Appearance of Barium in Lithium-Iodine Plasma Edward Esko* ABSTRACT In studies conducted at Quantum Rabbit (QR) lab in Owls Head, Maine on April 10, 2013, funded by Woodland Energy and the New Energy Foundation, independent analysis of test samples by inductively coupled plasma mass spectroscopy (ICP-MS) revealed the anomalous presence of barium (Ba). Isotope distribution studies further revealed the presence of barium isotopes at variance with their natural distribution, notably elevated values for barium-134. The vacuum discharge tests employed copper (Cu) electrodes and lithium (Li) and iodine (I) test material. The appearance of novel isotope distribution in test samples diminishes the possibility that these results are due to contamination. Test results raise the possibility that barium was newly created through low energy transmutation. nuclear materials through LENR.” I proposed conducting tests on the following low energy fusion formula: 127I + 7Li → 134Ba iodine-127 + lithium-7 → barium-134 I went on to state: “Barium-134, the hypothetical transmutation product of iodine-127 and lithium-7 makes up 2.4% of naturally occurring barium isotopes. If test samples were found to contain barium-134 in amounts greater than this, it would help rule out contamination as the source of barium and offer proof of transmutation.” In Test 2 conducted on April 10, barium-134 was found at 4.04%, nearly double the quantity found in naturally occurring barium. BACKGROUND THE LITHIUM-IODINE STUDY In my paper “Preliminary Research on Nuclear Remediation” (IE #110, July/August 2013), I proposed beginning research into possible LENR nuclear remediation with tests on nonradioactive isotopes of strontium, iodine and cesium, the concept being that if these non-radioactive isotopes are successfully transmuted, it may be possible to apply LENR to transmuting their radioactive isotopes. If scalable, low energy transmutation could offer a sustainable solution to the nuclear waste problem. As I stated in my paper: “The goal of the iodine study is to transmute the stable isotope of iodine (I-127) into barium (Ba-134) through low energy nuclear reactions as another step in demonstrating the possibility of the remediation of The procedure of the study was exceedingly simple. We conducted three experiments using the vertical vacuum tube deployed in previous tests. Copper electrodes were inserted in the upper and lower ends of the tubes. A lithium plug was inserted in the center of the lower electrodes in Tests 1 and 2. Pure iodine crystals were placed on top of the lithium inserts. In Test 3, for variation, no lithium plug was used. Instead a small piece of lithium was placed in the center of the lower copper electrode. Iodine crystals surrounded the lithium. After pumping down to 3.5 torr, oxygen was admitted and the power turned on. When the arc was established and plasma struck, additional heat was provided by a hand-held Figure 1. The experiment tested the formula iodine-127 + lithium-7 → barium-134. Figure 2. The vertical tube used in the April 10 experiments. 1 INFINITE ENERGY • ISSUE 111 • SEPTEMBER/OCTOBER 2013 torch. The arc was maintained for approximately 10 to 15 minutes, at which time the power was disconnected and the tubes allowed to cool. Below is the worksheet I prepared prior to the experiments. 3. 4. 5. 6. 7. 8. Position electrode in tube. Maneuver upper electrode into position. Pump down to approx. 3.5 torr. Admit O2 fill and strike plasma. Apply torch as needed (optional). Continue approx. 15 minutes. Lithium-Iodine Study — April 10, 2013 Note: In Test 3, a piece of Li is placed on the lower electrode together with I, rather than inserting the Li plug in the electrode. Testing for 134Ba, 134Cs. Inputs: Copper electrodes Lithium test material Iodine test material Oxygen fill Procedures: 1. Insert Li plug in lower Cu electrode. 2. Place I on surface of Li plug (do not cover completely). All three tests proceeded according to plan. (See real time video of the experiments: YouTube.com/QuantumRabbit. Click on “Cool Fusion Science Iodine Study.”) We adjusted the electrode polarity between Test 1 and Tests 2 and 3. In Test 1, the upper electrode served as the anode, and in Tests 2 and 3, the upper electrode served as the cathode. The power supply was the same as that described in my earlier papers (see “Anomalous Metals Part II,” IE #103, May/June 2012). Three sets of samples were collected, labeled and packed for shipping. The samples were sent to Northern Analytical Laboratory in Londonderry, NH with the following instructions: Guidelines for Sample Analysis — April 2013 Sample Materials: A. Test 1: One thick copper electrode (with lithium insert and lithium-iodine residue); one thin copper electrode; and one glass tube. B. Test 2: One thick copper electrode (with lithium insert and lithium-iodine residue); one thin copper electrode; and one glass tube. C. Test 3: One thick copper electrode with lithium-iodine residue; one thin copper electrode; and one glass tube. Requested Analysis by ICPMS: Barium (isotope distribution percentage) Cesium Procedure for Each Sample: Figure 3. Tests 1 and 2 used a lithium insert. Test 3 used a piece of lithium surround- 1. Scrape surface (top and sides) of Cu eleced by iodine crystals. trodes, including surface of Li insert. 2. Collect powder and flake residue (loose material) from plastic baggie. 3. Scrape residue from inner surface of tube. 4. Combine scrapings and loose material into one sample for analysis. Note: Each sample to be analyzed separately. ISOTOPES OF BARIUM Figure 4. Lithium rod (left) and iodine crystals (right). Results came back on May 6. As predicted, barium was found in all three of the test samples, albeit in microscopic quantities (see Figure 7). In Test 1 barium was found at 3.5 ppm, in Test 2 at 1.8 ppm, and in Test 3 at 463 ppm. According to the Certificates of Analysis from Alfa Aesar, SEPTEMBER/OCTOBER 2013 • ISSUE 111 • INFINITE ENERGY 2 the supplier of the pure elements used in the test, barium was listed at <0.0005 ppm in the copper used for the electrodes. The lithium used in the test showed no value for barium, nor did the iodine crystals. The Certificate of Analysis for iodine is as follows: Product No.: 00158 Product: Iodine, crystalline, 99.99+% (metals basis) Lot No.: D22X020 Purity 99.99% Nonvolatile matter 0.004% Chlorine and bromine (as Cl) <0.005% To provide a further control, we sent a sample of the iodine used in the tests to Northern Analytical Laboratory with instructions to test for barium (Figure 6). The control sample was taken from the same batch used in the experiments. The test results came back showing traces of barium in the iodine at 0.43 ppm, far below the amounts detected in the test samples. For example, in Test 1, the amount of barium was eight times greater than that detected in the control, in Test 2, more than four times greater than the control, and in Test 3, barium was detected at a level more than 1,000 times greater than that detected in the control. The values of barium before and after the experiment were: Starting Concentration (ppm)* 0.43 0.43 0.43 Final Concentration (ppm)** 3.5 (Test 1) 1.8 (Test 2) 463 (Test 3) *Source: Test Report from Northern Analytical Laboratory, 6/19/13 **Source: Test Report from Northern Analytical Laboratory, 5/6/13 Figure 5. Vertical tube used in lithium-iodine study. 3 The distribution of barium isotopes in the test samples varied somewhat from the distribution found in nature, suggesting the possibility that detected barium was newly created through low energy transmutation and not introduced through contamination. A comparison of the isotope distribution of natural barium (National Nuclear Data Center) and the barium found in the April 10 experiments )see Figure 7) is as follows: Isotope Ba132 Ba134 Ba135 Ba136 Ba137 Ba138 Naturally Occurring % Test 1 % Test 2 % Test 3 % 0.101 1.36 3.92 0.19 2.417 2.73 4.04 2.42 6.592 6.62 6.18 6.72 7.854 8.17 8.68 8.04 11.232 10.9 10.9 11.9 71.698 70.2 66.3 70.8 The greatest variance in isotope distribution was seen in Test 2, with Ba-132 appearing at 3.92% compared to 0.101% in nature; Ba-134 at 4.04% compared to 2.417%; and Ba-138 at 66.3% compared to 71.698%. INTERPRETATION Low energy fusion between iodine (atomic number 53) and lithium (atomic number 3) could explain the consistent appearance of barium (atomic number 56) in all three tests, with a peak at 463 ppm in Test 3. The distribution of barium isotopes is perhaps more difficult to understand. Ba-134 can be accounted for by the fusion of iodine-127 and lithium-7. That formula was predicted beforehand. Barium-132 may have arisen following the ejection of a neutron at the moment of fusion between Li-6 and I-127. Perhaps the low energy fusion process releases neutrons, some of which are captured by newly formed barium-134 nuclei, thus explain- Figure 6. June 19, 2013 test report from Northern Analytical Laboratory. INFINITE ENERGY • ISSUE 111 • SEPTEMBER/OCTOBER 2013 ing the formation of isotopes heavier than Ba-134. More study is needed to fully explain the origin of the anomalous isotopes found in these experiments. About the Author Edward Esko is founder and president of Quantum Rabbit LLC. He designed the Quantum Rabbit® vacuum tubes used in the above research, plus the formulas and protocols utilized in QR studies. Esko is coauthor, with Alex Jack, of Cool Fusion: A Quantum Approach to Peak Minerals, Nuclear Waste and Future Metals Shock (Amber Waves, 2011), which features a compilation of his articles from Infinite Energy describing the Quantum Rabbit research. *109 Wendell Avenue, Pittsfield, MA 01201 Email: [email protected] Website: www.coolfusion.org Figure 7. May 6, 2013 test report from Northern Analytical Laboratory. SEPTEMBER/OCTOBER 2013 • ISSUE 111 • INFINITE ENERGY 4
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