FloraTech 291 East El Prado Court Chandler, Arizona 85225 TEL 480.545.7000 FAX 480.892.3000 To find your local Floratech Sales Representative, visit: FloraTech global partners sharing Emollients F o r m u l at i o n G u i d e Quality Innovation Service FloraTech has grown naturally, from the ground up. We started with a small jojoba oil mill in the Sonoran Desert near Apache Junction, Arizona. Over the past 30 years we have grown into a modern botanical derivative research and manufacturing center in central Arizona. Our growth has been achieved by providing you, our customer, with products and services that reflect our industry leadership and dedication to Quality, Innovation and Service. While the information provided here is believed to be reliable, we do not guarantee its accuracy. Customers are encouraged to conduct their own tests with materials described herein. © 2007 International Flora Technologies, Ltd. FLORATECH , FLORAESTERS , FLORASUN , FLORAMAC , FLORASOLVS , FLORABEADS , FLORASOMES , FLORAPEARLS , FLORASPHERES are registered trademarks of International Flora Technologies, Ltd. ® ® ® ® ® ® ® FloraTech Quality is managed in accordance with the ISO 9001 standards as certified by the British Standards Institute. We are the first ISO 9001 certified jojoba oil manufacturer. FloraTech Innovation is established by offering unique jojoba oil derivatives and specialty plant-derived cosmetic ingredients. FloraTech Service is delivered through an extraordinary international network of experienced cosmetic ingredient suppliers supported by our analytical and cosmetic laboratories. A ® ® FloraTech’s Quality Policy: Floratech will provide products and services to our customers and distributors that meet their requirements. We will continually improve the quality of our products and services, the Floratech culture, customer satisfaction and our ability to offer innovative new products. James H. Brown President A quantitative comparison of 20 common emollient ingredients’ relative attributes. B C At Floratech, we tested 20 different common emollients and measured 10 important attributes: TABLE 1 Emollient Spread Slip Occlusivity Viscosity OSI 22.10 84.50 1.09 62.0 7.6 OSI with 10% Iron Oxide Fragrance Fixative 2.00 0.33 Moisturization Penetration 32.32 The purpose of this study is... Refractive Index A Almond Oil 6.8 1.462 B Castor Oil 7.04 82.90 1.10 875.0 21.0 4.40 0.38 32.80 3.3 1.471 C Decyl Oleate 29.40 84.00 1.00 15.8 12.0 0.15 0.53 33.59 4.4 1.450 D Ethyl Hexyl Palmitate 34.60 78.70 1.05 11.1 92.5 68.60 1.12 28.40 5.6 1.439 E Floraesters 15 * 30.10 82.30 1.01 31.5 95.0 63.70 0.67 34.81 5.1 1.458 F Floraesters IPJ * 30.60 82.90 0.64 20.2 95.0 60.70 0.76 33.77 4.7 1.452 G Floramac 10 * 31.90 75.80 0.20 6.6 24.0 27.60 1.40 31.41 6.5 1.443 H Florasun 90 * 19.60 76.60 0.76 73.5 52.0 16.90 0.82 35.97 2.6 1.462 I High Oleic Safflower 17.20 82.60 1.17 67.0 12.0 3.20 0.80 35.14 6.0 1.463 J Jojoba Oil * 28.10 81.55 0.73 34.5 34.0 6.50 0.41 34.42 3.6 1.459 K Macadamia Oil * 23.20 83.10 0.66 61.0 72.0 41.90 0.60 35.61 8.2 1.461 L Mineral Oil 15.40 78.60 1.45 120.7 66.0 29.35 0.23 28.63 1.4 1.451 M Octyl Dodecanol 20.60 77.30 1.27 43.3 0.1 0.10 0.46 25.11 1.8 1.446 N Octyl Stearate 35.10 86.40 0.95 13.3 68.0 35.90 1.45 30.19 4.4 1.447 O Oleyl Alcohol 26.40 76.60 0.74 29.4 0.9 0.70 0.64 28.08 7.0 1.452 P Oleyl Erucate 26.82 84.80 1.25 39.6 5.2 1.70 0.62 28.53 5.2 1.458 Q Olive Oil 20.80 82.20 1.18 67.6 3.9 2.80 0.45 30.77 0.4 1.462 R Rice Bran Oil 23.20 88.50 1.18 62.0 7.8 1.75 0.77 31.23 2.5 1.467 S Soybean Oil 26.80 84.80 1.09 50.0 6.0 2.65 0.29 27.79 2.0 1.467 T Squalane 29.99 77.80 1.43 26.3 26.3 16.10 1.00 28.58 5.8 1.444 Average 24.95 81.60 1.00 85.5 35.1 19.34 0.69 31.36 4.4 1.456 Minimum 7.04 75.80 0.20 6.6 0.1 0.10 0.23 25.11 0.4 1.439 Maximum 35.10 88.50 1.45 875.0 95.0 68.60 1.45 35.97 8.2 1.471 ...to make direct comparisons between twenty different common emollients. This study helps the formulator to select emollients based on their relative attributes. This study measures selected attributes of each emollient and displays the numerical results in Table 1. These results generate charts 1 through 45, which simultaneously display two attributes of all 20 emollient ingredients in graph form. This display allows the formulator to evaluate two attributes of different ingredients simultaneously and to more easily select ingredients based on these attributes. A key showing attribute combinations is given in Table 2. Information about units, test methods, etc. are found on pages 8 and 9. How to read the graphsEach graph displays a comparison of 2 attributes of each of the 20 chosen emollients. The first attribute in the title is scaled along the horizontal (x) axis, and the second attribute in the title is scaled along the vertical (y) axis. All 20 emollients are plotted according to the x and y coordinates (see Table 1 for these respective values). Both the x and y axes intersect at each other’s average value. The minimum and maximum limits for each axis are determined by the minimum and maximum values measured among the 20 emollients. (This is why the graphs are not always perfectly symmetrical crosses). Each emollient is shown by its corresponding letter as read from Table 1. Results are reported in positive terms; for example, a high result for Slip means the material is more slippery and is graphically represented toward the right (x) or upward (y). *Available from Floratech - see page 11 1 2 3 4 5 6 7 8 10 11 12 13 14 15 16 17 18 19 20 21 22 23 25 26 27 28 29 30 31 32 33 34 36 37 38 39 40 41 42 43 44 read on x axis 45 2 35 24 9 K A HIGH PENETRATION O T P C x-axis E F J B H L R M Q Each letter represents its corresponding emollient ingredient in Table 1. The letterʼs position indicates its corresponding emollientʼs measured value for the displayed attribute. So, where are the Numbers? G I S LOW PENETRATION D N HIGH SPREAD Spread Slip Occlusivity Viscosity Oxidative Stability (OSI) OSI with 10% Iron Oxide Fragrance Fixative Moisturization Refractive Index read on y axis Spread vs Penetration 1 y-axis vs First attribute in title (i.e. “Spread”) is read on the x-axis (horizontal). The second attribute is read on the y-axis (vertical). LOW SPREAD Table 2 Key to locating each graph by number Pe ne t R e rati o f ra n M ctiv e oi stu I nd F r riz ex ag at io r OS ance n Iw Fi Ox ith 1 xati i d 0% ve a V i ti ve Iron sc o S t Ox Oc sity abi l ide i ty cl u (O S l si vi SI ip ty ) Graph number as shown in Table 2. The measured values are all found in Table 1. The graphʼs purpose is to provide spatial illustration of each emollientʼs relative attributes. For example, point P shows us that Oleyl Erucate has a higher than average Spread value along with a higher than average Penetration value. 3 For an example of how to read these graphs, please refer to graph 1. Spread vs Refractive Index 2 Slip vs Penetration 10 Spread vs OSI 6 Slip vs OSI with 10% Iron Oxide 14 B EF R K D D E S O I G K H Q A K N L P J T E I D O F C T N M G Spread vs Moisturization H 7 K I H T H Q D O S P J O 8 TE F C 5 N G I B A DN O O K E Slip vs Viscosity L C A G R Q H Q I J T O L M J O M G S Spread vs Slip 9 Spread vs OSI with 10% Iron Oxide T D Slip vs Fragrance Fixative F L M P N L B C K I Q H J I O H B 4 I T Q A R M S OP D L T M J H C E O G E H O R F J AS C T F E G B D D P S R QI N A N N G K C Slip vs Occlusivity 17 T R E F P E D G 13 R S P S D J A A K F R B N H F E D N M K I F CE C S AP Q 16 Slip vs Moisturization 12 B S B D P R J T G I J M Q C C L N P F T T B K L T G Spread vs Occlusivity L D K E H G M Q E F R M N O P R Slip vs OSI 15 A K L R A K M R S C AP H Spread vs Fragrance Fixative H QI B D I Q J M I O M Slip vs Refractive Index 11 G P OS J L B I L T Q Spread vs Viscosity N 4 M L R H R S A Q L G S CF B N N B B E J C H C S P O A R Q M D 3 G B I T F J J K P E H L F A N FK P K C M J L Q B A S G 5 For an example of how to read these graphs, please refer to graph 1. 18 Occlusivity vs Penetration 22 Occlusivity vs OSI with 10% Iron Oxide K O I D T F S H L G B H C R S H M L C Occlusivity vs Refractive Index S H A F E K E N T R T D T G B C Q Q M 32 Viscosity vs Fragrance Fixative 28 OSI vs Refractive Index N G B SR L C D Q A T I H R Q N H P D O TL S E F E O J D NC H F K O J IR E C Q H B M E J F A Q R B G N L G H L J C P O S H T S Q K I N R L OSI vs Moisturization 33 K J M D C F P B A S L E F E P T Q A I T D N T G D A G M F L C M Viscosity vs OSI with 10% Iron Oxide 29 N O K S K G O B T Viscosity vs Penetration 25 P E H C N C D G Occlusivity vs Fragrance Fixative R I F R PM J O M I A S K Q K J P G 6 H L B A 21 J R S I E E F N B L S R Q P M B H D C P O T P I Occlusivity vs Viscosity 24 G I M A S O J A N D Occlusivity vs Moisturization O G J M G K A L C OSI vs Penetration I J L M 31 B N R A Q S P H CF P O F Viscosity vs Moisturization ED K Q I O 27 H K C R I J B T D Occlusivity vs OSI 23 B T G L M G B S IQ A R PM O O F N T J Q 20 L N J J K N EJ P N C K E B R I A Q H K K P E F D A G F Viscosity vs OSI 30 E F 19 Viscosity vs Refractive Index 26 D O PM S R IQ A T L D B M 7 For an example of how to read these graphs, please refer to graph 1. 37 OSI with 10% Iron Oxide vs Refractive Index OSI vs Fragrance Fixative 34 Fragrance Fixative vs Penetration 40 Moisturization vs Penetration 43 K N G D H F O P K C MQ E L I F C K G K J L T P E O N Fragrance Fixative vs Moisturization 42 OSI with 10% Iron Oxide vs Fragrance Fixative D P N C R MS D F E A O F C T K I E G B D J C M Q BJ A S L Q Slip – F K P E J E L P O S T D L in vitro, percentage - the portion of standard P5 filter paper over which 20 drops of the test emollient will spread in 10 minutes. Larger values represent higher spread. in vitro, degrees - inclination angle from vertical at which a standard weight, lubricated by test emollient, will begin to slide on a standard glass plane. Larger values represent higher slip. in vitro - the inverse of the rate at which water transpires through an area of standard filter paper bearing film of test emollient. Larger values represent higher occlusivity. Viscosity – in vitro, poise - the force needed to move a standard spindle through the test emollient at constant temperature and velocity. Larger values represent higher viscosity. in vitro, hours - identical to OSI, in the presence of 10% untreated Iron Oxide pigment. Fragrance Fixative – Moisturization – Penetration – Refractive Index – R S L Q M Oxidative Stability (OSI) – B H M Occlusivity – OSI with 10% Iron Oxides – C F DEFINITIONS Spread – N N H OP H I T G R Q A G T RI Refractive Index vs Penetration 45 H K N G D D J OA N M G M H F C T T 39 K J E O L F C D I A P M G B Q J B R H N K 8 I Q A P O S OSI with 10% Iron Oxide vs Penetration I S R L H T QS I M O PA R C S L G Moisturization vs Refractive Index B B R Q N 44 B E J A L Q Fragrance Fixative vs Refractive Index 41 H R Q K J S M G 38 OSI with 10% Iron Oxide vs Moisturization E F C N B M D E F N R H L D I DT P D J S N H 36 B T A G F C F L T OSI vs OSI with 10% Iron Oxide 35 P E K M J B A S H O C E O G I J P O A RS I AQ T R I K B in vitro, hours - the number of hours before the test emollient begins rapid oxidation under standard test conditions. Larger values represent higher oxidative stability. in vitro, proportion (normalized). The proportion of Limonene fragrance remaining in the test emollient after 5 hours at 45°C, relative to squalane, as measured by Gas Chromatography. Larger values represent higher fragrance fixating ability. in vivo, unitless - is the Corneometer® value divided by the 24 hour TEWL value, proportional to (among others) water volume in the skin, divided by rate of water loss through transpiration through skin treated with test emollient. Larger values represent greater skin moisturization. in vivo, unitless - results are inversely proportional to the amount of test emollient remaining on the skin surface, 3 hours after application. Measurements taken by Sebumeter®. Larger values represent higher penetration. in vitro, unitless - measured by refractometer. Higher refractive index generally imparts more gloss. 9 rs ipj Flo r Jojo aes ba ters oil f l o - Refin m a r a m ed cad ac am ia o flo il ram Ref ine ac d 10 flo ras un 90 TRADE NAME ste INCI NAME rae Flo Flo rae ste rs 15 S o lu b i l i t y Data Acetone Butylene Glycol Caprylic/Capric Triglyceride Castor Oil Cyclomethicone Decyl Glucoside Decyl Oleate Dimethicone Ethyl Acetate Ethyl Alcohol Jojoba Esters Floraesters 15 Isopropyl Palmitate Lanolin Oil Mineral Oil Octyldodecyl Stearoyl Stearate Oleyl Alcohol Polysorbate 20 CAS EINECS JCIC PACKAGING 61789-91-1 307-351-1 520987 180 kg drum (standard) 16 kg (available) Floraesters IPJ 181314-46-5 * MHW Approved 180 kg drum (standard) 16 kg (available) Simmondsia Chinesis (Jojoba) Seed Oil Floraesters Jojoba Oil - Refined 61789-91-1 289-964-3 520987 180 kg drum (standard) 16 kg (available) Macadamia Integrifolia Seed Oil Floramac Macadamia Oil - Refined 159518-86-2 273-313-5 521074 190 kg drum (standard) 17 kg (available) Ethyl Macadamiate Floramac 10 214495-31-5 285-205-5 102246 190 kg drum (standard) 17 kg (available) Helianthus Annuus (Sunflower) Oil Florasun 90 8001-21-6 232-273-9 520924 190 kg drum (standard) 17 kg (available) Isopropyl Jojobate (&) Jojoba Alcohol (&) Jojoba Esters Glycerine Isononyl Isononanoate Isopropyl Alcohol Isopropyl Myristate All Floratech Emollients are: * 292-963-0 (&) 268-107-7 (&) 307-351-1 • Globally Approved • Bio/plant-based • Non-GMO • Non-BSE • No trans-fatty acids Find your local Floratech representative at www.floratech.com Polysorbate 80 PPG-15 Stearyl Ether Propylene Glycol Sodium Lauryl Sulfate, 30% solution Sorbitol Sunflower Oil Water = Soluble 10 = Partially Soluble ALL TESTS 50:50 at 25oC = Insoluble 11
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