MATERIAL SAFETY DATA SHEET
Manganese(II) Oxide - feed additive
Material safety data sheet according to 1907/2006/EC, article 31
1.
IDENTIFICATION OF THE PRODUCT AND THE COMPANY
Trade name:
Manganese(II) Oxide – feed additive
Synonyms:
Other name:
Intended use:
Manganous Oxide, Mangaan Oxide, Oxide de Manganese
Feed additive. Compounds of trace elements, content:
manganese(II)oxide(E5)
As an mineral feed additive for animals
Material safety data sheet supplier
Gambit Humański, Janiszewski sp.j.
99-300 Kutno; Spółdzielcza Str. 3
0048 24 2547073
0048 24 2544880
[email protected]
Name:
Add:
Telephone:
Fax:
e-mail:
Website:
Emergency telephone
number:
Date of preparation:
Date of revision:
2.
www.gambitkutno.pl
+48 (024) 2547073 or +48 (0)601335519
02.01.2015
10.03.2015
HAZARDS IDENTIFICATION
The product is classified as the hazardous product in the sense of Regulation (EC) No 1272/2008 of
the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and
1999/45/EC, and amending Regulation (EC) No 1907/2006
In accordance with the criteria of Regulation (EC) No 1272/2008 product is not classified as
hazardous.
Inhalation:
Inhalation:
May cause irritation to the respiratory tract.
Ingestion:
May cause abdominal pain and nausea.
Skin contact:
May cause irritation with redness and pain. Small particles embedded into the skin can cause
localized inflammatory reactions.
Eye contact:
May cause irritation, redness and pain
3.
COMPOSITION/INFORMATION ON INGREDIENTS
Manganese(II) Oxide as MnO – min. 78%
CAS No:
EINECS No:
Index No:
4.
13463-43-9
215-695-8
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FIRST AID MEASURES
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an
Manganese(II) Oxide – feed additive
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MATERIAL SAFETY DATA SHEET
Manganese(II) Oxide - feed additive
Material safety data sheet according to 1907/2006/EC, article 31
4.
FIRST AID MEASURES
unconscious person. Get medical attention.
Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated
clothing and shoes. Wash clothing before use. Thoroughly clean shoes before reuse. Get medical
attention if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids
occasionally. Get medical attention if irritation persists.
5.
FIRE FIGHTING MEASURES
Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing
apparatus with full face-piece operated in the pressure demand or other positive pressure mode.
6.
ACCIDENTAL RELEASE MEASURE
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill.
Wear appropriate personal protective equipment as specified in Section 8. Spill: Pick up and place in
a suitable container for reclamation or disposal, using a method that does not generate dust.
7.
HANDLING AND STORAGE
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical
damage. Do not stack pallets.
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
5 mg/m3 Ceiling for manganese compounds as Mn
ACGIH Threshold Limit Value (TLV)
0,2 mg/m3 (TWA) for manganese, elemental and inorganic compounds as Mn
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the
Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the
emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices,
most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face dust/ mist respirator may be worn for up to ten times the
exposure limit or the maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest. A full-face dust/mist respirator may be worn up to 50 times
the exposure limit or the maximum use concentration specified by the appropriate regulatory agency,
or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels
are not known, use a full-face piece positive-pressure, air-supplied respirator. Warning: Air-purifying
respirators do not protect workers in oxygen-deficient atmospheres.
Skin protection:
Wear protective gloves and clean body-covering clothing
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is
possible. Maintain eye wash fountain and quick-drench facilities in work area.
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MATERIAL SAFETY DATA SHEET
Manganese(II) Oxide - feed additive
Material safety data sheet according to 1907/2006/EC, article 31
9.
PHYSICAL AND CHEMICAL PROPERTIES
Formula
Physical form
Colour
Odour
Density
Molecular weight
pH
Moisture
Boiling point
Melting point
Vapor density (Air=1)
Vapor pressure (mm Hg)
Evaporation rate (BuAc=1)
Solubility
10.
MnO
Solid, Free Flowing Powder
Greenish Brown
Odourless
1,80 – 1,90 g/cm3
70.94
No information found
Max. 2%
1945°C
No information found
Not applicable
Not applicable
No information found
Water insoluble/ Acid soluble
STABILITY AND REACTIVITY
Stability:
Stable under ordinary conditions of use and storage.0
Hazardous Decomposition Products:
Oxides of manganese may form when heated to decomposition.
Hazardous Polymerization: Will not occur
Incompatibilities: Reacts vigorously with strong reducing agents, acids or bases.
Conditions to Avoid: Incompatibles
11.
TOXICOLOGICAL INFORMATION
No LD50/LC50 information found relating to normal routes of occupational exposure.
Acute toxicity:
Oral mouse LD50: 1000 mg/kg
12.
ECOLOGICAL INFORMATION
Environmental Fate
Environmental Toxicity
13.
: No information found.
: No information found.
DISPOSAL CONSIDERATIONS
Whatever cannot be saved for recovery or recycling should be manager in an appropriate and
approved waste disposal facility. Processing, use or contamination of this product may change the
waste management options. State and local disposal regulations may differ from federal disposal
regulations. Dispose of container and unused contents in accordance with federal, state and local
requirements.
14.
TRANSPORT INFORMATION
It is not classified, that is not regarded as dangerous goods under the UN Orange Book and
international transport codes e.g. RID (rail), ADR (road) and IMDG (sea).
15.
REGULATORY INFORMATION
Directives 1999/45/EC and 67/548/EEC and relative amendments and additions
Directive 2000/39/EC and relative amendments and additions
Manganese(II) Oxide – feed additive
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MATERIAL SAFETY DATA SHEET
Manganese(II) Oxide - feed additive
Material safety data sheet according to 1907/2006/EC, article 31
15.
REGULATORY INFORMATION
Directive 1999/13/EC and relative amendments and additions
Directive 1996/82/EC and relative amendments and additions
Directive 2000/60/EC and relative amendments and additions
Directives 91/156/EEC, 91/689/EEC and 94/62/EC and relative amendments and additions
Directive 89/391/EEC and relative amendments and additions
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006
Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on
detergents
Directive 91/155/EEC as amended by Commission Directive 93/112/EC of 10 December 1993
Commission Directive 2006/8/EC of 23 January 2006 amending, for the purposes of their adaptation
to technical progress, Annexes II, III and V to Directive 1999/45/EC of the European Parliament and
of the Council concerning the approximation of the laws, regulations and administrative provisions of
the Member States relating to the classification, packaging and labelling of dangerous preparations.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008
on classification, labelling and packaging of substances and mixtures, amending and repealing
Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Labelling according to Regulation (EC) No 1272/2008 – does not require warning signs.
16.
OTHER INFORMATION
Product Use:
As an mineral feed additive for animals.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designation and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information: 10.03.2015
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