.1194
3440.6060
3440.9888
3443.8765
3465.8606
3475.4502
3476.7019
3490.5740
3497.8406
3521.2612
3526.0408
3541.0833
3554.9246
3558.5151
3565.3789
3570.0977
3570.2542
3581.1931
3585.3188
3586.9849
3606.6794
3608.8594
3618.7678
3631.4631
3647.8428
3679.9133
3687.4568
3705.5659
3707.9199
3709.2463
3719.9348
3722.5630
3727.6189
3733.3176
3734.8638
3737.1316
3743.3621
3745.5613
3745.8994
3748.2622
3749.4854
3758.2329
3760.0498
3763.7891
3765.5388
3767.1919
3795.0022
3799.5476
3812.9646
3815.8403
3820.4253
3824.4436
3825.8811
Spectrum
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
ATOMIC SPECTROSCOPIC DATA
1787
Strong Lines of Iron 共Fe兲—Continued
Intensity
120
100
50
80
250
500
150
300
30
80
120
40
60
120
120
200
40
300
150
120
40
80
30
40
30
80
120
120
120
150
80
200
120
30
60
40
50
150
250
50
100
120
80
80
30
50
40
30
50
120
25
25
60
100
P
P
P
P
Wavelength 共Å兲
3827.8225
3834.2224
3840.4375
3841.0481
3856.3716
3859.9114
3878.5732
3886.2822
3888.5134
3895.6565
3899.7075
3902.9458
3920.2581
3922.9119
3927.9199
3930.2966
4005.2419
4045.8125
4063.5942
4071.7380
4132.0581
4143.8682
4202.0293
4216.1836
4250.7871
4260.4746
4271.7607
4282.4028
4307.9023
4325.7622
4375.9302
4383.5449
4404.7505
4415.1226
4427.2979
4461.6528
4920.5029
4957.5967
5167.4883
5171.5962
5227.1509
5269.5376
5270.3564
5328.0386
5328.5317
5341.0239
5371.4897
5397.1279
6247.56
6456.38
11607.5752
11689.9756
11882.8467
11973.0498
Spectrum
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
Ref
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
RMW44
RMW44
NJLT94
NJLT94
NJLT94
NJLT94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1788
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Iron 共Fe I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
6
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
5
1000
2483.2708
4.81
3d 4s
3d 6 ( 5 D)4s4p( 1 P)
a D
x 5Fo
4
5
0.000
40257.311
NJLT94
OWLW91
600
2488.1426
4.20
3d 6 4s 2
3d 6 ( 5 D)4s4p( 1 P)
a 5D
x 5Fo
3
4
415.933
40594.429
NJLT94
OWLW91
500
2490.6443
3.45
3d 6 4s 2
3d 6 ( 5 D)4s4p( 1 P)
a 5D
x 5Fo
2
3
704.007
40842.151
NJLT94
OWLW91
400
2522.8494
2.13
3d 6 4s 2
3d 6 ( 5 D)4s4p( 1 P)
a 5D
x 5Do
4
4
0.000
39625.801
NJLT94
OWLW91
400
2719.0273
1.42
3d 6 4s 2
3d 6 ( 5 D)4s4p( 1 P)
a 5D
y 5Po
4
3
0.000
36766.964
NJLT94
OWLW91
300
2788.1047
0.59
3d 7 ( 4 F)4s
3d 6 ( 3 H)4s4p( 3 P)
a 5F
y 5Go
5
6
6928.268
42784.349
NJLT94
OWLW91
400
3440.6060
0.171
3d 6 4s 2
3d 6 ( 5 D)4s4p( 3 P)
a 5D
z 5Po
4
3
0.000
29056.322
NJLT94
M03
600
3581.1931
1.02
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
z 5Go
5
6
6928.268
34843.955
NJLT94
FW96
600
3719.9348
0.162
3d 6 4s 2
3d 6 ( 5 D)4s4p( 3 P)
a 5D
z 5Fo
4
5
0.000
26874.548
NJLT94
FW96
700
3734.8638
0.902
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
y 5Fo
5
5
6928.268
33695.395
NJLT94
FW96
600
3737.1316
0.141
3d 6 4s 2
3d 6 ( 5 D)4s4p( 3 P)
a 5D
z 5Fo
3
4
415.933
27166.818
NJLT94
M03
600
3745.5613
0.115
3d 6 4s 2
3d 6 ( 5 D)4s4p( 3 P)
a 5D
z 5Fo
2
3
704.007
27394.689
NJLT94
FW96
400
3749.4854
0.764
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
y 5Fo
4
4
7376.764
34039.514
NJLT94
FW96
300
3758.2329
0.634
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
y 5Fo
3
3
7728.059
34328.750
NJLT94
FW96
500
3820.4253
0.668
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 5F
y 5Do
5
4
6928.268
33095.939
NJLT94
FW96
500
3859.9114
0.0969
3d 6 4s 2
3d 6 ( 5 D)4s4p( 3 P)
a 5D
z 5Do
4
4
0.000
25899.987
NJLT94
M03
300
4045.8125
0.863
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 3F
y 3Fo
4
4
11976.238
36686.174
NJLT94
FW96
200
4383.5449
0.500
3d 7 ( 4 F)4s
3d 7 ( 4 F)4p
a 3F
z 5Go
4
5
11976.238
34782.419
NJLT94
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1789
Energy Levels of Neutral Iron 共Fe I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3d 6 4s 2
a 5D
4
3
2
1
0
0.000
415.933
704.007
888.132
978.074
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 7 ( 4 F)4s
a 5F
5
4
3
2
1
6928.268
7376.764
7728.059
7985.784
8154.713
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 7 ( 4 F)4s
a 3F
4
3
2
11976.238
12560.933
12968.553
NJLT94
NJLT94
NJLT94
3d 7 ( 4 P)4s
a 5P
3
2
1
17550.180
17726.987
17927.381
NJLT94
NJLT94
NJLT94
3d 6 4s 2
a 3P
2
1
0
18378.185
19552.477
20037.815
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 7Do
5
4
3
2
1
19350.892
19562.440
19757.033
19912.494
20019.634
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 6 4s 2
a 3H
6
5
4
19390.167
19621.005
19788.250
NJLT94
NJLT94
NJLT94
3d 6 4s 2
b 3F
4
3
2
20641.109
20874.481
21038.986
NJLT94
NJLT94
NJLT94
3d 7 ( 2 G)4s
a 3G
5
4
3
21715.731
21999.129
22249.428
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 7Fo
6
5
4
3
2
1
0
22650.414
22845.867
22996.672
23110.937
23192.498
23244.836
23270.382
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 7 ( 4 P)4s
b 3P
2
1
0
22838.321
22946.814
23051.748
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 7Po
4
3
2
23711.454
24180.860
24506.915
NJLT94
NJLT94
NJLT94
3d 6 4s 2
b 3G
5
4
3
23783.617
24118.817
24338.765
NJLT94
NJLT94
NJLT94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1790
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Iron 共Fe I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3d ( P)4s
3
c P
2
1
0
24335.764
24772.016
25091.597
NJLT94
NJLT94
NJLT94
3d 7 ( 2 G)4s
a 1G
4
24574.653
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 5Do
4
3
2
1
0
25899.987
26140.177
26339.694
26479.379
26550.477
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 7 ( 2 H)4s
b 3H
6
5
4
26105.906
26351.038
26627.607
NJLT94
NJLT94
NJLT94
3d 7 (a 2 D)4s
a 3D
3
2
1
26224.967
26623.733
26406.463
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 5Fo
5
4
3
2
1
26874.548
27166.818
27394.689
27559.581
27666.346
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 7 ( 2 P)4s
a 1P
1
27543.001
NJLT94
3d 7 (a 2 D)4s
a 1D
2
28604.611
NJLT94
3d ( H)4s
1
a H
5
28819.952
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 5Po
3
2
1
29056.322
29469.022
29732.734
NJLT94
NJLT94
NJLT94
3d 6 4s 2
a 1I
Configuration
7 2
7 2
6
29313.006
NJLT94
2
3
b D
3
2
1
29371.810
29356.742
29320.024
NJLT94
NJLT94
NJLT94
3d 6 4s 2
b 1G
4
29798.934
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 3Fo
4
3
2
31307.243
31805.069
32133.989
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 3Do
3
2
1
31322.611
31686.349
31937.323
NJLT94
NJLT94
NJLT94
3d 8
c 3F
4
3
2
32873.630
33412.715
33765.304
NJLT94
NJLT94
NJLT94
3d 7 ( 4 F)4p
y 5Do
4
3
2
1
0
33095.939
33507.121
33801.570
34017.101
34121.601
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
6
3d 4s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1791
Energy Levels of Neutral Iron 共Fe I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3d ( F)4p
5 o
y F
5
4
3
2
1
33695.395
34039.514
34328.750
34547.209
34692.146
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 3 P)
z 3Po
2
1
0
33946.931
34362.871
34555.595
NJLT94
NJLT94
NJLT94
3d 6 4s 2
b 1D
2
34636.790
NJLT94
3d 7 ( 4 F)4p
z 5Go
6
5
4
3
2
34843.955
34782.419
35257.322
35611.623
35856.400
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 7 ( 4 F)4p
z 3Go
5
4
3
35379.206
35767.562
36079.370
NJLT94
NJLT94
NJLT94
3d 7 ( 4 F)4p
y 3Fo
4
3
2
36686.174
37162.744
37521.158
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 1 P)
y 5Po
3
2
1
36766.964
37157.564
37409.552
NJLT94
NJLT94
NJLT94
3d 7 ( 2 F)4s
d 3F
2
3
4
36940.588
36975.586
37045.932
NJLT94
NJLT94
NJLT94
3d 7 ( 4 F)4p
y 3Do
3
2
1
38175.352
38678.036
38995.733
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 1 P)
x 5Do
4
3
2
1
0
39625.801
39969.850
40231.333
40404.515
40491.281
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 5 ( 6 S)4s 2 4p
y 7Po
4
3
2
40421.935
40207.088
40052.032
NJLT94
NJLT94
NJLT94
3d 6 ( 5 D)4s4p( 1 P)
x 5Fo
5
4
3
2
1
40257.311
40594.429
40842.151
41018.048
41130.596
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
3d 8
c 3P
2
1
0
40871.409
41178.409
41234.502
NJLT94
NJLT94
NJLT94
3d 6 ( 3 P)4s4p( 3 P)
z 5So
2
40894.987
NJLT94
Configuration
7 4
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1792
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Iron 共Fe I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3d ( P)4s4p( P)
5 o
x P
3
2
1
42532.738
42859.775
43079.020
NJLT94
NJLT94
NJLT94
3d 6 ( 3 H)4s4p( 3 P)
y 5Go
6
5
4
3
2
42784.349
42911.914
43022.982
43137.484
43210.022
NJLT94
NJLT94
NJLT94
NJLT94
NJLT94
63737
SC85
Configuration
6 3
3
Fe II ( 6 D9/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1793
Persistent Lines of Singly-ionized Iron 共Fe II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
6 5
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
6
400
2343.4951
1.73
3d ( D)4s
3d 6 ( 5 D)4p
a D
z 6Po
9/2
7/2
0.000
42658.224
NLTH91
M03
1000
2382.0376
3.13
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Fo
9/2
11/2
0.000
41968.046
NLTH91
M03
700
2395.6254
2.67
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Fo
7/2
9/2
384.790
42114.818
NLTH91
M03
500
2404.8858
2.05
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Fo
5/2
7/2
667.683
42237.033
NLTH91
M03
300
2493.2637
3.4
3d 6 ( 3 H)4s
3d 6 ( 3 H)4p
a 4H
z 4Io
13/2
15/2
21251.608
61347.614
NLTH91
FW96
300
2585.8758
0.861
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Do
9/2
7/2
0.000
38660.043
NLTH91
M03
400
2598.3692
1.42
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Do
7/2
5/2
384.790
38858.958
NLTH91
M03
800
2599.3956
2.36
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Do
9/2
9/2
0.000
38458.981
NLTH91
M03
300
2607.0871
1.74
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Do
5/2
3/2
667.683
39013.206
NLTH91
M03
400
2611.8736
1.23
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Do
7/2
7/2
384.790
38660.043
NLTH91
M03
400
2739.5474
1.9
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 4D
z 4Do
7/2
7/2
7955.299
44446.878
NLTH91
FW96
400
2749.3216
2.1
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 4D
z 4Fo
5/2
7/2
8391.938
44753.799
NLTH91
FW96
500
2755.7365
2.1
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 4D
z 4Fo
7/2
9/2
7955.299
44232.512
NLTH91
FW96
Energy Levels of Singly-ionized Iron 共Fe II兲
Term
J
Level (cm⫺1 )
Ref
3d ( D)4s
6
a D
9/2
7/2
5/2
3/2
1/2
0.000
384.790
667.683
862.613
977.053
J78
J78
J78,BKE98
J78,BKE98
J78,BKE98
3d 7
a 4F
9/2
7/2
5/2
3/2
1872.567
2430.097
2837.950
3117.461
J78
J78
J78
J78
3d 6 ( 5 D)4s
a 4D
7/2
5/2
3/2
1/2
7955.299
8391.938
8680.454
8846.768
J78
J78
J78
J78
Configuration
6 5
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1794
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Iron 共Fe II兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
7
4
a P
5/2
3/2
1/2
13474.411
13673.185
13904.824
J78
J78
J78
3d 7
a 2G
9/2
7/2
15844.65
16369.36
J78
J78
3d 7
a 2P
3/2
1/2
18360.646
18886.780
J78
J78
3d 7
a 2H
11/2
9/2
20340.30
20805.77
J78
J78
3d 7
a 2D2
5/2
3/2
20516.960
21308.04
J78
J78
3d 6 ( 3 P2 )4s
b 4P
5/2
3/2
1/2
20830.582
21812.055
22409.852
J78
J78
J78
3d 6 ( 3 H)4s
a 4H
13/2
11/2
9/2
7/2
21251.608
21430.359
21581.638
21711.917
J78
J78
J78
J78
3d 6 ( 3 F2 )4s
b 4F
9/2
7/2
5/2
3/2
22637.205
22810.357
22939.358
23031.300
J78
J78
J78
J78
3d 5 4s 2
a 6S
5/2
23317.633
J78
3d ( G)4s
4
a G
11/2
9/2
7/2
5/2
25428.784
25805.328
25981.629
26055.423
J78
J78
J78
J78
3d 6 ( 3 P2 )4s
b 2P
3/2
1/2
25787.598
26932.748
J78
J78
3d 6 ( 3 H)4s
b 2H
11/2
9/2
26170.181
26352.766
J78
J78
3d 6 ( 3 F2 )4s
a 2F
7/2
5/2
27314.922
27620.412
J78
J78
3d 6 ( 3 G)4s
b 2G
9/2
7/2
30388.542
30764.485
J78
J78
3d 6 ( 3 D)4s
b 4D
3/2
1/2
5/2
7/2
31364.440
31368.450
31387.948
31483.176
J78
J78
J78
J78
3d 7
b 2F
5/2
7/2
31811.822
31999.048
J78
J78
3d 6 ( 1 I)4s
a 2I
13/2
11/2
32875.646
32909.905
J78
J78
3d 6 ( 1 G2 )4s
c 2G
9/2
7/2
33466.463
33501.253
J78
J78
3d
6 3
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1795
Energy Levels of Singly-ionized Iron 共Fe II兲—Continued
J
Level (cm⫺1 )
3d ( D)4s
2
b D
3/2
5/2
36126.387
36252.918
J78
J78
3d 6 ( 1 S2 )4s
a 2S
1/2
37227.326
J78
3d ( D2 )4s
2
c D
5/2
3/2
38164.194
38214.507
J78
J78
3d 6 ( 5 D)4p
z 6Do
9/2
7/2
5/2
3/2
1/2
38458.981
38660.043
38858.958
39013.206
39109.307
J78
J78
J78
J78
J78
3d 6 ( 5 D)4p
z 6Fo
11/2
9/2
7/2
5/2
3/2
1/2
41968.046
42114.818
42237.033
42334.822
42401.302
42439.822
J78
J78
J78
J78
J78
J78
3d 6 ( 5 D)4p
z 6Po
7/2
5/2
3/2
42658.224
43238.586
43620.957
J78
J78
J78
3d 6 ( 5 D)4p
z 4Fo
9/2
7/2
5/2
3/2
44232.512
44753.799
45079.879
45289.801
J78
J78
J78
J78
3d 6 ( 5 D)4p
z 4Do
7/2
5/2
3/2
1/2
44446.878
44784.761
45044.168
45206.450
J78
J78
J78
J78
3d 6 ( 1 F)4s
c 2F
7/2
5/2
44915.046
44929.55
J78
J78
3d 6 ( 5 D)4p
z 4Po
5/2
3/2
1/2
46967.444
47389.779
47626.076
J78
J78
J78
3d 7
d 2D1
3/2
5/2
47674.721
48039.090
J78
J78
3d 6 ( 3 P1 )4s
c 4P
1/2
3/2
5/2
49100.976
49506.934
50212.826
J78
J78
J78
3d 6 ( 3 F1 )4s
c 4F
3/2
5/2
9/2
7/2
50075.910
50142.786
50157.452
50187.813
J78
J78
J78
J78
3d 5 ( 6 S)4s4p( 3 Po)
z 8Po
5/2
7/2
9/2
52299.39
52582.51
52965.82
J78
J78
J78
3d 6 ( 3 P1 )4s
c 2P
1/2
3/2
54063.459
54902.315
J78
J78
Configuration
6 3
6 1
Term
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1796
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Iron 共Fe II兲—Continued
J
Level (cm⫺1 )
4
b G
11/2
9/2
5/2
7/2
54232.195
54273.641
54275.637
54283.220
J78
J78
J78
J78
3d 6 ( 3 F1 )4s
d 2F
5/2
7/2
54870.528
54904.222
J78
J78
3d 5 4s 2
d 4P
5/2
3/2
1/2
57411.065
57493.321
57578.484
J78
J78
J78
3d 6 ( 1 G1 )4s
d 2G
9/2
7/2
58631.531
58666.258
J78
J78
3d 6 ( 3 P2 )4p
z 4So
3/2
59663.456
J78
3d 5 4s 2
c 4D
7/2
1/2
3/2
5/2
60270.339
60384.370
60441.033
60445.275
J78
J78
J78
J78
3d 6 ( 3 P2 )4p
y 4Po
5/2
1/2
3/2
60402.342
61035.287
61332.764
J78
J78
J78
3d 6 ( 3 H)4p
z 4Go
11/2
9/2
7/2
5/2
60625.449
60807.230
60956.781
61041.748
J78
J78
J78
J78
3d 6 ( 3 H)4p
z 4Ho
13/2
11/2
9/2
7/2
60837.569
60887.598
60989.444
61156.835
J78
J78
J78
J78
3d 6 ( 3 P2 )4p
z 2Do
5/2
3/2
61093.413
62125.600
J78
J78
3d 6 ( 3 H)4p
z 4Io
15/2
9/2
13/2
11/2
61347.614
61512.634
61527.616
61587.214
J78
J78
J78
J78
Configuration
5
3d 4s
2
Term
Fe III ( 5 D4 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
130563
Ref
SC85
ATOMIC SPECTROSCOPIC DATA
1797
Krypton „Kr…
Atomic number⫽36
Atomic weight⫽83.80
Isotope
78
Kr
Kr
82
Kr
83
Kr
84
Kr
86
Kr
80
Mass
Abundance
Spin
77.920400
79.916380
81.913482
82.914135
83.911507
85.910616
0.35%
2.25%
11.6%
11.5%
57.0%
17.3%
0
0
0
9/2
0
0
Mag moment
⫺0.970
Kr I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 1S0
Ionization energy: 112 914.50 cm⫺1 共13.999 61 eV兲
o
Kr II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 5 2P3/2
⫺1
Ionization energy: 196 475.4 cm 共24.359 84 eV兲
Strong Lines of Krypton 共Kr兲
Intensity
20
70
30
20
70
20
70
30
20
20
30
20
20
70
300
130
70
700
100
80
30
80
80
700
150
150
150
300
1000
P
P
P
P
P
P
30 h
20
25 h
30
30 h
70
Wavelength 共Å兲
Vacuum
729.40
761.18
763.98
766.20
771.03
773.69
782.10
783.72
818.15
830.38
844.06
864.82
868.87
884.14
886.30
891.01
911.39
917.43
945.4414
946.5443
951.056
953.4041
963.3745
964.97
1001.0606
1003.5504
1030.0232
1164.8671
1235.8378
Air
2464.77
2492.48
2712.40
2833.00
3607.88
3631.889
Spectrum
Ref
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
II
I
I
I
I
I
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
MSP69
K93
K93
K93
K93
K93
MSP69
K93
K93
K93
K93
K93
Kr
Kr
Kr
Kr
Kr
Kr
II
II
II
II
II
II
RCWM80
DHM33
DHM33
DHM33
DHM33
HP70a
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1798
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Krypton 共Kr兲—Continued
Intensity
80
13
50
15
25
100
70
50
70
50
25
150
150
50
50
70
30
30
100
100
150
80
30
80
50
150
15
200
70
150
70
150
50
15
1000
80
70
130
100
30
15
150
200
100
130
250
130
100
130
70
250
100
50
150
300
250
700
150
30
Wavelength 共Å兲
d
h
h
h
h
h
P
h
h
h
h
h
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3653.928
3665.324
3669.01
3679.58
3686.182
3718.02
3718.595
3721.350
3741.638
3744.80
3754.245
3778.046
3783.095
3875.44
3906.177
3920.081
3994.840
3997.793
4057.037
4065.128
4088.337
4098.729
4109.248
4145.122
4250.580
4273.9694
4282.9674
4292.923
4300.49
4317.81
4318.5513
4319.5794
4322.98
4351.3597
4355.477
4362.6416
4369.69
4376.1216
4386.54
4399.9663
4425.1901
4431.685
4436.812
4453.9175
4463.6900
4475.014
4489.88
4502.3543
4523.14
4556.61
4577.209
4582.978
4592.80
4615.292
4619.166
4633.885
4658.876
4680.406
4691.301
Spectrum
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
II
I
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
I
I
II
I
II
I
II
I
II
I
I
II
II
I
I
II
II
I
II
II
II
II
II
II
II
II
II
II
II
Ref
HP70a
KH69
DHM33
KH69
HP70a
DHM33
HP70a
HP70a
HP70a
DHM33
HP70a
HP70a
HP70a
DHM33
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
K93
K93
HP70a
DHM33
DHM33
K93
K93
DHM33
K93
HP70a
K93
DHM33
K93
DHM33
K93
K93
HP70a
HP70a
K93
K93
HP70a
DHM33
K93
DHM33
DHM33
HP70a
HP70a
DHM33
HP70a
HP70a
HP70a
HP70a
HP70a
HP70a
ATOMIC SPECTROSCOPIC DATA
1799
Strong Lines of Krypton 共Kr兲—Continued
Intensity
70
1000
100
300
100
100
250
250
50
100
70
80
130
150
70
150
70
80
300
13
15
130
70
15
500
70
10
10
100
15
30
50
10
15
80
15
13
130
130
10
70
15
100
150
300
50
150
200
80
25
130
30
30
70
40
15
250
700
1000
P
P
P
P
h
P
h
P
P
P
Wavelength 共Å兲
4694.360
4739.002
4762.435
4765.744
4811.76
4825.18
4832.077
4846.612
4857.20
4945.59
5022.40
5086.52
5125.73
5208.32
5308.66
5333.41
5468.17
5562.2253
5570.2894
5580.3873
5649.5618
5681.89
5690.35
5832.8566
5870.9160
5992.22
5993.8502
6056.1263
6420.18
6421.0270
6456.2889
6570.07
6699.2296
6904.6788
7213.13
7224.104
7287.258
7289.78
7407.02
7425.541
7435.78
7486.862
7524.46
7587.4136
7601.5457
7641.16
7685.2459
7694.5401
7735.69
7746.827
7854.8234
7913.4251
7928.5988
7933.22
7973.62
7982.401
8059.5048
8104.3655
8112.9012
Spectrum
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
II
II
I
I
II
I
I
II
I
I
II
I
I
II
I
I
II
II
I
II
I
II
I
I
II
I
I
II
I
I
I
I
II
II
I
I
I
I
Ref
HP70a
HP70a
HP70a
HP70a
DHM33
DHM33
HP70a
HP70a
DHM33
DHM33
DHM33
DHM33
DHM33
DHM33
DHM33
DHM33
DHM33
K93
K93
K93
K93
DHM33
DHM33
K93
K93
DHM33
K93
K93
DHM33
K93
K93
DHM33
K93
K93
DHM33
KH69
KH69
DHM33
DHM33
KH69
DHM33
KH69
DHM33
K93
K93
DHM33
K93
K93
DHM33
KH69
K93
K93
K93
DHM33
DHM33
KH69
K93
K93
K93
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1800
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Krypton 共Kr兲—Continued
Intensity
10
500
70
13
500
15
250
800
15
500
25
1000
300
150
150
70
100
15
70
70
150
150
130
70
70
300
150
80
300
15
30
25
80
25
250
100
25
15
200
150
400
130
30
100
25
90
25
30
300
15
250
90
80
70
20
25
300
20
250
Wavelength 共Å兲
P
P
P
P
P
P
P,h,l
h
h
h
P
P,h
h
h
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
8132.967
8190.0566
8202.72
8218.365
8263.2426
8272.353
8281.0522
8298.1099
8412.430
8508.8728
8764.110
8776.7505
8928.6934
9238.48
9293.82
9320.99
9361.95
9362.082
9402.82
9470.93
9577.52
9605.80
9619.61
9663.34
9711.60
9751.7610
9803.14
9856.314
10221.46
11187.108
11257.711
11259.126
11457.481
11792.425
11819.377
11997.105
12077.224
12861.892
13177.412
13622.415
13634.220
13658.394
13711.036
13738.851
13974.027
14045.657
14104.298
14402.22
14426.793
14517.84
14734.436
14762.672
14765.472
14961.894
15005.307
15209.526
15239.615
15326.480
15334.958
Spectrum
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
I
I
II
I
I
I
I
I
I
I
I
I
I
II
II
II
II
I
II
II
II
II
II
II
II
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
KH69
K93
DHM33
KH69
K93
KH69
K93
K93
KH69
K93
KH69
K93
K93
DHM33
DHM33
DHM33
DHM33
KH69
DHM33
DHM33
DHM33
DHM33
DHM33
DHM33
DHM33
K93
DHM33
KH69
DHM33
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
ATOMIC SPECTROSCOPIC DATA
1801
Strong Lines of Krypton 共Kr兲—Continued
Intensity
Wavelength 共Å兲
120
30
30
20
30
300
150
400 P
250
300
100
120
20
25
110
120
400 P
15
25
50
30
30
25
50
25
100
300
20
30
20
30
100
30
150
25
25
50
50
50
80
200
40
15
250
200
80
50
200
40
15372.037
15474.026
15681.02
15820.09
16726.513
16785.128
16853.488
16890.441
16896.753
16935.806
17098.771
17367.606
17404.443
17616.854
17842.737
18002.229
18167.315
18399.786
18580.896
18696.294
18785.460
18797.703
20209.878
20423.964
20446.971
21165.471
21902.513
22485.775
23340.416
24260.506
24292.221
25233.820
28610.55
28655.72
28769.71
28822.49
29236.69
30663.54
30979.16
39300.6
39486.52
39557.25
39572.60
39588.4
39589.6
39954.8
39966.6
40306.1
40685.16
Spectrum
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
Kr
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
KH69
HPCA67
KH69
KH69
KH69
HPCA67
HPCA67
HPCA67
HPCA67
HPCA67
KH69
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1802
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Krypton 共Kr I兲
Inten
300
1000
300
500
700
1000
500
500
800
500
1000
400
300
400
400
Wavelength 共Å兲
1164.8671
1235.8378
5570.2894
5870.9160
8104.3655
8112.9012
8190.0566
8263.2426
8298.1099
8508.8728
8776.7505
A ki (108 s⫺1 )
3.16
3.12
0.021
0.018
0.13
0.36
0.11
0.35
0.32
0.24
0.27
13634.220
14426.793
16890.441
18167.315
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Term
J
Level (cm⫺1 )
S
关 1/2兴 o
0
1
S
关 3/2兴 o
Configuration
6
Wl Ref
A Ref
0.000
85846.7051
K93
FW96
0
1
0.000
80916.7685
K93
FW96
关 3/2兴 o
关 1/2兴
2
1
79971.7422
97919.1473
K93
FW96
关 3/2兴 o
关 3/2兴
1
2
80916.7685
97945.1669
K93
FW96
关 3/2兴 o
关 5/2兴
2
2
79971.7422
92307.3791
K93
FW96
关 3/2兴 o
关 5/2兴
2
3
79971.7422
92294.4017
K93
FW96
关 3/2兴 o
关 3/2兴
1
2
80916.7685
93123.3414
K93
FW96
关 1/2兴 o
关 3/2兴
1
2
85846.7051
97945.1669
K93
FW96
关 3/2兴 o
关 3/2兴
1
1
80916.7685
92964.3948
K93
FW96
关 1/2兴 o
关 3/2兴
1
1
85846.7051
97595.9158
K93
FW96
关 3/2兴 o
关 5/2兴
1
2
80916.7685
92307.3791
K93
FW96
关 5/2兴
关 3/2兴 o
3
2
92294.4017
99626.883
KH69
关 3/2兴
关 3/2兴 o
1
1
92964.3948
99894.048
KH69
关 5/2兴
关 7/2兴 o
2
3
92307.3791
98226.268
KH69
关 5/2兴
关 7/2兴 o
3
4
92294.4017
97797.287
KH69
1
4p
o
)5s
4p 5 ( 2 P1/2
2
4p 6
o
)5s
4p 5 ( 2 P3/2
2
1
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P1/2)5p
2
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P1/2)5p
2
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5s
4 p 5 ( 2 P1/2
5 2 o
4 p ( P1/2)5p
2
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5s
4 p 5 ( 2 P1/2
5 2 o
4 p ( P1/2)5p
2
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5p
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)6s
2
o
)5p
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)6s
2
o
)5p
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)4d
2
o
)5p
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)4d
2
2
2
2
2
2
2
2
2
2
2
2
2
2
ATOMIC SPECTROSCOPIC DATA
1803
Energy Levels of Neutral Krypton 共Kr I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
o
)5s
4 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
79971.7422
80916.7685
K93
K93
o
)5s
4 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
85191.6171
85846.7051
K93
K93
o
)5p
4 p 5 ( 2 P3/2
2
关 1/2兴
1
0
91168.5155
94092.8631
K93
K93
o
)5p
4 p 5 ( 2 P3/2
2
关 5/2兴
3
2
92294.4017
92307.3791
K93
K93
o
)5p
4 p 5 ( 2 P3/2
2
关 3/2兴
1
2
92964.3948
93123.3414
K93
K93
o
)5p
4 p 5 ( 2 P1/2
2
关 3/2兴
1
2
97595.9158
97945.1669
K93
K93
o
)5p
4 p 5 ( 2 P1/2
2
关 1/2兴
1
0
97919.1473
98855.0703
K93
K93
o
)4d
4 p 5 ( 2 P3/2
2
关 7/2兴 o
4
3
97797.287
98226.268
K93
K93
o
)6s
4 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
99626.883
99894.048
K93
K93
4p
6
o
)
Kr II ( 2 P3/2
0.000
Limit
112914.50
K93
YG94,BHU02
Persistent Lines of Singly-ionized Krypton 共Kr II兲
Inten
30
300
700
700
1000
700
1000
300
250
Wavelength 共Å兲
A ki (108 s⫺1 )
4355.477
4658.876
4739.002
4765.744
4832.077
Wl Ref
P
P
3/2
3/2
0.00
118474.36
MSP69
2 o
P
P
3/2
5/2
0.00
112828.27
MSP69
4p 5
4s4 p 6
2 o
P
S
3/2
1/2
0.00
109000.36
MSP69
M00
4p 5
4s4 p 6
2 o
P
S
1/2
1/2
5370.10
109000.36
MSP69
M00
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
P
Do
5/2
7/2
112828.27
135781.42
HP70a
FW96
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
P
P
5/2
3/2
112828.27
134286.67
HP70a
FW96
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
P
P
5/2
5/2
112828.27
133923.86
HP70a
FW96
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
P
Do
3/2
5/2
115092.01
136069.23
HP70a
FW96
4p 4 ( 3 P)5s
4 p 4 ( 3 P)5p
4
P
P
3/2
1/2
115092.01
135781.26
HP70a
FW96
4p
4 p 4 ( 3 P)5s
4p 5
4 p 4 ( 3 P)5s
886.30
964.97
Level (cm⫺1 )
5
844.06
917.43
J
Configuration
0.23
0.098
1.0
0.65
0.76
0.67
0.73
Term
2 o
2
4
2
2
4
4 o
4 o
4
4 o
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1804
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Krypton 共Kr II兲—Continued
Inten
Wavelength 共Å兲
250
Configuration
4 3
4846.612
150
300
A ki (108 s⫺1 )
9577.52
10221.46
J
Level (cm⫺1 )
P
P
3/2
1/2
118474.36
139101.57
HP70a
F
P
5/2
3/2
129697.19
140135.40
DHM33
F
Do
9/2
7/2
126000.82
135781.42
DHM33
Term
4p ( P)5s
4 p 4 ( 3 P)5p
2
4p 4 ( 3 P)4d
4 p 4 ( 3 P)5p
4
4p 4 ( 3 P)4d
4 p 4 ( 3 P)5p
4
2 o
2 o
4
Wl Ref
A Ref
Energy Levels of Singly-ionized Krypton 共Kr II兲
Ref
Term
4p5
2 o
P
3/2
1/2
0.00
5370.10
SM91
SM91
4s4 p 6
2
S
1/2
109000.36
SM91
4 p ( P)5s
4
P
5/2
3/2
1/2
112828.27
115092.01
117603.02
SM91
SM91
SM91
4 p 4 ( 3 P)5s
2
P
3/2
1/2
118474.36
121002.15
SM91
SM91
4p 4 ( 3 P)4d
4
D
7/2
5/2
3/2
1/2
120209.87
120426.93
121000.37
121779.54
SM91
SM91
SM91
SM91
4p 4 ( 3 P)4d
4
F
9/2
7/2
5/2
3/2
126000.82
127929.52
129697.19
130512.73
SM91
SM91
SM91
SM91
4p 4 ( 1 D)5s
2
D
3/2
5/2
127597.49
127861.51
SM91
SM91
4p 4 ( 3 P)5p
4 o
P
5/2
3/2
1/2
133923.86
134286.67
135781.26
SM91
SM91
SM91
4 p 4 ( 3 P)5p
4
Do
7/2
5/2
3/2
1/2
135781.42
136069.23
138379.61
140161.46
SM91
SM91
SM91
SM91
4 p 4 ( 3 P)5p
2 o
P
1/2
3/2
139101.57
140135.40
SM91
SM91
4 p 4 ( 3 P)5p
2
Do
5/2
3/2
140117.23
141993.94
SM91
SM91
Limit
196475.4
SM91
4 3
Kr III ( 3 P2 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
ATOMIC SPECTROSCOPIC DATA
1805
Lanthanum „La…
Atomic number⫽57
Atomic weight⫽138.9055
Isotope
138
La
La
139
Mass
Abundance
Spin
Mag moment
137.907105
138.906346
0.09%
99.10%
5
7/2
⫹3.707
⫹2.778
La I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )5d6s 2 2D3/2
Ionization energy: 44 981 cm⫺1 共5.5769 eV兲
La II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )5d 2 3F2
Ionization energy: 89 200 cm⫺1 共11.059 eV兲
Strong Lines of Lanthanum 共La兲
Intensity
90
60
60
90
150
100
150
300
250
110
250
400
400
200
400
200
140
120
200
250
1000
500
400
250
300
300
300
300
600
250
500
120
400
150
200
400
500
200
200
90
P
d
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Air
2256.76
3245.13
3265.67
3303.11
3337.49
3344.56
3380.91
3574.43
3641.53
3645.42
3759.08
3790.83
3794.78
3849.02
3871.64
3886.37
3916.05
3921.54
3927.56
3929.22
3949.10
3988.52
3995.75
4015.39
4031.69
4042.91
4060.33
4077.35
4086.72
4089.61
4123.23
4151.97
4187.32
4196.55
4238.38
4280.27
4333.74
4423.90
4429.90
4522.37
Spectrum
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
II
II
II
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
I
II
II
I
II
II
I
II
II
I
II
I
II
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1806
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Lanthanum 共La兲—Continued
Wavelength 共Å兲
Intensity
200
300
90
110
110
500
80
300
250
300
600
400
800
90
1000
700
500
500
700
700
300
250
500
400
600
400
1000
600
300
300
200
200
150
120
100
120
130
90
Spectrum
4567.91
4570.02
4899.92
4920.98
4921.79
4949.77
4999.47
5050.57
5056.46
5106.23
5145.42
5158.69
5177.31
5183.42
5211.86
5234.27
5253.46
5271.19
5455.15
5501.34
5648.25
5740.66
5769.34
5789.24
5791.34
5930.62
6249.93
6394.23
6410.99
6455.99
6543.16
6578.51
7334.18
7539.23
8086.05
8324.69
8346.53
8545.44
P
P
P
P
P
P
P
P
P
P
c,w
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
I
I
II
II
II
I
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Lanthanum 共La I兲
Inten
300
300
400
400
500
600
Wavelength 共Å兲
A ki (108 s⫺1 )
2
3574.43
5d6s
4 f 5d( 3 Do)6s
5d 2 ( 3 F)6s
4 f 5d( 3 Go)6s
4060.33
4187.32
4280.27
4949.77
Configuration
0.87
5145.42
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Wl Ref
D
3/2
3/2
0.000
27968.54
MCS75
F
Go
9/2
11/2
4121.572
28743.24
MCS75
4
2
D
3/2
5/2
0.000
23874.95
MCS75
D
5/2
7/2
1053.164
24409.68
MCS75
D
3/2
1/2
0.000
20197.34
MCS75
F
Do
5/2
3/2
3010.002
22439.36
MCS75
Term
2
o
4
5d6s 2
5d6s( 3 D)6p
o
5d6s 2
4 f 5d( 1 Go)6s
o
5d6s 2
5d6s( 1 D)6p
o
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
2
2
4
4
A Ref
M00
ATOMIC SPECTROSCOPIC DATA
1807
Persistent Lines of Neutral Lanthanum 共La I兲—Continued
Wavelength 共Å兲
Inten
800
A ki (108 s⫺1 )
2 3
5177.31
1000
5211.86
700
5234.27
700
5455.15
700
5501.34
600
0.529
5791.34
1000
6249.93
600
Configuration
6394.23
J
Level (cm⫺1 )
Wl Ref
F
Do
7/2
5/2
3494.526
22804.25
MCS75
Term
5d ( F)6s
5d 2 ( 3 F)6p
4
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
4
F
Do
9/2
7/2
4121.572
23303.26
MCS75
4
5d 2 ( 3 F)6s
5d6s( 3 D)6p
4
F
9/2
7/2
4121.572
23221.10
MCS75
5d6s 2
5d 2 ( 3 F)6p
2
D
Do
5/2
5/2
1053.164
19379.40
MCS75
5d6s 2
5d 2 ( 3 F)6p
2
D
Do
3/2
3/2
0.000
18172.35
MCS75
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
4
F
F
9/2
9/2
4121.572
21384.00
MCS75
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
4
F
Go
9/2
11/2
4121.572
20117.38
MCS75
5d 2 ( 3 F)6s
5d 2 ( 3 F)6p
4
F
Go
7/2
9/2
3494.526
19129.31
MCS75
4
o
2
2
4 o
4
4
A Ref
M00
Energy Levels of Neutral Lanthanum 共La I兲
Configuration
J
Level (cm⫺1 )
Ref
2
D
3/2
5/2
0.000
1053.164
MZH78
MZH78
5d 2 ( 3 F)6s
4
F
3/2
5/2
7/2
9/2
2668.188
3010.002
3494.526
4121.572
MZH78
MZH78
MZH78
MZH78
5d 2 ( 3 F)6s
2
F
5/2
7/2
7011.909
8052.162
MZH78
MZH78
5d 2 ( 3 P)6s
4
P
1/2
3/2
5/2
7231.407
7490.521
7679.939
MZH78
MZH78
MZH78
5d 2 ( 1 D)6s
2
D
3/2
5/2
8446.044
9183.797
MZH78
MZH78
5d 2 ( 3 P)6s
2
P
1/2
3/2
9044.214
9719.439
MZH78
MZH78
5d 2 ( 1 G)6s
2
G
9/2
7/2
9919.821
9960.904
MZH78
MZH78
5d 3
4
F
3/2
5/2
7/2
9/2
12430.609
12787.404
13238.323
13747.276
MZH78
MZH78
MZH78
MZH78
5d6s( 3 D)6p
4 o
3/2
5/2
7/2
9/2
13260.38
14804.08
15019.51
16243.17
MZH78
MZH78
MZH78
MZH78
5d6s
2
Term
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1808
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Lanthanum 共La I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
5/2
13631.04
MZH78
1/2
3/2
5/2
7/2
14095.69
14708.92
15503.64
16099.29
MZH78
MZH78
MZH78
MZH78
3/2
15031.64
MZH78
3
5d6s( D)6p
o
5d6s( 3 D)6p
4
5d6s( 3 D)6p
o
4 f 6s 2
2 o
5/2
7/2
15196.83
16538.39
MZH78
MZH78
5d6s( 3 D)6p
o
1/2
15219.89
MZH78
6s 2 ( 1 S)6p
o
3/2
16280.26
MZH78
5d 3
4
1/2
3/2
5/2
16617.30
16735.14
17099.38
MZH78
MZH78
MZH78
5d 2 ( 3 F)6p
o
5/2
16856.80
MZH78
5d 2 ( 1 S)6s
2
S
1/2
16991.42
MZH78
5d 3
2
G
7/2
9/2
17023.36
17140.90
MZH78
MZH78
5d6s( 3 D)6p
4 o
1/2
3/2
5/2
17567.49
17797.29
18156.97
MZH78
MZH78
MZH78
5d 2 ( 3 F)6p
o
7/2
17910.17
MZH78
5d 2 ( 3 F)6p
4
Go
5/2
7/2
9/2
11/2
17947.13
18603.92
19129.31
20117.38
MZH78
MZH78
MZH78
MZH78
5d 2 ( 3 F)6p
2
Do
3/2
5/2
18172.35
19379.40
MZH78
MZH78
5d 2 ( 3 F)6p
4 o
3/2
5/2
7/2
9/2
20082.98
20338.25
20763.21
21384.00
MZH78
MZH78
MZH78
MZH78
5d6s( 1 D)6p
o
1/2
20197.34
MZH78
5d 2 ( 3 F)6p
4
1/2
3/2
5/2
7/2
22246.64
22439.36
22804.25
23303.26
MZH78
MZH78
MZH78
MZH78
5d6s( 3 D)6p
o
7/2
23221.10
MZH78
5d6s( 3 D)6p
o
5/2
23874.95
MZH78
4 f 5d( 1 Go)6s
o
7/2
24409.68
MZH78
3
4 f 5d( G )6s
4
5/2
7/2
9/2
11/2
27022.62
27455.31
28089.17
28743.24
MZH78
MZH78
MZH78
MZH78
4 f 5d( 3 Do)6s
o
3/2
27968.54
MZH78
44981
MZH78
Do
F
o
P
P
F
Do
o
G
3
La II ( F2 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1809
Persistent Lines of Singly-ionized Lanthanum 共La II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
0.34
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
M00
2
5d
5d6p
3
a F
x 3Fo
4
4
1970.70
28565.40
MCS75
250
3759.08
400
3790.83
5d 2
5d6p
a 3F
y 3Do
3
2
1016.10
27388.11
MCS75
400
3794.78
5d 2
5d6p
a 3F
y 3Do
4
3
1970.70
28315.25
MCS75
400
3871.64
5d 2
5d6p
a 3F
x 3Fo
3
3
1016.10
26837.66
MCS75
1000
3949.10
5d6s
5d6p
a 3D
x 3Fo
3
4
3250.35
28565.40
MCS75
500
3988.52
5d6s
5d6p
a 3D
y 3Do
3
3
3250.35
28315.25
MCS75
400
3995.75
5d 2
5d6 p
2
2
1394.46
26414.01
MCS75
x 3Fo
300
4031.69
5d6s
5d6p
a 3D
y 3Do
2
2
2591.60
27388.11
MCS75
300
4042.91
5d 2
5d6p
a 1G
x 1Fo
4
3
7473.32
32201.05
MCS75
300
4077.35
5d6s
5d6p
a 3D
x 3Fo
1
2
1895.15
26414.01
MCS75
600
4086.72
5d 2
5d6p
a 3F
y 1Do
2
2
0.00
24462.66
MCS75
500
4123.23
5d6s
5d6p
a 3D
x 3Fo
2
3
2591.60
26837.66
MCS75
500
4333.74
5d 2
5d6 p
2
2
1394.46
24462.66
MCS75
y 1Do
0.552
M00
Energy Levels of Singly-ionized Lanthanum 共La II兲
Configuration
5d
2
Term
3
a F
5d 2
J
Level (cm⫺1 )
Ref
2
3
4
0.00
1016.10
1970.70
MZH78
MZH78
MZH78
2
1394.46
MZH78
5d6s
a 3D
1
2
3
1895.15
2591.60
3250.35
MZH78
MZH78
MZH78
5d 2
a 3P
0
1
2
5249.70
5718.12
6227.42
MZH78
MZH78
MZH78
6s 2
a 1S
0
7394.57
MZH78
5d 2
a 1G
4
7473.32
MZH78
2
10094.86
MZH78
5d6s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1810
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Lanthanum 共La II兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
o
)6s 1/2
4 f ( 2 F5/2
(5/2,1/2)
o
2
3
14147.98
14375.17
MZH78
MZH78
o
)6s 1/2
4 f ( 2 F7/2
(7/2,1/2) o
4
3
15698.74
15773.77
MZH78
MZH78
4 f 5d
z 1Go
4
16599.17
MZH78
4 f 5d
y 3Fo
2
3
4
17211.93
18235.56
19214.54
MZH78
MZH78
MZH78
4 f 5d
z 3Ho
4
5
6
17825.62
18580.41
19749.62
MZH78
MZH78
MZH78
4 f 5d
z 1Do
2
18895.41
MZH78
4 f 5d
z 3Go
3
4
5
20402.82
21331.60
22282.90
MZH78
MZH78
MZH78
4 f 5d
z 3Do
1
2
3
21441.73
22106.02
22537.30
MZH78
MZH78
MZH78
4 f 5d
z 3Po
0
1
2
22683.70
22705.15
23246.93
MZH78
MZH78
MZH78
5d6 p
y 1Do
2
24462.66
MZH78
4 f 5d
y 1Fo
3
24522.70
MZH78
5d6 p
3
o
y D
1
2
3
25973.37
27388.11
28315.25
MZH78
MZH78
MZH78
5d6 p
x 3Fo
2
3
4
26414.01
26837.66
28565.40
MZH78
MZH78
MZH78
5d6 p
o
1
27423.91
MZH78
6s6 p
y 3Po
0
27545.85
MZH78
6s6 p
o
1
28154.55
MZH78
4 f 5d
z 1Ho
5
28525.71
MZH78
6s6 p
o
2
29498.05
MZH78
4 f 5d
y 1Po
1
30353.33
MZH78
5d6 p
3 o
x P
0
1
31785.82
32160.99
MZH78
MZH78
5d6 p
x 1Fo
3
32201.05
MZH78
89200
SR65
La III ( 2 D3/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1811
Lead „Pb…
Atomic number⫽82
Atomic weight⫽207.2
Isotope
204
Pb
Pb
207
Pb
208
Pb
206
Mass
Abundance
Spin
203.973020
205.974440
206.975872
207.976627
1.4%
24.1%
22.1%
52.4%
0
0
1/2
0
Mag moment
⫹0.5926
2
(1/2,1/2) 0
Pb I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 1/2
⫺1
Ionization energy: 59 819.2 cm 共7.416 63 eV兲
o
Pb II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 2P1/2
⫺1
Ionization energy: 121 245.14 cm 共15.032 48 eV兲
Strong Lines of Lead 共Pb兲
Intensity
200
200
1000
1000
500
500
600
400
1000
200
200
150
500
50
20
4
15
200
90
300
120
300
120
100
2
2
1
30
150
10
400
50
80
12
1000
15
50
P
P
P
P
P
P
P,r
P
P,r
r
r
r
P,r
P,r
r
P,r
r
c
P,r
P,r
P
P
P
Wavelength 共Å兲
Vacuum
1060.619
1121.325
1433.906
1512.298
1671.553
1682.127
1726.802
1796.669
1822.052
Air
2022.016
2053.284
2170.005
2203.534
2393.792
2401.940
2411.734
2613.655
2614.175
2663.154
2801.995
2823.189
2833.053
2873.311
3016.387
3220.528
3240.186
3262.355
3572.729
3639.568
3671.491
3683.462
3713.982
3739.935
4019.632
4057.807
4062.136
4152.82
Spectrum
Ref
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
II
II
II
II
II
II
II
II
II
WRSH74
WRSH74
KT96
KT96
KT96
KT96
KT96
KT96
KT96
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
I
I
I
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
II
I
I
I
I
II
WA68
WA68
WA68
WRSH74
WA68
WA68
WA68
WA68
WA68
WA68
WA68
WA68
WA68
WA68
WRSH74
WA68
WA68
WA68
WA68
WA68
WA68
WA68
WRSH74
WA68
WA68
WA68
WA68
WRSH74
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1812
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Lead 共Pb兲—Continued
Wavelength 共Å兲
Intensity
4
100
50
100
50
50
3
250
50
50
50
1
50
50
50
100
6
5
200
200
50
250
100
4
50
50
50
50
50
2
1
4168.033
4244.92
4352.74
4386.46
4579.051
4582.27
5005.416
5042.58
5070.58
5074.53
5111.64
5201.437
5367.64
5372.099
5544.25
5608.85
5895.624
6001.862
6075.74
6081.409
6159.89
6660.20
7193.60
7228.965
7558.97
7632.56
8395.68
9050.82
9063.43
10290.458
10498.965
P,c
P,c
P
c
P,c
P
P
P,c
Spectrum
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
I
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
I
I
II
II
II
II
II
I
II
II
II
II
II
I
I
Ref
WA68
WRSH74
WRSH74
WRSH74
WRSH74
WRSH74
WA68
WRSH74
WRSH74
WRSH74
WRSH74
WA68
WRSH74
WRSH74
WRSH74
WRSH74
WA68
WA68
WRSH74
WRSH74
S75
WRSH74
S75
WA68
S75
S75
WRSH74
WRSH74
WRSH74
WA68
WA68
Persistent Lines of Neutral Lead 共Pb I兲
Inten
200
Wavelength 共Å兲
2022.016
A ki (108 s⫺1 )
0.059
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
共1/2, 1/2兲
(3/2,1/2) o
0
1
0.000
49439.616
WA68
M00
6p 3/27s 1/2
Configuration
2
6 p 1/2
200
2053.284
0.102
2
6p 1/2
6p 1/28s 1/2
共1/2, 1/2兲
(1/2,1/2) o
0
1
0.000
48686.934
WA68
M00
150
2170.005
1.5
2
6p 1/2
6p 1/26d
共1/2, 1/2兲
2
关 3/2兴 o
0
1
0.000
46068.438
WA68
FW96
50
2393.792
6p 1/26 p 3/2
6p 1/27d
共1/2, 3/2兲
2
关 5/2兴 o
2
3
10650.327
52412.325
WA68
200
2614.175
1.9
6p 1/26 p 3/2
6p 1/26d
共1/2, 3/2兲
2
关 3/2兴 o
1
2
7819.263
46060.836
WA68
FW96
300
2801.995
1.6
6p 1/26 p 3/2
6p 1/26d
共1/2, 3/2兲
2
关 5/2兴 o
2
3
10650.327
46328.667
WA68
FW96
300
2833.053
0.58
2
6p 1/2
6p 1/27s 1/2
共1/2, 1/2兲
(1/2,1/2) o
0
1
0.000
35287.224
WA68
FW96
150
3639.568
0.34
6p 1/26 p 3/2
6p 1/27s 1/2
共1/2,3/2兲
(1/2,1/2) o
1
1
7819.263
35287.224
WA68
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1813
Persistent Lines of Neutral Lead 共Pb I兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
400
3683.462
1.5
6p 1/26 p 3/2
6p 1/27s 1/2
共1/2, 3/2兲
(1/2,1/2) o
1
0
7819.263
34959.908
WA68
FW96
80
3739.935
0.73
2
6p 3/2
6p 3/27s 1/2
共3/2, 3/2兲
(3/2,1/2) o
2
2
21457.798
48188.630
WA68
FW96
1000
4057.807
0.89
6p 1/26 p 3/2
6p 1/27s 1/2
共1/2, 3/2兲
(1/2,1/2) o
2
1
10650.327
35287.224
WA68
FW96
15
4062.136
0.92
2
6p 3/2
6p 1/26d
共3/2, 3/2兲
2
关 3/2兴 o
2
1
21457.798
46068.438
WA68
FW96
Configuration
Energy Levels of Neutral Lead 共Pb I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
2
6 p 1/2
共1/2, 1/2兲
0
0.000
WA68
6 p 1/26p 3/2
共1/2, 3/2兲
1
2
7819.263
10650.327
WA68
WA68
2
6 p 3/2
共3/2, 3/2兲
2
0
21457.798
29466.830
WA68
WA68
6 p 1/27s 1/2
(1/2,1/2) o
0
1
34959.908
35287.224
WA68
WA68
6p 1/27p 1/2
共1/2,1/2兲
1
0
42918.643
44400.890
WA68
WA68
6 p 1/27p 3/2
共1/2, 3/2兲
1
2
44674.986
44809.364
WA68
WA68
6 p 1/26d
2
关 5/2兴 o
2
3
45443.171
46328.667
WA68
WA68
6p 1/26d
2
关 3/2兴 o
2
1
46060.836
46068.438
WA68
WA68
6p 3/27s 1/2
(3/2,1/2) o
2
1
48188.630
49439.616
WA68
WA68
6p 1/28s 1/2
(1/2,1/2) o
1
48686.934
WA68
6p 1/27d
2
关 5/2兴 o
2
3
52101.660
52412.325
WA68
WA68
6p 1/27d
2
关 3/2兴 o
2
1
52311.315
52499.639
WA68
WA68
59819.2
WA68
o
)
Pb II ( 2 P1/2
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1814
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Lead 共Pb II兲
Inten
1000
1000
600
1000
500
100
100
250
100
200
200
250
Wavelength 共Å兲
A ki (108 s⫺1 )
1433.906
2
14.1
1512.298
1726.802
1822.052
11.8
2203.534
Configuration
4.94
4244.92
4386.46
5042.58
5608.85
6075.74
6081.409
6660.20
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
6s 6 p
6s 2 6d
2 o
P
D
1/2
3/2
0.000
69739.603
KT96
6s 2 6 p
6s6p 2
2 o
P
P
1/2
3/2
0.000
66124.53
KT96
6s 2 6 p
6s6p 2
2 o
P
P
1/2
1/2
0.000
57910.48
KT96
6s 2 6 p
6s 2 6d
2 o
P
D
3/2
5/2
14081.074
68964.310
KT96
M00
6s 2 6 p
6s 2 7s
2 o
P
S
3/2
1/2
14081.074
59448.56
WRSH74
M00
6s 2 6d
6s 2 5 f
2
D
F
5/2
7/2
68964.310
92515.24
WRSH74
6s 2 6d
6s 2 5 f
2
D
F
3/2
5/2
69739.603
92530.66
WRSH74
6s 2 7 p
6s 2 7d
2 o
P
D
1/2
3/2
74458.99
94284.58
WRSH74
6s 2 7s
6s 2 7 p
2
S
P
1/2
3/2
59448.56
77272.57
WRSH74
6s 2 5 f
6s 2 6g
2 o
F
G
7/2
9/2
92515.24
108969.58
WRSH74
6s 2 5 f
6s 2 6g
2 o
F
G
5/2
7/2
92530.66
108969.67
WRSH74
6s 2 7s
6s 2 7 p
2
S
P
1/2
1/2
59448.56
74458.99
WRSH74
2
4
4
2
2
2 o
2 o
2
2 o
2
2
2 o
M00
Energy Levels of Singly-ionized Lead 共Pb II兲
J
Level (cm⫺1 )
Ref
2 o
1/2
3/2
0.000
14081.074
WRSH74
WRSH74
6s6 p 2
4
P
1/2
3/2
5/2
57910.48
66124.53
73905.708
WRSH74
WRSH74
WRSH74
6s 2 7s
2
S
1/2
59448.56
WRSH74
6s 2 6d
2
D
5/2
3/2
68964.310
69739.603
WRSH74
WRSH74
6s 2 7p
2 o
1/2
3/2
74458.99
77272.57
WRSH74
WRSH74
6s6 p 2
2
D
5/2
88972.16
WRSH74
6s 2 8s
2
S
1/2
89180.18
WRSH74
6s 2 5 f
2 o
7/2
5/2
92515.24
92530.66
WRSH74
WRSH74
Configuration
Term
6s 2 6p
P
P
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1815
Energy Levels of Singly-ionized Lead 共Pb II兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
2
6s 7d
2
D
3/2
5/2
94284.58
95304.25
WRSH74
WRSH74
6s 2 6g
2
G
9/2
7/2
108969.58
108969.67
WRSH74
WRSH74
Limit
121245.14
RWS76
Pb III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1816
J. E. SANSONETTI AND W. C. MARTIN
Lithium „Li…
Atomic number⫽3
Atomic weight⫽6.941
Isotope
6
7
Li
Li
Mass
Abundance
Spin
Mag moment
6.015121
7.016003
7.5%
92.5%
1
3/2
⫹0.822056
⫹3.25644
Li I Ground state: 1s 2 2s 2S1/2
Ionization energy: 43 487.150 cm⫺1 共5.391 719 eV兲
Li II Ground state: 1s 2 1S0
Ionization energy: 610 078 cm⫺1 共75.6400 eV兲
Strong Lines of Lithium 共Li兲
Intensity
30
300 P
1000 P
10
10
30
10
50
20
10
60
15
30
6
15
30
6
40
50
10
10
20
15
10
10
15
30
20
10
15
20
30
20
20
7
50*
50*
40
20
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
171.575
178.014
199.280
944.73
1017.88
1131.88
1166.63
1198.092
1237.29
1253.32
1420.900
1492.931
1492.973
1493.036
1653.077
1653.132
1653.213
1681.661
1755.332
Air
2329.836
2381.538
2383.199
2402.331
2410.842
2429.814
2506.940
2508.785
2539.487
2551.70
2605.081
2657.293
2657.303
2674.460
2728.288
2728.315
2730.473
2730.551
2766.989
2790.313
Spectrum
Ref
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
R37
R37
R37
SO82
SO82
SO82
SO82
HM59
SO82
SO82
DM01
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
SO82
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
ATOMIC SPECTROSCOPIC DATA
1817
Strong Lines of Lithium 共Li兲—Continued
Intensity
20*
20*
20*
20*
20
10
70*
70*
2*
2*
50
40
30
2*
2*
10
15
15
15
30*
30*
30
10
80
25
80
15
15
5
5
10
15
300
500
400
300
400*
400*
500
1000
150
300
100
2*
2*
2*
10
5
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3029.121
3029.136
3155.308
3155.330
3196.330
3196.356
3199.332
3199.434
3232.633
3232.643
3249.868
3306.284
3684.320
4132.624
4132.625
4155.946
4325.419
4325.471
4602.831
4602.898
4602.902
4671.651
4671.705
4678.056
4678.290
4788.363
4881.320
4881.386
4881.490
4971.665
4971.748
5037.915
5483.56
5484.50
5485.11
6103.542
6103.654
6103.667
6707.775
6707.926
8126.232
8126.453
9581.42
18703.01
18703.11
18703.14
26877.67
26878.36
Spectrum
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
Li
II
II
II
II
II
II
II
II
I
I
II
II
II
I
I
II
II
II
I
I
I
II
II
II
II
II
II
II
II
I
I
II
II
II
II
I
I
I
I
I
I
I
II
I
I
I
I
I
Ref
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
REB95
REB95
HM59
HM59
HM59
REB95
REB95
DM01
HM59
HM59
REB95
REB95
REB95
HM59
HM59
HM59
HM59
HM59
HM59
HM59
HM59
REB95
REB95
HM59
HM59
HM59
HM59
REB95
REB95
REB95
REB95
REB95
REB95
REB95
SO82
REB95
REB95
REB95
REB95
REB95
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1818
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Lithium 共Li I兲
Inten
Wavelength 共Å兲
15
4602.831
30
4602.898
300
6103.542
400
6103.654
500
6707.775
1000
6707.926
150
8126.232
300
10
5
8126.453
26877.67
26878.36
A ki (108 s⫺1 )
0.223
0.223
0.686
0.686
0.369
0.369
0.349
0.349
0.038
0.038
J
Level (cm⫺1 )
Wl Ref
P
D
1/2
3/2
14903.622
36623.297
REB95
FW96
2p
4d
2 o
P
D
3/2
5/2
14903.957
36623.312
REB95
FW96
2p
3d
2 o
P
D
1/2
3/2
14903.622
31283.018
REB95
FW96
2p
3d
2 o
P
D
3/2
5/2
14903.957
31283.053
REB95
FW96
2s
2p
2
S
P
1/2
3/2
0.000
14903.957
REB95
FW96
2s
2p
2
S
P
1/2
1/2
0.000
14903.622
REB95
FW96
2p
3s
2 o
P
S
1/2
1/2
14903.622
27206.066
REB95
WSG66
2p
3s
2 o
P
S
3/2
1/2
14903.957
27206.066
REB95
WSG66
3s
3p
2
S
P
1/2
3/2
27206.066
30925.613
REB95
WSG66
3s
3p
2
S
P
1/2
1/2
27206.066
30925.517
REB95
WSG66
Configuration
Term
2p
4d
2 o
2
2
2
2
2 o
2 o
2
2
2 o
2 o
A Ref
Energy Levels of Neutral Lithium 共Li I兲
Ref
Term
2s
2
S
1/2
0.000
REB95
2p
2 o
P
1/2
3/2
14903.622
14903.957
REB95
REB95
3s
2
S
1/2
27206.066
REB95
3p
2 o
P
1/2
3/2
30925.517
30925.613
REB95
REB95
3d
2
D
3/2
5/2
31283.018
31283.053
REB95
REB95
4p
2 o
P
1/2
3/2
36469.714
36469.754
REB95
REB95
4d
2
D
3/2
5/2
36623.297
36623.312
REB95
REB95
Limit
43487.150
K87
Li II 1s 2 ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
ATOMIC SPECTROSCOPIC DATA
1819
Persistent Lines of Singly-ionized Lithium 共Li II兲
Inten
Wavelength 共Å兲
300
178.014
1000
199.280
A ki (108 s⫺1 )
77.9
256
Configuration
Term
J
Level (cm⫺1 )
1s 2
1s3 p
1
1 o
S
P
0
1
0.
561751.50
R37
WSG66
1s 2
1s2 p
1 o
S
P
0
1
0.
501807.59
R37
WSG66
S
P
1
0
476034.24
494265.57
HM59
WSG66
S
P
1
2
476034.24
494262.48
HM59
WSG66
S
P
1
1
476034.24
494260.32
HM59
WSG66
S
P
0
1
491373.58
501807.59
TE62
WSG66
1
300
5483.56
0.228
1s2s
1s2 p
3
500
5484.50
0.228
1s2s
1s2 p
3
400
5485.11
0.228
1s2s
1s2 p
3
100
9581.42
0.0518
1s2s
1s2 p
1
3 o
3 o
3 o
1 o
Wl Ref
A Ref
Energy Levels of Singly-ionized Lithium 共Li II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
1s2s
3
S
1
476034.24
HM59
1s2s
1
S
0
491373.58
TE62
1s2p
3 o
P
1
2
0
494260.32
494262.48
494265.57
HM59
HM59
HM59
1s2 p
1 o
P
1
501807.59
HM59
1s3s
3
S
1
554753.69
HM59
1s3s
1
S
0
558776.88
HM59
1s3p
3 o
P
1
2
0
559499.53
559500.39
559501.32
HM59
HM59
HM59
1s3 p
1 o
1
561751.50
DM01
Limit
610078.4
DM01
1s
2
Li III 1s ( 2 S1/2)
P
0.
HM59
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1820
J. E. SANSONETTI AND W. C. MARTIN
Lutetium „Lu…
Atomic number⫽17
Atomic weight⫽174.967
Isotope
175
Lu
Lu
176
Mass
Abundance
Spin
Mag moment
174.940770
175.942679
97.41%
2.59%
7/2
7
⫹2.2327
⫹3.19
Lu I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 )5d6s 2 2D3/2
Ionization energy: 43 762.50 cm⫺1 共5.425 86 eV兲
Lu II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 )6s 2 1S0
Ionization energy: 112 000 cm⫺1 共13.9 eV兲
Strong Lines of Lutetium 共Lu兲
Intensity
90
90
100
1000
100
150
80
250
60
200
100
150
150
80
400
250
500
250
130
250
150
120
400
700
400
300
250
500
1000
800
1000
800
120
200
250
250
500
200
250
600
P,h
P
h
P
h
P
h
h
P
P
P
P
P
P
P,h
P
P
P
P
P
P
P
P
P
P,c
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2195.54
2578.79
2613.40
2615.42
2619.26
2657.80
2685.08
2701.71
2728.95
2754.17
2765.74
2796.63
2847.51
2885.14
2894.84
2900.30
2911.39
2963.32
2969.82
2989.27
3020.54
3056.72
3077.60
3081.47
3118.43
3171.36
3254.31
3278.97
3281.74
3312.11
3359.56
3376.50
3385.50
3396.82
3397.07
3472.48
3507.39
3508.42
3554.43
3567.84
Spectrum
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
II
II
II
II
II
II
I
II
I
II
I
II
II
I
II
II
II
II
II
I
II
II
II
I
I
I
II
I
I
I
I
I
I
I
II
II
II
I
II
I
Ref.
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1821
Strong Lines of Lutetium 共Lu兲—Continued
Wavelength 共Å兲
Intensity
90
300
400
60
90
400
60
90
400
130
60
110
400
70
120
70
200
60
120
60
Spectrum
3636.25
3647.77
3841.18
3968.46
4054.45
4124.73
4154.08
4184.25
4518.57
4658.02
4904.88
5001.14
5135.09
5402.57
5476.69
5736.55
6004.52
6055.03
6221.87
6463.12
P
P
P
P
P
P
P
P
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Ref.
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
I
I
I
II
II
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Lutetium 共Lu I兲
Inten
700
400
500
1000
800
1000
800
600
300
400
400
400
Wavelength 共Å兲
3081.47
3118.43
3278.97
3281.74
3312.11
3359.56
3376.50
3567.84
3647.77
3841.18
4124.73
4518.57
A ki (108 s⫺1 )
2.62
2.03
1.00
3.05
1.85
2.44
1.68
0.69
0.92
0.265
0.89
0.226
Configuration
2
2
5d( D)6s
5d6s( 3 D)6p
5d( 2 D)6s 2
5d6s( 3 D)6p
5d( 2 D)6s 2
6s 2 ( 1 S)7p
5d( 2 D)6s 2
5d6s( 1 D)6p
5d( 2 D)6s 2
5d6s( 3 D)6p
5d( 2 D)6s 2
5d6s( 3 D)6p
5d( 2 D)6s 2
5d6s( 1 D)6p
5d( 2 D)6s 2
5d6s( 1 D)6p
6s 2 ( 1 S)6p
6s 2 ( 1 S)6d
5d( 2 D)6s 2
5d6s( 1 D)6p
6s 2 ( 1 S)6p
6s 2 ( 1 S)6d
5d( 2 D)6s 2
5d6s( 3 D)6p
J
Level (cm⫺1 )
Wl Ref
A Ref
D
P
5/2
3/2
1993.92
34436.49
MCS75
FHLP00
D
P
3/2
1/2
0.00
32058.1
MCS75
FHLP00
D
P
3/2
3/2
0.00
30488.62
MCS75
FHLP00
D
Do
5/2
5/2
1993.92
32456.87
MCS75
FHLP00
D
F
3/2
5/2
0.00
30183.55
MCS75
FHLP00
D
F
5/2
7/2
1993.92
31751.17
MCS75
FHLP00
D
Do
3/2
3/2
0.00
29607.98
MCS75
FHLP00
D
F
3/2
5/2
0.00
28020.18
MCS75
FHLP00
2 o
P
D
1/2
3/2
4136.00
31542.24
MCS75
FHLP00
D
F
5/2
5/2
1993.92
28020.18
MCS75
FHLP00
2 o
P
D
3/2
5/2
7476.35
31713.60
MCS75
FHLP00
D
Do
3/2
3/2
0.00
22124.70
MCS75
FHLP00
Term
2
2 o
2
2 o
2
2 o
2
2
2
2 o
2
2 o
2
2
2
2 o
2
2
2 o
2
2
2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1822
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Lutetium 共Lu I兲—Continued
Inten
Wavelength 共Å兲
400
5135.09
200
6004.52
A ki (108 s⫺1 )
Configuration
2
2
5d( D)6s
5d6s( 3 D)6p
0.091
6s 2 ( 1 S)6p
6s 2 ( 1 S)7s
0.49
J
Level (cm⫺1 )
Wl Ref
A Ref
D
Do
5/2
5/2
1993.92
21462.35
MCS75
FHLP00
2 o
3/2
1/2
7476.35
24125.86
MCS75
FHLP00
Term
2
2
2
P
S
Energy Levels of Neutral Lutetium 共Lu I兲
J
Level (cm⫺1 )
Ref
2
D
3/2
5/2
0.00
1993.92
MZH78
MZH78
6s 2 ( 1 S)6p
2 o
P
1/2
3/2
4136.00
7476.35
MZH78
MZH78
5d6s( 3 D)6p
4 o
F
3/2
5/2
7/2
9/2
17427.28
18504.56
20432.53
22609.46
MZH78
MZH78
MZH78
MZH78
5d 2 ( 3 F)6s
4
F
3/2
5/2
7/2
9/2
18851.31
19403.31
20247.29
21242.26
MZH78
MZH78
VW78
VW78
5d6s( 3 D)6p
4
Do
1/2
3/2
5/2
7/2
20762.42
21195.37
22221.64
23524.24
MZH78
MZH78
MZH78
MZH78
5d6s( 3 D)6p
2
Do
5/2
3/2
21462.35
22124.70
MZH78
MZH78
5d 2 ( 3 P)6s
4
P
1/2
3/2
5/2
21472.33
22467.53
25860.76
MZH78
MZH78
MZH78
5d6s( 3 D)6p
4 o
P
1/2
3/2
5/2
24108.72
24308.20
25191.57
MZH78
MZH78
MZH78
6s 2 ( 1 S)7s
2
S
1/2
24125.86
MZH78
5d 2 ( 1 D?)6s
2
D
3/2
5/2
24518.16
24711.19
MZH78
MZH78
5d 2 ( 1 G)6s
2
G
7/2
9/2
26570.40
26671.32
MZH78
MZH78
5d 2 ( 3 F)6s
2
F
5/2
7/2
—
27991.75
MZH78
Configuration
2
5d( D)6s
2
Term
5d6s( 1 D)6p
2 o
F
5/2
7/2
28020.18
29486.94
MZH78
MZH78
5d 2 ( 3 P?)6s
2
P
1/2
3/2
28793.34
29937.81
MZH78
MZH78
6s 2 ( 1 S)7p
2 o
1/2
3/2
29430.90
30488.62
MZH78
MZH78
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1823
Energy Levels of Neutral Lutetium 共Lu I兲—Continued
J
Level (cm⫺1 )
5d6s( D)6p
2
o
D
3/2
29607.98
MZH78
5d6s( 3 D)6p
2 o
F
5/2
7/2
30183.55
31751.17
MZH78
MZH78
5d 2 ( 1 S)6s
2
S
1/2
30747.18
MZH78
5d6s( 1 D)6p
2 o
P
3/2
1/2
31523.14
33443.20
MZH78
MZH78
6s 2 ( 1 S)6d
2
D
3/2
5/2
31542.24
31713.60
MZH78
MZH78
5d6s( 3 D)6p
2 o
P
1/2
3/2
32058.1
34436.49
MZH78
MZH78
5d6s( 1 D)6p
2
Do
5/2
32456.87
MZH78
Limit
43762.50
CT72,MMMS89
Configuration
Term
1
Lu II ( 1 S0 )
Ref
Persistent Lines of Singly-ionized Lutetium 共Lu II兲
Inten
90
1000
250
200
400
250
500
250
150
400
250
250
250
Wavelength 共Å兲
A ki (108 s⫺1 )
2195.54
0.714
2615.42
4.53
2701.71
2754.17
2894.84
0.92
1.66
2900.30
2911.39
2.42
2963.32
3020.54
3077.60
3254.31
3397.07
3472.48
1.24
0.60
Configuration
6s 2
5d6p
6s 2
6s6 p
Term
J
Level (cm⫺1 )
Wl Ref
1
0
1
0.00
45532.33
MCS75
M00
S
P
0
1
0.00
38223.49
MCS75
M00
D
P
3
2
14199.08
51201.66
MCS75
D
Do
2
3
12435.32
48733.19
MCS75
QPBM99
D
Do
3
3
14199.08
48733.19
MCS75
QPBM99
D
Do
2
2
12435.32
46904.38
MCS75
D
F
3
4
14199.08
48536.83
MCS75
D
Do
1
1
11796.24
45532.33
MCS75
D
Do
2
1
12435.32
45532.33
MCS75
D
F
2
3
12435.32
44918.68
MCS75
QPBM99
D
F
3
3
14199.08
44918.68
MCS75
QPBM99
D
F
1
2
11796.24
41224.96
MCS75
D
F
2
2
12435.32
41224.96
MCS75
3
S
Do
1
1 o
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
5d6s
5d6p
3
3 o
3
3
3
3 o
3
3
3 o
3 o
3 o
3 o
A Ref
QPBM99
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1824
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Lutetium 共Lu II兲—Continued
Inten
Wavelength 共Å兲
500
250
120
120
A ki (108 s⫺1 )
3507.39
0.125
3554.43
5476.69
6221.87
0.099
Configuration
2
6s
6s6 p
Term
J
Level (cm⫺1 )
Wl Ref
1
S
P
0
1
0.00
28503.16
MCS75
D
Do
2
2
17332.58
45458.56
MCS75
D
P
3
2
14199.08
32453.26
MCS75
D
P
2
1
12435.32
28503.16
MCS75
3 o
5d6s
5d6p
1
5d6s
6s6 p
3
5d6s
6s6 p
3
1
3 o
3 o
A Ref
M00
QPBM99
Energy Levels of Singly-ionized Lutetium 共Lu II兲
Level (cm⫺1 )
Configuration
Term
J
6s 2
1
S
0
0.00
MZH78
5d6s
3
D
1
2
3
11796.24
12435.32
14199.08
MZH78
MZH78
MZH78
5d6s
1
D
2
17332.58
MZH78
6s6p
3 o
0
1
2
27264.40
28503.16
32453.26
MZH78
MZH78
MZH78
5d 2
3
2
3
4
29406.70
30889.09
32503.62
MZH78
MZH78
MZH78
5d 2
3
0
1
2
35652.1
36557.05
38574.94
MZH78
MZH78
MZH78
2
36098.18
MZH78
P
F
P
5d 2
Ref
6s6p
1 o
P
1
38223.49
MZH78
5d6 p
3 o
F
2
3
4
41224.96
44918.68
48536.83
MZH78
MZH78
MZH78
5d6 p
1
Do
2
45458.56
MZH78
5d6 p
3
Do
1
2
3
45532.33
46904.38
48733.19
MZH78
MZH78
MZH78
5d6 p
3 o
P
0
1
2
49963.58
50049.20
51201.66
MZH78
MZH78
MZH78
5d6 p
1 o
F
3
53079.33
MZH78
5d6 p
1 o
P
1
59122.4
MZH78
6s7s
3
S
1
63774.3
MZH78
6s7s
1
S
0
68988.80
MZH78
Lu III ( 2 S1/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
112000
MZH78
ATOMIC SPECTROSCOPIC DATA
1825
Magnesium „Mg…
Atomic number⫽12
Atomic weight⫽24.3050
Isotope
24
Mg
Mg
26
Mg
25
Mass
Abundance
Spin
Mag moment
23.985042
24.985837
25.982593
78.99%
10.00%
11.01%
0
5/2
0
⫺0.85545
Mg I Ground state: 1s 2 2s 2 2p 6 3s 2 1S0
Ionization energy: 61 671.05 cm⫺1 共7.646 235 eV兲
Mg II Ground state: 1s 2 2s 2 2p 6 3s 2S1/2
Ionization energy: 121 267.64 cm⫺1 共15.035 27 eV兲
Strong Lines of Magnesium 共Mg兲
Intensity
14
12
25
20
15
15
20
20
25
20
30
2
2
40
50
3
40
50
5
P
P
P
P
2
2
6
5
15*
15*
5
6
13
1000
15
600
2
2
3
1000
2
3
4
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
1025.9681
1026.1134
1239.9253
1240.3946
1367.257
1367.708
1369.423
1476.000
1478.004
1480.880
1482.890
1683.412
1707.061
1734.852
1737.628
1747.794
1750.663
1753.474
1827.934
Air
2025.824
2736.542
2776.690
2778.270
2779.820
2779.834
2781.416
2782.972
2790.776
2795.5301
2797.998
2802.7056
2846.716
2848.342
2851.660
2852.1251
2938.473
3091.065
3092.984
Spectrum
Ref
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
I
II
II
I
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
I
I
I
I
I
I
I
I
II
II
II
II
I
I
I
I
I
I
I
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
PTW98
KM91a
PTW98
KM91a
KM91a
KM91a
PTW98
KM91a
KM91a
KM91a
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1826
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Magnesium 共Mg兲—Continued
Intensity
Wavelength 共Å兲
2
3
25 P
50 P
80 P
2
3
10
14 P
13 P
5
12 P
40 P
70 P
5
10
11 d
2
3
3
3
2
12
13
3
10
11
2
2
2
10
3
11
2
10
11
3
14
13
2
5
10 d
10
4
3
3
3
12
11
2
3
3
14
6
11
10
4
4
5
3096.890
3329.919
3829.355
3832.300
3838.292
4167.271
4351.906
4390.572
4481.126
4481.325
4571.096
5167.322
5172.684
5183.604
5711.088
6346.742
6545.973
7387.685
7657.603
7659.152
7659.902
7691.550
7877.054
7896.366
8213.034
8213.987
8234.636
8346.120
8712.689
8717.825
8734.980
8736.021
8745.663
8806.757
8824.318
8835.080
8923.569
9218.250
9244.265
9246.499
9255.778
9327.545
9340.542
9414.964
9429.814
9432.764
9438.783
9631.892
9632.431
9983.20
9986.48
9993.21
10092.16
10811.08
10914.23
10951.78
10953.32
10957.30
10965.45
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
I
I
I
I
I
I
I
II
II
II
I
I
I
I
I
II
II
I
I
I
I
I
II
II
I
II
II
I
I
I
II
I
II
I
II
II
I
II
II
I
I
II
II
I
I
I
I
II
II
I
I
I
II
I
II
II
I
I
I
Ref
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
ATOMIC SPECTROSCOPIC DATA
1827
Strong Lines of Magnesium 共Mg兲—Continued
Wavelength 共Å兲
Intensity
2
2
8P
5
5
6P
5
4
5
Spectrum
11032.10
11033.66
11828.17
12083.65
14877.53
15025.00
15040.25
15047.71
17108.63
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Ref
I
I
I
I
I
I
I
I
I
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
KM91a
Persistent Lines of Neutral Magnesium 共Mg I兲
Inten
2
15*
15*
1000
25
50
Wavelength 共Å兲
A ki (108 s⫺1 )
2025.824
0.612
2779.820
2779.834
2852.1251
3829.355
3832.300
1.31
3.92
5.00
0.940
1.27
0.703
80
12
40
70
8
6
3838.292
5167.322
5172.684
5183.604
11828.17
15025.00
1.68
0.116
0.346
0.575
0.26
0.139
Term
J
Level (cm⫺1 )
Wl Ref
1
S
P
0
1
0.000
49346.729
KM91a
M03
3s3 p
3p2
3 o
P
P
1
1
21870.464
57833.40
KM91a
WSM69
3s3 p
3p2
3 o
P
P
2
2
21911.178
57873.94
KM91a
WSM69
S
P
0
1
0.000
35051.264
PTW98
FW96
3s3p
3s3d
3 o
P
D
0
1
21850.405
47957.058
KM91a
WSM69
3s3p
3s3d
3 o
P
D
1
2
21870.464
47957.027
KM91a
WSM69
3s3p
3s3d
3 o
P
D
1
1
21870.464
47957.058
3s3p
3s3d
3 o
P
D
2
3
21911.178
47957.045
KM91a
WSM69
3s3p
3s4s
3 o
P
S
0
1
21850.405
41197.403
KM91a
FW96
3s3p
3s4s
3 o
P
S
1
1
21870.464
41197.403
KM91a
FW96
3s3p
3s4s
3 o
P
S
2
1
21911.178
41197.403
KM91a
FW96
3s3p
3s4s
1 o
P
S
1
0
35051.264
43503.333
KM91a
WSM69
3s4s
3s4 p
3
S
P
1
2
41197.403
47851.162
KM91a
WSM69
Configuration
3s 2
3s4 p
3s 2
3s3 p
1 o
3
3
1
1 o
3
3
3
3
3
3
3
1
3 o
A Ref
WSM69
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1828
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Magnesium 共Mg I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
0.000
MZ80
3s3p
3 o
P
0
1
2
21850.405
21870.464
21911.178
MZ80
MZ80
MZ80
3s3 p
1 o
P
1
35051.264
MZ80
3s4s
3
S
1
41197.403
MZ80
3s4s
1
S
0
43503.333
MZ80
3s3d
1
D
2
46403.065
MZ80
3s4p
3 o
P
0
1
2
47841.119
47844.414
47851.162
MZ80
MZ80
MZ80
3s3d
3
D
2
3
1
47957.027
47957.045
47957.058
MZ80
MZ80
MZ80
3s4p
1 o
P
1
49346.729
MZ80
3s5s
3
S
1
51872.526
MZ80
3s5s
1
S
0
52556.206
MZ80
3s4d
1
D
2
53134.642
MZ80
3s4d
3
D
3
2
1
54192.256
54192.294
54192.335
MZ80
MZ80
MZ80
3s5p
3 o
P
0
1
2
54248.809
54250.086
54252.726
MZ80
MZ80
MZ80
3s4 f
1 o
F
3
54676.438
MZ80
3s4 f
3 o
F
2
3
4
54676.654
54676.701
54676.755
MZ80
MZ80
MZ80
3s5 p
1 o
P
1
54706.536
MZ80
3s6s
3
S
1
55891.80
MZ80
3s6s
1
S
0
56186.873
MZ80
3s5d
1
D
2
56308.381
MZ80
3s5d
3
D
3
2
1
56968.218
56968.248
56968.271
MZ80
MZ80
MZ80
3s6p
3 o
P
0
1
2
57017.078
57017.724
57019.025
MZ80
MZ80
MZ80
3s5 f
1 o
3
57204.163
MZ80
3s
2
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1829
Energy Levels of Neutral Magnesium 共Mg I兲—Continued
J
Level (cm⫺1 )
3s5 f
3 o
F
2
3
4
57204.228
57204.267
57204.305
MZ80
MZ80
MZ80
3s6 p
1 o
P
1
57214.992
MZ80
3s5g
G
3,4
57262.760
MZ80
3p2
3
0
1
2
57812.77
57833.40
57873.94
MZ80
MZ80
MZ80
Limit
61671.05
KM91a
Configuration
Term
P
Mg II ( 2 S1/2)
Ref
Persistent Lines of Singly-ionized Magnesium 共Mg II兲
Inten
14
12
25
20
13
1000
15
600
14
13
Wavelength 共Å兲
A ki (108 s⫺1 )
1025.9681
0.032
1026.1134
0.032
1239.9253
0.014
1240.3946
0.015
2790.7767
4.0
2795.5301
2.6
2797.998
4.8
2802.7056
2.6
4481.126
2.23
4481.325
2.08
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
1/2
3/2
0.00
97468.92
KM91a
M03
S
P
1/2
1/2
0.00
97455.12
KM91a
M03
S
P
1/2
3/2
0.00
80650.02
KM91a
M03
S
P
1/2
1/2
0.00
80619.50
KM91a
M03
3p
3d
2 o
P
D
1/2
3/2
35669.31
71491.06
KM91a
FW96
3s
3p
2
S
P
1/2
3/2
0.00
35760.88
PTW98
FW96
3p
3d
2 o
P
D
3/2
5/2
35760.88
71490.19
KM91a
FW96
3s
3p
2
S
P
1/2
1/2
0.00
35669.31
PTW98
FW96
3d
4f
2
D
F
5/2
7/2
71490.19
93799.75
KM91a
FW96
3d
4f
2
D
F
3/2
5/2
71491.06
93799.63
KM91a
FW96
Configuration
Term
3s
5p
2
3s
5p
2
3s
4p
2
3s
4p
2
2 o
2 o
2 o
2 o
2
2 o
2
2 o
2 o
2 o
Energy Levels of Singly-ionized Magnesium 共Mg II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
3s
2
S
1/2
0.00
MZ80
3p
2 o
P
1/2
3/2
35669.31
35760.88
MZ80
MZ80
4s
2
S
1/2
69804.95
MZ80
3d
2
D
5/2
3/2
71490.19
71491.06
MZ80
MZ80
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1830
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Magnesium 共Mg II兲—Continued
J
Level (cm⫺1 )
4p
2 o
P
1/2
3/2
80619.50
80650.02
MZ80
MZ80
5s
2
S
1/2
92790.51
MZ80
4d
2
D
5/2
3/2
93310.59
93311.11
MZ80
MZ80
4f
2 o
F
5/2
7/2
93799.63
93799.75
MZ80
MZ80
5p
2 o
P
1/2
3/2
97455.12
97468.92
MZ80
MZ80
6s
2
S
1/2
103196.75
MZ80
Limit
121267.64
KM91a
Configuration
Term
Mg III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1831
Manganese „Mn…
Atomic number⫽25
Atomic weight⫽54.938 05
Isotope
55
Mn
Mass
Abundance
Spin
Mag moment
54.938047
100%
5/2
⫹3.4687
Mn I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 5 4s 2 6S5/2
Ionization energy: 59 959.4 cm⫺1 共7.434 02 eV兲
Mn II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 5 4s 7S3
Ionization energy: 126 145.0 cm⫺1 共15.6400 eV兲
Strong Lines of Manganese 共Mn兲
Intensity
8
7
400 P
500 P
700
60
60
11
20
30
7
8
8
8
8
12
20
20
1000
20
9
500
9
8
400
15
40
15
15
11
7
9
9
7
13
8
11
7
9
7
P
P
P
P
Wavelength 共Å兲
Vacuum
1915.10
1921.250
1996.056
1999.511
Air
2003.849
2092.159
2109.585
2208.806
2213.855
2221.837
2534.221
2535.658
2537.919
2548.750
2558.605
2563.642
2572.755
2575.509
2576.103
2584.302
2592.944
2593.720
2595.763
2598.905
2605.680
2610.200
2618.145
2625.606
2632.354
2638.173
2639.849
2672.581
2688.247
2701.024
2701.698
2703.98
2705.732
2707.544
2708.452
2710.336
Spectrum
Ref
Mn
Mn
Mn
Mn
II
II
I
I
IV64
IV64
CMG64
CMG64
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
I
I
I
I
I
I
II
II
II
II
II
II
I
I
II
I
I
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
IV64
IV64
IV64
IV64
IV64
IV64
CMG64
CMG64
KG00
CMG64
CMG64
KG00
CMG64
IV64
KG00
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
IV64
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1832
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Manganese 共Mn兲—Continued
Intensity
9
250
200
140
7
13
7
90
120
9
150
12
9
40
11
30
12
25
11
11
15
8
60
30
30
25
15
12
8
13
40
50
40
14
80
25
50
25
11
15
15
13
11
10
10
120
25
80
14
20
50
13
25
13
60
1000
700
400
60
Wavelength 共Å兲
P
P
P
P
P
h
P
P
h
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2711.568
2794.817
2798.270
2801.084
2879.482
2889.600
2900.154
2933.054
2939.308
2940.331
2949.205
3044.566
3054.362
3228.092
3230.716
3236.778
3243.777
3248.512
3252.949
3256.137
3330.775
3336.394
3441.985
3460.314
3474.038
3482.904
3488.675
3495.833
3497.525
3531.836
3532.110
3547.794
3548.022
3548.182
3569.494
3569.804
3577.870
3586.540
3595.110
3607.530
3608.485
3610.298
3619.272
3693.671
3790.214
3806.715
3809.593
3823.508
3823.891
3833.865
3834.368
3839.779
3841.074
3843.988
4018.106
4030.755
4033.068
4034.485
4035.729
Spectrum
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
II
I
I
I
II
II
II
II
II
I
II
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
IV64
CMG64
CMG64
CMG64
IV64
IV64
IV64
KG00
KG00
CMG64
KG00
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
IV64
IV64
KG00
KG00
KG00
KG00
KG00
KG00
KG00
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
ATOMIC SPECTROSCOPIC DATA
1833
Strong Lines of Manganese 共Mn兲—Continued
Intensity
Wavelength 共Å兲
200 P
40
70
40
25
25
11
25
25
40
40
14
20
11
11
10
4
13
30
10
20
11
9
9
40
30
11
20
30
40
11
4041.357
4048.747
4055.548
4058.936
4061.737
4063.530
4070.280
4079.241
4079.415
4082.945
4083.634
4235.154
4235.300
4257.669
4265.928
4281.100
4326.633
4414.887
4451.575
4458.263
4462.033
4464.679
4498.897
4502.223
4754.048
4762.376
4765.856
4766.426
4783.432
4823.528
6021.787
Spectrum
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
IV64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
CMG64
Persistent Lines of Neutral Manganese 共Mn I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
6
400
1996.056
0.77
3d 4s
3d 5 ( 4 P)4s4 p( 3 Po)
a S
v 6Po
5/2
3/2
0.00
50099.03
CMG64
M91
500
1999.511
0.76
3d 5 4s 2
3d 5 ( 4 P)4s4 p( 3 Po)
a 6S
v 6Po
5/2
5/2
0.00
50012.50
CMG64
M91
700
2003.849
0.76
3d 5 4s 2
3d 5 ( 4 P)4s4 p( 3 Po)
a 6S
v 6Po
5/2
7/2
0.00
49888.01
CMG64
M91
250
2794.817
3.7
3d 5 4s 2
3d 5 ( 6 S)4s4 p( 1 Po)
a 6S
y 6Po
5/2
7/2
0.00
35769.97
CMG64
FW96
200
2798.270
3.6
3d 5 4s 2
3d 5 ( 6 S)4s4 p( 1 Po)
a 6S
y 6Po
5/2
5/2
0.00
35725.85
CMG64
FW96
140
2801.084
3.7
3d 5 4s 2
3d 5 ( 6 S)4s4 p( 1 Po)
a 6S
y 6Po
5/2
3/2
0.00
35689.98
CMG64
FW96
120
3806.715
0.59
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Fo
9/2
11/2
17052.29
43314.23
CMG64
FW96
1000
4030.755
0.17
3d 5 4s 2
3d 5 ( 6 S)4s4 p( 3 Po)
a 6S
z 6Po
5/2
7/2
0.00
24802.25
CMG64
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1834
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Manganese 共Mn I兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
6
700
4033.068
0.165
3d 4s
3d 5 ( 6 S)4s4 p( 3 Po)
a S
z 6Po
5/2
5/2
0.00
24788.05
CMG64
FW96
400
4034.485
0.158
3d 5 4s 2
3d 5 ( 6 S)4s4 p( 3 Po)
a 6S
z 6Po
5/2
3/2
0.00
24779.32
CMG64
FW96
200
4041.357
0.787
3d 6 ( 5 D)4s
3d 6 ( 5 D)4p
a 6D
z 6Do
9/2
9/2
17052.29
41789.48
CMG64
FW96
Energy Levels of Neutral Manganese 共Mn I兲
Level (cm⫺1 )
Configuration
Term
J
3d 5 4s 2
a 6S
5/2
0.00
SC85
3d 6 ( 5 D)4s
a 6D
9/2
7/2
5/2
3/2
1/2
17052.29
17282.00
17451.52
17568.48
17637.15
SC85
SC85
SC85
SC85
SC85
3d 5 ( 6 S)4s4p( 3 Po)
z 8Po
5/2
7/2
9/2
18402.46
18531.64
18705.37
SC85
SC85
SC85
3d 6 ( 5 D)4s
a 4D
7/2
5/2
3/2
1/2
23296.67
23549.20
23719.52
23818.87
SC85
SC85
SC85
SC85
3d 5 ( 6 S)4s4p( 3 Po)
z 6Po
3/2
5/2
7/2
24779.32
24788.05
24802.25
SC85
SC85
SC85
3d 5 ( 6 S)4s4p( 3 Po)
z 4Po
5/2
3/2
1/2
31001.15
31076.42
31124.95
SC85
SC85
SC85
3d 5 ( 6 S)4s4p( 1 Po)
y 6Po
3/2
5/2
7/2
35689.98
35725.85
35769.97
SC85
SC85
SC85
3d 6 ( 5 D)4p
z 6Do
9/2
7/2
5/2
3/2
1/2
41789.48
41932.64
42053.73
42143.57
42198.56
SC85
SC85
SC85
SC85
SC85
3d 6 ( 5 D)4p
z 6Fo
11/2
9/2
7/2
5/2
3/2
1/2
43314.23
43428.58
43524.08
43595.50
43644.45
43672.66
SC85
SC85
SC85
SC85
SC85
SC85
3d 5 ( 4 P)4s4p( 3 Po)
v 6Po
7/2
5/2
3/2
49888.01
50012.50
50099.03
SC85
SC85
SC85
Limit
59959.4
SC85
Mn II ( 7 S3 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1835
Persistent Lines of Singly-ionized Manganese 共Mn II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5 6
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
7
1000
2576.103
2.82
3d ( S)4s
3d 5 ( 6 S)4p
a S
z 7Po
3
4
0.00
38806.67
KG00
KG00
500
2593.720
2.77
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 7S
z 7Po
3
3
0.00
38543.08
KG00
KG00
400
2605.680
2.72
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 7S
z 7Po
3
2
0.00
38366.18
KG00
KG00
90
2933.054
1.94
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 5S
z 5Po
2
1
9472.97
43557.14
KG00
KG00
120
2939.308
1.95
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 5S
z 5Po
2
2
9472.97
43484.64
KG00
KG00
150
2949.205
1.94
3d 5 ( 6 S)4s
3d 5 ( 6 S)4p
a 5S
z 5Po
2
3
9472.97
43370.51
KG00
KG00
60
3441.985
0.36
3d 6
3d 5 ( 6 S)4p
a 5D
z 5Po
4
3
14325.86
43370.51
KG00
KG00
Energy Levels of Singly-ionized Manganese 共Mn II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3d 5 ( 6 S)4s
a 7S
3
0.00
SC85
3d 5 ( 6 S)4s
a 5S
2
9472.97
SC85
5
a D
4
3
2
1
0
14325.86
14593.82
14781.19
14901.18
14959.84
SC85
SC85
SC85
SC85
SC85
3d 5 ( 4 G)4s
a 5G
6
5
4
3
2
27547.25
27571.25
27583.57
27588.50
27589.28
SC85
SC85
SC85
SC85
SC85
3d 5 ( 6 S)4p
z 7Po
2
3
4
38366.18
38543.08
38806.67
SC85
SC85
SC85
3d 5 ( 6 S)4p
z 5Po
3
2
1
43370.51
43484.64
43557.14
SC85
SC85
SC85
3d
6
Mn III ( 6 S5/2)
Limit
126145.0
SC85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1836
J. E. SANSONETTI AND W. C. MARTIN
Mercury „Hg…
Atomic number⫽80
Atomic weight⫽200.59
Isotope
196
Hg
Hg
199
Hg
200
Hg
201
Hg
202
Hg
204
Hg
198
Mass
Abundance
Spin
195.965807
197.966743
198.968254
199.968300
200.970277
201.970617
203.973467
0.15%
10.1%
17.0%
23.1%
13.2%
29.65%
6.85%
0
0
1/2
0
3/2
0
0
Mag moment
⫹0.5059
⫺0.5602
Hg I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 1S0
Ionization energy: 84 184.1 cm⫺1 共10.4375 eV兲
Hg II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2S1/2
Ionization energy: 151 284.4 cm⫺1 共18.7568 eV兲
Strong Lines of Mercury 共Hg兲
Intensity
20
12
20
25
25
20
20
1000 P
1000 P
1000 P
15
10
20
400
20
10
60
400
10
1000
25
40
400
30
25
250
70
90
80
80
12
10
10
600
P
P
P,c
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
893.0847
915.819
942.630
962.711
969.142
1039.6315
1062.7802
1649.9373
1849.499
1942.273
1973.794
1987.841
Air
2026.860
2052.828
2224.711
2252.786
2260.294
2262.223
2263.634
2536.517
2652.039
2653.679
2847.675
2916.250
2947.074
2967.280
3021.498
3125.668
3131.548
3131.839
3208.169
3532.594
3605.762
3650.153
Spectrum
Ref
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
II
II
II
II
II
II
II
II
I
II
II
II
SR01
SR01
SR01
SR01
SR01
SR01
SR01
SR01
WA63
SR01
SR01
SR01
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
II
II
II
II
II
II
II
I
I
I
II
II
II
I
I
I
I
I
II
II
II
I
SR01
SR01
SR01
SR01
SR01
SR01
SR01
BAL50
BAL50
BAL50
SR01
SR01
SR01
BAL50
BAL50
BAL50
BAL50
BAL50
SR01
SR01
SR01
BAL50
ATOMIC SPECTROSCOPIC DATA
1837
Strong Lines of Mercury 共Hg兲—Continued
Wavelength 共Å兲
Intensity
70
50
1000
400
60
100
1000
12
15
80
500
200
50
60
12
20
15
250
25
6
250
6
200
50
40
50
50
25
Spectrum
3654.836
3663.279
3983.931
4046.563
4339.223
4347.494
4358.328
5128.442
5204.768
5425.253
5460.735
5677.105
5769.598
5790.663
5871.279
5888.939
6146.435
6149.475
7081.90
7346.508
7944.555
9520.198
10139.76
13570.21
13673.51
15295.82
17072.79
23253.07
P,c
P
P
c
P
P
P
c
P,c
P
h
P
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
I
I
II
I
I
I
I
II
II
II
I
II
I
I
II
II
II
II
I
II
II
II
I
I
I
I
I
I
Ref
BAL50
BAL50
SR01
BAL50
BAL50
BAL50
BAL50
SR01
SR01
SR01
BAL50
SR01
BAL50
BAL50
SR01
SR01
SR01
SR01
F54
SR01
SR01
SR01
BAL50
H53
H53
H53
H53
PBT55
Persistent Lines of Neutral Mercury 共Hg I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
1000
1849.499
7.46
5d 10( 1 S)6s 2
5d 10( 1 S)6s6 p
1
5d 10( 1 S)6s 2
5d 10( 1 S)6s6 p
1
1000
2536.517
0.080
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
0
1
0.000
54068.781
WA63
M00
S
P
0
1
0.000
39412.300
BAL50
FW96
Term
1 o
3 o
250
2967.280
0.45
5d 10( 1 S)6s6 p
5d 10( 1 S)6s6d
3 o
P
共1/2,3/2兲
0
1
37645.080
71336.164
BAL50
FW96
600
3650.153
1.3
5d 10( 1 S)6s6 p
5d 10( 1 S)6s6d
3 o
P
共1/2,5/2兲
2
3
44042.977
71431.311
BAL50
FW96
400
4046.563
0.21
5d 10( 1 S)6s6 p
5d 10( 1 S)6s7s
3 o
P
S
0
1
37645.080
62350.456
BAL50
FW96
5d 10( 1 S)6s6 p
5d 10( 1 S)6s7s
3 o
P
S
1
1
39412.300
62350.456
BAL50
FW96
5d 10( 1 S)6s6 p
5d 10( 1 S)6s7s
3 o
P
S
2
1
44042.977
62350.456
BAL50
FW96
5d 10( 1 S)6s6 p
5d 10( 1 S)6s7s
1 o
1
0
54068.781
63928.243
BAL50
FW96
1000
500
200
4358.328
5460.735
10139.76
0.557
0.487
0.271
3
3
3
1
P
S
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1838
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Mercury 共Hg I兲
Configuration
10 1
5d ( S)6s
2
Term
1
Level (cm⫺1 )
J
Ref
S
0
0.000
BAL50
5d 10( 1 S)6s6p
3 o
P
0
1
2
37645.080
39412.300
44042.977
BAL50
BAL50
BAL50
5d 10( 1 S)6s6p
1 o
P
1
54068.781
BAL50
5d 10( 1 S)6s7s
3
S
1
62350.456
BAL50
5d 10( 1 S)6s7s
1
S
0
63928.243
BAL50
5d 9 6s 2 6p
3 o
P
2
68886.60
M58
5d 10( 1 S)6s7p
3 o
P
0
1
2
69516.66
69661.89
71207.51
M58
M58
M58
5d 10( 1 S)6s7p
1 o
1
71295.15
M58
5d 10( 1 S)6s6d
共1/2 ,3/2兲
2
1
71333.182
71336.164
BAL50
BAL50
5d 10( 1 S)6s6d
共1/2,5/2兲
2
3
71396.220
71431.311
BAL50
BAL50
84184.1
B83
P
Hg II ( 2 S1/2)
Limit
Persistent Lines of Singly-ionized Mercury 共Hg II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
1000
1649.9373
5.56
1000
1942.273
3.44
Configuration
J
Level (cm⫺1 )
S
P
1/2
3/2
S
P
Term
5d 10( 1 S)6s
5d 10( 1 S)6p
2
5d 10( 1 S)6s
5d 10( 1 S)6p
2
2 o
2 o
Wl Ref
A Ref
0.000
60608.362
SR01
M00
1/2
1/2
0.000
51486.070
SR01
M00
400
2052.828
5d 9 6s 2
5d 9 ( 2 D5/2)6s6p( 3 Po1 )
2
D
(5/2,1) o
5/2
7/2
35514.624
84212.404
SR01
400
2262.223
5d 9 6s 2
5d 9 ( 2 D5/2)6s6p( 3 Po0 )
2
D
(5/2,0) o
5/2
5/2
35514.624
79705.262
SR01
400
2847.675
5d 10( 1 S)6p
5d 10( 1 S)7s
2 o
P
S
3/2
1/2
60608.362
95714.406
SR01
D
P
5/2
3/2
35514.624
60608.362
SR01
D
F
3/2
5/2
104984.138
123411.351
SR01
D
F
5/2
7/2
105544.042
123153.775
SR01
S
P
1/2
3/2
95714.406
111971.464
SR01
S
P
1/2
1/2
95714.406
108298.183
SR01
1000
80
200
250
250
3983.931
5425.253
5677.105
6149.475
7944.555
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5d 9 6s 2
5d 10( 1 S)6p
2
2
2 o
5d 10( 1 S)6d
5d 10( 1 S)5 f
2
5d 10( 1 S)6d
5d 10( 1 S)5 f
2
5d 10( 1 S)7s
5d 10( 1 S)7p
2
5d 10( 1 S)7s
5d 10( 1 S)7p
2
2 o
2 o
2 o
2 o
ATOMIC SPECTROSCOPIC DATA
1839
Energy Levels of Singly-ionized Mercury 共Hg II兲
Configuration
10 1
Term
5d ( S)6s
2
5d 9 6s 2
Level (cm⫺1 )
Ref
1/2
0.000
SR01
2
D
5/2
3/2
35514.624
50555.567
SR01
SR01
5d 10( 1 S)6p
2 o
1/2
3/2
51486.070
60608.362
SR01
SR01
5d 9 ( 2 D5/2)6s6p( 3 Po0 )
(5/2,0) o
5/2
79705.262
SR01
5d 9 ( 2 D5/2)6s6p( 3 Po1 )
(5/2,1) o
7/2
5/2
3/2
84212.404
84836.143
86178.478
SR01
SR01
SR01
5d 9 ( 2 D5/2)6s6p( 3 Po2 )
(5/2,2) o
9/2
3/2
7/2
5/2
1/2
91139.508
94092.834
95187.361
95304.138
96187.932
SR01
SR01
SR01
SR01
SR01
5d 10( 1 S)7s
2
S
1/2
95714.406
SR01
5d 10( 1 S)6d
2
D
3/2
5/2
104984.138
105544.042
SR01
SR01
5d 10( 1 S)7p
2 o
P
1/2
3/2
108298.183
111971.464
SR01
SR01
5d 10( 1 S)5 f
2 o
7/2
5/2
123153.775
123411.351
SR01
SR01
151284.4
SR01
Hg III ( 1 S0 )
S
J
P
F
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1840
J. E. SANSONETTI AND W. C. MARTIN
Molybdenum „Mo…
Atomic number⫽42
Atomic weight⫽95.94
Isotope
92
Mo
Mo
95
Mo
96
Mo
97
Mo
100
Mo
94
Mass
Abundance
Spin
91.906808
93.905085
94.905840
95.904678
96.906020
98.907477
14.84%
9.25%
15.92%
16.68%
9.55%
9.63%
0
0
5/2
0
5/2
0
Mag moment
⫺0.9133
⫺0.9133
Mo I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 5 5s 7S3
Ionization energy: 57 204.3 cm⫺1 共7.092 43 eV兲
Mo II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 5 6S5/2
Ionization energy: 130 300 cm⫺1 共16.16 eV兲
Strong Lines of Molybdenum 共Mo兲
Intensity
500
1000
500
400
120
60
60
100
70
40
40
20
30
25
11
11
20
20
10
14
15
25
50
14
40
30
20
40
20
10
50
50
20
30
50
70
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2015.109
2020.314
2038.452
2045.973
2081.681
2089.52
2092.50
2093.11
2100.84
2104.29
2108.02
2269.69
2538.46
2542.67
2548.225
2572.345
2593.710
2602.800
2613.084
2616.786
2629.850
2636.670
2638.761
2640.984
2644.348
2646.486
2649.458
2653.347
2655.021
2658.111
2660.576
2672.843
2673.27
2679.854
2683.234
2684.140
Spectrum
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
I
I
I
II
II
I
II
II
I
II
I
I
II
II
II
I
II
II
Ref
SPNL01
SPNL01
SPNL01
SPNL01
SPNL01
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
WB88
WB88
SPNL01
SPNL01
WB88
WB88
WB88
SPNL01
SPNL01
WB88
SPNL01
SPNL01
WB88
SPNL01
WB88
WB88
SPNL01
SPNL01
MCS75
WB88
SPNL01
SPNL01
ATOMIC SPECTROSCOPIC DATA
1841
Strong Lines of Molybdenum 共Mo兲—Continued
Intensity
40
40
20
25
20
11
15
20
130
70
30
30
130
15
130
30
30
15
130
15
100
70
20
40
80
100
80
60
20
20
20
10
30
20
30
30
20
20
20
50
20
500
15
200
300
13
13
250
10
11
30
100
20
12
30
20
40
30
30
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
2687.992
2701.416
2717.35
2732.880
2746.30
2751.468
2763.62
2769.76
2775.402
2780.037
2784.99
2807.753
2816.158
2817.44
2848.233
2853.23
2863.81
2866.69
2871.512
2879.05
2890.994
2894.451
2903.07
2909.117
2911.917
2923.392
2930.502
2934.298
2956.057
2963.797
2972.611
3041.699
3064.274
3065.04
3074.369
3085.616
3087.62
3094.663
3101.344
3112.119
3122.00
3132.594
3152.82
3158.167
3170.344
3183.033
3185.104
3193.979
3195.960
3205.217
3205.887
3208.838
3215.072
3221.734
3228.212
3229.795
3233.142
3237.060
3256.208
Spectrum
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
I
II
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
SPNL01
SPNL01
MCS75
SPNL01
MCS75
WB88
MCS75
MCS75
SPNL01
SPNL01
MCS75
SPNL01
SPNL01
MCS75
SPNL01
MCS75
MCS75
MCS75
SPNL01
MCS75
SPNL01
SPNL01
MCS75
SPNL01
SPNL01
SPNL01
SPNL01
SPNL01
SPNL01
SPNL01
SPNL01
WB88
WB88
MCS75
WB88
WB88
MCS75
WB88
WB88
WB88
MCS75
WB88
MCS75
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1842
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Molybdenum 共Mo兲—Continued
Intensity
Wavelength 共Å兲
10
15
30
11
40
30
11
11
20
12
12
40
11
60
30
30
11
70
20
40
13
11
20
110 P
20
10
30
20
11
11
30
20
15
20
11
20
14
10
11
50
9
50
11
30
14
20
20
40
50
15
11
12
12
1000 P
10
20
30
60
13
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3262.626
3264.401
3270.899
3285.355
3289.011
3290.820
3305.563
3307.125
3323.949
3325.674
3327.304
3344.730
3347.004
3358.118
3363.778
3379.965
3382.482
3384.609
3404.335
3405.94
3434.788
3435.448
3437.213
3447.124
3449.074
3451.75
3456.386
3460.778
3466.824
3469.219
3504.411
3508.114
3521.413
3537.28
3542.166
3558.095
3563.136
3566.052
3573.878
3581.885
3602.938
3624.462
3626.180
3635.43
3657.357
3664.811
3672.807
3680.590
3694.939
3727.679
3732.709
3770.445
3781.592
3798.252
3801.840
3826.694
3828.876
3833.747
3847.246
Spectrum
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
MCS75
WB88
WB88
WB88
WB88
WB88
MCS75
WB88
WB88
WB88
WB88
WB88
WB88
WB88
MCS75
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
MCS75
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
ATOMIC SPECTROSCOPIC DATA
1843
Strong Lines of Molybdenum 共Mo兲—Continued
Intensity
1000
20
20
13
700
9
50
80
40
30
25
20
100
15
90
50
9
30
40
50
25
30
12
30
70
90
30
12
15
20
14
12
15
20
25
25
14
14
12
15
20
250
200
90
11
15
20
20
20
30
40
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3864.104
3869.082
3886.822
3901.770
3902.953
4056.012
4062.077
4069.882
4081.44
4084.373
4107.462
4120.093
4143.55
4185.819
4188.324
4232.589
4269.279
4276.906
4277.239
4288.631
4292.134
4293.215
4293.880
4326.137
4381.630
4411.695
4434.949
4449.738
4457.354
4474.570
4536.796
4609.874
4626.464
4707.248
4731.441
4760.183
4819.249
4830.513
4868.018
5238.206
5360.513
5506.494
5533.031
5570.444
5632.463
5689.146
5751.409
5791.839
5858.267
5888.310
6030.645
Spectrum
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
Mo
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
MCS75
WB88
WB88
WB88
MCS75
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
WB88
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1844
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Molybdenum 共Mo I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5 6
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
7
500
3132.594
1.79
4d ( S)5s
4d 4 5s( 6 D)5p
a S
y 7Po
3
4
0.000
31913.171
WB88
FW96
200
3158.167
0.463
4d 5 ( 6 S)5s
4d 4 5s( 6 D)5p
a 7S
z 7Do
3
3
0.000
31654.786
WB88
FW96
300
3170.344
1.37
4d 5 ( 6 S)5s
4d 4 5s( 6 D)5p
a 7S
y 7Po
3
3
0.000
31533.206
WB88
FW96
250
3193.979
1.53
4d 5 ( 6 S)5s
4d 4 5s( 6 D)5p
a 7S
y 7Po
3
2
0.000
31299.876
WB88
FW96
100
3208.838
0.277
4d 5 ( 6 S)5s
4d 4 5s( 6 D)5p
a 7S
z 7Do
3
2
0.000
31154.935
WB88
FW96
110
3447.124
0.875
4d 4 5s 2
4d 5 ( 4 G)5p
a 5D
y 5Fo
4
5
12346.280
41347.664
WB88
FW96
1000
3798.252
0.690
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 7S
z 7Po
3
4
0.000
26320.420
WB88
FW96
1000
3864.104
0.624
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 7S
z 7Po
3
3
0.000
25871.887
WB88
FW96
700
3902.953
0.617
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 7S
z 7Po
3
2
0.000
25614.367
WB88
FW96
80
4069.882
0.325
4d 5 ( 4 G)5s
4d 5 ( 4 G)5p
a 5G
y 5Fo
6
5
16783.856
41347.664
WB88
FW96
90
4188.324
0.332
4d 5 ( 4 G)5s
4d 5 ( 4 G)5p
a 5G
z 5Ho
5
6
16784.522
40653.701
WB88
FW96
90
4411.695
0.263
4d 5 ( 4 G)5s
4d 5 ( 4 G)5p
a 5G
z 5Go
5
5
16784.522
39445.182
WB88
FW96
250
5506.494
0.361
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 5S
z 5Po
2
3
10768.332
28923.668
WB88
FW96
200
5533.031
0.372
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 5S
z 5Po
2
2
10768.332
28836.592
WB88
FW96
90
5570.444
0.330
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 5S
z 5Po
2
1
10768.332
28715.242
WB88
FW96
Energy Levels of Neutral Molybdenum 共Mo I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
4d 5 ( 6 S)5s
a 7S
3
0.000
WB88
4d 5 ( 6 S)5s
a 5S
2
10768.332
WB88
4d 4 5s 2
a 5D
0
1
2
3
4
10965.947
11142.784
11454.362
11858.499
12346.280
WB88
WB88
WB88
WB88
WB88
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1845
Energy Levels of Neutral Molybdenum 共Mo I兲—Continued
J
Level (cm⫺1 )
4d ( G)5s
5
a G
2
3
4
6
5
16641.081
16692.905
16747.720
16783.856
16784.522
WB88
WB88
WB88
WB88
WB88
4d 5 ( 6 S)5p
z 7Po
2
3
4
25614.367
25871.887
26320.420
WB88
WB88
WB88
4d 5 ( 6 S)5p
z 5Po
1
2
3
28715.242
28836.592
28923.668
WB88
WB88
WB88
4d 4 5s( 6 D)5p
z 7Do
1
2
3
4
5
30846.584
31154.935
31654.786
32123.128
32611.837
WB88
WB88
WB88
WB88
WB88
4d 4 5s( 6 D)5p
y 7Po
2
3
4
31299.876
31533.206
31913.171
WB88
WB88
WB88
4d 5 ( 4 G)5p
z 5Go
5
39445.182
WB88
4d 5 ( 4 G)5p
z 5Ho
6
40653.701
WB88
5 o
5
41347.664
WB88
57204.3
RMBH87
Configuration
5 4
5 4
4d ( G)5p
Term
y F
Mo II ( 6 S5/2)
Limit
Ref
Persistent Lines of Singly-ionized Molybdenum 共Mo II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
6
500
2015.109
0.88
4d
4d 4 ( 5 D)5p
a S
z 6Po
5/2
5/2
0.00
49608.74
SPNL01
SPNL01
1000
2020.314
2.15
4d 5
4d 4 ( 5 D)5p
a 6S
z 6Po
5/2
7/2
0.00
49481.04
SPNL01
SPNL01
500
2038.452
1.84
4d 5
4d 4 ( 5 D)5p
a 6S
z 6Po
5/2
3/2
0.00
49040.82
SPNL01
SPNL01
400
2045.973
1.18
4d 5
4d 4 ( 5 D)5p
a 6S
z 4Po
5/2
5/2
0.00
48860.57
SPNL01
SPNL01
120
2081.681
0.200
4d 5
4d 4 ( 5 D)5p
a 6S
z 4Po
5/2
3/2
0.00
48022.45
SPNL01
SPNL01
60
2089.52
4d 5
4d 4 ( 3 H)5p
a 4G
y 4Go
5/2
5/2
15199.25
63041.47
MCS75
60
2092.50
4d 5
4d 4 (a 3 F)5p
a 4G
y 4Fo
7/2
7/2
15330.56
63104.63
MCS75
100
2093.11
4d 5
4d 4 ( 3 H)5p
a 4G
y 4Go
11/2
11/2
15446.97
63207.43
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1846
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Molybdenum 共Mo II兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
4d
5
Term
J
Level (cm⫺1 )
Wl Ref
4
a G
1o
9/2
7/2
15427.73
63012.24
MCS75
A Ref
70
2100.84
130
2775.402
2.26
4d 4 ( 5 D)5s
4d 4 ( 5 D)5p
a 6D
z 6Po
9/2
7/2
13460.70
49481.04
SPNL01
SPNL01
130
2816.158
2.33
4d 4 ( 5 D)5s
4d 4 ( 5 D)5p
a 6D
z 6Fo
9/2
11/2
13460.70
48959.68
SPNL01
SPNL01
130
2848.233
1.66
4d 4 ( 5 D)5s
4d 4 ( 5 D)5p
a 6D
z 6Fo
7/2
9/2
12900.33
47999.47
SPNL01
SPNL01
130
2871.512
1.15
4d 4 ( 5 D)5s
4d 4 ( 5 D)5p
a 6D
z 6Fo
5/2
7/2
12417.28
47231.98
SPNL01
SPNL01
Energy Levels of Singly-ionized Molybdenum 共Mo II兲
Configuration
J
Level (cm⫺1 )
Ref
6
a S
5/2
0.00
K58
4d 4 ( 5 D)5s
a 6D
1/2
3/2
5/2
7/2
9/2
11783.36
12034.06
12417.28
12900.33
13460.70
K58
K58
K58
K58
K58
4d 5
a 4G
5/2
7/2
9/2
11/2
15199.25
15330.56
15427.73
15446.97
K58
K58
K58
K58
4d 4 ( 5 D)5p
z 6Fo
1/2
3/2
5/2
7/2
9/2
11/2
45853.08
46148.12
46614.14
47231.98
47999.47
48959.68
K58
K58
K58
K58
K58
K58
4d 4 ( 5 D)5p
z 4Po
1/2
3/2
5/2
47208.36
48022.45
48860.57
K58
K58
K58
4d 4 ( 5 D)5p
z 6Po
3/2
7/2
5/2
49040.82
49481.04
49608.74
K58
K58
K58
4d 4 ( 3 H)5p
y 4Go
7/2
9/2
5/2
11/2
62917.94
62953.75
63041.47
63207.43
K58
K58
K58
K58
1o
7/2
63012.24
K58
y 4Fo
7/2
63104.63
K58
4d
5
Term
4d 4 (a 3 F)5p
Mo III ( 5 D0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
130300
SM88
ATOMIC SPECTROSCOPIC DATA
1847
Neodymium „Nd…
Atomic number⫽60
Atomic weight⫽144.24
Isotope
142
Nd
Nd
144
Nd
145
Nd
146
Nd
148
Nd
150
Nd
143
Mass
Abundance
Spin
141.907719
142.909810
143.910083
144.912570
145.913113
147.916889
149.920889
27.13%
12.18%
23.80%
8.30%
17.19%
5.76%
5.64%
0
7/2
0
7/2
0
0
0
Mag moment
⫺1.08
⫺0.66
Nd I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 4 6s 2 5I4
Ionization energy: 44 562 cm⫺1 共5.5250 eV兲
Nd II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 4 6s 6I7/2
Ionization energy: 86 500 cm⫺1 共10.72 eV兲
Strong Lines of Neodymium 共Nd兲
Intensity
Wavelength 共Å兲
250
100
100
110
200
120
140
130
200
200
110
90
150
150
90
250
130
110
90
400
200
500
100
110
130
200
100
90
140
300
300*
300*
300
400*
400*
Air
3484.88
3665.18
3672.36
3673.54
3685.80
3714.73
3723.50
3728.13
3735.54
3738.06
3752.49
3757.82
3758.95
3763.47
3769.65
3775.50
3779.47
3780.40
3781.32
3784.25
3803.47
3805.36
3808.77
3810.49
3814.73
3826.42
3828.85
3830.47
3836.54
3838.98
3848.24
3848.31
3848.52
3851.66
3851.74
h
d
d
P
P
d
d
P,d
P,d
Spectrum
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1848
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Neodymium 共Nd兲—Continued
Intensity
Wavelength 共Å兲
700*
700*
150
200
200
140
200
100
250
250
250
110
150
400
250
300
90
400
150
110
200
90
110
90
400
400
150
110
90
250
200
140
140
140
250
200
200
100
700
100
200
200
200
200
200
600
150
150
900
200
130
250
500
90
90
600
90
150
400
3863.33
3863.40
3869.07
3878.58
3879.55
3880.38
3880.78
3887.87
3889.93
3890.58
3890.94
3891.51
3894.63
3900.21
3901.84
3905.89
3907.84
3911.16
3912.23
3915.95
3920.96
3927.10
3934.82
3938.86
3941.51
3951.16
3952.20
3958.00
3962.21
3963.12
3973.30
3973.69
3976.85
3979.49
3990.10
3991.74
3994.68
4004.02
4012.25
4012.70
4020.87
4021.34
4021.78
4023.00
4031.82
4040.80
4051.15
4059.96
4061.09
4069.28
4075.12
4109.08
4109.46
4110.48
4135.33
4156.08
4156.26
4175.61
4177.32
P,d
P,d
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1849
Strong Lines of Neodymium 共Nd兲—Continued
Intensity
120
250
400
150
130
1000
200
90
100
130
150
130
100
90
110
250
140
250
300
200
200
200
600
200
1000
700
400
600
400
600
200
200
400
250
500
250
250
400
700
500
500
250
400
400
900
500
600
130
90
120
300
130
110
200
130
90
400
250
200
P
P
P
P
P
P
P
P
P
P
P
P
P
d
Wavelength 共Å兲
4179.59
4232.38
4247.38
4252.44
4284.52
4303.58
4325.76
4327.93
4338.70
4351.29
4358.17
4385.66
4400.83
4411.06
4446.39
4451.57
4462.99
4527.25
4559.67
4586.62
4603.82
4609.87
4621.94
4627.98
4634.24
4641.10
4646.40
4649.67
4654.73
4683.45
4684.04
4690.35
4696.44
4706.96
4719.02
4731.77
4779.46
4866.74
4883.81
4891.07
4896.93
4901.53
4901.84
4913.41
4924.53
4944.83
4954.78
5130.60
5191.45
5192.62
5213.23
5249.59
5273.43
5291.67
5293.17
5319.82
5620.54
5675.97
5729.29
Spectrum
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
I
II
II
I
II
II
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1850
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Neodymium 共Nd I兲
Inten
Wavelength 共Å兲
600
4621.94
A ki (108 s⫺1 )
0.56
Configuration
4
4 f 6s
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
5
I
6
6
2366.597
23996.513
MCS75
M00
I
Ho
4
3
0.000
21572.610
MCS75
M00
o
1000
4634.24
0.84
4 f 4 6s 2
4 f 4 6s6 p
5
5
700
4641.10
MCS75
600
4649.67
MCS75
600
4683.45
0.52
4 f 4 6s 2
5
I
4
4
0.000
21345.837
MCS75
M00
I
4
4
0.000
21184.881
MCS75
M00
I
Ko
8
9
5048.602
25518.700
MCS75
K91
I
Ko
5
6
1128.056
21543.326
MCS75
K91
I
Ko
4
5
0.000
20300.875
MCS75
M00
5
5
I
5
6
1128.056
21345.572
MCS75
M00
I
4
5
0.000
20176.912
MCS75
M00
o
500
4719.02
0.33
4 f 4 6s 2
5
o
700
500
900
500
4883.81
4896.93
4924.53
4944.83
0.88
0.59
0.90
0.67
4 f 4 6s 2
4 f 4 6s6 p
5
5
4 f 4 6s 2
4 f 4 6s6 p
5
5
4 f 4 6s 2
4 f 4 6s6 p
5
4 f 4 6s 2
o
600
4954.78
0.29
4 f 4 6s 2
5
o
Energy Levels of Neutral Neodymium 共Nd I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4 f 4 6s 2
5
I
4
5
6
7
8
0.000
1128.056
2366.597
3681.696
5048.602
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 3 ( 4 Io)5d6s 2
5 o
L
6
7
8
9
10
6764.211
8402.487
10160.612
12162.142
—
MZH78
MZH78
MZH78
MZH78
4 f 3 ( 4 Io)5d6s 2
5
Ko
5
6
7
8
9
6853.994
8411.900
10017.790
11704.640
—
MZH78
MZH78
MZH78
MZH78
4 f 4 ( 5 I)5d6s( 3 D)
7
L
5
6
7
8
9
10
11
8475.355
9115.092
9939.704
10897.998
11959.761
13101.411
14304.110
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1851
Energy Levels of Neutral Neodymium 共Nd I兲—Continued
Configuration
3 4 o
2 3
J
Level (cm⫺1 )
Ref
6
7
8
9
10
11
12
8800.392
9692.277
10784.929
11887.735
—
—
—
MZH78
MZH78
MZH78
MZH78
I
4
5
6
7
8
9083.813
10004.583
11179.045
12927.232
14732.200
MZH78
MZH78
MZH78
MZH78
MZH78
K
4
5
6
7
8
9
10
9814.683
10376.842
11109.167
11918.353
12902.422
13953.585
15073.203
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
Term
6
o
4 f ( I )5d ( F)( M )6s
7
o
4 f 3 ( 4 Io)5d6s 2
5 o
4 f 4 ( 5 I)5d6s( 3 D)
7
4 f 3 ( 4 Io)5d6s 2
5
3
4
5
6
7
9927.387
10672.571
12394.260
14308.080
15396.590
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 4 6s 2
5
F
1
2
3
4
5
10118.968
10469.468
11118.466
11866.108
12894.721
MZH78
MZH78
MZH78
ABK92
ABK92
4 f 4 ( 5 I)5d6s( 3 D)
5
L
6
7
8
9
10
10774.927
12056.824
13333.505
14687.945
16092.06
MZH78
MZH78
MZH78
MZH78
MZH78
5
20176.912
MZH78
5
6
7
8
9
20300.875
21543.326
22761.440
24121.478
25518.700
MZH78
MZH78
MZH78
MZH78
MZH78
o
4
21184.881
MZH78
o
6
21345.572
MZH78
o
4
21345.837
MZH78
3
21572.610
MZH78
6
23996.513
MZH78
44562
WSPC78
M
Ho
o
4
4 f 6s6p
4 f 4 6s6p
5
5
o
Nd II ( 6 I7/2)
o
K
Ho
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1852
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Neodymium 共Nd II兲
Inten
400
500
400*
Wavelength 共Å兲
A ki (108 s⫺1 )
4 5
3784.25
3805.36
Configuration
0.31
3851.66
J
Level (cm⫺1 )
Wl Ref
I
I
11/2
11/2
3066.755
29484.605
MCS75
I
I
13/2
15/2
2585.460
28856.895
MCS75
I
13/2
15/2
2585.460
28540.945
MCS75
I
Ho
11/2
9/2
1470.105
27425.000
MCS75
I
I
7/2
9/2
0.000
25877.160
MCS75
I
Ho
7/2
5/2
0.000
25876.545
MCS75
Term
4 f ( I)6s
4 f 4 ( 5 I)6p
4
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
6
4 o
6 o
o
400*
700*
700*
400
400
3851.74
3863.33
0.11
3863.40
3900.21
3911.16
400
700
600
3941.51
3951.16
4012.25
0.45
0.40
1.25
4040.80
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
I
Ho
15/2
13/2
3801.930
29434.255
MCS75
6
4 f 4 ( 5 I)6s
6
I
15/2
15/2
3801.930
29362.520
MCS75
I
I
9/2
9/2
513.330
25877.160
MCS75
M00
I
I
11/2
11/2
1470.105
26772.080
MCS75
M00
M00
6
6 o
6
500
600
400
400
4061.09
4109.46
4156.08
0.72
0.51
0.42
4177.32
4247.38
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
I
Ko
17/2
19/2
5085.640
30002.310
MCS75
6
4 f 4 ( 5 I)6s
6
I
11/2
13/2
1470.105
26210.740
MCS75
I
Ko
15/2
17/2
3801.930
28418.970
MCS75
M00
I
Ko
13/2
15/2
2585.460
26912.765
MCS75
M00
I
Ko
11/2
13/2
1470.105
25524.470
MCS75
M00
6 o
6 o
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
I
Ko
9/2
11/2
513.330
24445.380
MCS75
6
4 f 4 ( 5 I)6s
6
I
7/2
9/2
0.000
23537.380
MCS75
I
Ko
7/2
9/2
0.000
23229.980
MCS75
6
6
6
o
1000
4303.58
0.44
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
M00
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
o
900
M00
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
o
400
A Ref
4 f 4 ( 5 I)6s
4 f 4 ( 5 I)6p
6
6
M00
ATOMIC SPECTROSCOPIC DATA
1853
Energy Levels of Singly-ionized Neodymium 共Nd II兲
Configuration
4 5
Term
J
Level (cm⫺1 )
Ref
4 f ( I)6s
6
I
7/2
9/2
11/2
13/2
15/2
17/2
0.000
513.330
1470.105
2585.460
3801.930
5085.640
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)6s
4
I
9/2
11/2
13/2
15/2
1650.205
3066.755
4512.495
5985.580
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)5d
6
L
11/2
13/2
15/2
17/2
19/2
21/2
4437.560
5487.655
6637.430
7868.910
9166.210
10516.790
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)5d
6
K
9/2
11/2
13/2
15/2
17/2
19/2
6005.270
6931.800
7950.075
9042.760
10194.805
11392.190
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)5d
6
I
7/2
9/2
11/2
13/2
15/2
17/2
7524.735
8420.320
9357.910
10337.100
11373.475
12459.995
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)5d
6
G
3/2
5/2
7/2
9/2
11/2
13/2
8716.445
8796.365
9198.395
10883.250
12021.340
12334.230
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 3 ( 4 Io)5d 2 ( 3 F)
6
Mo
13/2
15/2
17/2
19/2
21/2
23/2
8009.810
9448.185
10980.540
12600.805
14299.295
16064.085
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)5d
6
H
5/2
7/2
9/2
11/2
13/2
15/2
9674.835
10666.780
11709.615
12887.085
13298.880
14481.970
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1854
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Neodymium 共Nd II兲—Continued
Configuration
4 5
4 f ( I)6p
Term
6
o
K
o
J
Level (cm⫺1 )
9/2
11/2
13/2
15/2
17/2
19/2
23229.980
24445.380
25524.470
26912.765
28418.970
30002.310
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
9/2
23537.380
BWDA84
Ref
4 f 4 ( 5 I)6p
6 o
I
7/2
9/2
11/2
13/2
15/2
17/2
25044.645
25877.160
26772.080
27744.190
28856.895
30246.770
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
4 f 4 ( 5 I)6p
6
Ho
5/2
7/2
9/2
11/2
13/2
15/2
25876.545
26640.080
27425.000
28285.610
29434.255
30707.280
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
BWDA84
13/2
26210.740
BWDA84
4 o
9/2
11/2
13/2
15/2
27921.385
29484.605
31153.855
32464.635
BWDA84
BWDA84
BWDA84
BWDA84
o
15/2
28540.945
BWDA84
o
15/2
29362.520
BWDA84
Limit
86500
SR65
o
4 f 4 ( 5 I)6p
I
Nd III ( 5 I4 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1855
Neon „Ne…
Atomic number⫽10
Atomic weight⫽20.1797
Isotope
20
Ne
Ne
22
Ne
21
Mass
Abundance
Spin
Mag moment
19.992435
20.993843
21.991383
90.48%
0.27%
9.25%
0
3/2
0
⫺0.66179
Ne I Ground state: 1s 2 2s 2 2p 6 1S0
Ionization energy: 173 929.75 cm⫺1 共21.564 54 eV兲
o
Ne II Ground state: 1s 2 2s 2 2p 5 2P3/2
⫺1
Ionization energy: 330 388.6 cm 共40.962 96 eV兲
Strong Lines of Neon 共Ne兲
Intensity
90
60
90
60
150
120
200
300
250
200
150
200
10
120
90
1000
500
30
30
30
70
100
70
30
70
130
170
170
130
200
200
1000
400
60
70
90
100
90
90
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
352.9549
354.9620
361.4321
362.4544
405.8538
407.1377
445.0393
446.2552
446.5902
447.8146
454.6540
455.2730
456.2728
456.3485
456.8962
460.7284
462.3908
587.2127
587.1792
589.9114
591.8306
595.9200
598.7056
598.8897
600.0365
602.7263
615.6283
618.6716
619.1023
626.8232
629.7388
735.8962
743.7195
993.8825
1068.6488
1131.7224
1131.8490
1229.8367
1418.3779
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
Ref
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
P71
P71
P71
P71
P71
P71
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1856
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Neon 共Ne兲—Continued
Intensity
Wavelength 共Å兲
90
90
120
200
100
100
200
500 P
300 P
200
100 c
1428.5822
1436.0813
1681.6840
1688.3553
1888.1064
1889.7120
1907.4940
1916.0818
1930.0345
1938.8269
1945.4521
Air
2007.009
2025.560
2085.466
2096.106
2096.248
2562.123
2567.121
2623.107
2629.885
2636.069
2638.289
2644.097
2762.921
2792.019
2794.221
2809.485
2906.592
2906.816
2910.061
2910.408
2911.138
2915.122
2925.618
2932.103
2940.653
2946.044
2955.725
2963.236
2967.184
2972.997
2974.7189
2979.461
2982.6696
3001.668
3017.311
3027.016
3028.864
3030.787
3034.461
3035.923
3037.720
3039.586
3044.088
3045.556
3047.556
3054.345
3054.677
80
80
150
200
120
80
90
80
80
90
80
80
80
90
80
100
80
80
90
90
80
80
80
80
80
90
150
150
150
100
30
100
30
150
120
300
300
100
120
100
100
100
100
100
120
100
100
w
w
w
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ref
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
II
II
II
II
II
II
II
II
II
II
II
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
SS04
P71
SS04
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
ATOMIC SPECTROSCOPIC DATA
1857
Strong Lines of Neon 共Ne兲—Continued
Intensity
30
100
100
100
100
100
100
120
100
120
100
100
100
100
120
300
100
100
100
100
100
120
500 P
60
120
120
150
150
120
120
200
120
120
150
100
100
100
100
150
150
300
1000 P
150
100
200
150
300
150
200
120
200
120
100
120
50
70
100
500 P
150
Wavelength 共Å兲
3057.3907
3059.106
3062.491
3063.301
3070.887
3071.529
3075.731
3088.166
3092.092
3092.901
3094.006
3095.103
3097.131
3117.980
3118.160
3141.332
3143.721
3148.681
3164.429
3165.648
3188.743
3194.579
3198.586
3208.965
3209.356
3213.735
3214.329
3218.193
3224.818
3229.573
3230.070
3230.419
3232.022
3232.372
3243.396
3244.095
3248.345
3250.355
3297.726
3309.740
3319.722
3323.745
3327.153
3329.158
3334.836
3344.395
3345.453
3345.829
3355.016
3357.820
3360.597
3362.161
3362.707
3367.218
3369.8076
3369.9072
3371.799
3378.216
3388.417
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
Ref
SS04
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
SS04
SS04
P71
P71
P71
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1858
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Neon 共Ne兲—Continued
Intensity
120
300
100
120
100
120
120
50
5
120
20
10
100
100
10
10
20
50
150
200
200
10
20
20
100 P
120
120
100
250
100
200
50
30
10
10
150
200
10
10
200
4
150
250
250
800 P
1000 P
100
120
150
100
120
120
70
150
100
200
150
150
100
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3388.945
3392.798
3404.822
3406.947
3413.148
3416.914
3417.688
3417.9031
3418.0055
3428.687
3447.7024
3454.1944
3456.610
3459.321
3460.5237
3464.3382
3466.5781
3472.5706
3479.519
3480.718
3481.933
3498.0636
3501.2159
3515.1902
3520.4711
3542.847
3557.805
3561.198
3568.502
3574.181
3574.612
3593.5257
3593.6389
3600.1685
3633.6640
3643.927
3664.073
3682.2421
3685.7352
3694.213
3701.2244
3709.622
3713.079
3727.107
3766.259
3777.133
3818.427
3829.749
4219.745
4233.850
4250.649
4369.862
4379.400
4379.550
4385.059
4391.991
4397.990
4409.299
4413.215
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
II
II
II
II
II
II
II
I
I
II
I
I
II
II
I
I
I
I
II
II
II
I
I
I
I
II
II
II
II
II
II
I
I
I
I
II
II
I
I
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
P71
P71
P71
P71
P71
P71
P71
SS04
SS04
P71
SS04
SS04
P71
P71
SS04
SS04
SS04
SS04
P71
P71
P71
SS04
SS04
SS04
SS04
P71
P71
P71
P71
P71
P71
SS04
SS04
SS04
SS04
P71
P71
SS04
SS04
P71
SS04
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
ATOMIC SPECTROSCOPIC DATA
1859
Strong Lines of Neon 共Ne兲—Continued
Intensity
100
100
100
150
150
120
100
100
100
150
120
100
150
150
50
100
50
100
100
50
50
50
60
100
60
200
50
50
50
50
70
50
50
200
50
100
5
5
50
50
50
60
15
100
100
30
10
100
100
15
100
100
10
30
100
100
200
150
10
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
4421.389
4428.516
4428.634
4430.904
4430.942
4457.049
4522.720
4537.7545
4569.057
4704.3949
4708.8594
4710.0650
4712.0633
4715.344
4752.7320
4788.9258
4790.2195
4827.338
4884.9170
5005.1587
5037.7512
5144.9384
5330.7775
5341.0938
5343.2834
5400.5618
5562.7662
5656.6588
5719.2248
5748.2985
5764.4188
5804.4496
5820.1558
5852.4879
5872.8275
5881.8952
5902.4623
5906.4294
5944.8342
5965.4710
5974.6273
5975.5340
5987.9074
6029.9969
6074.3377
6096.1631
6128.4499
6143.0626
6163.5939
6182.1460
6217.2812
6266.4950
6304.7889
6328.1646
6334.4278
6382.9917
6402.248
6506.5281
6532.8822
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
II
II
II
II
II
II
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
P71
P71
P71
P71
P71
P71
P71
SS04
P71
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1860
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Neon 共Ne兲—Continued
Intensity
100
15
50
7
1000
300
800
20
100
800
150
150
800
150
30
300
100
150
300
130
1
120
2
120
3
13
80
60
100
40
12
170
30
100
70
10
300
100
50
100
800
30
250
40
13
700
15
30
400
350
60
600
80
100
130
150
30
100
600
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
6598.9529
6652.0927
6678.2762
6717.0430
6929.4673
7024.0504
7032.4131
7051.2923
7059.1074
7173.9381
7213.200
7235.188
7245.1666
7343.945
7472.4386
7488.8712
7492.102
7522.818
7535.7741
7544.0443
7724.6233
7740.738
7839.0529
7926.201
7927.1177
7936.9961
7943.1814
8082.4580
8084.345
8118.5492
8128.9108
8136.4054
8259.3790
8264.807
8266.0772
8267.1162
8300.3258
8314.995
8365.7466
8372.106
8377.6080
8417.1606
8418.4274
8463.3575
8484.4435
8495.3598
8544.6958
8571.3524
8591.2584
8634.6470
8647.0411
8654.3831
8655.5220
8668.256
8679.4925
8681.9211
8704.1116
8771.6563
8780.6226
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
I
I
I
I
I
I
I
I
I
I
II
II
I
II
I
I
II
II
I
I
I
II
I
II
I
I
I
I
II
I
I
I
I
II
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
Ref
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
P71
P71
SS04
P71
SS04
SS04
P71
P71
SS04
SS04
SS04
P71
SS04
P71
SS04
SS04
SS04
SS04
P71
SS04
SS04
SS04
SS04
P71
SS04
SS04
SS04
P71
SS04
P71
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
P71
SS04
SS04
SS04
SS04
SS04
ATOMIC SPECTROSCOPIC DATA
1861
Strong Lines of Neon 共Ne兲—Continued
Intensity
400
6
300
20
150
60
20
100
120
90
60
20
20
9
200
80
8
30
70
15
50
30
50
60
30
120
180
100
4
80
60
90
300
500
150
90
300
150
90
30
130
30
150
130
30
70
200
40
60
80
40
50
20
20
40
9
15
13
140
P
P
P
P
Wavelength 共Å兲
8783.7533
8830.9072
8853.8668
8865.3063
8865.7552
8919.5006
8988.5564
9079.462
9148.6716
9201.7591
9220.0601
9221.5801
9226.6903
9275.5196
9287.563
9300.8527
9310.5839
9313.9726
9326.5068
9373.3078
9425.3788
9459.2095
9486.6818
9534.1629
9547.4049
9577.013
9665.4197
9808.860
10295.4174
10562.4075
10798.0429
10844.4772
11143.0200
11177.5240
11390.4339
11409.1343
11522.7459
11525.0194
11536.3445
11601.5366
11614.0807
11688.0017
11766.7924
11789.0435
11789.8891
11984.912
12066.334
12459.389
12689.201
12912.014
13219.241
15230.714
17161.929
18035.812
18083.181
18083.263
18221.087
18227.016
18276.642
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
SS04
SS04
SS04
SS04
SS04
SS04
SS04
P71
SS04
SS04
SS04
SS04
SS04
SS04
P71
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
P71
SS04
P71
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1862
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Neon 共Ne兲—Continued
Intensity
100
70
20
60
90
40
60
13
40
70
100
16
20
30
30
13
13
80
13
25
40
50
30
170
12
60
110
50
60
11
20
30
70
40
20
30
17
30
13
50
6
6
8
17
5
4
12
4
6
8
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
18282.614
18303.967
18359.094
18384.826
18389.937
18402.836
18422.402
18458.640
18475.800
18591.541
18597.698
18618.908
18625.159
21041.27
21708.11
22247.36
22428.14
22530.38
22661.79
23100.48
23260.27
23372.96
23565.33
23636.48
23701.66
23709.13
23951.40
23956.43
23978.16
24098.57
24161.43
24249.61
24365.01
24371.61
24447.86
24459.39
24776.49
24928.89
25161.70
25524.33
28386.20
30200.49
33173.09
33352.38
33899.81
33903.02
33913.10
34131.34
34471.43
35834.81
Spectrum
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
Ne
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
SS04
ATOMIC SPECTROSCOPIC DATA
1863
Persistent Lines of Neutral Neon 共Ne I兲
Inten
170
170
130
200
200
1000
400
100
200
200
100
100
100
100
100
100
100
200
150
100
1000
Wavelength 共Å兲
615.6283
618.6716
619.1023
626.8232
629.7388
735.8962
743.7195
3520.4711
5400.5618
5852.4879
6029.9969
6074.3377
6143.0626
6163.5939
6217.2812
6266.4950
6382.9917
6402.248
6506.5281
6598.9529
6929.4673
A ki (108 s⫺1 )
0.380
0.929
0.330
0.741
0.480
3.16
0.486
0.093
0.0090
0.682
0.0561
0.603
0.282
0.146
0.0637
0.249
0.321
0.514
0.300
0.232
0.174
Configuration
6
1
2p
o
)3d
2 p 5 ( 2 P1/2
2
2p 6
o
)3d
2 p 5 ( 2 P3/2
2
2p 6
o
)3d
2 p 5 ( 2 P3/2
2
2p 6
o
)4s
2 p 5 ( 2 P1/2
2
2p 6
o
)4s
2 p 5 ( 2 P3/2
2
2p 6
o
)3s
2 p 5 ( 2 P1/2
2
2p 6
o
)3s
2 p 5 ( 2 P3/2
2
1
1
1
1
1
1
o
)3s
2 p 5 ( 2 P1/2
5 2 o
2 p ( P1/2)4p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P1/2)3p
2
o
)3s
2 p 5 ( 2 P1/2
5 2 o
2 p ( P1/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P1/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P1/2
o
2 p 5 ( 2 P1/2
)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P1/2
5 2 o
2 p ( P1/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2 p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P1/2
5 2 o
2 p ( P1/2)3p
2
o
)3s
2 p 5 ( 2 P1/2
5 2 o
2 p ( P3/2)3p
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Term
J
S
关 3/2兴 o
0
1
S
关 3/2兴 o
Level (cm⫺1 )
Wl Ref
A Ref
0.00
162435.6780
SS04
VVF96
0
1
0.00
161636.6175
SS04
VVF96
S
关 1/2兴 o
0
1
0.00
161524.1739
SS04
VVF96
S
关 1/2兴 o
0
1
0.00
159534.6196
SS04
VVF96
S
关 3/2兴 o
0
1
0.00
158795.9924
SS04
VVF96
S
关 1/2兴 o
0
1
0.00
135888.7173
SS04
VVF96
S
关 3/2兴 o
0
1
0.00
134459.2871
SS04
VVF96
关 1/2兴 o
关 1/2兴
1
0
135888.7173
164285.8872
SS04
FW96
关 3/2兴 o
关 1/2兴
1
0
134459.2871
152970.7328
SS04
FW96
关 1/2兴 o
关 1/2兴
1
0
135888.7173
152970.7328
SS04
FW96
关 3/2兴 o
关 1/2兴
1
1
134459.2871
151038.4524
SS04
FW96
关 3/2兴 o
关 1/2兴
1
0
134459.2871
150917.4307
SS04
FW96
关 3/2兴 o
关 3/2兴
2
2
134041.8400
150315.8612
SS04
FW96
关 1/2兴 o
关 1/2兴
0
1
134818.6405
151038.4524
SS04
FW96
关 3/2兴 o
关 3/2兴
2
1
134041.8400
150121.5922
SS04
FW96
关 1/2兴 o
关 3/2兴
0
1
134818.6405
150772.1118
SS04
FW96
关 3/2兴 o
关 3/2兴
1
1
134459.2871
150121.5922
SS04
FW96
关 3/2兴 o
关 5/2兴
2
3
134041.8400
149657.0393
SS04
FW96
关 3/2兴 o
关 5/2兴
1
2
134459.2871
149824.2215
SS04
FW96
关 1/2兴 o
关 1/2兴
1
1
135888.7173
151038.4524
SS04
FW96
关 1/2兴 o
关 3/2兴
1
2
135888.7173
150315.8612
SS04
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1864
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Neon 共Ne I兲—Continued
Inten
Wavelength 共Å兲
800
7032.4131
800
7173.9381
800
7245.1666
800
8377.6080
600
8654.3831
600
500
300
0.253
0.0287
0.0935
0.51
0.445
8780.6226
400
300
A ki (108 s⫺1 )
8783.7533
0.313
11143.0200
11177.5240
11522.7459
Configuration
Term
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P1/2
5 2 o
2p ( P3/2)3p
2
o
)3s
2 p 5 ( 2 P3/2
5 2 o
2p ( P3/2)3p
2
o
)3p
2 p 5 ( 2 P3/2
5 2 o
2p ( P3/2)3d
2
o
)3p
2 p 5 ( 2 P1/2
o
2p 5 ( 2 P1/2
)3d
2
o
)3p
2 p 5 ( 2 P3/2
5 2 o
2p ( P3/2)3d
2
o
)3p
2 p 5 ( 2 P1/2
5 2 o
2p ( P1/2)3d
2
o
)3p
2 p 5 ( 2 P3/2
5 2 o
2p ( P3/2)4s
2
o
)3p
2 p 5 ( 2 P3/2
5 2 o
2p ( P3/2)4s
2
o
)3p
2 p 5 ( 2 P1/2
o
2p 5 ( 2 P1/2
)4s
2
2
2
2
2
2
2
2
2
2
2
关 3/2兴
关 1/2兴
J
Level (cm⫺1 )
Wl Ref
A Ref
o
2
1
134041.8400
148257.7898
SS04
FW96
关 1/2兴 o
关 5/2兴
1
2
135888.7173
149824.2215
SS04
FW96
关 3/2兴 o
关 1/2兴
1
1
134459.2871
148257.7898
SS04
FW96
关 5/2兴
关 7/2兴 o
3
4
149657.0393
161590.3412
SS04
WSG66
关 3/2兴
关 5/2兴 o
2
3
150858.5079
162410.1736
SS04
WSG66
关 3/2兴
关 5/2兴 o
2
3
150315.8612
161701.4486
SS04
关 1/2兴
关 3/2兴 o
1
2
151038.4524
162419.9818
SS04
关 5/2兴
关 3/2兴 o
2
1
149824.2215
158795.9924
SS04
关 5/2兴
关 3/2兴 o
3
2
149657.0393
158601.1152
SS04
关 3/2兴
关 1/2兴 o
2
1
150858.5079
159534.6196
SS04
FW96
Energy Levels of Neutral Neon 共Ne I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
2p6
1
o
)3s
2p 5 ( 2 P3/2
2
关 3/2兴
o
2
1
134041.8400
134459.2871
SS04
SS04
o
)3s
2 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
134818.6405
135888.7173
SS04
SS04
o
)3p
2 p 5 ( 2 P3/2
2
关 1/2兴
1
0
148257.7898
150917.4307
SS04
SS04
o
)3p
2 p 5 ( 2 P3/2
2
关 5/2兴
3
2
149657.0393
149824.2215
SS04
SS04
o
)3p
2 p 5 ( 2 P3/2
2
关 3/2兴
1
2
150121.5922
150315.8612
SS04
SS04
o
)3p
2 p 5 ( 2 P1/2
2
关 3/2兴
1
2
150772.1118
150858.5079
SS04
SS04
o
)3p
2 p 5 ( 2 P1/2
2
关 1/2兴
1
0
151038.4524
152970.7328
SS04
SS04
o
)4s
2 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
158601.1152
158795.9924
SS04
SS04
o
)4s
2 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
159379.9935
159534.6196
SS04
SS04
S
0
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
0.00
SS04
ATOMIC SPECTROSCOPIC DATA
1865
Energy Levels of Neutral Neon 共Ne I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
o
)3d
2 p 5 ( 2 P3/2
2
关 1/2兴
o
0
1
161509.6305
161524.1739
SS04
SS04
o
)3d
2 p 5 ( 2 P3/2
2
关 7/2兴 o
4
3
161590.3412
161592.1200
SS04
SS04
o
)3d
2 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
161607.2609
161636.6175
SS04
SS04
o
)3d
2 p 5 ( 2 P3/2
2
关 5/2兴 o
2
3
161699.6613
161701.4486
SS04
SS04
o
)3d
2 p 5 ( 2 P1/2
2
关 5/2兴 o
2
3
162408.6536
162410.1736
SS04
SS04
o
)3d
2 p 5 ( 2 P1/2
2
关 3/2兴 o
2
1
162419.9818
162435.6780
SS04
SS04
o
)4p
2 p 5 ( 2 P1/2
2
关 1/2兴
0
164285.8872
SS04
o
2 p 5 ( 2 P3/2
)4d
2
关 7/2兴 o
4
167000.0317
SS04
173929.75
KM72
Ne II
o
( 2 P3/2
)
Limit
Persistent Lines of Singly-ionized Neon 共Ne II兲
Inten
90
60
200
300
250
1000
500
500
300
300
300
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
352.9549
6.69
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)4s
354.9620
445.0397
446.2556
446.5901
460.7284
462.3908
1916.083
1930.028
3027.016
3028.864
17.3
13.1
32.6
26.0
53.9
26.6
0.69
0.57
1.4
0.47
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3d
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 5
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 5
2s2 p 6
2s 2 2 p 5
2s2 p 6
J
Level (cm⫺1 )
P
P
3/2
3/2
2 o
P
P
2 o
Term
Wl Ref
A Ref
0.00
283322.35
P71
VVF96
3/2
3/2
0.00
281720.28
P71
VVF96
P
P
3/2
1/2
0.00
224699.27
P71
VVF96
2 o
P
P
3/2
3/2
0.00
224087.02
P71
VVF96
2 o
P
P
1/2
1/2
780.34
224699.27
P71
VVF96
2 o
P
S
3/2
1/2
0.00
217047.61
P71
VVF96
2 o
P
S
1/2
1/2
780.34
217047.61
P71
VVF96
P
P
3/2
3/2
224087.02
276276.85
P71
FW96
2 o
2
2
2
2
2
2
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 1 D)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 1 D)3p
2
P
P
1/2
1/2
224699.27
276511.82
P71
FW96
2s 2 2 p 4 ( 3 P)3p
2s 2 2 p 4 ( 3 P)3d
4 o
P
D
5/2
5/2
246192.45
279218.66
P71
FW96
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
P
S
1/2
3/2
219947.46
252953.54
P71
FW96
2 o
2 o
4
4 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1866
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Neon 共Ne II兲—Continued
Wavelength 共Å兲
Inten
500
3198.586
1000
3323.745
500
3378.216
800
3766.259
1000
3777.133
A ki (108 s⫺1 )
Configuration
2
1.7
1.6
1.7
0.29
0.42
4 3
J
Level (cm⫺1 )
D
F
5/2
7/2
P
P
Term
2s 2 p ( P)3p
2s 2 2 p 4 ( 3 P)3d
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
2
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
2s 2 2 p 4 ( 3 P)3s
2s 2 2 p 4 ( 3 P)3p
4
2
Wl Ref
A Ref
249445.99
280700.77
P71
FW96
3/2
3/2
224087.02
254165.01
P71
FW96
P
P
1/2
1/2
224699.27
254292.19
P71
FW96
P
P
3/2
5/2
219648.44
246192.45
P71
FW96
P
P
1/2
3/2
219947.46
246415.04
P71
FW96
o
2 o
2 o
4 o
4 o
Energy Levels of Singly-ionized Neon 共Ne II兲
Configuration
2
J
Level (cm⫺1 )
Ref
2 o
3/2
1/2
0.00
780.34
P71
P71
2s2 p 6
2
S
1/2
217047.61
P71
2s 2 2p 4 ( 3 P)3s
4
P
5/2
3/2
1/2
219130.78
219648.44
219947.46
P71
P71
P71
2s 2 2p 4 ( 3 P)3s
2
P
3/2
1/2
224087.02
224699.27
P71
P71
2s 2 2p 4 ( 3 P)3p
4 o
P
5/2
3/2
1/2
246192.45
246415.04
246597.71
P71
P71
P71
2s 2 2p 4 ( 1 D)3s
2
D
5/2
3/2
246394.13
246397.49
P71
P71
2s 2 2p 4 ( 3 P)3p
4
Do
7/2
5/2
3/2
1/2
249108.64
249445.99
249695.53
249839.63
P71
P71
P71
P71
2s 2 2p 4 ( 3 P)3p
2 o
S
1/2
252798.48
P71
2s 2p ( P)3p
4 o
S
3/2
252953.54
P71
2s 2 2p 4 ( 3 P)3p
2 o
P
3/2
1/2
254165.01
254292.19
P71
P71
2s 2 2p 4 ( 1 D)3p
2 o
P
3/2
1/2
276276.85
276511.82
P71
P71
2s 2 2p 4 ( 1 S)3s
2
S
1/2
276677.13
P71
2s 2 2p 4 ( 3 P)3d
4
D
5/2
279218.66
P71
2s 2p ( P)3d
2
F
7/2
280700.77
P71
2s 2 2p 4 ( 3 P)3d
2
P
3/2
281720.28
P71
2s 2 2p 4 ( 3 P)4s
2
P
3/2
283322.35
P71
Limit
330388.6
P71
2s 2p
2
2
5
Term
4 3
4 3
P
Ne III ( 3 P2 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1867
Neptunium „Np…
Atomic number⫽93
Atomic weight⫽237.0482
Isotope
237
Np
Mass
Abundance
Spin
Mag moment
237.048167
0
5/2
⫹3.14
Np I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 4 6d7s 2 6L11/2
Ionization energy: 50 536 cm⫺1 共6.2657 eV兲
Np II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 4 6d7s 7L5
Ionization energy: not available
Strong Lines of Neptunium 共Np兲
Intensity
300
300
300
300
1000
300
300
1000
300
300
300
300
1000
1000
300
300
300
300
300
1000
300
300
300
300
300
300
300
300
300
300
300
300
300
P
P,h
P,l
P,s
P
P,l
P,s
P,s
P,l
P,l
P,l
P,l
P
P
s
s
s
l
P,l
l
P,s
P,l
s
l
P,l
P,s
l
P,l
s
P,s
l
l
Wavelength 共Å兲
Air
3481.93
3501.50
3986.89
5044.66
5380.98
5878.04
6930.31
6972.09
7735.14
7765.75
7791.38
8339.12
8372.88
8529.96
8696.23
8906.02
8942.70
9004.75
9006.31
9016.18
9141.30
9379.33
9468.66
9679.13
9930.55
10091.99
10817.45
11695.15
11776.64
12148.18
12377.42
12407.99
13834.33
Spectrum
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
Np
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
FTBC76
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1868
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Neptunium 共Np I兲
Inten
300
Wavelength 共Å兲
A ki (108 s⫺1 )
3481.93
J
Level (cm⫺1 )
Wl Ref
L
11/2
13/2
0.000
28711.465
FTBC76
L
11/2
13/2
0.000
28551.035
FTBC76
L
11/2
13/2
0.000
25075.145
FTBC76
K
9/2
9/2
2033.965
21851.300
FTBC76
L
Mo
11/2
13/2
0.000
17007.700
FTBC76
K
L
9/2
9/2
2033.965
16459.340
FTBC76
L
Mo
11/2
11/2
0.000
14338.880
FTBC76
L
Mo
15/2
15/2
6903.440
19827.885
FTBC76
8
8
M
11/2
9/2
7112.430
19985.980
FTBC76
L
Mo
13/2
13/2
3502.855
16334.010
FTBC76
8
8
M
11/2
9/2
7112.430
19100.810
FTBC76
L
11/2
9/2
0.000
11940.075
FTBC76
G
3/2
5/2
6474.180
18194.400
FTBC76
M
11/2
9/2
7112.430
18200.530
FTBC76
K
9/2
9/2
2033.965
11940.075
FTBC76
I
7/2
7/2
3450.995
12692.765
FTBC76
I
7/2
9/2
3450.995
11940.075
FTBC76
G
5/2
7/2
4615.670
12692.765
FTBC76
Configuration
Term
4 5
6
5 f ( I)6d7s
2
o
300
3501.50
5 f 4 ( 5 I)6d7s 2
6
o
300
3986.89
5 f 4 ( 5 I)6d7s 2
6
o
300
5044.66
5 f 4 ( 5 I)6d7s 2
6
o
300
300
1000
300
300
5878.04
6930.31
6972.09
7735.14
7765.75
5 f 4 ( 5 I)6d7s 2
5 f 4 6d7s7 p
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I)6d7s7 p
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I)6d7s7 p
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I)6d7s7 p
5 f 4 ( 5 I)6d 2 ( 3 F)7s
6
6
6
8 o
6
8
6
o
300
300
7791.38
8339.12
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I)6d7s7 p
5 f 4 ( 5 I)6d 2 ( 3 F)7s
6
o
1000
1000
1000
8372.88
8529.96
9016.18
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I4 )7s 2 7 p 1/2
o
6
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I4 )7s 2 7 p 3/2
o
5 f 4 ( 5 I)6d 2 ( 3 F)7s
8
6
o
300
300
300
300
10091.99
10817.45
11776.64
12377.42
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I4 )7s 2 7 p 1/2
o
6
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I4 )7s 2 7 p 1/2
o
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I4 )7s 2 7 p 1/2
o
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I4 )7s 2 7 p 1/2
o
6
6
4
A Ref
ATOMIC SPECTROSCOPIC DATA
1869
Energy Levels of Neutral Neptunium 共Np I兲
Configuration
4 5
Term
J
Level (cm⫺1 )
Ref
2
6
11/2
13/2
15/2
17/2
19/2
21/2
0.000
3502.855
6903.440
10020.990
12930.155
16051.925
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 4 ( 5 I)6d7s 2
6
9/2
11/2
13/2
15/2
17/2
19/2
2033.965
5185.015
7792.035
10502.850
12948.015
15319.605
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 4 ( 5 I)6d7s 2
6
7/2
9/2
11/2
13/2
15/2
17/2
3450.995
6643.510
9694.045
11382.815
13049.900
14870.460
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 4 ( 5 I)6d7s 2
4
5/2
4615.670
BW92b
6
3/2
6474.180
BW92b
7/2
6892.085
BW92b
5 f ( I)6d7s
4 5
5 f ( I)6d7s
2
L
K
I
G
G
5 f 4 ( 5 I)6d7s 2
5 f 4 ( 5 I)6d7s 2
6
H
5/2
7015.155
BW92b
5 f 4 ( 5 I)6d 2 ( 3 F)7s
8
M
11/2
7112.430
BW92b
5 f ( I4 )7s 7p 1/2
o
9/2
7/2
11940.075
12692.765
BW92b
BW92b
5 f 4 ( 5 I)6d7s7p
8
4 5
2
Mo
11/2
14338.880
BW92b
5 f ( I4 )7s 7p 1/2
o
11/2
15743.235
BW92b
5 f 4 ( 5 I)6d7s7p
8
13/2
16334.010
BW92b
5 f 4 ( 5 I)6d7s7p
8 o
L
9/2
16459.340
BW92b
5 f 4 6d7s7p
6
Mo
4 5
4 5
2
2
5 f ( I4 )7s 7p 3/2
5 f 4 ( 5 I)6d7s7p
Np II (5 f 4 6d7s 7L5 )
Mo
13/2
17007.700
BW92b
o
5/2
18194.400
BW92b
o
9/2
18200.530
BW92b
o
9/2
19100.810
BW92b
8
Mo
15/2
19827.885
BW92b
o
9/2
19985.980
BW92b
o
9/2
21851.300
BW92b
o
13/2
25075.145
BW92b
o
13/2
28551.035
BW92b
o
13/2
28711.465
BW92b
Limit
50536
KDEE97
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1870
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Neptunium 共Np II兲
Inten
Wavelength 共Å兲
1000
A ki (108 s⫺1 )
Configuration
4
5 f 6d7s
5 f 4 7s7 p
5380.98
Term
J
Level (cm⫺1 )
Wl Ref
7
4
4
5451.830
24030.585
FTBC76
o
I
A Ref
Energy Levels of Singly-ionized Neptunium 共Np II兲
Configuration
Term
5 f 4 6d7s
7
5 f 4 7s 2
Level (cm⫺1 )
Ref
5
0.000
BW92b
5
4
24.270
BW92b
o
)7s
5 f 5 ( 6 H5/2
(5/2 ,1/2) o
2
3
83.490
1053.100
BW92b
BW92b
5 f 4 6d7s
7
L
6
1774.150
BW92b
4
5 f 6d7s
7
K
4
2473.180
BW92b
5 f 4 7s 2
5
I
5
3836.145
BW92b
5 f 4 6d7s
7
K
5
4007.270
BW92b
5 f 4 6d7s
7
I
3
4209.465
BW92b
5 f 6d7s
7
L
7
4797.670
BW92b
5 f 4 6d7s
5
L
6
5068.225
BW92b
5 f 4 6d7s
7
I
4
5451.830
BW92b
5 f 4 7s7p
o
4
24030.585
BW92b
I
4
Np III (5 f
L
J
56
o
H5/2
)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1871
Nickel „Ni…
Atomic number⫽28
Atomic weight⫽58.69
Isotope
58
Ni
Ni
61
Ni
62
Ni
64
Ni
60
Mass
Abundance
Spin
Mag moment
57.935346
59.930788
60.931058
61.928346
63.927968
68.27%
26.10%
1.13%
3.59%
0.91%
0
0
3/2
0
0
⫺0.75002
Ni I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 8 4s 2 3F4
Ionization energy: 61 619 cm⫺1 共7.6398 eV兲
Ni II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 2D5/2
Ionization energy: 146 541.56 cm⫺1 共18.168 84 eV兲
Strong Lines of Nickel 共Ni兲
Intensity
150 P
150
300
300
250
130
130
400
500
100
800
700
1000
130
150
150
300
130
130
200
80
150
250
200
150
150
150
150
300
250
150
110
60
150
50
150
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
1741.547
Air
2165.553
2169.096
2174.666
2175.147
2180.473
2184.605
2185.504
2192.090
2201.409
2205.548
2206.715
2216.482
2220.402
2222.957
2264.461
2270.214
2277.282
2278.770
2289.987
2300.781
2302.996
2310.961
2312.344
2313.656
2313.983
2316.039
2317.165
2320.034
2321.383
2325.802
2329.970
2337.488
2345.543
2347.514
2375.418
Spectrum
Ref
Ni II
S70
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
S70
LBT93
LBT93
S70
LBT93
LBT93
LBT93
LBT93
S70
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
S70
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
I
I
I
II
I
I
I
I
I
I
I
I
II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1872
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Nickel 共Ni兲—Continued
Intensity
150
300
60
70
60
120
500
250
500
40
200
400
200
250
60
50
300
150
400
130
70
80
80
40
40
300
100
40
40
40
400
50
400
150
400
40
40
1000
200
300
120
600
150
600
600
200
70
700
80
300
800
80
1000
40
600
120
150
150
60
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
2394.519
2416.134
2943.912
2981.646
2992.592
2994.453
3002.485
3003.621
3012.001
3019.143
3037.932
3050.816
3054.312
3057.639
3064.618
3080.752
3101.557
3101.878
3134.104
3232.933
3243.054
3297.600
3315.663
3320.259
3322.309
3331.875
3358.676
3361.554
3365.765
3366.166
3369.566
3371.987
3380.570
3391.043
3392.986
3413.476
3413.936
3414.764
3423.708
3433.556
3437.278
3446.259
3452.889
3458.460
3461.652
3472.545
3483.777
3492.956
3500.851
3510.335
3515.052
3519.765
3524.536
3548.182
3566.372
3571.864
3597.703
3610.462
3612.740
Spectrum
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
S70
S70
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
S70
LBT93
LBT93
LBT93
S70
S70
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
LBT93
ATOMIC SPECTROSCOPIC DATA
1873
Strong Lines of Nickel 共Ni兲—Continued
Intensity
Wavelength 共Å兲
800 P
70
90
90
150
80
150
120
3619.391
3775.571
3783.530
3807.144
3858.297
4992.024
8096.75
8121.48
Spectrum
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
I
I
I
I
I
II
II
II
Ref
LBT93
LBT93
LBT93
LBT93
LBT93
S70
S70
S70
Persistent Lines of Neutral Nickel 共Ni I兲
Inten
Wavelength 共Å兲
250
2310.961
300
150
500
500
400
300
400
1000
600
600
600
700
800
1000
600
2320.034
2345.543
3002.485
3012.001
3050.816
3101.557
3134.104
3414.764
3446.259
3458.460
3461.652
3492.956
3515.052
3524.536
3566.372
A ki (108 s⫺1 )
Configuration
3d 8 ( 3 F)4s 2
3d 8 ( 3 F)4s4 p( 1 Po)
6.94
2.23
0.903
1.3
0.604
0.699
0.749
0.615
0.455
0.667
0.278
1.02
0.474
1.09
0.56
3d 8 ( 3 F)4s 2
3d 8 ( 3 F)4s4 p( 1 Po)
3d 8 ( 3 F)4s 2
3d 8 ( 1 D)4s4p( 3 Po)
Term
J
Level (cm⫺1 )
Wl Ref
3
F
F
4
4
0.000
43258.726
LBT93
F
Go
4
5
0.000
43089.578
LBT93
M03
F
Do
4
3
0.000
42620.994
LBT93
M03
D
Do
3
3
204.787
33500.822
LBT93
M03
D
Do
2
2
3409.937
36600.791
LBT93
FW96
D
F
3
4
204.787
32973.376
LBT93
M03
D
F
2
3
879.816
33112.334
LBT93
M03
D
Do
1
2
1713.087
33610.890
LBT93
M03
D
F
3
4
204.787
29480.989
LBT93
M03
D
Do
2
2
879.816
29888.477
LBT93
M03
D
F
1
2
1713.087
30619.414
LBT93
M03
D
F
3
4
204.787
29084.456
LBT93
M03
D
P
2
1
879.816
29500.674
LBT93
M03
D
F
2
3
879.816
29320.762
LBT93
M03
D
P
3
2
204.787
28569.203
LBT93
M03
D
Do
2
2
3409.937
31441.635
LBT93
FW96
3 o
3
3
3
3
3d 9 ( 2 D)4s
3d 8 ( 3 F)4s4 p( 3 Po)
3
3d 9 ( 2 D)4s
3d 8 ( 3 F)4s4 p( 3 Po)
1
3d 9 ( 2 D)4s
3d 8 ( 3 F)4s4 p( 3 Po)
3
3d 9 ( 2 D)4s
3d 8 ( 3 F)4s4 p( 3 Po)
3
3d 9 ( 2 D)4s
3d 8 ( 3 F)4s4 p( 3 Po)
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
3
3d 9 ( 2 D)4s
3d 8 ( 3 F)4s4 p( 3 Po)
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
3
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
1
3
1
3 o
3 o
3
3 o
3
3 o
5 o
3 o
3 o
3 o
1
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1874
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Nickel 共Ni I兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
800
3619.391
0.66
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3d 9 ( 2 D)4s
3d 9 ( 2 D)4p
1
2
3
3409.937
31031.020
LBT93
FW96
D
F
1 o
Energy Levels of Neutral Nickel 共Ni I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
3d 8 ( 3 F)4s 2
3
F
4
3
2
0.000
1332.164
2216.550
LBT93
LBT93
LBT93
3d 9 ( 2 D)4s
3
D
3
2
1
204.787
879.816
1713.087
LBT93
LBT93
LBT93
3d 9 ( 2 D)4s
1
D
2
3409.937
LBT93
3d 8 ( 1 D)4s 2
1
D
2
13521.347
LBT93
3d 10
1
0
14728.840
LBT93
2
3
2
1
0
15609.844
15734.001
16017.306
LBT93
LBT93
LBT93
3d 8 ( 1 G)4s 2
1
8 3
3d ( P)4s
S
P
4
22102.325
LBT93
3d ( F)4s4p( P )
5
o
D
4
3
2
1
0
25753.553
26665.887
27414.868
27943.524
28212.998
LBT93
LBT93
LBT93
LBT93
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
5
Go
6
5
4
3
2
27260.894
27580.391
28068.065
28578.018
29013.206
LBT93
LBT93
LBT93
LBT93
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
5 o
F
5
4
3
2
1
28542.105
29084.456
29832.779
30163.124
30392.003
LBT93
LBT93
LBT93
LBT93
LBT93
3d 9 ( 2 D)4p
3 o
P
2
1
0
28569.203
29500.674
30192.251
LBT93
LBT93
LBT93
3d 9 ( 2 D)4p
3 o
F
4
3
2
29480.989
29320.762
30619.414
LBT93
LBT93
LBT93
3d 9 ( 2 D)4p
3
Do
3
2
1
29668.893
29888.477
30912.817
LBT93
LBT93
LBT93
3d 9 ( 2 D)4p
o
3
29668.918
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
3
5
4
3
30922.734
30979.749
31786.162
LBT93
LBT93
LBT93
8 3
3 o
G
Go
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1875
Energy Levels of Neutral Nickel 共Ni I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3d ( D)4p
1 o
F
3
31031.020
LBT93
3d 9 ( 2 D)4p
1
Do
2
31441.635
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
3 o
F
4
3
2
32973.376
33112.334
34163.264
LBT93
LBT93
LBT93
3d 9 ( 2 D)4p
1 o
P
1
32982.260
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
3
Do
3
2
1
33500.822
33610.890
34408.555
LBT93
LBT93
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
1
Go
4
33590.130
LBT93
3d 8 ( 3 F)4s4p( 3 Po)
1 o
3
35639.122
LBT93
3d ( F)4s4p( P )
1
o
D
2
36600.791
LBT93
3d 8 ( 3 P)4s4p( 3 Po)
5 o
P
3
2
1
40361.249
40484.212
40768.996
LBT93
LBT93
LBT93
3d 8 ( 1 D)4s4p( 3 Po)
3 o
F
4
3
2
42585.212
42767.853
42954.203
LBT93
LBT93
LBT93
3d 9 ( 2 D5/2)5s
2
关 5/2兴
3
2
42605.945
42790.010
LBT93
LBT93
3d 8 ( 1 D)4s4p( 3 Po)
3
Do
3
2
1
42620.994
42653.661
42656.289
LBT93
LBT93
LBT93
3d 8 ( 3 F)4s4p( 1 Po)
3
Go
5
4
3
43089.578
44314.904
44565.037
LBT93
LBT93
LBT93
3d 8 ( 3 F)4s4p( 1 Po)
3 o
4
3
2
43258.726
45281.089
45418.804
LBT93
LBT93
LBT93
61619
PG90
Configuration
9 2
8 3
3 o
F
F
Ni II ( 2 D5/2)
Limit
Persistent Lines of Singly-ionized Nickel 共Ni II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
150
1741.547
0.939
150
300
400
2165.553
2174.666
2185.504
2.36
1.56
Configuration
3d 9
3d 8 ( 3 F)4p
J
Level (cm⫺1 )
D
Do
5/2
5/2
F
F
Term
2
2
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
4
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
4
3d 8 ( 1 D)4s
3d 8 ( 3 P)4p
2
Wl Ref
A Ref
0.00
57420.16
S70
M03
9/2
9/2
8393.90
54557.05
S70
FL99
F
Go
7/2
9/2
9330.04
55299.65
S70
FL99
D
Do
5/2
7/2
25036.38
70778.12
S70
4 o
2
4
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1876
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Nickel 共Ni II兲—Continued
Inten
Wavelength 共Å兲
500
800
700
1000
300
150
A ki (108 s⫺1 )
8 3
2192.090
2205.548
2206.715
2216.482
2270.214
2316.039
Configuration
1.52
3.57
1.61
2.90
J
Level (cm⫺1 )
o
G
H
9/2
11/2
53365.17
98969.44
S70
Go
H
11/2
13/2
53496.49
98822.55
S70
F
F
5/2
7/2
10115.66
55417.83
S70
FL99
F
Go
9/2
11/2
8393.90
53496.49
S70
FL99
F
Go
7/2
9/2
9330.04
53365.17
S70
FL99
F
Do
9/2
7/2
8393.90
51557.85
S70
FL99
Term
3d ( F)4p
3d 8 ( 3 F)4d
4
3d 8 ( 3 F)4p
3d 8 ( 3 F)4d
4
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
4
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
4
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
4
3d 8 ( 3 F)4s
3d 8 ( 3 F)4p
4
2
4
4 o
4
4
4
Wl Ref
A Ref
Energy Levels of Singly-ionized Nickel 共Ni II兲
Configuration
J
Level (cm⫺1 )
Ref
2
D
5/2
3/2
0.00
1506.94
S70
S70
3d 8 ( 3 F)4s
4
F
9/2
7/2
5/2
3/2
8393.90
9330.04
10115.66
10663.89
S70
S70
S70
S70
3d 8 ( 3 F)4s
2
F
7/2
5/2
13550.39
14995.57
S70
S70
3d 8 ( 3 P)4s
4
P
5/2
3/2
1/2
23108.28
24788.20
24835.93
S70
S70
S70
3d 8 ( 1 D)4s
2
D
3/2
5/2
23796.18
25036.38
S70
S70
3d 8 ( 3 P)4s
2
P
3/2
1/2
29070.93
29593.46
S70
S70
3d 8 ( 1 G)4s
2
G
9/2
7/2
32499.53
32523.54
S70
S70
3d 7 4s 2
4
F
9/2
7/2
5/2
3/2
51045.46
52205.95
53037.93
53601.19
S70
S70
S70
S70
3d 8 ( 3 F)4p
4
Do
7/2
5/2
3/2
1/2
51557.85
52738.45
53634.62
54176.26
S70
S70
S70
S70
3d 8 ( 3 F)4p
4
Go
9/2
11/2
7/2
5/2
53365.17
53496.49
54262.63
55018.71
S70
S70
S70
S70
3d
9
Term
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1877
Energy Levels of Singly-ionized Nickel 共Ni II兲—Continued
J
Level (cm⫺1 )
3d ( F)4p
4 o
F
9/2
7/2
5/2
3/2
54557.05
55417.83
56075.26
56424.49
S70
S70
S70
S70
3d 8 ( 3 F)4p
2
Go
9/2
7/2
55299.65
56371.41
S70
S70
3d 8 ( 3 F)4p
2 o
F
7/2
5/2
57080.55
58493.21
S70
S70
3d 8 ( 3 F)4p
2
Do
5/2
3/2
57420.16
58705.95
S70
S70
3d 8 ( 3 P)4p
4 o
P
5/2
3/2
1/2
66571.34
66579.71
67031.02
S70
S70
S70
3d 8 ( 1 D)4p
2 o
5/2
7/2
67694.64
68131.21
S70
S70
3d 7 4s 2
4
P
5/2
3/2
1/2
67880.16
68156.57
68709.76
S70
S70
S70
3d 8 ( 1 D)4p
2
Do
3/2
5/2
68154.31
68735.98
S70
S70
3d 8 ( 1 D)4p
2 o
1/2
3/2
68281.62
68965.65
S70
S70
3d 7 4s 2
2
G
9/2
7/2
70358.94
71457.74
S70
S70
3d 8 ( 3 P)4p
4
Do
5/2
3/2
1/2
7/2
70635.46
70706.77
70748.70
70778.12
S70
S70
S70
S70
3d 8 ( 3 F)4d
4
D
7/2
5/2
1/2
3/2
98467.25
99559.33
100010.17
100078.78
S70
S70
S70
S70
3d 8 ( 3 F)4d
4
P
5/2
1/2
3/2
98561.22
100845.41
100490.95
S70
S70
S70
3d 8 ( 3 F)4d
4
H
13/2
11/2
9/2
7/2
98822.55
100309.29
100332.09
101144.63
S70
S70
S70
S70
3d 8 ( 3 F)4d
2
H
11/2
9/2
98969.44
101357.20
S70
S70
Limit
146541.56
S70
Configuration
8 3
Ni III ( 3 F4 )
Term
F
P
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1878
J. E. SANSONETTI AND W. C. MARTIN
Niobium „Nb…
Atomic number⫽41
Atomic weight⫽92.906 38
Isotope
93
Nb
Mass
Abundance
Spin
Mag moment
92.906377
100%
9/2
⫹6.1705
Nb I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 4 5s 6D1/2
Ionization energy: 54 513.8 cm⫺1 共6.758 85 eV兲
Nb II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 4 5D0
Ionization energy: 113 000 cm⫺1 共14.0 eV兲
Strong Lines of Niobium 共Nb兲
Intensity
1000
900
600
500
300
500
110
120
120
120
15
100
20
20
300
100
100
140
140
20
20
150
250
150
150
140
140
200
140
300
250
300
120
100
100
140
110
120
500
500
120
Wavelength 共Å兲
P
P
P
P
c
P
P
P
P
c
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2029.3423
2033.0102
2109.4384
2125.2164
2126.5498
2131.1832
2295.6800
2544.806
2583.987
2590.943
2592.20
2646.254
2647.50
2654.45
2697.060
2698.860
2702.194
2716.622
2721.981
2758.61
2773.20
2868.515
2875.390
2877.038
2883.174
2897.806
2908.240
2910.587
2911.743
2927.814
2941.543
2950.882
2972.571
2974.094
2990.278
2994.728
3028.440
3076.865
3094.176
3130.782
3145.403
Spectrum
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
II
II
II
II
II
II
II
II
II
II
I
II
I
I
II
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
MCS75
RCL00
MCS75
MCS75
RCL00
RCL00
RCL00
RCL00
RCL00
MCS75
MCS75
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
ATOMIC SPECTROSCOPIC DATA
1879
Strong Lines of Niobium 共Nb兲—Continued
Intensity
Wavelength 共Å兲
400 P
120
300 P
120
250 P
120
100
20
25
80 P
80 P
110 P
25
20
110 P
20
20
15
20
15
20
30
30
120 P
80
30
20
60
40
40
90 P
300 P
30
50
30
30
30
25
120
40
60
15
90
20
200
30
150
15
150 P
200
15
110
30
20
30
50
110
80
200
3163.401
3180.285
3194.975
3215.593
3225.467
3236.410
3254.066
3296.01
3312.60
3341.97
3343.71
3349.06
3349.52
3354.74
3358.42
3366.96
3374.92
3380.41
3392.34
3408.38
3478.69
3498.63
3507.96
3535.30
3537.48
3544.02
3550.45
3554.66
3563.50
3563.62
3575.85
3580.27
3584.97
3589.11
3589.36
3593.97
3602.56
3649.85
3651.182
3660.37
3664.70
3674.78
3697.85
3711.34
3713.01
3716.99
3726.24
3738.42
3739.80
3740.714
3741.78
3742.39
3763.49
3765.08
3771.85
3781.01
3787.06
3790.15
3791.21
Spectrum
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
Ref
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
RCL00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
RCL00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
RCL00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1880
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Niobium 共Nb兲—Continued
Intensity
150
15
150
40
30
40
30
30
40
20
20
20
15
30
50
40
70
40
40
40
30
40
30
60
70
1000
20
800
15
30
400
20
300
40
50
140
30
150
20
50
300
50
300
250
200
20
80
50
50
80
20
20
50
20
25
25
50
25
20
Wavelength 共Å兲
d
P,c
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3798.12
3801.30
3802.92
3803.88
3804.74
3810.49
3811.03
3815.51
3824.88
3835.18
3858.95
3863.38
3867.92
3877.56
3878.82
3883.14
3885.44
3885.68
3891.30
3914.70
3920.20
3937.44
3943.67
3966.09
4032.52
4058.94
4060.79
4079.73
4084.86
4100.40
4100.92
4116.90
4123.81
4129.43
4129.93
4137.10
4139.44
4139.71
4143.21
4150.12
4152.58
4163.47
4163.66
4164.66
4168.13
4184.44
4190.88
4192.07
4195.09
4195.66
4198.51
4201.52
4205.31
4214.73
4217.94
4229.15
4262.05
4266.02
4270.69
Spectrum
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1881
Strong Lines of Niobium 共Nb兲—Continued
Intensity
Wavelength 共Å兲
25
40
40
25
20
25
20
20
20
30
30
25
40
30
80
30
30
30
20
40
30
20
50
25
15
15
15
15
30
20
13 c,w
Spectrum
4286.99
4299.60
4300.99
4311.27
4326.33
4331.37
4351.57
4410.21
4447.18
4523.41
4546.82
4564.53
4573.08
4581.62
4606.77
4630.11
4648.95
4663.83
4666.24
4672.09
4675.37
4685.14
5078.96
5095.30
5160.33
5164.38
5271.53
5318.60
5344.17
5350.74
6660.84
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Niobium 共Nb I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
3
2
Term
J
Level (cm⫺1 )
Wl Ref
4
80
3341.97
4d 5s
4d 3 5s(a 5 F)5p
a F
x 4Go
3/2
5/2
1142.79
31056.60
MCS75
80
3343.71
4d 3 5s 2
4d 3 5s(a 5 F)5p
a 4F
x 4Go
5/2
7/2
1586.90
31485.20
MCS75
110
3349.06
4d 3 5s 2
4d 3 5s(a 5 F)5p
a 4F
x 4Go
7/2
9/2
2154.11
32004.63
MCS75
110
3358.42
4d 3 5s 2
4d 3 5s(a 5 F)5p
a 4F
x 4Go
9/2
11/2
2805.36
32572.72
MCS75
120
3535.30
4d 4 (a 5 D)5s
4d 3 5s(a 5 P)5p
4d 4 (a 5 D)5s
4d 3 5s(a 5 P)5p
a 6D
y 6Po
a 6D
y 6Po
7/2
7/2
1/2
3/2
695.25
28973.12
0.00
28278.25
MCS75
90
3575.85
4d 4 (a 5 D)5s
4d 3 5s(a 5 P)5p
a 6D
y 6Po
7/2
5/2
695.25
28652.66
MCS75
300
3580.27
4d 4 (a 5 D)5s
4d 3 5s(a 5 P)5p
a 6D
y 6Po
9/2
7/2
1050.26
28973.12
MCS75
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1882
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Niobium 共Nb I兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
4
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
5
6
150
3739.80
0.59
4d (a D)5s
4d 4 (a 5 D)5p
a D
x 6Do
7/2
7/2
695.25
27427.07
MCS75
DHL86
1000
4058.94
1.28
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
9/2
11/2
1050.26
25680.36
MCS75
DHL86
4d 3 5s 2
4d 3 5s(a 5 P)5p
a 2D
x 4Po
5/2
3/2
10237.51
34867.68
800
4079.73
0.99
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
7/2
9/2
695.25
25199.81
MCS75
DHL86
400
4100.92
0.76
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
5/2
7/2
391.99
24769.91
MCS75
DHL86
4d 4 (b 3 F)5s
4d 4 (c 3 F)5p
b 4F
u 4Go
9/2
9/2
13145.71
37523.53
300
4123.81
0.58
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
3/2
5/2
154.19
24396.80
MCS75
DHL86
300
4152.58
0.38
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
7/2
7/2
695.25
24769.91
MCS75
DHL86
300
4163.66
0.65
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
3/2
3/2
154.19
24164.79
MCS75
DHL86
250
4164.66
0.50
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
5/2
5/2
391.99
24396.80
MCS75
DHL86
200
4168.13
0.91
4d 4 (a 5 D)5s
4d 4 (a 5 D)5p
a 6D
y 6Fo
1/2
1/2
0.00
23984.87
MCS75
DHL86
Energy Levels of Neutral Niobium 共Nb I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4d 4 (a 5 D)5s
a 6D
1/2
3/2
5/2
7/2
9/2
0.00
154.19
391.99
695.25
1050.26
M52
M52
M52
M52
M52
4d 3 5s 2
a 4F
3/2
5/2
7/2
9/2
1142.79
1586.90
2154.11
2805.36
M52
M52
M52
M52
4d 3 5s 2
a 4P
1/2
3/2
5/2
4998.17
5297.92
5965.45
M52
M52
M52
4d 4 (a 5 D)5s
a 4D
1/2
3/2
5/2
7/2
8410.90
8705.32
9043.14
9497.52
M52
M52
M52
M52
4d 3 5s 2
a 2D
3/2
5/2
9439.08
10237.51
M52
M52
4d 4 (b 3 F)5s
b 4F
9/2
13145.71
M52
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1883
Energy Levels of Neutral Niobium 共Nb I兲—Continued
Configuration
4
5
Term
6 o
J
Level (cm⫺1 )
Ref
4d (a D)5p
y F
1/2
3/2
5/2
7/2
9/2
11/2
23984.87
24164.79
24396.80
24769.91
25199.81
25680.36
M52
M52
M52
M52
M52
M52
4d 4 (a 5 D)5p
x 6Do
7/2
27427.07
M52
4d 3 5s(a 5 P)5p
y 6Po
3/2
5/2
7/2
28278.25
28652.66
28973.12
M52
M52
M52
4d 3 5s(a 5 F)5p
x 4Go
5/2
7/2
9/2
11/2
31056.60
31485.20
32004.63
32572.72
M52
M52
M52
M52
4d 3 5s(a 5 P)5p
x 4Po
3/2
34867.68
M52
4d 4 (c 3 F)5p
u 4Go
9/2
37523.53
M52
Limit
54513.8
RMBH87
Nb II ( 5 D0 )
Persistent Lines of Singly-ionized Niobium 共Nb II兲
Inten
Wavelength 共Å兲
1000
2029.3423
900
600
300
140
140
250
150
300
300
500
A ki (108 s⫺1 )
2033.0102
2109.4384
2697.0598
2716.6220
2721.9807
2875.3904
2883.1739
2927.8137
2950.8816
3094.1756
1.0
0.43
0.43
Term
J
Level (cm⫺1 )
Wl Ref
4d 3 ( 4 F)5s
4d 2 ( 3 F)5s5 p( 3 P)
5
F
Do
5
4
4146.036
53407.279
RCL00
4d 3 ( 4 F)5s
4d 2 ( 3 F)5s5 p( 3 P)
5
F
Do
4
3
3542.561
52714.892
RCL00
4d 3 ( 4 F)5s
4d 2 ( 3 F)5s5 p( 3 P)
5
F
F
5
5
4146.036
51537.014
RCL00
4
4
1224.823
38291.252
RCL00
M00
4
5
1224.823
38024.336
RCL00
M00
D
F
3
4
801.326
37528.382
RCL00
M00
F
Do
3
2
3029.629
37797.316
RCL00
F
Do
4
3
3542.561
38216.387
RCL00
F
Do
5
4
4146.036
38291.252
RCL00
F
F
5
5
4146.036
38024.336
RCL00
F
Go
5
6
4146.036
36455.457
RCL00
Configuration
4d 4
4d 3 ( 4 F)5p
4d 4
4d 3 ( 4 F)5p
4d 4
4d 3 ( 4 F)5p
5
5
5 o
5
5
D
Do
5
D
F
5 o
5
5 o
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
5
5
5
5 o
5
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1884
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Niobium 共Nb II兲—Continued
Inten
Wavelength 共Å兲
500
400
300
250
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
4d ( F)5s
4d 3 ( 4 F)5p
5
F
Go
4
5
3542.561
35474.197
RCL00
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
F
Go
3
4
3029.629
34632.033
RCL00
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
F
Go
2
3
2629.132
33919.244
RCL00
4d 3 ( 4 F)5s
4d 3 ( 4 F)5p
5
F
Go
1
2
2356.816
33351.090
RCL00
Configuration
3 4
3130.7824
3163.4006
3194.9747
3225.4667
5
5
5
5
A Ref
Energy Levels of Singly-ionized Niobium 共Nb II兲
Level (cm⫺1 )
Configuration
Term
J
4d 4
5
D
0
1
2
3
4
0.000
158.984
438.361
801.326
1224.823
RCL00
RCL00
RCL00
RCL00
RCL00
4d 3 ( 4 F)5s
5
F
1
2
3
4
5
2356.816
2629.132
3029.629
3542.561
4146.037
RCL00
RCL00
RCL00
RCL00
RCL00
4d 4
3
P
0
1
2
5562.241
6192.310
7261.324
RCL00
RCL00
RCL00
4d 3 ( 2 P)5s
3
P
1
2
0
14626.199
14660.755
14678.318
RCL00
RCL00
RCL00
4d 3 ( 4 F)5p
5
Go
2
3
4
5
6
33351.090
33919.244
34632.033
35474.197
36455.457
RCL00
RCL00
RCL00
RCL00
RCL00
4d 3 ( 4 F)5p
5 o
F
1
2
3
4
5
36731.805
36962.774
37376.901
37528.382
38024.336
RCL00
RCL00
RCL00
RCL00
RCL00
4d 3 ( 4 F)5p
5
Do
0
1
2
3
4
37298.242
37480.076
37797.316
38216.387
38291.252
RCL00
RCL00
RCL00
RCL00
RCL00
4d 2 ( 3 F)5s5p( 3 P)
5 o
F
5
51537.014
RCL00
4d 2 ( 3 F)5s5p( 3 P)
5
Do
3
4
52714.892
53407.279
RCL00
RCL00
Nb III ( 4 F3/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
113000
Ref
M52
ATOMIC SPECTROSCOPIC DATA
1885
Nitrogen „N…
Atomic number⫽7
Atomic weight⫽14.006 74
Isotope
14
15
N
N
Mass
Abundance
Spin
Mag moment
14.003074
15.000108
99.63%
0.37%
1
1/2
⫹0.40376
⫺0.28319
o
N I Ground state: 1s 2 2s 2 2p 3 4S3/2
⫺1
Ionization energy: 117 225.7 cm 共14.5341 eV兲
N II Ground state: 1s 2 2s 2 2p 2 3P0
Ionization energy: 238 750.3 cm⫺1 共29.6013 eV兲
Strong Lines of Nitrogen 共N兲
Intensity
200
600
1000
80
200
50
50
60
200
25
60
15
100
90
90
1000
700
300
250
90
250
120
150
200
150
P
P
P
P
P
P
P,d
P,d
P
P,d
P
P
P
P
P
P
P
P
20
50 P
30
20
30 P
30
20
20
40 P
30
20
80
20
30
Wavelength 共Å兲
Vacuum
644.635
644.837
645.179
692.70
775.967
915.613
915.963
916.019
916.708
1083.994
1084.580
1085.550
1085.710
1134.165
1134.415
1199.550
1200.223
1200.710
1243.179
1411.94
1492.625
1492.820
1494.675
1742.729
1745.252
Air
3955.85
3995.00
4041.31
4241.78
4447.03
4601.48
4607.16
4621.39
4630.54
4643.08
4803.29
4963.98
4994.36
5001.48
Spectrum
Ref
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
II
II
II
I
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
E83
E83
E83
M75a
E83
E83
E83
E83
E83
E83
E83
E83
E83
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
N
N
N
N
N
N
N
N
N
N
N
N
N
N
II
II
II
II
II
II
II
II
II
II
II
I
II
II
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1886
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Nitrogen 共N兲—Continued
Wavelength 共Å兲
Intensity
40
30
20
30
30
30
40
20
20
150
30
30
40
90
40
150
200
200
90
90
140
90
90
30
120
140
150
120
150
150
120
120
140
120
120
140
80
90
90
200
120
200
P
Spectrum
5005.15
5007.32
5010.62
5045.10
5666.63
5676.02
5679.56
5686.21
5710.77
5752.50
5931.78
5941.65
6482.05
6482.70
6610.56
7423.64
7442.29
7468.31
8184.87
8188.02
8216.34
8223.14
8242.39
8438.74
8567.74
8594.00
8629.24
8655.89
8680.28
8683.40
8686.15
8703.25
8711.70
8718.83
9386.80
9392.79
10112.48
10114.64
12186.82
12469.62
13429.61
13581.33
P
P
P
P
P
P
P
P
P
P
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
Ref
II
II
II
II
II
II
II
II
II
I
II
II
II
I
II
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
M75a
Persistent Lines of Neutral Nitrogen 共N I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
1000
1199.550
4.07
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
700
300
250
1200.223
1200.710
1243.179
4.02
4.00
3.21
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 3
2s 2 2 p 2 ( 1 D)3s
J
Level (cm⫺1 )
S
P
3/2
5/2
0.000
83364.620
M75a
M03
4 o
S
P
3/2
3/2
0.000
83317.830
M75a
M03
4 o
S
P
3/2
1/2
0.000
83284.070
M75a
M03
Do
D
5/2
5/2
19224.464
99663.427
M75a
WFD96
Term
4 o
4
4
4
2
2
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1887
Persistent Lines of Neutral Nitrogen 共N I兲—Continued
Wavelength 共Å兲
Inten
250
1492.625
200
1742.729
200
7442.29
200
7468.31
150
8680.28
150
8683.40
200
12469.62
200
13581.33
A ki (108 s⫺1 )
3.13
1.16
0.124
0.193
0.246
0.180
0.228
0.0639
Configuration
2
3
2s 2 p
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
J
Level (cm⫺1 )
o
D
P
5/2
3/2
19224.464
86220.510
M75a
WFD96
2 o
P
P
3/2
3/2
28839.306
86220.510
M75a
WFD96
P
S
3/2
3/2
83317.830
96750.840
M75a
WFD96
P
S
5/2
3/2
83364.620
96750.840
M75a
WFD96
P
Do
5/2
7/2
83364.620
94881.820
M75a
WFD96
P
Do
3/2
5/2
83317.830
94830.890
M75a
WFD96
Do
F
5/2
7/2
96864.050
104881.350
M75a
WFD96
P
S
3/2
1/2
86220.510
93581.550
M75a
WFD96
Term
2
2
2
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
4
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
4
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
4
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
4
2s 2 2 p 2 ( 3 P)3p
2s 2 2 p 2 ( 3 P)3d
2
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
2
4 o
4 o
4
4
2
2 o
Wl Ref
A Ref
Energy Levels of Neutral Nitrogen 共N I兲
Configuration
2
J
Level (cm⫺1 )
Ref
4 o
3/2
0.000
M75a
2s 2 2p 3
2
Do
5/2
3/2
19224.464
19233.177
M75a
M75a
2s 2 2p 3
2 o
P
1/2
3/2
28838.920
28839.306
M75a
M75a
2s 2 2p 2 ( 3 P)3s
4
P
1/2
3/2
5/2
83284.070
83317.830
83364.620
M75a
M75a
M75a
2s 2 2p 2 ( 3 P)3s
2
P
1/2
3/2
86137.350
86220.510
M75a
M75a
2s2p 4
4
P
5/2
3/2
1/2
88107.260
88151.170
88170.570
M75a
M75a
M75a
2s 2 2p 2 ( 3 P)3p
2 o
S
1/2
93581.550
M75a
2s 2 2p 2 ( 3 P)3p
4
Do
1/2
3/2
5/2
7/2
94770.880
94793.490
94830.890
94881.820
M75a
M75a
M75a
M75a
2s 2 2p 2 ( 3 P)3p
4 o
1/2
3/2
5/2
95475.310
95493.690
95532.150
M75a
M75a
M75a
2s 2 2p 2 ( 3 P)3p
4 o
3/2
96750.840
M75a
2
3/2
5/2
96787.680
96864.050
M75a
M75a
2s 2p
2
3
Term
2 3
2s 2p ( P)3p
S
P
S
o
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1888
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Nitrogen 共N I兲—Continued
J
Level (cm⫺1 )
Ref
2s 2p ( P)3p
2 o
P
1/2
3/2
97770.180
97805.840
M75a
M75a
2s 2 2p 2 ( 1 D)3s
2
D
5/2
3/2
99663.427
99663.912
M75a
M75a
2s 2 2p 2 ( 3 P)4s
4
P
1/2
3/2
5/2
103622.51
103667.16
103735.48
M75a
M75a
M75a
2s 2 2p 2 ( 3 P)4s
2
P
1/2
3/2
104144.820
104221.630
M75a
M75a
2s 2 2p 2 ( 3 P)3d
2
P
3/2
1/2
104615.470
104654.030
M75a
M75a
2s 2 2p 2 ( 3 P)3d
4
F
3/2
5/2
7/2
9/2
104664.130
104683.060
104716.950
104765.77
M75a
M75a
M75a
M75a
2s 2 2p 2 ( 3 P)3d
2
F
5/2
7/2
104810.360
104881.350
M75a
M75a
117225.7
M75a
Configuration
2
Term
2 3
N II ( 3 P0 )
Limit
Persistent Lines of Singly-ionized Nitrogen 共N II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
200
644.635
12.1
600
1000
400
50
50
60
644.837
645.179
775.967
915.613
915.963
916.019
36.4
60.7
30.8
4.38
13.2
3.26
3.33
200
916.708
9.90
5.46
25
1083.994
2.18
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
Term
J
Level (cm⫺1 )
3
P
S
0
1
0.00
155126.73
E83
WFD96
P
S
1
1
48.67
155126.73
E83
WFD96
P
S
2
1
130.80
155126.73
E83
WFD96
D
Do
2
2
15316.17
144187.94
E83
WFD96
P
P
0
1
0.00
109216.44
E83
WFD96
P
P
1
0
48.67
109223.34
E83
WFD96
P
P
1
2
48.67
109216.93
E83
WFD96
P
P
1
1
48.67
109216.44
P
P
3
P
3 o
P
2
2
2
1
130.80
109216.93
130.80
109216.44
E83
WFD96
E83
WFD96
3
0
1
0.00
92251.46
E83
WFD96
3 o
3
3 o
3
3 o
1
1
3
3 o
3
3 o
3
3 o
3
3 o
3
3 o
3
P
Do
Wl Ref
A Ref
WFD96
ATOMIC SPECTROSCOPIC DATA
1889
Persistent Lines of Singly-ionized Nitrogen 共N II兲—Continued
Inten
Wavelength 共Å兲
60
1084.580
A ki (108 s⫺1 )
1.61
2.93
15
1085.550
100
1085.710
50
3995.00
30
4447.03
40
4630.54
40
5005.15
40
5679.56
30
5941.65
40
6482.05
40
6610.56
0.947
3.87
1.35
1.14
0.772
1.16
0.525
0.554
0.301
0.634
Term
J
Level (cm⫺1 )
3
1
1
48.67
92251.46
1
2
48.67
92249.91
P
Do
3
P
3 o
D
2
2
2
1
130.80
92249.91
130.80
92251.46
E83
WFD96
E83
WFD96
3
P
Do
2
3
130.80
92236.46
E83
WFD96
2s 2 2 p( 2 Po)3s
2s 2 2 p( 2 Po)3p
1 o
P
D
1
2
149187.80
174212.03
M75a
WFD96
2s 2 2 p( 2 Po)3p
2s 2 2 p( 2 Po)3d
1
P
Do
1
2
164610.76
187091.37
M75a
WFD96
2s 2 2 p( 2 Po)3s
2s 2 2 p( 2 Po)3p
3 o
P
P
2
2
149076.52
170666.23
M75a
WFD96
2s 2 2 p( 2 Po)3p
2s 2 2 p( 2 Po)3d
3
D
F
3
4
166678.64
186652.49
M75a
WFD96
2s 2 2 p( 2 Po)3s
2s 2 2 p( 2 Po)3p
3 o
P
D
2
3
149076.52
166678.64
M75a
WFD96
2s 2 2 p( 2 Po)3p
2s 2 2 p( 2 Po)3d
3
P
Do
2
3
170666.23
187491.90
M75a
WFD96
2s 2 2 p( 2 Po)3s
2s 2 2 p( 2 Po)3p
1 o
P
P
1
1
149187.80
164610.76
M75a
WFD96
2s 2 2 p( 2 Po)3p
2s 2 2 p( 2 Po)3d
1
D
F
2
3
174212.03
189335.16
M75a
WFD96
Configuration
2 1
2s ( S)2p
2s( 2 S)2p 3
2
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
2s 2 ( 1 S)2p 2
2s( 2 S)2p 3
P
Do
3
3
P
Do
3
3
3
3
1
1
3
3 o
3
3
1
1 o
Wl Ref
E83
A Ref
WFD96
WFD96
Energy Levels of Singly-ionized Nitrogen 共N II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
2s 2 ( 1 S)2p 2
3
0
1
2
0.00
48.67
130.80
2s 2 ( 1 S)2p 2
1
2
15316.17
S95
2s 2 ( 1 S)2p 2
1
0
32688.64
E83
2s( 2 S)2p 3
5 o
2
46784.56
E83
3
o
D
3
2
1
92236.46
92249.91
92251.46
E83
E83
E83
2s( 2 S)2p 3
3 o
1
2
0
109216.44
109216.93
109223.34
E83
E83
E83
2s( 2 S)2p 3
1
2
144187.94
M75a
2
2s( S)2p
3
P
D
S
S
P
Do
BVEC94
BVEC94
BVEC94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1890
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Nitrogen 共N II兲—Continued
J
Level (cm⫺1 )
2s 2p( P )3s
3 o
P
0
1
2
148908.59
148940.17
149076.52
M75a
M75a
M75a
2s 2 2p( 2 Po)3s
1 o
P
1
149187.80
M75a
2s( 2 S)2p 3
3 o
S
1
155126.73
M75a
2s 2 2p( 2 Po)3p
1
P
1
164610.76
M75a
2s 2 2p( 2 Po)3p
3
D
1
2
3
166521.69
166582.45
166678.64
M75a
M75a
M75a
2s( 2 S)2p 3
1 o
P
1
166765.66
M75a
2s 2 2p( 2 Po)3p
3
S
1
168892.21
M75a
2s 2p( P )3p
3
P
0
1
2
170572.61
170607.89
170666.23
M75a
M75a
M75a
2s 2 2p( 2 Po)3p
1
D
2
174212.03
M75a
2s 2 2p( 2 Po)3p
1
S
0
178273.38
M75a
2s 2 2p( 2 Po)3d
3 o
F
2
3
4
186511.58
186570.98
186652.49
M75a
M75a
M75a
2s 2 2p( 2 Po)3d
1
Do
2
187091.37
M75a
2s 2 2p( 2 Po)3d
3
Do
1
2
3
187437.56
187461.56
187491.90
M75a
M75a
M75a
2s 2 2p( 2 Po)3d
3 o
P
2
1
0
188857.37
188909.17
188937.24
M75a
M75a
M75a
2s 2 2p( 2 Po)3d
1 o
3
189335.16
M75a
Limit
238750.3
E83
Configuration
2
2
N III
2 o
2 o
Term
F
o
)
( 2 P1/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1891
Osmium „Os…
Atomic number⫽76
Atomic weight⫽190.2
Isotope
184
Os
Os
187
Os
188
Os
189
Os
190
Os
192
Os
186
Mass
Abundance
Spin
183.952488
185.953830
186.955741
187.955860
188.958137
189.958436
191.961476
0.02%
1.58%
1.6%
13.3%
16.1%
26.4%
41.0%
0
0
1/2
0
3/2
0
0
Mag moment
⫹0.0646
⫹0.6599
Os I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 6 6s 2 5D4
Ionization energy: 68 058.9 cm⫺1 共8.438 23 eV兲
Os II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 6 6s 6D9/2
Ionization energy: not available
Strong Lines of Osmium 共Os兲
Intensity
300
400
300
600
1000
1000
500
500
600
900
300*
300*
400
1000
500
250
250
500
100
100
100
200
200
70
150
250
70
200
80
90
40
40
80
110
40
P
P
P
P
P
P
Wavelength 共Å兲
Air
2001.45
2003.73
2004.81
2010.15
2018.14
2020.26
2022.76
2028.23
2034.44
2045.36
2058.69
2058.78
2061.69
2067.21
2070.67
2076.95
2078.09
2079.97
2082.54
2089.03
2089.21
2097.60
2100.63
2117.66
2117.96
2119.79
2123.84
2137.11
2149.97
2154.59
2157.84
2158.53
2161.00
2166.90
2167.75
Spectrum
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1892
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Osmium 共Os兲—Continued
Intensity
Wavelength 共Å兲
70
30
110 P
40
40
250 P
50
30
200 P
30
25
25
90 P
30
15
30
60 P
12
90
30
60
40
30
12
12
25
50
30
14
60
14
30
70 P
90
25
80
25
25
100 P
30
25
20
20
15
25
30
20
60
30
20
130 P
70
70
20
20
70
20
20
100 P
2171.65
2184.68
2194.39
2234.61
2252.15
2255.85
2264.60
2270.17
2282.26
2283.67
2308.31
2313.75
2336.80
2350.23
2355.28
2362.77
2367.35
2375.06
2377.03
2379.39
2387.29
2395.88
2401.13
2405.08
2420.02
2423.07
2424.97
2450.74
2454.91
2461.42
2468.90
2476.84
2486.24
2498.41
2512.87
2513.25
2515.04
2518.44
2538.00
2542.51
2563.16
2566.49
2578.32
2580.03
2581.96
2590.76
2596.00
2613.06
2619.94
2621.82
2637.13
2644.11
2658.60
2659.83
2674.57
2689.82
2699.59
2706.70
2714.64
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
I
I
II
I
I
II
I
I
II
I
I
II
II
II
II
I
II
II
I
I
I
I
I
II
II
II
I
I
II
I
II
I
II
I
I
I
I
I
II
I
II
I
II
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1893
Strong Lines of Osmium 共Os兲—Continued
Intensity
Wavelength 共Å兲
20
40
30
20
20
25
30
25
20
20
100 P
25
200 P
25
80
50
50
300 P
70
20
70
20
40 h
50
20
25
20
20
150 P
40
100
15
300 P
20
40
20
110
25
20
70
110 P
110 P
20
20
40
250 P
20
30
30
20
20
20
40
30
40
20
12
130
70 P
2715.36
2720.04
2721.86
2730.61
2732.80
2761.42
2770.71
2782.55
2786.31
2796.73
2806.91
2814.20
2838.63
2841.60
2844.40
2850.76
2860.96
2909.06
2912.33
2917.26
2919.79
2931.28
2948.23
2949.53
2962.15
2970.97
2982.90
3017.25
3018.04
3030.70
3040.90
3042.74
3058.66
3062.19
3077.72
3109.38
3156.25
3173.93
3213.31
3232.06
3262.29
3267.94
3269.21
3275.20
3290.26
3301.56
3310.91
3336.15
3370.59
3387.84
3401.86
3504.66
3528.60
3559.79
3560.86
3598.11
3604.48
3752.52
3782.20
Spectrum
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1894
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Osmium 共Os兲—Continued
Intensity
Wavelength 共Å兲
20
25
30
25
30
40
90
40
20
40
150 P
20
20
20
150 P
20
25
9
9
6
6
3790.14
3876.77
3963.63
3977.23
4066.69
4112.02
4135.78
4173.23
4175.63
4211.86
4260.85
4293.95
4311.40
4394.86
4420.47
4550.41
4793.99
5202.63
5523.53
5721.93
5780.82
Spectrum
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Os
Ref
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Osmium 共Os I兲
Inten
Wavelength 共Å兲
1000
2018.14
A ki (108 s⫺1 )
Configuration
5d 6 6s 2
Term
J
Level (cm⫺1 )
Wl Ref
5
D
4
5
0.00
49534.28
MCS75
D
4
3
0.00
49138.11
MCS75
D
4
3
0.00
48874.93
MCS75
D
4
5
0.00
48062.22
MCS75
D
Do
4
4
0.00
37908.77
MCS75
D
Do
4
4
0.00
36826.39
MCS75
D
P
4
3
0.00
35615.92
MCS75
F
F
5
4
5143.92
40361.92
MCS75
D
F
4
5
0.00
34365.33
MCS75
D
P
4
3
0.00
33124.48
MCS75
D
F
4
4
0.00
32684.61
MCS75
F
Do
3
3
14091.37
46776.29
o
600
5d 6 6s 2
2034.44
5
o
900
5d 6 6s 2
2045.36
5
o
500
5d 6 6s 2
2079.97
5
o
130
100
100
200
300
150
300
5d 6 6s 2
5d 6 6s( 4 D)6p
2637.13
5d 6 6s 2
5d 6 6s( 6 D)6p
2714.64
5d 6 6s 2
5d 6 6s( 6 D)6p
2806.91
5d 7 ( 4 F)6s
5d 6 6s( 4 D)6p
2838.63
5d 6 6s 2
5d 6 6s( 6 D)6p
2909.06
5d 6 6s 2
5d 6 6s( 6 D)6p
3018.04
3058.66
0.29
5d 6 6s 2
5d 6 6s( 6 D)6p
5d 7 ( 4 F)6s
5d 7 ( 4 F)6p
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5
5
5
5
5
5 o
5
3 o
5
5 o
5
7 o
5
7 o
3
3
A Ref
M00
ATOMIC SPECTROSCOPIC DATA
1895
Persistent Lines of Neutral Osmium 共Os I兲—Continued
Wavelength 共Å兲
Inten
110
A ki (108 s⫺1 )
6
3267.94
250
3301.56
70
0.058
0.099
5d 6 6s 2
5d 6 6s( 6 D)6p
5d 6 6s 2
5d 6 6s( 6 D)6p
4260.85
150
5d 6 6s 2
5d 6 6s( 6 D)6p
5d 6 6s 2
5d 6 6s( 6 D)6p
3782.20
150
2
5d 6s
5d 6 6s( 6 D)6p
3262.29
110
Configuration
5d 6 6s 2
5d 6 6s( 6 D)6p
4420.47
Term
J
Level (cm⫺1 )
Wl Ref
5
D
F
3
4
4159.32
34803.82
MCS75
D
P
4
4
0.00
30591.45
MCS75
M00
D
F
4
5
0.00
30279.95
MCS75
M00
D
P
3
4
4159.32
30591.45
MCS75
D
Do
4
5
0.00
23462.90
MCS75
D
Do
4
4
0.00
22615.69
MCS75
5 o
5
7 o
5
7 o
5
7 o
5
7
5
7
A Ref
Energy Levels of Neutral Osmium 共Os I兲
Term
J
Level (cm⫺1 )
Ref
5
D
4
3
2
1
0
0.00
4159.32
2740.49
5766.14
6092.79
KK61
KK61
KK61
KK61
KK61
5d 7 ( 4 F)6s
5
F
5
4
3
2
1
5143.92
8742.83
11378.00
12774.38
13020.07
KK61
KK61
KK61
KK61
KK61
5d 6 6s 2
3
P
2
1
0
10165.98
17667.34
18301.40
KK61
KK61
KK61
5d 7 ( 4 F)6s
3
F
4
3
2
11030.58
14091.37
13364.83
KK61
KK61
KK61
5d 6 6s( 6 D)6p
7
Do
5
4
3
2
1
23462.90
22615.69
25012.93
25275.42
27786.79
KK61
KK61
KK61
KK61
KK61
5d 6 6s( 6 D)6p
7 o
F
5
4
30279.95
32684.61
KK61
KK61
5d 6 6s( 6 D)6p
7 o
P
4
3
30591.45
33124.48
KK61
KK61
5d 6 6s( 6 D)6p
5 o
F
5
4
34365.33
34803.82
KK61
KK61
5d 6 6s( 6 D)6p
5 o
P
3
35615.92
KK61
5d 6 6s( 6 D)6p
5
Do
4
36826.39
KK61
Configuration
6
5d 6s
2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1896
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Osmium 共Os I兲—Continued
Term
J
Level (cm⫺1 )
5d 6s( D)6p
5
o
D
4
37908.77
KK61
5d 6 6s( 4 D)6p
3 o
F
4
40361.92
KK61
5d 7 ( 4 F)6p
3
Do
3
46776.29
KK61
o
5
48062.22
KK61
o
3
48874.93
KK61
o
3
49138.11
KK61
o
5
49534.28
KK61
Limit
68058.9
CLS97
Configuration
6
4
6
Os II ( D9/2)
Ref
Persistent Lines of Singly-ionized Osmium 共Os II兲
Inten
Wavelength 共Å兲
1000
2067.21
500
110
250
200
90
60
70
100
A ki (108 s⫺1 )
2070.67
2194.39
2255.85
2282.26
2336.80
2367.35
2486.24
2538.00
J
Level (cm⫺1 )
Wl Ref
D
F
7/2
9/2
3593.15
51951.61
MCS75
D
F
5/2
7/2
3928.94
52206.48
MCS75
D
P
7/2
7/2
3593.15
49149.39
MCS75
D
Do
9/2
9/2
0.00
44315.40
MCS75
D
Do
9/2
7/2
0.00
43802.36
MCS75
D
Do
7/2
5/2
3593.15
46373.51
MCS75
D
Do
5/2
3/2
3928.94
46157.19
MCS75
D
Do
7/2
7/2
3593.15
43802.36
MCS75
D
P
9/2
7/2
0.00
39389.49
MCS75
Configuration
Term
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 5 6s( 7 S)6p
6
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
5d 6 ( 5 D)6s
5d 5 6s( 7 S)6p
6
6 o
6 o
6 o
6
6
6
6
6
8 o
A Ref
Energy Levels of Singly-ionized Osmium 共Os II兲
J
Level (cm⫺1 )
Ref
D
9/2
7/2
5/2
3/2
1/2
0.00
3593.15
3928.94
5592.05
6636.57
KK61
KK61
KK61
KK61
KK61
6
S
5/2
7891.93
KK61
4
D
7/2
5/2
3/2
11459.90
11654.08
13136.61
KK61
KK61
KK61
Configuration
Term
5d 6 ( 5 D)6s
6
5d 5 6s 2
5d 6 ( 5 D)6s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1897
Energy Levels of Singly-ionized Osmium 共Os II兲—Continued
J
Level (cm⫺1 )
5d 6s( S)6p
8 o
P
5/2
7/2
9/2
37321.53
39389.49
41282.95
KK61
KK61
KK61
5d 6 ( 5 D)6p
6
Do
7/2
9/2
3/2
5/2
43802.36
44315.40
46157.19
46373.51
KK61
KK61
KK61
KK61
5d 6 ( 5 D)6p
6 o
F
5/2
9/2
7/2
48798.70
51951.61
52206.48
KK61
KK61
KK61
5d 5 6s( 7 S)6p
6 o
7/2
49149.39
KK61
Configuration
5
7
Os III ( 5 D4 )
Term
P
Ref
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1898
J. E. SANSONETTI AND W. C. MARTIN
Oxygen „O…
Atomic number⫽8
Atomic weight⫽15.9994
Isotope
16
O
O
18
O
17
Mass
Abundance
Spin
Mag moment
15.994915
16.999311
17.999160
99.76%
0.048%
0.20%
0
5/2
0
⫺1.89379
O I Ground state: 1s 2 2s 2 2p 4 3P2
Ionization energy: 109 837.02 cm⫺1 共13.618 05 eV兲
o
O II Ground state: 1s 2 2s 2 2p 3 4S3/2
⫺1
Ionization energy: 283 270.9 cm 共35.1211 eV兲
Strong Lines of Oxygen 共O兲
Intensity
400
700
1000
800
1000
600
800
700
500
800
500
250
250
250
400
500
50
80
50
1000
700
300
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
250
250
90
400 P
250
300
250
250
250
300
400 P
60
50
50
400 P
200
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
429.918
430.041
430.177
537.8319
538.2636
538.318
539.0855
539.5489
539.8544
718.5036
718.5663
796.664
796.682
832.7587
833.3302
834.4655
988.773
1025.762
1039.230
1302.168
1304.858
1306.029
Air
2445.538
2733.289
2972.29
3134.720
3138.335
3287.472
3390.209
3470.676
3727.320
3749.486
3911.957
3947.29
3947.48
3947.59
3973.2562
3982.7140
Spectrum
Ref
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
M75b
M75b
M75b
M75b
M75b
M75b
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
II
II
I
II
II
II
II
II
II
II
II
I
I
I
II
II
MKM93
MKM93
HHMR86
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
M75b
M75b
M75b
MKM93
MKM93
ATOMIC SPECTROSCOPIC DATA
1899
Strong Lines of Oxygen 共O兲—Continued
Intensity
250
400
250
250
400
250
250
400
250
300
250
300
400
300
250
250
130
150
150
130
150
130
150
300
250
250
130
250
300
300
150
150
150
130
200
200
150
200
200
200
150
150
150
200
200
150
150
250
250
200
200
200
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
4072.157
4075.862
4119.215
4185.449
4189.789
4317.138
4349.426
4414.905
4416.974
4590.972
4596.175
4641.810
4649.135
4661.633
4676.235
4705.352
6155.98
6156.77
6158.18
6455.98
7002.23
7254.15
7254.45
7771.94
7774.17
7775.39
8221.82
8446.25
8446.36
8446.76
9260.81
9260.84
9260.94
9262.58
9262.67
9262.77
9265.94
9266.01
11286.34
11286.91
11287.02
11287.32
11295.10
11297.68
11302.38
12464.02
12570.04
13163.89
13164.85
13165.11
18021.21
18243.63
Spectrum
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
M75b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1900
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Oxygen 共O I兲
Wavelength 共Å兲
Inten
1000
1302.168
700
1304.858
300
1306.029
300
7771.94
250
7774.17
250
7775.39
250
8446.25
300
8446.36
300
8446.76
200
9266.01
250
13163.89
250
13164.85
A ki (108 s⫺1 )
3.15
1.87
0.623
0.369
0.369
0.369
0.322
0.322
0.322
0.445
0.0714
0.119
Term
J
Level (cm⫺1 )
3
P
S
2
1
0.000
76794.978
M75b
M03
P
S
1
1
158.265
76794.978
M75b
M03
P
S
0
1
226.977
76794.978
M75b
M03
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
5 o
S
P
2
3
73768.200
86631.454
M75b
WFD96
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
5 o
S
P
2
2
73768.200
86627.778
M75b
WFD96
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
5 o
S
P
2
1
73768.200
86625.757
M75b
WFD96
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
3 o
S
P
1
0
76794.978
88631.303
M75b
WFD96
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
3 o
S
P
1
2
76794.978
88631.146
M75b
WFD96
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 3 ( 4 So)3p
3 o
S
P
1
1
76794.978
88630.587
M75b
WFD96
2s 2 2 p 3 ( 4 So)3p
2s 2 2 p 3 ( 4 So)3d
5
P
Do
3
4
86631.454
97420.630
M75b
WFD96
2s 2 2 p 3 ( 4 So)3p
2s 2 2 p 3 ( 4 So)4s
3
P
S
1
1
88630.587
96225.049
M75b
WFD96
2s 2 2 p 3 ( 4 So)3p
2s 2 2 p 3 ( 4 So)4s
3
P
S
2
1
88631.146
96225.049
M75b
WFD96
Configuration
2
4
2s 2 p
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 4
2s 2 2 p 3 ( 4 So)3s
2s 2 2 p 4
2s 2 2 p 3 ( 4 So)3s
3 o
3
3 o
3
3 o
5
5
5
3
3
3
5
3 o
3 o
Wl Ref
A Ref
Energy Levels of Neutral Oxygen 共O I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
2s 2 2p 4
3
P
2
1
0
0.000
158.265
226.977
MG93
MG93
MG93
2s 2 2p 4
1
D
2
15867.862
MG93
2s 2 2p 4
1
S
0
33792.583
MG93
2s 2 2p 3 ( 4 So)3s
5 o
S
2
73768.200
MG93
2s 2 2p 3 ( 4 So)3s
3 o
S
1
76794.978
MG93
2s 2p ( S )3p
5
P
1
2
3
86625.757
86627.778
86631.454
MG93
MG93
MG93
2s 2 2p 3 ( 4 So)3p
3
P
2
1
0
88631.146
88630.587
88631.303
MG93
MG93
MG93
2s 2 2p 3 ( 4 So)4s
5 o
2
95476.728
MG93
2
3 4 o
S
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1901
Energy Levels of Neutral Oxygen 共O I兲—Continued
Term
J
Level (cm⫺1 )
Ref
2s 2p ( S )4s
3 o
S
1
96225.049
MG93
2s 2 2p 3 ( 4 So)3d
5
Do
4
3
2
1
0
97420.630
97420.716
97420.839
97420.942
97420.991
MG93
MG93
MG93
MG93
MG93
2s 2 2p 3 ( 4 So)3d
3
Do
1
2
3
97488.378
97488.448
97488.538
MG93
MG93
MG93
Configuration
2
3 4 o
o
)
O II ( 4 S3/2
Limit
109837.02
MG93
Persistent Lines of Singly-ionized Oxygen 共O II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
300
429.918
42.5
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3d
700
1000
800
1000
600
800
700
500
800
500
250
400
500
430.041
430.177
537.8319
538.2636
538.318
539.0855
539.5489
539.8544
718.5036
718.5663
832.7587
833.3302
834.4655
41.3
43.6
57.3
51.8
5.87
9.83
9.81
9.81
19.0
18.5
8.67
8.65
8.61
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3d
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3d
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 3
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s2 p 4
2s 2 2 p 3
2s2 p 4
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
3/2
1/2
0.00
232602.492
MKM93
WFD96
4 o
S
P
3/2
3/2
0.00
232535.949
MKM93
WFD96
4 o
S
P
3/2
5/2
0.00
232462.724
MKM93
WFD96
Do
P
3/2
1/2
26830.57
212762.25
MKM93
WFD96
Do
P
5/2
3/2
26810.55
212593.82
MKM93
WFD96
Do
P
3/2
3/2
26830.57
212593.82
MKM93
WFD96
4 o
S
P
3/2
5/2
0.00
185499.124
MKM93
WFD96
4 o
S
P
3/2
3/2
0.00
185340.577
MKM93
WFD96
4 o
S
P
3/2
1/2
0.00
185235.281
MKM93
WFD96
Do
D
5/2
5/2
26810.55
165988.46
MKM93
WFD96
Do
D
3/2
3/2
26830.57
165996.50
MKM93
WFD96
4 o
S
P
3/2
1/2
0.00
120082.86
MKM93
WFD96
4 o
S
P
3/2
3/2
0.00
120000.43
MKM93
WFD96
4 o
3/2
5/2
0.00
119837.21
MKM93
WFD96
Term
4 o
4
4
4
2
2
2
2
2
2
4
4
4
2
2
2
2
4
4
4
S
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1902
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Oxygen 共O II兲—Continued
Wavelength 共Å兲
Inten
400
3134.720
400
3911.957
400
3973.256
400
4075.862
400
4414.905
300
4641.810
400
4649.135
A ki (108 s⫺1 )
Configuration
2
1.23
1.09
1.02
1.98
0.847
0.585
0.784
2 3
J
Level (cm⫺1 )
Wl Ref
A Ref
D
P
7/2
5/2
207002.482
238893.96
MKM93
WFD96
D
P
5/2
3/2
206971.68
232527.09
MKM93
WFD96
P
P
3/2
3/2
189068.514
214229.671
MKM93
WFD96
Do
F
7/2
9/2
207002.482
231530.246
MKM93
WFD96
P
Do
3/2
5/2
189068.514
211712.732
MKM93
WFD96
P
Do
3/2
5/2
185340.577
206877.865
MKM93
WFD96
P
Do
5/2
7/2
185499.124
207002.482
MKM93
WFD96
Term
2s 2 p ( P)3p
2s 2 2 p 2 ( 3 P)4s
4
2s 2 2 p 2 ( 1 D)3s
2s 2 2 p 2 ( 1 D)3p
2
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
2
2s 2 2 p 2 ( 3 P)3p
2s 2 2 p 2 ( 3 P)3d
4
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
2
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
4
2s 2 2 p 2 ( 3 P)3s
2s 2 2 p 2 ( 3 P)3p
4
4
o
2 o
2 o
4
2
4
4
Energy Levels of Singly-ionized Oxygen 共O II兲
Term
2s 2 2p 3
4 o
3/2
0.00
MKM93
2
o
D
5/2
3/2
26810.55
26830.57
MKM93
MKM93
2s 2 2p 3
2 o
P
3/2
1/2
40468.01
40470.00
MKM93
MKM93
2s2 p 4
4
P
5/2
3/2
1/2
119837.21
120000.43
120082.86
MKM93
MKM93
MKM93
2s2 p 4
2
D
5/2
3/2
165988.46
165996.50
MKM93
MKM93
2s 2 2p 2 ( 3 P)3s
4
P
1/2
3/2
5/2
185235.281
185340.577
185499.124
MKM93
MKM93
MKM93
2s 2 2p 2 ( 3 P)3s
2
P
1/2
3/2
188888.543
189068.514
MKM93
MKM93
2s2 p 4
2
S
1/2
195710.47
MKM93
2s 2 2p 2 ( 3 P)3p
2 o
S
1/2
203942.288
MKM93
2s 2 2p 2 ( 3 P)3p
4
Do
1/2
3/2
5/2
7/2
206730.762
206786.286
206877.865
207002.482
MKM93
MKM93
MKM93
MKM93
2s 2 2p 2 ( 1 D)3s
2
D
5/2
3/2
206971.68
206972.72
MKM93
MKM93
2s 2 2p 2 ( 3 P)3p
4 o
1/2
3/2
5/2
208346.104
208392.258
208484.202
MKM93
MKM93
MKM93
2
2s 2p
3
S
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
Ref
ATOMIC SPECTROSCOPIC DATA
1903
Energy Levels of Singly-ionized Oxygen 共O II兲—Continued
J
Level (cm⫺1 )
Ref
2s 2p ( P)3p
2
o
D
3/2
5/2
211522.117
211712.732
MKM93
MKM93
2s 2 2p 2 ( 3 P)3p
4 o
S
3/2
212161.881
MKM93
2s2 p 4
2
P
3/2
1/2
212593.82
212762.25
MKM93
MKM93
2s 2 2p 2 ( 3 P)3p
2 o
P
1/2
3/2
214169.920
214229.671
MKM93
MKM93
2s 2 2p 2 ( 1 D)3p
2 o
F
5/2
7/2
228723.84
228747.45
MKM93
MKM93
2s 2 2p 2 ( 1 D)3p
2
Do
5/2
3/2
229947.07
229968.44
MKM93
MKM93
2s 2 2p 2 ( 1 S)3s
2
S
1/2
230609.45
MKM93
2s 2p ( P)3d
4
F
3/2
5/2
7/2
9/2
231296.126
231350.087
231427.970
231530.246
MKM93
MKM93
MKM93
MKM93
2s 2 2p 2 ( 3 P)3d
4
P
5/2
3/2
1/2
232462.724
232535.949
232602.492
MKM93
MKM93
MKM93
2s 2 2p 2 ( 1 D)3p
2 o
P
1/2
3/2
232480.44
232527.09
MKM93
MKM93
2s 2 2p 2 ( 3 P)3d
4
D
1/2
3/2
5/2
7/2
232711.642
232745.981
232747.562
232753.816
MKM93
MKM93
MKM93
MKM93
2s 2 2p 2 ( 3 P)3d
2
F
5/2
7/2
232796.298
232959.210
MKM93
MKM93
2s 2 2p 2 ( 3 P)3d
2
P
3/2
1/2
233430.53
233544.59
MKM93
MKM93
2s 2 2p 2 ( 3 P)3d
2
D
3/2
5/2
234402.797
234454.634
MKM93
MKM93
2s 2 2p 2 ( 3 P)4s
4
P
1/2
3/2
5/2
238627.46
238732.65
238893.96
MKM93
MKM93
MKM93
Limit
283270.9
MKM93
Configuration
2
2
2 3
2 3
O III ( 3 P0 )
Term
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1904
J. E. SANSONETTI AND W. C. MARTIN
Palladium „Pd…
Atomic number⫽46
Atomic weight⫽106.42
Isotope
102
Pd
Pd
105
Pd
106
Pd
108
Pd
110
Pd
104
Mass
Abundance
Spin
101.905634
103.904029
104.905079
105.903478
107.903895
109.905167
1.02%
11.14%
22.33%
27.33%
26.46%
11.72%
0
0
5/2
0
0
0
Mag moment
⫺0.642
Pd I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 10 1S0
Ionization energy: 67 242 cm⫺1 共8.3369 eV兲
Pd II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 9 2D5/2
Ionization energy: 156 700 cm⫺1 共19.43 eV兲
Strong Lines of Palladium 共Pd兲
Intensity
600
700
1000
800
600
700
600
600
700
800
700
600
800
900
P
P
P
P
400
700
400
800
300
500
300
250
250
400
700
400
300
300
150
100
400
40
40
100
500
P
P
P
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1162.1700
1183.4003
1196.4051
1203.9645
1214.5242
1218.6219
1225.2684
1235.1957
1237.0677
1320.0229
1363.6892
1365.5430
1367.7039
1374.8481
Air
2231.5907
2296.5164
2351.3469
2360.5341
2367.9664
2446.1888
2447.9058
2469.2517
2476.4127
2486.5260
2488.9146
2498.7769
2505.7293
2551.8452
2565.5045
2658.7201
2763.0899
2776.6595
2854.5776
3114.0380
3242.6983
Spectrum
Ref
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
II
II
II
II
II
II
II
II
II
II
II
II
II
II
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
LLTL01
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
II
II
II
II
II
II
I
II
I
II
II
II
II
II
II
II
I
II
II
I
I
LLJ94
LLJ94
LLJ94
LLJ94
LLJ94
LLJ94
ELLW98
LLJ94
ELLW98
LLJ94
LLJ94
LLJ94
LLJ94
LLJ94
LLJ94
LLJ94
ELLW98
LLJ94
LLJ94
ELLW98
ELLW98
ATOMIC SPECTROSCOPIC DATA
1905
Strong Lines of Palladium 共Pd兲—Continued
Wavelength 共Å兲
Intensity
110
150
150
200
1000
500
500
250
300
400
80
500
500
200
800
800
200
90
100
Spectrum
3251.6361
3258.7765
3302.1262
3372.9943
3404.5764
3421.2214
3433.4278
3441.3896
3460.7381
3481.1516
3489.7700
3516.9438
3553.0803
3571.1489
3609.5547
3634.6884
3690.3368
3894.1988
4212.9537
P
P
P
P
P
P
P
P
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Ref
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
ELLW98
Persistent Lines of Neutral Palladium 共Pd I兲
Inten
300
250
400
500
1000
500
300
400
500
500
800
800
Wavelength 共Å兲
2447.9058
2476.4127
2763.0899
3242.6983
3404.5764
A ki (108 s⫺1 )
0.111
0.188
0.169
0.77
1.34
3421.2214
3460.7381
0.30
3481.1516
3516.9438
1.03
3553.0803
3609.5547
3634.6884
0.82
Term
J
Level (cm⫺1 )
Wl Ref
S
关 1/2兴 o
0
1
0.000
40838.874
ELLW98
M00
0
1
0.000
40368.796
ELLW98
M00
S
关 3/2兴 o
0
1
0.000
36180.677
ELLW98
M00
关 5/2兴
关 5/2兴 o
3
3
6564.148
37393.762
ELLW98
BGKZ82
关 5/2兴
关 7/2兴 o
3
4
6564.148
35927.948
ELLW98
BGKZ82
关 5/2兴
关 5/2兴 o
2
2
7755.025
36975.973
ELLW98
关 5/2兴
关 7/2兴 o
3
3
6564.148
35451.443
ELLW98
关 3/2兴
关 5/2兴 o
1
2
10093.992
38811.896
ELLW98
关 5/2兴
关 3/2兴 o
2
1
7755.025
36180.677
ELLW98
关 3/2兴
关 5/2兴 o
2
3
11721.809
39858.361
ELLW98
关 5/2兴
关 7/2兴 o
2
3
7755.025
35451.443
ELLW98
关 5/2兴
关 3/2兴 o
3
2
6564.148
34068.977
ELLW98
Configuration
10
1
4d
4d 9 ( 2 D5/2)5p
2
4d 10
4d 9 ( 2 D5/2)5p
2
4d 10
4d 9 ( 2 D5/2)5p
2
1
S
关 3/2兴 o
1
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
4d 9 ( 2 D5/2)5s
4d 9 ( 2 D5/2)5p
2
2
2
2
2
2
2
2
2
2
A Ref
BGKZ82
BGKZ82
BGKZ82
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1906
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Palladium 共Pd I兲
Configuration
4d
10
Level (cm⫺1 )
Ref
Term
J
S
0
0.000
ELLW98
1
4d 9 ( 2 D5/2)5s
2
关 5/2兴
3
2
6564.148
7755.025
ELLW98
ELLW98
4d 9 ( 2 D3/2)5s
2
关 3/2兴
1
2
10093.992
11721.809
ELLW98
ELLW98
4d 8 5s 2
3
F
4
3
2
25101.235
28213.767
29711.109
ELLW98
ELLW98
ELLW98
4d 9 ( 2 D5/2)5p
2
关 3/2兴 o
2
1
34068.977
36180.677
ELLW98
ELLW98
4d 9 ( 2 D5/2)5p
2
关 7/2兴 o
3
4
35451.443
35927.948
ELLW98
ELLW98
4d 9 ( 2 D5/2)5p
2
关 5/2兴 o
2
3
36975.973
37393.762
ELLW98
ELLW98
4d 9 ( 2 D3/2)5p
2
关 1/2兴 o
0
1
38088.192
40838.874
ELLW98
ELLW98
4d 9 ( 2 D3/2)5p
2
关 5/2兴 o
2
3
38811.896
39858.361
ELLW98
ELLW98
4d 9 ( 2 D3/2)5p
2
关 3/2兴 o
1
2
40368.796
40771.510
ELLW98
ELLW98
67242
CHR88a
Pd II ( 2 D5/2)
Limit
Persistent Lines of Singly-ionized Palladium 共Pd II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
600
1162.1700
3.36
700
1000
1183.4003
1196.4051
13.9
6.62
Configuration
4d 9
4d 8 ( 1 G)5p
4d 9
4d 8 ( 3 P)5p
4d 9
4d 8 ( 1 G)5p
800
1203.9645
4.54
4d 9
4d 8 5 p
700
1218.6219
2.63
4d 9
4d 8 ( 1 D)5p
700
1237.0677
3.97
4d 9
4d 8 ( 3 P)5p
800
1320.0229
4.68
4d 9
4d 8 ( 3 F)5p
700
1363.6892
0.578
4d 9
4d 8 ( 3 F)5p
800
1367.7039
2.54
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4d 9
4d 8 ( 3 F)5p
J
Level (cm⫺1 )
Wl Ref
A Ref
D
F
5/2
7/2
0.000
86046.027
LLTL01
Q96
D
P
3/2
1/2
3539.242
88041.479
LLTL01
Q96
D
F
3/2
5/2
3539.242
87122.977
LLTL01
Q96
D
7o
5/2
7/2
0.000
83058.993
LLTL01
Q96
2
D
Do
5/2
5/2
0.000
82059.859
LLTL01
Q96
D
Do
3/2
3/2
3539.242
84375.505
LLTL01
Q96
D
3o
5/2
5/2
0.000
75756.251
LLTL01
Q96
2
D
F
5/2
7/2
0.000
73330.436
LLTL01
Q96
D
2o
5/2
5/2
0.000
73115.191
LLTL01
Q96
Term
2
2 o
2
2 o
2
2 o
2
2
2
2
2
4 o
2
ATOMIC SPECTROSCOPIC DATA
1907
Persistent Lines of Singly-ionized Palladium 共Pd II兲—Continued
Inten
Wavelength 共Å兲
900
400
700
400
A ki (108 s⫺1 )
1374.8481
1.27
2231.5907
2296.5164
2351.3469
Configuration
9
2
4d
4d 8 ( 3 F)5p
J
Level (cm⫺1 )
Wl Ref
A Ref
D
F
5/2
5/2
0.000
72735.273
LLTL01
Q96
F
F
9/2
9/2
25084.270
69881.432
LLJ94
F
Go
9/2
11/2
25084.270
68615.072
LLJ94
F
Go
7/2
7/2
27097.084
69612.887
LLJ94
Term
4 o
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
4 o
4
4
300
2367.9664
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
F
1o
9/2
9/2
25084.270
67301.702
LLJ94
500
2446.1888
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
7/2
5/2
27097.084
67964.621
LLJ94
4
F
Do
400
2486.5260
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
F
1o
7/2
9/2
27097.084
67301.702
LLJ94
700
2488.9146
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
4
F
Do
9/2
7/2
25084.270
65250.309
LLJ94
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
2
F
Go
7/2
9/2
32280.538
72288.057
LLJ94
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
2
7/2
9/2
32280.538
67301.702
LLJ94
400
40
2498.7769
2854.5776
4
4
F
1o
Energy Levels of Singly-ionized Palladium 共Pd II兲
J
Level (cm⫺1 )
Ref
2
D
5/2
3/2
0.000
3539.242
LLTL01
LLTL01
4d 8 ( 3 F)5s
4
F
9/2
7/2
5/2
3/2
25084.270
27097.084
28929.419
29948.151
LLTL01
LLTL01
LLTL01
LLTL01
4d 8 ( 3 F)5s
2
F
7/2
5/2
32280.538
34424.689
LLTL01
LLTL01
4d 8 ( 3 F)5p
4
Do
7/2
5/2
3/2
1/2
65250.309
67964.621
70122.300
71181.651
LLTL01
LLTL01
LLTL01
LLTL01
4d 8 ( 3 F)5p
1o
9/2
67301.702
LLTL01
4d 8 ( 3 F)5p
4
11/2
7/2
5/2
9/2
68615.072
69612.887
71072.300
72288.057
LLTL01
LLTL01
LLTL01
LLTL01
4d 8 ( 3 F)5p
4 o
9/2
3/2
5/2
7/2
69881.432
72350.620
72735.273
73330.436
LLTL01
LLTL01
LLTL01
LLTL01
Configuration
Term
4d 9
Go
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1908
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Palladium 共Pd II兲—Continued
J
Level (cm⫺1 )
4d ( F)5p
2 o
F
7/2
71247.547
LLTL01
4d 8 ( 3 F)5p
2o
5/2
73115.191
LLTL01
4d 8 ( 3 F)5p
2
Go
7/2
74321.209
LLTL01
4d 8 ( 3 F)5p
4 o
F
3/2
75100.265
LLTL01
4d ( F)5p
3
o
5/2
75756.251
LLTL01
4d 8 ( 3 P)5p
4 o
P
3/2
5/2
1/2
76757.777
76770.145
76810.059
LLTL01
LLTL01
LLTL01
4d 8 ( 1 D)5p
2
Do
5/2
82059.859
LLTL01
o
7/2
83058.933
LLTL01
Configuration
8 3
8 3
8 1
Term
Ref
4d ( D)5p
7
4d 8 ( 3 P)5p
2
Do
5/2
3/2
83805.443
84375.505
LLTL01
LLTL01
4d 8 ( 3 P)5p
2 o
P
3/2
1/2
85154.023
88041.479
LLTL01
LLTL01
4d 8 ( 1 G)5p
2 o
7/2
5/2
86046.027
87122.977
LLTL01
LLTL01
F
Pd III ( 3 F4 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
156700
M58
ATOMIC SPECTROSCOPIC DATA
1909
Phosphorus „P…
Atomic number⫽15
Atomic weight⫽30.973 762
Isotope
31
P
Mass
Abundance
Spin
Mag moment
30.973762
100%
1/2
⫹1.13160
o
P I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 3 4S3/2
⫺1
Ionization energy: 84 580.83 cm 共10.486 69 eV兲
P II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 2 3P0
Ionization energy: 159 451.5 cm⫺1 共19.7695 eV兲
Strong Lines of Phosphorus 共P兲
Intensity
200
80
130
80
130
800
1000
1000
800
700
600
400
P
P
P
P
P
P
P
P
P
P
200
300
200 P
400 P
400 P
150 P
300 P
400 P
500 P
400 P
300
80
110 P
110 P
130 P
110
80
80
80
110 P
80
110 P
70
70
60
130 P
130 P
130 P
Wavelength 共Å兲
Vacuum
1310.700
1532.530
1535.917
1536.410
1542.297
1674.591
1679.695
1774.951
1782.838
1787.656
1858.886
1859.393
Air
2032.432
2033.477
2135.465
2136.182
2149.145
2152.940
2154.080
2533.987
2535.606
2553.253
2554.904
4420.71
4588.04
4589.86
4602.08
4943.53
5296.13
5425.91
5450.74
6024.18
6034.04
6043.12
6087.82
6165.59
6199.024
6459.99
6503.46
6507.97
Spectrum
Ref
P II
P II
P II
P II
P II
PI
PI
PI
PI
PI
PI
PI
SMZ83
SMZ83
SMZ83
SMZ83
SMZ83
S80
S80
S80
S80
S80
S80
S80
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
P II
P II
P II
P II
P II
P II
P II
P II
P II
P II
P II
P II
P II
PI
P II
P II
P II
S80
S80
S80
S80
S80
S80
S80
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
M59
S80
M59
M59
M59
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1910
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Phosphorus 共P兲—Continued
Intensity
Wavelength 共Å兲
30
50
30
70
30
50
50
30
70
90
80
90
40
20
30
80
80
30
90
20
50
70
40
25
40
90
30
8741.529
9193.85
9278.88
9304.94
9323.50
9435.069
9441.86
9452.83
9493.56
9525.73
9545.18
9563.439
9609.04
9638.939
9676.24
9734.750
9750.77
9790.21
9796.85
9903.68
10529.52
10581.57
11183.23
14241.64
15711.52
16482.92
16590.07
P
P
P
P
P
P
Spectrum
Ref
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
PI
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
S80
Persistent Lines of Neutral Phosphorus 共P I兲
Inten
800
1000
1000
800
700
200
400
400
150
Wavelength 共Å兲
1674.591
1679.695
1774.951
1782.838
1787.656
2135.465
2136.182
2149.145
2152.940
A ki (108 s⫺1 )
0.773
0.845
2.38
2.38
2.52
0.211
2.83
3.18
0.485
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
2
3s 3 p
3s3 p 4
3
3s 2 3 p 3
3s3 p 4
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 1 D)4s
J
Level (cm⫺1 )
S
P
3/2
3/2
4 o
S
P
4 o
Term
Wl Ref
A Ref
0.00
59715.921
S80
M03
3/2
5/2
0.00
59534.549
S80
M03
S
P
3/2
5/2
0.00
56339.656
S80
M03
4 o
S
P
3/2
3/2
0.00
56090.626
S80
M03
4 o
S
P
3/2
1/2
0.00
55939.421
S80
M03
Do
P
3/2
3/2
11361.02
58174.366
S80
FW96
Do
P
5/2
3/2
11376.63
58174.366
S80
FW96
Do
P
3/2
1/2
11361.02
57876.574
S80
FW96
2 o
1/2
3/2
18722.71
65156.242
S80
FW96
4 o
4
4
4
4
4
2
2
2
2
2
2
2
P
D
ATOMIC SPECTROSCOPIC DATA
1911
Persistent Lines of Neutral Phosphorus 共P I兲—Continued
Inten
300
Wavelength 共Å兲
2154.080
A ki (108 s⫺1 )
0.58
0.173
400
500
400
90
80
90
80
80
90
2533.987
2535.606
2553.253
9525.73
0.200
0.95
0.71
0.18
9545.18
9563.439
9734.750
9750.77
9796.85
0.24
0.21
Configuration
2
3
3s 3 p
3s 2 3 p 2 ( 1 D)4s
3s 2 3 p 3
3s 2 3 p 2 ( 1 D)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 3
3s 2 3 p 2 ( 3 P)4s
J
Level (cm⫺1 )
P
D
3/2
5/2
18748.01
65157.126
2 o
P
D
3/2
3/2
18748.01
65156.242
2 o
P
P
1/2
3/2
18722.71
58174.366
M59
FW96
2 o
P
P
3/2
3/2
18748.01
58174.366
M59
FW96
2 o
P
P
1/2
1/2
18722.71
57876.574
M59
FW96
P
S
5/2
3/2
56339.656
66834.648
S80
BMQZ94
P
Do
5/2
3/2
56339.656
66813.271
S80
P
P
3/2
5/2
56090.626
66544.243
S80
P
P
3/2
3/2
56090.626
66360.282
S80
P
P
3/2
1/2
56090.626
66343.438
S80
BMQZ94
P
P
5/2
5/2
56339.656
66544.243
S80
BMQZ94
Term
2 o
2
2
2
2
2
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
4 o
2
4 o
4 o
4 o
4 o
Wl Ref
S80
A Ref
FW96
FW96
Energy Levels of Neutral Phosphorus 共P I兲
Ref
Term
3s 2 3p 3
4 o
3/2
0.00
MZM85
3s 2 3p 3
2
Do
3/2
5/2
11361.02
11376.63
MZM85
MZM85
3s 2 3p 3
2 o
P
1/2
3/2
18722.71
18748.01
MZM85
MZM85
3s 2 3p 2 ( 3 P)4s
4
P
1/2
3/2
5/2
55939.421
56090.626
56339.656
MZM85
MZM85
MZM85
3s 2 3p 2 ( 3 P)4s
2
P
1/2
3/2
57876.574
58174.366
MZM85
MZM85
3s3 p 4
4
P
5/2
3/2
1/2
59534.549
59715.921
59820.371
MZM85
MZM85
MZM85
3s 2 3p 2 ( 3 P)4p
2 o
S
1/2
64239.591
MZM85
3s 2 3p 2 ( 1 D)4s
2
D
3/2
5/2
65156.242
65157.126
MZM85
MZM85
S
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1912
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Phosphorus 共P I兲—Continued
J
Level (cm⫺1 )
Ref
3s 3p ( P)4p
4
o
D
1/2
3/2
5/2
7/2
65373.556
65450.125
65585.130
65788.455
MZM85
MZM85
MZM85
MZM85
3s 2 3p 2 ( 3 P)4p
4 o
P
1/2
3/2
5/2
66343.438
66360.282
66544.243
MZM85
MZM85
MZM85
3s 2 3p 2 ( 3 P)4p
2
Do
3/2
5/2
66813.271
67113.870
MZM85
MZM85
3s 2 3p 2 ( 3 P)4p
4 o
3/2
66834.648
MZM85
Limit
84580.83
MZM85
Configuration
2
Term
2 3
S
P II ( 3 P0 )
Persistent Lines of Singly-ionized Phosphorus 共P II兲
Inten
200
80
130
80
130
110
110
130
110
110
130
130
130
Wavelength 共Å兲
1310.700
1532.530
1535.917
1536.410
1542.297
4588.04
4589.86
4602.08
6024.18
6043.12
A ki (108 s⫺1 )
0.328
0.029
0.0385
0.018
0.048
1.7
1.6
1.9
0.51
0.68
6459.99
6503.46
6507.97
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
2
3s 3 p
3s3p 3
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3
P
P
2
2
469.12
76764.06
SMZ83
M03
P
Do
0
1
0.00
65251.45
SMZ83
M03
P
Do
1
2
164.90
65272.35
SMZ83
M03
P
Do
1
1
164.90
65251.45
SMZ83
M03
P
Do
2
3
469.12
65307.17
SMZ83
M03
D
F
2
3
103339.14
125128.87
M59
FW96
D
F
1
2
103165.61
124946.73
M59
FW96
3 o
3s 2 3 p 2
3s3p 3
3
3s 2 3 p 2
3s3p 3
3
3s 2 3 p 2
3s3p 3
3
3s 2 3 p 2
3s3p 3
3
3s 2 3 p4 p
3s 2 3 p4d
3
3s 2 3 p4 p
3s 2 3 p4d
3
3s 2 3 p4 p
3s 2 3 p4d
3
D
F
3
4
103667.86
125391.13
M59
FW96
3s 2 3 p4s
3s 2 3 p4 p
3 o
P
D
1
2
86743.96
103339.14
M59
FW96
3s 2 3 p4s
3s 2 3 p4 p
3 o
P
D
2
3
87124.60
103667.86
M59
FW96
3s 2 3 p3d
3s 2 3 p4 p
3 o
F
D
4
3
88192.13
103667.86
M59
3s 2 3 p3d
3s 2 3 p4 p
3 o
F
D
3
2
87966.81
103339.14
M59
3s 2 3 p3d
3s 2 3 p4 p
3 o
2
1
87804.10
103165.61
M59
3
3
3
3
3 o
3 o
3 o
3
3
3
3
3
F
D
ATOMIC SPECTROSCOPIC DATA
1913
Energy Levels of Singly-ionized Phosphorus 共P II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
2
3
0
1
2
0.00
164.90
469.12
MZM85
MZM85
MZM85
3s 2 3p 2
1
2
8882.31
MZM85
3s 2 3p 2
1
S
0
21575.63
MZM85
3s3p 3
5 o
2
45697.02
MZM85
3s3p 3
3
Do
1
2
3
65251.45
65272.35
65307.17
MZM85
MZM85
MZM85
3s3p 3
3 o
P
2
1
0
76764.06
76812.33
76823.11
MZM85
MZM85
MZM85
3s 2 3p3d
1
Do
2
77710.19
MZM85
3s 3p4s
3 o
P
0
1
2
86597.55
86743.96
87124.60
MZM85
MZM85
MZM85
3s 2 3p3d
3 o
F
2
3
4
87804.10
87966.81
88192.13
MZM85
MZM85
MZM85
3s 2 3p4s
1 o
P
1
88893.22
MZM85
3s 2 3p4p
1
2
3s 3p
2
P
D
S
P
1
101635.69
MZM85
3s 3p3d
1 o
P
1
102798.26
MZM85
3s 2 3p4p
3
D
1
2
3
103165.61
103339.14
103667.86
MZM85
MZM85
MZM85
3s 2 3p3d
3 o
P
2
1
0
103629.70
103755.91
103940.38
MZM85
MZM85
MZM85
3s 2 3p3d
3
Do
3
1
2
104050.27
104053.81
104101.75
MZM85
MZM85
MZM85
3s 2 3p4p
3
P
0
1
2
105224.06
105302.37
105549.67
MZM85
MZM85
MZM85
3s 2 3p4p
3
S
1
106001.25
MZM85
3s 2 3p3d
1 o
F
3
107360.25
MZM85
3s 3p4p
1
D
2
107922.93
MZM85
3s3p 3
3 o
S
1
110254.77
MZM85
3s 2 3p4p
1
S
0
111507.66
MZM85
3s3p 3
1
Do
2
112606.86
MZM85
1 o
1
118341.71
MZM85
2
2
3s3p
3
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1914
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Phosphorus 共P II兲—Continued
J
Level (cm⫺1 )
3s 3p5s
3 o
P
0
1
2
123344.19
123455.46
123890.81
MZM85
MZM85
MZM85
3s 2 3p5s
1 o
P
1
124432.26
MZM85
3s 2 3p4d
3 o
2
3
4
124946.73
125128.87
125391.13
MZM85
MZM85
MZM85
Limit
159451.5
MZM85
Configuration
2
Term
F
o
)
P III ( 2 P1/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1915
Platinum „Pt…
Atomic number⫽78
Atomic weight⫽195.08
Isotope
190
Pt
Pt
194
Pt
195
Pt
196
Pt
198
Pt
192
Mass
Abundance
Spin
189.959917
191.961019
193.962655
194.964766
195.967315
197.967869
0.01%
0.79%
32.9%
33.8%
25.3%
7.2%
0
0
0
1/2
0
0
Mag moment
⫹0.6095
Pt I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 9 6s 3D3
Ionization energy: 72 257.3 cm⫺1 共8.9588 eV兲
Pt II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 9 2D5/2
Ionization energy: 149 723 cm⫺1 共18.563 eV兲
Strong Lines of Platinum 共Pt兲
Intensity
30
30
90
80
30
60
60
70
110
40
40
90
200
40
40
30
70
30
30
30
50
40
40
40
30
30
30
30
120
100
200
80
40
30
30
40
Wavelength 共Å兲
Vacuum
1164.4184
1166.8635
1169.7477
1178.9614
1182.3552
1186.2203
1193.4484
1198.7745
1219.4931
1229.0134
1232.8739
1238.8499
1248.6069
1264.5677
1271.7939
1283.6978
1289.9515
1290.0131
1290.0131
1292.7998
1302.4578
1303.1187
1327.4314
1348.8300
1352.9768
1363.3059
1364.1171
1373.1724
1378.9572
1382.0460
1403.9006
1429.5248
1447.8030
1454.2866
1454.2866
1461.0786
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1916
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Platinum 共Pt兲—Continued
Intensity
Wavelength 共Å兲
40
60
150
25
200
100
200
140
110
30
600
30
150
900
900
80
60
100
50
60 l
30
40
110
200
30
40
40
40
30
30
40
200
80
90
40
40
40
40
9
80 l
80
120
25
8
50
200
20
50
50
7
30
80
40
7
150
50
90
14
10
1462.6591
1475.6306
1482.8256
1491.9735
1494.7256
1498.1132
1499.3707
1505.2462
1506.2923
1507.6288
1509.2920
1520.7414
1524.5715
1524.7295
1524.7295
1528.2831
1530.1969
1534.9063
1540.5040
1541.8337
1542.7098
1546.8248
1552.3268
1554.9285
1558.3479
1559.3893
1561.5450
1561.5450
1568.9021
1573.1802
1573.8180
1574.3059
1579.4357
1581.3980
1587.7205
1589.3735
1594.0344
1594.2611
1604.0102
1621.6590
1631.0903
1634.2337
1636.1647
1644.4634
1659.4860
1669.2312
1677.8443
1684.5867
1684.5867
1690.7825
1698.4958
1707.0710
1713.8364
1714.4801
1723.1314
1727.6799
1735.8642
1737.1732
1744.4305
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
I
I
II
II
I
II
II
I
II
II
II
I
II
II
II
I
I
Ref
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
ATOMIC SPECTROSCOPIC DATA
1917
Strong Lines of Platinum 共Pt兲—Continued
Intensity
120
120
14
25
120
200
40
600
20
250
30
25
20
20
15
8
13
25
40
80
30
80
25
13
9
40
80
90
30
70
600
30
140
30
30
40
30
15
400
40
250
40
50
100
130
20
150
40
30
11
13
30
50
25
40
9
15
80
8
P
P
P
P
l
Wavelength 共Å兲
1753.8286
1753.8286
1764.5948
1766.0328
1767.1612
1775.0160
1776.5571
1777.0866
1777.2783
1781.8617
1785.8803
1786.6480
1802.9398
1812.8819
1817.8736
1825.3262
1826.1377
1833.3875
1835.0745
1836.5075
1838.8246
1839.5258
1845.7517
1849.6831
1853.4523
1853.4523
1867.1302
1870.4100
1871.1038
1879.1031
1883.0587
1885.8171
1889.5226
1895.0088
1897.5769
1898.1722
1899.0445
1903.2186
1911.7092
1928.4320
1929.2449
1929.6829
1934.3690
1937.4245
1939.8110
1940.0319
1944.4617
1949.9102
1954.7436
1963.1429
1969.6807
1971.5374
1978.8444
1979.7647
1983.7486
1987.7868
1989.1056
1990.5751
1991.5830
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
II
II
I
II
II
II
I
II
I
II
II
I
I
I
I
I
I
II
II
II
II
II
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
I
II
I
II
II
II
I
I
I
II
I
II
I
I
II
I
Ref
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1918
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Platinum 共Pt兲—Continued
Intensity
Wavelength 共Å兲
11
1995.8991
Air
2007.7572
2014.9330
2020.5434
2030.6456
2032.4256
2035.7985
2036.4666
2041.5751
2049.1689
2049.3915
2057.0265
2060.7621
2062.7943
2067.5105
2070.9443
2070.9443
2075.4004
2084.5960
2097.4478
2101.5979
2101.6839
2101.6839
2103.3449
2103.7804
2103.7804
2109.6631
2115.5823
2127.4231
2128.5878
2128.6340
2130.7079
2135.1631
2144.2123
2144.2458
2165.2108
2174.6853
2180.5042
2190.3216
2202.2230
2202.4664
2209.5043
2222.6134
2225.0094
2232.9725
2234.9262
2240.8965
2241.2288
2244.9773
2245.5244
2246.5216
2247.4822
2249.3075
2249.3075
2249.8994
2251.5105
2251.8084
2262.7185
140
200
9
20
30
7
250
150
30
60
100
9
15
20
8
8
80
50
200
50
10
10
70
30
30
8
60
80
25
90
60
7
130
900
20
200
11
100
30
40
40
13
120
40
12
600
40
14
400
300
40
15
60
11
50
30
600
P
u
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ref
Pt I
SRSA92
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
II
II
I
I
I
I
II
II
II
I
II
I
I
I
I
I
II
I
II
II
I
I
I
II
II
I
II
II
I
I
II
I
I
II
I
I
I
II
I
II
II
I
II
II
I
II
II
I
II
II
II
I
II
I
II
II
II
ATOMIC SPECTROSCOPIC DATA
1919
Strong Lines of Platinum 共Pt兲—Continued
Intensity
50
15
40
50
12
70
40
60
400
15
60
30
25
500
9
40
30
30
30
14
40
30
14
60
8
7
25
11
40
10
40
150
25
40
25
110
80
7
50
10
40
40
200
200
40
25
20
60
40
7
70
40
9
80
30
140
9
200
15
P
P
c
P
P
P
Wavelength 共Å兲
2263.8611
2268.8384
2271.6194
2274.3816
2274.8409
2281.1942
2286.4390
2287.3643
2288.2050
2289.2765
2292.3987
2302.3068
2308.0437
2310.9626
2315.5024
2318.2969
2319.8869
2326.3386
2339.0741
2340.1805
2357.1047
2366.3729
2368.2781
2377.2773
2383.6432
2386.8089
2389.5358
2403.0918
2405.7269
2418.0583
2420.8161
2424.8672
2433.3064
2434.4610
2436.6887
2440.0608
2450.4390
2450.9670
2467.4003
2467.4824
2478.9449
2486.9827
2487.1685
2487.1685
2488.8753
2490.1265
2495.8126
2498.4996
2498.6806
2508.4973
2513.8885
2515.5770
2524.3065
2528.7336
2539.2067
2580.8102
2603.1374
2628.0269
2639.3454
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
II
I
II
I
I
II
II
II
II
I
I
II
I
II
I
I
II
II
II
I
I
II
I
II
I
I
I
I
II
I
II
II
II
II
I
I
II
I
I
I
II
II
I
I
II
I
I
I
II
I
II
I
I
II
I
II
I
I
I
Ref
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1920
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Platinum 共Pt兲—Continued
Intensity
15
90
300
500
9
50
20
200
150
130
300
13
300
300
8
30
7
100
20
200
30
40
300
15
30
110
1000
40
130
60
40
8
15
15
7
400
7
60
600
40
20
800
1000
20
110
25
90
40
90
120
40
80
12
7
30
50
10
11
25
Wavelength 共Å兲
P
P
P
P
P
P
P
P,c
P
P
P
P,c
P,c
P,c
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2639.3454
2646.8804
2650.8524
2659.4503
2674.5700
2677.1477
2698.4248
2702.3995
2705.8951
2719.0333
2719.5239
2729.9123
2733.9567
2743.2944
2753.8531
2754.9122
2769.8332
2771.6594
2803.2357
2816.9021
2818.2450
2823.0513
2830.2919
2834.7107
2842.4101
2874.9196
2875.6314
2877.2783
2893.8630
2897.8715
2899.3861
2905.8974
2912.2515
2913.5386
2921.3792
2929.7894
2960.7494
2991.4665
2997.9622
3002.2641
3036.4425
3042.6318
3064.7110
3071.9336
3096.8104
3100.0252
3139.3870
3156.5625
3167.2244
3199.5087
3200.7097
3204.0364
3230.2837
3233.4167
3251.9787
3255.9088
3268.4170
3281.9670
3290.2196
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
I
I
I
I
I
I
I
I
I
I
II
I
I
II
I
I
I
I
I
II
I
II
I
I
II
II
II
II
I
I
II
I
I
I
I
I
I
II
I
I
I
I
I
I
II
I
I
I
II
II
I
I
I
I
I
I
I
I
I
Ref
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
ATOMIC SPECTROSCOPIC DATA
1921
Strong Lines of Platinum 共Pt兲—Continued
Intensity
250
150
9
25
900
30
25
12
60
60
10
9
40
60
13
25
25
40
30
50
15
12
10
20
14
15
40
30
13
250
15
15
15
30
12
13
60
15
9
100
11
60
30
11
9
13
60
50
25
11
12
50
9
15
8
25
8
9
20
P
P
P,c
d
s
s
c
c
Wavelength 共Å兲
3301.8596
3315.0419
3343.8961
3345.2555
3408.1308
3417.8034
3427.9268
3483.4231
3485.2641
3508.8500
3514.7134
3528.5348
3548.5211
3628.1107
3628.8660
3638.7879
3638.7879
3643.1667
3643.6290
3665.1680
3671.9990
3674.0449
3682.9727
3687.4152
3699.9126
3706.5217
3708.4731
3761.1616
3801.0723
3818.6874
3868.4209
3875.7150
3898.7316
3900.7228
3904.3823
3910.8955
3922.9559
3925.3359
3948.3881
3966.3570
3996.5674
4013.7145
4065.7046
4065.9283
4081.4669
4092.2522
4118.6745
4164.5491
4192.4231
4327.0533
4391.83
4442.55
4445.55
4498.76
4520.90
4552.42
4879.53
5044.04
5059.48
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
I
I
I
II
I
II
I
I
I
II
I
I
II
I
I
I
I
I
II
II
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1922
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Platinum 共Pt兲—Continued
Intensity
Wavelength 共Å兲
25
25
8
8
9
9
4
13
5
4
5
5
6
7
13
40
13
7
5227.66
5301.02
5368.99
5390.79
5475.77
5478.50
5763.57
5840.12
5844.84
6026.04
6318.37
6326.58
6523.45
6710.42
6760.02
6842.60
7113.73
8224.74
Spectrum
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Platinum 共Pt I兲
Inten
Wavelength 共Å兲
200
2487.1685
200
300
500
200
150
300
300
130
400
600
800
2628.0269
2650.8524
2659.4503
2702.3995
2705.8951
2733.9567
2830.2919
2893.8630
2929.7894
2997.9622
3042.6318
A ki (108 s⫺1 )
0.482
0.0962
0.890
0.523
0.380
0.672
0.168
0.0647
0.185
0.288
0.0769
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Term
J
Level (cm⫺1 )
Wl Ref
5d 9 6s
5d 8 ( 3 F)6s6 p( 3 Po)
1
D
Go
2
3
775.892
40970.165
SRSA92
5d 9 6s
5d 8 ( 3 F)6s6 p( 3 Po)
3
D
F
3
4
0.000
40194.228
5d 9 6s
5d 8 ( 1 D)6s6p( 3 Po)
1
D
F
2
2
775.892
38815.908
SRSA92
M00
F
Go
4
5
823.678
38536.160
SRSA92
M00
D
F
3
4
0.000
37590.569
SRSA92
M00
D
Do
2
3
775.892
37769.073
SRSA92
M00
F
Do
4
3
823.678
37769.073
SRSA92
M00
D
P
2
2
775.892
37342.101
SRSA92
M00
D
Do
3
3
0.000
35321.653
SRSA92
M00
D
Do
2
3
775.892
35321.653
SRSA92
M00
D
F
3
3
0.000
34122.165
SRSA92
M00
D
F
2
3
775.892
34122.165
SRSA92
M00
F
F
4
5
823.678
33680.402
SRSA92
M00
Configuration
5d 8 6s 2
5d 8 ( 3 F)6s6 p( 3 Po)
5
5 o
3 o
3
5
5d 9 6s
5d 9 6 p
3
5d 9 6s
5d 9 6 p
1
5d 8 6s 2
5d 9 6 p
3 o
3
3
3
5d 9 6s
5d 9 6 p
1
5d 9 6s
5d 8 ( 3 F)6s6 p( 3 Po)
3
5d 9 6s
5d 8 ( 3 F)6s6 p( 3 Po)
1
5d 9 6s
5d 9 6 p
3
5d 9 6s
5d 9 6 p
1
5d 8 6s 2
5d 8 ( 3 F)6s6 p( 3 Po)
3 o
5
5
3 o
3 o
3
5 o
A Ref
ATOMIC SPECTROSCOPIC DATA
1923
Persistent Lines of Neutral Platinum 共Pt I兲—Continued
Wavelength 共Å兲
Inten
1000
3064.7110
250
3301.8596
150
3315.0419
900
3408.1308
250
A ki (108 s⫺1 )
0.644
0.343
0.00176
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
9
5d 6s
5d 9 6 p
3
D
P
3
2
0.000
32620.018
SRSA92
M00
5d 9 6s
5d 9 6 p
3
D
P
2
1
6567.461
36844.710
SRSA92
M00
5d 9 6s
5d 8 ( 3 F)6s6 p( 3 Po)
3
D
Do
3
4
0.000
30156.854
SRSA92
M00
F
Do
4
4
823.678
30156.854
SRSA92
M00
F
Go
3
4
10116.729
36296.310
SRSA92
3 o
3 o
5d 8 6s 2
5d 8 ( 3 F)6s6 p( 3 Po)
0.0129
5d 8 6s 2
5d 8 ( 3 F)6s6 p( 3 Po)
3818.6874
5
3
5
3
5
Energy Levels of Neutral Platinum 共Pt I兲
Term
J
Level (cm⫺1 )
Ref
9
5d 6s
3
D
3
2
1
0.000
6567.461
10131.887
BVWE92
BVWE92
BVWE92
5d 9 6s
1
D
2
775.892
BVWE92
5d 8 6s 2
3
F
4
3
2
823.678
10116.729
15501.845
BVWE92
BVWE92
BVWE92
5d 10
1
S
0
6140.180
BVWE92
2
3
P
0
1
2
16983.492
18566.558
13496.271
BVWE92
BVWE92
BVWE92
5d 8 6s 2
1
G
4
21967.111
BVWE92
5d 8 6s 2
1
D
2
26638.591
BVWE92
5d 8 ( 3 F)6s6p( 3 Po)
5
Do
4
3
2
30156.854
35321.653
40516.243
BVWE92
BVWE92
BVWE92
5d 9 6p
3 o
P
2
1
2
32620.018
36844.710
37342.101
BVWE92
BVWE92
BVWE92
5d 8 ( 3 F)6s6p( 3 Po)
5 o
F
5
4
33680.402
40194.228
BVWE92
BVWE92
5d 9 6p
3 o
F
3
4
34122.165
37590.569
BVWE92
BVWE92
5d 8 ( 3 F)6s6p( 3 Po)
5
Go
4
6
5
3
36296.310
36781.551
38536.160
40970.165
BVWE92
BVWE92
BVWE92
BVWE92
5d 9 6p
3
Do
3
37769.073
BVWE92
5d 8 ( 1 D)6s6p( 3 Po)
3 o
2
38815.908
BVWE92
Configuration
8
5d 6s
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1924
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Platinum 共Pt I兲—Continued
Term
J
Level (cm⫺1 )
5d ( P)6s6p( P )
5 o
P
2
40787.857
BVWE92
5d 8 ( 1 D)6s6p( 3 Po)
3 o
0
40873.529
BVWE92
72257.3
MMHS95,JS00
Configuration
8 3
3 o
P
Pt II ( 2 D5/2)
Limit
Ref
Persistent Lines of Singly-ionized Platinum 共Pt II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
600
1777.0866
8.77
5d 8 ( 3 F)6s
5d 8 ( 3 F4 )6p 3/2
4
F
(4,3/2) o
9/2
11/2
4786.611
61058.490
SRSA92
WBJ95
600
1883.0587
2.98
5d 8 ( 3 P)6s
5d 8 ( 3 P2 )6p 3/2
4
P
(2,3/2) o
5/2
7/2
13329.227
66434.315
SRSA92
WBJ95
400
1911.7092
5.12
5d 8 ( 3 F)6s
5d 8 ( 3 F4 )6p 3/2
4
F
(4,3/2) o
7/2
7/2
9356.274
61665.485
SRSA92
WBJ95
250
1929.2449
3.72
5d 8 ( 3 F)6s
5d 8 ( 3 F4 )6p 3/2
4
F
(4,3/2) o
7/2
5/2
9356.274
61190.026
SRSA92
WBJ95
250
2036.4666
2.40
5d 8 ( 3 F)6s
5d 8 ( 3 F4 )6p 1/2
4
F
(4,1/2) o
9/2
9/2
4786.611
53875.493
SRSA92
WBJ95
900
2144.2458
3.93
5d 8 ( 3 F)6s
5d 8 ( 3 F4 )6p 1/2
4
F
(4,1/2) o
9/2
7/2
4786.611
51408.370
SRSA92
WBJ95
600
2240.8965
5d 8 ( 3 P2 )6p 1/2
5d 8 ( 1 D)7s
(2,1/2) o
2
D
3/2
5/2
56587.934
101199.085
SRSA92
400
2245.5244
5d 8 ( 3 F)6s
5d 8 ( 3 F4 )6p 1/2
4
F
(4,1/2) o
7/2
9/2
9356.274
53875.493
SRSA92
300
2246.5216
5d 8 ( 3 P2 )6p 1/2
5d 8 ( 1 D)7s
(2,1/2) o
2
D
5/2
3/2
57018.130
101517.59
SRSA92
600
2262.7185
5d 8 ( 3 P2 )6p 1/2
5d 8 ( 1 D)7s
(2,1/2) o
2
D
5/2
5/2
57018.130
101199.085
SRSA92
400
2288.2050
1.45
5d 8 ( 3 P)6s
5d 8 ( 3 P2 )6p 1/2
4
P
(2,1/2) o
5/2
5/2
13329.227
57018.130
SRSA92
WBJ95
500
2310.9626
2.01
5d 8 ( 3 P)6s
5d 8 ( 3 P2 )6p 1/2
4
P
(2,1/2) o
5/2
3/2
13329.227
56587.934
SRSA92
WBJ95
300
2719.5239
5d 8 ( 3 F3 )6p 1/2
5d 8 ( 1 D)7s
(3,1/2) o
2
D
5/2
3/2
64757.343
101517.59
SRSA92
300
2743.2944
5d 8 ( 3 F3 )6p 1/2
5d 8 ( 1 D)7s
(3,1/2) o
2
D
5/2
5/2
64757.343
101199.085
SRSA92
1000
2875.6314
5d 8 ( 3 P2 )6p 3/2
5d 8 ( 1 D)7s
(2,3/2) o
2
D
7/2
5/2
66434.315
101199.085
SRSA92
2.14
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
WBJ95
ATOMIC SPECTROSCOPIC DATA
1925
Energy Levels of Singly-ionized Platinum 共Pt II兲
Configuration
J
Level (cm⫺1 )
Ref
2
D
5/2
3/2
0.000
8419.822
BW92a
BW92a
5d 8 ( 3 F)6s
4
F
9/2
7/2
5/2
3/2
4786.611
9356.274
16820.894
21168.684
BW92a
BW92a
BW92a
BW92a
5d 8 ( 3 P)6s
4
P
5/2
1/2
3/2
13329.227
21717.260
23875.553
BW92a
BW92a
BW92a
5d 8 ( 1 D)6s
2
D
3/2
15791.276
BW92a
5d 8 ( 3 F)6s
2
F
7/2
5/2
18097.715
23461.503
BW92a
BW92a
5d 7 6s 2
4
F
9/2
7/2
5/2
3/2
24879.480
34647.221
36484.028
37877.792
BW92a
BW92a
BW92a
BW92a
5d 8 ( 3 P)6s
2
P
1/2
27255.687
BW92a
5d ( G)6s
2
G
7/2
9/2
29030.479
29261.967
BW92a
BW92a
5d 8 ( 1 D)6s
2
D
3/2
5/2
32237.007
32918.561
BW92a
BW92a
5d 8 ( 3 F4 )6p 1/2
(4,1/2) o
7/2
9/2
51408.370
53875.493
BW92a
BW92a
5d 8 ( 3 P2 )6p 1/2
(2,1/2) o
3/2
5/2
56587.934
57018.130
BW92a
BW92a
5d 8 ( 3 F4 )6p 3/2
(4,3/2) o
9/2
11/2
5/2
7/2
60907.688
61058.490
61190.026
61665.485
BW92a
BW92a
BW92a
BW92a
5d 8 ( 3 P2 )6p 3/2
(2,3/2) o
1/2
5/2
3/2
7/2
62781.658
65351.069
66028.014
66434.315
BW92a
BW92a
BW92a
BW92a
5d 7 ( 4 F9/2)6s6p( 3 Po0 )
(9/2,0) o
9/2
62820.489
BW92a
5d 7 ( 4 F9/2)6s6p( 3 Po1 )
(9/2,1) o
5d
9
Term
8 1
11/2
65046.23
BW92a
5d ( F3 )6p 1/2
(3,1/2)
o
7/2
5/2
63738.841
64757.343
BW92a
BW92a
5d 8 ( 3 F2 )6p 1/2
(2,1/2) o
3/2
64388.642
BW92a
5d 8 ( 3 P0 )6p 1/2
(0,1/2) o
1/2
65587.115
BW92a
5d 8 ( 1 D)7s
2
5/2
3/2
101199.085
101517.59
BW92a
BW92a
149723
S38b
8 3
Pt III ( 3 F4 )
D
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1926
J. E. SANSONETTI AND W. C. MARTIN
Plutonium „Pu…
Atomic number⫽94
Atomic weight⫽(244)
Isotope
239
Pu
Pu
244
Pu
242
Mass
Abundance
Spin
Mag moment
239.052157
242.058737
244.064199
0
0
0
1/2
0
0
⫹0.203
Pu I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 6 7s 2 7F0
Ionization energy: 48 603 cm⫺1 共6.0260 eV兲
Pu II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 6 7s 8F1/2
Ionization energy: 关 90 000兴 cm⫺1 共11.2 eV兲
Strong Lines of Plutonium 共Pu兲
Intensity
500
700
700
700
700
700
700
700
700
700
700
700
700
700
700
700
700
700
500
500
700
500
700
500
700
700
500
700
700
700
500
500
700
500
500
700
500
700
700
Wavelength 共Å兲
P
P
P
P
P
P
P
P
d
P
d
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2933.298
2933.602
2951.820
2964.644
2966.843
2969.035
2972.500
2980.227
2994.046
2996.406
3000.572
3029.924
3159.201
3174.488
3175.152
3198.467
3220.942
3224.873
3232.224
3244.162
3245.206
3252.070
3260.539
3265.177
3273.111
3275.125
3275.236
3279.326
3289.977
3290.345
3292.560
3301.754
3312.647
3320.607
3320.834
3337.708
3338.942
3350.330
3391.405
Spectrum
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
II
I
II
II
I
II
II
II
I
I
II
I
I
II
I
II
II
Ref
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BW92b
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
ATOMIC SPECTROSCOPIC DATA
1927
Strong Lines of Plutonium 共Pu兲—Continued
Intensity
700
700
500
800
1000
500
500
500
500
500
500
500
500
500
500
400
500
400
500
500
500
500
1000
500
500
500
1000
500
500
800
500
800
1000
500
500
500
800
500
500
500
1000
150
150
150
Wavelength 共Å兲
d
Spectrum
3401.09
3632.210
3632.210
3720.243
3720.243
3753.628
3755.940
3758.338
3774.384
3792.220
3799.368
3805.923
3811.396
3835.520
3851.007
3851.849
3878.540
3895.888
4133.005
4140.041
4151.091
4151.443
4206.481
4208.234
4261.886
4404.894
4536.146
5712.382
6192.798
6304.661
6449.744
6486.707
6488.853
6535.271
6544.207
6608.947
6887.710
7258.049
7572.923
8309.602
8630.189
9533.071
12231.212
16897.369
P
P
P
P
P
P
P
P
P
P
P
P
P
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Pu
Ref
II
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
BFG84
Persistent Lines of Neutral Plutonium 共Pu I兲
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
3753.628
5 f 6 7s 2
5 f 6 7s7 p
7
F
0
1
0.000
26633.288
BFG84
500
3755.940
5 f 6 7s 2
5 f 6 7s7 p
7
F
1
0
2203.606
28820.548
BFG84
500
3758.338
5 f 6 7s 2
7
F
6
6
10238.473
36838.42
BFG84
500
3774.384
5 f 6 7s 2
7
F
1
1
2203.606
28690.480
BFG84
Inten
Wavelength 共Å兲
500
A ki (108 s⫺1 )
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1928
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Plutonium 共Pu I兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
Level (cm⫺1 )
Wl Ref
0
1
0.000
25959.849
BFG84
500
3851.007
5 f 7s
5 f 5 6d 2 7s
500
3878.540
5 f 6 7s 2
5 f 6 7s7 p
7
1
2
2203.606
27979.161
BFG84
1000
4206.481
5 f 6 7s 2
5 f 5 7s7 p
7
0
1
0.000
23766.139
BFG84
0
1
0.000
15856.888
BFG84
1
2
2203.606
17615.482
BFG84
F
Go
0
1
0.000
15406.760
BFG84
Ko
L
4
4
6313.866
20828.477
BFG84
4
3
6313.866
17897.919
BFG84
6887.710
1000
7
5 f 6 7s 2
5 f 5 ( 6 Ho)6d7s 2
6488.853
800
F
5 f 6 7s 2
5 f 5 ( 6 Fo)6d7s 2
6486.707
1000
F
5 f 6 7s 2
5 f 5 ( 6 Fo)6d7s 2
6304.661
800
2
J
7
800
6
Term
8630.189
F
Do
7
7
F
Go
7
F
F
7 o
7
7
5 f 5 ( 6 Ho)6d7s 2
5 f 5 6d7s( 8 Ko)7p
7
5 f 5 ( 6 Ho)6d7s 2
o
)7s 2 7 p 1/2
5 f 5 ( 6 H5/2
7
9
Ko
共5/2,1/2兲
A Ref
Energy Levels of Neutral Plutonium 共Pu I兲
Term
J
Level (cm⫺1 )
Ref
7
F
0
1
2
3
4
5
6
0.000
2203.606
4299.659
6144.515
7774.653
9179.262
10238.473
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 5 ( 6 Ho)6d7s 2
7
Ko
4
5
6
7
8
9
10
6313.866
9386.801
12351.522
15074.958
17554.704
19872.154
22710.37
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 5 ( 6 Ho)6d7s 2
7
Ho
2
3
4
5
6
7
8
8768.139
11840.715
14025.007
16155.109
18672.411
20697.436
22160.184
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 5 ( 6 Ho)6d7s 2
7 o
3
4
5
6
7
8
9
9724.351
12159.465
14292.176
16888.909
19236.116
20830.616
22719.717
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
Configuration
6
5 f 7s
2
I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1929
Energy Levels of Neutral Plutonium 共Pu I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
5 f 5 ( 6 Ho)6d7s 2
7
Go
1
15406.760
BW92b
5 f 5 ( 6 Fo)6d7s 2
7
Go
1
15856.888
BW92b
7 o
2
17615.482
BW92b
o
)7s 2 7p 1/2
5 f 5 ( 6 H5/2
共5/2 ,1/2兲
3
17897.919
BW92b
5 f 5 6d7s( 8 Ko)7p
9
L
4
20828.477
BW92b
5 f 5 7s7p
7
Do
1
23766.139
BW92b
5 f 6d 7s
1
25959.849
BW92b
5 f 6 7s7p
1
26633.288
BW92b
5 f 6 7s7p
2
27979.161
BW92b
1
28690.480
BW92b
0
28820.548
BW92b
6
36838.42
BW92b
48603
WCJP93,KDEE97
5 6 o
5 f ( F )6d7s
5
2
F
2
5 f 6 7s7p
Pu II ( 8 F1/2)
Limit
Persistent Lines of Singly-ionized Plutonium 共Pu II兲
Inten
Wavelength 共Å兲
700
2933.602
700
2951.820
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
F
1/2
3/2
0.000
34077.84
BFG84
F
1/2
3/2
0.000
33867.55
BFG84
F
1/2
3/2
0.000
33721.06
BFG84
F
5/2
5/2
3969.850
37641.00
BFG84
F
13/2
15/2
9707.985
43339.89
BFG84
F
1/2
3/2
0.000
31255.97
BFG84
F
3/2
1/2
2014.970
33052.83
BFG84
F
1/2
3/2
0.000
31000.03
BFG84
F
3/2
5/2
2014.970
32820.810
BFG84
F
3/2
1/2
2014.970
32558.12
BFG84
F
3/2
5/2
5502.070
36026.44
BFG84
F
1/2
3/2
3235.775
33721.06
BFG84
Configuration
Term
5 f 6 7s
5 f 67 p
8
5 f 6 7s
8
o
o
700
2964.644
5 f 6 7s
8
o
700
2969.035
5 f 6 7s
8
o
700
2972.500
5 f 6 7s
8
o
700
3198.467
5 f 6 7s
8
o
700
3220.942
5 f 6 7s
8
o
700
700
700
3224.873
3245.206
3273.111
5 f 6 7s
5 f 5 6d7s
8
5 f 6 7s
5 f 67 p
8
5 f 6 7s
8
o
o
o
700
3275.125
5 f 6 7s
6
o
700
3279.326
5 f 6 7s
6
o
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1930
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Plutonium 共Pu II兲—Continued
Inten
700
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
6
8
5 f 7s
3289.977
J
Level (cm⫺1 )
Wl Ref
F
9/2
9/2
7278.870
37665.47
BFG84
F
P
3/2
5/2
2014.970
32398.17
BFG84
F
13/2
11/2
9707.985
39886.62
BFG84
F
1/2
3/2
0.000
29952.07
BFG84
F
7/2
9/2
9242.365
39081.59
BFG84
F
13/2
11/2
9707.985
39185.84
BFG84
F
Go
1/2
1/2
0.000
22038.970
BFG84
Term
o
700
700
3290.345
3312.647
5 f 6 7s
5 f 5 7s 2
8
5 f 6 7s
8
6 o
o
700
5 f 6 7s
3337.708
8
o
700
5 f 6 7s
3350.330
6
o
700
5 f 6 7s
3391.405
8
o
1000
5 f 6 7s
5 f 67 p
4536.146
8
8
A Ref
Energy Levels of Singly-ionized Plutonium 共Pu II兲
J
Level (cm⫺1 )
Ref
F
1/2
3/2
5/2
7/2
9/2
11/2
13/2
0.000
2014.970
3969.850
5717.985
7278.870
8638.250
9707.985
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
F
1/2
3/2
5/2
7/2
9/2
11/2
3235.775
5502.070
7498.380
9242.365
10726.330
11799.245
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
6
Ho
5/2
8198.665
BW92b
5 f 5 6d7s
8
Ko
7/2
8709.640
BW92b
5 f 5 6d7s
8
Ko
9/2
10436.770
BW92b
5 f 5 7s 2
6
Ho
7/2
11504.095
BW92b
6
8
o
1/2
22038.970
BW92b
o
3/2
29952.07
BW92b
o
3/2
31000.03
BW92b
o
3/2
31255.97
BW92b
6 o
5/2
32398.17
BW92b
o
1/2
32558.12
BW92b
Configuration
Term
5 f 6 7s
8
5 f 6 7s
6
5 f 5 7s 2
5 f 7p
5 f 5 6d7s
5 f 5 7s 2
G
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1931
Energy Levels of Singly-ionized Plutonium 共Pu II兲—Continued
Configuration
6
5 f 7p
6
5 f 7p
Pu III ( 7 F0 )
Term
J
Level (cm⫺1 )
Ref
o
5/2
32820.810
BW92b
o
1/2
33052.83
BW92b
o
3/2
33721.06
BW92b
o
3/2
33867.55
BW92b
o
3/2
34077.84
BW92b
o
5/2
36026.44
BW92b
o
5/2
37641.00
BW92b
o
9/2
37665.47
BW92b
o
9/2
39081.59
BW92b
o
11/2
39185.84
BW92b
o
11/2
39886.62
BW92b
o
15/2
43339.89
BW92b
Limit
†90000‡
CNWM70
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1932
J. E. SANSONETTI AND W. C. MARTIN
Polonium „Po…
Atomic number⫽84
Atomic weight⫽209
Isotope
210
Po
Po
216
Po
218
Po
211
Mass
Abundance
Spin
209.982848
210.986627
216.001889
218.0089
Trace
Trace
Trace
Trace
0
9/2
0
0
Mag moment
Po I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 4 3P2
Ionization energy: 67 860 cm⫺1 共8.414 eV兲
o
Po II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 3 4S3/2
Ionization energy: not available
Strong Lines of Polonium 共Po兲
Wavelength 共Å兲
Intensity
600
300
300
600
300
250
250
1000
250
500
300
250
Spectrum
Air
2450.08
2483.94
2490.53
2558.01
2663.33
2761.92
2958.92
3003.21
3328.60
4170.52
4493.21
7962.62
P,w
P,w
h
P,w
P
Po
Po
Po
Po
Po
Po
Po
Po
Po
Po
Po
Po
Ref
I
I
I
I
C66a
C66a
C66a
C66a
CHPT55
C66a
C66a
C66a
C66a
C66a
C66a
C66a
I
I
I
I
I
I
I
Persistent Lines of Neutral Polonium 共Po I兲
Configuration
Term
J
Level (cm⫺1 )
2450.08
6p 4
6p 3 ( 4 So)7s
3
3 o
2
1
0.00
40802.70
C66a
600
2558.01
6p 4
6p 3 ( 4 So)7s
5 o
2
2
0.00
39081.19
C66a
1000
3003.21
6p 4
6p 3 ( 4 So)7s
3 o
0
1
7514.69
40802.70
C66a
500
4170.52
6p 4
6p 3 ( 4 So)7s
3 o
1
1
16831.61
40802.70
C66a
Inten
Wavelength 共Å兲
600
A ki (108 s⫺1 )
P
S
3
P
S
3
P
S
3
P
S
Wl Ref
A Ref
Energy Levels of Neutral Polonium 共Po I兲
Term
J
Level (cm⫺1 )
Ref
4
3
2
0
1
0.00
7514.69
16831.61
C66a
C66a
C66a
6p 4
1
D
2
21679.11
C66a
3 4 o
6p ( S )7s
5 o
S
2
39081.19
C66a
6 p 3 ( 4 So)7s
3 o
1
40802.70
C66a
67860
C66a
Configuration
6p
P
S
o
)
Po II ( 4 S3/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1933
Potassium „K…
Atomic number⫽19
Atomic weight⫽39.0983
Isotope
39
K
K
41
K
40
Mass
Abundance
Spin
Mag moment
38.963707
39.963999
40.961825
93.2581%
0.012%
6.7302%
3/2
4
3/2
⫹0.39146
⫺1.298
⫹0.21487
K I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2S1/2
Ionization energy: 35 009.8140 cm⫺1 共4.340 6633 eV兲
K II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 1S0
Ionization energy: 255 100 cm⫺1 共31.63 eV兲
Strong Lines of Potassium 共K兲
Intensity
800
150
300
1000
1000 P
800 P
1000 P
200
200
150
120
200
300
250
250
400
400
250
200
120
150
200
200
250
250
250
700 P
700 P
250
250
250
250
250
Wavelength 共Å兲
Vacuum
441.81
465.08
469.50
476.03
495.14
600.77
607.93
612.62
Air
2190.00
2550.02
2992.12
2992.22
3034.76
3034.92
3101.79
3102.04
3105.00
3217.16
3217.62
3440.05
3446.37
3447.38
3530.75
3618.49
3648.84
3648.98
3681.54
3816.56
3817.50
3897.92
4001.24
4044.14
4047.21
4134.72
4149.19
4186.24
4222.97
4225.67
Spectrum
Ref.
K
K
K
K
K
K
K
K
II
II
II
II
II
II
II
II
E31
E31
E31
E31
E31
E31
E31
E31
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
II
II
I
I
I
I
I
I
II
I
I
II
I
I
II
II
I
I
II
II
II
II
II
I
I
II
II
II
II
II
D26
D26
R56
R56
R56
R56
R56
R56
D26
R56
R56
D26
R56
R56
D26
D26
R56
R56
D26
D26
D26
D26
D26
R56
R56
D26
D26
D26
D26
D26
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1934
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Potassium 共K兲—Continued
Intensity
250
250
250
250
250
400
400
150
250
200
300
200
300
250
300
300
300
300
300
400
300
400
400
400
250
250
400
400
400
500
500
500
500
600
600
700
600
700
250
250
800
500
800
300
500
1000 P
1000 P
200
150
300
250
400
300
120
80
40
400
400
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4263.40
4305.00
4309.10
4388.16
4608.45
4641.88
4642.37
4740.91
4744.35
4753.93
4757.39
4786.49
4791.05
4799.75
4804.35
4829.23
4849.86
4856.09
4863.48
4869.76
4942.02
4950.82
4956.15
4965.03
5005.60
5056.27
5084.23
5097.17
5099.20
5112.25
5323.28
5339.69
5342.97
5359.57
5782.38
5801.75
5812.15
5831.89
6120.27
6307.29
6911.08
6936.28
6938.77
6964.18
6964.67
7664.8991
7698.9645
7955.37
7956.83
8078.11
8079.62
8250.18
8251.74
8390.22
8391.44
8417.54
8420.00
8503.45
8505.11
Spectrum
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
D26
D26
D26
D26
D26
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
D26
R56
R56
R56
R56
R56
R56
R56
R56
D26
D26
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
D26
D26
R56
R56
R56
R56
R56
E99
E99
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
ATOMIC SPECTROSCOPIC DATA
1935
Strong Lines of Potassium 共K兲—Continued
Intensity
Wavelength 共Å兲
150
120
500
500
200
150
300
120
250
600
600
250
200
400
200
300
700
600
700 P
600 P
700 P
8763.96
8767.05
8902.19
8904.02
8923.31
8925.44
9347.24
9349.25
9351.59
9595.70
9597.83
9949.67
9954.14
10479.63
10482.15
10487.11
11019.87
11022.67
11690.21
11769.62
11772.83
12432.24
12522.11
13377.86
13397.09
15163.08
15168.40
40158.37
Spectrum
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
K
Ref.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
L70b
Persistent Lines of Neutral Potassium 共K I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
700
4044.14
0.0116
700
1000
1000
700
600
700
4047.21
7664.8991
7698.9645
11690.21
11769.62
11772.83
0.0107
0.379
0.374
0.220
0.0434
0.259
J
Level (cm⫺1 )
S
P
1/2
3/2
0.000
24720.139
R56
M03
S
P
1/2
1/2
0.000
24701.382
R56
M03
S
P
1/2
3/2
0.000
13042.876
E99
M03
S
P
1/2
1/2
0.000
12985.170
E99
M03
4p
3d
2 o
P
D
1/2
3/2
12985.170
21536.988
R56
WSM69
4p
3d
2 o
P
D
3/2
3/2
13042.876
21536.988
R56
WSM69
4p
3d
2 o
3/2
5/2
13042.876
21534.680
R56
WSM69
Configuration
Term
4s
5p
2
4s
5p
2
4s
4p
2
4s
4p
2
2 o
2 o
2 o
2 o
2
2
2
P
D
Wl Ref
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1936
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Potassium 共K I兲
Level (cm⫺1 )
J
Ref
Configuration
Term
4s
2
S
1/2
0.000
E99
4p
2 o
P
1/2
3/2
12985.186
13042.896
E99
E99
3d
2
D
5/2
3/2
21534.700
21537.004
SC85
SC85
5p
2 o
1/2
3/2
24701.382
24720.139
SC85
SC85
Limit
35009.8140
SC85
P
K II ( 1 S0 )
Persistent Lines of Singly-ionized Potassium 共K II兲
Inten
Wavelength 共Å兲
1000
800
1000
A ki (108 s⫺1 )
Configuration
6
600.77
3p
3 p 5 4s
607.93
0.013
J
Level (cm⫺1 )
1
S
P
0
1
0.0
166461.5
E31
S
P
0
1
0.0
164496.1
E31
S
P
0
1
0.0
163237.0
E31
1 o
3p 6
3 p 5 3d
1
3 o
3p 6
3 p 5 4s
612.62
Term
1
3 o
Wl Ref
A Ref
FW96
Energy Levels of Singly-ionized Potassium 共K II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3p6
1
S
0
0.0
SC85
3 p 5 4s
3 o
P
2
1
0
162507.0
163237.0
165149.5
SC85
SC85
SC85
3 p 5 3d
3 o
P
0
1
2
163436.3
164496.1
164932.3
SC85
SC85
SC85
3 p 5 4s
1 o
1
166461.5
SC85
255100
K87
P
o
)
K III ( 2 P3/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
1937
Praseodymium „Pr…
Atomic number⫽59
Atomic weight⫽140.907 65
Isotope
141
Pr
Mass
Abundance
Spin
Mag moment
140.907647
100%
5/2
⫹4.3
o
Pr I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 3 6s 2 4I9/2
⫺1
Ionization energy: 44 140 cm 共5.473 eV兲
o
)6s (9/2,1/2) o4
Pr II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 3 ( 4 I9/2
⫺1
Ionization energy: 85 100 cm 共10.55 eV兲
Strong Lines of Praseodymium 共Pr兲
Intensity
80
130
70
60
80
130
130
60
80
250
130
60
200
90
110
250
140
200
90
90
300
130
80
80
150
120
60
250
80
200
90
70
70
140
150
150
70
500
90
110
300
h
c
c
c
c
c
c
c
c
c
c
P
c
Wavelength 共Å兲
Air
2579.31
2881.60
3668.83
3714.05
3739.18
3761.87
3800.30
3804.84
3811.84
3816.02
3818.28
3821.80
3830.72
3840.99
3846.59
3850.79
3851.55
3852.80
3865.45
3876.19
3877.18
3880.47
3885.19
3889.34
3908.05
3912.90
3913.55
3918.85
3919.63
3925.47
3927.46
3929.29
3935.82
3947.63
3949.43
3953.51
3956.75
3959.44
3962.45
3964.26
3964.81
Spectrum
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1938
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Praseodymium 共Pr兲—Continued
Intensity
110
100
60
120
60
250
70
300
110
60
120
140
400
120
140
120
90
70
70
140
200
140
90
250
70
90
400
400
90
700
700*
100
100
150
100
110
70
600
300
70
300
500
300
120
140
1000
500
110
60
500
100
60
60
700
700
60
60
200
70
c
c
c
c
c
c
c
P
P
c
c
P,c
c
c
P
c
P
P
c
P,c
P
P
c
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3966.57
3971.16
3971.67
3972.14
3974.85
3989.68
3992.16
3994.79
3997.04
3999.12
4000.173
4004.702
4008.691
4010.601
4015.391
4020.96
4022.712
4025.54
4029.72
4031.753
4033.827
4038.455
4039.341
4044.813
4047.082
4051.13
4054.860
4056.537
4058.800
4062.804
4062.806
4079.77
4080.980
4081.85
4083.341
4096.820
4098.400
4100.717
4118.457
4130.771
4141.224
4143.112
4164.156
4171.822
4172.246
4179.391
4189.479
4191.605
4201.17
4206.719
4208.315
4211.862
4217.810
4222.931
4225.346
4233.114
4236.153
4241.010
4243.507
Spectrum
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
G90
G90
G90
G90
G90
MCS75
G90
MCS75
MCS75
MCS75
G90
G90
G90
G90
G90
MCS75
G90
G90
G90
G90
G90
MCS75
G90
MCS75
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
MCS75
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
ATOMIC SPECTROSCOPIC DATA
1939
Strong Lines of Praseodymium 共Pr兲—Continued
Intensity
150
100
60
150
90
150
90
60
300
250
70
120
90
70
90
80
250
60
80
300
80
250
140
200
200
150
70
70
400
400
500
500
800
400
500
700
250
300
400
500
400
800
400
1000
300
300
500
500
250
300
800
400
500
70
110
80
700
250
120
c
c
c
c
c
c,w
c
c
c
c
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
4247.631
4254.402
4269.093
4272.273
4280.07
4282.456
4298.965
4303.61
4305.764
4333.973
4338.702
4344.30
4347.491
4350.399
4354.91
4359.788
4368.334
4371.62
4405.825
4408.820
4413.770
4429.128
4449.826
4468.663
4496.456
4510.153
4534.154
4535.923
4632.28
4635.68
4639.55
4687.80
4695.77
4709.52
4730.67
4736.69
4744.16
4906.99
4914.02
4924.60
4936.00
4939.74
4940.30
4951.37
4975.75
5018.59
5019.76
5026.96
5033.38
5043.83
5045.52
5053.40
5087.12
5110.384
5110.763
5129.536
5133.44
5139.81
5173.905
Spectrum
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
I
I
II
Ref
G90
G90
G90
G90
MCS75
G90
G90
MCS75
G90
G90
G90
MCS75
G90
G90
MCS75
G90
G90
MCS75
G90
G90
G90
G90
G90
G90
G90
G90
G90
G90
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
G90
G90
G90
MCS75
MCS75
G90
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1940
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Praseodymium 共Pr兲—Continued
Intensity
Wavelength 共Å兲
300
70
70
110
300
130
70
70
80
120
120
90
150
150
250
110
90
90
90
90
110
110
120*
120*
90
400
150*
150*
120
140
110
140
120
110
140
90
140
5194.43
5206.561
5219.048
5220.108
5227.97
5259.737
5292.024
5292.620
5322.772
5531.16
5562.06
5661.57
5668.46
5707.61
5779.28
5835.13
5874.72
5878.10
5879.04
5884.72
5920.76
5986.14
5987.14
5987.29
6049.26
6055.13
6148.23
6148.24
6322.36
6359.03
6393.18
6411.23
6486.55
6491.75
6616.67
6747.09
6798.60
c
c
h
c
c
c
c
c
c
h
c
c,w
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
I
II
II
II
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
II
I
I
I
I
I
I
I
I
I
Ref
MCS75
G90
G90
G90
MCS75
G90
G90
G90
G90
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1941
Persistent Lines of Neutral Praseodymium 共Pr I兲
A ki (108 s⫺1 )
Level (cm⫺1 )
Inten
Wavelength 共Å兲
500
3959.44
500
4639.55
500
4687.80
MCS75
800
4695.77
MCS75
500
4730.67
0.34
4 f 3 6s 2
4 o
I
11/2
9/2
1376.60
22509.40
MCS75
M00
700
4736.69
0.53
4 f 3 6s 2
4 o
I
9/2
7/2
0.00
21105.88
MCS75
M00
500
4924.60
0.59
4 f 3 6s 2
4 o
I
11/2
11/2
1376.60
21677.15
MCS75
M00
800
4939.74
4 o
13/2
13/2
2846.75
23085.08
MCS75
9/2
9/2
0.00
20190.85
MCS75
13/2
15/2
2846.75
22762.55
MCS75
11/2
13/2
1376.60
21263.71
MCS75
M00
15/2
17/2
4381.10
24195.13
MCS75
M00
4 o
I
13/2
15/2
2846.75
22498.81
MCS75
M00
4 o
9/2
11/2
0.00
19474.75
MCS75
M00
1000
500
500
800
4951.37
5045.52
Term
J
Wl Ref
A Ref
MCS75
4 f 3 6s 2
4 o
I
4 f 3 6s 2
4 f 3 6s6 p?
4
4 f 3 6s 2
4 f 3 ( 4 Io)6s6p( 1 Po)?
0.83
4 f 3 6s 2
4 f 3 6s6 p?
5019.76
5026.96
Configuration
500
5087.12
0.44
4 f 3 6s 2
700
5133.44
0.38
4 f 3 6s 2
4 f 3 6s6 p?
I
I?
4 o
4 f 3 6s 2
4 f 3 6s6 p?
0.71
4 o
4
4
4 f 3 6s 2
4 f 3 ( 4 Io)6s6p?
0.40
I
I?
I
K?
4 o
4
I
K?
4 o
4
4
I
K?
I
I?
11/2
9/2
1376.60
22924.39
MCS75
M00
Energy Levels of Neutral Praseodymium 共Pr I兲
J
Level (cm⫺1 )
Ref
4 o
I
9/2
11/2
13/2
15/2
0.00
1376.60
2846.75
4381.10
MZH78
MZH78
MZH78
MZH78
4 f 2 ( 3 H)5d6s 2
4
I
9/2
11/2
13/2
15/2
4432.22
6313.23
7951.31
—
MZH78
MZH78
MZH78
4 f 2 ( 3 H)5d6s 2
4
K
11/2
13/2
15/2
17/2
4866.54
6603.60
8363.91*
—
MZH78
MZH78
MZH78
4 f 2 ( 3 H)5d6s 2
2
H
9/2
11/2
5822.87
6892.95
MZH78
MZH78
Configuration
Term
4 f 3 6s 2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1942
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Praseodymium 共Pr I兲—Continued
J
Level (cm⫺1 )
Ref
4
H
7/2
9/2
11/2
13/2
6535.51
8029.24
9675.01
—
MZH78
MZH78
MZH78
4 f 2 ( 3 H)5d 2 ( 3 F)( 5 L)6s
6
L
11/2
13/2
15/2
17/2
19/2
21/2
6714.22
7630.16
—
—
—
—
MZH78
MZH78
4 f 3 6s6p?
4
I?
11/2
19474.75
MZH78
4
I?
9/2
20190.85
MZH78
7/2
21105.88
MZH78
13/2
21263.71
MZH78
11/2
21677.15
MZH78
15/2
22498.81
MZH78
9/2
22509.40
MZH78
15/2
22762.55
MZH78
9/2
22924.39
MZH78
Configuration
2 3
4 f ( H)5d6s
3 4 o
Term
2
1 o
4 f ( I )6s6p( P )?
4 f 3 ( 4 Io)6s6p?
4
4 f 3 6s6p?
4
3
K?
K?
4 f 6s6p?
4
I?
13/2
23085.08
MZH78
4 f 3 6s6p?
4
K?
17/2
24195.13
MZH78
Limit
44140
WSPC78
o
)6s (9/2 ,1/2) o4
Pr II ( 4 I9/2
Persistent Lines of Singly-ionized Praseodymium 共Pr II兲
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
700*
4062.804
0.34
o
)6s 1/2
4 f 3 ( 4 I13/2
4 f 3 ( 4 Io)6p
(13/2,1/2) o
3
K
6
7
3403.21
28009.80
G90
700*
4062.806
o
)6s 1/2
4 f 3 ( 4 I13/2
2
4 f 5d 2
(13/2,1/2) o
7
6
2998.36
27604.94
G90
600
4100.717
0.71
o
)6s 1/2
4 f 3 ( 4 I15/2
4 f 3 ( 4 Io)6p
(15/2,1/2) o
5
K
8
9
4437.14
28816.25
G90
GKQW91
500
4143.112
0.54
o
)6s 1/2
4 f 3 ( 4 I13/2
3 4 o
4 f ( I )6p
(13/2,1/2) o
5
K
7
8
2998.36
27128.00
G90
GKQW91
1000
4179.391
0.54
o
)6s 1/2
4 f 3 ( 4 I11/2
4 f 3 ( 4 Io)6p
(11/2,1/2) o
5
K
6
7
1649.01
25569.19
G90
GKQW91
500
4189.479
0.30
o
)6s 1/2
4 f 3 ( 4 I13/2
3 4 o
4 f ( I )6p
(13/2,1/2) o
5
I
7
7
2998.36
26860.95
G90
GKQW91
500
4206.719
0.45
o
)6s 1/2
4 f 3 ( 4 I15/2
4 f 3 ( 4 Io)6p
(15/2,1/2) o
5
I
8
8
4437.14
28201.95
G90
GKQW91
700
4222.931
0.34
o
)6s 1/2
4 f 3 ( 4 I9/2
3 4 o
4 f ( I )6p
(9/2,1/2) o
5
K
5
6
441.95
24115.48
G90
GKQW91
700
4225.346
0.55
o
)6s 1/2
4 f 3 ( 4 I9/2
3 4 o
4 f ( I )6p
(9/2,1/2) o
5
I
4
4
0.00
23660.08
G90
GKQW91
Inten
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wl Ref
A Ref
GKQW91
ATOMIC SPECTROSCOPIC DATA
1943
Energy Levels of Singly-ionized Praseodymium 共Pr II兲
Configuration
Term
o
)6s 1/2
4 f 3 ( 4 I9/2
(9/2 ,1/2)
o
)6s 1/2
4 f 3 ( 4 I11/2
J
o
Level (cm⫺1 )
Ref
4
5
0.00
441.95
MZH78
MZH78
(11/2 ,1/2) o
6
5
1649.01
1743.72
MZH78
MZH78
o
)6s 1/2
4 f 3 ( 4 I13/2
(13/2 ,1/2) o
7
6
2998.36
3403.21
MZH78
MZH78
4 f 3 ( 4 Io)5d
5 o
L
6
7
8
9
10
3893.46
5108.40
6417.83
7805.61
9255.19
G89
G89
G89
G89
G89
4 f 3 ( 4 Io)5d
5
Ko
5
6
7
8
9
4097.58
5226.52
6413.93
7659.72
8958.44
G89
G89
G89
G89
G89
o
)6s 1/2
4 f 3 ( 4 I15/2
(15/2 ,1/2) o
8
7
4437.14
5079.34
MZH78
MZH78
4 f 2 ( 3 H)5d 2 ( 3 F)
5
L
6
5854.54
G89
4 f 2 ( 3 H)5d 2 ( 3 F)
5
I
4
7228.00
G89
4 f ( I )6p
5
K
5
6
7
8
9
22675.44
24115.48
25569.19
27128.00
28816.25
G89
G89
G89
G89
G89
4 f 3 ( 4 Io)6p
5
I
4
5
6
7
8
23660.08
24716.04
25656.69
26860.95
28201.95
G89
G89
G89
G89
G89
6
27604.94
G89
7
28009.80
G89
85100
SR65
3 4 o
4 f 2 5d 2
3 4 o
4 f ( I )6p
o
)
Pr III ( 4 I9/2
3
K
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1944
J. E. SANSONETTI AND W. C. MARTIN
Promethium „Pm…
Atomic number⫽61
Atomic weight⫽145
Isotope
145
Pm
Pm
147
Pm
149
Pm
151
Pm
146
Mass
Abundance
Spin
144.912743
145.914708
146.915135
148.918332
150.921203
0
0
0
0
0
5/2
3
7/2
7/2
5/2
Mag moment
⫹2.7
⫾3.3
⫾1.8
o
Pm I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 5 6s 2 6H5/2
⫺1
Ionization energy: 45 020 cm 共5.582 eV兲
Pm II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 5 6s 7Ho2
Ionization energy: 87 900 cm⫺1 共10.90 eV兲
Strong Lines of Promethium 共Pm兲
Intensity
300
500
400
300
300
400
300
300
400
800
150
300
500
300
500
400
300
300
800
1000
400
1000
1000
800
300
1000
500
300
1000
500
300
600
600
500
300
600
300
Wavelength 共Å兲
P
P
P
P
P
P,r
r
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
3072.41
3427.40
3449.80
3634.20
3659.39
3689.79
3692.50
3697.50
3702.63
3711.72
3726.01
3742.52
3745.86
3747.09
3750.09
3795.66
3820.53
3842.98
3877.62
3892.15
3899.78
3910.26
3919.10
3936.48
3944.21
3957.74
3980.74
3995.05
3998.96
4009.96
4051.54
4055.20
4075.84
4086.10
4192.92
4297.78
4336.54
Spectrum
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RD67
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
ATOMIC SPECTROSCOPIC DATA
1945
Strong Lines of Promethium 共Pm兲—Continued
Intensity
300
150
150
100
1000
400
500
600
800
300
150
600
600
150
800
150
100
100
200
100
150
100
100
200
100
200
150
150
100
100
150
100
150
300
150
100
150
200
100
300
150
400
150
150
700
1000
400
200
600
500
200
350
350
700
300
150
100
350
350
r
r
r
P
P
r
r
P
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
r
P,r
r
r
P,r
P,r
P,r
r
P,r
P,r
r
P,r
P,r
P,r
r
r
r
P,r
P,r
Wavelength 共Å兲
4342.12
4369.64
4388.49
4412.47
4417.96
4432.51
4445.41
4446.90
4453.95
4473.23
4481.60
4500.15
4525.20
4527.70
4529.21
4575.27
4597.55
4600.25
4605.66
4609.85
4617.02
4619.75
4621.57
4623.68
4624.41
4625.29
4633.45
4643.36
4643.76
4647.03
4653.41
4660.79
4663.46
4665.19
4671.23
4677.92
4678.09
4682.92
4696.80
4728.36
4728.68
4734.27
4745.13
4757.73
4759.00
4762.57
4773.46
4781.29
4798.98
4801.36
4809.54
4811.85
4837.66
4860.74
4865.72
4872.42
4887.02
4892.52
4932.99
Spectrum
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
II
I
I
I
II
II
II
II
II
II
I
II
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
RCWM80
RD67
RD67
RD67
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RD67
RCWM80
RCWM80
RD67
RCWM80
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RD67
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1946
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Promethium 共Pm兲—Continued
Intensity
500
1000
1000
400
300
1000
700
400
300
500
300
500
500
300
400
500
800
800
500
300
400
150
100
50
300
200
50
100
50
100
50
500
50
300
50
400
80
70
80
70
400
50
80
70
50
50
60
70
50
50
70
60
90
90
300
80
Wavelength 共Å兲
P,r
P,r
P,r
r
r
P,r
P,r
P
P
c
c
P
h
h
P,d
P
w
c
h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4959.46
4997.10
5058.31
5094.83
5100.77
5127.34
5146.30
5153.86
5169.71
5171.58
5194.05
5208.09
5236.26
5236.66
5246.33
5270.64
5546.08
5576.02
5823.93
5868.79
5946.49
5956.42
6043.39
6069.06
6100.21
6151.76
6229.64
6286.06
6308.29
6323.84
6390.31
6431.93
6517.25
6520.45
6542.20
6598.15
6598.66
6606.37
6625.23
6649.81
6659.05
6661.68
6667.51
6677.47
6685.55
6685.68
6700.33
6714.67
6717.26
6720.71
6727.50
6743.71
6749.91
6750.48
6772.29
6833.30
Spectrum
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
Pm
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
Ref
RD67
RD67
RD67
RD67
RD67
RD67
RD67
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
RCWM80
ATOMIC SPECTROSCOPIC DATA
1947
Persistent Lines of Neutral Promethium 共Pm I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5
Term
o
J
Level (cm⫺1 )
Wl Ref
2
6
H
7/2
9/2
803.82
21920.49
RD67
400
4734.27
4 f 6s
700
4759.00
4 f 5 6s 2
6
Ho
15/2
17/2
5089.79
26096.75
RD67
1000
4762.57
4 f 5 6s 2
6
Ho
15/2
17/2
5089.79
26080.99
RD67
400
4773.46
4 f 5 6s 2
6
Ho
11/2
13/2
2797.10
23740.42
RD67
600
4798.98
4 f 5 6s 2
6
Ho
11/2
13/2
2797.10
23629.06
RD67
500
4801.36
4 f 5 6s 2
6
Ho
7/2
9/2
803.82
21625.45
RD67
350
4811.85
4 f 5 6s 2
6 o
F
9/2
9/2
7497.99
28274.21
RD67
350
4837.66
4 f 5 6s 2
6
Ho
9/2
11/2
1748.78
22414.17
RD67
700
4860.74
4 f 5 6s 2
6
Ho
7/2
7/2
803.82
21371.05
RD67
350
4892.52
4 f 5 6s 2
6
Ho
7/2
9/2
803.82
21237.49
RD67
350
4932.99
4 f 5 6s 2
6
Ho
5/2
5/2
0.00
20265.98
RD67
500
4959.46
4 f 5 6s 2
6
Ho
5/2
7/2
0.00
20157.85
RD67
1000
4997.10
4 f 5 6s 2
6
Ho
5/2
3/2
0.00
20006.04
RD67
1000
5058.31
4 f 5 6s 2
6
Ho
7/2
5/2
803.82
20567.76
RD67
1000
5127.34
4 f 5 6s 2
6
Ho
11/2
9/2
2797.10
22294.96
RD67
700
5146.30
4 f 5 6s 2
6
Ho
13/2
11/2
3919.03
23345.07
RD67
300
6100.21
RCWM80
300
6520.45
RCWM80
400
6598.15
RCWM80
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1948
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Promethium 共Pm I兲
J
Level (cm⫺1 )
6
Ho
5/2
7/2
9/2
11/2
13/2
15/2
0.00
803.82
1748.78
2797.10
3919.03
5089.79
RD67
RD67
RD67
RD67
RD67
RD67
6 o
1/2
3/2
5/2
7/2
9/2
11/2
5249.48
5460.50
5872.84
6562.86
7497.99
8609.21
RD67
RD67
RD67
RD67
RD67
RD67
7/2
17104.72
RD67
3/2
20006.04
RD67
7/2
20157.85
RD67
5/2
20265.98
RD67
5/2
20567.76
RD67
9/2
21237.49
RD67
7/2
21371.05
RD67
9/2
21625.45
RD67
9/2
21920.49
RD67
9/2
22294.96
RD67
11/2
22414.17
RD67
11/2
23345.07
RD67
13/2
23629.06
RD67
13/2
23740.42
RD67
11/2
24912.34
RD67
17/2
26096.75
RD67
9/2
28274.21
RD67
45020
WSPC78
Configuration
Term
4 f 5 6s 2
4 f 5 6s 2
Pm II (
F
7
Ho2 )
Limit
Ref
Persistent Lines of Singly-ionized Promethium 共Pm II兲
Inten
Wavelength 共Å兲
1000
3892.15
1000
3910.26
1000
3919.10
800
3936.48
A ki (108 s⫺1 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
RCMW80
5 6
o
4 f ( H )6s
7
o
H
6
7
2950.31
28516.85
RCMW80
RCMW80
4 f 5 ( 6 Ho)6s
7
Ho
5
6
1983.52
27379.79
RCMW80
A Ref
ATOMIC SPECTROSCOPIC DATA
1949
PersistentLinesofSingly-ionizedPromethium共PmII兲—Continued
Wavelength共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level(cm⫺1 )
3957.74
Wl Ref
A Ref
RCMW80
3998.96
4 f 5 ( 6 Ho)6s
7
Ho
4
5
1133.45
26132.87
RCMW80
4075.84
4 f 5 ( 6 Ho)6s
7
Ho
2
3
0.00
24527.89
RCMW80
4086.10
4 f 5 ( 6 Ho)6s
7
Ho
2
3
0.00
24466.32
RCMW80
4297.78
4 f 5 ( 6 Ho)6s
4 f 5 ( 6 Ho)6p
7
Ho
I
2
3
0.00
23261.30
RCMW80
4 f 5 ( 6 Ho)6s
7
Ho
4
3
1133.45
23761.98
RCMW80
4417.96
7
4453.95
RCMW80
4529.21
RCMW80
5546.08
5576.02
4 f 5 ( 6 Ho)5d
4 f 5 ( 6 Ho)6p
7
4 f 5 ( 6 Ho)5d
4 f 5 ( 6 Ho)6p
7
7
7
Ko
I
5
4
6131.47
24157.20
RCMW80
Ko
I
4
3
5332.36
23261.30
RCMW80
Energy Levels of Singly-ionized Promethium 共Pm II兲
Configuration
Term
J
Level (cm⫺1 )
4 f 5 ( 6 Ho)6s
7
Ho
2
3
4
5
6
7
8
0.00
446.45
1133.45
1983.52
2950.31
4000.15
—
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 5 ( 6 Ho)6s
5
Ho
3
4
5
6
7
1602.97
2666.76
3812.31
5017.77
—
MZH78
MZH78
MZH78
MZH78
4 f 5 ( 6 Fo)6s
7 o
F
0
1
2
3
4
5
6
5280.88
5391.46
5632.40
6048.50
6705.18
—
—
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 5 ( 6 Ho)5d
7
Ko
4
5
6
7
8
9
10
5332.36
6131.47
7040.66
8041.72
9119.34
—
—
OHRW95
OHRW95
OHRW95
OHRW95
OHRW95
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1950
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Promethium 共Pm II兲—Continued
J
Level (cm⫺1 )
4 f ( F )6s
5 o
F
1
2
3
4
5
6629.40
7012.87
7701.09
—
—
MZH78
MZH78
MZH78
4 f 5 ( 6 Ho)6p
7
I
3
4
5
6
7
23261.30
24157.20
25015.69
26027.56
27110.08
MZH78
MZH78
MZH78
MZH78
MZH78
3
23761.98
MZH78
3
24466.32
MZH78
3
24527.89
MZH78
5
26132.87
MZH78
6
27379.79
MZH78
7
28516.85
MZH78
87900
SR65
Configuration
5 6 o
Term
o
)
Pm III ( 6 H5/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
Ref
ATOMIC SPECTROSCOPIC DATA
1951
Protactinium „Pa…
Atomic number⫽91
Atomic weight⫽231.035 88
Isotope
231
Pa
Pa
234
Mass
Abundance
Spin
Mag moment
231.035880
234.043303
Trace
Trace
3/2
4
⫹2.01
Pa I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 2 6d7s 2 4K11/2
Ionization energy: 47 500 cm⫺1 共5.89 eV兲
Pa II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 2 7s 2 3H4
Ionization energy: not available
Strong Lines of Protactinium 共Pa兲
Intensity
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
1000
300
300
300
300
300
1000
300
300
1000
300
300
h
l
h
h
h
l
s
l
l
l
l
l
l
l
l
s
l
l
s
P
s
P,l
s
P
l
s
Wavelength 共Å兲
Air
2492.85
2599.16
2699.22
2822.792
2832.14
2870.005
2871.413
2891.139
2906.93
3011.10
3033.59
3071.24
3093.23
3126.23
3146.28
3170.89
3171.54
3240.58
3274.46
3332.69
3346.661
3394.49
3452.82
3504.97
3530.65
3570.56
3571.82
3618.07
3636.52
3702.74
3752.67
3873.35
3931.83
3952.62
3957.85
3970.07
3981.82
3982.23
4012.96
4018.21
Spectrum
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
I
I
I
I
I
I
I
II
II
II
I
I
II
II
Ref
BW92b
BW92b
BW92b
G67
BW92b
G67
G67
G67
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
G67
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1952
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Protactinium 共Pa兲—Continued
Intensity
300
300
1000
1000
300
300
1000
1000
300
300
300
300
300
300
300
300
300
300
300
300
300
300
1000
300
300
300
300
300
1000
300
300
300
1000
300
1000
300
1000
1000
1000
1000
300
1000
300
300
1000
1000
1000
1000
300
300
300
1000
1000
300
300
1000
300
300
300
s
P,s
P,s
l
P,l
P,s
s
s
s
l
l
l
h
P
h
s
h
P,s
h
P,l
h
P,h
h
P,h
P
P,s
P
P,h
l
P
P,h
P
P
s
s
h
P,h
P,s
h
h
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4030.16
4046.93
4056.20
4070.40
4117.62
4176.18
4217.23
4248.083
4291.345
4400.77
4436.13
4601.43
4628.19
4820.34
4861.49
6035.78
6162.56
6216.35
6358.61
6379.25
6438.97
6792.75
6945.72
6960.09
6961.78
6992.73
7076.27
7100.94
7114.89
7171.55
7227.13
7318.79
7368.25
7471.89
7493.15
7558.26
7608.20
7626.79
7635.18
7669.34
7679.20
7749.19
7872.95
7945.56
8039.34
8099.84
8199.04
8271.87
8358.98
8369.60
8441.04
8532.66
8572.96
8639.91
8653.51
8735.27
10594.38
10923.32
11646.78
Spectrum
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
Pa
II
II
II
II
I
II
II
II
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
G67
G67
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
ATOMIC SPECTROSCOPIC DATA
1953
Strong Lines of Protactinium 共Pa兲—Continued
Intensity
Wavelength 共Å兲
1000 P
300
300
1000 P
1000 P
300
Spectrum
11791.73
12279.01
13234.09
13522.40
14344.76
18478.61
Pa
Pa
Pa
Pa
Pa
Pa
I
I
I
I
I
I
Ref
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
Persistent Lines of Neutral Protactinium 共Pa I兲
Inten
Wavelength 共Å兲
1000
3636.52
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
I
9/2
9/2
825.415
28316.365
BW92b
K
11/2
11/2
0.000
25104.455
BW92b
K
L
11/2
11/2
0.000
14393.410
BW92b
I
9/2
9/2
825.415
14876.545
BW92b
I
L
9/2
11/2
825.415
14393.410
BW92b
9/2
7/2
3323.860
16665.690
BW92b
o
9/2
9/2
3323.860
16463.970
BW92b
o
K
13/2
11/2
3711.625
16819.670
BW92b
K
15/2
13/2
7512.695
20606.365
BW92b
I
Ko
11/2
11/2
4121.450
17156.785
BW92b
a 4G
5/2
5/2
1618.325
14519.355
BW92b
K
I
13/2
11/2
3711.625
16147.025
BW92b
I
11/2
9/2
4121.450
16463.970
BW92b
I
I
9/2
9/2
825.415
13018.610
BW92b
I
9/2
7/2
825.415
12911.260
BW92b
7/2
5/2
2966.530
14683.005
BW92b
11/2
9/2
0.000
11444.705
BW92b
Configuration
5 f 2 ( 3 H)6d7s 2
Term
4
o
1000
3982.23
5 f 2 ( 3 H)6d7s 2
4
o
1000
1000
6945.72
7114.89
5 f 2 ( 3 H)6d7s 2
5 f 2 6d7s7 p
5 f 2 ( 3 H)6d7s 2
4
6 o
4
o
1000
1000
1000
1000
7368.25
7493.15
7608.20
7626.79
5 f 2 ( 3 H)6d7s 2
5 f 2 6d7s7 p
4
6 o
5 f 2 ( 3 H)6d7s 2
5 f 2 ( 3 H)6d7s 2
5 f 2 ( 3 H)6d7s 2
4
o
1000
7635.18
5 f 2 ( 3 H)6d7s 2
4
o
1000
1000
7669.34
7749.19
5 f 2 ( 3 H)6d7s 2
5 f 2 6d7s7 p
5 f 2 6d7s 2
4
6
o
1000
1000
8039.34
8099.84
5 f 2 ( 3 H)6d7s 2
5 f 3 7s 2
5 f 2 ( 3 H)6d7s 2
4
4 o
4
o
1000
1000
8199.04
8271.87
5 f 2 ( 3 H)6d7s 2
5 f 3 7s 2
5 f 2 ( 3 H)6d7s 2
4
4 o
4
o
1000
8532.66
5 f 2 6d7s 2
a 4H
o
1000
8735.27
5 f 2 ( 3 H)6d7s 2
5 f 2 7s 2 7 p 1/2
4
K
(4,1/2) o
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1954
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Protactinium 共Pa I兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
2
Term
2
4
1000
11791.73
5 f 6d7s
5 f 2 7s 2 7 p 1/2
a H
(4,1/2) o
1000
13522.40
5 f 2 ( 3 H)6d 2 ( 3 F)( 5 L)7s
5 f 2 6d7s7 p
6
5 f 2 6d7s 2
5 f 2 7s 2 7 p 1/2
b 4H
(4,1/2) o
1000
14344.76
L
L
6 o
J
Level (cm⫺1 )
Wl Ref
7/2
9/2
2966.530
11444.705
BW92b
11/2
11/2
7000.290
14393.410
BW92b
7/2
7/2
5149.465
12118.750
BW92b
A Ref
Energy Levels of Neutral Protactinium 共Pa I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5 f 2 ( 3 H)6d7s 2
4
11/2
13/2
15/2
17/2
0.000
3711.625
7512.695
11198.270
BW92b
BW92b
BW92b
BW92b
5 f 2 ( 3 H)6d7s 2
4
9/2
11/2
13/2
15/2
825.415
4121.450
7383.295
10049.875
BW92b
BW92b
BW92b
BW92b
5 f 2 6d7s 2
a 4G
5/2
7/2
9/2
1618.325
4713.870
7330.815
BW92b
BW92b
BW92b
5 f ( 2 F)6d 2 ( 3 F)7s 2
4
7/2
9/2
11/2
13/2
1978.220
5335.730
8419.075
11498.725
BW92b
BW92b
BW92b
BW92b
5 f ( 2 F)6d 2 ( 3 F)7s 2
4 o
9/2
2659.405
BW92b
5 f 2 6d7s 2
a 4H
7/2
2966.530
BW92b
9/2
3323.860
BW92b
11/2
4576.005
BW92b
7/2
5149.465
BW92b
5/2
5938.650
BW92b
9/2
6149.805
BW92b
11/2
6302.230
BW92b
o
7/2
6425.830
BW92b
b 4G
5/2
6708.56
BW92b
11/2
7000.290
BW92b
2 3
5 f ( H)6d7s
K
I
Ho
I
2
5 f 2 ( 3 H)6d7s 2
5 f 2 6d7s 2
b 4H
5 f 2 ( 3 H)6d7s 2
2
5 f 6d7s
2
4
a H
5 f ( 2 F)6d 2 ( 3 F)7s 2
5 f 2 6d7s 2
2 3
5 f ( H)6d ( F)( L)7s
5 f 2 7s 2 7p 1/2
(4,1/2) o
9/2
7/2
11444.705
12118.750
BW92b
BW92b
o
7/2
12911.260
BW92b
9/2
13018.610
BW92b
5 f 7s
2
5
I
6
3
2 3
4 o
L
4 o
I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1955
Energy Levels of Neutral Protactinium 共Pa I兲—Continued
Configuration
J
Level (cm⫺1 )
Ref
11/2
14393.410
BW92b
o
5/2
14519.355
BW92b
o
5/2
14683.005
BW92b
o
9/2
14876.545
BW92b
11/2
16147.025
BW92b
o
9/2
16463.970
BW92b
o
7/2
16665.690
BW92b
o
11/2
16819.670
BW92b
11/2
17156.785
BW92b
o
9/2
18661.700
BW92b
o
13/2
20606.365
BW92b
o
11/2
25104.455
BW92b
o
9/2
28316.365
BW92b
47500
S74
Term
2
6 o
5 f 6d7s7p
L
5 f 3 7s 2
4 o
I
5 f 2 6d7s7p
6
Ko
Pa II (5 f 2 7s 2 3H4 )
Limit
Persistent Lines of Singly-ionized Protactinium 共Pa II兲
Inten
Wavelength 共Å兲
1000
3957.85
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
5 f 2 6d7s
5
K
7
7
5458.850
30717.935
BW92b
K
5
5
823.265
25469.955
BW92b
o
1000
5 f 2 6d7s
4056.20
5
o
1000
4070.40
1000
4217.23
BW92b
5 f 2 6d7s
5
K
6
5
1764.365
25469.955
BW92b
H
4
5
0.000
23533.415
G67
o
1000
A Ref
5 f 2 7s 2
4248.083
3
o
Energy Levels of Singly-ionized Protactinium 共Pa II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5 f 2 7s 2
3
H
4
0.000
BW92b
2
5 f 6d7s
5
K
5
823.265
BW92b
5 f 2 6d7s
5
I
4
1744.800
BW92b
5 f 2 6d7s
5
K
6
1764.365
BW92b
5 f 2 6d7s
5
G
2
2232.135
BW92b
5 f 6d7s
5
I
5
2555.865
BW92b
5 f 2 6d7s
5
H?
3
3078.285
BW92b
5 f 2 7s 2
3
2
3150.950
BW92b
2
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1956
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Protactinium 共Pa II兲—Continued
Configuration
Level (cm⫺1 )
Ref
Term
J
2
5 f 6d7s
5
3
4011.455
BW92b
5 f 2 7s 2
3
H
5
4447.575
BW92b
5 f 2 6d7s
5
H
4
4555.030
BW92b
5 f 2 6d7s
3
I?
5
4716.445
BW92b
5 o
4
4751.660
BW92b
4
4895.130
BW92b
6
4924.960
BW92b
3
5088.230
BW92b
7
5458.850
BW92b
o
5
23533.415
BW92b
o
5
25469.955
BW92b
o
7
30717.935
BW92b
2
5 f 6d 7s
H
I
5 f 2 6d7s
5 f 2 6d7s
2
3
5 f 6d 7s
o
5 f 2 6d7s
5
o
)
Pa III (5 f 2 ( 3 H)6d 4 I11/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
K
K
Limit
ATOMIC SPECTROSCOPIC DATA
1957
Radium „Ra…
Atomic number⫽88
Atomic weight⫽226.0254
Isotope
Mass
223
Ra
Ra
226
Ra
228
Ra
223.018501
224.020186
226.025402
228.031064
224
Abundance
Spin
Some
Some
Some
Some
1/2
0
0
0
Mag moment
Ra I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 7s 2 1S0
Ionization energy: 42 573.36 cm⫺1 共5.278 423 eV兲
Ra II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 7s 2S1/2
Ionization energy: 81 842.31 cm⫺1 共10.147 15 eV兲
Strong Lines of Radium 共Ra兲
Intensity
100
150
500
1000
500
100
150
500
1000
200
200
200
500
100
300
200
200
200
200
500
200
200
250
Wavelength 共Å兲
Spectrum
Air
2708.96
2813.76
3649.55
3814.42
4340.64
4436.27
4533.11
4682.28
4825.91
5400.23
5406.81
5555.85
5660.81
5813.63
6200.30
6446.20
6487.32
6980.22
7118.50
7141.21
7225.16
7838.12
8019.70
P
P
P
P
P
P
P
P
P
P
P
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ra
Ref
II
II
II
II
II
II
II
II
I
I
I
I
I
II
I
I
I
I
I
I
I
I
II
R34a
R34a
R34a
R34a
R34a
R34a
R34a
R34a
R34b
R34b
R34b
R34b
R34b
R34a
R34b
R34b
R34b
R34b
R34b
R34b
R34b
R34b
R34a
Persistent Lines of Neutral Radium 共Ra I兲
Inten
Wavelength 共Å兲
1000
4825.91
500
300
500
5660.81
6200.30
7141.21
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
7s 2
7s7 p
1
S
P
0
1
0.00
20715.71
R34b
7s6d
6d7p
3
D
F
3
4
14707.35
32367.78
R34b
7s6d
6d7p
3
D
F
2
3
13993.97
30117.78
R34b
7s 2
7s7 p
1
S
P
0
1
0.00
13999.38
R34b
1 o
3 o
3 o
3 o
Wl Ref
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1958
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Radium 共Ra I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
1
S
0
0.00
M58
7s7 p
3 o
P
0
1
2
13078.44
13999.38
16688.54
M58
M58
M58
7s6d
3
D
1
2
3
13715.85
13993.97
14707.35
M58
M58
M58
7s6d
1
D
2
17081.45
M58
7s7 p
1 o
P
1
20715.71
M58
7s8s
3
S
1
26754.05
M58
6d7p
3 o
F
2
3
4
28038.05
30117.78
32367.78
M58
M58
M58
6d7 p
1
Do
2
30918.14
M58
7s8 p
3 o
0
1
2
31085.88
31563.29
31874.44
M58
M58
M58
Limit
42573.36
AWT80
7s
2
P
Ra II ( 2 S1/2)
Persistent Lines of Singly-ionized Radium 共Ra II兲
J
Level (cm⫺1 )
D
F
5/2
7/2
13743.11
49272.31
R34a
7p
7d
2 o
P
D
1/2
3/2
21351.20
48744.04
R34a
3814.42
7s
7p
2
S
P
1/2
3/2
0.00
26208.86
R34a
500
4340.64
7p
7d
2 o
P
D
3/2
5/2
26208.86
49240.48
R34a
150
4533.11
7p
8s
2 o
P
S
1/2
1/2
21351.20
43405.01
R34a
500
4682.28
7s
7p
2
S
P
1/2
1/2
0.00
21351.20
R34a
250
8019.70
6d
7p
2
D
P
5/2
3/2
13743.11
26208.86
R34a
Inten
Wavelength 共Å兲
150
A ki (108 s⫺1 )
Configuration
Term
2813.76
6d
5f
2
500
3649.55
1000
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2 o
2
2 o
2
2
2 o
2 o
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1959
Energy Levels of Singly-ionized Radium 共Ra II兲
Ref
Term
7s
2
S
1/2
0.00
M58
6d
2
D
3/2
5/2
12084.38
13743.11
M58
M58
7p
2 o
P
1/2
3/2
21351.20
26208.86
M58
M58
8s
2
S
1/2
43405.01
M58
7d
2
D
3/2
5/2
48744.04
49240.48
M58
M58
5f
2 o
F
5/2
7/2
48987.98
49272.31
M58
M58
8p
2 o
P
1/2
3/2
50606.01
52392.05
M58
M58
9s
2
S
1/2
59165.23
M58
Limit
81842.31
M58
1
Ra III ( S0 )
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1960
J. E. SANSONETTI AND W. C. MARTIN
Radon „Rn…
Atomic number⫽86
Atomic weight⫽(222)
Isotope
219
Rn
Rn
222
Rn
220
Mass
Abundance
Spin
219.009479
220.011368
222.017570
Trace
Trace
Trace
5/2
0
0
Mag moment
Rn I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 1S0
Ionization energy: 86 692.5 cm⫺1 共10.7485 eV兲
o
Rn II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 5 2P3/2
Ionization energy: not available
Strong Lines of Radon 共Rn兲
Wavelength 共Å兲
Intensity
Vacuum
1451.56
1786.07
Air
3753.65
4307.76
4349.60
4459.25
4508.48
4577.72
4609.38
4721.76
6627.23
6751.81
7055.42
7268.11
7291.00
7450.00
7746.64
7809.82
8049.00
8099.51
8270.96
8520.95
8600.07
8675.83
9327.02
P
P
70
250
300
150
150
150
150
100
50
70
700
300
70
1000
70
300
70
300
300
70
300
50
150
Spectrum
P
P
P
P
P
P
P
P
Ref
Rn I
Rn I
R30
R30
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
Rn
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
R33
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Persistent Lines of Neutral Radon 共Rn I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
1451.56
1786.07
300
700
4349.60
7055.42
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
6
1
6p
o
)6d
6p 5 ( 2 P3/2
2
6p 6
o
)7s
6p 5 ( 2 P3/2
2
1
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)8p
2
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)7p
2
2
2
Term
J
Level (cm⫺1 )
S
关 1/2兴 o
0
1
0.0
68891.34
R30
S
关 3/2兴 o
0
1
0.0
55989.03
R30
关 3/2兴 o
关 5/2兴
2
3
54620.35
77604.53
R33
关 3/2兴 o
关 3/2兴
2
2
54620.35
68789.93
R33
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1961
Persistent Lines of Neutral Radon 共Rn I兲—Continued
Inten
Wavelength 共Å兲
300
1000
300
300
A ki (108 s⫺1 )
7268.11
7450.00
7809.82
8099.51
J
Level (cm⫺1 )
Wl Ref
o
1
0
55989.03
69743.98
R33
关 3/2兴 o
关 5/2兴
2
3
54620.35
68039.48
R33
关 3/2兴 o
关 3/2兴
1
2
55989.03
68789.93
R33
关 3/2兴 o
关 3/2兴
1
1
55989.03
68332.10
R33
关 3/2兴 o
2
关 5/2兴
2
2
54620.35
66707.53
R33
关 3/2兴 o
关 1/2兴
2
1
54620.35
66244.97
R33
Configuration
Term
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)7p
2
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)7p
2
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)7p
2
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)7p
2
2
2
2
2
300
8270.96
o
)7s
6 p 5 ( 2 P3/2
o
6 p 5 ( 2 P3/2
)7p
2
300
8600.07
o
)7s
6 p 5 ( 2 P3/2
5 2 o
6 p ( P3/2)7p
2
2
关 3/2兴
关 1/2兴
A Ref
Energy Levels of Neutral Radon 共Rn I兲
Configuration
Term
6p6
1
o
)7s
6p 5 ( 2 P3/2
2
关 3/2兴
o
)7p
6 p 5 ( 2 P3/2
2
o
)7p
6 p 5 ( 2 P3/2
J
S
0
o
Level (cm⫺1 )
0.0
Ref
M58
2
1
54620.35
55989.03
M58
M58
关 1/2兴
1
0
66244.97
69743.98
M58
M58
2
关 5/2兴
2
3
66707.53
68039.48
M58
M58
o
)6d
6 p 5 ( 2 P3/2
2
关 1/2兴 o
0
1
67906.52
68891.34
M58
M58
o
)7p
6 p 5 ( 2 P3/2
2
关 3/2兴
1
2
68332.10
68789.93
M58
M58
o
)7s
6 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
85976
87053
M58
M58
86692.5
R33
o
)
Rn II ( 2 P3/2
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1962
J. E. SANSONETTI AND W. C. MARTIN
Rhenium „Re…
Atomic number⫽75
Atomic weight⫽186.207
Isotope
185
Re
Re
187
Mass
Abundance
Spin
Mag moment
184.952951
186.955744
37.40%
62.60%
5/2
5/2
⫹3.172
⫹3.2197
Re I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 5 6s 2 6S5/2
Ionization energy: 63 181.6 cm⫺1 共7.833 52 eV兲
Re II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 5 6s 7S3
Ionization energy: not available
Strong Lines of Rhenium 共Re兲
Intensity
Wavelength 共Å兲
800 P,c
500
300
500
80
200
200
50
600
250
70
90
60
1000
40
30
15
8
15
40
40
900
30
50
50
60
7
11
12
15
15
12
20
10
9
40
25
13
20
P
P
P
P
P
P
P
P
P
P,c
P,c
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1973.1340
Air
2003.53
2017.87
2049.08
2074.70
2085.59
2097.12
2109.22
2139.04
2142.74
2156.67
2167.94
2176.21
2214.2749
2214.58
2226.42
2235.44
2255.73
2256.19
2264.39
2274.62
2275.2532
2281.62
2287.51
2294.49
2298.09
2299.77
2302.99
2306.54
2322.49
2344.78
2352.07
2365.90
2367.68
2369.27
2370.76
2405.06
2405.60
2419.81
Spectrum
Ref
Re II
WJLG97
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
WJLG97
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
WJLG97
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
I
I
I
I
I
I
I
II
II
I
I
I
II
I
I
I
I
I
I
I
II
I
I
I
II
I
I
I
I
I
I
I
I
I
II
I
I
I
ATOMIC SPECTROSCOPIC DATA
1963
Strong Lines of Rhenium 共Re兲—Continued
Intensity
Wavelength 共Å兲
50
9
8
11
11
30
7
130 c
30
20
7
20
90 P
40
30 c
10
10
10
13 d
60
20
90 P
60
7
110 P
11 d
50
10
12
7
15
25
30
100 P
10
15
50
15 c
10
15 c
8
13
25
30
100 P
9
7
30
6
10
13
13
8
8
13
11
20
20
20 c
2428.58
2431.54
2432.18
2446.98
2449.71
2455.83
2461.20
2461.84
2467.57
2483.92
2485.81
2487.33
2502.35
2504.60
2508.99
2520.01
2521.50
2540.51
2544.74
2554.63
2556.51
2568.64
2571.81
2586.79
2608.50
2611.54
2635.83
2636.64
2651.90
2654.12
2674.34
2715.47
2731.56
2733.04
2783.57
2819.95
2887.68
2902.48
2909.82
2927.42
2943.14
2965.11
2965.76
2992.36
2999.60
3016.02
3030.45
3067.40
3069.94
3082.43
3100.67
3108.81
3128.94
3151.64
3168.37
3182.87
3184.76
3185.57
3204.25
Spectrum
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
I
I
I
I
I
II
I
II
II
I
I
I
II
II
I
I
I
I
I
II
I
II
II
I
II
I
II
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1964
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Rhenium 共Re兲—Continued
Intensity
7
11
11
50
11
40
30
15
50
70
12
12
15
150
7
300
1000
700
7
7
10
140
12
15
15
8
15
25
9
70
15
15
13
10
30
13
12
70
7
50
9
40
25
30
10
P
P
P,c
P,c
P,c
P,c
c
c
P
c
c,w
c,w
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3235.94
3258.85
3259.55
3303.21
3322.48
3338.18
3342.24
3344.32
3379.06
3399.30
3404.72
3405.89
3419.41
3424.62
3426.19
3451.88
3460.46
3464.73
3467.96
3480.38
3503.06
3580.15
3580.97
3583.02
3637.84
3651.97
3689.50
3691.48
3703.24
3725.76
3735.31
3740.10
3787.52
3929.85
4136.45
4144.36
4221.08
4227.46
4358.69
4513.31
4522.73
4889.14
5270.95
5275.56
5834.31
Spectrum
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
Re
I
I
I
II
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1965
Persistent Lines of Neutral Rhenium 共Re I兲
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
5
Term
J
Level (cm⫺1 )
Wl Ref
2
6
S
16o
5/2
3/2
0.00
49895.57
MCS75
500
2003.53
5d 6s
300
2017.87
5d 5 6s 2
6
S
15o
5/2
5/2
0.00
49540.96
MCS75
500
2049.08
5d 5 6s 2
6
S
14°
5/2
7/2
0.00
48786.35
MCS75
80
2074.70
5d 5 6s 2
6
S
13o
5/2
7/2
0.00
48184.20
MCS75
200
2085.59
5d 5 6s 2
5d 6 ( 5 D)6p
6
S
F
5/2
7/2
0.00
47932.55
MCS75
6 o
200
2097.12
5d 5 6s 2
6
S
12o
5/2
7/2
0.00
47669.01
MCS75
90
2167.94
5d 5 6s 2
6
5/2
5/2
0.00
46112.24
MCS75
100
2999.60
5d 6 ( 5 D)6s
5d 6 ( 5 D)6p
6
D
F
9/2
11/2
11754.52
45082.63
MCS75
S
11o
6 o
A Ref
70
3399.30
5d 6 ( 5 D)6s
6
D
10o
9/2
7/2
11754.52
41163.91
MCS75
150
3424.62
5d 6 ( 5 D)6s
5d 5 6s( 5 P)6p
6
D
Do
9/2
7/2
11754.52
40946.53
MCS75
S
P
5/2
3/2
0.00
28961.55
MCS75
FMW88
S
P
5/2
7/2
0.00
28889.72
MCS75
FMW88
S
P
5/2
5/2
0.00
28854.18
MCS75
FMW88
300
3451.88
1000
0.174
3460.46
700
0.313
3464.73
0.249
5d 5 6s 2
5d 5 6s( 7 S)6p
5d 5 6s 2
5d 5 6s( 7 S)6p
5d 5 6s 2
5d 5 6s( 7 S)6p
6
6
6 o
6
6 o
6
6 o
Energy Levels of Neutral Rhenium 共Re I兲
Configuration
5
Term
2
6
5d 5 6s 2
5d 6s
S
J
Level (cm⫺1 )
Ref
5/2
0.00
KMVC57
1
5/2
11583.96
KMVC57
5d 6 ( 5 D)6s
6
9/2
7/2
5/2
3/2
1/2
11754.52
14216.86
15770.42
16327.51
17238.30
KMVC57
KMVC57
KMVC57
KMVC57
KMVC57
5d 5 6s 2
2
3/2
13826.12
KMVC57
5d 5 6s 2
3
5/2
14621.46
KMVC57
5d 5 6s 2
4
7/2
11/2
9/2
15058.19
16307.15
16619.28
KMVC57
KMVC57
KMVC57
5d 5 6s 2
4
1/2
15165.89
KMVC57
D
G
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1966
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Rhenium 共Re I兲—Continued
J
Level (cm⫺1 )
Ref
5
7/2
17330.82
KMVC57
5d 5 6s( 7 S)6p
8 o
5/2
7/2
9/2
18950.1
20447.8
23631.82
KMVC57
KMVC57
KMVC57
5d 5 6s 2
6
5/2
19457.89
KMVC57
5d 5 6s 2
7
1/2
19757.91
KMVC57
5d 5 6s 2
8
3/2
20481.73
KMVC57
5d 5 6s( 7 S)6p
6 o
5/2
7/2
3/2
28854.18
28889.72
28961.55
KMVC57
KMVC57
KMVC57
5d 5 6s( 5 P)6p
6
Do
7/2
40946.53
KMVC57
o
10
7/2
41163.91
KMVC57
6 o
F
11/2
45082.63
KMVC57
11o
5/2
46112.24
KMVC57
12o
7/2
47669.01
KMVC57
6 o
F
7/2
47932.55
KMVC57
13o
7/2
48184.20
KMVC57
14o
7/2
48786.35
KMVC57
15o
5/2
49540.96
KMVC57
o
3/2
49895.57
KMVC57
Limit
63181.6
CS96
Configuration
5
5d 6s
Term
2
P
P
5d 6 ( 5 D)6p
6 5
5d ( D)6p
16
Re II ( 7 S3 )
Persistent Lines of Singly-ionized Rhenium 共Re II兲
Inten
800 c
1000 c
900 c
Wavelength 共Å兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
5d ( S)6s
5d 4 6s( 6 D)6p
7
S
P
3
4
0.000
50680.795
WJLG97
5d 5 ( 6 S)6s
5d 4 6s( 6 D)6p
7
S
P
3
3
0.000
45147.445
WJLG97
5d 5 ( 6 S)6s
5d 4 6s( 6 D)6p
7
S
P
3
2
0.000
43937.578
WJLG97
5 6
1973.1340
2214.2749
2275.2532
Term
Configuration
1.34
7 o
7 o
7 o
90
2502.35
5d 5 ( 4 G)6s
5
G
12o
5
5
20976.4
60926.8
MCS75
90
2568.64
5d 6
5
D
11o
4
3
14882.6
53802.1
MCS75
110
2608.50
5d 5 ( 4 D)6s
2
10o
2
2
14352.2
52677.0
MCS75
100
2733.04
5d 5 ( 6 S)6s
5
S
11o
2
3
17223.5
53802.1
MCS75
140
3580.15
5d 5 ( 6 S)6s
5d 4 6s( 6 D)6p
5
2
3
17223.5
45147.5
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
S
P
7 o
A Ref
WJLG97
ATOMIC SPECTROSCOPIC DATA
1967
Energy Levels of Singly-ionized Rhenium 共Re II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
5d ( S)6s
7
3
5d 4 6s 2
1
0
13777.3
MCS58
5d 5 ( 4 D)6s
2
2
14352.2
MCS58
5d 5 ( 4 D)6s
3
1
14824.0
MCS58
5
4
14882.6
MCS58
5d 5 ( 4 D)6s
4
3
14930.5
MCS58
5d 5 ( 6 S)6s
5
S
2
17223.5
MCS58
5d ( G)6s
5
G
2
3
4
6
5
18845.8
19139.7
20463.2
20781.5
20976.4
MCS58
MCS58
MCS58
MCS58
MCS58
5d 4 6s( 6 D)6p
7 o
P
2
3
4
43937.578
45147.445
50680.795
WJLG97
WJLG97
WJLG97
10o
2
52677.0
MCS58
11o
3
53802.1
MCS58
o
5
60926.8
MCS58
5 6
5d
6
5 4
S
D
12
Re III ( 6 S5/2)
0.000
WJLG97
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1968
J. E. SANSONETTI AND W. C. MARTIN
Rhodium „Rh…
Atomic number⫽45
Atomic weight⫽102.905 50
Isotope
103
Rh
Mass
Abundance
Spin
Mag moment
102.905500
100%
1/2
⫺0.0884
Rh I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 8 5s 4F9/2
Ionization energy: 60 160.1 cm⫺1 共7.458 90 eV兲
Rh II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 8 3F4
Ionization energy: 145 800 cm⫺1 共18.08 eV兲
Strong Lines of Rhodium 共Rh兲
Intensity
1000
400
1000
400
400
40
800
30
30
25
300
25
40
400
400
40
20
500
40
60
25
40
40
400
20
15
20
30
15
300
20
25
15
50
20
25
50
20
60
60
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1604.45
1624.47
1628.94
1634.72
1637.88
Air
2322.58
2334.77
2361.92
2382.89
2383.40
2415.84
2429.52
2440.34
2461.03
2490.79
2509.70
2515.75
2520.52
2545.70
2555.36
2625.88
2652.66
2703.73
2715.27
2718.54
2728.94
2826.68
2862.94
2907.21
2910.15
2924.02
2968.66
2977.68
2986.20
3083.96
3123.70
3191.19
3197.13
3263.14
3271.61
Spectrum
Ref
Rh
Rh
Rh
Rh
Rh
II
II
II
II
II
S58
S58
S58
S58
S58
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
I
II
I
I
I
II
I
I
II
II
I
I
II
I
I
I
I
I
II
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
MCS75
S58
MCS75
MCS75
MCS75
S58
MCS75
MCS75
S58
S58
MCS75
MCS75
S58
MCS75
MCS75
MCS75
MCS75
MCS75
S58
MCS75
MCS75
MCS75
MCS75
MCS75
S58
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1969
Strong Lines of Rhodium 共Rh兲—Continued
Intensity
250
250
30
20
30
400
40
30
40
120
600
90
15
90
40
900
150
40
20
25
600
20
500
500
200
130
600
300
900
90
30
130
200
25
130
500
500
600
30
300
25
20
200
30
40
900
30
140
20
60
200
1000
100
30
40
800
100
70
40
P
P
P
P
P
P
d
P
P
P
Wavelength 共Å兲
3280.55
3283.57
3289.14
3294.28
3300.46
3323.09
3338.54
3360.80
3368.38
3372.25
3396.82
3399.70
3406.55
3412.27
3421.22
3434.89
3440.53
3455.22
3457.07
3457.93
3462.04
3469.62
3470.66
3474.78
3478.91
3498.73
3502.52
3507.32
3528.02
3538.14
3541.91
3543.95
3549.54
3564.13
3570.18
3583.10
3596.19
3597.15
3605.86
3612.47
3614.78
3620.46
3626.59
3639.51
3654.87
3657.99
3661.86
3666.22
3666.91
3681.04
3690.70
3692.36
3695.52
3698.26
3698.60
3700.91
3713.02
3735.28
3737.27
Spectrum
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1970
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Rhodium 共Rh兲—Continued
Intensity
Wavelength 共Å兲
40
130
25
40
50
110
250
50
40
110
140
400
500
80
140
50
80
140
400
250
200
600
50
40
25
200
60
400
40
25
25
40
60
120
150
200
25
40
400
90
400 P
15
14
15
14
3744.17
3748.22
3754.12
3754.27
3755.58
3760.40
3765.08
3769.97
3778.13
3788.47
3792.18
3793.22
3799.31
3805.92
3806.76
3815.01
3816.47
3818.19
3822.26
3828.48
3833.89
3856.52
3870.01
3877.34
3922.19
3934.23
3942.72
3958.86
3975.31
3984.40
3995.61
3996.15
4082.78
4121.68
4128.87
4135.27
4154.37
4196.50
4211.14
4288.71
4374.80
4675.03
5354.40
5599.42
5983.60
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
Rh
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
1971
Persistent Lines of Neutral Rhodium 共Rh I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
8 3
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
4
400
3323.09
0.63
4d ( F)5s
4d 8 ( 3 F)5p
a F
z 2Go
7/2
9/2
1529.97
31613.78
MCS75
DL85
600
3396.82
0.65
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Fo
9/2
9/2
0.00
29430.86
MCS75
DL85
900
3434.89
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Go
9/2
11/2
0.00
29104.71
MCS75
600
3502.52
0.43
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Go
9/2
9/2
0.00
28542.69
MCS75
DL85
300
3507.32
0.34
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Go
5/2
7/2
2598.03
31101.75
MCS75
DL85
900
3528.02
0.85
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Fo
7/2
7/2
1529.97
29866.34
MCS75
DL85
900
3657.99
0.88
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Do
7/2
5/2
1529.97
28859.64
MCS75
DL85
1000
3692.36
0.91
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Do
9/2
7/2
0.00
27075.26
MCS75
DL85
800
3700.91
0.39
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 4F
z 4Go
7/2
9/2
1529.97
28542.69
MCS75
DL85
400
4374.80
0.164
4d 8 ( 3 F)5s
4d 8 ( 3 F)5p
a 2F
z 4Go
7/2
9/2
5690.97
28542.69
MCS75
DL85
Energy Levels of Neutral Rhodium 共Rh I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4d 8 ( 3 F)5s
a 4F
9/2
7/2
5/2
3/2
0.00
1529.97
2598.03
3472.68
M58
M58
M58
M58
4d 9
a 2D
5/2
3/2
3309.86
5657.97
M58
M58
4d 8 ( 3 F)5s
a 2F
7/2
5/2
5690.97
7791.23
M58
M58
4d 8 ( 3 F)5p
z 4Do
7/2
5/2
3/2
1/2
27075.26
28859.64
30397.27
31146.68
M58
M58
M58
M58
4d 8 ( 3 F)5p
z 4Go
9/2
11/2
7/2
5/2
28542.69
29104.71
31101.75
32243.32
M58
M58
M58
M58
4d 8 ( 3 F)5p
z 4Fo
9/2
7/2
5/2
3/2
29430.86
29866.34
31474.50
32277.43
M58
M58
M58
M58
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1972
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Rhodium 共Rh I兲—Continued
Configuration
Term
8 3
2
4d ( F)5p
o
z G
Rh II ( 3 F4 )
J
Level (cm⫺1 )
9/2
7/2
31613.78
33043.91
M58
M58
Limit
60160.1
CHR88a
Ref
Persistent Lines of Singly-ionized Rhodium 共Rh II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
8
Term
J
Level (cm⫺1 )
3
Wl Ref
1000
1604.45
4d
4d 7 ( 4 F)5p
a F
z 3Fo
4
4
0.0
62326.1
S58
400
1624.47
4d 8
4d 7 ( 4 F)5p
a 3F
z 3Go
3
4
2401.3
63959.5
S58
1000
1628.94
4d 8
4d 7 ( 4 F)5p
a 3F
z 3Fo
2
2
3580.7
64970.4
S58
400
1634.72
4d 8
4d 7 ( 4 F)5p
a 3F
z 5Go
4
4
0.0
61173.1
S58
400
1637.88
4d 8
4d 7 ( 4 F)5p
a 3F
z 3Fo
3
3
2401.3
63454.9
S58
800
2334.77
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
a 5F
z 5Go
5
6
16884.8
59702.4
S58
300
2415.84
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
a 5F
z 5Go
3
4
19792.4
61173.1
S58
400
2461.03
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
a 5F
z 5Do
4
4
18540.4
59161.5
S58
400
2490.79
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
a 5F
z 5Fo
5
5
16884.8
57020.8
S58
500
2520.52
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
a 5F
z 5Fo
5
4
16884.8
56547.3
S58
400
2715.27
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
b 3F
z 3Go
4
5
25376.9
62194.4
S58
300
2910.15
4d 7 ( 4 F)5s
4d 7 ( 4 F)5p
b 3F
z 5Go
4
5
25376.9
59729.4
S58
A Ref
Energy Levels of Singly-ionized Rhodium 共Rh II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
4d 8
a 3F
4
3
2
0.0
2401.3
3580.7
S58
S58
S58
4d 8
a 3P
2
1
0
8164.4
10515.0
10760.8
S58
S58
S58
4d 8
a 1D
2
11643.7
S58
4d 8
a 1G
4
14855.4
S58
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1973
Energy Levels of Singly-ionized Rhodium 共Rh II兲—Continued
Term
J
Level (cm⫺1 )
4d ( F)5s
5
a F
5
4
3
2
1
16884.8
18540.4
19792.4
20646.9
21180.0
S58
S58
S58
S58
S58
4d 7 ( 4 F)5s
b 3F
4
3
2
25376.9
27439.4
28834.6
S58
S58
S58
4d 7 ( 4 F)5p
z 5Fo
4
5
3
2
1
56547.3
57020.8
58358.5
59698.6
60573.2
S58
S58
S58
S58
S58
4d 7 ( 4 F)5p
z 5Do
4
3
2
1
0
59161.5
60448.4
61355.9
61881.1
62012.5
S58
S58
S58
S58
S58
4d 7 ( 4 F)5p
z 5Go
6
5
4
3
2
59702.4
59729.4
61173.1
61939.8
62288.3
S58
S58
S58
S58
S58
4d 7 ( 4 F)5p
z 3Go
5
4
3
62194.4
63959.5
65321.2
S58
S58
S58
4d 7 ( 4 F)5p
z 3Fo
4
3
2
62326.1
63454.9
64970.4
S58
S58
S58
Configuration
7 4
Rh III ( 4 F9/2)
Limit
145800
Ref
M58
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1974
J. E. SANSONETTI AND W. C. MARTIN
Rubidium „Rb…
Atomic number⫽37
Atomic weight⫽85.4678
Isotope
85
87
Rb
Rb
Mass
Abundance
Spin
Mag moment
84.911794
86.909187
72.17%
27.83%
5/2
3/2
⫹1.35302
⫹2.7512
Rb I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 5s 2S1/2
Ionization energy: 33 690.81 cm⫺1 共4.177 128 eV兲
Rb II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 1S0
Ionization energy: 220 105.0 cm⫺1 共27.2895 eV兲
Strong Lines of Rubidium 共Rb兲
Intensity
2
3
30 P
15
30 P
70 P
110 P
11
60
20
11
110
11
11
300
110
60
20
20
600
20
11
11
11
11
60 c
13
1
20
15
13
1
1
13
11
15
30
30 l
11
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
513.266
530.173
589.419
643.878
697.049
711.187
741.456
1604.12
1760.50
Air
2068.92
2071.50
2075.95
2090.29
2125.25
2143.83
2217.08
2291.71
2333.39
2385.34
2472.20
2496.38
2524.24
2684.10
2711.76
3051.36
3148.90
3161.00
3227.98
3270.99
3321.49
3340.55
3348.72
3350.82
3393.03
3434.18
3461.50
3521.39
3531.55
3541.15
Spectrum
Ref
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
II
II
II
II
II
II
II
II
II
R75
R75
R75
R75
R75
R75
R75
R75
R75
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
I
I
II
II
II
II
II
II
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
RE80
R75
R75
R75
RE80
RE80
R75
R75
R75
R75
R75
R75
ATOMIC SPECTROSCOPIC DATA
1975
Strong Lines of Rubidium 共Rb兲—Continued
Intensity
Wavelength 共Å兲
1
60
110
11 c
30 c
40
30
11
30 l
300 P
11 c
20
30 c
20 c
20 c
40
11 P
6P
1000 P
150
30 c
15
11
30
11
30
200
30 c
110
11
11
300 P
60 c
15 c
110 P
1
60
60 c
30 d
1
1
11 c
1c
1c
110 P
11
60
30 l
1l
2
2l
3
1
1000 c,P
500 c,P
20
11
20 c
1
3587.05
3600.60
3600.64
3662.74
3699.58
3796.81
3801.90
3826.66
3926.44
3940.51
3978.15
4029.49
4083.88
4104.28
4136.11
4193.08
4201.80
4215.53
4244.40
4273.14
4287.97
4293.97
4346.96
4377.12
4469.47
4530.34
4571.77
4622.42
4648.57
4730.45
4755.30
4775.95
4782.83
4885.59
5152.08
5431.532
5522.78
5635.99
5699.15
5724.121
6070.755
6199.08
6206.309
6298.325
6458.33
6555.62
6560.81
6775.07
7279.997
7408.173
7618.933
7757.651
7759.436
7800.27
7947.60
8603.96
9479.32
9689.05
13235.17
Spectrum
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
Rb
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
I
I
II
I
I
II
II
II
II
I
I
I
I
I
I
I
II
II
II
I
Ref
RE80
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
RE80
RE80
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
R75
B59
R75
R75
R75
B59
B59
R75
B59
B59
R75
R75
R75
R75
B59
B59
B59
B59
B59
J61b
J61b
R75
R75
R75
J61b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1976
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Rubidium 共Rb兲—Continued
Intensity
Wavelength 共Å兲
1
11 P
9P
2
13665.01
14752.41
15288.43
15289.48
Spectrum
Rb
Rb
Rb
Rb
Ref
I
I
I
I
J61b
J61b
J61b
J61b
Persistent Lines of Neutral Rubidium 共Rb I兲
Inten
Wavelength 共Å兲
11
4201.80
6
4215.53
1000
7800.27
500
7947.60
11
A ki (108 s⫺1 )
0.018
0.015
0.370
0.340
14752.41
9
15288.43
J
Level (cm⫺1 )
S
P
1/2
3/2
S
P
Configuration
Term
5s
6p
2
Wl Ref
A Ref
0.000
23792.591
RE80
FW96
5s
6p
2
1/2
1/2
0.000
23715.081
RE80
FW96
5s
5p
2
S
P
1/2
3/2
0.000
12816.545
J61b
FW96
5s
5p
2
S
P
1/2
1/2
0.000
12578.950
J61b
FW96
5p
4d
2 o
P
D
1/2
3/2
12578.950
19355.649
J61b
5p
4d
2 o
3/2
3/2
12816.545
19355.649
J61b
2 o
2 o
2 o
2 o
2
2
P
D
Energy Levels of Neutral Rubidium 共Rb I兲
Level (cm⫺1 )
Configuration
Term
J
5s
2
S
1/2
0.000
J61b
5p
2 o
P
1/2
3/2
12578.950
12816.545
J61b
J61b
4d
2
D
5/2
3/2
19355.203
19355.649
J61b
J61b
6s
2
S
1/2
20132.510
J61b
6p
2 o
1/2
3/2
23715.081
23792.591
J61b
J61b
Limit
33690.81
J61b
P
Rb II ( 1 S0 )
Ref
Persistent Lines of Singly-ionized Rubidium 共Rb II兲
Inten
Wavelength 共Å兲
30
589.419
30
70
110
A ki (108 s⫺1 )
697.049
711.187
741.456
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
4p 6
4 p 5 4d
1
4p 6
4 p 5 4d
1
4p 6
o
)5s
4 p 5 ( 2 P1/2
1
4p 6
o
)5s
4 p 5 ( 2 P3/2
1
Term
J
Level (cm⫺1 )
S
P
0
1
0.00
169658.536
R75
S
P
0
1
0.00
143461.977
R75
S
关 1/2兴 o
0
1
0.00
140610.047
R75
S
关 3/2兴 o
0
1
0.00
134869.751
R75
1 o
3 o
2
2
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
1977
Persistent Lines of Singly-ionized Rubidium 共Rb II兲—Continued
Inten
Wavelength 共Å兲
300
1000
11
110
110
A ki (108 s⫺1 )
3940.51
4244.40
4755.30
5152.08
6458.33
Configuration
Term
o
)5s
4 p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5s
4p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5p
4p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)6s
2
o
)5s
4p 5 ( 2 P3/2
5 2 o
4 p ( P3/2)5p
2
o
)5s
4p 5 ( 2 P1/2
o
4 p 5 ( 2 P3/2
)5p
2
关 3/2兴
关 3/2兴
J
Level (cm⫺1 )
Wl Ref
o
2
2
133341.607
158711.854
R75
关 3/2兴 o
关 5/2兴
2
3
133341.607
156895.486
R75
关 3/2兴
关 3/2兴 o
2
2
158711.854
179735.123
R75
关 3/2兴 o
关 1/2兴
1
1
134869.751
154273.980
R75
关 1/2兴 o
2
关 1/2兴
0
1
138794.380
154273.980
R75
2
2
2
2
A Ref
Energy Levels of Singly-ionized Rubidium 共Rb II兲
Configuration
Term
J
S
0
Level (cm⫺1 )
Ref
4p6
1
o
)5s
4 p 5 ( 2 P3/2
2
关 3/2兴
o
2
1
133341.607
134869.751
R75
R75
o
)5s
4p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
138794.380
140610.047
R75
R75
4p 5 4d
3 o
P
0
1
2
143022.335
143461.977
143955.871
R75
R75
R75
o
)5p
4p 5 ( 2 P3/2
2
关 1/2兴
1
0
154273.980
161200.171
R75
R75
o
)5p
4p 5 ( 2 P3/2
2
关 5/2兴
2
3
156737.011
156895.486
R75
R75
o
)5p
4p 5 ( 2 P3/2
2
关 3/2兴
1
2
158151.666
158711.854
R75
R75
o
)5p
4p 5 ( 2 P1/2
2
关 3/2兴
1
2
163924.55
164968.007
R75
R75
o
)5p
4p 5 ( 2 P1/2
2
关 1/2兴
1
0
165089.580
167632.436
R75
R75
4p 5 4d
1 o
1
169658.536
R75
o
)6s
4p 5 ( 2 P3/2
2
2
1
179735.123
180168.372
R75
R75
220105.0
R75
o
)
Rb III ( 2 P3/2
P
关 3/2兴
o
Limit
0.00
R75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1978
J. E. SANSONETTI AND W. C. MARTIN
Ruthenium „Ru…
Atomic number⫽44
Atomic weight⫽101.07
Isotope
96
Ru
Ru
99
Ru
100
Ru
101
Ru
102
Ru
104
Ru
98
Mass
Abundance
Spin
95.907599
97.905287
98.905939
99.904219
100.905582
101.904348
103.905424
5.53%
1.87%
12.7%
12.6%
17.1%
31.6%
18.6%
0
0
5/2
0
5/2
0
0
Mag moment
⫺6.413
⫺0.7188
Ru I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 7 5s 5F5
Ionization energy: 59 366.4 cm⫺1 共7.360 50 eV兲
Ru II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 7 4F9/2
Ionization energy: 135 200 cm⫺1 共16.76 eV兲
Strong Lines of Ruthenium 共Ru兲
Intensity
600
600
600
250
250
250
200
250
200
60
70
70
40
200
1000
250
200
500
400
200
200
300
50
30
80
40
40
400
900
400
250
60
400
150
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1875.564
1888.043
1903.221
1916.816
1939.043
1939.505
Air
2076.43
2083.78
2090.22
2255.53
2272.091
2279.582
2317.784
2357.916
2402.72
2455.531
2456.438
2456.57
2478.93
2498.42
2498.57
2507.01
2549.56
2609.062
2612.06
2642.946
2659.617
2661.61
2678.76
2692.06
2712.41
2719.51
2734.35
2735.727
Spectrum
Ref.
Ru
Ru
Ru
Ru
Ru
Ru
II
II
II
II
II
II
CHR88a
JJLL94
JJLL94
JJLL94
JJLL94
JJLL94
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
I
I
I
I
I
II
II
II
II
I
II
I
K59
K59
K59
K59
K59
K59
K59
JJLL94
MCS75
JJ93
JJLL94
MCS75
MCS75
MCS75
MCS75
MCS75
K59
K59
K59
K59
K59
MCS75
MCS75
MCS75
MCS75
K59
MCS75
K59
ATOMIC SPECTROSCOPIC DATA
1979
Strong Lines of Ruthenium 共Ru兲—Continued
Intensity
150
40
60
40
50
150
70
30
100
250
30
50
200
200
50
130
40
40
40
30
80
70
40
30
80
30
30
300
400
40
600
800
60
70
60
40
600
600
600
120
30
300
600
80
60
40
50
800
1000
600
40
300
80
40
250
70
80
110
30
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
2810.551
2829.149
2854.075
2861.408
2866.653
2874.984
2886.528
2908.883
2916.251
2945.67
2949.492
2965.166
2965.55
2976.584
2976.923
2988.945
2994.967
3006.588
3064.834
3096.565
3099.284
3100.836
3294.109
3301.593
3339.555
3368.455
3392.533
3417.332
3428.319
3430.764
3436.737
3498.944
3514.491
3539.368
3570.606
3587.204
3589.220
3593.029
3596.185
3599.769
3626.740
3634.931
3661.364
3663.378
3669.546
3716.998
3726.096
3726.926
3728.026
3730.432
3739.470
3742.287
3742.798
3744.396
3745.592
3753.546
3755.937
3759.838
3760.019
Spectrum
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
I
I
I
I
I
I
I
I
I
II
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
K59
K59
K59
K59
K59
K59
K59
K59
K59
MCS75
K59
K59
MCS75
JJLL94
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1980
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Ruthenium 共Ru兲—Continued
Intensity
Wavelength 共Å兲
50
50
140
40
50
400
500
70
700 P
700 P
50
70
70
60
50
70
80
40
70
40
120
60
120
60
70
140
300
50
70
40
50
50
80
140
50
130
60
30
70
90
500
80
150
200
60
80
50
50
700 P
140
500
70
80
30
50
70
70
30
70
3761.511
3767.353
3777.588
3781.171
3782.749
3786.065
3790.521
3798.054
3798.899
3799.353
3812.739
3817.293
3819.039
3822.091
3824.938
3831.795
3839.699
3846.672
3850.441
3856.458
3857.551
3862.690
3867.844
3892.230
3909.085
3923.486
3925.930
3931.787
3945.586
3950.230
3978.449
3979.420
3984.862
4022.168
4023.832
4051.402
4054.050
4064.456
4068.367
4076.730
4080.599
4097.787
4112.741
4144.160
4145.737
4167.514
4197.572
4198.864
4199.892
4206.020
4212.062
4214.445
4217.263
4220.675
4230.309
4241.058
4243.058
4246.736
4284.330
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
ATOMIC SPECTROSCOPIC DATA
1981
Strong Lines of Ruthenium 共Ru兲—Continued
Wavelength 共Å兲
Intensity
50
300
80
30
50
50
60
80
200
80
120
150
150
40
40
100
500
150
70
130
50
50
40
40
50
50
80
25
Spectrum
4295.932
4297.714
4307.604
4318.441
4319.871
4342.073
4354.130
4361.204
4372.200
4385.393
4385.650
4390.440
4410.028
4439.745
4449.322
4460.031
4554.514
4584.440
4647.594
4709.482
4757.844
4869.163
4903.066
5057.340
5136.558
5155.140
5171.026
5636.233
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ref.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
K59
Persistent Lines of Neutral Ruthenium 共Ru I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
600
3436.737
0.728
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Go
4
5
1190.64
30279.68
K59
WSL94
800
3498.944
0.861
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Go
5
6
0.00
28571.89
K59
WSL94
600
3589.220
0.911
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Go
1
2
3105.49
30958.80
K59
WSL94
600
3593.029
0.817
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Go
2
3
2713.24
30537.06
K59
WSL94
600
3596.185
0.420
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 3Go
3
4
2091.54
29890.91
K59
WSL94
800
3726.926
0.753
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Fo
4
4
1190.64
28014.79
K59
WSL94
1000
3728.026
0.820
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Fo
5
5
0.00
26816.23
K59
WSL94
600
3730.432
0.706
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Fo
3
3
2091.54
28890.47
K59
WSL94
700
3798.899
0.598
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 5F
z 5Do
4
3
1190.64
27506.59
K59
WSL94
Wl Ref
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1982
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Ruthenium 共Ru I兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
7
4
Term
J
Level (cm⫺1 )
5
Wl Ref
A Ref
700
3799.353
0.533
4d (a F)5s
4d 7 (a 4 F)5p
a F
z 5Do
5
4
0.00
26312.83
K59
WSL94
700
4199.892
0.399
4d 7 (a 4 F)5s
4d 7 (a 4 F)5p
a 3F
z 3Fo
4
4
6545.03
30348.45
K59
WSL94
Energy Levels of Neutral Ruthenium 共Ru I兲
Term
J
Level (cm⫺1 )
4d (a F)5s
5
a F
5
4
3
2
1
0.00
1190.64
2091.54
2713.24
3105.49
M58
M58
M58
M58
M58
4d 7 (a 4 F)5s
a 3F
4
3
2
6545.03
8084.12
9183.66
M58
M58
M58
4d 6 5s 2
a 5D
4
3
2
1
0
7483.07
8575.42
9057.64
9072.98
9492.37
M58
M58
M58
M58
M58
4d 7 (a 4 P)5s
a 5P
2
3
1
8043.69
8770.93
9620.29
M58
M58
M58
4d 7 (a 4 F)5p
z 5Do
4
3
2
1
0
26312.83
27506.59
28465.69
29118.49
29569.90
M58
M58
M58
M58
M58
4d 7 (a 4 F)5p
z 5Fo
5
4
3
2
1
26816.23
28014.79
28890.47
29427.32
29693.57
M58
M58
M58
M58
M58
4d 7 (a 4 F)5p
z 3Go
5
4
3
28495.10
29890.91
31852.90
M58
M58
M58
4d 7 (a 4 F)5p
z 5Go
6
5
3
2
4
28571.89
30279.68
30537.06
30958.80
31345.79
M58
M58
M58
M58
M58
4d 7 (a 4 F)5p
z 3Fo
4
3
2
30348.45
32391.95
33172.02
M58
M58
M58
Limit
59366.4
CHR88a
Configuration
7
4
Ru II ( 4 F9/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
1983
Persistent Lines of Singly-ionized Ruthenium 共Ru II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
4d
4d 6 ( 5 D)5p
4
a F
z 4Do
9/2
7/2
0.0
53317.1
SM58
Configuration
7
Wl Ref
A Ref
600
1875.564
600
1888.045
0.548
4d 7
4d 6 ( 5 D)5p
a 4F
z 4Fo
9/2
9/2
0.0
52964.4
SM58
JJLL94
600
1903.227
1.00
4d 7
4d 6 ( 5 D)5p
a 4F
z 4Do
7/2
5/2
1523.1
54065.4
SM58
JJLL94
250
1916.829
1.14
4d 7
4d 6 ( 5 D)5p
a 4F
z 4Do
5/2
3/2
2493.9
54663.4
SM58
JJLL94
250
1939.043
0.497
4d 7
4d 6 ( 5 D)5p
a 4F
z 4Do
5/2
5/2
2493.9
54065.4
JJ93
JJLL94
250
1939.505
0.665
4d 7
4d 6 ( 5 D)5p
a 4F
z 4Do
3/2
3/2
3104.2
54663.4
JJ93
JJLL94
200
2357.916
0.84
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Po
9/2
7/2
9151.4
51548.8
JJLL94
JJLL94
1000
2402.72
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Fo
9/2
11/2
9151.4
50758.3
MCS75
200
2456.438
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Po
5/2
7/2
10851.7
51548.8
JJLL94
500
2456.57
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Fo
7/2
9/2
10150.4
50845.3
MCS75
400
2478.93
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Fo
5/2
5/2
10851.7
51179.7
MCS75
300
2507.01
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Fo
3/2
5/2
11303.8
51179.7
MCS75
400
2661.61
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
9/2
7/2
9151.4
46711.5
MCS75
900
2678.76
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
9/2
9/2
9151.4
46471.0
MCS75
250
2712.41
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
5/2
3/2
10851.7
47708.6
MCS75
400
2734.35
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
7/2
7/2
10150.4
46711.5
MCS75
200
2976.584
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 4D
z 4Fo
7/2
9/2
19378.7
52964.4
JJLL94
1.59
1.08
JJLL94
JJLL94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1984
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Ruthenium 共Ru II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
7
4
a F
9/2
7/2
5/2
3/2
0.0
1523.1
2493.9
3104.2
SM58
SM58
SM58
SM58
4d 7
a 4P
5/2
3/2
1/2
8256.7
8477.7
9373.9
SM58
SM58
SM58
4d 6 ( 5 D)5s
a 6D
9/2
7/2
5/2
3/2
1/2
9151.4
10150.4
10851.7
11303.8
11604.0
SM58
SM58
SM58
SM58
SM58
4d 6 ( 5 D)5s
a 4D
7/2
5/2
3/2
1/2
19378.7
20515.0
21246.4
21645.6
SM58
SM58
SM58
SM58
4d 6 ( 5 D)5p
z 6Do
9/2
7/2
5/2
3/2
1/2
46471.0
46711.5
47285.1
47708.6
47983.8
SM58
SM58
SM58
SM58
SM58
4d 6 ( 5 D)5p
z 6Fo
11/2
9/2
7/2
5/2
3/2
1/2
50758.3
50845.3
50862.5
51179.7
51317.0
51380.1
SM58
SM58
SM58
SM58
SM58
SM58
4d 6 ( 5 D)5p
z 6Po
7/2
5/2
3/2
51548.8
52820.3
53685.2
SM58
SM58
SM58
4d 6 ( 5 D)5p
z 4Fo
9/2
7/2
5/2
3/2
52964.4
54225.5
54794.3
55224.2
SM58
SM58
SM58
SM58
4d 6 ( 5 D)5p
z 4Do
7/2
5/2
3/2
1/2
53317.1
54065.4
54663.4
54981.5
SM58
SM58
SM58
SM58
4d
Ru III ( 5 D4 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
135200
SM58
ATOMIC SPECTROSCOPIC DATA
1985
Samarium „Sm…
Atomic number⫽62
Atomic weight⫽150.36
Isotope
144
Sm
Sm
148
Sm
149
Sm
150
Sm
152
Sm
154
Sm
147
Mass
Abundance
Spin
143.911998
146.914895
147.914820
148.917181
149.917273
151.919729
153.922206
3.1%
15.0%
11.3%
13.8%
7.4%
26.6%
22.6%
0
7/2
0
7/2
0
0
0
Mag moment
⫺0.813
⫺0.670
Sm I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 6 6s 2 7F0
Ionization energy: 45 519.6 cm⫺1 共5.6437 eV兲
Sm II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 6 6s 8F1/2
Ionization energy: 89 300 cm⫺1 共11.07 eV兲
Strong Lines of Samarium 共Sm兲
Intensity
200
400
200
200
300
200
300
300
200
1000
1000
400
800
400
200
200
800
500
500
250
200
200
200
400
500
400
200
700*
700*
200
300
600*
600*
200
500
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Air
3254.377
3306.388
3307.017
3310.661
3321.179
3340.579
3365.863
3382.399
3408.676
3568.271
3592.603
3604.285
3609.491
3621.229
3627.014
3631.126
3634.290
3661.365
3670.840
3693.989
3708.654
3718.877
3721.847
3728.469
3731.258
3735.980
3737.141
3739.117
3739.197
3741.288
3743.868
3745.465
3745.605
3755.276
3756.411
Spectrum
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
I
Ref
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1986
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Samarium 共Sm兲—Continued
Intensity
Wavelength 共Å兲
300
500
250
250*
250*
250
400
400
400
200
400
250
400
400
300
600
300
200
250
200
200
900
400
300
600
500
300
200
300
400*
400*
200
400
400
250
250
250
200
200
400*
400*
200
200
200
200
200
200
300*
300*
200
200
250
200*
200*
500
200
300
200
250
3757.529
3760.694
3764.370
3773.331
3773.422
3778.135
3788.125
3793.971
3797.730
3800.887
3826.202
3831.501
3834.476
3843.500
3853.295
3854.209
3854.556
3855.901
3858.737
3871.778
3880.766
3885.286
3896.977
3903.417
3922.397
3928.279
3941.874
3948.113
3951.887
3962.98
3963.03
3970.528
3971.397
3974.665
3976.270
3976.430
3979.200
3983.138
3986.682
3990.002
3990.025
3993.308
4023.231
4035.110
4042.723
4042.905
4047.160
4064.55
4064.57
4066.737
4075.845
4092.266
4107.277
4107.387
4118.551
4149.831
4152.209
4169.478
4188.128
d
d
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
II
II
II
I
II
II
II
II
II
II
II
II
I
II
I
II
I
II
I
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
RAVS90
RAVS90
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
RAVS90
RAVS90
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
ATOMIC SPECTROSCOPIC DATA
1987
Strong Lines of Samarium 共Sm兲—Continued
Intensity
250
200
250
200
300
500
300
300*
300*
500
400
300
1000
200
500
300
400
300
300
600
250
200
300
200
300
400
200
250
200*
200*
200
300
400
250
700
300
400
400
300
300
400
300
300
250
500
500
200
250
200
200
200
200
300
200
200
250
200
200
300
P
P
P
P
P
d
d
P
P
P
Wavelength 共Å兲
4203.051
4220.659
4225.328
4229.704
4236.745
4256.393
4262.677
4279.678
4279.747
4280.789
4282.208
4282.833
4296.743
4309.012
4318.936
4319.530
4329.016
4330.016
4334.153
4336.137
4347.801
4362.040
4362.912
4378.236
4380.423
4390.858
4397.341
4401.174
4403.06
4403.13
4411.585
4419.332
4420.526
4421.138
4424.339
4429.664
4433.885
4434.323
4441.812
4442.276
4445.153
4452.727
4454.629
4458.517
4467.342
4470.886
4478.657
4499.108
4519.633
4533.799
4543.948
4581.581
4581.729
4642.235
4645.405
4649.491
4663.556
4669.396
4670.747
Spectrum
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
II
II
II
II
II
II
II
II
II
II
I
I
I
II
II
I
II
I
II
I
II
II
I
II
I
II
I
I
II
I
I
I
II
II
II
I
II
II
I
I
I
II
II
II
II
I
II
I
II
I
II
I
I
II
I
I
I
II
I
Ref
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1988
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Samarium 共Sm兲—Continued
Wavelength 共Å兲
Intensity
250
250
500
500
500
400
200
600
500
400
250
250
300
300
200
300
250
Spectrum
4674.599
4688.733
4716.097
4728.423
4760.27
4783.103
4785.864
4841.701
4883.971
4910.400
4918.986
5044.279
5071.200
5117.162
5122.136
5175.419
5271.403
P
P
P
P
P
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
Sm
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
K35
Persistent Lines of Neutral Samarium 共Sm I兲
Inten
600*
400*
1000
600
Wavelength 共Å兲
A ki (108 s⫺1 )
3745.465
0.27
3990.025
4296.743
0.43
1.00
Configuration
4 f 6 6s 2
4 f 5 ( 6 Fo)5d6s 2
4 f 6 6s 2
4 f 5 ( 6 Fo)5d6s 2
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
4 f 6 6s 2
4336.137
Term
J
Level (cm⫺1 )
7
F
F
3
4
F
F
7
7
Wl Ref
A Ref
1489.55
28180.95
K35
M00
5
4
3125.46
28180.95
K35
M00
F
Go
6
7
4020.66
27287.58
K35
M00
F
5
6
3125.46
26180.92
K35
F
Go
0
1
0.00
22914.07
K35
7
7
F
4
4
2273.09
24633.75
K35
F
Do
5
5
3125.46
24323.51
K35
F
Do
3
3
1489.55
22632.30
K35
M00
F
Do
2
2
811.92
21813.22
K35
M00
7
7
F
6
5
4020.66
24668.79
K35
M00
F
Do
5
4
3125.46
23594.84
K35
7 o
7
7 o
7
o
300
500
500
500
500
600
500
4362.912
0.49
4 f 6 6s 2
4 f 5 ( 6 Fo)5d6s 2
4470.886
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
4716.097
4728.423
4760.27
4841.701
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
0.49
0.13
0.87
4883.971
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
4 f 6 6s 2
4 f 6 ( 7 F)6s6 p( 1 Po)
7
o
7
7
7
7
7
o
7
7
M00
ATOMIC SPECTROSCOPIC DATA
1989
Energy Levels of Neutral Samarium 共Sm I兲
Term
J
Level (cm⫺1 )
Ref
7
F
0
1
2
3
4
5
6
0.00
292.58
811.92
1489.55
2273.09
3125.46
4020.66
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)5d( 8 H)6s
9
H
1
2
3
4
5
6
7
8
9
10801.10
11044.90
11406.50
11877.50
12445.35
13095.75
13814.90
14591.70
15418.65
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)5d( 8 D)6s
9
D
2
3
4
5
6
12313.11
12846.64
13458.46
14202.85
15082.94
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)5d( 8 H)6s
7
H
2
3
4
5
6
7
8
13050.05
13542.80
14154.30
14856.20
15617.45
16392.93
17270.96
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)6s6p( 1 Po)
7
Do
1
2
3
4
5
21193.68
21813.22
22632.30
23594.84
24323.51
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)6s6p( 1 Po)
7
Go
1
22914.07
MZH78
4 f 5 ( 6 Fo)5d6s 2
o
4
24633.75
MZH78
o
5
24668.79
MZH78
o
6
26180.92
MZH78
0
1
2
3
4
5
6
—
26281.09
26786.80
27425.50
28180.95
29023.96
30092.53
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
7
27287.58
MZH78
Limit
45519.6
JRB00
Configuration
6
4 f 6s
2
6 7
1 o
4 f ( F)6s6p( P )
4 f 5 ( 6 Fo)5d6s 2
4 f 6 ( 7 F)6s6p( 1 Po)
Sm II ( 8 F1/2)
7 o
F
7
Go
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1990
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Samarium 共Sm II兲
Inten
Wavelength 共Å兲
1000
1000
800
800
250
700*
700*
A ki (108 s⫺1 )
3568.271
0.64
3592.603
0.66
3609.491
0.58
3634.290
0.56
3693.989
0.091
3739.117
0.17
3739.197
Configuration
6 7
J
Level (cm⫺1 )
F
13/2
15/2
F
Term
4 f ( F)6s
4 f 5 5d6s?
8
4 f 6 ( 7 F)6s
4 f 5 5d6s?
8
4 f 6 ( 7 F)6s
4 f 5 5d6s?
8
4 f 6 ( 7 F)6s
4 f 5 5d6s?
8
4 f 6 ( 7 F)6s
4 f 5 5d6s?
8
4 f 6 ( 7 F)6s
4 f 5 5d6s?
8
4 f 6 ( 7 F)6s
6
Wl Ref
A Ref
3909.62
31926.40
K35
M00
11/2
13/2
3052.65
30879.74
K35
M00
F
9/2
11/2
2237.97
29934.80
K35
M00
F
7/2
9/2
1489.16
28997.14
K35
M00
F
1/2
3/2
0.00
27063.30
K35
M00
F
3/2
3/2
326.64
27063.30
K35
M00
F
9/2
11/2
4386.03
31122.17
K35
o
o
o
o
o
o
o
600*
900
600
500
500
700
500
3745.605
0.066
3885.286
3922.397
4256.393
4280.789
4424.339
4467.342
4 f 6 ( 7 F)6s
4 f 5 5d6s?
8
F
Go
1/2
1/2
0.00
26690.30
K35
8
4 f 6 ( 7 F)6s
4 f 6 ( 7 F)6p?
8
F
13/2
13/2
3909.62
29640.51
K35
4 f 6 ( 7 F)6s
4 f 6 ( 7 F)6p
8
F
11/2
11/2
3052.65
28540.12
K35
4 f 6 ( 7 F)6s
4 f 5 5d6s
8
F
11/2
13/2
3052.65
26540.12
K35
4 f 6 ( 7 F)6s
4 f 5 5d6s
8
F
13/2
15/2
3909.62
27263.25
K35
4 f 6 ( 7 F)6s
4 f 6 ( 7 F)6p
8
F
13/2
11/2
3909.62
26505.53
K35
4 f 6 ( 7 F)6s
4 f 5 5d6s?
6
F
11/2
13/2
5317.56
27695.96
K35
o
o
o
o
o
o
M00
Energy Levels of Singly-ionized Samarium 共Sm II兲
J
Level (cm⫺1 )
Ref
F
1/2
3/2
5/2
7/2
9/2
11/2
13/2
0.00
326.64
838.22
1489.16
2237.97
3052.65
3909.62
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
F
1/2
3/2
5/2
7/2
9/2
11/2
1518.29
2003.23
2688.69
3499.12
4386.03
5317.56
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
Configuration
Term
4 f 6 ( 7 F)6s
8
4 f 6 ( 7 F)6s
6
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
1991
Energy Levels of Singly-ionized Samarium 共Sm II兲—Continued
Configuration
6 7
Term
J
Level (cm⫺1 )
Ref
4 f ( F)5d
8
H
3/2
5/2
7/2
9/2
11/2
13/2
15/2
17/2
7135.06
7524.86
8046.00
8679.23
9406.63
10214.38
11094.06
12045.10
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)5d
8
D
3/2
5/2
7/2
9/2
11/2
8578.70
9410.00
10180.70
10960.16
11791.05
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 6 ( 7 F)6p
o
11/2
26505.53
MZH78,RAVS90
4 f 5d6s
o
13/2
26540.12
MZH78,RAVS90
4 f 5 5d6s?
8
1/2
26690.30
MZH78
4 f 5 5d6s?
o
3/2
27063.30
MZH78
4 f 5 5d6s
o
15/2
27263.25
MZH78,RAVS90
4 f 5d6s?
o
13/2
27695.96
MZH78
4 f 6 ( 7 F)6p
o
11/2
28540.12
MZH78,RAVS90
4 f 5 5d6s?
o
9/2
28997.14
MZH78
4 f 6 ( 7 F)6p?
o
13/2
29640.51
MZH78
4 f 5d6s?
o
11/2
29934.80
MZH78
4 f 5 5d6s?
o
13/2
30879.74
MZH78
o
11/2
31122.17
MZH78
o
15/2
31926.40
MZH78
Limit
89300
SR65
5
5
5
4 f 5 5d6s?
7
Sm III ( F0 )
Go
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1992
J. E. SANSONETTI AND W. C. MARTIN
Scandium „Sc…
Atomic number⫽21
Atomic weight⫽44.955 910
Isotope
45
Sc
Mass
Abundance
Spin
Mag moment
44.955910
100%
7/2
⫹4.756
Sc I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d4s 2 2D3/2
Ionization energy: 52 922.0 cm⫺1 共6.561 49 eV兲
Sc II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d4s 3D1
Ionization energy: 103 237.1 cm⫺1 共12.799 77 eV兲
Strong Lines of Scandium 共Sc兲
Intensity
100
80
15
25
15
50
60
15
90
120
15
70
200
250
400
70
60
60
140
250
12
25
12
100
250
200
500
400
300
140
140
1000
700
500
250
200
900
1000
200
250
900
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2552.350
2560.232
2706.738
2711.341
2965.879
2974.010
2980.755
2988.965
3015.367
3019.349
3030.759
3255.676
3269.897
3273.628
3353.724
3359.668
3361.257
3361.926
3368.936
3372.150
3431.351
3435.541
3457.442
3535.713
3558.534
3567.702
3572.530
3576.340
3580.928
3589.633
3590.474
3613.831
3630.742
3642.782
3645.308
3651.798
3907.484
3911.812
3933.375
3996.601
4020.387
Spectrum
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
Ref
JL80
JL80
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
JL80
JL80
JL80
JL80
JL80
JL80
AV77
AV77
AV77
JL80
JL80
JL80
JL80
JL80
JL80
JL80
JL80
JL80
JL80
JL80
JL80
JL80
AV77
AV77
AV77
AV77
AV77
ATOMIC SPECTROSCOPIC DATA
1993
Strong Lines of Scandium 共Sc兲—Continued
Intensity
900
10
10
120
250
10
250
15
20
25
30
50
15
500
150
120
90
70
20
25
30
30
50
10
11
25
11
90
50
50
15
12
15
25
15
14
15
12
12
15
25
12
15
12
30
25
25
30
25
70
50
50
40
10
25
14
11
30
40
40
P
P
P
h
h
h
P
Wavelength 共Å兲
4023.678
4030.622
4043.803
4047.797
4054.544
4056.593
4082.387
4087.150
4132.984
4140.272
4152.341
4165.187
4238.053
4246.820
4314.082
4320.745
4324.998
4374.462
4729.209
4734.109
4737.647
4741.024
4743.821
4779.354
5064.306
5070.257
5075.820
5081.561
5083.721
5085.549
5087.123
5089.930
5096.721
5099.274
5101.119
5116.648
5210.547
5219.634
5258.364
5349.342
5356.097
5375.373
5392.058
5446.195
5482.012
5484.628
5514.230
5520.519
5526.785
5671.828
5686.856
5700.186
5711.793
5717.314
6210.66
6239.80
6258.90
6305.65
22052.1
22065.4
Spectrum
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
Ref
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
JL80
JL80
JL80
JL80
JL80
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
JL80
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
AV77
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1994
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Scandium 共Sc I兲
Inten
Wavelength 共Å兲
200
250
900
3269.897
3273.628
3907.484
1000
200
250
900
900
250
250
3911.812
3933.375
3996.601
4020.387
4023.678
4054.544
4082.387
A ki (108 s⫺1 )
Configuration
2
3.13
3d4s
3d4s( 3 D)4p
3d4s 2
3d4s( 3 D)4p
2.81
3d4s 2
3d4s( 3 D)4p
1.66
3d4s 2
3d4s( 3 D)4p
1.79
3d4s 2
3d4s( 3 D)4p
0.162
3d4s 2
3d4s( 3 D)4p
0.165
3d4s 2
3d4s( 3 D)4p
1.63
3d4s 2
3d4s( 3 D)4p
1.65
3d4s 2
3d4s( 1 D)4p
0.441
3d4s 2
3d4s( 1 D)4p
0.410
Term
2
D
P
2 o
2
D
P
2 o
2
D
F
2 o
2
D
F
2 o
2
D
F
2 o
2
2
D
Do
2
2
D
Do
2
2
D
Do
2
D
P
2 o
2
D
P
2 o
J
Level (cm⫺1 )
3/2
1/2
Wl Ref
A Ref
0.00
30573.17
AV77
FW96
5/2
3/2
168.34
30706.66
AV77
FW96
3/2
5/2
0.00
25584.64
AV77
FW96
5/2
7/2
168.34
25724.68
AV77
FW96
5/2
5/2
168.34
25584.64
AV77
FW96
3/2
5/2
0.00
25014.21
AV77
FW96
3/2
3/2
0.00
24866.17
AV77
FW96
5/2
5/2
168.34
25014.21
AV77
FW96
3/2
1/2
0.00
24656.72
AV77
M03
5/2
3/2
168.34
24656.88
AV77
M03
Energy Levels of Neutral Scandium 共Sc I兲
Term
3d4s 2
2
D
3/2
5/2
0.00
168.34
SC85
SC85
3d 2 ( 3 F)4s
4
F
3/2
5/2
7/2
9/2
11519.99
11557.69
11610.28
11677.38
SC85
SC85
SC85
SC85
3d 2 ( 3 F)4s
2
F
5/2
7/2
14926.07
15041.92
SC85
SC85
3d4s( 3 D)4p
4 o
F
3/2
5/2
7/2
9/2
15672.58
15756.57
15881.75
16026.62
SC85
SC85
SC85
SC85
3d4s( 3 D)4p
4
Do
1/2
3/2
5/2
7/2
16009.77
16021.82
16141.06
16210.85
SC85
SC85
SC85
SC85
3d4s( 1 D)4p
2
Do
5/2
3/2
16022.73
16096.90
SC85
SC85
3d4s( 3 D)4p
4 o
1/2
3/2
5/2
18504.06
18515.69
18571.41
SC85
SC85
SC85
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
Ref
ATOMIC SPECTROSCOPIC DATA
1995
Energy Levels of Neutral Scandium 共Sc I兲—Continued
J
Level (cm⫺1 )
Ref
4s 4p
2 o
P
1/2
3/2
18711.02
18855.74
SC85
SC85
3d4s( 1 D)4p
2 o
F
5/2
7/2
21032.75
21085.85
SC85
SC85
3d4s( 1 D)4p
2 o
P
1/2
3/2
24656.72
24656.88
SC85
SC85
3d4s( 3 D)4p
2
Do
3/2
5/2
24866.17
25014.21
SC85
SC85
3d4s( 3 D)4p
2 o
F
5/2
7/2
25584.64
25724.68
SC85
SC85
3d 2 ( 3 F)4p
4
Go
5/2
7/2
9/2
11/2
29022.82
29096.18
29189.84
29303.51
SC85
SC85
SC85
SC85
3d4s( 3 D)4p
2 o
1/2
3/2
30573.17
30706.66
SC85
SC85
Limit
52922.0
SC85
Configuration
Term
2
P
Sc II ( 3 D1 )
Persistent Lines of Singly-ionized Scandium 共Sc II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
400
3353.724
1.51
250
500
400
300
1000
700
500
500
3372.150
3572.530
3576.340
3580.928
3613.831
3630.742
3642.782
4246.820
0.99
1.38
1.06
1.23
1.48
1.20
1.13
1.29
Configuration
Term
J
Level (cm⫺1 )
3d4s
3d4 p
1
D
F
2
3
3d4s
3d4 p
5
D
P
3d4s
3d4 p
3
3d4s
3d4 p
3
3d4s
3d4 p
3
3d4s
3d4 p
3
3d4s
3d4 p
3
3d4s
3d4 p
3
3d4s
3d4 p
1
Wl Ref
A Ref
2540.95
32349.98
JL80
FW96
3
2
177.76
29823.93
JL80
FW96
D
Do
3
3
177.76
28161.17
JL80
FW96
D
Do
2
2
67.72
28021.29
JL80
FW96
D
Do
1
1
0.00
27917.78
JL80
FW96
D
F
3
4
177.76
27841.35
JL80
FW96
D
F
2
3
67.72
27602.45
JL80
FW96
D
F
1
2
0.00
27443.71
JL80
FW96
D
Do
2
2
2540.95
26081.34
JL80
FW96
1 o
3 o
3
3
3
3 o
3 o
3 o
1
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1996
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Scandium 共Sc II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3d4s
5
D
1
2
3
0.00
67.72
177.76
SC85
SC85
SC85
3d4s
1
D
2
2540.95
SC85
3d 2
3
2
3
4
4802.87
4883.57
4987.79
SC85
SC85
SC85
3d 2
1
2
10944.56
SC85
4s 2
1
0
11736.36
SC85
3d 2
3
0
1
2
12074.10
12101.50
12154.42
SC85
SC85
SC85
3d 2
1
4
14261.32
SC85
2
1
S
0
25955.2
SC85
3d4p
1
Do
2
26081.34
SC85
3d4 p
3 o
F
2
3
4
27443.71
27602.45
27841.35
SC85
SC85
SC85
3d4 p
3
Do
1
2
3
27917.78
28021.29
28161.17
SC85
SC85
SC85
3d4 p
3 o
P
0
1
2
29736.27
29742.16
29823.93
SC85
SC85
SC85
3d4 p
1 o
P
1
30815.70
SC85
3d4 p
1 o
3
32349.98
SC85
3d
F
D
S
P
G
F
Sc III ( 2 D3/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
103237.1
SC85
ATOMIC SPECTROSCOPIC DATA
1997
Selenium „Se…
Atomic number⫽34
Atomic weight⫽78.96
Isotope
74
Se
Se
77
Se
78
Se
80
Se
82
Se
76
Mass
Abundance
Spin
73.922475
75.919212
76.919212
77.9173
79.916520
81.916698
0.9%
9.2%
7.6%
23.7%
49.8%
8.8%
0
0
1/2
0
0
0
Mag moment
⫹0.535506
Se I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 4 3P2
Ionization energy: 78 658.35 cm⫺1 共9.752 39 eV兲
o
Se II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 3 4S3/2
⫺1
Ionization energy: 170 900 cm 共21.19 eV兲
Strong Lines of Selenium 共Se兲
Intensity
800
800
800
800
1000
1000
800
800
1000
300
300
400
400
300
600
150
600
400
600
600
700
300
800
1000
600
400
300
800
1000
800
1000
800
300
300
300
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
832.62
912.69
1013.40
1013.99
1033.56
1049.65
1057.41
1141.97
1192.24
1795.28
1855.20
1898.55
1913.79
1919.19
1960.894
1995.111
Air
2039.842
2062.779
2074.784
2164.188
2413.535
2547.98
4175.28
4180.90
4730.78
4739.03
4742.25
4844.941
5227.533
5305.347
6055.84
6444.29
7062.065
8000.96
8918.86
Spectrum
Ref
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
G62
G62
G62
G62
G62
G62
G62
G62
G62
RG34
RG34
RG34
RG34
RG34
LP77
LP77
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
I
I
I
I
I
I
II
II
I
I
I
II
II
II
II
II
I
I
I
LP77
LP77
LP77
LP77
LP77
RG34
G62
G62
RG34
RG34
RG34
G62
G62
G62
G62
G62
E72
RG34
MV74
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1998
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Selenium 共Se兲—Continued
Wavelength 共Å兲
Intensity
400
1000 P
700 P
400
500
600
400
400
400
600
800 P
500
400
600
Spectrum
10307.45
10327.26
10386.36
14817.93
14917.47
15151.44
15471.00
15618.40
16659.44
16813.78
21442.56
21473.48
24385.99
25127.43
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Se
Ref
I
I
I
I
I
I
I
I
I
I
I
I
I
I
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
MV74
Persistent Lines of Neutral Selenium 共Se I兲
Inten
Wavelength 共Å兲
600
1960.894
150
600
400
600
600
700
600
1000
700
800
A ki (108 s⫺1 )
2.13
2062.779
2074.784
2164.188
0.98
0.33
0.017
0.0032
2413.535
4730.78
10327.26
10386.36
21442.56
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Term
J
Level (cm⫺1 )
3
2
1
Wl Ref
A Ref
0.00
50997.161
LP77
M00
0
1
22446.202
72568.72
LP77
1
1
1989.497
50997.161
LP77
M00
0
1
2534.36
50997.161
LP77
M00
2
2
0.00
48182.420
LP77
M00
1
2
1989.497
48182.420
LP77
M00
D
S
2
1
9576.149
50997.161
LP77
4p 3 ( 4 So)5s
4 p 3 ( 4 So)6p
5 o
S
P
2
3
48182.420
69314.635
RG34
4p 3 ( 4 So)5s
4 p 3 ( 4 So)5p
3 o
S
P
1
2
50997.161
60677.618
MV74
4p 3 ( 4 So)5s
4 p 3 ( 4 So)5p
3 o
S
P
1
1
50997.161
60622.532
MV74
4p 3 ( 4 So)5p
4p 3 ( 4 So)4d
3
P
Do
2
3
60677.618
65339.968
MV74
4p 4
4p 3 ( 4 So)5s
4p 4
4p 3 ( 2 Po)5s
1995.111
2039.842
Configuration
4p 4
4p 3 ( 4 So)5s
4p 4
4p 3 ( 4 So)5s
4p 4
4p 3 ( 4 So)5s
4p 4
4p 3 ( 4 So)5s
4p 4
4p 3 ( 4 So)5s
P
S
3 o
1
S
P
1 o
3
P
S
3 o
3
P
S
3 o
3
P
S
5 o
3
P
S
5 o
1
3 o
5
3
3
3
ATOMIC SPECTROSCOPIC DATA
1999
Energy Levels of Neutral Selenium 共Se I兲
Term
J
Level (cm⫺1 )
4
3
2
1
0
0.00
1989.497
2534.36
E72
E72
E72
4p 4
1
2
9576.149
E72
4p4
1
S
0
22446.202
E72
4 p 3 ( 4 So)5s
5 o
S
2
48182.420
MV74,LP77
4 p 3 ( 4 So)5s
3 o
S
1
50997.161
MV74,LP77
4 p 3 ( 4 So)5p
5
P
1
2
3
59243.028
59288.048
59391.536
MV74,LP77
MV74,LP77
MV74,LP77
4p 3 ( 4 So)5p
3
P
1
2
0
60622.532
60677.618
60696.219
MV74,LP77
MV74,LP77
MV74,LP77
4p 3 ( 2 Do)5s
3
Do
1
2
3
61681.493
61828.723
62247.832
MV74,LP77
MV74,LP77
MV74,LP77
4 p 3 ( 4 So)4d
5
Do
4
2
0
1
3
63370.165
63373.374
63381.104
63382.996
63387.646
MV74,LP77
MV74,LP77
MV74,LP77
MV74,LP77
MV74,LP77
4 p 3 ( 2 Do)5s
1
Do
2
63479.487
MV74,LP77
4 p 3 ( 4 So)4d
3
Do
2
1
3
65278.169
65299.784
65339.968
MV74,LP77
MV74,LP77
MV74,LP77
4 p 3 ( 4 So)6p
5
P
1
2
3
69263.466
69277.846
69314.635
MV74,LP77
MV74,LP77
MV74,LP77
4p 3 ( 2 Po)5s
1 o
1
72568.72
LP77
Limit
78658.35
MV74,LP77
Configuration
4p
P
D
P
o
)
Se II ( 4 S3/2
Ref
Persistent Lines of Singly-ionized Selenium 共Se II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
800
1013.40
11.4
4s 2 4 p 3
4s 2 4 p 2 ( 3 P)5s
1000
1000
1000
1033.56
1049.65
1192.24
10.3
9.96
4s 2 4 p 3
4s 2 4 p 2 ( 3 P)5s
4s 2 4 p 3
4s 2 4 p 2 ( 3 P)5s
4s 2 4 p 3
4s4 p 4
J
Level (cm⫺1 )
S
P
3/2
5/2
4 o
S
P
4 o
Term
Wl Ref
A Ref
0.0
98674.4
G62
M00
3/2
3/2
0.0
96753.3
G62
M00
S
P
3/2
1/2
0.0
95270.0
G62
M00
4 o
3/2
5/2
0.0
83876.7
G62
4 o
4
4
4
4
S
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2000
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Selenium 共Se II兲—Continued
Wavelength 共Å兲
Inten
1000
A ki (108 s⫺1 )
2
4180.90
1000
5227.533
1000
Configuration
2 3
J
Level (cm⫺1 )
o
D
F
7/2
9/2
117798.7
141710.1
G62
P
Do
5/2
7/2
98674.4
117798.7
G62
3/2
3/2
104873.7
121381.9
G62
Term
4s 4 p ( P)5p
4s 2 4 p 2 ( 3 P)5d
4
4s 2 4 p 2 ( 3 P)5s
4s 2 4 p 2 ( 3 P)5p
4
4s 2 4 p 2 ( 3 P)5p
2 o
6055.84
4
4
7
P
Wl Ref
A Ref
Energy Levels of Singly-ionized Selenium 共Se II兲
Ref
Term
4s 2 4p 3
4 o
3/2
0.0
M35
4s 2 4p 3
2
Do
3/2
5/2
13168.2
13784.4
M35
M35
4s 2 4p 3
2 o
1/2
3/2
23038.3
23894.8
M35
M35
4s4 p 4
4
P
5/2
3/2
1/2
83876.7
85579.5
86437.7
M35
M35
M35
4s 2 4p 2 ( 3 P)5s
4
P
1/2
3/2
5/2
95270.0
96753.3
98674.4
M35
M35
M35
3/2
104873.7
M35
S
P
7
2
2 3
o
J
Level (cm⫺1 )
Configuration
4s 4p ( P)5p
4
D
1/2
3/2
5/2
7/2
114299.0
114711.7
116068.1
117798.7
M35
M35
M35
M35
4s 2 4p 2 ( 3 P)5p
2
P
1/2
3/2
121273.2
121381.9
M35
M35
4s 2 4p 2 ( 3 P)5d
4
F
9/2
141710.1
M35
170900
CR58
Se III ( 3 P0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
2001
Silicon „Si…
Atomic number⫽14
Atomic weight⫽28.0855
Isotope
28
Si
Si
30
Si
29
Mass
Abundance
Spin
Mag moment
27.976927
28.976495
29.973770
92.23%
4.67%
3.10%
0
1/2
0
⫺0.5553
Si I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 2 3P0
Ionization energy: 65 747.76 cm⫺1 共8.15168 eV兲
o
Si II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 2P1/2
⫺1
Ionization energy: 131 838.14 cm 共16.345 84 eV兲
Strong Lines of Silicon 共Si兲
Intensity
70
70
300
700
800
70
100
100
70
130
500
1000
100
70
150
300
70
70
90
100
100
200
200
250
300
30
250
40
200
400
200
200
200
300
200
250
400
250
200
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
892.001
992.684
1190.4160
1193.2898
1194.5004
1228.746
1229.388
1248.426
1250.433
1251.164
1260.4223
1264.7379
1309.2766
1350.057
1526.70698
1533.4318
1594.5655
1594.9493
1622.8806
1629.441
1629.9477
1675.2052
1696.2065
1697.9409
1770.9223
1808.01288
1814.0794
1816.9290
1836.5102
1841.4490
1843.7700
1845.5203
1846.1118
1847.4737
1848.1504
1848.7480
1850.6719
1852.4717
1874.8423
Spectrum
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
Ref
RA65
RA65
KE74
KE74
KE74
S61b
S61b
S61b
S61b
S61b
KE74
KE74
KE74
S61b
GK00
KE74
RAKL67
RAKL67
RAKL67
KRA66
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
GK00
RAKL67
KE74
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2002
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Silicon 共Si兲—Continued
Intensity
400
400
400
300
300
500
1000
P
P
P
P
P
P
P
600
20
30
400
500
300
500
400
300
400
400
500
400
400
400
200
1000
50
80
150
15
15
15
7
20
30
20
30
100
40
200
50
70
20
130
130
25
70
70
70
25
20
25
20
130
60
40
25
80
25
30
P
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
h
h
h
P,h
h
P,h
P,h
P
P
h
h
h
h
h
h
h
h
P,h
h
h
h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
1901.3377
1977.5978
1979.2056
1980.6185
1983.2330
1986.3640
1988.9937
Air
2058.1323
2072.016
2072.701
2207.978
2210.894
2211.744
2216.669
2218.057
2435.154
2506.897
2514.316
2516.112
2519.202
2524.108
2528.509
2631.282
2881.5771
2904.283
2905.692
2987.645
3053.184
3188.97
3193.09
3199.514
3203.872
3210.020
3333.139
3339.819
3856.017
3862.595
3905.523
4128.067
4130.893
4621.721
5041.026
5055.981
5192.86
5202.41
5466.432
5466.868
5496.45
5576.66
5639.48
5660.66
5669.562
5684.484
5688.81
5701.37
5708.397
5800.47
5806.74
Spectrum
Ref
Si
Si
Si
Si
Si
Si
Si
I
I
I
I
I
I
I
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
RAKL67
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
I
II
II
KRA66
S61b
S61b
RA65
RA65
RA65
RA65
RA65
RA65
RA65
RA65
RA65
RA65
RA65
RA65
RA65
BE93
S61b
S61b
RA65
S61b
S61b
S61b
S61b
S61b
RA65
S61b
S61b
S61b
S61b
RA65
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
S61b
RA65
S61b
S61b
RA65
S61b
S61b
ATOMIC SPECTROSCOPIC DATA
2003
Strong Lines of Silicon 共Si兲—Continued
Wavelength 共Å兲
Intensity
50
25
50
80
80
40
40
30
30
40
130
100
40
40
60
50
40
40
100
90
50
60
100
50
70
25
30
25
20
20
20
20
20
50
30
60
20
15
25
h
Spectrum
5868.40
5915.22
5948.545
5957.561
5978.929
6155.134
6237.320
6243.813
6244.468
6254.188
6347.103
6371.359
7003.567
7005.883
7034.903
7165.545
7250.625
7275.294
7289.1730
7405.7740
7409.082
7415.946
7423.497
7848.80
7849.72
7932.349
7944.001
8556.7803
10585.140
10603.427
10660.970
10827.088
10869.539
11984.201
11991.562
12031.503
12103.535
12270.692
15888.431
P
P
P
P
P
P
P
P
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Si
Ref
II
II
I
II
II
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
S61b
S61b
RA65
S61b
S61b
RA65
RA65
RA65
RA65
RA65
S61b
S61b
RA65
RA65
RA65
RA65
RA65
RA65
MKMD94
MKMD94
RA65
RA65
RA65
S61b
S61b
RA65
RA65
BE93
BE93
BE93
BE93
BE93
BE93
BE93
BE93
BE93
BE93
BE93
BE93
Persistent Lines of Neutral Silicon 共Si I兲
Inten
400
400
400
400
300
Wavelength 共Å兲
1850.6719
A ki (108 s⫺1 )
3.14
1979.2056
1980.6185
2
2
3s 3 p
3s 2 3 p3d
3s 2 3 p 2
3s 2 3 p4d
1901.3377
1977.5978
Configuration
0.279
0.870
0.207
3s 2 3 p 2
3s 2 3 p3d
3s 2 3 p 2
3s 2 3 p3d
3s 2 3 p 2
3s 2 3 p3d
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3
2
3
223.157
54257.574
RAKL67
M03
2
3
6298.847
58893.362
RAKL67
0
1
0.000
50566.414
RAKL67
M03
1
0
77.112
50602.435
RAKL67
M03
1
1
77.112
50566.414
RAKL67
M03
3
P
Do
1
D
F
1 o
3
P
P
3 o
3
P
P
3 o
3
P
P
3 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2004
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Silicon 共Si I兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
300
1983.2330
0.218
500
1000
600
400
500
300
500
400
400
400
500
400
400
400
1000
50
1986.3640
1988.9937
0.657
2207.978
2210.894
2211.744
2216.669
2218.057
2506.897
2514.316
2516.112
2519.202
2524.108
2528.509
2881.5771
5948.545
7289.173
80
7405.774
J
Level (cm⫺1 )
Wl Ref
3
P
P
1
2
77.112
50499.843
RAKL67
M03
P
P
2
1
223.157
50566.414
RAKL67
M03
P
P
2
2
223.157
50499.843
RAKL67
M03
D
P
2
1
6298.847
54871.027
KRA66
P
Do
0
1
0.000
45276.187
RA65
M03
P
Do
1
2
77.112
45293.623
RA65
M03
P
Do
1
1
77.112
45276.187
RA65
M03
P
Do
2
3
223.157
45321.848
RA65
M03
P
Do
2
2
223.157
45293.623
RA65
M03
P
P
1
2
77.112
39955.051
RA65
M03
P
P
0
1
0.000
39760.285
RA65
M03
P
P
2
2
223.157
39955.051
RA65
M03
P
P
1
1
77.112
39760.285
RA65
M03
P
P
1
0
77.112
39683.158
RA65
M03
P
P
2
1
223.157
39760.285
RA65
M03
D
P
2
1
6298.847
40991.888
BE93
FW96
3s 2 3 p4s
3s 2 3 p5 p
1 o
1
2
40991.888
57798.080
RA65
FW96
3s3p 3
o
)4 f
3s 2 3 p( 2 P3/2
3
Do
2
关 7/2兴
3
4
45321.848
59037.043
RA65
3s3 p 3
o
)4 f
3s 2 3 p( 2 P1/2
3
Do
关 5/2兴
1
2
45276.187
58775.442
RA65
2
3s3 p 3
o
)4 f
3s 2 3 p( 2 P1/2
Do
关 7/2兴
3
4
45321.848
58788.878
RA65
2
3s 2 3 p 2
3s 2 3 p3d
3s 2 3 p 2
3s 2 3 p3d
3s 2 3 p 2
3s 2 3 p3d
3s 2 3 p 2
3s 2 3 p5s
2058.1323
100
100
0.365
Term
Configuration
0.262
0.345
0.181
0.454
0.109
0.547
0.740
1.68
0.549
2.22
0.904
1.89
0.022
0.037
7423.497
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3s 2 3 p 2
3s3 p 3
3s 2 3 p 2
3s3 p 3
3s 2 3 p 2
3s3 p 3
3s 2 3 p 2
3s3 p 3
3s 2 3 p 2
3s3 p 3
3s 2 3 p 2
3s 2 3 p4s
3s 2 3 p 2
3s 2 3 p4s
3s 2 3 p 2
3s 2 3 p4s
3s 2 3 p 2
3s 2 3 p4s
3s 2 3 p 2
3s 2 3 p4s
3s 2 3 p 2
3s 2 3 p4s
3s 2 3 p 2
3s 2 3 p4s
3 o
3
3 o
3
3 o
1
1 o
3
3
3
3
3
3
3
3
3
3
3
3 o
3
3 o
3
3 o
3
3 o
3
3 o
3
3 o
1
1 o
1
3
P
D
A Ref
FW96
ATOMIC SPECTROSCOPIC DATA
2005
Persistent Lines of Neutral Silicon 共Si I兲—Continued
Inten
Wavelength 共Å兲
50
11984.201
60
A ki (108 s⫺1 )
12031.503
Configuration
Term
J
Level (cm⫺1 )
3s 2 3 p4s
3s 2 3 p4 p
3 o
P
D
1
2
39760.285
48102.321
BE93
3s 2 3 p4s
3s 2 3 p4 p
3 o
2
3
39955.051
48264.290
BE93
3
3
P
D
Wl Ref
A Ref
Energy Levels of Neutral Silicon 共Si I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3s 2 3p 2
3
P
0
1
2
0.000
77.112
223.157
MKMD94
MKMD94
MKMD94
3s 2 3p 2
1
D
2
6298.847
MKMD94
3s 2 3p 2
1
S
0
15394.362
MKMD94
5 o
S
2
33326.040
MKMD94
3s 2 3p4s
3 o
P
0
1
2
39683.158
39760.285
39955.051
MKMD94
MKMD94
MKMD94
3s 2 3p4s
1 o
1
40991.888
MKMD94
3s3 p 3
3
Do
1
2
3
45276.187
45293.623
45321.848
MKMD94
MKMD94
MKMD94
3s 2 3p4p
1
P
1
47284.057
MKMD94
3s 2 3p3d
1
Do
2
47351.553
MKMD94
3s 2 3p4p
3
D
1
2
3
48020.074
48102.321
48264.290
MKMD94
MKMD94
MKMD94
3s 2 3p4p
3
P
0
1
2
49028.291
49060.599
49188.615
MKMD94
MKMD94
MKMD94
3s 2 3p4p
3
S
1
49399.669
MKMD94
3s 2 3p3d
3 o
F
2
3
4
49850.832
49933.783
50054.811
MKMD94
MKMD94
MKMD94
3s 2 3p4p
1
D
2
50189.391
MKMD94
3s 2 3p3d
3 o
P
2
1
0
50499.843
50566.414
50602.435
MKMD94
MKMD94
MKMD94
3s 2 3p4p
1
S
0
51612.009
MKMD94
3s 2 3p3d
1 o
3
53362.258
MKMD94
3s 2 3p3d
1 o
1
53387.342
MKMD94
3
1
2
3
54185.257
54205.083
54257.574
MKMD94
MKMD94
MKMD94
3s3p
2
3
3s 3p3d
P
F
P
o
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2006
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Silicon 共Si I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3s 3p5s
3 o
P
0
1
2
54245.021
54313.817
54528.218
MKMD94
MKMD94
MKMD94
3s 2 3p5s
1 o
P
1
54871.027
MKMD94
3s 2 3p4d
1
Do
2
56503.348
MKMD94
3s 2 3p4d
3 o
P
2
1
0
56690.902
56700.225
56733.370
MKMD94
MKMD94
MKMD94
3s 2 3p5p
1
P
1
56780.429
MKMD94
3s 2 3p5p
3
D
1
2
3
56978.251
57017.502
57198.013
MKMD94
MKMD94
MKMD94
3s 2 3p5p
3
P
0
1
2
57295.880
57328.785
57468.244
MKMD94
MKMD94
MKMD94
3s 2 3p4d
3 o
F
2
3
4
57372.302
57450.583
57583.657
MKMD94
MKMD94
MKMD94
3s 2 3p5p
3
S
1
57541.915
MKMD94
3s 2 3p5p
1
D
2
57798.080
MKMD94
3s 2 3p5p
1
S
0
58311.667
MKMD94
o
3p( 2 P1/2
)4 f
2
关 5/2兴
3
2
58774.365
58775.442
MKMD94
MKMD94
o
)4 f
3s 2 3p( 2 P1/2
2
关 7/2兴
3
4
58786.852
58788.878
MKMD94
MKMD94
3s 2 3p4d
1 o
1
58801.525
MKMD94
3s 2 3p4d
1 o
3
58893.362
MKMD94
3s 3p4d
3
o
D
2
1
3
59032.174
59056.494
59117.991
MKMD94
MKMD94
MKMD94
o
)4 f
3s 2 3p( 2 P3/2
2
关 7/2兴
3
4
59034.988
59037.043
MKMD94
MKMD94
o
)4 f
3s 2 3p( 2 P3/2
2
关 5/2兴
3
2
59109.956
59110.890
MKMD94
MKMD94
o
)4 f
3s 2 3p( 2 P3/2
2
关 9/2兴
5
4
59128.407
59131.908
MKMD94
MKMD94
o
)4 f
3s 2 3p( 2 P3/2
2
关 3/2兴
1
2
59190.444
59191.066
MKMD94
MKMD94
Limit
65747.76
MKMD94
Configuration
2
3s
2
2
P
F
o
)
Si II ( 2 P1/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2007
Persistent Lines of Singly-ionized Silicon 共Si II兲
Wavelength 共Å兲
Inten
300
A ki (108 s⫺1 )
1190.4160
700
1193.2898
800
1194.5004
500
1260.4223
1000
1264.7379
300
6.86
27.3
34.0
24.7
29.3
1533.4318
100
7.50
4128.067
70
4130.893
130
5041.026
130
0.98
5055.981
130
1.26
5669.562
130
0.50
6347.103
100
2 1
0.66
6371.359
0.77
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
3s ( S)3p
3s3 p 2
2 o
P
P
1/2
3/2
0.00
84004.26
KE74
M03
3s 2 ( 1 S)3p
3s3 p 2
2 o
P
P
1/2
1/2
0.00
83801.95
KE74
M03
3s 2 ( 1 S)3p
3s3 p 2
2 o
P
P
3/2
3/2
287.24
84004.26
KE74
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)3d
2 o
P
Do
1/2
3/2
0.00
79338.50
KE74
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)3d
2 o
P
D
3/2
5/2
287.24
79355.02
KE74
M03
3s 2 ( 1 S)3p
3s 2 ( 1 S)4s
2 o
3/2
1/2
287.24
65500.47
KE74
M03
D
P
5/2
3/2
55325.18
81251.32
S61b
D
F
3/2
5/2
79338.50
103556.16
S61b
2
2
2
2
2
2
3s3 p 2
3s 2 ( 1 S)4p
3856.017
50
Configuration
P
S
2
2 o
3s 2 ( 1 S)3d
3s 2 ( 1 S)4 f
2
3s 2 ( 1 S)3d
3s 2 ( 1 S)4 f
2
D
F
5/2
7/2
79355.02
103556.03
S61b
3s 2 ( 1 S)4p
3s 2 ( 1 S)4d
2 o
P
D
1/2
3/2
81191.34
101023.05
S61b
FW96
3s 2 ( 1 S)4p
3s 2 ( 1 S)4d
2 o
P
D
3/2
5/2
81251.32
101024.35
S61b
BBC95
3s3 p( 3 Po)3d
3s3 p( 3 Po)4p
4 o
F
D
9/2
7/2
114529.14
132162.29
S61b
BBC95
3s 2 ( 1 S)4s
3s 2 ( 1 S)4p
2
S
P
1/2
3/2
65500.47
81251.32
S61b
BBC95
3s 2 ( 1 S)4s
3s 2 ( 1 S)4p
2
S
P
1/2
1/2
65500.47
81191.34
S61b
BBC95
2 o
2 o
2
2
4
2 o
2 o
Energy Levels of Singly-ionized Silicon 共Si II兲
Ref
Term
3s 2 ( 1 S)3p
2 o
P
1/2
3/2
0.00
287.24
MZ83
MZ83
3s3 p 2
4
P
1/2
3/2
5/2
42824.29
42932.62
43107.91
MZ83
MZ83
MZ83
3s3p 2
2
D
3/2
5/2
55309.35
55325.18
MZ83
MZ83
3s 2 ( 1 S)4s
2
S
1/2
65500.47
MZ83
2
S
1/2
76665.35
MZ83
2
D
3/2
5/2
79338.50
79355.02
MZ83
MZ83
3s3p
2
3s 2 ( 1 S)3d
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2008
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Silicon 共Si II兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
3s 2 ( 1 S)4p
2 o
1/2
3/2
81191.34
81251.32
MZ83
MZ83
3s3 p 2
2
P
1/2
3/2
83801.95
84004.26
MZ83
MZ83
3s 2 ( 1 S)5s
2
S
1/2
97972.09
MZ83
3s 2 ( 1 S)4d
2
D
3/2
5/2
101023.05
101024.35
MZ83
MZ83
3s 2 ( 1 S)4 f
2 o
F
7/2
5/2
103556.03
103556.16
MZ83
MZ83
3s 2 ( 1 S)5p
2 o
P
1/2
3/2
103860.74
103885.25
MZ83
MZ83
3s3 p( 3 Po)3d
2
Do
3/2
5/2
108778.7
108820.6
MZ83
MZ83
3s 2 ( 1 S)5d
2
D
3/2
5/2
112394.56
112394.72
MZ83
MZ83
3s 2 ( 1 S)5 f
2 o
F
7/2
5/2
113760.15
113760.32
MZ83
MZ83
3s 2 ( 1 S)5g
2
G
7/2,9/2
114177.1
MZ83
3s3p( 3 Po)3d
4 o
F
3/2
5/2
7/2
9/2
114265.64
114327.15
114414.58
114529.14
MZ83
MZ83
MZ83
MZ83
3s3 p( 3 Po)4s
4 o
P
1/2
3/2
5/2
116862.38
116978.38
117178.06
MZ83
MZ83
MZ83
3s3 p( 3 Po)4s
2 o
P
1/2
3/2
121444.12
121590.19
MZ83
MZ83
3p3
4 o
S
3/2
123033.5
MZ83
3s3 p( 3 Po)3d
4
Do
5/2
3/2
1/2
7/2
124316.9
124325.3
124337.3
124449.5
MZ83
MZ83
MZ83
MZ83
3s3 p( 3 Po)3d
4 o
P
5/2
3/2
1/2
124567.4
124615.6
124638.9
MZ83
MZ83
MZ83
3s3 p( 3 Po)3d
2 o
P
3/2
1/2
126236.4
126279.0
MZ83
MZ83
3s3 p( 3 Po)3d
2 o
F
5/2
7/2
131677.1
131918.8
MZ83
MZ83
3s3 p( 3 Po)4p
4
D
1/2
3/2
5/2
7/2
131784.9
131861.93
131988.05
132162.29
MZ83
MZ83
MZ83
MZ83
Limit
131838.14
MZ83
P
Si III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2009
Silver „Ag…
Atomic number⫽47
Atomic weight⫽107.8682
Isotope
107
Ag
Ag
109
Mass
Abundance
Spin
Mag moment
106.905092
108.904757
51.84%
48.16%
1/2
1/2
⫺0.1135
⫺0.1305
Ag I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2S1/2
Ionization energy: 61 106.45 cm⫺1 共7.576 23 eV兲
Ag II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 10 1S0
Ionization energy: 173 227.4 cm⫺1 共21.477 46 eV兲
Strong Lines of Silver 共Ag兲
Intensity
1000
600
700
9
300
400
5
300
300
300
20
9
300
300
700
300
300
200
400
300
500
1000
1000
200
200
5
9
60
1000
500
20
9
9
9
8
9
50
5
100
P
P
P
r
P,r
P,r
P,r
P
P,r
P,r
P,r
P,r
P,r
h
P,r
P,r
h
h
h
h
h
Wavelength 共Å兲
Vacuum
1106.9931
1112.4006
1195.8092
1515.63
1644.4958
1665.3513
1651.52
1682.8353
1723.6119
1994.3173
Air
2061.162
2069.844
2113.8250
2243.4485
2246.4120
2248.7490
2279.9812
2317.0342
2320.2451
2324.6670
2331.3665
2413.1883
2437.7832
2477.1279
2711.8732
2721.77
2824.39
2934.0209
3280.680
3382.887
3810.941
3840.750
3981.580
4055.476
4210.960
4212.814
4620.0361
4668.477
4788.3968
Spectrum
Ref
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
II
II
II
I
II
II
I
II
II
II
KLLT02
KLLT02
KLLT02
S40
KLLT02
KLLT02
S40
KLLT02
KLLT02
KLLT02
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
I
I
I
I
I
I
I
II
I
II
PZ01
PZ01
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
KLLT02
S40
S40
KLLT02
PZ01
PZ01
PZ01
PZ01
PZ01
PZ01
PZ01
PZ01
KLLT02
PZ01
KLLT02
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2010
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Silver 共Ag兲—Continued
Intensity
Wavelength 共Å兲
9
50
90
90
9
9
30
50
5
4874.10
5027.3433
5209.078
5465.497
5471.555
5667.34
7687.772
8273.509
16819.5
P
P
P
P
Spectrum
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ref
I
II
I
I
I
I
I
I
I
S40
KLLT02
PZ01
PZ01
PZ01
S40
PZ01
PZ01
S40
Persistent Lines of Neutral Silver 共Ag I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
1000
3280.680
1.47
500
90
90
30
50
3382.887
1.35
5209.078
0.75
5465.497
0.86
7687.772
8273.509
J
Level (cm⫺1 )
S
P
1/2
3/2
S
P
4d 10( 1 S)5p
4d 10( 1 S)5d
2 o
Configuration
Term
Wl Ref
A Ref
4d 10( 1 S)5s
4d 10( 1 S)5p
2
0.000
30472.703
PZ01
M00
4d 10( 1 S)5s
4d 10( 1 S)5p
2
1/2
1/2
0.000
29552.061
PZ01
M00
P
D
1/2
3/2
29552.061
48743.969
PZ01
FW96
4d 10( 1 S)5p
4d 10( 1 S)5d
2 o
P
D
3/2
5/2
30472.703
48764.219
PZ01
FW96
4d 10( 1 S)5p
4d 10( 1 S)6s
2 o
P
S
1/2
1/2
29552.061
42556.152
PZ01
4d 10( 1 S)5p
4d 10( 1 S)6s
2 o
3/2
1/2
30472.703
42556.152
PZ01
2 o
2 o
2
2
2
2
P
S
Energy Levels of Neutral Silver 共Ag I兲
Configuration
10 1
Term
J
Level (cm⫺1 )
Ref
4d ( S)5s
2
S
1/2
0.000
PZ01
4d 10( 1 S)5p
2 o
1/2
3/2
29552.061
30472.703
PZ01
PZ01
4d 9 5s 2
2
D
5/2
3/2
30242.291
34714.305
PZ01
PZ01
4d 10( 1 S)6s
2
S
1/2
42556.152
PZ01
4d 10( 1 S)6p
2 o
P
1/2
3/2
48297.402
48500.805
PZ01
PZ01
4d 10( 1 S)5d
2
D
3/2
5/2
48743.969
48764.219
PZ01
PZ01
4d 10( 1 S)7s
2
P
S
1/2
51886.971
PZ01
4d ( S)7p
2 o
P
1/2
3/2
54040.99
54121.129
M58
PZ01
4d 10( 1 S)6d
2
D
3/2
5/2
54203.119
54213.570
PZ01
PZ01
4d 10( 1 S)4 f
2 o
5/2,3/2
54204.73
M58
Limit
61106.45
LBS99
10 1
F
Ag II ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2011
Persistent Lines of Singly-ionized Silver 共Ag II兲
Inten
Wavelength 共Å兲
1000
600
700
300
700
300
300
400
300
500
1000
1000
A ki (108 s⫺1 )
1106.9931
6.93
1112.4006
7.71
1195.8092
0.57
2113.8250
3.26
2246.4120
3.91
2248.7490
2.95
2279.9812
1.39
2320.2451
2.74
2324.6670
0.72
2331.3665
2.54
2413.1883
2.21
2437.7832
2.88
Configuration
10
4d
4d 9 ( 2 D)5p
4d 10
4d 9 ( 2 D)5p
4d 10
4d 9 ( 2 D)5p
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1
S
Do
0
1
0.000
90334.836
KLLT02
BPKR97
S
P
0
1
0.000
89895.502
KLLT02
BPKR97
S
P
0
1
0.000
83625.479
KLLT02
BPKR97
D
Do
3
3
39168.032
86460.650
KLLT02
BPKR97
D
F
3
4
39167.986
83669.614
KLLT02
BPKR97
D
F
2
2
40745.335
85200.721
KLLT02
BPKR97
D
P
2
1
46049.029
89895.502
KLLT02
BPKR97
D
F
2
3
46049.029
89134.688
KLLT02
BPKR97
D
F
3
3
39167.986
82171.697
KLLT02
BPKR97
D
P
2
1
40745.335
83625.479
KLLT02
BPKR97
D
F
2
3
40745.335
82171.697
KLLT02
BPKR97
D
P
3
2
39167.986
80176.425
KLLT02
BPKR97
3
1
1 o
1
3 o
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
1
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
1
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
4d 9 ( 2 D)5s
4d 9 ( 2 D)5p
3
3
3 o
3 o
1 o
1 o
3 o
3 o
3 o
3 o
Energy Levels of Singly-ionized Silver 共Ag II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
4d 10
1
S
0
0.000
KLLT02
4d ( D)5s
3
D
3
2
1
39167.986
40745.335
43742.702
KLLT02
KLLT02
KLLT02
4d 9 ( 2 D)5s
1
D
2
46049.029
KLLT02
4d 9 ( 2 D)5p
3 o
P
2
1
0
80176.425
83625.479
86140.050
KLLT02
KLLT02
KLLT02
4d 9 ( 2 D)5p
3 o
F
3
4
2
82171.697
83669.614
85200.721
KLLT02
KLLT02
KLLT02
4d 9 ( 2 D)5p
3
Do
3
1
2
86460.616
90334.836
90887.806
KLLT02
KLLT02
KLLT02
4d 9 ( 2 D)5p
1
Do
2
86888.063
KLLT02
9 2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2012
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Silver 共Ag II兲—Continued
J
Level (cm⫺1 )
Ref
4d ( D)5p
1 o
F
3
89134.688
KLLT02
4d 9 ( 2 D)5p
1 o
1
89895.502
KLLT02
Configuration
9 2
Term
P
Ag III ( 2 D5/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
173227.4
BJK75
ATOMIC SPECTROSCOPIC DATA
2013
Sodium „Na…
Atomic number⫽11
Atomic weight⫽22.989 768
Isotope
23
Na
Mass
Abundance
Spin
Mag moment
22.989767
100%
3/2
2.21752
Na I Ground state: 1s 2 2s 2 2p 6 3s 2S1/2
Ionization energy: 41 449.451 cm⫺1 共5.139 076 eV兲
Na II Ground state: 1s 2 2s 2 2p 6 1S0
Ionization energy: 381 390.2 cm⫺1 共47.2864 eV兲
Strong Lines of Sodium 共Na兲
Intensity
90 P
90
50
60
30
150 P
200
50
50
40
50
40
40
50
40
40
90
150
150
150
600
300
300
300
300
500
500
600
500
2
1
500
400
600
5P
2P
400
400
500
500
Wavelength 共Å兲
Vacuum
300.15
300.20
301.32
301.44
302.45
372.08
376.38
1374.69
1404.68
1506.41
1776.57
1787.19
1798.41
1807.09
1835.22
1853.17
1881.91
Air
2315.65
2420.99
2424.73
2493.15
2515.46
2531.54
2586.31
2594.96
2611.81
2661.00
2671.83
2678.09
2680.34
2680.43
2809.52
2839.56
2841.72
2852.81
2853.01
2859.49
2871.28
2881.15
2886.26
Spectrum
Ref
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
I
I
II
II
II
II
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
R56
R56
W71
W71
W71
R56
R56
W71
W71
W71
W71
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2014
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Sodium 共Na兲—Continued
Intensity
500
400
600
600
600
700
700
600
500
500
700
600
600
600
600
700
300
400
400
300
500
600
400
400
600
400
400
900
1000
900
500
1000
1000
600
900
900
800
500
1000
900
15
8
800
600
500
1
800
700
500
150
1
1
600
1
400
500
400
1
1
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
2901.14
2904.72
2904.92
2917.52
2919.05
2919.85
2920.95
2923.49
2937.74
2947.50
2951.24
2952.40
2977.13
2979.66
2980.63
2984.19
3004.15
3007.44
3009.14
3015.40
3053.67
3056.16
3060.25
3061.35
3092.73
3094.45
3095.55
3124.42
3135.48
3137.86
3145.71
3149.28
3163.74
3179.06
3189.79
3212.19
3257.96
3274.22
3285.60
3301.35
3302.37
3302.98
3304.96
3318.04
3327.69
3426.86
3533.05
3631.27
3711.07
4113.70
4324.62
4390.03
4392.81
4393.34
4405.12
4455.23
4490.87
4494.18
4497.66
Spectrum
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
I
II
II
II
II
I
I
II
I
II
II
II
I
I
Ref
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
W71
R56
R56
W71
W71
W71
R56
W71
W71
W71
W71
R56
R56
W71
R56
W71
W71
W71
R56
R56
ATOMIC SPECTROSCOPIC DATA
2015
Strong Lines of Sodium 共Na兲—Continued
Intensity
2
2
2
5
1
1
50
4
1
7
1000 P
500 P
2
3
50
70
70
70
1
60 P
10 P
110 P
1
1
1
1
1
1
2
1
2
1
5P
12 P
5
1
1
1
1
5P
1
1
1
Wavelength 共Å兲
4664.811
4668.560
4978.541
4982.813
5148.838
5153.402
5414.55
5682.633
5688.193
5688.205
5889.950
5895.924
6154.225
6160.747
6514.21
6530.70
6544.04
6545.75
7809.78
8183.256
8194.790
8194.824
8649.92
8650.89
9153.88
9465.94
9961.28
10572.28
10746.44
10749.29
10834.87
11197.21
11381.45
11403.78
12679.17
14767.48
14779.73
16373.85
16388.85
18465.25
22056.44
23348.41
23379.13
Spectrum
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
Na
I
I
I
I
I
I
II
I
I
I
I
I
I
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
R56
R56
R56
R56
R56
R56
W71
R56
R56
R56
R56
R56
R56
R56
W71
W71
W71
W71
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
R56
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2016
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Sodium 共Na I兲
Inten
Wavelength 共Å兲
5
2852.81
2
2853.01
15
3302.37
8
3302.98
1000
5889.950
500
5895.924
60
8183.256
10
8194.790
110
5
12
5
8194.824
11381.45
11403.78
18465.25
A ki (108 s⫺1 )
0.00554
0.00554
0.0281
0.0281
0.616
0.614
0.453
0.090
0.54
0.090
0.176
0.140
0.00933
J
Level (cm⫺1 )
S
P
1/2
3/2
0.000
35042.85
R56
M03
S
P
1/2
1/2
0.000
35040.38
R56
M03
S
P
1/2
3/2
0.000
30272.58
R56
M03
S
P
1/2
1/2
0.000
30266.99
R56
M03
S
P
1/2
3/2
0.000
16973.368
R56
M03
S
P
1/2
1/2
0.000
16956.172
R56
M03
3p
3d
2 o
P
D
1/2
3/2
16956.172
29172.889
R56
FW96
3p
3d
2 o
P
D
3/2
3/2
16973.368
29172.889
R56
FW96
3p
3d
2 o
P
D
3/2
5/2
16973.368
29172.839
R56
FW96
3p
4s
2 o
P
S
1/2
1/2
16956.172
25739.991
R56
FW96
3p
4s
2 o
P
S
3/2
1/2
16973.368
25739.991
R56
FW96
3d
4f
2
D
F
5/2
7/2
29172.839
34586.92
R56
WSM69
3d
4f
2
D
F
5/2
5/2
29172.839
34586.92
Configuration
Term
3s
5p
2
3s
5p
2
3s
4p
2
3s
4p
2
3s
3p
2
3s
3p
2
2 o
2 o
2 o
2 o
2 o
2 o
2
2
2
2
2
2 o
2 o
Wl Ref
A Ref
WSM69
Energy Levels of Neutral Sodium 共Na I兲
Ref
Term
3s
2
S
1/2
0.000
MZ81
3p
2 o
P
1/2
3/2
16956.172
16973.368
MZ81
MZ81
4s
2
S
1/2
25739.991
MZ81
3d
2
D
5/2
3/2
29172.839
29172.889
MZ81
MZ81
4p
2 o
P
1/2
3/2
30266.99
30272.58
MZ81
MZ81
4f
2 o
F
5/2,7/2
34586.92
MZ81
5p
2 o
1/2
3/2
35040.38
35042.85
MZ81
MZ81
Limit
41449.451
BBLB98
P
Na II 2s 2 2p 6 ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
J
Level (cm⫺1 )
Configuration
ATOMIC SPECTROSCOPIC DATA
2017
Persistent Lines of Singly-ionized Sodium 共Na II兲
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
90
300.15
30.
2p 6
o
)4s
2p 5 ( 2 P1/2
2
150
372.08
34.
2p 6
2p 5 3s
1 o
600
3092.73
1000
3285.60
Inten
Term
J
Level (cm⫺1 )
S
关 1/2兴 o
0
1
S
P
2p 5 3s
2 p 53 p
3 o
2p 5 3s
2 p 53 p
Wl Ref
A Ref
0.00
333162.94
W71
FW96
0
1
0.00
268762.96
W71
FW96
P
D
2
3
264924.32
297248.82
W71
1 o
1
2
268762.96
299189.96
W71
1
1
3
1
P
D
Energy Levels of Singly-ionized Sodium 共Na II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
S
0
0.00
MZ81
2 p 5 3s
3 o
P
2
1
0
264924.32
265689.62
266281.62
MZ81
MZ81
MZ81
2 p 5 3s
1 o
P
1
268762.96
MZ81
5
2 p 3p
3
S
1
293220.33
MZ81
2 p 5 3p
3
D
3
2
1
297248.82
297635.61
298165.44
MZ81
MZ81
MZ81
2p 5 3p
1
D
2
299189.96
MZ81
o
)4s
2 p 5 ( 2 P1/2
2
关 1/2兴 o
1
333162.94
MZ81
Limit
381390.2
MZ81
2p
6
Na III
1
o
( 2 P3/2
)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2018
J. E. SANSONETTI AND W. C. MARTIN
Strontium „Sr…
Atomic number⫽38
Atomic weight⫽87.62
Isotope
84
Sr
Sr
87
Sr
88
Sr
86
Mass
Abundance
Spin
83.913430
85.909267
86.908884
87.905619
0.56%
9.86%
7.00%
82.58%
0
0
9/2
0
Mag moment
⫺1.093
Sr I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 5s 2 1S0
Ionization energy: 45 932.09 cm⫺1 共5.694 85 eV兲
Sr II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 5s 2S1/2
Ionization energy: 88 964.0 cm⫺1 共11.0301 eV兲
Strong Lines of Strontium 共Sr兲
Intensity
Wavelength 共Å兲
30 P
30 P
14 P
20 P
20
1000 P
4
700 P
7P
1000 P
50
30
20
70 P
60
50 P
30
120 P
20 P
20
30
30
40
70 P
25
110 P
50
40
30
30
140 P
80 P
25
50
30 P
70 P
20 P
80 P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Air
2152.84
2165.96
3380.71
3464.46
4030.38
4077.71
4161.80
4215.52
4305.45
4607.33
4722.28
4741.92
4784.32
4811.88
4832.08
4872.49
4876.32
4962.26
4967.94
5222.20
5225.11
5229.27
5238.55
5256.90
5450.84
5480.84
5504.17
5521.83
5534.81
5540.05
6408.47
6504.00
6550.26
6617.26
6791.05
6878.38
6892.59
7070.10
Spectrum
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
II
II
II
II
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
2019
Strong Lines of Strontium 共Sr兲—Continued
Intensity
Wavelength 共Å兲
40
4
7
20 P
4
7309.41
8688.91
10036.66
10327.31
10914.88
Spectrum
Sr
Sr
Sr
Sr
Sr
Ref
I
II
II
II
II
MCS75
NOL73
S38a
S38a
S38a
Persistent Lines of Neutral Strontium 共Sr I兲
Inten
Wavelength 共Å兲
1000
4607.33
70
50
120
20
70
110
140
80
30
70
20
80
A ki (108 s⫺1 )
4872.49
4962.26
4967.94
5256.90
5480.84
6408.47
6504.00
6791.05
6878.38
0.00048
7070.10
J
Level (cm⫺1 )
Wl Ref
A Ref
1
S
P
0
1
0.000
21698.482
MCS75
FW96
5s5 p
5p2
3 o
P
P
2
2
14898.563
35674.668
MCS75
5s5 p
5s5d
3 o
P
D
1
2
14504.351
35022.015
MCS75
5s5 p
5s5d
3 o
P
D
2
3
14898.563
35045.055
MCS75
5s5 p
5s5d
3 o
P
D
2
2
14898.563
35022.015
MCS75
5s4d
4d5 p
3
D
P
3
2
18319.267
37336.616
MCS75
5s4d
4d5 p
3
D
Do
3
3
18319.267
36559.514
MCS75
5s4d
4d5 p
3
D
F
3
4
18319.267
33919.330
MCS75
5s4d
4d5 p
3
D
F
2
3
18218.795
33589.724
MCS75
5s5 p
5s6s
3 o
P
S
0
1
14317.520
29038.795
MCS75
5s5 p
5s6s
3 o
P
S
1
1
14504.351
29038.795
MCS75
S
P
0
1
0.000
14504.351
MCS75
3 o
2
1
14898.563
29038.795
MCS75
5s 2
5s5 p
2.01
4811.88
6892.59
Term
Configuration
1 o
3
3
3
3
3 o
3
3 o
3 o
3
3
5s 2
5s5 p
1
3 o
5s5 p
5s6s
3
P
S
M00
Energy Levels of Neutral Strontium 共Sr I兲
Configuration
Level (cm⫺1 )
Term
J
1
S
0
0.000
M52
5s5 p
3 o
P
0
1
2
14317.520
14504.351
14898.563
M52
M52
M52
5s4d
3
D
1
2
3
18159.056
18218.795
18319.267
M52
M52
M52
5s
2
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2020
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Strontium 共Sr I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
5s4d
1
D
2
20149.700
M52
5s5p
1 o
P
1
21698.482
M52
5s6s
3
S
1
29038.795
M52
5s6s
1
S
0
30591.80
M52
4d5p
3 o
F
2
3
4
33266.872
33589.724
33919.330
M52
M52
M52
4d5 p
1
Do
2
33826.927
M52
5s5d
1
D
2
34727.483
M52
5s5d
3
D
1
2
3
35006.943
35022.015
35045.055
M52
M52
M52
5p 2
3
P
0
1
2
35193.47
35400.138
35674.668
M52
M52
M52
4d5p
3
Do
1
2
3
36264.181
36381.769
36559.514
M52
M52
M52
4d5 p
3 o
0
1
2
37292.106
37302.760
37336.616
M52
M52
M52
Limit
45932.09
RB78
P
Sr II ( 2 S1/2)
Persistent Lines of Singly-ionized Strontium 共Sr II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
D
F
3/2
5/2
14555.90
60991.7
MCS75
Configuration
Term
A Ref
30
2152.84
4d
4f
2
30
2165.96
4d
4f
2
D
F
5/2
5/2
14836.24
60991.7
MCS75
14
3380.71
5p
5d
2 o
P
D
1/2
3/2
23715.19
53286.31
MCS75
20
3464.46
3.1
5p
5d
2 o
P
D
3/2
5/2
24516.65
53372.97
MCS75
FW96
1000
4077.71
1.42
5s
5p
2
S
P
1/2
3/2
0.00
24516.65
MCS75
FW96
700
4215.52
1.27
5s
5p
2
S
P
1/2
1/2
0.00
23715.19
MCS75
FW96
7
4305.45
1.4
5p
6s
2 o
P
S
3/2
1/2
24516.65
47736.53
MCS75
FW96
20
10327.31
4d
5p
2
D
P
5/2
3/2
14836.24
24516.65
S38a
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2 o
2 o
2
2
2 o
2 o
2
2 o
ATOMIC SPECTROSCOPIC DATA
2021
Energy Levels of Singly-ionized Strontium 共Sr II兲
Ref
Term
5s
2
S
1/2
0.00
M52
4d
2
D
3/2
5/2
14555.90
14836.24
M52
M52
5p
2 o
P
1/2
3/2
23715.19
24516.65
M52
M52
6s
2
S
1/2
47736.53
M52
5d
2
D
3/2
5/2
53286.31
53372.97
M52
M52
6p
2 o
P
1/2
3/2
55769.7
56057.9
M52
M52
4f
2 o
F
5/2
7/2
60991.7
—
M52
M52
7s
2
S
1/2
64964.10
M52
Limit
88964.0
M52
Sr III ( 1 S0 )
J
Level (cm⫺1 )
Configuration
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2022
J. E. SANSONETTI AND W. C. MARTIN
Sulfur „S…
Atomic number⫽16
Atomic weight⫽32.066
Isotope
32
S
S
34
S
36
S
33
Mass
Abundance
Spin
31.972070
32.971456
33.967866
35.967080
95.02%
0.75%
4.21%
0.02%
0
3/2
0
0
Mag moment
⫹0.64382
S I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 4 3P2
Ionization energy: 83 559.1 cm⫺1 共10.360 01 eV兲
o
S II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 3 4S3/2
⫺1
Ionization energy: 188 232.7 cm 共23.337 88 eV兲
Strong Lines of Sulfur 共S兲
Intensity
400
300
250
250
300
250
400
900
1000
200
120
250
150
1000
600
200
250
1000
700
900
800
1000
900
800
200
100
200
250
40
140
250
400
150
150
150
150
120
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Vacuum
906.885
910.484
912.735
937.421
937.684
1014.449
1250.578
1253.805
1259.518
1388.435
1392.588
1396.112
1401.514
1425.030
1433.280
1433.310
1436.968
1473.995
1483.039
1666.688
1687.530
1807.311
1820.343
1826.245
1900.286
1914.698
Air
4153.064
4162.665
4694.13
5428.667
5432.815
5453.828
5473.620
5509.718
5606.151
5639.972
5659.985
Spectrum
Ref
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
S
S
S
S
S
S
S
S
S
S
S
II
II
I
II
II
II
II
II
II
II
II
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
ATOMIC SPECTROSCOPIC DATA
2023
Strong Lines of Sulfur 共S兲—Continued
Wavelength 共Å兲
Intensity
40
150
120
100
80
120
40
150
100
80
200
30
130
Spectrum
6757.16
7578.909
7629.740
7923.90
7967.371
8314.594
8694.71
9212.865
9228.092
9237.538
10455.451
10456.757
10459.406
P
P
P
P
P
P
P
P
P
P
S
S
S
S
S
S
S
S
S
S
S
S
S
Ref
I
II
II
I
II
II
I
I
I
I
I
I
I
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
KM93
Persistent Lines of Neutral Sulfur 共S I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
1000
1425.030
2.92
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)3d
3
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)3d
3
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)3d
3
3s 2 3 p 4
3s 2 3 p 3 ( 2 Do)4s
3
3s 2 3 p 4
3s 2 3 p 3 ( 2 Do)4s
1
3s 2 3 p 4
3s 2 3 p 3 ( 2 Do)3d
1 o
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)4s
3 o
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)4s
3 o
3s 2 3 p 4
3s 2 3 p 3 ( 4 So)4s
3 o
600
200
1000
900
800
1000
900
800
150
100
80
200
30
130
1433.280
1433.310
1473.995
1666.688
1687.530
1807.311
1820.343
1826.245
9212.865
9228.092
9237.538
10455.451
10456.757
10459.406
2.16
1.20
1.82
6.3
0.94
3.08
1.70
0.549
0.30
0.28
0.28
0.22
0.22
0.22
Term
J
Level (cm⫺1 )
Wl Ref
3
P
Do
2
3
0.000
70173.968
KM93
M03
P
Do
1
2
396.055
70166.195
KM93
M03
P
Do
1
1
396.055
70164.650
KM93
M03
P
Do
2
3
0.000
67842.867
KM93
M03
D
Do
2
2
9238.609
69237.886
KM93
FW96
S
P
0
1
22179.954
81438.30
KM93
FW96
P
S
2
1
0.000
55330.811
KM93
M03
P
S
1
1
396.055
55330.811
KM93
M03
P
S
0
1
573.640
55330.811
KM93
M03
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
5 o
S
P
2
3
52623.640
63475.051
KM93
WSM69
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
5 o
S
P
2
2
52623.640
63457.142
KM93
WSM69
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
5 o
S
P
2
1
52623.640
63446.065
KM93
WSM69
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
3 o
S
P
1
2
55330.811
64892.582
KM93
WSM69
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
3 o
S
P
1
0
55330.811
64891.386
KM93
WSM69
3s 2 3 p 3 ( 4 So)4s
3s 2 3 p 3 ( 4 So)4p
3 o
1
1
55330.811
64888.964
KM93
WSM69
3
3
3
1
1
3
3
3
5
5
5
3
3
3
S
P
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2024
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Sulfur 共S I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
3s 2 3p 4
3
2
1
0
0.000
396.055
573.640
MZM90
MZM90
MZM90
3s 2 3p 4
1
2
9238.609
MZM90
3s 2 3p 4
1
S
0
22179.954
MZM90
3s 2 3p 3 ( 4 So)4s
5 o
S
2
52623.640
MZM90
3s 2 3p 3 ( 4 So)4s
3 o
S
1
55330.811
MZM90
3s 2 3p 3 ( 4 So)4p
5
P
1
2
3
63446.065
63457.142
63475.051
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)4p
3
P
1
0
2
64888.964
64891.386
64892.582
MZM90
MZM90
MZM90
3s 2 3p 3 ( 2 Do)4s
3
Do
1
2
3
67816.351
67825.188
67842.867
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)3d
5
Do
4
0
1
2
3
67877.635
67884.158
67885.535
67887.805
67890.016
MZM90
MZM90
MZM90
MZM90
MZM90
3s 2 3p 3 ( 2 Do)4s
1
Do
2
69237.886
MZM90
3s 2 3p 3 ( 4 So)3d
3
Do
1
2
3
70164.650
70166.195
70173.968
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)5s
5 o
S
2
70702.790
MZM90
3s 2 3p 3 ( 4 So)5s
3 o
S
1
71351.399
MZM90
3s3 p 5
3 o
P
2
1
0
72023.495
72382.328
72571.630
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)5p
5
P
1
2
3
73911.259
73914.928
73920.961
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)5p
3
P
2
1
0
74268.547
74269.600
74271.651
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)4d
5
Do
4
3
2
1
0
74973.14
74974.10
74975.19
74976.06
74976.61
MZM90
MZM90
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)4d
3
Do
1
2
3
75951.95
75952.35
75956.53
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)6s
5 o
2
76464.06
MZM90
P
D
S
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2025
Energy Levels of Neutral Sulfur 共S I兲—Continued
Term
J
Level (cm⫺1 )
Ref
3s 3p ( S )4 f
5
F
4
5
3
2
1
76654.767
76654.769
76654.794
76654.811
76654.847
MZM90
MZM90
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)4 f
3
F
4
3
2
76656.324
76656.330
76656.358
MZM90
MZM90
MZM90
3s 2 3p 3 ( 4 So)6s
3 o
S
1
76720.65
MZM90
3s 3p ( P )4s
3 o
P
0
1
2
77135.52
77150.14
77181.15
MZM90
MZM90
MZM90
3s 2 3p 3 ( 2 Do)4p
1
P
1
77854.906
MZM90
3s 2 3p 3 ( 2 Do)4p
3
D
2
1
3
78152.071
78152.336
78203.180
MZM90
MZM90
MZM90
3s 2 3p 3 ( 2 Po)4s
1 o
P
1
78288.44
MZM90
3s 3p ( D )4p
3
F
2
3
4
78409.89
78435.81
78463.04
MZM90
MZM90
MZM90
3s 2 3p 3 ( 2 Do)4p
1
F
3
78639.923
MZM90
3s 2 3p 3 ( 2 Do)4p
3
P
2
1
0
79375.80
79405.30
79418.01
MZM90
MZM90
MZM90
3s 2 3p 3 ( 2 Do)3d
1 o
1
81438.30
MZM90
Limit
83559.1
MZM90
Configuration
2
3 4 o
2
3 2 o
2
S II
3 2
o
P
o
)
( 4 S3/2
Persistent Lines of Singly-ionized Sulfur 共S II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
400
1250.578
0.463
900
1000
140
250
400
1253.805
1259.518
5428.667
5432.815
5453.828
0.462
0.465
0.42
0.68
0.85
Configuration
3s 2 3 p 3
3s3 p 4
3s 2 3 p 3
3s3 p 4
3s 2 3 p 3
3s3 p 4
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
3/2
1/2
0.00
79962.61
KM93
M03
4 o
S
P
3/2
3/2
0.00
79756.83
KM93
M03
4 o
S
P
3/2
5/2
0.00
79395.39
KM93
M03
P
Do
1/2
3/2
109560.69
127976.34
KM93
FW96
P
Do
3/2
5/2
109831.59
128233.20
KM93
FW96
P
Do
5/2
7/2
110268.60
128599.16
KM93
FW96
Term
4 o
4
4
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
4
4
4
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2026
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Sulfur 共S II兲—Continued
Wavelength 共Å兲
Inten
150
5473.620
150
5509.718
150
5606.151
150
5639.972
150
A ki (108 s⫺1 )
2
0.73
0.40
0.54
0.66
7578.909
120
7629.740
80
7967.371
120
8314.594
Configuration
0.080
0.16
2 3
J
Level (cm⫺1 )
Wl Ref
P
Do
1/2
1/2
109560.69
127825.08
KM93
FW96
P
Do
3/2
3/2
109831.59
127976.34
KM93
FW96
F
Do
9/2
7/2
110766.56
128599.16
KM93
FW96
P
Do
3/2
5/2
113461.54
131187.19
KM93
FW96
G
F
9/2
7/2
127128.35
140319.23
KM93
G
F
7/2
5/2
127127.10
140230.10
KM93
P
S
1/2
1/2
112937.57
125485.29
KM93
WSM69
P
S
3/2
1/2
113461.54
125485.29
KM93
WSM69
Term
3s 3 p ( P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)3d
3s 2 3 p 2 ( 3 P)4p
4
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
2
3s 2 3 p 2 ( 1 D)3d
3s 2 3 p 2 ( 1 D)4p
2
3s 2 3 p 2 ( 1 D)3d
3s 2 3 p 2 ( 1 D)4p
2
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
2
3s 2 3 p 2 ( 3 P)4s
3s 2 3 p 2 ( 3 P)4p
2
4
4
4
2
2 o
2 o
2 o
2 o
A Ref
Energy Levels of Singly-ionized Sulfur 共S II兲
Configuration
2
J
Level (cm⫺1 )
Ref
4 o
S
3/2
0.00
MZM90
3s 2 3p 3
2
Do
3/2
5/2
14852.94
14884.73
MZM90
MZM90
3s 2 3p 3
2 o
1/2
3/2
24524.83
24571.54
MZM90
MZM90
3s3 p 4
4
5/2
3/2
1/2
79395.39
79756.83
79962.61
MZM90
MZM90
MZM90
3s3p 4
2
D
3/2
5/2
97890.74
97918.86
MZM90
MZM90
3s 2 3p 2 ( 3 P)3d
2
P
3/2
1/2
105599.06
106044.24
MZM90
MZM90
3s 2 3p 2 ( 3 P)4s
4
P
1/2
3/2
5/2
109560.69
109831.59
110268.60
MZM90
MZM90
MZM90
3s 2 3p 2 ( 3 P)3d
4
F
3/2
5/2
7/2
9/2
110177.02
110313.40
110508.71
110766.56
MZM90
MZM90
MZM90
MZM90
3s 2 3p 2 ( 3 P)4s
2
P
1/2
3/2
112937.57
113461.54
MZM90
MZM90
3s 2 3p 2 ( 3 P)3d
4
D
1/2
3/2
5/2
7/2
114162.30
114200.54
114231.04
114279.33
MZM90
MZM90
MZM90
MZM90
3s 3p
3
Term
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2027
Energy Levels of Singly-ionized Sulfur 共S II兲—Continued
Configuration
2
2 3
Term
J
Level (cm⫺1 )
Ref
5/2
7/2
114804.37
115285.61
MZM90
MZM90
3s 3p ( P)3d
2
3s3p 4
2
S
1/2
119783.77
MZM90
3s 2 3p 2 ( 1 D)4s
2
D
3/2
5/2
121528.72
121530.02
MZM90
MZM90
3s 2 3p 2 ( 3 P)4p
2 o
S
1/2
125485.29
MZM90
3s 2 3p 2 ( 1 D)3d
2
G
7/2
9/2
127127.10
127128.35
MZM90
MZM90
3s 2 3p 2 ( 3 P)4p
4
Do
1/2
3/2
5/2
7/2
127825.08
127976.34
128233.20
128599.16
MZM90
MZM90
MZM90
MZM90
3s 2 3p 2 ( 3 P)4p
4 o
P
1/2
3/2
5/2
129787.83
129858.18
130134.16
MZM90
MZM90
MZM90
3s 2 3p 2 ( 3 P)3d
4
P
5/2
3/2
1/2
130602.21
130818.85
130948.94
MZM90
MZM90
MZM90
3s 2 3p 2 ( 3 P)4p
2
Do
3/2
5/2
130641.11
131187.19
MZM90
MZM90
3s 2 3p 2 ( 3 P)4p
4 o
S
3/2
131028.85
MZM90
3s 2 3p 2 ( 3 P)4p
2 o
P
1/2
3/2
133268.68
133399.97
MZM90
MZM90
3s 2 3p 2 ( 3 P)3d
2
D
3/2
5/2
133360.86
133814.84
MZM90
MZM90
3s 2 3p 2 ( 1 S)4s
2
S
1/2
136328.79
MZM90
3s 2 3p 2 ( 1 D)3d
2
F
5/2
7/2
138509.17
138527.98
MZM90
MZM90
3s 2 3p 2 ( 1 D)3d
2
P
1/2
3/2
139844.99
140016.77
MZM90
MZM90
3s 2 3p 2 ( 1 D)4p
2 o
5/2
7/2
140230.10
140319.23
MZM90
MZM90
Limit
188232.7
MZM90
S III ( 3 P0 )
F
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2028
J. E. SANSONETTI AND W. C. MARTIN
Tantalum „Ta…
Atomic number⫽73
Atomic weight⫽180.9479
Isotope
180
Ta
Ta
181
Mass
Abundance
Spin
Mag moment
179.947462
220.011368
0.012%
99.998%
9
7/2
⫹2.370
Ta I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 3 6s 2 4F3/2
Ionization energy: 60 891.4 cm⫺1 共7.549 57 eV兲
Ta II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 3 6s 5F1
Ionization energy: not available
Strong Lines of Tantalum 共Ta兲
Intensity
500
600
300
250
300
500
200
500
600
600
200
600*
600*
600
200
500
200
400
400
300
400
80
300
250
400
300
250
100
100
250
120
600
1000
140
200
250
200
250
200
250
P
P
P
P,d
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2140.13
2146.87
2150.62
2165.01
2178.03
2182.71
2193.20
2193.88
2196.03
2199.67
2207.14
2210.03
2210.19
2239.48
2249.79
2250.76
2258.71
2261.42
2262.30
2271.85
2272.59
2279.85
2285.25
2286.59
2289.16
2331.98
2332.19
2357.30
2361.09
2364.24
2371.58
2387.06
2400.63
2427.64
2432.70
2474.62
2484.95
2488.70
2490.46
2504.45
Spectrum
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
II
I
I
II
I
II
II
I
II
I
I
II
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
2029
Strong Lines of Tantalum 共Ta兲—Continued
Intensity
250
90
500
250
90
200
200
90
500
200
150
150
250
130
150
200
250
500
120
130
120
500
200
300
200
250
900
110
1000
700
600
250
300
250
600
130
100
200
90
400
200
500
1000
90
200
200
150
200
500
300
400
200
300
150
250
300
150
150
200
d
d
P
P
d
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
2507.45
2512.65
2526.35
2532.12
2546.80
2551.07
2554.62
2555.05
2559.43
2562.10
2573.54
2573.79
2577.37
2577.78
2593.08
2595.26
2603.49
2608.63
2611.34
2615.46
2615.66
2635.58
2636.67
2636.90
2646.22
2646.37
2647.47
2651.22
2653.27
2656.61
2661.34
2668.62
2675.90
2684.28
2685.17
2691.31
2692.40
2694.52
2696.81
2698.30
2706.69
2710.13
2714.67
2717.18
2720.76
2727.44
2727.78
2746.68
2748.78
2749.83
2758.31
2761.68
2775.88
2787.69
2796.34
2797.76
2802.07
2806.30
2806.58
Spectrum
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
I
I
I
II
I
I
II
I
I
I
I
I
II
I
I
I
II
I
I
I
I
II
I
I
I
I
I
II
I
I
I
I
II
I
II
I
I
II
I
I
I
I
I
I
I
II
I
I
I
I
I
II
I
I
I
II
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2030
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Tantalum 共Ta兲—Continued
Intensity
Wavelength 共Å兲
100
250
110 c
200
600 P
700 P
140
120
200
100
100
150
300
100
200
120
150
120
700 P
200
500
90
200
130
600 P
300
300
130
150
800 P
110 d
200
200
140
200
150
150
100
120
100
250
90
400 P
250
140 d
250
140
150
200
150
90
200
300
400
200
90
150
120
120
2842.82
2844.25
2845.35
2848.52
2850.49
2850.98
2861.98
2868.65
2871.42
2873.36
2873.56
2880.02
2891.84
2899.04
2902.05
2915.49
2925.19
2932.70
2933.55
2940.06
2940.22
2942.14
2951.92
2953.56
2963.32
2965.13
2965.54
2969.47
2975.56
3012.54
3027.48
3049.56
3069.24
3077.24
3103.25
3124.97
3130.58
3132.64
3170.29
3173.59
3180.95
3184.55
3311.16
3318.84
3330.99
3371.54
3385.05
3406.94
3480.52
3497.85
3503.87
3511.04
3607.41
3626.62
3642.06
3833.74
4061.40
4067.91
4205.88
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
II
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
2031
Strong Lines of Tantalum 共Ta兲—Continued
Intensity
Wavelength 共Å兲
140 d
130
100
150 P
130 P
90
90
100
100
80
150
80
4510.98
4574.31
4619.51
4681.88
5156.56
5877.36
5944.02
6045.39
6430.79
6450.36
6485.37
6866.23
Spectrum
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ref
I
I
I
I
I
I
I
I
I
I
I
I
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Tantalum 共Ta I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
3
Term
J
Level (cm⫺1 )
Wl Ref
2
4
F
17o
3/2
5/2
0.00
39059.52
MCS75
500
2559.43
5d 6s
500
2608.63
5d 3 6s 2
4
F
19o
5/2
7/2
2010.10
40333.03
MCS75
900
2647.47
5d 3 6s 2
4
F
15o
3/2
3/2
0.00
37760.67
MCS75
1000
2653.27
5d 3 6s 2
4
F
18o
5/2
5/2
2010.10
39688.20
MCS75
700
2656.61
5d 3 6s 2
4
F
14o
3/2
5/2
0.00
37630.09
MCS75
600
2661.34
5d 3 6s 2
4
F
20o
9/2
11/2
5621.04
43185.09
MCS75
400
2698.30
5d 3 6s 2
4
F
17o
5/2
5/2
2010.10
39059.52
MCS75
1000
2714.67
5d 3 6s 2
4
F
13o
3/2
5/2
0.00
36825.97
MCS75
400
2758.31
5d 3 6s 2
4
F
16o
5/2
5/2
2010.10
38253.39
MCS75
700
2850.98
5d 3 6s 2
5d 3 6s( 3 G)6p
4
F
4 o
9/2
9/2
5621.04
40686.42
MCS75
G
700
2933.55
5d 3 6s 2
4
F
10o
3/2
3/2
0.00
34078.42
MCS75
600
2963.32
5d 3 6s 2
4
F
11o
5/2
7/2
2010.10
35746.18
MCS75
400
3311.16
5d 3 6s 2
4
F
12o
9/2
11/2
5621.04
35813.47
MCS75
150
4681.88
5d 3 6s 2
5d 3 6s( 5 F)6p
4
F
4 o
5/2
5/2
2010.10
23363.09
MCS75
5d 3 6s 2
5d 3 6s( 5 F)6p
4
F
6 o
9/2
11/2
5621.04
25008.83
MCS75
130
5156.56
0.015
F
G
A Ref
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2032
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Tantalum 共Ta I兲
Configuration
3
Term
J
Level (cm⫺1 )
Ref
2
4
F
3/2
5/2
7/2
9/2
0.00
2010.10
3963.92
5621.04
M58
M58
M58
M58
5d 3 6s 2
4
P
1/2
3/2
5/2
6049.42
6068.91
9253.43
M58
M58
M58
5d 3 6s 2
2
G
7/2
9/2
9705.38
10690.32
M58
M58
1
3/2
10950.22
M58
5d 3 6s 2
2
P
1/2
3/2
11792.13
15903.77
M58
M58
5d 3 6s 2
2
D2
5/2
3/2
12865.97
25876.05
M58
DAGW97
5d 3 6s 2
2
H
11/2
9/2
15114.14
15391.01
M58
M58
5d 3 6s 2
2
F
5/2
17224.47
M58
7/2
17383.12
M58
F
5/2
23363.09
M58
Go
11/2
25008.83
M58
10o
3/2
34078.42
M58
6
Do
7/2
34094.66
M58
o
11
7/2
35746.18
M58
12o
11/2
35813.47
M58
13o
5/2
36825.97
M58
14o
5/2
37630.09
M58
o
15
3/2
37760.67
M58
16o
5/2
38253.39
M58
17o
5/2
39059.52
M58
o
18
5/2
39688.20
M58
19o
7/2
40333.03
M58
4
9/2
40686.42
M58
11/2
43185.09
M58
Limit
60891.4
SKJ94
5d 6s
3
5
5d 6s( F)6p
4 o
5d 3 6s( 5 F)6p
6
5d 3 6s( 5 P)6p
5d 3 6s( 3 G)6p?
Go?
20o
5
Ta II ( F1 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2033
Persistent Lines of Singly-ionized Tantalum 共Ta II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
3 4
Term
J
Level (cm⫺1 )
Wl Ref
600
2146.87
5d ( F)6s
5
F
9o
2
1
1031.36
47595.98
MCS75
600
2196.03
5d 3 ( 4 F)6s
5
F
13o
4
4
4415.79
49937.74
MCS75
600
2199.67
5d 3 ( 4 F)6s
5
F
6o
1
2
0.00
45446.85
MCS75
600*
2210.03
5d 3 ( 4 F)6s
5
F
5o
1
1
0.00
45233.91
MCS75
600*
2210.19
5d 3 ( 4 F)6s
5
F
12o
4
3
4415.79
49646.62
MCS75
600
2239.48
5d 3 ( 4 F)6s
5
F
11o
4
5
4415.79
49055.18
MCS75
5d 3 ( 4 F)6s
5
F
8o
3
4
2642.26
47280.89
600
2387.06
5d 3 ( 4 F)6s
5
F
7o
4
5
4415.79
46295.03
MCS75
1000
2400.63
5d 3 ( 4 F)6s
5
F
10o
5
6
6186.81
47829.75
MCS75
500
2635.58
5d 3 ( 4 F)6s
5
F
3o
2
3
1031.36
38962.32
MCS75
600
2685.17
5d 2 6s 2
3
P
4o
5
F
1o
0
1
1
2
4124.85
41355.11
0.00
37230.75
MCS75
3
1
2
5330.77
38515.55
MCS75
5d 3 ( 4 F)6s
800
5d 2 6s 2
3012.54
P
2o
A Ref
Energy Levels of Singly-ionized Tantalum 共Ta II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5d 3 ( 4 F)6s
5
1
2
3
4
5
0.00
1031.36
2642.26
4415.79
6186.81
K62a
K62a
K62a
K62a
K62a
5d 2 6s 2
3
2
3
4
3180.04
6831.31
9746.28
K62a
K62a
K62a
5d 2 6s 2
3
0
1
2
4124.85
5330.77
5657.90
K62a
K62a
K62a
F
F
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2034
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Tantalum 共Ta II兲—Continued
Term
J
Level (cm⫺1 )
F
2
3
4
9690.47
14581.07
18493.66
K62a
K62a
K62a
1o
2
37230.75
K62a
2o
2
38515.55
K62a
3o
3
38962.32
K62a
4o
1
41355.11
K62a
5o
1
45233.91
K62a
6o
2
45446.85
K62a
o
5
46295.03
K62a
8o
4
47280.89
K62a
9o
1
47595.98
K62a
10o
6
47829.75
K62a
o
2
49055.18
K62a
12o
3
49646.62
K62a
13o
4
49937.74
K62a
Configuration
3 4
5d ( F)6s
3
7
11
Ta III ( 4 F3/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
Ref
ATOMIC SPECTROSCOPIC DATA
2035
Technetium „Tc…
Atomic number⫽43
Atomic weight⫽98.9062
Isotope
97
Tc
Tc
99
Tc
98
Mass
Abundance
Spin
Mag moment
96.906364
97.907215
98.906254
0
0
0
9/2
6
9/2
⫹5.6847
Tc I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 5 5s 2 6S5/2
Ionization energy: 58 700 cm⫺1 共7.28 eV兲
Tc II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 5 5s 7S3
Ionization energy: 123 100 cm⫺1 共15.26 eV兲
Strong Lines of Technetium 共Tc兲
Intensity
200
1000
1000
150
100
200
1000
100
70
100
100
100
130
100
300
70
200
100
100
100
100
100
70
150
300
200
200
500
700
700
500
100
100
100
80
80
80
200
600
P
P,c
P,c
c
P
P
P
P,c
P
P
P,c
c
c
c
c
Wavelength 共Å兲
Air
2496.77
2543.23
2609.99
2614.23
2615.87
2634.91
2647.01
2652.35
2707.90
2708.78
2726.69
2782.05
2795.78
2802.81
2811.61
2821.35
2859.11
2887.73
2896.34
2913.15
2928.20
3099.10
3122.64
3131.23
3173.30
3182.37
3183.11
3195.20
3212.02
3237.02
3466.28
3475.59
3486.23
3500.70
3502.70
3525.83
3538.68
3541.77
3549.72
Spectrum
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
II
II
II
I
I
II
II
II
II
I
I
I
II
I
II
II
I
I
I
I
I
I
I
I
I
I
I
II
II
II
I
I
I
I
I
I
I
I
I
Ref
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2036
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Technetium 共Tc兲—Continued
Intensity
400
80
80
100
60
80
200
400
100
100
200
100
300
1000
100
90
100
60
100
100
500
70
80
800
120
150
400
100
500
100
400
100
200
500
300
200
300
100
60
150
80
80
100
60
60
400
200
500
100
50
30
100
1000
50
500
500
700
50
500
Wavelength 共Å兲
c
c
c
c
c
c
P,c
c
c
P
c
c
c
P,c
P,c
c
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3550.64
3560.32
3568.85
3580.06
3581.26
3582.08
3582.63
3587.94
3595.66
3607.32
3608.27
3627.36
3635.15
3636.07
3638.22
3639.38
3648.04
3651.47
3658.59
3679.15
3684.74
3703.83
3712.26
3718.86
3723.67
3724.40
3726.35
3746.15
3746.84
3752.13
3754.37
3758.54
3761.81
3768.77
3771.03
3779.37
3780.68
3797.77
3832.82
3837.56
3841.31
3845.97
3868.24
3880.72
3899.83
3946.57
3947.09
3984.97
3994.51
4012.00
4017.22
4020.76
4031.63
4039.25
4049.11
4088.71
4095.67
4110.22
4115.08
Spectrum
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
ATOMIC SPECTROSCOPIC DATA
2037
Strong Lines of Technetium 共Tc兲—Continued
Intensity
30
400
50
40
300
150
500
50
200
250
50
40
500
800
40
200
30
1000
40
40
120
40
400
80
30
40
80
40
40
40
40
120
80
80
80
40
80
150
400
40
150
400
40
40
800
400
300
40
80
250
300
150
150
80
70
50
300
200
150
P,c
P
P
c
c
P
c
c
Wavelength 共Å兲
4119.27
4124.22
4128.27
4139.85
4144.95
4145.08
4165.61
4169.68
4170.27
4172.53
4176.28
4186.51
4238.19
4262.27
4262.69
4274.97
4278.90
4297.06
4429.59
4481.53
4487.06
4515.98
4522.84
4539.53
4552.85
4557.05
4564.54
4578.45
4593.35
4616.86
4630.57
4637.50
4648.33
4660.21
4669.30
4706.92
4717.77
4719.28
4740.61
4752.72
4771.54
4820.74
4834.37
4835.39
4853.59
4866.73
4891.92
4908.51
4909.57
4976.34
5096.28
5161.81
5174.81
5275.51
5285.07
5320.20
5589.02
5620.45
5642.13
Spectrum
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2038
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Technetium 共Tc兲—Continued
Wavelength 共Å兲
Intensity
80
70
100
60
80
100
100
80
60
100
60
60
80
80
80
Spectrum
5644.94
5725.31
5924.47
5931.93
6085.23
6120.68
6130.80
6192.66
6244.18
6455.90
6461.93
7452.49
7540.26
7793.04
7817.72
c
c
c
c
c
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Tc
Ref
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
BMC67
Persistent Lines of Neutral Technetium 共Tc I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5
2
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
6
300
3173.30
0.86
4d 5s
4d 6 ( 5 D)5p
a S
y 4Po
5/2
3/2
0.00
31503.93
BMC67
PW99
200
3182.37
0.39
4d 5 5s 2
4d 6 ( 5 D)5p
a 6S
y 4Po
5/2
7/2
0.00
31414.05
BMC67
PW99
200
3183.11
0.56
4d 5 5s 2
4d 6 ( 5 D)5p
a 6S
y 4Po
5/2
5/2
0.00
31406.74
BMC67
PW99
500
3466.28
1.22
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
y 4Po
9/2
7/2
2572.89
31414.05
BMC67
PW99
1000
3636.07
1.57
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Fo
9/2
11/2
2572.89
30067.29
BMC67
PW99
800
3718.86
1.05
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Fo
7/2
9/2
3250.91
30133.26
BMC67
PW99
500
3984.97
0.42
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
9/2
7/2
2572.89
27660.10
BMC67
PW99
1000
4031.63
1.01
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
9/2
9/2
2572.89
27369.79
BMC67
PW99
700
4095.67
0.49
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 6D
z 6Do
7/2
7/2
3250.91
27660.10
BMC67
PW99
500
4238.19
0.38
4d 5 5s 2
4d 5 5s( 7 S)5s
a 6S
z 6Po
5/2
3/2
0.00
23588.40
BMC67
PW99
800
4262.27
0.40
4d 5 5s 2
4d 5 5s( 7 S)5s
a 6S
z 6Po
5/2
5/2
0.00
23455.21
BMC67
PW99
1000
4297.06
0.42
4d 5 5s 2
4d 5 5s( 7 S)5s
a 6S
z 6Po
5/2
7/2
0.00
23265.32
BMC67
PW99
800
4853.59
0.49
4d 6 ( 5 D)5s
4d 6 ( 5 D)5p
a 4D
z 4Fo
7/2
9/2
10516.53
31114.08
BMC67
PW99
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2039
Energy Levels of Neutral Technetium 共Tc I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
4d 5 5s 2
a 6S
5/2
0.00
BCT68
4d 6 ( 5 D)5s
a 6D
9/2
7/2
5/2
3/2
1/2
2572.89
3250.91
3700.54
4002.57
4178.75
BCT68
BCT68
BCT68
BCT68
BCT68
4d 6 ( 5 D)5s
a 4D
7/2
5/2
3/2
1/2
10516.53
11063.07
11578.60
11890.70
BCT68
BCT68
BCT68
PW99
4d 5 5s( 7 S)5p
z 8Po
5/2
7/2
9/2
16428.71
16874.51
17522.92
BCT68
BCT68
BCT68
4d 5 5s( 7 S)5p
z 6Po
7/2
5/2
3/2
23265.32
23455.21
23588.40
BCT68
BCT68
BCT68
4d 6 ( 5 D)5p
z 6Do
9/2
7/2
5/2
3/2
1/2
27369.79
27660.10
27940.73
28151.28
28296.67
BCT68
BCT68
BCT68
BCT68
BCT68
4d 6 ( 5 D)5p
z 6Fo
11/2
9/2
7/2
5/2
3/2
1/2
30067.29
30133.26
30382.06
30528.86
30630.62
30689.12
BCT68
BCT68
BCT68
BCT68
BCT68
BCT68
4d 6 ( 5 D)5p
z 4Fo
9/2
5/2
5/2
3/2
31114.08
31605.00
32014.81
32253.65
BCT68
BCT68
BCT68
BCT68
4d 6 ( 5 D)5p
y 6Po
5/2
7/2
3/2
31406.74
31414.05
31503.93
BCT68
BCT68
BCT68
58700
M58
Tc II ( 7 S3 )
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2040
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Technetium 共Tc II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
5 6
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
7
1000
2543.23
4.1
4d ( S)5s
4d 5 ( 6 S)5p
a S
z 7Po
3
4
0.00
39308.38
BMC67
B88
1000
2609.99
3.8
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 7S
z 7Po
3
3
0.00
38302.80
BMC67
B88
1000
2647.01
3.7
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 7S
z 7Po
3
2
0.00
37767.21
BMC67
B88
500
3195.20
2.0
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 5S
z 5Po
2
1
12617.20
43905.00
BMC67
B88
700
3212.02
1.9
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 5S
z 5Po
2
2
12617.20
43741.33
BMC67
B88
700
3237.02
1.9
4d 5 ( 6 S)5s
4d 5 ( 6 S)5p
a 5S
z 5Po
2
3
12617.20
43500.96
BMC67
B88
Energy Levels of Singly-ionized Technetium 共Tc II兲
Configuration
5 6
Term
J
Level (cm⫺1 )
Ref
4d ( S)5s
7
a S
3
0.00
M58
4d 6
a 5D
4
3
2
1
0
3461.27
4217.17
4669.22
4961.14
5100.98
M58
M58
M58
M58
M58
4d 5 ( 6 S)5s
a 5S
2
12617.20
M58
4d ( S)5p
7 o
z P
2
3
4
37767.21
38302.80
39308.38
M58
M58
M58
4d 5 ( 6 S)5p
z 5Po
3
2
1
43500.96
43741.33
43905.00
M58
M58
M58
5 6
Tc III ( 6 S5/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
123100
M58
ATOMIC SPECTROSCOPIC DATA
2041
Tellurium „Te…
Atomic number⫽52
Atomic weight⫽127.60
Isotope
122
Te
Te
124
Te
125
Te
126
Te
128
Te
130
Te
123
Mass
Abundance
Spin
121.903054
122.904271
123.902823
124.904433
125.903314
127.904463
129.906229
2.57%
0.89%
4.76%
7.10%
18.89%
31.73%
33.97%
0
1/2
0
1/2
0
0
0
Mag moment
⫺0.7359
⫺0.8871
Te I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 4 3P2
Ionization energy: 72 667 cm⫺1 共9.0096 eV兲
o
Te II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 3 4S3/2
Ionization energy: 150 000 cm⫺1 共18.6 eV兲
Strong Lines of Tellurium 共Te兲
Intensity
40
40
40
50
60
40
40
40
40
50
40
50
50
50
500
500
500
1000
250
700
120
14
15
5
20
5
100
50
60
250
5
100
50
50
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
802.28
1059.51
1077.66
1174.34
1175.79
1208.54
1220.98
1253.62
1270.52
1324.92
1363.24
1374.80
1608.41
1613.15
1822.155
1857.296
1994.839
Air
2002.028
2081.172
2142.822
2147.260
2159.864
2215.630
2255.507
2259.034
2265.536
2373.06
2383.277
2385.792
2438.69
2530.738
2567.82
2574.96
2591.12
Spectrum
Ref
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
MV75
MV75
MV75
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
I
I
I
I
I
I
I
I
I
II
I
I
II
I
II
II
II
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
HM64
MV75
MV75
HM64
MV75
HM64
HM64
HM64
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2042
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Tellurium 共Te兲—Continued
Intensity
50
50
50
500
4
500
800
400
400
4
800
250
500
250
500
500
800
800
500
500
900
1000
500
500
500
500
500
800
800
600
1000
800
800
500
1000
800
500
120
200
20
25
250
150
30
70
400
250
60
40
60
90
140
80
110
40
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
2592.85
2605.72
2624.86
2649.66
2677.13
2858.29
2895.41
2967.29
3047.00
3175.147
3406.79
3521.11
3611.78
4006.52
4169.77
4261.11
4364.00
4478.63
4557.78
4641.12
4654.37
4686.91
4696.38
4706.53
4766.05
4784.87
4827.14
4831.28
4842.90
4865.12
4866.24
5576.35
5649.26
5666.20
5708.12
5755.85
5974.68
8758.183
9722.742
9868.92
9956.30
10051.41
10091.01
10493.57
10918.34
11089.56
11487.23
13247.75
14513.51
15452.45
15546.23
16403.90
17303.54
18291.59
21043.73
Spectrum
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
HM64
HM64
HM64
HM64
MCS75
HM64
HM64
HM64
HM64
MV75
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
HM64
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
MV75
ATOMIC SPECTROSCOPIC DATA
2043
Persistent Lines of Neutral Tellurium 共Te I兲
Inten
Wavelength 共Å兲
500
0.40
2385.792
200
250
0.13
2383.277
60
MV75
1
2
4750.712
58592.434
MV75
1
2
4750.712
54880.070
MV75
1
1
4750.712
54683.886
MV75
2
2
10557.877
58592.434
MV75
2
1
0.000
46652.738
MV75
2
2
10557.877
57114.206
MV75
2
2
0.000
44253.000
MV75
M00
0
1
4706.500
46652.738
MV75
M00
P
S
1
1
4750.712
46652.738
MV75
M00
5p 3 ( 4 S)6s
5 p 3 ( 4 S)6p
5 o
S
P
2
3
44253.000
54535.345
MV75
5p 3 ( 4 S)6s
5 p 3 ( 4 S)6p
5 o
S
P
2
2
44253.000
54199.122
MV75
5p 3 ( 4 S)6s
5 p 3 ( 4 S)6p
3 o
S
P
1
2
46652.738
55667.758
MV75
5p 3 ( 4 S)6s
5 p 3 ( 4 S)6p
3 o
1
1
46652.738
55355.672
MV75
5p 4
5p 3 ( 4 S)6s
0.81
9722.742
10051.41
11089.56
11487.23
3
P
Do
3
3
P
Do
3
3
P
Do
3
3
P
Do
1
3
D
Do
3
P
S
3 o
5p 4
5p 3 ( 2 D)6s
2259.034
50
400
3.11
2147.260
20
0.000
54880.070
5p 4
5p 3 ( 4 S)5d
2142.822
120
2
2
5p 4
5p 3 ( 2 D)6s
2081.172
700
Wl Ref
3
5p 4
5p 3 ( 2 D)6s
2002.028
250
Level (cm⫺1 )
5p 4
5p 3 ( 4 S)5d
1994.839
1000
J
5p
5p 3 ( 2 D)6s
1857.296
500
Term
Configuration
4
1822.155
500
250
A ki (108 s⫺1 )
5p 4
5p 3 ( 4 S)6s
1
1
D
Do
3
P
S
5 o
5p 4
5p 3 ( 4 S)6s
3
P
S
3 o
5p 4
5p 3 ( 4 S)6s
3
3 o
5
5
3
3
S
P
A Ref
M00
Energy Levels of Neutral Tellurium 共Te I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
5p4
3
2
0
1
0.000
4706.500
4750.712
MV75
MV75
MV75
5p 4
1
2
10557.877
MV75
4
1
S
0
23198.392
MV75
5p 3 ( 4 S)6s
5 o
S
2
44253.000
MV75
5p 3 ( 4 S)6s
3 o
S
1
46652.738
MV75
5p 3 ( 4 S)6p
5
P
1
2
3
54160.094
54199.122
54535.345
MV75
MV75
MV75
5p
P
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2044
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Tellurium 共Te I兲—Continued
Term
J
Level (cm⫺1 )
Ref
5 p ( D)6s
3
D
1
2
54683.886
54880.070
MV75
MV75
5p 3 ( 4 S)6p
3
P
1
2
0
55355.672
55667.758
55809.132
MV75
MV75
MV75
5p 3 ( 4 S)5d
5
Do
3
4
2
0
1
55677.722
55816.219
55817.311
55826.538
55851.533
MV75
MV75
MV75
MV75
MV75
5p 3 ( 2 D)6s
1
Do
2
57114.206
MV75
5p 3 ( 4 S)5d
3
Do
2
1
3
58592.434
58746.074
58826.951
MV75
MV75
MV75
72667
M58
Configuration
3 2
o
o
)
Te II ( 4 S3/2
Limit
Persistent Lines of Singly-ionized Tellurium 共Te II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
2
3
J
Level (cm⫺1 )
Wl Ref
4 o
S
17
3/2
5/2
0.000
92793.22
HM64
Term
40
1077.66
5s 5 p
50
1174.34
5s 2 5 p 3
4 o
S
7
3/2
3/2
0.000
85159.66
HM64
60
1175.79
5s 2 5 p 3
4 o
S
6
3/2
5/2
0.000
85049.41
HM64
50
1324.92
5s 2 5 p 3
2
Do
11
5/2
7/2
12421.854
87899.86
HM64
250
3521.11
5s5 p 4
5s 2 5 p 2 ( 3 P)6p
4
P
20o
5/2
3/2
71192.53
99584.59
HM64
250
4006.52
5s5p 4
5s 2 5 p 2 ( 3 P)6p
4
5/2
3/2
71192.53
96144.74
HM64
900
800
1000
4654.37
P
Do
1
S
2 o
1/2
1/2
76300.87
97780.09
HM64
5s 2 5 p 2 ( 3 P)6p
2
Do
4
1/2
3/2
78448.22
96144.74
HM64
5s 2 5 p 2 ( 3 P)6p
8
Do
4
5/2
7/2
85591.83
103105.86
HM64
5s 2 5 p 2 ( 3 P)6p
5649.26
5708.12
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4
A Ref
ATOMIC SPECTROSCOPIC DATA
2045
Energy Levels of Singly-ionized Tellurium 共Te II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
2
5s 5p
3
4 o
3/2
0.000
E74
2
3
2
o
D
3/2
5/2
10222.385
12421.854
E74
E74
5s 2 5p 3
2 o
1/2
3/2
20546.591
24032.095
E74
E74
5s5 p 4
4
5/2
3/2
71192.53
74893.40
E74
E74
1
1/2
76300.87
HM64
2
1/2
78448.22
HM64
3
3/2
81895.43
HM64
4
3/2
82743.33
HM64
5
1/2
83577.41
HM64
6
5/2
85049.41
HM64
7
3/2
85159.66
HM64
8
5/2
85591.83
HM64
9
3/2
86759.90
HM64
10
5/2
87404.54
HM64
11
7/2
87899.86
HM64
12
1/2
88796.16
HM64
13
9/2
90519.67
HM64
14
7/2
90797.21
HM64
15
3/2
92191.47
HM64
16
1/2
92691.51
HM64
17
5/2
92793.22
HM64
5s 2 5p 2 ( 3 P)6p
4
Do
1/2
3/2
5/2
7/2
93978.93
96144.74
100112.10
103105.86
HM64
HM64
HM64
HM64
5s 2 5p 2 ( 3 P)6p
2 o
S
1/2
97780.09
HM64
5s 2 5p 2 ( 3 P)6p
20o
3/2
99584.59
HM64
5s 2 5p 2 ( 3 P)6p
21o
3/2
101220.97
HM64
5s 5p ( P)6p
4 o
P
1/2
101370.86
HM64
5s 2 5p 2 ( 3 P)6p
22o
5/2
102324.49
HM64
5s 2 5p 2 ( 3 P)6p
23o
3/2
103935.90
HM64
5s 2 5p 2 ( 3 P)6p
2 o
3/2
105006.08
HM64
5s 5p ( P)6p
o
24
5/2
105583.02
HM64
5s 2 5p 2 ( 3 P)6p
2 o
1/2
106119.20
HM64
150000
M58
5s 5p
2
2
S
P
P
2 3
2 3
Te III ( 3 P0 )
P
P
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2046
J. E. SANSONETTI AND W. C. MARTIN
Terbium „Tb…
Atomic number⫽65
Atomic weight⫽158.92534
Isotope
159
Tb
Mass
Abundance
Spin
Mag moment
158.925342
100%
3/2
⫹1.95
o
Tb I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 9 6s 2 6H15/2
⫺1
Ionization energy: 47 294 cm 共5.8638 eV兲
o
)6s (15/2,1/2) o8
Tb II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 9 ( 6 H15/2
⫺1
Ionization energy: 92 900 cm 共11.52 eV兲
Strong Lines of Terbium 共Tb兲
Intensity
120
200
200
200
250
700
1000
250
200
600
700
300
200
300
400
400
700
800
400
200
200
300
400
500
150
600
600
400
500
400
300
300
300
400
400
200
200
200
700
200
1000
P
P
P
P
P
P
P
P
P
d
P
P
P
d
P
P,w
P
P
P,d
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
3078.905
3218.925
3219.982
3285.030
3293.065
3324.413
3509.146
3523.679
3540.270
3561.708
3568.513
3568.970
3579.227
3600.410
3650.421
3658.891
3676.363
3702.856
3703.930
3711.768
3755.251
3765.136
3776.489
3830.261
3842.471
3848.740
3874.172
3899.197
3901.325
3976.845
3981.875
4005.474
4032.284
4033.027
4061.558
4144.412
4203.749
4266.340
4318.847
4322.224
4326.472
Spectrum
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
II
I
II
I
II
I
I
I
I
I
Ref
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
B01
ATOMIC SPECTROSCOPIC DATA
2047
Strong Lines of Terbium 共Tb兲—Continued
Wavelength 共Å兲
Intensity
200
300
200
600
250
300
140
40
40
50
40
70
60
40
50
25
30
Spectrum
4332.117
4336.455
4337.646
4338.435
4340.609
4356.837
4493.077
4578.69
4641.98
4645.31
4702.41
4752.53
4786.78
5228.12
5354.88
6794.58
8212.57
P
P
P
P
P
P
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Tb
Ref
I
I
I
I
I
I
I
II
II
II
II
II
I
I
I
II
I
B01
B01
B01
B01
B01
B01
B01
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
Persistent Lines of Neutral Terbium 共Tb I兲
Inten
Wavelength 共Å兲
500
3830.261
A ki (108 s⫺1 )
Configuration
4 f 8 ( 7 F)5d6s 2
J
Level (cm⫺1 )
G
13/2
15/2
285.530
26386.005
B01
G
15/2
17/2
462.120
26087.175
B01
D
11/2
11/2
2310.120
27102.955
B01
G
15/2
15/2
462.120
25076.265
B01
Term
8
o
500
300
3901.325
4032.284
4 f 8 ( 7 F)5d6s 2
4 f 8 5d6s6 p?
4 f 8 ( 7 F)5d6s 2
8
o
8
o
400
4061.558
4 f 8 ( 7 F)5d6s 2
8
o
Wl Ref
700
4318.847
4 f 9 6s 2
o
)6s6p( 1 Po1 )
4 f 9 ( 6 H15/2
6
Ho
共15/2,1兲
15/2
15/2
0.000
23147.820
B01
1000
4326.472
4 f 9 6s 2
o
)6s6p( 1 Po1 )
4 f 9 ( 6 H15/2
6
Ho
共15/2,1兲
15/2
17/2
0.000
23107.025
B01
300
4336.455
4 f 9 6s 2
o
)6s6p( 1 Po1 )
4 f 9 ( 6 H13/2
6
Ho
共13/2,1兲
13/2
15/2
2771.675
25825.505
B01
600
4338.435
4 f 9 6s 2
o
)6s6p( 1 Po1 )
4 f 9 ( 6 H15/2
6
Ho
共15/2,1兲
15/2
13/2
0.000
23043.310
B01
300
4356.837
4 f 9 6s 2
o
)6s6p( 1 Po1 )
4 f 9 ( 6 H13/2
6
Ho
共13/2,1兲
13/2
13/2
2771.675
25717.655
B01
50
5354.88
4 f 8 ( 7 F)5d6s 2
4 f 8 5d6s6 p?
8
15/2
17/2
462.120
19131.480
MCS75
o
G
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2048
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Terbium 共Tb I兲
Configuration
9
4 f 6s
2
Term
6
o
H
4 f 8 ( 7 F)5d6s 2
8
G
4 f 8 ( 7 F)5d6s 2
J
Level (cm⫺1 )
15/2
13/2
11/2
9/2
7/2
5/2
0.000
2771.675
4670.450
6174.920
—
—
B01
B01
B01
B01
13/2
15/2
11/2
7/2
9/2
5/2
3/2
1/2
285.530
462.120
509.855
2419.470
2840.170
3174.575
3705.790
4018.160
B01
B01
B01
B01
B01
B01
B01
B01
Ref
9/2
1371.050
B01
2
8
11/2
7/2
5/2
3/2
2310.120
3819.850
4695.495
5483.985
B01
B01
B01
B01
4 f 8 ( 7 F)5d6s 2
8
13/2
11/2
9/2
1/2
7/2
5/2
3/2
3719.720
5353.370
5829.845
6259.095
6488.275
6801.175
6849.725
B01
B01
B01
B01
B01
B01
B01
4 f 8 ( 7 F)5d6s 2
8
17/2
15/2
13/2
11/2
9/2
7/2
5/2
3/2
4646.825
5425.065
6351.750
6988.795
7441.020
7839.820
8130.685
8336.310
B01
B01
B01
B01
B01
B01
B01
B01
4 f 8 5d6s6p?
o
17/2
19131.480
B01
共15/2,1兲
13/2
17/2
15/2
23043.310
23107.025
23147.820
B01
B01
B01
o
15/2
25076.265
B01
o
)6s6p( 1 Po1 )
4 f 9 ( 6 H13/2
共13/2,1兲
11/2
13/2
15/2
25637.845
25717.655
25825.505
B01
B01
B01
4 f 8 5d6s6p?
o
17/2
26087.175
B01
o
15/2
26386.005
B01
o
11/2
27102.955
B01
Limit
47296
WSPC78
8 7
4 f ( F)5d6s
9 6
4f (
o
)6s6p( 1 Po1 )
H15/2
D
F
H
Tb II (15/2,1/2) o8
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2049
Persistent Lines of Singly-ionized Terbium 共Tb II兲
Inten
700
Wavelength 共Å兲
A ki (108 s⫺1 )
3509.146
600
3561.708
700
3568.513
400
3650.421
Level (cm⫺1 )
8
9
3423.295
33495.130
B01
o
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
8
9
0.000
28488.810
B01
o
)6s 1/2
4 f 9 ( 6 H13/2
9 6 o
4 f ( H13/2)6p 3/2
(13/2,1/2) o
共13/2,3/2兲
7
8
3010.050
31078.460
B01
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
8
8
0.000
28014.875
B01
4 f 8 ( 7 F)5d( 8 G)6s
4 f 8 5d6 p?
9
8
8
3423.295
30809.590
B01
o
8 7
8
4 f ( F)5d( G)6s
3324.413
1000
J
Configuration
0.537
1.13
Term
9
G
G
Wl Ref
A Ref
M00
M00
400
3658.891
1.71
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
7
6
1016.380
28339.285
B01
M00
700
3676.363
1.19
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
7
7
1016.380
28209.430
B01
M00
800
3702.856
0.619
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 3/2
(15/2,1/2) o
共15/2,3/2兲
7
8
1016.380
28014.875
B01
M00
400
3703.930
4 f 8 ( 7 F)5d( 8 G)6s
4 f 8 5d6 p?
9
7
7
3235.190
30225.865
B01
o
6
5
3440.825
29992.75
B01
o
6
6
3440.825
29912.930
B01
o
300
400
G
4 f 8 ( 7 F)5d( 8 G)6s
3765.136
4 f 8 ( 7 F)5d( 8 G)6s
4 f 8 5d6 p?
3776.489
600
3848.740
0.543
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 1/2
(15/2,1/2) o
共15/2,1/2兲
8
8
0.000
25975.160
B01
M00
600
3874.172
1.00
o
)6s 1/2
4 f 9 ( 6 H15/2
o
4 f 9 ( 6 H15/2
)6p 1/2
(15/2,1/2) o
共15/2,1/2兲
8
7
0.000
25804.650
B01
M00
400
3899.197
o
)6s 1/2
4 f 9 ( 6 H13/2
9 6 o
4 f ( H13/2)6p 1/2
(13/2,1/2) o
共13/2,1/2兲
7
7
3010.050
28649.095
B01
400
3976.845
o
)6s 1/2
4 f 9 ( 6 H15/2
(15/2,1/2) o
8
8
0.000
25138.450
B01
400
4033.027
o
)6s 1/2
4 f 9 ( 6 H15/2
9 6 o
4 f ( H15/2)6p 1/2
(15/2,1/2) o
共15/2,1/2兲
7
7
1016.380
25804.650
B01
50
4645.31
o
)6s 1/2
4 f 9 ( 6 H15/2
(15/2,1/2) o
8
7
0.000
21521.040
MCS75
70
4752.53
o
)6s 1/2
4 f 9 ( 6 H15/2
(15/2,1/2) o
8
8
0.000
21035.530
MCS75
0.374
M00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2050
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Terbium 共Tb II兲
J
Level (cm⫺1 )
Ref
o
8
7
0.000
1016.380
B01
B01
o
)6s 1/2
4 f 9 ( 6 H13/2
(13/2 ,1/2) o
7
6
3010.050
3542.400
B01
B01
4 f 8 ( 7 F)5d( 8 G)6s
9
7
8
3235.190
3423.295
B01
B01
6
3440.825
B01
5
4158.785
B01
Configuration
9 6
4f (
o
H15/2
)6s 1/2
Term
(15/2 ,1/2)
G
4 f 8 ( 7 F)5d( 8 G)6s
8 7
8
4 f ( F)5d( G)6s
8
21035.56
B01
7
21521.06
B01
8
25138.450
B01
o
H15/2
)6p 1/2
共15/2 ,1/2兲
7
8
25804.650
25975.160
B01
B01
o
)6p 3/2
4 f 9 ( 6 H15/2
共15/2 ,3/2兲
8
7
6
9
28014.875
28209.430
28339.285
28488.810
B01
B01
B01
B01
o
)6p 1/2
4 f 9 ( 6 H13/2
共13/2 ,1/2兲
7
28649.095
B01
4 f 8 5d6p?
o
6
29912.930
B01
o
5
29992.75
B01
4 f 8 5d6p?
o
7
30225.865
B01
4 f 8 5d6p?
o
8
30809.590
B01
o
)6p 3/2
4 f 9 ( 6 H13/2
共13/2 ,3/2兲
8
31078.460
B01
o
9
33495.130
B01
92900
SR65
9 6
4f (
o
)
Tb III ( 6 H15/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
2051
Thallium „Tl…
Atomic number⫽81
Atomic weight⫽204.3833
Isotope
203
Tl
Tl
205
Mass
Abundance
Spin
Mag moment
202.972320
204.974401
29.52%
70.48%
1/2
1/2
⫹1.6223
⫹1.6382
Tl I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 2P1/2
Ionization energy: 49 265.91 cm⫺1 共6.108 194 eV兲
Tl II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 1S0
Ionization energy: 16 4765 cm⫺1 共20.4283 eV兲
Strong Lines of Thallium 共Tl兲
Intensity
500
300
500
500
800
500
300
400
700
800
r
r
r
r
P,r
r
P,r
P,r
5
5
1000
7
40
700
40
20
200
14
140
20
700
500
500
500
60
500
500
1000
250
600
700
1000
700
500
800
800
900
r
r
P
P,r
P,h
P
P
P,d
P
P
P
P
P
P,c,w
P
P
P
Wavelength 共Å兲
Vacuum
696.30
817.18
1162.55
1307.50
1321.644
1561.58
1792.827
1814.776
1881.121
1908.617
Air
2007.56
2210.71
2298.058
2315.98
2379.69
2530.740
2580.14
2709.23
2767.87
2826.16
2918.32
2921.52
3091.570
3185.51
3186.56
3187.74
3229.75
3291.01
3369.15
3519.24
3529.43
3775.72
4274.98
4306.80
4737.05
4981.35
5078.54
5152.14
5350.46
Spectrum
Ref
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
II
II
II
II
II
II
II
II
II
II
ES36
ES36
ES36
ES36
JKBL96
ES36
JKBL96
JKBL96
JKBL96
JKBL96
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
I
I
II
I
I
II
I
I
I
I
I
I
II
II
II
II
I
II
II
I
I
I
II
II
II
II
II
II
I
C52
C52
JKBL96
MCS75
MCS75
JKBL96
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
JKBL96
ES36
ES36
ES36
MCS75
ES36
ES36
MCS75
MCS75
MCS75
ES36
ES36
ES36
ES36
ES36
ES36
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2052
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Thallium 共Tl兲—Continued
Wavelength 共Å兲
Intensity
500
800
700
1
50
40
d
P
Spectrum
5384.85
5949.48
9130.
9130.5
11512.82
13013.2
P
P
Tl
Tl
Tl
Tl
Tl
Tl
Ref
II
II
II
I
I
I
ES36
ES36
ES36
MM52
MM52
MM52
Persistent Lines of Neutral Thallium 共Tl I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
2379.69
0.44
40
40
2580.14
200
2767.87
140
2918.32
60
3229.75
1000
3519.24
250
3529.43
600
3775.72
900
5350.46
50
0.18
1.26
0.42
0.173
1.24
0.220
0.625
0.795
11512.82
40
13013.2
J
Level (cm⫺1 )
Wl Ref
A Ref
P
D
1/2
3/2
0.0
42011.4
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 8s
2 o
P
S
1/2
1/2
0.0
38745.9
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 6d
2 o
P
D
1/2
3/2
0.0
36117.9
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 7d
2 o
P
D
3/2
5/2
7792.7
42049.0
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 8s
2 o
P
S
3/2
1/2
7792.7
38745.9
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 6d
2 o
P
D
3/2
5/2
7792.7
36199.9
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 6d
2 o
P
D
3/2
3/2
7792.7
36117.9
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 7s
2 o
P
S
1/2
1/2
0.0
26477.5
MCS75
FW96
5d 106s 2 6 p
5d 106s 2 7s
2 o
P
S
3/2
1/2
7792.7
26477.5
MCS75
FW96
5d 106s 2 7s
5d 106s 2 7 p
2
S
P
1/2
3/2
26477.5
35161.1
MM52
5d 106s 2 7s
5d 106s 2 7 p
2
S
P
1/2
1/2
26477.5
34159.9
MM52
Configuration
Term
5d 106s 2 6 p
5d 106s 2 7d
2 o
2
2
2
2
2
2
2
2
2
2 o
2 o
Energy Levels of Neutral Thallium 共Tl I兲
J
Level (cm⫺1 )
Ref
5d 6s 6p
2 o
P
1/2
3/2
0.0
7792.7
M58
M58
5d 106s 2 7s
2
S
1/2
26477.5
M58
5d 106s 2 7p
2 o
P
1/2
3/2
34159.9
35161.1
M58
M58
5d 106s 2 6d
2
D
3/2
5/2
36117.9
36199.9
M58
M58
5d 106s 2 8s
2
S
1/2
38745.9
M58
Configuration
10
2
Term
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2053
Energy Levels of Neutral Thallium 共Tl I兲—Continued
J
Level (cm⫺1 )
2 o
P
1/2
3/2
41368.1
41740.8
M58
M58
2
D
3/2
5/2
42011.4
42049.0
M58
M58
Limit
49265.91
BC85
Configuration
Term
5d 106s 2 8p
5d 106s 2 7d
Tl II ( 1 S0 )
Ref
Persistent Lines of Singly-ionized Thallium 共Tl II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
16.9
Configuration
10
2
5d 6s
5d 106s6 p
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
1
S
P
0
1
0.00
75663.33
JKBL96
C00
800
1321.644
300
1792.827
5d 106s6 p
5d 106s7s
3 o
P
S
0
1
49451.45
105229.28
JKBL96
400
1814.776
5d 106s6 p
5d 106s6d
3 o
P
D
2
3
61727.68
116830.90
JKBL96
800
1908.617
S
P
0
1
0.00
52393.96
JKBL96
1000
2298.058
5d 106s6 p
5d 106s7s
3 o
P
S
2
1
61727.68
105229.28
JKBL96
700
2530.740
5d 106s6 p
5d 106s6d
1 o
P
D
1
2
75663.33
115165.60
JKBL96
700
3091.570
5d 106s6 p
5d 106s7s
1 o
1
0
75663.33
107999.96
JKBL96
0.26
1.18
1 o
3
3
5d 106s 2
5d 106s6 p
1
3 o
3
1
1
P
S
C00
C00
Energy Levels of Singly-ionized Thallium 共Tl II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
5d 106s 2
1
S
0
0.00
JKBL96
5d 106s6p
3 o
P
0
1
2
49451.45
52393.96
61727.68
JKBL96
JKBL96
JKBL96
5d 106s6p
1 o
P
1
75663.33
JKBL96
5d 106s7s
3
S
1
105229.28
JKBL96
5d 6s7s
1
S
0
107999.96
JKBL96
5d 106s6d
1
D
2
115165.60
JKBL96
5d 106s6d
3
D
1
2
3
116152.00
116436.16
116830.90
JKBL96
JKBL96
JKBL96
5d 106s7p
3 o
P
0
1
2
119361.
119576.
122029.
ES36
ES36
ES36
5d 106s5 f
3 o
3
2
4
136115.
136216.
136230.
ES36
ES36
ES36
Limit
164765
M58
10
Tl III ( 2 S1/2)
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2054
J. E. SANSONETTI AND W. C. MARTIN
Thorium „Th…
Atomic number⫽90
Atomic weight⫽232.0381
Isotope
232
Th
Mass
Abundance
Spin
232.038054
100%
0
Mag moment
Th I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 6d 2 7s 2 3F2
Ionization energy: 50 867 cm⫺1 共6.3067 eV兲
Th II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 6d 2 7s 3/2
Ionization energy: 96 000 cm⫺1 共11.9 eV兲
Strong Lines of Thorium 共Th兲
Intensity
Wavelength 共Å兲
120
90
110
120
100
200
300 P
80
150
130
80
90
90
150
80
150
90
90
100
110
90
150
110
120
150
120
120
90
110
150
100
100
70
70
100
250 P
70
200
90
90
90
Air
2565.593
2684.288
2692.415
2747.156
2752.166
2832.3154
2837.2954
2842.8127
2848.0839
2870.4066
2884.2897
2885.0491
2887.8176
2936.0846
2942.8600
2943.7288
2988.2318
3034.0654
3049.0924
3067.7294
3072.1150
3078.8280
3080.2170
3108.2968
3116.2630
3119.5262
3122.9634
3124.3874
3125.5071
3136.2161
3139.3066
3142.8356
3146.0434
3154.3009
3175.7257
3180.1937
3184.9492
3188.2329
3192.5856
3195.6891
3214.3801
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
I
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
II
II
II
I
I
I
Ref
GSZ70
GSZ70
Z79
Z79
GSZ70
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
ATOMIC SPECTROSCOPIC DATA
2055
Strong Lines of Thorium 共Th兲—Continued
Intensity
130
130
110
140
200
70
200
300
200
200
200
150
200
150
400
800
200
120
90
200
400
150
150
500
250
70
150
90
400
90
200
70
70
200
300
300
400
300
400
700
500
250
200
80
200
200
80
90
300
300
120
300
150
120
200
120
200
250
120
P
P
P
P
P
P
P
Wavelength 共Å兲
3221.2912
3229.0096
3235.8400
3238.1157
3244.4488
3251.9159
3256.2738
3257.3667
3262.6684
3272.0268
3285.7525
3287.7893
3291.7394
3292.5209
3301.6511
3304.2383
3309.3654
3321.4508
3324.7527
3325.1207
3330.4770
3334.6041
3337.8703
3348.7684
3351.2286
3354.1796
3358.6020
3367.8189
3374.9749
3378.5734
3380.8595
3385.5316
3386.5006
3387.9205
3392.0349
3396.7278
3398.5448
3405.5584
3413.0130
3421.2100
3423.9897
3433.9988
3435.9771
3438.9503
3442.5790
3451.7023
3462.8505
3468.2198
3469.9208
3471.2186
3480.0525
3486.5512
3489.1841
3496.8107
3498.6210
3503.7859
3511.1574
3518.4040
3521.0595
Spectrum
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
II
II
II
II
I
II
II
I
II
I
I
II
II
II
I
I
I
II
II
II
I
II
II
I
II
II
II
II
I
II
I
II
II
I
II
I
I
I
I
I
I
II
II
II
I
I
II
II
II
I
I
I
I
I
I
I
I
I
I
Ref
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2056
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Thorium 共Th兲—Continued
Intensity
120
250
150
300
300
250
300
130
200
120
300
150
300
500
500
90
300
250
300
110
90
90
250
500
120
400
300
150
400
250
500
150
250
150
300
300
600
70
1000
200
200
300
70
150
250
200
300
140
80
150
140
1000
80
130
800
120
200
70
150
Wavelength 共Å兲
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3526.6342
3531.4505
3539.5872
3544.0179
3549.5959
3551.4019
3555.0135
3559.4500
3563.3756
3569.8204
3576.5574
3583.1022
3589.7495
3592.7794
3598.1199
3601.0344
3608.3779
3609.4452
3612.4275
3615.1327
3617.1173
3625.6280
3632.8303
3635.9433
3638.6444
3642.2490
3649.7349
3659.6294
3663.2025
3668.1398
3669.9684
3675.5675
3682.4863
3690.6238
3692.5664
3698.1061
3706.7672
3711.3041
3719.4347
3721.8254
3727.9027
3741.1830
3747.5390
3752.5689
3757.6941
3765.2401
3770.0560
3776.2711
3785.6002
3789.1679
3795.3858
3803.0750
3813.0676
3825.1331
3828.3846
3836.5851
3839.7475
3841.9601
3846.8876
Spectrum
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
I
I
II
I
I
I
I
II
I
I
I
I
I
I
I
II
I
II
I
II
II
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
II
I
II
I
II
II
II
I
I
I
I
II
I
I
I
II
I
I
I
II
II
I
Ref
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
ATOMIC SPECTROSCOPIC DATA
2057
Strong Lines of Thorium 共Th兲—Continued
Intensity
140
90
110
150
400
250
150
600
200
140
200
250
140
300
200
700
300
250
200
130
400
400
500
1000
250
400
400
90
200
250
400
70
150
90
200
140
150
120
150
250
200
400
500
250
300
200
80
300
110
200
250
150
200
150
200
90
90
140
200
P
P
P
P
P
P
P
Wavelength 共Å兲
3852.1353
3854.5108
3863.4059
3869.6633
3875.3731
3879.6441
3886.9159
3895.4192
3903.1024
3911.9091
3919.0234
3925.0934
3929.6693
3932.9113
3959.3000
3967.3921
3972.1545
3980.0896
3991.7309
3994.5494
4008.2102
4009.0573
4012.4952
4019.1289
4027.0091
4030.8424
4036.0479
4048.2876
4050.8872
4059.2529
4063.4071
4069.2014
4069.4612
4075.5030
4081.3678
4085.4341
4086.5205
4088.7264
4094.7470
4100.3414
4108.4198
4112.7545
4115.7589
4116.7137
4127.4120
4131.0021
4132.7533
4134.0681
4149.9870
4158.5352
4165.7661
4178.0597
4193.0164
4208.8907
4210.9232
4220.0651
4227.3872
4235.4636
4253.5385
Spectrum
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
I
II
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
I
I
I
II
I
I
I
I
I
I
I
II
I
I
I
I
II
I
II
I
II
I
I
II
I
I
II
I
II
I
I
II
I
II
I
I
I
I
I
Ref
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2058
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Thorium 共Th兲—Continued
Intensity
120
200
70
110
150
90
140
150
90
200
200
90
90
140
140
140
300
250
90
90
140
140
130
200
90
70
120
120
110
130
110
150
70
60
60
60
200
140
120
150
200
100
100
120
100
80
100
80
80
90
50
60
40
50
40
50
70
40
50
Wavelength 共Å兲
P
P
P
P
P
P
P
h
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4256.2537
4260.3330
4273.3574
4277.3139
4282.0413
4297.3066
4299.8393
4307.1762
4315.2543
4318.4157
4337.2774
4349.0722
4354.4824
4359.3719
4365.9301
4374.1239
4381.8616
4391.1105
4392.9740
4401.5812
4408.8828
4458.0015
4482.1693
4498.9401
4505.2167
4510.5259
4521.1939
4555.8127
4570.9722
4595.4206
4676.0555
4723.4382
4863.1724
4919.8157
5017.2540
5049.7960
5067.9737
5158.6041
5160.7309
5199.1637
5231.1597
5343.5812
5587.0263
5760.5508
6169.8221
6182.6217
6457.2824
6462.6131
6531.3418
6989.6553
7168.8952
7208.0063
7428.9405
7647.3794
7978.9731
8330.4494
8967.6403
9048.2501
11230.2547
Spectrum
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
I
I
II
II
II
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
PE83
ATOMIC SPECTROSCOPIC DATA
2059
Strong Lines of Thorium 共Th兲—Continued
Intensity
Wavelength 共Å兲
30
30
30
25
25
25
25
25
25
25
12127.3016
12231.9446
12646.5347
15429.78
15831.75
17307.66
17381.91
17481.04
17584.52
18811.88
Spectrum
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Ref
I
I
I
I
I
I
I
I
I
I
PE83
PE83
PE83
GBCZ74
GBCZ74
GBCZ74
GBCZ74
GBCZ74
GBCZ74
GBCZ74
Persistent Lines of Neutral Thorium 共Th I兲
Inten
Wavelength 共Å兲
800
3304.2383
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
6d 2 7s 2
3
F
2
3
0.000
30255.452
PE83
F
2
2
0.000
29853.143
PE83
F
4
5
4961.659
34182.708
PE83
G
4
5
8111.005
35081.017
PE83
F
Go
2
3
0.000
26878.162
PE83
o
500
3348.7684
6d 2 7s 2
3
o
700
3421.2100
6d 2 7s 2
3
o
600
3706.7672
6d 2 7s 2
1
o
1000
1000
800
3719.4347
3803.0750
3828.3846
6d 2 7s 2
6d 2 7s7 p
3
6d 2 7s 2
6d 2 7s7 p
3
F
Do
2
1
0.000
26287.049
PE83
3
6d 2 7s 2
3
F
2
2
0.000
26113.270
PE83
Ho
H
4
4
7795.275
33459.180
PE83
F
4
4
4961.659
30160.003
PE83
F
3
2
2869.259
27784.366
PE83
F
2
2
0.000
24307.749
PE83
F
1
2
5563.142
29853.143
PE83
3
o
600
700
3895.4192
3967.3921
5 f 6d7s 2
5 f 6d7s7p
3
6d 2 7s 2
3
3
o
500
4012.4952
6d 2 7s 2
3
o
400
4112.7545
6d 2 7s 2
3
o
500
4115.7589
Wl Ref
6d 3 ( 4 F)7s
5
o
200
5067.9737
5 f 6d7s 2
3
Ho
4
4
7795.275
27521.527
PE83
200
5231.1597
6d 2 7s 2
6d 2 7s7 p
3
P
P
0
1
2558.057
21668.956
PE83
6d 2 7s 2
5 f 6d7s 2
3
F
Do
2
1
0.000
17354.639
PE83
120
5760.5508
5 o
3
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2060
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Thorium 共Th I兲—Continued
Inten
Wavelength 共Å兲
100
100
90
70
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
6d 7s
5 f 6d7s 2
3
F
Do
4
3
4961.659
21165.096
PE83
5 f 6d7s 2
5 f 6d7s7p
3
Ho
I
4
5
7795.275
23277.387
PE83
5 f 6d7s 2
5 f 6d7s7p
3
Ho
I
4
4
7795.275
22098.187
PE83
6d 3 ( 4 F)7s
6d 2 7s7 p
5
F
F
4
4
8800.251
19948.395
PE83
Configuration
2
6169.8221
6457.2824
6989.6553
8967.6403
2
3
5
5
5 o
Wl Ref
A Ref
Energy Levels of Neutral Thorium 共Th I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
6d 2 7s 2
3
2
3
4
0.000
2869.259
4961.659
BW92b
BW92b
BW92b
6d 2 7s 2
3
P
0
2
1
2558.057
3687.987
3865.475
BW92b
BW92b
BW92b
6d 3 ( 4 F)7s
5
F
1
2
3
4
5
5563.142
6362.396
7502.288
8800.251
9804.807
BW92b
BW92b
BW92b
BW92b
BW92b
6d 2 7s 2
1
D
2
7280.124
BW92b
5 f 6d7s 2
3
Ho
4
5
6
7795.275
11197.031
14481.869
BW92b
BW92b
BW92b
6d 2 7s 2
1
G
4
8111.005
BW92b
5 f 6d7s 2
3 o
F
2
3
4
8243.601
11241.730
14206.917
BW92b
BW92b
BW92b
5 f 6d7s 2
1
Go
4
10414.136
BW92b
5 f 6d7s 2
3
Go
3
4
5
10526.544
13175.113
15490.077
BW92b
BW92b
BW92b
6d7s 2 7p
3 o
F
2
3
10783.154
13945.307
BW92b
BW92b
6d 3 ( 4 P)7s
5
P
1
2
3
11601.031
11802.934
12847.971
BW92b
BW92b
BW92b
5 f 6d7s 2
3
Do
1
17354.639
BW92b
6d 7s7p
5 o
F
4
19948.395
BW92b
5 f 6d7s 2
3
Do
3
21165.096
BW92b
2
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2061
Energy Levels of Neutral Thorium 共Th I兲—Continued
Term
J
Level (cm⫺1 )
6d 7s7p
5 o
P
1
21668.956
BW92b
5 f 6d7s7 p
5
I
4
5
6
22098.187
23277.387
26997.247
BW92b
BW92b
BW92b
o
2
24307.749
BW92b
o
2
26113.270
BW92b
Configuration
2
Ref
6d 2 7s7p
3
Do
1
26287.049
BW92b
6d 2 7s7p
3
Go
3
26878.162
BW92b
4
27521.527
BW92b
o
2
27784.366
BW92b
o
2
29853.143
BW92b
o
4
30160.003
BW92b
o
3
30255.452
BW92b
4
33459.180
BW92b
o
5
34182.708
BW92b
o
5
35081.017
BW92b
50867
KDEE97
3
5 f 6d7s7 p
H
Th II 共3/2兲
Limit
Persistent Lines of Singly-ionized Thorium 共Th II兲
Inten
Wavelength 共Å兲
300
2837.2954
250
250
300
250
300
250
300
1000
3180.1937
3351.2286
A ki (108 s⫺1 )
0.88
0.37
3392.0349
3433.9988
3469.9208
0.27
0.51
4019.1289
Level (cm⫺1 )
F
Go
9/2
11/2
6213.490
41447.959
PE83
F
Go
5/2
7/2
1521.896
32957.429
PE83
NZLJ02
4
6d 2 ( 3 F)7s
6d7s( 3 D)7p
4
F
5/2
3/2
1521.896
31353.125
PE83
NZLJ02
6d 2 ( 3 F)7s
6d7s( 3 D)7p
4
F
F
5/2
7/2
1521.896
30994.266
PE83
6d 2 ( 3 F)7s
6d 2 ( 3 F)7p
4
F
3/2
5/2
1859.938
30972.162
PE83
NZLJ02
6d 2 ( 3 F)7s
6d 2 ( 3 F)7p
4
F
Go
7/2
7/2
4146.576
32957.429
PE83
NZLJ02
5/2
5/2
4113.359
31810.548
PE83
5/2
5/2
1521.896
28243.812
PE83
NZLJ02
o
3/2
5/2
0.000
24873.983
PE83
NZLJ02
o
Term
6d 2 ( 3 F)7s
6d 2 ( 3 F)7p
4
6d 2 ( 3 F)7s
6d 2 ( 3 F)7p
4
6d( 2 D)7s 2
6d7s( 3 D)7p
3609.4452
3741.1830
J
Configuration
0.54
0.41
6d 2 ( 3 F)7s
6d7s( 3 D)7p
6d 2 ( 3 F)7s
6d7s( 3 D)7p
4
o
4 o
o
4
o
4
F
Wl Ref
A Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2062
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Thorium 共Th II兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
3
o
Term
250
4116.7137
5 f 6d( H )7s
5 f 6d( 3 Ho)7p
4
o
300
4381.8601
5 f 6d( 3 Ho)7s
5 f 2 ( 3 F)7s
o
250
4391.1105
5 f ( 2 Fo)7s 2
5 f 7s( 3 Fo)7p
2 o
H
F
J
Level (cm⫺1 )
7/2
9/2
6168.356
30452.725
PE83
9/2
9/2
6700.186
29515.134
PE83
5/2
7/2
4490.262
27257.149
PE83
Wl Ref
A Ref
Energy Levels of Singly-ionized Thorium 共Th II兲
Configuration
Term
6d 2 ( 3 F)7s
6d 2 ( 3 F)7s
4
J
Level (cm⫺1 )
Ref
3/2
0.000
BW92b
5/2
3/2
7/2
9/2
1521.896
1859.938
4146.576
6213.490
BW92b
BW92b
BW92b
BW92b
5/2
4113.359
BW92b
F
5/2
7/2
4490.262
8378.859
BW92b
BW92b
F
6d( 2 D)7s 2
5 f ( 2 Fo)7s 2
2 o
5 f 6d( 3 Ho)7s
4
Ho
7/2
11/2
9/2
13/2
6168.356
10189.067
10572.041
13406.433
BW92b
BW92b
BW92b
BW92b
6d 2 ( 3 P)7s
4
P
1/2
3/2
5/2
6244.294
8018.192
9061.103
BW92b
BW92b
BW92b
5 f 6d( 3 Fo)7s
4 o
3/2
5/2
7/2
9/2
6691.387
7331.485
9720.297
12488.287
BW92b
BW92b
BW92b
BW92b
5 f 6d( 3 Ho)7s
o
9/2
6700.186
BW92b
3/2
7001.420
BW92b
F
6d 3
6d 2 ( 1 P)7s
1/2
7828.560
BW92b
2 o
7/2
8378.859
BW92b
6d 3
4
3/2
5/2
7/2
9/2
8460.352
9400.964
10855.323
13248.708
BW92b
BW92b
BW92b
BW92b
6d 2 ( 1 F)7s
2
5/2
8605.841
BW92b
2 o
5 f ( F )7s
2
F
F
1
o
F
5 f 6d( G )7s
2
o
G
7/2
9/2
9202.265
9238.020
BW92b
BW92b
5 f 6d( 3 Go)7s
4
Go
5/2
7/2
9/2
11/2
9585.404
11116.584
13468.967
15349.879
BW92b
BW92b
BW92b
BW92b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2063
Energy Levels of Singly-ionized Thorium 共Th II兲—Continued
Configuration
2 1
Term
6d ( G)7s
2
6d7s( 3 D)7p
o
G
J
Level (cm⫺1 )
Ref
7/2
9711.962
BW92b
5/2
24873.983
BW92b
7/2
27257.149
BW92b
5/2
28243.812
BW92b
5 f ( F)7s
9/2
29515.134
BW92b
5 f 6d( 3 Ho)7p
9/2
30452.725
BW92b
5 f 7s( 3 Fo)7p
6d7s( 3 D)7p
o
2 3
6d 2 ( 3 F)7p
o
5/2
30972.162
BW92b
6d7s( D)7p
4 o
7/2
30994.266
BW92b
6d7s( 3 D)7p
o
3/2
31353.125
BW92b
6d7s( 3 D)7p
o
5/2
31810.548
BW92b
6d 2 ( 3 F)7p
4
Go
7/2
32957.429
BW92b
4
o
11/2
41447.959
BW92b
Limit
96000
MCS75
3
2 3
6d ( F)7p
Th III ( 3 Ho4 )
F
G
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2064
J. E. SANSONETTI AND W. C. MARTIN
Thulium „Tm…
Atomic number⫽69
Atomic weight⫽168.934 21
Isotope
169
Tm
Mass
Abundance
Spin
Mag moment
168.93421
100%
1/2
⫺0.2316
o
Tm I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 136s 2 2F7/2
⫺1
Ionization energy: 49 879.8 cm 共6.184 31 eV兲
o
)6s (7/2,1/2) o4
Tm II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 13( 2 F7/2
⫺1
Ionization energy: 97 200 cm 共12.05 eV兲
Strong Lines of Thulium 共Tm兲
Intensity
Wavelength 共Å兲
90
150
40
60
15
90
80
60
80
80
70
20
200
70
80
70
50
60
70
150
70
40
80
800 P
250
200
150
40
250
130
200
250
30
200
200
130
90
120
130
130
250
Air
2480.13
2509.08
2552.764
2561.65
2596.489
2607.06
2624.33
2721.19
2794.60
2797.27
2827.92
2854.166
2869.23
2890.94
2926.74
2935.99
2973.218
2981.48
2990.54
3015.30
3073.08
3081.121
3098.60
3131.26
3133.89
3151.04
3157.34
3172.654
3172.83
3236.81
3240.23
3241.54
3246.963
3258.05
3266.64
3267.40
3268.99
3276.81
3283.40
3285.61
3291.00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
II
II
I
II
I
II
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
II
II
II
Ref
MCS75
MCS75
SMC73
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
2065
Strong Lines of Thulium 共Tm兲—Continued
Intensity
200
130
25
400
200
80
30
30
700
110
30
90
600
600
1000
20
30
30
40
30
25
200
90
40
20
30
40
150
40
30
250
40
110
120
500
400
800
100
250
500
150
700
500
800
80
60
60
30
150
30
1000
700
200
500
40
80
400
60
150
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3302.46
3309.80
3349.987
3362.61
3397.50
3410.048
3412.590
3416.588
3425.08
3425.63
3429.332
3429.96
3441.50
3453.66
3462.20
3467.513
3476.692
3480.975
3487.379
3499.948
3517.598
3535.52
3536.58
3537.910
3555.818
3560.916
3563.876
3566.47
3567.356
3586.067
3608.77
3638.408
3643.65
3668.09
3700.26
3701.36
3717.914
3725.06
3734.12
3744.064
3751.806
3761.33
3761.91
3795.75
3798.541
3807.719
3817.39
3826.386
3838.20
3840.869
3848.02
3883.132
3883.44
3887.348
3896.617
3900.79
3916.477
3929.58
3949.270
Spectrum
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
II
II
I
II
II
I
I
I
II
II
I
II
II
II
II
I
I
I
I
I
I
II
II
I
I
I
I
II
I
I
II
I
II
II
II
II
I
II
II
I
I
II
II
II
I
I
II
I
II
I
II
I
II
I
I
II
I
II
I
Ref
MCS75
MCS75
SMC73
MCS75
MCS75
SMC73
SMC73
SMC73
MCS75
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
SMC73
SMC73
SMC73
SMC73
SMC73
SMC73
MCS75
MCS75
SMC73
SMC73
SMC73
SMC73
MCS75
SMC73
SMC73
MCS75
SMC73
MCS75
MCS75
MCS75
MCS75
SMC73
MCS75
MCS75
SMC73
SMC73
MCS75
MCS75
MCS75
SMC73
SMC73
MCS75
SMC73
MCS75
SMC73
MCS75
SMC73
MCS75
SMC73
SMC73
MCS75
SMC73
MCS75
SMC73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2066
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Thulium 共Tm兲—Continued
Wavelength 共Å兲
Intensity
150
200
20
40
1000
1000
110
900
60
600
40
300
25
15
250
140
20
14
60
15
30
25
30
15
70
14
20
20
15
60
25
50
20
14
20
14
Spectrum
3958.10
3996.52
4024.230
4044.474
4094.187
4105.841
4138.334
4187.615
4199.92
4203.727
4222.671
4242.15
4271.716
4298.365
4359.928
4386.434
4394.420
4396.495
4481.26
4519.595
4522.57
4599.017
4615.94
4681.920
4733.335
4957.175
5009.77
5034.22
5060.895
5307.116
5631.406
5675.835
5764.287
5971.264
6460.261
7558.33
P
P
P
P
P
P
P
P
P
P
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
Tm
II
II
I
I
I
I
I
I
II
I
I
II
I
I
I
I
I
I
II
I
II
I
II
I
I
I
II
II
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
SMC73
SMC73
SMC73
SMC73
SMC73
SMC73
MCS75
SMC73
SMC73
MCS75
SMC73
SMC73
SMC73
SMC73
SMC73
SMC73
MCS75
SMC73
MCS75
SMC73
MCS75
SMC73
SMC73
SMC73
MCS75
MCS75
SMC73
SMC73
SMC73
SMC73
SMC73
SMC73
SMC73
SMC73
Persistent Lines of Neutral Thulium 共Tm I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
J
Level (cm⫺1 )
Wl Ref
A Ref
800
3717.914
1.44
4 f 13( 2 Fo)6s 2
4 f 12( 3 H5 )5d 5/26s 2
2 o
F
共5,5/2兲
7/2
9/2
0.000
26889.125
SMC73
WL97
500
3744.064
0.990
4 f 13( 2 Fo)6s 2
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
2 o
F
7/2
7/2
0.000
26701.325
SMC73
WL97
700
3883.132
1.06
4 f 13( 2 Fo)6s 2
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
2 o
F
7/2
5/2
0.000
25745.117
SMC73
WL97
500
3887.348
0.372
4 f 13( 2 Fo)6s 2
4 f 12( 3 H5 )5d 5/26s 2
2 o
F
共5,5/2兲
7/2
7/2
0.000
25717.197
SMC73
WL97
400
3916.477
1.98
4 f 13( 2 Fo)6s 2
o
)6s6p( 1 Po1 )
4 f 13( 2 F5/2
2 o
F
共5/2,1兲
5/2
7/2
8771.243
34297.17
SMC73
WL97
1000
4094.187
0.979
4 f 13( 2 Fo)6s 2
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
2 o
7/2
5/2
0.000
24418.018
SMC73
WL97
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
Term
F
共7/2,1兲
ATOMIC SPECTROSCOPIC DATA
2067
Persistent Lines of Neutral Thulium 共Tm I兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
13 2 o
J
Level (cm⫺1 )
Wl Ref
A Ref
2 o
Term
2
1000
4105.841
0.636
4 f ( F )6s
4 f 12( 3 H5 )5d 3/26s 2
F
共5,3/2兲
7/2
9/2
0.000
24348.692
SMC73
WL97
900
4187.615
0.640
4 f 13( 2 Fo)6s 2
4 f 12( 3 F4 )5d 5/26s 2
2 o
F
7/2
7/2
0.000
23873.207
SMC73
WL97
600
4203.727
0.243
4 f 13( 2 Fo)6s 2
4 f 12( 3 F4 )5d 5/26s 2
2 o
F
共4,5/2兲
7/2
9/2
0.000
23781.698
SMC73
WL97
250
4359.928
0.120
4 f 13( 2 Fo)6s 2
4 f 12( 3 H5 )5d 5/26s 2
2 o
F
7/2
5/2
0.000
22929.717
SMC73
WL97
140
4386.434
0.037
4 f 13( 2 Fo)6s 2
4 f 12( 3 H5 )5d 3/26s 2
2 o
F
共5,3/2兲
7/2
7/2
0.000
22791.176
SMC73
WL97
70
4733.335
0.020
4 f 13( 2 Fo)6s 2
4 f 12( 3 F4 )5d 3/26s 2
2 o
F
共4,3/2兲
7/2
7/2
0.000
21120.836
SMC73
WL97
60
5307.116
0.022
4 f 13( 2 Fo)6s 2
4 f 12( 3 H6 )5d 5/26s 2
2 o
F
共6,5/2兲
7/2
9/2
0.000
18837.385
SMC73
WL97
50
5675.835
0.013
4 f 13( 2 Fo)6s 2
o
)6s6p( 3 Po1 )
4 f 13( 2 F7/2
2 o
7/2
9/2
0.000
17613.659
SMC73
M00
F
共7/2,1兲
Energy Levels of Neutral Thulium 共Tm I兲
Configuration
Term
J
Level (cm⫺1 )
Ref
7/2
5/2
0.000
8771.243
MZH78
MZH78
4 f 13( 2 Fo)6s 2
2 o
4 f 12( 3 H6 )5d 3/26s 2
共6,3/2兲
9/2
15/2
11/2
13/2
13119.610
15271.002
15587.811
17454.818
MZH78
MZH78
MZH78
MZH78
4 f 12( 3 H6 )5d 5/26s 2
共6,5/2兲
17/2
7/2
15/2
9/2
11/2
13/2
16456.913
16957.006
18693.074
18837.385
18853.823
19466.663
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
o
)6s6p( 3 Po0 )
4 f 13( 2 F7/2
共7/2,0兲
7/2
16742.237
MZH78
o
4 f 13( 2 F7/2
)6s6p( 3 Po1 )
共7/2,1兲
7/2
9/2
5/2
17343.374
17613.659
17752.634
MZH78
MZH78
MZH78
o
)6s6p( 3 Po2 )
4 f 13( 2 F7/2
共7/2,2兲
11/2
3/2
5/2
9/2
7/2
18990.406
19132.245
19548.834
19748.543
19753.830
MZH78
MZH78
MZH78
MZH78
MZH78
o
)5d6s( 3 D)
4 f 13( 2 F7/2
3
关 3/2兴 o
5/2
3/2
1/2
20406.840
21799.380
24160.63
MZH78
MZH78
MZH78
F
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2068
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Thulium 共Tm I兲—Continued
Configuration
12 3
4 f ( F4 )5d 3/26s
Term
2
共4,3/2兲
J
Level (cm⫺1 )
Ref
7/2
5/2
9/2
11/2
21120.836
21161.401
21737.685
21997.473
MZH78
MZH78
MZH78
MZH78
o
)5d6s( 3 D)
4 f 13( 2 F7/2
3
关 11/2兴 o
9/2
11/2
13/2
22419.764
22559.502
22742.777
MZH78
MZH78
MZH78
4 f 12( 3 H6 )6s 2 6p 1/2
(6,1/2) o
11/2
13/2
22468.046
22902.127
MZH78
MZH78
4 f 12( 3 H5 )5d 3/26s 2
共5,3/2兲
7/2
13/2
9/2
11/2
22791.176
23374.681
24348.692
25488.545
MZH78
MZH78
MZH78
MZH78
5/2
22929.717
MZH78
4 f 12( 3 H5 )5d 5/26s 2
4 f 12( 3 F4 )5d 5/26s 2
共4,5/2兲
11/2
23309.979
MZH78
o
)5d6s( 3 D)
4 f 13( 2 F7/2
3
关 5/2兴 o
7/2
5/2
3/2
23335.111
23431.844
23574.415
MZH78
MZH78
MZH78
4 f 12( 3 F4 )5d 5/26s 2
共4,5/2兲
9/2
23781.698
MZH78
4 f 12( 3 F4 )5d 5/26s 2
7/2
23873.207
MZH78
4 f 12( 3 F4 )5d 5/26s 2
3/2
23882.41
MZH78
9/2
5/2
7/2
23941.071
24611.303
24708.041
MZH78
MZH78
MZH78
13/2
24137.196
MZH78
o
)5d6s( 3 D)
4 f 13( 2 F7/2
3
关 7/2兴 o
4 f 12( 3 F4 )5d 5/26s 2
o
)5d6s( 3 D)
4 f 13( 2 F7/2
3
关 9/2兴 o
7/2
9/2
11/2
24246.425
24701.058
24957.469
MZH78
MZH78
MZH78
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
共7/2,1兲
5/2
24418.018
MZH78
4 f 12( 3 H5 )5d 5/26s 2
共5,5/2兲
15/2
7/2
9/2
13/2
11/2
25130.453
25717.197
26889.125
27377.13
27491.31
MZH78
MZH78
MZH78
MZH78
MZH78
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
5/2
25745.117
MZH78
o
4 f 13( 2 F7/2
)6s6p( 1 Po1 )
7/2
26701.325
MZH78
7/2
34297.17
MZH78
Limit
49879.8
C71
o
4 f 13( 2 F5/2
)6s6p( 1 Po1 )
o
Tm II ( 2 F7/2
)6s 1/2 (7/2 ,1/2) o4
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
共5/2,1兲
ATOMIC SPECTROSCOPIC DATA
2069
Persistent Lines of Singly-ionized Thulium 共Tm II兲
Inten
Wavelength 共Å兲
800
3131.26
A ki (108 s⫺1 )
1.06
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
o
)6s 1/2
4 f 13( 2 F7/2
12
(7/2,1/2)
o
4
5
0.00
31926.82
MCS75
WL97
4 f 5d6s
400
3362.61
0.934
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
3
2
236.95
29967.17
MCS75
WL97
700
3425.08
0.652
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
3
3
236.95
29424.98
MCS75
WL97
600
3441.50
0.560
o
)6s 1/2
4 f 13( 2 F7/2
13
4 f 6p
(7/2,1/2) o
3
2
236.95
29285.72
MCS75
WL97
600
3453.66
0.266
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
3
4
236.95
29183.39
MCS75
WL97
1000
3462.20
0.540
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
4
5
0.00
28875.12
MCS75
WL97
500
3700.26
0.223
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
3
4
236.95
27254.42
MCS75
WL97
400
3701.36
0.157
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
4
4
0.00
27009.39
MCS75
WL97
700
3761.33
0.351
o
)6s 1/2
4 f 13( 2 F7/2
12 3
4 f ( F)6s 2
(7/2,1/2) o
3
F
4
3
0.00
26578.77
MCS75
WL97
500
3761.91
0.194
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
4
4
0.00
26574.66
MCS75
WL97
800
3795.75
0.300
o
)6s 1/2
4 f 13( 2 F7/2
12
4 f 5d6s
(7/2,1/2) o
3
4
236.95
26574.66
MCS75
WL97
1000
3848.02
0.466
o
)6s 1/2
4 f 13( 2 F7/2
13
4 f 6p
(7/2,1/2) o
4
3
0.00
25980.02
MCS75
WL97
300
4242.15
0.0465
o
)6s 1/2
4 f 13( 2 F7/2
4 f 125d6s
(7/2,1/2) o
3
4
236.95
23803.28
MCS75
WL97
Energy Levels of Singly-ionized Thulium 共Tm II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
o
)6s 1/2
4 f 13( 2 F7/2
(7/2 ,1/2)
o
4
3
0.00
236.95
MZH78
MZH78
o
)6s 1/2
4 f 13( 2 F5/2
(5/2 ,1/2) o
2
3
8769.68
8957.47
MZH78
MZH78
4 f 12( 3 H)6s 2
3
H
6
5
4
12457.29
20619.05
24932.00
MZH78
MZH78
MZH78
4 f 12( 3 H6 )5d6s( 3 D1 )
共6,1兲
5
7
6
16567.47
19619.08
22355.43
MZH78
MZH78
MZH78
o
)5d 3/2
4 f 13( 2 F7/2
(7/2 ,3/2) o
2
5
3
4
17624.65
20228.75
21713.74
22457.51
MZH78
MZH78
MZH78
MZH78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2070
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Thulium 共Tm II兲—Continued
Configuration
12 3
4 f ( F)6s
2
Term
3
F
J
Level (cm⫺1 )
Ref
4
3
2
17974.30
26578.77
—
MZH78
MZH78
4 f 12( 3 H6 )5d6s( 3 D2 )
共6,2兲
4
6
8
7
18291.37
19526.82
19682.97
22052.39
MZH78
MZH78
MZH78
MZH78
4 f 12( 3 H6 )5d6s( 3 D3 )
共6,3兲
9
3
8
5
6
7
20465.82
21608.26
23024.29
23768.84
23904.43
23961.60
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
5
21021.98
MZH78
6
2
1
4
3
5
21133.68
21978.77
22141.96
23524.09
23934.73
24273.20
MZH78
MZH78
MZH78
MZH78
MZH78
MZH78
4 f 125d6s
4
22308.82
MZH78
4 f 125d6s
4
23803.28
MZH78
4 f 6p
3
25980.02
MZH78
4 f 125d6s
4
26574.66
MZH78
4 f 125d6s
4
27009.39
MZH78
4 f 125d6s
4
27254.42
MZH78
4 f 5d6s
5
28875.12
MZH78
4 f 125d6s
4
29183.39
MZH78
4 f 136p
2
29285.72
MZH78
4 f 125d6s
3
29424.98
MZH78
4 f 5d6s
2
29967.17
MZH78
4 f 125d6s
5
31926.82
MZH78
92700
SR65
4 f 125d6s
o
)5d 5/2
4 f 13( 2 F7/2
(7/2 ,5/2) o
13
12
12
o
)
Tm III ( 2 F7/2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
2071
Tin „Sn…
Atomic number⫽50
Atomic weight⫽118.710
Isotope
112
Sn
Sn
115
Sn
116
Sn
117
Sn
118
Sn
119
Sn
120
Sn
122
Sn
124
Sn
114
Mass
Abundance
Spin
111.904826
113.902784
114.903348
115.901747
116.902956
117.901609
118.903310
119.902220
121.903440
123.905724
0.97%
0.65%
0.36%
14.53%
7.68%
24.22%
8.58%
32.59%
4.63%
5.79%
0
0
1/2
0
1/2
0
1/2
0
0
0
Mag moment
⫺0.918
⫺1.000
⫺1.046
Sn I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 2 3P0
Ionization energy: 59 232.7 cm⫺1 共7.343 92 eV兲
o
Sn II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 2P1/2
Ionization energy: 118 017.0 cm⫺1 共14.6322 eV兲
Strong Lines of Tin 共Sn兲
Intensity
600
500
1000
1000
1000 P
1000 P
300
140
300 P
200
80
200
300
300
80
300
300
400
400
700
80
600
700
25
200
60
140
300
400
140
140
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Vacuum
1223.721
1242.926
1290.880
1316.576
1400.440
1474.997
1811.201
1860.330
1899.881
Air
2091.590
2150.844
2199.346
2209.660
2246.057
2266.016
2268.930
2286.681
2317.230
2334.812
2354.850
2368.226
2421.694
2429.495
2448.908
2483.410
2486.967
2495.724
2546.549
2571.594
2594.421
2661.244
Spectrum
Ref
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
II
II
II
II
II
II
II
I
II
B64
B64
B64
B64
B64
B64
B64
B64
B64
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
I
II
I
I
I
II
I
I
I
I
I
II
I
I
II
I
II
I
I
I
I
I
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2072
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Tin 共Sn兲—Continued
Wavelength 共Å兲
Intensity
500 P
1000 P
700 P
140
500 P
140
600 P
400 P
400 P
50 P
60 P
200 P
110 P
30 P
30 P
30 P
60
30 P
30
40
40
20
50 P
30 P
20
15
20
20
30
20 h
40
11
9
11
9
14
14
Spectrum
2706.505
2839.976
2863.315
2913.559
3009.133
3032.778
3034.115
3175.035
3262.331
3283.140
3351.952
3801.011
4524.734
5332.339
5561.910
5588.815
5631.676
5798.860
6054.674
6069.117
6149.604
6154.446
6453.542
6844.186
7190.776
7741.425
8114.030
8422.624
8552.531
9805.184
9850.381
11454.407
11616.152
11739.591
11932.82
12981.01
13459.2
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Sn
Ref
I
I
I
I
I
I
I
I
I
II
II
I
I
II
II
II
I
II
I
I
I
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
B64
Persistent Lines of Neutral Tin 共Sn I兲
Inten
Wavelength 共Å兲
200
2091.590
200
300
300
300
700
2199.346
2209.660
2246.057
2268.930
2354.850
A ki (108 s⫺1 )
Configuration
5p 2
5 p5d
0.29
0.56
1.48
1.14
1.85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5p 2
5 p5d
5p 2
5 p5d
5p 2
5 p5d
5p 2
5 p5d
5p 2
5 p5d
Term
J
Level (cm⫺1 )
3
P
P
1
0
1691.806
49487.127
B64
P
F
1
2
1691.806
47145.684
B64
FW96
P
P
2
2
3427.673
48669.409
B64
FW96
P
Do
0
1
0.000
44508.677
B64
M00
P
F
2
3
3427.673
47487.696
B64
M00
P
Do
1
2
1691.806
44144.368
B64
M00
3 o
3
3 o
3
3 o
3
3
3
3 o
3
3
Wl Ref
A Ref
ATOMIC SPECTROSCOPIC DATA
2073
Persistent Lines of Neutral Tin 共Sn I兲—Continued
Inten
Wavelength 共Å兲
600
700
140
500
1000
700
500
600
400
400
200
110
2421.694
2429.495
2661.244
2706.505
2839.976
2863.315
3009.133
3034.115
3175.035
3262.331
3801.011
4524.734
A ki (108 s⫺1 )
2.5
1.5
0.153
0.539
1.57
0.544
0.355
1.89
0.893
2.7
0.28
0.26
Configuration
2
5p
5 p5d
Term
J
Level (cm⫺1 )
1
D
F
2
3
P
Do
Wl Ref
A Ref
8612.955
49893.823
B64
FW96
2
3
3427.673
44576.006
B64
FW96
P
P
1
1
1691.806
39257.053
B64
M00
P
P
1
2
1691.806
38628.876
B64
M00
P
P
2
2
3427.673
38628.876
B64
M00
P
P
0
1
0.000
34914.282
B64
M00
P
P
1
1
1691.806
34914.282
B64
M00
P
P
1
0
1691.806
34640.758
B64
M00
P
P
2
1
3427.673
34914.282
B64
M00
D
P
2
1
8612.955
39257.053
B64
FW96
D
P
2
1
8612.955
34914.282
B64
FW96
S
P
0
1
17162.499
39257.053
B64
FW96
1 o
5p 2
5 p5d
3
3
5p 2
5 p6s
3
1 o
5p 2
5 p6s
3
3 o
5p 2
5 p6s
3
3 o
5p 2
5 p6s
3
3 o
5p 2
5 p6s
3
3 o
5p 2
5 p6s
3
3 o
5p 2
5 p6s
3
3 o
5p 2
5 p6s
1
1 o
5p 2
5 p6s
1
3 o
5p 2
5 p6s
1
1 o
Energy Levels of Neutral Tin 共Sn I兲
Term
J
Level (cm⫺1 )
Ref
2
3
0
1
2
0.000
1691.806
3427.673
B64
B64
B64
5p2
1
2
8612.955
B64
5p 2
1
S
0
17162.499
B64
5p6s
3 o
P
0
1
2
34640.758
34914.282
38628.876
B64
B64
B64
5p6s
1 o
P
1
39257.053
B64
5s5p 3
5 o
S
2
39625.506
B64
5p6 p
3
D
1
2
3
42342.216
43430.135
47006.830
B64
B64
B64
5 p6p
1
P
1
43368.634
B64
5p5d
1
2
43682.737
B64
Configuration
5p
P
D
o
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2074
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Tin 共Sn I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
5 p6 p
3
P
0
1
2
43799.085
46603.517
47235.221
B64
B64
B64
5 p5d
3
Do
2
1
3
44144.368
44508.677
44576.006
B64
B64
B64
5 p5d
3 o
F
2
3
4
47145.684
47487.696
48107.27
B64
B64
B64
5 p6 p
3
S
1
47805.840
B64
5 p6p
1
D
2
48189.791
B64
5 p5d
3 o
P
2
1
0
48669.409
48981.934
49487.127
B64
B64
B64
5 p6 p
1
S
0
49406.162
B64
5 p5d
1 o
F
3
49893.823
B64
5 p5d
1 o
1
50125.971
B64
59232.7
BTG77
P
o
)
Sn II ( 2 P1/2
Limit
Ref
Persistent Lines of Singly-ionized Tin 共Sn II兲
Inten
1000
1000
300
80
80
80
50
60
30
30
Wavelength 共Å兲
1400.440
1474.997
1899.881
A ki (108 s⫺1 )
17.5
19.5
5.90
2150.844
2266.016
2368.226
3283.140
3351.952
5332.339
5561.910
0.0044
1.0
1.0
0.86
1.2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
2 1
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
5s ( S)5p
5s 2 ( 1 S)5d
2 o
P
D
1/2
3/2
0.000
71406.139
B64
M00
5s 2 ( 1 S)5p
5s 2 ( 1 S)5d
2 o
P
D
3/2
5/2
4251.494
72048.257
B64
M00
5s 2 ( 1 S)5p
5s 2 ( 1 S)6s
2 o
P
S
3/2
1/2
4251.494
56886.365
B64
M00
5s 2 ( 1 S)5p
5s5 p 2
2 o
P
P
3/2
5/2
4251.494
50730.255
B64
5s 2 ( 1 S)5p
5s5 p 2
2 o
P
P
3/2
3/2
4251.494
48368.188
B64
5s 2 ( 1 S)5p
5s5 p 2
2 o
3/2
1/2
4251.494
46464.291
B64
FW96
3/2
5/2
58844.182
89294.052
B64
FW96
D
F
5/2
7/2
59463.482
89288.248
B64
FW96
5s 2 ( 1 S)6p
5s 2 ( 1 S)6d
2 o
P
D
1/2
3/2
71493.275
90241.555
B64
FW96
5s 2 ( 1 S)6p
5s 2 ( 1 S)6d
2 o
3/2
5/2
72377.450
90351.894
B64
FW96
5s5 p 2
5s 2 ( 1 S)4 f
5s5p 2
5s 2 ( 1 S)4 f
2
2
2
4
4
P
P
4
2
D
F
2 o
2
2 o
2
2
P
D
ATOMIC SPECTROSCOPIC DATA
2075
Persistent Lines of Singly-ionized Tin 共Sn II兲—Continued
Inten
Wavelength 共Å兲
30
30
50
30
A ki (108 s⫺1 )
5588.815
0.85
5798.860
0.81
6453.542
1.2
6844.186
0.66
Configuration
2 1
J
Level (cm⫺1 )
D
F
3/2
5/2
D
F
Term
5s ( S)5d
5s 2 ( 1 S)4 f
2
5s 2 ( 1 S)5d
5s 2 ( 1 S)4 f
2
5s 2 ( 1 S)6s
5s 2 ( 1 S)6p
2
5s 2 ( 1 S)6s
5s 2 ( 1 S)6p
2
Wl Ref
A Ref
71406.139
89294.052
B64
FW96
5/2
7/2
72048.257
89288.248
B64
FW96
S
P
1/2
3/2
56886.365
72377.450
B64
FW96
S
P
1/2
1/2
56886.365
71493.275
B64
FW96
2 o
2 o
2 o
2 o
Energy Levels of Singly-ionized Tin 共Sn II兲
Ref
Term
5s 2 ( 1 S)5p
2 o
1/2
3/2
0.000
4251.494
B64
B64
5s5 p 2
4
P
1/2
3/2
5/2
46464.291
48368.188
50730.255
B64
B64
B64
5s 2 ( 1 S)6s
2
S
1/2
56886.365
B64
5s5p 2
2
D
3/2
5/2
58844.182
59463.482
B64
B64
5s 2 ( 1 S)5d
2
D
3/2
5/2
71406.139
72048.257
B64
B64
5s 2 ( 1 S)6p
2 o
P
1/2
3/2
71494.275
72377.450
B64
B64
5s 2 ( 1 S)4 f
2 o
F
7/2
5/2
89288.248
89294.052
B64
B64
5s 2 ( 1 S)6d
2
D
3/2
5/2
90241.555
90351.894
B64
B64
Sn III ( 1 S0 )
P
J
Level (cm⫺1 )
Configuration
Limit
118017.0
M58
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2076
J. E. SANSONETTI AND W. C. MARTIN
Titanium „Ti…
Atomic number⫽22
Atomic weight⫽47.88
Isotope
46
Ti
Ti
48
Ti
49
Ti
50
Ti
47
Mass
Abundance
Spin
45.952629
46.951764
47.947947
48.947871
49.944792
8.0%
7.43%
73.8%
5.5%
5.4%
0
5/2
0
7/2
0
Mag moment
⫺0.7885
⫺1.0417
Ti I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 2 4s 2 3F2
Ionization energy: 55 072.5 cm⫺1 共6.828 12 eV兲
Ti II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 2 4s 4F3/2
Ionization energy: 109 494 cm⫺1 共13.5755 eV兲
Strong Lines of Titanium 共Ti兲
Intensity
Wavelength 共Å兲
25
25
30
25
25
25
30
40
70
40
80
100
120
30
60
40
150
200
25
110 d
50
90
130
200 P
300 P
90
25
40
60
80
130
300
80
400
500
60
30
Air
2279.967
2305.674
2525.586
2529.871
2541.908
2593.640
2599.904
2605.133
2611.285
2619.933
2641.087
2644.253
2646.625
2802.494
2912.083
2928.327
2948.242
2956.123
2967.225
3066.229
3072.117
3072.986
3075.231
3078.651
3088.042
3119.723
3123.073
3161.231
3161.798
3162.586
3168.550
3186.451
3190.914
3191.993
3199.915
3202.559
3203.825
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
I
I
II
II
II
II
I
II
I
I
II
I
Ref
F91
F91
HJLW82
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
F91
F91
HJLW82
HJLW82
HJLW82
HJLW82
F91
HJLW82
F91
F91
HJLW82
F91
ATOMIC SPECTROSCOPIC DATA
2077
Strong Lines of Titanium 共Ti兲—Continued
Intensity
30
90
110
40
60
40
600
400
300
200
100
80
100
100
100
40
40
30
110
30
50
250
30
200
50
150
90
700
30
400
1000
500
40
40
600
40
140
600
500
150
400
40
120
500
20
200
120
90
70
50
50
30
40
70
50
25
25
80
600
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3214.237
3217.073
3222.839
3228.618
3229.194
3229.430
3234.513
3236.581
3239.038
3241.994
3248.605
3251.909
3252.916
3254.251
3261.585
3287.657
3292.076
3309.497
3314.421
3318.021
3321.697
3322.939
3326.765
3329.458
3332.112
3335.182
3340.341
3341.874
3346.745
3349.029
3349.405
3354.633
3358.271
3360.989
3361.227
3361.266
3370.434
3371.452
3372.798
3377.486
3377.575
3379.211
3380.277
3383.769
3385.660
3385.941
3387.840
3394.578
3444.322
3461.507
3477.187
3480.525
3491.072
3504.900
3510.862
3547.028
3598.713
3610.153
3635.462
Spectrum
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
II
II
II
II
II
II
II
II
I
II
II
II
I
I
I
II
I
I
I
II
I
I
I
II
II
I
I
II
II
II
II
II
I
II
II
II
I
I
I
I
Ref
F91
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
F91
F91
F91
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
F91
HJLW82
HJLW82
HJLW82
F91
F91
F91
HJLW82
F91
F91
F91
HJLW82
F91
F91
F91
HJLW82
HJLW82
F91
F91
HJLW82
HJLW82
HJLW82
HJLW82
HJLW82
F91
HJLW82
HJLW82
HJLW82
F91
F91
F91
F91
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2078
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Titanium 共Ti兲—Continued
Intensity
800
25
900
40
80
50
50
80
250
80
40
60
40
80
400
400
30
700
80
300
250
80
110
30
30
60
40
25
300
40
60
40
140
110
140
600
600
700
120
120
600
70
700
1000
120
25
150
25
40
50
25
25
110
40
30
50
40
30
30
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3642.674
3646.196
3653.495
3654.590
3658.095
3660.629
3668.963
3671.671
3685.205
3689.914
3709.957
3717.391
3722.570
3724.569
3729.806
3741.060
3741.644
3752.858
3753.633
3759.300
3761.326
3771.651
3786.042
3866.439
3875.257
3882.891
3900.559
3900.959
3904.784
3913.477
3914.334
3921.422
3924.526
3929.874
3947.769
3948.670
3956.334
3958.201
3962.851
3964.269
3981.761
3982.480
3989.758
3998.636
4008.927
4009.656
4024.571
4030.511
4055.011
4060.262
4064.209
4065.095
4078.470
4082.455
4112.708
4186.117
4263.133
4274.588
4282.698
Spectrum
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
II
I
I
II
II
I
I
I
I
I
II
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
F91
F91
F91
F91
F91
F91
F91
F91
HJLW82
F91
F91
F91
F91
F91
F91
F91
HJLW82
F91
F91
HJLW82
HJLW82
F91
F91
F91
F91
F91
HJLW82
F91
F91
HJLW82
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
ATOMIC SPECTROSCOPIC DATA
2079
Strong Lines of Titanium 共Ti兲—Continued
Intensity
Wavelength 共Å兲
110
110
120
110
110
250
25
25
400
500
800 P
150
50
25
20
30
30
110
110
70
110
40
120
140
40
30
70
30
30
100
130
130
100
800
500
300
150
150
90
120
120
90
120
60
25
30
30
25
90
110
120
25
25
40
40
25
60
40
25
4286.003
4287.402
4289.070
4290.929
4295.748
4298.665
4299.202
4299.629
4300.554
4301.079
4305.907
4314.800
4318.629
4325.126
4393.922
4395.004
4417.273
4427.098
4449.143
4450.894
4453.312
4453.698
4455.317
4457.426
4465.805
4471.236
4481.258
4489.087
4496.145
4512.733
4518.021
4522.796
4527.305
4533.239
4534.775
4535.567
4535.918
4536.039
4544.687
4548.763
4552.453
4555.483
4617.268
4623.097
4629.336
4639.360
4639.660
4639.939
4656.468
4667.584
4681.908
4691.331
4698.760
4758.118
4759.269
4820.410
4840.873
4856.010
4868.259
Spectrum
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
HJLW82
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2080
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Titanium 共Ti兲—Continued
Intensity
30
50
50
40
700
600
500
30
500
30
400
300
70
110
110
70
40
150
110
90
150
200
25
30
30
30
25
140
150
200
30
25
40
30
40
30
25
50
30
40
25
30
40
50
50
40
30
20
60
30
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
4870.127
4885.081
4899.908
4913.615
4981.730
4991.066
4999.501
5000.988
5007.206
5013.281
5014.186
5014.275
5016.160
5020.024
5022.866
5024.843
5025.569
5035.902
5036.463
5038.396
5039.955
5064.651
5113.439
5120.415
5145.459
5147.477
5152.184
5173.740
5192.969
5210.384
5224.304
5224.933
5512.523
5514.343
5514.531
5644.132
5662.147
5866.448
5899.291
5953.156
5965.824
5978.538
5999.008
6258.099
6258.705
6261.096
7209.434
8426.504
8434.959
8435.648
Spectrum
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
Ti
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
F91
ATOMIC SPECTROSCOPIC DATA
2081
Persistent Lines of Neutral Titanium 共Ti I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
2
2
Term
J
Level (cm⫺1 )
3
Wl Ref
A Ref
600
3635.462
0.909
3d 4s
3d 2 ( 3 F)4s4 p( 1 Po)
a F
y 3Go
2
3
0.000
27498.983
F91
M03
800
3642.674
0.895
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 1 Po)
a 3F
y 3Go
3
4
170.134
27614.678
F91
M03
900
3653.495
0.869
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 1 Po)
a 3F
y 3Go
4
5
386.875
27750.136
F91
M03
700
3752.858
0.581
3d 2 4s 2
3d 2 ( 1 D)4s4p( 3 Po)
a 3F
x 3Fo
4
4
386.875
27025.658
F91
M03
600
3948.670
0.560
3d 2 4s 2
3d 3 ( 4 F)4p
a 3F
y 3Do
2
1
0.000
25317.815
F91
M03
600
3956.334
0.346
3d 2 4s 2
3d 3 ( 4 F)4p
a 3F
y 3Do
3
2
170.134
25438.906
F91
M03
700
3958.201
0.488
3d 2 4s 2
3d 3 ( 4 F)4p
a 3F
y 3Do
4
3
386.875
25643.699
F91
M03
600
3981.761
0.442
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 1 Po)
a 3F
y 3Fo
2
2
0.000
25107.410
F91
M03
700
3989.758
0.448
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 1 Po)
a 3F
y 3Fo
3
3
170.134
25227.220
F91
M03
1000
3998.636
0.481
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 1 Po)
a 3F
y 3Fo
4
4
386.875
25388.331
F91
M03
800
4305.907
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
x 5Do
5
4
6842.965
30060.338
F91
700
4981.730
0.660
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
y 5Go
5
6
6842.965
26910.712
F91
FW96
600
4991.066
0.584
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
y 5Go
4
5
6742.755
26772.969
F91
FW96
400
5007.206
0.492
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
y 5Go
2
3
6598.764
26564.398
F91
FW96
400
5014.186
0.0611
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 3 Po)
a 3F
z 3Do
2
1
0.000
19937.852
F91
M03
200
5064.651
0.0437
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 3 Po)
a 3F
z 3Do
4
3
386.875
20126.060
F91
M03
200
5210.384
0.0411
3d 2 4s 2
3d 2 ( 3 F)4s4 p( 3 Po)
a 3F
z 3Fo
4
4
386.875
19573.973
F91
M03
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2082
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Titanium 共Ti I兲
Configuration
Level (cm⫺1 )
Ref
Term
J
3
a F
2
3
4
0.000
170.134
386.875
F91
F91
F91
3d 3 ( 4 F)4s
a 5F
1
2
3
4
5
6556.833
6598.764
6661.004
6742.755
6842.965
F91
F91
F91
F91
F91
3d 2 4s 2
a 1D
2
7255.354
F91
2
3
a P
0
1
2
8436.617
8492.421
8602.342
F91
F91
F91
3d 3 ( 4 F)4s
b 3F
2
3
4
11531.759
11639.810
11776.811
F91
F91
F91
3d 2 4s 2
a 1G
4
12118.394
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 5Go
2
3
4
5
6
15877.080
15975.630
16106.075
16267.481
16458.672
F91
F91
F91
F91
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 5Fo
1
2
3
4
5
16817.160
16875.121
16961.441
17075.258
17215.389
F91
F91
F91
F91
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 5Do
0
1
2
3
4
18462.721
18482.772
18525.059
18593.946
18695.133
F91
F91
F91
F91
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 3Fo
2
3
4
19322.984
19421.580
19573.973
F91
F91
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 3Do
1
2
3
19937.852
20006.042
20126.060
F91
F91
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 3Go
3
4
5
21469.487
21588.494
21739.707
F91
F91
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 1Do
2
22081.187
F91
3d 2 ( 3 F)4s4p( 3 Po)
z 1Fo
3
22404.740
F91
3d ( F)4s4p( P )
1
o
z G
4
24694.892
F91
3d 2 ( 3 P)4s4p( 3 Po)
z 3So
1
24921.115
F91
2
3d 4s
3d 4s
2 3
2
2
3 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2083
Energy Levels of Neutral Titanium 共Ti I兲—Continued
Term
J
Level (cm⫺1 )
3d ( P)4s4p( P )
5 o
z S
2
25102.874
F91
3d 2 ( 3 F)4s4p( 1 Po)
y 3Fo
2
3
4
25107.410
25227.220
25388.331
F91
F91
F91
3d 3 ( 4 F)4p
y 3Do
1
2
3
25317.815
25438.906
25643.699
F91
F91
F91
3d 2 ( 1 D)4s4p( 3 Po)
z 3Po
2
1
0
25493.734
25537.284
25574.909
F91
F91
F91
3d 2 ( 3 P)4s4p( 3 Po)
y 5Do
0
1
2
3
4
25612.387
25635.723
25699.984
25797.594
25926.766
F91
F91
F91
F91
F91
3d 3 ( 4 F)4p
y 5Go
2
3
4
5
6
26494.330
26564.398
26657.416
26772.969
26910.712
F91
F91
F91
F91
F91
3d 2 ( 1 D)4s4p( 3 Po)
x 3Fo
2
3
4
26803.420
26892.935
27025.658
F91
F91
F91
3d 2 ( 1 D)4s4p( 3 Po)
x 3Do
1
2
3
27355.059
27418.030
27480.066
F91
F91
F91
3d 2 ( 3 F)4s4p( 1 Po)
y 3Go
3
4
5
27498.983
27614.678
27750.136
F91
F91
F91
3d 3 ( 4 F)4p
x 5Do
0
1
2
3
4
29829.111
29855.255
29907.286
29986.197
30060.338
F91
F91
F91
F91
F91
55072.5
SZK90
Configuration
2 3
3 o
Ti II ( 4 F3/2)
Limit
Ref
Persistent Lines of Singly-ionized Titanium 共Ti II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
200
3078.651
1.34
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Do
7/2
5/2
300
3088.042
1.50
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Do
600
3234.513
1.71
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Fo
Wl Ref
A Ref
225.73
32697.99
SC85
M03
9/2
7/2
393.44
32767.07
SC85
M03
9/2
9/2
393.44
31301.01
SC85
M03
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2084
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Titanium 共Ti II兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
2 3
Term
J
Level (cm⫺1 )
4
Wl Ref
A Ref
400
3236.581
1.37
3d ( F)4s
3d 2 ( 3 F)4p
a F
z 4Fo
7/2
7/2
225.73
31113.65
SC85
M03
300
3239.038
1.26
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Fo
5/2
5/2
94.10
30958.50
SC85
M03
400
3349.029
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 2F
z 2Go
7/2
9/2
4897.65
34748.40
SC85
1000
3349.405
1.68
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Go
9/2
11/2
393.44
30240.88
SC85
M03
600
3361.227
1.58
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Go
7/2
9/2
225.73
29968.30
SC85
M03
500
3372.798
1.41
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Go
5/2
7/2
94.10
29734.54
SC85
M03
500
3383.769
1.39
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 4F
z 4Go
3/2
5/2
0.00
29544.37
SC85
M03
250
3685.205
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 2F
z 2Do
7/2
5/2
4897.65
32025.47
SC85
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 2F
z 2Do
5/2
3/2
4628.58
31756.51
300
3759.300
0.94
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 2F
z 2Fo
7/2
7/2
4897.65
31490.82
SC85
FW96
250
3761.326
0.99
3d 2 ( 3 F)4s
3d 2 ( 3 F)4p
a 2F
z 2Fo
5/2
5/2
4628.58
31207.42
SC85
FW96
Energy Levels of Singly-ionized Titanium 共Ti II兲
Configuration
Term
J
Level (cm⫺1 )
Ref
3d 2 ( 3 F)4s
a 4F
3/2
5/2
7/2
9/2
0.00
94.10
225.73
393.44
SC85
SC85
SC85
SC85
3d 3
b 4F
3/2
5/2
7/2
9/2
908.02
983.89
1087.32
1215.84
SC85
SC85
SC85
SC85
3d 2 ( 3 F)4s
a 2F
5/2
7/2
4628.58
4897.65
SC85
SC85
3d 2 ( 1 D)4s
a 2D
3/2
5/2
8710.44
8744.25
SC85
SC85
3d 3
a 2G
7/2
9/2
8997.71
9118.26
SC85
SC85
3d 3
a 4P
1/2
3/2
5/2
9363.62
9395.71
9518.06
SC85
SC85
SC85
3d 3
a 2P
1/2
3/2
9850.90
9975.92
SC85
SC85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2085
Energy Levels of Singly-ionized Titanium 共Ti II兲—Continued
J
Level (cm⫺1 )
3d ( P)4s
4
b P
1/2
3/2
5/2
9872.73
9930.69
10024.73
SC85
SC85
SC85
3d 3
b 2D
3/2
5/2
12628.73
12758.11
SC85
SC85
3d 3
a 2H
9/2
11/2
12676.97
12774.69
SC85
SC85
3d 2 ( 1 G)4s
b 2G
9/2
7/2
15257.43
15265.62
SC85
SC85
3d 2 ( 3 P)4s
b 2P
1/2
3/2
16515.86
16625.11
SC85
SC85
3d 3
b 2F
7/2
5/2
20891.66
20951.62
SC85
SC85
3d4s 2
c 2D
3/2
5/2
24961.03
25192.79
SC85
SC85
3d 2 ( 3 F)4p
z 4Go
5/2
7/2
9/2
11/2
29544.37
29734.54
29968.30
30240.88
SC85
SC85
SC85
SC85
3d 2 ( 3 F)4p
z 4Fo
3/2
5/2
7/2
9/2
30836.32
30958.50
31113.65
31301.01
SC85
SC85
SC85
SC85
3d 2 ( 3 F)4p
z 2Fo
5/2
7/2
31207.42
31490.82
SC85
SC85
3d 2 ( 3 F)4p
z 2Do
3/2
5/2
31756.51
32025.47
SC85
SC85
3d 2 ( 1 D)4s
a 2S
1/2
31787.75
SC85
3d 3
d 2D1
3/2
5/2
32275.32
32332.73
SC85
SC85
3d 2 ( 3 F)4p
z 4Do
1/2
3/2
5/2
7/2
32532.21
32602.55
32697.99
32767.07
SC85
SC85
SC85
SC85
3d 2 ( 3 F)4p
z 2Go
7/2
9/2
34543.26
34748.40
SC85
SC85
Configuration
2 3
Ti III ( 3 F2 )
Term
Limit
109494
Ref
SC85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2086
J. E. SANSONETTI AND W. C. MARTIN
Tungsten „W…
Atomic number⫽74
Atomic weight⫽183.85
Isotope
180
W
W
183
W
184
W
186
W
182
Mass
Abundance
Spin
Mag moment
79.946701
81.948202
82.950220
83.950928
85.954357
0.12%
26.3%
14.28%
30.7%
28.6%
0
0
1/2
0
0
⫹0.11778
W I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 4 6s 2 5D0
Ionization energy: 63 427.7 cm⫺1 共7.864 03 eV兲
W II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 4 6s 6D1/2
Ionization energy: 130 000 cm⫺1 共16.1 eV兲
Strong Lines of Tungsten 共W兲
Intensity
Wavelength 共Å兲
1000 P
900 P
600
600
900 P
500
400
800
300
250
250
500
900
150
300
140
200
140
600
600
200
140
200
400
150
140
150
90
80
130
150
50
50
90
60
30
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Vacuum
1951.051
1962.140
1977.524
1982.907
1989.394
1990.863
Air
2001.712
2008.095
2009.982
2010.236
2014.238
2026.088
2029.995
2035.043
2049.636
2065.573
2071.208
2075.590
2079.118
2079.120
2088.204
2089.156
2090.48
2094.751
2098.602
2100.675
2101.54
2106.187
2110.323
2118.874
2121.576
2153.558
2157.796
2166.316
2182.90
2194.528
Spectrum
Ref
W
W
W
W
W
W
II
II
II
II
II
II
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
I
II
II
II
II
II
II
II
I
II
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
MCS75
EKM00
EKM00
EKM00
MCS75
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
EKM00
MCS75
EKM00
ATOMIC SPECTROSCOPIC DATA
2087
Strong Lines of Tungsten 共W兲—Continued
Intensity
80
30
50
60
60
50
50
70
100
60
80
50
70
70
200
70
100
70
70
200
70
50
100
50
70
90
90
130
60
150
60
140
100
50
150
60
70
50
25
70
80
90
90
50
90
70
140
90
300
50
25
40
80
30
100
25
80
110
60
P
P
d
d
d
P
P
P
Wavelength 共Å兲
2204.483
2248.758
2249.80
2277.58
2294.49
2313.17
2321.63
2360.44
2363.07
2374.47
2384.82
2397.107
2397.73
2397.98
2405.58
2415.68
2424.21
2431.08
2433.98
2435.96
2444.06
2451.476
2452.00
2454.72
2454.98
2455.51
2456.53
2459.30
2462.79
2466.85
2472.51
2474.15
2480.13
2480.96
2481.44
2482.10
2484.74
2487.50
2489.231
2495.26
2504.70
2521.32
2523.41
2527.76
2533.64
2545.34
2547.14
2550.38
2551.35
2553.82
2554.853
2555.095
2561.97
2571.444
2580.49
2589.160
2606.39
2613.08
2613.82
Spectrum
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
II
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
II
II
I
II
I
II
I
I
I
Ref
EKM00
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
EKM00
MCS75
EKM00
MCS75
EKM00
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2088
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Tungsten 共W兲—Continued
Intensity
50
50
50
50
50
90
50
80
50
200
50
25
90
90
80
50
250
80
13
80
50
50
50
50
50
250
300
50
80
50
25
50
90
90
90
90
50
90
200
90
50
90
80
80
70
70
50
150
80
300
300
60
13
50
60
80
50
60
90
Wavelength 共Å兲
d
d
P
d
P
P
P
P
P
P
d
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2620.25
2622.21
2625.22
2632.48
2632.70
2633.13
2638.62
2646.18
2646.73
2656.54
2657.38
2658.032
2662.84
2671.47
2677.28
2678.88
2681.42
2695.67
2697.710
2699.59
2700.01
2706.58
2708.59
2708.80
2715.50
2718.91
2724.35
2725.03
2748.84
2762.34
2764.261
2769.74
2770.88
2774.00
2774.48
2792.70
2799.93
2818.06
2831.38
2833.63
2841.57
2848.02
2856.03
2866.06
2879.11
2879.40
2896.01
2896.44
2935.00
2944.40
2946.99
2947.39
2952.268
2964.52
2977.11
2979.71
2993.61
3016.47
3017.44
Spectrum
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
ATOMIC SPECTROSCOPIC DATA
2089
Strong Lines of Tungsten 共W兲—Continued
Intensity
50
50
90
60
120
80
50
50
50
50
50
80
200
15
80
50
70
90
60
80
120
120
150
130
80
200
80
1000
60
110
80
600
120
60
50
60
150
500
250
70
70
70
90
90
90
d
P
P
P
P
P
P
Wavelength 共Å兲
3041.73
3046.44
3049.69
3207.25
3215.56
3300.82
3311.38
3326.20
3331.69
3373.75
3495.24
3545.22
3617.52
3641.408
3682.08
3683.30
3688.06
3707.92
3757.92
3760.13
3768.45
3780.77
3817.48
3835.06
3846.22
3867.99
3881.41
4008.75
4015.22
4045.59
4069.95
4074.36
4102.70
4137.46
4171.17
4244.36
4269.38
4294.61
4302.11
4484.19
4659.87
4680.51
4843.81
5053.28
5224.66
Spectrum
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2090
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Tungsten 共W I兲
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
4
5
D
391o
0
1
0.00
39183.20
MCS75
M00
5d 6s
300
2551.35
250
2681.42
5d 5 ( 6 S)6s
7
S
402o
3
4
2951.29
40233.97
MCS75
300
2724.35
5d 5 ( 6 S)6s
7
S
396o
3
3
2951.29
39646.41
MCS75
200
2831.38
5d 5 ( 6 S)6s
7
S
382o
3
4
2951.29
38259.40
MCS75
150
2896.44
5d 5 ( 6 S)6s
7
S
374o
3
2
2951.29
37466.30
MCS75
300
2944.40
5d 5 ( 6 S)6s
7
S
369o
3
2
2951.29
36904.16
MCS75
300
2946.99
5d 5 ( 6 S)6s
7
S
368o
3
3
2951.29
36874.36
MCS75
120
3215.56
0.21
5d 4 6s 2
5
D
373o
4
5
6219.33
37309.16
MCS75
FW96
200
3617.52
0.11
5d 5 ( 6 S)6s
5d 4 ( 5 D)6s6p( 3 Po)
7
S
P
3
3
2951.29
30586.64
MCS75
FW96
5d 5 ( 6 S)6s
5d 5 ( 6 S)6p
7
S
P
3
4
2951.29
27889.68
MCS75
FW96
5d 5 ( 6 S)6s
5d 5 ( 6 S)6p
7
S
P
3
3
2951.29
27488.11
MCS75
FW96
5d 5 ( 6 S)6s
5d 5 ( 6 S)6p
7
S
P
3
2
2951.29
26229.77
MCS75
FW96
5d 5 ( 6 S)6s
5d 4 ( 5 D)6s6p( 3 Po)
7
S
Do
3
3
2951.29
26189.20
MCS75
FW96
1000
4008.75
600
4074.36
500
4294.61
250
4302.11
1.78
2
0.163
0.10
0.12
0.036
5 o
7 o
7 o
7 o
7
Energy Levels of Neutral Tungsten 共W I兲
Term
J
Level (cm⫺1 )
Ref
5
D
0
1
2
3
4
0.00
1670.29
3325.53
4830.00
6219.33
LC68
LC68
LC68
LC68
LC68
5d 5 ( 6 D)6s
7
S
3
2951.29
LC68
5d 4 6s 2
a 3P
0
1
2
9258.06
13307.10
19253.56
LC68
LC68
LC68
5d 4 ( 5 D)6s6p( 3 Po)
7
Do
3
26189.20
LC68
5d 5 ( 6 D)6p
7 o
2
3
4
26229.77
27488.11
27889.68
LC68
LC68
LC68
Configuration
4
5d 6s
2
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2091
Energy Levels of Neutral Tungsten 共W I兲—Continued
Configuration
4 5
3 o
5d ( D)6s6p( P )
Term
J
Level (cm⫺1 )
Ref
5 o
P
3
30586.64
LC68
368o
3
36874.36
LC68
369o
2
36904.16
LC68
373o
5
37309.16
LC68
o
374
2
37466.30
LC68
382o
4
38259.40
LC68
391o
1
39183.20
LC68
o
396
3
39646.41
LC68
402o
4
40233.97
LC68
Limit
63427.7
CS96
W II ( 6 D1/2)
Persistent Lines of Singly-ionized Tungsten 共W II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
J
Level (cm⫺1 )
Wl Ref
A Ref
1000
1951.051
2.16
5d ( D)6s
6
D
5o
1/2
3/2
0.000
51254.429
EKM00
EKM00
900
1962.140
3.38
5d 4 ( 5 D)6s
6
D
8o
5/2
3/2
3172.473
54137.225
EKM00
EKM00
900
1989.394
1.97
5d 4 ( 5 D)6s
6
D
12o
9/2
9/2
6147.085
56413.649
EKM00
EKM00
400
2001.712
0.50
5d 4 ( 5 D)6s
6
D
6o
5/2
5/2
3172.473
53113.533
EKM00
EKM00
800
2008.095
1.68
5d 4 ( 5 D)6s
6
D
10o
7/2
7/2
4716.278
54498.608
EKM00
EKM00
300
2009.982
0.65
5d 4 ( 5 D)6s
6
D
5o
3/2
3/2
1518.829
51254.429
EKM00
EKM00
500
2026.088
1.18
5d 4 ( 5 D)6s
6
D
7o
7/2
9/2
4716.278
54056.594
EKM00
EKM00
900
2029.995
2.38
5d 4 ( 5 D)6s
6
9/2
9/2
6147.085
55392.446
EKM00
EKM00
600*
2079.118
3.80
5d 4 ( 5 D)6s
6
9/2
11/2
6147.085
54229.082
EKM00
EKM00
600*
2079.120
0.63
5d 4 ( 5 D)6s
6
D
5o
5/2
3/2
3172.473
51254.429
EKM00
EKM00
400
2094.751
2.03
5d 4 ( 5 D)6s
6
3/2
5/2
1518.829
49242.042
EKM00
EKM00
80
2204.483
1.66
5d 4 ( 5 D)6s
5d 4 ( 5 D)6p
6
D
F
9/2
11/2
6147.085
51495.054
EKM00
EKM00
5d 4 ( 5 D)6s
5d 3 ( 4 F)6s6 p
6
D
F
1/2
1/2
0.000
44455.212
EKM00
EKM00
30
2248.758
2.84
4 5
Term
D
11o
D
9o
D
4o
6 o
6 o
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2092
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Tungsten 共W II兲—Continued
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
4 5
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
25
2554.853
0.22
5d ( D)6s
6
D
2o
1/2
3/2
0.000
39129.460
EKM00
EKM00
40
2555.095
0.50
5d 4 ( 5 D)6s
5d 4 ( 5 D)6p
6
D
3o
5/2
3/2
3172.473
42298.223
EKM00
EKM00
25
2764.261
0.54
5d 4 ( 5 D)6s
5d 4 6 p
6
1/2
1/2
0.000
36165.356
EKM00
EKM00
D
1o
Energy Levels of Singly-ionized Tungsten 共W II兲
Configuration
Term
5d 4 ( 5 D)6s
6
5d 5
5d 4 (a 3 F)6s
5d 4 6p
5d 4 ( 5 D)6p
3 4
5d ( F)6s6p
5d 4 ( 5 D)6p
D
J
Level (cm⫺1 )
Ref
1/2
3/2
5/2
7/2
9/2
0.000
1518.829
3172.473
4716.278
6147.085
EKM00
EKM00
EKM00
EKM00
EKM00
6
S
5/2
7420.261
EKM00
4
F
3/2
5/2
7/2
8711.274
11301.024
13411.939
EKM00
EKM00
EKM00
1
9/2
14857.160
EKM00
1o
1/2
36165.356
EKM00
2o
3/2
39129.460
EKM00
3o
3/2
42298.223
EKM00
6 o
F
1/2
44455.212
EKM00
4o
5/2
49242.042
EKM00
5o
3/2
51254.429
EKM00
6 o
F
11/2
51495.054
EKM00
o
5/2
53113.533
EKM00
7o
9/2
54056.594
EKM00
8o
3/2
54137.225
EKM00
6
9o
11/2
54229.082
EKM00
o
7/2
54498.608
EKM00
11o
9/2
55392.446
EKM00
12o
9/2
56413.649
EKM00
10
5
W III ( D0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
130000
MH84
ATOMIC SPECTROSCOPIC DATA
2093
Uranium „U…
Atomic number⫽92
Atomic weight⫽238.0289
Isotope
234
U
U
238
U
235
Mass
Abundance
Spin
Mag moment
34.040946
35.043924
38.050784
0.005%
0.720%
99.275%
0
7/2
0
⫺0.35
U I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 3 6d7s 2 5Lo6
Ionization energy: 49 958.4 cm⫺1 共6.1941 eV兲
o
U II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 104 f 145s 2 5 p 6 5d 106s 2 6 p 6 5 f 3 7s 2 4I9/2
⫺1
Ionization energy: 85 000 cm 共10.6 eV兲
Strong Lines of Uranium 共U兲
Intensity
120
150
200
130
130
200
140
200
200
250
150
150
120
250
150
120
120
120
130
130
120
130
130
120
120
120
200
140
140
150
140
150
200
120
250
120
200
110
100
Wavelength 共Å兲
Air
2635.529
2793.934
2802.560
2807.119
2817.958
2821.121
2828.935
2832.061
2865.681
2889.624
2906.794
2908.272
2931.414
2941.916
2943.896
2956.060
2967.936
2971.066
3022.210
3031.987
3050.197
3057.939
3062.537
3072.783
3093.005
3102.422
3111.618
3124.952
3149.240
3229.499
3232.156
3291.332
3305.8912
3357.8437
3390.3775
3424.5566
3435.4913
3459.9191
3462.2200
Spectrum
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
I
I
Ref
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2094
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Uranium 共U兲—Continued
Intensity
140
200
100
110
140
500
110
200
100
250
100
500
130
100
100
100
250
200
100
400
120
700
150
100
110
130
1000
120
140
100
100
100
250
130
200
150
300
600
200
110
120
140
200
200
150
100
130
150
400
120
120
120
600
150
400
400
200
500
1000
Wavelength 共Å兲
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
3463.5479
3466.3010
3473.4269
3480.3634
3482.4900
3489.3672
3493.9963
3500.0760
3504.0089
3507.3442
3513.6742
3514.6107
3533.5659
3534.3346
3542.5704
3549.2018
3550.8223
3555.3188
3561.4110
3561.8038
3563.6559
3566.5909
3569.0781
3574.7602
3577.9162
3578.7211
3584.8774
3591.7443
3605.2742
3616.3305
3620.0838
3622.6987
3638.1986
3644.2422
3651.5366
3652.0641
3659.1548
3670.0701
3701.5161
3713.5546
3738.0405
3746.4190
3748.6758
3751.1746
3758.3480
3763.2643
3766.8864
3773.4339
3782.8407
3793.1002
3793.2638
3808.9207
3811.9911
3826.5084
3831.4593
3839.6255
3854.2202
3854.6448
3859.5716
Spectrum
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
I
I
I
II
I
I
I
I
I
I
I
II
I
I
I
II
I
I
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
II
II
I
II
II
II
I
I
I
I
I
II
II
I
I
I
II
II
I
I
II
II
Ref
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
SPMR72
PKE80
PKE80
PKE80
ATOMIC SPECTROSCOPIC DATA
2095
Strong Lines of Uranium 共U兲—Continued
Intensity
400
500
130
130
200
400
130
150
130
120
100
100
400
400
110
120
250
130
120
300
130
300
200
400
150
300
120
300
110
200
140
130
130
100
120
130
50
50
70
30
25
7
9
15
13
30
10
15
15
30
25
10
P
P
P
P
P
P
P
P
P
P
P
P
P
P,h
P
P
P
Wavelength 共Å兲
3865.9176
3871.0353
3874.0387
3878.0847
3881.4546
3890.3615
3892.6810
3894.1206
3899.7775
3906.4530
3926.2078
3926.7153
3932.0221
3943.8161
3964.2064
3966.5211
3985.7924
4005.2094
4017.7163
4042.7496
4047.6117
4050.0412
4062.5440
4090.1319
4116.0974
4153.9710
4156.6483
4171.5886
4222.3677
4241.6646
4341.6865
4355.7400
4362.0510
4393.5858
4472.3297
4543.6255
4756.8059
5027.3841
5915.385
6826.913
8607.950
8691.282
8757.760
10157.91
10259.55
10554.93
11167.84
11384.13
11859.42
11908.83
13185.16
13961.58
Spectrum
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
II
I
II
II
II
II
II
I
II
I
I
I
II
I
I
II
II
I
II
I
I
II
II
II
II
I
I
II
I
II
II
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
SPMR72
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
PKE80
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
BW92b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2096
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Neutral Uranium 共U I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
2
5 o
L
6
5
0.000
28650.294
SPMR72
M00
Configuration
3 4 o
500
3489.3672
0.13
5 f ( I )6d7s
500
3514.6107
0.12
5 f 3 ( 4 Io)6d7s 2
5 o
L
6
5
0.000
28444.517
SPMR72
M00
400
3561.8038
0.057
5 f 3 ( 4 Io)6d7s 2
5 o
L
6
5
0.000
28067.646
SPMR72
M00
700
3566.5909
0.24
5 f 3 ( 4 Io)6d7s 2
5
Ko
5
5
620.323
28650.294
SPMR72
M00
1000
3584.8774
0.19
5 f 3 ( 4 Io)6d7s 2
5 f 3 6d 2 7 p
5 o
L
N
6
7
0.000
27886.995
SPMR72
M00
7
5 f 3 ( 4 Io)6d7s 2
5
Ko
5
6
620.323
27941.253
SPMR72
5 f 3 ( 4 Io)6d7s 2
5 o
L
6
6
0.000
26225.569
SPMR72
5 f 3 ( 4 Io)6d7s 2
5 o
L
7
7
3800.829
29837.643
SPMR72
300
3659.1548
600
3811.9911
400
3839.6255
500
3871.0353
0.19
5 f 3 ( 4 Io)6d7s 2
5 o
L
6
6
0.000
25825.565
PKE80
M00
400
3943.8161
0.21
5 f 3 ( 4 Io)6d7s 2
5 o
L
6
6
0.000
25348.977
PKE80
M00
300
4042.7496
5 f 3 ( 4 Io)6d7s 2
5
Ko
5
6
620.323
25348.977
PKE80
300
4153.9710
5 f 3 ( 4 Io)6d7s 2
5 o
L
6
7
0.000
24066.566
PKE80
120
4156.6483
5 f 3 ( 4 Io)6d7s 2
5
Ko
5
6
620.323
24671.388
PKE80
130
4355.7400
5 f 3 ( 4 Io)6d7s 2
5
Ko
5
6
620.323
23572.086
PKE80
130
4362.0510
5 f 3 ( 4 Io)6d7s 2
5 f 3 6d7s7 p
5 o
L
L
6
7
0.000
22918.553
PKE80
M00
5 f 3 ( 4 Io)6d7s 2
5 f 3 6d7s7 p
5 o
6
7
0.000
16900.386
PKE80
M00
70
5915.385
0.16
0.12
0.11
0.045
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
5
7
L
M
M00
M00
ATOMIC SPECTROSCOPIC DATA
2097
Energy Levels of Neutral Uranium 共U I兲
Configuration
3 4 o
5 f ( I )6d7s
Term
2
5 o
L
Level (cm⫺1 )
Ref
6
7
8
9
10
0.000
3800.829
7645.645
11308.153
14845.326
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 3 ( 4 Io)6d7s 2
5
5
6
7
8
9
620.323
4275.707
7326.118
10685.787
13535.186
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 3 ( 4 Io)6d7s 2
o
3
3868.486
BW92b
5 f 3 ( 4 Io)6d7s 2
5 o
4
4453.419
BW92b
5 f 3 ( 4 Io)6d7s 2
o
5
5762.079
BW92b
5 f 3 ( 4 Fo)6d7s 2
o
3 4 o
5 f ( I )6d7s
2
Ko
J
I
0
5988.061
BW92b
o
H
4
5991.314
BW92b
Mo
6
6249.029
BW92b
5
5 f 3 ( 4 Io)6d 2 ( 2 F)7s
7
5 f 3 ( 4 Io)6d7s 2
o
6
7005.532
BW92b
5 f 4 7s 2
5
4
5
6
7
8
7020.709
10051.312
12643.378
14858.786
16862.069
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 3 ( 4 Io)6d7s 2
o
3
7103.921
BW92b
5 f 3 ( 4 Io)6d7s 2
5
2
7191.682
BW92b
5 f 3 ( 4 Io)6d7s 2
5
Ko
7
7326.118
BW92b
5 o
L
8
7645.645
BW92b
5 f 3 ( 4 Io)6d7s 2
5 o
I
5
7864.204
BW92b
5 f 3 ( 4 Io)6d 2 ( 2 F)7s
7
Mo
7
8118.632
BW92b
5 f 3 6d7s 2
5
Ho
3 4 o
5 f ( I )6d7s
2
I
Go
4
8133.291
BW92b
2
o
2
8856.992
BW92b
5 f 3 ( 4 Fo)6d7s 2
o
3
8878.547
BW92b
5 f 3 6d7s7p
7
M
7
16900.386
BW92b
5 f 3 6d7s7p
5
L
7
22918.553
BW92b
6
23572.086
BW92b
7
24066.566
BW92b
6
24671.388
BW92b
6
25348.977
BW92b
6
25825.565
BW92b
6
26225.569
BW92b
3 4 o
5 f ( F )6d7s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2098
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Uranium 共U I兲—Continued
Configuration
3
2
5 f 6d 7p
Term
J
Level (cm⫺1 )
7
7
27886.995
BW92b
6
27941.253
BW92b
5
28444.517
BW92b
5
28650.294
BW92b
7
29837.643
BW92b
6
31871.569
BW92b
49958.4
CABC82
N
o
)
U II ( 4 I9/2
Limit
Ref
Persistent Lines of Singly-ionized Uranium 共U II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
600
3670.0701
0.26
Configuration
Term
914.765
28154.450
SPMR72
L
11/2
13/2
289.041
26716.697
SPMR72
I
7/2
9/2
4663.803
30756.116
SPMR72
I
Ko
7/2
9/2
4663.803
30599.179
PKE80
L
M
11/2
13/2
289.041
26191.309
PKE80
NIJL02
11/2
11/2
2294.696
28154.450
PKE80
NIJL02
L
400
3831.4593
5 f 4 ( 5 I)7s
5 f 47 p
6
5 f 4 ( 5 I)7s
5 f 4 ( 5 Io)7p
6
5 f 3 ( 4 Io)6d7s
5 f 3 6d7 p
6 o
5 f 3 ( 4 Io)6d7s
5 f 3 6d7 p
o
400
3865.9176
0.27
0.14
NIJL02
9/2
11/2
6 o
3859.5716
A Ref
Ko
L
6
5 f 3 ( 4 Io)6d7s
1000
Wl Ref
6
3782.8407
3854.6448
Level (cm⫺1 )
5 f 3 ( 4 Io)6d7s
5 f 3 6d7 p
400
500
J
o
6
6
6
400
3890.3615
5 f 3 ( 4 Io)6d7s
6 o
L
11/2
13/2
289.041
25986.312
PKE80
400
3932.0221
5 f 3 ( 4 Io)6d7s
6 o
L
11/2
13/2
289.041
25714.049
PKE80
300
4050.0412
5 f 3 ( 4 Io)7s 2
5 f 3 7s7 p
4 o
I
I
9/2
9/2
0.000
24684.132
PKE80
NIJL02
5 f 3 ( 4 Io)6d7s
5 f 3 6d7 p
6 o
L
M
13/2
13/2
1749.123
26191.309
PKE80
NIJL02
400
4090.1319
0.080
0.19
6
6
300
4171.5886
0.092
5 f 3 ( 4 Io)6d7s
6 o
13/2
13/2
1749.123
25714.049
PKE80
NIJL02
200
4241.6646
0.24
5 f 3 ( 4 Io)6d 2 ( 3 F)
5 f 3 6d7 p
o
13/2
11/2
4585.434
28154.450
PKE80
NIJL02
5 f 3 ( 4 Io)6d7s
5 f 3 7s7 p
6 o
L
K
11/2
9/2
289.041
23315.090
PKE80
NIJL02
5 f 3 ( 4 Io)6d7s
6
Ko
L
9/2
11/2
914.765
22917.451
PKE80
140
130
4341.6865
0.070
4543.6255
L
6
6
6
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
L
ATOMIC SPECTROSCOPIC DATA
2099
Energy Levels of Singly-ionized Uranium 共U II兲
J
Level (cm⫺1 )
Ref
4 o
I
9/2
11/2
13/2
15/2
0.000
4420.870
8276.733
11708.483
BW92b
BW92b
BW92b
BW92b
5 f 3 ( 4 Io)6d7s
6 o
L
11/2
13/2
15/2
17/2
19/2
21/2
289.041
1749.123
5259.652
8853.748
12350.355
—
BW92b
BW92b
BW92b
BW92b
BW92b
5 f 3 ( 4 Io)6d7s
6
Ko
9/2
914.765
BW92b
5 f 3 ( 4 Io)6d7s
o
11/2
2294.696
BW92b
5 f 3 ( 4 Io)6d 2 ( 3 F)
o
13/2
4585.434
BW92b
7/2
4663.803
BW92b
Configuration
Term
5 f 3 ( 4 Io)7s 2
4 5
5 f ( I)7s
6
5 f 3 ( 4 Io)6d7s
o
5/2
4706.272
BW92b
5 f 3 6d7s
o
7/2
5401.504
BW92b
5 f 3 ( 4 Io)6d7s
6
13/2
5526.748
BW92b
7/2
5667.331
BW92b
9/2
5716.449
BW92b
11/2
5790.641
BW92b
13/2
6283.431
BW92b
9/2
6445.035
BW92b
3 4 o
5 f ( I )6d7s
I
Ko
6 o
I
5 f 4 ( 5 I)7s
5 f 3 ( 4 Io)6d7s
o
5 f 3 ( 4 Io)6d7s
4 o
3 4 o
L
5 f ( I )6d7s
o
5 f 3 ( 4 Fo)7s 2
4 o
3/2
7017.172
BW92b
5 f 3 6d7s
o
9/2
7166.630
BW92b
5 f 3 ( 4 Io)6d7s
o
7/2
7547.373
BW92b
5 f 6d7s
o
11/2
7598.355
BW92b
5 f 4 ( 5 I)7s
6
11/2
8347.689
BW92b
5 f 3 ( 4 Io)6d7s
o
9/2
8379.696
BW92b
5 f 3 ( 4 Io)6d 2
6
15/2
8394.362
BW92b
3/2
8400.125
BW92b
9/2
8423.417
BW92b
o
5/2
8430.185
BW92b
5 f 6d7s
o
11/2
8510.866
BW92b
5 f 3 ( 4 Io)6d7s
6
15/2
8521.922
BW92b
5 f 3 6d7s
o
13/2
8755.640
BW92b
5 f 3 6d7s
o
7/2
9075.731
BW92b
5 f 6d7s
o
9/2
9241.971
BW92b
5 f 3 6d7s
o
5/2
9344.624
BW92b
3
3 4 o
5 f ( I )6d7s
F
I
Mo
o
5 f 4 ( 5 I)7s
5 f 3 ( 4 Io)6d7s
3
3
Ko
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2100
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Uranium 共U II兲—Continued
J
Level (cm⫺1 )
5 f ( I )6d7s
6 o
11/2
9553.185
BW92b
5 f 3 ( 4 Io)6d7s
o
13/2
9626.113
BW92b
5 f 3 ( 2 Ho)7s 2
o
9/2
9690.665
BW92b
5 f 3 ( 4 Fo)6d7s
o
3/2
9881.618
BW92b
5 f ( I )6d7s
o
9/2
9882.725
BW92b
5 f 3 6d7s
o
7/2
9933.224
BW92b
Configuration
3 4 o
3 4 o
Term
I
Ref
6
L
11/2
22917.451
BW92b
5 f 7s7p
6
K
9/2
23315.090
BW92b
5 f 3 7s7p
6
I
9/2
24684.132
BW92b
13/2
25714.049
BW92b
13/2
25986.312
BW92b
13/2
26191.309
BW92b
13/2
26716.697
BW92b
3
3
5 f 6d7p
6
M
5 f 3 6d7p
6
L
11/2
28154.450
BW92b
5 f 4 ( 5 Io)7p
6
Ko
9/2
30599.179
BW92b
9/2
30756.116
BW92b
85000
SRC71
4
5 f 7p
o
U III ( 5 I4 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
2101
Vanadium „V…
Atomic number⫽23
Atomic weight⫽50.9415
Isotope
50
51
V
V
Mass
Abundance
Spin
Mag moment
49.947161
50.943962
0.25%
99.75%
6
7/2
⫹3.34745
⫹5.1574
V I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 3 4s 2 4F3/2
Ionization energy: 54 411.7 cm⫺1 共6.746 19 eV兲
V II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 5D0
Ionization energy: 117 900 cm⫺1 共14.618 eV兲
Strong Lines of Vanadium 共V兲
Intensity
20
20
30
20
20
300
200
140
150
20
20
250
140
250
400
250
130
600
200
140
150
30
60
600
400
200
250
120
20
20
20
300
20
150
30
150
20
20
20
20
P
P
P
P
P
P
Wavelength 共Å兲
Air
2507.782
2519.622
2526.221
2530.183
2574.018
2687.954
2700.937
2706.174
2715.664
2864.361
2868.095
2891.644
2892.433
2892.652
2893.307
2906.454
2907.462
2908.810
2910.016
2910.385
2911.058
2914.926
2923.619
2924.017
2924.630
2930.805
2941.372
2941.499
2942.319
2942.388
2943.189
2944.569
2949.629
2952.068
2962.781
2968.374
2977.540
3043.119
3043.548
3044.933
Spectrum
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
I
I
I
I
I
II
II
II
II
I
I
II
II
II
II
II
II
II
II
II
II
I
I
II
II
II
II
II
I
I
I
II
I
II
I
II
I
I
I
I
Ref
DA78
DA78
DA78
DA78
DA78
ICL88
ICL88
ICL88
ICL88
DA78
DA78
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
DA78
DA78
ICL88
ICL88
ICL88
ICL88
ICL88
DA78
DA78
DA78
ICL88
DA78
ICL88
DA78
ICL88
DA78
DA78
DA78
DA78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2102
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Vanadium 共V兲—Continued
Intensity
40
100
120
200
1000
800
700
500
400
140
110
250
400
300
110
140
200
40
60
40
40
30
300
250
200
150
20
50
150
150
150
130
50
20
20
25
25
25
50
40
110
80
120
40
80
300
150
50
20
40
90
50
50
25
40
20
80
110
20
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3053.653
3056.334
3060.456
3066.374
3093.102
3102.292
3110.709
3118.376
3125.282
3130.272
3133.339
3183.412
3183.992
3185.385
3187.717
3188.522
3190.686
3198.012
3202.389
3205.577
3207.408
3212.432
3267.702
3271.124
3276.130
3517.296
3529.733
3533.676
3545.195
3556.800
3589.763
3592.021
3592.530
3663.604
3667.741
3673.406
3675.699
3680.119
3683.118
3687.498
3688.069
3690.282
3692.222
3695.342
3695.864
3703.574
3704.703
3705.038
3778.675
3790.325
3794.962
3799.907
3803.475
3807.502
3808.517
3809.596
3813.485
3818.240
3819.960
Spectrum
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
I
I
I
I
II
II
II
II
II
II
II
I
I
I
II
II
II
I
I
I
I
I
II
II
II
II
I
I
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
DA78
DA78
DA78
DA78
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
ICL88
D76
D76
DA78
ICL88
ICL88
ICL88
DA78
DA78
DA78
DA78
DA78
ICL88
ICL88
ICL88
ICL88
DA78
DA78
ICL88
ICL88
ICL88
ICL88
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
ATOMIC SPECTROSCOPIC DATA
2103
Strong Lines of Vanadium 共V兲—Continued
Intensity
20
50
40
25
140
25
50
200
30
25
100
250
110
20
120
40
50
60
40
200
60
20
20
20
20
40
20
40
30
30
25
20
20
90
150
70
250
50
20
20
250
200
700
20
400
150
20
150
250
250
200
20
20
30
50
40
40
40
30
P
P
P
P
P
P
Wavelength 共Å兲
3821.483
3822.002
3822.886
3823.209
3828.555
3834.216
3840.429
3840.750
3844.434
3847.326
3855.363
3855.845
3864.856
3867.601
3875.071
3875.898
3876.082
3890.179
3892.858
3902.256
3909.888
3922.431
3924.651
3930.022
3934.010
3990.570
3992.802
3998.726
4050.955
4051.347
4057.064
4063.928
4071.536
4090.571
4092.684
4095.477
4099.784
4102.151
4104.382
4104.767
4105.155
4109.778
4111.780
4113.506
4115.180
4116.473
4119.446
4123.503
4128.064
4131.989
4134.485
4179.408
4209.853
4232.458
4268.638
4271.550
4276.953
4284.047
4291.82
Spectrum
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2104
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Vanadium 共V兲—Continued
Intensity
40
40
60
80
1000 P
600 P
400 P
300 P
120
200
250
300 P
400 P
50
50
40
25
20
40
50
70
50
50
30
80
150
50
30
30
30
25
40
50
70
110
20
25
40
50
60
30
25
100
80
50
70
20
20
40
40
110 P
25
50
25
40
40
40
60
25
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4330.026
4332.825
4341.008
4352.871
4379.230
4384.710
4389.980
4395.223
4400.572
4406.638
4407.633
4408.195
4408.501
4416.469
4421.566
4426.002
4428.517
4429.800
4436.133
4437.830
4441.68
4444.192
4452.006
4457.470
4459.752
4460.331
4462.360
4469.705
4488.889
4545.395
4560.716
4577.178
4580.403
4586.370
4594.119
4619.777
4851.489
4864.733
4875.486
4881.555
5627.631
5670.847
5698.529
5703.586
5706.997
5727.046
5731.248
5737.065
6039.728
6081.440
6090.208
6111.650
6119.528
6135.363
6199.191
6216.370
6230.803
6243.110
6251.823
Spectrum
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
MCS75
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
DA78
ATOMIC SPECTROSCOPIC DATA
2105
Persistent Lines of Neutral Vanadium 共V I兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
3
2
Term
J
Level (cm⫺1 )
4
Wl Ref
A Ref
250
3183.412
2.4
3d 4s
3d 3 ( 4 F)4s4 p( 1 Po)
a F
x 4Go
5/2
7/2
137.382
31541.147
D76
FW96
400
3183.992
2.5
3d 3 4s 2
3d 3 ( 4 F)4s4 p( 1 Po)
a 4F
x 4Go
7/2
9/2
323.457
31721.708
D76
FW96
300
3185.385
2.8
3d 3 4s 2
3d 3 ( 4 F)4s4 p( 1 Po)
a 4F
x 4Go
9/2
11/2
552.961
31937.266
DA78
M03
300
3703.574
0.92
3d 4 ( 5 D)4s
3d 3 ( 4 P)4s4 p( 3 Po)
a 6D
y 6Po
9/2
7/2
2424.783
29418.073
DA78
FW96
250
3855.845
0.578
3d 3 4s 2
3d 4 ( 5 D)4p
a 4F
y 4Do
9/2
7/2
552.961
26480.291
DA78
FW96
200
3902.256
0.268
3d 3 4s 2
3d 4 ( 5 D)4p
a 4F
y 4Fo
9/2
9/2
552.961
26171.916
DA78
FW96
700
4111.780
1.01
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Do
9/2
9/2
2424.783
26738.318
DA78
FW96
400
4115.180
0.58
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Do
7/2
7/2
2311.355
26604.796
DA78
FW96
250
4128.064
0.77
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Do
5/2
3/2
2220.106
26437.640
DA78
FW96
250
4131.989
0.55
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Do
7/2
5/2
2311.355
26505.932
DA78
FW96
1000
4379.230
1.1
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
9/2
11/2
2424.783
25253.432
DA78
FW96
600
4384.710
1.1
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
7/2
9/2
2311.355
25111.467
DA78
FW96
400
4389.980
0.69
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
5/2
7/2
2220.106
24992.884
DA78
FW96
300
4395.223
0.55
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
3/2
5/2
2153.207
24898.771
DA78
FW96
300
4408.195
0.60
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
5/2
5/2
2220.106
24898.771
DA78
FW96
400
4408.501
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
3/2
3/2
2153.207
24830.228
DA78
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 6D
y 6Fo
1/2
1/2
2112.282
24789.385
3d 4 ( 5 D)4s
3d 4 ( 5 D)4p
a 4D
z 4Po
7/2
5/2
8715.761
25131.005
110
6090.208
0.26
DA78
FW96
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2106
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Vanadium 共V I兲
Configuration
Level (cm⫺1 )
Term
J
4
a F
3/2
5/2
7/2
9/2
0.00
137.38
323.46
552.96
DA78
DA78
DA78
DA78
3d 4 ( 5 D)4s
a 6D
1/2
3/2
5/2
7/2
9/2
2112.28
2153.21
2220.11
2311.36
2424.78
DA78
DA78
DA78
DA78
DA78
3d 4 ( 5 D)4s
a 4D
1/2
3/2
5/2
7/2
8413.00
8476.23
8578.53
8715.76
DA78
DA78
DA78
DA78
3d 3 4s 2
a 4P
1/2
3/2
5/2
9544.63
9637.03
9824.61
DA78
DA78
DA78
3d 4 ( 5 D)4p
z 6Po
3/2
5/2
7/2
24648.11
24727.86
24838.55
DA78
DA78
DA78
3d 4 ( 5 D)4p
z 4Po
1/2
3/2
5/2
24770.68
24915.14
25131.00
DA78
DA78
DA78
3d 4 ( 5 D)4p
y 6Fo
1/2
3/2
5/2
7/2
9/2
11/2
24789.38
24830.23
24898.77
24992.88
25111.47
25253.43
DA78
DA78
DA78
DA78
DA78
DA78
3d 4 ( 5 D)4p
y 4Fo
3/2
5/2
7/2
9/2
25930.55
26004.23
26122.08
26171.92
DA78
DA78
DA78
DA78
3d 4 ( 5 D)4p
y 4Do
1/2
3/2
5/2
7/2
26182.63
26249.48
26352.65
26480.29
DA78
DA78
DA78
DA78
3d 4 ( 5 D)4p
y 6Do
1/2
3/2
5/2
7/2
9/2
26397.54
26437.64
26505.93
26604.80
26738.32
DA78
DA78
DA78
DA78
DA78
3d 3 ( 4 P)4s4p( 3 Po)
y 6Po
3/2
5/2
7/2
29202.75
29296.38
29418.07
DA78
DA78
DA78
3d 3 ( 2 G)4s4p( 3 Po)
x 4Fo
3/2
5/2
7/2
9/2
31200.15
31229.03
31268.11
31317.44
DA78
DA78
DA78
DA78
3
3d 4s
2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Ref
ATOMIC SPECTROSCOPIC DATA
2107
Energy Levels of Neutral Vanadium 共V I兲—Continued
Configuration
3 4
1 o
3d ( F)4s4p( P )
Term
J
Level (cm⫺1 )
4
5/2
7/2
9/2
11/2
31397.83
31541.15
31721.71
31937.27
DA78
DA78
DA78
DA78
Limit
54411.7
JKLC94
o
x G
V II ( 5 D0 )
Ref
Persistent Lines of Singly-ionized Vanadium 共V II兲
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
4
Term
J
Level (cm⫺1 )
Wl Ref
5
A Ref
300
2687.954
0.767
3d
3d 3 ( 4 F)4p
a D
z 5Do
4
4
339.21
37531.08
ICL88
M03
200
2700.937
0.345
3d 4
3d 3 ( 4 F)4p
a 5D
z 5Fo
4
5
339.21
37352.45
ICL88
M03
400
2893.307
1.1
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Do
4
3
2968.27
37520.57
ICL88
BGFM89
600
2908.810
1.54
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Do
5
4
3162.80
37531.08
ICL88
BGFM89
600
2924.017
1.73
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Fo
5
5
3162.80
37352.45
ICL88
BGFM89
400
2924.630
1.21
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Fo
4
4
2968.27
37150.51
ICL88
BGFM89
1000
3093.102
2.1
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Go
5
6
3162.80
35483.39
ICL88
BGFM89
800
3102.292
1.77
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Go
4
5
2968.27
35193.13
ICL88
BGFM89
700
3110.709
1.68
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Go
3
4
2808.82
34946.55
ICL88
BGFM89
500
3118.376
1.54
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Go
2
3
2687.11
34745.72
ICL88
BGFM89
400
3125.282
1.51
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 5F
z 5Go
1
2
2604.88
34592.75
ICL88
BGFM89
200
3190.686
0.33
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 3F
z 3Fo
4
4
9097.83
40430.04
ICL88
BGFM89
200
3276.130
0.52
3d 3 ( 4 F)4s
3d 3 ( 4 F)4p
a 3F
z 3Go
4
5
9097.83
39612.96
ICL88
BGFM89
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2108
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Vanadium 共V II兲
Configuration
Level (cm⫺1 )
Ref
Term
J
5
a D
0
1
2
3
4
0.00
36.05
106.63
208.89
339.21
ICL88
ICL88
ICL88
ICL88
ICL88
3d 3 ( 4 F)4s
a 5F
1
2
3
4
5
2604.88
2687.11
2808.82
2968.27
3162.80
ICL88
ICL88
ICL88
ICL88
ICL88
3d 3 ( 4 F)4s
a 3F
2
3
4
8640.31
8841.97
9097.83
ICL88
ICL88
ICL88
3d 3 ( 4 F)4p
z 5Go
2
3
4
5
6
34592.75
34745.72
34946.55
35193.13
35483.39
ICL88
ICL88
ICL88
ICL88
ICL88
3d 3 ( 4 F)4p
z 5Fo
2
3
1
4
5
36673.48
36919.21
36954.63
37150.51
37352.45
ICL88
ICL88
ICL88
ICL88
ICL88
3d 3 ( 4 F)4p
z 5Do
0
1
2
3
4
37201.35
37259.39
37368.96
37520.57
37531.08
ICL88
ICL88
ICL88
ICL88
ICL88
3d 3 ( 4 F)4p
z 3Go
3
4
5
39234.05
39403.74
39612.96
ICL88
ICL88
ICL88
3d 3 ( 4 F)4p
z 3Fo
2
3
4
40001.70
40195.52
40430.04
ICL88
ICL88
ICL88
3d
4
V III ( 4 F3/2)
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
117900
ICL88
ATOMIC SPECTROSCOPIC DATA
2109
Xenon „Xe…
Atomic number⫽54
Atomic weight⫽131.29
Isotope
128
Xe
Xe
130
Xe
131
Xe
132
Xe
134
Xe
136
Xe
129
Mass
Abundance
Spin
127.903531
128.904780
129.903509
130.905072
131.904144
133.905395
135.907214
1.91%
26.4%
4.1%
21.2%
26.9%
10.4%
8.9%
0
1/2
0
3/2
0
0
0
Mag moment
⫺0.7768
Xe I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 1S0
Ionization energy: 97 833.79 cm⫺1 共12.129 84 eV兲
o
Xe II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 5 2P3/2
Ionization energy: 169 175 cm⫺1 共20.9750 eV兲
Strong Lines of Xenon 共Xe兲
Intensity
120
120
200
120
200
80
250
250
150
250
400
300
400
700
200
400
200
80
250
25
200
25
100
60
70
50
130
30
100
70
30
1
1
1
P
P
P
P
P
P
P
P
P
P
P
P
h
h
h
h
Wavelength 共Å兲
Vacuum
740.41
803.07
880.80
885.54
925.87
935.40
972.77
976.68
1032.44
1037.68
1041.31
1048.27
1051.92
1074.48
1083.86
1100.43
1158.47
1169.63
1183.05
1192.0376
1244.76
1250.2091
1295.5878
1469.6123
Air
2864.73
2895.22
2979.32
3017.43
3121.87
3366.72
3461.26
3506.74
3549.86
3554.04
Spectrum
Ref.
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
I
I
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
B36
BVHU01
B36
BVHU01
BVHU01
BVHU01
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
II
II
II
II
II
II
II
I
I
I
H39
H39
H39
H39
H39
H39
H39
HM33
HM33
HM33
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2110
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Xenon 共Xe兲—Continued
Intensity
2
1
1
1
4
4
30
30
70
30
70
300
150
100
30
100
30
100
130
150
30
150
150
300
70
30
150
150
70
50
150
300
150
30
60
15
50
40
30
700
50
50
70
130
100
30
20
70
300
100
30
30
100
130
30
150
150
700
100
l
l
h
l
h
h
h
h
h
h
h
h
l
h
h
l
h
l
h
l
l
l
h
h
l
l
P
l
l
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3610.32
3613.06
3633.06
3669.91
3685.90
3693.49
3907.91
4037.59
4057.46
4098.89
4158.04
4180.10
4193.15
4208.48
4209.47
4213.72
4215.60
4223.00
4238.25
4245.38
4251.57
4296.40
4310.51
4330.52
4369.20
4373.78
4393.20
4395.77
4406.88
4416.07
4448.13
4462.19
4480.86
4521.86
4734.152
4792.619
4807.02
4829.71
4843.29
4844.33
4916.51
4923.152
4971.71
4972.71
4988.77
4991.17
5028.280
5044.92
5080.62
5122.42
5125.70
5178.82
5188.04
5191.37
5192.10
5260.44
5261.95
5292.22
5309.27
Spectrum
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
II
I
I
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
Ref.
HM33
HM33
HM33
HM33
HM33
HM33
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
HM33
HM33
HM33
HM33
HM33
HP87
HM33
HM33
H39
H39
H39
H39
HM33
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
ATOMIC SPECTROSCOPIC DATA
2111
Strong Lines of Xenon 共Xe兲—Continued
Intensity
300
700
70
70
150
10
1000
250
100
70
130
300
30
70
200
10
100
100
200
50
10
70
70
150
150
100
100
30
30
15
10
100
10
70
10
150
100
700
70
300
700
200
500
130
30
30
15
12
30
150
10
150
130
30
10
80
50
130
200
P
l
P
P
P
Wavelength 共Å兲
5313.87
5339.33
5363.20
5368.07
5372.39
5392.80
5419.15
5438.96
5445.45
5450.45
5460.39
5472.61
5494.86
5525.53
5531.07
5566.62
5616.67
5659.38
5667.56
5670.91
5695.75
5699.61
5716.10
5726.91
5751.03
5758.65
5776.39
5815.96
5823.89
5824.80
5875.02
5893.29
5894.99
5905.13
5934.17
5945.53
5971.13
5976.46
6008.92
6036.20
6051.15
6093.50
6097.59
6101.43
6115.08
6146.45
6178.30
6179.66
6182.42
6194.07
6198.26
6270.82
6277.54
6284.41
6286.01
6300.86
6318.06
6343.96
6356.35
Spectrum
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
II
II
I
I
I
II
I
II
I
II
II
II
II
II
II
II
II
II
II
II
I
I
I
II
I
II
II
II
I
II
I
II
II
Ref.
H39
H39
H39
H39
H39
HM33
H39
H39
H39
H39
H39
H39
H39
H39
H39
HM33
H39
H39
H39
H39
HM33
H39
H39
H39
H39
H39
H39
H39
HM33
HM33
HM33
H39
HM33
H39
HM33
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
H39
HM33
HM33
HM33
H39
HM33
H39
H39
H39
HM33
H39
HM33
H39
H39
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2112
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Xenon 共Xe兲—Continued
Intensity
70
30
30
15
12
10
20
100
70
10
300
10
130
30
15
100
20
50
30
300
20
10
30
25
10
250
10
700
50
50
15
70
150
30
70
70
10
15
100
20
25
50
10
70
20
10
10
30
50
10
20
15
10
50
10
70
1000
50
700
h
h
s
h
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
6375.28
6397.99
6469.70
6472.84
6487.76
6498.72
6504.18
6512.83
6528.65
6533.16
6595.01
6595.56
6597.25
6598.84
6668.92
6694.32
6728.01
6788.71
6790.37
6805.74
6827.32
6872.11
6882.16
6910.22
6925.53
6942.11
6976.18
6990.88
7082.15
7119.60
7147.50
7149.03
7164.83
7284.34
7301.80
7339.30
7386.00
7393.79
7548.45
7584.68
7618.57
7642.02
7643.91
7670.66
7787.04
7802.65
7881.32
7887.40
7967.34
8029.67
8057.26
8061.34
8101.98
8151.80
8171.02
8206.34
8231.635
8266.52
8280.117
Spectrum
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
II
II
I
I
I
I
I
II
II
I
II
I
II
II
I
II
I
II
II
II
I
I
I
II
I
II
I
II
II
I
II
II
II
II
II
II
I
I
II
I
II
I
I
II
II
I
I
I
I
I
I
I
I
II
I
I
I
I
I
Ref.
H39
H39
HM33
HM33
HM33
HM33
HM33
H39
H39
HM33
H39
HM33
H39
H39
HM33
H39
HM33
H39
H39
H39
HM33
HM33
HM33
H39
HM33
H39
HM33
H39
H39
HM33
H39
H39
H39
H39
H39
H39
HM33
HM33
H39
HM33
H39
HM33
HM33
H39
H39
HM33
HM33
HM33
HM33
HM33
HM33
HM33
HM33
H39
HM33
HM33
HP70b
HM33
HP70b
ATOMIC SPECTROSCOPIC DATA
2113
Strong Lines of Xenon 共Xe兲—Continued
Intensity
200
30
200
15
20
15
25
10
20
15
30
10
500
30
20
20
100
10
20
40
50
10
10
20
15
15
15
10
200
300
10
9
40
10
30
250
25
200
120
80
40
14
300
10
250
15
25
10
100
12
150
150
40
15
300
25
120
11
200
h
h
h
P
h
l
P
P
P
Wavelength 共Å兲
8346.823
8347.24
8409.191
8515.19
8576.01
8604.23
8648.54
8692.20
8696.86
8716.19
8739.39
8758.20
8819.411
8862.32
8908.73
8930.83
8952.252
8981.05
8987.57
9045.45
9162.65
9167.52
9374.76
9513.38
9591.35
9685.32
9698.68
9718.16
9799.700
9923.190
10838.37
11742.01
12235.24
12257.76
12590.20
12623.399
13544.15
13657.06
14142.44
14240.96
14364.99
14660.81
14732.816
15099.72
15418.39
15557.13
15979.54
16039.90
16053.28
16554.49
16728.15
17325.77
18788.13
20187.19
20262.24
21470.09
23193.33
23279.54
24824.71
Spectrum
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
I
II
I
II
I
II
I
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
HP70b
H39
HP70b
H39
HM33
H39
HM33
HM33
HM33
H39
HM33
HM33
HP70b
HM33
HM33
HM33
HP70b
HM33
HM33
HM33
HM33
HM33
HM33
HM33
H39
HM33
H39
HM33
HP70b
HP70b
HM33
H73
H73
H73
H73
HP70b
H73
H73
H73
H73
H73
H73
HP70b
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2114
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Xenon 共Xe兲—Continued
Intensity
Wavelength 共Å兲
20
200
250
25
80
30
15
10
10
60
150
10
50
600 P
12
60
10
200
400
15
40
15
500 P
11
25
15
40
80
14
20
25
12
25145.84
26269.08
26510.86
28381.54
28582.25
29384.41
29448.06
29649.58
29813.62
30253.14
30475.46
30504.12
30794.18
31069.23
31336.01
31607.91
32293.08
32739.26
33666.69
34014.67
34335.27
34744.00
35070.26
35246.92
36209.21
36231.74
36508.36
36788.83
38685.98
38737.82
38939.60
39955.14
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Spectrum
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
Xe
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
H73
HP70b
H73
H73
H73
H73
H73
H73
H73
H73
HP70b
H73
H73
H73
H73
H73
H73
H73
H73
H73
ATOMIC SPECTROSCOPIC DATA
2115
Persistent Lines of Neutral Xenon 共Xe I兲
Inten
Wavelength 共Å兲
25
1192.0376
25
2.73
8231.635
700
8280.117
500
8819.411
300
500
2.53
1469.6123
1000
600
0.149
1295.5878
60
300
5.93
1250.2091
100
250
A ki (108 s⫺1 )
9923.190
12623.399
14732.816
31069.23
35070.26
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
S
关 3/2兴 o
0
1
0.000
83889.971
BVHU01
M00
0
1
0.000
79986.619
BVHU01
M00
0
1
0.000
77185.040
BVHU01
M00
S
关 3/2兴 o
0
1
0.000
68045.156
BVHU01
M00
关 3/2兴 o
关 3/2兴
2
2
67067.547
79212.464
HP70b
关 3/2兴 o
关 1/2兴
1
0
68045.156
80118.962
HP70b
关 3/2兴 o
关 5/2兴
2
3
67067.547
78403.060
HP70b
关 3/2兴 o
关 5/2兴
1
2
68045.156
78119.798
HP70b
关 1/2兴
关 3/2兴 o
1
2
77269.144
85188.774
HP70b
关 5/2兴
关 3/2兴 o
3
2
78403.060
85188.774
HP70b
关 3/2兴
关 5/2兴 o
2
3
79212.464
82430.205
HP70b
关 5/2兴 o
关 7/2兴 o
2
3
78119.798
80970.439
HP70b
Configuration
6
1
5p
o
)5d
5 p 5 ( 2 P3/2
2
5p 6
o
)5d
5 p 5 ( 2 P3/2
2
5p 6
o
)6s
5 p 5 ( 2 P1/2
2
5p 6
o
)6s
5 p 5 ( 2 P3/2
2
1
S
关 1/2兴 o
1
S
关 1/2兴 o
1
o
)6s
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)6p
2
o
)6s
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)6p
2
o
)6s
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)6p
2
o
)6s
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)6p
2
o
)6p
5 p 5 ( 2 P3/2
o
5p 5 ( 2 P3/2
)7s
2
o
)6p
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)7s
2
o
)6p
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)5d
2
o
)6p
5 p 5 ( 2 P3/2
5 2 o
5p ( P3/2)5d
2
2
2
2
2
2
2
2
2
Energy Levels of Neutral Xenon 共Xe I兲
Configuration
5p
6
Level (cm⫺1 )
Ref
Term
J
S
0
0.000
BVHU01
1
o
)6s
5p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
67067.547
68045.156
BVHU01
BVHU01
o
)6s
5 p 5 ( 2 P1/2
2
关 1/2兴 o
0
1
76196.767
77185.040
BVHU01
BVHU01
o
)6p
5 p 5 ( 2 P3/2
2
关 1/2兴
1
0
77269.144
80118.962
HP70b
HP70b
o
)6p
5 p 5 ( 2 P3/2
2
关 5/2兴 o
2
3
78119.798
78403.060
HP70b
HP70b
o
)6p
5 p 5 ( 2 P3/2
2
关 3/2兴
1
2
78956.031
79212.464
HP70b
HP70b
o
)5d
5 p 5 ( 2 P3/2
2
关 1/2兴 o
0
1
79771.268
79986.619
HP70b
HP70b
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2116
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Xenon 共Xe I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
o
)5d
5 p 5 ( 2 P3/2
2
关 7/2兴
o
4
3
80196.629
80970.439
HP70b
HP70b
o
)5d
5 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
80322.747
83889.971
HP70b
HP70b
o
)5d
5 p 5 ( 2 P3/2
2
关 5/2兴 o
2
3
81925.515
82430.205
HP70b
HP70b
o
)7s
5 p 5 ( 2 P3/2
2
关 3/2兴 o
2
1
85188.774
85440.014
HP70b
HP70b
o
)6p
5 p 5 ( 2 P1/2
2
关 3/2兴
1
2
88379.126
89162.355
HP70b
HP70b
o
)6p
5 p 5 ( 2 P1/2
2
关 1/2兴 o
1
0
89278.706
89860.015
HP70b
HP70b
o
)5d
5 p 5 ( 2 P1/2
2
关 5/2兴 o
2
3
91152.671
91746.575
HP70b
HP70b
Limit
97833.787
BVHU01,KW85
o
)
Xe II ( 2 P3/2
Persistent Lines of Singly-ionized Xenon 共Xe II兲
Inten
Wavelength 共Å兲
250
972.77
400
300
400
700
400
250
200
700
700
1000
700
A ki (108 s⫺1 )
0.21
5976.46
B36
2 o
P
D
3/2
3/2
0.00
96033.48
B36
2 o
P
D
3/2
5/2
0.00
95396.74
B36
2 o
P
P
3/2
3/2
0.00
95064.38
B36
2 o
P
P
3/2
5/2
0.00
93068.44
B36
2 o
P
S
3/2
1/2
0.00
90873.83
B36
2 o
P
P
1/2
3/2
10537.01
95064.38
B36
5p 5
5s5 p 6
2 o
P
S
1/2
1/2
10537.01
90873.83
B36
M00
5p 4 ( 3 P)6s
5 p 4 ( 3 P)6p
4
P
Do
5/2
7/2
93068.44
113705.40
HP87
FW96
5p 4 ( 3 P)6s
5 p 4 ( 3 P)6p
4
P
P
5/2
5/2
93068.44
111958.89
H39
FW96
5p 4 ( 3 P)6s
5 p 4 ( 3 P)6p
4
P
Do
3/2
5/2
95064.38
113512.36
H39
FW96
5p 4 ( 3 P)6s
5 p 4 ( 3 P)6p
4
P
P
3/2
3/2
95064.38
111792.17
H39
FW96
5p 5
5s5 p 6
5p 5
5 p 4 ( 3 P)6s
1183.05
5419.15
0.00
102799.07
5p 5
5 p 4 ( 3 P)6s
1074.48
5292.22
3/2
3/2
2 o
5p 5
5 p 4 ( 3 P)6s
1051.92
4844.33
P
P
o
)
5p 5 ( 2 P3/2
4 3
5 p ( P)6s
5p 5
5 p 4 ( 3 P)5d
1048.27
1244.76
Level (cm⫺1 )
Term
5p 5
5 p 4 ( 3 P)5d
1041.31
1100.43
J
Configuration
0.072
1.1
0.89
0.62
0.28
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2
4
4
4
4
2
4
2
4
4 o
4
4 o
Wl Ref
A Ref
M00
ATOMIC SPECTROSCOPIC DATA
2117
Persistent Lines of Singly-ionized Xenon 共Xe II兲—Continued
Inten
Wavelength 共Å兲
700
500
A ki (108 s⫺1 )
6051.15
0.17
6097.59
0.26
Configuration
4 3
J
Level (cm⫺1 )
D
P
7/2
5/2
D
P
5/2
3/2
Term
5p ( P)5d
5 p 4 ( 3 P)6p
4
5p 4 ( 3 P)5d
5 p 4 ( 3 P)6p
4
4 o
4 o
Wl Ref
A Ref
95437.67
111958.89
H39
FW96
95396.74
111792.17
H39
FW96
Energy Levels of Singly-ionized Xenon 共Xe II兲
J
Level (cm⫺1 )
Ref
2 o
3/2
1/2
0.00
10537.01
HP87
HP87
5s5 p 6
2
S
1/2
90873.83
HP87
5 p 4 ( 3 P)6s
4
P
5/2
3/2
1/2
93068.44
95064.38
101157.48
HP87
HP87
HP87
5 p 4 ( 3 P)5d
4
D
7/2
5/2
3/2
95437.67
95396.74
96033.48
HP87
HP87
HP87
5 p 4 ( 3 P)6s
2
P
3/2
1/2
102799.07
106906.12
HP87
HP87
5 p 4 ( 3 P)6p
4 o
P
5/2
3/2
1/2
111958.89
111792.17
113672.89
HP87
HP87
HP87
5 p 4 ( 3 P)6p
4
Do
7/2
5/2
113705.40
113512.36
HP87
HP87
5 p 4 ( 3 P)6p
2
Do
1/2
121179.80
HP87
5 p 4 ( 3 P)6p
4
Do
3/2
121628.82
HP87
169175
HP87
Configuration
5p
5
Xe III ( 3 P2 )
Term
P
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2118
J. E. SANSONETTI AND W. C. MARTIN
Ytterbium „Yb…
Atomic number⫽70
Atomic weight⫽173.04
Isotope
168
Yb
Yb
171
Yb
172
Yb
173
Yb
174
Yb
176
Yb
170
Mass
Abundance
Spin
167.933894
169.934759
170.936323
171.936378
172.938208
173.938859
175.942564
0.13%
3.05%
14.3%
21.9%
16.12%
31.8%
12.7%
0
0
1/2
0
5/2
0
0
Mag moment
⫹0.4919
⫺0.6776
Yb I Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 146s 2 1S0
Ionization energy: 50 443.2 cm⫺1 共6.254 16 eV兲
Yb II Ground state: (1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 105s 2 5 p 6 )4 f 146s 2S1/2
Ionization energy: 98 207 cm⫺1 共12.176 eV兲
Strong Lines of Ytterbium 共Yb兲
Intensity
140
150
20
50
40
8
9
25
8
15
6
6
60
11
20
20
9
6
13
70
9
6
6
8
6
11
13
6
20
6
25
8
6
11
11
P
P
P
P
P
P
P
P
h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2116.67
2126.74
2161.60
2185.71
2224.46
2320.81
2390.74
2464.50
2512.061
2538.67
2617.01
2644.306
2653.75
2665.038
2671.958
2672.656
2718.349
2732.742
2748.664
2750.477
2776.280
2784.656
2798.211
2821.152
2824.974
2830.989
2847.175
2848.445
2851.126
2859.392
2859.805
2861.212
2861.34
2867.06
2888.04
Spectrum
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
II
II
II
II
II
II
II
I
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Ref
M67
M67
M67
M67
M67
M67
M67
MT78
M67
M67
M67
M67
M67
M67
MT78
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
ATOMIC SPECTROSCOPIC DATA
2119
Strong Lines of Ytterbium 共Yb兲—Continued
Intensity
Wavelength 共Å兲
200 P
9
8
15
8
7
110 P
11
9
15
6
9
9
50
6
6
9
11
13
7
7
20
13
7
1000 P
7
8
4
13
15 d
4
6
6
13
8
8
20
13
6
5
30
11 d
7
20
130 P
30
30
6 h,w
13
6
11
9
20
7
11
6
13
4
5
2891.384
2914.210
2915.275
2919.346
2945.907
2964.755
2970.564
2983.990
2994.805
3005.766
3009.392
3017.560
3026.669
3031.110
3065.040
3089.102
3107.902
3117.806
3140.936
3169.056
3180.919
3192.885
3201.160
3261.508
3289.370
3305.252
3305.733
3319.412
3337.171
3342.93
3343.071
3352.491
3362.438
3375.483
3387.505
3418.390
3426.044
3431.107
3438.848
3452.398
3454.080
3458.286
3458.391
3460.269
3464.37
3476.303
3478.835
3495.90
3520.293
3549.822
3560.327
3560.704
3585.466
3606.478
3619.803
3634.525
3637.757
3648.150
3655.729
Spectrum
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
I
II
II
II
II
II
II
I
I
I
I
II
I
II
II
I
I
I
II
II
II
II
II
II
II
II
II
II
I
II
I
I
Ref
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
MT78
M67
MT78
M67
M67
M67
M67
M67
M67
MT78
MT78
MT78
MT78
M67
MT78
M67
M67
MT78
MT78
MT78
M67
M67
M67
M67
M67
M67
M67
M67
M67
M67
MT78
M67
MT78
MT78
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2120
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Ytterbium 共Yb兲—Continued
Intensity
13
8
1000
4
10
30
4
9
20
20
8
1000
50
4
25
7
25
7
20
8
7
4
7
25
5
5
40
11
4
8
11
9
9
40
8
4
12
5
6
8
9
8
5
130
12
20
10
40
40
4
P
P
P
h
d
h
h
P
h
P
h
h
P
P
P
h
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3669.69
3675.085
3694.190
3700.580
3734.694
3770.095
3774.323
3839.907
3872.852
3900.85
3911.272
3987.99
3990.885
4052.283
4089.68
4119.464
4149.066
4174.56
4180.809
4218.565
4231.972
4277.738
4305.966
4439.19
4482.422
4563.95
4576.209
4582.355
4589.211
4590.834
4726.08
4781.867
4786.61
4935.500
4966.902
5069.144
5074.34
5211.604
5244.11
5277.04
5335.15
5352.95
5539.053
5556.466
5719.99
6489.06
6667.82
6799.60
7699.49
8922.56
Spectrum
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
II
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
II
II
I
I
I
I
I
I
I
I
I
I
II
I
II
I
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
II
Ref
M67
M67
M67
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
M67
MT78
MT78
M67
M67
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
MT78
M67
MT78
M67
MT78
MT78
MT78
MT78
MT78
MT78
MT78
M67
M67
MT78
MT78
MT78
MT78
MT78
MT78
MT78
M67
ATOMIC SPECTROSCOPIC DATA
2121
Persistent Lines of Neutral Ytterbium 共Yb I兲
Inten
Wavelength 共Å兲
25
2464.50
20
2671.958
A ki (108 s⫺1 )
14 1
1.00
0.143
J
Level (cm⫺1 )
Wl Ref
A Ref
S
P
0
1
0.000
40563.97
MT78
M00
S
0
1
0.000
37414.59
MT78
M00
Configuration
Term
2
4 f ( S)6s
4 f 14( 1 S)6s7 p
1
4 f 14( 1 S)6s 2
4 f 13( 2 Fo)5d6s 2
1
1 o
o
130
3464.37
0.683
4 f 14( 1 S)6s 2
o
)5d 5/26s 2
4 f 13( 2 F7/2
1
S
(7/2,5/2) o
0
1
0.000
28857.014
MT78
M00
1000
3987.99
1.92
4 f 14( 1 S)6s 2
4 f 14( 1 S)6s6 p
1
S
P
0
1
0.000
25068.222
MT78
M00
4 f 14( 1 S)6s6 p
4 f 14( 1 S)6p 2
3 o
P
P
2
2
19710.388
44760.37
MT78
4 f 14( 1 S)6s6 p
4 f 14( 1 S)6s6d
3 o
P
D
1
2
17992.007
39838.04
MT78
4 f 14( 1 S)6s6 p
4 f 14( 1 S)6s6d
3 o
P
D
2
3
19710.388
39966.09
MT78
4 f 14( 1 S)6s 2
4 f 14( 1 S)6s6 p
1
S
P
0
1
0.000
17992.007
MT78
4 f 14( 1 S)6s6 p
4 f 14( 1 S)6s7s
3 o
P
S
1
1
17992.007
32694.692
MT78
4 f 14( 1 S)6s6 p
4 f 14( 1 S)6s7s
3 o
2
1
19710.388
32694.692
MT78
50
3990.885
40
4576.209
40
4935.500
130
5556.466
40
0.0115
6799.60
40
7699.49
1 o
3
3
3
3 o
3
3
P
S
M00
Energy Levels of Neutral Ytterbium 共Yb I兲
Configuration
14 1
4 f ( S)6s
2
Term
1
J
Level (cm⫺1 )
Ref
S
0
0.000
MT78
4 f 14( 1 S)6s6p
3 o
0
1
2
17288.439
17992.007
19710.388
MT78
MT78
MT78
o
)5d 3/26s 2
4 f 13( 2 F7/2
(7/2 ,3/2) o
2
5
3
4
23188.518
25859.682
27445.638
28184.512
MT78
MT78
MT78
MT78
4 f 14( 1 S)5d6s
3
D
1
2
3
24489.102
24751.948
25270.902
MT78
MT78
MT78
4 f 14( 1 S)6s6p
1 o
1
25068.222
MT78
o
)5d 5/26s 2
4 f 13( 2 F7/2
(7/2 ,5/2) o
6
2
1
4
3
5
27314.919
28195.960
28857.014
29774.958
30207.380
30524.714
MT78
MT78
MT78
MT78
MT78
MT78
4 f 14( 1 S)5d6s
1
2
27677.665
MT78
P
P
D
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2122
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Ytterbium 共Yb I兲—Continued
Term
J
Level (cm⫺1 )
Ref
o
)6s 2 6p 1/2
4 f 13( 2 F7/2
共7/2,1/2兲
3
4
32065.282
32273.597
MT78
MT78
4 f 14( 1 S)6s7s
3
S
1
32694.692
MT78
4 f 14( 1 S)6s7s
1
S
0
34350.65
MT78
o
)6s 2 6p 3/2
4 f 13( 2 F7/2
共7/2,3/2兲
5
2
3
4
35178.78
35196.98
35807.52
36060.98
MT78
MT78
MT78
MT78
4 f 13( 2 Fo)5d6s 2
o
1
37414.59
MT78
4 f 14( 1 S)6s7p
3 o
0
1
2
38090.71
38174.17
38551.93
MT78
MT78
MT78
4 f 13( 2 Fo)5d6s 2
3
Do
1
38422.36
MT78
4 f ( S)6s6d
3
D
1
2
3
39808.72
39838.04
39966.09
MT78
MT78
MT78
o
o
)5d( 2 D)6s6p( 3 Po)( 4 F3/2
)
4 f 13( 2 F7/2
共7/2,3/2兲
2
5
4
3
39880.26
42935.78
44984.75
45462.54
MT78
MT78
MT78
MT78
4 f 14( 1 S)6s6d
1
D
2
40061.51
MT78
4 f 14( 1 S)6s7p
1 o
P
1
40563.97
MT78
4 f ( S)6s8s
3
S
1
41615.04
MT78
o
o
)5d( 2 D)6s6p( 3 Po)( 4 F5/2
)
4 f 13( 2 F7/2
共7/2,5/2兲
3
41827.30
MT78
4 f 14( 1 S)6s8s
1
0
41939.90
MT78
o
o
)5d( 2 D)6s6p( 3 Po)( 4 F5/2
)
4 f 13( 2 F7/2
共7/2,5/2兲
1
42436.70
MT78
3
0
1
2
42436.91
43805.42
44760.37
MT78
MT78
MT78
Limit
50443.2
A80
Configuration
P
14 1
14 1
14 1
4 f ( S)6p
2
S
P
Yb II ( 2 S1/2)
Persistent Lines of Singly-ionized Ytterbium 共Yb II兲
Inten
140
150
50
40
Wavelength 共Å兲
2116.67
2126.74
2185.71
2224.46
A ki (108 s⫺1 )
0.341
0.495
0.316
0.479
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
14 1
Term
J
Level (cm⫺1 )
S
关 1/2兴 o
1/2
1/2
Wl Ref
A Ref
0.00
47228.96
M67
M00
4 f ( S)6s
o
)5d6s( 1 D)
4 f 13( 2 F5/2
2
4 f 14( 1 S)6s
o
)5d6s( 1 D)
4 f 13( 2 F5/2
2
S
关 3/2兴 o
1/2
3/2
0.00
47005.46
M67
M00
1
4 f 14( 1 S)6s
o
)5d 2 ( 3 F)
4 f 13( 2 F7/2
2
S
1/2
3/2
0.00
45737.29
M67
M00
4 f 14( 1 S)6s
o
)5d6s( 3 D)
4 f 13( 2 F5/2
2
S
1/2
3/2
0.00
44940.61
M67
M00
1
o
o
ATOMIC SPECTROSCOPIC DATA
2123
Persistent Lines of Singly-ionized Ytterbium 共Yb II兲—Continued
Inten
Wavelength 共Å兲
A ki (108 s⫺1 )
Configuration
Level (cm⫺1 )
Wl Ref
A Ref
60
2653.75
3.90
4 f ( F )6s
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
F
7/2
7/2
21418.75
59090.13
M67
BDMQ98
70
2750.477
3.20
4 f 13( 2 Fo)6s 2
o
)6s6p( 1 Po1 )
4 f 13( 2 F7/2
2 o
F
共7/2,1兲
7/2
9/2
21418.75
57765.32
M67
BDMQ98
200
2891.384
0.342
4 f 14( 1 S)6s
o
)5d6s( 1 D)
4 f 13( 2 F7/2
2
S
关 3/2兴 o
1/2
3/2
0.00
34575.37
M67
M00
4 f 14( 1 S)6s
o
)5d6s( 3 D)
4 f 13( 2 F7/2
2
S
关 3/2兴 o
1/2
1/2
0.00
33653.86
M67
M00
4 f 14( 1 S)6s
4 f 14( 1 S)6p
2
S
P
1/2
3/2
0.00
30392.23
M67
M00
4 f 14( 1 S)6s
4 f 14( 1 S)6p
2
S
P
1/2
1/2
0.00
27061.82
M67
M00
2970.564
1000
3289.370
1000
3694.190
0.261
1.62
1.23
2
J
2 o
110
13 2 o
Term
1
3
2 o
2 o
Energy Levels of Singly-ionized Ytterbium 共Yb II兲
Configuration
14 1
Term
J
Level (cm⫺1 )
Ref
4 f ( S)6s
2
S
1/2
0.00
M67
4 f 13( 2 Fo)6s 2
2 o
F
7/2
5/2
21418.75
31568.08
M67
M67
4 f 14( 1 S)5d
2
D
3/2
5/2
22960.80
24332.69
M67
M67
o
)5d6s( 3 D)
4 f 13( 2 F7/2
3
关 3/2兴 o
5/2
3/2
1/2
26759.02
28757.98
33653.86
M67
M67
M67
4 f 14( 1 S)6p
2 o
P
1/2
3/2
27061.82
30392.23
M67
M67
o
)5d6s( 1 D)
4 f 13( 2 F7/2
1
关 3/2兴 o
3/2
34575.37
M67
o
4 f 13( 2 F5/2
)5d6s( 3 D)
o
3/2
44940.61
M67
o
4 f 13( 2 F7/2
)5d 2 ( 3 F)
o
3/2
45737.29
M67
o
4 f 13( 2 F5/2
)5d6s( 1 D)
1
关 3/2兴
o
3/2
47005.46
M67
o
4 f 13( 2 F5/2
)5d6s( 1 D)
1
关 1/2兴 o
1/2
47228.96
M67
o
4 f 13( 2 F7/2
)6s6p( 1 Po1 )
共7/2,1兲
9/2
57765.32
M67
7/2
59090.13
M67
98207
SK79
o
4 f 13( 2 F7/2
)6s6p( 1 Po1 )
1
Yb III ( S0 )
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2124
J. E. SANSONETTI AND W. C. MARTIN
Yttrium „Y…
Atomic number⫽39
Atomic weight⫽88.905 85
Isotope
89
Y
Mass
Abundance
Spin
Mag moment
88.905849
100%
1/2
⫺0.1373
Y I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d5s 2 2D3/2
Ionization energy: 50 145.6 cm⫺1 共6.2173 eV兲
Y II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 5s 2 1S0
Ionization energy: 98 590 cm⫺1 共12.224 eV兲
Strong Lines of Yttrium 共Y兲
Intensity
25
40
40
40
50
80
20
300
200
150
150
300
500
400
15
130
300
50
15
20
25
250
30
300
800
500
600
400
150
600
250
15
1000
90
800
110
600
100
300
300
300
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2243.045
2422.186
2948.406
2964.964
2974.588
2984.254
3045.363
3173.045
3195.613
3200.269
3203.320
3216.680
3242.272
3327.876
3485.722
3496.079
3549.002
3552.690
3558.741
3571.431
3576.052
3584.514
3587.743
3592.915
3600.731
3601.915
3611.043
3620.940
3628.700
3633.121
3664.610
3692.523
3710.287
3747.551
3774.330
3776.556
3788.693
3818.341
3832.889
3950.349
3982.592
Spectrum
Y II
Y II
YI
YI
YI
YI
YI
Y II
Y II
Y II
Y II
Y II
Y II
Y II
YI
Y II
Y II
YI
YI
YI
YI
Y II
YI
YI
Y II
Y II
Y II
YI
Y II
Y II
Y II
YI
Y II
Y II
Y II
Y II
Y II
Y II
Y II
Y II
Y II
Ref
NJK91
NJK91
P77
P77
P77
P77
P77
NJK91
NJK91
NJK91
NJK91
NJK91
NJK91
NJK91
P77
NJK91
NJK91
P77
P77
P77
P77
NJK91
P77
P77
NJK91
NJK91
NJK91
P77
NJK91
NJK91
NJK91
P77
NJK91
NJK91
NJK91
NJK91
NJK91
NJK91
NJK91
NJK91
NJK91
ATOMIC SPECTROSCOPIC DATA
2125
Strong Lines of Yttrium 共Y兲—Continued
Intensity
90
250
900
200
1000
6
900
800
250
200
600
15
30
200
100
40
200
40
900
200
15
20
15
30
50
90
40
13
200
20
200
20
15
15
40
15
20
80
60
40
300
30
700
600
700
20
300
500
20
20
70
30
70
20
60
60
15
100
120
P
P
P
P
P
h
h
P
h
P
P
P
P
Wavelength 共Å兲
4039.826
4047.628
4077.359
4083.705
4102.364
4106.384
4128.299
4142.841
4167.513
4174.133
4177.528
4217.799
4220.629
4235.929
4251.201
4302.290
4309.620
4348.783
4374.933
4398.008
4475.720
4476.952
4477.442
4487.460
4505.948
4527.239
4527.783
4596.528
4643.698
4658.319
4674.848
4696.800
4728.514
4752.790
4760.978
4786.875
4799.301
4839.866
4845.668
4852.682
4854.861
4859.841
4883.682
4900.118
5087.418
5135.199
5200.409
5205.722
5240.800
5438.226
5466.466
5503.464
5527.561
5577.416
5581.874
5630.138
5706.714
6024.271
6191.720
Spectrum
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
Y II
YI
YI
YI
YI
YI
Y II
YI
Y II
Y II
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
Y II
YI
Y II
Y II
Y II
YI
Y II
Y II
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
Ref
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
NJK91
P77
P77
P77
P77
P77
NJK91
P77
NJK91
NJK91
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
NJK91
P77
NJK91
NJK91
NJK91
P77
NJK91
NJK91
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2126
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Yttrium 共Y兲—Continued
Wavelength 共Å兲
Intensity
30
100
15
20
50
30
30
200
400
250
600
500
1000
1000
1000
900
800
700
500
400
Spectrum
6222.579
6435.022
6687.571
6793.704
9476.928
10329.701
10605.150
15619.966
17123.808
17366.720
17422.838
17663.292
17903.209
18049.810
18115.296
18181.765
21260.444
22543.828
23990.450
24920.894
P
P
P
P
P
P
Ref
YI
YI
YI
YI
Y II
Y II
Y II
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
YI
P77
P77
P77
P77
NJK91
NJK91
NJK91
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
P77
Persistent Lines of Neutral Yttrium 共Y I兲
Inten
900
1000
900
800
600
1000
1000
800
700
500
Wavelength 共Å兲
4077.359
4102.364
4128.299
4142.841
A ki (108 s⫺1 )
1.1
1.3
1.6
1.6
17422.838
17903.209
18049.810
21260.444
22543.828
23990.450
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Configuration
2
4d5s
4d( 3 D)5s5p
4d5s 2
4d( 3 D)5s5p
4d5s 2
4d( 1 D)5s5p
4d5s 2
4d( 1 D)5s5p
Term
0.000
24518.751
P77
FW96
5/2
7/2
530.351
24899.632
P77
FW96
5/2
5/2
530.351
24746.573
P77
FW96
D
Do
3/2
3/2
0.000
24131.250
P77
FW96
F
Do
5/2
5/2
11078.614
16816.641
P77
F
Do
9/2
7/2
11532.096
17116.156
P77
F
Do
7/2
5/2
11277.928
16816.641
P77
F
F
9/2
9/2
11532.096
16234.382
P77
F
F
7/2
7/2
11277.928
15712.522
P77
F
F
5/2
5/2
11078.614
15245.803
P77
D
F
2
D
F
2 o
2
D
Do
2
4d 2 ( 3 F)5s
4d( 3 D)5s5p
4
4d 2 ( 3 F)5s
4d( 3 D)5s5p
4
4d 2 ( 3 F)5s
4d( 3 D)5s5p
4
4d 2 ( 3 F)5s
4d( 3 D)5s5p
4
4d 2 ( 3 F)5s
4d( 3 D)5s5p
4
4d 2 ( 3 F)5s
4d( 3 D)5s5p
4
4
4
4
3/2
5/2
A Ref
2 o
2
Level (cm⫺1 )
Wl Ref
2
2
J
4 o
4 o
4 o
ATOMIC SPECTROSCOPIC DATA
2127
Energy Levels of Neutral Yttrium 共Y I兲
Configuration
J
Level (cm⫺1 )
Ref
2
D
3/2
5/2
0.000
530.351
P77
P77
5s 2 5p
2 o
P
1/2
3/2
10529.169
11359.757
P77
P77
4d 2 ( 3 F)5s
4
F
3/2
5/2
7/2
9/2
10937.390
11078.614
11277.928
11532.096
P77
P77
P77
P77
4d( 3 D)5s5p
4 o
F
3/2
5/2
7/2
9/2
14948.994
15245.803
15712.522
16234.382
P77
P77
P77
P77
4d 2 ( 3 P)5s
4
P
1/2
3/2
5/2
15221.633
15328.865
15476.533
P77
P77
P77
4d 2 ( 3 F)5s
2
F
5/2
7/2
15326.741
15864.481
P77
P77
4d 2 ( 1 D)5s
2
D
3/2
5/2
15994.045
16158.865
P77
P77
4d( 3 D)5s5p
2
Do
5/2
3/2
16066.064
16146.138
P77
P77
4d( 3 D)5s5p
4
Do
1/2
3/2
5/2
7/2
16435.907
16597.304
16816.641
17116.156
P77
P77
P77
P77
4d 2 ( 1 G)5s
2
G
9/2
7/2
18499.315
18512.402
P77
P77
4d( 3 D)5s5p
4 o
P
1/2
3/2
5/2
18976.366
19027.593
19147.983
P77
P77
P77
4d( 1 D)5s5p
2
Do
3/2
5/2
24131.250
24746.573
P77
P77
4d( 3 D)5s5p
2 o
5/2
7/2
24518.751
24899.632
P77
P77
50145.6
GRTE73,JS00
4d5s
2
Term
Y II ( 1 S0 )
F
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2128
J. E. SANSONETTI AND W. C. MARTIN
Persistent Lines of Singly-ionized Yttrium 共Y II兲
Inten
Wavelength 共Å兲
500
300
800
600
600
1000
800
300
300
600
900
700
600
700
500
A ki (108 s⫺1 )
3242.272
2.0
3549.002
0.397
3600.731
1.4
3611.043
1.04
Configuration
Term
J
Level (cm⫺1 )
Wl Ref
A Ref
4d5s
4d5 p
3
D
P
3
2
1449.752
32283.420
NJK91
FW96
4d5s
4d5 p
3
D
Do
2
3
1045.076
29213.958
NJK91
FW96
4d5s
4d5 p
3
D
Do
3
3
1449.752
29213.958
NJK91
FW96
4d5s
4d5 p
3
D
Do
2
2
1045.076
28730.010
NJK91
FW96
S
P
0
1
0.000
27516.699
NJK91
D
F
3
4
1449.752
28394.177
NJK91
FW96
D
F
2
3
1045.076
27532.321
NJK91
FW96
D
F
3
3
1449.752
27532.321
NJK91
FW96
D
Do
2
2
1045.076
26147.252
NJK91
FW96
D
F
2
2
3296.180
27227.027
NJK91
FW96
D
Do
2
2
3296.180
26147.252
NJK91
FW96
F
Do
4
3
8743.322
29213.958
NJK91
FW96
F
Do
3
2
8328.039
28730.010
NJK91
FW96
F
F
4
4
8743.322
28394.177
NJK91
FW96
F
F
3
3
8328.039
27532.321
NJK91
FW96
3 o
3
3
3
5s 2
4d5 p
3633.121
3710.287
1.5
3774.330
1.1
3832.889
0.30
3982.592
0.27
4177.528
0.527
4374.933
0.997
4883.682
0.47
4900.118
0.451
5087.418
0.20
5205.722
0.16
1
1 o
4d5s
4d5 p
3
4d5s
4d5 p
3
4d5s
4d5 p
3
4d5s
4d5 p
3
4d5s
4d5 p
1
4d5s
4d5 p
1
3 o
3 o
3 o
1
3 o
1
4d 2
4d5 p
3
3
4d 2
4d5 p
3
3
4d 2
4d5 p
3
3 o
4d 2
4d5 p
3
3 o
Energy Levels of Singly-ionized Yttrium 共Y II兲
Level (cm⫺1 )
Ref
Configuration
Term
J
5s 2
1
S
0
0.000
NJK91
4d5s
3
D
1
2
3
840.198
1045.076
1449.752
NJK91
NJK91
NJK91
4d5s
1
D
2
3296.180
NJK91
4d 2
3
F
2
3
4
8003.126
8328.039
8743.322
NJK91
NJK91
NJK91
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2129
Energy Levels of Singly-ionized Yttrium 共Y II兲—Continued
Term
J
Level (cm⫺1 )
P
Configuration
Ref
2
3
0
1
2
13883.379
14018.267
14098.076
NJK91
NJK91
NJK91
4d 2
1
2
14832.862
NJK91
4d 2
1
G
4
15682.905
NJK91
5s5p
3 o
P
0
1
2
23445.063
23776.245
24647.121
NJK91
NJK91
NJK91
4d5 p
1
Do
2
26147.252
NJK91
4d5 p
3 o
2
3
4
27227.027
27532.321
28394.177
NJK91
NJK91
NJK91
4d5 p
1 o
1
27516.699
NJK91
4d5 p
3
o
D
1
2
3
28595.285
28730.010
29213.958
NJK91
NJK91
NJK91
4d5 p
3 o
0
1
2
32048.788
32124.054
32283.420
NJK91
NJK91
NJK91
98590
NJK91
4d
Y III ( 2 D3/2)
D
F
P
P
Limit
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2130
J. E. SANSONETTI AND W. C. MARTIN
Zinc „Zn…
Atomic number⫽30
Atomic weight⫽65.39
Isotope
64
Zn
Zn
67
Zn
68
Zn
70
Zn
66
Mass
Abundance
Spin
Mag moment
63.929145
65.926034
66.927129
67.924846
69.925325
48.6%
27.9%
4.1%
18.8%
0.6%
0
0
5/2
0
0
⫹0.87515
Zn I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 1S0
Ionization energy: 75 769.33 cm⫺1 共9.394 199 eV兲
Zn II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2S1/2
Ionization energy: 144 892.6 cm⫺1 共17.964 39 eV兲
Strong Lines of Zinc 共Zn兲
Intensity
1000
1000
400
1000
200
1000
300
500
10
20
8
20
6
60
100
50
200
70
400
80
15
100
250
400
80
120
100
40
30
50
60
40
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
Air
2025.4845
2062.0011
2064.2266
2099.9273
2102.1661
2138.5735
2501.9945
2557.9460
2608.5576
2770.8538
2770.9740
2800.8635
2801.0500
3075.8971
3196.31
3282.3256
3302.5829
3302.9395
3345.0134
3345.5694
3345.9353
4680.1359
4722.1569
4810.5321
4911.6269
4924.0132
5894.3607
6214.5778
6362.3458
7478.7691
7588.4648
7732.4886
Spectrum
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
Zn
II
II
II
II
II
I
II
II
I
I
I
I
I
I
II
I
I
I
I
I
I
I
I
I
II
II
II
II
I
II
II
II
Ref
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
CD68
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
GL00
ATOMIC SPECTROSCOPIC DATA
2131
Persistent Lines of Neutral Zinc 共Zn I兲
Inten
1000
20
25
60
50
200
70
400
80
15
100
250
400
30
Wavelength 共Å兲
2138.5735
A ki (108 s⫺1 )
7.14
2800.8635
2801.0500
3075.8971
3282.3256
3302.5829
3302.9395
3345.0134
3345.5694
3345.9353
0.000375
0.90
1.2
0.67
1.7
0.40
0.045
4680.1359
4722.1569
4810.5321
6362.3458
0.474
Term
J
Level (cm⫺1 )
1
S
P
0
1
4s4 p
4s5d
3 o
P
D
4s4 p
4s5d
3 o
Configuration
Wl Ref
A Ref
0.000
46745.404
GL00
M03
2
3
32890.327
68583.083
GL00
P
D
2
2
32890.327
68580.705
GL00
S
P
0
1
0.000
32501.399
GL00
M03
4s4 p
4s4d
3 o
P
D
0
1
32311.319
62768.747
GL00
FW96
4s4 p
4s4d
3 o
P
D
1
2
32501.399
62772.014
GL00
FW96
4s4 p
4s4d
3 o
P
D
1
1
32501.399
62768.747
GL00
FW96
4s4 p
4s4d
3 o
P
D
2
3
32890.327
62776.981
GL00
FW96
4s4 p
4s4d
3 o
P
D
2
2
32890.327
62772.014
GL00
FW96
4s4 p
4s4d
3 o
P
D
2
1
32890.327
62768.747
GL00
FW96
4s4 p
4s5s
3 o
P
S
0
1
32311.319
53672.240
GL00
4s4 p
4s5s
3 o
P
S
1
1
32501.399
53672.240
GL00
4s4 p
4s5s
3 o
P
S
2
1
32890.327
53672.240
GL00
4s4 p
4s4d
1 o
1
2
46745.404
62458.533
GL00
2
4s
4s4p
1 o
3
3
4s 2
4s4p
1
3 o
3
3
3
3
3
3
3
3
3
1
P
D
FW96
Energy Levels of Neutral Zinc 共Zn I兲
Level (cm⫺1 )
Ref
Configuration
Term
J
4s 2
1
S
0
0.000
GL00
4s4 p
3 o
P
0
1
2
32311.319
32501.399
32890.327
GL00
GL00
GL00
4s4p
1 o
P
1
46745.404
GL00
4s5s
3
S
1
53672.240
GL00
4s5s
1
S
0
55789.213
GL00
4s4d
1
D
2
62458.533
GL00
4s4d
3
D
1
2
3
62768.747
62772.014
62776.981
GL00
GL00
GL00
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2132
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Zinc 共Zn I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
4s5d
3
1
2
3
68579.141
68580.705
68583.083
GL00
GL00
GL00
Limit
75769.33
SM95
D
Zn II ( 2 S1/2)
Persistent Lines of Singly-ionized Zinc 共Zn II兲
Inten
Wavelength 共Å兲
1000
1000
400
1000
300
500
80
120
A ki (108 s⫺1 )
2025.4845
4.07
2062.0011
3.86
2064.2266
4.6
2099.9273
5.6
2501.9945
2557.9460
4911.6269
1.6
4924.0132
Configuration
10
J
Level (cm⫺1 )
S
P
1/2
3/2
Term
Wl Ref
A Ref
0.000
49355.003
GL00
M03
3d 4s
3d 104 p
2
3d 104s
3d 104 p
2
S
P
1/2
1/2
0.000
48481.077
GL00
M03
3d 104 p
3d 104d
2 o
P
D
1/2
3/2
48481.077
96909.893
GL00
FW96
3d 104 p
3d 104d
2 o
P
D
3/2
5/2
49355.003
96960.588
GL00
FW96
3d 104 p
3d 105s
2 o
P
S
1/2
1/2
48481.077
88437.149
GL00
3d 104 p
3d 105s
2 o
P
S
3/2
1/2
49355.003
88437.149
GL00
3d 104d
3d 104 f
2
D
F
3/2
5/2
96909.893
117264.063
GL00
3d 104d
3d 104 f
2
D
F
5/2
7/2
96960.588
117263.558
GL00
2 o
2 o
2
2
2
2
2 o
2 o
FW96
Energy Levels of Singly-ionized Zinc 共Zn II兲
Configuration
Term
3d 104s
2
J
Level (cm⫺1 )
Ref
S
1/2
0.000
GL00
3d 4p
2 o
P
1/2
3/2
48481.077
49355.003
GL00
GL00
3d 9 4s 2
2
D
5/2
3/2
62722.506
65411.745
GL00
GL00
3d 105s
2
S
1/2
88437.149
GL00
3d 104d
2
D
3/2
5/2
96909.893
96960.588
GL00
GL00
3d 105p
2 o
P
1/2
3/2
101366.038
101611.418
GL00
GL00
3d 104 f
2 o
7/2
5/2
117263.558
117264.063
GL00
GL00
144892.6
SM95
10
F
Zn III ( 1 S0 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
ATOMIC SPECTROSCOPIC DATA
2133
Zirconium „Zr…
Atomic number⫽40
Atomic weight⫽91.224
Isotope
90
Zr
Zr
92
Zr
94
Zr
96
Zr
91
Mass
Abundance
Spin
89.904703
90.905644
91.905039
93.906314
95.908275
51.45%
11.22%
17.15%
17.38%
2.80%
0
5/2
0
0
0
Mag moment
⫺1.303
Zr I Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 2 5s 2 3F2
Ionization energy: 53 506.0 cm⫺1 共6.633 90 eV兲
Zr II Ground state: 1s 2 2s 2 2p 6 3s 2 3p 6 3d 104s 2 4p 6 4d 2 5s 4F3/2
Ionization energy: 106 000 cm⫺1 共13.1 eV兲
Strong Lines of Zirconium 共Zr兲
Intensity
300
400
300
130
250
90
250
200
120
120
90
200
90
200
120
40
140
90
250
250
90
250
120
120
100
90
90
100
120
90
150
150
150
150
130
110
200
P
P
P
P
P
Wavelength 共Å兲
Air
2568.871
2571.457
2678.632
2700.129
2722.609
2732.721
2734.851
2742.553
2745.854
2752.202
2758.806
2814.902
2825.557
2837.226
2844.575
2848.186
2875.980
2960.867
2985.388
3011.743
3028.038
3029.515
3054.833
3106.576
3120.746
3129.173
3129.760
3132.060
3138.678
3164.313
3165.977
3182.860
3191.215
3212.016
3214.189
3231.692
3234.123
Spectrum
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
II
II
II
II
II
II
II
II
II
II
II
I
II
I
II
II
I
I
I
I
II
I
II
II
I
II
II
I
II
II
II
II
I
I
II
II
I
Ref.
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2134
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Zirconium 共Zr兲—Continued
Intensity
130
90
60
90
200
250
90
150
90
150
130
130
90
100
130
1000
100
100
130
200
800
150
60
70
140
150
60
200
250
130
700
140
300
600
80
130
60
110
500
60
200
300
400
300
400
300
250
250
80
1000
120
200
200
300
90
70
300
140
150
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
3241.044
3250.393
3260.111
3272.222
3273.047
3279.264
3282.732
3284.712
3305.152
3306.277
3340.553
3356.087
3357.261
3387.869
3388.295
3391.972
3393.119
3404.827
3410.243
3430.527
3438.231
3447.362
3455.902
3457.561
3463.013
3471.185
3478.780
3479.387
3481.155
3483.532
3496.206
3505.666
3509.321
3519.604
3525.808
3533.223
3535.159
3542.621
3547.683
3549.731
3550.460
3551.951
3556.594
3566.099
3572.468
3575.790
3576.853
3586.293
3587.974
3601.191
3611.891
3613.097
3614.772
3623.865
3634.148
3661.202
3663.648
3674.715
3698.165
Spectrum
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
II
I
I
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
II
I
I
II
II
II
II
II
I
I
II
I
I
II
I
I
I
II
II
I
II
I
II
I
II
I
II
II
II
I
I
I
I
II
II
Ref.
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
ATOMIC SPECTROSCOPIC DATA
2135
Strong Lines of Zirconium 共Zr兲—Continued
Intensity
130
100
150
140
140
200
150
150
600
250
100
150
150
800
200
300
60
400
800
600
110
150
300
150
140
300
200
60
140
140
60
110
200
300
70
70
140
110
70
150
140
70
110
60
200
150
90
400
600
90
60
70
600
60
200
60
70
110
200
P
P
P
P
P
P
P
P
Wavelength 共Å兲
3709.269
3745.947
3751.590
3764.389
3766.714
3780.534
3791.397
3822.413
3835.962
3836.761
3843.018
3847.008
3849.250
3863.872
3864.332
3877.595
3879.048
3885.422
3890.316
3891.380
3900.512
3921.788
3929.529
3958.220
3966.659
3968.256
3973.502
3975.294
3991.127
3998.965
4007.596
4023.977
4024.912
4027.201
4028.947
4029.675
4030.032
4035.887
4042.219
4043.570
4044.560
4045.612
4048.666
4050.476
4055.027
4055.704
4061.523
4064.151
4072.698
4074.925
4076.524
4078.305
4081.209
4108.394
4149.198
4152.640
4161.200
4166.366
4187.559
Spectrum
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
II
II
II
I
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
II
II
I
I
I
I
I
II
I
I
I
I
I
II
II
I
I
I
I
I
I
I
I
I
I
I
II
I
II
I
I
Ref.
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2136
J. E. SANSONETTI AND W. C. MARTIN
Strong Lines of Zirconium 共Zr兲—Continued
Intensity
110
150
110
110
600
60
600
200
200
300
90
150
150
90
150
300
90
150
150
60
60
140
200
700
150
500
400
250
60
70
200
80
60
70
100
130
200
130
150
80
150
250
110
80
P
P
P
P
P
P
P
P
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Wavelength 共Å兲
4194.760
4201.451
4208.980
4213.863
4227.750
4236.056
4239.309
4240.335
4241.197
4241.683
4268.015
4282.198
4294.787
4302.878
4341.127
4347.888
4360.800
4507.109
4535.742
4553.008
4555.124
4575.513
4633.982
4687.799
4688.450
4710.074
4739.475
4772.313
4784.921
4805.872
4815.630
4824.288
4851.362
5046.583
5064.904
5078.252
6127.457
6143.201
7097.727
7102.922
7169.092
8070.099
8132.984
8212.571
Spectrum
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
I
I
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref.
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
J98
ATOMIC SPECTROSCOPIC DATA
2137
Persistent Lines of Neutral Zirconium 共Zr I兲
Wavelength 共Å兲
Inten
A ki (108 s⫺1 )
Configuration
2
2
Term
J
Level (cm⫺1 )
3
Wl Ref
A Ref
600
3519.604
4d 5s
4d 2 5s(a 2 F)5p
a F
x 3Go
2
3
0.00
28404.26
J98
500
3547.683
4d 2 5s 2
4d 2 5s(a 2 F)5p
a 3F
x 3Go
3
4
570.41
28749.80
J98
300
3575.790
0.53
4d 2 5s 2
4d 2 5s(a 2 F)5p
a 3F
w 3Fo
3
4
570.41
28528.36
J98
BGHL81
1000
3601.191
1.33
4d 2 5s 2
4d 2 5s(a 2 F)5p
a 3F
x 3Go
4
5
1240.84
29001.65
J98
D95
300
3663.648
0.57
4d 2 5s 2
4d 2 5s(a 2 F)5p
a 3F
w 3Fo
4
4
1240.84
28528.36
J98
BGHL81
600
3835.962
4d 2 5s 2
4d 2 5s(a 2 D)5p
a 3F
x 3Fo
2
2
0.00
26061.70
J98
800
3863.872
4d 2 5s 2
4d 2 5s(a 2 D)5p
a 3F
x 3Fo
3
3
570.41
26443.88
J98
800
3890.316
4d 2 5s 2
4d 2 5s(a 2 D)5p
a 3F
x 3Fo
4
4
1240.84
26938.42
J98
600
3891.380
0.39
4d 2 5s 2
4d 2 5s(a 2 F)5p
a 3F
z 5Go
4
4
1240.84
26931.35
J98
BGHL81
600
4072.698
1.19
4d 3 (b 4 F)5s
4d 3 (b 4 F)5p
a 5F
x 5Do
4
3
5540.54
30087.33
J98
BGHL81
600
4081.209
4d 3 (b 4 F)5s
4d 3 (b 4 F)5p
a 5F
x 5Do
5
4
5888.93
30384.50
J98
600
4227.750
4d 3 (b 4 F)5s
4d 3 (b 4 F)5p
a 5F
y 5Fo
5
5
5888.93
29535.48
J98
600
4239.309
4d 3 (b 4 F)5s
4d 3 (b 4 F)5p
a 5F
y 5Fo
4
4
5540.54
29122.71
J98
700
4687.799
0.85
4d 3 (b 4 F)5s
4d 3 (b 4 F)5p
a 5F
y 5Go
5
6
5888.93
27214.89
J98
BGHL81
500
4710.074
0.64
4d 3 (b 4 F)5s
4d 3 (b 4 F)5p
a 5F
y 5Go
4
5
5540.54
26765.66
J98
BGHL81
Energy Levels of Neutral Zirconium 共Zr I兲
Configuration
2
Term
J
Level (cm⫺1 )
Ref
2
3
a F
2
3
4
0.00
570.41
1240.84
M52
M52
M52
4d 2 5s 2
a 3P
2
0
1
4186.11
4196.85
4376.28
M52
M52
M52
4d 3 (b 4 F)5s
a 5F
1
2
3
4
5
4870.53
5023.41
5249.07
5540.54
5888.93
M52
M52
M52
M52
M52
4d 5s
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2138
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Neutral Zirconium 共Zr I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
Ref
4d 2 5s 2
a 1D
2
5101.68
M52
2
1
a G
4
8057.30
M52
4d 3 (b 4 P)5s
a 5P
1
2
3
10885.36
11016.65
11258.38
M52
M52
M52
4d 3 (b 4 F)5s
b 3F
2
3
4
11640.72
11956.33
12342.37
M52
M52
M52
4d 3 (a 4 G)5s
a 3G
3
4
5
12503.44
12760.66
12772.78
M52
M52
M52
4d 2 5s 2
a 1S
0
13141.76
M52
3
4d (b D)5s
3
a D
1
2
3
14123.01
14348.78
14697.03
M52
M52
M52
4d 2 5s(a 4 F)5p
z 5Go
2
3
4
5
6
14783.54
15201.26
15720.36
16316.96
16978.29
M52
M52
M52
M52
M52
4d 2 5s(a 4 F)5p
z 3Fo
2
3
4
16296.51
16843.93
17556.26
M52
M52
M52
4d 2 5s(a 4 F)5p
z 5Fo
1
2
3
4
5
16786.93
17059.61
17422.17
17833.73
18276.92
M52
M52
M52
M52
M52
4d 2 5s(a 4 F)5p
z 5Do
0
1
2
3
4
18976.36
19096.53
19323.84
19625.58
19833.78
M52
M52
M52
M52
M52
4d 2 5s(a 4 F)5p
z 3Go
3
4
5
21849.33
22144.08
22563.89
M52
M52
M52
4d 2 5s(a 2 D)5p
x 3Fo
2
3
4
26061.70
26443.88
26938.42
M52
M52
M52
4d 2 5s(a 2 F)5p
z 5Go
4
26931.35
M52
4d 3 (b 4 F)5p
y 5Go
5
6
26765.66
27214.89
M52
M52
4d 2 5s(a 2 F)5p
w 3Fo
2
3
4
27876.16
28157.42
28528.36
M52
M52
M52
4d 2 5s(a 2 F)5p
x 3Go
3
4
5
28404.26
28749.80
29001.65
M52
M52
M52
4d 5s
2
2
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
ATOMIC SPECTROSCOPIC DATA
2139
Energy Levels of Neutral Zirconium 共Zr I兲—Continued
Configuration
Term
J
Level (cm⫺1 )
4d 3 (b 4 F)5p
y 5Fo
4
5
29122.71
29535.48
M52
M52
4d 3 (b 4 F)5p
x 5Do
3
4
30087.33
30384.50
M52
M52
Limit
53506.0
HHMR86
Zr II ( 4 F3/2)
Ref
Persistent Lines of Singly-ionized Zirconium 共Zr II兲
Configuration
Term
J
Level (cm⫺1 )
2568.871
4d 2 (a 3 F)5s
4d5s(a 3 D)5p
a 4F
x 4Do
9/2
7/2
1322.730
40238.668
J98
400
2571.457
4d 2 (a 3 F)5s
4d5s(a 3 D)5p
a 4F
x 4Do
7/2
5/2
763.428
39640.238
J98
300
2678.632
4d 2 (a 3 F)5s
4d5s(a 3 D)5p
a 4F
y 4Fo
9/2
9/2
1322.730
38644.130
J98
250
2722.609
4d 2 (a 3 F)5s
4d 2 (a 3 P)5p
a 4F
y 4Do
9/2
7/2
1322.730
38041.326
J98
250
2734.851
4d 2 (a 3 F)5s
4d5s(a 3 D)5p
a 4F
y 4Fo
5/2
5/2
314.673
36868.921
J98
250
3279.264
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 4F
z 4Fo
7/2
7/2
763.428
31249.288
J98
1000
3391.972
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 4F
z 4Go
9/2
11/2
1322.730
30795.649
J98
800
3438.231
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 4F
z 4Go
7/2
9/2
763.428
29839.821
J98
200
3479.387
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 2F
z 2Go
5/2
7/2
5752.868
34485.338
J98
250
3481.155
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 2F
z 2Go
7/2
9/2
6467.509
35185.385
J98
700
3496.206
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 4F
z 4Go
5/2
7/2
314.673
28908.930
J98
300
3551.951
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 4F
z 4Go
7/2
7/2
763.428
28908.930
J98
400
3556.594
4d 3
4d 2 (a 3 F)5p
b 4F
z 4Fo
9/2
9/2
3757.732
31866.493
J98
400
3572.468
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 4F
z 4Go
3/2
5/2
0.000
27983.864
J98
250
3576.853
4d 3
4d 2 (a 3 F)5p
b 4F
z 4Fo
7/2
7/2
3299.732
31249.288
J98
250
3836.761
0.51
4d 2 (a 1 D)5s
4d 2 (a 3 F)5p
a 2D
z 2Fo
5/2
7/2
4505.496
30561.756
J98
BGHL81
200
4149.198
0.45
4d 2 (a 3 F)5s
4d 2 (a 3 F)5p
a 2F
z 2Fo
7/2
7/2
6467.509
30561.756
J98
BGHL81
Inten
Wavelength 共Å兲
300
A ki (108 s⫺1 )
1.03
0.32
Wl Ref
A Ref
BGHL81
BGHL81
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2140
J. E. SANSONETTI AND W. C. MARTIN
Energy Levels of Singly-ionized Zirconium 共Zr II兲
Configuration
2
3
Term
J
Level (cm⫺1 )
Ref.
4d (a F)5s
4
a F
3/2
5/2
7/2
9/2
0.000
314.673
763.428
1322.730
J98
J98
J98
J98
4d 3
b 4F
3/2
5/2
7/2
9/2
2572.372
2895.097
3299.732
3757.732
J98
J98
J98
J98
4d 2 (a 1 D)5s
a 2D
3/2
5/2
4248.165
4505.496
J98
J98
4d 2 (a 3 P)5s
a 2P
1/2
3/2
5724.150
6111.529
J98
J98
4d 2 (a 3 F)5s
a 2F
5/2
7/2
5752.868
6467.509
J98
J98
4d 2 (a 3 F)5p
z 4Go
5/2
7/2
9/2
11/2
27983.864
28908.930
29839.821
30795.649
J98
J98
J98
J98
4d 2 (a 3 F)5p
z 4Fo
3/2
5/2
7/2
9/2
29777.624
30551.468
31249.288
31866.493
J98
J98
J98
J98
4d 2 (a 3 F)5p
z 2Fo
7/2
30561.752
J98
4d 2 (a 3 F)5p
z 2Go
7/2
9/2
34485.338
35185.385
J98
J98
4d 2 (a 3 P)5p
y 4Do
7/2
38041.326
J98
4d5s(a 3 D)5p
y 4Fo
5/2
9/2
36868.921
38644.130
J98
J98
4d5s(a 3 D)5p
x 4Do
5/2
7/2
39640.238
40238.668
J98
J98
Zr III ( 3 F2 )
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Limit
106000
J98
ATOMIC SPECTROSCOPIC DATA
2141
3. References and Notes
A80
A95
ABDJ90
ABK92
AJK89
AM59
APS71
AV77
AWT80
B36
B59
B64
M. Aymar, A. Debarré, and O. Robaux, J.
Phys. B 13, 1089 共1980兲.
V. I. Azarov, unpublished compilation of F I
data 共1995兲.
F: Azarov reoptimized the energy levels
using Lidén’s 关L49兴 analysis and wavelength
data and a few more recent measurements.
The Ritz-principle consistency of the levels
included here indicates relative uncertainties
smaller than 0.010 cm⫺1 within the system
of 2p 4 3s,3p levels. Lidén 关L49兴 used the
seven strong 2p 5 2Po – 2p 4 3s resonance
lines to obtain the position of the 2p 4 nl level
system with respect to the 2p 5 2Po levels.
His estimated uncertainty of 0.003 Å for
these wavelengths corresponds to an
uncertainty of about 0.33 cm⫺1 for even the
best-determined 2p 4 nl levels. Azarov’s
values for the 2p 4 nl levels are about
0.12 cm⫺1 below Lidén’s because Azarov
included some weaker lines omitted by
Lidén in deriving the 2p 5 – 2p 4 nl
connection. We here adopt Lidén’s
connection by giving Azarov’s 2p 4 nl levels
a systematic adjustment of 0.120 cm⫺1 ,
which is practically insignificant relative to
the uncertainty involved.
E. Arnold, W. Borchers, H. T. Duong, P.
Juncar, J. Lermé, P. Lievens, W. Neugart, M.
Pellarin, J. Pinard, J. L. Vialle, K. Wendt,
and the ISOLDE Collaboration, J. Phys. B
23, 3511 共1990兲.
P. Aufmuth, A. Bernard, and E.-G. Kopp, Z.
Phys. D 23, 15 共1992兲.
B. Arcimowicz, Y. N. Joshi, and V.
Kaufman, Can. J. Phys. 67, 572 共1989兲.
K. L. Andrew and K. W. Meissner, J. Opt.
Soc. Am. 49, 146 共1959兲.
Y. Accad, C. L. Pekeris, and B. Schiff, Phys.
Rev. A 4, 516 共1971兲.
Z. Ben Ahmed and J. Vergés, Physica
共Utrecht兲 92C, 113 共1977兲, as compiled in
关KS88兴.
J. A. Armstrong, J. J. Wynne, and F. S.
Tomkins, J. Phys. B 13, L133 共1980兲.
J. C. Boyce, Phys. Rev. 49, 730 共1936兲.
J. R. Beacham, M.S. Thesis, Purdue Univ.
共1970兲.
W. G. Brill, Ph. D. Thesis, Purdue Univ.
共1964兲.
B69
B83
B88
B01
BA56
BAL50
Sn: The wavelengths for Sn II lines in the
region below 2000 Å have been derived
from Brill’s energy level values. His
estimated uncertainty for the levels of all
excited configurations with respect to the
5s 2 5 p 2Po ground-term levels is 0.05 cm⫺1 .
K. S. Bhatia, Ph. D. thesis, Univ. British
Columbia, 1969 and K. S. Bhatia, J. Phys. B
11, 2421 共1978兲.
In: Although this thesis has In III and In IV
as the main subjects, new wavelength
measurements for In II lines are included.
Bhatia’s wavenumber for the 5s5p
3 o
P2 – 5s6s 3S1 line, 48095.0 cm⫺1 , has a
Ritz-principle disagreement of about
1.2 cm⫺1 with determinations of the 3Po
intervals given by his measurements in the
1607–1977 Å region. We have not used the
observed wavenumber of this line in
determining the level value and, instead,
give a Ritz-principle wavelength of
2078.608 Å for the line. Bhatia’s
experimental procedures are described in his
published paper on In III: K. S. Bhatia, J.
Phys. B 11, 2421 共1978兲.
M. A. Baig, J. Phys. B 16, 1511 共1983兲.
A. S. Bakhtiyarov, Astrofizica 29, 625
共1988兲.
Tc: The oscillator strengths were
calculated with single-configuration wave
functions. The values given here were
obtained with the length form of the
transition operator; values obtained with the
velocity form differ by up to 40% from the
corresponding length-form values.
J. Blaise, unpublished material 共2001兲.
Tb: Based on new observations, this work
gives improved values for the levels of Tb I
and Tb II in 关MZH78兴 and includes
extensions and some revisions of the
analyses.
K. Burns and K. B. Adams, J. Opt. Soc. Am.
46, 94 共1956兲.
K. Burns, K. B. Adams, and J. Longwell, J.
Opt. Soc. Am. 40, 339 共1950兲.
Hg: The lines of natural Hg I are
broadened by hyperfine and isotopic
structures. As a result, the line shapes can
vary according to spectrometer resolution,
observation time, etc. Mainly because such
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2142
BBBL98
BBC95
BBLB98
BC85
BCT68
BDD72
BDGL98
BDMQ98
BE93
BE99
J. E. SANSONETTI AND W. C. MARTIN
effects can affect the measured wavelengths,
we have given no more than three decimal
places for the lines of Hg I. Using a
low-pressure electrodeless lamp source,
Sansonetti et al. 关SSR96兴 have made
high-accuracy measurements of 26 of the
Hg I wavelengths measured by Burns et al.
in the 2536 –5791 Å region; the resulting
standard deviation of 0.003 Å between the
two sets of measurements may be at least
partly due to line-shape effects. We also note
that the wavelengths given here should not
be used for calibrations based on lines from
pencil-type lamps if uncertainties smaller
than 0.01 Å are desired; measurements by
Sansonetti et al. 关SSR96兴 in the region
2536 –5791 Å show the pencil-lamp Hg
wavelengths to be systematically longer than
the values of Burns et al. by an average of
0.0068共32兲 Å.
S. D. Bergeson, A. Balakrishnan, K. G. H.
Baldwin, T. B. Lucatorto, J. P. Marangos, T.
J. McIlrath, T. R. O’Brian, S. L. Rolston, C.
J. Sansonetti, J. Wen, N. Westbrook, C. H.
Cheng, and E. E. Eyler, Phys. Rev. Lett. 80,
3475 共1998兲.
F. Blanco, B. Botho, and J. Campos, Phys.
Scr. 52, 628 共1995兲.
J. F. Baugh, C. E. Burkhardt, J. J. Leventhal,
and T. Bergeman, Phys. Rev. A 58, 1585
共1998兲.
Na: See also 关CBLB92兴.
M. A. Baig and J. P. Connerade, J. Phys. B
18, 1101 共1985兲.
W. R. Bozman, C. H. Corliss, and J. L. Tech,
J. Res. Natl. Bur. Stand. 共U.S.兲 72A, 559
共1968兲.
H. G. Berry, J. Desesquelles, and M. Dufay,
Phys. Rev. A 6, 600 共1972兲.
E. Biémont, P. S. Doidge, H. P. Garnir, Z. S.
Li, C. Lynga, and S. Svanberg, Abstr. of
Sixth Int. Colloq. on Atomic Spectra and
Oscillator Strengths for Astrophysical and
Laboratory Plasmas, Univ. Victoria, BC,
1998, p. 8.
E. Biémont, J.-F. Dutrieux, I. Martin, and P.
Quinet, J. Phys. B 31, 3321 共1998兲.
J. W. Brault and R. Engleman, Jr.,
unpublished 共1993兲.
J. M. Brown and K. M. Evenson, Phys. Rev.
A 60, 956 共1999兲.
Al: Brown and Evenson have measured
the splitting of the ground state to be
112.064 95(6) cm⫺1 . For consistency with
the excited-configuration levels we have
here retained the less accurate interval from
关MZ79兴.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
BFG84
BG78
BGFM89
BGHL81
BGKZ82
BHU02
BJ71
BJK75
BKE98
BM00
BM99
BMC67
BMQZ94
BPKR97
J. Blaise, M. Fred, and R. G. Gutmacher,
Argonne Natl. Lab. Rep. ANL-83-95 共1984兲.
Pu: The relative intensities for both Pu I
and Pu II are from Blaise and Wyart
关BW92b兴, who used a very compressed
scale.
C. M. Brown and M. L. Ginter, J. Opt. Soc.
Am. 68, 243 共1978兲.
E. Biémont, N. Grevesse, L. M. Faires, G.
Marsden, J. E. Lawler, and W. Whaling,
Astron. Astrophys. 209, 391 共1989兲.
E. Biémont, N. Grevesse, P. Hannaford, and
R. M. Lowe, Astrophys. J. 248, 867 共1981兲.
E. Biémont, M. Grevesse, M. Kwiatowski,
and P. Zimmerman, Astron. Astrophys. 108,
127 共1982兲.
F. Brandi, W. Hogervorst, and W. Ubacks, J.
Phys. B 35, 1071 共2002兲.
Kr: Comparisons of three 86Kr I levels as
determined by these authors with the
corresponding 86Kr level values in 关K93兴 and
关SM91兴
give
a
correction
of
for
the
previous
0.0121(12) cm⫺1
connection of the excited levels to the
ground level. We have applied this
correction to the 84Kr I excited levels in
关K93兴.
K. S. Bhatia and W. E. Jones, Can. J. Phys.
49, 1773 共1971兲.
H. Benschop, Y. N. Joshi, and T. A. M. van
Kleef, Can. J. Phys. 53, 700 共1975兲.
J. M. Brown, H. Korsgen, and K. M.
Evenson, Astrophys. J. 509, 927 共1998兲.
Fe: This reference gives experimental
values for two of the Fe II 3d 6 4s a 6 D
ground-term
level
separations
as
6
D3/2 – 6 D1/2⫽3430.7762(19) GHz
(114.438 38(7) cm⫺1 ) and 6D5/2 – 6 D3/2
⫽5843.7984(12) GHz
(194.928 13(4) cm⫺1 ). For consistency
with the Fe II levels derived in 关J78兴 we have
retained the less accurate values 114.440 and
194.930 cm⫺1 , respectively, for these
separations.
J. Baker and P. Mohr, unpublished
calculations 共2000兲.
P. Bogandovich and I. Martinson, Phys. Scr.
60, 217 共1999兲.
W. R. Bozman, W. F. Meggers and C. H.
Corliss, J. Res. Natl. Bur. Stand. 共U.S.兲 71A,
547 共1967兲.
E. Biémont, F. Martin, P. Quinet, and C. J.
Zeippen, Astron. Astrophys. 283, 339
共1994兲.
E. Biémont, E. H. Pinnington, J. A.
Kernahan, and G. Rieger, J. Phys. B 30,
2067 共1997兲.
ATOMIC SPECTROSCOPIC DATA
BPQ01
BTG74
BTG75
BTG77
BVEC94
BVHU01
BVWE92
BW86
BW92a
Ag: We have corrected the typographical
error for the Ag II line at 1106.9931 Å as
noted by 关BM99兴.
E. Biémont, P. Palmeri, and P. Quinet,
Database of Rare Earths at Mons University
共Updated 4 Sep. 2001兲 关Online兴. Available:
http://www.umh.ac.be/具p典astro/dream.shtml
C. M. Brown, S. G. Tilford, and M. L.
Ginter, J. Opt. Soc. Am. 64, 877 共1974兲.
C. M. Brown, S. G. Tilford, and M. L.
Ginter, J. Opt. Soc. Am. 65, 1404 共1975兲.
C. M. Brown, S. G. Tilford, and M. L.
Ginter, J. Opt. Soc. Am. 67, 607 共1977兲.
J. M. Brown, T. D. Varberg, K. M. Evenson,
and A. L. Cooksy, Astrophys. J. 428, L37
共1994兲.
N: These authors have measured the
fine-structure intervals for the 3P ground
term of N II to be 1461.131 90共61兲 GHz
(48.738 11 cm⫺1 ) for the J⫽0 to J⫽1
transition and 2459.380 06共37兲 GHz
(82.036 09 cm⫺1 ) for the J⫽1 to J⫽2
transition.
F. Brandi, I. Velchev, W. Horgervorst, and W.
Ubachs, Phys. Rev. A 64, 032505 共2001兲.
Xe: These authors determined the value of
o
)6s 2 关 1/2兴 o0 level to be
the 136Xe I 5p 5 ( 2 P1/2
⫺1
with respect to the
76 196.7848(35) cm
ground level. Using the isotope shifts for this
level 关BVHU01兴, we have here lowered this
value 共by 0.018 cm⫺1 ) to the isotopic
center-of-gravity position for natural Xe. We
also used pertinent measurements 关PBFS89,
JC74, JC75兴 to adjust all the other levels
tabulated here to center-of-gravity values.
We used a constant correction for all levels
of any particular configuration; the available
data 关JC74, JC75兴 indicate that this
approximation is valid within deviations of
at most a few units in the third place.
J. Blaise, J. Vergés, J.-F. Wyart, and R.
Engleman, Jr., J. Res. Natl. Inst. Stand. Tech.
97, 213 共1992兲.
Pt: We have changed the order of electron
coupling for the 5d 8 6s6 p configuration.
R. Beigang and J. J. Wynne, J. Opt. Soc. Am.
B 3, 949 共1986兲.
Sb: The ionization energy determined by
these authors was based on a value of
45 945.4 cm⫺1 for the ( 3 P)6s 4P3/2 level. We
have lowered their value for the ionization
energy by 0.06 cm⫺1 in accordance with the
more accurate ( 3 P)6s 4P3/2 level value from
关HARV88兴.
J. Blaise and J.-F. Wyart, J. Res. Natl. Inst.
Stand. Tech. 97, 217 共1992兲.
BW92b
BWCC91
BWDA84
BWWI85
BZE98
C52
C66a
C66b
C71
C73
2143
Pt: In 关WBJ95兴 the analysis of Pt II is
extended and LS coupling designations for
odd parity levels are given.
J. Blaise and J.-F. Wyart, Energy Levels and
Atomic Spectra of Actinides, International
Tables of Selected Constants 20, 528 pages
共1992兲. Available: http//www.lac.u-psud.fr/
Database/Contents.html
Np: The authors note that the Np II
energy-level analysis is preliminary. Only
one Np II line is given with an energy-level
classification.
S. Bisson, E. F. Worden, J. G. Conway, B.
Comaskey, J. A. D. Stockdale, and F.
Nehring, J. Opt. Soc. Am. B 8, 1545 共1991兲.
Ce: These authors give wavelengths and
transition probabilities for 228 lines of Ce I
in the range 4506 –9337 Å. Unfortunately,
no transition probabilities were given for the
12 Ce I lines selected here as being
persistent.
J. Blaise, J.-F. Wyart, M. T. Djerad, and Z.
Ben Ahmed, Phys. Scr. 29, 119 共1984兲.
Nd: Note that the energy-level data for
Nd II in this reference supersede the data in
关MZH78兴.
J. J. Bollinger, J. S. Wells, D. J. Wineland,
and W. M. Itano, Phys. Rev. A 31, 2711
共1985兲.
J. M. Brown, L. R. Zink, and K. M.
Evenson, Phys. Rev. A 57, 2507 共1998兲.
F: These authors determined the F II 2p 4
3
P1 – 3 P0 fine-structure interval to be
148.544 537(53) cm⫺1 .
H. E. Clearman, J. Opt. Soc. Am. 42, 373
共1952兲.
G. W. Charles, J. Opt. Soc. Am. 56, 1292
共1966兲.
Po: The adopted value for the Po I
ionization energy is intermediate between
the two values 67 840 and 67 885 cm⫺1
obtained in this reference.
C. Chan, Ph. D. thesis, Univ. British
Columbia 共1966兲.
Sb: The values Chan derived for the Sb II
ionization energy from thirteen different
three-member series vary by up to several
hundred cm⫺1 . We have rounded off his
adopted value to the nearest 100 cm⫺1 .
P. Camus, Ph. D. thesis, Univ. Paris, Orsay
共1971兲.
C. H. Corliss, J. Res. Natl. Bur. Stand. 共U.S.兲
77A, 419 共1973兲.
Ce: The Ce II levels as presented here are
from 关MZH78兴, with many levels grouped
into terms.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2144
C74
C84
C00
CABC82
CBLB92
CBS86
CBV76
CBZS95
CD68
CFSK74
CG98
CHPT55
CHR88a
CHR88b
CKNJ94
CLS97
CM34
CMG64
CNWM70
CR58
J. E. SANSONETTI AND W. C. MARTIN
H. M. Crosswhite, J. Res. Natl. Bur. Stand.
共U.S.兲 79A, 17 共1974兲.
R. Crossley, J. Opt. Soc. Am. B 1, 266
共1984兲.
L. J. Curtis, Phys. Scr. 62, 31 共2000兲.
A. Coste, R. Avril, P. Blancard, J. Chatelet,
D. Lambert, J. Legre, S. Liberman, and J.
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M. Ciocca, C. E. Burkhardt, J. J. Leventhal,
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共1992兲.
A. L. Cooksy, G. A. Blake, and R. J.
Saykally, Astrophys. J. 305, L89 共1986兲.
C: These authors give high-accuracy
o
o
splitting
– 2 P1/2
values for the C II 2p 2P3/2
12
13
for isotopes C and C, the value for 12C
being
1 900 536.9共1.3兲
MHz
(63.395 09(5) cm⫺1 ).
J. G. Conway, J. Blaise, and J. Vergés,
Spectrochim. Acta B 31, 31 共1976兲.
L. Caiyan, U. Berzinsh, R. Zerne, and S.
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A. M. Crooker and K. A. Dick, Can. J. Phys.
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W. J. Childs, M. Fred, E. Schrodl, and T. A.
M. van Kleef, Phys. Rev. A 10, 1028 共1974兲.
E. S. Chang and M. Geller, Phys. Scr. 58,
326 共1998兲.
C: Some of the separations of C I levels in
this reference have estimated uncertainties
less than 0.01 cm⫺1 . The values here are
rounded to two decimal places because the
absolute uncertainty 共with respect to the
ground level兲 of even the best-determined
levels higher than the 2s2 p 3 5So2 level is
about 0.04 cm⫺1 关J66, KW66, KE74兴.
G. W. Charles, D. J. Hunt, G. Pish, and D. L.
Timma, J. Opt. Soc. Am. 45, 869 共1955兲.
C. L. Callender, P. A. Hackett, and D. M.
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C. L. Callender, P. A. Hackett, and D. M.
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J. R. Crespo Lopéz-Urrutia, B. Kenner, T.
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P. Colarusso, M. A. Lebeault-Dorget, and B.
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M. F. Crawford and A. B. McLay, Proc. R.
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M. A. Catalán, W. F. Meggers, and O.
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T. A. Carlson, C. W. Nestor, Jr., N.
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63 共1970兲.
M. A. Catalán and F. R. Rico, An. R. Soc.
Esp. Fis. Quim. 54, 301 共1958兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
CS96
CSBE86
CT72
CWBC77
CWBV77
D26
D38
D76
D95
D96
D03
DA78
DAGW97
DHL86
DHM33
DL85
DLW02
DM98
DM01
M. D. Campbell-Miller and B. Simard, J.
Opt. Soc. Am. B 13, 2115 共1996兲.
A. L. Cooksy, R. J. Saykally, J. M. Brown,
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J. G. Conway, E. F. Worden, J. Blaise, P.
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J. G. Conway, E. F. Worden, J. Blaise, and J.
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T. L. de Bruin, Z. Phys. 38, 94 共1926兲.
J. C. Dobbie, Ann. Sol. Phys. Obs.
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D. S. Davis, Ph. D. Thesis, Purdue Univ.,
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P. S. Doidge, Spectrochim. Acta 50B, 209
共1995兲.
G. W. F. Drake, High Precision Calculations
for Helium, in Atomic Molecular, & Optical
Physics, G.W.F. Drake, ed. 共American Inst.
of Physics, Woodbury, New York, 1996兲,
pp. 154 –171.
G. W. F. Drake, calculated energies for He I
levels 共2003兲, to be published in Can. J.
Phys.
He: These data comprise a revision of
Table 11.7 of 关D96兴.
D. S. Davis and K. L. Andrew, J. Opt. Soc.
Am. 68, 206 共1978兲.
V: The energy-level values in this paper
are listed in tabular form in 关D76兴. See also
关PBQS97兴.
J. Dembczynski, B. Arcimowicz, G. H.
Guthöhrlein, and L. Windholz, Z. Phys. D
39, 143 共1997兲.
D. W. Duquette, E. A. Den Hartog, and J. E.
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35, 281 共1986兲.
T. L. de Bruin, C. J. Humphreys and W. F.
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409 共1933兲.
D. W. Duquette and J. E. Lawler, J. Opt. Soc.
Am. B 2, 1948 共1985兲.
L. Dolk, U. Litzén, and G. M. Wahlgren,
Astron. Astrophys. 388, 692 共2002兲.
G. W. F. Drake and W. C. Martin, Can. J.
Phys. 76, 679 共1998兲.
G. W. F. Drake and W. C. Martin,
unpublished 共2001兲.
Li: The data are based on accurate new
energy-level calculations for 7Li II. In
addition to a lowering of the ionization
energy of 关HM59兴 by 1.00 cm⫺1 the results
indicate that the 1s3 p 1Po, 1s4s, 5s, 6s 1S
and 1s4d – 8d 1D level values of 关HM59兴
ATOMIC SPECTROSCOPIC DATA
DMZ53
DR72a
DR72b
E31
E72
E74
E83
E95
E99
ED71
EJN64
EKM00
EL01
ELLW98
EOHJ70
ER56
ES36
EUVH97
are 0.3 cm⫺1 too high with respect to their
more accurately determined levels. Accurate
calculated term values for 1s4 p 1Po and
1s5 p 1Po levels disagree with the values in
关HM59兴, in accordance with the conclusions
of Crossley 关C84兴 and the calculations of
Accad, et al. 关APS71兴.
G. V. Deverall, K. W. Meissner, and G. J.
Zissis, Phys. Rev. 91, 297 共1953兲.
S. P. Davis and J. Reader, unpublished
material 共1972兲.
Pm: See 关DR72b兴.
S. P. Davis and J. Reader, J. Opt. Soc. Am. B
62, 1370A 共1972兲.
E. Ekefors, Z. Phys. 71, 53 共1931兲.
K. B. S. Eriksson, Phys. Lett. A 41, 97
共1972兲.
K. B. S. Eriksson, J. Opt. Soc. Am. 64, 1272
共1974兲.
K. B. S. Eriksson, Phys. Scr. 28, 593 共1983兲.
J. Emsley, Oxford Chemistry Guides: The
Elements 共Oxford Univ. Press, New York,
NY, 1995兲.
R. Engleman, unpublished wave number
measurements 共1999兲 quoted in 关M03兴.
K: The uncertainty of the K I 4p 2Po levels
is probably less than 0.001 cm⫺1 .
J. C. Ehrhardt and S. P. Davis, J. Opt. Soc.
Am. 61, 1342 共1971兲.
K. B. Eriksson, I. Johansson, and G. Norlén,
Ark. Fys. 28, 233 共1964兲.
J. O. Ekberg, R. Kling, and W. Mende, Phys.
Scr. 61, 146 共2000兲.
W: The eigenvector percentages in Table
III of this paper indicate that no meaningful
LS-coupling names can be assigned to some
energy levels. We have used numerical
designations for these levels.
R. Engleman, Jr. and U. Litzén, unpublished
data 共2001兲.
B: Engleman and Litzén improved and
extended the infrared observations of B I and
also made new measurements of several
ultraviolet lines. The new infrared
wavelengths and resulting level values
supersede the data in 关L70b兴.
R. Engelman, Jr., U. Litzén, H. Lundberg,
and J.-F. Wyart, Phys. Scr. 57, 345 共1998兲.
B. Edlén, A. Ölme, G. Herzberg, and J. W. C.
Johns, J. Opt. Soc. Am. 60, 889 共1970兲.
B. Edlén and P. Risberg, Ark. Fys. 10, 553
共1956兲.
C. B. Ellis and R. A. Sawyer, Phys. Rev. 49,
145 共1936兲.
K. S. E. Eikema, W. Ubachs, W. Vassen, and
H. Horgovorst, Phys. Rev. A 55, 1866
共1997兲.
EW70
F54
F91
FHLP00
FL99
FMW88
FT57
FTBC76
FW96
G54
G62
G67
G89
G90
GBCZ74
GF02
GK00
2145
K. B. S. Eriksson and I. Wenåker, Phys. Scr.
1, 21 共1970兲.
G. R. Fowles, J. Opt. Soc. Am. 44, 760
共1954兲.
P. Forsberg, Phys. Scr. 44, 446 共1991兲.
J. A. Fedchak, E. A. Den Hartog, J.
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J. R. Fuhr, G. A. Martin, and W. L. Wiese, J.
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M. Fred and F. S. Tomkins, J. Opt. Soc. Am.
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M. Fred, F. S. Tomkins, J. E. Blaise, P.
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Rep. No. 76-68 共1976兲.
J. R. Fuhr and W. L. Wiese, NIST Atomic
Transition
Probability
Tables,
CRC
Handbook of Chemistry & Physics, 77th ed.,
D. R. Lide, ed. 共CRC Press, Inc., Boca
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W. R. S. Garton, Proc. Phys. Soc. 共London兲
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In: Garton’s wavelength measurements
for the four 5s 2 5 p 2Po – 5s5p 2 2P
autoionization-broadened transitions have
Ritz-principle consistency of a few
cm⫺1 . This multiplet was first identified in
关C52兴.
S. George, Ph. D. thesis, Univ. British
Columbia 共1962兲.
A. Giachetti, J. Opt. Soc. Am. 57, 728
共1967兲.
A. Ginbre, Phys. Scr. 39, 694 共1989兲.
A. Ginbre, At. Data Nucl. Data Tables 44, 1
共1990兲.
A. Giacchetti, J. Blaise, C. H. Corliss, and R.
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W. L. Glab and A. M. Falleur, J. Quant.
Spectrosc. Rad. Trans. 73, 121 共2002兲.
U. Griesmann and R. Kling, Astrophys. J.
536, L113 共2000兲.
Al: The values obtained for the Al II 3s3p
1 o
P
level
by
these
authors
is
59 851.976(4) cm⫺1 . We have retained the
less accurate value from 关MZ79兴 for
consistency with the other Al II levels in the
table.
Si: The values of the two Si II levels
corresponding
to
the
high-accuracy
wavelengths from this reference are
55 309.3404共4兲 and 65 500.4538(7) cm⫺1 .
We have retained the less accurate level
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2146
GKQW91
GL80
GL00
GM62
GM65
GMV85
GRTE73
GSZ70
GV72
H39
H53
H73
HA64
HA85
HARV88
HHMR86
HJ69
HJLW82
HM33
HM59
J. E. SANSONETTI AND W. C. MARTIN
values from 关MZ83兴 for consistency with the
other levels in the table.
A. Goly, J. Kusz, B. Nguyen Quang, and S.
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Y. Guern and J. Lotrian, J. Quant. Spectrosc.
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P. Gunnwald and L. Minnhagen, Ark. Fys.
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S. George, J. H. Munsee, and J. Vergés, J.
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Bi: The wavelengths for which this
reference is cited were derived from the
energy levels in the reference.
W. R. S. Garton, E. M. Reeves, F. S.
Tomkins, and B. Ercoli, Proc. R. Soc.
London, Ser. A 333, 17 共1973兲.
A. Giacchetti, R. W. Stanley, and R. Zalubas,
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C. J. Humphreys, J. Res. Natl. Bur. Stand.
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C. J. Humphreys, J. Opt. Soc. Am. 43, 1027
共1953兲.
C. J. Humphreys, J. Phys. Chem. Ref. Data
2, 519 共1973兲.
Xe: These are 136Xe I wavelengths
calculated from level differences 关HP70b兴.
C. J. Humphreys and K. L. Andrew, J. Opt.
Soc. Am. 54, 1134 共1964兲.
L. E. Howard and K. L. Andrew, J. Opt. Soc.
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F. Hassini, Z. Ben Ahmed, O. Robaux, J.
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5, 2060 共1988兲.
P. A. Hackett, M. R. Humphries, S. A.
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J. E. Holmström and L. Johansson, Ark. Fys.
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37, 1293 共1959兲.
Li: The data pertain to the 7Li isotope. The
wavelengths for some of the stronger lines
and the values for the triplet levels are
weighted averages of large hyperfine
structures, for some of which the resolved
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
HM64
HP70a
HP70b
HP87
HPCA67
HWL02
HWL99
ICL88
IL85
IV64
J61a
components are given in 关HM59兴. The
ionization energy and, consequently, all
excited levels from this reference have been
lowered by 1.00 cm⫺1 关DM01兴. Although
higher accuracy measurements of the 1s2p
3 o
P separation have been made more recently
关RGKP93兴, we have for consistency retained
the term values 共positions with respect to the
limit兲 for these levels from 关HM59兴.
M. B. Handrup and J. E. Mack, Physica 30,
1245 共1964兲.
Te: Energy level values have been reduced
by 0.47 cm⫺1 , as suggested by 关E74兴.
C. J. Humphreys and E. Paul, Jr., J. Opt. Soc.
Am. 60, 200 共1970兲.
Kr: These authors give four or five place
Kr II wavelengths of the 86Kr isotope. We
have rounded the values to three decimals to
be more in accordance with their probable
accuracies when used as wavelengths for a
natural Kr isotopic mixture.
C. J. Humphreys and E. Paul, Jr., J. Opt. Soc.
Am. 60, 1302 共1970兲.
Xe: We have here adjusted the 136Xe I
levels in this reference to a more accurate
connection with the ground level and to
isotopic center-of-gravity positions for
natural Xe 共see note with 关BVHU01兴兲. The
infrared Xe I wavelengths given here with
the 关HP70b兴 reference are Ritz-principle
values calculated from the isotopic
center-of-gravity level values.
J. E. Hansen and W. Persson, Phys. Scr. 36,
602 共1987兲.
C. J. Humphreys, E. Paul, Jr., R. D. Cowan,
and K. L. Andrew, J. Opt. Soc. Am. 57, 855
共1967兲.
E. A. Den Hartog, M. E. Wickliffe, and J. E.
Lawler, Astrophys. J. Suppl. Ser. 141, 255
共2002兲.
E. A. Den Hartog, L. M. Wiese, and J. E.
Lawler, J. Opt. Soc. Am. B 16, 2278 共1999兲.
L. Iglesias, M. I. Cabeza, and B. de Luis,
Pub. Inst. Opt. Madrid, No. 47 共1988兲.
B. Isberg and U. Litzén, Phys. Scr. 31, 533
共1985兲.
Ga: See 关SSM03兴 also.
L. Iglesias and R. Velasco, Pub. Inst. Opt.
Madrid, No. 23 共1964兲.
L. Johansson, Ark. Fys. 20, 489 共1961兲.
Be: The Be II levels and ionization energy
given in this reference have been decreased
by 0.02 cm⫺1 关KM00兴 in accordance with a
more accurate determination of the 1s 2 2p
2 o
P levels 关BWWI85兴. The uncertainty of the
2 p 2Po levels is about 0.005 cm⫺1 . The
ATOMIC SPECTROSCOPIC DATA
J61b
J66
J78
J98
JC74
JC75
JJ93
JJLL94
JKBL96
JKLC94
JL65
uncertainty of the other excited levels
relative to the 2s and 2p levels is about
0.2 cm⫺1 , but the levels above 3s should, in
general, be accurate within 0.10 cm⫺1
relative to the 3s level.
I. Johansson, Ark. Fys. 20, 135 共1961兲.
L. Johansson, Ark. Fys. 31, 201 共1966兲.
C: Johansson’s values for most of the
best-known C I excited-configuration levels
共with respect to the 2p 2 3P0 ground level兲
agree with newer redetermined values
关KW66, CG98兴 within 0.01 cm⫺1 . The value
o
of 90 883.84(10) cm⫺1 for the C II 2 p 2P3/2
limit, as derived by Johansson from the C I
2pnp 3D3 series, is not changed significantly
by the more recent work. His resulting value
o
limit has been adjusted to
for the C II 2P1/2
the more accurate value of 63.395 cm⫺1 for
o
o
– 2 P1/2
splitting 关CBS86兴.
the C II 2p 2P3/2
Given the absolute uncertainty of about
0.04 cm⫺1 for the 2pnp 3D levels and the
additional uncertainty of the limit
determination,
Johansson’s
estimated
uncertainty of 0.10 cm⫺1 for the ionization
energy is reasonable. We used Johansson’s
wave numbers for the two pertinent lines
near 2965 Å together with the new 2p 2 3P1
and 3P2 level values to adjust his 2s2 p 3 5So2
level upwards by 0.02 cm⫺1 .
S. Johansson, Phys. Scr. 18, 217 共1978兲.
S. Johansson, unpublished 共1998兲.
Zr: New observations of Zr I and Zr II and
extensions of the analysis. No newly
evaluated Zr I levels are available yet.
D. A. Jackson and M.-C. Coulombe, Proc. R.
Soc. London A 338, 277 共1974兲.
D. A. Jackson and M.-C. Coulombe, Proc. R.
Soc. London A 343, 453 共1975兲.
A. Joueizadeh and S. Johansson, Natl. Inst.
Stand. Tech. Spec. Pub. 885, 131 共1993兲.
S. G. Johansson, A. Joueizadeh, U. Litzén, J.
Larsson, A. Persson, C.-G. Wahlström, S.
Svanberg, D. Leckrone, and G. M.
Wahlgren, Astrophys. J. 421, 809 共1994兲.
S. Johansson, G. Kalus, T. Brage, D. S.
Leckrone, and G. M. Wahlgren, Astrophys.
J. 462, 943 共1996兲.
Tl: The Tl II wavelengths were obtained
by averaging the isotope and hyperfine
components of each transition with
weighting by intensities. We evaluated the
levels using the average wavelengths.
A. M. James, P. Kowalczyk, E. Langlois, M.
D. Campbell, A. Ogawa, and B. Simard, J.
Chem. Phys. 101, 4485 共1994兲.
L. Johansson and U. Litzén, Ark. Fys. 29,
175 共1965兲.
JL67
JL80
JLKK93
JM86
JPHC81
JRB00
JS00
K35
K40
2147
I. Johansson and U. Litzén, Ark. Fys. 34, 573
共1967兲.
Ga: See 关SSM03兴 also. The values of the
Ga I 4s 2 5 – 7p, 6 – 8s, and 5 – 7d levels in
关JL67兴 should be increased by 0.02 cm⫺1 for
consistency with the value of the 4s 2 5s level
from 关ND82兴. We have applied this
correction to the 4s 2 5 p and 6s levels given
here.
S. Johannson and U. Litzén, Phys. Scr. 22,
49 共1980兲, as compiled in 关KS88兴.
S. G. Johansson, U. Litzén, J. Kasten, and
M. Kock, Astrophys. J. 403, L25 共1993兲.
B: The wavelengths of transitions
involving the B I 2s 2 2 p, 2s 2 3s, and 2s2p 2
2
D levels are given separately for the 11B and
10
B isotopes in this reference. Weighted
average wavelengths are given here for these
lines, with the two isotopic wavelengths for
each transition being weighted according to
the relative abundances. Combination of the
measurements of the 2s 2 2 p 2P– 2s2p 2 2D
lines 关JLKK93兴 with the isotopic
ionization-energy shift obtained for the
2s2 p 2 2D term by Edlén et al. 关EOHJ70兴
shows that the isotopically weighted average
ionization energy for each of the 2s 2 2p 2P
ground-configuration levels probably differs
by less than 0.01 cm⫺1 from the ionization
energy of the corresponding level of the
dominant 11B isotope. The values of the two
2s 2 2 p 2P levels given in 关JLKK93兴 共based
on a value 0.000 cm⫺1 for the 2P1/2 level of
each isotope兲 are thus taken as equal to
isotopically
averaged
values.
The
isotopically averaged values of the higher
levels were obtained by using the averaged
wavenumbers of the lines. Any additional
error introduced by this procedure should be
smaller than 0.01 cm⫺1 . It should be noted
that the separations of the two isotopic
components of the lines 共which range from
0.011 to 0.025 Å兲 are large relative to the
uncertainties of the individual measurements
共less than 0.001 Å兲.
Y. N. Joshi and M. Mazzoni, Phys. Lett. A
118, 237 共1986兲.
P. Juncar, J. Pinard, J. Hamond, and A.
Chartier, Metrologia 17, 77 共1981兲.
T. Jaysekharan, M. A. N. Razvi, and G. L.
Bhale, J. Phys. B 33, 3123 共2000兲.
Z. J. Jakubeh and B. Simard, J. Phys. B 33,
1827 共2000兲.
Y: We adopt a weighted average with
关GRTE73兴.
A. S. King, Astrophys. J. 82, 140 共1935兲.
C. C. Kiess, unpublished 共1940兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2148
K51
K53
K57
K58
K59
K62a
K62b
K87
K91
K93
KC59
KDEE97
KE74
KFW02
KG00
KH69
J. E. SANSONETTI AND W. C. MARTIN
C. C. Kiess, J. Res. Natl. Bur. Stand. 共U.S.兲
47, 385 共1951兲.
C. C. Kiess, J. Res. Natl. Bur. Stand. 共U.S.兲
51, 247 共1953兲.
T. A. M. van Kleef, Physica 23, 843 共1957兲.
Ir: We have changed the order of electron
coupling for the 5d 7 6s6 p configuration, as
indicated in 关CFSK74兴.
C. C. Kiess, J. Res. Natl. Bur. Stand. 共U.S.兲
60, 375 共1958兲.
K. G. Kessler, J. Res. Natl. Bur. Stand.
共U.S.兲 63A, 213 共1959兲.
C. C. Kiess, J. Res. Natl. Bur. Stand. 共U.S.兲
66A, 111 共1962兲.
H. Kleiman, J. Opt. Soc. Am. 52, 441
共1962兲.
R. L. Kelly, J. Phys. Chem. Ref. Data 16,
Suppl. 1 共1987兲.
V. A. Komarovskii, Opt. Spectrosc. 共USSR兲
71, 559 共1991兲.
V. Kaufman, J. Res. Natl. Inst. Stand. Tech.
98, 717 共1993兲.
Kr: We give Kr I wavelengths and energy
levels as obtained for the 84Kr isotope
because these values are close to the
center-of-gravity values for a mixture of the
natural isotopic abundances. The values of
the 84Kr I excited levels have here been
increased by 0.0121 cm⫺1 关BHU02兴. For the
Kr I resonance lines 共945–1236 Å兲, we list
Ritz wavelengths obtained from the adjusted
84
Kr I levels. The 84Kr I levels needed for
five of these lines were not included in
关K93兴; we obtained values 共not tabulated兲
for these levels by using adjusted 86Kr level
values and 84Kr– 86Kr isotope shifts as
estimated from related data in 关K93兴.
C. C. Kiess and C. H. Corliss, J. Res. Natl.
Bur. Stand. 共U.S.兲 63A, 1 共1959兲.
S. Köhler, R. Diessenberger, K. Eberhardt,
N. Erdmann, G. Herrmann, G. Huber, J. V.
Kratz, M. Nunnemann, G. Passler, P. M.
Rao, J. Riegel, N. Trautmann, and K. Wendt,
Spectrochim. Acta B 52, 717 共1997兲.
V. Kaufman and B. Edlén, J. Phys. Chem.
Ref. Data 3, 825 共1974兲.
J. Z. Klose, J. R. Fuhr, and W. L. Wiese, J.
Phys. Chem Ref. Data 31, 217 共2002兲.
R. Kling and U. Griesmann, Astrophys. J.
531, 1173 共2000兲.
V. Kaufman and C. J. Humphreys, J. Opt.
Soc. Am. 59, 1614 共1969兲.
Kr: These Kr I wavelengths are Ritz
values from 86Kr I energy levels; no
comparably accurate values have been
determined for either 84Kr or natural Kr. We
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
KK61
KL99
KLLT02
KM72
KM78
KM91a
KM91b
KM93
KM97
KM00
KMVC57
KRA66
KS88
KT96
KW66
have rounded off the original four- or
five-place wavelengths to three places and
most of the original three-place values to
two places. These 86Kr I wavelengths may
still differ from the natural Kr values by a
few units or more in the last decimal place
retained by us.
T. A. M. van Kleef and P. F. A. Klinkenberg,
Physica 27, 83 共1961兲.
H. Karlsson and U. Litzén, Phys. Scr. 60,
321 共1999兲.
G. Kalus, U. Litzén, F. Launay, and W.-U. L.
Tchang-Brillet, Phys. Scr. 65, 46 共2002兲.
V. Kaufman and L. Minnhagen, J. Opt. Soc.
Am. 62, 92 共1972兲.
T. A. M. van Kleef and B. C. Metsch,
Physica 95, 251 共1978兲.
Ir: We have made configuration and/or
term assignments, or omitted such
assignments, on the basis of the calculated
eigenvectors.
V. Kaufman and W. C. Martin, J. Phys.
Chem. Ref. Data 20, 83 共1991兲.
Mg: We have quoted Ritz-calculated
wavelengths for most Mg II lines from this
compilation. These values are much more
accurate than the directly measured
wavelengths in the region below 2000 Å.
V. Kaufman and W. C. Martin, J. Phys.
Chem. Ref. Data 20, 775 共1991兲.
V. Kaufman and W. C. Martin, J. Phys.
Chem. Ref. Data 22, 279 共1993兲.
A. E. Kramida and W. C. Martin, J. Phys.
Chem. Ref. Data 26, 1185 共1997兲.
A. E. Kramida and W. C. Martin,
unpublished compilation 共2000兲.
P. F. A. Klinkenberg, W. F. Meggers, R.
Velasco, and M. A. Catalán, J. Res. Natl.
Bur. Stand. 共U.S.兲 59, 319 共1957兲.
Re: Names for even parity levels adopted
here are based on eigenvector percentages
from 关W78兴. We have assigned sequential
numbers instead of term designations for
those levels having no meaningful names
according to the eigenvectors.
V. Kaufman, L. J. Radziemski, and K. L.
Andrew, J. Opt. Soc. Am. 56, 911 共1966兲.
V. Kaufman and J. Sugar, J. Phys. Chem.
Ref. Data 17, 1679 共1988兲.
G. Kalus and A. Thorne, 5th International
Colloquium on Atomic Spectra and
Oscillator Strengths, eds. W.-U. L.
Tchang-Brillet, J. F. Wyart, and C. J.
Zeippen, 1996, p. 4.
V. Kaufman and J. F. Ward, J. Opt. Soc. Am.
56, 1591 共1966兲.
ATOMIC SPECTROSCOPIC DATA
KW85
KWL97
L49
L64
L70a
L70b
L99
LA71
LB82
LBS99
LBT93
LC68
LLJ94
LLTL01
R. D. Knight and L. Wang, J. Opt. Soc. Am.
B 2, 1084 共1985兲.
Xe: These authors determined the
o
)6s
ionization energy of the Xe I 5p 5 ( 2 P1/2
o
2
⫺1
1/2
level
as
21
637.02(1)
cm
Brandi
关 兴0
et al. 关BVHU01兴 combined this result with
their accurate value for this level with
respect to the ground level to obtain an
improved value for the 136Xe I principal
ionization energy. Using the isotopic shifts
关BVHU01兴, we have adjusted this value
down to the isotopic center-of-gravity
ionization energy for natural Xe.
S. Kroger, J.-F. Wyart, and P. Luc, Phys. Scr.
55, 579 共1997兲.
K. Lidén, Ark. Fys. 1, 229 共1949兲.
D. D. Laun, J. Res. Natl. Bur. Stand. 共U.S.兲
68, 207 共1964兲.
U. Litzén, Phys. Scr. 2, 103 共1970兲.
U. Litzén, Phys. Scr. 1, 251 共1970兲.
U. Litzén, unpublished wave number
determinations 共1999兲, as quoted in 关M03兴.
Ca: The uncertainty of the Ca II 4p 2Po
levels is 0.002 cm⫺1 .
H. Li and K. L. Andrew, J. Opt. Soc. Am. 61,
96 共1971兲.
A. Laguna and H. Beatty, Chem. Phys. Lett.
88, 439 共1982兲.
F: We combined the wave numbers of the
o
o
– 2 P1/2
hfs transitions
two strong F I 2p 5 2P3/2
given in this reference with the more
accurate values for the hfs splittings of the
o
2 o
P3/2 and 2P1/2
levels in 关RHB61兴 and 关H65兴,
respectively, to obtain a value of
404.1407(20) cm⫺1 for the separation of the
o
o
and 2P1/2
hfs centers of gravity of the 2P3/2
levels.
H.-P. Loock, L. M. Beaty, and B. Simard,
Phys. Rev. A 59, 873 共1999兲.
U. Litzén, J. W. Brault, and A. P. Thorne,
Phys. Scr. 47, 628 共1993兲.
D. D. Laun and C. H. Corliss, J. Res. Natl.
Bur. Stand. 共U.S.兲 72, 609 共1968兲.
W: The numerical designations of the
theoretically uninterpreted odd-parity levels
are those used in 关L64兴.
H. Lundberg, U. Litzén, and S. Johansson,
Phys. Scr. 50, 110 共1994兲.
U. Litzén, H. Lundberg, W.-U. L.
Tchang-Brillet, F. Launay, and R. Engleman,
Jr., Phys. Scr. 64, 63 共2001兲.
Pd: The leading eigenvector percentages
given for the 4d 8 5p levels indicate that no
meaningful LS-coupling names exist for
some levels. We have used numerical names
for several such levels.
LP77
LS31
LZJK98
M35
M52
M58
M59
M60a
M60b
M62
M64a
M64b
2149
B. Lindgren and H. P. Palenius, Sol. Phys.
53, 347 共1977兲.
R. J. Lang and R. A. Sawyer, Z. Phys. 71,
453 共1931兲.
In: The wavelength 2079.26 Å tabulated
for the important 5s5 p 3Po2 – 5s6s 3S1 line in
this paper is the vacuum wavelength,
contrary to the column heading.
U. Litzén, T. Zethson, P. Jönsson, J. Kasten,
R. Kling, and F. Launay, Phys. Rev. A 57,
2477 共1998兲.
B: The authors measured two isotopic
components for each B II transition
involving the 2s 2 , 2s2 p, and 2p 2 levels, the
observed 10B/ 11B splittings being in the
range 0.42– 0.89 cm⫺1 . The wavelengths
given here are isotopically weighted
averages. We also give weighted averages
for the corresponding energy levels.
Although we have retained two decimal
places for the levels, the user should keep in
mind the relatively large isotopic splittings.
D. C. Martin, Phys. Rev. 48, 938 共1935兲.
C. E. Moore, Atomic Energy Levels, Natl.
Bur. Stand. 共U.S.兲 Circ. 467, Vol. II 共1952兲;
reprinted as Natl. Stand. Ref. Data Ser., Natl.
Bur. Stand. 共U.S.兲 35 共1971兲.
C. E. Moore, Atomic Energy Levels, Natl.
Bur. Stand. 共U.S.兲 Circ. 467, Vol. III 共1958兲;
reprinted as Natl. Stand. Ref. Data Ser., Natl.
Bur. Stand. 共U.S.兲 35 共1971兲.
Ta: Term designations for some Ta I levels
have here been changed or omitted to
correspond to the eigenvectors given in
关DAGW97兴. Ta I and II levels with no term
designation have been given sequential
numbers for identification in the line list.
W. C. Martin, J. Opt. Soc. Am. 49, 1071
共1959兲.
W. C. Martin, J. Res. Natl. Bur. Stand. 共U.S.兲
64A, 19 共1960兲.
L. Minnhagen, Ark. Fys. 18, 97 共1960兲.
Ar: We have increased Minnhagen’s 1960
value for the Ar II ionization energy by
0.1 cm⫺1 ,
in accordance with his
redetermination of the connection between
the excited levels and the ground level
关M71兴. The uncertainty of the ionization
energy is probably about 1.0 cm⫺1 .
L. Minnhagen, Ark. Fys. 21, 415 共1962兲.
R. McLaughlin, J. Opt. Soc. Am. 54, 965
共1964兲.
L. C. Marquet, Ph. D. thesis, Univ.
California, Berkeley 共1964兲.
Er: The most complete available list of
energy-level classifications for Er I lines is
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2150
M67
M71
M73
M75a
M75b
M75c
M87
M91
M98
M00
M02
M03
J. E. SANSONETTI AND W. C. MARTIN
given in an unpublished report by Spector
and Held 关SH80兴.
W. F. Meggers, J. Res. Natl. Bur. Stand.
共U.S.兲 71A, 396 共1967兲.
L. Minnhagen, J. Opt. Soc. Am. 61, 1257
共1971兲.
L. Minnhagen, J. Opt. Soc. Am. 63, 1185
共1973兲.
Ar: Minnhagen gave values of the Ar I
excited levels with up to four decimal places
to exhibit their relative accuracies; his
estimated uncertainty for the connection of
the excited levels to the 1S0 ground level was
0.05 cm⫺1 . This connection has recently
been determined within an estimated
uncertainty of 0.003 cm⫺1 关VHU99兴. The
resulting correction to the levels given by
Minnhagen with respect to the ground level
is only ⫹0.0053(30) cm⫺1 . We have made
this adjustment to the levels given here and
have also made corresponding small
adjustments for the tabulated Ritz
wavelengths 共867–1067 Å兲. The estimated
uncertainties of most of the five-place
wavelengths are 0.000 03–0.000 04 Å.
C. E. Moore, Natl. Stand. Ref. Data Ser.,
Natl. Bur. Stand. 共U.S.兲 3, Sect. 5 共1975兲.
C. E. Moore, Natl. Stand. Ref. Data Ser.,
Natl. Bur. Stand. 共U.S.兲 3, Sect. 7 共1975兲.
W. C. Martin, unpublished material 共1975兲.
W. C. Martin, Phys. Rev. A 36, 3575 共1987兲.
D. C. Morton, Astrophys J. Suppl. Ser. 77,
119 共1991兲.
W. C. Martin, unpublished material 共1998兲.
D. C. Morton, Astrophys. J. Suppl. Ser. 130,
403 共2000兲.
W. C. Martin, ongoing compilation of data
for He I 共2002兲.
He: This work includes an updating of the
energy-level data in 关M87兴. The uncertainty
of the excited-level system and limit with
respect to the ground level is about
关EUVH97,
BBBL98兴.
0.002 cm⫺1
References for most of the more recent
experimental data are given in 关DM98兴.
Some level separations are known to six or
more decimal places, but have here been
rounded to four places. The values for some
levels are derived from recent theoretical
calculations 关D03兴. The wavelengths are
calculated from the energy levels. The
estimated uncertainty of the wavelengths of
the resonance lines given to five places
共507–591 Å兲 is at most one unit in the fifth
place.
D. C. Morton, Astrophys. J. Suppl. Ser. 149,
205 共2003兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
MC60
MCS58
MCS75
MFT57
MG93
MGGB89
MH42
MH84
MHRS74
MK00a
MK00b
MKM93
MKMD94
W. C. Martin and C. H. Corliss, J. Res. Natl.
Bur. Stand. 共U.S.兲 64A, 443 共1960兲.
W. F. Meggers, M. A. Catalán, and M. Sales,
J. Res. Natl. Bur. Stand. 共U.S.兲 61, 441
共1958兲.
Re: Names for even parity levels adopted
here are based on eigenvector percentages
from 关W77兴.
W. F. Meggers, C. H. Corliss, and B. F.
Scribner, Natl. Bur. Stand. 共U.S.兲, Monogr.
145 共1975兲.
W. F. Meggers, M. Fred, and F. S. Tomkins,
J. Res. Natl. Bur. Stand. 共U.S.兲 58, 297
共1957兲.
Ac: The data pertain to the 227Ac isotope.
The designations for several of the
odd-parity levels of Ac II are taken from
关BW92b兴.
C. E. Moore, Tables of Spectra of Hydrogen,
Carbon, Nitrogen, and Oxygen, J. W.
Gallagher, ed. 共CRC Press, Inc., Boca Raton,
FL, 1993兲.
o
– 2 P1/2 separation of
C: The C II 2 p 2P3/2
⫺1
63.42 cm
from this reference is
0.025 cm⫺1 larger than a more recent
high-accuracy value 关CBS86兴. We have
retained the older value for consistency with
the other C II levels tabulated here, which
have not been re-evaluated.
C. W. Matthews, M. L. Ginter, D. S. Ginter,
and C. M. Brown, J. Opt. Soc. Am. B 6,
1627 共1989兲.
W. F. Meggers and C. J. Humphreys, J.
Res. Natl. Bur. Stand. 共U.S.兲 28, 463
共1942兲.
R. G. Montague and M. F. A. Harrison, J.
Phys. B 17, 2707 共1984兲.
W. C. Martin, L. Hagan, J. Reader, and J.
Sugar, J. Phys. Chem. Ref. Data 3, 771
共1974兲.
P. Mohr and S. Kotochigova, unpublished
calculations 共2000兲.
H: The wavelengths for the Balmer-alpha
and Balmer-beta transitions at 6563 and
4861 Å include only the stronger
components of more extensive fine
structures.
P. Mohr and S. Kotochigova, unpublished
calculations 共2000兲.
He: Several weaker fine-structure
components for the He II multiplet at 4685 Å
have been omitted here.
W. C. Martin, V. Kaufman, and A.
Musgrove, J. Phys. Chem. Ref. Data 22,
1179 共1993兲.
W. C. Martin, V. Kaufman, A. Musgrove,
and G. R. Dalton, unpublished compilation
ATOMIC SPECTROSCOPIC DATA
MKSM92
MM52
MM76
MMHS95
MMMS89
MOW98
MS96
MSB51
MSP69
MT61
MT78
MT84
MV74
MV75
MZ79
of energy-level and wavelength data for Si I
共1994兲.
Si: The energy-level data supersede those
in 关MZ83兴.
W. C. Martin, V. Kaufman, J. Sugar, and A.
Musgrove,
unpublished
preliminary
compilation of the wavelength and
energy-level data for the spectra of chlorine
共1992–1997兲.
Cl: Many of the energy-level data are
available in the NIST Atomic Spectra
Database.
W. F. Meggers and R. J. Murphy, J. Res.
Natl. Bur. Stand. 共U.S.兲 48, 334 共1952兲.
W. F. Meggers and C. E. Moore, Natl. Bur.
Stand. 共U.S.兲, Monogr. 153 共1976兲.
A. Marijnissen, J. J. ter Meulen, P. A.
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2606 共1995兲.
H. Maeda, Y. Mizugai, Y. Matsumoto, A.
Suzuki, and M. Takami, J. Phys. B 22, L511
共1989兲.
M. Miyabe, M. Oba, and I. Wakaida, J. Phys.
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W. C. Martin and J. Sugar, Phys. Rev. A 53,
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W. F. Meggers, B. F. Scribner, and W. R.
Bozman, J. Res. Natl. Bur. Stand. 共U.S.兲 46,
85 共1951兲.
L. Minnhagen, H. Strihed, and B. Petersson,
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W. C. Martin and J. L. Tech, J. Opt. Soc.
Am. 51, 591 共1961兲.
W. F. Meggers and J. L. Tech, J. Res. Natl.
Bur. Stand. 共U.S.兲 83, 13 共1978兲.
Yb: Wyart and Camus 关WC79兴 extended
the energy-level analysis of Yb I. The names
of the odd-parity levels having J⫽1 at
37 414.59 and 38 422.36 cm⫺1 are from their
paper.
W. C. Martin and J. L. Tech, unpublished
preliminary extension and revision of Br II
analysis 共1984兲.
Br: See 关MT61兴.
C. Morillon and J. Vergés, Phys. Scr. 10, 227
共1974兲.
Se: All 4p 3 nl levels from this reference
have been increased by 0.23 cm⫺1 , in
accordance with 关LP77兴.
C. Morillon and J. Vergés, Phys. Scr. 12, 129
共1975兲.
Te: Wavelengths for Te I shorter than 9800
Å are calculated from energy levels given in
this reference.
W. C. Martin and R. Zalubas, J. Phys. Chem.
Ref. Data 8, 817 共1979兲, as modified by
关KM91b兴.
MZ80
MZ81
MZ83
MZH78
MZM85
MZM90
N73
ND81
ND82
NG00
NIJL02
NJK91
NJLT94
NLTH91
NOL73
NRCA00
NZLJ02
O70
OHRW95
2151
W. C. Martin and R. Zalubas, J. Phys. Chem.
Ref. Data 9, 1 共1980兲.
W. C. Martin and R. Zalubas, J. Phys. Chem.
Ref. Data 10, 153 共1981兲.
Na: See 关JPHC81兴 and 关BBLB98兴 for
more recent, higher-accuracy data for Na I.
W. C. Martin and R. Zalubas, J. Phys. Chem.
Ref. Data 12, 323 共1983兲.
W. C. Martin, R. Zalubas, and L. Hagan,
Atomic Energy Levels—The Rare Earth
Elements, Natl. Stand. Ref. Data Ser., Natl.
Bur. Stand. 共U.S.兲 60 共1978兲.
Eu, Ho, Nd, Sm: Wavelengths for which
this reference is given are calculated from
the energy levels.
W. C. Martin, R. Zalubas, and A. Musgrove,
J. Phys. Chem. Ref. Data 14, 751 共1985兲.
W. C. Martin, R. Zalubas, and A. Musgrove,
J. Phys. Chem. Ref. Data 19, 821 共1990兲.
G. Norlén, Phys. Scr. 8, 249 共1973兲.
J. H. M. Neijzen and A. Donszelmann,
Physica 106C, 271 共1981兲.
J. H. M. Neijzen and A. Donszelmann,
Physica 114C, 241 共1982兲.
Ga: The stated uncertainties of the Ga I 5s
2
S level and the ionization energy are 0.007
and 0.010 cm⫺1 , respectively.
G. Nave and U. Griesmann, Phys. Scr. 62,
463 共2000兲.
Dy: Only newly classified lines and newly
found energy levels for Dy I and Dy II are
listed in this paper. Wavelengths and levels
tablulated here were taken from complete
line and level tables provided by the authors.
H. Nilsson, S. Ivarsson, S. Johansson, and H.
Lundberg, Astron. Astrophys. 381, 1090
共2002兲.
A. E. Nilsson, S. Johansson, and R. L.
Kurucz, Phys. Scr. 44, 226 共1991兲.
G. Nave, S. Johansson, R. C. M. Learner, A.
P. Thorne, and J. W. Brault, Astrophys. J.
Suppl. Ser. 94, 221 共1994兲.
G. Nave, R. C. M. Learner, A. P. Thorne, and
C. J. Harris, J. Opt. Soc. Am. B 8, 2028
共1991兲.
G. H. Newsom, S. O’Connor, and R. C. M.
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S. G. Nakhate, M. A. N. Razvi, J. P.
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5191 共2000兲.
H. Nilsson, Z. G. Zhang, H. Lundberg, S.
Johansson, and B. Nordström, Astron.
Astrophys. 382, 368 共2002兲.
A. Ölme, Phys. Scr. 1, 256 共1970兲.
R. Otto, H. Hühnermann, J. Reader, and J.-F.
Wyart, J. Phys. B 28, 3615 共1995兲.
Pm: Tables 1 and 4 of this reference
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2152
OL92
OWLW91
P38
P69
P71
P77
PBFS89
PBQS97
PBT55
PC38
J. E. SANSONETTI AND W. C. MARTIN
comprise the most extensive published data
on energy-level classifications for Pm II
lines. The wavelengths in Table 1 were
apparently derived from the levels by using
an inaccurate formula for the dispersion of
air; the resulting values are longer than the
more accurate values in 关RCWM80兴 by
0.02–0.05 Å.
T. R. O’Brian and J. E. Lawler, Astron.
Astrophys. 255, 420 共1992兲.
T. R. O’Brian, M. E. Wickliffe, J. E. Lawler,
W. Whaling, and J. W. Brault, J. Opt. Soc.
Am. B 8, 1185 共1991兲.
F. Paschen, Ann. Physik 共5兲 32, 148 共1938兲.
In: We have adjusted the values of the
5s5p 2 4P levels to the more accurate 5s 2 5 p
2 o
P ground term fine-structure splitting given
by the measurements in 关DMZ53兴.
H. P. Palenius, Ark. Fys. 39, 15 共1969兲.
F: Palenius’s estimate of the wavelength
uncertainty near 600 Å implies an
in
the
uncertainty
of
1 – 2 cm⫺1
excited-configuration level values and the
ionization limit with respect to the 2p 4 3P
ground-term levels. His value for the 2p 4
3
P1 – 3 P0 fine structure interval differs from
the more accurate measurement in 关BZE98兴
by only 0.36 cm⫺1 . We have adjusted the
values for these two levels to display the
more accurate interval, assuming Palenius’s
value for the 2p 4 3P2 – 3 P1 interval as
somewhat more accurate than his 3P1 – 3 P0
interval. We have not correspondingly
reevaluated the upper levels or Palenius’s
Ritz-principle wavelengths for the resonance
lines 共wavelength less than 608 Å兲 because
the resulting wavelength changes for any of
these lines would be less than 0.001 Å,
which is insignificant relative to the
uncertainties.
W. Persson, Phys. Scr. 3, 133 共1971兲.
B. A. Palmer, Ph. D. thesis, Purdue Univ.,
1977.
M. D. Plimmer, P. E. G. Baird, C. J. Foot, D.
N. Stacey, J. B. Swan, and G. K. Woodgate,
J. Phys. B 22, L241 共1989兲.
P. Palmeri, E. Biémont, P. Quinet, G.
Szawiola, and R. L. Kurucz, Phys. Scr. 55,
586 共1997兲.
V: These authors have recently extended
the energy-level analysis of V I, including
hyperfine structures.
E. K. Plyer, L. R. Blaine, and E. Tidwell, J.
Res. Natl. Bur. Stand. 共U.S.兲 55, 279 共1955兲.
F. Paschen and J. S. Campbell, Ann. Phys.
共5兲 31, 29 共1938兲.
In: Wavelengths of resolved hyperfine
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
PE83
PG90
PKE80
PRUJ98
PT96
PTW98
PVHA85
PW99
PZ01
Q96
components are tabulated for many of the
In II lines in this paper, together with the
corresponding hfs center-of-gravity wave
number for each line. The wavelengths for
such lines quoted here were derived by
converting these center-of-gravity wave
numbers back to air wavelengths using, in
effect, the same 共now superseded兲
air-dispersion formula as Paschen and
Campbell.
B. A. Palmer and R. Engleman, Jr., Los
Alamos Natl. Lab. Report LA-9615 共1983兲.
Th: The accuracy of these data is
comfirmed by their agreement with
optogalvanic measurements 关SW84兴 to
⫾0.0002 Å in the wavelength range 5750–
6900 Å.
R. H. Page and C. S. Gudeman, J. Opt. Soc.
Am. B 7, 1761 共1990兲.
B. A. Palmer, R. A. Keller, and R. Engleman,
Jr., Los Alamos Natl. Lab. Report
LA-8251-MS 共1980兲.
J. C. Pickering, A. J. J. Raassen, P. H. M.
Uylings, and S. Johansson, Astrophys. J.
Suppl. Ser. 117, 261 共1998兲.
J. C. Pickering and A. P. Thorne, Astrophys.
J. Suppl. Ser. 107, 761 共1996兲.
J. C. Pickering, A. P. Thorne, and J. K.
Webb, Mon. Not. R. Astron Soc. 300, 131
共1998兲.
Mg: High-accuracy measurements of Mg I
and Mg II resonant lines 关PTW98兴, quoted
here,
give
improved
values
of
35 051.277(1) cm⫺1 for the Mg I 3s3p 1Po
level
and
35 669.298共2兲
and
35 760.848(2) cm⫺1 for the Mg II 3p 2Po
levels. We have retained the less accurate
values from 关MZ80兴 for these levels for
consistency with the values of other levels in
the tables.
B. H. Post, W. Vassen, W. Hogervorst, M.
Aymar, and O. Robaux, J. Phys. B 18, 187
共1985兲.
Ba: The value for the Ba I ionization
energy quoted here is 0.01 cm⫺1 higher than
the value given in this reference, as
suggested in 关KL99兴 on the basis of an
improved value for the 6s5d 3D1 level.
P. Palmeri and J.-F. Wyart, J. Quant.
Spectrosc. Radiat. Transfer 61, 603 共1999兲.
Tc: This paper reports an extension and
revision of the energy-level analysis and a
calculation of A values for Tc I based on a
theoretical interpretation.
J. C. Pickering and V. Zilio, Eur. Phys. J. D
13, 181 共2001兲.
P. Quinet, Phys. Scr. 54, 483 共1996兲.
ATOMIC SPECTROSCOPIC DATA
QPBM99
R30
R33
R34a
R34b
R37
R56
R58
R68
R69
R75
R98
R02
P. Quinet, P. Palmeri, E. Biémont, M. M.
McCurdy, G. Reiger, E. H. Pinnington, M. E.
Wickliffe, and J. E. Lawler, Mon. Not. R.
Astron. Soc. 307, 934 共1999兲.
E. Rasmussen, Z. Phys. 62, 494 共1930兲.
E. Rasmussen, Z. Phys. 80, 726 共1933兲.
E. Rasmussen, Z. Phys. 86, 24 共1934兲.
E. Rasmussen, Z. Phys. 87, 607 共1934兲.
H. A. Robinson, Phys. Rev. 51, 14 共1937兲.
Li: The tabulated wavelengths for the first
three resonance lines of Li II 共199, 178, and
171 Å兲 were quoted by Robinson from
measurements by B. Edlén.
P. Risberg, Ark. Fys. 10, 583 共1956兲.
Na: See 关JPHC81兴 and 关BBLB98兴 for
more recent, higher-accuracy data for Na I.
Y. B. Rao, Indian J. Phys. 32, 497 共1958兲.
G. Risberg, Ark. Fys. 37, 231 共1968兲.
C. B. Ross, Jr., Ph. D. dissertation, Purdue
Univ., 1969.
Cu: The Cu II data are also given by C. B.
Ross, Los Alamos Report LA-4498 共1970兲.
J. Reader, J. Opt. Soc. Am. 65, 286 共1975兲.
A. N. Ryabtsev, private communication
共1998兲.
B: Ryabtsev has reevaluated the B II levels
using all available data. Since no transition
between singlet and triplet levels has been
observed, he followed Ölme 关O70兴 in fixing
the triplet system relative to the singlets by
assuming that the 2s6g 1G and 3G levels
have the same value relative to the ground
level. The new level values then required a
lowering of the basic 2s2 p 3Po and 2p 2 3P
levels by 0.5 cm⫺1 from their previous
values. We have lowered Ölme’s value for
the B II ionization energy by 0.4 cm⫺1 based
on Ryabtsev’s new values for the 2s5g and
2s6g levels used by Ölme. The uncertainties
of the singlet–triplet connection and of the
ionization energy are both probably of the
order of 1.0 cm⫺1 .
A. N. Ryabtsev, private communication
共2002兲.
B: Ryabtsev obtained a value of
66 928.04(3) cm⫺1 for the 11B I ionization
energy by adjusting the experimental value
of Glab and Falleur 关GF02兴 to a more
accurate value for the 11B I 2s 2 3s level
关JLKK93兴. We quote this adjusted 11B value
as the most accurate estimate of the
isotopically averaged B I ionization energy
共see our note appended to 关JLKK93兴兲. With
an appropriate adjustment, the value
obtained by Edlén et al. 关EOHJ70兴 for the
center-of-gravity ionization energy was
66 928.15(10) cm⫺1 .
RA65
RAKL67
RAVS90
RB78
RCL00
RCWM80
RD67
RE75
RE80
REB95
RG34
RGKP93
RHB61
RK69
RK74
RMBH87
RMW44
RR44
2153
L. J. Radziemski, Jr. and K. L. Andrew, J.
Opt. Soc. Am. 55, 474 共1965兲.
L. J. Radziemski, K. L. Andrew, V.
Kaufman, and U. Litzén, J. Opt. Soc. Am.
57, 336 共1967兲.
P. M. Rao, S. A. Ahmad, A. Venugopalan,
and G. D. Saksena, Z. Phys. D 15, 211
共1990兲.
Sm: Configuration assignments for four
odd-parity Sm II levels have been taken from
this reference.
J. R. Rubbmark and S. A. Borgström, Phys.
Scr. 18, 196 共1978兲.
A. N. Ryabtsev, S. S. Churilov, and U.
Litzén, Phys. Scr. 62, 368 共2000兲.
J. Reader, C. H. Corliss, W. L. Wiese, and G.
A. Martin, Natl. Stand. Ref. Data Ser., Natl.
Bur. Stand. 共U.S.兲 68 共1980兲.
Pm: The Pm II wavelengths in this
reference were taken from 关MSB51兴 and
关DR72a兴. The energy-level classifications for
the Pm II persistent lines given here are from
关DR72a兴 and 关OHRW95兴.
J. Reader and S. P. Davis, J. Res. Natl. Bur.
Stand. 共U.S.兲 71A, 587 共1967兲 and
unpublished material.
J. Reader and G. L. Epstein, J. Opt. Soc. Am.
65, 638 共1975兲.
J. Reader and G. L. Epstein, Natl. Bur. Stand
共U.S.兲, unpublished 共1980兲.
L. J. Radziemski, R. Engleman, Jr., and
J. W. Brault, Phys. Rev. A 52, 4462
共1995兲.
J. E. Ruedy and R. C. Gibbs, Phys. Rev. 46,
880 共1934兲.
H. Rong, S. Grafström, J. Kowalski, G. zu
Pulitz, W. Jastrzebski, and R. Neumann, Z.
Phys. D 25, 337 共1993兲, and references
therein.
H. E. Radford, V. W. Hughes, and V.
Beltran-Lopez, Phys. Rev. 123, 153 共1961兲.
L. J. Radziemski, Jr. and V. Kaufman, J. Opt.
Soc. Am. 59, 424 共1969兲.
Cl: See 关MKSM92兴 for more complete
energy-level data.
L. J. Radziemski, Jr. and V. Kaufman, J. Opt.
Soc. Am. 64, 366 共1974兲.
Cl: See 关MKSM92兴 for more complete
energy-level data.
D. M. Rayner, S. A. Mitchell, O. L. Bourne,
and P. A. Hackett, J. Opt. Soc. Am. B 4, 900
共1987兲.
H. N. Russell, C. E. Moore, and D. W.
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共1944兲.
R. Ramanadham and K. R. Rao, Indian J.
Phys. 18, 317 共1944兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2154
RT76
RW97
RWS76
S38a
S38b
S40
S48
S58
S61a
S61b
S63a
S70
S74
S75
S80
J. E. SANSONETTI AND W. C. MARTIN
R. A. Roig and G. Tondello, J. Phys. B 9,
2373 共1976兲.
B: The quantity ‘‘x’’ represents an
uncertain correction for the B I 2s2 p 2 4P
term. The estimated value of ‘‘x’’ is 0.0
⫾15 cm⫺1 .
M. Rosberg and J.-F. Wyart, Phys. Scr. 55,
690 共1997兲.
Au: The uncertainty of the 5d 10 1S ground
level is 0.06 cm⫺1 with respect to the best
determined excited levels. The estimated
relative uncertainties of the excited Au II
levels given here are about 0.005 cm⫺1
except
for
the
5d 9 6d
level
at
⫺1
116 050.55 cm , which has an uncertainty
of about 0.2 cm⫺1 . The intensities of the
lines above 2000 Å are based on the ‘‘peak
value’’ intensities from this reference, except
that we have increased the intensities 共to
somewhat arbitrary values兲 for three
transitions to metastable lower 5d 9 6s levels
that were clearly affected by self-absorption.
The intensities of most of the lines below
2000 Å are also based roughly on values
estimated by Rosberg and Wyart, but we
have expanded the scale. We have omitted
term names for the two Au II 5d 8 6s 2 levels
designated as 3P2 and 3F2 because the
eigenvectors indicate that no meaningful
single-term names exist for them.
C. B. Ross, D. R. Wood, and P. S. Scholl, J.
Opt. Soc. Am. 66, 36 共1976兲.
F. J. Sullivan, Univ. Pitts. Bull. 35, 1 共1938兲.
A. G. Shenstone, Phil. Trans. R. Soc.
共London兲 237A, 57 共1938兲.
A. G. Shenstone, Phys. Rev. 57, 894 共1940兲.
A. G. Shenstone, Phil. Trans. R. Soc.
共London兲 241A, 297 共1948兲.
F. J. Sancho, Anales Real. Soc. Esp. Fis. y
Quim. 54A, 41 共1958兲.
Rh: We have interchanged Sancho’s
designations for thee Rh II 4d 8 1D2 and 3P2
levels, as indicated by the calculations of
Shadmi 关S61a兴.
Y. Shadmi, Bull. Res. Council Israel 9F, 141
共1961兲.
A. G. Shenstone, Proc. R. Soc. London, Ser.
A 261, 153 共1961兲.
A. G. Shenstone, Proc. R. Soc. London, Ser.
A 276, 293 共1963兲.
A. G. Shenstone, J. Res. Natl. Bur. Stand.
共U.S.兲 74A, 801 共1970兲.
J. Sugar, J. Chem. Phys. 60, 4103 共1974兲.
P. S. Scholl, unpublished material 共1975兲;
data taken from 关RCWM80兴.
N. Svendenius, Phys. Scr. 22, 240 共1980兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
S81
S95
SAV81
SC85
SH80
SK79
SKJ94
SKRR03
SM58
SM88
SM90
SM91
SM93a
SM93b
SM95
SM02
C. J. Sansonetti, dissertation, Purdue
University, 1981.
J. Spyromilio, Mon. Not. R. Astron. Soc.
277, L59 共1995兲.
N: The N II 3P2 – 3 P1 ground-term interval
derived from the wavelength measurements
for the two 3P– 1 D2 transitions in this
reference
is
82.033(2) cm⫺1 ,
not
⫺1
as given by the author. The
82.059 cm
corrected value is in excellent agreement
with the more accurate value of
82.036 09 cm⫺1 关BVEC94兴.
C. J. Sansonetti, K. L. Andrew, and J.
Vergés, J. Opt. Soc. Am. 71, 423 共1981兲.
J. Sugar and C. Corliss, J. Phys. Chem. Ref.
Data 14, Suppl. 2 共1985兲.
o
and
K: We have increased the 3d 2D5/2
2 o
D3/2 levels by 0.020 and 0.016 cm⫺1 ,
respectively, in accordance with the new
values for the 4p 2Po levels 关E99兴.
Ca: We have increased the values of the
two-place Ca II excited levels, as well as the
ionization energy, by 0.01 cm⫺1 in
accordance with the new values of the 4p
2 o
P levels 关L99兴.
N. Spector and S. Held, Israel Atomic
Energy Comm. Report IA-1354-T 共1980兲.
J. Sugar and V. Kaufman, J. Opt. Soc. Am.
69, 141 共1979兲.
B. Simard, P. Kowalczyk, and A. M. James,
Phys. Rev. A 50, 846 共1994兲.
C. J. Sansonetti, F. Kerber, J. Reader, and M.
R. Rosa, to be published 共2003兲.
Cr: The wavelengths from this reference
have estimated uncertainties of 0.002 Å.
A. G. Shenstone and W. F. Meggers, J. Res.
Natl. Bur. Stand. 共U.S.兲 61, 373 共1958兲.
J. Sugar and A. Musgrove, J. Phys. Chem.
Ref. Data 17, 155 共1988兲.
J. Sugar and A. Musgrove, J. Phys. Chem.
Ref. Data 19, 527 共1990兲.
J. Sugar and A. Musgrove, J. Phys. Chem.
Ref. Data 20, 861 共1991兲.
Kr: This compilation gives three-place
values for the Kr II 4 p 4 ( 3 P)5s and 5p
levels as determined for 86Kr 关HP70a兴. These
values have been rounded to two places here.
E. B. Saloman and W. C. Martin,
unpublished material 共1993兲.
J. Sugar and A. Musgrove, J. Phys. Chem
Ref. Data 22, 1213 共1993兲.
J. Sugar and A. Musgrove, J. Phys. Chem.
Ref. Data 24, 1803 共1995兲.
J. E. Sansonetti and W. C. Martin 共this
work兲.
In: Paschen and Campbell observed the
ATOMIC SPECTROSCOPIC DATA
spectrum from 2078 to 9246 Å, but adopted
a value of 43 349 cm⫺1 for the 5s 2
1
S0 – 5s5p 3Po1 separation, as determined
earlier by Lang and Sawyer 关LS31兴. The
value for the 5s 2 1S0 – 5s5p 3Po1 wave
number obtained from Bhatia’s more recent
measurement 关B69兴 of the corresponding
line is 43 351.00 cm⫺1 , in good agreement
with the value 43 350.85 cm⫺1 obtained for
the wave number of this line by Paschen and
Campbell. We have thus adopted a value of
43 350.9 cm⫺1 for the 5s5 p 3Po1 level and
used this value together with measurements
of 5s5p 3Po – 5s6s 3S, 5s5d 3D, 5p 2 3P,
and 5p 2 1D wavelengths 共1607–1977 Å兲
from Bhatia to redetermine the 5s5 p 3Po0 ,
3 o
P2 , and 5s6s 3S1 levels. The Ritz-principle
consistency of six determinations of 5s5p
3 o
P
level separations from Bhatia’s
measurements indicates a wave number
uncertainty of the order of 0.3 cm⫺1 ,
corresponding to a wavelength error of order
0.010 Å at 1800 Å. Our new position for the
5s6s 3S1 level is 4.37 cm⫺1 above the value
in Atomic Energy Levels 关M58兴, which was
taken from 关PC38兴. Since Paschen and
Campbell evaluated the 5s5p 1Po1 level and
all levels above the 5s6s 3S1 level with
respect to the 5s6s 3S1 level, all levels given
to two decimal places by Moore 关M58兴
should be increased by 4.37 cm⫺1 . The
ionization energy is also increased by
4 cm⫺1 . The corrected levels can be used to
obtain Ritz vacuum UV wavelengths for In II
having much greater accuracy than the
measured values of Lang and Sawyer and,
for wavelengths below about 1600 Å, greater
accuracy than those given by Bhatia. Thus,
for example, the new Ritz wavelength of
734.773 Å for the 5s 2 1S0 – 5s8 p 1Po1 line
should be accurate to about 0.002 Å,
whereas the values from Bhatia 关B69兴 and
Lang and Sawyer 关LS31兴 are longer than this
Ritz value by 0.005 and 0.17 Å, respectively.
Sb: Wavelengths are calculated from
energy levels in 关HARV88兴. The relative
intensities are from 关MH42兴, except that we
have increased the intensities for the three
lines below 2000 Å to be more in accord
with the scale used above 2000 Å. Although
we have given the Sb I levels with
LS-coupling designations as assigned by
Hassini et al. 关HARV88兴, their calculations
show that several of the even-parity levels
tabulated here have no meaningful term
names; the average purity in the three
( 3 P)5d ‘‘4P’’ levels, for example, is 32%.
SMC73
SMZ83
SO82
SP49
SPMR72
SPNL01
SR01
SR65
SR73
SRC71
SRSA92
SS04
SSM03
SSR96
ST76
SW84
SZK90
T63
TE62
TW71
UH87
2155
J. Sugar, W. F. Meggers, and P. Camus, J.
Res. Natl. Bur. Stand. 共U.S.兲 77A, 1 共1973兲.
N. Svendenius, C. E. Magnusson, and P. O.
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A. R. Striganov and G. A. Odintsova, Tables
of Spectral Lines of Atoms and Ions
共Energoizdat, Moscow, 1982兲.
A. G. Shenstone and J. T. Pittenger, J. Opt.
Soc. Am. 39, 219 共1949兲.
D. W. Steinhaus, M. V. Phillips, J. B. Moody,
L. J. Radziemski, Jr., K. J. Fisher, and D. R.
Hahn, Los Alamos Sci. Lab. Rep. LA-4944
共1972兲.
C. M. Sikström, H. Pihlemark, U. Litzén, S.
Johansson, Z. S. Li, and H. Lundberg, J.
Phys. B 34, 477 共2001兲.
C. J. Sansonetti and J. Reader, Phys. Scr. 63,
219 共2001兲.
J. Sugar and J. Reader, J. Opt. Soc. Am. B
55, 1286 共1965兲.
J. Sugar and J. Reader, J. Chem. Phys. 59,
2083 共1973兲.
D. W. Steinhaus, L. J. Radziemski, Jr.,
and R. D. Cowan, Natl. Aeronaut. Space
Admin. Spec. Publ. NASA SP-236, 151
共1971兲.
J. E. Sansonetti, J. Reader, C. J. Sansonetti,
and N. Acquista, J. Res. Natl. Inst. Stand.
Tech. 97, 1 共1992兲.
E. B. Saloman and C. J. Sansonetti, J. Phys.
Chem. Ref. Data 33, 1113 共2004兲.
T. Shirai, J. Sugar, A. Musgrove, and J.
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to be submitted for publication in J. Phys.
Chem. Ref. Data, expected publication year
2005.
C. J. Sansonetti, M. L. Salit, and J. Reader,
Appl. Opt. 35, 74 共1996兲.
Hg: Gives wavelengths with uncertainties
of about 0.001 Å for 19 lines 共2536 –5791
Å兲 emitted by Hg pencil-type lamps.
G. Smith and F. Tomkins, Philos. Trans. R.
Soc. London, Ser. A 283, 345 共1976兲.
C. J. Sansonetti and K.-H. Weber, J. Opt.
Soc. Am. B 1, 361 共1984兲.
J. E. Sohl, Y. Zhu, and R. D. Knight, J. Opt.
Soc. Am. B 7, 9 共1990兲.
J. L. Tech, J. Res. Natl. Bur. Stand. 共U.S.兲
67A, 505 共1963兲.
Y. G. Toresson and B. Edlén, Ark. Fys. 23,
117 共1962兲.
Li: The 1s2s 1S energy level has been
lowered by 1.00 cm⫺1 关DM01兴.
J. L. Tech and J. F. Ward, Phys. Rev. Lett.
27, 367 共1971兲.
H. Uehara and K. Horiai, J. Opt. Soc. Am. B
4, 1217 共1987兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2156
VHU99
VVF96
VW78
W71
W78
WA63
WA68
WACB95
WB88
WBBF01
WBJ95
WC78
WC79
WCJP93
WFD96
WHGC76
J. E. SANSONETTI AND W. C. MARTIN
I. Velchev, W. Hogervorst, and W. Ubachs, J.
Phys. B 32, L511 共1999兲.
Ar: These authors determined the wave
number corresponding to the Ar I resonance
transition at 1048 Å separately for each of
the three isotopes. We have used the
isotopically
weighted
value
95 399.8329(30) cm⫺1 for this separation.
D. A. Verner, E. M. Verner, and G. J.
Ferland, At. Data Nucl. Data Tables 64, 1
共1996兲.
J. Verges and J.-F. Wyart, Phys. Scr. 17, 495
共1978兲.
Lu: The values of two levels and definite
names for three other levels are taken from
this extension of the Lu I analysis.
C. M. Wu, thesis, University of British
Columbia, 1971.
J. F. Wyart, Phys. Scr. 18, 87 共1978兲.
P. G. Wilkinson and K. L. Andrew, J. Opt.
Soc. Am. 53, 710 共1963兲.
D. Wood and K. L. Andrew, J. Opt. Soc. Am.
58, 818 共1968兲.
W. Whaling, W. H. C. Anderson, M. T.
Carle, J. W. Brault, and H. A. Zarem, J.
Quant. Spectrosc. Radiat. Transfer 53, 1
共1995兲.
Ar: The uncertainty of these Ar II levels
with respect to the 3s 2 3p 5 2Po ground-term
levels is about 0.04 cm⫺1 关M71兴.
W. Whaling and J. W. Brault, Phys. Scr. 38,
707 共1988兲.
G. M. Wahlgren, T. Brage, J. C. Brandt, J.
Fleming, S. Johansson, D. S. Leckrone, C.
R. Proffitt, J. Reader, and C. J. Sansonetti,
Astrophys. J. 551, 520 共2001兲.
J.-F. Wyart, J. Blaise, and Y. N. Joshi, Phys.
Scr. 52, 535 共1995兲.
E. F. Worden and J. G. Conway, At. Data
Nucl. Data Tables 22, 329 共1978兲.
J.-F. Wyart and P. Camus, Phys. Scr. 20, 43
共1979兲.
E. F. Worden, L. R. Carlson, S. A. Johnson,
J. A. Paisner, and R. W. Solarz, J. Opt. Soc.
Am. B 10, 1998 共1993兲.
W. L. Wiese, J. R. Fuhr, and T. M. Deters, J.
Phys. Chem. Ref. Data, Monogr. 7 共1996兲.
E. F. Worden, E. K. Hulet, R. G. Gutmacher,
and J. G. Conway, At. Data Nucl. Data
Tables 18, 459 共1976兲.
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
WJLG97
WL97
WLGC74
WLN00
WRSH74
WS87
WSG66
WSL94
WSM69
WSPC78
YG94
YKH85
YS91
Z79
ZLLZ00
G. M. Wahlgren, S. G. Johansson, U. Litzén,
N. D. Gibson, J. C. Cooper, J. E. Lawler, D.
S. Leckrone, and R. Engleman, Jr.,
Astrophys. J. 475, 380 共1997兲.
M. E. Wickliffe and J. E. Lawler, J. Opt. Soc.
Am. B 14, 737 共1997兲.
E. F. Worden, R. W. Lougheed, R. G.
Gutmacher, and J. G. Conway, J. Opt. Soc.
Am. 64, 77 共1974兲.
M. E. Wickliffe, J. E. Lawler, and G. Nave,
J. Quant. Spectrosc. Radiat. Transfer 66, 363
共2000兲.
D. R. Wood, C. B. Ross, P. S. Scholl, and M.
Hoke, J. Opt. Soc. Am. 64, 1159 共1974兲.
Pb: Pb II wavelengths shorter than 1200 Å
have been calculated from the energy levels
given in this paper.
K.-H. Weber and C. J. Sansonetti, Phys. Rev.
A 35, 4650 共1987兲.
W. L. Wiese, M. W. Smith, and B. M.
Glennon, Natl. Stand. Ref. Data Ser., Natl.
Bur. Stand. 共U.S.兲 4 共1966兲.
H: The transition probabilities given for
the persistent lines at 4340, 12 818, and
18 751 Å are ‘‘average’’ values as defined
and tabulated 共Table A兲 in this reference.
M. E. Wickliffe, S. Salih, and J. E. Lawler, J.
Quant. Spectrosc. Radiat. Transfer 51, 545
共1994兲.
W. L. Wiese, M. W. Smith, and B. M. Miles,
Natl. Stand. Ref. Data Ser., Natl. Bur. Stand.
共U.S.兲 22 共1969兲.
E. F. Worden, R. W. Solarz, J. A. Paisner,
and J. G. Conway, J. Opt. Soc. Am. B 68, 52
共1978兲.
S. Yoon and W. L. Glab, J. Phys. B 27, 1433
共1994兲.
C. Yamada, H. Kanamori, and E. Hiroita, J.
Chem. Phys. 83, 552 共1985兲.
Ar: These authors determined the Ar II
3s 2 3 p 5 2Po ground-term level separation
within a stated uncertainty of 0.0007 cm⫺1 .
S. Yamamoto and S. Saito, Astrophys. J. 370,
L103 共1991兲.
R. Zalubas, unpublished 共1979兲.
Z. Zhiguo, Z. S. Li, H. Lundberg, K. Y.
Zhang, Z. W. Dai, J. Zhankui, and S.
Svanberg, J. Phys. B 33, 521 共2000兲.
ATOMIC SPECTROSCOPIC DATA
2157
4. Finding List
Finding List
Intensity
30
300
1000
15
20
30
50
100
300
150
90
90
50
60
30
1000
500
10
90
60
90
60
150
200
150
120
400
700
1000
800
200
300
250
200
150
200
10
120
90
1000
500
150
P
P
c
c
c
c
c
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
300
900 P
10
15
10
1000
2
3
4
5
7
Wavelength 共Å兲
Vacuum
171.575
178.014
199.280
231.4541
232.5842
234.3472
237.3307
243.0266
256.3166
256.3177
300.15
300.20
301.32
301.44
302.45
303.7804
303.7858
320.293
352.9549
354.9620
361.4321
362.4544
372.08
376.38
405.8538
407.1377
429.918
430.041
430.177
441.81
445.0393
446.2552
446.5902
447.8146
454.6540
455.2730
456.2728
456.3485
456.8962
460.7284
462.3908
465.08
469.50
476.03
484.602
487.2272
490.6495
490.7013
495.14
505.50035
505.68433
505.91252
506.20034
506.57057
Spectrum
Li II
Li II
Li II
He II
He II
He II
He II
He II
He II
He II
Na II
Na II
Na II
Na II
Na II
He II
He II
He I
Ne II
Ne II
Ne II
Ne II
Na II
Na II
Ne II
Ne II
O II
O II
O II
K II
Ne II
Ne II
Ne II
Ne II
Ne II
Ne II
Ne II
Ne II
Ne II
Ne II
Ne II
K II
K II
K II
F II
Ar II
Ar II
Ar II
K II
He I
He I
He I
He I
He I
Finding List—Continued
Ref
R37
R37
R37
GM65
GM65
GM65
GM65
GM65
MK00b
MK00b
W71
W71
W71
W71
W71
MK00b
MK00b
TW71
P71
P71
P71
P71
W71
W71
P71
P71
MKM93
MKM93
MKM93
E31
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
P71
E31
E31
E31
P69
M71
M71
M71
E31
M02
M02
M02
M02
M02
Intensity
10
15
20
25
35
2
50
10
100
3
400
800
1000
600
800
700
500
10
70
25
25
25
10
25
10
1000
30
30
30
30
50
70
100
25
70
30
70
1000
130
10
900
800
1000
700
800
800
900
10
1000
170
170
130
200
200
20
15
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
507.05802
507.71809
508.64338
509.99829
512.09856
513.266
515.61684
519.3270
522.21309
530.173
537.02992
537.8319
538.2636
538.318
539.0855
539.5489
539.8544
542.9124
543.2033
547.4606
556.8170
573.3619
576.7364
580.2632
583.4371
584.33436
587.1792
587.2127
589.419
589.9114
591.41207
591.8306
595.9200
597.7001
598.7056
598.8897
600.0365
600.77
602.7263
602.8584
605.669
606.288
606.804
606.923
607.472
607.93
608.062
612.3716
612.62
615.6283
618.6716
619.1023
626.8232
629.7388
639.36
643.878
He I
He I
He I
He I
He I
Rb II
He I
Ar II
He I
Rb II
He I
O II
O II
O II
O II
O II
O II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
He I
Ne I
Ne I
Rb II
Ne I
He I
Ne I
Ne I
Ar II
Ne I
Ne I
Ne I
K II
Ne I
Ar II
F II
F II
F II
F II
F II
K II
F II
Ar II
K II
Ne I
Ne I
Ne I
Ne I
Ne I
Cs II
Rb II
Ref
M02
M02
M02
M02
M02
R75
M02
M71
M02
R75
M02
MKM93
MKM93
MKM93
MKM93
MKM93
MKM93
M71
M71
M71
M71
M71
M71
M71
M71
M02
SS04
SS04
R75
SS04
M02
SS04
SS04
M71
SS04
SS04
SS04
E31
SS04
M71
P69
P69
P69
P69
P69
E31
P69
M71
E31
SS04
SS04
SS04
SS04
SS04
RE75
R75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2158
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
200 P
600 P
1000 P
150 P
10
70
300 P
1000 P
25
10
10
70
600 P
1000 P
80
180
500 r
30 P
70 P
70
150
800 P
500 P
1000 P
150
20
25
1000 P
70
120
110 P
400 P
70
25
70
30
20
70
20
200 P
70
30
600
600
600
250
250
40
20
120
100
60
30
40
150 P
50
150 P
120
70
300 r
Wavelength 共Å兲
Spectrum
644.635
644.837
645.179
661.8690
664.5623
666.0109
670.9455
671.8513
676.2425
677.9518
679.2184
679.4006
687.0526
687.346
692.70
693.947
696.30
697.049
711.187
718.0899
718.14
718.5036
718.5663
723.3606
725.5485
729.40
730.9297
735.8962
740.2692
740.41
741.456
743.7195
744.9248
745.3223
761.18
763.98
766.20
771.03
773.69
775.967
782.10
783.72
787.580
788.740
793.342
796.664
796.682
802.28
802.85896
803.07
806.4710
806.86887
807.21842
807.6529
808.76
809.92660
813.84
816.23193
816.46391
817.18
N II
N II
N II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
Ar II
C II
C II
NI
B II
Tl II
Rb II
Rb II
Ar II
Cs II
O II
O II
Ar II
Ar II
Kr II
Ar II
Ne I
Ar II
Xe II
Rb II
Ne I
Ar II
Ar II
Kr II
Kr II
Kr II
Kr II
Kr II
N II
Kr II
Kr II
Cl II
Cl II
Cl II
O II
O II
Te II
Ar I
Xe II
Ar I
Ar I
Ar I
Ar I
Cs II
Ar I
Cs II
Ar I
Ar I
Tl II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
E83
E83
E83
M71
M71
M71
M71
M71
M71
M71
M71
M71
KE74
KE74
M75a
O70
ES36
R75
R75
M71
RE75
MKM93
MKM93
M71
M71
MSP69
M71
SS04
M71
B36
R75
SS04
M71
M71
MSP69
MSP69
MSP69
MSP69
MSP69
E83
MSP69
MSP69
RK74
RK74
RK74
MKM93
MKM93
HM64
M73
B36
M73
M73
M73
M73
RE75
M73
RE75
M73
M73
ES36
Intensity
20
80
120
120
140
20
800
250
400
150
500
100
700
900
800
100
30
600
20
180
20
150
180
100
180
200
500
500
70
120
300
400
1000
400
130
70
20
500
150
500
400
400
400
150
300
750
150
500
400
300
70
800
250
500
50
12
50
60
200
700
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P,d
P,d
P
Wavelength 共Å兲
Spectrum
818.15
820.12352
825.34592
826.36484
829.529
830.38
832.62
832.7587
833.3302
834.3918
834.4655
835.00210
839.297
839.599
841.414
842.80506
844.06
851.691
864.82
866.79997
868.87
869.75411
876.05767
879.84
879.94656
880.80
882.543
882.681
884.14
885.54
886.30
886.943
889.25
890.567
891.01
892.001
893.0847
893.678
894.31013
896.65
896.759
901.073
901.27
903.6235
903.9616
904.1416
904.4801
906.01
906.885
910.484
911.39
912.69
912.735
914.213
915.613
915.819
915.963
916.019
916.708
917.43
Kr II
Ar I
Ar I
Ar I
Ga II
Kr II
Se II
O II
O II
Ar I
O II
Ar I
Cl II
Cl II
Cl II
Ar I
Kr II
Cl II
Kr II
Ar I
Kr II
Ar I
Ar I
I II
Ar I
Xe II
B II
B II
Kr II
Xe II
Kr II
Cu II
Br II
Cu II
Kr II
Si II
Hg II
Cu II
Ar I
Br II
Cu II
Cu II
Cs II
C II
C II
C II
C II
Br II
S II
S II
Kr II
Se II
S II
Cu II
N II
Hg II
N II
N II
N II
Kr II
Ref
MSP69
M73
M73
M73
IL85
MSP69
G62
MKM93
MKM93
M73
MKM93
M73
RK74
RK74
RK74
M73
MSP69
RK74
MSP69
M73
MSP69
M73
M73
MC60
M73
B36
O70
O70
MSP69
B36
MSP69
R69
MT84
R69
MSP69
RA65
SR01
R69
M73
MT84
R69
R69
RE75
KE74
KE74
KE74
KE74
MT84
KM93
KM93
MSP69
G62
KM93
R69
E83
SR01
E83
E83
E83
MSP69
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
300
400
200
15
400
20
300
400
400
400
80
400
250
300
30
20
400
10
100
400
80
50
30
500
80
1000
800
500
5
25
80
700
25
6
100
250
400
100
250
100
500
50
8
70
60
150
150
500
800
800
250
1000
10
200
15
300
80
14
12
150
P
P
P
P
P
P
P
P
c
P
c
P
P
c
P
P
c
P
P
P
Wavelength 共Å兲
Spectrum
919.7810
922.019
925.87
926.2256
926.66
930.7482
932.0537
932.939
935.058
935.086
935.40
935.898
937.421
937.684
937.8034
942.630
943.335
944.73
945.4414
945.525
946.5443
949.7430
951.056
951.870
953.4041
954.826
955.546
958.525
958.70
962.711
963.3745
964.97
969.142
972.11
972.5367
972.77
973.895
976.217
976.68
977.743
984.99
988.773
992.36
992.684
993.8825
1001.0606
1003.5504
1012.13
1013.40
1013.99
1014.449
1015.53
1017.88
1018.58
1025.27
1025.7222
1025.762
1025.9681
1026.1134
1030.0232
Ar II
Cu II
Xe II
HI
Cs II
HI
Ar II
Cu II
Cu II
Cu II
Xe II
Cu II
S II
S II
HI
Hg II
Cu II
Li II
Kr I
Cu II
Kr I
HI
Kr I
FI
Kr I
FI
FI
FI
He II
Hg II
Kr I
Kr II
Hg II
He II
HI
Xe II
FI
FI
Xe II
FI
Br II
OI
He II
Si II
Ne II
Kr I
Kr I
Br II
Se II
Se II
S II
Br II
Li II
I II
He II
HI
OI
Mg II
Mg II
Kr I
2159
Finding List—Continued
Ref
M71
R69
B36
MK00a
RE75
MK00a
M71
R69
R69
R69
B36
R69
KM93
KM93
MK00a
SR01
R69
SO82
K93
R69
K93
MK00a
K93
L49
K93
L49
L49
L49
GM65
SR01
K93
MSP69
SR01
GM65
MK00a
B36
L49
L49
B36
L49
MT84
M75b
GM65
RA65
P71
K93
K93
MT84
G62
G62
KM93
MT84
SO82
MC60
GM65
MK00a
M75b
KM91a
KM91a
K93
Intensity
150
1000
500
250
400
500
500
250
50
400
400
20
400
500
500
1000
300
1000
1000
400
400
400
800
400
40
200
400
20
400
700
400
100
500
300
70
1000
700
500
700
150
600
40
600
500
500
200
25
60
30
300
15
100
400
250
500
1000
120
600
200
200
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P,d
c
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
1032.44
1033.56
1034.66
1036.3367
1036.470
1036.98
1037.0182
1037.68
1039.230
1039.348
1039.582
1039.6315
1041.31
1044.519
1044.744
1048.21987
1048.27
1048.94
1049.65
1051.92
1054.690
1056.955
1057.41
1059.096
1059.51
1060.619
1060.634
1062.7802
1063.005
1063.831
1064.71
1066.34
1066.65980
1067.945
1068.6488
1071.036
1071.767
1071.84
1074.48
1075.21
1075.230
1077.66
1079.080
1081.875
1082.073
1083.86
1083.994
1084.580
1084.94
1085.51
1085.550
1085.710
1100.43
1105.00
1106.74
1106.9931
1111.16
1112.4006
1113.708
1119.133
Xe II
Se II
I II
C II
Cu II
Br II
C II
Xe II
OI
Cu II
Cu II
Hg II
Xe II
Cu II
Cu II
Ar I
Xe II
Br II
Se II
Xe II
Cu II
Cu II
Se II
Cu II
Te II
Pb II
Cu II
Hg II
Cu II
Cl II
Br II
I II
Ar I
Cl II
Ne II
Cl II
Cl II
Br II
Xe II
I II
Cl II
Te II
Cl II
B II
B II
Xe II
N II
N II
He II
Ge II
N II
N II
Xe II
I II
Ge II
Ag II
I II
Ag II
Ga II
Ga II
Ref
B36
G62
MC60
KE74
R69
MT84
KE74
B36
M75b
R69
R69
SR01
B36
R69
R69
VHU99
B36
MT84
G62
B36
R69
R69
G62
R69
HM64
WRSH74
R69
SR01
R69
RK74
MT84
MC60
M73
RK74
P71
RK74
RK74
MT84
B36
MC60
RK74
HM64
RK74
O70
O70
B36
E83
E83
GM65
S63a
E83
E83
B36
MC60
S63a
KLLT01
MC60
KLLT01
IL85
IL85
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2160
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
Wavelength 共Å兲
Spectrum
500 P
200
200
300
100
90
100
30
90
90
500 P
800
200
200
500 P
600 P
500 r
30
300 P
1000 P
10
30
80
90
50 P
60 P
250
500 P
80
150
500
500
30
250 P
700 P
60
800 P
200 P
300 P
500 P
300
25 P
1000 P
300*
300*
400
100
700 P
60
800 P
700 P
1000 P
400
50
70
250
1000 P
400
700 P
300 P
1120.46
1121.325
1125.25
1130.760
1131.50
1131.7224
1131.8490
1131.88
1134.165
1134.415
1139.80
1141.97
1143.039
1158.47
1160.56
1162.1700
1162.55
1164.4184
1164.8671
1166.48
1166.63
1166.8635
1169.63
1169.7477
1174.34
1175.79
1175.84
1178.65
1178.9614
1179.293
1181.19
1181.65
1182.3552
1183.05
1183.4003
1186.2203
1187.34
1188.73
1190.4160
1190.85
1191.26
1192.0376
1192.24
1193.0088
1193.0308
1193.2402
1193.2644
1193.2898
1193.4484
1194.5004
1195.8092
1196.4051
1197.188
1198.092
1198.7745
1198.88
1199.550
1200.22
1200.223
1200.710
Ge II
Pb II
I II
Ga II
I II
Ne II
Ne II
Li II
NI
NI
I II
Se II
Be II
Xe II
I II
Pd II
Tl II
Pt II
Kr I
I II
Li II
Pt II
Xe II
Pt II
Te II
Te II
I II
I II
Pt II
Cl I
Ge II
Ge II
Pt II
Xe II
Pd II
Pt II
I II
Ge II
Si II
I II
Ge II
Xe I
Se II
CI
CI
CI
CI
Si II
Pt II
Si II
Ag II
Pd II
Be II
Li II
Pt II
I II
NI
I II
NI
NI
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
S63a
WRSH74
MC60
IL85
MC60
P71
P71
SO82
M75a
M75a
MC60
G62
J61a
B36
MC60
LLTL01
ES36
SRSA92
K93
MC60
SO82
SRSA92
B36
SRSA92
HM64
HM64
MC60
MC60
SRSA92
RK69
S63a
S63a
SRSA92
B36
LLTL01
SRSA92
MC60
S63a
KE74
MC60
S63a
BVHU01
G62
J66
J66
KE74
KE74
KE74
SRSA92
KE74
KLLT01
LLTL01
J61a
HM59
SRSA92
MC60
M75a
MC60
M75a
M75a
Intensity
800 P
40
800
600
35
50 c
1000 P
500 P
800
700 P
110
90
1000 P
40
600
600 P
600
70
40
100
90
600
500
100
40
1000 P
600
1000 P
500 P
700 P
20
90
25 P
20 P
400 P
800
500
1000 P
250 P
200 P
900
150
100
200
25 P
70
400 P
130
10
40
900 P
800
40
1000 P
500 P
200
500 P
1000 P
40
1000 P
Wavelength 共Å兲
Spectrum
1203.9645
1208.54
1211.17
1214.5242
1215.09
1215.17
1215.66824
1215.67364
1218.10
1218.6219
1219.4931
1220.165
1220.89
1220.98
1223.721
1224.592
1225.2684
1228.746
1229.0134
1229.388
1229.8367
1229.901
1230.160
1232.43
1232.8739
1234.06
1235.1957
1235.8378
1237.059
1237.0677
1237.29
1238.8499
1239.9253
1240.3946
1241.045
1241.31
1242.926
1243.08
1243.179
1244.76
1245.67
1247.554
1248.426
1248.6069
1250.2091
1250.433
1250.578
1251.164
1253.32
1253.62
1253.805
1258.58
1259.51
1259.518
1260.4223
1261.5520
1261.905
1263.77
1264.5677
1264.7379
Pd II
Te II
As II
Pd II
He II
He II
HI
HI
As II
Pd II
Pt II
Cr II
I II
Te II
Sn II
Au II
Pd II
Si II
Pt II
Si II
Ne II
Au II
B II
Br I
Pt II
I II
Pd II
Kr I
Ge II
Pd II
Li II
Pt II
Mg II
Mg II
Bi II
As II
Sn II
As II
NI
Xe II
As II
Cr II
Si II
Pt II
Xe I
Si II
S II
Si II
Li II
Te II
S II
As II
II
S II
Si II
CI
Ge II
As II
Pt II
Si II
Ref
LLTL01
HM64
LA71
LLTL01
GM65
GM65
MK00a
MK00a
LA71
LLTL01
SRSA92
SKRR03
MC60
HM64
B64
RW97
LLTL01
S61b
SRSA92
S61b
P71
RW97
O70
T63
SRSA92
MC60
LLTL01
K93
KE74
LLTL01
SO82
SRSA92
KM91a
KM91a
WBBF01
LA71
B64
LA71
M75a
B36
LA71
SKRR03
S61b
SRSA92
BVHU01
S61b
KM93
S61b
SO82
HM64
KM93
LA71
KC59
KM93
KE74
KE74
KE74
LA71
SRSA92
KE74
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
800
800
40
40
800
400
800
200
1000
800
700
30
300
700
40
70
30
30
1000
30
100
130
1000
50
40
40
700
700
300
500
100
200
40
1000
40
800
800
50
800
40
9
200
100
800
80
150
300
1000
1000
1000
40
70
500
30
800
70
400
800
40
600
P
P
P
P
P
P
P
P
P
P
P
r
P
P
P,r
P
P
h
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
1266.34
1267.59
1270.52
1271.7939
1274.938
1277.2452
1277.2824
1277.5131
1277.5497
1280.3330
1280.99
1283.6978
1283.715
1287.54
1289.40
1289.9515
1290.0131
1290.0131
1290.880
1292.7998
1295.5878
1300.34
1302.168
1302.4578
1302.98
1303.1187
1304.858
1305.70
1306.029
1307.50
1309.2766
1310.700
1313.95
1316.576
1317.54
1320.0229
1321.644
1324.92
1327.378
1327.4314
1328.374
1329.5775
1329.6005
1333.15
1334.5323
1335.7077
1335.726
1336.52
1341.55
1347.240
1348.8300
1350.057
1351.657
1352.9768
1354.955
1355.10
1355.616
1355.93
1357.97
1358.009
As II
As II
Te II
Pt II
Sb II
CI
CI
CI
CI
CI
As II
Pt II
Bi II
As II
II
Pt II
Pt II
Pt II
Sn II
Pt II
Xe I
II
OI
Pt II
II
Pt II
OI
As II
OI
Tl II
Si II
P II
II
Sn II
II
Pd II
Tl II
Te II
Sb II
Pt II
Au I
CI
CI
As II
C II
C II
Cl I
I II
As II
Cl I
Pt II
Si II
Cl I
Pt II
Sb II
II
Au II
As II
II
Sb II
2161
Finding List—Continued
Ref
LA71
LA71
HM64
SRSA92
AJK89
KE74
KE74
KE74
KE74
KE74
LA71
SRSA92
WBBF01
LA71
KC59
SRSA92
SRSA92
SRSA92
B64
SRSA92
BVHU01
KC59
M75b
SRSA92
KC59
SRSA92
M75b
LA71
M75b
ES36
KE74
SMZ83
KC59
B64
KC59
LLTL01
JKBL96
HM64
AJK89
SRSA92
BG78
KE74
KE74
LA71
KE74
KE74
RK69
MC60
LA71
RK69
SRSA92
S61b
RK69
SRSA92
AJK89
KC59
RW97
LA71
KC59
AJK89
Intensity
200
70
40
400
1000
40
30
500
700
30
600
15
800
15
150
20
1000
120
30
800
50
50
900
1000
800
120
500
100
50
150
800
1000
200
500
500
40
120
800
250
500
800
1000
150
200
50
600
9
90
1000
90
60
1000
110
1000
90
80
800
600
600
500
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
1358.773
1360.97
1361.11
1362.326
1362.463
1363.24
1363.3059
1363.447
1363.6892
1364.1171
1365.5430
1367.257
1367.7039
1367.708
1367.951
1369.423
1369.77
1373.116
1373.1724
1373.65
1374.69
1374.80
1374.8481
1375.07
1375.78
1378.9572
1379.528
1382.0460
1383.23
1384.60
1384.656
1387.565
1388.435
1389.693
1389.957
1390.75
1392.588
1394.64
1396.112
1396.527
1400.31
1400.440
1401.514
1403.9006
1404.68
1407.784
1408.451
1411.94
1414.401
1418.3779
1420.900
1425.030
1425.49
1426.208
1428.5822
1429.5248
1431.323
1431.865
1432.056
1433.004
Cu II
II
II
Au II
B II
Te II
Pt II
Cl I
Pd II
Pt II
Pd II
Mg II
Pd II
Mg II
Cu II
Mg II
As II
Cl I
Pt II
As II
Na II
Te II
Pd II
As II
As II
Pt II
Cl I
Pt II
II
Br I
Sb II
Sb II
SI
Cl I
Cl I
II
SI
As II
SI
Cl I
As II
Sn II
SI
Pt II
Na II
Sb II
Au I
NI
Ga II
Ne II
Li II
SI
II
Cr II
Ne II
Pt II
Cr II
Cr II
Cr II
Cr II
Ref
R69
KC59
KC59
RW97
LZJK98
HM64
SRSA92
RK69
LLTL01
SRSA92
LLTL01
KM91a
LLTL01
KM91a
R69
KM91a
LA71
RK69
SRSA92
LA71
W71
HM64
LLTL01
LA71
LA71
SRSA92
RK69
SRSA92
KC59
T63
AJK89
AJK89
KM93
RK69
RK69
KC59
KM93
LA71
KM93
RK69
LA71
B64
KM93
SRSA92
W71
AJK89
BG78
M75a
IL85
P71
DM01
KM93
KC59
SKRR03
P71
SRSA92
SKRR03
SKRR03
SKRR03
SKRR03
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2162
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
600
200
1000
600
400
350
90
800
400
250
70
40
300
P
P
P
P
P
P
P
P
P
70
30
30
500
70
70
130
50
40
40
60
1000
1000
60
20
25
20
9
150
30
700
500
400
700
500
25
250
120
70
15
30
6
150
200
100
800
200
140
110
40
70
30
600
600
1000
800
P
P
P
P
P
P
P
P
P,c
Wavelength 共Å兲
Spectrum
1433.280
1433.310
1433.906
1434.808
1435.207
1435.582
1436.0813
1436.447
1436.810
1436.968
1446.26
1447.8030
1448.428
1451.56
1453.18
1454.2866
1454.2866
1455.091
1457.39
1457.47
1457.98
1459.15
1461.0786
1462.6591
1469.6123
1473.995
1474.997
1475.6306
1476.000
1478.004
1480.880
1481.764
1482.8256
1482.890
1483.039
1486.547
1486.954
1488.45
1488.637
1491.9735
1492.625
1492.820
1492.89
1492.931
1492.973
1493.036
1494.675
1494.7256
1498.1132
1498.549
1499.3707
1505.2462
1506.2923
1506.41
1507.04
1507.6288
1509.2920
1512.269
1512.298
1512.412
SI
SI
Pb II
Cr II
Cr II
Cr II
Ne II
Sb II
Bi II
SI
II
Pt II
Cr II
Rn I
II
Pt II
Pt II
Bi II
II
II
II
II
Pt II
Pt II
Xe I
SI
Sn II
Pt II
Mg II
Mg II
Mg II
Au I
Pt II
Mg II
SI
Au II
Bi II
Br I
Cu II
Pt II
NI
NI
II
Li II
Li II
Li II
NI
Pt II
Pt II
Sb II
Pt II
Pt II
Pt II
Na II
II
Pt II
Pt II
Be II
Pb II
Be II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
KM93
KM93
KT96
SKRR03
SKRR03
SKRR03
P71
AJK89
WBBF01
KM93
KC59
SRSA92
SKRR03
R30
KC59
SRSA92
SRSA92
WBBF01
KC59
KC59
KC59
KC59
SRSA92
SRSA92
BVHU01
KM93
B64
SRSA92
KM91a
KM91a
KM91a
BG78
SRSA92
KM91a
KM93
RW97
WBBF01
T63
R69
SRSA92
M75a
M75a
KC59
HM59
HM59
HM59
M75a
SRSA92
SRSA92
AJK89
SRSA92
SRSA92
SRSA92
W71
KC59
SRSA92
SRSA92
J61a
KT96
J61a
Intensity
800
200
70
9
200
400
400
30
800
150
900
900
150
80
60
400
80
400
300
100
800
130
80
300
400
800
50
300
500
60
130
30
40
110
200
30
40
200
500
200
600
40
40
500
800
30
200
30
400
40
200
400
900
250
500
80
800
90
300
20
r
P
P
P
P
P
P
P
P
l
P
P
P
P
r
P
P
P
P
Wavelength 共Å兲
Spectrum
1513.255
1514.26
1514.68
1515.63
1518.05
1519.837
1520.549
1520.7414
1524.367
1524.5715
1524.7295
1524.7295
1526.70698
1528.2831
1530.1969
1531.74
1532.530
1533.139
1533.4318
1534.9063
1535.309
1535.917
1536.410
1536.745
1538.037
1539.830
1540.5040
1540.65
1541.703
1541.8337
1542.297
1542.7098
1546.8248
1552.3268
1554.9285
1558.3479
1559.3893
1560.309
1560.682
1560.709
1561.438
1561.5450
1561.5450
1561.58
1565.501
1568.9021
1571.58
1573.1802
1573.69
1573.8180
1574.3059
1574.84
1576.099
1576.39
1576.855
1579.4357
1581.353
1581.3980
1582.31
1586.340
Sb II
Cd II
II
Ag I
II
Cu II
Bi II
Pt II
Sb II
Pt II
Pt II
Pt II
Si II
Pt II
Pt II
Br I
P II
Bi II
Si II
Pt II
Ga II
P II
P II
Bi II
Bi II
Al II
Pt II
Br I
Cu II
Pt II
P II
Pt II
Pt II
Pt II
Pt II
Pt II
Pt II
CI
CI
CI
CI
Pt II
Pt II
Tl II
Sb II
Pt II
Cd II
Pt II
Bi II
Pt II
Pt II
Br I
Sb II
Br I
Ge II
Pt II
Sb II
Pt II
Br I
In II
Ref
AJK89
SP49
KC59
S40
KC59
R69
WBBF01
SRSA92
AJK89
SRSA92
SRSA92
SRSA92
GK00
SRSA92
SRSA92
T63
SMZ83
WBBF01
KE74
SRSA92
IL85
SMZ83
SMZ83
WBBF01
WBBF01
KM91b
SRSA92
T63
R69
SRSA92
SMZ83
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
SRSA92
KE74
KE74
KE74
KE74
SRSA92
SRSA92
ES36
AJK89
SRSA92
SP49
SRSA92
WBBF01
SRSA92
SRSA92
T63
AJK89
T63
KE74
SRSA92
AJK89
SRSA92
T63
SM02
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
20
40
40
600
400
70
40
40
70
70
9
11
1000
1000
50
400
400
50
70
400
80
90
700
500
1000
300
9
700
400
1000
100
100
80
1000
120
400
25
400
120
50
7
25
180
25
15
8
300
14
250
1000
5
140
15
30
6
500
400
1000
400
400
P
P
P
l
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
1587.158
1587.7205
1589.3735
1591.76
1593.556
1593.58
1594.0344
1594.2611
1594.5655
1594.9493
1604.0102
1604.12
1604.45
1606.952
1608.41
1609.69
1611.358
1613.15
1617.60
1621.426
1621.6590
1622.8806
1623.597
1623.790
1624.023
1624.175
1624.335
1624.376
1624.47
1628.94
1629.441
1629.9477
1631.0903
1633.40
1634.2337
1634.72
1636.1647
1637.88
1640.3321
1640.3447
1640.3750
1640.3914
1640.4742
1640.4897
1640.5326
1644.4634
1644.4958
1646.674
1649.858
1649.9373
1651.52
1651.991
1653.077
1653.132
1653.213
1656.267
1656.928
1657.008
1657.379
1657.907
Au I
Pt II
Pt II
Bi II
Cu II
II
Pt II
Pt II
Si I
Si I
Pt I
Rb II
Rh II
Sb II
Te II
Bi II
Bi II
Te II
II
Cu II
Pt II
Si I
B II
B II
B II
B II
Au I
B II
Rh II
Rh II
Si I
Si I
Pt II
Br I
Pt II
Rh II
Pt I
Rh II
He II
He II
He II
He II
He II
He II
He II
Pt I
Ag II
Au I
Ca II
Hg II
Ag I
Ca II
Li II
Li II
Li II
CI
CI
CI
CI
CI
2163
Finding List—Continued
Ref
BG78
SRSA92
SRSA92
WBBF01
R69
KC59
SRSA92
SRSA92
RAKL67
RAKL67
SRSA92
R75
S58
AJK89
HM64
WBBF01
WBBF01
HM64
KC59
R69
SRSA92
RAKL67
LZJK98
LZJK98
LZJK98
LZJK98
BG78
LZJK98
S58
S58
KRA66
RAKL67
SRSA92
T63
SRSA92
S58
SRSA92
S58
MK00b
MK00b
MK00b
MK00b
MK00b
MK00b
MK00b
SRSA92
KLLT01
BG78
ER56
SR01
S40
ER56
HM59
HM59
HM59
KE74
KE74
KE74
KE74
KE74
Intensity
Wavelength 共Å兲
Spectrum
500 P
50
100 P
400
9
900 P
300
500
200
170
1000 P
500
150
800 P
200
200
20
1000 P
40
120
500
300
2
50
50
800 P
200
7
200
250
30
20 P
200 P
2
80
14 P,w
40
7
80 r
800 P
500
900 P
150
300
500
900 P
600 P
50
40
90
14
50
600
150 P
200 P
10
150
3
80
40
1658.121
1659.4860
1661.478
1665.3513
1665.755
1666.688
1666.850
1667.272
1669.2312
1669.876
1670.7886
1671.553
1672.738
1674.591
1675.2052
1676.152
1677.8443
1679.695
1681.661
1681.6840
1682.127
1682.8353
1683.412
1684.5867
1684.5867
1687.530
1688.3553
1690.7825
1696.2065
1697.9409
1698.4958
1699.339
1702.07
1707.061
1707.0710
1711.1
1713.8364
1714.4801
1716.784
1719.440
1721.244
1721.271
1723.1314
1723.6119
1724.952
1724.984
1726.802
1727.6799
1734.852
1735.8642
1737.1732
1737.628
1740.475
1741.547
1742.729
1744.4305
1745.252
1747.794
1750.043
1750.663
CI
Pt II
Be I
Ag II
Au I
SI
BI
BI
Pt II
Cr II
Al II
Pb II
Cr II
PI
Si I
Cr II
Pt I
PI
Li II
Ne II
Pb II
Ag II
Mg I
Pt II
Pt II
SI
Ne II
Pt I
Si I
Si I
Pt II
Au I
II
Mg I
Pt II
In I
Pt II
Pt I
Ge I
Al II
Al II
Al II
Pt II
Ag II
Al II
Al II
Pb II
Pt II
Mg II
Pt II
Pt I
Mg II
Au II
Ni II
NI
Pt I
NI
Mg I
Ge I
Mg II
Ref
KE74
SRSA92
KM97
KLLT01
BG78
KM93
BTG74
BTG74
SRSA92
SKRR03
GK00
KT96
SKRR03
S80
RAKL67
SKRR03
SRSA92
S80
HM59
P71
KT96
KLLT01
KM91a
SRSA92
SRSA92
KM93
P71
SRSA92
RAKL67
RAKL67
SRSA92
BG78
KC59
KM91a
SRSA92
G54
SRSA92
SRSA92
KE74
KM91b
KM91b
KM91b
SRSA92
KLLT01
KM91b
KM91b
KT96
SRSA92
KM91a
SRSA92
SRSA92
KM91a
RW97
S70
M75a
SRSA92
M75a
KM91a
KE74
KM91a
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2164
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
Wavelength 共Å兲
Spectrum
500 P
180
50
120
120
50
14 P,w
60
180
30
500
700 P
14
50
300
25
50
120
150
400
50
300
80
1000 P
200
40
50
800 P
600 P
20
250
150 P
800 P
600
80
30
P
25
40
600
700 P
700 P
300 P,r
300
400
40
70
20
50
1000 P
30
300
20
800 P
250
400 P,r
700
40
300
15
1751.827
1752.585
1753.474
1753.8286
1753.8286
1755.332
1757.3
1760.50
1760.747
1762.899
1763.869
1763.952
1764.5948
1765.636
1765.815
1766.0328
1766.385
1767.1612
1767.457
1767.731
1769.140
1770.9223
1774.176
1774.951
1775.0160
1776.5571
1776.57
1777.05
1777.0866
1777.2783
1781.8617
1782.76
1782.838
1783.200
1785.046
1785.8803
1786.07
1786.6480
1787.19
1787.406
1787.656
1791.842
1792.827
1795.28
1796.669
1798.41
1799.09
1802.9398
1807.09
1807.311
1808.01288
1811.201
1812.8819
1813.878
1814.0794
1814.776
1814.964
1816.9290
1817.843
1817.8736
CI
Cr II
Mg II
Pt II
Pt II
Li II
In I
Rb II
Cr II
Al I
Al II
Al II
Pt I
Al I
Al II
Pt II
Al I
Pt II
Cr II
Al II
Al I
Si I
Ge I
PI
Pt II
Pt I
Na II
Bi II
Pt II
Pt I
Pt II
II
PI
Au II
Ge I
Pt II
Rn I
Pt I
Na II
Bi II
PI
Bi II
Tl II
Se I
Pb II
Na II
II
Pt I
Na II
SI
Si II
Sn II
Pt I
Ga II
Si I
Tl II
Sb II
Si II
BI
Pt I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
KE74
SKRR03
KM91a
SRSA92
SRSA92
HM59
G54
R75
SKRR03
KM91b
KM91b
KM91b
SRSA92
KM91b
KM91b
SRSA92
KM91b
SRSA92
SKRR03
KM91b
KM91b
RAKL67
KE74
S80
SRSA92
SRSA92
W71
WBBF01
SRSA92
SRSA92
SRSA92
KC59
S80
RW97
KE74
SRSA92
R30
SRSA92
W71
WBBF01
S80
WBBF01
JKBL96
RG34
KT96
W71
KC59
SRSA92
W71
KM93
GK00
B64
SRSA92
IL85
RAKL67
JKBL96
AJK89
KE74
BTG74
SRSA92
Intensity
500
900
1000
500
700
8
800
13
800
1000
5
600
1000
25
40
40
80
200
30
80
250
1
80
400
80
500
200
200
900
200
25
200
300
200
250
1000
13
400
250
80
40
9
40
300
500
700
600
1
400
200
140
1000
80
90
30
400
120
200
600
70
P
P
P
P
P
P
P
P
h
h
P
P
P
P
P
P
P
r
P
P,r
r
P
Wavelength 共Å兲
Spectrum
1818.348
1820.343
1822.052
1822.155
1823.728
1825.3262
1825.894
1826.1377
1826.245
1826.400
1827.934
1828.588
1830.38
1833.3875
1835.0745
1835.22
1836.5075
1836.5102
1838.8246
1839.5258
1840.061
1840.50
1841.328
1841.4490
1842.410
1842.820
1843.7700
1844.45
1845.199
1845.5203
1845.7517
1846.1118
1847.4737
1848.1504
1848.7480
1849.499
1849.6831
1850.6719
1852.4717
1853.134
1853.17
1853.4523
1853.4523
1855.20
1857.296
1858.026
1858.886
1859.16
1859.393
1860.086
1860.330
1862.311
1867.1302
1870.4100
1871.1038
1871.154
1874.256
1874.8423
1875.564
1879.1031
BI
SI
Pb II
Te I
Bi II
Pt I
BI
Pt I
SI
BI
Mg I
Al II
II
Pt II
Pt II
Na II
Pt II
Si I
Pt II
Pt II
Ca II
Cs II
Ge I
Si I
Ge I
B II
Si I
II
Ga II
Si I
Pt I
Si I
Si I
Si I
Si I
Hg I
Pt I
Si I
Si I
Ge I
Na II
Pt I
Pt II
Se I
Te I
Al II
PI
Cs II
PI
Ge I
Sn I
Al II
Pt II
Pt II
Pt II
Sb I
Ge I
Si I
Ru II
Pt II
Ref
BTG74
KM93
KT96
MV75
WBBF01
SRSA92
EL01
SRSA92
KM93
EL01
KM91a
KM91b
KC59
SRSA92
SRSA92
W71
SRSA92
RAKL67
SRSA92
SRSA92
ER56
S81
KE74
RAKL67
KE74
LZJK98
RAKL67
KC59
IL85
RAKL67
SRSA92
RAKL67
RAKL67
RAKL67
RAKL67
WA63
SRSA92
RAKL67
RAKL67
KE74
W71
SRSA92
SRSA92
RG34
MV75
KM91b
S80
S81
S80
KE74
B64
KM91b
SRSA92
SRSA92
SRSA92
SM02
KE74
RAKL67
CHR88a
SRSA92
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
9
700
90
200
600
1
30
600
100
140
100
700
30
30
40
400
30
300
200
400
1000
15
600
200
200
800
400
400
100
8
500
250
120
300
7
300
40
250
40
200
300
1000
50
1
6
100
400
500
200
500
250
250
130
20
1000
150
80
100
40
300
P
P
P,r
P
P
P
P
r
P,r
P
P
P
r
P
r
P
P
P
P,r
P
P
P
P
l
P
c
r
Wavelength 共Å兲
Spectrum
1879.829
1881.121
1881.91
1882.568
1883.0587
1883.93
1885.8171
1888.043
1888.1064
1889.5226
1889.7120
1890.43
1895.0088
1897.5769
1898.1722
1898.55
1899.0445
1899.881
1900.286
1901.3377
1902.341
1903.2186
1903.221
1904.702
1907.4940
1908.617
1911.7092
1913.79
1914.698
1915.10
1916.0818
1916.816
1917.592
1919.19
1921.250
1922.23
1928.4320
1929.2449
1929.6829
1929.826
1930.0345
1930.906
1934.3690
1935.19
1936.217
1937.4245
1937.59
1938.008
1938.8269
1938.891
1939.043
1939.505
1939.8110
1940.0319
1942.273
1944.4617
1944.731
1945.4521
1949.9102
1950.393
Au I
Tl II
Na II
Sb I
Pt II
Cs II
Pt II
Ru II
Ne II
Pt II
Ne II
As I
Pt II
Pt II
Pt II
Se I
Pt II
Sn II
SI
Si I
Bi II
Pt I
Ru II
Ge I
Ne II
Tl II
Pt II
Se I
SI
Mn II
Ne II
Ru II
Ge I
Se I
Mn II
Cd II
Pt II
Pt II
Pt II
Ge I
Ne II
CI
Pt I
Cs II
In II
Pt I
As I
Ge II
Ne II
Ge II
Ru II
Ru II
Pt II
Pt I
Hg II
Pt II
Ge I
Ne II
Pt II
Sb I
2165
Finding List—Continued
Ref
BG78
JKBL96
W71
SM02
SRSA92
S81
SRSA92
JJLL94
P71
SRSA92
P71
HA85
SRSA92
SRSA92
SRSA92
RG34
SRSA92
B64
KM93
RAKL67
WBBF01
SRSA92
JJLL94
KE74
P71
JKBL96
SRSA92
RG34
KM93
IV64
P71
JJLL94
KE74
RG34
IV64
SP49
SRSA92
SRSA92
SRSA92
KE74
P71
KE74
SRSA92
S81
B69
SRSA92
HA85
KE74
P71
KE74
JJLL94
JJLL94
SRSA92
SRSA92
SR01
SRSA92
KE74
P71
SRSA92
SM02
Intensity
Wavelength 共Å兲
Spectrum
1000 P
300 P
30
80
250 P
600 P
200
900 P
11
50 c
6P
13
140
80
30
200 P,r
800 P,c
15
11 P
600
400 P
50
400 P
25
300 P
300 P
600
300 P
40
500 P
9
10
120 h
120 P
1000 P
15
900 P
700
80
500
8
300
500 P
150 P
200
11
400 P
60 c
200 r
500 P
1951.051
1954.706
1954.7436
1955.115
1960.049
1960.894
1962.013
1962.140
1963.1429
1964.59
1966.711
1969.6807
1970.769
1970.880
1971.5374
1972.62
1973.1340
1973.794
1977.359
1977.524
1977.5978
1978.8444
1979.2056
1979.7647
1979.956
1980.6185
1982.907
1983.2330
1983.7486
1986.3640
1987.7868
1987.841
1987.849
1988.267
1988.9937
1989.1056
1989.394
1990.531
1990.5751
1990.863
1991.5830
1994.3173
1994.839
1995.111
1995.43
1995.8991
1996.056
1998.01
1998.887
1999.511
Air
1999.698
2000.792
2001.45
2001.712
2002.028
2003.35
2003.53
2003.73
2003.849
W II
Bi I
Pt II
Ge I
Bi I
Se I
Ge I
W II
Pt I
Be I
In II
Pt I
Co I
Ge I
Pt I
As I
Re II
Hg II
In II
W II
Si I
Pt II
Si I
Pt I
Cu II
Si I
W II
Si I
Pt II
Si I
Pt I
Hg II
Ge I
Ge I
Si I
Pt I
W II
Al II
Pt II
W II
Pt I
Ag II
Te I
Se I
Cd II
Pt I
Mn I
Be I
Ge I
Mn I
EKM00
WBBF01
SRSA92
KE74
WBBF01
LP77
KE74
EKM00
SRSA92
KM97
B69
SRSA92
PT96
KE74
SRSA92
HA85
WJLG97
SR01
B69
EKM00
RAKL67
SRSA92
RAKL67
SRSA92
R69
RAKL67
EKM00
RAKL67
SRSA92
RAKL67
SRSA92
SR01
KE74
KE74
RAKL67
SRSA92
EKM00
KM91b
SRSA92
EKM00
SRSA92
KLLT01
MV75
LP77
SP49
SRSA92
CMG64
KM97
KE74
CMG64
Cu II
Au II
Os I
W II
Te I
As I
Re I
Os I
Mn I
R69
RW97
MCS75
EKM00
MV75
HA85
MCS75
MCS75
CMG64
150
150
300
400
1000
200
500
400
700
P
P
P
P,r
P
P
Ref
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2166
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
300
80
5
140
800
300
600
250
600
80
1000
700
250
200
500
300
1000
700
1000
1000
9
250
250
200
500
500
1000
80
2
500
20
1000
500
1000
900
20
30
200
900
300
900
600
150
7
200
250
150
500
30
600
150
900
600
250
150
900
400
500
30
60
r
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
r
P
P,r
P,r
P
P
P
P
Wavelength 共Å兲
Spectrum
2004.81
2007.009
2007.56
2007.7572
2008.095
2009.982
2010.15
2010.236
2010.65
2011.29
2012.00
2012.78
2014.238
2014.9330
2015.109
2017.87
2018.14
2019.068
2020.26
2020.314
2020.5434
2021.149
2021.38
2022.016
2022.35
2022.76
2025.4845
2025.560
2025.824
2026.088
2026.860
2028.18
2028.23
2029.3423
2029.995
2030.6456
2032.4256
2032.432
2033.0102
2033.477
2033.57
2034.44
2035.043
2035.7985
2035.854
2036.4666
2037.127
2038.452
2039.792
2039.842
2041.5751
2041.712
2043.770
2043.802
2044.587
2045.36
2045.973
2049.08
2049.1689
2049.3915
Os I
Ne II
Tl I
Pt II
W II
W II
Os I
W II
Ir I
Ge I
Au I
Hf II
W II
Pt II
Mo II
Re I
Os I
Ge I
Os
Mo II
Pt I
Bi I
Au I
Pb I
Ir I
Os I
Zn II
Ne II
Mg I
W II
Hg II
Hf II
Os I
Nb II
W II
Pt I
Pt I
PI
Nb II
PI
Ir I
Os I
W II
Pt I
Cu II
Pt II
Cu II
Mo II
Sb I
Se I
Pt II
Ge I
Ge I
Cu II
Au II
Os I
Mo II
Re I
Pt II
Pt I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
MCS75
P71
C52
SRSA92
EKM00
EKM00
MCS75
EKM00
MCS75
AM59
MCS75
MCS75
EKM00
SRSA92
SPNL01
MCS75
MCS75
AM59
MCS75
SPNL01
SRSA92
WBBF01
MCS75
WA68
MCS75
MCS75
GL00
P71
KM91a
EKM00
SR01
MCS75
MCS75
RCL00
EKM00
SRSA92
SRSA92
S80
RCL00
S80
MCS75
MCS75
EKM00
SRSA92
R69
SRSA92
R69
SPNL01
SM02
LP77
SRSA92
AM59
AM59
R69
RW97
MCS75
SPNL01
MCS75
SRSA92
SRSA92
Intensity
Wavelength 共Å兲
Spectrum
Ref
60 P,r
300
400
400 P
200 P
150
100
1000 P
50
100
80 h
600 P
300*
300*
300
9
20
700 P
25 P
300 P
400
1000 P
400 P
15
400 P
300 r
500 P
140
200
200
250
1000 P
20
400 P,r
1000 P,r
20
400 h
9
500 P
8
8
200
11
20
30
80 P
600 P
80
140
110
200
250
250
14 P
600 P
600 P
500 P
250 P
120 P
400 P
2049.577
2049.636
2052.22
2052.828
2053.284
2054.461
2054.734
2055.59
2056.012
2057.0265
2057.238
2058.1323
2058.69
2058.78
2060.64
2060.7621
2061.162
2061.54
2061.63
2061.634
2061.69
2062.0011
2062.779
2062.7943
2064.2266
2065.215
2065.46
2065.573
2066.364
2066.646
2067.186
2067.21
2067.5105
2068.344
2068.656
2068.92
2068.937
2069.844
2070.67
2070.9443
2070.9443
2071.208
2071.50
2072.016
2072.701
2074.70
2074.784
2075.4004
2075.590
2075.95
2076.43
2076.95
2078.09
2078.608
2079.118
2079.120
2079.97
2081.172
2081.681
2082.077
Sb I
W II
Ir I
Hg II
Pb I
Ge I
Sb II
Cr II
Be I
Pt II
Ge I
Si I
Os I
Os I
Ir I
Pt I
Ag I
Cr II
II
Bi I
Os I
Zn II
Se I
Pt I
Zn II
Ge I
Cr II
W II
BI
BI
BI
Os II
Pt I
Sb I
Ge I
Rb II
Bi II
Ag I
Os II
Pt I
Pt I
W II
Rb II
Si II
Si II
Re I
Se I
Pt II
W II
Rb II
Ru I
Os I
Os
In II
W II
W II
Os I
Te I
Mo II
Au II
SM02
EKM00
MCS75
SR01
WA68
AM59
AJK89
K51
KM97
SRSA92
AM59
KRA66
MCS75
MCS75
MCS75
SRSA92
PZ01
K51
KC59
WBBF01
MCS75
GL00
LP77
SRSA92
GL00
AM59
K51
EKM00
GV72,GM62
GV72,GM62
GV72,GM62
MCS75
SRSA92
SM02
AM59
R75
WBBF01
PZ01
MCS75
SRSA92
SRSA92
EKM00
R75
S61b
S61b
MCS75
LP77
SRSA92
EKM00
R75
K59
MCS75
MCS75
SM02
EKM00
EKM00
MCS75
MV75
SPNL01
RW97
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
100
200
250
50
150
200
200
150
200
1000
400
100
140
100
60
500
200
11
200
1000
200
60
60
800
100
800
700
400
200
140
120
200
200
200
20
150
1000
200
140
70
150
50
10
10
200
70
30
30
40
90
90
40
50
600
60
8
200
80
500
150
P
P
P
P
P
P
P
P
P
P,r
P
P
r
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2082.54
2083.22
2083.78
2084.5960
2085.466
2085.59
2085.74
2086.021
2088.204
2088.82
2088.889
2089.03
2089.156
2089.21
2089.52
2089.570
2090.22
2090.29
2090.48
2090.771
2091.590
2092.159
2092.50
2092.63
2093.11
2094.258
2094.264
2094.751
2096.106
2096.18
2096.248
2097.12
2097.4478
2097.60
2098.424
2098.602
2099.9273
2100.63
2100.675
2100.84
2101.54
2101.5979
2101.6839
2101.6839
2102.1661
2103.3449
2103.7804
2103.7804
2104.29
2105.824
2106.187
2108.02
2109.22
2109.4384
2109.585
2109.6631
2110.217
2110.323
2110.685
2112.68
Os I
Ir I
Ru I
Pt I
Ne II
Re I
Ir I
Ge I
W II
Ir I
BI
Os I
W II
Os I
Mo II
BI
Ru I
Rb II
WI
Ga II
Sn I
Mn I
Mo II
Ir I
Mo II
Ge I
Al II
W II
Ne II
Hf II
Ne II
Re I
Pt II
Os I
Sb I
W II
Zn II
Os I
W II
Mo II
WI
Pt II
Pt I
Pt I
Zn II
Pt I
Pt II
Pt II
Mo II
Ge I
W II
Mo II
Re I
Nb II
Mn I
Pt I
Bi I
W II
Au II
Ir I
2167
Finding List—Continued
Ref
MCS75
MCS75
K59
SRSA92
P71
MCS75
MCS75
AM59
EKM00
MCS75
JLKK93
MCS75
EKM00
MCS75
MCS75
JLKK93
K59
R75
MCS75
IL85
B64
CMG64
MCS75
MCS75
MCS75
AM59
KM91b
EKM00
P71
MCS75
P71
MCS75
SRSA92
MCS75
SM02
EKM00
GL00
MCS75
EKM00
MCS75
MCS75
SRSA92
SRSA92
SRSA92
GL00
SRSA92
SRSA92
SRSA92
MCS75
AM59
EKM00
MCS75
MCS75
RCL00
CMG64
SRSA92
WBBF01
EKM00
RW97
MCS75
Intensity
300
60
140
70
150
130
250
150
70
500
11
300
150
800
80
250
25
90
60
500
120
7
200
600
400
200
1000
600
40
500
250
700
300
130
900
1000
40
600
120
200
400
80
150
300
80
600
30
150
50
300
90
150
70
50
40
500
40
14
80
20
P,r
P
P
P
P
P
P
P
P
P,r
P
P
u
P
P,r
P,r
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2113.8250
2115.5823
2116.67
2117.66
2117.96
2118.874
2119.79
2121.576
2123.84
2125.2164
2125.25
2126.5498
2126.74
2126.81
2127.4231
2127.94
2128.5878
2128.6340
2130.7079
2131.1832
2133.600
2135.1631
2135.465
2135.981
2136.182
2137.11
2138.5735
2139.04
2139.698
2140.13
2142.74
2142.822
2143.83
2144.2123
2144.2458
2144.408
2144.841
2146.87
2147.260
2148.22
2149.145
2149.97
2150.54
2150.62
2150.844
2152.68
2152.84
2152.940
2153.558
2154.080
2154.59
2155.81
2156.67
2157.796
2157.84
2158.05
2158.53
2159.864
2161.00
2161.60
Ag II
Pt II
Yb II
Os I
Os I
W II
Os
W II
Os I
Nb II
Rb II
Nb II
Yb II
Ir II
Pt II
Ir I
Pt I
Pt I
Pt II
Nb II
Bi I
Pt I
PI
Cu II
PI
Os I
Zn I
Re II
Sb I
Ta II
Re II
Te I
Rb II
Pt I
Pt II
Cd II
Sb I
Ta II
Te I
Ir I
PI
Os
Ir I
Ta II
Sn II
Ir II
Sr II
PI
W II
PI
Os I
Ir I
Re I
W II
Os I
Ir I
Os I
Te I
Os
Yb II
Ref
KLLT01
SRSA92
M67
MCS75
MCS75
EKM00
MCS75
EKM00
MCS75
RCL00
R75
RCL00
M67
KM78
SRSA92
MCS75
SRSA92
SRSA92
SRSA92
RCL00
WBBF01
SRSA92
S80
R69
S80
MCS75
GL00
MCS75
SM02
MCS75
MCS75
MV75
R75
SRSA92
SRSA92
SP49
SM02
MCS75
MV75
MCS75
S80
MCS75
MCS75
MCS75
B64
KM78
MCS75
S80
EKM00
S80
MCS75
MCS75
MCS75
EKM00
MCS75
MCS75
MCS75
MV75
MCS75
M67
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2168
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
Wavelength 共Å兲
Spectrum
800 P
120
600 P
250
130 P
20
150 P
30 P
90
110
40
90 P
300
1000 P
150 P,r
100
70
300 P
200
50 P,c
60 P
250
250
600 P,r
60
300
30
150
150 P
100 P,r
500
130
11
150 P
500
60
130
30
400 P
50 P
600 P
300
500
200
100
200
500 P
600 P
200
200
500
110 P
30
1000
90 P,h
600 P
2162.25
2162.88
2164.188
2165.01
2165.09
2165.2108
2165.553
2165.96
2166.316
2166.90
2167.75
2167.94
2169.096
2169.42
2170.005
2170.855
2171.65
2174.666
2174.6853
2174.986
2175.103
2175.147
2175.24
2175.818
2176.21
2178.03
2178.0808
2178.17
2178.94
2179.190
2179.410
2180.473
2180.5042
2181.72
2182.71
2182.90
2184.605
2184.68
2185.504
2185.71
2186.930
2187.43
2189.630
2190.00
2190.3216
2190.38
2192.090
2192.268
2193.20
2193.605
2193.88
2194.39
2194.528
2194.557
2195.54
2196.03
2197.787
2198.714
2199.346
2199.58
At I
Ir I
Se I
Ta II
Cu I
Pt I
Ni II
Sr II
W II
Os I
Os I
Re I
Ni II
Ir II
Pb I
Sb II
Os I
Ni II
Pt I
Be I
Be I
Ni II
Ir I
Sb I
Re I
Ta II
Fe I
Ir I
Cu I
Sb I
Cu II
Ni II
Pt I
Cu I
Ta II
WI
Ni II
Os I
Ni II
Yb II
Bi II
Ir II
Cu II
K II
Pt II
Ir II
Ni II
Cu II
Ta II
Co II
Ta II
Os II
W II
Cd II
Lu II
Ta II
Ca II
Ge I
Sn I
Cu I
130 P,r
200 P
150
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
M64a
MCS75
LP77
MCS75
S48
SRSA92
S70
MCS75
EKM00
MCS75
MCS75
MCS75
S70
MCS75
WA68
AJK89
MCS75
S70
SRSA92
KM97
KM97
S70
MCS75
SM02
MCS75
MCS75
NJLT94
MCS75
S48
SM02
R69
S70
SRSA92
S48
MCS75
MCS75
S70
MCS75
S70
M67
DLW02
MCS75
R69
D26
SRSA92
MCS75
S70
R69
MCS75
PRUJ98
MCS75
MCS75
EKM00
SP49
MCS75
MCS75
ER56
AM59
B64
S48
Intensity
600
100
30
40
500
80
500
800
700
200
400
150
120
11
40
300
600*
600*
500
5
60
500
300
20
400
1000
40
150
15
1000
500
110
400
500
80
130
30
13
150
40
20
120
200
30
150
120
200
250
600
400
40
40
12
15
600
600
40
600
400
P
P
P
P
P
P
P
P,r
P
P,d
P
r
P
P
h
P,c
P
P
P
P
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2199.67
2201.409
2202.2230
2202.4664
2203.534
2204.483
2204.96
2205.548
2206.715
2207.14
2207.978
2208.09
2208.430
2208.611
2208.806
2209.5043
2209.660
2210.03
2210.19
2210.268
2210.71
2210.82
2210.894
2211.744
2213.855
2214.031
2214.2749
2214.58
2214.58
2215.630
2216.482
2216.669
2217.08
2218.057
2218.108
2220.37
2220.402
2221.837
2222.6134
2222.957
2224.46
2224.711
2225.0094
2225.70
2226.42
2227.78
2228.203
2228.915
2230.08
2230.602
2231.5907
2232.9725
2234.61
2234.9262
2235.44
2239.48
2240.8965
2241.2288
2242.618
2242.69
Ta II
Ni II
Pt I
Pt II
Pb II
W II
Ir II
Ni II
Ni II
Ta II
Si I
Ir II
Sb I
Ca II
Mn I
Pt II
Sn I
Ta II
Ta II
Cu II
Tl I
Hf II
Si I
Si I
Mn I
Bi II
Re II
Re I
Cu I
Te I
Ni II
Si I
Rb II
Si I
Cu II
Ir I
Ni II
Mn I
Pt I
Ni II
Yb II
Hg II
Pt II
Cu I
Re I
Cu I
Bi I
Au II
Cu I
Bi I
Pd II
Pt II
Os I
Pt I
Re I
Ta II
Pt II
Pt II
Cu II
Ir II
Ref
MCS75
S70
SRSA92
SRSA92
WRSH74
EKM00
KM78
S70
S70
MCS75
RA65
MCS75
SM02
ER56
CMG64
SRSA92
B64
MCS75
MCS75
R69
C52
MCS75
RA65
RA65
CMG64
DLW02
WJLG97
MCS75
S48
MV75
S70
RA65
R75
RA65
R69
MCS75
S70
CMG64
SRSA92
S70
M67
SR01
SRSA92
S48
MCS75
S48
WBBF01
RW97
S48
WBBF01
LLJ94
SRSA92
MCS75
SRSA92
MCS75
MCS75
SRSA92
SRSA92
R69
KM78
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
25
300
1000
250
14
400
300
700
300
700
40
400
300
30
15
60
200
50
11
500
50
30
40
10
120
40
120
5
60
8
80
250
15
200
90
200
80
20
30
60
400
400
400
120
600
200
700
10
50
40
150
50
50
1000
5
80
60
15
15
60
P
P
P
P
P,r
P
P
P,r
P
P
P
P
r
P
P
P
P
Wavelength 共Å兲
Spectrum
2243.045
2243.4485
2244.01
2244.26
2244.9773
2245.5244
2246.057
2246.4120
2246.5216
2247.002
2247.4822
2248.562
2248.7490
2248.758
2249.3075
2249.3075
2249.79
2249.80
2249.8994
2250.76
2251.5105
2251.8084
2252.15
2252.786
2253.38
2254.01
2255.10
2255.507
2255.53
2255.73
2255.81
2255.85
2256.19
2256.745
2256.76
2258.71
2258.86
2259.034
2259.5103
2260.294
2261.42
2262.223
2262.30
2262.483
2262.7185
2263.08
2263.627
2263.634
2263.8611
2264.39
2264.461
2264.60
2264.61
2265.018
2265.536
2266.016
2266.33
2267.65
2268.8384
2268.90
Y II
Ag II
At I
Cu I
Pt I
Pt II
Sn I
Ag II
Pt II
Cu II
Pt II
Au II
Ag II
W II
Pt I
Pt II
Ta II
WI
Pt I
Ta II
Pt II
Pt II
Os I
Hg II
Ir I
Hf II
Ir I
Te I
Ru I
Re I
Ir I
Os II
Re I
Co II
La II
Ta II
Ir I
Te I
Fe I
Hg II
Ta II
Hg II
Ta II
Sb I
Pt II
Cu I
Au II
Hg II
Pt II
Re I
Ni II
Os I
Ir I
Cd II
Te I
Sn II
Ir I
Cs II
Pt I
Ir I
2169
Finding List—Continued
Ref
NJK91
KLLT01
M64a
S48
SRSA92
SRSA92
B64
KLLT01
SRSA92
R69
SRSA92
RW97
KLLT01
EKM00
SRSA92
SRSA92
MCS75
MCS75
SRSA92
MCS75
SRSA92
SRSA92
MCS75
SR01
MCS75
MCS75
MCS75
MV75
K59
MCS75
MCS75
MCS75
MCS75
PRUJ98
MCS75
MCS75
MCS75
MV75
NJLT94
SR01
MCS75
SR01
MCS75
SM02
SRSA92
S48
RW97
SR01
SRSA92
MCS75
S70
MCS75
MCS75
SP49
MV75
B64
MCS75
S81
SRSA92
MCS75
Intensity
300
40
20
30
300
40
300
70
400
8
50
40
12
900
120
70
130
60
130
70
80
25
300
150
70
30
200
200
30
300
1000
40
250
300
60
50
800
50
400
400
15
200
60
200
60
30
300
250
60
50
110
700
50
1000
60
60
7
30
50
80
P
P
P
P,c
P
P
P
P
P,r
P,r
P
d
P
P
Wavelength 共Å兲
Spectrum
2268.930
2269.096
2269.69
2270.17
2270.214
2271.6194
2271.85
2272.091
2272.59
2273.84
2274.3816
2274.62
2274.8409
2275.2532
2275.462
2277.16
2277.282
2277.58
2278.770
2279.582
2279.85
2279.967
2279.9812
2281.02
2281.1942
2281.62
2282.26
2283.522
2283.67
2285.25
2286.159
2286.4390
2286.59
2286.681
2287.3643
2287.51
2288.022
2288.12
2288.2050
2289.16
2289.2765
2289.987
2291.71
2291.991
2292.3987
2292.5249
2293.390
2293.84
2294.49
2294.49
2295.6800
2296.5164
2298.05
2298.058
2298.09
2298.1689
2299.77
2300.1418
2300.50
2300.781
Sn I
Al I
Mo II
Os I
Ni II
Pt II
Ta II
Ru I
Ta II
Cs II
Pt I
Re I
Pt I
Re II
Ca I
Hf II
Ni II
WI
Ni II
Ru I
Ta I
Ti I
Ag II
Ir II
Pt II
Re I
Os II
Co II
Os I
Ta II
Co II
Pt II
Ta II
Sn I
Pt II
Re I
Cd I
As I
Pt II
Ta II
Pt I
Ni I
Rb II
Co II
Pt I
Fe I
Co II
Cu I
WI
Re I
Nb II
Pd II
Ir I
Tl II
Re II
Fe I
Re I
Fe I
Ir I
Ni I
Ref
B64
KM91b
MCS75
MCS75
S70
SRSA92
MCS75
K59
MCS75
S81
SRSA92
MCS75
SRSA92
WJLG97
R68
MCS75
S70
MCS75
S70
K59
MCS75
F91
KLLT01
MCS75
SRSA92
MCS75
MCS75
PRUJ98
MCS75
MCS75
PRUJ98
SRSA92
MCS75
B64
SRSA92
MCS75
BA56
HA85
SRSA92
MCS75
SRSA92
LBT93
R75
PRUJ98
SRSA92
NJLT94
PRUJ98
S48
MCS75
MCS75
RCL00
LLJ94
MCS75
JKBL96
MCS75
NJLT94
MCS75
NJLT94
MCS75
LBT93
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2170
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
300
30
11
150
150
20
250
25
6
120
12
1
800
25
25
50
120
250
500
1000
500
200
1000
50
150
25
150
500
300
9
150
7
150
200
200
150
400
500
40
40
30
300
400
8
200
250
50
70
15
40
110
40
300
300
40
150
200
30
500
60
P
P,c
r
P
P
P
P,r
P
P
P
P
h
P
P,r
P,r
Wavelength 共Å兲
Spectrum
2301.403
2302.3068
2302.99
2302.996
2304.22
2304.247
2304.684
2305.674
2306.046
2306.507
2306.54
2306.86
2307.860
2308.0437
2308.31
2308.93
2309.010
2310.961
2310.9626
2311.463
2311.604
2312.344
2312.766
2313.17
2313.656
2313.75
2313.983
2314.056
2314.975
2315.5024
2315.65
2315.98
2316.039
2317.0342
2317.070
2317.165
2317.230
2317.30
2317.784
2318.2969
2319.8869
2320.034
2320.2451
2320.81
2321.074
2321.383
2321.63
2322.47
2322.49
2322.58
2323.145
2323.25
2324.321
2324.6670
2324.89
2325.802
2326.100
2326.3386
2326.473
2327.3958
Co II
Pt II
Re I
Ni II
Ir I
Ba II
Au II
Ti I
In II
Sb I
Re I
In I
Co II
Pt I
Os I
Ir I
Co I
Ni I
Pt II
Sb I
Co II
Ni I
Cd II
WI
Ni I
Os II
Ni I
Co II
Co II
Pt I
Na II
Tl I
Ni II
Ag II
Co II
Ni I
Sn I
Br II
Ru I
Pt I
Pt II
Ni I
Ag II
Yb II
Cd II
Ni I
WI
Hf II
Re I
Rh I
Co I
Hf II
Co II
Ag II
Hf II
Ni I
Co II
Pt II
Co II
Fe II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
PRUJ98
SRSA92
MCS75
S70
MCS75
KL99
RW97
F91
PC38,B69
SM02
MCS75
P38
PRUJ98
SRSA92
MCS75
MCS75
PT96
LBT93
SRSA92
SM02
PRUJ98
LBT93
SP49
MCS75
LBT93
MCS75
LBT93
PRUJ98
PRUJ98
SRSA92
W71
MCS75
S70
KLLT01
PRUJ98
LBT93
B64
R58
K59
SRSA92
SRSA92
LBT93
KLLT01
M67
SP49
LBT93
MCS75
MCS75
MCS75
MCS75
PT96
MCS75
PRUJ98
KLLT01
MCS75
LBT93
PRUJ98
SRSA92
PRUJ98
NLTH91
Intensity
10
110
60
500
300
250
14
200
30
20
40
30
800
400
30
90
60
120
30
14
90
400
40
50
90
15
150
200
40
50
120
150
1000
100
30
60
300
60
400
12
15
90
200
700
30
15
40
100
200
120
90
70
70
800
100
30
30
150
100
500
P,r
P
P
P
P
P
P
P
P,r
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2329.836
2329.970
2331.3084
2331.3665
2331.98
2332.19
2332.46
2332.7990
2333.30
2333.39
2333.84
2334.50
2334.77
2334.812
2335.267
2336.80
2337.488
2338.0065
2339.0741
2340.1805
2343.18
2343.4951
2343.61
2343.9610
2344.2816
2344.78
2345.543
2347.399
2347.44
2347.514
2348.1159
2348.3025
2348.610
2349.84
2350.23
2350.703
2350.829
2351.22
2351.3469
2352.07
2352.65
2353.368
2353.422
2354.850
2355.00
2355.28
2357.1047
2357.30
2357.916
2359.1322
2359.9997
2360.2945
2360.44
2360.5341
2361.09
2361.92
2362.77
2363.04
2363.07
2363.800
Li II
Ni I
Fe II
Ag II
Ta II
Ta II
Cs II
Fe II
Ir I
Rb II
Ir I
Ir I
Rh II
Sn I
Ba II
Os II
Ni I
Fe II
Pt II
Pt I
Ir I
Fe II
Ir I
Fe II
Fe II
Re I
Ni I
Co II
Hf II
Ni I
Fe II
Fe II
Be I
As I
Os II
Be I
Be I
Hf II
Pd II
Re I
Au I
Co I
Co II
Sn I
Ir I
Os II
Pt I
Ta I
Ru II
Fe II
Fe II
Fe II
WI
Pd II
Ta I
Rh I
Os I
Ir I
WI
Co II
Ref
HM59
LBT93
NLTH91
KLLT01
MCS75
MCS75
S81
NLTH91
MCS75
R75
MCS75
MCS75
S58
B64
KL99
MCS75
LBT93
NLTH91
SRSA92
SRSA92
MCS75
NLTH91
MCS75
NLTH91
NLTH91
MCS75
LBT93
PRUJ98
MCS75
LBT93
NLTH91
NLTH91
KM97
HA85
MCS75
KM97
KM97
MCS75
LLJ94
MCS75
MCS75
PT96
PRUJ98
B64
MCS75
MCS75
SRSA92
MCS75
JJLL94
NLTH91
NLTH91
NLTH91
MCS75
LLJ94
MCS75
MCS75
MCS75
MCS75
MCS75
PRUJ98
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
40
250
120
50
20
30
50
60
10
300
60
80
14
600
50
9
50
40
70
120
200
100
90
40
150
60
60
12
50
40
150
70
90
60
400
50
30
40
70
10
30
200
1000
30
20
40
50
6
25
300
120
8
80
20
7
60
200
500
7
80
P
P
P
P
P
P
P,r
P
P
h
P
P,h
P
P
P
h
c
P
P
Wavelength 共Å兲
Spectrum
2363.8612
2364.24
2364.8281
2365.7654
2365.90
2366.3729
2367.052
2367.35
2367.68
2367.9664
2368.04
2368.226
2368.2781
2368.384
2368.5964
2369.27
2369.9534
2370.76
2370.77
2371.58
2372.77
2373.06
2373.124
2373.6245
2373.631
2373.7357
2374.47
2375.06
2375.09
2375.1940
2375.418
2376.4294
2377.03
2377.2773
2378.626
2379.2765
2379.39
2379.69
2380.7616
2381.538
2381.62
2381.765
2382.0376
2382.89
2383.199
2383.2452
2383.277
2383.303
2383.40
2383.459
2383.616
2383.6432
2384.82
2385.34
2385.40
2385.792
2386.370
2386.70
2386.8089
2386.89
Fe II
Ta II
Fe II
Fe II
Re I
Pt II
Al I
Os II
Re I
Pd II
Ir II
Sn II
Pt I
Bi II
Fe II
Re I
Fe II
Re II
As I
Ta I
Ir I
Te II
Al I
Fe I
Sb I
Fe II
WI
Os II
Ir II
Fe II
Ni II
Fe II
Os I
Pt II
Co II
Fe II
Os I
Tl I
Fe II
Li II
Ir I
Co II
Fe II
Rh I
Li II
Fe II
Te I
Cr I
Rh I
Co II
Sb I
Pt I
WI
Rb II
He II
Te I
Co II
Br II
Pt I
Ir I
2171
Finding List—Continued
Ref
NLTH91
MCS75
NLTH91
NLTH91
MCS75
SRSA92
KM91b
MCS75
MCS75
LLJ94
KM78
B64
SRSA92
DLW02
NLTH91
MCS75
NLTH91
MCS75
HA85
MCS75
MCS75
HM64
KM91b
NJLT94
SM02
NLTH91
MCS75
MCS75
MCS75
NLTH91
S70
NLTH91
MCS75
SRSA92
PRUJ98
NLTH91
MCS75
MCS75
NLTH91
HM59
MCS75
PRUJ98
NLTH91
MCS75
HM59
NLTH91
MV75
K53
MCS75
PRUJ98
SM02
SRSA92
MCS75
R75
GM65
MV75
PRUJ98
R58
SRSA92
MCS75
Intensity
600
60
11
200
500
400
25
2
500
150
9
150
250
10
50
50
80
150
200
700
40
50
200
70
70
200
1000
30
20
15
1000
11
200
500
25
12
60
200
13
40
150
150
50
250
7
40
200
10
120
250
4
1000
30
90
700
250
250
70
300
300
P
P
P,r
P
P
P
r
P
P
d
P
P
r
P,r
P
P
Wavelength 共Å兲
Spectrum
2387.06
2387.29
2387.75
2388.6289
2388.917
2388.96
2389.5358
2389.54
2389.69
2390.62
2390.74
2391.18
2392.63
2392.86
2393.36
2393.792
2393.83
2394.519
2395.048
2395.6254
2395.88
2397.107
2397.386
2397.73
2397.98
2399.2413
2400.63
2401.13
2401.940
2402.331
2402.72
2403.0918
2404.172
2404.8858
2405.06
2405.08
2405.42
2405.58
2405.60
2405.7269
2406.66
2406.6612
2406.9761
2407.256
2408.60
2410.14
2410.5192
2410.842
2411.0677
2411.624
2411.734
2413.1883
2413.31
2413.3104
2413.535
2414.464
2415.290
2415.68
2415.84
2416.134
Ta II
Os I
Au I
Fe II
Co II
Br II
Pt I
In I
Br II
Ir I
Yb II
Ir I
Cu I
Cs II
Hf II
Pb I
Hf II
Ni II
B II
Fe II
Os I
W II
Co II
WI
WI
Fe II
Ta II
Os I
Pb I
Li II
Ru II
Pt I
Co II
Fe II
Re I
Os II
Hf II
WI
Re I
Pt II
Cu I
Fe II
Fe II
Co I
Cr I
Hf II
Fe II
Li II
Fe II
Co I
Pb I
Ag II
Ir I
Fe II
Se I
Co I
Co I
WI
Rh II
Ni II
Ref
MCS75
MCS75
MCS75
NLTH91
PRUJ98
R58
SRSA92
P38
R58
MCS75
M67
MCS75
S48
S81
MCS75
WA68
MCS75
S70
O70
NLTH91
MCS75
EKM00
PRUJ98
MCS75
MCS75
NLTH91
MCS75
MCS75
WA68
HM59
MCS75
SRSA92
PRUJ98
NLTH91
MCS75
MCS75
MCS75
MCS75
MCS75
SRSA92
S48
NLTH91
NLTH91
PT96
K53
MCS75
NLTH91
HM59
NLTH91
PT96
WA68
KLLT01
MCS75
NLTH91
LP77
PT96
PT96
MCS75
S58
S70
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2172
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
300
40
50
10
40
20
12
2
40
150
600
40
40
25
90
100
150
150
200
50
30
30
140
250
70
50
700
25
10
70
70
30
9
80
8
150
50
200
40
25
70
40
300
200
140
25
1000
250
110
90
110
40
100
200
40
70
60
150
250
60
P
P
P
P
P,r
P
r
Wavelength 共Å兲
Spectrum
2417.659
2417.69
2417.8707
2418.0583
2418.11
2419.81
2420.02
2420.456
2420.8161
2420.99
2421.694
2422.186
2422.6882
2423.07
2424.1456
2424.21
2424.73
2424.8672
2424.935
2424.97
2426.53
2427.61
2427.64
2427.95
2428.3638
2428.58
2429.495
2429.52
2429.814
2430.0783
2431.08
2431.24
2431.54
2431.94
2432.18
2432.213
2432.2612
2432.70
2432.8732
2433.3064
2433.98
2434.4610
2435.154
2435.96
2436.662
2436.6887
2437.7832
2438.69
2439.040
2439.3014
2440.0608
2440.34
2441.64
2442.617
2443.7100
2444.06
2444.5154
2445.502
2445.538
2445.5732
Co II
Hf II
Fe II
Pt I
Ir I
Re I
Os II
Ar II
Pt II
Na II
Sn I
Y II
Fe II
Os II
Fe II
WI
Na II
Pt II
Co I
Os I
Ir II
Ir I
Ta I
Au I
Fe II
Re I
Sn I
Rh I
Li II
Fe II
WI
Ir I
Re I
Ir I
Re I
Co I
Fe II
Ta II
Fe II
Pt II
WI
Pt II
Si I
WI
Co I
Pt I
Ag II
Te II
Co I
Fe II
Pt I
Rh I
Cu I
Co II
Fe II
WI
Fe II
Sb I
O II
Fe II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
PRUJ98
MCS75
NLTH91
SRSA92
MCS75
MCS75
MCS75
N73
SRSA92
W71
B64
NJK91
NLTH91
MCS75
NLTH91
MCS75
W71
SRSA92
PT96
MCS75
MCS75
MCS75
MCS75
MCS75
NLTH91
MCS75
B64
MCS75
HM59
NLTH91
MCS75
MCS75
MCS75
MCS75
MCS75
PT96
NLTH91
MCS75
NLTH91
SRSA92
MCS75
SRSA92
RA65
MCS75
PT96
SRSA92
KLLT01
HM64
PT96
NLTH91
SRSA92
MCS75
S48
PRUJ98
NLTH91
MCS75
NLTH91
SM02
MKM93
NLTH91
Intensity
200
500
11
50
200
300
25
11
200
600
150
80
30
7
50
100
50
50
14
70
90
250
80
30
200
400
90
500
150
90
130
3
40
50
400
7
50
60
130
60
150
1000
60
50
200
25
30
80
40
40
150
50
50
10
30
2
60
14
250
40
P
P
P,w
c
P
P,r
P
P
c
P
P
h
h
Wavelength 共Å兲
Spectrum
2446.017
2446.1888
2446.98
2447.25
2447.711
2447.9058
2448.908
2449.71
2450.002
2450.08
2450.08
2450.4390
2450.74
2450.9670
2451.476
2452.00
2452.81
2454.72
2454.91
2454.98
2455.51
2455.531
2455.61
2455.83
2456.438
2456.53
2456.53
2456.57
2457.5891
2458.7838
2459.30
2460.08
2460.4404
2460.49
2461.03
2461.20
2461.2835
2461.42
2461.84
2461.8610
2462.6472
2462.764
2462.79
2464.19
2464.199
2464.50
2464.77
2465.1492
2466.6713
2466.8194
2466.85
2467.30
2467.4003
2467.4824
2467.57
2468.02
2468.8799
2468.90
2469.2517
2469.5147
Co II
Pd II
Re I
Hf II
Co II
Pd I
Sn II
Re I
Co II
Po I
Ga I
Pt II
Os I
Pt I
W II
WI
Ir I
WI
Os II
WI
WI
Ru II
Ir I
Re II
Ru II
As I
WI
Ru II
Fe I
Fe II
WI
In I
Fe II
Hf II
Rh II
Re I
Fe II
Os I
Re II
Fe II
Fe I
Cm II
WI
Hf II
Co II
Yb I
Kr II
Fe I
Fe II
Fe II
WI
Ir I
Pt I
Pt I
Re II
In I
Fe I
Os II
Pd II
Fe II
Ref
PRUJ98
LLJ94
MCS75
MCS75
PRUJ98
ELLW98
B64
MCS75
PRUJ98
C66a
MM52
SRSA92
MCS75
SRSA92
EKM00
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
JJ93
MCS75
MCS75
JJLL94
HA85
MCS75
MCS75
NJLT94
NLTH91
MCS75
P38
NLTH91
MCS75
S58
MCS75
NLTH91
MCS75
MCS75
NLTH91
NJLT94
WHGC76
MCS75
MCS75
PRUJ98
MT78
RCWM80
NJLT94
NLTH91
NLTH91
MCS75
MCS75
SRSA92
SRSA92
MCS75
P38
NJLT94
MCS75
LLJ94
NLTH91
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
50
600
80
60
100
140
250
60
200
250
30
200
150
400
40
400
40
120
100
90
60
50
120
150
60
50
60
1000
200
30
20
300
100
40
70
200
7
70
80
200
400
60
40
200
200
20
50
600
250
40
700
25
50
100
25
200
300
500
400
40
P
P
P
P
d
P
P
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2470.6694
2472.20
2472.3320
2472.51
2472.8713
2474.15
2474.62
2474.8145
2475.12
2476.4127
2476.84
2477.1279
2478.316
2478.561
2478.5722
2478.93
2478.9449
2479.7764
2480.13
2480.13
2480.1577
2480.96
2481.18
2481.44
2482.10
2482.1172
2482.6577
2483.2708
2483.410
2483.5334
2483.92
2483.94
2484.1875
2484.2446
2484.74
2484.95
2485.81
2486.24
2486.3728
2486.441
2486.5260
2486.967
2486.9827
2487.1685
2487.1685
2487.33
2487.50
2488.1426
2488.70
2488.8753
2488.9146
2489.231
2489.4833
2489.7524
2490.1265
2490.46
2490.53
2490.6443
2490.79
2490.8584
Fe II
Rb II
Fe I
WI
Fe I
WI
Ta I
Fe I
Ir I
Pd I
Os I
Ag II
Sb I
CI
Fe II
Ru II
Pt II
Fe I
WI
Tm II
Fe II
WI
Ir I
WI
WI
Fe II
Fe II
Fe I
Sn I
Fe I
Re I
Po I
Fe I
Fe II
WI
Ta I
Re I
Os II
Fe I
Co II
Pd II
Sn II
Pt II
Pt I
Pt I
Re I
WI
Fe I
Ta II
Pt II
Pd II
W II
Fe II
Fe I
Pt I
Ta I
Po I
Fe I
Rh II
Fe II
2173
Finding List—Continued
Ref
NLTH91
R75
NJLT94
MCS75
NJLT94
MCS75
MCS75
NJLT94
MCS75
ELLW98
MCS75
KLLT01
SM02
J66
NLTH91
MCS75
SRSA92
NJLT94
MCS75
MCS75
NLTH91
MCS75
MCS75
MCS75
MCS75
NLTH91
NLTH91
NJLT94
B64
NJLT94
MCS75
C66a
NJLT94
NLTH91
MCS75
MCS75
MCS75
MCS75
NJLT94
PRUJ98
LLJ94
B64
SRSA92
SRSA92
SRSA92
MCS75
MCS75
NJLT94
MCS75
SRSA92
LLJ94
EKM00
NLTH91
NJLT94
SRSA92
MCS75
C66a
NJLT94
S58
NLTH91
Intensity
200
60
200
20
300
40
600
60
300
100
70
140
20
8
20
60
500
200
800
90
200
60
200
40
400
200
200
500
100
300
90
40
250
40
10
250
40
80
300
50
500
400
15
300
250
20
50
7
30
30
150
40
100
200
9
70
8
40
30
90
P
h
P
P
P
P
P
P
P
P
P
P
c
c
Wavelength 共Å兲
Spectrum
2491.1550
2491.3965
2492.15
2492.48
2492.85
2493.08
2493.15
2493.1846
2493.2637
2494.728
2495.26
2495.724
2495.8126
2496.30
2496.38
2496.5337
2496.769
2496.77
2497.722
2498.41
2498.42
2498.4996
2498.57
2498.6806
2498.7769
2498.821
2500.19
2500.54
2501.1318
2501.9945
2502.35
2502.3930
2502.98
2503.8745
2504.31
2504.45
2504.60
2504.70
2505.7293
2506.0935
2506.464
2506.897
2506.940
2507.01
2507.45
2507.782
2507.9004
2508.4973
2508.785
2508.99
2509.08
2509.70
2510.8350
2511.160
2511.20
2511.7603
2512.061
2512.3650
2512.58
2512.65
Fe I
Fe II
Cu I
Kr II
Pa II
Ir I
Na II
Fe II
Fe II
Be I
WI
Sn I
Pt I
Cr I
Rb II
Fe I
BI
Tc II
BI
Os I
Ru II
Pt I
Ru II
Pt II
Pd II
Co II
Ga I
Ge II
Fe I
Zn II
Re II
Fe II
Ir I
Fe II
Cr I
Ta I
Re II
WI
Pd II
Fe II
Co II
Si I
Li II
Ru II
Ta I
VI
Fe I
Pt I
Li II
Re I
Tm II
Rh I
Fe I
Co II
He II
Fe II
Yb II
Fe I
Ir II
Ta I
Ref
NJLT94
NLTH91
S48
DHM33
BW92b
MCS75
W71
NLTH91
NLTH91
KM97
MCS75
B64
SRSA92
K53
R75
NJLT94
JLKK93
BMC67
JLKK93
MCS75
MCS75
SRSA92
MCS75
SRSA92
LLJ94
PRUJ98
MM52
S63a
NJLT94
GL00
MCS75
NLTH91
MCS75
NLTH91
K53
MCS75
MCS75
MCS75
LLJ94
NLTH91
PRUJ98
RA65
HM59
MCS75
MCS75
DA78
NJLT94
SRSA92
HM59
MCS75
MCS75
MCS75
NJLT94
PRUJ98
GM65
NLTH91
M67
NJLT94
MCS75
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2174
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
70
25
70
80
70
400
25
300
40
20
500
3
100
30
80
25
40
400
20
20
500
10
500
90
200
6
10
400
400
90
400
11
50
9
200
300
120
30
30
200
500
200
50
400
800
500
80
140
80
25
200
20
5
700
40
300
250
60
400
70
P
P
P
P
P
P
P
P
d
P
P,r
P
Wavelength 共Å兲
Spectrum
2512.69
2512.87
2513.03
2513.25
2513.8885
2514.316
2515.04
2515.46
2515.5770
2515.75
2516.112
2516.789
2516.88
2517.6611
2518.1018
2518.44
2519.0472
2519.202
2519.51
2519.622
2519.823
2520.01
2520.52
2521.32
2521.365
2521.37
2521.50
2521.70
2522.8494
2523.41
2524.108
2524.24
2524.2925
2524.3065
2524.634
2524.974
2525.3879
2525.586
2526.221
2526.2939
2526.35
2527.4351
2527.76
2528.509
2528.509
2528.616
2528.7336
2528.970
2529.1350
2529.871
2530.080
2530.183
2530.738
2530.740
2531.19
2531.54
2532.12
2533.13
2533.518
2533.6274
Hf II
Os I
Hf II
Os I
Pt II
Si I
Os I
Na II
Pt I
Rh I
Si I
Ar II
Hf II
Fe I
Fe I
Os I
Fe II
Si I
Cr I
VI
Co II
Re I
Rh II
WI
Co I
In I
Re I
Br II
Fe I
WI
Si I
Rb II
Fe I
Pt I
Co II
Co II
Fe II
Ti II
VI
Fe II
Ta I
Fe I
WI
Si I
Sb I
Co II
Pt II
Co I
Fe I
Ti I
Co II
VI
Te I
Tl II
Hf II
Na II
Ta II
Ir I
Au II
Fe II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
MCS75
MCS75
MCS75
MCS75
SRSA92
RA65
MCS75
W71
SRSA92
MCS75
RA65
N73
MCS75
NJLT94
NJLT94
MCS75
NLTH91
RA65
K53
DA78
PRUJ98
MCS75
S58
MCS75
PT96
P38
MCS75
R58
NJLT94
MCS75
RA65
R75
NJLT94
SRSA92
PRUJ98
PRUJ98
NLTH91
HJLW82
DA78
NLTH91
MCS75
NJLT94
MCS75
RA65
SM02
PRUJ98
SRSA92
PT96
NJLT94
F91
PRUJ98
DA78
MV75
JKBL96
MCS75
W71
MCS75
MCS75
RW97
NLTH91
Intensity
90
200
400
7
60
60
3
70
500
40
8
140
1000
40
120
30
8
100
30
15
60
60
90
30
20
10
120
60
50
40
25
300
30
30
30
25
1000
40
500
13
120
70
40
80
50
300
50
200
90
140
300
11
60
8
50
50
40
8
50
60
P
P
P,c
P
P
P
d
Wavelength 共Å兲
Spectrum
2533.64
2533.801
2533.987
2534.221
2534.4186
2534.46
2534.709
2535.4856
2535.606
2535.6069
2535.658
2535.966
2536.517
2536.6726
2536.80
2537.22
2537.919
2538.00
2538.46
2538.67
2538.7987
2538.9094
2538.99
2539.2067
2539.487
2540.51
2540.66
2540.9722
2541.1010
2541.8358
2541.908
2541.953
2542.02
2542.1013
2542.51
2542.67
2543.23
2543.3781
2543.97
2544.74
2544.806
2545.34
2545.70
2545.9785
2546.03
2546.549
2546.6701
2546.739
2546.80
2547.14
2547.98
2548.225
2548.7442
2548.750
2549.0833
2549.3947
2549.4616
2549.548
2549.56
2549.6133
WI
Co II
PI
Mn II
Fe II
Ir I
Ar II
Fe II
PI
Fe I
Mn II
Co I
Hg I
Fe II
Fe II
Ir I
Mn II
Os II
Mo II
Yb II
Fe II
Fe II
Fe II
Pt I
Li II
Re I
Fe II
Fe I
Fe II
Fe II
Ti I
Co II
Ir I
Fe I
Os I
Mo II
Tc II
Fe II
Ir I
Re I
Nb II
WI
Rh I
Fe I
Ir I
Sn I
Fe II
Co II
Ta I
WI
Se I
Mo I
Fe II
Mn II
Fe II
Fe II
Fe II
Cr I
Ru I
Fe I
Ref
MCS75
PRUJ98
M59
IV64
NLTH91
MCS75
N73
NLTH91
M59
NJLT94
IV64
PT96
BAL50
NLTH91
C74
MCS75
IV64
MCS75
MCS75
M67
NLTH91
NLTH91
C74
SRSA92
HM59
MCS75
C74
NJLT94
NLTH91
NLTH91
F91
PRUJ98
MCS75
NJLT94
MCS75
MCS75
BMC67
NLTH91
MCS75
MCS75
RCL00
MCS75
MCS75
NJLT94
MCS75
B64
NLTH91
PRUJ98
MCS75
MCS75
RG34
WB88
NLTH91
IV64
NLTH91
NLTH91
NLTH91
K53
K59
NJLT94
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
200
40
90
30
200
300
40
10
300
100
100
40
400
50
9
200
60
25
300
90
40
60
20
500
600
8
300
500
200
60
80
6
60
80
5
200
80
250
25
120
12
500
50
150
120
20
40
90
100
25
90
300
30
400
400
100
8
60
11
20
d
P
P
P,d
P
P
P
P,w
P
P
w
P
P
P
Wavelength 共Å兲
Spectrum
2550.02
2550.0274
2550.38
2550.6832
2551.07
2551.35
2551.40
2551.70
2551.8452
2552.350
2552.658
2552.764
2553.253
2553.82
2554.434
2554.62
2554.63
2554.853
2554.904
2555.05
2555.095
2555.36
2556.51
2557.9460
2558.01
2558.605
2559.405
2559.43
2560.031
2560.150
2560.232
2560.695
2561.65
2561.97
2562.087
2562.10
2562.123
2562.5356
2563.16
2563.4755
2563.642
2564.034
2564.18
2565.5045
2565.593
2566.49
2566.9126
2567.121
2567.82
2567.984
2568.64
2568.871
2571.444
2571.457
2571.594
2571.67
2571.74
2571.81
2572.345
2572.755
K II
Fe II
WI
Fe II
Ta I
WI
Hf II
Li II
Pd II
Sc II
Au II
Tm I
PI
WI
In II
Ta II
Re II
W II
PI
Ta I
W II
Rh I
Re I
Zn II
Po I
Mn II
Co II
Ta I
Co II
In I
Sc II
Cr I
Tm II
WI
Ar II
Ta I
Ne II
Fe II
Os II
Fe II
Mn II
Co II
Ir I
Pd II
Th II
Os I
Fe II
Ne II
Te II
Al I
Re II
Zr II
W II
Zr II
Sn I
Hf II
Cr I
Re II
Mo I
Mn I
2175
Finding List—Continued
Ref
D26
NLTH91
MCS75
NLTH91
MCS75
MCS75
MCS75
SO82
LLJ94
JL80
RW97
SMC73
M59
MCS75
PC38
MCS75
MCS75
EKM00
M59
MCS75
EKM00
MCS75
MCS75
GL00
C66a
IV64
PRUJ98
MCS75
PRUJ98
P38
JL80
K53
MCS75
MCS75
N73
MCS75
P71
NLTH91
MCS75
NLTH91
IV64
PRUJ98
MCS75
LLJ94
GSZ70
MCS75
NLTH91
P71
HM64
KM91b
MCS75
J98
EKM00
J98
B64
MCS75
K53
MCS75
WB88
CMG64
Intensity
500
150
150
40
20
90
50
50
20
1000
30
40
4
40
250
130
40
40
20
90
80
15
40
800
100
140
25
300
40
60
100
120
20
150
300
300
7
500
500
200
25
30
120
50
60
20
40
15
200
50
9
150
25
20
500
140
300
200
9
20
P
P
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2572.930
2573.54
2573.79
2573.90
2574.018
2574.3662
2574.96
2575.094
2575.509
2576.103
2576.6902
2576.82
2577.14
2577.26
2577.37
2577.78
2577.9219
2578.14
2578.32
2578.79
2579.31
2580.03
2580.14
2580.326
2580.49
2580.8102
2581.96
2582.240
2582.54
2582.5832
2582.79
2583.987
2584.302
2584.5359
2585.8758
2586.31
2586.79
2587.220
2587.524
2588.904
2589.160
2590.76
2590.943
2591.12
2591.5428
2591.84
2592.06
2592.20
2592.534
2592.85
2592.944
2593.08
2593.640
2593.710
2593.720
2594.421
2594.96
2595.26
2595.763
2596.00
Cd II
Ta I
Ta I
Hf II
VI
Fe II
Te II
Al I
Mn I
Mn II
Fe I
Hf II
Eu II
Ir I
Ta II
Ta I
Fe II
Hf II
Os II
Lu II
Pr I
Os II
Tl I
Co II
WI
Pt II
Os I
Co II
Hf II
Fe II
I II
Nb II
Mn I
Fe I
Fe II
Na II
Re I
Co II
Co II
Co II
W II
Os I
Nb II
Te II
Fe II
Cr I
Ir I
Nb I
Ge I
Te II
Mn I
Ta I
Ti I
Mo II
Mn II
Sn I
Na II
Ta I
Mn I
Os II
Ref
SP49
MCS75
MCS75
MCS75
DA78
NLTH91
HM64
KM91b
CMG64
KG00
NJLT94
MCS75
MCS75
MCS75
MCS75
MCS75
NLTH91
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
PRUJ98
MCS75
SRSA92
MCS75
PRUJ98
MCS75
NLTH91
MC60
RCL00
CMG64
NJLT94
NLTH91
W71
MCS75
PRUJ98
PRUJ98
PRUJ98
EKM00
MCS75
RCL00
HM64
NLTH91
K53
MCS75
MCS75
AM59
HM64
CMG64
MCS75
F91
SPNL01
KG00
B64
W71
MCS75
CMG64
MCS75
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2176
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
Wavelength 共Å兲
Spectrum
15
600 P,r
200 r
400 P
8
40
300
700 P
30
30
11
20
9
250
15
40
400 P
50
50
80
200
80
50
90
300 P
40
110 P
10
500 P
30
1000 P,c
15
70
110
120 d
11 d
500
400 P
80
120 r
60
110
10
100
15 r
60
200
200 P,r
150
1000 P
130
120
100
400
14
6
1000
200
40
250
2596.489
2598.048
2598.084
2598.3692
2598.905
2599.04
2599.16
2599.3956
2599.5669
2599.904
2601.76
2602.800
2603.1374
2603.49
2605.081
2605.133
2605.680
2605.72
2606.37
2606.39
2606.5162
2606.8264
2607.03
2607.06
2607.0871
2608.25
2608.50
2608.5576
2608.63
2609.062
2609.99
2610.200
2611.285
2611.30
2611.34
2611.54
2611.81
2611.8736
2612.06
2612.304
2613.06
2613.08
2613.084
2613.40
2613.655
2613.82
2613.8243
2614.175
2614.23
2615.42
2615.46
2615.66
2615.87
2616.393
2616.786
2617.01
2617.169
2617.6174
2618.145
2618.37
Tm I
Sb I
Sb I
Fe II
Mn II
Ir I
Pa II
Fe II
Fe I
Ti I
In I
Mo II
Pt I
Ta II
Li II
Ti I
Mn II
Te II
Hf II
WI
Fe II
Fe I
Hf II
Tm II
Fe II
Ir I
Re II
Zn I
Ta I
Ru I
Tc II
Mn II
Ti I
Ir I
Ta I
Re I
Na II
Fe II
Ru I
Sb I
Os I
WI
Mo I
Lu II
Pb I
WI
Fe II
Pb I
Tc I
Lu II
Ta I
Ta I
Tc I
Au II
Mo I
Yb II
Cm II
Fe II
Mn II
Cu I
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
SMC73
SM02
SM02
NLTH91
IV64
MCS75
BW92b
NLTH91
NJLT94
F91
P38
SPNL01
SRSA92
MCS75
HM59
F91
KG00
HM64
MCS75
MCS75
NLTH91
NJLT94
MCS75
MCS75
NLTH91
MCS75
MCS75
GL00
MCS75
K59
BMC67
IV64
F91
MCS75
MCS75
MCS75
W71
NLTH91
K59
SM02
MCS75
MCS75
WB88
MCS75
WA68
MCS75
NLTH91
WA68
BMC67
MCS75
MCS75
MCS75
BMC67
RW97
WB88
M67
WHGC76
NLTH91
IV64
S48
Intensity
100
40
30
50
60
20
50
50
80
40
25
80
50
50
15
120
25
80
200
90
15
80
150
200
150
15
50
50
90
40
20
200
120
500
30
50
90
1000
10
200
25
300
130
11
80
50
130
50
15
15
15
200
7
14
80
6
130
25
40
80
P
P
w
P
P
d
P
P
Wavelength 共Å兲
Spectrum
2619.26
2619.933
2619.94
2620.25
2620.41
2621.82
2622.21
2622.74
2623.107
2623.5339
2623.688
2624.33
2624.86
2625.22
2625.606
2625.6671
2625.88
2627.904
2628.0269
2628.2931
2629.850
2629.885
2631.0471
2631.282
2631.3232
2632.354
2632.48
2632.70
2633.13
2634.17
2634.803
2634.91
2635.529
2635.58
2635.8088
2635.83
2636.069
2636.281
2636.64
2636.67
2636.670
2636.90
2637.13
2638.173
2638.289
2638.62
2638.71
2638.761
2638.77
2639.3454
2639.3454
2639.71
2639.849
2640.984
2641.087
2641.27
2641.41
2641.480
2642.946
2644.097
Lu II
Ti I
Os I
WI
Fe II
Os I
WI
Hf II
Ne II
Fe I
Dy I
Tm II
Te II
WI
Mn II
Fe II
Rh I
Bi I
Pt I
Fe II
Mo I
Ne II
Fe II
Si I
Fe II
Mn II
WI
WI
WI
Ir I
Dy II
Tc II
U II
Ta II
Fe I
Re II
Ne II
Cm II
Re I
Ta I
Mo II
Ta I
Os I
Mn II
Ne II
WI
Hf II
Mo II
Eu II
Pt I
Pt I
Ir I
Mn II
Mo I
Ti I
Eu II
Hf II
Au I
Ru I
Ne II
Ref
MCS75
F91
MCS75
MCS75
D38
MCS75
MCS75
MCS75
P71
NJLT94
NG00
MCS75
HM64
MCS75
IV64
NLTH91
MCS75
WBBF01
SRSA92
NLTH91
WB88
P71
NLTH91
RA65
NLTH91
IV64
MCS75
MCS75
MCS75
MCS75
NG00
BMC67
BW92b
MCS75
NJLT94
MCS75
P71
WHGC76
MCS75
MCS75
SPNL01
MCS75
MCS75
IV64
P71
MCS75
MCS75
SPNL01
MCS75
SRSA92
SRSA92
MCS75
IV64
WB88
F91
MCS75
MCS75
ED71
K59
P71
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
70
100
6
40
80
200
100
250
30
120
50
90
1000
80
900
20
20
500
100
60
200*
200*
60
100
300
1000
500
110
200
12
25
100
40
1000
40
13
40
60
1000
7
20
20
200
700
20
30
50
150
25
10
13
70
100
500
40
20
50
500
140
600
P,c
P
P
P
P
P
P
P
P
P
P
P
P
P
d
P
P
P
Wavelength 共Å兲
Spectrum
2644.11
2644.253
2644.306
2644.348
2646.18
2646.22
2646.254
2646.37
2646.486
2646.625
2646.73
2646.8804
2647.01
2647.29
2647.47
2647.50
2649.458
2649.66
2650.454
2650.550
2650.613
2650.619
2650.694
2650.760
2650.8524
2651.171
2651.172
2651.22
2651.568
2651.90
2652.039
2652.35
2652.66
2653.27
2653.347
2653.57
2653.679
2653.75
2653.804
2654.12
2654.45
2655.021
2656.54
2656.61
2657.293
2657.303
2657.38
2657.80
2658.032
2658.111
2658.59
2658.60
2658.7201
2659.4503
2659.617
2659.83
2660.576
2661.00
2661.244
2661.34
Os I
Ti I
Yb II
Mo II
WI
Ta I
Nb II
Ta I
Mo II
Ti I
WI
Pt I
Tc II
Hf II
Ta I
Nb I
Mo I
Te II
Be I
Be I
Be I
Be I
Be I
Be I
Pt I
Cm II
Ge I
Ta II
Ge I
Re I
Hg I
Tc II
Rh I
Ta I
Mo II
Cr II
Hg I
Yb II
Cm II
Re I
Nb I
Mo I
WI
Ta I
Li II
Li II
WI
Lu II
W II
Mo I
Cr II
Os I
Pd II
Pt I
Ru I
Os I
Mo II
Na II
Sn I
Ta I
2177
Finding List—Continued
Ref
MCS75
F91
M67
SPNL01
MCS75
MCS75
RCL00
MCS75
SPNL01
F91
MCS75
SRSA92
BMC67
MCS75
MCS75
MCS75
WB88
HM64
KM97
KM97
KM97
KM97
KM97
KM97
SRSA92
WHGC76
AM59
MCS75
AM59
MCS75
BAL50
BMC67
MCS75
MCS75
SPNL01
K51
BAL50
M67
WHGC76
MCS75
MCS75
WB88
MCS75
MCS75
HM59
HM59
MCS75
MCS75
EKM00
WB88
K51
MCS75
LLJ94
SRSA92
K59
MCS75
SPNL01
W71
B64
MCS75
Intensity
400
110
90
90
300
15
40
150
11
25
200
30
11
250
15
30
40
120
90
20
600
30
20
9
20
15
50
20
15
20
9
20
300
300
4
50
90
80
500
4
300
900
15
50
60
30
2
1
250
50
11
70
250
90
300
80
600
4
12
300
P
h
P
r
P
P
P
P
P
P
h
P
P
Wavelength 共Å兲
Spectrum
2661.61
2661.98
2662.84
2663.154
2663.33
2663.42
2664.6638
2664.79
2665.038
2666.02
2666.740
2666.8125
2668.34
2668.62
2668.71
2669.91
2670.260
2670.630
2671.47
2671.80
2671.83
2671.84
2671.958
2672.581
2672.656
2672.83
2672.843
2673.27
2674.34
2674.460
2674.5700
2674.57
2675.90
2675.954
2677.13
2677.1477
2677.19
2677.28
2678.09
2678.29
2678.632
2678.76
2678.79
2678.88
2679.0242
2679.854
2680.34
2680.43
2681.42
2683.234
2684.10
2684.140
2684.28
2684.288
2684.7536
2685.08
2685.17
2685.66
2687.09
2687.954
Ru II
Ir I
WI
Pb I
Po
Cr II
Fe II
Ir I
Yb II
Cr II
Co II
Fe I
Eu II
Ta I
Cr II
Ir I
Er II
Sb I
WI
Cr II
Na II
Ir I
Yb I
Mn II
Yb II
Cr II
Mo II
Mo II
Re I
Li II
Pt I
Os I
Ta II
Au I
Te I
Pt I
Cr II
WI
Na II
Eu II
Zr II
Ru II
Cr II
WI
Fe I
Mo I
Na I
Na I
WI
Mo II
Rb II
Mo II
Ta I
Th II
Fe II
Lu I
Ta II
Eu II
Cr II
V II
Ref
MCS75
MCS75
MCS75
WA68
CHPT55
K51
NLTH91
MCS75
M67
K51
PRUJ98
NJLT94
MCS75
MCS75
K51
MCS75
M64b
SM02
MCS75
K51
W71
MCS75
MT78
IV64
M67
K51
SPNL01
MCS75
MCS75
HM59
SRSA92
MCS75
MCS75
ED71
MCS75
SRSA92
K51
MCS75
W71
MCS75
J98
MCS75
K51
MCS75
NJLT94
WB88
R56
R56
MCS75
SPNL01
R75
SPNL01
MCS75
GSZ70
NLTH91
MCS75
MCS75
MCS75
K51
ICL88
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2178
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
40
9
40
500
70
15
130
200
9
400
100
110
40
200
200
80
90
300
13
400
9
20
9
100
300
80
20
50
130
300
200
500
7
12
40
13
250
13
100
200
400
40
8
40
4
300
11
150
140
500
50
40
200
200
20
15
200
7
70
9
P
P
P
P
c
P
P
P
P
P
Wavelength 共Å兲
Spectrum
2687.992
2688.247
2689.2122
2689.300
2689.82
2691.03
2691.31
2691.341
2692.03
2692.06
2692.40
2692.415
2692.6019
2694.23
2694.52
2695.67
2696.81
2697.060
2697.710
2698.30
2698.40
2698.4248
2698.68
2698.860
2699.22
2699.59
2699.59
2700.01
2700.129
2700.491
2700.937
2700.962
2701.024
2701.14
2701.416
2701.698
2701.71
2701.90
2702.194
2702.3995
2703.184
2703.73
2703.98
2703.9891
2705.28
2705.61
2705.732
2705.8951
2706.174
2706.505
2706.58
2706.5820
2706.606
2706.69
2706.70
2706.738
2707.343
2707.544
2707.90
2708.452
Mo II
Mn II
Fe I
Cu II
Os I
Cr II
Ta I
Ge I
Eu II
Ru II
Ta I
Th II
Fe II
Ir I
Ta II
WI
Ta I
Nb II
W II
Ta I
Cr II
Pt I
Cr II
Nb II
Pa II
WI
Os I
WI
Zr II
Ga II
V II
Cu II
Mn II
Eu II
Mo II
Mn II
Lu II
Eu II
Nb II
Pt I
Cu II
Rh I
Mn II
Fe II
Eu II
Hf I
Mn II
Pt I
V II
Sn I
WI
Fe I
Co II
Ta I
Os I
Sc I
Co II
Mn II
Tc II
Mn II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
SPNL01
IV64
NJLT94
R69
MCS75
K51
MCS75
AM59
MCS75
MCS75
MCS75
Z79
NLTH91
MCS75
MCS75
MCS75
MCS75
RCL00
EKM00
MCS75
K51
SRSA92
K51
RCL00
BW92b
MCS75
MCS75
MCS75
J98
IL85
ICL88
R69
IV64
MCS75
SPNL01
IV64
MCS75
MCS75
RCL00
SRSA92
R69
MCS75
IV64
NLTH91
MCS75
MCS75
IV64
SRSA92
ICL88
B64
MCS75
NJLT94
PRUJ98
MCS75
MCS75
AV77
PRUJ98
IV64
BMC67
IV64
Intensity
50
1000
100
50
100
20
300
15
500
90
7
25
9
11
200
25
250
500
15
50
100
1000
400
20
25
50
150
140
12
90
20
9
20
110
400
250
400
130
60
300
40
200
150
60
140
5
30
140
250
9
1
40
300
100
50
1000
20
100
200
50
P,s
d
P
P
h
P
P
P
P
P
P
P
P
P
P
P
s
Wavelength 共Å兲
Spectrum
2708.59
2708.66
2708.78
2708.80
2708.96
2709.23
2709.624
2709.981
2710.13
2710.265
2710.336
2711.341
2711.568
2711.76
2711.8732
2712.40
2712.41
2713.508
2713.94
2714.4129
2714.64
2714.67
2715.27
2715.36
2715.47
2715.50
2715.664
2716.622
2716.98
2717.18
2717.35
2718.349
2718.54
2718.59
2718.778
2718.91
2719.0273
2719.0333
2719.51
2719.5239
2720.04
2720.76
2720.9023
2721.19
2721.645
2721.77
2721.86
2721.981
2722.609
2722.74
2723.19
2723.5774
2724.35
2724.57
2725.03
2725.682
2726.496
2726.69
2727.44
2727.5392
WI
Es II
Tc I
WI
Ra II
Tl I
Ge I
Eu I
Ta I
In I
Mn II
Sc I
Mn II
Rb II
Ag II
Kr II
Ru II
Cu II
In I
Fe II
Os I
Ta I
Rh II
Os I
Re I
WI
V II
Nb II
Eu II
Ta I
Mo II
Yb II
Rh I
Hf I
Cu II
WI
Fe I
Pt I
Ru I
Pt II
Os I
Ta I
Fe I
Tm II
Ca I
Ag I
Os I
Nb II
Zr II
Cr II
He I
Fe I
WI
Es II
WI
Cm II
Cr I
Tc I
Ta II
Fe II
Ref
MCS75
WLGC74
BMC67
MCS75
R34a
MCS75
AM59
ST76
MCS75
P38
IV64
AV77
IV64
R75
KLLT01
DHM33
MCS75
R69
P38
NLTH91
MCS75
MCS75
S58
MCS75
MCS75
MCS75
ICL88
RCL00
MCS75
MCS75
MCS75
M67
MCS75
MCS75
R69
MCS75
NJLT94
SRSA92
K59
SRSA92
MCS75
MCS75
NJLT94
MCS75
R68
S40
MCS75
RCL00
J98
K51
M60a
NJLT94
MCS75
WLGC74
MCS75
WHGC76
K53
BMC67
MCS75
NLTH91
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
150
70 P
20
7
50
15
60 h
6
400
13
50*
50*
20
30
14
90
6
20
25
100 P
250
12 c
100
300 P
400 P
250 P
50
150
8
2
1000
50
80
1000
400 P
80
200
120
300 P
13
120
20
200
200
120
1000 s
1000
100 P
1000 P
13
500
80
15
400 P
60
300
120
70 P
20
11
Wavelength 共Å兲
Spectrum
2727.78
2727.78
2728.288
2728.315
2728.90
2728.94
2728.95
2729.44
2729.78
2729.9123
2730.473
2730.551
2730.61
2731.56
2731.895
2732.721
2732.742
2732.80
2732.880
2733.04
2733.289
2733.30
2733.5806
2733.9567
2734.35
2734.851
2735.4753
2735.727
2736.463
2736.542
2736.892
2737.3091
2738.76
2739.31
2739.5474
2742.4053
2742.553
2743.1969
2743.2944
2743.63
2745.854
2746.30
2746.4838
2746.68
2747.156
2748.019
2748.039
2748.253
2748.549
2748.664
2748.78
2748.84
2748.98
2749.3216
2749.4860
2749.83
2750.1406
2750.477
2750.72
2751.468
Ta I
Eu II
Li II
Li II
Fe II
Rh I
Lu I
Eu II
Ge II
Pt I
Li II
Li II
Os I
Re II
Cr I
Zr II
Yb II
Os I
Mo II
Re II
O II
He II
Fe I
Pt I
Ru II
Zr II
Fe I
Ru I
Cr I
Mg I
Cm II
Fe I
Hf II
Cf II
Fe II
Fe I
Zr II
Fe II
Pt II
Cr II
Zr II
Mo II
Fe II
Ta I
Th II
Bk II
Cm II
Au I
Cd II
Yb II
Ta I
WI
Cr II
Fe II
Fe II
Ta I
Fe I
Yb II
Cr II
Mo I
2179
Finding List—Continued
Ref
MCS75
MCS75
HM59
HM59
C74
MCS75
MCS75
MCS75
S63a
SRSA92
HM59
HM59
MCS75
MCS75
K53
J98
M67
MCS75
SPNL01
MCS75
MKM93
GM65
NJLT94
SRSA92
MCS75
J98
NJLT94
K59
K53
KM91a
WHGC76
NJLT94
MCS75
RCWM80
NLTH91
NJLT94
J98
NLTH91
SRSA92
K51
J98
MCS75
NLTH91
MCS75
Z79
WC78
WHGC76
ED71
SP49
M67
MCS75
MCS75
K51
NLTH91
NLTH91
MCS75
NJLT94
M67
K51
WB88
Intensity
40
15
100
120
50
8
40
200
250
30
60
500
40
8
20
400
20
90
1000
25
200
200
100
250
50
40
80
400
15
2
25
100
100
250
40
40
200
500
50
20
7
12
150
50
30
20
90
8
100
30
20
120
90
90
1000
2
130
300
9
40
P
P
P
P
s
P
P,s
P
P
P
h
l
P
P,d
r
P
P
P
Wavelength 共Å兲
Spectrum
2751.81
2751.85
2752.166
2752.202
2753.2877
2753.8531
2753.878
2754.17
2754.588
2754.9122
2755.630
2755.7365
2756.550
2757.086
2757.72
2758.31
2758.61
2758.806
2759.10
2761.42
2761.63
2761.68
2761.81
2761.92
2762.34
2762.58
2762.921
2763.0899
2763.62
2763.80
2764.261
2765.74
2765.76
2766.37
2766.55
2766.989
2767.87
2769.669
2769.74
2769.76
2769.8332
2769.902
2769.931
2770.016
2770.71
2770.8538
2770.88
2770.9740
2771.6594
2772.0740
2773.20
2773.36
2774.00
2774.48
2774.52
2775.37
2775.402
2775.88
2776.280
2776.6595
Hf II
Cr II
Th II
Zr II
Fe II
Pt I
In I
Lu II
Ge I
Pt I
Er II
Fe II
Am II
Cr I
Cr II
Ta I
Nb I
Zr II
Cf II
Os I
Hf I
Ta II
Fe II
Po I
WI
Cr II
Ne II
Pd I
Mo II
He I
W II
Lu I
Es II
Cu I
Cr II
Li II
Tl I
Cu II
WI
Mo II
Pt I
Cr I
Sb I
Er II
Os I
Zn I
WI
Zn I
Pt I
Fe I
Nb I
Hf II
WI
WI
Cf II
In I
Mo II
Ta I
Yb II
Pd II
Ref
MCS75
K51
GSZ70
J98
NLTH91
SRSA92
P38
MCS75
AM59
SRSA92
M64b
NLTH91
FT57
K53
K51
MCS75
MCS75
J98
RCWM80
MCS75
MCS75
MCS75
C74
C66a
MCS75
K51
P71
ELLW98
MCS75
M60a
EKM00
MCS75
WLGC74
S48
K51
HM59
MCS75
R69
MCS75
MCS75
SRSA92
K53
SM02
M64b
MCS75
GL00
MCS75
GL00
SRSA92
NJLT94
MCS75
MCS75
MCS75
MCS75
RCWM80
P38
SPNL01
MCS75
M67
LLJ94
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2180
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
6
60
5
200
15*
15*
300
70
900
50
30
9
30
5
8
100
25
6
10
6
1000
30
20
300
150
300
20
13
90
90
150
80
80
250
1000
130
100
250
150
20
110
80
30
90
300
15
6
200
50
20
6
140
300
600
150
30
200
600
100
30
P
P
P,r
P,l
P
P
P
P
l
P
P
P
P
P,r
P
P
Wavelength 共Å兲
Spectrum
2776.690
2778.2202
2778.270
2779.37
2779.820
2779.834
2779.977
2780.037
2780.22
2780.476
2780.695
2780.822
2781.29
2781.416
2781.89
2782.05
2782.55
2782.972
2783.57
2784.656
2784.826
2784.99
2786.31
2787.10
2787.69
2788.1047
2790.313
2790.776
2792.019
2792.70
2793.934
2794.221
2794.60
2794.817
2795.5301
2795.78
2796.11
2796.34
2796.63
2796.73
2796.93
2797.27
2797.35
2797.70
2797.76
2797.998
2798.211
2798.270
2799.93
2800.8635
2801.0500
2801.084
2801.995
2802.036
2802.07
2802.494
2802.560
2802.7056
2802.81
2802.84
Mg I
Fe I
Mg I
Hf I
Mg I
Mg I
Ga II
Mo II
As I
Bi I
Cr I
Au I
Ir I
Mg I
Eu II
Tc I
Os I
Mg I
Re I
Yb II
Cm II
Mo II
Os I
Es II
Ta I
Fe I
Li II
Mg II
Ne II
WI
U II
Ne II
Tm II
Mn I
Mg II
Tc II
Es II
Ta I
Lu II
Os I
Gd II
Tm II
Ir I
Ir I
Ta II
Mg II
Yb II
Mn I
WI
Zn I
Zn I
Mn I
Pb I
Au II
Ta I
Ti I
U II
Mg II
Tc I
Eu II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
KM91a
NJLT94
KM91a
MCS75
KM91a
KM91a
IL85
SPNL01
HA85
WBBF01
K53
ED71
MCS75
KM91a
MCS75
BMC67
MCS75
KM91a
MCS75
M67
WHGC76
MCS75
MCS75
WLGC74
MCS75
NJLT94
HM59
KM91a
P71
MCS75
BW92b
P71
MCS75
CMG64
PTW98
BMC67
WLGC74
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
MCS75
KM91a
M67
CMG64
MCS75
GL00
GL00
CMG64
WA68
RW97
MCS75
F91
BW92b
PTW98
BMC67
MCS75
Intensity
20
40
150
200
100
150
130
30
100
500
90
150
300
1000
4
40
250
150
60
25
200
300*
300*
200
130
9
600
200
15
100
130
90
10
30
200
15
140
30
200
8
70
9
1000
60
300
40
40
120
30
1000
9
70
6
400
60
90
14
20
1000
70
P
s
P
P
l
P,l
l
P
P
P
P
r
P
h
h
s
Wavelength 共Å兲
Spectrum
2803.2357
2804.5203
2806.30
2806.58
2806.91
2806.9841
2807.119
2807.753
2809.485
2809.52
2809.72
2810.551
2811.61
2811.618
2811.75
2812.920
2813.2864
2813.76
2813.94
2814.20
2814.902
2815.15
2815.15
2815.282
2816.158
2816.18
2816.185
2816.9021
2817.44
2817.68
2817.958
2818.06
2818.2
2818.2450
2819.793
2819.95
2820.22
2820.78
2821.121
2821.152
2821.35
2822.38
2822.546
2822.68
2822.792
2823.0513
2823.18
2823.189
2823.2756
2824.204
2824.39
2824.45
2824.974
2825.437
2825.5557
2825.557
2826.16
2826.68
2827.567
2827.92
Pt I
Fe I
Ta I
Ta I
Os I
Fe I
U II
Mo II
Ne II
Na II
Gd II
Ru I
Tc II
Cm II
Eu II
Am II
Fe I
Ra II
Eu II
Os I
Zr I
Es I
Es II
Am II
Mo II
Eu II
Al II
Pt II
Mo II
Hf I
U II
WI
He I
Pt I
Au II
Re I
Hf II
Eu II
U II
Yb II
Tc II
Cr II
Au II
Hf II
Pa II
Pt II
Ir I
Pb I
Fe I
Cm II
Ag I
Ir I
Yb II
Au II
Fe I
Zr II
Tl I
Rh I
Bk II
Tm II
Ref
SRSA92
NJLT94
MCS75
MCS75
MCS75
NJLT94
BW92b
SPNL01
P71
W71
MCS75
K59
BMC67
WHGC76
MCS75
FT57
NJLT94
R34a
MCS75
MCS75
J98
WLGC74
WLGC74
FT57
SPNL01
MCS75
KM91b
SRSA92
MCS75
MCS75
BW92b
MCS75
BDD72
SRSA92
RW97
MCS75
MCS75
MCS75
BW92b
M67
BMC67
K51
RW97
MCS75
G67
SRSA92
MCS75
WA68
NJLT94
WHGC76
S40
MCS75
M67
RW97
NJLT94
J98
MCS75
MCS75
WC78
MCS75
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
Wavelength 共Å兲
Spectrum
7 c,w
140
4
40
300 P,c
9
11
200 P
1000 P
200
300 l
1000 P,s
200
150
30
300 P,r
1000 P
90
15
130 P
50
500 P
100
10 c
200
300 P
400 P
120
20
200 P
60
400
1000 P
50
50
25
600
30
80
100
90 P
100
250
80
120
110 c
1000 P
200
2
400
100 h
13 h
150
400 P
90
150
40
130 P
2
6
2828.72
2828.935
2829.08
2829.149
2830.2919
2830.46
2830.989
2831.38
2831.843
2832.061
2832.14
2832.258
2832.3154
2832.4355
2833.00
2833.053
2833.580
2833.63
2834.7107
2835.63
2836.40
2836.710
2836.900
2836.92
2837.226
2837.2954
2837.603
2837.848
2838.1194
2838.63
2839.16
2839.56
2839.976
2840.22
2841.57
2841.60
2841.72
2842.4101
2842.8127
2842.82
2843.24
2843.9763
2844.25
2844.40
2844.575
2845.35
2845.527
2845.83
2846.716
2846.920
2847.16
2847.175
2847.51
2847.675
2848.02
2848.0839
2848.186
2848.233
2848.342
2848.445
Eu II
U II
He I
Ru I
Pt I
Cr II
Yb II
WI
Ge II
U II
Pa II
Am II
Th II
Fe I
Kr II
Pb I
Cm II
WI
Pt I
Cr II
Ir I
C II
Cd I
In I
Zr I
Th II
C II
Au II
Fe I
Os I
Ir I
Na II
Sn I
Ir I
WI
Os I
Na II
Pt II
Th II
Ta I
Cr II
Fe I
Ta I
Os I
Zr II
Ta I
Ge II
Hf I
Mg I
Au II
Ac II
Yb II
Lu II
Hg II
WI
Th I
Zr II
Mo II
Mg I
Yb II
2181
Finding List—Continued
Ref
MCS75
BW92b
M60a
K59
SRSA92
K51
M67
MCS75
S63a
BW92b
BW92b
FT57
PE83
NJLT94
DHM33
WA68
WHGC76
MCS75
SRSA92
K51
MCS75
MG93
BA56
P38
J98
PE83
MG93
RW97
NJLT94
MCS75
MCS75
W71
B64
MCS75
MCS75
MCS75
W71
SRSA92
PE83
MCS75
K51
NJLT94
MCS75
MCS75
J98
MCS75
S63a
MCS75
KM91a
RW97
MFT57
M67
MCS75
SR01
MCS75
PE83
J98
SPNL01
KM91a
M67
Intensity
200
200
60
600
50
120
700
20
3
80
1000
1000
5
2
30
60
20
40
1000
50
80
2
500
30
200
6
400
4
25
1000
25
50
90
8
6
40
90
140
40
5
30
700
30
20
70
40
200
80
1000
50
15
30
11
25
20
150
120
200
300
130
P
P
P
P
l
P
P
P
P
s
P
c
c
P,r
P
P
P
P
Wavelength 共Å兲
Spectrum
2848.52
2849.72
2849.83
2850.49
2850.76
2850.96
2850.98
2851.126
2851.660
2851.7969
2852.03
2852.1251
2852.81
2853.01
2853.23
2854.075
2854.166
2854.5776
2855.24
2855.67
2856.03
2858.14
2858.29
2858.91
2859.11
2859.392
2859.49
2859.67
2859.805
2860.44
2860.92
2860.96
2861.01
2861.212
2861.34
2861.408
2861.70
2861.98
2862.57
2862.57
2862.94
2863.315
2863.81
2864.361
2864.73
2865.10
2865.681
2866.06
2866.37
2866.653
2866.69
2866.72
2867.06
2867.65
2868.095
2868.515
2868.65
2869.23
2870.005
2870.4066
Ta I
Ir I
Cr II
Ta I
Os I
Hf I
Ta I
Yb II
Mg I
Fe I
Cf II
Mg I
Na I
Na I
Mo II
Ru I
Tm I
Pd II
Cf II
Cr II
WI
In I
Te II
Cr II
Tc I
Yb II
Na II
Eu II
Yb II
As I
Cr II
Os I
Hf II
Yb II
Yb II
Ru I
Hf II
Ta I
Cr II
Eu II
Rh I
Sn I
Mo II
VI
Xe II
Cr II
U II
WI
Hf I
Ru I
Mo II
Cr II
Yb II
Cr II
VI
Nb II
Ta I
Tm II
Pa II
Th II
Ref
MCS75
MCS75
K51
MCS75
MCS75
MCS75
MCS75
M67
KM91a
NJLT94
RCWM80
PTW98
R56
R56
MCS75
K59
SMC73
LLJ94
RCWM80
K51
MCS75
P38
HM64
K51
BMC67
M67
W71
MCS75
M67
HA85
K51
MCS75
MCS75
M67
M67
K59
MCS75
MCS75
K51
MCS75
MCS75
B64
MCS75
DA78
H39
K51
BW92b
MCS75
MCS75
K59
MCS75
K51
M67
K51
DA78
RCL00
MCS75
MCS75
G67
PE83
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
2182
J. E. SANSONETTI AND W. C. MARTIN
Finding List—Continued
Intensity
11
400
300
200
130
1000
120
100
100
400
110
150
250
1000
15
140
12
150
400
40
400
9
1000
15
70
70
7
150
100
30
500
1000
130
50
150
25
80
1000
90
80
500
70
8
50
100
90
11
200
40
13
400
250
1000
7
70
100
300
200
8
250
h
P
l
r
P
P
P
P,r
P,s
r
P
P
l
h
l
s
P,d
h
P
Wavelength 共Å兲
Spectrum
2870.43
2871.28
2871.413
2871.42
2871.512
2872.114
2873.311
2873.36
2873.56
2874.235
2874.9196
2874.984
2875.390
2875.6314
2875.97
2875.980
2876.24
2877.038
2877.100
2877.2783
2877.913
2877.97
2878.572
2879.05
2879.11
2879.40
2879.482
2880.02
2880.767
2880.98
2881.15
2881.5771
2881.60
2882.64
2883.174
2883.446
2884.2897
2884.772
2885.0491
2885.14
2886.26
2886.528
2886.995
2887.68
2887.73
2887.8176
2888.04
2888.505
2889.294
2889.600
2889.62
2889.624
2889.803
2890.179
2890.94
2890.994
2891.139
2891.384
2891.612
2891.644
Cr II
Na II
Pa II
Ta I
Mo II
Bk II
Pb I
Ta I
Ta I
Ga I
Pt II
Ru I
Nb II
Pt II
Cr II
Zr I
Cr II
Nb II
Cu II
Pt II
Sb I
Cr II
Bk II
Mo II
WI
WI
Mn II
Ta I
Cd I
Ho II
Na II
Si I
Pr I
Ir I
Nb II
Au I
Th II
Bk II
Th II
Lu I
Na II
Ru I
Cr I
Re I
Tc I
Th II
Yb II
Am II
Cr I
Mn II
Hf I
U II
Bk II
In II
Tm II
Mo II
Pa II
Yb II
Ar II
V II
J. Phys. Chem. Ref. Data, Vol. 34, No. 4, 2005
Finding List—Continued
Ref
K51
W71
G67
MCS75
SPNL01
WC78
WA68
MCS75
MCS75
JL67
SRSA92
K59
RCL00
SRSA92
K51
J98
K51
RCL00
R69
SRSA92
SM02
K51
WC78
MCS75
MCS75
MCS75
IV64
MCS75
BA56
MCS75
W71
BE93
MCS75
MCS75
RCL00
ED71
PE83
WC78
PE83
MCS75
W71
K59
K53
MCS75
BMC67
PE83
M67
FT57
K53
IV64
MCS75
BW92b
WC78
PC38
MCS75
SPNL01
G67
M67
N73
ICL88
Intensity
300
25
140
20
250
13
400
20
400
1000
30
130
10
70
400
50
800
50
100
150
10
40
140
60
500
800
100
40
40
1000
7
250
500
200
15
20
50
500
90
400
400
600
9
80
8
250
80
50
150
80
300
300
20
15
130
140
150
600
30
15
P
P
s
P
P
h
P
P
P
l
P
c
P
P
h
P
Wavelength 共Å兲
Spectrum
2891.84
2891.961
2892.433
2892.502
2892.652
2893.013
2893.247
2893.254
2893.307
2893.660
2893.838
2893.8630
2894.168
2894.451
2894.84
2895.22
2895.41
2896.01
2896.34
2896.44
2896.756
2897.15
2897.806
2897.8715
2897.965
2898.26
2899.04
2899.3861
2899.562
2899.904
2900.154
2900.30
2901.14
2902.05
2902.48
2903.07
2904.283
2904.41
2904.469
2904.72
2904.75
2904.92
2905.477
2905.692
2905.8974
2906.454
2906.592
2906.68
2906.794
2906.816
2906.93
2907.03
2907.042
2907.21
2907.462
2908.240
2908.272
2908.810
2908.883
2908.993
Ta I
Au I
V II
Eu I
V II
Eu I
Au II
Cr I
V II
Bk II
Eu I
Pt I
Cr I
Mo II
Lu II
Xe II
Te II
WI
Tc I
WI
Cr I
Ir I
Nb II
Pt I
Bi I
Hf I
Ta I
Pt II
Am II
Cm II
Mn II
Lu II
Na II
Ta I
Re I
Mo II
Si II
Hf I
Er II
Na II
Hf I
Na II
Cr I
Si II
Pt I
V II
Ne II
Eu II
U II
Ne II
Pa II
Es
Au II
Rh I
V II
Nb II
U II
V II
Ru I
Eu I
Ref
MCS75
ED71
ICL88
ST76
ICL88
ST76
RW97
K53
ICL88
WC78
ST76
SRSA92
K53
SPNL01
MCS75
H39
HM64
MCS75
BMC67
MCS75
K53
MCS75
RCL00
SRSA92
WBBF01
MCS75
MCS75
SRSA92
FT57
WHGC76
IV64
MCS75
W71
MCS75
MCS75
MCS75
S61b
MCS75
M64b
W71
MCS75
W71
K53
S61b
SRSA92
ICL88
P71
MCS75
BW92b
P71
BW92b
WLGC74
RW97
MCS75
ICL88
RCL00
BW92b
ICL88
K59
ST76
ATOMIC SPECTROSCOPIC DATA
Finding List—Continued
Intensity
13
300
40
40
10
200
90
300
140
140
90
200
1000
13
150
40
80
12
500
140
80
60
15
70
1000
100
40
15
140
9
200
30
80
8
120
30
100
900
20
600
700
400
140
250
600
15
40
70
700
200
700
7
20
100
600
60
600
20
400
250
P
c
P
l
l
P
c
P
P
P
P
s
P
P
P
Wavelength 共Å兲
Spectrum
2909.049
2909.06
2909.117
2909.41
2909.82
2910.016
2910.061
2910.15
2910.359
2910.385
2910.408
2910.587
2910.645
2910.892
2911.058
2911.130
2911.138
2911.148
2911.39
2911.743
2911.917
2912.083
2912.2515
2912.33
2912.965
2913.15
2913.517
2913.5386
2913.559
2914.210
2914.672
2914.926
2915.122
2915.275
2915.49
2916.