Chemistry Test 4-3 (May) Please use the answer sheet. Thank you! Multiple Choice (60%) 1) Please consider a 5.00-mL sample of lead with a density of 11.4 g/mL and a 5.00-mL sample of gold with a density of 19.2 g/mL. Please choose all true statements. A) B) C) D) E) 2) A sample of a solution has more water added to it. Which one is true? A) B) C) D) 3) The gold has a smaller volume than the lead. The gold has the same mass as the lead. The gold contains fewer atoms than the lead. The gold has a greater mass than the lead. None of these are true. The molarity increases because solvent has been added. The molarity increases because solute has been added. The molarity decreases because solvent has been added. The molarity decreases because solute has been added. Which one occurs when a seed crystal is dropped into a supersaturated solution? A) B) C) D) It dissolves and then precipitates. It dissolves and remains dissolved. It falls to the bottom and remains undissolved. It causes dissolved solute to precipitate. 4) A solution has [H+] = 4.71 X 10–3. What is the pH? 5) A solution has [OH–] = 2.50 X 10–4. What is the pH? 6) Please choose all compounds with ionic bonds. A) C) E) 7) K2S CO2 As2O3 CaCl2 Br2 B) D) SO2 Ni(ClO2)2 Which one is an example of a cation that is isoelectronic with Kr? A) 9) B) D) Please choose all compounds with covalent bonds. A) C) E) 8) P4O6 O2 (NH4)2(SO4) Br+ B) Y3– C) Se2+ D) Sr2– E) Y3+ Which one is an example of an anion that is isoelectronic with Ne? A) Al3+ B) F2– C) O2– D) Mg2– E) F+ 10) What is the name for H3P ? A) C) 11) B) D) HSO4 HSO3 Concentrated with a high molarity Dilute with a high molarity B) D) Concentrated with a low molarity Dilute with a low molarity pH 8 = weak base pH 14 = strong base pH 1 = weak acid B) D) pH 14 = strong acid pH 6 = strong acid Which one will decrease the solubility of a gaseous solute in water? A) B) C) D) 15) H2S H2SO4 H2SO3 Please choose all that are matched correctly. A) C) E) 14) Phosphoric acid Hydrophosphoric acid Which one best describes a solution with a large mass of solvent and a small mass of solute? A) C) 13) B) D) Which one is the formula for sulfurous acid? A) C) E) 12) Phosphorous acid Hydrophosphorous acid Increase the temperature and increase the pressure Increase the temperature and decrease the pressure Decrease the temperature and increase the pressure Decrease the temperature and decrease the pressure Which one will decrease the solubility of a solid solute in water? A) B) C) D) Increase the temperature and increase the surface area Increase the temperature and decrease the surface area Decrease the temperature and increase the surface area Decrease the temperature and decrease the surface area 16) What is the empirical formula for C6H15 ? 17) A compound has an empirical formula C2H5 and a molar mass of 116.28 g. What is the molecular formula? 18) Which atom would we predict to have the greatest electron affinity? A) B) C) D) One with many protons and many electron clouds One with few protons and many electron clouds One with many protons and few electron clouds One with few protons and few electron clouds Please consider the Lewis dot diagram for SO32– for questions 19-21. 19) Which one best describes the central atom in HCO– ? A) B) C) D) 20) What is the electronic geometry for HCO– ? A) C) E) 21) B) C) D) Trigonal planar Trigonal pyramidal Linear B) D) Tetrahedral Bent The O atom has a smaller ionization energy because it has fewer protons and more electron clouds. The F atom has a greater ionization energy because it has more protons and the same number of electron clouds. The O atom has a larger radius because it has fewer protons and the same number of electron clouds. The F atom has a greater ionization energy because it has more protons and fewer electron clouds. K B) Cu C) Ca D) Kr E) Br Which one has the largest radius? A) 25) Tetrahedral Bent Which one has the smallest atomic radius? A) 24) B) D) Please consider an atom of oxygen and an atom of fluorine. Please choose all correct statements. A) 23) Trigonal planar Trigonal pyramidal Linear What is the molecular geometry for HCO– ? A) C) E) 22) 2 bonding pairs of electrons and 0 lone pairs 3 bonding pairs of electrons and 1 lone pair 3 bonding pairs of electrons and 0 lone pairs 2 bonding pairs of electrons and 1 lone pair Si4– B) Cl– C) K+ D) Ar E) Sc3+ Please choose all molecules that would be polar covalent. A) B) C) D) Trigonal planar electronic geometry and bent molecular geometry Tetrahedral electronic geometry and trigonal pyramidal molecular geometry Tetrahedral electronic geometry and tetrahedral molecular geometry Tetrahedral electronic geometry and bent molecular geometry 26) D T (oC) E C B A Heat (J) Please choose all true statements. A) B) C) D) E) D represents heat of fusion and heat of vaporization. B represents heat of solidification and heat of condensation. C represents liquid H2O boiling. E represents steam being heated. A represents ice being melting. 27) What is the ending electron configuration for As2– ? 28) Please choose all that have identical atoms as the representative particle. A) C) E) 29) B) D) Helium Sand (SiO2) Please choose all true statements. A) B) C) D) E) 30) 14 kt gold 24 kt gold Air The boiling point of water is 0oC. Heat of condensation = +q. Heat of fusion = –q. Heat of solidification = –q. The melting point of ice is 0oC. Please use the attached solubility graph. When a saturated solution of NaNO3 in 100 g H2O is heated from 10oC to 35oC, what additional mass of NaNO3 will dissolve in the solution to keep the solution saturated? Problems (40%) Please show all your work for any credit! 1) How many ppies are in 3.70 X 10–13 kpies? 2) How many MJ are in 94.0 cJ? 3) What is the % yield oxygen? 2 Al(ClO3)3 (s) 2 AlCl3 (s) + 9 O2 (g) Mass of crucible Mass of crucible + Al(ClO3)3 60.00 g 64.67 g Mass of crucible after heating 62.94 g 4) A compound contains 33.138 g carbon, 3.716 g hydrogen & 44.147 g oxygen. What is its empirical formula? 5) A 47.8-g sample of aluminum has an initial temperature of 7.0oC. It loses 563 J of heat. What is the final temperature of the sample? The specific heat capacity of aluminum is 0.900 J/goC. Chemistry Test 4-3 (Flowers) Please use the answer sheet. Thank you! Multiple Choice (60%) 1) Please consider a 5.00-mL sample of lead with a density of 11.4 g/mL and a 5.00-mL sample of gold with a density of 19.2 g/mL. Please choose all true statements. A) B) C) D) E) 2) A sample of a solution has more water added to it. Which one is true? A) B) C) D) 3) The gold has a smaller volume than the lead. The gold has the same mass as the lead. The gold contains fewer atoms than the lead. The gold has a greater mass than the lead. None of these are true. The molarity increases because solvent has been added. The molarity increases because solute has been added. The molarity decreases because solvent has been added. The molarity decreases because solute has been added. Which one occurs when a seed crystal is dropped into a supersaturated solution? A) B) C) D) It dissolves and then precipitates. It dissolves and remains dissolved. It falls to the bottom and remains undissolved. It causes dissolved solute to precipitate. 4) A solution has [H+] = 4.71 X 10–3. What is the pH? 5) A solution has [OH–] = 2.50 X 10–4. What is the pH? 6) Please choose all compounds with ionic bonds. A) C) E) 7) K2S CO2 As2O3 CaCl2 Br2 B) D) SO2 Ni(ClO2)2 Which one is an example of a cation that is isoelectronic with Kr? A) 9) B) D) Please choose all compounds with covalent bonds. A) C) E) 8) P4O6 O2 (NH4)2(SO4) Br+ B) Y3– C) Se2+ D) Sr2– E) Y3+ Which one is an example of an anion that is isoelectronic with Ne? A) Al3+ B) F2– C) O2– D) Mg2– E) F+ 10) What is the name for H3P ? A) C) 11) B) D) HSO4 HSO3 Concentrated with a high molarity Dilute with a high molarity B) D) Concentrated with a low molarity Dilute with a low molarity pH 8 = weak base pH 14 = strong base pH 1 = weak acid B) D) pH 14 = strong acid pH 6 = strong acid Which one will decrease the solubility of a gaseous solute in water? A) B) C) D) 15) H2S H2SO4 H2SO3 Please choose all that are matched correctly. A) C) E) 14) Phosphoric acid Hydrophosphoric acid Which one best describes a solution with a large mass of solvent and a small mass of solute? A) C) 13) B) D) Which one is the formula for sulfurous acid? A) C) E) 12) Phosphorous acid Hydrophosphorous acid Increase the temperature and increase the pressure Increase the temperature and decrease the pressure Decrease the temperature and increase the pressure Decrease the temperature and decrease the pressure Which one will decrease the solubility of a solid solute in water? A) B) C) D) Increase the temperature and increase the surface area Increase the temperature and decrease the surface area Decrease the temperature and increase the surface area Decrease the temperature and decrease the surface area 16) What is the empirical formula for C6H15 ? 17) A compound has an empirical formula C2H5 and a molar mass of 116.28 g. What is the molecular formula? 18) Which atom would we predict to have the greatest electron affinity? A) B) C) D) One with many protons and many electron clouds One with few protons and many electron clouds One with many protons and few electron clouds One with few protons and few electron clouds Please consider the Lewis dot diagram for SO32– for questions 19-21. 19) Which one best describes the central atom in HCO– ? A) B) C) D) 20) What is the electronic geometry for HCO– ? A) C) E) 21) B) C) D) Trigonal planar Trigonal pyramidal Linear B) D) Tetrahedral Bent The O atom has a smaller ionization energy because it has fewer protons and more electron clouds. The F atom has a greater ionization energy because it has more protons and the same number of electron clouds. The O atom has a larger radius because it has fewer protons and the same number of electron clouds. The F atom has a greater ionization energy because it has more protons and fewer electron clouds. K B) Cu C) Ca D) Kr E) Br Which one has the largest radius? A) 25) Tetrahedral Bent Which one has the smallest atomic radius? A) 24) B) D) Please consider an atom of oxygen and an atom of fluorine. Please choose all correct statements. A) 23) Trigonal planar Trigonal pyramidal Linear What is the molecular geometry for HCO– ? A) C) E) 22) 2 bonding pairs of electrons and 0 lone pairs 3 bonding pairs of electrons and 1 lone pair 3 bonding pairs of electrons and 0 lone pairs 2 bonding pairs of electrons and 1 lone pair Si4– B) Cl– C) K+ D) Ar E) Sc3+ Please choose all molecules that would be polar covalent. A) B) C) D) Trigonal planar electronic geometry and bent molecular geometry Tetrahedral electronic geometry and trigonal pyramidal molecular geometry Tetrahedral electronic geometry and tetrahedral molecular geometry Tetrahedral electronic geometry and bent molecular geometry 26) D T (oC) E C B A Heat (J) Please choose all true statements. A) B) C) D) E) D represents heat of fusion and heat of vaporization. B represents heat of solidification and heat of condensation. C represents liquid H2O boiling. E represents steam being heated. A represents ice being melting. 27) What is the ending electron configuration for As2– ? 28) Please choose all that have identical atoms as the representative particle. A) C) E) 29) B) D) Helium Sand (SiO2) Please choose all true statements. A) B) C) D) E) 30) 14 kt gold 24 kt gold Air The boiling point of water is 0oC. Heat of condensation = +q. Heat of fusion = –q. Heat of solidification = –q. The melting point of ice is 0oC. Please use the attached solubility graph. When a saturated solution of NaNO3 in 100 g H2O is heated from 10oC to 35oC, what additional mass of NaNO3 will dissolve in the solution to keep the solution saturated? Problems (40%) Please show all your work for any credit! 1) How many kpies are in 3.70 X 10–13 ppies? 2) How many cJ are in 94.0 MJ? 3) What is the % yield oxygen? 2 Al(ClO3)3 (s) 2 AlCl3 (s) + 9 O2 (g) Mass of crucible Mass of crucible + Al(ClO3)3 60.00 g 64.88 g Mass of crucible after heating 62.63 g 4) A compound contains 24.822 g carbon, 2.087 g hydrogen & 44.091 g oxygen. What is its empirical formula? 5) A 37.8-g sample of aluminum has an initial temperature of 8.0oC. It loses 653 J of heat. What is the final temperature of the sample? The specific heat capacity of aluminum is 0.900 J/g oC. Chemistry Test 4-2 Form__________ Multiple Choice (60%) 1) _____ 16) _____ 2) _____ 17) _____ 3) _____ 18) _____ 4) _____ 19) _____ 5) _____ 20) _____ 6) _____ 21) _____ 7) _____ 22) _____ 8) _____ 23) _____ 9) _____ 24) _____ 10) _____ 25) _____ 11) _____ 26) _____ 12) _____ 27) _____ 13) _____ 28) _____ 14) _____ 29) _____ 15) _____ 30) _____ Name __________________________________ Problems (40%) Please show all your work for any credit. 1) ____________________ 2) ____________________ 3) ____________________ 4) ____________________ 5) ____________________
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