® Solutions for the Photovoltaic Industry Your Reliable Partner for Adhesives and Sealants Henkel is your global partner for photovoltaic solutions One Source for All Your Needs Quality with Brands and Technologies Developing efficient solutions for the photovoltaic industry requires a 360-degree approach. Henkel’s high-quality tailor-made adhesives, sealants and cleaners improve quality, enable highly automated production processes, increase production speed, and thus decrease your manufacturing cost. The innovative Henkel solutions have an excellent ® reputation worldwide. Our Competencies • Product development experience Your Benefits at a Glance • Improve your process and product quality through • Technology and application know-how – fast, highly automated processes • Comprehensive system of products and services – more durable products • Cooperation with machine manufacturers • Reduce your overall costs • Global team, global presence – local support • Assurance from industry approvals • Benefit from ongoing product development • Gain a long-term partner 2 Henkel Products and Services Along the Photovoltaic Value Chain Ingot Bonding ............................................................... page 04 Cleaning ............................................................................ page 05 Silicon Wafers Cells/ Modules BuildingIntegrated Photovoltaic Crystalline .............................................. Thinfilm .................................................... Flexible ..................................................... Concentrator ....................................... page 6 page 8 page 11 page 12 Lamination ...................... page 14 Electrical Devices ........................................................ page 16 Photovoltaic and more… Quick Reference Guide .......................................... page 17 Applications & Lead Materials ............................ page 18 3 Silicon Wafers Building-Integrated Photovoltaic Cells/Modules Silicon Wafer Production Environmentally responsible and perfect cleaning results – the key requirements for your production Ingot Bonding Loctite® Two-Component (2K) Epoxies – the reliable solution • • • • • 4 High bond strength Fast cure Removable in hot water No acid required for debonding Reduce edge breakage Cleaning of Silicon Wafers – P3® Product Range Decades of cleaning expertise Pre-cleaning • Main residues from silicon block cutting are removed • Benefit from lubrication properties to facilitate wafer separation • Adaptable products with different lubrication properties depending on the intermediate storage time Main cleaning • Cleaning of wafers to remove all silicon scraps, acid and bonding residues • Clean surfaces without disturbing substances for the texturizing • Our products suit your process: ultrasonic baths or horizontal lines with sprays Product Description Ratio Hardness Cure Time Debond TEMP Loctite 3388P™ Ingot Bonding 1:1 80 D 2 hr. 60ºC-80ºC Loctite 3382™ Ingot Bonding 1:1 80 D 7 hr. 60ºC-80ºC P3 AllPass™ 230™ Wafer Clean 1%-5% by Vol ® ® ® 5 Silicon Wafers Building-Integrated Photovoltaic Cells/Modules Crystalline Crystalline Module Production Module Framing and Module Mounting Terostat® MS and Loctite® Silicones – reliable high performance elastic bonding with long-term experience • • • • • • • • • • Instant handling hot melt Traditional 1K silicone Ultrafast 2K SMP (Silyl Modified Polymer) Outstanding resistance to mechanical loads and high wind loads Superb long-term resistance to hard weathering conditions Highly automated processes and high production speed Excellent primerless adhesion to glass, metal and plastics IEC 61215/61730 compliant RoHS compliant UL® listed and approved Product Description Application Ratio Fixture TIme Cure Method Terostat® MS 647™ Fast 2K SMP Framing 10:1 15 min. Self Mix Terostat MS 500™ 1K Hot Melt SMP Framing 1 Part 2-3 min. Moisture Terostat MS 650™ Fast 2K SMP Rail Bonding 10:1 5 min. Self Mix Loctite® 5606™ Medium 2K Silicone J-Box Bonding 4:1 20 min. Self Mix Loctite® 5970™ 1K RTV Silicone J-Box Bonding 1 Part 3 hr. RTV Loctite® 5640™ Primerless 2K Silicone J-Box Potting 10:1 5 min. Self Mix Loctite® 5240™ UV Cure Silicone J-Box Potting 1 Part 20-40 sec. UV/Moisture Cure Loctite® 5611™ F Fast 2K Silicone J-Box Potting 10:1 2-3 min. Self Mix Loctite® 5611™ S Standard 2K Silicone J-Box Potting 10:1 15-20 min. Self Mix Loctite® 460™ Instant Adhesive Fixturing 1 Part 10-30 sec. Moisture ® ® *Note: SMP (Silyl Modified Polymer) 6 New dimensions in photovoltaic module manufacturing Junction Box Potting Loctite® – self-leveling potting compounds • One-component silicones • Two-component silicones • UV curable resins Junction Box Bonding & Sealing Loctite® Silicones • • • • • • • In combination with Prism® Instant Adhesive, instant handling strength Highly automated processes Superb long-term resistance to hard weathering conditions Excellent adhesion to glass, metal and plastics IEC 61215/61646/61730 compliant UL® listed RoHS compliant Junction Box Preliminary Fixing Loctite® Instant Adhesives • • • • Instant bonding strength with excellent initial adhesion to glass, metal and plastics Compatible with Loctite® 1K & 2K Silicones Reduces buffer storage systems RoHS compliant 7 Silicon Wafers Building-Integrated Photovoltaic Cells/Modules THINFILM Thinfilm Module Production Outstanding reliable products and comprehensive know-how Module Framing Terostat® Butyls – the water vapor tight solution • • • • • • • Initial handling strength right after application Highly automated processes and very high production speed Excellent primerless adhesion to glass, metal and plastics Superb long-term resistance to hard weathering conditions Strongly improved creep resistance at elevated temperatures IEC 61646 compliant RoHS compliant Product Description Application Ratio Fixture Cure Method Terostat® MS 647™ Fast 2K SMP Framing 10:1 15 min. Self Mix Terostat® MS 500™ Instant 1K Hot Melt SMP Framing 1 Part 2-3 min. Moisture Terostat® 2780™ PIB Seal Edge Sealing 1 Part Pumpable Hot Melt Terostat® 2781™ PIB Seal Edge Sealing 1 Part Pumpable Hot Melt Terostat® 2782™ Flexible PIB Seal Edge Sealing 1 Part Pumpable Hot Melt Terophon® 23100™ Mastic Butyl Mastic Tape 1 Part Tape Apply N/A Loctite® 5640™ Primerless 2K Silicone J-Box Potting 10:1 5 min. Self Mix *Note: SMP (Silyl Modified Polymer) 8 Junction Box Bonding & Sealing Loctite® Silicone – high performance bonding and sealing • In combination with Prism® Instant Adhesive, instant handling strength • Highly automated processes • Superb long-term resistance to hard weathering conditions • Excellent adhesion to glass, metal and plastics • IEC 61215/61646/61730 compliant • UL® listed • RoHS compliant Junction Box Preliminary Fixing Prism® Instant Adhesive • • • • • • Instant bonding strength Compatible with Loctite® 1K & 2K Silicone Highly automated processes Makes buffer storage systems redundant Excellent adhesion to glass, metal and plastics RoHS compliant Junction Box Potting Loctite® and Terostat® – self-leveling potting compounds according to your specific requirements • Butyls (water vapor tight) • Two-component silicones • UV curable resins 9 Silicon Wafers Cells/Modules Building-Integrated Photovoltaic THINFILM Thinfilm Module Production – Frameless and Flexible Modules Innovative ideas and fast process applications Frameless Sealing Terostat® Butyls – the water vapor tight solution • • • • • • • • Incorporated adhesion promoter provides excellent adhesion to glass Fully automatic nozzle application from bulk Excellent processability and high output with drum unloader Resistant to laminating temperature of 302°F (150°C) No waste of release paper Black color IEC 61646 compliant RoHS compliant Module Mounting Terostat® MS and Loctite® Silicones – high performance elastic bonding • • • • • 10 Outstanding resistance to mechanical loads and high wind loads Superb long-term resistance to hard weathering conditions Highly automated processes and very high production speed Excellent primerless adhesion to glass, metal and plastics RoHS compliant Silicon Wafers Building-Integrated Photovoltaic Cells/Modules FLEXIBLE Junction Box Bonding & Sealing Loctite® Silicone – high performance bonding and sealing • • • • • • • In combination with Prism® Instant Adhesive, instant handling strength Highly automated processes Superb long-term resistance to hard weathering conditions Excellent adhesion to glass, metal and plastics IEC 61215/61646/61730 compliant UL® listed RoHS compliant Product Description Application Ratio Fixture Cure Method Terostat® MS 647™ Fast 2K SMP Framing 10:1 15 min. Self Mix Terostat® MS 500™ Instant 1K Hot Melt SMP Framing 1 Part 2-3 min. Moisture Terostat® 2780™ PIB Seal Edge Sealing 1 Part Pumpable Hot Melt Terostat® 2781™ PIB Seal Edge Sealing 1 Part Pumpable Hot Melt Terostat® 2782™ Flexible PIB Seal Edge Sealing 1 Part Pumpable Hot Melt Terophon® 23100™ Mastic Butyl J-Box Sealing 1 Part Tape Apply None Loctite® 5640™ Primerless 2K Silicone J-Box Potting 10:1 5 min. Self Mix Loctite® 5600™ Instant 2K Silicone Rail Bonding 2:1 2-3 min. Self Mix Terostat® MS 650™ Fast 2K SMP Rail Bonding 10:1 5 min. Self Mix Loctite® 5606™ Medium 2K Silicone Rail Bonding 4:1 20 min. Self Mix *Note: SMP (Silyl Modified Polymer) 11 Silicon Wafers Building-Integrated Photovoltaic Cells/Modules Concentrator CPV – Concentrator Module Production Unique solutions for an emerging market Assembly of Housing High performance elastic bonding • Excellent primerless adhesion to metal • UV resistant • Outstanding resistance to mechanical loads and wind loads • Superb long-term resistance to hard weathering conditions • Highly automated processes and high production speed • RoHS compliant Product Description Application Ratio Fixture time Cure Method Terostat® MS 647™ Fast 2K SMP Lens to Housing 10:1 15 min. Self Mix Terostat® MS 510™ Medium 2K SMP Lens to Housing 10:1 45 min. Self Mix Terostat® MS 939™ Standard 2K SMP Lens to Housing 10:1 3 hr. Self Mix Loctite® 5600™ Instant 2K Silicone Lens to Housing 2:1 2 min. Self Mix Loctite® 5604™ Fast 2K Silicone Lens to Housing 4:1 5 min. Self Mix Loctite® 5606™ Medium 2K Silicone Lens to Housing 4:1 20 min. Self Mix Loctite® Nuva-Sil® 5084™ UV/Moisture Cure Silicone Lens Bonding 1 Part 20-40 sec. UV/Moisture Purfect Glaze® SA White™ Fast 1K PU 1 Part 1-2 min. Moisture *Note: SMP (Silyl Modified Polymer) 12 Mirror Bonding Glass Lens Bonding and Sealing Loctite® 2K Silicones – high performance elastic bonding on glass and metal • Superior liquid seal • Initial handling strength right after application • Excellent primerless adhesion to PMMA, glass and metal • Excellent primerless adhesion to glass and metal • Highly UV resistant • Outstanding resistance to mechanical loads and wind loads • Superb long-term resistance to hard weathering conditions • Highly automated processes and high production speed • RoHS compliant 13 Silicon Wafers Building-Integrated Photovoltaic Cells/Modules lamination Building-Integrated Photovoltaic with Flexible Modules Reliable lamination on flexible roofing membranes or rigid metal/plastic panels Laminating on Plastic or Metal Panels Laminating on Flexible Roofing Membranes Terostat® MS – the brand new high performance solution for fully automated processes Purmelt® and Macromelt® – hotmelt solutions for fully continuous roll-to-roll manufacturing • • • • • • • • • • Excellent adhesion to many plastics and to metal High bond strength Chemical crosslinking Highly weathering and temperature resistant Very elastic and durable bond line Two-component Terostat® MS: Together with our OEM partners, Henkel has developed a new application technology for flat lamination with two-component Terostat® MS products. One- or Two-component Terostat MS: The ideal UV resistant edge seal ® 14 Instant high tack Excellent adhesion to many plastics High bond strength Highly weathering and temperature resistant No creep at elevated temperatures Purmelt®: The PUR hot melt for flat lamination of the flexible modules Macromelt®: The highly UV resistant, black polyamide for edge sealing Self-Adhesive Terostat® Butyl Mastic: • Instant tack • Peel-n-stick ease • Tape or drum apply Product Description Application Ratio Fixture Cure Method Terostat® MS 642™ Metal Panel Bonding Installation 10:1 45 min. Self Mix Purmelt® QR 4571™ PVC Bonder Installation 1 Part 2-5 min. Moisture Purmelt® QR 513C™ Membrane Bonder Installation 1 Part 2-5 min. Moisture Macromelt® 6240™ Polyamide Edge Bond Edge Bonding 1 Part 1-2 min. Hot Melt Terostat® 2785™ Flexible Membrane Tape Installation 1 Part Mastic N/A Terophon® 23100™ Flexible Membrane Tape Peel-N-Stick 1 Part Mastic N/A Silicon Wafers Cells/Modules Installation Product Description Application Loctite® Natural Blue® Field cleaner, concentrated cleaner Cleaner Loctite® 243™ Liquid apply anaerobic Threadlocker Loctite® 249™ Paste apply anaerobic Threadlocker Loctite® C5-A® Copper general-purpose anti-seize Anti-seize Loctite® 5606™ Structural silicone for glass to rail bonding Glass bonder Alodine® T5700™ Wipes Aluminum cleaner/treatment wipes prior to bonding Metal prep Bonderite® 1455™ Wipes Steel cleaner/treatment wipe prior to bonding Metal prep Terostat® MS 939™ Pumpable bonder for flexible panel to TPO at edge Flexible edge seal Terophon® 23100™ Peel and stick butyl mastic Flexible panel bonding Terophon® 23100™ Die-cut gasket for sealing around roof penetration Roof penetration seal Fixmaster® Anchor Bolt Grout HP Concrete anchoring adhesive for tower mounts Anchoring adhesive Loctite® 5640™ UL® approved potting material General potting Loctite® 435™ Instant bonding adhesive Instant adhesive 15 Photovoltaic and more… Electrical Devices Electronics protection for outdoor applications under extreme conditions Grommet and Junction Macromelt® Molding • Molding of cable junction • Preassembling of the cable with simultaneous sealing and strain relief Connectors Macromelt® Molding • Molding of connectors • Sealing of contact area • Strain relief of cables Junction Box Assembly Terostat® MS • Fixing of electrical parts • Bonding of housing and cover 16 Protection of Electronics against Weather and UV Radiation Macromelt® Molding – the innovative process solution • Extremely short cycle time compared to traditional two-component casting • Makes the application of plastic housing redundant due to its plastic-like attributes • Process approved and clean in handling • Service temperature range from -40°F to 266°F (-40°C to +130°C) • Protects devices effectively against environmental influences Quick Reference Guide Application Product Description Ratio Fixture Time Cure Method J-Box Bonding Loctite 5970™ RTV Silicone 1 Part 3 hr. RTV J-Box POtting Loctite® 5240™ UV Cure 1 Part 5-20 sec. UV/Moisture Loctite 5611™ F Fast Silicone 10:1 2-3 min. Self Mix Loctite 5640™ Primerless Silicone 10:1 5 min. Self Mix Terophon 23100™ Mastic Butyl 1 Part Tape Apply None Instant Silicone 2:1 2-3 min. Self Mix Terostat MS 650™ Fast SMP 10:1 5 min. Self Mix Loctite 5606™ Standard Silicone 4:1 20 min. Self Mix Loctite 5600™ Instant Silicone 2:1 2 min. Self Mix Loctite 5604™ Fast Silicone 4:1 5 min. Self Mix Loctite 5606™ Standard Silicone 4:1 20 min. Self Mix Loctite 5905™ RTV Silicone 1 Part 3 hr. RTV Terostat MS 500™ Instant Hot Melt SMP 1 Part 2-3 min. Moisture Terostat MS 647™ Fast SMP 10:1 15 min. Self Mix Terostat MS 647™ Fast SMP 10:1 15 min. Self Mix Terostat MS 510™ Medium SMP 10:1 45 min. Self Mix Terostat MS 939™ Standard SMP 10:1 3 hr. Self Mix lens Bonding Nuva-Sil 5084™ UV Cure/Moisture Cure Silicone 1 Part 20-40 sec. UV/Moisture Mirror bonding Purfect Glaze SA White™ Fast PU Hot Melt 1 Part 1-2 min. Moisture Fixturing Loctite 460™ Prism Instant Adhesive 1 Part 10-30 sec. Moisture Edge Sealing ® Terostat 2780™ PIB Seal 1 Part Pumpable Hot Melt Terostat® 2781™ PIB Seal 1 Part Pumpable Hot Melt Terostat 2782™ Flexible PIB Seal 1 Part Pumpable Hot Melt Terostat MS 642™ Metal Panel Bonding 10:1 45 min. Self Mix Loctite 243™ Medium Strength Threadlocker 1 Part N/A Anaerobic Loctite C5-A Copper Anti-Seize Lubricant 1 Part N/A N/A Purmelt QR 4571™ PVC Bonder 1 Part 2-5 min. Moisture Purmelt QR 513C™ Membrane Bonder 1 Part 2-5 min. Moisture Terophon 2785™ Flexible Membrane Tape 1 Part Mastic None Edge bonding Macromelt 6240™ Polyamide Edge Bond 1 Part 1-2 min. Hot Melt Peel-N-Stick Terophon 23100™ Flexible Membrane Tape 1 Part Mastic None ® ® ® J-BoX Sealing ® Back Rail Bonding Loctite 5600™ ® ® ® Framing ® ® ® ® ® ® lens to housing ® ® ® ® ® ® ® Installation ® ® ® ® ® ® ® ® ® ® *Note: SMP (Silyl Modified Polymer) 17 Solar Market Subsegment - Applications & Lead Materials Crystalline Silicon Module Henkel Application Potential Lead Material Frame Bonding......................................... Terostat® MS 647™ J-box Bonding.......................................... Loctite® 5970™ J-box Potting............................................ Loctite® 5640™ Back Rail Bonding – Manual...................... Loctite® 5606™ Back Rail Bonding – Automated................. Terostat® MS 650™ Frame Threadlocking................................. Loctite® 243™ Silicon Wafer Production Ingot Bonding........................................... Loctite® 3388P™ (2K Epoxy) Wafer Cleaning – Pre-clean....................... P3® Synergic™ 9210™ Wafer Main Cleaner.................................. P3® Allpass™ 230™ Rigid Thin Film – CdTe, CIGS, a-Si, Organic Frame Bonding......................................... Terostat® MS 647™ (2-part) J-box Bonding.......................................... Loctite® 5970™ (1K Silicone) J-box Potting............................................ Loctite® 5640™ (2K Silicone) Module Mounting (Back Rails).................... Loctite® 5600™ (Two-part) Frame Thread Locking............................... Loctite® 243™ Edge Sealing – PIB................................... Terostat® 2782™ Flexible Thin Film – BIPV a-Si, CIGS, CdTe, Organic J-box Bonding.......................................... Loctite® 5970™ (1K Silicone) J-box Potting............................................ Loctite® 5640™ (2K Silicone) Module Peel-N-Stick Butyl......................... Terostat® 23100™ Module Edge Bonding............................... Macromelt® 6240™ Building Roof Membrane Bonding.............. Purmelt® QR4571™ Cable Connect Overmold........................... Macromelt® OM 648™ Concentrated Photovoltaics (CPV) Metal-to-Metal Bonding............................. Loctite® H4500™ Anti-weld Spatter...................................... Aerodag® Ceramishield® Steel Clean/Prime..................................... Bonderite® 1455™ Wipes Aluminum Clean/Prime.............................. Alodine® 5700™ Wipes Frame/Tracker Corrosion Protection................. Aquence® 930™ Frame/Tracker Bonding............................. Terostat® MS 647™ Mirror Bonding.......................................... Purfect Glaze® SA White Glass Module Edge Seal............................ Loctite® 5970™ (1K RTV Silicone) J-box Potting............................................ Loctite® 5640™ (2K Silicone) J-box Bonding.......................................... Loctite® 5970™ (2K Silicone) Water Vapor Seal...................................... Terostat® 2781™ Glass/Mirror Primer................................... Terostat® 8519P™ Threadlocker............................................ Loctite® 243™ Concentrated Solar Power (CSP) Metal-to-Metal Bonding............................. Loctite® H4500™ Anti-weld Spatter...................................... Aerodag® Ceramishield® Steel Clean/Prime..................................... Bonderite® 1455™ Wipes Aluminum Clean/Prime.............................. Alodine® 5700™ Wipes Metal Corrosion Protection & Prime............ Aquence® 930™ Frame/Tracker Bonding............................. Terostat® MS 647™ Mirror/Reflector Bonding........................... Loctite® 3370™ Mirror Lamination, Primerless VOC-free........ Terostat® MS 647™ Mirror Lamination – with Primer................. Loctite® 3370™ Composite Mold Release........................... Frekote® Glass/Mirror Primer................................... Terostat® 8519P™ Metal Cutting Lubricant............................. Multan® B-240™ Threadlocker............................................ Loctite® 243™ Solar Module Operation & Maintenance Cleaning Glass Panel Cleaner.................................. Loctite® Natural Blue® Solar Array Cleaner................................... P3® Glin Plus Glass Cleaner........................................... P3® Grato™ 3000™ 18 Henkel – Sustainable Solutions About us Founded in 1876 in Germany by Fritz Henkel, the company is now represented in more than 125 countries. Henkel operates in three strategic business areas – laundry and home care, personal care, and adhesives, sealants and surface treatments. We hold an internationally leading position in environmental and consumer protection. This derives not least from Henkel’s pronounced capability to innovate. Henkel is the world leader in adhesives, sealants and surface treatments. With its exceptionally broad range of products and specific process know-how, Henkel offers unique business opportunities for industrial customers in almost all sectors. Our customers receive tailor-made system solutions, optimally adapted to their production and manufacturing processes. Production centers on all continents assure optimum supply and logistics in all regions of the world. Industrial Adhesives, Sealants and Cleaners Henkel offers the world’s most extensive portfolio of adhesives, sealants and surface treatments for industrial applications worldwide. Henkel Corporation Engineering Adhesives www.henkelna.com/solar USA Canada Mexico Henkel Corporation Engineering Adhesives One Henkel Way Rocky Hill, Connecticut 06067 Tel: 1.800.LOCTITE (562.8483) Tel: 860.571.5100 Fax: 860.571.5465 Henkel Canada Corporation Engineering Adhesives 2225 Meadowpine Blvd. Mississauga, Ontario L5N 7P2 Tel: 1.800.263.5043 (within Canada) Tel: 905.814.6511 Fax: 905.814.5391 Henkel Capital, S.A. de C.V. Boulevard Magnocentro No. 8 Piso 2 Centro Urbano Interlomas 52760 Huixquilucan, Estado de Mexico Technical Product Assistance: 52.55.3300.3669 To place an order: 52.55.3300.3644 Fax: 52.55.3300.3019 Except as otherwise noted, all marks used are trademarks and/or registered trademarks of Henkel and/or its affiliates in the U.S. and elsewhere. ® = registered in the U.S. Patent and Trademark Office. UL is a registered trademark of Underwriters Laboratories Inc. © Henkel Corporation, 2012. All rights reserved. 7772/LT-6101 (2/12)
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